WO2023078924A1 - Dispositif et procédé d'introduction d'un agent de conservation dans une boisson avec des capteurs de pression - Google Patents
Dispositif et procédé d'introduction d'un agent de conservation dans une boisson avec des capteurs de pression Download PDFInfo
- Publication number
- WO2023078924A1 WO2023078924A1 PCT/EP2022/080545 EP2022080545W WO2023078924A1 WO 2023078924 A1 WO2023078924 A1 WO 2023078924A1 EP 2022080545 W EP2022080545 W EP 2022080545W WO 2023078924 A1 WO2023078924 A1 WO 2023078924A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressure
- preservative
- pressure sensor
- pump
- sensors
- Prior art date
Links
- 239000003755 preservative agent Substances 0.000 title claims abstract description 74
- 230000002335 preservative effect Effects 0.000 title claims abstract description 72
- 235000013361 beverage Nutrition 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims description 16
- 239000007788 liquid Substances 0.000 claims abstract description 34
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 claims abstract description 22
- GZDFHIJNHHMENY-UHFFFAOYSA-N Dimethyl dicarbonate Chemical compound COC(=O)OC(=O)OC GZDFHIJNHHMENY-UHFFFAOYSA-N 0.000 description 12
- 235000010300 dimethyl dicarbonate Nutrition 0.000 description 12
- 239000004316 dimethyl dicarbonate Substances 0.000 description 12
- 230000008901 benefit Effects 0.000 description 9
- 239000000523 sample Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- 238000011049 filling Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- -1 phosphorus compound Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 235000014101 wine Nutrition 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical class C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 1
- 238000012371 Aseptic Filling Methods 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- AFCIMSXHQSIHQW-UHFFFAOYSA-N [O].[P] Chemical class [O].[P] AFCIMSXHQSIHQW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000019987 cider Nutrition 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- FFYPMLJYZAEMQB-UHFFFAOYSA-N diethyl pyrocarbonate Chemical compound CCOC(=O)OC(=O)OCC FFYPMLJYZAEMQB-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 150000004715 keto acids Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 235000010298 natamycin Nutrition 0.000 description 1
- 239000004311 natamycin Substances 0.000 description 1
- NCXMLFZGDNKEPB-FFPOYIOWSA-N natamycin Chemical compound O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C[C@@H](C)OC(=O)/C=C/[C@H]2O[C@@H]2C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 NCXMLFZGDNKEPB-FFPOYIOWSA-N 0.000 description 1
- 229960003255 natamycin Drugs 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/42—Preservation of non-alcoholic beverages
- A23L2/44—Preservation of non-alcoholic beverages by adding preservatives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/001—Details of apparatus, e.g. for transport, for loading or unloading manipulation, pressure feed valves
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
- A23L3/3517—Carboxylic acid esters
Definitions
- the invention relates to a device and a method for preserving beverages and the use of the device for this purpose.
- Preservatives such as dialkyl dicarbonates, sulfur dioxide, natamycin, benzoates or sorbates are used in the beverage industry for the cold sterilization of non-alcoholic carbonated or still fruit juice beverages, fruit juices, wines, non-alcoholic wines, ciders, ice teas and other beverages.
- the dialkyl dicarbonates such as in particular dimethyl dicarbonate or diethyl dicarbonate, are a special cold disinfectant and have a number of advantages.
- the outstanding advantage lies in the fact that taste and color are not affected, in contrast to hot filling.
- persistent preservatives such as sodium benzoate or benzoic acid or potassium sorbate or sorbic acid, the advantage consists in particular in the absence of any impairment of taste and the disappearance of the effect. Due to the decomposition of the dialkyl dicarbonates into harmless components, no preservative or preservative is consumed by the actual consumer.
- the devices with diaphragm pumps usually consist of a magnetically or electrically driven diaphragm pump, storage vessels, a device attached to the beverage line for atomizing the dialkyl dicarbonate, the flow meter attached to the beverage line, and an electronic control system. Dosing pumps of this type are usually permanently installed in the beverage line.
- the dosing pumps should be suitable for several different performance parameters, especially for small and very small quantities. In addition, these dosing pumps should have a high level of accuracy when dosing, a high atomization pressure and a wide control range.
- Dialkyl dicarbonates are thus dosed proportionally into the beverage tube in the required amount.
- Examples of these pumps are the VelcorinDT devices from Lanxess.
- WO1998042983A1 discloses a metering pump for the metered delivery of liquids.
- the dosing pumps used for such devices and methods must meet different performance parameters. On the one hand, they should be suitable for supplying small or very small quantities. In addition, these dosing pumps should have a high ness, but at the same time also provide a high atomization pressure and also have a wide control range, in particular for a wide variety of applications.
- the object of the present invention is therefore to improve monitoring of the supply of the preservative. According to the invention, this object is achieved by the subject matter of the independent patent claims. Advantageous embodiments and developments are the subject of the dependent claims.
- a device for preserving beverages has a measuring device which is suitable and intended for determining a flow rate of a liquid flowing through a beverage line and in particular of a beverage. Furthermore, the device has a pump device which conveys a preservative and in particular dialkyl dicarbonate into the beverage line and at least one receptacle for receiving the preservative (which is preferably arranged upstream of the pump device in a conveying direction of the preservative).
- the pump device can be controlled as a function of a flow rate of the drink determined by the measuring device.
- the device has a first and a second sensor and in particular a first and a second pressure sensor, the first sensor and in particular the pressure sensor and the second sensor and in particular the pressure sensor each measure a value characteristic of the preservative and/or a value characteristic of the flow of the preservative and in particular a pressure of the preservative.
- a (weight) sensor for example in the form of a load cell
- the weight of a container containing the preservative can be measured.
- a quantity of liquid removed from the container can be inferred from a weight difference and, in turn, a conveyed quantity can be inferred from this.
- the device has a processor device which uses the measured pressure and/or a pressure change to determine a quantity of the preservative supplied to the beverage line, for example taking into account a weight difference in a quantity of liquid which corresponds to this quantity of preservative. For example, a specific pressure difference measured inside a container or a weight difference in the container filled with the preservative can be used to deduce a weight difference in the liquid in the container and this weight difference in turn to a volume difference.
- the device has a further conveying device and in particular a further pump device, which conveys the preservative from the original receiving container (transport container) into the measuring receiving container. In particular, this can be implemented by using a vacuum pump or using compressed air.
- a preferred device has, for example, a storage container containing dimethyl dicarbonate and a lance in this container for sucking dimethyl dicarbonate into a buffer vessel.
- a lance leads the dialkyl dicarbonate into a buffer vessel, from the buffer vessel a dosing pump takes the disinfectant on the suction side and feeds it on the pressure side - preferably via a nozzle - into the beverage or into the beverage line.
- pressure sensors represent a relatively simple way of inferring the supply of the preservative into the beverage.
- pressure sensors are sometimes very expensive or that cheaper variants do not achieve the desired reliability.
- the invention therefore proposes providing two redundant pressure sensors which determine the pressure of the preservative.
- the pressure sensors can preferably be operated and/or read out independently of one another.
- redundant pressure sensors instead of redundant pressure sensors, redundant sensors of other types, for example redundant flow sensors, or weight sensors could also be used.
- the applicant therefore reserves the right to also claim protection for a device and a method which use redundant flow sensors or weight sensors.
- the pressure sensors and/or the device particularly preferably allow online flow measurement and in particular indirect online flow measurement.
- One way to measure and monitor the amount of dimethyl dicarbonate is to use pressure sensors.
- a small tank or a tube or a burette is used to store dialkyl dicarbonate.
- the fill level inside the storage vessel can now be determined using a pressure sensor, since the applied liquid pressure minus the air pressure is proportional to the fill level in the tank, tube or burette.
- the pressure sensor and in particular the at least two pressure sensors can be installed at different points of the storage vessel.
- the pressure sensor or the pressure sensors can be used near the bottom of the storage vessel in order to electronically determine a maximum and minimum fill level in the vessel and preferably to regulate the device accordingly.
- a level difference can be deduced from a pressure difference.
- the invention allows the preservative to be metered in proportionally, also as a function of the values output by the at least two pressure sensors.
- the device preferably has a control device which controls the pump device as a function of at least one pressure sensor and preferably of both pressure sensors or the values output by them.
- the device can have a flow measuring device which measures a flow of the preservative, in particular in the direction of the beverage line.
- This flow measuring device is preferably arranged on or in a pressure line which branches off from the pump device.
- the flow measuring device is arranged in a connecting line which connects the pump device to the beverage line.
- the pressure sensor is particularly preferably a pressure transmitter.
- This pressure sensor is therefore particularly preferably also suitable and determines measured values which are characteristic of a pressure of the liquid, in particular of the preservative.
- the pressure sensor has a membrane for pressure measurement arranged within a housing and in particular within a stainless steel housing.
- the pressure sensor is an electrically operated pressure sensor. The pressure sensor is preferably supplied with an operating voltage.
- the pressure sensor or the pressure sensors have a piezoresistive measuring cell and/or a thin-film measuring cell.
- a maximum pressure that can be measured with the pressure sensor is preferably greater than 5 bar, preferably greater than 10 bar, preferably greater than 20 bar and particularly preferably greater than 40 bar.
- the pressure sensor has a step response time that is less than 50 ms, preferably less than 40 ms, preferably less than 30 ms, preferably less than 20 ms and particularly preferably less than 10 ms. In this way, pressure differences can be determined very quickly.
- the pressure sensor(s) can preferably be used at ambient temperatures between -40.degree. C. and +85.degree.
- the pressure sensor or sensors can be used at temperatures of the preservative which are between -40°C and +125°C, preferably between -20°C and 100°C, preferably between -10°C and 90°C and particularly preferably between 0 °C and 70°C.
- At least one pressure sensor has a screw thread in order to be screwed onto an element of the device.
- Pressure sensors with the above properties were deliberately selected by the applicant in order to ensure reliable operation of a corresponding device.
- the pressure sensor particularly preferably allows these measured values to be output wirelessly.
- the pressure sensor is a differential pressure sensor.
- the pressure sensor is preferably arranged in such a way that the pressure difference directly a delivery rate of the preservative can be determined.
- At least one pressure sensor is preferably suitable and intended to output a signal which uniquely identifies this pressure sensor. In this way, it can be determined within a system which pressure value was output by which pressure sensor. In this way, for example, in the event of an error, a possibly defective pressure sensor can be determined very quickly.
- At least one pressure sensor can preferably be replaced while the device is in operation.
- One of the pressure sensors is particularly preferably a redundant pressure sensor. Both pressure sensors are preferably arranged in the same area of the system and/or measure the same pressure as intended. Both pressure sensors should therefore particularly preferably output the same values for the pressure. In this case, it would be possible for the first pressure sensor and the second pressure sensor to be arranged adjacent to one another.
- the first and second pressure sensors are preferably arranged in a region of the device in which the same preservative pressures are to be expected.
- the device has a comparison device which compares the pressure value measured by the first pressure sensor and the pressure value measured by the second pressure sensor. It is possible for a processor device to check whether any differences in the pressures that are output are within a specified tolerance range or within a specified threshold range.
- the processor device it is possible for the processor device to be suitable and intended to carry out a plausibility check on the values output by the pressure sensors. If, for example, one of the two pressure sensors fails completely and/or outputs technically unrealistic values, the values of the second pressure sensor can be used for control at least for temporary operation. At the same time, in this case, the information can be output to the user that a specific pressure sensor needs to be checked. In addition, it is also possible for an alarm to be issued when the deviation between the two pressure sensors is too high.
- the pressure is preferably measured several times and/or continuously.
- a pressure profile is preferably measured. From this pressure profile, a conclusion can be drawn as to the amount of preservative added to the beverage (per unit of time).
- a control device preferably also controls the device and in particular the pump device on the basis of the measured values output by at least one of the pressure sensors.
- the device Several approaches would be conceivable here. It would thus be conceivable for the device to be controlled on the basis of the value originating from one of the sensors and for the second pressure sensor to be used to check the correct functioning of the first sensor.
- the device prefferably controlled on the basis of a measured value that results from the measured values of the two pressure sensors, for example on the basis of an average of these values.
- the device particularly preferably has a memory device which stores the pressure values output by the pressure sensors over a predetermined period of time. It is also possible here for a profile of the recorded pressure values to be determined, in particular over time.
- the pressure sensors are particularly preferably pressure sensors of the same type and/or structurally identical. These are preferably arranged in such a way that essentially the same values are output during working operation if they are functioning properly. For example, in the case of a liquid line, both pressure sensors can be arranged in an identical alignment on this liquid line.
- the device has a removal device which removes the preservative from the or a receiving container takes.
- This removal device is preferably arranged on the receiving container in a detachable manner.
- this receptacle can be exchangeable.
- the removal device is particularly preferably designed in such a way that the preservative is sucked out of the receptacle.
- the removal device can preferably be designed as a lance or suction lance or suction tube.
- the suction preferably takes place in particular with the aid of the pump device mentioned above.
- a line can be provided that leads to the pump device or to a further receptacle.
- the removal device is assigned a sensor device and in particular a pressure sensor and/or a flow sensor device.
- This pressure sensor is particularly preferably arranged on an end section and/or a tip of the removal device or the removal lance, in particular an end section which protrudes into the preservative during operation.
- the sensor device assigned to the extraction device it would also be possible for the sensor device assigned to the extraction device to be a flow sensor.
- a further advantageous aspect of the invention are (pressure) sensors which are located at the tip of the lance, with the aid of which dialkyl dicarbonate is sucked out of the storage container. These sensors allow a fill level display in the storage container as well as a further control of the dosed quantity.
- the pump device is particularly preferably a diaphragm pump and in particular a magnetically and/or electrically actuated diaphragm pump.
- the device particularly preferably has a further receptacle, in particular in the form of a buffer receptacle, which can be filled with preservative removed from the receptacle.
- This buffer container is particularly preferably arranged in the flow path of the preservative between the receiving container and the pump device.
- the pump device preferably removes the preservative from said buffer container.
- the first pressure sensor and the second pressure sensor are preferably in this buffer container arranged and / or assigned to this buffer container.
- two sensors can be located on the bottom of the container in the buffer container or buffer vessel.
- two or one sensor can be provided at the overflow or the upper liquid level of this buffer container.
- the pressure sensors arranged on the bottom of the buffer container can measure a pressure of the preservative arranged in the buffer container.
- the device has at least one (suction) line arranged between the receptacle and the pump device, and one or the first and second pressure sensors are preferably arranged in or on this suction line.
- This suction line is particularly preferably provided between the buffer vessel and the pump device.
- a corresponding suction line it would also be possible for a corresponding suction line to be arranged between the receiving container and the further receiving container or the buffer container.
- Two pressure sensors are particularly preferably provided in the suction line as well as in the above-mentioned buffer container.
- a capacity of the second receptacle is preferably smaller than a capacity of the first receptacle.
- the device preferably contains two pressure sensors in the suction line, which also allows the correct functioning of the suction and the pump to be monitored.
- the device has at least one additional pressure sensor and preferably at least two additional pressure sensors, which are arranged downstream of the pump device in the direction of flow of the preservative.
- the one or more additional pressure sensors are preferably provided in a pressure line, which leads the preservative from the pump device to the feed point, in which the preservative is transferred into the beverage line.
- a pressure sensor in the pressure line allows additional diagnostics for the correct functioning of the pump, preferably via pressure curves.
- the metering pump pressure history curves can also be used as diagnostic indicators to monitor pump function.
- the device particularly preferably has an injection device in order to supply the preservative to the beverage line.
- This can be a nozzle, for example, which enables the preservative to be introduced into the beverage line under high pressure.
- a pressure sensor or two pressure sensors can be provided in the area of this injection device.
- At least one further sensor and in particular at least two further sensors are particularly preferably assigned to the buffer container. These can likewise be pressure sensors, but it would also be possible for these to be level sensors which check a pressure level in the buffer container.
- the buffer container particularly preferably has a capacity which is greater than 50 ml, preferably greater than 100 ml and preferably greater than 200 ml.
- the buffer container particularly preferably has a volume which is less than 12 l, preferably less than 8 l, preferably less than 5 l and preferably less than 3I.
- the device has a display device in order to display characteristic or essential data for the process (the supply of the preservative).
- a pressure value can be displayed, for example, or a value that is characteristic of a flow or other values.
- the device has a calibration device for calibrating the sensor devices. It is thus possible, for example, for two redundant pressure sensors (or also other sensors such as flow sensors) to be calibrated by this calibration device, so that their values are matched to one another as part of the calibration process. In particular, teaching the pressure sensors is possible in this way.
- a third pressure sensor is provided, with at least one preferably at least at least two of these pressure sensors are redundant.
- three pressure sensors per measuring point can be used to advantage.
- a deviating probe or a deviating sensor can be sorted out immediately (in particular mathematically) by comparison and error tolerance definitions. In this case, the device can continue to work and the pending service requirement for replacing the respective faulty probe or the faulty pressure sensor can be processed with sufficient time.
- the pressure sensors are preferably designed as probes.
- a deviating probe can be sorted out—preferably immediately—in particular mathematically by comparison and error tolerance definitions.
- the dosing device can continue to work and the pending service requirement to replace the respective faulty probe can be processed with sufficient time.
- the present invention is also directed to a method for preserving beverages, with a measuring device determining a flow rate of a liquid flowing through a beverage line and in particular a beverage, and a pump device conveying a preservative and in particular dialkyl dicarbonates into the beverage line and with the preservative being received in a receptacle is, the pump device being controlled as a function of a flow rate determined by the measuring device.
- the device has a first and a second sensor and in particular a pressure sensor, the first (pressure) sensor and the second (pressure) sensor measuring at least one pressure of the preservative.
- the first (pressure) sensor and the second (pressure) sensor measuring at least one pressure of the preservative.
- it would also be possible (in particular redundantly) to measure other properties such as a fill level or a flow rate (of the preservative) or a weight of the receptacle filled with the preservative.
- a pressure of the preservative means in particular the pressure that the (particularly liquid) preservative exerts on a pressure sensor arranged in a predetermined area. It is pointed out that a first and a second pressure sensor are preferably used redundantly here. However, it would also be possible to use other sensor devices such as flow sensor devices redundantly (which accordingly measure a flow of the preservative. The applicant reserves the right to also claim protection for such configurations.
- a preservative is conveyed from the receiving container into a further receiving container and in particular a buffer container.
- an active conveying device such as in particular a second pump device, can preferably be used.
- the measuring device which determines a flow rate of the liquid flowing through the beverage line
- the measuring device is a flow sensor.
- a pressure sensor it would also be possible for a pressure sensor to be used at this point.
- At least two measuring devices are also particularly preferably provided, which determine the flow rate of the liquid flowing through the beverage line.
- two redundant or one redundant measuring device are particularly preferably provided. In this way, greater security can also be enabled when determining the flow rate through the beverage line.
- dimethyl dicarbonate is used as the dialkyl dicarbonate, and even more preferably using dimethyl dicarbonate with a purity of >99.8% as the dialkyl dicarbonate.
- dimethyl dicarbonate is used which has been stabilized by suitable methods. Processes of this type, such as the use of a phosphorus compound from the group consisting of phosphorus oxides, phosphorus-oxygen acids and derivatives thereof, are known, for example, from EP 2 013 160 B1.
- EP 2 016 041 B1 describes the use of at least one protic acid from the series of inorganic acids and organic carboxylic acids and their derivatives, the organic carboxylic acids being saturated and mono- or polyunsaturated aliphatic monocarboxylic acids and saturated and one - or polyunsaturated aliphatic di- and polycarboxylic acids and their derivatives are hydroxamic acids, hydroxycarboxylic acids, aldehyde and keto acids, for the stabilization of dialkyl dicarbonates against chemical and thermal degradation reactions, the protic acid or mixtures thereof in an amount of 0.01 to 100,000 ppm based on dialkyl dicarbonates or mixtures thereof is used.
- dimethyl dicarbonate is used in a mixture with phosphorus compounds, such as preferably phosphates, even more preferably with trimethyl phosphate or phosphoric acid.
- phosphorus compounds such as preferably phosphates, even more preferably with trimethyl phosphate or phosphoric acid.
- the phosphorus compound is preferably used in an amount of between 0.01 ppm and 1000 ppm, based on the total amount of the mixture of dimethyl dicarbonate and phosphorus compounds.
- FIG. 1 shows a schematic representation of a device according to the invention.
- the reference number 10 designates a liquid line and in particular a beverage line, in which the liquid or the beverage is conveyed to a container 20 .
- the reference number 3 designates a measuring device such as, in particular but not exclusively, a flow sensor which is suitable and intended for determining the flow rate of the beverage flowing through the liquid line 10 .
- the reference number 4 designates a pump device, which is used to supply a preservative to the beverage via a supply line and in particular a pressure line 6 and a nozzle 10a. This pump device 4 is controlled by a control device 14 .
- the measuring device 3 transmits to the control device 14 a value that is characteristic of the flow rate of the liquid flowing through the liquid line, and the control device controls the pump device taking this value into account.
- the reference number 8 designates a first receiving container, which serves to receive the liquid preservative.
- This receptacle is preferably interchangeable and is preferably designed without a sensor device.
- the reference number 32 designates a removal device which is suitable and intended for removing the liquid from the receptacle. This removal device is preferably designed as a hollow lance which sucks the preservative out of the receptacle.
- Reference number 45 designates a sensor and in particular a pressure sensor which, in an advantageous embodiment, is arranged at a lower end of the removal device.
- Preservative removed from the receptacle 8 (for example using a pump device 27) is fed via a connecting line 26 (shown only schematically) to a further receptacle 18, which is designed here as a buffer container.
- a connecting line 26 shown only schematically
- the supply and the function of the pump device 27 can also be implemented , either by applying excess pressure to the container 8 and thus conveying the preservative further, or alternatively by applying negative pressure to the container 18 , whereby the preservative is sucked into the container 18 .
- the pump device 4 can suck the preservative out of the buffer container 18 via a connecting line 34 .
- the connecting line can also go down from the bottom of the buffer tank.
- the buffer tank 18 allows the To continue to operate device 1 in the periods in which the receptacle 8 is replaced.
- the buffer vessel can take various forms and can be vented or it can be sealed from the environment.
- the buffer container can also be operated with either aeration or non-aeration, controlled by a valve.
- the height of the liquid column in the buffer container influences the pressure difference to be measured for different filling states. Buffer tanks that are built higher can therefore be advantageous in order to increase the measured values of the pressure differences in different filling states.
- At least one first pressure sensor 22 and preferably two pressure sensors 22, 24 are arranged on the bottom of the buffer container. A pressure of the liquid within the buffer container 18 can be determined by means of this pressure sensor 22 and the filling level of the liquid in the buffer container can thus be inferred.
- At least two weight force sensors could also be provided, which measure the weight of the receptacle 18 filled with the preservative. These weight force sensors (not shown) would preferably be arranged below the receiving container.
- a change in the pressure results in a corresponding change in the fill level, and in this way it is possible to draw conclusions about a quantity of the preservative conveyed by the pump device 4 and thus about a quantity of the quantity supplied to the beverage line 10 .
- a pressure sensor or preferably two pressure sensors 52, 54 can also be provided on the connecting line. From the measured values output by these pressure sensors 52, 54 it is also possible (additionally or alternatively) to infer a flow of the liquid through the connecting line 34 and thus a delivery quantity.
- Reference number 56 designates a fill level sensor which determines a fill level of the preservative inside the receptacle 18 . The data measured by this level sensor is used in particular to check the values output by the pressure sensors.
- the buffer vessel 18 there are, for example, two sensors 22, 24 at the bottom of the buffer vessel 18, two sensors (only one sensor 56 shown) at the overflow or upper liquid level, and two sensors in the pressure line.
- the reference symbols 62 and 64 identify further pressure sensors which are arranged in the pressure line 6 in addition or as an alternative to the sensors described above. A delivery quantity of the preservative fed to the beverage line 10 can also be determined in this way.
- these pressure sensors can also be used to check whether the preservative is being supplied to the liquid line at a pressure that is sufficient or is within predetermined limits.
- the individual measured values of the sensors are preferably supplied to the control device 14, which controls and in particular regulates the pump device on the basis of these measured values.
- the pump device preferably also has at least one sensor device 42 and preferably a plurality of sensor devices 42, 44.
- This can be, for example, position sensors that determine the position of specific pump elements.
- current or voltage sensors can also be involved, which determine values that are characteristic of the operation of the pump device, or the like.
- the values of these sensor devices are also preferably supplied to the control device 14 for controlling and/or regulating the pump device 4 .
- Reference number 30 designates a display and/or operating device for operating the device.
- This display and/or operating device 30 is preferably suitable and intended for outputting information that is important for the operation of the device, such as measured pressures or the like.
- user inputs can preferably also be made via this display and/or operating device 30 .
- a fill level display and/or pressure display and/or flow rate display can be visualized directly on a touch panel (the display and/or operating device 30. This makes it possible to announce the bottle change to the operator in good time.
- An advantage of the pressure sensors described above is their low price compared to other components.
- a device according to FIG. 1 was used for dosing dimethyl dicarbonate into an apple spritzer. After about 20 hours of operation, it was observed that the sensor 22 had an electronic defect. Since the two sensors 22 and 24 were monitored by the controller and after averaging the difference between the individual values and the mean exceeded 10%, which served as a control limit and was exceeded, an alarm message could be triggered in the system controller. This enabled the operator to take note of the fault. At the same time, by eliminating the faulty signal (outside the defined pressure limits), continued operation of the device until the pressure sensor was replaced was ensured by the device only including one of the pressure sensors for dosing control.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Dentistry (AREA)
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- Devices For Dispensing Beverages (AREA)
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Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22813210.6A EP4387466A1 (fr) | 2021-11-04 | 2022-11-02 | Dispositif et procédé d'introduction d'un agent de conservation dans une boisson avec des capteurs de pression |
MX2024003532A MX2024003532A (es) | 2021-11-04 | 2022-11-02 | Aparato y metodo para suministrar un conservante en una bebida con sensores de presion. |
CN202280067942.4A CN118102885A (zh) | 2021-11-04 | 2022-11-02 | 利用压力传感器将防腐剂供给到饮料的装置和方法 |
AU2022381333A AU2022381333A1 (en) | 2021-11-04 | 2022-11-02 | Device and method for feeding a preservative into a beverage with pressure sensors |
CONC2024/0005726A CO2024005726A2 (es) | 2021-11-04 | 2024-04-30 | Aparato y método para suministrar un conservante en una bebida con sensores de presión |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21206578 | 2021-11-04 | ||
EP21206578.3 | 2021-11-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2023078924A1 true WO2023078924A1 (fr) | 2023-05-11 |
Family
ID=78528778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2022/080545 WO2023078924A1 (fr) | 2021-11-04 | 2022-11-02 | Dispositif et procédé d'introduction d'un agent de conservation dans une boisson avec des capteurs de pression |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP4387466A1 (fr) |
CN (1) | CN118102885A (fr) |
AU (1) | AU2022381333A1 (fr) |
CO (1) | CO2024005726A2 (fr) |
MX (1) | MX2024003532A (fr) |
WO (1) | WO2023078924A1 (fr) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998042983A1 (fr) | 1997-03-22 | 1998-10-01 | Lang Apparatebau Gmbh | Pompe de dosage pour refouler des liquides de maniere dosee |
WO2009043715A1 (fr) * | 2007-09-26 | 2009-04-09 | Lanxess Deutschland Gmbh | Procédé de dosage de dicarbonates de dialkyle dans des boissons |
WO2010062548A1 (fr) * | 2008-10-27 | 2010-06-03 | Pepsico, Inc. | Système conservateur pour boissons basé sur des combinaisons d'acide trans-cinnamique, d'arginate de lauryle et de dicarbonate de diméthyle |
EP2013160B1 (fr) | 2006-04-22 | 2012-07-11 | LANXESS Deutschland GmbH | Stabilisation de diesters d'acide dicarbonique comprenant des composés phosphorés |
EP2016041B1 (fr) | 2006-04-22 | 2013-08-07 | LANXESS Deutschland GmbH | Stabilisation de diesters d'acide dicarbonique comprenant des acides protoniques |
DE102015011424A1 (de) * | 2015-09-01 | 2017-03-02 | Fresenius Medical Care Deutschland Gmbh | Verfahren zur Kalibrierung und / oder Überwachung eines Flusssensors |
-
2022
- 2022-11-02 EP EP22813210.6A patent/EP4387466A1/fr active Pending
- 2022-11-02 MX MX2024003532A patent/MX2024003532A/es unknown
- 2022-11-02 AU AU2022381333A patent/AU2022381333A1/en active Pending
- 2022-11-02 WO PCT/EP2022/080545 patent/WO2023078924A1/fr active Application Filing
- 2022-11-02 CN CN202280067942.4A patent/CN118102885A/zh active Pending
-
2024
- 2024-04-30 CO CONC2024/0005726A patent/CO2024005726A2/es unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998042983A1 (fr) | 1997-03-22 | 1998-10-01 | Lang Apparatebau Gmbh | Pompe de dosage pour refouler des liquides de maniere dosee |
EP2013160B1 (fr) | 2006-04-22 | 2012-07-11 | LANXESS Deutschland GmbH | Stabilisation de diesters d'acide dicarbonique comprenant des composés phosphorés |
EP2016041B1 (fr) | 2006-04-22 | 2013-08-07 | LANXESS Deutschland GmbH | Stabilisation de diesters d'acide dicarbonique comprenant des acides protoniques |
WO2009043715A1 (fr) * | 2007-09-26 | 2009-04-09 | Lanxess Deutschland Gmbh | Procédé de dosage de dicarbonates de dialkyle dans des boissons |
WO2010062548A1 (fr) * | 2008-10-27 | 2010-06-03 | Pepsico, Inc. | Système conservateur pour boissons basé sur des combinaisons d'acide trans-cinnamique, d'arginate de lauryle et de dicarbonate de diméthyle |
DE102015011424A1 (de) * | 2015-09-01 | 2017-03-02 | Fresenius Medical Care Deutschland Gmbh | Verfahren zur Kalibrierung und / oder Überwachung eines Flusssensors |
Also Published As
Publication number | Publication date |
---|---|
CN118102885A (zh) | 2024-05-28 |
EP4387466A1 (fr) | 2024-06-26 |
MX2024003532A (es) | 2024-04-01 |
CO2024005726A2 (es) | 2024-05-30 |
AU2022381333A1 (en) | 2024-03-28 |
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