WO2023063287A1 - Procédé et appareil de production d'une substance utile - Google Patents

Procédé et appareil de production d'une substance utile Download PDF

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Publication number
WO2023063287A1
WO2023063287A1 PCT/JP2022/037773 JP2022037773W WO2023063287A1 WO 2023063287 A1 WO2023063287 A1 WO 2023063287A1 JP 2022037773 W JP2022037773 W JP 2022037773W WO 2023063287 A1 WO2023063287 A1 WO 2023063287A1
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Prior art keywords
steam
raw material
pressure
opening
producing
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PCT/JP2022/037773
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English (en)
Japanese (ja)
Inventor
三郎 松井
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Ｇ－８ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｔｒａｄｉｎｇ株式会社
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Publication of WO2023063287A1 publication Critical patent/WO2023063287A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/78—Recycling of wood or furniture waste

Definitions

  • the present invention relates to a method and apparatus for producing useful substances, and in particular, to a method and apparatus for producing useful substances that use wood as a raw material, particularly fulvic acid/humic acid and wood acetic acid.
  • Humic substances such as fulvic acid and humic acid are said to be a generic term for "organic substances with unspecified chemical structures (non-living organic substances)" that are organic substances that have decayed due to microbial and chemical action after the death of living organisms. There is It is empirically known that some humic substances exhibit functionality and others do not. It is considered that whether or not the intermediate product is included in the process has a large effect. A humic substance that exhibits functionality when it contains this intermediate product is sometimes referred to as a humic precursor. (Non-Patent Document 1)
  • Patent Document 1 discloses a wastewater treatment method using a bacterial group consisting of soil-dwelling facultative anaerobic bacteria cultivated to produce metabolites containing phenol and/or compounds with phenol-exposed groups. It is a technology related to This "metabolite containing a phenol or/and a compound with a phenol-exposed group" causes a polycondensation reaction of humification by reacting with silicic acid, etc., and is an excellent wastewater that utilizes humus. It is intended to disclose a processing method.
  • humic plants are known to contain humin, fulvic acid, humic acid, etc. as the degree of humification (degree of polycondensation reaction) of their components.
  • Common humic substances contain fulvic acid and humic acid at a weight ratio of about 2:8.
  • Patent Document 1 in the process of treating wastewater containing organic substances, there are those that use substances corresponding to this humic substance, but fulvic acid, humic acid, etc. in humic substances are not simple substances, Because of the fact that all of them are regarded as a group of multiple organic compounds, and because it is difficult to separate them, there has not been sufficient research on which substances have what effects specifically. .
  • commercially available solutions containing fulvic acid are also expected to be effective as (micro)biologically active liquids, and are also suitable for applications such as agriculture where large quantities of products are required to be provided at the lowest possible cost. In order to utilize , there is a demand for a product that selectively contains fulvic acid at a high concentration.
  • Patent Document 2 Japanese Patent Application Laid-Open No. 2017-112947
  • Patent Document 2 regarding fulvic acid, which is expected to be used as a (micro)biologically active liquid among humic substances, compared to the ratio of general humic substances, humin
  • the following production method has been proposed for the purpose of providing a method for producing a fulvic acid-rich liquid containing a high ratio of fulvic acid to acid.
  • an organic substance mixed liquid in which an organic substance and fulvic acid-acclimated sludge are mixed is heated to a dissolved oxygen concentration of 0.1 mg-O / L or less for 4 hours.
  • an anaerobic culture step in which the organic substance in the organic substance mixture is reduced by anaerobic culture to obtain an anaerobic culture solution, and a dissolved oxygen concentration of 0.2 mg-O / in the anaerobic culture solution.
  • the method for producing fulvic acid proposed in this patent publication is a sealed container having a closable processing space therein; steam ejection means for ejecting high-temperature and high-pressure steam into the closed container; , an apparatus preparation step of preparing a processing apparatus having an opening/closing mechanism and a discharge unit for discharging the processing liquid generated by processing the raw material with the steam to the outside; A raw material charging step of charging a raw material containing wood chips as a main raw material from the supply unit into the processing space of the closed container of the processing apparatus; While introducing steam having a temperature of 120 to 250° C.
  • the raw material is subjected to subcritical water reaction treatment while stirring the raw material, a process step of obtaining a mixed solution containing a suspension of fulvic acid, humic acid and wood chips and/or fragments thereof, and A method for producing a fulvic acid solution, comprising a step of obtaining a fulvic acid solution by separating fulvic acid from the obtained mixed solution.
  • fulvic acid with good purity can be produced efficiently.
  • wood contains a number of other useful substances (including useful substances derived from wood). was not utilized effectively.
  • an object of the present invention is to provide a useful substance manufacturing method and a manufacturing apparatus for manufacturing two or more useful substances using wood as a raw material.
  • a device preparation step of preparing a device A raw material charging step of charging a raw material containing wood chips as a main raw material from the supply unit into the processing space of the closed container of the processing apparatus; While introducing steam having a temperature of 120 to 200° C.
  • the raw material is carbonized by a subcritical water reaction while stirring the raw material.
  • a second subcritical water treatment step of obtaining a second mixed solution containing the formed carbonized solid and pyroligneous acid produced along with the carbonization;
  • a final pressure reduction step of opening the steam exhaust valve to exhaust high pressure steam from the processing space to reduce the pressure in the processing space from high pressure to atmospheric pressure;
  • a second liquid recovery step of opening the opening/closing valve to recover only the liquid that will be the raw material of pyroligneous acid from the processing space, and a solid recovery step of opening the opening/closing mechanism to recover solid carbide from the processing space.
  • a method for producing a useful substance comprising: (2) The method for producing a useful substance according to (1) above, wherein the maximum temperature holding time is 15 to 20 minutes in the first subcritical water treatment step. (3) The method for producing a useful substance according to (1) or (2), wherein the maximum temperature holding time is 15 to 20 minutes in the second subcritical water treatment step. (4) The method for producing a useful substance according to (1), wherein the wood is felled wood or waste wood. (5) The method for producing a useful substance according to (4) above, wherein the felled timber is from a broad-leaved tree or a coniferous tree.
  • the processing equipment includes a condensing means connected to the steam outlet, and the condensing means recovers the wood-derived volatile organic compounds from the high-pressure steam ejected from the steam outlet by condensing the (1) ) to (16).
  • a useful substance manufacturing apparatus for manufacturing at least two kinds of useful substances by processing wood chips as raw materials comprising: a closed container having a closable processing space therein; and supplying raw materials into the closed container.
  • a supply unit for the purpose, a steam ejection means for ejecting high-temperature and high-pressure steam into the sealed container, an opening/closing valve for discharging only the liquid from the closed container, and an opening/closing mechanism for discharging the solid matter.
  • an outlet a steam outlet having a steam outlet valve for discharging high-pressure steam from the closed container, and a wood-derived volatile organic compound connected to the steam outlet and ejected from the high-pressure steam ejected from the steam outlet.
  • a useful substance manufacturing apparatus equipped with condensing means for condensing and recovering compounds.
  • FIG. 2 is a diagram showing changes in treatment pressure and treatment temperature in a treatment step in the method for producing a useful substance of the present invention.
  • the manufacturing apparatus 10 includes a sealed container 12 having a closed space S1, which is a processing space for containing raw materials, which are wood chips, and a steam jet for jetting high-temperature and high-pressure steam, which is subcritical water, into the closed container 12.
  • means 14 a discharge port 16 provided on the bottom side of the sealed container 12 and having an opening/closing mechanism 26, and a separating and recovering means 18 for separating and collecting the raw material and the liquid which have been treated only by the direct discharge operation from the discharge port 16. and have.
  • the shape of the closed container 12 may be, for example, a rectangular box shape, a three-dimensional polygonal cylinder shape, a cylindrical shape, a barrel shape, a drum shape, or any other shape. A shape that is ejected is preferred. It is preferable that the bottom surface of the closed container is inclined downward toward the outlet.
  • the separation and recovery means 18 includes a liquid recovery section 50 communicating with the inside of the sealed container 12 through the discharge port 16, and recovers only the liquid in the closed container 12 to the recovery section 50 by gravity flow through the discharge port 16. It is good also as having a gravity collection mechanism 52 and.
  • the raw material as a solid content processed near the discharge port 16 remains in the closed container 12 as it is, and only the liquid naturally flows down to the recovery section 50 using gravity, so that the raw material and the liquid can be separated and recovered.
  • the recovery unit 50 may have any configuration, such as a metal tank, a three-dimensional polygonal box, or a tubular body, as long as it has a closed space S2 for recovering the liquid. A plurality of accommodating portions may be formed.
  • the separation means is incorporated in the processing apparatus, but the separation means may be provided separately in the processing apparatus itself.
  • the gravity recovery mechanism 52 also includes a liquid recovery channel 54 that communicates and connects the discharge port 16 of the sealed container 12 and the recovery unit 50 . It may be provided horizontally or downwardly toward the 50 side.
  • an opening/closing mechanism 26 is provided in the middle of the discharge route R1 from the discharge port 16 of the processed raw material, and the liquid introduction port 58 of the liquid recovery channel 54 is connected to the discharge upstream side of the opening/closing mechanism 26 .
  • liquid recovery channel 54 is selected so as to block the channel during the processing of the raw material in the sealed container 12 and to allow the channel to communicate when only the liquid is recovered after the processing.
  • An opening/closing valve 60 is provided for switching between them.
  • the bottom surface of the closed space S2 of the recovery unit 50 may be provided lower than the position of the discharge port 16 of the sealed container 12.
  • the sealed container 12 is preferably formed in a sideways barrel shape in which a discharge port 16 is provided on the bottom side of the left-right central portion and the diameter gradually decreases from the left-right central portion toward the left and right end sides.
  • a stirring member 30 is provided inside the sealed container 12 .
  • the stirring means 30 is provided horizontally coaxially with the horizontal central axis of the sealed container 12, and has a rotating shaft 49 rotatably supported at both ends thereof. and a stirring blade 48 extending in the circumferential direction, and the length from the rotating shaft 49 of the stirring blade 48 to the tip of the blade corresponds to the overturned barrel shape of the closed container 12, as shown in the figure. It is preferable that it is formed so that it is large at the central position in the longitudinal direction of 49 and gradually becomes smaller toward both ends.
  • the steam jetting means 14 includes a rotating shaft/steam jetting pipe 28 configured by forming a plurality of steam jetting holes 44 on the peripheral surface of the hollow tube with the rotating shaft 49 as a hollow tube. good too.
  • the sealed container 12 is preferably supported by supporting legs so as to be positioned at a certain height from the ground. It is preferable that the closed container 12 is formed by processing a metal plate so as to have heat resistance and pressure resistance, and that the closed space inside is provided with a size of about 2 m 3 or more.
  • the airtight container 12 is provided with an inlet section 20 at the central upper portion and an outlet section 22 at the central bottom portion, and is provided with opening/closing mechanisms 24 and 26, respectively, so that it can be opened and closed.
  • the sealed container 12 is provided with, for example, a safety valve (not shown) capable of adjusting the set pressure, which releases the internal steam when the internal pressure becomes higher than the set value.
  • a silencing/deodorizing device is provided in the middle of the exhaust pipe connected to the safety valve, and the steam exhausted through the safety valve is muted and deodorized before being discharged to the outside air.
  • the diameter of the discharge port 16 is, for example, about 300 mm.
  • a downward projecting discharge tube 36 is connected to the discharge port 16 to form the discharge route R1 for the processed raw material.
  • the opening/closing mechanism 26 for opening and closing the discharge port 16 is provided in the middle of the discharge path R1 of the discharge tube 36.
  • the discharge section 22 is configured to include the discharge port 16 , the discharge tube 36 , and the opening/closing mechanism 26 . Since the sealed container 12 is formed in a barrel-like shape lying down, the raw material inside tends to gather from the left and right toward the central portion where the discharge port 16 is provided due to gravity, and can be easily processed simply by opening the opening and closing mechanism 26. The finished raw material can be discharged from the discharge port 16 .
  • the input port 42 is opened in the center of the upper side of the sealed container 12 in the input part 20, and the input cylinder 43 projecting upward is attached to the input port 42, and the inside of the input cylinder 43 is opened and closed.
  • the opening/closing mechanism 24 is provided as follows. Via the opening/closing mechanism 24, the input port 42 can be opened to input the raw material into the closed container, and closed during processing to maintain the closed state of the closed space S1 in the closed container 12. ⁇
  • the steam ejecting means 14 ejects high-temperature, high-pressure steam into the sealed container 12, and sets the inside of the closed container 12 to a high-temperature, high-pressure state, and processes the raw material using the steam.
  • the steam ejection means 14 includes a steam ejection pipe 28 which is a hollow tube arranged in the sealed container 12 and formed with a large number of steam ejection holes 44 on the peripheral surface side, and a steam generator such as a boiler.
  • the steam generator 46 includes a steam supply control valve 46a for controlling the supply state and the supply stop state of the generated steam, and by closing the steam supply control valve 46a, the supply of steam can be temporarily stopped. It is possible.
  • the steam supply control valve 46 a may be provided in the steam pipe 47 .
  • the steam jetted from the steam jetting means 14 into the sealed container 12 is set to a high temperature and high pressure that satisfies the conditions of subcritical water in order to properly treat the raw material.
  • the steam ejected from the steam ejection pipe 28 has a temperature of 120 to 250° C. and a pressure of 4 to 30 atm.
  • the inside of the sealed container 12 is kept at a temperature of 120 to 250° C. and a pressure of 4 to 30 atm.
  • the steam ejection pipe 28 is arranged long in the horizontal direction at a substantially central position in the vertical direction of the sealed container 12, and is rotatably supported via bearings 45 provided on both end walls 12a and 12b of the sealed container. That is, the steam ejection pipe 28 is adapted to directly apply the steam to the raw material while rotating around the horizontal axis and ejecting the steam radially.
  • the steam ejection pipe 28 is rotated by receiving rotational driving force from a rotational driving device (not shown) such as a motor through a chain 70 or the like. Further, the steam ejection pipe 28 is attached with a stirring blade 48 that constitutes the stirring means, and the steam ejection pipe 28 also serves as a rotating shaft 49 of the stirring means.
  • the steam ejecting means 14 is a rotating shaft and steam configured by using a hollow tube as the rotating shaft 49 of the stirring means and forming a plurality of steam ejecting holes on the peripheral surface of the hollow tube.
  • the steam ejection means is not limited to this configuration, and may be of any other configuration, such as a configuration in which steam is ejected from the tip of a pipe inserted into a closed container, a configuration in which a plurality of steam ejection pipes are arranged, and the like. good.
  • the stirring means 30 is a means for stirring raw materials to be processed in a closed container, and can process the raw materials evenly and quickly.
  • the stirring means 30 includes a rotating shaft 49 made up of the steam ejection pipe 28, and stirring blades 48 attached to the rotating shaft 49 and having portions extending in the circumferential direction of the rotating shaft.
  • the stirring blade 48 is formed of a right-handed spiral blade 48a and a left-handed spiral blade 48b, which are provided at a substantially central position in the axial direction of the rotating shaft 49 so as to be wound in opposite directions.
  • the stirring blades 48 are provided such that the length from the rotating shaft to the tip of the blade gradually decreases in diameter from the left-right central portion toward both ends.
  • the raw material can be reliably agitated corresponding to the overturned barrel shape of the closed container 12 . Furthermore, it is provided so as to form a certain amount of gap H between the tip of the blade and the inner wall of the closed container 12 .
  • the spiral blades 48a and 48b stir the raw material while crushing the solid raw material while conveying the raw material from the central portion toward the both end wall sides.
  • the raw material conveyed to the side of both end walls 12a and 12b by the stirring blade 48 is pushed by the raw material that is subsequently conveyed on the side of the end walls 12a and 12b, along the inner wall of the sealed container 12 and through the gap H. Transported back to center.
  • the stirring means 30 is not limited to the configuration described above, and may be of any other configuration.
  • the separation/recovery means 18 is a separation/recovery means that separates and recovers the processed raw material and the liquid in the sealed container 12 after steam treatment only by direct operation from the discharge port. As shown in FIG. 1, the separation and recovery means 18 includes a liquid recovery section 50 that communicates with the inside of the sealed container 12 through the discharge port 16, and the recovery section 50 recovers the liquid through the discharge port 16 by gravity flow. and a gravity recovery mechanism 52 .
  • the liquid recovery channel 54 has a liquid inlet port 58 connected to the discharge port 16 so as to form a liquid recovery route R2 branched from the processed raw material discharge route R1.
  • the liquid recovery channel 54 is provided by, for example, a metal tube having an inner diameter of about 6 mm.
  • the liquid recovery channel 54 is provided with the opening/closing valve 60 for selectively switching the communication state of the channel, as described above.
  • the opening/closing valve 60 is switched so as to block the flow path during the processing of the raw material in the closed container and open the flow path when only the liquid is separated and recovered after the processing.
  • the moisture and steam contained in the raw material are liquefied at the same time as the raw material, and the liquid containing bacteria and malodorous components in the raw material can be treated with high-temperature, high-pressure steam.
  • the liquid separated and recovered after the treatment can be recovered in a state such as sterilization or decomposition of odors and harmful components. Time can be shortened.
  • a volatile useful substance recovery mechanism 30 such as terpene oil is provided in the upper part of the closed container 12, and this volatile useful substance recovery mechanism 30 is connected to the high-pressure high-temperature steam discharge port 19 provided in the closed container 12.
  • a high-temperature and high-pressure steam discharge pipe 31 communicating with the closed space S1 via a steam discharge valve 32 provided upstream of the high-temperature and high-pressure steam discharge pipe 31, and receiving the high-temperature and high-pressure steam from the steam discharge valve 32.
  • Condensing means 34 for cooling and condensing said high pressure and high temperature steam to recover a liquid containing volatile organic compounds derived from wood, and a storage vessel to which the liquid from said condensing means 34 is conveyed via a line 35. 38.
  • the liquid stored in the storage container 38 is a liquid containing volatile organic compounds derived from wood as described above, and the volatile organic compounds are extracted from the liquid as necessary to produce products.
  • the manufacturing apparatus 10 is composed of a central processing circuit and the like, and according to a predetermined program stored in advance, the opening/closing mechanism 26, the steam discharge valve 32, the steam generator 46, the steam supply control valve 46a, the opening/closing valve 60, etc.
  • a control circuit 100 is provided to control the operation.
  • a method for producing a useful substance according to an embodiment of the present invention comprises an apparatus preparation step of preparing the processing apparatus as described above; A raw material charging step of charging a raw material containing wood chips as a main raw material from the supply unit into the processing space of the closed container of the processing apparatus; While introducing steam having a temperature of 120 to 200° C.
  • the raw material is carbonized by a subcritical water reaction while stirring the raw material.
  • a second subcritical water treatment step of obtaining a second mixed solution containing the formed carbonized solid and pyroligneous acid produced along with the carbonization;
  • a final pressure reduction step of opening the steam exhaust valve to exhaust high pressure steam from the processing space to reduce the pressure in the processing space from high pressure to atmospheric pressure;
  • the main raw material is wood chips.
  • the size of the chip is preferably about 50 to 150 cm on the long side and about 5 cm on the short side 2 .
  • an alkaline solution can be added in order to efficiently produce more fulvic acid.
  • the vapor pressure and temperature when adding the alkaline solution may be the same as when not adding.
  • the felled wood may be either broad-leaved trees or coniferous trees.
  • any broad-leaved tree may be used, but at present, for example, white birch, willow, chestnut, oak, beech, etc. are preferably used.
  • conifers pine, cedar, Japanese cypress, Asunaro, etc. can be preferably used at present.
  • felled wood it is not necessary to remove the bark or the like. It may also contain leaves, roots, or fruit shells such as coconut shells as they are or in the form of chips.
  • Waste materials include wood chips (square timbers, planks: solid timbers, laminated timbers/plywood timbers (plywood)) generated during the demolition of wooden houses. Since such wood waste is generally made into chips, it can be used as it is as a raw material.
  • the raw materials mentioned above may be mixed and used. For example, when trees are felled in ordinary households, felled wood of various kinds of trees is discharged. These woods may be used as a raw material by mixing the whole wood as chips without sorting them. Of course, waste chips may be mixed therein.
  • the raw materials which are chips as described above, are put into the processing space, and the amount of raw materials is preferably 90% or less, particularly 50 to 80%, of the closed space S1 of the closed container 12, that is, the processing space. If the input amount of raw material is lower than this range, the treatment efficiency is poor, and if it exceeds this range, the steam may not act well on the raw material, resulting in insufficient production of fulvic acid.
  • ⁇ First subcritical water treatment process>> high-pressure high-temperature steam is introduced into the processing space in which the raw materials are charged, and the raw materials are subjected to a subcritical water reaction treatment while stirring the raw materials to obtain fulvic acid, humic acid, and wood chips. and/or obtain a first mixed solution containing solids of the fragments.
  • the steam should have a temperature of 120 to 200° C. and a pressure of 4 to 15 atm. Therefore, the inside of the processing space is set to a processing temperature and pressure of 120 to 200° C. and a pressure of 4 to 15 atm.
  • the amount of steam introduced depends on the volume of the processing space and the amount of raw material to be processed, but should be the amount that completely fills the surplus space (the space obtained by subtracting the volume of the raw material introduced from the processing space). is preferred.
  • the high-pressure high-temperature steam supplied in the treatment process preferably has a temperature of 120 to 200° C. and a pressure of 4 to 15 atm.
  • the high-pressure and high-temperature steam supplied in the treatment process preferably has a temperature of 140 to 200° C. and a pressure of 5 to 15 atm.
  • steam is introduced into the treatment space into which the raw material is introduced, and the raw material is stirred to treat the raw material by the subcritical water reaction.
  • the duration of the treatment step is preferably 15 to 20 minutes at the maximum temperature/maximum pressure retention time, that is, the set treatment temperature/pressure.
  • the treatment time is shorter than the above range, the reaction time is insufficient, that is, the production of fulvic acid and humic acid is not sufficient, and a considerable amount of fulvic acid and humic acid remains in the raw material. If the above range is exceeded, the raw material will be carbonized, and unintended substances will be mixed into the solution.
  • the raw material is subjected to subcritical water reaction treatment, and fulvic acid and humic acid are contained in the solution.
  • This solution also contains a suspension of wood chips and/or fragments thereof.
  • a mixed solution containing fulvic acid, humic acid and a suspension of wood chips and/or fragments thereof is obtained.
  • the mixed solution obtained in this step contains 3 to 12% of fulvic acid in the total amount of fulvic acid and humic acid (in solid content).
  • the steam exhaust valve 32 is opened to partially exhaust high-pressure steam from the processing space, thereby lowering the pressure in the processing space from the high pressure.
  • This pressure drop is for enabling the next first liquid recovery step to be carried out safely and efficiently. It is not necessary to lower the pressure to atmospheric pressure. Although the temperature also drops with this pressure drop, it is extremely small, and the drop is about several degrees Celsius including the temperature drop in the next first liquid recovery step. The drop in temperature is due to natural cooling. In order to efficiently perform the second subcritical water treatment step to be performed later, it is desirable that the temperature drop be as small as possible.
  • the vapor discharged in this process is guided to the condensing means 34, where it is condensed with a liquid containing useful components such as volatile components, and collected in a storage container 38 via a conduit 35. be done.
  • ⁇ First liquid recovery step>> In this step, while the opening/closing mechanism 26 is kept closed, the opening/closing valve 60 is opened, and the liquid (mixed solution of fulvic acid/humic acid) that is the raw material of fulvic acid/humic acid is discharged from the processing space into a liquid recovery stream. It is recovered to the recovery section 50 via the path 54 . Although the mixed solution may be used as it is, humic acid and fulvic acid are separated from this mixed solution to obtain a fulvic acid solution and a humic acid solution. The separation of humic acid and fulvic acid in this acquisition step is carried out by making the pH of the solution acidic and separating humic acid by precipitation or separation by filtration.
  • the pH of the solution is preferably 2-3. At this time, the solid content remains in the closed container 12 and waits for the next treatment.
  • the pressure reduction step and the first liquid recovery step are preferably performed by closing the steam supply control valve 46a and temporarily stopping the supply of steam to the sealed container 12. As shown in FIG.
  • the solids remaining in the treatment space are treated with sub-critical water with steam having a higher temperature and pressure than the steam used in the first sub-critical water treatment step. That is, while introducing steam having a temperature of 200 to 250 ° C. and a pressure of 15 to 30 atm into the processing space, the raw material is carbonized by a subcritical water reaction while stirring the raw material. A second mixed solution is obtained which contains the carbonized solid matter and the pyroligneous acid produced along with the carbonization.
  • coconut shell is used as the material, it becomes a well-known coconut shell activated carbon, which is a particularly preferable useful substance.
  • This liquid is a pyroligneous acid-rich liquid that can be used as a sterilizing liquid, a crop growth inhibitor, a crop growth promoter, a deodorant, etc., by simply diluting it to a predetermined dilution concentration without purification or the like. can be used.
  • FIG. 2 shows changes in processing pressure and processing temperature in the above processing steps.

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  • Oil, Petroleum & Natural Gas (AREA)
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  • Wood Science & Technology (AREA)
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  • Processing Of Solid Wastes (AREA)

Abstract

La présente invention concerne un procédé de production d'une substance utile en traitant des copeaux de bois, qui sont une matière première, en vue de produire au moins deux substances utiles, lequel est caractérisé en ce qu'il comprend : une étape de préparation de dispositif destinée à préparer un dispositif de traitement pourvu d'un contenant étanche à l'air, d'une partie d'alimentation, d'un moyen de projection de vapeur, d'une partie formant orifice de décharge ayant une vanne d'ouverture/fermeture et un mécanisme d'ouverture/fermeture, et d'un orifice de décharge de vapeur ayant une vanne de décharge de vapeur ; une étape d'introduction de matière première destinée à introduire une matière première contenant des copeaux de bois en tant que matière première principale depuis la partie d'alimentation dans un espace de traitement du contenant étanche à l'air du dispositif de traitement ; une première étape de traitement à l'eau sous-critique destinée à introduire de la vapeur ayant une température allant de 120 à 200 °C et une pression allant de 4 à 15 atm dans l'espace de traitement dans lequel a été introduite la matière première tout en agitant la matière première et en effectuant un traitement de réaction à l'eau sous-critique sur la matière première afin d'obtenir une première solution mélangée contenant de l'acide fulvique, de l'acide humique et des matières solides de copeaux et/ou de fragments de bois ; une étape intermédiaire de réduction de la pression pour ouvrir la vanne de décharge de vapeur et décharger la vapeur à haute pression de l'espace de traitement afin d'abaisser la pression dans l'espace de traitement depuis une pression élevée ; une étape de récupération de liquide pour ouvrir la vanne d'ouverture/fermeture afin de récupérer uniquement un liquide servant de matière première pour l'acide fulvique/acide humique à partir de l'espace de traitement ; une étape de fermeture pour fermer la vanne de décharge de vapeur et la vanne d'ouverture/fermeture ; une deuxième étape de traitement à l'eau sous-critique destinée à introduire une vapeur ayant une température allant de 200 à 250 °C et une pression allant de 15 à 30 atm dans l'espace de traitement dans lequel se trouve la matière solide tout en agitant la matière première afin d'obtenir une matière solide carbonisée formée en carbonisant la matière première au moyen d'une réaction à l'eau sous-critique et une deuxième solution mixte contenant un vinaigre de bois généré selon la carbonisation ; une étape finale de réduction de la pression pour ouvrir la vanne de décharge de vapeur et décharger la vapeur à haute pression depuis l'espace de traitement afin d'abaisser la pression dans l'espace de traitement de la haute pression à la pression atmosphérique ; une étape de récupération du liquide pour ouvrir la vanne d'ouverture/fermeture afin de récupérer uniquement le liquide devant être une matière première pour le vinaigre de bois à partir de l'espace de traitement ; et une étape de récupération du solide pour ouvrir le mécanisme d'ouverture/fermeture afin de récupérer le carbure solide à partir de l'espace de traitement.
PCT/JP2022/037773 2021-10-12 2022-10-11 Procédé et appareil de production d'une substance utile WO2023063287A1 (fr)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57111380A (en) * 1980-11-14 1982-07-10 Baiyaa Erunsuto Method of obtaining solid, liquid and gaseous fuel from organic raw material
JP2001192670A (ja) * 1999-10-29 2001-07-17 Ryoichi Okamoto 炭化物の製造方法および有機廃棄物の熱分解装置
JP2003047409A (ja) * 2001-08-07 2003-02-18 Toshimasa Itakura 原料加工方法、飼料製造方法、肥料製造方法並びに原料加工装置
JP2012228683A (ja) * 2011-04-12 2012-11-22 Jfe Shoji Trade Corp 熱帯植物廃棄物、又は木質系廃棄物の処理方法と、そのリサイクル方法
JP2018111055A (ja) * 2017-01-10 2018-07-19 株式会社ファインテック 植物系バイオマスの改質方法
WO2019043961A1 (fr) * 2017-08-31 2019-03-07 Ｇ－８ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｔｒａｄｉｎｇ 株式会社 Procédé de production d'une solution d'acide fulvique, et solution d'acide fulvique
JP2020537623A (ja) * 2017-09-13 2020-12-24 シャルテッガー プロイェクトプラーヌンゲン 木材、樹皮、穀物わら、葉、草本植物、木菌、下水汚泥およびその他の有機廃棄物などのバイオマスからの腐植物質の生産プロセス
JP2021066801A (ja) * 2019-10-23 2021-04-30 宮崎みどり製薬株式会社 土壌のｐＨ調整材及びこれを用いた土壌のｐＨ調整方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57111380A (en) * 1980-11-14 1982-07-10 Baiyaa Erunsuto Method of obtaining solid, liquid and gaseous fuel from organic raw material
JP2001192670A (ja) * 1999-10-29 2001-07-17 Ryoichi Okamoto 炭化物の製造方法および有機廃棄物の熱分解装置
JP2003047409A (ja) * 2001-08-07 2003-02-18 Toshimasa Itakura 原料加工方法、飼料製造方法、肥料製造方法並びに原料加工装置
JP2012228683A (ja) * 2011-04-12 2012-11-22 Jfe Shoji Trade Corp 熱帯植物廃棄物、又は木質系廃棄物の処理方法と、そのリサイクル方法
JP2018111055A (ja) * 2017-01-10 2018-07-19 株式会社ファインテック 植物系バイオマスの改質方法
WO2019043961A1 (fr) * 2017-08-31 2019-03-07 Ｇ－８ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｔｒａｄｉｎｇ 株式会社 Procédé de production d'une solution d'acide fulvique, et solution d'acide fulvique
JP2020537623A (ja) * 2017-09-13 2020-12-24 シャルテッガー プロイェクトプラーヌンゲン 木材、樹皮、穀物わら、葉、草本植物、木菌、下水汚泥およびその他の有機廃棄物などのバイオマスからの腐植物質の生産プロセス
JP2021066801A (ja) * 2019-10-23 2021-04-30 宮崎みどり製薬株式会社 土壌のｐＨ調整材及びこれを用いた土壌のｐＨ調整方法

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