WO2023050609A1 - 金属加工切削液及其制备方法 - Google Patents
金属加工切削液及其制备方法 Download PDFInfo
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- WO2023050609A1 WO2023050609A1 PCT/CN2021/141135 CN2021141135W WO2023050609A1 WO 2023050609 A1 WO2023050609 A1 WO 2023050609A1 CN 2021141135 W CN2021141135 W CN 2021141135W WO 2023050609 A1 WO2023050609 A1 WO 2023050609A1
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- parts
- cutting fluid
- corrosion inhibitor
- emulsifier
- fluid according
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 44
- 239000002184 metal Substances 0.000 title claims abstract description 44
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003112 inhibitor Substances 0.000 claims abstract description 72
- 238000005260 corrosion Methods 0.000 claims abstract description 61
- 230000007797 corrosion Effects 0.000 claims abstract description 60
- -1 alcohol amine Chemical class 0.000 claims abstract description 35
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 34
- 150000002148 esters Chemical class 0.000 claims abstract description 29
- 239000002253 acid Substances 0.000 claims abstract description 27
- 239000013556 antirust agent Substances 0.000 claims abstract description 24
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000013329 compounding Methods 0.000 claims abstract description 22
- 150000001408 amides Chemical class 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002199 base oil Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 14
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical group NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000001412 amines Chemical class 0.000 claims abstract description 11
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims abstract description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005555 metalworking Methods 0.000 claims description 21
- 150000002191 fatty alcohols Chemical class 0.000 claims description 12
- 229940049964 oleate Drugs 0.000 claims description 12
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 12
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims description 11
- 239000012964 benzotriazole Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000008233 hard water Substances 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000004135 Bone phosphate Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Definitions
- the invention relates to the technical field of cutting fluids, in particular to metalworking cutting fluids and a preparation method thereof.
- Cutting fluid is an industrial liquid used in metal cutting and grinding processes to cool and lubricate tools and workpieces.
- the cutting fluid is made of a variety of super functional additives through scientific compounding. It also has good cooling performance, lubricating performance, anti-rust performance, degreasing and cleaning function, anti-corrosion function, and easy dilution. It overcomes the shortcomings of traditional soap-based emulsions, which are easy to smell in summer, difficult to dilute in winter, and poor anti-rust effect, and has no adverse effect on lathe paint. It is suitable for cutting and grinding of ferrous metals. It is a leading semi-synthetic product at present.
- the present invention provides a cutting fluid for metal processing.
- the invention also provides a preparation method of the cutting fluid for metal processing.
- a cutting fluid for metal processing comprising the following components: alcohol amine, antirust agent, base oil, synthetic ester, amide, emulsifier, corrosion inhibitor, metal corrosion inhibitor and water;
- the alcohol amine is compounded by triethanolamine It is obtained from a special amine, which is diglycolamine or 2-amino-2-methyl-1-propanol;
- the antirust agent is compounded by a film-forming agent with a ternary organic polycarboxylic acid or a dibasic acid And get.
- the metal processing cutting fluid mentioned above uses amides and emulsifiers to make the emulsified particles of the cutting fluid small, has good cleaning performance, and has low foaming properties; good lubrication performance; ordinary triethanolamine is used to compound special amines, so that the product has good alkali reserve.
- the anti-rust agent uses a film-forming agent polyacid compounded with tribasic acid and dibasic acid, which not only has better anti-rust performance, but also has good resistance to hard water; this product is not Contains substances that are harmful to the environment and the human body, and has good environmental protection performance.
- the metalworking cutting fluid includes the following components in parts by weight: 10-20 parts of alcohol amine, 10-15 parts of rust inhibitor, 15-35 parts of base oil, 8-15 parts of synthetic ester, 2-6 parts of amide, 2-8 parts of emulsifier, 0.5-1 part of corrosion inhibitor, 1-3 parts of metal corrosion inhibitor and 10-25 parts of water.
- the film-forming agent is a polymeric acid.
- the ternary organic polycarboxylic acid is TAT730 or NEUF485, and the dibasic acid is sebacic acid or dodecanedioic acid.
- the synthetic ester is one or a combination of trihydroxypropane oleate, pentaerythritol oleate and tetrameric ricinoleate.
- the emulsifier is alkoxylated fatty alcohol.
- the corrosion inhibitor is one or a combination of benzotriazole and benzotriazole derivatives.
- the metal corrosion inhibitor is silicone.
- the present invention also provides a kind of preparation method of described metal working cutting fluid, comprises the following steps:
- the stirring time in both the step S1 and the step S2 is 10 min-15 min.
- the invention provides a metalworking cutting fluid, comprising the following components: alcohol amine, antirust agent, base oil, synthetic ester, amide, emulsifier, corrosion inhibitor, metal corrosion inhibitor and water; the alcohol amine consists of three It is obtained by compounding ethanolamine with a special amine, and the special amine is diglycolamine or 2-amino-2-methyl-1-propanol; the antirust agent is obtained by compounding a film-forming agent with a ternary organic polycarboxylic acid or Dibasic acid derived.
- the above metalworking cutting fluid includes the following components by weight: 10-20 parts of alcohol amine, 10-15 parts of rust inhibitor, 15-35 parts of base oil, 8-15 parts of synthetic ester, 2-6 parts of amide 2-8 parts of emulsifier, 0.5-1 part of corrosion inhibitor, 1-3 parts of metal corrosion inhibitor and 10-25 parts of water.
- the cutting fluid system has good protection for aluminum alloy and good adaptability to human skin.
- the product does not contain phosphorus, boron, sodium nitrite and other substances harmful to the environment and human body, so it has good environmental protection performance.
- Alcohol amine is obtained by compounding triethanolamine with special amine, and the special amine is diglycolamine or 2-amino-2-methyl-1-propanol.
- the use of the alcohol amine can dissolve acidic substances such as antirust agents to prevent rust, and at the same time provide an alkaline environment to achieve antibacterial effects.
- the antirust agent is obtained by compounding a film-forming agent with a ternary organic polycarboxylic acid or a dibasic acid.
- the anti-rust agent can be neutralized with alkali after compounding, and has good anti-rust performance.
- the film-forming agent is polymeric acid.
- the ternary organic polycarboxylic acid is TAT730 or NEUF485.
- the dibasic acid is sebacic acid or dodecane dibasic acid.
- TAT730 is from Lupu Chemical Technology
- NEUF485 is from Nuotai Bio.
- the synthetic ester is one or a combination of trihydroxypropane oleate, pentaerythritol oleate and tetrapolyricinoleate. This combination provides good lubrication and extrusion properties.
- Amide not only acts as an emulsifier, but also enhances the anti-rust performance.
- One dose has multiple effects to achieve the best anti-rust performance.
- Emulsifiers are alkoxylated fatty alcohols. Alkoxylated fatty alcohols such as one or more of RT42 or RT64. This emulsifier not only has good emulsifying effect, but also has low foam.
- the corrosion inhibitor is one or a combination of benzotriazole and benzotriazole derivatives.
- the corrosion inhibitor is siloxane.
- the present invention also provides the preparation method of above-mentioned metalworking cutting fluid, comprises the steps:
- the stirring time in both step S1 and step S2 is 10min-15min. Agitation at this time also serves to homogenize the components.
- the metal processing cutting fluid mentioned above uses amides and emulsifiers to make the emulsified particles of the cutting fluid small, has good cleaning performance, and has low foaming properties; good lubrication performance; ordinary triethanolamine is used to compound special amines to make the product have good alkali reserves.
- the product has a good anti-rust environment and antibacterial performance;
- the anti-rust agent uses a film-forming agent polyacid compounded with tribasic acid and dibasic acid, which not only has better anti-rust performance, but also has good resistance to hard water; this product is not Contains substances that are harmful to the environment and the human body, and has good environmental protection performance.
- This embodiment provides a metalworking cutting fluid, which consists of the following components in parts by weight: 15 parts of alcohol amine, 12 parts of rust inhibitor, 25 parts of base oil, 12 parts of synthetic ester, 4 parts of amide, 5 parts of emulsifier, 0.8 parts of corrosion inhibitor, 2 parts of metal corrosion inhibitor and 18 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, and the antirust agent is obtained by compounding three-component film-forming agent It is obtained from organic polycarboxylic acid TAT730, the synthetic ester is trihydroxypropane oleate, the emulsifier is alkoxylated fatty alcohol RT64, the corrosion inhibitor is benzotriazole, and the metal corrosion inhibitor is silicone ketone.
- This embodiment provides a metalworking cutting fluid, which consists of the following components by weight: 10 parts of alcohol amine, 10 parts of rust inhibitor, 15 parts of base oil, 8 parts of synthetic ester, 2 parts of amide, 2 parts of emulsifier, 0.5 parts of corrosion inhibitor, 1 part of metal corrosion inhibitor and 10 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and 2-amino-2-methyl-1-propanol in a mass ratio of 2:1.
- the agent is obtained by compounding sebacic acid with film forming agent, the synthetic ester is pentaerythritol oleate, the emulsifier is alkoxylated fatty alcohol RT64, the corrosion inhibitor is a derivative of benzotriazole, and the metal corrosion inhibitor is Silicone.
- This embodiment provides a metalworking cutting fluid, which is composed of the following components by weight: 20 parts of alcohol amine, 15 parts of rust inhibitor, 35 parts of base oil, 15 parts of synthetic ester, 6 parts of amide, 8 parts of emulsifier, 1 part of corrosion inhibitor, 3 parts of metal corrosion inhibitor and 25 parts of water, among which, the alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, and the antirust agent is compounded by film forming agent It is obtained from carbon dibasic acid, the synthetic ester is tetrameric ricinoleic acid ester, the emulsifier is alkoxylated fatty alcohol RT64, the corrosion inhibitor is a derivative of benzotriazole, and the metal corrosion inhibitor is silicone ketone .
- This embodiment provides a metalworking cutting fluid, which is composed of the following components by weight: 18 parts of alcohol amine, 13 parts of rust inhibitor, 20 parts of base oil, 12 parts of synthetic ester, 3 parts of amide, 5 parts of emulsifier, 0.6 parts of corrosion inhibitor, 2.5 parts of metal corrosion inhibitor and 20 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, and antirust agent is obtained by compounding TAT730 with film forming agent
- the synthetic ester is trihydroxypropane oleate
- the emulsifier is alkoxylated fatty alcohol RT64
- the corrosion inhibitor is benzotriazole
- the metal corrosion inhibitor is silicone ketone.
- This comparative example provides a metal processing cutting fluid, which is composed of the following components in parts by weight: 15 parts of alcohol amine, 12 parts of rust inhibitor, 25 parts of base oil, 12 parts of synthetic ester, 4 parts of amide, 5 parts of emulsifier, 0.8 parts of corrosion inhibitor, 2 parts of metal corrosion inhibitor and 18 parts of water, among which, alcohol amine is triethanolamine, antirust agent is obtained by compounding TAT730 with film forming agent, synthetic ester is trihydroxypropane oleate, emulsifier It is alkoxylated fatty alcohol RT64, the corrosion inhibitor is benzotriazole, and the metal corrosion inhibitor is siloxane.
- This comparative example provides a metal processing cutting fluid, which is composed of the following components in parts by weight: 15 parts of alcohol amine, 12 parts of rust inhibitor, 25 parts of base oil, 12 parts of synthetic ester, 4 parts of amide, 5 parts of emulsifier, 0.8 parts of corrosion inhibitor, 2 parts of metal corrosion inhibitor and 18 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, the antirust agent is TAT730, and the synthetic ester is trihydroxy Propane oleate RT64, emulsifier is alkoxylated fatty alcohol, corrosion inhibitor is benzotriazole, metal corrosion inhibitor is siloxane.
- This comparative example provides a metalworking cutting fluid, which is composed of the following components by weight: 15 parts of alcohol amine, 12 parts of antirust agent, 37 parts of base oil, 0 part of synthetic ester, 4 parts of amide, 5 parts of emulsifier, 0.8 parts of corrosion inhibitor, 2 parts of metal corrosion inhibitor and 18 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, and the antirust agent is obtained by compounding TAT730 with film forming agent
- the emulsifier is alkoxylated fatty alcohol
- the corrosion inhibitor is benzotriazole
- the metal corrosion inhibitor is silicone.
- This comparative example provides a metal processing cutting fluid, which is composed of the following components in parts by weight: 15 parts of alcohol amine, 12 parts of rust inhibitor, 25 parts of base oil, 12 parts of synthetic ester, 4 parts of amide, 5 parts of emulsifier, 0.8 parts of corrosion inhibitor, 2 parts of metal corrosion inhibitor and 18 parts of water, among which, alcohol amine is obtained by compounding triethanolamine and diglycolamine in a mass ratio of 1:1, and the antirust agent is obtained by compounding TAT730 with film forming agent
- the synthetic ester is trihydroxypropane oleate
- the emulsifier is fatty alcohol polyoxyethylene ether AEO9
- the corrosion inhibitor is benzotriazole
- the metal corrosion inhibitor is silicone ketone.
- Comparative Example 1 uses a single alcohol amine, and its antirust and antibacterial properties are relatively weak; Comparative Example 2 uses a single antirust agent, and its antirust and hard water resistance are relatively weak; Comparative Example 3 does not add synthetic esters, etc.
- the lubricating performance is relatively weak; in comparative example 4, different emulsifier fatty alcohol polyoxyethylene ether AEO9 is used, and the foam is relatively more.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
一种金属加工切削液及其制备方法，该金属加工切削液包括如下组分：醇胺、防锈剂、基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂、金属缓蚀剂及水；所述醇胺由三乙醇胺复配特殊胺而得，所述特殊胺为二甘醇胺或2-氨基-2-甲基-1-丙醇；所述防锈剂由成膜剂复配三元酸或二元酸而得。所述的金属加工切削液，清洗性、润滑性、防锈性及抗硬水性能好，具有环保特性。
Description
本发明涉及切削液技术领域，特别是涉及金属加工切削液及其制备方法。
切削液是一种用在金属切削、磨削加工过程中，用来冷却和润滑刀具、加工件的工业用液体。切削液由多种超强功能助剂经科学复合配合而成，同时具备良好的冷却性能、润滑性能、防锈性能、除油清洗功能、防腐功能、易稀释特点。克服了传统皂基乳化液夏天易臭、冬天难稀释、防锈效果差的的毛病，对车床漆也无不良影响，适用于黑色金属的切削及磨加工，属当前领先的半合成产品。
切削液各项指标均优于皂化油，它具有良好的润滑冷却、清洗、防锈等特点。目前市面上的金属加工切削液很多防锈和清洗性能相对较弱，对人体有害。
发明内容
基于此，为解决上述问题，本发明提供一种金属加工切削液。
本发明还提供一种金属加工切削液的制备方法。
一种金属加工切削液，包括如下组分：醇胺、防锈剂、基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂、金属缓蚀剂及水；所述醇胺由三乙醇胺复配特殊胺而得，所述特殊胺为二甘醇胺或2-氨基-2-甲基-1-丙醇；所述防锈剂由成膜剂复配三元有机聚羧酸或二元酸而得。
上述的金属加工切削液，采用酰胺配合乳化剂，使得切削液乳化颗粒小， 清洗性好，具有低泡特性；润滑性能好；采用普通三乙醇胺复配特殊胺，让产品具有良好的碱储备，保证产品具有良好防锈环境和抑菌性能；防锈剂采用成膜剂多聚酸复配三元酸和二元酸，不仅具有更好的防锈性，而且抗硬水性能好；该产品不含等对环境和人体有危害的物质，环保性能好。
一实施例中，所述的金属加工切削液，包括如下重量份的组分：醇胺10-20份、防锈剂10-15份、基础油15-35份、合成酯8-15份、酰胺2-6份、乳化剂2-8份、腐蚀抑制剂0.5-1份、金属缓蚀剂1-3份及水10-25份。
一实施例中，所述成膜剂为多聚酸。
一实施例中，所述三元有机聚羧酸为TAT730或NEUF485，所述二元酸为癸二酸或十二碳二元酸。
一实施例中，所述合成酯为三羟基丙烷油酸酯、季戊四醇油酸酯及四聚蓖麻油酸酯中的一种或几种的组合。
一实施例中，所述乳化剂为烷氧基化脂肪醇。
一实施例中，所述腐蚀抑制剂为苯并三氮唑及苯并三氮唑的衍生物中的一种或几种的组合。
一实施例中，所述金属缓蚀剂为硅氧烷酮。
本发明还提供一种所述的金属加工切削液的制备方法，包括如下步骤：
S1、依次将水、醇胺和防锈剂加入容器中，搅拌至溶解；
S2、依次将基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂及金属缓蚀剂加入所述容器中，搅拌至均匀透明。
一实施例中，所述步骤S1与所述步骤S2中的搅拌时间均为10min-15min。
为了便于理解本发明，下面将对本发明进行更全面的描述。但是，本发明可以以许多不同的形式来实现，并不限于本文所描述的实施例。相反地，提供这些实施例的目的是使对本发明的公开内容的理解更加透彻全面。
除非另有定义，本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的，不是旨在于限制本发明。
本发明提供一种金属加工切削液，包括如下组分：醇胺、防锈剂、基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂、金属缓蚀剂及水；所述醇胺由三乙醇胺复配特殊胺而得，所述特殊胺为二甘醇胺或2-氨基-2-甲基-1-丙醇；所述防锈剂由成膜剂复配三元有机聚羧酸或二元酸而得。
进一步地，上述的金属加工切削液包括如下重量份的组分：醇胺10-20份、防锈剂10-15份、基础油15-35份、合成酯8-15份、酰胺2-6份、乳化剂2-8份、腐蚀抑制剂0.5-1份、金属缓蚀剂1-3份及水10-25份。
该切削液体系对铝合金保护好，且对人体皮肤适应性好。同时该产品不含磷、硼、亚硝酸钠等对环境和人体有危害物质，因此环保性能好。
例如，醇胺10份、11份、13份、14份、16份、17份、18份、19份及20份；防锈剂10份、11份、12.5份、13份、13.2份、14份、14.5份及15份；基础油15份、18份、20份、22份、26份、28份、30份、32份、34份及35份；合成酯8份、9份、10份、10.5份、11份、12份、13份、14份及15份；酰胺2份、2.5份、3份、3.4份、4份、4.5份、5份、5.5份及6份；乳化剂2份、2.5份、2.8份、3份、3.5份、4份、5份、6份、7份及8份；腐蚀抑制剂0.5份、0.5份、0.7份、0.75份、0.8份、0.9份及1份；金属缓蚀剂1份、1.2份、1.5份、2份、2.2份、2.6份、2.8份及3份；水10份、12份、15份、 18份、20份、21份、23份及25份。
醇胺由三乙醇胺复配特殊胺而得，特殊胺为二甘醇胺或2-氨基-2-甲基-1-丙醇。采用该醇胺可将防锈剂等酸性物质溶解起到防锈作用，同时提供碱性环境起到抑菌效果。
防锈剂由成膜剂复配三元有机聚羧酸或二元酸而得。防锈剂复配后可与碱中和，起到良好的防锈性能。其中，成膜剂为多聚酸。三元有机聚羧酸为TAT730或NEUF485。二元酸为癸二酸或十二碳二元酸。TAT730来自绿普化工科技，NEUF485来自诺泰生物。
合成酯为三羟基丙烷油酸酯、季戊四醇油酸酯及四聚蓖麻油酸酯中的一种或几种的组合。该组合可以提供良好润滑和挤压性能。
酰胺不仅起到乳化作用，同时可以增强防锈性能，一剂多效，达到最好的防锈性能。
乳化剂为烷氧基化脂肪醇。烷氧基化脂肪醇如RT42或RT64中的一种或多种。这种乳化剂不仅乳化效果好，而且泡沫低。
腐蚀抑制剂为苯并三氮唑及苯并三氮唑的衍生物中的一种或几种的组合。
缓蚀剂为硅氧烷酮。
本发明还提供上述的金属加工切削液的制备方法，包括如下步骤：
依次将去离子水、醇胺及防锈剂加入容器中，搅拌至溶解；
在容器中依次加入润滑剂、腐蚀抑制剂及金属缓蚀剂，搅拌至均匀透明。
其中，步骤S1与步骤S2中的搅拌时间均为10min-15min。在该时间搅拌也可以将各组分混合均匀。
上述的金属加工切削液，采用酰胺配合乳化剂，使得切削液乳化颗粒小，清洗性好，具有低泡特性；润滑性能好；采用普通三乙醇胺复配特殊胺，让产 品具有良好的碱储备，保证产品具有良好防锈环境和抑菌性能；防锈剂采用成膜剂多聚酸复配三元酸和二元酸，不仅具有更好的防锈性，而且抗硬水性能好；该产品不含等对环境和人体有危害的物质，环保性能好。
以下将通过几个实施例来进一步说明本发明的实施方式。
实施例一
本实施例提供一种金属加工切削液，由如下重量份的组分组成：醇胺15份、防锈剂12份、基础油25份、合成酯12份、酰胺4份、乳化剂5份、腐蚀抑制剂0.8份、金属缓蚀剂2份及水18份，其中，醇胺由三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂由成膜剂复配三元有机聚羧酸TAT730而得，合成酯为三羟基丙烷油酸酯，乳化剂为烷氧基化脂肪醇RT64，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
实施例二
本实施例提供一种金属加工切削液，由如下重量份的组分组成：醇胺10份、防锈剂10份、基础油15份、合成酯8份、酰胺2份、乳化剂2份、腐蚀抑制剂0.5份、金属缓蚀剂1份及水10份，其中，醇胺由三乙醇胺与2-氨基-2-甲基-1-丙醇2:1质量比复配而得，防锈剂由成膜剂复配癸二酸而得，合成酯为季戊四醇油酸酯，乳化剂为烷氧基化脂肪醇RT64，腐蚀抑制剂为苯并三氮唑的衍生物，金属缓蚀剂为硅氧烷酮。
实施例三
本实施例提供一种金属加工切削液，由如下重量份的组分组成：醇胺20份、防锈剂15份、基础油35份、合成酯15份、酰胺6份、乳化剂8份、腐蚀抑制剂1份、金属缓蚀剂3份及水25份，其中，醇胺由三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂由成膜剂复配十二碳二元酸而得，合成酯为四聚蓖麻油 酸酯，乳化剂为烷氧基化脂肪醇RT64，腐蚀抑制剂为苯并三氮唑的衍生物，金属缓蚀剂为硅氧烷酮。
实施例四
本实施例提供一种金属加工切削液，由如下重量份的组分组成：醇胺18份、防锈剂13份、基础油20份、合成酯12份、酰胺3份、乳化剂5份、腐蚀抑制剂0.6份、金属缓蚀剂2.5份及水20份，其中，醇胺由三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂由成膜剂复配TAT730而得，合成酯为三羟基丙烷油酸酯，乳化剂为烷氧基化脂肪醇RT64，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
对比例一
本对比例提供一种金属加工切削液，由如下重量份的组分组成：醇胺15份、防锈剂12份、基础油25份、合成酯12份、酰胺4份、乳化剂5份、腐蚀抑制剂0.8份、金属缓蚀剂2份及水18份，其中，醇胺为三乙醇胺，防锈剂由成膜剂复配TAT730而得，合成酯为三羟基丙烷油酸酯，乳化剂为烷氧基化脂肪醇RT64，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
对比例二
本对比例提供一种金属加工切削液，由如下重量份的组分组成：醇胺15份、防锈剂12份、基础油25份、合成酯12份、酰胺4份、乳化剂5份、腐蚀抑制剂0.8份、金属缓蚀剂2份及水18份，其中，醇胺由三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂为TAT730，合成酯为三羟基丙烷油酸酯RT64，乳化剂为烷氧基化脂肪醇，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
对比例三
本对比例提供一种金属加工切削液，由如下重量份的组分组成：醇胺15份、 防锈剂12份、基础油37份、合成酯0份、酰胺4份、乳化剂5份、腐蚀抑制剂0.8份、金属缓蚀剂2份及水18份，其中，醇胺为三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂由成膜剂复配TAT730而得，乳化剂为烷氧基化脂肪醇，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
对比例四
本对比例提供一种金属加工切削液，由如下重量份的组分组成：醇胺15份、防锈剂12份、基础油25份、合成酯12份、酰胺4份、乳化剂5份、腐蚀抑制剂0.8份、金属缓蚀剂2份及水18份，其中，醇胺为三乙醇胺与二甘醇胺1:1质量比复配而得，防锈剂由成膜剂复配TAT730而得，合成酯为三羟基丙烷油酸酯，乳化剂为脂肪醇聚氧乙烯醚AEO9，腐蚀抑制剂为苯并三氮唑，金属缓蚀剂为硅氧烷酮。
以下将对上述各实施例以及对比例进行实验，以对比其对铝合金的保护性、防锈以及润滑性能等相关技术数据，结果见表一。
表一
对比例一采用了单一的醇胺，防锈和抑菌性能相对较弱；对比例二采用单一的防锈剂，防锈性和抗硬水性能相对较弱；对比例三不加合成酯用等量基础代替，润滑性能相对较弱；对比例四采用不同的乳化剂脂肪醇聚氧乙烯醚AEO9，泡沫相对较多。
以上所述实施例的各技术特征可以进行任意的组合，为使描述简洁，未对上述实施例中的各个技术特征所有可能的组合都进行描述，然而，只要这些技术特征的组合不存在矛盾，都应当认为是本说明书记载的范围。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。
Claims (10)
- 一种金属加工切削液，其特征在于，包括如下组分：醇胺、防锈剂、基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂、金属缓蚀剂及水；所述醇胺由三乙醇胺复配特殊胺而得，所述特殊胺为二甘醇胺或2-氨基-2-甲基-1-丙醇；所述防锈剂由成膜剂复配三元有机聚羧酸或二元酸而得。
- 根据权利要求1所述的金属加工切削液，其特征在于，包括如下重量份的组分：醇胺10-20份、防锈剂10-15份、基础油15-35份、合成酯8-15份、酰胺2-6份、乳化剂2-8份、腐蚀抑制剂0.5-1份、金属缓蚀剂1-3份及水10-25份。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述成膜剂为多聚酸。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述三元有机聚羧酸为TAT730或NEUF485，所述二元酸为癸二酸或十二碳二元酸。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述合成酯为三羟基丙烷油酸酯、季戊四醇油酸酯及四聚蓖麻油酸酯中的一种或几种的组合。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述乳化剂为烷氧基化脂肪醇。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述腐蚀抑制剂为苯并三氮唑及苯并三氮唑的衍生物中的一种或几种的组合。
- 根据权利要求1或2所述的金属加工切削液，其特征在于，所述金属缓蚀剂为硅氧烷酮。
- 一种如权利要求1-8任一项所述的金属加工切削液的制备方法，其特征在于，包括如下步骤：S1、依次将水、醇胺和防锈剂加入容器中，搅拌至溶解；S2、依次将基础油、合成酯、酰胺、乳化剂、腐蚀抑制剂及金属缓蚀剂加入所述容器中，搅拌至均匀透明。
- 根据权利要求9所述的金属加工切削液的制备方法，其特征在于，所述步骤S1与所述步骤S2中的搅拌时间均为10min-15min。
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101240217A (zh) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | 微乳型金属切削液组合物 |
| CN106118834A (zh) * | 2016-06-22 | 2016-11-16 | 东莞市科泽润滑油有限公司 | 一种使用寿命长的铝合金切削液及其制备方法 |
| CN106318586A (zh) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | 一种多用途半合成金属加工液及其制备方法 |
| CN106479654A (zh) * | 2016-09-06 | 2017-03-08 | 深圳市宏达威表面处理技术有限公司 | 水基金属切削液 |
| WO2021091578A1 (en) * | 2019-11-08 | 2021-05-14 | Hewlett-Packard Development Company, L.P. | Water-based carbon nanotube cutting fluid for a cnc cutting process |
| CN112812876A (zh) * | 2020-12-31 | 2021-05-18 | 温州君怡化工贸易有限公司 | 一种全合成多功能不锈钢切削液及其制备方法 |
| CN113801724A (zh) * | 2021-09-30 | 2021-12-17 | 安美科技股份有限公司 | 金属加工切削液及其制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613634B (zh) * | 2009-07-28 | 2012-06-06 | 武汉玻尔科技有限公司 | 一种高性能水基乳化切削液组合物 |
| CN104277902B (zh) * | 2014-09-12 | 2016-08-24 | 广州中机实业有限公司 | 一种重负荷金属加工全合成切削液及其制备方法与应用 |
| CN108822948A (zh) * | 2018-05-22 | 2018-11-16 | 济南大学 | 一种低泡沫环保型微乳化金属切削液的制备方法 |
-
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101240217A (zh) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | 微乳型金属切削液组合物 |
| CN106118834A (zh) * | 2016-06-22 | 2016-11-16 | 东莞市科泽润滑油有限公司 | 一种使用寿命长的铝合金切削液及其制备方法 |
| CN106318586A (zh) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | 一种多用途半合成金属加工液及其制备方法 |
| CN106479654A (zh) * | 2016-09-06 | 2017-03-08 | 深圳市宏达威表面处理技术有限公司 | 水基金属切削液 |
| WO2021091578A1 (en) * | 2019-11-08 | 2021-05-14 | Hewlett-Packard Development Company, L.P. | Water-based carbon nanotube cutting fluid for a cnc cutting process |
| CN112812876A (zh) * | 2020-12-31 | 2021-05-18 | 温州君怡化工贸易有限公司 | 一种全合成多功能不锈钢切削液及其制备方法 |
| CN113801724A (zh) * | 2021-09-30 | 2021-12-17 | 安美科技股份有限公司 | 金属加工切削液及其制备方法 |
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