WO2023035831A1 - Aluminum alloy for extrusion, and preparation method therefor - Google Patents

Aluminum alloy for extrusion, and preparation method therefor Download PDF

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WO2023035831A1
WO2023035831A1 PCT/CN2022/110595 CN2022110595W WO2023035831A1 WO 2023035831 A1 WO2023035831 A1 WO 2023035831A1 CN 2022110595 W CN2022110595 W CN 2022110595W WO 2023035831 A1 WO2023035831 A1 WO 2023035831A1
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aluminum
extrusion
aluminum alloy
temperature
refining
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PCT/CN2022/110595
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French (fr)
Chinese (zh)
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赵立洋
张桓
乔恒
段妍彤
张军
金榕
章安楠
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江苏亨通电力特种导线有限公司
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0075Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00Obtaining aluminium
    • C22B21/06Obtaining aluminium refining
    • C22B21/066Treatment of circulating aluminium, e.g. by filtration
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/10General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals with refining or fluxing agents; Use of materials therefor, e.g. slagging or scorifying agents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

Definitions

  • the invention relates to the field of aluminum alloy die-casting processing, in particular to an aluminum alloy for extrusion and a preparation method thereof.
  • Aluminum alloy extrusion products are widely used in automobiles, airplanes, home appliances and other fields.
  • the processing cost due to die loss accounts for 30% of the total cost, and the average production of 3.5 tons of extruded products
  • Existing aluminum alloy materials have poor fluidity and ductility, and wall breakage often occurs when extruding thin-walled products, resulting in cost losses.
  • problems such as poor structural continuity, poor corrosion resistance, and coarse grains leading to poor toughness of aluminum alloy materials. Therefore, there is still a need for an aluminum alloy material to improve the extrusion performance of the material, which is suitable for extrusion products with complex structures or thin-wall structures, and prolongs the service life of extrusion dies.
  • the present invention provides an aluminum alloy for extrusion and a preparation method thereof, which have significantly improved corrosion resistance, material strength, fluidity and tissue continuity.
  • the present invention claims to protect an aluminum alloy for extrusion, its components and the mass percentage of each component are: Si 0.1-0.2%, Fe 0.15-0.25%, Mn 1.8-2.4%, Zn 0.05-0.18%, Er 0.03 -0.06%, Ti 0.008-0.04%, Be 0.04-0.08%, V 0.01-0.02%, the rest are Al and unavoidable impurities, and the total amount of impurities does not exceed 0.015%.
  • the components of the aluminum alloy for extrusion and the mass percent of each component are: Si 0.18%, Fe 0.23%, Mn 2.23%, Zn 0.14%, Er 0.05%, Ti 0.02%, Be 0.06%, V 0.015 %, the rest is Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
  • the preparation method of aluminum alloy for extrusion of the present invention comprises the following steps:
  • S2 Add an intermediate alloy to the first aluminum liquid in the holding furnace, stir for 25-35 minutes, and obtain the second aluminum liquid; wherein, the temperature of the holding furnace is 780-800°C, and the intermediate alloy is one or more types, containing Si , Fe, Mn, Zn, Er, Ti, Be and V;
  • the medium-strength aluminum alloy materials used for extrusion in the industry mainly use Mn as the main element.
  • Mn has the advantages of improving strength and corrosion resistance of materials, but there are the following problems: (1) High slag content, extrusion The material has very strict requirements on the slag content of the structure. During the extrusion process, these impurities will form hard spots, which will increase the wear of the mold, and will destroy the continuity of the structure and affect the quality of the extruded product; (2) The structure is not uniform , High manganese element is easy to segregate, grain growth is uneven after annealing, material properties are unstable, aluminum sticking and wall breaking are easy to occur during extrusion, which reduces mold life and product quality.
  • the present invention obtains a high-strength, high-fluidity, high-ductility and corrosion-resistant aluminum alloy material by improving the raw material composition and proportion of the aluminum alloy, and cooperating with the production process and heat treatment process.
  • step S1 the time for one refining is 35-45 minutes.
  • step S1 or S3 a refining agent is added at a rate of 2-3 kg/t of aluminum liquid.
  • the pore size of the second filter is 60 mesh, and the pore size of the first filter is smaller than 60 mesh, preferably 40 mesh.
  • step S5 the speed of feeding the AlTiC wire is 1.5-2.0 m/min.
  • AlTiC is selected as the refiner to avoid the formation of hard phase, thereby reducing the loss of the die during the extrusion process and increasing the continuity of the product.
  • the titanium content in the molten aluminum can be kept fluctuating within 0.008-0.04%.
  • step S5 horizontal casting is performed on the fourth molten aluminum.
  • step S5 the pore size of the casting filter is 16 mesh.
  • step S6 the flow rate of the rolling emulsion is 35-38 m 3 /h, the pressure is 180-200 kPa, and the final rolling temperature can be adjusted by the flow rate and pressure of the rolling emulsion.
  • step S7 keep warm for 90-96h.
  • the present invention also claims extruded products prepared using the aforementioned aluminum alloys.
  • the present invention has at least the following advantages:
  • Mn can improve the corrosion resistance of aluminum alloys. Its maximum solid solubility in aluminum is 1.82%. Excessive Mn content can easily lead to intragranular segregation. The content of Mn in the medium can achieve corrosion resistance. By adding Fe, it can form FeMnAl 6 phase with Mn, reduce the solid solution of Mn in the aluminum matrix, and improve the ductility of the alloy. At the same time, cooperate with Zn and Er to further reduce the solid solution of Mn And reduce the segregation phenomenon, refine the coarse phase in the structure, and significantly improve the mechanical properties of the material.
  • the present invention matches the heat treatment process of the present invention by adding Er, Si, and Be to heat treatment at low temperature for a long time, so that the compound dissolved in the aluminum matrix is slowly precipitated, the amount of manganese element precipitation is promoted, and the growth of the precipitated phase is suppressed at the same time.
  • Large, to realize the fine and dispersed distribution of the second phase improve the extrusion fluidity of the alloy material, avoid the coarse grains caused by high temperature annealing, and provide an alloy material with excellent toughness.
  • Figure 1 shows the aluminum alloys prepared in Example 1 and Comparative Examples 2, 8, and 9.
  • the components of aluminum alloy for extrusion and the mass percentage of each component are: Si 0.18%, Fe 0.23%, Mn 2.23%, Zn 0.14%, Er 0.05%, Ti 0.02%, Be 0.06%, V 0.015%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
  • the preparation method of aluminum alloy for extrusion comprises the following steps:
  • the components of the aluminum alloy for extrusion and the mass percentage of each component are: Si 0.1%, Fe 0.16%, Mn 1.8%, Zn 0.18%, Er 0.06%, Ti 0.015%, Be 0.08%, V 0.02%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
  • the preparation method of aluminum alloy for extrusion comprises the following steps:
  • S5 Continuously cast the molten aluminum after the online treatment of S4, adopt horizontal casting, and add a 16-mesh casting filter to filter the scale at the gate, control the casting temperature to 710°C, the casting speed to 6.5t/h, and the cooling water temperature 35°C, and the billet temperature is 520°C.
  • the components of aluminum alloy for extrusion and the mass percentage of each component are: Si 0.2%, Fe 0.2%, Mn 2%, Zn 0.05%, Er 0.03%, Ti 0.04%, Be 0.04%, V 0.01%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
  • the preparation method of aluminum alloy for extrusion comprises the following steps:
  • a filter plate which is respectively the 40 mesh filter plate of the front channel and the 60 mesh filter plate of the rear channel, performs double-stage filtration.
  • S5 Continuously cast the molten aluminum after S4 on-line treatment, adopt horizontal casting, and add a 16-mesh casting filter to filter the scale at the gate, control the casting temperature to 720°C, the casting speed to 7.5t/h, and the cooling water temperature 25°C, and the billet temperature is 550°C.
  • Si is not added to the composition of the aluminum alloy for extrusion, and the rest is the same as in Example 1.
  • the temperature during the annealing treatment in S7 was 560° C., and the rest were the same as in Example 1.
  • the time during the annealing treatment in S7 was 85h (a) and 103h (b), and the rest were the same as in Example 1.
  • Example 1 has increased respectively compared with Comparative Examples 1-9: 9.52%, 8.49%, 8.49%, 16.16%, 7.48%, 9.52%, 17.35%, 15%, 15% (a), 12.75% (b); From elongation aspect, embodiment 1 has improved respectively compared with example 1-9: 30.56%, 34.29%, 30.56%, 56.67%, 27.03%, 38.24%, 56.67%, 38.24% %, 42.42% (a), 38.24% (b); from the aspect of product qualified rate, the unqualified rate of embodiment 1 has reduced respectively compared with comparative example 1-9: 82.76%, 79.17%, 81.48%, 84.38%, 79.17% %, 80%, 82.76%, 77.27%, 82.14% (a), 82.76% (b); from the aspect of mold life, embodiment 1 has improved respectively compared with comparative example 1-9: 27.91%, 25%, 22.22%, 197.3%, 26.44%,
  • embodiment 1 has improved 2.4 compared with comparative example 1, and embodiment 1 has improved 2.2 compared with comparative example 2, and embodiment 1 has improved 2 compared with comparative example 3, and embodiment 1 has improved 7.3 compared with comparative example 4 , the difference sum of comparative examples 1-3 and embodiment 1 is 6.4 (7.3 less than the difference value 7.3 of comparative example 4 and embodiment 1), it can be seen that the combined effect of Er, Si and Be improves the sum of the effect of using separately than respectively up 10.61%.
  • the present invention increases the content of manganese element, forms FeMnAl 6 phase by adding Zn, Fe, Er, reduces the solid solution of Mn in the aluminum matrix, and improves the ductility of the alloy. At the same time, it cooperates with Zn and Er to further reduce the solid solution of Mn and reduce the segregation phenomenon, refine the coarse phase in the structure, and solve the problem of high segregation and unevenness of Mn element.
  • Zn and Er can assist in the elimination of Si element Existing broken wall or shrinkage porosity problem, Zn, Fe, Er can significantly improve the processing performance of aluminum alloy material; From the above table we can know (also taking extrusion die life as an example), embodiment 1 has improved 2.4% compared with comparative example 1 , embodiment 1 has improved 2.3 compared with comparative example 5, and embodiment 1 has improved 2.1 compared with comparative example 6, and embodiment 1 has improved 7.5 compared with comparative example 7, and the difference sum of comparative examples 1,5,6 and embodiment 1 is 6.8 (7.5 less than the difference between Comparative Example 7 and Example 1), it can be seen that the combined effect of Er, Fe and Zn is 10.29% higher than the sum of the effects of separate use. Therefore, there is a synergistic effect among various elements in the present invention, which improves the comprehensive performance of the aluminum alloy material, and each component is indispensable.
  • the present invention improves the performance of the material by optimizing the production process and heat treatment process: during the production process, refining is carried out in both the smelting furnace and the holding furnace, two-stage filtration is added and casting filter screens are added to filter most of the impurities, and the substrate is purified with Er and other elements; the heat treatment process Among them, the inventors have found through a large number of experiments that the optimal heat treatment condition is to keep warm at 450-460°C for 88-100h, and the grains grow uniformly after annealing, as shown in Figure 1 (A is the aluminum alloy prepared in Example 1, and B is the The aluminum alloy prepared in Example 8, C is the aluminum alloy b prepared in Comparative Example 9, and D is the aluminum alloy prepared in Comparative Example 2), the grain size in A is uniform, while the extruded walls of B-D are uneven, and C is due to the excessive holding time Long, coarse grains, and segregation phenomenon occurs in the preparation process, the material performance is unstable during extrusion, and aluminum sticking and wall breaking appear.

Abstract

The present invention relates to an aluminum alloy for extrusion. The components of the aluminum alloy and the mass percentage of each component comprise: 0.1-0.2% of Si, 0.15-0.25% of Fe, 1.8-2.4% of Mn, 0.05-0.18% of Zn, 0.03-0.06% of Er, 0.008-0.04% of Ti, 0.04-0.08% of Be, and 0.01-0.02% of V, with the balance being Al and inevitable impurities, wherein the total amount of the impurities is not more than 0.015%. The aluminum alloy is prepared by means of process steps of smelting, alloying, refining, molten-aluminum online treatment, continuous casting, continuous rolling, cooling and take-up, annealing treatment, etc. The aluminum alloy of the present invention is significantly improved in terms of corrosion resistance, material strength, fluidity and structure continuity, such that the pressure-bearing capacity of a prepared extrusion material is significantly improved, and the service life thereof is prolonged.

Description

一种挤压用铝合金及其制备方法Aluminum alloy for extrusion and preparation method thereof 技术领域technical field
本发明涉及铝合金压铸加工领域,尤其涉及一种挤压用铝合金及其制备方法。The invention relates to the field of aluminum alloy die-casting processing, in particular to an aluminum alloy for extrusion and a preparation method thereof.
背景技术Background technique
铝合金挤压产品广泛应用于汽车、飞机、家电等领域,其中铝合金在连续挤压制作冷凝扁管过程中,因模具损耗产生的加工费用占全部费用的30%,平均生产3.5吨产品挤压模具就会出现不同程度的损伤,需要更换新的模具。因此,如何延长挤压模具的寿命成为亟需解决的问题。现有的铝合金材料流动性及延展性不佳,挤压薄壁产品时经常出现破壁现象,造成成本损失。另外,还存在组织连续性差、耐腐蚀性能差、晶粒粗大导致铝合金材料的韧性较差等问题。因此,仍需一种铝合金材料来提高材料挤压性能,适用于复杂结构或是薄壁结构的挤压产品,延长挤压模具的使用寿命。Aluminum alloy extrusion products are widely used in automobiles, airplanes, home appliances and other fields. In the process of continuous extrusion of aluminum alloy to produce condensing flat tubes, the processing cost due to die loss accounts for 30% of the total cost, and the average production of 3.5 tons of extruded products There will be different degrees of damage to the compression mold, and a new mold needs to be replaced. Therefore, how to extend the life of the extrusion die has become an urgent problem to be solved. Existing aluminum alloy materials have poor fluidity and ductility, and wall breakage often occurs when extruding thin-walled products, resulting in cost losses. In addition, there are also problems such as poor structural continuity, poor corrosion resistance, and coarse grains leading to poor toughness of aluminum alloy materials. Therefore, there is still a need for an aluminum alloy material to improve the extrusion performance of the material, which is suitable for extrusion products with complex structures or thin-wall structures, and prolongs the service life of extrusion dies.
发明内容Contents of the invention
为解决上述技术问题,本发明提供了一种挤压用铝合金及其制备方法,在耐腐蚀性、材料强度、流动性和组织连续性方面有显著的提升。In order to solve the above technical problems, the present invention provides an aluminum alloy for extrusion and a preparation method thereof, which have significantly improved corrosion resistance, material strength, fluidity and tissue continuity.
本发明要求保护一种挤压用铝合金,其组分及各组分的质量百分比为:Si 0.1-0.2%、Fe 0.15-0.25%、Mn 1.8-2.4%、Zn 0.05-0.18%、Er 0.03-0.06%、Ti 0.008-0.04%、Be 0.04-0.08%、V 0.01-0.02%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。The present invention claims to protect an aluminum alloy for extrusion, its components and the mass percentage of each component are: Si 0.1-0.2%, Fe 0.15-0.25%, Mn 1.8-2.4%, Zn 0.05-0.18%, Er 0.03 -0.06%, Ti 0.008-0.04%, Be 0.04-0.08%, V 0.01-0.02%, the rest are Al and unavoidable impurities, and the total amount of impurities does not exceed 0.015%.
优选地,挤压用铝合金的组分及各组分的质量百分比为:Si 0.18%、Fe 0.23%、Mn 2.23%、Zn 0.14%、Er 0.05%、Ti 0.02%、Be 0.06%、V 0.015%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。Preferably, the components of the aluminum alloy for extrusion and the mass percent of each component are: Si 0.18%, Fe 0.23%, Mn 2.23%, Zn 0.14%, Er 0.05%, Ti 0.02%, Be 0.06%, V 0.015 %, the rest is Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
本发明的挤压用铝合金的制备方法,包括以下步骤:The preparation method of aluminum alloy for extrusion of the present invention comprises the following steps:
S1:将纯度不小于99.7%的铝合金加入熔炼炉中加热融化,在780-800℃下保温,吹入精炼剂,用氮气或氩气进行一次精炼,得到第一铝液;S1: Add aluminum alloy with a purity of not less than 99.7% into a melting furnace to heat and melt, keep it warm at 780-800°C, blow in refining agent, and conduct a refining with nitrogen or argon to obtain the first aluminum liquid;
S2:在保温炉中向第一铝液中加入中间合金,搅拌25-35min,得到第二铝液;其中,保温炉的温度为780-800℃,中间合金为一种或多种,含有Si、Fe、Mn、Zn、Er、Ti、Be和V;S2: Add an intermediate alloy to the first aluminum liquid in the holding furnace, stir for 25-35 minutes, and obtain the second aluminum liquid; wherein, the temperature of the holding furnace is 780-800°C, and the intermediate alloy is one or more types, containing Si , Fe, Mn, Zn, Er, Ti, Be and V;
S3:第二铝液的成分检验合格后,吹入精炼剂,用氮气或氩气进行二次精炼,静置后进行扒渣,得到第三铝液;其中,二次精炼时,吹入精炼剂后闷炉20-30min,精炼温度为780-800℃;S3: After the composition of the second aluminum liquid is qualified, the refining agent is blown in, the second refining is carried out with nitrogen or argon, and the slag is removed after standing to obtain the third aluminum liquid; Furnace 20-30min after dosing, refining temperature is 780-800℃;
S4:第三铝液通过保温炉倾倒,在进入除气箱前喂AlTiC丝,之后进行除气和双级过滤,得到第四铝液;S4: The third aluminum liquid is poured through the holding furnace, fed with AlTiC wire before entering the degassing box, and then degassed and double-stage filtered to obtain the fourth aluminum liquid;
S5:对第四铝液进行连续浇铸,在浇嘴处设置铸造过滤网;其中,浇铸温度为710-720℃,浇铸速度为6.5-7.5t/h,冷却水温为25-35℃,出坯温度为520-550℃;S5: Carry out continuous casting of the fourth molten aluminum, and install a casting filter at the gate; wherein, the casting temperature is 710-720°C, the casting speed is 6.5-7.5t/h, the cooling water temperature is 25-35°C, and the billet is discharged The temperature is 520-550°C;
S6:对S5中连续浇铸得到的铸坯进行轧制,得到铝杆;其中,进轧温度为510-540℃,终轧温度为200-300℃;S6: rolling the slab obtained by continuous casting in S5 to obtain an aluminum rod; wherein, the rolling temperature is 510-540°C, and the finishing rolling temperature is 200-300°C;
S7:将铝杆降温至60-80℃,吹干后进行收线,之后在7-9h内升温至450-460℃,保温88-100h,随炉冷至20-30℃,得到挤压用铝合金。S7: Cool down the aluminum rod to 60-80°C, blow it dry and take it up, then raise the temperature to 450-460°C within 7-9 hours, keep it warm for 88-100 hours, and cool it to 20-30°C with the furnace to obtain extrusion aluminum alloy.
目前,行业内挤压用的中强度铝合金材料主要是以Mn为主元素,Mn具有提高强度、提升材料耐蚀性能等优点,但是存在以下几个问题:(1)渣含量高,挤压材料对组织的渣含量要求极为严格,在挤压过程中,这些杂质会形成硬质点从而增大模具的磨损,同时会破坏组织连续性,影响挤压产品的质量;(2)组织不均匀,锰元素高易偏析,退火后晶粒长大不均匀,材料性能不稳定,挤压过程易出现粘铝、破壁等现象,降低模具寿命和产品质量。因此铝合金材料中锰含量不能过高,但锰含量降低又会导致其耐蚀性能较差。本发明通过改进铝合金的原料成分及其配比,同时配合生产工艺及热处理工艺,得到了一种高强度、高流动性、高延展性且耐腐蚀的铝合金材 料。At present, the medium-strength aluminum alloy materials used for extrusion in the industry mainly use Mn as the main element. Mn has the advantages of improving strength and corrosion resistance of materials, but there are the following problems: (1) High slag content, extrusion The material has very strict requirements on the slag content of the structure. During the extrusion process, these impurities will form hard spots, which will increase the wear of the mold, and will destroy the continuity of the structure and affect the quality of the extruded product; (2) The structure is not uniform , High manganese element is easy to segregate, grain growth is uneven after annealing, material properties are unstable, aluminum sticking and wall breaking are easy to occur during extrusion, which reduces mold life and product quality. Therefore, the manganese content in the aluminum alloy material should not be too high, but the lower manganese content will lead to poor corrosion resistance. The present invention obtains a high-strength, high-fluidity, high-ductility and corrosion-resistant aluminum alloy material by improving the raw material composition and proportion of the aluminum alloy, and cooperating with the production process and heat treatment process.
进一步地,在步骤S1中,一次精炼的时间为35-45min。Further, in step S1, the time for one refining is 35-45 minutes.
进一步地,在步骤S1或S3中,按2-3kg/t铝液加入精炼剂。Further, in step S1 or S3, a refining agent is added at a rate of 2-3 kg/t of aluminum liquid.
进一步地,在步骤S4中,双级过滤中第二次过滤的孔径为60目,第一次过滤的孔径小于60目,优选为40目。Further, in step S4, in the two-stage filtration, the pore size of the second filter is 60 mesh, and the pore size of the first filter is smaller than 60 mesh, preferably 40 mesh.
进一步地,在步骤S5中,喂AlTiC丝的速度为1.5-2.0m/min。选用AlTiC作细化剂,避免了硬质相的形成,从而降低了挤压过程中模具的损耗,增加了产品的连续性。此速度范围内可保持铝液中的钛含量在0.008~0.04%内波动。Further, in step S5, the speed of feeding the AlTiC wire is 1.5-2.0 m/min. AlTiC is selected as the refiner to avoid the formation of hard phase, thereby reducing the loss of the die during the extrusion process and increasing the continuity of the product. Within this speed range, the titanium content in the molten aluminum can be kept fluctuating within 0.008-0.04%.
进一步地,在步骤S5中,对第四铝液进行水平浇铸。Further, in step S5, horizontal casting is performed on the fourth molten aluminum.
进一步地,在步骤S5中,铸造过滤网的孔径为16目。Further, in step S5, the pore size of the casting filter is 16 mesh.
进一步地,在步骤S6中,轧制乳化液的流量为35-38m 3/h,压力为180-200kPa,终轧温度可通过轧制乳化液的流量和压力进行调节。 Further, in step S6, the flow rate of the rolling emulsion is 35-38 m 3 /h, the pressure is 180-200 kPa, and the final rolling temperature can be adjusted by the flow rate and pressure of the rolling emulsion.
进一步地,在步骤S7中,保温90-96h。Further, in step S7, keep warm for 90-96h.
进一步地,每一步骤结束之后静置35-45min来沉淀铝液中的杂质。Further, after each step, stand still for 35-45 minutes to precipitate impurities in the aluminum liquid.
本发明还要求保护使用上述铝合金制备的挤压产品。The present invention also claims extruded products prepared using the aforementioned aluminum alloys.
借由上述方案,本发明至少具有以下优点:By means of the above solution, the present invention has at least the following advantages:
(1)Mn可以提升铝合金的耐蚀性,其在铝中的最大固溶度为1.82%,过高的Mn含量容易导致晶内偏析,退火后组织晶粒不均匀,本发明提高合金材料中Mn的含量,实现耐腐蚀性能,通过添加Fe,与Mn形成FeMnAl 6相,降低Mn在铝基体中的固溶,提高合金的延展性,同时与Zn和Er配合,进一步降低Mn的固溶以及减少偏析现象,细化组织中的粗大相,显著提高了材料的机械性能。 (1) Mn can improve the corrosion resistance of aluminum alloys. Its maximum solid solubility in aluminum is 1.82%. Excessive Mn content can easily lead to intragranular segregation. The content of Mn in the medium can achieve corrosion resistance. By adding Fe, it can form FeMnAl 6 phase with Mn, reduce the solid solution of Mn in the aluminum matrix, and improve the ductility of the alloy. At the same time, cooperate with Zn and Er to further reduce the solid solution of Mn And reduce the segregation phenomenon, refine the coarse phase in the structure, and significantly improve the mechanical properties of the material.
(2)本发明通过低温长时间保温,并添加Er、Si、Be来匹配本发明的热处理工艺,使固溶在铝基体中的化合物缓慢析出,促进锰元素析出量,同 时抑制析出相的长大,实现第二相细小弥散分布,提高了合金材料的挤压流动性,同时避免了高温退火造成的晶粒粗大,提供一种韧性优良的合金材料。(2) The present invention matches the heat treatment process of the present invention by adding Er, Si, and Be to heat treatment at low temperature for a long time, so that the compound dissolved in the aluminum matrix is slowly precipitated, the amount of manganese element precipitation is promoted, and the growth of the precipitated phase is suppressed at the same time. Large, to realize the fine and dispersed distribution of the second phase, improve the extrusion fluidity of the alloy material, avoid the coarse grains caused by high temperature annealing, and provide an alloy material with excellent toughness.
(3)本发明的铝合金材料生产时,在熔炼炉和保温炉中均进行精炼,喂丝之后进行双级过滤,并设置铸造过滤网,因溜槽到浇包的过程中铝液会出现翻腾现象,造成氧化皮并通过铝液带入坯料中,形成大杂质,本发明可排除这些杂质干扰。(3) When the aluminum alloy material of the present invention is produced, refining is carried out in both the smelting furnace and the holding furnace, two-stage filtration is carried out after wire feeding, and a casting filter screen is set, because the aluminum liquid will churn during the process from the chute to the ladle Phenomenon, resulting in scale and brought into the billet through the aluminum liquid, forming large impurities, the present invention can eliminate the interference of these impurities.
上述说明仅是本发明技术方案的概述,为了能够更清楚了解本发明的技术手段,并可依照说明书的内容予以实施,以下以本发明的较佳实施例并配合详细附图说明如后。The above description is only an overview of the technical solutions of the present invention. In order to understand the technical means of the present invention more clearly and implement them according to the contents of the description, the preferred embodiments of the present invention are described below with detailed drawings.
附图说明Description of drawings
为了使本发明的内容更容易被清楚的理解,下面根据本发明的具体实施例并结合附图,对本发明作进一步详细的说明。In order to make the content of the present invention more clearly understood, the present invention will be further described in detail below according to the specific embodiments of the present invention and in conjunction with the accompanying drawings.
图1为实施例1和对比例2、8、9制备的铝合金。Figure 1 shows the aluminum alloys prepared in Example 1 and Comparative Examples 2, 8, and 9.
具体实施方式Detailed ways
下面结合附图和具体实施例对本发明作进一步说明,以使本领域的技术人员可以更好地理解本发明并能予以实施,但所举实施例不作为对本发明的限定。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments, so that those skilled in the art can better understand the present invention and implement it, but the examples given are not intended to limit the present invention.
实施例1Example 1
挤压用铝合金的组分及各组分的质量百分比为:Si 0.18%、Fe 0.23%、Mn 2.23%、Zn 0.14%、Er 0.05%、Ti 0.02%、Be 0.06%、V 0.015%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。The components of aluminum alloy for extrusion and the mass percentage of each component are: Si 0.18%, Fe 0.23%, Mn 2.23%, Zn 0.14%, Er 0.05%, Ti 0.02%, Be 0.06%, V 0.015%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
挤压用铝合金的制备方法包括以下步骤:The preparation method of aluminum alloy for extrusion comprises the following steps:
S1:将Al99.70的重熔铝锭投入熔炼炉中后加热融化,795℃下保温,在溶体中加入精炼剂,并使用纯度≥99.999%的高纯氮气进行一次精炼,精炼时间45min,静置45min后将铝液放入保温炉中。S1: Put the remelted aluminum ingot of Al99.70 into the smelting furnace and heat it to melt, keep it warm at 795°C, add refining agent to the melt, and use high-purity nitrogen with a purity ≥ 99.999% for a refining, refining time 45min, static After standing for 45 minutes, put the molten aluminum into the holding furnace.
S2:在保温炉中对铝液进行合金化,温度设定为795℃,加入铝铁合金、 铝锰合金、铝锌合金、铝铒合金、铝钛合金、铝铍合金、铝钒合金,使用电磁搅拌30min,之后静置40min,取样分析炉前成分,根据结果进行补料或稀释,直至成分合格,进入精炼工序。S2: Alloy the molten aluminum in the holding furnace, set the temperature at 795°C, add aluminum-iron alloy, aluminum-manganese alloy, aluminum-zinc alloy, aluminum-erbium alloy, aluminum-titanium alloy, aluminum-beryllium alloy, aluminum-vanadium alloy, and use electromagnetic Stir for 30 minutes, then stand still for 40 minutes, take a sample and analyze the composition before the furnace, and feed or dilute according to the result until the composition is qualified, and then enter the refining process.
S3:对保温炉中合金化之后的铝液进行二次精炼,按2.8kg/t加入颗粒精炼剂,使用纯度≥99.999%的高纯氮气进行精炼,精炼剂吹入后要进行闷炉30min,之后进行扒渣,精炼温度设定为790℃,精炼后静置45min。S3: Carry out secondary refining on the molten aluminum after alloying in the holding furnace, add granular refining agent at 2.8kg/t, and use high-purity nitrogen with a purity ≥ 99.999% for refining. After that, slag removal is carried out, the refining temperature is set at 790°C, and the refining is allowed to stand for 45 minutes.
S4:铝液通过保温炉的倾倒,在进入除气箱前进行在线喂AlTiC丝,喂丝速度1.8m/min,之后铝液通过溜槽进入在线除气系统和过滤系统,并且在过滤箱中添加两块过滤板,分别是前道的40目和后道的60目过滤板进行双级过滤。S4: The aluminum liquid is poured through the holding furnace, and the AlTiC wire is fed online before entering the degassing box. The wire feeding speed is 1.8m/min. Two filter plates, 40 mesh in the front and 60 mesh in the back, are used for double-stage filtration.
S5:对S4在线处理后的铝液进行连续浇铸,采用水平浇铸,并在浇嘴处添加一块16目的铸造过滤网过滤氧化皮,控制浇铸温度为713℃,浇铸速度6.8t/h,冷却水温30℃,出坯温度为540℃。S5: Continuously cast the molten aluminum after S4 on-line processing, adopt horizontal casting, and add a 16-mesh casting filter to filter the scale at the gate, control the casting temperature to 713°C, the casting speed to 6.8t/h, and the cooling water temperature 30°C, the billet temperature is 540°C.
S6:对连续浇铸出的铸坯进行校直,控制进轧温度保持在530℃,并通过控制乳化液流量和压力来控制终轧温度为280℃,具体的,乳液化流量为38m 3/h,压力为200kPa。 S6: Straighten the continuous casting slab, control the rolling temperature at 530°C, and control the finishing rolling temperature at 280°C by controlling the flow and pressure of the emulsion. Specifically, the emulsification flow rate is 38m 3 /h , the pressure is 200kPa.
S7:对轧制出的铝杆进行水冷降温,降温至80℃,并吹干后进行紧密收线。退火处理时,在8h内升温至455℃,保温93小时,随炉冷至室温,完成后得本发明的挤压用铝合金。S7: Water-cool the rolled aluminum rod to 80°C, dry it, and take it up tightly. During the annealing treatment, the temperature is raised to 455° C. within 8 hours, kept at a temperature of 93 hours, and then cooled to room temperature with the furnace. After completion, the aluminum alloy for extrusion of the present invention is obtained.
实施例2Example 2
挤压用铝合金的组分及各组分的质量百分比为:Si 0.1%、Fe 0.16%、Mn 1.8%、Zn 0.18%、Er 0.06%、Ti 0.015%、Be 0.08%、V 0.02%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。The components of the aluminum alloy for extrusion and the mass percentage of each component are: Si 0.1%, Fe 0.16%, Mn 1.8%, Zn 0.18%, Er 0.06%, Ti 0.015%, Be 0.08%, V 0.02%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
挤压用铝合金的制备方法包括以下步骤:The preparation method of aluminum alloy for extrusion comprises the following steps:
S1:将Al99.70的重熔铝锭投入熔炼炉中后加热融化,780℃下保温,在溶体中加入精炼剂,并使用纯度≥99.999%的高纯氮气进行一次精炼,精炼时 间40min,静置45min后将铝液放入保温炉中。S1: Put the remelted aluminum ingot of Al99.70 into the smelting furnace, heat it to melt, keep it warm at 780°C, add refining agent to the melt, and use high-purity nitrogen with a purity ≥ 99.999% for a refining, refining time 40min, static After standing for 45 minutes, put the molten aluminum into the holding furnace.
S2:在保温炉中对铝液进行合金化,温度设定为780℃,加入铝铁合金、铝锰合金、铝锌合金、铝铒合金、铝钛合金、铝铍合金、铝钒合金,使用电磁搅拌35min,之后静置45min,取样分析炉前成分,根据结果进行补料或稀释,直至成分合格,进入精炼工序。S2: Alloy the molten aluminum in the holding furnace, set the temperature at 780°C, add aluminum-iron alloy, aluminum-manganese alloy, aluminum-zinc alloy, aluminum-erbium alloy, aluminum-titanium alloy, aluminum-beryllium alloy, aluminum-vanadium alloy, and use electromagnetic Stir for 35 minutes, then stand still for 45 minutes, take a sample and analyze the ingredients before the furnace, and feed or dilute according to the results until the ingredients are qualified, and then enter the refining process.
S3:对保温炉中合金化之后的铝液进行二次精炼,按2kg/t加入颗粒精炼剂,使用纯度≥99.999%的高纯氮气进行精炼,精炼剂吹入后要进行闷炉30min,之后进行扒渣,精炼温度设定为785℃,精炼后静置45min。S3: Carry out secondary refining on the molten aluminum after alloying in the holding furnace, add granular refining agent at 2kg/t, and use high-purity nitrogen with a purity ≥ 99.999% for refining. Carry out slag removal, set the refining temperature at 785°C, and let stand for 45 minutes after refining.
S4:铝液通过保温炉的倾倒,在进入除气箱前进行在线喂AlTiC丝,喂丝速度1.5m/min,之后铝液通过溜槽进入在线除气系统和过滤系统,并且在过滤箱中添加两块过滤板,分别是前道的40目和后道的60目过滤板进行双级过滤。S4: The aluminum liquid is poured through the holding furnace, and the AlTiC wire is fed online before entering the degassing box. The wire feeding speed is 1.5m/min. Two filter plates, 40 mesh in the front and 60 mesh in the back, are used for double-stage filtration.
S5:对S4在线处理后的铝液进行连续浇铸,采用水平浇铸,并在浇嘴处添加一块16目的铸造过滤网过滤氧化皮,控制浇铸温度为710℃,浇铸速度6.5t/h,冷却水温35℃,出坯温度为520℃。S5: Continuously cast the molten aluminum after the online treatment of S4, adopt horizontal casting, and add a 16-mesh casting filter to filter the scale at the gate, control the casting temperature to 710°C, the casting speed to 6.5t/h, and the cooling water temperature 35°C, and the billet temperature is 520°C.
S6:对连续浇铸出的铸坯进行校直,控制进轧温度保持在510℃,并通过控制乳化液流量和压力来控制终轧温度为200℃,具体的,乳液化流量为35m 3/h,压力为180kPa。 S6: Straighten the continuous casting slab, control the rolling temperature at 510°C, and control the finishing rolling temperature at 200°C by controlling the flow and pressure of the emulsion. Specifically, the emulsification flow rate is 35m 3 /h , the pressure is 180kPa.
S7:对轧制出的铝杆进行水冷降温,降温至60℃,并吹干后进行紧密收线。退火处理时,在9h内升温至460℃,保温90小时,随炉冷至室温,完成后得本发明的挤压用铝合金。S7: Water-cool the rolled aluminum rod to 60°C, dry it, and take it up tightly. During the annealing treatment, the temperature is raised to 460° C. within 9 hours, kept at a temperature of 90 hours, and then cooled to room temperature with the furnace. After completion, the aluminum alloy for extrusion of the present invention is obtained.
实施例3Example 3
挤压用铝合金的组分及各组分的质量百分比为:Si 0.2%、Fe 0.2%、Mn 2%、Zn 0.05%、Er 0.03%、Ti 0.04%、Be 0.04%、V 0.01%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。The components of aluminum alloy for extrusion and the mass percentage of each component are: Si 0.2%, Fe 0.2%, Mn 2%, Zn 0.05%, Er 0.03%, Ti 0.04%, Be 0.04%, V 0.01%, the rest Al and unavoidable impurities, the total amount of impurities is not more than 0.015%.
挤压用铝合金的制备方法包括以下步骤:The preparation method of aluminum alloy for extrusion comprises the following steps:
S1:将Al99.70的重熔铝锭投入熔炼炉中后加热融化,800℃下保温,在溶体中加入精炼剂,并使用纯度≥99.999%的高纯氮气进行一次精炼,精炼时间40min,静置45min后将铝液放入保温炉中。S1: Put the remelted aluminum ingot of Al99.70 into the smelting furnace, heat it to melt, keep it warm at 800°C, add refining agent to the melt, and use high-purity nitrogen with a purity ≥ 99.999% for a refining, refining time 40min, static After standing for 45 minutes, put the molten aluminum into the holding furnace.
S2:在保温炉中对铝液进行合金化,温度设定为800℃,加入铝铁合金、铝锰合金、铝锌合金、铝铒合金、铝钛合金、铝铍合金、铝钒合金,使用电磁搅拌35min,之后静置45min,取样分析炉前成分,根据结果进行补料或稀释,直至成分合格,进入精炼工序。S2: Alloy the molten aluminum in the holding furnace, set the temperature at 800°C, add aluminum-iron alloy, aluminum-manganese alloy, aluminum-zinc alloy, aluminum-erbium alloy, aluminum-titanium alloy, aluminum-beryllium alloy, aluminum-vanadium alloy, and use electromagnetic Stir for 35 minutes, then stand still for 45 minutes, take a sample and analyze the ingredients before the furnace, and feed or dilute according to the results until the ingredients are qualified, and then enter the refining process.
S3:对保温炉中合金化之后的铝液进行二次精炼,按3kg/t加入颗粒精炼剂,使用纯度≥99.999%的高纯氮气进行精炼,精炼剂吹入后要进行闷炉30min,之后进行扒渣,精炼温度设定为795℃,精炼后静置45min。S3: Carry out secondary refining on the molten aluminum after alloying in the holding furnace, add granular refining agent at a rate of 3kg/t, and use high-purity nitrogen with a purity ≥ 99.999% for refining. Carry out slag removal, set the refining temperature to 795°C, and let stand for 45 minutes after refining.
S4:铝液通过保温炉的倾倒,在进入除气箱前进行在线喂AlTiC丝,喂丝速度2m/min,之后铝液通过溜槽进入在线除气系统和过滤系统,并且在过滤箱中添加两块过滤板,分别是前道的40目和后道的60目过滤板进行双级过滤。S4: The aluminum liquid is poured through the holding furnace, and the AlTiC wire is fed online before entering the degassing box. The wire feeding speed is 2m/min. A filter plate, which is respectively the 40 mesh filter plate of the front channel and the 60 mesh filter plate of the rear channel, performs double-stage filtration.
S5:对S4在线处理后的铝液进行连续浇铸,采用水平浇铸,并在浇嘴处添加一块16目的铸造过滤网过滤氧化皮,控制浇铸温度为720℃,浇铸速度7.5t/h,冷却水温25℃,出坯温度为550℃。S5: Continuously cast the molten aluminum after S4 on-line treatment, adopt horizontal casting, and add a 16-mesh casting filter to filter the scale at the gate, control the casting temperature to 720°C, the casting speed to 7.5t/h, and the cooling water temperature 25°C, and the billet temperature is 550°C.
S6:对连续浇铸出的铸坯进行校直,控制进轧温度保持在540℃,并通过控制乳化液流量和压力来控制终轧温度为260℃,具体的,乳液化流量为36m 3/h,压力为190kPa。 S6: Straighten the continuous casting slab, control the rolling temperature at 540°C, and control the finishing rolling temperature at 260°C by controlling the flow and pressure of the emulsion. Specifically, the emulsification flow rate is 36m 3 /h , the pressure is 190kPa.
S7:对轧制出的铝杆进行水冷降温,降温至70℃,并吹干后进行紧密收线。退火处理时,在7h内升温至450℃,保温96小时,随炉冷至室温,完成后得本发明的挤压用铝合金。S7: Water-cool the rolled aluminum rod to 70°C, dry it, and take it up tightly. During the annealing treatment, the temperature is raised to 450° C. within 7 hours, kept at a temperature of 96 hours, and then cooled to room temperature with the furnace. After completion, the aluminum alloy for extrusion of the present invention is obtained.
对比例1Comparative example 1
挤压用铝合金的组分中未添加Er,其余与实施例1相同。No Er was added to the composition of the aluminum alloy for extrusion, and the rest were the same as in Example 1.
对比例2Comparative example 2
挤压用铝合金的组分中未添加Si,其余与实施例1相同。Si is not added to the composition of the aluminum alloy for extrusion, and the rest is the same as in Example 1.
对比例3Comparative example 3
挤压用铝合金的组分中未添加Be,其余与实施例1相同。No Be was added to the composition of the aluminum alloy for extrusion, and the rest were the same as in Example 1.
对比例4Comparative example 4
挤压用铝合金的组分中未添加Er、Si、Be,其余与实施例1相同。No Er, Si, and Be were added to the composition of the aluminum alloy for extrusion, and the rest were the same as in Example 1.
对比例5Comparative example 5
挤压用铝合金的组分中未添加Fe,其余与实施例1相同。Fe is not added to the composition of the aluminum alloy for extrusion, and the rest are the same as in Example 1.
对比例6Comparative example 6
挤压用铝合金的组分中未添加Zn,其余与实施例1相同。No Zn is added to the composition of the aluminum alloy for extrusion, and the rest are the same as in Example 1.
对比例7Comparative example 7
挤压用铝合金的组分中未添加Fe、Zn、Er,其余与实施例1相同。No Fe, Zn, and Er were added to the composition of the aluminum alloy for extrusion, and the rest were the same as in Example 1.
对比例8Comparative example 8
S7中退火处理时的温度为560℃,其余与实施例1相同。The temperature during the annealing treatment in S7 was 560° C., and the rest were the same as in Example 1.
对比例9Comparative example 9
S7中退火处理时的时间为85h(a)和103h(b),其余与实施例1相同。The time during the annealing treatment in S7 was 85h (a) and 103h (b), and the rest were the same as in Example 1.
将实施例1-3、对比例1-9所制备的铝合金按照GB/T 4909.3进行测试,并将其用于薄壁口琴管的挤压生产,测试结果如下表所示。The aluminum alloys prepared in Examples 1-3 and Comparative Examples 1-9 were tested according to GB/T 4909.3, and used for the extrusion production of thin-walled harmonica tubes. The test results are shown in the table below.
Figure PCTCN2022110595-appb-000001
Figure PCTCN2022110595-appb-000001
Figure PCTCN2022110595-appb-000002
Figure PCTCN2022110595-appb-000002
如上表所示,从抗拉强度方面,实施例1比对比例1-9分别提高了:9.52%、8.49%、8.49%、16.16%、7.48%、9.52%、17.35%、15%、15%(a)、12.75%(b);从延长率方面,实施例1比对比例1-9分别提高了:30.56%、34.29%、30.56%、56.67%、27.03%、38.24%、56.67%、38.24%、42.42%(a)、38.24%(b);从产品合格率方面,实施例1的不合格率比对比例1-9分别降低了:82.76%、79.17%、81.48%、84.38%、79.17%、80%、82.76%、77.27%、82.14%(a)、82.76%(b);从模具寿命方面,实施例1比对比例1-9分别提高了:27.91%、25%、22.22%、197.3%、26.44%、23.6%、214.29%、35.8%、61.76%(a)、64.18%(b)。As shown in the above table, in terms of tensile strength, Example 1 has increased respectively compared with Comparative Examples 1-9: 9.52%, 8.49%, 8.49%, 16.16%, 7.48%, 9.52%, 17.35%, 15%, 15% (a), 12.75% (b); From elongation aspect, embodiment 1 has improved respectively compared with example 1-9: 30.56%, 34.29%, 30.56%, 56.67%, 27.03%, 38.24%, 56.67%, 38.24% %, 42.42% (a), 38.24% (b); from the aspect of product qualified rate, the unqualified rate of embodiment 1 has reduced respectively compared with comparative example 1-9: 82.76%, 79.17%, 81.48%, 84.38%, 79.17% %, 80%, 82.76%, 77.27%, 82.14% (a), 82.76% (b); from the aspect of mold life, embodiment 1 has improved respectively compared with comparative example 1-9: 27.91%, 25%, 22.22%, 197.3%, 26.44%, 23.6%, 214.29%, 35.8%, 61.76% (a), 64.18% (b).
本发明的铝合金材料组分之间存在协同作用,Si元素不添加易出现挤压破壁现象,但添加易出现缩松,通过Er、Si和Be相互配合,协同促进锰元素高效且彻底析出,促进固溶在基体中的元素析出,且以弥散形式析出,不会形成大颗粒第二相,使第二相细小均匀分布,从而大大延长挤压模具使用寿命;从上表可知(以挤压模具寿命为例),实施例1比对比例1提高了2.4,实施例1比对比例2提高了2.2,实施例1比对比例3提高了2,实施例1比对比例4提高了7.3,对比例1-3与实施例1的差值总和为6.4(小于对比例4与实施例1的差值7.3),可见,Er、Si和Be组合使用效果比分别单独使用的效果之和提高了10.61%。There is a synergistic effect among the components of the aluminum alloy material of the present invention. If the Si element is not added, the phenomenon of extrusion wall breaking will easily occur, but the addition of Si element will easily cause shrinkage porosity. Through the mutual cooperation of Er, Si and Be, the efficient and thorough precipitation of the manganese element is synergistically promoted. , to promote the precipitation of elements dissolved in the matrix, and precipitate in a dispersed form, without forming a second phase of large particles, so that the second phase is fine and evenly distributed, thereby greatly prolonging the service life of the extrusion die; Die life is an example), embodiment 1 has improved 2.4 compared with comparative example 1, and embodiment 1 has improved 2.2 compared with comparative example 2, and embodiment 1 has improved 2 compared with comparative example 3, and embodiment 1 has improved 7.3 compared with comparative example 4 , the difference sum of comparative examples 1-3 and embodiment 1 is 6.4 (7.3 less than the difference value 7.3 of comparative example 4 and embodiment 1), it can be seen that the combined effect of Er, Si and Be improves the sum of the effect of using separately than respectively up 10.61%.
同时,本发明为增强铝合金材料的强度及耐蚀性,提高了锰元素的含量,通过添加Zn、Fe、Er,形成FeMnAl 6相,降低Mn在铝基体中的固溶,提高合金的延展性,同时与Zn和Er配合,进一步降低Mn的固溶以及减少偏析现象,细化组织中的粗大相,解决了Mn元素高易偏析及不均匀的问题, 同时Zn和Er可辅助消除Si元素存在的破壁或缩松问题,Zn、Fe、Er配合可显著提高铝合金材料的加工性能;从上表可知(同样以挤压模具寿命为例),实施例1比对比例1提高了2.4,实施例1比对比例5提高了2.3,实施例1比对比例6提高了2.1,实施例1比对比例7提高了7.5,对比例1、5、6与实施例1的差值总和为6.8(小于对比例7与实施例1的差值7.5),可见,Er、Fe和Zn组合使用效果比分别单独使用的效果之和提高了10.29%。因此,本发明中多种元素之间存在协同作用,提升了铝合金材料的综合性能,各组分缺一不可。 At the same time, in order to enhance the strength and corrosion resistance of the aluminum alloy material, the present invention increases the content of manganese element, forms FeMnAl 6 phase by adding Zn, Fe, Er, reduces the solid solution of Mn in the aluminum matrix, and improves the ductility of the alloy. At the same time, it cooperates with Zn and Er to further reduce the solid solution of Mn and reduce the segregation phenomenon, refine the coarse phase in the structure, and solve the problem of high segregation and unevenness of Mn element. At the same time, Zn and Er can assist in the elimination of Si element Existing broken wall or shrinkage porosity problem, Zn, Fe, Er can significantly improve the processing performance of aluminum alloy material; From the above table we can know (also taking extrusion die life as an example), embodiment 1 has improved 2.4% compared with comparative example 1 , embodiment 1 has improved 2.3 compared with comparative example 5, and embodiment 1 has improved 2.1 compared with comparative example 6, and embodiment 1 has improved 7.5 compared with comparative example 7, and the difference sum of comparative examples 1,5,6 and embodiment 1 is 6.8 (7.5 less than the difference between Comparative Example 7 and Example 1), it can be seen that the combined effect of Er, Fe and Zn is 10.29% higher than the sum of the effects of separate use. Therefore, there is a synergistic effect among various elements in the present invention, which improves the comprehensive performance of the aluminum alloy material, and each component is indispensable.
本发明通过优化生产工艺和热处理工艺提升材料性能:生产过程中在熔炼炉和保温炉中均进行精炼,双级过滤并增加铸造过滤网过滤大部分杂质,与Er等元素配合净化基体;热处理过程中,发明人经大量试验发现,在450-460℃下保温88-100h为最优热处理条件,退火后晶粒长大均匀,见图1(A为实施例1制备的铝合金,B为对比例8制备的铝合金,C为对比例9制备的铝合金b,D为对比例2制备的铝合金),A中晶粒大小均匀,而B-D挤出的壁不均匀,C由于保温时间过长,晶粒粗大,且制备过程中均出现偏析现象,挤压时材料性能不稳定,出现粘铝、破壁现象,未经本发明热处理工艺制备的铝合金制成的模具最大承受重量仅为6.8t。The present invention improves the performance of the material by optimizing the production process and heat treatment process: during the production process, refining is carried out in both the smelting furnace and the holding furnace, two-stage filtration is added and casting filter screens are added to filter most of the impurities, and the substrate is purified with Er and other elements; the heat treatment process Among them, the inventors have found through a large number of experiments that the optimal heat treatment condition is to keep warm at 450-460°C for 88-100h, and the grains grow uniformly after annealing, as shown in Figure 1 (A is the aluminum alloy prepared in Example 1, and B is the The aluminum alloy prepared in Example 8, C is the aluminum alloy b prepared in Comparative Example 9, and D is the aluminum alloy prepared in Comparative Example 2), the grain size in A is uniform, while the extruded walls of B-D are uneven, and C is due to the excessive holding time Long, coarse grains, and segregation phenomenon occurs in the preparation process, the material performance is unstable during extrusion, and aluminum sticking and wall breaking appear. The maximum bearing weight of the mold made of aluminum alloy without the heat treatment process of the present invention is only 6.8t.
显然,上述实施例仅仅是为清楚地说明所作的举例,并非对实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式变化或变动。这里无需也无法对所有的实施方式予以穷举。而由此所引申出的显而易见的变化或变动仍处于本发明创造的保护范围之中。Apparently, the above-mentioned embodiments are only examples for clear description, and are not intended to limit the implementation. For those of ordinary skill in the art, on the basis of the above description, other changes or changes in various forms can also be made. It is not necessary and impossible to exhaustively list all the implementation manners here. However, the obvious changes or changes derived therefrom are still within the scope of protection of the present invention.

Claims (10)

  1. 一种挤压用铝合金,其特征在于,所述挤压用铝合金的组分及各组分的质量百分比为:Si 0.1-0.2%、Fe 0.15-0.25%、Mn 1.8-2.4%、Zn 0.05-0.18%、Er 0.03-0.06%、Ti 0.008-0.04%、Be 0.04-0.08%、V 0.01-0.02%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。An aluminum alloy for extrusion, characterized in that the components of the aluminum alloy for extrusion and the mass percentages of each component are: Si 0.1-0.2%, Fe 0.15-0.25%, Mn 1.8-2.4%, Zn 0.05-0.18%, Er 0.03-0.06%, Ti 0.008-0.04%, Be 0.04-0.08%, V 0.01-0.02%, the rest are Al and unavoidable impurities, and the total amount of impurities does not exceed 0.015%.
  2. 根据权利要求1所述的挤压用铝合金,其特征在于:所述挤压用铝合金的组分及各组分的质量百分比为:Si 0.18%、Fe 0.23%、Mn 2.23%、Zn 0.14%、Er 0.05%、Ti 0.02%、Be 0.06%、V 0.015%,其余为Al以及无法避免的杂质,杂质的总量不超过0.015%。The aluminum alloy for extrusion according to claim 1, characterized in that: the components of the aluminum alloy for extrusion and the mass percentages of each component are: Si 0.18%, Fe 0.23%, Mn 2.23%, Zn 0.14 %, Er 0.05%, Ti 0.02%, Be 0.06%, V 0.015%, the rest are Al and unavoidable impurities, and the total amount of impurities does not exceed 0.015%.
  3. 一种权利要求1或2所述的挤压用铝合金的制备方法,其特征在于,包括以下步骤:A method for preparing an aluminum alloy for extrusion according to claim 1 or 2, characterized in that it comprises the following steps:
    S1:将纯度不小于99.7%的铝合金加入熔炼炉中加热融化,在780-800℃下保温,吹入精炼剂,用氮气或氩气进行一次精炼,得到第一铝液;S1: Add aluminum alloy with a purity of not less than 99.7% into a melting furnace to heat and melt, keep it warm at 780-800°C, blow in refining agent, and conduct a refining with nitrogen or argon to obtain the first aluminum liquid;
    S2:在保温炉中向所述第一铝液中加入中间合金,搅拌25-35min,得到第二铝液;其中,保温炉的温度为780-800℃,所述中间合金为一种或多种,含有Si、Fe、Mn、Zn、Er、Ti、Be和V;S2: Add an intermediate alloy to the first molten aluminum in the holding furnace, and stir for 25-35 minutes to obtain the second molten aluminum; wherein, the temperature of the holding furnace is 780-800°C, and the intermediate alloy is one or more species, containing Si, Fe, Mn, Zn, Er, Ti, Be and V;
    S3:所述第二铝液的成分检验合格后,吹入精炼剂,用氮气或氩气进行二次精炼,静置后进行扒渣,得到第三铝液;其中,二次精炼时,吹入精炼剂后闷炉20-30min,精炼温度为780-800℃;S3: After the composition of the second aluminum liquid is qualified, the refining agent is blown in, nitrogen or argon is used for secondary refining, and after standing still, the slag is removed to obtain the third aluminum liquid; After adding the refining agent, the furnace is stuffy for 20-30 minutes, and the refining temperature is 780-800°C;
    S4:所述第三铝液通过保温炉倾倒,在进入除气箱前喂AlTiC丝,之后进行除气和双级过滤,得到第四铝液;S4: The third aluminum liquid is poured through the holding furnace, fed with AlTiC wire before entering the degassing box, and then degassed and double-stage filtered to obtain the fourth aluminum liquid;
    S5:对所述第四铝液进行连续浇铸,在浇嘴处设置铸造过滤网;其中,浇铸温度为710-720℃,浇铸速度为6.5-7.5t/h,冷却水温为25-35℃,出坯温度为520-550℃;S5: Continuously cast the fourth molten aluminum, and set a casting filter at the gate; wherein, the casting temperature is 710-720°C, the casting speed is 6.5-7.5t/h, and the cooling water temperature is 25-35°C, The billet temperature is 520-550°C;
    S6:对S5中连续浇铸得到的铸坯进行轧制,得到铝杆;其中,进轧温度为510-540℃,终轧温度为200-300℃;S6: rolling the slab obtained by continuous casting in S5 to obtain an aluminum rod; wherein, the rolling temperature is 510-540°C, and the finishing rolling temperature is 200-300°C;
    S7:将所述铝杆降温至60-80℃,吹干后进行收线,之后在7-9h内升温至450-460℃,保温88-100h,随炉冷至20-30℃,得到所述挤压用铝合金。S7: Cool down the aluminum rod to 60-80°C, blow it dry and take it up, then raise the temperature to 450-460°C within 7-9 hours, keep it warm for 88-100 hours, and cool it to 20-30°C with the furnace to obtain the obtained aluminum alloy for extrusion.
  4. 根据权利要求3所述的制备方法,其特征在于:在步骤S1中,一次精炼的时间为35-45min。The preparation method according to claim 3, characterized in that: in step S1, the time for one refining is 35-45min.
  5. 根据权利要求3所述的制备方法,其特征在于:在步骤S1或S3中,按2-3kg/t铝液加入精炼剂。The preparation method according to claim 3, characterized in that: in step S1 or S3, the refining agent is added at 2-3 kg/t aluminum liquid.
  6. 根据权利要求3所述的制备方法,其特征在于:在步骤S4中,双级过滤中第二次过滤的孔径为60目。The preparation method according to claim 3, characterized in that: in step S4, the pore size of the second filtration in the double-stage filtration is 60 mesh.
  7. 根据权利要求3所述的制备方法,其特征在于:在步骤S5中,喂AlTiC丝的速度为1.5-2.0m/min。The preparation method according to claim 3, characterized in that: in step S5, the speed of feeding AlTiC wire is 1.5-2.0m/min.
  8. 根据权利要求3所述的制备方法,其特征在于:在步骤S5中,所述铸造过滤网的孔径为16目。The preparation method according to claim 3, characterized in that: in step S5, the pore size of the casting filter is 16 mesh.
  9. 根据权利要求3所述的制备方法,其特征在于:在步骤S7中,保温90-96h。The preparation method according to claim 3, characterized in that: in step S7, keep warm for 90-96h.
  10. 使用权利要求1所述的挤压用铝合金制备的挤压产品。An extruded product prepared by using the aluminum alloy for extrusion according to claim 1.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116555606A (en) * 2023-05-15 2023-08-08 上海萨新东台热传输材料有限公司 Preparation method of wear-resistant aluminum alloy pipeline

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113846249B (en) * 2021-09-08 2022-07-08 江苏亨通电力特种导线有限公司 Aluminum alloy for extrusion and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2177638A1 (en) * 2008-10-15 2010-04-21 "Impexmetal" S.A. Aluminium alloy, in particular for heat exchangers manufacturing
CN102286679A (en) * 2011-09-02 2011-12-21 上海交通大学 Rare earth aluminum alloy used for heat exchanger and preparation method thereof
CN103103404A (en) * 2013-01-28 2013-05-15 华峰铝业股份有限公司 Anti-corrosion aluminum-manganese alloy and preparation method thereof
JP2018178170A (en) * 2017-04-06 2018-11-15 三菱アルミニウム株式会社 Thin wall fin material excellent in erosion resistance, manufacturing method of thin wall fin material excellent in erosion resistance, and manufacturing method of heat exchanger
CN108977699A (en) * 2018-08-17 2018-12-11 江苏亨通电力特种导线有限公司 A kind of preparation method of extrusion forming aluminium and corresponding aluminum alloy materials
CN109371295A (en) * 2018-11-23 2019-02-22 沈阳航空航天大学 A kind of high Mn content Al-Mn alloy and preparation method thereof
CN113846249A (en) * 2021-09-08 2021-12-28 江苏亨通电力特种导线有限公司 Aluminum alloy for extrusion and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6254054A (en) * 1985-09-02 1987-03-09 Showa Alum Corp Aluminum alloy excellent in cold workability
CN105296816B (en) * 2015-12-08 2016-09-14 江苏东强股份有限公司 High connductivity aluminum alloy materials and the preparation method of aluminum alloy cable conductor thereof
CN109439977A (en) * 2018-12-06 2019-03-08 广东兴发铝业有限公司 A kind of high tough erosion-resisting aluminium alloy and its preparation and pressing method
CN111424194B (en) * 2020-05-14 2021-07-06 永杰新材料股份有限公司 Aluminium-manganese alloy and its production method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2177638A1 (en) * 2008-10-15 2010-04-21 "Impexmetal" S.A. Aluminium alloy, in particular for heat exchangers manufacturing
CN102286679A (en) * 2011-09-02 2011-12-21 上海交通大学 Rare earth aluminum alloy used for heat exchanger and preparation method thereof
CN103103404A (en) * 2013-01-28 2013-05-15 华峰铝业股份有限公司 Anti-corrosion aluminum-manganese alloy and preparation method thereof
JP2018178170A (en) * 2017-04-06 2018-11-15 三菱アルミニウム株式会社 Thin wall fin material excellent in erosion resistance, manufacturing method of thin wall fin material excellent in erosion resistance, and manufacturing method of heat exchanger
CN108977699A (en) * 2018-08-17 2018-12-11 江苏亨通电力特种导线有限公司 A kind of preparation method of extrusion forming aluminium and corresponding aluminum alloy materials
CN109371295A (en) * 2018-11-23 2019-02-22 沈阳航空航天大学 A kind of high Mn content Al-Mn alloy and preparation method thereof
CN113846249A (en) * 2021-09-08 2021-12-28 江苏亨通电力特种导线有限公司 Aluminum alloy for extrusion and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116555606A (en) * 2023-05-15 2023-08-08 上海萨新东台热传输材料有限公司 Preparation method of wear-resistant aluminum alloy pipeline
CN116555606B (en) * 2023-05-15 2024-01-02 上海萨新东台热传输材料有限公司 Preparation method of wear-resistant aluminum alloy pipeline

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