WO2023033034A1 - ガラス体 - Google Patents

ガラス体 Download PDF

Info

Publication number
WO2023033034A1
WO2023033034A1 PCT/JP2022/032740 JP2022032740W WO2023033034A1 WO 2023033034 A1 WO2023033034 A1 WO 2023033034A1 JP 2022032740 W JP2022032740 W JP 2022032740W WO 2023033034 A1 WO2023033034 A1 WO 2023033034A1
Authority
WO
WIPO (PCT)
Prior art keywords
radio wave
conductive film
film
glass body
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2022/032740
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
稲岡大介
岡秀俊
大島英明
藤沢章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Sheet Glass Co Ltd
Original Assignee
Nippon Sheet Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Sheet Glass Co Ltd filed Critical Nippon Sheet Glass Co Ltd
Priority to CN202280060367.5A priority Critical patent/CN117916208A/zh
Priority to EP22864616.2A priority patent/EP4400483A4/en
Priority to US18/688,747 priority patent/US20250179872A1/en
Priority to JP2022570664A priority patent/JP7292540B1/ja
Publication of WO2023033034A1 publication Critical patent/WO2023033034A1/ja
Priority to JP2023090816A priority patent/JP2023113772A/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
    • E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/12—Supports; Mounting means
    • H01Q1/1271—Supports; Mounting means for mounting on windscreens
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0013—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices working as frequency-selective reflecting surfaces, e.g. FSS, dichroic plates, surfaces being partly transmissive and reflective
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/211—SnO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/216—ZnO
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/25—Metals
    • C03C2217/251—Al, Cu, Mg or noble metals
    • C03C2217/254—Noble metals
    • C03C2217/256—Ag
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/25—Metals
    • C03C2217/261—Iron-group metals, i.e. Fe, Co or Ni
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/32—After-treatment
    • C03C2218/328—Partly or completely removing a coating
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • E06B2009/2417—Light path control; means to control reflection

Definitions

  • the present invention relates to a glass body.
  • a glass body having heat insulation or heat shielding properties, in which a Low-E film (low-emissivity film) is formed on the plate surface of the window glass of a vehicle or building, is known (see Patent Document 1, for example).
  • This Low-E film has a problem that it has low permeability (has blocking properties) for radio waves in a frequency band of several hundred MHz to several tens of GHz.
  • an opening composed of a plurality of parallel lines is provided in the Low-E film, and the ratio of the length of the plurality of lines to the area of the Low-E film is By stipulating, the radio wave permeability is enhanced for radio waves in the frequency band of several hundred MHz to several tens of GHz.
  • Patent Document 3 discloses a multi-layer glass in which a first film region is provided on the second surface of the first glass plate, and an antenna is provided on the fourth surface of the second glass plate at a position facing the first film region.
  • An embodiment of a panel is disclosed.
  • Radio waves of 700 MHz to 30 GHz included in the frequency band used in the 4th generation mobile communication system (hereinafter referred to as "4G") and the 5th generation mobile communication system (hereinafter referred to as “5G”) are in the lower frequency band.
  • the straightness of the radio wave is higher than that of the radio wave, and the opening described in Patent Document 2 and the first film region described in the Patent Document 3 are set to have a shape that ensures the straightness of the radio wave.
  • the opening described in Patent Document 2 has a plurality of parallel lines in the Low-E film, it is likely to be visually recognized as a striped pattern, which greatly affects the appearance.
  • a glass body includes a first glass plate having a first surface and a second surface opposite to the first surface, and at least one of the first surface and the second surface
  • One of the plate surfaces includes a radio wave transmitting region through which radio waves having a straight wavelength can pass, and the radio wave transmitting region includes a plurality of radio wave passing portions that pass the radio waves and are adjacent to each other. and a conductive film portion in which the conductive film having the radio wave shielding property is formed between the radio wave passing portions, and the radio wave transmitting region is a part of the radio wave that has passed through the plurality of the radio wave passing portions. diffracts and overlaps in the space facing the conductive film portion.
  • radio waves of 700 MHz to 3.5 GHz, which is the frequency band of 4G, and radio waves of 3.6 GHz to 30 GHz, which is the frequency band of 5G have high straightness.
  • the radio wave intensity increases in the range facing the area of the plate without the conductive film.
  • it is better not to provide a conductive film on the glass body but in that case, the heat insulation and heat shielding properties (hereinafter referred to as "heat insulating performance”) will be lost, and the heat insulating performance and radio wave permeability will be lost.
  • the glass body of this configuration is provided with a plurality of mutually spaced radio wave passage portions for passing radio waves in the radio wave transmission region, and a conductive film portion is provided between the adjacent radio wave passage portions.
  • the heat insulation performance is enhanced by providing the conductive film portion
  • radio wave transparency is enhanced by providing a plurality of radio wave passing portions.
  • the radio wave transmission region of this configuration is configured with a radio wave diffusion structure in which part of the radio wave that has passed through the multiple radio wave passage portions is diffracted and overlapped in the space facing the conductive film portion.
  • the radio wave that has passed through the radio wave passing portion not only travels straight but also diffracts, and the radio wave diffraction components overlap in the space facing the conductive film portion.
  • the radio wave intensity can be increased in the space facing the conductive film portion where the radio wave intensity tends to be weak, and the radio wave reception area can be enlarged.
  • the glass body has radio wave transparency that can expand the reception area.
  • the radio wave passing portion has a maximum length of a line segment passing through the center that is four times or less the wavelength.
  • the radio wave passage part is rectangular and the length of one side is 100 mm, the radio wave diffraction component with a wavelength of 25 mm or more (frequency band of about 12 GHz or less) increases.
  • the maximum length of the line segment passing through the center of the radio wave passing part is set to four times or less than the wavelength, the radio wave passing can increase the radio wave intensity in a wide reception area according to the frequency band used.
  • the dimensions of the part can be determined.
  • the width of the conductive film portion which is the shortest distance between the adjacent radio wave passing portions, is 10 mm or more and 500 mm or less.
  • the width of the conductive film portion which is the shortest distance between adjacent radio wave passing portions, is 10 mm or more and 500 mm or less, both heat insulation performance and radio wave transparency can be achieved. If the width of the conductive film portion is less than 10 mm, the radio wave shielding property of the conductive film portion is reduced, and the entire radio wave transmission region has integral radio wave transparency. If the width of the film portion is greater than 500 mm, a dead space in which radio waves do not overlap is likely to occur in the vicinity of the first glass plate.
  • the at least one plate surface includes a radio wave non-transmitting region in which the conductive film is formed around the radio wave transmitting region, and the radio wave passing portion includes the conductive films spaced apart from each other. A patterning having a plurality of islands covered with is formed.
  • a thin line having a line width of 1 ⁇ m or more and 100 ⁇ m or less is formed between the adjacent islands, and the interval between the adjacent thin lines is 200 ⁇ m or more and 10 mm or less.
  • thin lines having a line width of 1 ⁇ m or more and 100 ⁇ m or less are formed between adjacent islands, and if the distance between adjacent thin lines is 200 ⁇ m or more and 10 mm or less, radio wave transmission is ensured. while reducing the influence on the appearance. If the line width of the thin wire is less than 1 ⁇ m, it becomes difficult to insulate adjacent islands, making it difficult to ensure radio wave transmission. Also, if the distance between adjacent thin wires is less than 200 ⁇ m, the heat insulation performance is lowered, and if it is more than 10 mm, the radio wave transmittance tends to be reduced.
  • Another feature is that the island is rectangular.
  • the wavelength is 10 mm or more and 428 mm or less.
  • the linearity is particularly high, so the usefulness of adopting the glass body with the above configuration can be enhanced.
  • the conductive film is a Low-E film.
  • the conductive film is a Low-E film as in this configuration, it is possible to ensure radio wave transparency that can expand the reception area while improving the heat insulation performance.
  • a second glass plate having a third surface facing the second surface and a fourth surface opposite to the third surface, the second surface and the third surface and forming a gap layer between the first glass plate and the second glass plate, wherein the radio wave transmitting region is formed on the second surface or the third surface.
  • the heat insulating performance is enhanced.
  • the radio wave transmission region is formed on the second surface or the third surface, the usefulness of the glass body having the above configuration can be enhanced.
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through an opening in a comparative example
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing a simulation result of radio waves passing through the radio wave transmission region in the present embodiment
  • FIG. 10 is a diagram showing spread of radio waves passing through an opening in Comparative Example 1;
  • FIG. 10 is a diagram showing spread of radio waves passing through an opening in Comparative Example 2;
  • FIG. 10 is a diagram showing spread of radio waves passing through an opening in Comparative Example 3;
  • FIG. 4 is a diagram showing spread of radio waves passing through the radio wave transmission region in the embodiment.
  • FIG. 10 is a diagram showing spread of radio waves passing through an opening when a plurality of glass bodies of Comparative Example 3 are arranged side by side in the plate surface direction;
  • FIG. 5 is a diagram showing spread of radio waves passing through radio wave transmission regions when a plurality of glass bodies of the present embodiment are arranged side by side in the plate surface direction.
  • FIG. 11 is an enlarged front view of a glass body having a radio wave transmission region in another embodiment;
  • the glass body 100 in this embodiment can be used for various purposes, for example, it can be used as window glass of buildings, window glass of automobiles, aircraft, ships, trains, and other moving bodies.
  • FIG. 1 shows a schematic diagram in which the glass body 100 is used as a windowpane of a building.
  • the glass body 100 may be a window glass that contacts the outside air, or may be a window glass that partitions a room.
  • the glass body 100 includes a first glass plate 1 whose plate surface has a rectangular outer shape.
  • the glass body 100 is a straight 4G frequency band of 700 MHz to 3.5 GHz (wavelength: 428 mm to 85 mm) or a 5G frequency band of 3.6 GHz to 30 GHz (wavelength: 83 mm to 10 mm).
  • a radio wave non-transmitting region 42 in which a Low-E film 41 (an example of a conductive film) is formed around the radio wave transmitting region 43 .
  • the radio wave transmission region 43 in this embodiment has a radio wave diffusion structure in which part of the radio wave is diffracted to expand the radio wave reception area. Details of the radio wave transmission region 43 will be described later.
  • the material of the first glass plate 1 (the same applies to the second glass plate 2 described later) is not particularly limited, and known glass plates can be used.
  • various glass plates such as heat-absorbing glass, clear glass, green glass, UV green glass, and soda-lime glass can be used.
  • the thickness of the first glass plate 1 is not particularly limited, it is preferably 2 to 15 mm, more preferably 2.5 to 8 mm.
  • the first glass plate 1 has a first surface 11 and a second surface 12 opposite to the first surface 11 .
  • a Low-E film 41 (an example of a conductive film) having radio wave shielding properties is formed on the second surface 12 of the first glass plate 1 .
  • the Low-E film 41 is a conductive thin film that blocks radio waves.
  • the surface resistivity of the conductive thin film is preferably less than 20 ⁇ . By doing so, the Low-E film 41 has a high reflectance in the wavelength region from the infrared region to the radio wave region (frequency band of several hundred MHz to several tens of GHz).
  • the plate surface of the first glass plate 1 on which the Low-E film 41 is formed has low radio wave transmittance, but also has a low emissivity.
  • the second surface 12 of the first glass plate 1 has a radio wave impermeable region 42 over which a Low-E film 41 is formed.
  • a radio wave transmission region 43 is formed by removing a portion of the Low-E film 41 by laser processing or the like on a portion of the second surface 12 (central portion in the figure), which is the plate surface on which the Low-E film 41 is formed. is provided.
  • This radio wave transmission region 43 is a straight 4G frequency band of 700 MHz to 3.5 GHz (wavelength 428 mm to 85 mm) and a 5G frequency band of 3.6 GHz to 30 GHz (wavelength 83 mm to 10 mm). are arranged to allow transmission of radio waves corresponding to the band of The radio wave non-transmitting region 42 and the radio wave transmitting region 43 may be provided on the first surface 11 of the first glass plate 1 .
  • the glass body 100 is a multi-layer glass having two glass plates having substantially the same rectangular outer shape, that is, a first glass plate 1 and a second glass plate 2 .
  • a pair of glass plates 1 and 2 are connected to each other by spacers 5 arranged at their peripheral edges.
  • a space layer 3 is formed between the pair of glass plates 1 and 2 by the spacers 5 .
  • the first glass plate 1 has a first surface 11 that is a plate surface on the outdoor side, and a second surface 12 that is a plate surface on the void layer 3 side opposite to the first surface 11 .
  • the second glass plate 2 has a third surface 13 which is a plate surface on the void layer 3 side, and a fourth surface 14 which is a plate surface on the indoor side opposite to the third surface 13 . That is, the spacer 5 is in contact with the second surface 12 and the third surface 13 .
  • a low-E film 41 (an example of a conductive film) having radio wave shielding properties is formed on the plate surface (second surface 12) on the void layer 3 side.
  • the space layer 3 is sealed by a frame in which a sealing material arranged outside the spacer 5 is arranged.
  • the second surface 12 of the first glass plate 1 has a radio wave non-transmissive area 42 in which a Low-E film 41 is formed over the entire area. Further, on the second surface 12, which is the plate surface on which the Low-E film 41 is formed, a radio wave transmission region 43 is provided by removing part of the Low-E film 41 by laser processing or the like.
  • This radio wave transmission region 43 is a straight 4G frequency band of 700 MHz to 3.5 GHz (wavelength 428 mm to 85 mm) and a 5G frequency band of 3.6 GHz to 30 GHz (wavelength 83 mm to 10 mm).
  • the multi-layer glass as in the present embodiment, if the Low-E film 41 is arranged on the second surface 12 of the first glass plate 1 or the third surface 13 of the second glass plate 2, the heat insulation performance is improved. .
  • the radio wave non-transmitting region 42 and the radio wave transmitting region 43 may be provided on the first surface 11 of the first glass plate 1 or the fourth surface 14 of the second glass plate 2 .
  • an antenna (not shown) for radio wave transmission/reception may be installed on the plate surface (fourth surface 14) of the glass body 100 on the indoor side, or an antenna may be installed on the indoor ceiling or the like.
  • the Low-E film 41 is not particularly limited as long as it does not interfere with the object of the present invention, but is preferably a multilayer film containing a layer containing silver as a main component. Also, the Low-E film 41 preferably comprises a multi-layer structure in which two or more layers selected from a metal layer, a metal oxide layer, a metal nitride layer and a metal oxynitride layer are laminated.
  • Suitable examples of metal layers include silver layers.
  • Suitable examples of metal oxide layers include tin oxide layers, titanium oxide layers and zinc oxide layers.
  • Suitable examples of metal nitride layers include silicon nitride.
  • Suitable examples of metal oxynitride layers include silicon oxynitride.
  • the Low-E film 41 is preferably formed by a vacuum film formation method such as physical vapor deposition (PVD), and is particularly preferred by a sputtering method because it can form a film uniformly over a large area.
  • the radio wave transmitting region 43 is formed by, for example, forming a Low-E film 41 on a glass plate by sputtering and then removing the Low-E film 41 by laser processing or the like.
  • the radio wave transmitting region 43 may be formed using various masking materials. By forming the radio wave transmitting region 43 by such a method, it can be easily arranged at a desired position on the glass plate.
  • the Low-E film 41 is more preferably a multi-layer laminate of three or more layers selected from a tin oxide layer, a silicon nitride layer, a silicon oxynitride layer, a titanium oxide layer, a zinc oxide layer and a silver layer. , (1) tin oxide layer (first antireflection layer), zinc oxide layer (first antireflection layer), silver layer (metal layer), zinc oxide layer (second antireflection layer), and Tin oxide layer (second antireflection layer), (2) silicon nitride layer (first antireflection layer), zinc oxide layer (first antireflection layer), silver layer (metal layer) and zinc oxide layer (second reflection Most preferably, it consists of 3 or 5 layers laminated with a protective layer).
  • the Low-E film 41 contains a metal layer whose main component is silver.
  • the film thickness of the metal layer is preferably 5 nm or more and 20 nm or less, more preferably 10 nm or more and 15 nm or less. Since the Low-E film 41 has a metal layer containing silver as a main component and having a predetermined film thickness, heat radiation can be suppressed. Thereby, the glass body 100 can improve the heat insulation performance. In addition, since the film thickness of the metal layer is 15 nm or less, the influence of the Low-E film 41 on the appearance can be reduced.
  • the Low-E film 41 has a first antireflection layer on the inner side of the metal layer, which is closer to the plate surface on which the Low-E film 41 is formed, and the total optical film thickness of the first antireflection layer is It is suitable in it being 20 nm or more and 120 nm or less.
  • the Low-E film 41 has a second antireflection layer on the side far from the plate surface on which the Low-E film 41 is formed, which is the outside of the metal layer, and the total optical film thickness of the second antireflection layer is It is suitable in it being 60 nm or more and 120 nm or less.
  • the optical film thickness can be calculated by (refractive index n) ⁇ (film thickness d).
  • the first antireflection layer (second antireflection layer) is composed of a plurality of films
  • the sum of the optical film thicknesses calculated for the respective films is the thickness of the first antireflection layer (second antireflection layer).
  • Optical film thickness In calculating the optical film thickness, the value of the refractive index varies depending on the wavelength of visible light.
  • the optical film thickness is based on the refractive index when the wavelength of visible light is the standard wavelength (550 nm) in the general visible range.
  • the Low-E film 41 has the first antireflection layer having a predetermined thickness on the side closer to the second surface 12 of the first glass plate 1 than the metal layer. is protected, the Low-E film 41 has low reflection performance, and can reliably block heat.
  • the glass body 100 can achieve a high visible light transmittance and a suitable reflection color tone.
  • the Low-E film 41 protects the metal layer even when the second antireflection layer having a predetermined thickness exists on the far side of the second surface 12 of the first glass plate 1 with respect to the metal layer. As a result, the Low-E film 41 has low reflection performance and can reliably block heat. In addition, the glass body 100 can achieve a high visible light transmittance and a suitable reflection color tone.
  • the radio wave impermeable region 42 in this embodiment is a region in which the Low-E film 41 is formed around the radio wave transmitting region 43, and the radio wave transmitting region 43 is part of the radio wave. It has a radio wave diffusion structure that diffracts and expands the radio wave reception area.
  • the radio wave transmitting region 43 is configured with a radio wave diffusing structure in which a part of the radio wave passing through the plurality of radio wave passing portions 43A is diffracted and overlaps in the space facing the conductive film portion 43B.
  • the radio wave passing portion 43A in this embodiment is formed in a rectangular shape, and the longest side of the four sides is four times or less the wavelength of the passing radio wave (10 mm to 500 mm, hereinafter simply referred to as “wavelength”). It has become.
  • the maximum length L of the line segment passing through the center of the radio wave passing portion 43A (electric field vibration direction of the polarized radio wave) is four times or less the wavelength. In this way, if the maximum length L of the line segment passing through the center of the radio wave passing portion 43A is set to four times or less of the wavelength, the radio wave passing can increase the radio wave intensity in a wide receiving area according to the frequency band used.
  • the dimensions of portion 43A can be determined.
  • radio wave passing portion 43A For radio waves corresponding to the 5G (millimeter wave) frequency band of 30 GHz to 300 GHz (wavelength less than 11 mm), it is difficult to process the radio wave passing portion 43A.
  • the wavelength of the radio wave to be transmitted may be 10 mm or more, or may be limited to 5G (sub 6 band) wavelength 49 mm or more (frequency band 6 GHz or less).
  • the radio wave passing portion 43A is square, all four sides are equal to the maximum length L of the line segment passing through the center of the radio wave passing portion 43A. The other two sides are equal to the maximum length L of the line segment passing through the center of the radio wave passing portion 43A.
  • the maximum length L of the line segment passing through the center of the radio wave passing portion 43A is preferably 10 mm or more and 4 times or less the wavelength, and more preferably 20 mm or more and 2 times or less the wavelength. . If the maximum length L of the line segment passing through the center of the radio wave passing portion 43A is less than 10 mm, the patterning process described later becomes difficult. It becomes difficult to increase the strength.
  • the width W of the conductive film portion 43B which is the shortest distance between the adjacent radio wave passage portions 43A, is preferably 10 mm or more and 500 mm or less, more preferably 10 mm or more and 100 mm or less. As described above, if the width W of the conductive film portion 43B, which is the shortest distance between the adjacent radio wave passage portions 43A, is 10 mm or more and 500 mm or less, both heat insulation performance and radio wave transparency can be achieved. If the width W of the conductive film portion 43B is smaller than 10 mm, the radio wave shielding property of the conductive film portion 43B is reduced, and the entire radio wave transmission region 43 has integral radio wave transparency. If the width W of the conductive film portion 43B is larger than 500 mm, a dead space in which radio waves do not overlap is likely to occur in the space near the first glass plate 1 .
  • the radio wave passing portion 43A is formed by, for example, forming a Low-E film 41 on a glass plate by a sputtering method, and then removing only the Low-E film 41 by laser processing or the like. is formed.
  • the thin wire 43Ab By forming the thin wire 43Ab in this manner, the glass plate is not damaged, and the thin wire 43Ab can be made inconspicuous.
  • a plurality of islands 43Aa in the present embodiment are formed in a symmetrical shape that is spaced apart from each other at equal intervals via fine lines 43Ab having the same line width.
  • the line width of the thin wire 43Ab is preferably 1 ⁇ m or more and 100 ⁇ m or less, more preferably 5 ⁇ m or more and 30 ⁇ m or less. If the line width of the fine wire 43Ab is smaller than 1 ⁇ m, it becomes difficult to insulate the adjacent islands 43Aa from each other by forming the integrated Low-E film 41, making it difficult to ensure radio wave transmission. , the heat insulation performance tends to decrease.
  • the interval between the adjacent thin wires 43Ab (distance between the line centers of the adjacent thin wires 43Ab) is preferably 200 ⁇ m or more and 10 mm or less, more preferably 500 ⁇ m or more and 3 mm or less. Further, if the interval between the adjacent fine wires 43Ab is less than 200 ⁇ m, the heat insulating performance is lowered, and if it is larger than 10 mm, the radio wave transmittance tends to be lowered. In addition, the upper limit of the interval between the adjacent thin wires 43Ab is preferably one-third or less of the wavelength.
  • a soda-lime glass having a thickness of 6 mm is used for the first glass plate 1, and the Low-E film 41 covering the second surface 12 is made of SnO2/ZnO/Ag/SUS/ As ZnO/SnO2, the total film thickness was set to 80 nm, and the emissivity was set to 0.1.
  • the laser processing conditions for removing the Low-E film 41 are as follows: a YAG:Nd laser is used at a repetition frequency of 100 kHz, a wavelength of 355 nm, and an operation speed of 300 mm/sec so that only the Low-E film 41 can be removed without removing the glass. and
  • Emissivity was measured according to JIS-R3106 using a Fourier transform infrared spectrophotometer (Frontier Gold manufactured by Perkin Elmer). Table 1 shows the emissivity of the radio wave passing portion 43A when the number and size of the radio wave passing portion 43A, and the line width and spacing of the thin wires 43Ab are changed. All of the radio wave passing portions 43A and the islands 43Aa are formed in a square shape, and the width of the conductive film portion 43B, which is the shortest distance between the adjacent radio wave passing portions 43A, is set to 50 mm.
  • the line width of the thin wire 43Ab is set to 100 ⁇ m or less.
  • the interval between the fine wires 43Ab is set to 200 ⁇ m or more, deterioration of the emissivity is suppressed and heat insulation performance is maintained, compared to the case where the entire plate surface of the first glass plate 1 is covered with the Low-E film 41. is understandable.
  • FIGS. 5 to 12 show vertical incidence in which radio waves are vertically incident on the first surface 11 of the first glass plate 1, and FIGS. On the other hand, oblique incidence was used in which radio waves were obliquely incident.
  • 5 to 8 show simulations viewed from a plan view (upper side of the opening) having an opening of 100 mm ⁇ 100 mm (the maximum length L of a line segment passing through the center is 100 mm) as the radio wave passing portion 43A of the radio wave transmitting region 43. Results are shown.
  • a simulation was performed in which radio waves of 30 GHz to 1 GHz (wavelengths of 10 mm to 300 mm) were applied to the radio wave passing portion 43A.
  • the area surrounded by the dashed line in the figure shows the distribution of strong radio waves (radio wave transmission loss of 10 dB or less when the incident radio wave is 0 dB).
  • the radio wave passing through the radio wave passing portion 43A travels straight without being diffracted.
  • the radio wave passing through the radio wave passing portion 43A reaches the space facing the conductive film portion 43B. It can be seen that the light is diffracted so as to expand.
  • FIGS. 7 and 8 show how radio waves passing through adjacent radio wave passing portions 43A overlap when the width W of the conductive film portion 43B is set to 50 mm.
  • the radio wave transmitting region 43 is configured with a radio wave diffusing structure in which a part of the radio wave that has passed through the plurality of radio wave passing portions 43A is diffracted and overlaps in the space facing the conductive film portion 43B.
  • the low frequency band of 3 GHz to 1 GHz (wavelength 100 mm to 300 mm)
  • the wavelength of the radio wave (30 mm to 300 mm) is preferably larger than 1/4 of the opening length of 100 mm (the maximum length L of the line segment passing through the center).
  • the radio wave passing portion 43A is preferably four times or less the wavelength.
  • the wavelength of the radio wave (60 mm to 300 mm) is larger than half of the opening length of 100 mm (the maximum length L of the line segment passing through the center). It is less than twice the wavelength.
  • FIG. 9 shows Comparative Example 1 in which the entire second surface 12 of the first glass plate 1 is covered with the Low-E film 41, and FIG. Comparative Example 2 with one 100 mm ⁇ 100 mm opening formed by removing the -E film 41, FIG. 3 shows Comparative Example 3 having one 500 mm ⁇ 500 mm opening formed by FIG.
  • 12 shows that, like the glass body 100 according to the above-described embodiment, 5 ⁇ 5 radio wave transmitting portions 43A of 100 mm ⁇ 100 mm are arranged to form a total radio wave transmitting region 43 of 500 mm ⁇ 500 mm on the second surface of the first glass plate 1. 12 shows the present embodiment formed in the center.
  • Comparative Example 1 shown in FIG. 9 radio waves were blocked and the radio wave transmission loss was 30 dB or more.
  • Comparative Example 2 shown in FIG. 10 only radio waves propagated straight from the opening, and there was no spreading of the radio waves.
  • Comparative Example 3 shown in FIG. 11 the opening length was 500 mm, which was four times or more the radio wave wavelength of 86 mm, so there was almost no spread of radio waves.
  • the radio wave transmission loss spreads over the range of 3 dB to 15 dB, and although the radio wave intensity is slightly reduced, the radio wave reception area can be expanded.
  • FIGS. 13 and 14 show simulation results of the spread of radio waves when four first glass plates 1 are arranged side by side in the plate surface direction.
  • a radio wave having a frequency band of 3.5 GHz (wavelength 86 mm) is incident rightward from the first surface 11 side of each first glass plate 1 toward the second surface 12.
  • It shows the spread of radio waves in a region R (a chain double-dashed line in the figure) formed horizontally along the xy plane when the light is obliquely incident at an angle of 45 degrees.
  • the region R is a rectangular region formed by a first side portion A on which the four first glass plates 1 are arranged and a second side portion B perpendicular to the first side portion A.
  • FIG. 13 and 14 show simulation results of the spread of radio waves when four first glass plates 1 are arranged side by side in the plate surface direction.
  • the length of the first side A is set to 7800 mm, and the length of the second side B is set to 5500 mm.
  • a plurality of openings (radio wave transmission regions 43) along the first side A are set such that the distance P1 from both ends of the first side A to the openings is set to 900 mm, and the distance P2 between adjacent openings is set to 1800 mm.
  • the glass body of Comparative Example 3 having one opening of 500 mm ⁇ 500 mm formed by removing the Low-E film 41 in the center of the second surface 12 is used as the first glass plate 1 .
  • FIG. 13 the glass body of Comparative Example 3 having one opening of 500 mm ⁇ 500 mm formed by removing the Low-E film 41 in the center of the second surface 12 is used as the first glass plate 1 .
  • 5 ⁇ 5 radio wave transmitting portions 43A of 100 mm ⁇ 100 mm are arranged to form a radio wave transmitting region 43 of a total of 500 mm ⁇ 500 mm as a second glass plate.
  • the glass body of this embodiment formed in the center of the surface 12 is used.
  • each radio wave that has passed through the opening of the first glass plate 1 has a small spread in the horizontal direction, so the radio wave spreads only about half of the region R.
  • each radio wave that has passed through the radio wave transmission region 43 has a large spread in the horizontal direction. became.
  • a specific description will be given below.
  • a virtual diagonal line C is drawn from the upper left corner to the lower right corner of the region R, and the left side of the diagonal line C is defined as the first region R1 and the right side of the region R is defined as the second region R2. In this case, in FIG.
  • the radio waves passing through the opening of the first glass plate 1 reach the first region R1, but do not reach the region away from the diagonal line C in the second region R2.
  • FIG. 14 it was confirmed that the radio waves spread widely not only in the first region R1 but also in the second region R2, and that the radio waves spread over the region R as a whole, although the radio wave intensity was slightly reduced.
  • the glass body 100 of the present embodiment is provided with a plurality of radio wave passing portions 43A that pass radio waves in the radio wave transmitting region 43, and the conductive film portion 43B is provided between the adjacent radio wave passing portions 43A. ing.
  • the conductive film portion 43B in the radio wave transmitting region 43 as well, the heat insulation performance is enhanced, and by providing the plurality of radio wave passing portions 43A, the radio wave transmittance is enhanced.
  • the radio wave transmission region 43 is configured with a radio wave diffusion structure in which a part of the radio wave that has passed through the plurality of radio wave passage portions 43A is diffracted and overlaps in the space facing the conductive film portion 43B.
  • the radio wave that has passed through the radio wave passage portion 43A not only travels straight, but also is diffracted, and the radio wave diffraction components overlap in the space facing the conductive film portion 43B.
  • the radio wave intensity can be increased in the space facing the conductive film portion 43B where the radio wave intensity tends to be weak, and the radio wave reception area can be enlarged. Therefore, the glass body 100 has radio wave transparency capable of expanding the reception area.
  • the radio wave transmitting region 43 in the above-described embodiment is not limited to a rectangular shape, and may be, for example, circular, oval, elliptical, cross-shaped, or the like. Even in this case, it is preferable that the maximum length L of the line segment passing through the center of the radio wave passing portion 43A is 10 mm or more and 4 times or less of the wavelength.
  • the radio wave passing portion 43A of the radio wave transmitting region 43 may be formed in an annular shape. Even in this case, it is preferable that the radio wave passing portion 43A be subjected to a patterning process in which a plurality of thin wires 43Ab are concentrically formed at regular intervals.
  • the radio wave transmitting region 43 does not need to expose the glass plate by removing the Low-E film 41, and it is sufficient if at least the metal layer containing silver as a main component is removed.
  • the heat shield film is arranged on the second surface 12 of the first glass plate 1, and the Low-E film 41 is arranged on the third surface 13 of the second glass plate 2.
  • the heat shield film is preferably a multilayer film containing a layer containing titanium nitride as a main component.
  • a suitable example of the metal nitride layer is a titanium nitride layer.
  • the film thickness of the heat shield film is appropriately selected depending on the type of film to be laminated, but is usually 5 to 100 nm, preferably 10 to 50 nm.
  • the heat shielding film is composed of, for example, a heat absorbing film. When the heat shielding film is a heat ray absorbing film, infrared rays can be absorbed by the heat shielding film, so that the heat shielding property of the glass body 100 can be improved.
  • the present invention can be used for glass bodies as window glass of buildings and window glass of moving bodies such as automobiles, aircraft, ships, and trains.
  • first glass plate 2 second glass plate 3: void layer 5: spacer 11: first surface 12: second surface 13: third surface 14: fourth surface 41: Low-E film (conductive film) 42: radio wave non-transmitting region 43: radio wave transmitting region 43A: radio wave passing portion 43Aa: island 43Ab: thin wire 43B: conductive film portion 100: glass body L: maximum length W of line segment passing through the center: width of conductive film portion

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Surface Treatment Of Glass (AREA)
  • Securing Of Glass Panes Or The Like (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Aerials With Secondary Devices (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
PCT/JP2022/032740 2021-09-06 2022-08-31 ガラス体 Ceased WO2023033034A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN202280060367.5A CN117916208A (zh) 2021-09-06 2022-08-31 玻璃体
EP22864616.2A EP4400483A4 (en) 2021-09-06 2022-08-31 GLASS BODY
US18/688,747 US20250179872A1 (en) 2021-09-06 2022-08-31 Glass body
JP2022570664A JP7292540B1 (ja) 2021-09-06 2022-08-31 ガラス体
JP2023090816A JP2023113772A (ja) 2021-09-06 2023-06-01 ガラス体

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2021-144790 2021-09-06
JP2021144790 2021-09-06

Publications (1)

Publication Number Publication Date
WO2023033034A1 true WO2023033034A1 (ja) 2023-03-09

Family

ID=85411301

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2022/032740 Ceased WO2023033034A1 (ja) 2021-09-06 2022-08-31 ガラス体

Country Status (5)

Country Link
US (1) US20250179872A1 (https=)
EP (1) EP4400483A4 (https=)
JP (2) JP7292540B1 (https=)
CN (1) CN117916208A (https=)
WO (1) WO2023033034A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024095898A1 (ja) * 2022-10-31 2024-05-10 Ａｇｃ株式会社 熱線反射基板
WO2025070567A1 (ja) * 2023-09-29 2025-04-03 積水化学工業株式会社 窓材及び窓材の製造方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000226235A (ja) 1999-02-08 2000-08-15 Central Glass Co Ltd 低放射率ガラスおよびその製法
WO2019073116A2 (en) * 2017-10-10 2019-04-18 Stealthcase Oy CONSTRUCTION MATERIAL
WO2019189042A1 (ja) * 2018-03-27 2019-10-03 日本板硝子株式会社 車両用窓ガラス及びその製造方法
US20200048958A1 (en) * 2016-10-18 2020-02-13 Samsung Electronics Co., Ltd. Film laminate and window product comprising same
WO2020054762A1 (ja) 2018-09-14 2020-03-19 Ａｇｃ株式会社 電波透過性基板
WO2020221955A1 (en) * 2019-04-29 2020-11-05 Stealthcase Oy A microwave transformer and a system for fabricating the same
WO2021027269A1 (en) * 2019-08-12 2021-02-18 Antwave Intellectual Property Limited Slotted electrically conductive structure for improving indoor penetration of wireless communication signal
WO2021095885A1 (ja) 2019-11-15 2021-05-20 日本板硝子株式会社 ガラス体

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012126578A (ja) * 2009-04-13 2012-07-05 Asahi Glass Co Ltd 自動車ガラス用積層体、その製造方法、およびフロントガラス
JP5640906B2 (ja) * 2011-06-22 2014-12-17 日産自動車株式会社 合わせガラス
TR201900179T4 (tr) * 2012-10-15 2019-02-21 Saint Gobain Yüksek frekans iletimli panel.
FI127500B (en) * 2016-10-11 2018-07-31 Lammin Ikkuna Oy Frequency selective structure
JP7788240B2 (ja) * 2021-09-06 2025-12-18 日本板硝子株式会社 ガラス体

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000226235A (ja) 1999-02-08 2000-08-15 Central Glass Co Ltd 低放射率ガラスおよびその製法
US20200048958A1 (en) * 2016-10-18 2020-02-13 Samsung Electronics Co., Ltd. Film laminate and window product comprising same
WO2019073116A2 (en) * 2017-10-10 2019-04-18 Stealthcase Oy CONSTRUCTION MATERIAL
WO2019189042A1 (ja) * 2018-03-27 2019-10-03 日本板硝子株式会社 車両用窓ガラス及びその製造方法
WO2020054762A1 (ja) 2018-09-14 2020-03-19 Ａｇｃ株式会社 電波透過性基板
WO2020221955A1 (en) * 2019-04-29 2020-11-05 Stealthcase Oy A microwave transformer and a system for fabricating the same
WO2021027269A1 (en) * 2019-08-12 2021-02-18 Antwave Intellectual Property Limited Slotted electrically conductive structure for improving indoor penetration of wireless communication signal
WO2021095885A1 (ja) 2019-11-15 2021-05-20 日本板硝子株式会社 ガラス体

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP4400483A4

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024095898A1 (ja) * 2022-10-31 2024-05-10 Ａｇｃ株式会社 熱線反射基板
WO2025070567A1 (ja) * 2023-09-29 2025-04-03 積水化学工業株式会社 窓材及び窓材の製造方法

Also Published As

Publication number Publication date
US20250179872A1 (en) 2025-06-05
JP2023113772A (ja) 2023-08-16
EP4400483A1 (en) 2024-07-17
JP7292540B1 (ja) 2023-06-16
CN117916208A (zh) 2024-04-19
JPWO2023033034A1 (https=) 2023-03-09
EP4400483A4 (en) 2025-08-27

Similar Documents

Publication Publication Date Title
JP3243789B2 (ja) 電波吸収性パネル
JP7292540B1 (ja) ガラス体
JP7661232B2 (ja) ガラス体
US11563128B2 (en) Optically transparent electromagnetically shielding element comprising a plurality of zones
WO2023153328A1 (ja) フレネルゾーンプレートレンズ、フレネルゾーンプレートレンズ一体型窓ガラス、及びフレネルゾーンプレートレンズ付き窓ガラス
JP7748816B2 (ja) 複層ガラスパネル
JP2017538646A (ja) 電磁遮蔽用加熱ガラスパネル
RU2610079C2 (ru) Демпфирующее радиолокационное отражение остекление
WO2023032535A1 (ja) ガラス体
KR102832160B1 (ko) 전자파 투과 필름 및 윈도우 구조체
JP2017181911A (ja) 電波透過性赤外線反射積層体および閉鎖部材
JP7683608B2 (ja) 周波数選択表面装荷部材
KR102759824B1 (ko) 단열 필름 및 윈도우 구조체
JP2018002534A (ja) 合わせガラスおよび閉鎖部材
JP2002076672A (ja) 電磁波吸収体
WO2026004511A1 (ja) 電波透過体及び窓材
TW202602815A (zh) 電波穿透體及窗材
JP2025154063A (ja) 積層構造体
KR20250132160A (ko) 단열 필름 및 윈도우 구조체
CN119038883A (zh) 用于电磁波增透的低辐射玻璃
WO2026004510A1 (ja) 電波透過体及び窓材
CN118210089A (zh) 一种多光谱伪装装置及制造方法
CN119256250A (zh) 热线反射基板以及窗玻璃
JPH01171298A (ja) 電磁波遮蔽層

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2022570664

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 22864616

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 202280060367.5

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2022864616

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2022864616

Country of ref document: EP

Effective date: 20240408

WWP Wipo information: published in national office

Ref document number: 18688747

Country of ref document: US