WO2023020452A1 - 一种无卤阻燃聚丙烯组合物及其制备方法和应用 - Google Patents

一种无卤阻燃聚丙烯组合物及其制备方法和应用 Download PDF

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WO2023020452A1
WO2023020452A1 PCT/CN2022/112639 CN2022112639W WO2023020452A1 WO 2023020452 A1 WO2023020452 A1 WO 2023020452A1 CN 2022112639 W CN2022112639 W CN 2022112639W WO 2023020452 A1 WO2023020452 A1 WO 2023020452A1
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parts
retardant
halogen
flame
free flame
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French (fr)
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汪海
陈平绪
叶南飚
黄险波
杨霄云
胡志华
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金发科技股份有限公司
江苏金发环保科技有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition

Definitions

  • the invention belongs to the technical field of polymer materials, and in particular relates to a halogen-free flame-retardant polypropylene composition and a preparation method and application thereof.
  • Polypropylene (PP) as one of the five general-purpose plastics, has penetrated into industrial, agricultural, transportation, national defense and civilian plastics due to its good processing properties, excellent mechanical properties, high heat resistance and dielectric constant It has become one of the indispensable basic raw materials and important substances for national economic development and scientific and technological progress.
  • PP Polypropylene
  • Conventional flame retardants include halogens, organohalogen and organophosphorus compounds, metal hydroxides, borate additives and montmorillonites.
  • Invention patent CN 106810762B discloses a halogen-free flame-retardant PP composite material, which is compounded with phosphorus-based flame retardants, nitrogen-based flame retardants and inorganic flame retardants.
  • This flame retardant system is a relatively mature one among the current halogen-free flame retardant systems. It has certain applications in the direction of home appliances, but the cost is relatively high, and it is easy to precipitate, so it is not suitable for precision injection molding and parts with complex structures.
  • Invention patent CN 106867111A discloses a halogen-free flame-retardant PP, which is compounded with glass microspheres, magnesium hydroxide and phosphate, and can be added to about 35% to obtain a flame-retardant polypropylene with a flame-retardant grade of 3.2mm V-0, but A large amount of added flame retardants leads to poor toughness of the material and limited application space.
  • the object of the present invention is to provide a halogen-free flame-retardant polypropylene composition, which has high flame-retardant efficiency and good migration resistance, and can not only produce conventional flame-retardant products, but also produce thin-walled Products, expanding the application field of halogen-free flame-retardant PP.
  • a halogen-free flame-retardant polypropylene composition in parts by weight, comprising the following components:
  • Polypropylene 50-65 parts
  • Ammonium polyphosphate flame retardant 18-21 parts;
  • Triazine macromolecular char-forming agent 4-6 parts;
  • Anti-dripping agent 0.2-0.5 parts.
  • the synergist is one or a mixture of wollastonite or diatomite with a mesh number of 800-2500.
  • the polypropylene is a mixture of one or more of homopolypropylene or copolymerized polypropylene, and its notched Izod impact strength (type A) is 2kJ/m 2 - 15kJ/m 2 .
  • the triazine macromolecular char-forming agent of the present invention is a white powder prepared by reacting cyanuric chloride, ethanolamine and ethylenediamine in an aqueous alkaline environment, and can be self-made or purchased from the market.
  • the anti-dripping agent is polytetrafluoroethylene.
  • the halogen-free flame-retardant polypropylene composition of the present invention also includes 0-5 parts of toughening agent, and 0-2 parts of other auxiliary agents; the other auxiliary agents include anti- 0-0.5 parts of oxygen agent; 0-0.5 parts of lubricant; 0-2 parts of color masterbatch.
  • the toughening agent is ethylene octene copolymer POE;
  • the antioxidant is a compound of hindered phenol antioxidant and phosphite antioxidant at 1:1-2;
  • the lubricant is one or a mixture of acetylstearamide, polyethylene wax or oxidized polyethylene wax;
  • the color masterbatch is black masterbatch or other color masterbatch.
  • the present invention also provides a preparation method of the above-mentioned halogen-free flame-retardant polypropylene composition, comprising the following steps:
  • the process of the present invention adopts step-by-step mixing, so that the ammonium polyphosphate flame retardant and the triazine macromolecular char-forming agent can be fully mixed, and the pore structure on the surface of the synergist is prevented from absorbing the flame retardant during the one-step mixing process, resulting in flame retardant Reduced efficiency.
  • the present invention also provides the application of the above-mentioned halogen-free flame-retardant polypropylene composition in circuit boards, seat barrels or lamp sockets of electric vehicles.
  • the present invention has the following beneficial effects:
  • the present invention introduces a synergist and an anti-dripping agent into the existing nitrogen-phosphorus intumescent flame-retardant system, and the prepared halogen-free flame-retardant polypropylene composition has high flame-retardant efficiency and can meet the requirements of 2.0mm and 3.0mm Vertical combustion can even meet the vertical combustion of 1.0mm, not only can produce conventional flame-retardant products, but also can produce thin-walled products (thickness ⁇ 2mm), expanding the application field of halogen-free flame-retardant PP.
  • the halogen-free flame retardant system of the present invention reduces the flame retardant content, improves the easy precipitation performance of the halogen-free flame retardant system, has good precipitation resistance, and can still meet the flame retardant performance requirements after high-temperature water boiling experiments.
  • the preparation method of the present invention is simple, the production process can be carried out in conventional injection molding and extrusion processes, the processing window is wide, and continuous production can be easily realized.
  • Polypropylene 1 PP 425 powder (Tianchang Petrochemical) notched Izod impact strength (Type A) (GB/T 1843-2008) is a homopolymerized PP of 2kJ/ m2 ;
  • Polypropylene 2 PP T03H (Guangzhou Petrochemical) cantilever beam notched impact strength (Type A) (GB/T 1843-2008) is a homopolymer PP of 3kJ/ m2 ;
  • Polypropylene 3 PP EP548R (China Shipping Shell) notched Izod impact strength (Type A) (GB/T 1843-2008) is a copolymerized PP of 7kJ/m 2 ;
  • Polypropylene 4 PP EP300M (China Shipping Shell) notched Izod impact strength (Type A) (GB/T 1843-2008) is a copolymerized PP of 15kJ/m 2 ;
  • Polypropylene 5 PP K9930H (Yanshan Petrochemical) Izod notched impact strength (Type A) (GB/T 1843-2008) is a copolymerized PP of 55kJ/m 2
  • Triazine macromolecular carbon forming agent 1 Shanghai Lidao New Material Technology Co., Ltd. C2019-A;
  • Triazine macromolecular carbon forming agent 2 Guangzhou Yinyuan New Materials Co., Ltd. FR-CFA;
  • Ammonium polyphosphate flame retardant 1 Shouguang Puer Chemical AP730;
  • Ammonium polyphosphate flame retardant 2 Shandong Xianghengyuan Chemical Industry 001;
  • Synergist 1 Lingshou County Jianhui Mine Product Processing Plant, diatomite with a mesh number of 800;
  • Synergist 2 Wollastonite with a mesh number of 1250 mesh in Lingshou County Jianhui Mine Products Processing Plant;
  • Synergist 3 Wollastonite with a mesh number of 2500 mesh in Lingshou County Jianhui Mine Products Processing Plant;
  • Synergist 4 Wollastonite with a mesh number of 5,000 mesh in Lingshou County Jianhui Mine Product Processing Plant;
  • Synergist 5 Wollastonite with a mesh number of 500 in Lingshou County Jianhui Mine Products Processing Plant;
  • Anti-dripping agent polytetrafluoroethylene DF-16, commercially available
  • Toughener 1 Dow POE DF610;
  • Toughener 2 Dow POE ENGAGE 8842;
  • the antioxidant is a compound of hindered phenol antioxidant 1010 and phosphite antioxidant 168 at a ratio of 1:1, which is commercially available;
  • Lubricant polyethylene wax, commercially available
  • Color masterbatch black masterbatch, commercially available.
  • Embodiment 1-6 and comparative example 1-7 are identical to Embodiment 1-6 and comparative example 1-7:
  • Table 1 Composition (parts by weight) of the halogen-free flame-retardant polypropylene compositions of the examples and comparative examples
  • Boil resistance test Put the sample used for vertical combustion performance test in distilled water at 100°C for 168 hours, then dry it in an oven at 100°C for about 2 hours to constant weight, and then carry out the test of flame retardancy after boiling .
  • Test items unit experimental method Vertical Burning Performance level GB/T2408-2008
  • the polypropylene composition prepared by the present invention can meet the vertical combustion of 2.0mm and 3.2mm, and the present invention introduces synergist and anti-dripping After dropping the agent, not only the flame retardant content is reduced (from 32wt% to about 25wt%), especially the amount of char-forming agent is reduced (10wt% to about 6wt%), and the easy precipitation of the halogen-free flame retardant system is significantly improved. It can still meet the requirements of flame retardant performance after high temperature water boiling test.
  • Example 4 It can be seen from Example 4 and Comparative Example 2 that as the notched Izod impact strength of polypropylene increases, the flame retardancy decreases due to the increase in the content of the rubber phase in polypropylene.
  • the mesh number of the synergist has a great influence on the flame retardancy and precipitation resistance of the composition. If the mesh number is too low, the wollastonite particles are too large, which is easy to absorb and block If the mesh number is too high, wollastonite is difficult to disperse and easily agglomerates, reducing the flame retardant performance.
  • the present invention can significantly improve the flame retardancy and easy-to-separate performance of the composition by selecting a synergist with a specific mesh number.
  • Example 2 It can be seen from Example 2 and Comparative Example 6 that the synergist and the anti-dripping agent have a synergistic effect. After adding the anti-dripping agent to the flame retardant system, the flame retardant performance and precipitation resistance of the composition can be further improved performance.
  • Example 2 and Comparative Example 8 it can be seen from Example 2 and Comparative Example 8 that the present invention can obviously improve the flame retardant performance of the composition through step-by-step mixing, compared with one-step mixing.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

本发明公开了一种无卤阻燃聚丙烯组合物及其制备方法和应用，包括组分：聚丙烯：50份-65份；聚磷酸铵阻燃剂：18份-21份；三嗪类大分子成炭剂：4份-6份；协效剂：12份-17份；抗滴落剂：0.2-0.5份。本发明制备得到的无卤阻燃聚丙烯组合物阻燃效率高，可以满足2.0mm和3.0mm的垂直燃烧，甚至可以满足1.0mm的垂直燃烧，不仅可以生产常规阻燃产品，还可以生产薄壁化产品(厚度≤2mm)，且耐析出性能好，经过高温水煮实验以后仍然可以满足阻燃性能要求。

Description

一种无卤阻燃聚丙烯组合物及其制备方法和应用 技术领域
本发明属于高分子材料技术领域，具体涉及一种无卤阻燃聚丙烯组合物及其制备方法和应用。
背景技术
聚丙烯(PP)作为5大通用塑料之一，由于其具有良好的加工性能，优异的机械性能，高耐热性和介电常数，已渗透到工业、农业、运输、国通过防和民用塑料制品中，并已成为国民经济发展和科技进步不可或缺的基本原料和重要物质之一。然而，由于PP产品具有高的氢碳比，在燃烧过程中容易产生液滴，烟雾和有毒气体释放。因此，有必要通过开发新的阻燃材料来挽救生命和保护财产安全并降低火灾风险，但所选择的阻燃剂必须符合各种安全标准，以降低对环境或人类健康的不利影响。常规的阻燃剂包括卤素、有机卤素和有机磷化合物、金属氢氧化物、硼酸盐添加剂及蒙脱石。
近年来，研究较多的阻燃剂是含磷膨胀型阻燃剂。其中，聚磷酸铵(APP)是一种尤为重要的阻燃剂，由于其低毒、低烟、无卤和高磷氮比等优点而受到广泛关注。但是仅单独添加APP在PP中，往往存在着所需APP添加量高、阻燃效果低下等问题，因此亟需找到一种合适的协同阻燃剂以弥补此类缺点。
发明专利CN 106810762B公开了一种无卤阻燃PP复合材料，采用磷系阻燃剂、氮系阻燃剂和无机阻燃剂复配，所述磷系阻燃剂、氮系阻燃剂和无机阻燃剂的重量比为磷系阻燃剂：氮系阻燃剂：无机阻燃剂＝15：30：9。这个阻燃体系为现行无卤阻燃体系中比较成熟的一种，在家电方向有一定的应用，但是成本相对较高，并且容易析出，不适合精密注塑和结构复杂的制件。
发明专利CN 106867111A公开了一种无卤阻燃PP，采用玻璃微珠、氢氧化镁和磷酸盐复配，添加到35％左右能够得到3.2mm V-0阻燃等级的阻燃聚丙烯，但是大量添加的阻燃剂导致材料的韧性较差，应用空间受限。
发明内容
为了解决上述的问题，本发明的目的在于提供一种无卤阻燃聚丙烯组合物，该组合物阻燃效率高，耐迁移性能好，不仅可以生产常规阻燃产品，还可以生产薄壁化产品，拓展了无卤阻燃PP的应用领域。
本发明是通过以下技术方案实现的：
一种无卤阻燃聚丙烯组合物，按重量份数计，包括以下组分：
聚丙烯：50份-65份；
聚磷酸铵阻燃剂：18份-21份；
三嗪类大分子成炭剂：4份-6份；
协效剂：12份-17份；
抗滴落剂：0.2-0.5份。
其中，所述协效剂为目数在800-2500目的硅灰石或硅藻土中的一种或两种的混合。
优选的，所述聚丙烯为均聚聚丙烯或共聚聚丙烯中的一种或几种的混合，其悬臂梁缺口冲击强度(A型)按GB/T 1843-2008标准为2kJ/m 2-15kJ/m 2。
本发明所述的三嗪类大分子成炭剂是在水性的碱性环境中用三聚氯氰、乙醇胺和乙二胺反应制备的白色粉末，可自制，也可通过市购获得。
优选的，所述抗滴落剂为聚四氟乙烯。
为了实际性能需要，本发明所述的无卤阻燃聚丙烯组合物，按重量份计，还包括增韧剂0份-5份，其他助剂0-2份；所述其他助剂包括抗氧剂0份-0.5份；润滑剂0份-0.5份；色母粒0份-2份。
其中，所述增韧剂为乙烯辛烯共聚物POE；
所述的抗氧剂为受阻酚抗氧剂和亚磷酸酯类抗氧剂1:1-2的复配物；
所述的润滑剂为乙酰硬脂酰胺、聚乙烯蜡或氧化聚乙烯蜡的一种或两种的混合物；
所述的色母粒为黑母粒或其他色相的色母粒。
本发明还提供了上述无卤阻燃聚丙烯组合物的制备方法，包括如下步骤：
(1)按比例称取聚磷酸铵阻燃剂和三嗪类大分子成炭剂，混合1-2分钟，转速为500-1000转/分钟；
(2)加入占协效剂总量8-10wt％的部分协效剂，混合1-2分钟，转速为500-1000转/分钟；
(3)加入聚丙烯、剩余协效剂和抗滴落剂混合1-2分钟，转速为500-1000转/分钟，得到预混料；
(4)将预混料经双螺杆挤出机下料口加入，然后经过熔融挤出，螺杆各区温度为150℃-190℃，挤出造粒制得无卤阻燃聚丙烯组合物。
本发明工艺采用分步混合，这样可以使聚磷酸铵阻燃剂和三嗪类大分子成炭剂充分混合，避免在一步混合过程中协效剂表面的孔洞结构吸附阻燃剂，导致阻燃效率降低。
本发明还提供了上述无卤阻燃聚丙烯组合物在电路板、电动车的座桶或灯座中的应用。
与现有技术相比，本发明具有如下有益效果：
(1)本发明在现有的氮磷膨胀阻燃体系中引入协效剂和抗滴落剂，制备得到的无卤阻燃聚丙烯组合物阻燃效率高，可以满足2.0mm和3.0mm的垂直燃烧，甚至可以满足1.0mm的垂直燃烧，不仅可以生产常规阻燃产品，还可以生产薄壁化产品(厚度≤2mm)，拓展了无卤阻燃PP的应用领域。
(2)本发明无卤阻燃体系降低了阻燃剂含量，改善了无卤阻燃体系易析出的性能，耐析出性能好，经过高温水煮实验以后仍然可以满足阻燃性能要求。
(3)本发明制备方法简单，生产过程可以在常规注塑、挤出工艺中进行，加工窗口宽，容易实现连续化生产。
具体实施方式
下面给出实施例以对本发明进行具体的描述，但不限于此。
本发明实施例及对比例所用的原材料均来源于市购，具体做如下说明，但不限于这些材料：
聚丙烯1：PP 425粉(天长石化)悬臂梁缺口冲击强度(A型)(GB/T 1843-2008)为2kJ/m 2的均聚PP；
聚丙烯2：PP T03H(广州石化)悬臂梁缺口冲击强度(A型)(GB/T 1843-2008)为3kJ/m 2的均聚PP；
聚丙烯3：PP EP548R(中海壳牌)悬臂梁缺口冲击强度(A型)(GB/T 1843-2008)为7kJ/m 2的共聚PP；
聚丙烯4：PP EP300M(中海壳牌)悬臂梁缺口冲击强度(A型)(GB/T 1843-2008)为15kJ/m 2的共聚PP；
聚丙烯5：PP K9930H(燕山石化)悬臂梁缺口冲击强度(A型)(GB/T 1843-2008)为55kJ/m 2的共聚PP
三嗪类大分子成炭剂1：上海力道新材料科技股份有限公司C2019-A；
三嗪类大分子成炭剂2：广州市寅源新材料股份有限公司FR-CFA；
聚磷酸铵阻燃剂1：寿光普尔化工AP730；
聚磷酸铵阻燃剂2：山东祥恒源化工001；
协效剂1：灵寿县建辉矿产品加工厂，目数800目的硅藻土；
协效剂2：灵寿县建辉矿产品加工厂，目数1250目的硅灰石；
协效剂3：灵寿县建辉矿产品加工厂，目数2500目的硅灰石；
协效剂4：灵寿县建辉矿产品加工厂，目数5000目的硅灰石；
协效剂5：灵寿县建辉矿产品加工厂，目数500目的硅灰石；
抗滴落剂：聚四氟乙烯DF-16，市售；
增韧剂1：陶氏POE DF610；
增韧剂2：陶氏POE ENGAGE 8842；
抗氧剂：抗氧剂为受阻酚抗氧剂1010和亚磷酸酯类抗氧剂168按1:1的复配物,市售；
润滑剂：聚乙烯蜡，市售；
色母粒：黑母粒，市售。
实施例1-6和对比例1-7：
按表1重量份取聚磷酸铵阻燃剂和三嗪类大分子成炭剂，混合2分钟，转速为1000转/分钟；加入占协效剂总量8wt％的部分协效剂，混合2分钟，转速为800转/分钟；加入聚丙烯、剩余协效剂、抗滴落剂和其他助剂混合2分钟，转速为1000转/分钟，最后加入增韧剂混合1分钟，转速500转/分钟,得到预混料；将预混料经双螺杆挤出机下料口加入，然后经过熔融挤出，螺杆各区温度为150℃-190℃，挤出造粒制得无卤阻燃聚丙烯组合物。
对比例8：
按表1比例，将聚磷酸铵阻燃剂、三嗪类大分子成炭剂、协效剂、聚丙烯、抗滴落剂、增韧剂和其他助剂混合2分钟，转速为1000转/分钟，得到预混料；将预混料经双螺杆挤出机下料口加入，然后经过熔融挤出，螺杆各区温度为150℃-190℃，挤出造粒制得无卤阻燃聚丙烯组合物。
表1：实施例和对比例无卤阻燃聚丙烯组合物组成(重量份)
Figure PCTCN2022112639-appb-000001
续表1：
Figure PCTCN2022112639-appb-000002
将上述实施例1-6和对比例1-8中的样品按照统一工艺注塑成测试样条，按照表2中所列的测试标准和条件对其分别进行垂直燃烧性能测试，测试数据如下表3所示。
耐水煮实验：把用于垂直燃烧性能测试的样条放在100℃蒸馏水中蒸煮168h后，放在100℃的烘箱中烘干2小时左右至恒重，然后进行水煮后的阻燃性能测试。
表2：复合材料的性能测试标准和条件
测试项目 单位 实验方法
垂直燃烧性能 级别 GB/T2408-2008
表3：实施例1-6和对比例1-8中各组合物的性能测试结果
Figure PCTCN2022112639-appb-000003
备注：NG表示不通过，OK表示合格。
从实施例1-6可以看出，本发明制备得到的聚丙烯组合物均可以满足2.0mm和3.2mm的垂直燃烧，本发明在现有氮磷膨胀阻燃体系中引入协效剂和抗滴落剂后，不仅降低了阻燃剂含量(从32wt％降低到25wt％左右)，尤其是降低了成炭剂用量(10wt％降到6wt％左右)，明显改善了无卤阻燃体系易析出的性能，经过高温水煮实验以后仍然可以满足阻燃性能要求。
由实施例4和对比例2可以看出，随着聚丙烯的悬臂梁缺口冲击强度的增大，因聚丙烯中胶相含量增加，阻燃性能有所下降。
从实施例1和对比例3、5可以看出，协效剂的目数对组合物的阻燃性能和耐析出性能影响较大，目数太低，硅灰石颗粒太大，容易吸附阻燃剂，降低阻燃效率；目数太高，硅灰石难以分散，容易团聚，降低阻燃性能。本发明通过选用特定目数的协效剂，可以明显改善 组合物的阻燃性能和易析出性能。
由实施例2和对比例6可以看出，协效剂和抗滴落剂具有协同增效作用，在阻燃体系中加入抗滴落剂后，可以进一步提高组合物的阻燃性能和耐析出性能。
由实施例2和对比例8可以看出，本发明通过分步混合，相较于一步混合，能明显改善组合物的阻燃性能。

Claims (7)

  1. 一种无卤阻燃聚丙烯组合物，其特征在于，按重量份数计，包括以下组分：
    聚丙烯：50份-65份；
    聚磷酸铵阻燃剂：18份-21份；
    三嗪类大分子成炭剂：4份-6份；
    协效剂：12份-17份；
    抗滴落剂：0.2-0.5份；
    其中，所述协效剂为目数在800-2500目的硅灰石或硅藻土中的一种或两种的混合。
  2. 根据权利要求1所述的无卤阻燃聚丙烯组合物，其特征在于，所述聚丙烯为均聚聚丙烯或共聚聚丙烯中的一种或几种的混合，其悬臂梁缺口冲击强度按GB/T 1843-2008标准为2kJ/m 2-15kJ/m 2。
  3. 根据权利要求1所述的无卤阻燃聚丙烯组合物，其特征在于，所述抗滴落剂为聚四氟乙烯。
  4. 根据权利要求1所述的无卤阻燃聚丙烯组合物，其特征在于，按重量份计，还包括增韧剂0份-5份，其他助剂0-2份。
  5. 根据权利要求4所述的无卤阻燃聚丙烯组合物，其特征在于，所述其他助剂包括抗氧剂0份-0.5份；润滑剂0份-0.5份；色母粒0份-2份。
  6. 根据权利要求1-5任一项所述的无卤阻燃聚丙烯组合物的制备方法，其特征在于，包括如下步骤：
    (1)按比例称取聚磷酸铵阻燃剂和三嗪类大分子成炭剂，混合1-2分钟，转速为500-1000转/分钟；
    (2)加入占协效剂总量8-10wt％的部分协效剂，混合1-2分钟，转速为500-1000转/分钟；
    (3)加入聚丙烯、剩余协效剂和抗滴落剂混合1-2分钟，转速为500-1000转/分钟，得到预混料；
    (4)将预混料经双螺杆挤出机下料口加入，然后经过熔融挤出，螺杆各区温度为150℃-190℃，挤出造粒制得无卤阻燃聚丙烯组合物。
  7. 根据权利要求1-5任一项所述的无卤阻燃聚丙烯组合物在电路板、电动车的座桶或灯座中的应用。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116640387A (zh) * 2023-06-20 2023-08-25 铨盛聚碳科技股份有限公司 一种新能源电池薄膜的pp无卤阻燃母粒及其制备方法
CN117624789A (zh) * 2023-12-01 2024-03-01 杭州佳磊环保科技有限公司 一种改性聚丙烯复合管材及其制备工艺

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113817263A (zh) * 2021-08-17 2021-12-21 金发科技股份有限公司 一种无卤阻燃聚丙烯组合物及其制备方法和应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5722412B1 (ja) * 2013-11-15 2015-05-20 出光ライオンコンポジット株式会社 ポリプロピレン樹脂組成物、成形体および積層構造体
WO2017096519A1 (zh) * 2015-12-08 2017-06-15 东北林业大学 三嗪系高效膨胀阻燃剂及膨胀阻燃聚丙烯
CN108117694A (zh) * 2017-12-28 2018-06-05 广东聚石化学股份有限公司 一种耐寒、刚韧平衡的无卤阻燃聚丙烯复合材料及其制备方法
CN108250573A (zh) * 2017-12-28 2018-07-06 清远市普塞呋磷化学有限公司 一种耐热氧老化的无卤环保阻燃聚丙烯材料及其制备方法
CN108822400A (zh) * 2018-06-02 2018-11-16 山东兄弟科技股份有限公司 一种聚丙烯专用耐析出无卤阻燃剂的制备方法
CN113817263A (zh) * 2021-08-17 2021-12-21 金发科技股份有限公司 一种无卤阻燃聚丙烯组合物及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134352B (zh) * 2011-05-09 2013-06-12 中山大学 一种膨胀型阻燃聚丙烯复合材料及其制备方法
CN102585375B (zh) * 2012-03-14 2014-04-30 济南泰星精细化工有限公司 一种聚丙烯专用无卤环保阻燃剂
CN105419087A (zh) * 2015-11-27 2016-03-23 康平县塑编产业集群综合服务中心 一种新型阻燃环保的塑料编织袋及其生产工艺
CN108203527A (zh) * 2016-12-20 2018-06-26 上海杰事杰新材料(集团)股份有限公司 一种高极限氧指数无卤阻燃pp材料及其制备方法
CN106905609A (zh) * 2017-03-09 2017-06-30 江苏启蓝新材料有限公司 含三嗪系膨胀阻燃剂的无卤阻燃聚丙烯组合物及其制备
CN107434878B (zh) * 2017-08-17 2020-07-24 会通新材料股份有限公司 一种高灼热丝、耐水煮阻燃聚丙烯复合材料及制备方法
CN109082010A (zh) * 2018-07-23 2018-12-25 武汉理工大学 一种无卤膨胀阻燃碳纤维增强聚丙烯树脂复合材料及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5722412B1 (ja) * 2013-11-15 2015-05-20 出光ライオンコンポジット株式会社 ポリプロピレン樹脂組成物、成形体および積層構造体
WO2017096519A1 (zh) * 2015-12-08 2017-06-15 东北林业大学 三嗪系高效膨胀阻燃剂及膨胀阻燃聚丙烯
CN108117694A (zh) * 2017-12-28 2018-06-05 广东聚石化学股份有限公司 一种耐寒、刚韧平衡的无卤阻燃聚丙烯复合材料及其制备方法
CN108250573A (zh) * 2017-12-28 2018-07-06 清远市普塞呋磷化学有限公司 一种耐热氧老化的无卤环保阻燃聚丙烯材料及其制备方法
CN108822400A (zh) * 2018-06-02 2018-11-16 山东兄弟科技股份有限公司 一种聚丙烯专用耐析出无卤阻燃剂的制备方法
CN113817263A (zh) * 2021-08-17 2021-12-21 金发科技股份有限公司 一种无卤阻燃聚丙烯组合物及其制备方法和应用

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHEN YELONG, MENG CHENG-MING; SUN KAI: "Preparation of Halogen-free Flame Ｒetardant and Ｒeinforced Polypropylene ", CHINA PLASTICS INDUSTRY, vol. 42, no. 6, 20 June 2014 (2014-06-20), pages 42 - 45, XP093036352, ISSN: 1005-5770, DOI: 10.3969/j.issn.1005-5770.2014.06.011 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116640387A (zh) * 2023-06-20 2023-08-25 铨盛聚碳科技股份有限公司 一种新能源电池薄膜的pp无卤阻燃母粒及其制备方法
CN116640387B (zh) * 2023-06-20 2024-03-22 铨盛聚碳科技股份有限公司 一种新能源电池薄膜的pp无卤阻燃母粒及其制备方法
CN117624789A (zh) * 2023-12-01 2024-03-01 杭州佳磊环保科技有限公司 一种改性聚丙烯复合管材及其制备工艺
CN117624789B (zh) * 2023-12-01 2024-04-16 杭州佳磊环保科技有限公司 一种改性聚丙烯复合管材及其制备工艺

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