WO2022251121A1 - Aerosol generating composition comprising nicotine and acid or nicotine salt - Google Patents

Aerosol generating composition comprising nicotine and acid or nicotine salt Download PDF

Info

Publication number
WO2022251121A1
WO2022251121A1 PCT/US2022/030560 US2022030560W WO2022251121A1 WO 2022251121 A1 WO2022251121 A1 WO 2022251121A1 US 2022030560 W US2022030560 W US 2022030560W WO 2022251121 A1 WO2022251121 A1 WO 2022251121A1
Authority
WO
WIPO (PCT)
Prior art keywords
aerosol
generating
generating material
generating composition
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2022/030560
Other languages
English (en)
French (fr)
Inventor
John Ulrich
Jennifer Rowe
Michael F. Davis
JR. John Will CARAWAY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RAI Strategic Holdings Inc
Original Assignee
RAI Strategic Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RAI Strategic Holdings Inc filed Critical RAI Strategic Holdings Inc
Priority to JP2023573213A priority Critical patent/JP2024519173A/ja
Priority to EP22731405.1A priority patent/EP4346456A1/en
Priority to US18/564,401 priority patent/US20240245093A1/en
Priority to CN202280052775.6A priority patent/CN118159148A/zh
Priority to MX2023014157A priority patent/MX2023014157A/es
Priority to AU2022279989A priority patent/AU2022279989A1/en
Priority to KR1020237040822A priority patent/KR20240026904A/ko
Priority to BR112023024834A priority patent/BR112023024834A2/pt
Priority to IL308843A priority patent/IL308843A/en
Priority to CA3220348A priority patent/CA3220348A1/en
Publication of WO2022251121A1 publication Critical patent/WO2022251121A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/167—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
    • A24B15/241—Extraction of specific substances
    • A24B15/243—Nicotine
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/301—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/36—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring
    • A24B15/40—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms
    • A24B15/403—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms having only oxygen as hetero atoms
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/42—Treatment of tobacco products or tobacco substitutes by chemical substances by organic and inorganic substances
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/20—Cigarettes specially adapted for simulated smoking devices
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/20—Devices using solid inhalable precursors
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40—Constructional details, e.g. connection of cartridges and battery parts

Definitions

  • the aerosol-generating material and/or the aerosol-generating composition consists essentially of, or consists of, gelling agent; solvent; aerosol- former material; nicotine and acid. In some embodiments, the aerosol-generating material and/or the aerosol generating composition consists essentially of, or consists of, gelling agent; solvent; aerosol-former material; nicotine salt; and optionally a flavour and/or optionally an additional active substance and/or optionally filler.
  • the aerosol-generating material comprises about 15 wt% to about 80 wt% gelling agent, for example from about 20 wt%, 25 wt%, 30 wt%, 40 wt% or 45 wt% to about 65 wt%, 70 wt% or 75 wt% (all calculated on a dry weight basis).
  • the polysaccharide gelling agent is selected from alginate, pectin, starch or a derivative thereof, cellulose or a derivative thereof, and combinations thereof.
  • the polysaccharide gelling agent is selected from alginate, a cellulose derivative and combinations thereof.
  • the aerosol-generating material comprises nicotine and an acid.
  • the molar ratio of nicotine to acid is 2.2:1 or less, 1.5:1 or less or 1:1 or less.
  • the molar ratio of acid to nicotine is from 0.5:1 to 2.2:1, 0.7:1 to 2:1 or 0.7:1 to 1.5:1.
  • the aerosol-generating material may further comprise a filler.
  • a filler may help to reduce tackiness of the aerosol-generating material, for example if high levels of aerosol-former material are present.
  • the filler is fibrous.
  • the filler may be a fibrous organic filler material such as wood pulp, hemp fibre, cellulose or cellulose derivatives.
  • the filler comprises wood pulp.
  • fibrous filler in an aerosol-generating material may increase the tensile strength of the material. This may be particularly advantageous in examples wherein the aerosol-generating material is provided as a sheet, such as when an aerosol generating material sheet circumscribes a rod of aerosol-generating composition.
  • Such tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating material and/or the aerosol-generating composition is formed as a sheet and then shredded and incorporated into a consumable.
  • the aerosol-generating material may have a tensile strength of from around 600 N/m to around 900 N/m, or from around 700 N/m to around 900 N/m, or around 800 N/m.
  • Such tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating material and/or the aerosol-generating composition is included in a consumable/non-combustible aerosol provision system as a rolled sheet, suitably in the form of a tube.
  • the aerosol-generating material for use in aerosol generation may be present on or in a support, to form a substrate.
  • the support may, for example, be or comprise paper, card, paperboard, cardboard, reconstituted material, a plastics material, a ceramic material, a composite material, glass, a metal, or a metal alloy.
  • the support comprises (or is) a susceptor.
  • the susceptor is an aluminium sheet.
  • the susceptor is embedded within the material.
  • the susceptor is on one or either side of the material.
  • a non-combustible aerosol provision system comprising the consumable described herein and a non combustible aerosol provision device.
  • FIG. 1 and 2 there are shown a partially cut-away section view and a perspective view of an example of article consumable 101 (“article”).
  • the article 101 is adapted for use with a device having a power source and a heater.
  • the article 101 of this embodiment is particularly suitable for use with the device 1 shown in Figures 5 to 7, described below.
  • the article 101 may be removably inserted into the device shown in Figure 5 at an insertion point 20 of the device 1.
  • the article 101 of one example is in the form of a substantially cylindrical rod that includes a body of aerosol-generating composition 103 and a filter assembly 105 in the form of a rod.
  • the aerosol-generating material comprises the aerosol-generating material described herein. In some embodiments, it may be included in sheet form.
  • the filter segment 109 is between 6mm to 10mm in length, suitably 8mm.
  • a ventilation region 317 is provided in the article 301 to enable air to flow into the interior of the article 301 from the exterior of the article 301.
  • the ventilation region 317 takes the form of one or more ventilation holes 317 formed through the outer layer of the article 301.
  • the ventilation holes may be located in the cooling segment 307 to aid with the cooling of the article 301.
  • the ventilation region 317 comprises one or more rows of holes, and preferably, each row of holes is arranged circumferentially around the article 301 in a cross-section that is substantially perpendicular to a longitudinal axis of the article 301.
  • FIG. 5 to 7 there is shown an example of a device 1 arranged to heat aerosol-generating composition to volatilise at least one component of said aerosol-generating material, typically to form an aerosol which can be inhaled.
  • the device 1 is a heating device which releases compounds by heating, but not burning, the aerosol-generating material.
  • Embodiment 1 or the slurry of Embodiment 1A, comprising about 1-15 wt% nicotine.
  • the acid comprises at least one of succinic acid, lactic acid, benzoic acid, citric acid, tartartic acid, fumaric acid, levulinic acid, acetic acid, malic acid, formic acid, sorbic acid, benzoic acid, propanoic acid and pyruvic acid.
  • the aerosol-generating material or slurry of Embodiment 47 comprising about 30-55 wt% aerosol-former material.
  • Embodiment 72 The aerosol-generating material or slurry of Embodiment 71, wherein the polysaccharide gelling agent is a cellulose derivative.
  • Embodiment 106 The aerosol-generating composition of Embodiment 105, comprising from about 50-90 wt% (WWB) of the aerosol-generating material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Medicinal Preparation (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
PCT/US2022/030560 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt Ceased WO2022251121A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP2023573213A JP2024519173A (ja) 2021-05-27 2022-05-23 ニコチン及び酸、又はニコチン塩を含むエアロゾル生成組成物
EP22731405.1A EP4346456A1 (en) 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt
US18/564,401 US20240245093A1 (en) 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt
CN202280052775.6A CN118159148A (zh) 2021-05-27 2022-05-23 包含尼古丁和酸或尼古丁盐的气溶胶生成组合物
MX2023014157A MX2023014157A (es) 2021-05-27 2022-05-23 Composicion generadora de aerosoles.
AU2022279989A AU2022279989A1 (en) 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt
KR1020237040822A KR20240026904A (ko) 2021-05-27 2022-05-23 니코틴 및 산 또는 니코틴 염을 포함하는 에어로졸 생성 조성물
BR112023024834A BR112023024834A2 (pt) 2021-05-27 2022-05-23 Composição geradora de aerossol e seu uso, consumível, sistema de fornecimento de aerossol não combustível, pasta, método para produzir uma composição geradora de aerossol, método para gerar um aerossol
IL308843A IL308843A (en) 2021-05-27 2022-05-23 A spray for producing an aerosol that includes nicotine and nicotine acid or salt
CA3220348A CA3220348A1 (en) 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202163193877P 2021-05-27 2021-05-27
US63/193,877 2021-05-27

Publications (1)

Publication Number Publication Date
WO2022251121A1 true WO2022251121A1 (en) 2022-12-01

Family

ID=82100539

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2022/030560 Ceased WO2022251121A1 (en) 2021-05-27 2022-05-23 Aerosol generating composition comprising nicotine and acid or nicotine salt

Country Status (11)

Country Link
US (1) US20240245093A1 (https=)
EP (1) EP4346456A1 (https=)
JP (1) JP2024519173A (https=)
KR (1) KR20240026904A (https=)
CN (1) CN118159148A (https=)
AU (1) AU2022279989A1 (https=)
BR (1) BR112023024834A2 (https=)
CA (1) CA3220348A1 (https=)
IL (1) IL308843A (https=)
MX (1) MX2023014157A (https=)
WO (1) WO2022251121A1 (https=)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115813011A (zh) * 2022-12-30 2023-03-21 东莞市吉纯生物技术有限公司 一种具有茶氨酸的雾化液的制备方法与应用
CN116268541A (zh) * 2022-12-30 2023-06-23 安徽中烟工业有限责任公司 一种用于加热卷烟的混合烟碱盐及其制备方法
WO2024241058A1 (en) * 2023-05-23 2024-11-28 Nicoventures Trading Limited Aerosol-generating composition
WO2025086962A1 (zh) * 2023-10-27 2025-05-01 湖南中烟工业有限责任公司 烟碱逐口释放均匀性的新型烟草制品及其烟碱调节剂、稠浆、薄片的制备方法
WO2025141040A1 (en) * 2023-12-28 2025-07-03 Philip Morris Products S.A. Aerosol-generating article comprising a substrate with homogenised plant material
FR3159395A1 (fr) * 2024-02-19 2025-08-22 Swm Holdco Luxembourg Feuille de papier comprenant de la nicotine stabilisée
FR3159394A1 (fr) * 2024-02-19 2025-08-22 Swm Holdco Luxembourg Feuille de papier comprenant un extrait de plante et de la nicotine stabilisée

Families Citing this family (6)

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GB202301384D0 (en) * 2023-01-31 2023-03-15 Nicoventures Trading Ltd An aerosol generating material
GB202301396D0 (en) * 2023-01-31 2023-03-15 Nicoventures Trading Ltd An aerosol generating material
GB202301392D0 (en) * 2023-01-31 2023-03-15 Nicoventures Trading Ltd An aerosol generating material
TW202539533A (zh) * 2023-01-31 2025-10-16 英商尼可創業貿易有限公司 氣溶膠產生材料
GB202301400D0 (en) * 2023-01-31 2023-03-15 Nicoventures Trading Ltd An aerosol generating material
CN121419686A (zh) * 2024-04-30 2026-01-27 韩国烟草人参公社 气溶胶生成物品用薄片及包括其的气溶胶生成物品

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WO2015062983A2 (en) 2013-10-29 2015-05-07 British American Tobacco (Investments) Limited Apparatus for heating smokable material
WO2016135331A1 (en) 2015-02-27 2016-09-01 British American Tobacco (Investments) Limited Cartridge, components and methods for generating an inhalable medium
AU2016358470A1 (en) * 2015-11-24 2018-07-12 R. J. Reynolds Tobacco Company Electrically-powered aerosol delivery system
CN111072629A (zh) * 2019-11-22 2020-04-28 云南中烟工业有限责任公司 一种尼古丁-草酸盐复合物晶体及其应用
WO2020089095A1 (en) * 2018-10-29 2020-05-07 Nerudia Limited Smoking substitute consumable
WO2020207736A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Method of manufacturing an aerosol-generating film
WO2020207732A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating article comprising an aerosol-generating film
WO2020207734A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating system and aerosol-generating article comprising an aerosol-generating film
WO2020207733A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating substrate comprising an aerosol-generating film

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GB201508671D0 (en) * 2015-05-20 2015-07-01 British American Tobacco Co Aerosol generating material and devices including the same
JP7295860B2 (ja) * 2017-12-21 2023-06-21 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 加熱式エアロゾル発生物品内のエアロゾルアンモニアの減少法
GB201812500D0 (en) * 2018-07-31 2018-09-12 Nicoventures Holdings Ltd Aerosol generation
GB201812503D0 (en) * 2018-07-31 2018-09-12 Nicoventures Holdings Ltd Aerosol generation
AU2020392616A1 (en) * 2019-11-29 2022-06-16 Nicoventures Trading Limited Consumable comprising two different aerosol-generating materials for non-combustible aerosol provision device

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Publication number Priority date Publication date Assignee Title
WO2015062983A2 (en) 2013-10-29 2015-05-07 British American Tobacco (Investments) Limited Apparatus for heating smokable material
WO2016135331A1 (en) 2015-02-27 2016-09-01 British American Tobacco (Investments) Limited Cartridge, components and methods for generating an inhalable medium
AU2016358470A1 (en) * 2015-11-24 2018-07-12 R. J. Reynolds Tobacco Company Electrically-powered aerosol delivery system
WO2020089095A1 (en) * 2018-10-29 2020-05-07 Nerudia Limited Smoking substitute consumable
WO2020207736A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Method of manufacturing an aerosol-generating film
WO2020207732A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating article comprising an aerosol-generating film
WO2020207734A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating system and aerosol-generating article comprising an aerosol-generating film
WO2020207733A1 (en) * 2019-04-08 2020-10-15 Philip Morris Products S.A. Aerosol-generating substrate comprising an aerosol-generating film
CN111072629A (zh) * 2019-11-22 2020-04-28 云南中烟工业有限责任公司 一种尼古丁-草酸盐复合物晶体及其应用

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115813011A (zh) * 2022-12-30 2023-03-21 东莞市吉纯生物技术有限公司 一种具有茶氨酸的雾化液的制备方法与应用
CN116268541A (zh) * 2022-12-30 2023-06-23 安徽中烟工业有限责任公司 一种用于加热卷烟的混合烟碱盐及其制备方法
WO2024241058A1 (en) * 2023-05-23 2024-11-28 Nicoventures Trading Limited Aerosol-generating composition
WO2025086962A1 (zh) * 2023-10-27 2025-05-01 湖南中烟工业有限责任公司 烟碱逐口释放均匀性的新型烟草制品及其烟碱调节剂、稠浆、薄片的制备方法
WO2025141040A1 (en) * 2023-12-28 2025-07-03 Philip Morris Products S.A. Aerosol-generating article comprising a substrate with homogenised plant material
FR3159395A1 (fr) * 2024-02-19 2025-08-22 Swm Holdco Luxembourg Feuille de papier comprenant de la nicotine stabilisée
FR3159394A1 (fr) * 2024-02-19 2025-08-22 Swm Holdco Luxembourg Feuille de papier comprenant un extrait de plante et de la nicotine stabilisée
WO2025176686A1 (en) * 2024-02-19 2025-08-28 Swm Holdco Luxembourg Paper sheet comprising stabilized nicotine
WO2025176685A1 (en) * 2024-02-19 2025-08-28 Swm Holdco Luxembourg Paper sheet comprising a plant extract and stabilized nicotine

Also Published As

Publication number Publication date
JP2024519173A (ja) 2024-05-08
BR112023024834A2 (pt) 2024-02-20
CN118159148A (zh) 2024-06-07
CA3220348A1 (en) 2022-12-01
KR20240026904A (ko) 2024-02-29
IL308843A (en) 2024-01-01
US20240245093A1 (en) 2024-07-25
MX2023014157A (es) 2024-03-25
AU2022279989A1 (en) 2023-12-14
EP4346456A1 (en) 2024-04-10

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