WO2020089095A1

WO2020089095A1 - Smoking substitute consumable

Info

Publication number: WO2020089095A1
Application number: PCT/EP2019/079227
Authority: WO
Inventors: Kate FERRIE; Edward Ross SHENTON; Samantha MURRAY; Jill JONES; John Williams; David Jones; Chris Lord
Original assignee: Nerudia Limited
Priority date: 2018-10-29
Filing date: 2019-10-25
Publication date: 2020-05-07

Abstract

The present disclosure relates to a HNB consumable comprising an aerosol-forming substrate (e.g. tobacco) dosed with nicotine and/or a nicotine salt. The present disclosure also relates to an aerosol- forming article comprising an aerosol-forming substrate and a cooling element, the cooing element being adapted to increase the concentration of a volatile compound within a vapour generated by heating of the aerosol-forming substrate. For example, the aerosol-cooling element may comprise at least one volatile compound additive such as nicotine and/or a nicotine salt.

Description

Smoking substitute consumable

The present application claims priority from United Kingdom patent application numbers GB1817550.5 and GB1817546.3 filed on 29 October 2018, the entire contents of which are incorporated herein.

Field of the Disclosure

The present disclosure relates to a consumable for use in a smoking substitute system and particularly, although not exclusively, to a heat-not-burn (HNB) consumable.

Background

During the manufacturing process for tobacco products, such as cigarettes, tobacco waste is produced. The tobacco waste is typically in the form of tobacco dust, leaf or stem. The tobacco waste can be collected and processed to provide what is known as reconstituted tobacco, or“recon”.

Two distinct methods are most commonly employed to manufacture reconstituted tobacco, these are i) a paper-making process (i.e. to provide“Paper Recon”), and ii) slurry casting (to provide“Slurry-type Recon”). The products that result from these distinct processes have notably different properties and characteristics. For example, slurry-type recon generally has improved aroma/flavour and nicotine content in comparison to paper recon, yet slurry-type recon is typically more easily broken and often has poorer uniformity of quality.

In slurry casting the tobacco waste is milled to a fine powder and mixed with an aqueous solvent, typically water, and combined with a binding agent. The resultant slurry may undergo further milling to reduce the particle size of the tobacco material further. The slurry is then cast on a surface and dried to form a sheet. The dried sheet may be shredded to be used within various tobacco products, for example as a cigarette filler.

In the paper-making process the tobacco waste is mechanically beaten in the presence of an aqueous solvent to digest and process the tobacco into workable fibres. Subsequently, water soluble compounds present in the tobacco are extracted into the aqueous solvent. The aqueous extract and insoluble fibrous portion are separated. The separated fibrous portion, which may also be described as a“pulp”, undergoes further processing to form a base sheet via a typical paper-making procedure. The aqueous extract is concentrated and then reapplied to the base sheet. The base sheet is then dried to form a paper.

The smoking of tobacco is generally considered to expose a smoker to potentially harmful substances. It is generally thought that a significant amount of the potentially harmful substances are generated through the heat caused by the burning and/or combustion of the tobacco and the constituents of the burnt tobacco in the tobacco smoke itself.

Conventional combustible smoking articles, such as cigarettes, typically comprise a cylindrical rod of tobacco comprising shreds of tobacco which is surrounded by a wrapper, and usually also a cylindrical filter axially aligned in an abutting relationship with the wrapped tobacco rod. The filter typically comprises a filtration material which is circumscribed by a plug wrap. The wrapped tobacco rod and the filter are joined together by a wrapped band of tipping paper that circumscribes the entire length of the filter and an adjacent portion of the wrapped tobacco rod. A conventional cigarette of this type is used by lighting the end opposite to the filter, and burning the tobacco rod. The smoker receives mainstream smoke into their mouth by drawing on the mouth end or filter end of the cigarette.

Combustion of organic material such as tobacco is known to produce tar and other potentially harmful byproducts. There have been proposed various smoking substitute systems (or“substitute smoking systems”) in order to avoid the smoking of tobacco.

Such smoking substitute systems can form part of nicotine replacement therapies aimed at people who wish to stop smoking and overcome a dependence on nicotine.

Smoking substitute systems include electronic systems that permit a user to simulate the act of smoking by producing an aerosol (also referred to as a“vapour”) that is drawn into the lungs through the mouth (inhaled) and then exhaled. The inhaled aerosol typically bears nicotine and/or flavourings without, or with fewer of, the odour and health risks associated with traditional smoking.

In general, smoking substitute systems are intended to provide a substitute for the rituals of smoking, whilst providing the user with a similar experience and satisfaction to those experienced with traditional smoking and with combustible tobacco products. Some smoking substitute systems use smoking substitute articles that are designed to resemble a traditional cigarette and are cylindrical in form with a mouthpiece at one end.

The popularity and use of smoking substitute systems has grown rapidly in the past few years. Although originally marketed as an aid to assist habitual smokers wishing to quit tobacco smoking, consumers are increasingly viewing smoking substitute systems as desirable lifestyle accessories.

There are a number of different categories of smoking substitute systems, each utilising a different smoking substitute approach.

One approach for a smoking substitute system is the so-called "heat not burn" (“HNB”) approach in which tobacco (rather than an“e-liquid”) is heated or warmed to release vapour. The tobacco may be leaf tobacco or reconstituted tobacco. The vapour may contain nicotine and/or flavourings. In the HNB approach the intention is that the tobacco is heated but not burned, i.e. the tobacco does not undergo combustion.

A typical HNB smoking substitute system may include a device and a consumable. The consumable may include the tobacco material. The device and consumable may be configured to be physically coupled together. In use, heat may be imparted to the tobacco material by a heating element of the device, wherein airflow through the tobacco material causes moisture in the tobacco material to be released as vapour. A vapour may also be formed from a carrier in the tobacco material (this carrier may for example include propylene glycol and/or vegetable glycerine) and additionally volatile compounds released from the tobacco. The released vapour may be entrained in the airflow drawn through the tobacco.

As the vapour passes through the consumable (entrained in the airflow) from an inlet to a mouthpiece (outlet), the vapour cools and condenses to form an aerosol for inhalation by the user. The aerosol will normally contain the volatile compounds.

In HNB smoking substitute systems, heating as opposed to burning the tobacco material is believed to cause fewer, or smaller quantities, of the more harmful compounds ordinarily produced during smoking. Consequently, the HNB approach may reduce the odour and/or health risks that can arise through the burning, combustion and pyrolytic degradation of tobacco.

There is a need for improved design of HNB consumables to enhance the user experience and improve the function of the HNB smoking substitute system.

The present disclosure has been devised in the light of the above considerations.

Summary of the Disclosure

At its most general, the present disclosure relates to i) an aerosol-forming article e.g. an HNB consumable having an increased concentration of nicotine, and ii) an aerosol-forming article e.g. a smoking substitute article such as an HNB consumable having a cooling element that acts to increase the volatile compound concentration of the vapour.

According to a first aspect, the present invention provides an aerosol-forming article (e.g. an HNB consumable) comprising an aerosol-forming substrate dosed with nicotine and/or a nicotine salt, wherein the aerosol-forming substrate is a slurry-type reconstituted plant material.

Reference to“slurry-type” corresponds to a reconstituted plant material made by slurry-casting as opposed to a paper-making process. By using an aerosol-forming substrate (which will itself include a volatile compound) dosed with nicotine and/or a nicotine salt, the number/concentration of volatile compound(s) can be increased to provide the user with a vapour/aerosol containing a higher concentration of the volatile compound(s). This may provide the user with an enhanced recreational and/or medicinal effect when inhaled. In particular, the amount of nicotine in the consumable is increased. This improves the“nicotine” hit experienced by the user.

Preferably, the aerosol-forming substrate is dosed with a nicotine salt. Advantageously, nicotine salts exhibit lower volatility and higher stability than nicotine, therefore provide a safer and more convenient means of handling during processing.

According to a second aspect, there is provided an aerosol-forming article (e.g. a smoking substitute article such as an HNB consumable) comprising an aerosol-forming substrate and a cooling element wherein the cooing element is adapted to increase the concentration of a volatile compound within a vapour generated by heating of the aerosol-forming substrate.

By providing a cooling element that not only cools a vapour generated by heating of the aerosol-forming substrate, also increases the concentration of a volatile compound within the vapour, the recreational and/or medicinal effect achieved by the user upon inhalation of the vapour is enhanced.

The term“nicotine salt” is used to define an ionic compound formed by the reaction between nicotine and a proton donor e.g. by the reaction between nicotine and an acid. Accordingly, the nicotine salt may be an acid salt.

Optional features will now be set out. These are applicable singly or in any combination with any aspect. The aerosol-forming article is preferably a heat-not-burn (HNB) consumable.

The aerosol-forming substrate is capable of being heated to release at least one volatile compound that can form an aerosol. The aerosol-forming substrate may be located at the upstream end of the article/consumable.

In some embodiments, in order for the aerosol-cooling element to increase the concentration of the volatile compound in the vapour, the aerosol-cooling element comprises at least one volatile compound additive. The at least one volatile compound additive is intended to be vaporised/aerosolised as vapour from the aerosol-forming substrate passes through the cooling element. Suitable chemical and/or physiologically active volatile compound additives include the group consisting of: nicotine, cocaine, caffeine, opiates and opoids, cathine and cathinone, kavalactones, mysticin, beta-carboline alkaloids, salvinorin A together with any combinations, functional equivalents to, and/or synthetic alternatives of the foregoing. The at least one volatile compound additive may comprise nicotine and/or nicotine salts.

The aerosol-cooling element is downstream from the aerosol-forming substrate. For example, it may be between the aerosol-forming substrate and a/the filter element and/or between two filter elements. The aerosol cooling element may be at least partly (e.g. completely) circumscribed by the (paper) wrapping layer.

As used herein, the terms’’upstream” and“downstream” are intended to refer to the flow direction of the vapour/aerosol i.e. with the downstream end of the article/consumable being the mouth end or outlet where the aerosol exits the article/consumable for inhalation by the user. The upstream end of the article/consumable is the opposing end to the downstream end.

The aerosol-cooling element may be formed of a plastics material selected from the group consisting of polylactic acid (PLA), polyvinyl chloride (PVC), polyethylene (PE) and polyethylene terephthalate (PET). The aerosol-cooling element may be formed of a crimped/gathered sheet of material (e.g. plastic material) to form a structure having a high surface area with a plurality of longitudinal channels to maximise heat exchange and cooling of the aerosol.

The sheet of material may be sprayed with a solution of the volatile compound additive prior to crimping/gathering. Alternatively, the cooling element may be soaked in or impregnated with a solution of the volatile compound additive.

The aerosol-forming substrate may be located at the upstream end of the article/consumable.

The aerosol-forming substrate is capable of being heated to release at least one volatile compound that can form an aerosol. The volatile compound may be the same as or different to the volatile compound additive in the cooling element.

In order to generate an aerosol, the aerosol-forming substrate comprises at least one volatile compound that is intended to be vaporised/aerosolised and that may provide the user with a recreational and/or medicinal effect when inhaled. Suitable chemical and/or physiologically active volatile compounds include the group consisting of: nicotine, cocaine, caffeine, opiates and opoids, cathine and cathinone, kavalactones, mysticin, beta-carboline alkaloids, salvinorin A, together with any combinations, functional equivalents to, and/or synthetic alternatives of the foregoing.

Preferably, the nicotine salt is selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nicotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate, nicotine lactate and nicotine salicylate, and combinations thereof. The aerosol-forming substrate comprises plant material. The plant material may comprise at least one plant material selected from the list including Amaranthus dubius, Arctostaphylos uva-ursi (Bearberry), Argemone mexicana, Arnica, Artemisia vulgaris, Yellow Tees, Galea zacatechichi, Canavalia maritima (Baybean), , Cecropia mexicana (Guamura), Oestrum noctumum, Cynoglossum virginianum (wild comfrey), Cytisus scoparius, Damiana, Entada rheedii, Eschscholzia califomica (California Poppy), Fittonia albivenis, Hippobroma longi flora, Humulus japonica (Japanese Hops), Humulus lupulus (Hops), Lactuca virosa (Lettuce Opium), Laggera alata, Leonotis leonurus, Leonurus cardiaca (Motherwort), Leonurus sibiricus (Honeyweed), Lobelia cardinalis, Lobelia inflata (Indian-tobacco), Lobelia siphilitica, Nepeta cataria (Catnip), Nicotiana species (Tobacco), Nymphaea alba (White Lily), Nymphaea caerulea (Blue Lily), Opium poppy, Passiflora incamata (Passionflower), Pedicularis densiflora (Indian Warrior), Pedicularis groenlandica (Elephant's Head), Salvia divi norum, Salvia dorrii (Tobacco Sage), Salvia species (Sage), Scutellaria galericulata, Scutellaria lateriflora, Scutellaria nana, Scutellaria species (Skullcap), Sida acuta (Wireweed), Sida rhombi folia, Silene capensis, Syzygium aromaticum (Clove), Tagetes lucida (Mexican Tarragon), Tarchonanthus camphoratus, Tumera diffusa (Damiana), Verbascum (Mullein), Zamia latifolia (Maconha Brava) together with any combinations, functional equivalents to, and/or synthetic alternatives of the foregoing.

Preferably, the plant material is tobacco. Any type of tobacco may be used. This includes, but is not limited to, flue-cured tobacco, burley tobacco, Maryland Tobacco, dark-air cured tobacco, oriental tobacco, dark-fired tobacco, perique tobacco and rustica tobacco. This also includes blends of the above mentioned tobaccos.

Any suitable parts of the tobacco plant may be used. This includes leaves, stems, roots, bark, seeds and flowers.

The tobacco may comprise one or more of leaf tobacco, stem tobacco, tobacco powder, tobacco dust, tobacco derivatives, expanded tobacco, homogenised tobacco, shredded tobacco, extruded tobacco, cut rag tobacco and/or reconstituted tobacco (e.g. slurry recon or paper recon).

The aerosol-forming substrate may comprise a gathered sheet of homogenised slurry recon tobacco or gathered shreds/strips formed from such a sheet.

In some embodiments, the sheet used to form the aerosol-forming substrate has a grammage greater than or equal to 100 g/m², e.g. greater than or equal to 1 10 g/m² such as greater than or equal to 120 g/m².

The sheet may have a grammage of less than or equal to 300 g/m² e.g. less than or equal to 250 g/m² or less than or equal to 200 g/m².

The sheet may have a grammage of between 120 and 190 g/m². In some embodiments, the sheet used to form the aerosol-forming substrate has a density of less than 1 100 mg/cm³, preferably less than 1000 mg/cm³, and more preferably less than 900 mg/cm³.

In some embodiments, the aerosol-forming substrate has a mass/surface area of less than 0.09 mg/mm², preferably less than 0.085 mg/mm², preferably less than 0.08 mg/mm² and more preferably less than 0.075 mg/mm².

In some embodiments the aerosol-forming substrate may have a thickness less than about 1 mm, preferably less than about 0.5 mm, preferably between about 0.1 and 0.3 mm, such as about 0.2 mm.

The aerosol-forming substrate may comprise at least 50 wt% plant material, e.g. at least 60 wt% plant material e.g. around 65 wt% plant material. The aerosol-forming substrate may comprise 80 wt% or less plant material e.g. 75 or 70 wt% or less plant material.

The aerosol-forming substrate may comprise one or more additives selected from humectants, flavou rants, fillers, aqueous/ non-aq u eous solvents and binders.

Humectants are provided as vapour generators - the resulting vapour helps carry the volatile active compounds and increases visible vapour. Suitable humectants include polyhydric alcohols (e.g. propylene glycol (PG), triethylene glycol, 1 ,2-butane diol and vegetable glycerine (VG)) and their esters (e.g. glycerol mono-, di- or tri-acetate). They may be present in the aerosol-forming substrate in an amount between 1 and 50 wt%.

The humectant content of the aerosol-forming substrate may have a lower limit of at least 1 % by weight of the plant material, such as at least 2 wt %, such as at least 5 wt %, such as at least 10 wt %, such as at least 20 wt %, such as at least 30 wt %, or such as least 40 wt %.

The humectant content of the aerosol-forming substrate may have an upper limit of at most 50 % by weight of the plant material, such as at most 40 wt %, such as at most 30 wt %, or such as at most 20 wt %.

Preferably, the humectant content is 1 to 40 wt % of the aerosol-forming substrate, such as 1 to 20 wt %

Suitable binders are known in the art and may act to bind together the components forming the aerosolforming substrate. Binders may comprise starches and/or cellulosic binders such as methyl cellulose, ethyl cellulose, hydroxy propyl cellulose, hydroxyethyl cellulose and carboxymethyl cellulose, gums such as xanthan, guar, arabic and/or locust bean gum, organic acids and their salts such as alginic acid/ sodium alginate, agar and pectins. Preferably the binder content is 5 to 20 wt% of the aerosol-forming substrate e.g. around 5 to 10 wt% or around 6 to 8 wt%. The upper limit of binder is preferably up to 15 wt. %, such as up to 10 wt. %. Preferably the binder content is above 5 wt%.

Suitable fillers are known in the art and may act to strengthen the aerosol-forming substrate. Fillers may comprise fibrous (non-tobacco) fillers such as cellulose fibres, lignocellulose fibres (e.g. wood fibres), jute fibres and combinations thereof.

Preferably, the filler content is 5 to 10 wt% of the aerosol-forming substrate e.g. around 6 to 9 wt%.

The aerosol-forming substrate may comprise an aqueous and/or non-aqueous solvent. In some embodiments, the aerosol forming substrate has a water content of between 5 and 10 wt% e.g. between 6-9 wt% such as between 7-9 wt%.

Suitable flavourant may be provided in solid or liquid form. It may include menthol, liquorice, chocolate, fruit flavour (including e.g. citrus, cherry etc.), vanilla, spice (e.g. ginger, cinnamon) and tobacco flavour. The flavourant may be evenly dispersed throughout the aerosol-forming substrate or may be provided in isolated locations and/or varying concentrations throughout the aerosol-forming substrate.

The aerosol-forming substrate may be formed in a substantially cylindrical shape such that the article/consumable resembles a conventional cigarette. It may have a diameter of between 5 and 10mm e.g. between 6 and 9mm or 6 and 8mm e.g. around 7 mm. It may have an axial length of between 10 and 15mm e.g. between 1 1 and 14mm such as around 12 or 13mm.

The aerosol-forming substrate may be circumscribed by a wrapping layer e.g. a paper wrapping layer. The wrapping layer may overlie an inner foil layer or may comprise a paper/foil laminate (with the foil innermost).

The article/consumable may comprise at least one filter element. There may be a terminal filter element at the downstream/mouth end of the article/consumable. There may be a plurality of filter elements (e.g. the terminal filter element and an upstream filter element) which may be adjacent one another or which may be spaced apart. Any upstream filter element may be at least partly (e.g. entirely) circumscribed by the (paper) wrapping layer.

The or at least one of the filter element(s) (e.g. the terminal filter element and/or upstream filter element) may be comprised of cellulose acetate or polypropylene tow. The or at least one of the filter element(s) (e.g. the terminal filter element and/or upstream filter element may be comprised of activated charcoal. The or at least one of the filter element(s) (e.g. the terminal filter element and/or upstream filter element may be comprised of paper. The or at least one of the filter element(s) (e.g. the terminal filter element and/or upstream filter element may be comprised of plant material e.g. extruded plant material. The or each filter element may be circumscribed with a plug wrap e.g. a paper plug wrap.

The or each filter element may have a substantially cylindrical shape with a diameter substantially matching the diameter of the aerosol-forming substrate (with or without its associated wrapping layer). The axial length of the or each filter element may be less than 20mm, e.g. between 8 and 15mm, for example between 9 and 13 mm e.g. between 10 and 12mm.

The or at least one of the filter element(s) may be a solid filter element. The or at least one of the filter element(s) may be a hollow bore filter element. The or each hollow bore filter may have a bore diameter of between 1 and 5 mm, e.g. between 2 and 4 mm or between 2 and 3 mm.

There may be a plurality of e.g. two filter elements which may be adjacent one another or which may be spaced apart. Any filter element(s) upstream of the terminal filter element may be at least partly (e.g. entirely) circumscribed by the (paper) wrapping layer.

The terminal filter element (at the downstream end of the article/consumable) may be joined to the upstream elements forming the article/consumable by a circumscribing tipping layer e.g. a tipping paper layer. The tipping paper may have an axial length longer than the axial length of the terminal filter element such that the tipping paper completely circumscribes the terminal filter element plus the wrapping layer surrounding any adjacent upstream element.

The or at least one of the filter elements e.g. the terminal filter element may include a capsule e.g. a crushable capsule (crush-ball) containing a liquid flavourant e.g. any of the flavourants listed above. The capsule can be crushed by the user during smoking of the article/consumable to release the flavourant. The capsule may be located at the axial centre of the terminal filter element.

In some embodiments, the article/consumable may comprise an aerosol-cooling element which is adapted to cool the aerosol generated from the aerosol-forming substrate (by heat exchange) before being inhaled by the user.

The aerosol-cooling element will be downstream from the aerosol-forming substrate. For example, it may be between the aerosol-forming substrate and the upstream filter element and/or between the two filter elements. The aerosol cooling element may be at least partly (e.g. completely) circumscribed by the (paper) wrapping layer.

The aerosol-cooling element may be formed of a plastics material selected from the group consisting of polylactic acid (PLA), polyvinyl chloride (PVC), polyethylene (PE) and polyethylene terephthalate (PET). The aerosol-cooling element may be formed of a crimped/gathered sheet of material to form a structure having a high surface area with a plurality of longitudinal channels to maximise heat exchange and cooling of the aerosol.

The article/consumable may comprise a spacer element that defines a space or cavity between the aerosolforming substrate and the downstream end of the article/consumable. It may be provided between the aerosol-forming substrate and the upstream filter element and/or between the two filter elements. The spacer element may comprise a tubular element e.g. a cardboard tube. The spacer element may be at least partly (e.g. entirely) circumscribed by the (paper) wrapping layer. The spacer acts to allow both cooling and mixing of the aerosol.

The spacer element may have an external diameter of between 5 and 10mm e.g. between 6 and 9mm or 6 and 8mm e.g. around 7 mm. It may have an axial length of between 10 and 15mm e.g. between 12 and 14 mm or 13 and 14mm e.g. around 14mm.

In a third aspect, there is provided a smoking substitute system comprising an aerosol-forming article according to the first aspect or the second aspect, and a device comprising a heating element.

The device may be a HNB device i.e. a device adapted to heat but not combust the aerosol-forming substrate.

The device may comprise a main body for housing the heating element. The heating element may comprise an elongated e.g. rod, tube-shaped or blade heating element. The heating element may project into or surround a cavity within the main body for receiving the article/consumable described above.

The device (e.g. the main body) may further comprise an electrical power supply e.g. a (rechargeable) battery for powering the heating element. It may further comprise a control unit to control the supply of power to the heating element.

In a fourth aspect, there comprises a method of using a smoking substitute system according to the third aspect, the method comprising:

inserting the article/consumable into the device; and

heating the article/consumable using the heating element.

In some embodiments, the method comprises inserting the article/consumable into a cavity within the main body and penetrating the article/consumable with the heating element upon insertion of the article/consumable. For example, the heating element may penetrate the aerosol-forming substrate in the article/consumable. In a fifth aspect, there is provided a method for manufacturing an aerosol-forming substrate, wherein the aerosol forming substrate is a slurry-type reconstituted plant material comprising: combining a ground plant material with an aqueous medium to form a slurry; and combining nicotine and/or a nicotine salt with the slurry. Preferably, a nicotine salt is combined with the slurry.

Advantageously, by combining nicotine and/or a nicotine salt with the slurry a greater degree of homogeneity of the nicotine and the plant material is achieved. This provides the user with an enhanced and more consistent user experience. Also, the amount of nicotine can be more accurately controlled and tailored to the user’s requirements, thus more easily enabling the production of bespoke blends.

The nicotine and/or nicotine salt can be added to the slurry in combination with other additives or alone. In particular, the nicotine and/or nicotine salt may be combined with the tobacco prior to or following grinding. Alternatively, the nicotine and/or nicotine salt may be combined with the pulp mix.

There is no particular limitation as to when the nicotine and/or nicotine salt is added to the slurry (i.e. it can be added at any stage of slurry processing) as long as it is present in the slurry rather than, for example, being sprayed onto a cast sheet of slurry mixture.

It is preferable that the plant material is ground to a particle size of less than 120 microns. It is undesirable to have a particle size greater than 150 microns as this is associated with the formation of defects and inhomogeneous areas in the sheet formed by casting the slurry. Particularly, preferred is a particle size of 30 to 120 microns.

A binder may also be included within the slurry. The amount of binder used is chosen to provide an amount of 5 to 20 weight % of binder in the sheet ultimately produced from the slurry, such as 5 to 15 weight %, such as 5 to 10 weight %. The ground tobacco may be combined with the binder before combination with the aqueous medium. Or alternatively, the binder may be combined with the aqueous medium prior to combining the aqueous medium with the ground tobacco.

The slurry may also contain fillers, humectants, preservatives, and/or flavours. These may be combined with the ground plant material before combination with the aqueous medium, or alternatively can be added to the slurry separately

It is preferred that the total solids content of the slurry is between 15 % and 30 % of the total slurry weight. Of this preferred range about 50 to 90 % of the total solids content of the slurry should be the plant material. The plant material content of the slurry is not critical, but it is preferred that the minimum amount of aqueous medium is used to avoid leaching of plant material solubles into the aqueous medium. The slurry is formed by mixing the various components of the slurry. This may be achieved using a high energy mixer or a high shear mixer to homogenize the slurry. During mixing the slurry may optionally be heated.

Additionally, the slurry may be vibrated to aid homogenization of the slurry. This may be achieved by vibrating a tank or silo in which the slurry is contained.

After mixing the slurry is cast onto a moving support surface, such as a dryer belt to form a sheet. Casting of the sheet may be achieved by a roll coater system or a laminator, or any other method suitable in the art. It is preferred that the moisture content of the sheet at casting is between 60 and 80 % of the total weight of the cast slurry. The cast sheet is then dried by exposure to elevated temperatures and/or reduced pressures to remove excess moisture content from the sheet. Suitable drying methods include a steam dryer and/or heated air dryers. Alternatively, the sheet may be dried under ambient conditions,

Preferably, the nicotine salt is selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nicotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate, nicotine lactate and nicotine salicylate, and combinations thereof.

Advantageously, these salts provide a satisfactory“nicotine hit”. Also, by having lower volatility and higher stability in comparison to nicotine these salts are easier to handle during processing of the slurry.

Preferably, the nicotine and/or a nicotine salt is provided as an aqueous solution.

Advantageously, the non-toxicity and non-flammability of water minimises handling risks during processing. Furthermore, the“premixing” of the nicotine salt with a solvent prior to combination with the slurry, improves the homogeneous nature of the nicotine salt and the slurry mixture.

Preferably, the plant material is tobacco.

As the invention is primarily intended to provide a smoking consumable, the use of tobacco provides a slurry-type reconstituted plant material having the inherent properties of tobacco, for examples, the texture, aroma and presence of nicotine.

The method according the fifth aspect may comprise a step of winding the formed sheet onto a bobbin and/or a step of making an HNB consumable.

According to a sixth aspect there is provided an aerosol-forming substrate for an HNB device produced by the process according to the fifth aspect. Preferably, the aerosol-forming substrate according to the sixth aspect comprises a nicotine salt selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nicotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate nicotine lactate and nicotine salicylate, and combinations thereof, wherein the nicotine salt content is 2 to 15 % by weight of the reconstituted tobacco product.

The skilled person will appreciate that except where mutually exclusive, a feature or parameter described in relation to any one of the above aspects may be applied to any other aspect. Furthermore, except where mutually exclusive, any feature or parameter described herein may be applied to any aspect and/or combined with any other feature or parameter described herein.

Summary of the Figures

So that the invention may be understood, and so that further aspects and features thereof may be appreciated, embodiments illustrating the principles of the invention will now be discussed in further detail with reference to the accompanying figures, in which:

Figure 1 shows a first embodiment of an HNB consumable;

Figure 2 shows a second embodiment of an HNB consumable;

Figure 3 shows a third embodiment of an HNB consumable;

Figure 4 shows the first embodiment within a device forming an HNB system;

Figure 5 shows an illustrative diagram of an embodiment of the manufacturing process;

Figure 6 shows a fourth embodiment of an HNB consumable;

Figure 7 shows a fifth embodiment of an HNB consumable

Figure 8 shows a sixth embodiment of an HNB consumable; and

Figure 9 shows the fourth embodiment within a device forming an HNB system.

Detailed Description of the Figures

As shown in Figure 1 , the HNB consumable 1 comprises an aerosol-forming substrate 2 at the upstream end of the consumable 1.

The aerosol-forming substrate 2 comprises reconstituted tobacco which includes nicotine as a volatile compound and which is dosed with 2 to 15 wt% of a nicotine salt selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate, nicotine lactate and nicotine salicylate, and combinations thereof.

The aerosol-forming substrate 2 comprises 65 wt% tobacco which is provided in the form of gathered shreds produced from a sheet of slurry-type reconstituted tobacco. The tobacco is dosed with 20wt% of a humectant such as propylene glycol (PG) or vegetable glycerine (VG) and has a moisture content of between 7-9 wt%. The aerosol-forming substrate further comprises cellulose pulp filler and guar gum binder.

The aerosol-forming substrate 2 is formed in a substantially cylindrical shape such that the consumable resembles a conventional cigarette. It has diameter of around 7mm and an axial length of around 12 mm.

The aerosol-forming substrate 2 is circumscribed by a paper wrapping layer 3.

The consumable 1 comprises an upstream filter element 4 and a downstream (terminal) filter element 5. The two filter elements 4, 5 are spaced by a cardboard tube spacer 6. Both filter elements 4, 5 are formed of cellulose acetate tow and wrapped with a respective paper plug layer (not shown).

Both filter elements have a substantially cylindrical shape. The diameter of the upstream filter 4 matches the diameter of the aerosol-forming substrate 2. The diameter of the terminal filter element 5 is slightly larger and matches the combined diameter of the aerosol-forming substrate 2 and the wrapping layer 3. The upstream filter element is slightly shorter in axial length than the terminal filter element at an axial length of 10mm compared to 12mm for the terminal filer element.

The cardboard tube spacer is longer than each of the two filter portions having an axial length of around 14mm.

Each filter element 4, 5 is a hollow bore filter element with a hollow, longitudinally extending bore. The diameter of the bore in the upstream filter 4 is slightly larger than the diameter of the bore in the terminal filter 5, having a diameter of 3mm compared to 2 mm for the terminal filter element.

The cardboard tube spacer 6 and the upstream filter portion 4 are circumscribed by the wrapping layer 3.

The terminal filter element 5 is joined to the upstream elements forming the consumable by a circumscribing paper tipping layer 7. The tipping layer 7 encircles the terminal filter portion and has an axial length of around 20mm such that it overlays a portion of the cardboard tube spacer 6.

Figure 2 shows a second embodiment of a consumable 1 which is the same as that shown in Figure 1 except that the terminal filter element 5 comprises a crushable capsule 8 (crush-ball) containing a liquid menthol or cherry or vanilla flavourant. The capsule 8 is spherical and has a diameter of 3.5mm. It is positioned within the axial centre of the terminal filter portion 5.

Figure 3 shows a third embodiment of a consumable 1 which is the same as the first embodiment except that the wrapping layer 3 does not completely circumscribe the cardboard tube spacer 6 such that there is an annular gap 9 between the tipping layer 7 and the cardboard tube spacer 6 downstream of the end of the wrapping layer 3.

Figure 4 shows the first embodiment inserted into an HNB device 10 comprising a rod-shaped heating element 20. The heating element 20 projects into a cavity 1 1 within the main body 12 of the device.

The consumable 1 is inserted into the cavity 1 1 of the main body 12 of the device 10 such that the heating rod penetrates the aerosol-forming substrate 2. Heating of the reconstituted tobacco in the aerosol-forming substrate 2 is effected by powering the heating element (e.g. with a rechargeable battery (not shown)). As the tobacco is heated, moisture and volatile compound (e.g. nicotine) within the tobacco and the aerosol former are released as a vapour and entrained within an airflow generated by inhalation by the user at the terminal filter portion 5.

As the vapour cools within the upstream filer element 4 and the cardboard tube spacer 6, it condenses to form an aerosol containing the volatile compounds for inhalation by the user.

Figure 5 shows an illustrative diagram of an embodiment of the manufacturing process. Tobacco is ground to reduce the particle size to less than 120 microns 101

The ground tobacco 101 is then combined with a guar gum binder, cellulose pulp filler, propylene glycol and vegetable glycerine to form a mixture 102.

The mixture 102 is combined with an aqueous medium to form a slurry 103. Mixing of the mixture 102 with the aqueous medium is carried out in a high shear mixer. The tobacco content of the slurry is approximately 50 to 90 % of the total solids content of the slurry, where the total solids content is 15 to 30 weight % of the slurry.

A nicotine salt selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate, nicotine lactate and nicotine salicylate, and combinations thereof is combined with the slurry formed in step 103. The amount of nicotine salt is selected so as to ultimately provide a nicotine salt content of 2 to 15 weight % in the dried tobacco sheet.

The resultant slurry 104 is cast onto a dryer belt to form a sheet 105. The sheet is dried using a steam drying apparatus to remove excess moisture content from the sheet until the sheet is self-supporting 106.

The sheet is wound onto a bobbin 107 for storage. The moisture content of the cast sheet at winding is about 7 to 15 percent of dry weight of the tobacco sheet. The sheet can subsequently be made into a whole or part of an HNB consumable suitable for an HNB device 108. This is achieved by cutting the sheet to an appropriate size. The sheet may be used as whole or part of an HNB consumable for an HNB device 109. In particular, it is a slurry-type reconstituted tobacco product for use in an HNB device.

Turning now to consider Figure 6, there is shown a fourth embodiment of HNB consumable 1 , which is similar in several respects to the first embodiment illustrated in Figure 1. This embodiment again comprises an aerosol-forming substrate 2 at the upstream end of the consumable 1. The aerosol-forming substrate comprises reconstituted tobacco which includes nicotine as a volatile compound.

The aerosol-forming substrate 2 comprises 65 wt% tobacco which is provided in the form of gathered shreds produced from a sheet of slurry/paper recon tobacco. The tobacco is dosed with 20wt% of a humectant such as propylene glycol (PG) or vegetable glycerine (VG) and has a moisture content of between 7-9 wt%. The aerosol-forming substrate further comprises cellulose pulp filler and guar gum binder.

The aerosol-forming substrate 2 is circumscribed by a paper wrapping layer 3.

The consumable 1 comprises an upstream filter element 4 and a downstream (terminal) filter element 5. In this embodiment, the two filter elements 4, 5 are spaced by a cooling element 30 instead of by the cardboard tube spacer 6 of the previous embodiments.

The cooling element 30 is formed of a gathered sheet of polylactic acid (PLA) which is sprayed with an aqueous solution of a nicotine salt prior to gathering. The gathered sheet provides a cooling element 30 having numerous axially oriented channels which provide a large surface area over which the vapour produced from the aerosol-forming substrate can flow.

Both filter elements 4, 5 are formed of cellulose acetate tow and wrapped with a respective paper plug layer (not shown).

Both filter elements have a substantially cylindrical shape. The diameter of the upstream filter 4 matches the diameter of the aerosol-forming substrate 2. The diameter of the terminal filter element 5 is slightly larger and matches the combined diameter of the aerosol-forming substrate 2 and the wrapping layer 3. The upstream filter element is slightly shorter in axial length than the terminal filter element at an axial length of 10mm compared to 12mm for the terminal filter element.

The cooling element 30 is longer than each of the two filter portions having an axial length of around 14mm. Each filter element 4, 5 is a hollow bore filter element with a hollow, longitudinally extending bore. The diameter of the bore in the upstream filter 4 is slightly larger than the diameter of the bore in the terminal filter 5, having a diameter of 3mm compared to 2 mm for the terminal filter element.

The cooling element 30 and the upstream filter portion 4 are circumscribed by the wrapping layer 3.

The terminal filter element 5 is joined to the upstream elements forming the consumable by a circumscribing paper tipping layer 7. The tipping layer 7 encircles the terminal filter portion and has an axial length of around 20mm such that it overlays a portion of the cooling element 30.

Figure 7 shows a fifth embodiment of a consumable 1 which is the same as that shown in Figure 6 except that the terminal filter element 5 is a solid filter element and comprises a crushable capsule 8 (crush-ball) having a shell wall containing a liquid menthol or cherry or vanilla flavourant. The capsule 8 is spherical and has a diameter of 3.5mm. It is positioned within the axial centre of the terminal filter portion 5.

Figure 8 shows a sixth embodiment of a consumable 1 which is the same as the fourth embodiment except that the wrapping layer 3 does not completely circumscribe the cooling element 30 such that there is an annular gap 9 between the tipping layer 7 and the cooling element 30 downstream of the end of the wrapping layer 3.

Figure 9 shows the fourth embodiment inserted into an HNB device 10 comprising a rod-shaped heating element 20. The heating element 20 projects into a cavity 1 1 within the main body 12 of the device.

The consumable 1 is inserted into the cavity 1 1 of the main body 12 of the device 10 such that the heating rod 20 penetrates the aerosol-forming substrate 2. Heating of the reconstituted tobacco in the aerosolforming substrate 2 is effected by powering the heating element (e.g. with a rechargeable battery (not shown)). As the tobacco is heated, moisture and volatile compound (e.g. nicotine) within the tobacco and the humectant are released as a vapour and entrained within an airflow generated by inhalation by the user at the terminal filter portion 5.

As the vapour passes through the cooling element 30, heat exchange between the vapour and the cooling element vaporises the nicotine salts and cools the vapour such that condenses to form an aerosol containing the volatile compounds released from both the aerosol-forming substrate 2 and the cooling element 30 for inhalation by the user.

The features disclosed in the foregoing description, or in the following claims, or in the accompanying drawings, expressed in their specific forms or in terms of a means for performing the disclosed function, or a method or process for obtaining the disclosed results, as appropriate, may, separately, or in any combination of such features, be utilised for realising the invention in diverse forms thereof. While the invention has been described in conjunction with the exemplary embodiments described above, many equivalent modifications and variations will be apparent to those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments of the invention set forth above are considered to be illustrative and not limiting. Various changes to the described embodiments may be made without departing from the scope of the invention.

For the avoidance of any doubt, any theoretical explanations provided herein are provided for the purposes of improving the understanding of a reader. The inventors do not wish to be bound by any of these theoretical explanations.

Any section headings used herein are for organizational purposes only and are not to be construed as limiting the subject matter described.

Throughout this specification, including the claims which follow, unless the context requires otherwise, the words“have”,“comprise”, and“include”, and variations such as“having”,“comprises”,“comprising”, and “including” will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.

It must be noted that, as used in the specification and the appended claims, the singular forms“a,”“an,” and“the” include plural referents unless the context clearly dictates otherwise. Ranges may be expressed herein as from“about” one particular value, and/or to“about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by the use of the antecedent“about,” it will be understood that the particular value forms another embodiment. The term“about” in relation to a numerical value is optional and means, for example, +/- 10%.

The words "preferred" and "preferably" are used herein refer to embodiments of the invention that may provide certain benefits under some circumstances. It is to be appreciated, however, that other embodiments may also be preferred under the same or different circumstances. The recitation of one or more preferred embodiments therefore does not mean or imply that other embodiments are not useful, and is not intended to exclude other embodiments from the scope of the disclosure, or from the scope of the claims.

Claims

Claims:

1. An aerosol-forming article comprising an aerosol-forming substrate dosed with nicotine and/or a nicotine salt, wherein the aerosol-forming substrate is a slurry-type reconstituted plant material.

2. An article according to claim 1 , wherein the aerosol-forming substrate is dosed with nicotine salt selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate nicotine lactate and nicotine salicylate, and combinations thereof.

3. An article according to any one of the preceding claims wherein the plant material is tobacco.

4. An article according to any one of the preceding claims wherein the article is a heat-not-burn (HNB) consumable.

5. An aerosol-forming article comprising an aerosol-forming substrate and a cooling element wherein the cooing element is adapted to increase the concentration of a volatile compound within a vapour generated by heating of the aerosol-forming substrate.

6. An article according to claim 5 wherein the aerosol-cooling element comprises at least one volatile compound additive.

7. An article according to claim 6 wherein the at least one volatile compound additive may comprise nicotine and/or nicotine salts.

8. An article according to claim 7 wherein nicotine salt is selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate nicotine lactate and nicotine salicylate, and combinations thereof.

9. An article according to any one of claims 5 to 8 wherein the aerosol-cooling element may be formed of a plastics material selected from the group consisting of polylactic acid (PLA), polyvinyl chloride (PVC), polyethylene (PE) and polyethylene terephthalate (PET).

10. An article according to any one of claims 5 to 9 wherein the aerosol-cooling element is formed of a crimped/gathered sheet of material forming an aerosol-cooling element having a plurality of longitudinal channels.

11. An article according to claim 10 wherein the sheet of material is coated with the volatile compound additive.

12. An article according to any one of claims 5 to 11 wherein the aerosol-cooling element is spaced from the aerosol-forming substrate by an upstream filter element.

13. An article according to claim 12 wherein the upstream filter element is a hollow bore filter element.

14. An article according to any one of claims 5 to 13 further comprising a terminal filter element downstream of the aerosol-cooling element.

15. An article according to claim 14 wherein the terminal filter element is a hollow bore filter element.

16. A system comprising an aerosol-forming article according to any one of the preceding claims and a device comprising a heating element.

17. A system according to claim 16 wherein the device comprises a main body for housing the heating element and the heating element comprises an elongated heating element.

18. A method of using the system according to claim 16 or 17, the method comprising:

inserting the article into the device; and

heating the article using the heating element.

19. A method according to claim 18 comprising inserting the article into a cavity within a main body of the device and penetrating the article with the heating element upon insertion of the article.

20. A method for manufacturing an aerosol-forming substrate, wherein the aerosol-forming substrate is a slurry-type reconstituted plant material, the method comprising:

combining a ground plant material with an aqueous medium to form a slurry;

combining nicotine and/or a nicotine salt with the slurry;

casting the slurry to form a sheet; and

drying the sheet to form the aerosol-forming substrate.

21. A method according to claim 20, wherein the nicotine salt is selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate nicotine lactate and nicotine salicylate, and combinations thereof.

22. The method according to any one of claims 20 to 21 , wherein the nicotine and/or a nicotine salt is provided in aqueous solution

23. The method according to any one of claims 20 to 22, wherein the plant material is tobacco.

24. An aerosol-forming substrate for an HNB device produced by a process according to any of claims 20 to 23.

25. The aerosol-forming substrate according to claim 24 comprising a nicotine salt selected from nicotine hydrochloride, nicotine dihydrochloride, nicotine monotartrate, nicotine bitartrate, nicotine bitartrate dihydrate, nicotine benzoate, nicotine fumarate, nictotine orotate, nicotine sulphate, nicotine zinc chloride monohydrate nicotine lactate and nicotine salicylate, and combinations thereof, wherein the nicotine salt content is 2 to 15 % by weight of the aerosol-forming substrate.