WO2022246150A1 - Method of manufacture and scale-up of the metal-organic framework cu(qc)2 - Google Patents

Method of manufacture and scale-up of the metal-organic framework cu(qc)2 Download PDF

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Publication number
WO2022246150A1
WO2022246150A1 PCT/US2022/030183 US2022030183W WO2022246150A1 WO 2022246150 A1 WO2022246150 A1 WO 2022246150A1 US 2022030183 W US2022030183 W US 2022030183W WO 2022246150 A1 WO2022246150 A1 WO 2022246150A1
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WO
WIPO (PCT)
Prior art keywords
metal
mof
synthesis solution
making
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2022/030183
Other languages
English (en)
French (fr)
Inventor
Carter W. Abney
Julie J. Seo
Matthew T. Kapelewski
Dominick A. Zurlo
Joseph M. Falkowski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Technology and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Technology and Engineering Co filed Critical ExxonMobil Technology and Engineering Co
Priority to KR1020237043892A priority Critical patent/KR20240011761A/ko
Priority to EP22731377.2A priority patent/EP4340989A1/en
Priority to US18/561,619 priority patent/US20240246060A1/en
Priority to CN202280036262.6A priority patent/CN117377528A/zh
Priority to JP2023571860A priority patent/JP2024521103A/ja
Publication of WO2022246150A1 publication Critical patent/WO2022246150A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons

Definitions

  • the invention relates to:
  • Embodiment 2 A method of making metal-organic frameworks comprising the steps of: (a) providing a solvent composition comprising at least one solvent;
  • Embodiment 4 The method of making metal-organic frameworks of embodiments 2 or 3, wherein the solvent is selected from dimethylformamide and/or tetrahydrofuran.
  • Embodiment 12 A metal-organic framework MOF Cu(Qc)2 having an adsorption maxima (/.max) at a wavelength of about 474 nanometers, and a solvent inclusion between about 9.0 to about 12.7 percent by volume, wherein the metal-organic framework is made by a process comprising the steps of:
  • Embodiment 18 The method of making MOF Cu(Qc)2 of embodiment 13, wherein the buffer is a bicarbonate or sodium carbonate.
  • Embodiment 20 The method of making MOF Cu(Qc)2 of embodiments 13, 14, 15, 16, 17, 18, or 19, wherein the synthesis solution is heated between about 100°C and about 160°C.
  • Embodiment 24 The method of making MOF Cu(Qc)2 of embodiments 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, or 23, wherein the synthesis solution is heated in static, tumbling or stirred conditions.
  • Embodiment 31 The method of any one of the preceding embodiments, wherein MOF CU(QC) 2 has an ethane adsorption capacity of between about 2.0 and about 2.4.
  • Embodiment 32 The method of any one of the preceding embodiments, further comprising the step of filtering the metal-organic framework material.
  • Embodiment 33 The method of any one of the preceding embodiments, further comprising the step of washing the metal-organic framework material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/US2022/030183 2021-05-21 2022-05-20 Method of manufacture and scale-up of the metal-organic framework cu(qc)2 Ceased WO2022246150A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020237043892A KR20240011761A (ko) 2021-05-21 2022-05-20 금속-유기 골격 Cu(Qc)₂의 제조 방법 및 대규모화
EP22731377.2A EP4340989A1 (en) 2021-05-21 2022-05-20 Method of manufacture and scale-up of the metal-organic framework cu(qc)2
US18/561,619 US20240246060A1 (en) 2021-05-21 2022-05-20 Method Of Manufacture And Scale-Up Of The Metal-Organic Framework Cu(Qc)2
CN202280036262.6A CN117377528A (zh) 2021-05-21 2022-05-20 金属-有机骨架Cu(Qc)2的制备方法和规模化
JP2023571860A JP2024521103A (ja) 2021-05-21 2022-05-20 金属‐有機フレームワークＣｕ（Ｑｃ）２の製造方法およびスケールアップ方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202163191579P 2021-05-21 2021-05-21
US63/191,579 2021-05-21

Publications (1)

Publication Number Publication Date
WO2022246150A1 true WO2022246150A1 (en) 2022-11-24

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PCT/US2022/030183 Ceased WO2022246150A1 (en) 2021-05-21 2022-05-20 Method of manufacture and scale-up of the metal-organic framework cu(qc)2

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US (1) US20240246060A1 (cg-RX-API-DMAC7.html)
EP (1) EP4340989A1 (cg-RX-API-DMAC7.html)
JP (1) JP2024521103A (cg-RX-API-DMAC7.html)
KR (1) KR20240011761A (cg-RX-API-DMAC7.html)
CN (1) CN117377528A (cg-RX-API-DMAC7.html)
WO (1) WO2022246150A1 (cg-RX-API-DMAC7.html)

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CN121668891A (zh) * 2026-02-11 2026-03-17 太原工业学院 一种实现乙烷乙烯分离的装置及方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104368310A (zh) * 2013-08-14 2015-02-25 中国科学院大连化学物理研究所 一种强化甲烷吸附分离的金属有机骨架材料、制备及应用

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CH613813A5 (cg-RX-API-DMAC7.html) * 1975-11-14 1979-10-15 Photon Power Inc
CN110075805A (zh) * 2019-05-08 2019-08-02 华南理工大学 一种优先吸附乙烷的金属-有机骨架材料的常温制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104368310A (zh) * 2013-08-14 2015-02-25 中国科学院大连化学物理研究所 一种强化甲烷吸附分离的金属有机骨架材料、制备及应用

Non-Patent Citations (11)

* Cited by examiner, † Cited by third party
Title
CAS , no. 15684-35-2
CAS, no. 7250-53-5
CHEN ET AL.: "Tuning Pore Size in Square-Lattice Coordination Networks for Size Selective Sieving of CO", CHEM. INT. ED., vol. 55, 2016, pages 10268 - 10272
CHEN KAI-JIE ET AL: "Supporting Information Tuning Pore Size in Square-Lattice Coordination Networks for Size- Selective Sieving of CO 2", ANGEWANDTE CHEMIE, 21 July 2016 (2016-07-21), pages 1 - 58, XP055964539, Retrieved from the Internet <URL:https://doi.org/10.1002/ange.201603934> [retrieved on 20220926] *
CHEN, K. ET AL.: "Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO", ANGEW. CHEM. INT. ED., vol. 55, 2018, pages 10268 - 10272
KAI-JIE CHEN ET AL: "Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO2", ANGEWANDTE CHEMIE, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 128, no. 35, 21 July 2016 (2016-07-21), pages 10424 - 10428, XP071369012, ISSN: 0044-8249, DOI: 10.1002/ANGE.201603934 *
LIN ET AL.: "EthanelEthylene Separation in a Metal Organic Framework With Iron-Peroxo Sites", SCIENCE, vol. 362, 2018
LIN, W. ET AL.: "Boosting EthanelEthylene Separation within Isoreticular Ultramicroporous Metal-Organic Frameworks", J. AM. CHEM. SOC., vol. 140, 2018, pages 12940 - 12946
TANG YUNING ET AL: "Room temperature synthesis of Cu(Qc)2 and its application for ethane capture from light hydrocarbons", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 213, 20 November 2019 (2019-11-20), XP086005291, ISSN: 0009-2509, [retrieved on 20191120], DOI: 10.1016/J.CES.2019.115355 *
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Also Published As

Publication number Publication date
EP4340989A1 (en) 2024-03-27
JP2024521103A (ja) 2024-05-28
KR20240011761A (ko) 2024-01-26
US20240246060A1 (en) 2024-07-25
CN117377528A (zh) 2024-01-09

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