CN117377528A - 金属-有机骨架Cu(Qc)2的制备方法和规模化 - Google Patents

金属-有机骨架Cu(Qc)2的制备方法和规模化 Download PDF

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Publication number
CN117377528A
CN117377528A CN202280036262.6A CN202280036262A CN117377528A CN 117377528 A CN117377528 A CN 117377528A CN 202280036262 A CN202280036262 A CN 202280036262A CN 117377528 A CN117377528 A CN 117377528A
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China
Prior art keywords
metal
organic framework
mof
preparing
synthesis solution
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Pending
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CN202280036262.6A
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English (en)
Chinese (zh)
Inventor
C·W·艾布尼
J·J·谢奥
M·T·卡佩列夫斯基
D·A·祖罗
J·M·福尔科夫斯基
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ExxonMobil Technology and Engineering Co
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ExxonMobil Technology and Engineering Co
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Publication of CN117377528A publication Critical patent/CN117377528A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN202280036262.6A 2021-05-21 2022-05-20 金属-有机骨架Cu(Qc)2的制备方法和规模化 Pending CN117377528A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202163191579P 2021-05-21 2021-05-21
US63/191,579 2021-05-21
PCT/US2022/030183 WO2022246150A1 (en) 2021-05-21 2022-05-20 Method of manufacture and scale-up of the metal-organic framework cu(qc)2

Publications (1)

Publication Number Publication Date
CN117377528A true CN117377528A (zh) 2024-01-09

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CN202280036262.6A Pending CN117377528A (zh) 2021-05-21 2022-05-20 金属-有机骨架Cu(Qc)2的制备方法和规模化

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Country Link
US (1) US20240246060A1 (cg-RX-API-DMAC7.html)
EP (1) EP4340989A1 (cg-RX-API-DMAC7.html)
JP (1) JP2024521103A (cg-RX-API-DMAC7.html)
KR (1) KR20240011761A (cg-RX-API-DMAC7.html)
CN (1) CN117377528A (cg-RX-API-DMAC7.html)
WO (1) WO2022246150A1 (cg-RX-API-DMAC7.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN121668891A (zh) * 2026-02-11 2026-03-17 太原工业学院 一种实现乙烷乙烯分离的装置及方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4159914A (en) * 1975-11-14 1979-07-03 Photon Power, Inc. Photovoltaic cell
CN104368310A (zh) * 2013-08-14 2015-02-25 中国科学院大连化学物理研究所 一种强化甲烷吸附分离的金属有机骨架材料、制备及应用
CN110075805A (zh) * 2019-05-08 2019-08-02 华南理工大学 一种优先吸附乙烷的金属-有机骨架材料的常温制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4159914A (en) * 1975-11-14 1979-07-03 Photon Power, Inc. Photovoltaic cell
CN104368310A (zh) * 2013-08-14 2015-02-25 中国科学院大连化学物理研究所 一种强化甲烷吸附分离的金属有机骨架材料、制备及应用
CN110075805A (zh) * 2019-05-08 2019-08-02 华南理工大学 一种优先吸附乙烷的金属-有机骨架材料的常温制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DR. KAI-JIE CHEN ET AL.: ""Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO2"", 《ANGEWANDTE CHEMIE-INTERNATIONAL EDITION》, vol. 55, no. 35, 21 July 2016 (2016-07-21), pages 4 *
MAIK SCHLESINGER ET AL.: ""Evaluation of synthetic methods for microporous metal–organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3] and [Cu2(btc)(OH)(H2O)]"", 《MICROPOROUS AND MESOPOROUS MATERIALS》, vol. 132, no. 1, 14 February 2010 (2010-02-14), pages 2 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN121668891A (zh) * 2026-02-11 2026-03-17 太原工业学院 一种实现乙烷乙烯分离的装置及方法

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JP2024521103A (ja) 2024-05-28
KR20240011761A (ko) 2024-01-26
US20240246060A1 (en) 2024-07-25
WO2022246150A1 (en) 2022-11-24

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