WO2022223218A1 - Préparation cosmétique transparente - Google Patents

Préparation cosmétique transparente Download PDF

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Publication number
WO2022223218A1
WO2022223218A1 PCT/EP2022/057442 EP2022057442W WO2022223218A1 WO 2022223218 A1 WO2022223218 A1 WO 2022223218A1 EP 2022057442 W EP2022057442 W EP 2022057442W WO 2022223218 A1 WO2022223218 A1 WO 2022223218A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
preparation
polyglyceryl
preparation according
glucoside
Prior art date
Application number
PCT/EP2022/057442
Other languages
German (de)
English (en)
Inventor
Helen LANDSTORFER
Robert Klauck
Melanie Braun
Original Assignee
Beiersdorf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf Ag filed Critical Beiersdorf Ag
Priority to EP22716077.7A priority Critical patent/EP4326219A1/fr
Publication of WO2022223218A1 publication Critical patent/WO2022223218A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent

Definitions

  • the invention belongs to the cosmetic field and relates to an antiperspirant cosmetic preparation which is present as a transparent emulsion.
  • cosmetic products are not only used to make people look beautiful and attractive, but with their effect they make a decisive contribution to increased self-esteem and people's well-being. Accordingly, a wide variety of cosmetic products are used for the daily cleansing and care of the skin.
  • deodorants and antiperspirants which are used under the armpits to prevent bad smells.
  • the cause of bad odors is the decomposition of per se odorless sweat by bacteria. Fatty acid residues occur as a product of the decomposition, which characterize the typically known smell of sweat. Regardless of the fact that deodorants and antiperspirants are used on the same area of skin and have the same objective, they differ in their technical effect.
  • Antiperspirants contain antiperspirant active ingredients that serve to impede and reduce the flow of sweat. Aluminum-containing antiperspirant active ingredients clog the sweat glands.
  • Deodorants are characterized in that they do not prevent the flow of sweat. Instead, deodorants are products that contain special antimicrobial agents that reduce the growth of bacteria such as Corynebacterium jeikeium or Staphylococcus epidermidis. Consequently, the decomposition of the odorless sweat is reduced, so that less malodor occurs.
  • antiperspirants and deodorants are applied to the skin either by means of an application roller or as a spray.
  • Both propellant-operated aerosol sprays and those operated by means of a hand pump come as sprays Pump sprays used.
  • the composition of the cosmetic preparations varies significantly.
  • Antiperspirants which are applied to the skin using an application roller are described, inter alia, in WO2010009880 A1.
  • WO2010009880 A1 discloses antiperspirant cosmetic preparations which contain a) aluminum chlorohydrate, b) butylene glycol and/or glycerol, and c) at least one emulsifier. Isocetheth-20 is used as an emulsifier.
  • the disclosed formulations containing butylene glycol are transparent.
  • a disadvantage is the fact that, in addition to the selection of the polyols, it is crucial for the production of transparent perfume-containing preparations to use emulsifiers which have at least one polyethylene glycol subunit.
  • isocetheth-2020 has ethylene glycol units.
  • formulations are required which do not contain any such molecules, but it should be ensured that no inhomogeneities occur in the formulation and that the formulations do not become cloudy. In particular, there should be no turbidity if the preparations are stored under normal conditions for a period of 6 days.
  • the specific combination of the present invention was able to address this need.
  • the preparations of the invention were transparent and homogeneous.
  • the present invention relates to a cosmetic preparation in the form of an O/W emulsion containing a) polyglyceryl-4 caprates and/or polyglyceryl-10 laurates, b) an aluminum-containing antiperspirant active ingredient, and c) at least one alkyl glucoside, characterized in that no substances containing a polyethylene glycol subunit or that the proportion of substances containing a polyethylene glycol subunit is 0% by weight, based on the total weight of the preparation. All weight percentages (% by weight) given below are based on the total weight of the preparation according to the invention, unless otherwise stated. When ratios of certain components are disclosed in the following description, unless otherwise indicated, such ratios refer to weight ratios of the components.
  • normal conditions / normal conditions refers to 20 ° C., 1013 hPa and a relative humidity of 50%.
  • skin refers exclusively to human skin.
  • a polyethylene glycol subunit consists of at least 2 consecutive ethylene glycol units.
  • the preparation according to the invention was surprisingly able to eliminate or reduce the disadvantages of the prior art.
  • the preparation contains at least one aluminum-containing antiperspirant active ingredient.
  • Examples of aluminum salts according to the invention are:
  • Aluminum salts such as aluminum chloride AICL, aluminum sulfate Al 2 (S0 4 ) 3
  • At least one aluminum zirconium salt is present as the antiperspirant active ingredient.
  • These are advantageously selected from the group of aluminum/zirconium trichlorohydrex glycine ([AI 4 Zr(OH)i 3 Cl3] x H 2 0 x Gly), aluminum/zirconium tetrachlorohydrex glycine ([AI 4 Zr(OH)i 2 Cl4] x H 2 0 x Gly), aluminium/zirconium pentachlorohydrex glycine ([Al8Zr(OH)23Cl5] x H2O x Gly), aluminium/zirconium octachlorohydrex glycine ([Al8Zr(OH)2oCl8] x H2O x Gly) and the glycine free aluminium/ zirconium salts.
  • Aluminum/zirconium tetrachlorohydrex glycine is particularly preferred.
  • aluminum chlorohydrate aluminum sesquichlorohydrate and/or aluminum/zirconium tetrachlorohydrex glycine are present as the aluminum-containing antiperspirant active ingredient, with aluminum chlorohydrate being the most preferred.
  • the total proportion of aluminum-containing antiperspirant active ingredients is advantageously from 1% by weight to 30% by weight, preferably from 2% by weight to 25% by weight and particularly preferably from 5% by weight to 22% by weight on the total weight of the preparation.
  • the proportion of aluminum chlorohydrate is from 1% by weight to 30% by weight, preferably from 2% by weight to 25% by weight and particularly preferably from 5% by weight to 22% by weight. %, based on the total weight of the preparation.
  • the alkyl glucosides include heptyl glucosides, decyl glucosides, lauryl glucosides, caprylyl/caprylic glucosides and coco glucosides. It is preferred if caprylyl/caprylic glucoside is present as the alkyl glucoside.
  • the proportion of the alkyl glucosides is from 1 to 5% by weight, preferably from 1.5 to 4.5% by weight and particularly preferably from 1.8 to 4% by weight, based on the Total weight of the preparation is. It is particularly advantageous if caprylyl/caprylic glucoside is used in a proportion of 1 to 5% by weight, preferably 1.5 to 4.5% by weight and particularly preferably 1.8 to 4% by weight on the total weight of the preparation.
  • the weight ratio of the total proportion of polyglyceryl-4 caprate and polyglyceryl-10 laurate to the total proportion of the alkyl glucosides is advantageously from 1.6:1 to 1:1.6, preferably from 1.5:1 to 1:1.5 and particularly preferably 1 .4:1 to 1:1.4.
  • the preparation contains at least one short-chain polyol having a maximum of 6 carbon atoms.
  • Glycerol, propylene glycol, 1,3-propanediol, butylene glycol and/or pentylene glycol are advantageously selected from this group.
  • the total proportion by weight of the polyols selected from the group consisting of glycerol, propylene glycol, 1,3-propanediol, butylene glycol and pentylene glycol is advantageously from 2 to 30% by weight, preferably from 5 to 25% by weight and particularly preferably from 10 to 20% by weight, based on the total weight of the preparation.
  • 1,3-propanediol is particularly advantageously contained in the preparation.
  • such preparations are distinguished in particular by the fact that, after storage at ⁇ 10° C. for 6 days and subsequent thawing under normal conditions, they do not show any formation of streaks in the transparent preparation.
  • 1,3-propanediol in a proportion of 2 to 30 wt .-%, preferably from 5 to 25 wt .-% and particularly preferably from 10 to 20 wt .-%, based on the total weight of the preparation.
  • further polyols having a maximum of 6 carbon atoms can correspondingly advantageously be dispensed with. This means that their proportion is advantageously 0% by weight.
  • the other emulsifiers are advantageously selected from the group of emulsifiers which have an HLB value in the range from 10 to 20, preferably from 12 to 18 and particularly preferably from 14 to 17.
  • polyglyceryl esters are understood as meaning an ester which is formed from polyglycerol (for example polyglycerol-10) and at least one fatty acid.
  • One or more other emulsifiers are advantageous, selected from the group of polyglyceryl-3 methylglucose distearate, polyglyceryl-10 caprate, polyglyceryl-10 caprylate, polyglyceryl-10 dilaurate, polyglyceryl-10 trilaurate, polyglyceryl-10 myristate, polyglyceryl-10 dimyristate, polyglyceryl -10 Oleate, Polyglyceryl-10 Dioleate, Polyglyceryl-10 Stearate, Polyglyceryl-10 Distearate, Polyglyceryl-10 Diisostearate, Polyglyceryl-10 Isosteareate, Polyglyceryl-10 Tristearate, Polyglyceryl-6 Caprylate, Polyglyceryl-6 Dicaprylate, Polygylceryl-6 Tricaprylate, Polyglyceryl -6 Dicaprate, Polyglyceryl-6 Laurate, Polyglyceryl-6 Trilaurate, Polyglyceryl-6 Oleate,
  • the preparation additionally contains at least one or more perfume substances which are liquid under normal conditions.
  • perfumes are selected from essential oils, geraniol, geranyl acetate, linalool, linalyl acetate, tetrahydrolinalool, citronellol, citronellyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, tetrahydromyrcenol, terpineol, terpinyl acetate, nopol, nopyl acetate, 2-phenyl benzyl alcohol, benzyl acetate, benzyl salicylate, benzyl benzoate, styrallyl acetate, Amyl salicylate, dimethyl benzyl carbinol, trichloromethylphenyl carbinyl acetate, p-tert-butylcyclohexyl acetate, isononyl
  • the proportion of perfume substances which are liquid under normal conditions is advantageously from 0.001 to 2% by weight, preferably from 0.005 to 1.5% by weight and particularly preferably from 0.01 to 1.4% by weight, based on the total weight of the preparation .
  • the preparation contains water, it being preferred if the proportion of water is from 40 to 80% by weight, particularly preferably from 45 to 75% by weight, the figures relating to the total weight of the preparation relate.
  • oil phase of the preparation is less than 3% by weight, preferably less than 2% by weight, based on the total weight of the preparation, with emulsifiers by definition not belonging to the oil phase.
  • the preparations can contain further excipients.
  • These can include dyes, deodorants, thickeners or other ingredients.
  • this has a transmission of at least 80% at 880 nm.
  • the measurement is carried out with a Turbiscan Lab Expert Analyzer according to the principle of multiple light scattering at 30.5°C.
  • Backscatter is detected at a 45° scattering angle in relation to the incident light beam at 0°
  • transmission is detected at a 180° scattering angle in relation to the incident light beam at 0°.
  • the measurement of backscatter and transmission is height-resolved, the resolution in the Turbiscan lab is 40pm.
  • the device was calibrated with standard cells filled with silicone oil and made of Teflon.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation cosmétique contenant un polyol, un émulsifiant et un chlorohydrate d'aluminium.
PCT/EP2022/057442 2021-04-19 2022-03-22 Préparation cosmétique transparente WO2022223218A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP22716077.7A EP4326219A1 (fr) 2021-04-19 2022-03-22 Préparation cosmétique transparente

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102021203827.1 2021-04-19
DE102021203827.1A DE102021203827A1 (de) 2021-04-19 2021-04-19 Transparente kosmetische Zubereitung

Publications (1)

Publication Number Publication Date
WO2022223218A1 true WO2022223218A1 (fr) 2022-10-27

Family

ID=81307091

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2022/057442 WO2022223218A1 (fr) 2021-04-19 2022-03-22 Préparation cosmétique transparente

Country Status (3)

Country Link
EP (1) EP4326219A1 (fr)
DE (1) DE102021203827A1 (fr)
WO (1) WO2022223218A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010009880A1 (fr) 2008-07-25 2010-01-28 Beiersdorf Ag Produit inhibiteur de la migration de l'huile
EP3168251A1 (fr) * 2015-11-16 2017-05-17 Evonik Degussa GmbH Esters de polyglycerine reticules
WO2022100992A1 (fr) * 2020-11-16 2022-05-19 Beiersdorf Ag Pulvérisateur à pompe contenant des sels d'aluminium

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010009880A1 (fr) 2008-07-25 2010-01-28 Beiersdorf Ag Produit inhibiteur de la migration de l'huile
EP3168251A1 (fr) * 2015-11-16 2017-05-17 Evonik Degussa GmbH Esters de polyglycerine reticules
WO2022100992A1 (fr) * 2020-11-16 2022-05-19 Beiersdorf Ag Pulvérisateur à pompe contenant des sels d'aluminium

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ANONYM: "symbio solv clear plus MB", 1 April 2019 (2019-04-01), XP055945449, Retrieved from the Internet <URL:https://glenncorp.com/wp-content/uploads/2020/03/Symbio-Solv-Clear-Plus-MB.-TDS.-04.01.19.pdf> [retrieved on 20220722] *
DATABASE GNPD [online] MINTEL; 4 April 2018 (2018-04-04), ANONYMOUS: "BB Cream SPF15", XP055941243, retrieved from https://www.gnpd.com/sinatra/recordpage/5539589/ Database accession no. 5539589 *

Also Published As

Publication number Publication date
DE102021203827A1 (de) 2022-10-20
EP4326219A1 (fr) 2024-02-28

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