WO2022199869A1 - Polyamidzusammensetzungen - Google Patents

Polyamidzusammensetzungen Download PDF

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Publication number
WO2022199869A1
WO2022199869A1 PCT/EP2021/080418 EP2021080418W WO2022199869A1 WO 2022199869 A1 WO2022199869 A1 WO 2022199869A1 EP 2021080418 W EP2021080418 W EP 2021080418W WO 2022199869 A1 WO2022199869 A1 WO 2022199869A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
parts
formula
particularly preferably
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2021/080418
Other languages
German (de)
English (en)
French (fr)
Inventor
Jochen Endtner
Thorsten NUESSER
Matthias Bienmüller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
Original Assignee
Lanxess Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland GmbH filed Critical Lanxess Deutschland GmbH
Priority to EP21805486.4A priority Critical patent/EP4314144B1/de
Priority to CN202180096478.7A priority patent/CN117083331A/zh
Priority to KR1020237036011A priority patent/KR20230164095A/ko
Priority to JP2023558837A priority patent/JP2024511173A/ja
Publication of WO2022199869A1 publication Critical patent/WO2022199869A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317Phosphonic compounds, e.g. R—P(:O)(OR')2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313Phosphinic compounds, e.g. R2=P(:O)OR'
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof

Definitions

  • test specimens to be used here can be produced according to the relevant molding compound standard or by pressing and injection molding, or they can be taken from multi-purpose test specimens (DIN EN ISO 527 [2]).
  • DIN EN ISO 527 [2] The dimensions of the unnotched test specimen used within the scope of the present invention according to DIN EN ISO 3167, Type A are:
  • glass melts are made from pure quartz with additions of limestone, kaolin and boric acid. In addition to silicon dioxide, they contain varying amounts of various metal oxides.
  • the composition determines the properties of the products. According to the invention, preference is given to using at least one type of glass fiber from the group E glass, H glass, R glass, S glass, D glass, C glass and quartz glass, particularly preferably glass fibers made from E glass.
  • the glass can be colored, with non-colored glass being preferred as the starting material for use as component D).
  • Flow aids to be used as component E) are preferably copolymers of at least one ⁇ -olefin with at least one methacrylic acid ester or acrylic acid ester of an aliphatic alcohol. Particularly preferred are copolymers in which the a-olefin is made up of ethene and/or propene and the methacrylic acid ester or acrylic acid ester is linear or linear as the alcohol component contains branched alkyl groups with 6 to 20 carbon atoms. Acrylic acid (2-ethyl)hexyl ester is very particularly preferred. Copolymers suitable as flow aids are distinguished not only by their composition but also by their low molecular weight.
  • graft rubbers are ABS polymers which are produced by redox initiation with an initiator system of organic hydroperoxide and ascorbic acid according to US Pat. No. 4,937,285.
  • At least one laser absorber selected from the group consisting of antimony trioxide, tin oxide, tin orthophosphate, barium titanate, aluminum oxide, copper hydroxyphosphate, copper orthophosphate, potassium copper diphosphate, copper hydroxide, antimony tin oxide, bismuth trioxide and anthraquinone can be used as component E) with the loss of the property of high laser transmission.
  • Tin oxide, antimony trioxide or antimony tin oxide are particularly preferred.
  • Antimony trioxide is very particularly preferred.
  • the result was 64.3 g of the product of the formula (Ia) to be used as component B) as fine, colorless crystals, with a yield of 93%.
  • the glow-wire resistance was determined using the glow-wire ignition test GWIT (glow-wire-ignition-temperature) according to DIN EN 60695-2-13. In the GWIT test, the glow wire ignition temperature is specified, which is 25K (or 30K for temperatures in the range from 900°C to 960°C) higher than the maximum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/EP2021/080418 2021-03-26 2021-11-02 Polyamidzusammensetzungen Ceased WO2022199869A1 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP21805486.4A EP4314144B1 (de) 2021-03-26 2021-11-02 Polyamidzusammensetzungen
CN202180096478.7A CN117083331A (zh) 2021-03-26 2021-11-02 聚酰胺组合物
KR1020237036011A KR20230164095A (ko) 2021-03-26 2021-11-02 폴리아미드 조성물
JP2023558837A JP2024511173A (ja) 2021-03-26 2021-11-02 ポリアミド組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21165195.5 2021-03-26
EP21165195 2021-03-26

Publications (1)

Publication Number Publication Date
WO2022199869A1 true WO2022199869A1 (de) 2022-09-29

Family

ID=75252394

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2021/080418 Ceased WO2022199869A1 (de) 2021-03-26 2021-11-02 Polyamidzusammensetzungen

Country Status (5)

Country Link
EP (1) EP4314144B1 (https=)
JP (1) JP2024511173A (https=)
KR (1) KR20230164095A (https=)
CN (1) CN117083331A (https=)
WO (1) WO2022199869A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117683345A (zh) * 2023-12-19 2024-03-12 江苏晋伦塑料科技有限公司 防火耐热聚酰胺组合物及其制备方法和应用

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2035390A1 (de) 1969-07-17 1971-01-28 Eastman Kodak Co , Rochester, N Y (VStA) Formmasse zur Herstellung von Polyester formkorpern
DE2248242A1 (de) 1971-10-01 1973-04-12 Gen Electric Verstaerkte interkristalline thermoplastische polyester-zusammensetzungen
DE3631540A1 (de) 1986-09-17 1988-03-24 Bayer Ag Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit
DE3631539A1 (de) 1986-09-17 1988-03-24 Bayer Ag Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit
DE3704657A1 (de) 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
DE3704655A1 (de) 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
US4937285A (en) 1987-11-10 1990-06-26 Bayer Aktiengesellschaft Use of redox graft polymers to improve the petroleum-resistance of thermoplastic, aromatic polycarbonate and/or polyester carbonate moulding compositions
DE4236122A1 (de) 1992-10-27 1994-04-28 Bayer Ag Flammgeschützte, mineralgefüllte, thermoplastische Formmassen mit hoher Kriechstromfestigkeit
WO1997039053A1 (de) 1996-04-12 1997-10-23 Clariant Gmbh Synergistische flammschutzmittel-kombination für thermoplastische polymere
WO2006029711A1 (de) 2004-09-13 2006-03-23 Lanxess Deutschland Gmbh Halogenfreie flammgeschützte thermoplastische formmassen auf basis von polyamid mit erhöhter glühdrahtbeständigkeit
WO2009003976A1 (en) 2007-06-29 2009-01-08 Dsm Ip Assets B.V. Microsphere comprising a polymer core, a shell and an absorber
WO2020109469A1 (de) * 2018-11-30 2020-06-04 Clariant Plastics & Coatings Ltd Flammschutzmittelmischungen, flammhemmende polymerzusammensetzungen, damit ausgerüstete kabel und deren verwendung
WO2020132075A2 (en) 2018-12-20 2020-06-25 Lanxess Solutions Us Inc. Method of preparing phosphorus-containing flame retardants and their use in polymer compositions
WO2021076169A1 (en) 2019-10-18 2021-04-22 Lanxess Solutions Us Inc. Method of preparing phosphorus-containing flame retardants and their use in polymer compositions

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9745449B2 (en) * 2013-07-24 2017-08-29 Lanxess Solutions Us Inc. Phosphorus containing flame retardants
JP7218085B2 (ja) * 2017-07-26 2023-02-06 旭化成株式会社 難燃性樹脂成形体及びその製造方法

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2035390A1 (de) 1969-07-17 1971-01-28 Eastman Kodak Co , Rochester, N Y (VStA) Formmasse zur Herstellung von Polyester formkorpern
DE2248242A1 (de) 1971-10-01 1973-04-12 Gen Electric Verstaerkte interkristalline thermoplastische polyester-zusammensetzungen
DE3631540A1 (de) 1986-09-17 1988-03-24 Bayer Ag Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit
DE3631539A1 (de) 1986-09-17 1988-03-24 Bayer Ag Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit
DE3704657A1 (de) 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
DE3704655A1 (de) 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
US4937285A (en) 1987-11-10 1990-06-26 Bayer Aktiengesellschaft Use of redox graft polymers to improve the petroleum-resistance of thermoplastic, aromatic polycarbonate and/or polyester carbonate moulding compositions
DE4236122A1 (de) 1992-10-27 1994-04-28 Bayer Ag Flammgeschützte, mineralgefüllte, thermoplastische Formmassen mit hoher Kriechstromfestigkeit
WO1997039053A1 (de) 1996-04-12 1997-10-23 Clariant Gmbh Synergistische flammschutzmittel-kombination für thermoplastische polymere
WO2006029711A1 (de) 2004-09-13 2006-03-23 Lanxess Deutschland Gmbh Halogenfreie flammgeschützte thermoplastische formmassen auf basis von polyamid mit erhöhter glühdrahtbeständigkeit
WO2009003976A1 (en) 2007-06-29 2009-01-08 Dsm Ip Assets B.V. Microsphere comprising a polymer core, a shell and an absorber
WO2020109469A1 (de) * 2018-11-30 2020-06-04 Clariant Plastics & Coatings Ltd Flammschutzmittelmischungen, flammhemmende polymerzusammensetzungen, damit ausgerüstete kabel und deren verwendung
WO2020132075A2 (en) 2018-12-20 2020-06-25 Lanxess Solutions Us Inc. Method of preparing phosphorus-containing flame retardants and their use in polymer compositions
WO2021076169A1 (en) 2019-10-18 2021-04-22 Lanxess Solutions Us Inc. Method of preparing phosphorus-containing flame retardants and their use in polymer compositions

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
"Chemie Ingenieur Technik", vol. 72, 2000, WILEY-VCH VERLAGS GMBH, pages: 273 - 276
"Standard of Safety", 1998, UNDERWRITERS LABORATORIES INC., article "Test for Flammability of Plastic Materials for Parts in Devices and Appliances", pages: 14 - 18
A. F. HOLLEMANE. WIBERG: "Lehrbuch der Anorganischen Chemie", 1995, WALTER DE GRUYTER, pages: 764
CAS , no. 1078142-02-5
CAS, no. 72102-84-2
ULLMANN: "Enzyklopädie der Technischen Chemie", vol. 19, 1980, pages: 277 - 295

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117683345A (zh) * 2023-12-19 2024-03-12 江苏晋伦塑料科技有限公司 防火耐热聚酰胺组合物及其制备方法和应用

Also Published As

Publication number Publication date
EP4314144A1 (de) 2024-02-07
CN117083331A (zh) 2023-11-17
JP2024511173A (ja) 2024-03-12
EP4314144B1 (de) 2026-04-08
KR20230164095A (ko) 2023-12-01

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