WO2022199869A1 - Polyamidzusammensetzungen - Google Patents
Polyamidzusammensetzungen Download PDFInfo
- Publication number
- WO2022199869A1 WO2022199869A1 PCT/EP2021/080418 EP2021080418W WO2022199869A1 WO 2022199869 A1 WO2022199869 A1 WO 2022199869A1 EP 2021080418 W EP2021080418 W EP 2021080418W WO 2022199869 A1 WO2022199869 A1 WO 2022199869A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mass
- parts
- formula
- particularly preferably
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Definitions
- test specimens to be used here can be produced according to the relevant molding compound standard or by pressing and injection molding, or they can be taken from multi-purpose test specimens (DIN EN ISO 527 [2]).
- DIN EN ISO 527 [2] The dimensions of the unnotched test specimen used within the scope of the present invention according to DIN EN ISO 3167, Type A are:
- glass melts are made from pure quartz with additions of limestone, kaolin and boric acid. In addition to silicon dioxide, they contain varying amounts of various metal oxides.
- the composition determines the properties of the products. According to the invention, preference is given to using at least one type of glass fiber from the group E glass, H glass, R glass, S glass, D glass, C glass and quartz glass, particularly preferably glass fibers made from E glass.
- the glass can be colored, with non-colored glass being preferred as the starting material for use as component D).
- Flow aids to be used as component E) are preferably copolymers of at least one ⁇ -olefin with at least one methacrylic acid ester or acrylic acid ester of an aliphatic alcohol. Particularly preferred are copolymers in which the a-olefin is made up of ethene and/or propene and the methacrylic acid ester or acrylic acid ester is linear or linear as the alcohol component contains branched alkyl groups with 6 to 20 carbon atoms. Acrylic acid (2-ethyl)hexyl ester is very particularly preferred. Copolymers suitable as flow aids are distinguished not only by their composition but also by their low molecular weight.
- graft rubbers are ABS polymers which are produced by redox initiation with an initiator system of organic hydroperoxide and ascorbic acid according to US Pat. No. 4,937,285.
- At least one laser absorber selected from the group consisting of antimony trioxide, tin oxide, tin orthophosphate, barium titanate, aluminum oxide, copper hydroxyphosphate, copper orthophosphate, potassium copper diphosphate, copper hydroxide, antimony tin oxide, bismuth trioxide and anthraquinone can be used as component E) with the loss of the property of high laser transmission.
- Tin oxide, antimony trioxide or antimony tin oxide are particularly preferred.
- Antimony trioxide is very particularly preferred.
- the result was 64.3 g of the product of the formula (Ia) to be used as component B) as fine, colorless crystals, with a yield of 93%.
- the glow-wire resistance was determined using the glow-wire ignition test GWIT (glow-wire-ignition-temperature) according to DIN EN 60695-2-13. In the GWIT test, the glow wire ignition temperature is specified, which is 25K (or 30K for temperatures in the range from 900°C to 960°C) higher than the maximum
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21805486.4A EP4314144B1 (de) | 2021-03-26 | 2021-11-02 | Polyamidzusammensetzungen |
| CN202180096478.7A CN117083331A (zh) | 2021-03-26 | 2021-11-02 | 聚酰胺组合物 |
| KR1020237036011A KR20230164095A (ko) | 2021-03-26 | 2021-11-02 | 폴리아미드 조성물 |
| JP2023558837A JP2024511173A (ja) | 2021-03-26 | 2021-11-02 | ポリアミド組成物 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21165195.5 | 2021-03-26 | ||
| EP21165195 | 2021-03-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022199869A1 true WO2022199869A1 (de) | 2022-09-29 |
Family
ID=75252394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2021/080418 Ceased WO2022199869A1 (de) | 2021-03-26 | 2021-11-02 | Polyamidzusammensetzungen |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP4314144B1 (https=) |
| JP (1) | JP2024511173A (https=) |
| KR (1) | KR20230164095A (https=) |
| CN (1) | CN117083331A (https=) |
| WO (1) | WO2022199869A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117683345A (zh) * | 2023-12-19 | 2024-03-12 | 江苏晋伦塑料科技有限公司 | 防火耐热聚酰胺组合物及其制备方法和应用 |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2035390A1 (de) | 1969-07-17 | 1971-01-28 | Eastman Kodak Co , Rochester, N Y (VStA) | Formmasse zur Herstellung von Polyester formkorpern |
| DE2248242A1 (de) | 1971-10-01 | 1973-04-12 | Gen Electric | Verstaerkte interkristalline thermoplastische polyester-zusammensetzungen |
| DE3631540A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit |
| DE3631539A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit |
| DE3704657A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| DE3704655A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| US4937285A (en) | 1987-11-10 | 1990-06-26 | Bayer Aktiengesellschaft | Use of redox graft polymers to improve the petroleum-resistance of thermoplastic, aromatic polycarbonate and/or polyester carbonate moulding compositions |
| DE4236122A1 (de) | 1992-10-27 | 1994-04-28 | Bayer Ag | Flammgeschützte, mineralgefüllte, thermoplastische Formmassen mit hoher Kriechstromfestigkeit |
| WO1997039053A1 (de) | 1996-04-12 | 1997-10-23 | Clariant Gmbh | Synergistische flammschutzmittel-kombination für thermoplastische polymere |
| WO2006029711A1 (de) | 2004-09-13 | 2006-03-23 | Lanxess Deutschland Gmbh | Halogenfreie flammgeschützte thermoplastische formmassen auf basis von polyamid mit erhöhter glühdrahtbeständigkeit |
| WO2009003976A1 (en) | 2007-06-29 | 2009-01-08 | Dsm Ip Assets B.V. | Microsphere comprising a polymer core, a shell and an absorber |
| WO2020109469A1 (de) * | 2018-11-30 | 2020-06-04 | Clariant Plastics & Coatings Ltd | Flammschutzmittelmischungen, flammhemmende polymerzusammensetzungen, damit ausgerüstete kabel und deren verwendung |
| WO2020132075A2 (en) | 2018-12-20 | 2020-06-25 | Lanxess Solutions Us Inc. | Method of preparing phosphorus-containing flame retardants and their use in polymer compositions |
| WO2021076169A1 (en) | 2019-10-18 | 2021-04-22 | Lanxess Solutions Us Inc. | Method of preparing phosphorus-containing flame retardants and their use in polymer compositions |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9745449B2 (en) * | 2013-07-24 | 2017-08-29 | Lanxess Solutions Us Inc. | Phosphorus containing flame retardants |
| JP7218085B2 (ja) * | 2017-07-26 | 2023-02-06 | 旭化成株式会社 | 難燃性樹脂成形体及びその製造方法 |
-
2021
- 2021-11-02 CN CN202180096478.7A patent/CN117083331A/zh active Pending
- 2021-11-02 KR KR1020237036011A patent/KR20230164095A/ko active Pending
- 2021-11-02 EP EP21805486.4A patent/EP4314144B1/de active Active
- 2021-11-02 JP JP2023558837A patent/JP2024511173A/ja active Pending
- 2021-11-02 WO PCT/EP2021/080418 patent/WO2022199869A1/de not_active Ceased
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2035390A1 (de) | 1969-07-17 | 1971-01-28 | Eastman Kodak Co , Rochester, N Y (VStA) | Formmasse zur Herstellung von Polyester formkorpern |
| DE2248242A1 (de) | 1971-10-01 | 1973-04-12 | Gen Electric | Verstaerkte interkristalline thermoplastische polyester-zusammensetzungen |
| DE3631540A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit |
| DE3631539A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit |
| DE3704657A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| DE3704655A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| US4937285A (en) | 1987-11-10 | 1990-06-26 | Bayer Aktiengesellschaft | Use of redox graft polymers to improve the petroleum-resistance of thermoplastic, aromatic polycarbonate and/or polyester carbonate moulding compositions |
| DE4236122A1 (de) | 1992-10-27 | 1994-04-28 | Bayer Ag | Flammgeschützte, mineralgefüllte, thermoplastische Formmassen mit hoher Kriechstromfestigkeit |
| WO1997039053A1 (de) | 1996-04-12 | 1997-10-23 | Clariant Gmbh | Synergistische flammschutzmittel-kombination für thermoplastische polymere |
| WO2006029711A1 (de) | 2004-09-13 | 2006-03-23 | Lanxess Deutschland Gmbh | Halogenfreie flammgeschützte thermoplastische formmassen auf basis von polyamid mit erhöhter glühdrahtbeständigkeit |
| WO2009003976A1 (en) | 2007-06-29 | 2009-01-08 | Dsm Ip Assets B.V. | Microsphere comprising a polymer core, a shell and an absorber |
| WO2020109469A1 (de) * | 2018-11-30 | 2020-06-04 | Clariant Plastics & Coatings Ltd | Flammschutzmittelmischungen, flammhemmende polymerzusammensetzungen, damit ausgerüstete kabel und deren verwendung |
| WO2020132075A2 (en) | 2018-12-20 | 2020-06-25 | Lanxess Solutions Us Inc. | Method of preparing phosphorus-containing flame retardants and their use in polymer compositions |
| WO2021076169A1 (en) | 2019-10-18 | 2021-04-22 | Lanxess Solutions Us Inc. | Method of preparing phosphorus-containing flame retardants and their use in polymer compositions |
Non-Patent Citations (6)
| Title |
|---|
| "Chemie Ingenieur Technik", vol. 72, 2000, WILEY-VCH VERLAGS GMBH, pages: 273 - 276 |
| "Standard of Safety", 1998, UNDERWRITERS LABORATORIES INC., article "Test for Flammability of Plastic Materials for Parts in Devices and Appliances", pages: 14 - 18 |
| A. F. HOLLEMANE. WIBERG: "Lehrbuch der Anorganischen Chemie", 1995, WALTER DE GRUYTER, pages: 764 |
| CAS , no. 1078142-02-5 |
| CAS, no. 72102-84-2 |
| ULLMANN: "Enzyklopädie der Technischen Chemie", vol. 19, 1980, pages: 277 - 295 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117683345A (zh) * | 2023-12-19 | 2024-03-12 | 江苏晋伦塑料科技有限公司 | 防火耐热聚酰胺组合物及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP4314144A1 (de) | 2024-02-07 |
| CN117083331A (zh) | 2023-11-17 |
| JP2024511173A (ja) | 2024-03-12 |
| EP4314144B1 (de) | 2026-04-08 |
| KR20230164095A (ko) | 2023-12-01 |
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