WO2022163703A1 - 光学用粘着テープ - Google Patents
光学用粘着テープ Download PDFInfo
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- WO2022163703A1 WO2022163703A1 PCT/JP2022/002895 JP2022002895W WO2022163703A1 WO 2022163703 A1 WO2022163703 A1 WO 2022163703A1 JP 2022002895 W JP2022002895 W JP 2022002895W WO 2022163703 A1 WO2022163703 A1 WO 2022163703A1
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- sensitive adhesive
- pressure
- adhesive tape
- present
- weight
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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- B32B27/00—Layered products comprising a layer of synthetic resin
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/18—Manufacture of films or sheets
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C—CHEMISTRY; METALLURGY
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- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
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- C09J201/00—Adhesives based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
Definitions
- the form of the optical pressure-sensitive adhesive tape of the present invention is not particularly limited as long as the pressure-sensitive adhesive layer of the present invention is laminated on the first surface of the substrate of the present invention.
- it may be a single-sided adhesive tape having an adhesive surface only on one side, or a double-sided adhesive tape having an adhesive surface on both sides.
- the optical pressure-sensitive adhesive tape of the present invention is a double-sided pressure-sensitive adhesive tape
- the optical pressure-sensitive adhesive tape of the present invention may have a form in which both adhesive surfaces are provided by the pressure-sensitive adhesive layer of the present invention.
- the ratio of the dimensional change rate in the machine direction to the dimensional change rate in the width direction when the optical pressure-sensitive adhesive tape of the present invention is heated in an environment of 60 ° C. and a relative humidity of 90% for 500 hours is not particularly limited, it is preferably 0.5 or more and 2.0 or less.
- the ratio is within this range, in the tiling display of the present invention, the difference between the dimensional change rates in the width direction and the machine direction under the usage environment of the image display device of the present invention becomes small, and the difference between the image display devices It is preferable in that a good appearance can be maintained by suppressing conspicuous gaps, shrinkage or expansion is small, and transparency can be maintained without change.
- the ratio is preferably 0.6 or more and 1.8 or less, more preferably 0.7 or more and 1 in terms of suppressing conspicuous gaps between image display devices, reducing contraction or expansion, and maintaining transparency without change. 0.5 or less.
- the total light transmittance of the optical pressure-sensitive adhesive tape of the present invention is not particularly limited, it is preferably 85% or more.
- a configuration in which the optical pressure-sensitive adhesive tape of the present invention has a total light transmittance of 85% or more is preferable in terms of obtaining excellent transparency and an excellent appearance in the image display device of the present invention, and more preferably 88% or more. and may be 90% or more.
- the upper limit of the total light transmittance of the optical pressure-sensitive adhesive tape of the present invention is not particularly limited, it may be 95% or less.
- the total light transmittance of the optical adhesive tape of the present invention can be measured according to JIS K7361-1.
- the total light transmittance of the optical pressure-sensitive adhesive tape of the present invention depends on the type and thickness of the resin that constitutes the base material of the present invention, the type and thickness of the resin that constitutes the pressure-sensitive adhesive layer of the present invention, and the light reflected on the surface of the base material. It can be adjusted by applying anti-glare treatment and/or anti-glare treatment.
- the glass transition point (Tg) of the base material of the present invention can be measured according to JIS K 7121.
- the glass transition point (Tg) of the base material of the present invention can be adjusted by the type of resin constituting the base material of the present invention.
- the oxidized polyolefin may be prepared in-house, or a commercially available product may be used.
- the commercially available products include Disparlon 4200-20 (trade name, manufactured by Kusumoto Kasei Co., Ltd.) and Flownon SA300 (trade name, manufactured by Kyoeisha Chemical Co., Ltd.).
- a good solvent for the polyester-based resin can be suitably used.
- the solvent include ethyl acetate, methyl ethyl ketone, cyclopentanone and the like.
- the glass transition point (Tg) of the pressure-sensitive adhesive layer of the present invention is preferably -10°C or lower.
- the configuration in which the Tg of the pressure-sensitive adhesive layer of the present invention is ⁇ 10° C. or less maintains the stress relaxation property of the pressure-sensitive adhesive layer even in a low temperature environment, and the image display device of the present invention is resistant to shrinkage or expansion under the usage environment.
- the pressure-sensitive adhesive layer can sufficiently follow, can suppress lifting and peeling, and can sufficiently ensure adhesion to the adherend.
- the glass transition point of the pressure-sensitive adhesive layer of the present invention is preferably ⁇ 15° C. or less, and ⁇ 20° C. or less. There may be.
- the lower limit of the Tg of the pressure-sensitive adhesive layer of the present invention is not particularly limited. A temperature of -40°C or higher is preferable.
- the strain amount A of the pressure-sensitive adhesive layer of the present invention is not particularly limited, it is preferably 3% or more. In the configuration in which the strain amount A of the adhesive layer of the present invention is 3% or more, the adhesive layer sufficiently follows contraction or expansion under the usage environment of the image display device of the present invention, and lifting and peeling can be suppressed. point is preferable. In addition, when an adherend such as an image display panel has uneven steps due to wiring or the like, the pressure-sensitive adhesive layer can sufficiently follow the steps and can be filled without leaving air bubbles.
- the strain amount A of the pressure-sensitive adhesive layer of the present invention is more preferably 4% or more, and may be 5% or more, in order to prevent the optical pressure-sensitive adhesive tape of the present invention from floating or peeling and to follow steps.
- the adhesive composition forming the adhesive layer of the present invention may be in any form.
- the pressure-sensitive adhesive composition may be an emulsion type, a solvent type (solution type), an active energy ray-curable type, a heat-melting type (hot-melt type), or the like.
- solvent-type and active energy ray-curable pressure-sensitive adhesive compositions are preferable from the viewpoint of productivity and the ease with which a pressure-sensitive adhesive layer having excellent optical properties and appearance can be obtained.
- an active energy ray-curable adhesive composition is preferable from the viewpoint of facilitating control of the various properties of the adhesive layer (particularly, 300% tensile residual stress value, glass transition point, etc.) within a predetermined range.
- the pressure-sensitive adhesive layer of the present invention is an acrylic pressure-sensitive adhesive layer containing an acrylic polymer as a base polymer, and is preferably formed from an active energy ray-curable acrylic pressure-sensitive adhesive composition.
- the above acrylic polymer is a polymer composed (formed) of an acrylic monomer as an essential monomer component (monomer component).
- the acrylic polymer is preferably a polymer composed (formed) of a (meth)acrylic acid alkyl ester as an essential monomer component. That is, the acrylic polymer preferably contains a (meth)acrylic acid alkyl ester as a structural unit.
- “(meth)acryl” represents “acryl” and/or "methacryl” (either or both of "acryl” and “methacryl"), and so on.
- the said acrylic polymer is comprised by 1 type, or 2 or more types of monomer components.
- the proportion of the hydroxyl group-containing monomer in the total monomer components (100% by weight) constituting the acrylic polymer is particularly limited. However, it is preferably 0.5% by weight or more, more preferably 0.8% by weight or more, from the viewpoint of suppressing clouding in a high-humidity environment, improving durability, and obtaining high adhesion reliability. , more preferably 1% by weight or more.
- the acrylic pressure-sensitive adhesive composition may contain a hydroxyl group-containing monomer in addition to the acrylic polymer.
- the content (blending amount) of the hydroxyl group-containing monomer is 1 part by weight or more with respect to 100 parts by weight of the acrylic polymer. It is preferably 3 parts by weight or more, and still more preferably 5 parts by weight or more. When the content is 5 parts by weight or more, suppression of cloudiness and durability in a high-humidity environment can be further improved, and higher adhesion reliability can be obtained, which is preferable.
- Examples of the alicyclic structure-containing monomer include cyclopropyl (meth)acrylate, cyclobutyl (meth)acrylate, cyclopentyl (meth)acrylate, cyclohexyl (meth)acrylate, cycloheptyl (meth)acrylate, cyclooctyl (meth)acrylate, isobornyl (meth)acrylate, dicyclopentanyl (meth)acrylate, HPMPA represented by the following formula (2), TMA-2 represented by the following formula (3), HCPA represented by the following formula (4), etc. (Meth)acrylic monomers.
- the upper limit of the ratio of the alicyclic structure-containing monomer is the point of obtaining a pressure-sensitive adhesive layer having appropriate flexibility, and the various properties of the pressure-sensitive adhesive layer (especially, 300% tensile residual stress value, glass transition point, etc.) is preferably 50% by weight or less, more preferably 40% by weight or less, and even more preferably 30% by weight or less, from the viewpoint of facilitating control of the content within a predetermined range.
- the weight-average molecular weight (Mw) of the acrylic polymer can be determined by the GPC method in terms of polystyrene. For example, it can be measured under the following conditions using a high-speed GPC apparatus "HPLC-8120GPC" manufactured by Tosoh Corporation. Column: TSKgel SuperHZM-H/HZ4000/HZ3000/HZ2000 Solvent: Tetrahydrofuran Flow rate: 0.6 ml/min
- the glass transition temperature (Tg) of the acrylic polymer is not particularly limited, it is preferably -70 to -10°C, more preferably -65 to -15°C, and still more preferably -60 to -20°C.
- Tg glass transition temperature
- the structure in which the acrylic polymer has a glass transition temperature of ⁇ 10° C. or lower maintains the stress relaxation property of the adhesive layer even in a low temperature environment, and shrinks or expands in the environment in which the image display device of the present invention is used. It is preferable in that the pressure-sensitive adhesive layer sufficiently conforms to the surface, can suppress lifting and peeling, and can sufficiently ensure adhesion to the adherend.
- benzophenone-based photopolymerization initiator examples include benzophenone, benzoylbenzoic acid, 3,3'-dimethyl-4-methoxybenzophenone, polyvinylbenzophenone, ⁇ -hydroxycyclohexylphenyl ketone, and the like.
- ketal-based photopolymerization initiator examples include benzyl dimethyl ketal.
- the cyclic structure (ring) of the (meth)acrylic acid ester having a cyclic structure in the molecule (in one molecule) is an aromatic ring , a non-aromatic ring, and is not particularly limited.
- the aromatic ring include aromatic carbocyclic rings [eg, monocyclic carbocyclic rings such as benzene ring, condensed carbocyclic rings such as naphthalene ring, etc.], various aromatic heterocyclic rings, and the like.
- tricyclic or higher aliphatic hydrocarbon ring examples include, for example, a dicyclopentanyl group represented by the following formula (5a), and a dicyclopentanyl group represented by the following formula (5b).
- an adamantyl group represented by the following formula (5d) an adamantyl group represented by the following formula (5d)
- a tricyclopentenyl group represented by the following formula (5e) examples include, for example, a dicyclopentanyl group represented by the following formula (5a), and a dicyclopentanyl group represented by the following formula (5b).
- an adamantyl group represented by the following formula (5d) an adamantyl group represented by the following formula (5d)
- a chain transfer agent may be used in the polymerization of the acrylic oligomer to adjust the molecular weight (specifically, to adjust the weight average molecular weight to 1000 to 30000).
- the chain transfer agent include 2-mercaptoethanol, ⁇ -thioglycerol, 2,3-dimercapto-1-propanol, octylmercaptan, t-nonylmercaptan, dodecylmercaptan (laurylmercaptan), t-dodecylmercaptan, glycidyl mercaptan, thioglycolic acid, methyl thioglycolate, ethyl thioglycolate, propyl thioglycolate, butyl thioglycolate, t-butyl thioglycolate, 2-ethylhexyl thioglycolate, octyl thioglycolate, isooct
- the transmittance of the colorant is adjusted by an appropriate solvent such as tetrahydrofuran (THF) or a dispersion medium (organic solvent with low absorption in the wavelength range of 330 to 700 nm) so that the transmittance at a wavelength of 400 nm is about 50 to 60%. Measure using diluted solutions or dispersions.
- THF tetrahydrofuran
- a dispersion medium organic solvent with low absorption in the wavelength range of 330 to 700 nm
- Production example 9 (Preparation of acrylic pressure-sensitive adhesive composition 1) [Preparation of acrylic oligomer] 60 parts by weight of dicyclopentanyl methacrylate (DCPMA) and 40 parts by weight of methyl methacrylate (MMA) as monomer components, 3.5 parts by weight of ⁇ -thioglycerol as a chain transfer agent, and 100 parts by weight of toluene as a polymerization solvent are mixed. and stirred at 70° C. for 1 hour under a nitrogen atmosphere. Next, 0.2 parts by weight of 2,2′-azobisisobutyronitrile (AIBN) was added as a thermal polymerization initiator, reacted at 70° C. for 2 hours, and then heated to 80° C. for 2 hours. reacted.
- DCPMA dicyclopentanyl methacrylate
- MMA methyl methacrylate
- AIBN 2,2′-azobisisobutyronitrile
- Tg Glass transition point of substrate About 8 mg of a sample was collected, placed in an aluminum container, and subjected to DSC measurement.
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Abstract
Description
前記光学用粘着テープの前記粘着剤層を厚み50μmのPETフィルムに貼り合わせた後に10cm四方に切断した積層体を60℃相対湿度90%の環境下で500時間加熱したときの下記の最大カール量をD[mm]としたときに、下記式を満たすことが好ましい。
|C×D|≦3
・最大カール量:前記積層体のカールの凸になっている面が下側になるように水平面上に置いて、4隅の反りのうち最も高いものを最大カール量D[mm]とする。前記積層体の前記PETフィルム側を下側になるように水平面上に置いて測定した最大カール量を+、前記積層体の前記基材側を下側になるように水平面上に置いて測定した最大カール量を-とする。
本発明の第2の側面の画像表示装置は、本発明の第1の側面の光学用粘着テープを積層構造中に有するため、使用環境下における収縮又は膨張を抑制することができる。また、本発明の第2の側面の画像表示装置がある程度収縮又は膨張した場合であっても、前記粘着剤層は、画像表示装置の収縮又は膨張に十分に追従して、浮きや剥がれが生じにくい。従って、本発明の第2の側面の画像表示装置を複数枚並べて作製される本発明の第3の側面のタイリングディスプレイにおいては、使用環境下において、画像表示装置間の隙間が目立ちにくく、良好な外観を維持できる。また、透明性が変化なく維持できる。
本発明の第1の側面の光学用粘着テープを、本明細書において、「本発明の光学用粘着テープ」と称する場合がある。また、本発明の光学用粘着テープを構成する前記基材及び粘着剤層を、本明細書において、それぞれ、「本発明の基材」及び「本発明の粘着剤層」と称する場合がある。また、「粘着テープ」には、「粘着シート」の意味を含むものとする。すなわち、本発明の光学用粘着テープは、シート状の形態を有する粘着シートであってもよい。
また、本発明の第3の側面は、本発明の画像表示装置を複数枚並べたタイリングディスプレイを提供する。本発明の第3の側面のタイリングディスプレイを、本明細書において、「本発明のタイリングディスプレイ」と称する場合がある。
図1(a)において、光学用粘着テープ10Aは、基材1と、粘着剤層2とが積層された積層構造を有する。基材1は、第1面1aおよび第2面1bを有し、基材1の第1面1aに粘着剤層2が積層されている。
図1(b)において、光学用粘着テープ10Aの幅方向(TD)及び機械方向(MD)は、基材1の幅方向(TD)及び機械方向(MD)と対応して定められるものである。
以下、各構成について説明する。
本発明の光学用粘着テープにおける「光学」とは、光学用途に用いられることを意味し、より具体的には、光学部材が用いられた製品(光学製品)の製造などに用いられることを意味する。光学製品としては、例えば、画像表示装置、タッチパネルなどの入力装置などが挙げられるが、液晶画像表示装置、自発光型画像表示装置(例えば、有機EL(エレクトロルミネッセンス)画像表示装置、LED画像表示装置)などの製造に好適に使用することができる。特に、本発明の光学用粘着テープは、複数の画像表示装置をタイル状に並べるタイリングディスプレイの製造に適する。
寸法変化率(%)=[(60℃相対湿度90%の環境下で500時間加熱後の寸法)-(初期寸法)]/(初期寸法)×100
平均寸法変化率(%)=[(幅方向の寸法変化率(%))+(機械方向の寸法変化率(%))]/2
前記光学用粘着テープの前記粘着剤層を厚み50μmのPETフィルムに貼り合わせた後に10cm四方に切断した積層体を60℃相対湿度90%の環境下で500時間加熱したときの下記の最大カール量をD[mm]としたときに、下記式を満たすことが好ましい。
|C×D|≦3
・最大カール量:前記積層体のカールの凸になっている面が下側になるように水平面上に置いて、4隅の反りのうち最も高いものを最大カール量D[mm]とする。前記積層体の前記PETフィルム側を下側になるように水平面上に置いて測定した最大カール量を+、前記積層体の前記基材側を下側になるように水平面上に置いて測定した最大カール量を-とする。
前記|C×D|の下限値は、特に限定はなく、低いほど好ましいが、0.001以上であってもよい。
前記|D|の下限値は、特に限定はなく、低いほど好ましいが、0.1mm以上であってもよい。
前記湿度膨張率の下限値は、特に限定はなく、低いほど好ましいが、0.0001%以上であってもよい。
本発明の基材を構成する素材としては、ガラスやプラスチックフィルム等があげられる。前記プラスチックフィルムとしては、例えば、ポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)等のポリエステル系樹脂、環状オレフィン系ポリマー(COP)(例えば、商品名「アートン」(JSR(株)製)、商品名「ゼオノア」(日本ゼオン(株)製)等)、ポリメチルメタクリレート(PMMA)等のアクリル系樹脂、ポリカーボネート(PC)、トリアセチルセルロース(TAC)、ポリサルフォン、ポリアリレート、ポリエーテルエーテルケトン(PEEK)、ポリイミド(PI)、透明ポリイミド(CPI)、ポリ塩化ビニル、ポリ酢酸ビニル、ポリエチレン、ポリプロピレン、エチレン-プロピレン共重合体などのプラスチック材料が挙げられ、寸法安定性に優れ、収縮しにくいポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)等のポリエステル系樹脂、環状オレフィン系ポリマー(COP)、ポリカーボネート(PC)、ポリエーテルエーテルケトン(PEEK)、透明ポリイミド(CPI)が好ましい。なお、これらのプラスチック材料は、単独で又は2種以上を組み合わせて用いることができる。本発明の基材は、本発明の光学用粘着テープを被着体(画像表示パネル等)に貼付する際に、粘着剤層とともに被着体に貼付される部分である。本発明の光学用粘着テープの使用時(貼付時)に剥離される剥離ライナーは「基材」には含まない。
本発明の基材の湿度膨張係数の下限値は、特に限定はなく、低いほど好ましいが、0.001×10-5/%RH以上であってもよい。
平均傾斜角θa=tan-1Δa (1)
Δa=(h1+h2+h3・・・+hn)/L (2)
Ti値=β1/β2
ここで、β1はHAAKE社製レオストレス6000を用いてずり速度20(1/s)の条件で測定される粘度、β2はHAAKE社製レオストレス6000を用いてずり速度200(1/s)の条件で測定される粘度である。
本発明の粘着剤層は、基材(基材層)を有しない粘着剤層であってもよいし、基材を有するタイプの粘着剤層であってもよい。なお、本明細書において、基材(基材層)を有しない粘着剤層を「基材レス粘着剤層」と称する場合があり、基材を有するタイプの粘着剤層を「基材付き粘着剤層」と称する場合がある。上記基材レス粘着剤層としては、例えば、本発明の粘着剤層のみからなる単層の粘着剤層や、本発明の粘着剤層とその他の粘着剤層(本発明の粘着剤層以外の粘着剤層)からなる粘着剤層等が挙げられる。また、上記基材付き粘着剤層としては、基材の両面側に本発明の粘着剤層を有する粘着剤層や、基材の一方の面側に本発明の粘着剤層を有し、他方の面側にその他の粘着剤層を有する粘着剤層などが挙げられる。「基材付き粘着剤層」を構成する「基材(基材層)」としては、本発明の基材と同様のプラスチックフィルムを使用することができる。
<せん断試験>
厚み2mm、直径7.9mmの円盤状の粘着剤層の上下から60℃でねじり方向のせん断力500Paを600秒間かけた時の歪み量A(%)と、その後せん断力0Paで1800秒間保持した時の歪み量B(%)を測定し、下記式から復元率(%)を算出する。
復元率(%)=(歪み量A-歪み量B)/歪み量A×100
粘着剤層40は、厚さ2mm、直径7.9mmの円盤状の粘着剤層であり、本発明の粘着剤層により構成されるものであり、パラレルプレート41及び42は、それぞれ直径7.9mmの上面及び底面を有し、例えば、ステンレスなどで構成されるものである(図5(a))。パラレルプレート41の上面及びパラレルプレート42の底面を、それぞれ粘着剤層40の底面及び上面に位置を合わせて当接する(図5(b))。次に、周辺温度を60℃とし、粘着剤層40に、500Paのねじり方向のせん断力Fを600秒間かける(図5(c))。次に、パラレルプレート41及び42のせん断力を開放し、せん断力0Paで1800秒間放置する(図5(d))。「歪み量A」は、初期(図5(b))の粘着剤層40の外周(100%)に対するせん断力Fを600秒間かけた時点(図5(c))のねじり方向の変化量の百分率(%)である。「歪み量B」は、初期(図5(b))の粘着剤層40の外周(100%)に対する、せん断力Fを600秒間かけた後にせん断力0Paで1800秒間放置した時点(図5(d))のねじり方向の変化量の百分率(%)である。復元率(%)は、下記式から算出する。
復元率(%)=(歪み量A-歪み量B)/歪み量A×100
カラム:TSKgel SuperHZM-H/HZ4000/HZ3000/HZ2000
溶媒:テトラヒドロフラン
流速:0.6ml/分
1/Tg = W1/Tg1+W2/Tg2+・・・+Wn/Tgn
上記式中、Tgはアクリル系ポリマーのガラス転移温度(単位:K)、Tgiはモノマーiがホモポリマーを形成した際のガラス転移温度(単位:K)、Wiはモノマーiのモノマー成分全量中の重量分率を表す(i=1、2、・・・・n)。
上記アクリル系ポリマーを構成するモノマーのホモポリマーのTgとしては、下記の値を採用できる。
2-エチルヘキシルアクリレート -70℃
n-ヘキシルアクリレート -65℃
n-オクチルアクリレート -65℃
イソノニルアクリレート -60℃
n-ノニルアクリレート -58℃
n-ブチルアクリレート -55℃
エチルアクリレート -20℃
ラウリルアクリレート 0℃
2-エチルヘキシルメタクリレート -10℃
メチルアクリレート 8℃
n-ブチルメタクリレート 20℃
メチルメタクリレート 105℃
アクリル酸 106℃
メタクリル酸 228℃
酢酸ビニル 32℃
スチレン 100℃
カラム:TSKgel SuperHZM-H/HZ4000/HZ3000/HZ2000
溶媒:テトラヒドロフラン
流速:0.6ml/分
上記アクリル系オリゴマーを構成するモノマーのホモポリマーのTgとしては、下記の表1記載の値を採用できる。また、表1に記載のないモノマーのホモポリマーのTgとしては、「Polymer Handbook」(第3版、John Wiley & Sons,Inc、1989年)に記載の数値を採用できる。さらに、上記文献にも記載されていないモノマーのホモポリマーのTgとしては、上述の測定方法により得られる値(粘弾性試験によるtanδのピークトップ温度)を採用できる。
吸光度A:前記紫外線吸収剤の0.08%トルエン溶液に対して、波長400nmの光を当て、測定される吸光度
本発明の光学用粘着テープは、本発明の基材の第1面上に、本発明の粘着剤層を積層させることより調製することができる。
活性エネルギー線の照射により硬化を行う際は、塗膜の表面にさらにセパレータを付設して、粘着剤組成物を2枚のセパレータ間に挟持した状態で活性エネルギー線を照射して、酸素による重合阻害を防止することが好ましい。
活性エネルギー線の照射により硬化を行う際は、塗膜の表面にセパレータを付設して、粘着剤組成物を本発明の基材とセパレータの間に挟持した状態で活性エネルギー線を照射して、酸素による重合阻害を防止することが好ましい。
本発明の光学用粘着テープにおいて、表面又は任意の層間に帯電防止層を有していてもよい。本発明の光学用粘着テープが帯電防止層を有することにより、画像表示パネル等の被着体の破損を防止することができる。前記帯電防止層は、本発明の基材と本発明の粘着剤層の間に形成されることが好ましい。
本発明の光学用粘着テープにおいて、本発明の粘着剤層の表面(本発明の粘着剤層の粘着面)は、使用時まではセパレータにより保護されていてもよい。セパレータは粘着剤層の保護材として用いられるものであり、本発明の光学用粘着テープを被着体に貼付する際に剥がされる。
本発明の光学用粘着テープにおいて、本発明の基材の第2面は、表面保護フィルムにより保護されていてもよい。前記表面保護フィルムは、本発明の光学用粘着テープ、本発明の画像表示装置や本発明のタイリングディスプレイの製造時や搬送時に本発明の基材の第2面の保護材として用いられるものである。
本発明の画像表示装置は、本発明の光学用粘着テープと、画像表示パネルとが積層された積層構造を有する。図3において、画像表示装置20は、光学用粘着テープ10Bの粘着剤層1において、画像表示パネル4が積層されている。
本発明のタイリングディスプレイは、本発明の画像表示装置を複数枚並べて形成されるものである。図4において、タイリングディスプレイ30は、9枚の画像表示装置20(積層構造は図示略)を3×3の配列で、支持基板31上にタイル状に並べて形成されており、画像表示装置20同士は隙間32で接している。前記支持基板としては、本発明の基材と同様のガラス板やプラスチックフィルムを使用することができる。
(防眩性フィルム1の調製)
〔防眩層1形成用塗工液の調製〕
防眩層形成材料に含まれる樹脂として、紫外線硬化型ウレタンアクリレート樹脂(新中村化学社製、商品名「NKオリゴ UA-53H-80BK」)40重量部と、ペンタエリスリトールトリアクリレートを主成分とする多官能アクリレート(大阪有機化学工業株式会社製、商品名「ビスコート#300」)57.5重量部と、ジルコニア粒子と紫外線硬化性樹脂とを含有する光学調整層用組成物の希釈液(「オプスターZ7540」、JSR社製)2.5重量部と、シリコーン粒子(モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製、商品名「トスパール130ND」)2.8重量部と、チキソトロピー付与剤として有機粘土である合成スメクタイト(クニミネ工業株式会社製、商品名「スメクトンSAN」)2.5重量部と、光重合開始剤(BASF社製、商品名「OMNIRAD907」)3重量部と、架橋アクリルスチレン共重合樹脂の微粒子(積水化成品工業社製 商品名「SSX-103DXE」)6.5重量部と、レベリング剤(共栄社化学株式会社製、商品名「LE-303」)0.1重量部とを混合した。なお、前記有機粘土は、トルエンで固形分が6重量%になるよう希釈して用いた。この混合物を、固形分濃度が38重量%となるように、トルエン/シクロペンタノン(CPN)混合溶媒(重量比64/36)で希釈して、超音波分散機を用いて、防眩層形成材料(塗工液)を調製した。
基材として、透明プラスチックフィルム基材(PETフィルム、東レ株式会社製、商品名「38U413」、厚さ:38μm)を準備した。前記透明プラスチックフィルム基材の片面に、前記防眩層形成材料(塗工液)を、ワイヤーバーを用いて塗布して塗膜を形成した(塗工工程)。ついで、95℃で1分間加熱することにより前記塗膜を乾燥させた(乾燥工程)。その後、高圧水銀ランプにて積算光量300mJ/cm2の紫外線を照射し、前記塗膜を硬化処理して厚み6.5μmの防眩層を形成した。このようにして、前記光透過性基材と前記防眩層1との積層体を得た。
ペンタエリスリトールトリアクリレートを主成分とする多官能アクリレート(大阪有機化学工業株式会社製、商品名「ビスコート#300」)100重量部と、中空ナノシリカ粒子(日揮触媒化成工業株式会社製、商品名「スルーリア5320」)100重量部と、中実ナノシリカ粒子(日産化学工業株式会社製、商品名「MIBK-ST」、固形分30重量%、重量平均粒子径10nm)40重量部と、フッ素元素含有添加剤(信越化学工業株式会社製、商品名「KY-1203」)12重量部と、光重合開始剤(BASF社製、商品名「OMNIRAD907」)5重量部と、光重合開始剤(BASF社製、商品名「OMNIRAD2959」)5重量部とを混合した。その混合物に、希釈溶媒としてMIBK(メチルイソブチルケトン)およびPMA(プロピレングリコールモノメチルエーテルアセテート)を70:30重量比で混合した混合溶媒を添加して全体の固形分が1.5重量%となるようにし、攪拌して反射防止層形成用塗工液を調製した。
〔反射防止層1の形成〕
前記光透過性基材と前記防眩層1との積層体の防眩層面に、前記反射防止層形成用塗工液をワイヤーバーで塗工した(塗工工程)。前記塗工した塗工液を80℃で1分間加熱し、乾燥させて塗膜を形成した(乾燥工程)。乾燥後の前記塗膜に、高圧水銀ランプで積算光量300mJ/cm2の紫外線を照射して硬化処理した(硬化工程)。これにより、前記塗膜を硬化させ、厚み0.1μmの反射防止層1を形成した(反射防止層形成工程)。以上のようにして、本製造例1の防眩性フィルム1を製造した。
(防眩性フィルム2の調製)
〔防眩層2の形成〕
防眩層形成用塗工液の調製において、前記ペンタエリスリトールトリアクリレートを主成分とする多官能アクリレートの配合量を60重量部に変更したことと、シリコーン粒子の配合量を0.9重量部に変更したことと、チキソトロピー付与剤として有機粘土である合成スメクタイトを1.5重量部に変更したことと、ジルコニア粒子と紫外線硬化性樹脂とを含有する光学調整層用組成物の希釈液と、架橋アクリルスチレン共重合樹脂の微粒子を使用しなかったこと以外は、製造例1と同様の方法で前記光透過性基材と防眩層2との積層体を製造した。
〔反射防止層2の形成〕
反射防止層形成用塗工液の調製において、前記中空ナノシリカ粒子の配合量を240重量部に変更したこと以外は、製造例1と同様の方法で反射防止層2を形成した。以上のようにして、本製造例2の防眩性フィルム2を製造した。
(防眩性フィルム3の調製)
防眩層の形成において、基材として透明プラスチックフィルム基材(COPフィルム、日本ゼオン(株)製、商品名「ZF14」、厚さ:50μm)を使用した以外は、製造例1と同様な方法で本製造例3の防眩性フィルム3を製造した。
(防眩性フィルム4の調製)
防眩層の形成において、基材として透明プラスチックフィルム基材(PENフィルム、東洋紡(株)製、商品名「Q51」、厚さ:25μm)を使用した以外は、製造例1と同様な方法で本製造例4の防眩性フィルム4を製造した。
(防眩性フィルム5の調製)
防眩層の形成において、基材として透明プラスチックフィルム基材(PEEKフィルム、クラボウ(株)製、商品名「EXPEEK」、厚さ:50μm)を使用した以外は、製造例1と同様な方法で本製造例5の防眩性フィルム5を製造した。
(透明プラスチックフィルム基材の製造)
イソソルビド(以下「ISB」と略記することがある)81.98質量部に対して、トリシクロデカンジメタノール(以下「TCDDM」と略記することがある)47.19質量部、ジフェニルカーボネート(以下「DPC」と略記することがある)175.1質量部、及び触媒として、炭酸セシウム0.2質量%水溶液0.979質量部を反応容器に投入し、窒素雰囲気下にて、反応の第1段目の工程として、加熱槽温度を150℃に加熱し、必要に応じて攪拌しながら、原料を溶解させた(約15分)。次いで、圧力を常圧から13.3kPaにし、加熱槽温度を190℃まで1時間で上昇させながら、発生するフェノールを反応容器外へ抜き出した。反応容器全体を190℃で15分保持した後、第2段目の工程として、反応容器内の圧力を6.67kPaとし、加熱槽温度を230℃まで、15分で上昇させ、発生するフェノールを反応容器外へ抜き出した。攪拌機の攪拌トルクが上昇してくるので、8分で250℃まで昇温し、さらに発生するフェノールを取り除くため、反応容器内の圧力を0.200kPa以下に到達させた。所定の攪拌トルクに到達後、反応を終了し、生成した反応物を水中に押し出して、ポリカーボネート樹脂のペレットを得た。得られたポリカーボネート樹脂を80℃で5時間真空乾燥をした後、単軸押出機(芝浦機械(株)製、シリンダー設定温度:250℃)、Tダイ(幅300mm、設定温度:250℃)、チルロール(設定温度:120~130℃)および巻取機を備えたフィルム製膜装置を用いて、厚み40μmのポリカーボネート樹脂から構成される透明プラスチックフィルム基材を作製した。
(防眩性フィルム6の調製)
防眩層の形成において、基材として上記で得られたポリカーボネート樹脂から構成される透明プラスチックフィルム基材を使用した以外は、製造例1と同様な方法で本製造例6の防眩性フィルム6を製造した。
(防眩性フィルム7の調製)
防眩層の形成において、基材として透明プラスチックフィルム基材(CPIフィルム、KOLON社製、商品名「C_50_D」、厚さ:50μm)を使用した以外は、製造例1と同様な方法で本製造例7の防眩性フィルム7を製造した。
(防眩性フィルム8の調製)
防眩層の形成において、基材として透明プラスチックフィルム基材(TACフィルム、富士フィルム(株)製、商品名「TD80UL」、厚さ:80μm)を使用した以外は、製造例1と同様な方法で本製造例8の防眩性フィルム8を製造した。
(アクリル系粘着剤組成物1の調製)
〔アクリル系オリゴマーの調製〕
モノマー成分としてメタクリル酸ジシクロペンタニル(DCPMA)60重量部およびメタクリル酸メチル(MMA)40重量部、連鎖移動剤としてα-チオグリセロール3.5重量部、および重合溶媒としてトルエン100重量部を混合し、窒素雰囲気下にて70℃で1時間撹拌した。次に、熱重合開始剤として2,2'-アゾビスイソブチロニトリル(AIBN)0.2重量部を投入し、70℃で2時間反応させた後、80℃に昇温して2時間反応させた。その後、反応液を130℃に加熱して、トルエン、連鎖移動剤および未反応モノマーを乾燥除去して、固形状のアクリル系オリゴマー(アクリル系オリゴマーA)を得た。アクリル系オリゴマーAの重量平均分子量は5100、ガラス転移温度(Tg)は130℃であった。
プレポリマー形成用モノマー成分として、ラウリルアクリレート(LA)60重量部、2-エチルヘキシルアクリレート(2EHA)22重量部、4-ヒドロキシブチルアクリレート(4HBA)8重量部、およびN-ビニル-2-ピロリドン(NVP)10重量部、ならびに光重合開始剤としてBASF製「Omnirad184」0.1重量部、BASF製「Omnirad651」0.1重量部を配合し、紫外線を照射して重合を行い、プレポリマー組成物を得た。上記のプレポリマー組成物100重量部に、後添加成分として、2-エチルヘキシルアクリレート(2EHA)37重量部、1,6-ヘキサンジオールジアクリレート(商品名「A-HD-N」,新中村化学株式会社製)0.08重量部、上記のアクリル系オリゴマーA6重量部、およびシランカップリング剤(信越化学製「KBM403」)0.3重量部を添加した後、これらを均一に混合して、アクリル系粘着剤組成物1を調製した。
(プレポリマーおよびアクリル系粘着剤組成物2の調製)
プレポリマー形成用モノマー成分として、ブチルアクリレート(BA)67重量部、シクロヘキシルアクリレート(大阪有機化学工業社製「ビスコート#155」)14重量部、および4-ヒドロキシブチルアクリレート(4HBA)19重量部、ならびに光重合開始剤としてBASF製「Omnirad184」0.09重量部、BASF製「Omnirad651」0.09重量部を配合し、紫外線を照射して重合を行い、プレポリマー組成物を得た。上記のプレポリマー組成物100重量部に、後添加成分として、ヒドロキシルエチルアクリレート(HEA)9重量部、4-ヒドロキシブチルアクリレート(4HBA)8重量部、ジペンタエリスリトールヘキサアクリレート(DPHA)0.02重量部、光重合開始剤(BASF製「Omnirad651」)0.3重量部、およびシランカップリング剤(信越化学製「KBM403」)0.35重量部を添加した後、これらを均一に混合して、アクリル系粘着剤組成物2を調製した。
(プレポリマーおよびアクリル系粘着剤組成物3の調製)
プレポリマー形成用モノマー成分として、2-エチルヘキシルアクリレート(2EHA)78重量部、ヒドロキシルエチルアクリレート(HEA)4重量部、およびN-ビニル-2-ピロリドン(NVP)18重量部、ならびに光重合開始剤としてBASF製「Omnirad184」0.035重量部、BASF製「Omnirad651」0.035重量部を配合し、紫外線を照射して重合を行い、プレポリマー組成物を得た。上記のプレポリマー組成物100重量部に、後添加成分として、ヒドロキシルエチルアクリレート(HEA)17.6重量部、1,6-ヘキサンジオールジアクリレート(商品名「A-HD-N」,新中村化学株式会社製)0.294重量部、上記のアクリル系オリゴマーA11.8重量部、およびシランカップリング剤(信越化学製「KBM403」)0.35重量部を添加した後、これらを均一に混合して、アクリル系粘着剤組成物3を調製した。
(基材レス粘着剤層1の調製)
表面にシリコーン系離型層が設けられた厚み75μmのポリエチレンテレフタレート(PET)フィルム(三菱ケミカル製「ダイアホイルMRF75」)を基材(兼重剥離フィルム)として、基材の離型層上に上記のアクリル系粘着剤組成物1を厚み25μmになるように塗布して塗布層を形成した。この塗布層上に、カバーシート(兼軽剥離フィルム)として片面がシリコーン剥離処理された厚み75μmのPETフィルム(三菱ケミカル製「ダイアホイルMRE75」)の離型層を貼り合わせた。この積層体に、カバーシート側から、ランプ直下の照射面における照射強度が5mW/cm2になるように位置調節したブラックライトにより、紫外線を照射して光硬化を行い、厚み25μmの基材レス粘着剤層1を得た。
(粘着テープ1の調製)
上記で得られた基材レス粘着剤層1から一方の剥離フィルムを剥離して露出させた粘着面を、製造例1で示した防眩性フィルム1の非防眩層面に貼り付けることにより、防眩性フィルム1/粘着剤層1/剥離フィルムからなる粘着テープ1を得た。
(粘着テープ2の調製)
上記に記載した防眩性フィルム2を使用した以外は、実施例1と同様にして、防眩性フィルム2/粘着剤層1/剥離フィルムからなる粘着テープ2を得た。
(基材レス粘着剤層2の調製)
上記に記載したアクリル系粘着剤組成物2を使用した以外は、実施例1と同様にして、厚み25μmの基材レス粘着剤層2を得た。
(粘着テープ3の調製)
上記で得られた基材レス粘着剤層2を使用した以外は、実施例1と同様にして、防眩性フィルム1/粘着剤層2/剥離フィルムからなる粘着テープ3を得た。
(粘着テープ4の調製)
上記に記載した防眩性フィルム3を使用した以外は、実施例1と同様にして、防眩性フィルム3/粘着剤層1/剥離フィルムからなる粘着テープ4を得た。
(粘着テープ5の調製)
上記に記載した防眩性フィルム4を使用した以外は、実施例1と同様にして、防眩性フィルム4/粘着剤層1/剥離フィルムからなる粘着テープ5を得た。
(粘着テープ6の調製)
上記に記載した防眩性フィルム5を使用した以外は、実施例1と同様にして、防眩性フィルム5/粘着剤層1/剥離フィルムからなる粘着テープ6を得た。
(粘着テープ7の調製)
上記に記載した防眩性フィルム6を使用した以外は、実施例1と同様にして、防眩性フィルム6/粘着剤層1/剥離フィルムからなる粘着テープ7を得た。
(粘着テープ8の調製)
上記に記載した防眩性フィルム7を使用した以外は、実施例1と同様にして、防眩性フィルム7/粘着剤層1/剥離フィルムからなる粘着テープ8を得た。
(粘着テープ9の調製)
上記に記載した防眩性フィルム8を使用した以外は、実施例1と同様にして、防眩性フィルム8/粘着剤層1/剥離フィルムからなる粘着テープ9を得た。
(基材レス粘着剤層3の調製)
上記に記載したアクリル系粘着剤組成物3を使用した以外は、実施例1と同様にして、厚み25μmの基材レス粘着剤層3を得た。
(粘着テープ10の調製)
上記に記載した防眩性フィルム8及び基材レス粘着剤層3を使用した以外は、実施例1と同様にして、防眩フィルム8/粘着剤層3/剥離フィルムからなる粘着テープ10を得た。
上記の実施例及び比較例で得られた粘着テープを用いて、以下の評価を行った。評価方法を以下に示す。結果を表2に示す。
各実施例および各比較例で用意した粘着テープを、MD方向100mm×TD方向100mmの平面視略正方形状に切断し、その4隅のそれぞれにクロスパターンの傷を付けて、試験片を作製した。
加熱前の試験片(25℃)において、傷(クロスパターン中心)のMD方向間の距離(長さ)、および、そのTD方向間の距離(長さ)を、CNC三次元測定機(ミツトヨ社製、「LEGEX774」)を用いて室温(25℃)で測定した。これにより、MD方向およびTD方向のそれぞれにおいて、加熱前の長さを得た。
次いで、試験片を60℃相対湿度90%の環境下に500時間加熱した後、室温(25℃)で1時間放冷した。その後、傷のMD方向間の距離、およびTD方向間の距離を、CNC三次元測定機を測定した。これにより、MD方向およびTD方向のそれぞれにおいて、加熱後の長さを得た。次いで、下記の式により、MD方向およびTD方向のそれぞれにおいて、寸法変化率A1、A2を算出し、その平均値を平均寸法変化率(%)とした。また、TD方向の寸法変化率に対するMD方向の寸法変化率の割合(A1/A2)を求めた。
寸法変化率(%)=[加熱後の長さ(mm)-加熱前の長さ(mm)]/加熱前の長さ(mm)×100
平均寸法変化率(%)=[MD方向の寸法変化率+TD方向の寸法変化率]/2
各実施例および各比較例で用意した粘着テープの剥離フィルムを剥離し、PETフィルム(三菱ケミカル(株)製、商品名「ダイアホイル T100E50」を貼り付け、得られた積層体を100mm×100mmの平面視略正方形状に切断し、試験片を作製した。
次いで、試験片を60℃相対湿度90%の環境下に500時間加熱した後、室温(25℃)で1時間放冷した。その後、カールが凸になっている面が下側になるように水平面上に置き、角の4点の水平面から距離を測定し、水平面から最も長い点の距離を最大カール量(mm)とした。
なお、前記積層体の前記PETフィルム側を下側になるように水平面上に置いて測定した最大カール量を+、前記積層体の前記基材側(前記PETフィルムの反対側)を下側になるように水平面上に置いて測定した最大カール量を-とした。
各実施例および各比較例で得られた粘着テープの粘着面を、黒色のアクリル板に貼り付けて、試験片とした。得られた試験片を、分光光度計U4100(日立ハイテクノロジー社製)へ粘着テープ側を光源側に設置し、5°正反射の可視光領域の反射率(%)を測定した。
各実施例および各比較例で得られた粘着テープを、ヘイズ測定装置(村上色彩研究所製HR-100)を用いて、室温(23℃)にて測定した。繰り返し回数3回測定し、その平均値を測定値とした。
各実施例および比較例で得られた粘着剤層を40mm×40mmのサイズにカットし、片方の面のセパレータを剥がした後、粘着剤面同士が貼り合わせられるように1回折り畳み、片面のセパレータを再度剥がして再び粘着剤面同士を貼り合わせて、約10mm×40mmのサイズ、厚さが約400μmである粘着剤層サンプルを作製した。チャック間距離を20mmに設定した引張試験機に上記粘着剤層サンプルをセットし、引張速度200mm/分で60mm(300%)引っ張った(引張後のチャック間距離は80mm)。60mm引っ張った位置で300秒間固定保持し、その後の応力値を測定し、下記式より「300%引張残存応力値」を算出した。
300%引張残存応力値(N/cm2)=300秒間固定保持後の応力値(N)/(4×粘着シート厚さ(mm)/10)
各実施例および比較例で得られた粘着剤層からセパレータを剥離し、複数の粘着剤層を積層して、厚さ約2mmの試験サンプルを作製した。この試験サンプルを直径7.9mmの円盤状に打ち抜き、パラレルプレートに挟み込み、Rheometric Scientific社製「Advanced Rheometric Expansion System(ARES)」を用いて、以下の条件により、動的粘弾性測定を行い、測定結果から、各温度における貯蔵弾性率G'および損失正接tanδを読み取った。また、tanδが極大となる温度を粘着剤層のガラス転移温度とした。
(測定条件)
変形モード:ねじり
測定周波数:1Hz
測定温度:-70℃~150℃
各実施例および比較例で得られた粘着テープを幅10mm、長さ100mmのサイズにカットし、セパレータを剥離した後、前記粘着テープの粘着剤層の粘着(接着)面積が、1cm2になるように、アクリル樹脂板(アクリライト 三菱ケミカル製)に貼り合わせ、23℃で剥離速度0.06mm/minでせん断方向に引張り、そのときの最大荷重(N/cm2)をせん断力とした。
各実施例および比較例で得られた粘着剤層からセパレータを剥離し、複数の粘着剤層を積層して、厚さ約2mmの試験サンプルを作製し、この試験サンプルを直径7.9mmの円盤状に打ち抜き、試料とした。「歪み量A」、「歪み量B」、「復元率」を求めるためのせん断試験は、図5に示す形態で実施した。具体的には、直径7.9mmのパラレルプレート41及び42を有するRheometric Scientific社製「Advanced Rheometric Expansion System(ARES)」を用いて、パラレルプレート41の上面及びパラレルプレート42の底面を、それぞれ試料の粘着剤層の底面及び上面に位置を合わせて当接した(図5(b))。次に、以下の測定条件により動的粘弾性測定を行い、500Pa、600秒時点(図5(c))の歪み量A、その後0Pa、1800秒保持した時点(図5(d))の歪み量Bを読み取り、下記式により復元率を算出した。
(測定条件)
変形モード:ねじり
測定プログラム:500Pa 、600秒保持した後、0Pa、1800秒保持。
測定温度:60℃
Axial Force:0.2N
復元率:(歪み量A-歪み量B)/歪み量A×100
各実施例および比較例で得られた粘着テープを、TD方向に幅2mm×MD方向に長さ20mmに切断し、Bruker AXS株式会社製 HC-TMA4000SA型を用いて、下記条件により測定を行った。
(測定条件)
変形モード:引張
荷重:2g
保持時間:5時間
昇温速度:5%RH/min
測定雰囲気:60℃相対湿度30%において飽和するまで保持し、60℃相対湿度60%に制御
湿度膨張係数は、Bruker AXS社製 HC-TMA4000SA型を用いて、60℃において湿度を30%RHから60%RHまで変化させた時の各フィルムの伸びを測定することにより求めた(単位:/RH%)。
湿度膨張係数(α)は以下の式により算出した。
α=ΔL/{(T2-T1)×L}
T1:湿度膨張係数を求める低湿度側湿度(%RH)
T2:湿度膨張係数を求める高湿度側湿度(%RH)
ΔL:試験片についてのT1のときの長さとT2のときの長さの差(μm)
L:室温(60℃)での試験片の長さ(μm)
試料を約8mg採取し、アルミニウム製容器に入れ、DSC測定を行った。
装置:TA Instruments製 Q-2000
容器:アルミニウム製容器
温度プログラム:-30℃→300℃
昇温速度:10℃/min
雰囲気ガス:N2(50ml/min)
ガラスに、実施例および比較例で得られた粘着テープを5cm×5cmに切断して4枚隙間なく貼り、60℃相対湿度90%環境下に500時間加熱した後、室温(25℃)で1時間放冷した。その後、バックライト上にガラスを配置し、バックライトの光を照射した際の、粘着テープ間の隙間を目視にて、下記基準で評価した。
○・・・粘着テープ間の隙間は確認されなかった。
×・・・粘着テープ間の隙間が確認された
上記粘着テープ間の隙間確認で使用した、60℃相対湿度90%500時間加熱のサンプルの粘着テープ端部を光学顕微鏡にて確認し、下記基準で評価した。
○・・・粘着テープに剥がれが確認されなかった。
×・・・粘着テープに剥がれが確認された
〔付記1〕第1面および第2面を有する基材と、前記基材の第1面に粘着剤層が積層された積層構造を有する光学用粘着テープであって、
前記光学用粘着テープを60℃相対湿度90%の環境下で500時間加熱したときの幅方向及び機械方向の平均寸法変化率が±0.15%以内であり、
前記粘着剤層の300%引張残存応力値が10N/cm2以下であることを特徴とする光学用粘着テープ。
〔付記2〕前記光学用粘着テープを60℃相対湿度90%の環境下で500時間加熱したときの幅方向及び機械方向の平均寸法変化率をC[%]とし、
前記光学用粘着テープの前記粘着剤層を厚み50μmのPETフィルムに貼り合わせた後に10cm四方に切断した積層体を60℃相対湿度90%の環境下で500時間加熱したときの下記の最大カール量をD[mm]としたときに、下記式を満たす、付記1に記載の光学用粘着テープ。
|C×D|≦3
・最大カール量:前記積層体のカールの凸になっている面が下側になるように水平面上に置いて、4隅の反りのうち最も高いものを最大カール量D[mm]とする。前記積層体の前記PETフィルム側を下側になるように水平面上に置いて測定した最大カール量を+、前記積層体の前記基材側を下側になるように水平面上に置いて測定した最大カール量を-とする。
〔付記3〕前記基材のガラス転移点(Tg)が60℃以上である、付記1又は2に記載の光学用粘着テープ。
〔付記4〕前記粘着剤層のガラス転移点(Tg)が-10℃以下である、付記1~3のいずれか1つ2に記載の光学用粘着テープ。
〔付記5〕前記光学用粘着テープを60℃相対湿度30%から60℃相対湿度60%へ加湿したときの湿度膨張率が0.1%以下である、付記1~4のいずれか1つに記載の光学用粘着テープ。
〔付記6〕前記基材の湿度膨張係数が5×10-5/%RH以下である、付記1~5のいずれか1つに記載の光学用粘着テープ。
〔付記7〕前記基材の第2面は、反射防止処理及び/又はアンチグレア処理されている、付記1~6のいずれか1つに記載の光学用粘着テープ。
〔付記8〕前記粘着剤層がアクリル系ポリマーを含むアクリル系粘着剤層である、付記1~7のいずれか1つに記載の光学用粘着テープ。
〔付記9〕付記1~8いずれか1つに記載の光学用粘着テープと、画像表示パネルとが積層された画像表示装置。
〔付記10〕付記9に記載の画像表示装置を複数枚並べたタイリングディスプレイ。
1 基材
1a 基材の第1面
1b 基材の第2面
2 粘着剤層
3 反射防止処理及び/又はアンチグレア処理
20 画像表示装置
4 画像表示パネル
30 タイリングディスプレイ
31 支持基板
40 粘着剤層
41、42 パラレルプレート
Claims (10)
- 第1面および第2面を有する基材と、前記基材の第1面に粘着剤層が積層された積層構造を有する光学用粘着テープであって、
前記光学用粘着テープを60℃相対湿度90%の環境下で500時間加熱したときの幅方向及び機械方向の平均寸法変化率が±0.15%以内であり、
前記粘着剤層の300%引張残存応力値が10N/cm2以下であることを特徴とする光学用粘着テープ。 - 前記光学用粘着テープを60℃相対湿度90%の環境下で500時間加熱したときの幅方向及び機械方向の平均寸法変化率をC[%]とし、
前記光学用粘着テープの前記粘着剤層を厚み50μmのPETフィルムに貼り合わせた後に10cm四方に切断した積層体を60℃相対湿度90%の環境下で500時間加熱したときの下記の最大カール量をD[mm]としたときに、下記式を満たす、請求項1に記載の光学用粘着テープ。
|C×D|≦3
・最大カール量:前記積層体のカールの凸になっている面が下側になるように水平面上に置いて、4隅の反りのうち最も高いものを最大カール量D[mm]とする。前記積層体の前記PETフィルム側を下側になるように水平面上に置いて測定した最大カール量を+、前記積層体の前記基材側を下側になるように水平面上に置いて測定した最大カール量を-とする。 - 前記基材のガラス転移点(Tg)が60℃以上である、請求項1又は2に記載の光学用粘着テープ。
- 前記粘着剤層のガラス転移点(Tg)が-10℃以下である、請求項1~3のいずれか1項に記載の光学用粘着テープ。
- 前記光学用粘着テープを60℃相対湿度30%から60℃相対湿度60%へ加湿したときの湿度膨張率が0.1%以下である、請求項1~4のいずれか1項に記載の光学用粘着テープ。
- 前記基材の湿度膨張係数が5×10-5/%RH以下である、請求項1~5のいずれか1項に記載の光学用粘着テープ。
- 前記基材の第2面は、反射防止処理及び/又はアンチグレア処理されている、請求項1~6のいずれか1項に記載の光学用粘着テープ。
- 前記粘着剤層がアクリル系ポリマーを含むアクリル系粘着剤層である、請求項1~7のいずれか1項に記載の光学用粘着テープ。
- 請求項1~8いずれか1項に記載の光学用粘着テープと、画像表示パネルとが積層された画像表示装置。
- 請求項9に記載の画像表示装置を複数枚並べたタイリングディスプレイ。
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WO2011111576A1 (ja) * | 2010-03-10 | 2011-09-15 | 日東電工株式会社 | 光学用粘着シート |
JP2012040709A (ja) * | 2010-08-17 | 2012-03-01 | Mitsubishi Paper Mills Ltd | 易接着フィルムおよびこれを用いた積層体 |
JP2013159704A (ja) * | 2012-02-06 | 2013-08-19 | Nitto Denko Corp | アクリル系粘着テープ |
JP2017197622A (ja) * | 2016-04-26 | 2017-11-02 | 王子ホールディングス株式会社 | 加飾層付き両面粘着シート及び積層体 |
WO2020145188A1 (ja) * | 2019-01-08 | 2020-07-16 | 日東電工株式会社 | 粘着シート |
JP2020143242A (ja) * | 2019-03-08 | 2020-09-10 | 日東電工株式会社 | 粘着剤層及び粘着シート |
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WO2011111576A1 (ja) * | 2010-03-10 | 2011-09-15 | 日東電工株式会社 | 光学用粘着シート |
JP2012040709A (ja) * | 2010-08-17 | 2012-03-01 | Mitsubishi Paper Mills Ltd | 易接着フィルムおよびこれを用いた積層体 |
JP2013159704A (ja) * | 2012-02-06 | 2013-08-19 | Nitto Denko Corp | アクリル系粘着テープ |
JP2017197622A (ja) * | 2016-04-26 | 2017-11-02 | 王子ホールディングス株式会社 | 加飾層付き両面粘着シート及び積層体 |
WO2020145188A1 (ja) * | 2019-01-08 | 2020-07-16 | 日東電工株式会社 | 粘着シート |
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