WO2022149547A1 - Produit de nettoyage - Google Patents

Produit de nettoyage Download PDF

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Publication number
WO2022149547A1
WO2022149547A1 PCT/JP2021/048830 JP2021048830W WO2022149547A1 WO 2022149547 A1 WO2022149547 A1 WO 2022149547A1 JP 2021048830 W JP2021048830 W JP 2021048830W WO 2022149547 A1 WO2022149547 A1 WO 2022149547A1
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WO
WIPO (PCT)
Prior art keywords
cleaning agent
component
mass
agent according
formula
Prior art date
Application number
PCT/JP2021/048830
Other languages
English (en)
Japanese (ja)
Inventor
龍太郎 寺岡
哲郎 岩屋
朋子 中林
Original Assignee
旭化成アドバンス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 旭化成アドバンス株式会社 filed Critical 旭化成アドバンス株式会社
Priority to JP2022574039A priority Critical patent/JPWO2022149547A1/ja
Publication of WO2022149547A1 publication Critical patent/WO2022149547A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers

Definitions

  • the present invention relates to a cleaning agent.
  • Patent Document 1 describes a polyoxyalkylene ether-based non-polyoxyalkylene ether type having a hydrophilic group consisting of a polyoxyethylene residue and an oxypropylene residue for the purpose of providing a cosmetic for body cleaning that does not leave a sticky feeling after use.
  • Cosmetics for body cleaning which are characterized by containing an ionic surfactant and scrub particles of a synthetic polymer.
  • Patent Document 2 describes a copolymer of (meth) acrylic acid and (meth) acrylic acid ester and biodegradable polishing for the purpose of reducing the slimy feeling at the time of washing and improving the rinsing property.
  • body cleansers containing materials and polyoxyethylene polyoxypropylene propyl heptyl ethers.
  • Patent Document 3 has an inorganic value of 350 or more and 500 or less and an organic value of 350 or more and an organic value for the purpose of providing a body detergent having excellent detergency of stains derived from engine oil and cutting oil. It contains a polyoxyethylene polyoxypropylene propyl heptyl ether-based nonionic surfactant having an average number of moles of oxypropylene residues of 400 or more and 550 or less and an average number of moles of oxypropylene residues of 2.5 or less, and a polishing material. Body cleansers are disclosed.
  • Japanese Unexamined Patent Publication No. 2006-16402 Japanese Unexamined Patent Publication No. 2012-233128 Japanese Unexamined Patent Publication No. 2019-189820
  • an object of the present invention is to provide a cleaning agent having excellent detergency and a small change in viscosity even when the temperature changes.
  • the present invention includes the following embodiments.
  • Component A Nonionic surfactant (excluding component B below), Ingredient B: Polyoxyethylene polyoxypropylene glycol, Component C: Abrasive, and Component D: Thickener, Including cleaning agents.
  • Component B Nonionic surfactant (excluding component B below)
  • Ingredient B Polyoxyethylene polyoxypropylene glycol
  • Component C Abrasive
  • Component D Thickener
  • Including cleaning agents Including cleaning agents.
  • the component A has a hydrophobic portion and has a hydrophobic portion.
  • the polyoxyalkylene alkyl ether-based nonionic surfactant is the formula (1) or the formula (2): (R) -O- (PO) x- (EO) y -H ... (1) (R) -O- (EO) y- (PO) x -H ...
  • R is an alkyl group PO is an oxypropylene group and EO is an oxyethylene group x and y are independently positive integers
  • the cleaning agent according to [7], wherein the alkyl group having R of the formula (1) or the formula (2) is a linear alkyl group.
  • the component B is the formula (3) :.
  • ⁇ Cleaning agent> relates to a cleaning agent containing the following components A to D.
  • Component A Nonionic surfactant (excluding component B below)
  • Component B Polyoxyethylene Polyoxypropylene glycol
  • Component C Abrasive Material
  • Component D Thickener
  • the detergency can be improved and the temperature-dependent viscosity change can be suppressed.
  • the viscosity of the cleaning agent changes depending on the temperature, for example, when the viscosity becomes high, there arises a problem that the cleaning agent is difficult to be discharged from the container.
  • the viscosity is low, the fluidity of the cleaning agent is increased and it becomes difficult to hold the cleaning agent in the soiled portion, and as a result, there arises a problem that cleaning cannot be performed well. Since the cleaning agent according to the present embodiment suppresses the temperature-dependent viscosity change, such a problem can be avoided.
  • the rate of change in viscosity at 30 ° C. to 50 ° C. with respect to the viscosity at 25 ° C. is preferably in the range of 0.2 to 2.0, preferably 0.6 to 1.5. It is more preferably in the range of 0.9 to 1.2, and particularly preferably in the range of 0.9 to 1.2. Within this range, the change in viscosity is small under the temperature conditions normally used, and excellent handleability and detergency can be obtained.
  • the rate of change is the rate of change from the viscosity at 25 ° C (viscosity at a specific temperature / 25) with respect to the viscosity at 30 ° C to 50 ° C by measuring the viscosity between 25 ° C and 50 ° C in 5 ° C increments. It is determined by calculating the viscosity at ° C.), and the rate of change at all measured temperatures may be within the above range.
  • the cleaning agent according to the present embodiment preferably has a viscosity at 25 ° C. of 3,000 mPa ⁇ s to 16,000 mPa ⁇ s, and more preferably 5,000 mPa ⁇ s to 13,000 mPa ⁇ s. , 7,000 mPa ⁇ s to 11,000 mPa ⁇ s is more preferable.
  • a viscosity at 25 ° C. 3,000 mPa ⁇ s to 16,000 mPa ⁇ s, and more preferably 5,000 mPa ⁇ s to 13,000 mPa ⁇ s. , 7,000 mPa ⁇ s to 11,000 mPa ⁇ s is more preferable.
  • the cleaning agent according to the present embodiment contains component A (nonionic surfactant (however, component B is excluded)).
  • component A nonionic surfactant (however, component B is excluded)
  • component B polyoxyethylene polyoxypropylene glycol
  • Component A preferably has a polyoxyethylene group.
  • the component A preferably has a polyoxypropylene group.
  • the component A more preferably has a polyoxyethylene group and a polyoxypropylene group.
  • the component A preferably has a hydrophobic portion, and the number of carbon atoms in the hydrophobic portion is preferably 8 to 18, more preferably 8 to 14, and particularly preferably 8 or 10.
  • the component A is preferably a polyoxyalkylene alkyl ether-based nonionic surfactant (hereinafter, also referred to as "surfactant a").
  • the surfactant a preferably has a polyoxyethylene group.
  • the surfactant a preferably has a polyoxypropylene group. It is more preferable that the surfactant a has a polyoxyethylene group and a polyoxypropylene group.
  • the average number of moles of oxyethylene groups added to the surfactant a is preferably 1 to 10, more preferably 2 to 8, further preferably 2 to 6, and 2 to 4. Is particularly preferable.
  • the average number of moles of the oxypropylene group added to the surfactant a is preferably 1 to 10, more preferably 2 to 8, further preferably 2 to 6, and 2 to 4. Is particularly preferable.
  • the alkyl group of R is preferably a linear alkyl group.
  • the number of carbon atoms of the alkyl group of R is preferably 8 to 18, more preferably 8 to 14, and particularly preferably 8 or 10.
  • the cleaning agent according to this embodiment contains component B (polyoxyethylene polyoxypropylene glycol).
  • component B polyoxyethylene polyoxypropylene glycol
  • m is preferably a positive integer having an average molecular weight of the polyoxypropylene group of 1000 to 3000, and is a positive integer having an average molecular weight of the polyoxypropylene group of 1200 to 2500. Is more preferable, and it is further preferable that the average molecular weight of the polyoxypropylene group is a positive integer of 1500 to 1900.
  • the average molecular weight of the polyoxypropylene group can be measured by MALDI-TOF / MS.
  • n and l are preferably positive integers in which the total content of ethylene oxide is 1% by mass to 30% by mass, and the total content of ethylene oxide is 4% by mass to 20% by mass. It is more preferable that it is a positive integer such that the total content of ethylene oxide is 7% by mass to 15% by mass, and it is further preferable that it is a positive integer.
  • the total content of ethylene oxide can be measured by MALDI-TOF / MS.
  • the total content of the component A and the component B is preferably 1% by mass to 20% by mass, more preferably 1% by mass to 10% by mass, and 3% by mass or more, based on the mass of the cleaning agent. It is more preferably 9% by mass, and particularly preferably 5% by mass to 8% by mass. Further, in order to maintain an appropriate viscosity at 40 to 50 ° C. in the general operating temperature range of the cleaning agent, the content of the component B is 2.5% by mass or less based on the mass of the cleaning agent. It is preferably in the range of 1.0% by mass to 2.5% by mass, and more preferably in the range of 1.0% by mass to 2.5% by mass.
  • a special effect has been found by setting the blending balance of the component A and the component B within a specific range.
  • the content of the component A is preferably 50% by mass to 94% by mass, more preferably 60% by mass to 92% by mass, and 70% by mass or more, based on the total mass of the component A and the component B. It is more preferably 90% by mass. Within such a range, the degree of temperature-dependent change in the obtained detergent viscosity can be reduced, which is useful.
  • the content of the component B is preferably 6% by mass to 50% by mass, more preferably 8% by mass to 40% by mass, and 10% by mass or more, based on the total mass of the component A and the component B. It is more preferably 30% by mass.
  • the cleaning agent of the present embodiment may further contain a surfactant other than the component A and the component B as long as the effect is not adversely affected.
  • a surfactant include, for example, cationic surfactants, amphoteric surfactants, and anionic surfactants.
  • cationic surfactant examples include alkyltrimethylammonium chloride, alkyldimethylbenzylammonium chloride, dialkyldimethylammonium chloride, alkyltrimethylammonium bromide, alkylpentaethoxyammonium chloride, lanolin fatty acid ethyl sulfate aminopropylethyldimethylammonium, and cationization.
  • Amido-based surfactants such as cellulose; amide-based surfactants such as acyldiethylaminoethylamide, acyldimethylaminopropylamide, and polyoxyethylene fatty acid amide; myristyldimethylamine oxide and the like can be mentioned.
  • amphoteric surfactant examples include betaine-based surfactants such as alkyldimethylaminoacetic acid betaine and acylamide propyldimethylaminoacetic acid betaine having 13 or more carbon atoms in the fatty acid residue; N-alkyl-N-carboxymethyl.
  • -Imidazolinium-based surfactants such as N-hydroxyethyl imidazolinium betaine, N-alkyl-N-carboxymethyl-N-hydroxyethylethylenediamine-lauryl sulfate and salts thereof; glycine-based surfactants such as polyoctylpolyaminoethylglycine.
  • Activators Aminopropionic acid-based surfactants such as alkylaminopropionic acid and alkylaminodipropionic acid can be mentioned.
  • anionic surfactant examples include sodium soaps having 17 or less carbon atoms; acylsarcosins having 17 or less carbon atoms in fatty acid residues and salts thereof, acyl amino acids and salts thereof, acylated peptides and salts thereof, and the like.
  • polyoxyalkylene additives such as polyoxyethylene alkyl ether carboxylic acid and its salts, polyoxyethylene alkyl ether sulfuric acid and its salts, polyoxyethylene alkyl ether sulfonic acid and its salts; alkyl phosphate and its potassium Phosphoric acid-based surfactants such as salts, alkanolamine salts, polyoxyethylene alkyl ether phosphates and their salts; sulfosuccinic acid-based surfactants such as dialkyl sulfosuccinates and their salts, polyoxyethylene sulfosuccinate alkyl ethers and their salts Alkylphenol-based surfactants such as alkylphenol ether phosphate esters and salts thereof; Sodium laureth sulfate and the like can be mentioned.
  • the content of the other surfactant is preferably 0% by mass to 15% by mass, more preferably 0% by mass to 10% by mass, and 0% by mass to 5% by mass, based on the mass of the detergent. It is more preferably by mass%.
  • the cleaning agent according to this embodiment contains a component C (abrasive material).
  • Abrasives are also called scrubbing materials. By using the abrasive, the detergency is enhanced by the physical friction effect, and dirt can be adsorbed on the particle surface.
  • the abrasive is not particularly limited, and conventionally known abrasives can be appropriately selected and used.
  • the polishing material for example, inorganic particles such as porous silica particles, crystalline cellulose particles, cellulose acetate particles, cellulose particles such as chitosan / cellulose / starch mixture particles, walnut shell particles, corn cochlear particles, and apricots.
  • Nuclear particles polyhydroxybutyrate particles, poly (hydroxybutyrate / hydroxyhexanoate) particles, esterified starch particles, cellulose, cellulose acetate particles, chitosan / cellulose / starch mixture particles, polybutylene succinate particles, polybutylene succin Nate adipate particles, polylactic acid particles, polyethylene succinate particles, polycaprolactone resin particles, polyglycolic acid particles, polytetramethylene adipate co-terephthalate particles, polybutylene adipate terephthalate particles, polybutylene succinate co-adipate co -Telephthalate particles, polybutylene succinate carbonate particles, polybutylene succinate terephthalate particles, polyethylene particles and the like can be mentioned.
  • the abrasive one kind may be used alone, or two or more kinds may be used in combination.
  • the cleaning agent according to the present embodiment may or may not contain silicic acid anhydride.
  • the abrasive is preferably biodegradable particles. Since the particles are biodegradable, they are excellent in degradability when released into the environment and tend to have higher environmental aptitude.
  • Biodegradable particles include, for example, walnut shell particles, corn cochlear particles, apricot nuclei particles, polyhydroxybutyrate particles, poly (hydroxybutyrate / hydroxyhexanoate) particles, esterified starch particles, cellulose, and the like.
  • Examples thereof include co-terephthalate particles, polybutylene adipate terephthalate particles, polybutylene succinate co-adipate co-terephthalate particles, polybutylene succinate carbonate particles, and polybutylene succinate terephthalate particles.
  • the average particle size of the abrasive is preferably 1 ⁇ m to 700 ⁇ m, more preferably 50 ⁇ m to 400 ⁇ m, and even more preferably 100 ⁇ m to 300 ⁇ m.
  • the average particle size can be measured by a dry particle size distribution meter (robot shifter RPS-105M manufactured by Seishin Corporation, etc.) in accordance with JIS Z8801.
  • the content of the abrasive is preferably 1% by mass to 20% by mass, more preferably 2% by mass to 7% by mass, and 3% by mass to 5% by mass based on the mass of the cleaning agent. It is more preferable to have.
  • the content of the abrasive is 1% by mass or more, the detergency tends to be further improved. Further, when the content of the abrasive is 20% by mass or less, physical irritation when used on the body can be suppressed.
  • the cleaning agent according to this embodiment contains a component D (thickener).
  • a component D thickener
  • examples of the thickener include synthetic polymers and natural polymers.
  • Examples of the synthetic polymer include carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, polyvinyl alcohol, polyvinylpyrrolidone, carboxyalkyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose hydroxypropyltrimethylammonium chloride ether, methyl cellulose, ethyl cellulose and hydroxypropyl.
  • Cellulose Methyl hydroxypropyl cellulose, Arginate propylene glycol ester, methoxyethylene maleic anhydride copolymer, Polydimethylmethylene piperidinium, Polyacetic acid vinyl, Polyvinyl alcohol, Polyvinylpyrrolidone, Polyvinylmethyl ether, Nitrocellulose, Polyethylene glycol fatty acid ester , Polyoxyethylene fatty acid ester such as polyethylene glycol distearate, polyoxyethylene fatty acid ester methylglycoside such as polyoxyethylene dioleic acid methyl glucoside and the like.
  • natural polymers include starch, soluble starch, carboxymethyl starch, methyl starch, cellulose, gelatin, Arabic gum, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan, galactan, pectin, mannan, dextran, and succinoglucan. , Curdlan, casein, albumin, collagen and the like.
  • the content of the thickener is preferably 0.1% by mass to 5.0% by mass, more preferably 0.15% by mass to 1.0% by mass, based on the mass of the cleaning agent. , 0.2% by mass to 0.5% by mass, more preferably.
  • the stability of the cleaning agent for example, suppression of separation and prevention of sedimentation of the abrasive
  • the cleaning agent can be easily taken out of the container.
  • the cleaning agent according to the present embodiment may further contain other optional components in addition to the components A to D.
  • the optional component include a pH adjuster, a moisturizer, a solvent and the like. Water is preferable as the solvent.
  • the pH adjuster is not particularly limited as long as it is usually used for cleaning agents, but for example, inorganic substances such as sodium hydroxide, potassium hydroxide and aqueous ammonia; trimethylamine, diethanolamine, diethylamine, triethanolamine and the like. Examples include organic amines.
  • the content of the pH adjuster is preferably 0.1 to 20% by mass, more preferably 0.15 to 5.0% by mass, and 0.2 to 3% based on the mass of the cleaning agent. It is more preferably 0.0% by mass.
  • the moisturizer is not particularly limited as long as it is usually used for cleaning agents, and for example, trimethylglycine, glycerin, hyaluronic acid, urea, uric acid, ammonia, lecithin, lanolin, squalane, squalane, glucosamine, creatinine, etc. Nucleic acid-related substances such as DNA and RNA can be mentioned.
  • the content of the moisturizer is preferably 0.01 to 20% by mass, more preferably 0.03 to 10% by mass, and 0.05 to 5% by mass based on the mass of the cleaning agent. It is more preferable to have.
  • the cleaning agent according to this embodiment is preferably used on the body.
  • the part of the body is not particularly limited, but it is preferable to use it on the hand.
  • the cleaning agent according to this embodiment is preferably used for cleaning oil stains.
  • the type of oil stain is not particularly limited, and examples thereof include stains caused by engine oil, grease, cutting oil, and the like.
  • Two white artificial leathers (Royal Leatherna color: white) were prepared, one of which was coated with the above model stain (artificial leather A) and the other of which was coated with a cleaning agent (artificial leather B).
  • Artificial leathers A and B were rubbed together under the conditions of a test load of 9 kPa and 50 seconds using a Martindale wear tester (JAMES H.HEAL & CO.LTD.HALIMAX ENGLAND). Then, the surface of the artificial leather A was not rubbed and was allowed to flow under running water for 10 seconds. Finally, the residual stains on the artificial leather A were confirmed using the image analysis software "Scion”.
  • the residual black color derived from the model stains on the white artificial leather was quantified in the order of brightness from 0 (low detergency) to 255 (high detergency), and the detergency was evaluated.
  • the brightness was calculated as the average value of the entire surface of artificial leather.
  • the evaluation criteria are as follows. [Evaluation criteria] A: Brightness is 200 or more and 255 or less B: Brightness is 100 or more and less than 200 C: Brightness is 0 or more and less than 100
  • Viscosity change rate Put 50 ml of the cleaning agent in a beaker, adjust the temperature to 25 ° C, 30 ° C, 35 ° C, 40 ° C, 45 ° C and 50 ° C in a constant temperature bath, and measure the viscosity at each temperature with the RVDV-I prime B type viscometer. (Manufactured by Blockfield) was used, and spindle No. 5 was used for measurement at 20 rpm.
  • Viscosity change rate is 0.9 or more and 1.2 or less
  • B Viscosity change rate is 0.6 or more and 0.9 or less, or 1.2 or more and 1.5 or less
  • C Viscosity change rate is 0.2 or more and 0. 6 or less, or 1.5 or more and 2.0 or less
  • D Viscosity change rate is less than 0.2 or 2.0 or more

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention aborde le problème de l'obtention d'un agent de nettoyage qui présente d'excellentes performances de nettoyage et peu de changement de viscosité malgré les changements de température. Ce problème peut être résolu par un agent de nettoyage comprenant : le composant A, un tensioactif non ionique (autre que le composant B) ; le composant B, un polyoxyéthylène-polyoxypropylène glycol ; le composant C, un abrasif ; et le composant D, un épaississant.
PCT/JP2021/048830 2021-01-07 2021-12-28 Produit de nettoyage WO2022149547A1 (fr)

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Application Number Priority Date Filing Date Title
JP2022574039A JPWO2022149547A1 (fr) 2021-01-07 2021-12-28

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JP2021-001361 2021-01-07
JP2021001361 2021-01-07

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WO2022149547A1 true WO2022149547A1 (fr) 2022-07-14

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH101694A (ja) * 1996-04-15 1998-01-06 Lion Corp 濃厚液体洗浄剤組成物
JP2006188435A (ja) * 2004-12-28 2006-07-20 Mandom Corp 皮膚洗浄剤組成物
JP2012233057A (ja) * 2011-04-28 2012-11-29 Suzuki Yushi Kogyo Kk 生分解性スクラブ剤及び皮膚洗浄剤
JP2016084285A (ja) * 2014-10-22 2016-05-19 旭化成ケミカルズ株式会社 洗浄剤組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH101694A (ja) * 1996-04-15 1998-01-06 Lion Corp 濃厚液体洗浄剤組成物
JP2006188435A (ja) * 2004-12-28 2006-07-20 Mandom Corp 皮膚洗浄剤組成物
JP2012233057A (ja) * 2011-04-28 2012-11-29 Suzuki Yushi Kogyo Kk 生分解性スクラブ剤及び皮膚洗浄剤
JP2016084285A (ja) * 2014-10-22 2016-05-19 旭化成ケミカルズ株式会社 洗浄剤組成物

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