WO2022142100A1 - Laser opposing emission welding apparatus and method - Google Patents

Laser opposing emission welding apparatus and method Download PDF

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Publication number
WO2022142100A1
WO2022142100A1 PCT/CN2021/096098 CN2021096098W WO2022142100A1 WO 2022142100 A1 WO2022142100 A1 WO 2022142100A1 CN 2021096098 W CN2021096098 W CN 2021096098W WO 2022142100 A1 WO2022142100 A1 WO 2022142100A1
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WO
WIPO (PCT)
Prior art keywords
glass
pulsed laser
laser
focusing mirror
incident
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PCT/CN2021/096098
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French (fr)
Chinese (zh)
Inventor
王雪辉
陈航
王建刚
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武汉华工激光工程有限责任公司
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Publication of WO2022142100A1 publication Critical patent/WO2022142100A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20Bonding
    • B23K26/32Bonding taking account of the properties of the material involved
    • B23K26/324Bonding taking account of the properties of the material involved involving non-metallic parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/064Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/50Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
    • B23K2103/54Glass

Definitions

  • the present application relates to the technical field of laser welding, and in particular, to a laser butt beam welding device and method.
  • Laser welding technology is a new type of connection technology that uses a high-energy-density laser beam as a heat source. It has the advantages of selective welding, non-contact, and high efficiency, so it has been widely used and developed rapidly in engineering.
  • the purpose of this application is to provide a laser butt beam welding device and method, which can directly weld two glass materials without introducing opaque materials, has low requirements on the glass surface to be welded, and does not affect the transparency of the product after welding. Optical performance to improve welding quality and efficiency.
  • the present application provides a laser butt beam welding device, which includes a laser generator, a first focusing mirror, a second focusing mirror and a sample stage; the laser generator is configured to generate pulsed laser light, and the sample stage It is configured to place a first glass and a second glass, and the first glass and the second glass are stacked with a gap; the first focusing mirror is arranged between the laser generator and the first glass. During the time, the first focusing mirror is configured to inject the pulsed laser generated by the laser generator as the first pulsed laser from the side of the first glass away from the second glass to the first glass and the second glass.
  • the first pulsed laser is configured to generate plasma on the side of the second glass close to the first glass and melt the second glass to weld the first glass glass and the second glass;
  • the second focusing mirror is arranged between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as the first Two pulsed lasers are incident from the side of the second glass away from the first glass to the gap between the first glass and the second glass;
  • the second pulsed laser is configured to A side of the glass close to the second glass generates plasma and melts the first glass to weld the first glass and the second glass.
  • the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
  • the laser butt beam welding device also includes a polarization beam splitter, the polarization beam splitter is arranged between the laser generator and the sample stage, and the polarization beam splitter is configured to
  • the pulsed laser generated by the laser generator is divided into the first pulsed laser and the second pulsed laser, and the first pulsed laser is configured to be incident from the first glass after passing through the first focusing mirror,
  • the second pulsed laser light is configured to be incident from the second glass after passing through the second focusing mirror.
  • the laser generator includes a first generator and a second generator
  • the first generator is configured to generate the first pulsed laser
  • the A second generator is configured to generate the second pulsed laser light
  • the first pulsed laser light is configured to be incident from the first glass after passing through the first focusing mirror
  • the second pulsed laser light is configured to pass through the first focusing mirror After two focusing mirrors are incident from the second glass.
  • the laser butt-beam welding device also includes a beam expander collimator for adjusting the beam diameter and divergence angle of the pulsed laser generated by the laser generator, and the beam expander collimator is provided on the downstream of the propagation direction of the pulsed laser light of the laser generator.
  • the laser butt beam welding device further includes a first light guide mirror and a second light guide mirror, the first light guide mirror is arranged at a position of the first focusing mirror away from the first glass.
  • the second light guide mirror is arranged on the side of the second focusing mirror away from the second glass.
  • the laser butt beam welding device also includes an industrial computer and a displacement stage, the displacement stage is connected to the sample stage, and the industrial computer is respectively connected to the laser generator and the displacement stage. , to control the laser generator and the stage.
  • a fixing fixture is provided on the sample stage, and the fixing fixture fixes the first glass and the second glass.
  • the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light path from the second focusing mirror to the second glass is parallel or intersecting with the extension line.
  • the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the second glass on the side of the first glass
  • the second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the first glass on the side of the second glass.
  • the present application provides a laser butt beam welding device, comprising a laser generator, a first focusing mirror, a second focusing mirror and a sample stage;
  • the laser generator is configured to generate pulsed laser light
  • the sample stage is configured to A first glass and a second glass are placed, and the first glass and the second glass are stacked with a gap;
  • the first focusing mirror is arranged between the laser generator and the first glass,
  • the first focusing mirror is configured to inject the pulsed laser light generated by the laser generator into the first glass and the second glass from the side of the first glass away from the second glass as the first pulsed laser light at a gap between glasses;
  • the first pulsed laser is configured to generate plasma on a side of the first glass close to the second glass and melt the first glass to weld the first glass and the second glass the second glass;
  • the second focusing mirror is arranged between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as the second pulse
  • the laser is incident
  • the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
  • the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light path from the second focusing mirror to the second glass is parallel or intersecting with the extension line.
  • the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the first glass on the side of the second glass
  • the second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the second glass on the side of the first glass.
  • the gap between the first glass and the second glass is 5 ⁇ m or less.
  • the wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is less than 12 ps, and the repetition rate is more than 1 kHz.
  • the present application provides a laser butt beam welding method, configured to realize welding of a first glass and a second glass, the first glass and the second glass being stacked with a gap;
  • the laser beam beam welding method includes: incident a first pulsed laser light from a side of the first glass away from the second glass, and the first pulsed laser light is focused on a gap between the first glass and the second glass; the first pulsed laser is configured to generate plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass; and A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass.
  • the first pulsed laser light in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The two incident light paths are located on the same straight line.
  • the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The parallel or extension lines of the two incident light paths intersect.
  • the first pulsed laser is focused on the surface or inside of the second glass on the side of the first glass
  • the second pulsed laser is focused on the second glass.
  • the present application provides a laser butt-beam welding method configured to realize welding of a first glass and a second glass, the first glass and the second glass being stacked with a gap;
  • the laser beam-beam welding method includes: incident a first pulsed laser light from a side of the first glass away from the second glass, and the first pulsed laser light is focused on a gap between the first glass and the second glass; the first pulsed laser is configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass; and A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass.
  • the first pulsed laser light in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The two incident light paths are located on the same straight line.
  • the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The parallel or extension lines of the two incident light paths intersect.
  • the gap between the first glass and the second glass is 5 ⁇ m or less.
  • the wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is less than 12 ps, and the repetition rate is more than 1 kHz.
  • FIG. 1 is a schematic diagram of a welding principle of a laser butt beam welding method provided by an embodiment of the present application
  • FIG. 2 is a schematic diagram of a welding principle of a laser butt beam welding method provided by an embodiment of the present application
  • 3A and 3B are schematic diagrams of the welding principle of the laser butt beam welding method provided by the embodiment of the application;
  • FIG. 4 is a schematic structural diagram of a laser butt beam welding device provided by an embodiment of the present application.
  • FIG. 5 is a schematic structural diagram of a laser butt beam welding device provided by an embodiment of the present application.
  • the traditional laser welding method needs to introduce an opaque material between the two glasses before welding.
  • This welding method will reduce the light transmission performance of the welded product, and the introduced dissimilar materials may be due to differences in thermal expansion coefficients. It will cause the weld to be affected by thermal stress, which will lead to the failure of the weld, and it is difficult to ensure the welding quality.
  • the embodiment of the present application provides a laser butt beam welding device, which can directly weld two glass materials or two transparent materials, without disposing an opaque material between the two glasses, and the welding efficiency is high. And the requirements for the glass welding surface are low, the light transmission performance of the product is not affected after welding, the welding quality can be improved, and the welding of the two glasses can also be realized when there is a large gap between them, which can meet the welding requirements. Reliable requirements, good shear strength, and good sealing performance of welded products, a wide range of applications.
  • this embodiment provides a laser butt beam welding device, including a laser generator 6 , a first focusing mirror 15 , a second focusing mirror 18 , a sample stage, a displacement stage not shown, and an industrial computer.
  • the laser generator 6 is configured to generate pulsed laser light as the first pulsed laser light 2 and the second pulsed laser light 3
  • the sample stage is configured to place the first glass 4 and the second glass 5 with a gap between the first glass 4 and the second glass 5. Cascading settings.
  • the first focusing mirror 15 is arranged between the laser generator 6 and the first glass 4 , and the first focusing mirror 15 is configured so that the first pulsed laser 2 is incident on the first glass from the side of the first glass 4 away from the second glass 5 .
  • the convergence point of the first pulsed laser 2 incident from the first glass 4 can be located at the gap, on the first glass 4, or on the second glass 5
  • the first pulsed laser 2 is configured to generate plasma on the side of the first glass 4 close to the second glass 5 to melt the first glass 4, or to generate plasma on the side of the second glass 5 close to the first glass 4 to The second glass 5 is melted to weld the first glass 4 and the second glass 5 .
  • the second focusing mirror 18 is provided between the laser generator 6 and the second glass 5 , and the second focusing mirror 18 is configured so that the second pulsed laser 3 is incident on the first glass from the side of the second glass 5 away from the first glass 4 At the gap between 4 and the second glass 5, the convergence point of the second pulsed laser 3 incident from the second glass 5 can be located at the gap, on the first glass 4, or on the second glass 5
  • the second pulsed laser 3 is configured to generate plasma on the side of the first glass 4 close to the second glass 5 to melt the first glass 4, or to generate plasma on the side of the second glass 5 close to the first glass 4 to The second glass 5 is melted to weld the first glass 4 and the second glass 5 .
  • the first pulsed laser 2 and the second pulsed laser 3 in this application are respectively ultrashort pulsed lasers
  • ultrashort pulsed lasers mainly refer to picosecond or femtosecond pulsed lasers with laser pulse widths less than nanoseconds, which are suitable for gaps.
  • the ultra-short pulse laser wavelength can be 200nm to 2000nm
  • the pulse width can be less than or equal to 12ps
  • the repetition rate can be greater than or equal to 1kHz.
  • the stacking arrangement here can either be stacked vertically, as shown in FIG. 1 , there is a gap between the first glass 4 and the second glass 5 after stacking and is approximately horizontal; When stacked in the horizontal direction, as shown in FIG. 2 , there is a gap between the first glass 4 and the second glass 5 after stacking, and the glass is approximately vertical.
  • the stacked first glass 4 and the second glass 5 may also have a certain inclination angle relative to the horizontal direction, which is not specifically limited here.
  • a fixing fixture 1 is provided on the sample stage, which is configured to install and clamp the first glass 4 and the second glass 5 .
  • the gap between the stacked first glass 4 and the second glass 5 is less than 5 microns, for example, 1 micron, 2 microns, 3 microns, or 4 microns, etc., can be welded by the laser beam welding device provided in this embodiment.
  • the first glass 4 and the second glass 5 may be of the same material or may be of different materials.
  • the surfaces to be welded between the first glass 4 and the second glass 5 do not need to be subjected to special optical treatment, which reduces the requirements for the quality of the glass surface, and can be directly welded without optical contact conditions.
  • the first pulsed laser 2 and the second pulsed laser 3 may be generated by the same laser generator 6 , or may be generated by two laser generators 6 respectively.
  • a polarization beam splitter 13 is provided between the laser generator 6 and the first glass 4, that is, a polarization beam splitter 13 is provided.
  • the beam splitter 13 is provided between the laser generator 6 and the sample stage, and the polarization beam splitter 13 is configured to divide the pulsed laser light emitted by the laser generator 6 into a first pulsed laser light 2 and a second pulsed laser light 3 .
  • a beam expander collimator 7 may also be provided between the laser generator 6 and the polarization beam splitter 13 .
  • a first light guide mirror 14 may also be provided between the polarization beam splitter 13 and the first focusing mirror 15 to adjust the incident direction of the first pulsed laser 2 , and the first focusing mirror 15 is configured to adjust the first pulsed laser 2, to maximize the energy of the first pulsed laser 2 for welding.
  • a second light guide mirror 16 is further arranged between the polarization beam splitter 13 and the second focusing mirror 18 to adjust the incident direction of the second pulsed laser light 3 , and the second focusing mirror 18 is used to adjust the convergence of the second pulsed laser light 3 point to maximize the energy of the second pulsed laser 3 for welding. It is easy to understand that according to the relative positional relationship between the laser generator 6, the polarizing beam splitter 13, the first glass 4 and the second glass 5, the number and position of the first light guide mirror 14 and the second light guide mirror 16 can be flexibly adjusted , the number can be one or more, which is not specifically limited here.
  • the beam emitted by the laser generator 6 reaches the polarization beam splitter 13 after adjusting the beam diameter and divergence angle by the beam expander collimator 7, and is divided into the first pulse laser 2 and the second pulse laser 3 by the polarization beam splitter 13 , the first pulsed laser 2 passes through a first light guide mirror 14 and a first focusing mirror 15 in sequence, and is incident from the surface of the first glass 4 to form a first optical path. Further, in the first optical path, the first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction, so that the first pulsed laser 2 is reflected at the first light guide mirror 14 with a deflection angle of 90 degrees.
  • the focusing mirror 15 is incident on the first glass 4 approximately perpendicularly.
  • the second pulsed laser 3 passes through the two second light guide mirrors 16 and the second focusing mirror 18 in sequence, and is incident from the surface of the second glass 5 to form a second optical path. Further, in the second optical path, two second light guide mirrors 16 are arranged at intervals, and the second light guide mirror 16 (the first second light guide mirror 16 ) close to the polarization beam splitter 13 is 135 degrees relative to the horizontal direction.
  • the angle is set so that the second pulsed laser light 3 is reflected at the first second light guide mirror 16 with a deflection angle of 90 degrees, and reaches the second second light guide mirror 16 (the second one near the second focusing mirror 18).
  • the second second light guide mirror 16 is arranged at an angle of 45 degrees relative to the horizontal direction, so that the second pulsed laser 3 is reflected at the second second light guide mirror 16 with a deflection angle of 90 degrees, It is incident on the side of the second glass 5 approximately vertically through the second focusing mirror 18 .
  • the first pulsed laser 2 is incident on the first glass 4 on the side of the first glass 4 away from the second glass 5 and the second pulsed laser 3 is incident on the side of the second glass 5 away from the first glass 4 .
  • the directions of the second glass 5 are located on the same straight line, that is, as shown in FIG. 1 and FIG. 2 , the first incident optical path of the first pulsed laser 2 in the first optical path from the first focusing mirror 15 to the first glass 4 and the second In the optical path, the second incident optical path of the first pulsed laser 3 from the second focusing mirror 18 to the second glass 5 is located on the same straight line. That is, the converging point of the first pulsed laser light 2 and the converging point of the second pulsed laser light 3 are both located on the same straight line.
  • the incident angle of the first pulsed laser 2 on the side of the first glass 4 can be greater than 0 degrees and less than or equal to 90 degrees
  • the incident angle of the second pulsed laser 3 on the side of the second glass 5 can be greater than 0 degrees and less than or equal to 90 degrees Spend.
  • the first pulsed laser 2 is incident at an angle substantially perpendicular to the surface of the first glass 4
  • the second pulsed laser 3 is incident at an angle substantially perpendicular to the surface of the second glass 5 , which is not specifically limited here.
  • the first incident optical path of the first pulsed laser 2 and the second incident optical path of the second pulsed laser 3 may not be located on the same straight line, but may be parallel to each other, or may be extended lines intersecting,
  • the extension line crossing refers to that the extension line of the first incident light path intersects the extension line of the second incident light path.
  • the converging point of the first pulsed laser light 2 and the converging point of the second pulsed laser light 3 are in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5
  • the converging point of the first pulsed laser 2 and the converging point of the second pulsed laser The vertical direction of the arrangement direction can be located at the same height or staggered from each other.
  • the laser generator 6 includes a first generator 8 and a second generator 9, and the first generator 8 is configured In order to generate the first pulsed laser light 2 , the second generator 9 is configured to generate the second pulsed laser light 3 .
  • the first generator 8 and the second generator 9 are respectively arranged on two sides of the sample stage, that is, the first generator 8 is located on the side of the first glass 4, and the second generator 9 is located on the side of the second glass 5.
  • a first beam expander collimator 10, two first light guide mirrors 14 and a first focusing mirror 15 are arranged between the first generator 8 and the first glass 4 in sequence.
  • the first pulse emitted by the first generator 8 The laser 2 reaches the first first light guide mirror 14 after adjusting the beam diameter and the divergence angle of the first beam expander collimator 10.
  • the first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction, so that the first pulsed laser 2.
  • a reflection with a deflection angle of 90 degrees occurs at the first first light guide mirror 14, and then reaches the second first light guide mirror 14.
  • the second first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction , so that the first pulsed laser light 2 is reflected at the second first light guide mirror 14 with a deflection angle of 90 degrees, and after passing through the first focusing mirror 15 , it is incident on the side of the first glass 4 approximately vertically.
  • a second beam expander collimator 20, two second light guide mirrors 16 and a second focusing mirror 18 are arranged between the second generator 9 and the second glass 5 in sequence.
  • the second pulse emitted by the second generator 9 The laser 3 reaches the first second light guide mirror 16 after adjusting the beam diameter and the divergence angle of the second beam expander collimator 20.
  • the second light guide mirror 16 is arranged at an angle of 45 degrees relative to the horizontal direction, so that the first pulsed laser 3.
  • a reflection with a deflection angle of 90 degrees occurs at the first second light guide mirror 16, and then it is emitted to the second second light guide mirror 16, and the second second light guide mirror 16 is at an angle of 45 degrees relative to the horizontal direction.
  • the second pulsed laser 3 is reflected at the second second light guide mirror 16 with a deflection angle of 90 degrees, and is incident on the side of the second glass 5 approximately vertically after passing through the second focusing mirror 18 .
  • the provision of the first light guide mirror 14 may be omitted.
  • the arrangement position of the second generator 9 is adjusted so that the second pulsed laser 3 emitted by the second generator 9 is perpendicular to the surface of the second glass 5 or incident at the actual required preset angle, it can be omitted.
  • Arrangement of the second light guide mirror 16 .
  • a fixing fixture 1 is provided on the sample stage, and the first glass 4 and the second glass 5 are mounted on the fixing fixture 1 .
  • the translation stage is connected to the sample stage and configured to adjust the position of the sample stage.
  • the industrial computer is respectively connected with the laser generator 6 and the displacement stage, and is configured to control the laser generator 6 to emit the first pulsed laser 2 and the second pulsed laser 3, control the movement of the displacement stage, and adjust the frequency and single pulse of the first pulsed laser 2.
  • the frequency and single-pulse energy of the second pulse laser 3 and the incident angle and speed on the surface of the second glass 5 are adjusted according to the energy and the incident angle and speed on the surface of the first glass 4 to achieve automatic, fast and accurate welding.
  • the first glass 4 is the upper glass
  • the second glass 5 is the lower layer. Glass.
  • the first pulsed laser 2 is incident from the surface of the first glass 4 , the first pulsed laser 2 adopts an ultra-short pulsed laser, and the first pulsed laser 2 is focused on the side of the first glass 4 near the gap under the action of the first focusing mirror 15 On the surface or inside of the glass, it interacts with the first glass 4 nonlinearly to deposit laser energy and form a molten pool.
  • the molten material in the molten pool will splash in the direction of the second glass 5 under the extrusion of thermal pressure and gravity, and The connection between the first glass 4 and the second glass 5 is finally achieved.
  • the second pulsed laser 3 is incident from the surface of the second glass 5, which is the same as the first pulsed laser 2.
  • the second pulsed laser 3 interacts with the second glass 5 nonlinearly to deposit laser energy and form a molten pool.
  • the splash generated by the material of the second glass 5 realizes the welding of the first glass 4 and the second glass 5 .
  • the first pulsed laser 2 and the second pulsed laser 3 are used in opposite directions to generate more melts at their respective convergence points, which can realize welding with a larger gap and have a wider application range.
  • the convergence point of the first pulsed laser 2 and the second pulsed laser 3 The convergence points are staggered in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5 or are located at the same height.
  • the first pulsed laser 2 is focused on the surface or inside of the first glass 4 on the side of the second glass 5 under the action of the first focusing mirror 15 , or on the second glass 5 on the side of the first glass 5 .
  • the second pulsed laser 3 is focused on the surface or inside of the second glass 5 on the side of the first glass 4 under the action of the second focusing mirror 18, or is focused on the first glass 4 on the surface or inside of the second glass 5 side, where the first pulsed laser 2 is focused on the surface or inside of the first glass 4 on the second glass 5 side, and the second pulsed laser 3 is focused on the second glass
  • the case of the surface or the inside of the side close to the first glass 4 of 5 is the same as the above, so the description is omitted.
  • the first pulsed laser 2 is focused on the surface or the inside of the second glass 5 on the side of the first glass 4
  • the second pulsed laser 3 is focused on the surface of the first glass 4 on the side of the second glass 5 . or internal conditions.
  • the first pulsed laser 2 and the second glass 5 interact nonlinearly to deposit laser energy and form a molten pool, and the molten material in the molten pool will move towards the first glass 4 under the extrusion of thermal pressure and gravity Splashes are generated and the connection between the first glass 4 and the second glass 5 is finally achieved.
  • the first pulsed laser 2 interacts with the second glass 5 nonlinearly to generate plasma, and the plasma has strong absorption characteristics for the laser, which will have a shielding effect on the subsequent first pulsed laser 2, making it impossible to By penetrating the plasma and acting on the original focus, the acting point of the subsequent first pulsed laser 2 will be higher than the previous convergence point, which will cause the second glass 5 to be induced by the laser to generate plasma again.
  • the plasma region will expand from the original convergence point to the light source direction of the first pulsed laser 2 , that is, the expansion direction of the plasma region will be from the gap side of the second glass 5 .
  • the first glass 4 spreads in the direction of the light source of the first pulsed laser 2 .
  • the plasma area will transfer energy to the surrounding materials through the thermal diffusion effect, forming an external melting modification area, so that this area of the second glass 5 is melted.
  • the The droplet-shaped double-structure action area the lowermost end of the double-structure action area is the original converging point position of the first pulsed laser 2 . Therefore, when the ultra-short pulse laser is used to focus on the second glass 5 for welding, the laser action area always develops from the first glass 4 to the light source, and the first glass 5 is produced by protrusions or splashes generated by the second glass 5.
  • connection between the glass 4 and the second glass 5, that is, the action area of the first pulsed laser 2 develops from the surface of the second glass 5 near the gap to the light source of the first pulsed laser 2, so as to weld the first glass 4 and the second glass 5.
  • the second glass 5 The connection between the glass 4 and the second glass 5, that is, the action area of the first pulsed laser 2 develops from the surface of the second glass 5 near the gap to the light source of the first pulsed laser 2, so as to weld the first glass 4 and the second glass 5.
  • the second glass 5 .
  • the action area of the second pulsed laser 3 is from the surface of the first glass 4 on the side of the second glass 5 to the light source of the second pulsed laser 3 Development, the welding of the first glass 4 and the second glass 5 is achieved by bulges or splashes produced by the material of the first glass 4 .
  • the first pulsed laser 2 and the second pulsed laser 3 are used in opposite directions to generate more melts at their respective convergence points, which can realize welding with a larger gap and have a wider application range.
  • Embodiments of the present application further provide a laser butt beam welding method, which is performed by a laser butt beam welding device and configured to realize welding of a first glass 4 and a second glass 5 that are stacked with a gap.
  • the following steps of the laser butt-beam welding method are implemented by executing instructions or commands from the controller (not shown) of the laser-but-beam welding device:
  • the first pulsed laser 2 is incident from the side of the first glass 4 away from the second glass 5 , and the first pulsed laser 2 is focused on the first glass 4 or the second glass 5 ; Generate plasma on the side of the second glass 5 and melt the first glass 4 or generate plasma on the side of the second glass 5 close to the first glass 4 and melt the second glass 5 to weld the first glass 4 and the second glass 5.
  • the second pulsed laser 3 is incident from the side of the second glass 5 away from the first glass 4, and the second pulsed laser 3 is focused on the first glass 4 or the second glass 5; the second pulsed laser 3 is configured to A glass 4 near the second glass 5 generates plasma and melts the first glass 4 or generates plasma on the side of the second glass 5 near the first glass 4 and melts the second glass 5 to weld the first glass 5 Glass 4 and second glass 5.
  • the first pulsed laser 2 and the second pulsed laser 3 are used against each other, and the first pulsed laser 2 and the second pulsed laser 3 are ultra-short pulsed lasers, which can form more
  • the plasma and molten material can be used to realize glass welding with a larger gap.
  • the welding quality is reliable, and it has good shear performance and sealing performance. In addition, there is no need to introduce opaque materials, which reduces the requirements for the quality of the glass surface, and does not require optical contact conditions.
  • the welding is more efficient, and the light transmission performance of the welded product is not affected.
  • the first pulsed laser 2 is incident from the first glass 4 after passing through the first focusing mirror 15 and is focused on the first convergence point
  • the second pulsed laser 3 is incident and focused from the second glass 5 after passing through the second focusing mirror 18 .
  • the first incident light path of the first pulsed laser 2 from the first focusing mirror 15 to the first glass 4 and the second incident light path of the second pulsed laser 3 from the second focusing mirror 18 to the second glass 5 The optical paths are located on the same straight line
  • the first convergence point and the second convergence point are on the same straight line
  • the first convergence point is the intersection of the surface of the first glass 4 on the side of the gap and the above-mentioned same straight line
  • the second convergence point is An intersection of the surface of the second glass 5 on the side of the gap and the same straight line described above.
  • first incident light path and the second incident light path may not be on the same straight line, but parallel or intersect with each other, and the first converging point and the second converging point are in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5 Staggered
  • first convergence point is the intersection of the surface of the first glass 4 on the side of the gap and the first incident optical path or the intersection of the surface of the second glass 5 on the side of the gap and the first incident optical path
  • the second convergence point is The intersection of the surface of the first glass 4 on the side of the gap and the second incident light path or the intersection of the surface of the second glass 5 on the side of the gap and the second incident light path;
  • the first glass 4 and the second glass 5 may be the same It can also be a different material, which is not specifically limited here.
  • the first pulsed laser 2 is incident perpendicular to the surface of the first glass 4, and the second pulsed laser 3 is incident perpendicular to the surface of the second glass 5, so as to give full play to the first pulsed laser 2 and the second pulsed laser 3.
  • the energy deposited at the first convergence point and the second convergence point is more sufficient, more molten material is generated, the welding quality is improved, and the welding of the first glass 4 and the second glass 5 with a larger gap is suitable. Enhances shear and sealing properties of welded products.
  • the glass samples to be welded that is, the first glass 4 and the second glass 5 are both soda lime glass, and the first glass 4 and the second glass 5 are fixed by the fixing fixture 1 so that the distance is about 2 ⁇ m, and the ultra-short pulse laser wavelength is used. It is 1030nm, the pulse width is 350fs, the repetition rate is 1MHz, the single pulse energy is 0.6 ⁇ J, and the speed is 20mm/s.
  • the welded product can withstand a push-pull force of about 20Kg, and the air tightness can reach 5 ⁇ 10 -10 Pa. m 3 /s, indicating that the sample has good shear strength and sealing performance.
  • the glass samples to be welded that is, the first glass 4 and the second glass 5 are both D263 borosilicate glass, and the first glass 4 and the second glass 5 are fixed by the fixing fixture 1 in a way that the distance is about 3 ⁇ m, and the ultra-short pulse laser is used.
  • the wavelength is 1030nm
  • the pulse width is 350fs
  • the repetition rate is 1MHz
  • the single pulse energy is 1 ⁇ J
  • the speed is 24mm/s.
  • the welded product can withstand a push-pull force of about 15Kg, and the air tightness can reach 2 ⁇ 10 -10 Pa. m 3 /s, indicating that the sample has good shear strength and sealing performance.
  • the first glass 4 is D263 borosilicate glass
  • the second glass 5 is quartz glass.
  • the first glass 4 and the second glass 5 are fixed by the fixing jig 1 so that the distance is about 2 ⁇ m.
  • the short pulse laser wavelength is 1030nm
  • the pulse width is 350fs
  • the repetition rate is 1MHz
  • the single pulse energy is 1 ⁇ J
  • the speed is 12mm/s.
  • the welded product can withstand a push-pull force of about 25Kg, and the air tightness can reach 8 ⁇ 10 - 10 Pa.m 3 /s, indicating that the sample has good shear strength and sealing performance.
  • the laser butt-beam welding device and method provided in this embodiment can be applied to glass welding with a large gap, that is, less than or equal to 5 microns, which reduces the requirements for the quality of the glass surface and does not require optical contact conditions. And has good shear strength and sealing performance. There is no need to introduce opaque materials separately, which improves welding efficiency and quality, and reduces welding process requirements and welding costs.
  • the embodiments of the present application provide a laser butt beam welding device and method, which have the following beneficial effects:
  • the laser butt welding device includes a laser generator, a first focusing mirror and a second focusing mirror.
  • the pulsed laser emitted by the laser generator is used as the first pulsed laser and the second pulsed laser from two sides of the first glass and the second glass respectively.
  • Opposite radiation that is, the first pulsed laser is incident from the first glass side to the gap between the first glass and the second glass, and the second pulsed laser is incident from the second glass side to the space between the first glass and the second glass the gap.
  • the first pulsed laser is focused on the side of the second glass close to the first glass or the side of the first glass close to the second glass under the action of the first focusing mirror, and produces nonlinear interaction with the second glass or the first glass.
  • Plasma is generated, and the strong absorption of the laser by the plasma will produce a shielding effect on the subsequent first pulsed laser, so that it cannot penetrate the plasma and act on the original focus.
  • the plasma region will expand from the focal point to the light source direction of the first pulsed laser.
  • the plasma zone transfers energy to the surrounding material through thermal diffusion effects, forming an external melt-modified zone for welding the first glass and the second glass.
  • the second pulsed laser is focused on the side of the first glass close to the second glass or the side of the second glass close to the first glass under the action of the second focusing mirror , and produce a non-linear interaction with the first glass or the second glass to generate plasma, which will have a shielding effect on the subsequent second pulsed laser, making it unable to penetrate the plasma and act on the original focus, making the plasma
  • the zone will exhibit a phenomenon of expanding from the focal point towards the light source of the second pulsed laser. And through the thermal diffusion effect, the energy is transferred to the surrounding material to form an external melting modification zone to weld the first glass and the second glass.
  • the through-beam welding device has a simple structure, does not need to introduce an opaque material between the first glass and the second glass, has low optical requirements on the glass welding surface, and can realize the welding of the first glass with a large gap. Welding with the second glass to improve welding quality and efficiency.
  • the laser butt welding method utilizes the first pulsed laser and the second pulsed laser to be incident from the two sides of the first glass and the second glass respectively, that is to form an opposite beam, and uses the laser to generate nonlinear interaction with the glass material and generate plasma,
  • the strong absorption of the laser by the plasma will have a shielding effect on the subsequent laser, making it impossible to penetrate the plasma and act on the original focus.
  • the plasma region will expand from the focal point towards the laser source.
  • the plasma zone will transfer energy to the surrounding material through thermal diffusion effect, forming an external melting modification zone to weld the first glass and the second glass, this welding method does not need to be between the first glass and the second glass
  • This welding method does not need to be between the first glass and the second glass
  • the introduction of opaque materials has lower optical requirements for the glass welding surface, which can realize the welding of the first glass and the second glass with a large gap, improve the welding quality and efficiency, and does not affect the light transmission of the welded product performance.
  • the present application provides a laser butt beam welding device and method, and relates to the technical field of laser welding. Through the laser irradiation, plasma is generated on the side of the two glasses near the gap to form a melt, so as to weld the two glasses and improve the welding quality and efficiency.

Abstract

A laser opposing emission welding apparatus comprising a laser generator (6), a first focusing lens (15), a second focusing lens (18), and a sample stage, the laser generator (6) being configured to generate a pulsed laser, and a first piece of glass (4) and a second piece of glass (5) being in a stacked arrangement in a manner where a gap is present; the first focusing lens (15) is arranged between the laser generator (6) and the first piece of glass (4), the first focusing lens (15) is configured to allow the pulsed laser generated by the laser generator (6) to serve as a first pulsed laser (2) and be emitted into a gap between the first piece of glass (4) and the second piece of glass (5) from the side of the first piece of glass (4) away from the second piece of glass (5); the second focusing lens (18) is configured to allow the pulsed laser generated by the laser generator (6) to serve as a second pulsed laser (3) and be emitted into the gap between the first piece of glass (4) and the second piece of glass (5) from the side of the second piece of glass (5) away from the first piece of glass (4); and by means of opposing emissions of the first pulsed laser (2) and the second pulsed laser (3), plasma is generated at the side of the first piece of glass (4) near the gap and the side of the second piece of glass (5) near the gap, and a melted material is formed, so as to weld the first piece of glass (4) and the second piece of glass (5). Additionally, the present application further comprises a laser opposing emission welding method. Utilizing the present apparatus for welding, surfaces to be welded between a first piece of glass (4) and a second piece of glass (5) do not need to undergo special optical treatment, a requirement on glass surface quality is lowered, no optical contacting is necessary, welding is more efficient, the light transmission performance of a welded product is unaffected, and the shearing performance and sealing performance of the welded product are enhanced.

Description

激光对射焊接装置和方法Laser butt beam welding device and method
相关申请的交叉引用CROSS-REFERENCE TO RELATED APPLICATIONS
本申请要求于2020年12月31日提交中国专利局的申请号为2020116351037、名称为“激光对射焊接装置和方法”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims the priority of the Chinese Patent Application No. 2020116351037 and entitled "Laser Butt Beam Welding Apparatus and Method" filed with the Chinese Patent Office on December 31, 2020, the entire contents of which are incorporated herein by reference.
技术领域technical field
本申请涉及激光焊接技术领域,具体而言,涉及一种激光对射焊接装置和方法。The present application relates to the technical field of laser welding, and in particular, to a laser butt beam welding device and method.
背景技术Background technique
激光焊接技术是一种利用高能量密度的激光束作为热源的新型连接技术,具有选择性焊接、无接触、效率高等优点,因而在工程上得到了广泛应用和快速发展。Laser welding technology is a new type of connection technology that uses a high-energy-density laser beam as a heat source. It has the advantages of selective welding, non-contact, and high efficiency, so it has been widely used and developed rapidly in engineering.
然而该焊接技术用于玻璃焊接却较为困难,因为玻璃对大多数激光而言是透明的,即激光无法与玻璃发生相互作用而沉积能量,若采用不会透过玻璃的激光,如CO 2激光器发出的波长为10.6μm的激光,则激光会在玻璃表面上与其发生相互作用,而无法透过玻璃在其接触处沉积能量实现焊接。因此利用激光焊接技术对玻璃实施焊接时,需要在玻璃间隙中插入中间吸收层,或者下层材料为不透光材料,然后采用对玻璃具有透射性波长的激光,将其聚焦到玻璃间隙处,利用中间吸收层或者下层材料对激光的吸收来沉积激光能量从而实现焊接。这样的焊接方法显然会影响器件的整体透光性能,而且由于异质材料的引入,热膨胀系数的差异会导致焊缝受到热应力的影响,从而导致焊缝失效。 However, it is more difficult to use this welding technology for glass welding, because glass is transparent to most lasers , that is, the laser cannot interact with the glass to deposit energy. The emitted laser with a wavelength of 10.6 μm will interact with it on the surface of the glass, and cannot pass through the glass to deposit energy at its contact to achieve welding. Therefore, when using laser welding technology to weld glass, it is necessary to insert an intermediate absorption layer in the glass gap, or the underlying material is an opaque material, and then use a laser with a wavelength that transmits the glass to focus it on the glass gap. The absorption of the laser light by the intermediate absorbing layer or the underlying material deposits the laser energy for welding. Such a welding method will obviously affect the overall light transmission performance of the device, and due to the introduction of foreign materials, the difference in thermal expansion coefficient will cause the weld to be affected by thermal stress, resulting in weld failure.
发明内容SUMMARY OF THE INVENTION
本申请的目的在于提供一种激光对射焊接装置和方法,其能够直接对两个玻璃材质进行焊接,无需引入不透光材料,对需要焊接的玻璃表面要求低,焊接后不影响产品的透光性能,可提高焊接质量和效率。The purpose of this application is to provide a laser butt beam welding device and method, which can directly weld two glass materials without introducing opaque materials, has low requirements on the glass surface to be welded, and does not affect the transparency of the product after welding. Optical performance to improve welding quality and efficiency.
本申请的实施例可以这样实现:The embodiments of the present application can be implemented as follows:
第一方面,本申请提供一种激光对射焊接装置,其中,包括激光发生器、第一聚焦镜、第二聚焦镜和样品台;所述激光发生器配置成产生脉冲激光,所述样品台配置成放置第一玻璃和第二玻璃,所述第一玻璃和所述第二玻璃以具有间隙的方式层叠设置;所述第一聚焦镜设于所述激光发生器和所述第一玻璃之间,所述第一聚焦镜配置成将所述激光发生器产生的脉冲激光作为第一脉冲激光从所述第一玻璃远离所述第二玻璃 的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;所述第二聚焦镜设于所述激光发生器和所述第二玻璃之间,所述第二聚焦镜配置成将所述激光发生器产生的脉冲激光作为第二脉冲激光从所述第二玻璃远离所述第一玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。In a first aspect, the present application provides a laser butt beam welding device, which includes a laser generator, a first focusing mirror, a second focusing mirror and a sample stage; the laser generator is configured to generate pulsed laser light, and the sample stage It is configured to place a first glass and a second glass, and the first glass and the second glass are stacked with a gap; the first focusing mirror is arranged between the laser generator and the first glass. During the time, the first focusing mirror is configured to inject the pulsed laser generated by the laser generator as the first pulsed laser from the side of the first glass away from the second glass to the first glass and the second glass. the gap between the second glasses; the first pulsed laser is configured to generate plasma on the side of the second glass close to the first glass and melt the second glass to weld the first glass glass and the second glass; the second focusing mirror is arranged between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as the first Two pulsed lasers are incident from the side of the second glass away from the first glass to the gap between the first glass and the second glass; the second pulsed laser is configured to A side of the glass close to the second glass generates plasma and melts the first glass to weld the first glass and the second glass.
可选的,在上述的激光对射焊接装置中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。Optionally, in the above-mentioned laser butt beam welding device, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
可选的,在上述的激光对射焊接装置中,还包括偏振分束镜,所述偏振分束镜设于所述激光发生器和所述样品台之间,所述偏振分束镜配置成将所述激光发生器产生的脉冲激光分为所述第一脉冲激光和所述第二脉冲激光,所述第一脉冲激光配置成经所述第一聚焦镜后从所述第一玻璃入射,所述第二脉冲激光配置成经所述第二聚焦镜后从所述第二玻璃入射。Optionally, in the above-mentioned laser butt beam welding device, it also includes a polarization beam splitter, the polarization beam splitter is arranged between the laser generator and the sample stage, and the polarization beam splitter is configured to The pulsed laser generated by the laser generator is divided into the first pulsed laser and the second pulsed laser, and the first pulsed laser is configured to be incident from the first glass after passing through the first focusing mirror, The second pulsed laser light is configured to be incident from the second glass after passing through the second focusing mirror.
可选的,在上述的激光对射焊接装置中,其中,所述激光发生器包括第一发生器和第二发生器,所述第一发生器配置成产生所述第一脉冲激光,所述第二发生器配置成产生所述第二脉冲激光,所述第一脉冲激光配置成经所述第一聚焦镜后从所述第一玻璃入射,所述第二脉冲激光配置成经所述第二聚焦镜后从所述第二玻璃入射。Optionally, in the above-mentioned laser butt beam welding device, wherein the laser generator includes a first generator and a second generator, the first generator is configured to generate the first pulsed laser, the A second generator is configured to generate the second pulsed laser light, the first pulsed laser light is configured to be incident from the first glass after passing through the first focusing mirror, and the second pulsed laser light is configured to pass through the first focusing mirror After two focusing mirrors are incident from the second glass.
可选的,在上述的激光对射焊接装置中,还包括对所述激光发生器产生的脉冲激光的光束直径和发散角进行调整的扩束准直镜,所述扩束准直镜设于所述激光发生器的所述脉冲激光的传播方向的下游。Optionally, in the above-mentioned laser butt-beam welding device, it also includes a beam expander collimator for adjusting the beam diameter and divergence angle of the pulsed laser generated by the laser generator, and the beam expander collimator is provided on the downstream of the propagation direction of the pulsed laser light of the laser generator.
可选的,在上述的激光对射焊接装置中,还包括第一导光镜和第二导光镜,所述第一导光镜设于所述第一聚焦镜远离所述第一玻璃的一侧,所述第二导光镜设于所述第二聚焦镜远离所述第二玻璃的一侧。Optionally, in the above-mentioned laser butt beam welding device, it further includes a first light guide mirror and a second light guide mirror, the first light guide mirror is arranged at a position of the first focusing mirror away from the first glass. On one side, the second light guide mirror is arranged on the side of the second focusing mirror away from the second glass.
可选的,在上述的激光对射焊接装置中,还包括工控机和位移台,所述位移台与所述样品台连接,所述工控机分别与所述激光发生器和所述位移台连接,来控制所述激光发生器和所述位移台。Optionally, in the above-mentioned laser butt beam welding device, it also includes an industrial computer and a displacement stage, the displacement stage is connected to the sample stage, and the industrial computer is respectively connected to the laser generator and the displacement stage. , to control the laser generator and the stage.
可选的,在上述的激光对射焊接装置中,所述样品台上设有固定夹具,所述固定夹具固定所述第一玻璃和所述第二玻璃。Optionally, in the above laser butt beam welding device, a fixing fixture is provided on the sample stage, and the fixing fixture fixes the first glass and the second glass.
可选的,在上述的激光对射焊接装置中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二 玻璃的第二入射光路平行或延长线交叉。Optionally, in the above-mentioned laser butt beam welding device, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light path from the second focusing mirror to the second glass is parallel or intersecting with the extension line.
可选的,在上述的激光对射焊接装置中,所述第一聚焦镜配置成将所述第一脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部,所述第二聚焦镜配置成将所述第二脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部。Optionally, in the above-mentioned laser butt beam welding device, the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the second glass on the side of the first glass, The second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the first glass on the side of the second glass.
第二方面,本申请提供一种激光对射焊接装置,包括激光发生器、第一聚焦镜、第二聚焦镜和样品台;所述激光发生器配置成产生脉冲激光,所述样品台配置成放置第一玻璃和第二玻璃,所述第一玻璃和所述第二玻璃以具有间隙的方式层叠设置;所述第一聚焦镜设于所述激光发生器和所述第一玻璃之间,所述第一聚焦镜配置成将所述激光发生器产生的脉冲激光作为第一脉冲激光从所述第一玻璃远离所述第二玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;所述第二聚焦镜设于所述激光发生器和所述第二玻璃之间,所述第二聚焦镜配置成将所述激光发生器产生的脉冲激光作为第二脉冲激光从所述第二玻璃远离所述第一玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。In a second aspect, the present application provides a laser butt beam welding device, comprising a laser generator, a first focusing mirror, a second focusing mirror and a sample stage; the laser generator is configured to generate pulsed laser light, and the sample stage is configured to A first glass and a second glass are placed, and the first glass and the second glass are stacked with a gap; the first focusing mirror is arranged between the laser generator and the first glass, The first focusing mirror is configured to inject the pulsed laser light generated by the laser generator into the first glass and the second glass from the side of the first glass away from the second glass as the first pulsed laser light at a gap between glasses; the first pulsed laser is configured to generate plasma on a side of the first glass close to the second glass and melt the first glass to weld the first glass and the second glass the second glass; the second focusing mirror is arranged between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as the second pulse The laser is incident from the side of the second glass away from the first glass to the gap between the first glass and the second glass; the second pulsed laser is configured to be close to the second glass One side of the first glass generates plasma and melts the second glass to weld the first glass and the second glass.
可选的,在上述的激光对射焊接装置中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。Optionally, in the above-mentioned laser butt beam welding device, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
可选的,在上述的激光对射焊接装置中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线交叉。Optionally, in the above-mentioned laser butt beam welding device, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the The second incident light path from the second focusing mirror to the second glass is parallel or intersecting with the extension line.
可选的,在上述的激光对射焊接装置中,所述第一聚焦镜配置成将所述第一脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部,所述第二聚焦镜配置成将所述第二脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部。Optionally, in the above-mentioned laser butt beam welding device, the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the first glass on the side of the second glass, The second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the second glass on the side of the first glass.
可选的,在上述的激光对射焊接装置中,所述第一玻璃和所述第二玻璃之间的间隙为5μm以下。Optionally, in the above-mentioned laser butt beam welding device, the gap between the first glass and the second glass is 5 μm or less.
可选的,在上述的激光对射焊接装置中,所述第一脉冲激光和所述第二脉冲激光的波长为200nm至2000nm,脉宽为12ps以下,重复率为1kHz以上。Optionally, in the above-mentioned laser butt beam welding device, the wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is less than 12 ps, and the repetition rate is more than 1 kHz.
第三方面,本申请提供一种激光对射焊接方法,配置成实现第一玻璃和第二玻璃的焊接,所述第一玻璃和所述第二玻璃具有间隙地层叠设置;所述激光对射焊接方法包括:从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光,所述第一脉冲激光 聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;以及从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光,所述第二脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。In a third aspect, the present application provides a laser butt beam welding method, configured to realize welding of a first glass and a second glass, the first glass and the second glass being stacked with a gap; the laser beam beam welding method The welding method includes: incident a first pulsed laser light from a side of the first glass away from the second glass, and the first pulsed laser light is focused on a gap between the first glass and the second glass; the first pulsed laser is configured to generate plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass; and A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass.
可选的,在上述的激光对射焊接方法中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。Optionally, in the above-mentioned laser butt beam welding method, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The two incident light paths are located on the same straight line.
可选的,在上述的激光对射焊接方法中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线相交。Optionally, in the above-mentioned laser butt beam welding method, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The parallel or extension lines of the two incident light paths intersect.
可选的,在上述的激光对射焊接方法中,所述第一脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部,所述第二脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部。Optionally, in the above-mentioned laser butt beam welding method, the first pulsed laser is focused on the surface or inside of the second glass on the side of the first glass, and the second pulsed laser is focused on the second glass. The surface or interior of the first glass on the side of the second glass.
第四方面,本申请提供一种激光对射焊接方法,配置成实现第一玻璃和第二玻璃的焊接,所述第一玻璃和所述第二玻璃具有间隙地层叠设置;所述激光对射焊接方法包括:从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光,所述第一脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;以及从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光,所述第二脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。In a fourth aspect, the present application provides a laser butt-beam welding method configured to realize welding of a first glass and a second glass, the first glass and the second glass being stacked with a gap; the laser beam-beam welding method The welding method includes: incident a first pulsed laser light from a side of the first glass away from the second glass, and the first pulsed laser light is focused on a gap between the first glass and the second glass; the first pulsed laser is configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass; and A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass.
可选的,在上述的激光对射焊接方法中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入 射;从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。Optionally, in the above-mentioned laser butt beam welding method, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The two incident light paths are located on the same straight line.
可选的,在上述的激光对射焊接方法中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线相交。Optionally, in the above-mentioned laser butt beam welding method, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through the first focusing mirror. Incident from the first glass; in the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light passes through the second focusing mirror and passes through the second glass. Incident, the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser from the second focusing mirror to the second glass. The parallel or extension lines of the two incident light paths intersect.
可选的,在上述的激光对射焊接方法中,所述第一玻璃和所述第二玻璃之间的间隙为5μm以下。Optionally, in the above laser butt beam welding method, the gap between the first glass and the second glass is 5 μm or less.
可选的,在上述的激光对射焊接方法中,所述第一脉冲激光和所述第二脉冲激光的波长为200nm至2000nm,脉宽为12ps以下,重复率为1kHz以上。Optionally, in the above laser butt beam welding method, the wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is less than 12 ps, and the repetition rate is more than 1 kHz.
附图说明Description of drawings
为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to illustrate the technical solutions of the embodiments of the present application more clearly, the following drawings will briefly introduce the drawings that need to be used in the embodiments. It should be understood that the following drawings only show some embodiments of the present application, and therefore do not It should be regarded as a limitation of the scope, and for those of ordinary skill in the art, other related drawings can also be obtained according to these drawings without any creative effort.
图1为本申请实施例提供的激光对射焊接方法的焊接原理的示意图;1 is a schematic diagram of a welding principle of a laser butt beam welding method provided by an embodiment of the present application;
图2为本申请实施例提供的激光对射焊接方法的焊接原理的示意图;2 is a schematic diagram of a welding principle of a laser butt beam welding method provided by an embodiment of the present application;
图3A、3B为本申请实施例提供的激光对射焊接方法的焊接原理的示意图;3A and 3B are schematic diagrams of the welding principle of the laser butt beam welding method provided by the embodiment of the application;
图4为本申请实施例提供的激光对射焊接装置的结构示意图;4 is a schematic structural diagram of a laser butt beam welding device provided by an embodiment of the present application;
图5为本申请实施例提供的激光对射焊接装置的结构示意图。FIG. 5 is a schematic structural diagram of a laser butt beam welding device provided by an embodiment of the present application.
附图标记说明Description of reference numerals
1-固定夹具;2-第一脉冲激光;3-第二脉冲激光;4-第一玻璃;5-第二玻璃;6-激光发生器;7-扩束准直镜;8-第一发生器;9-第二发生器;10-第一扩束准直镜;20-第二扩束准直镜;13-偏振分束镜;14-第一导光镜;15-第一聚焦镜;16-第二导光镜;18-第二聚焦镜。1-fixed fixture; 2-first pulse laser; 3-second pulse laser; 4-first glass; 5-second glass; 6-laser generator; 7-beam expanding collimator; 8-first generation 9-second generator; 10-first beam expander collimator; 20-second beam expander collimator; 13-polarizing beam splitter; 14-first light guide mirror; 15-first focusing mirror ; 16 - the second light guide mirror; 18 - the second focusing mirror.
具体实施方式Detailed ways
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的 附图,对本申请实施例的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本申请实施例的组件可以以各种不同的配置来布置和设计。In order to make the purposes, technical solutions and advantages of the embodiments of the present application more clear, the technical solutions of the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application. Obviously, the described embodiments are Some embodiments of the present application, but not all of the embodiments. The components of the embodiments of the present application generally described and illustrated in the drawings herein may be arranged and designed in a variety of different configurations.
因此,以下对在附图中提供的本申请的实施例的详细描述并非旨在限制要求保护的本申请的范围,而是仅仅表示本申请的选定实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。Thus, the following detailed description of the embodiments of the application provided in the accompanying drawings is not intended to limit the scope of the application as claimed, but is merely representative of selected embodiments of the application. Based on the embodiments in the present application, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present application.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。It should be noted that like numerals and letters refer to like items in the following figures, so once an item is defined in one figure, it does not require further definition and explanation in subsequent figures.
在本申请的描述中,需要说明的是,若出现术语“上”、“下”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该申请产品使用时惯常摆放的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of this application, it should be noted that, if the terms "upper", "lower", "inner", "outer", etc. appear, the orientation or positional relationship indicated is based on the orientation or positional relationship shown in the drawings, or It is the orientation or positional relationship that the product of the application is usually placed in use, which is only for the convenience of describing the application and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation , so it cannot be construed as a limitation on this application.
此外,若出现术语“第一”、“第二”等仅用于区分描述,而不能理解为指示或暗示相对重要性。In addition, where the terms "first", "second" and the like appear, they are only used to differentiate the description, and should not be construed as indicating or implying relative importance.
需要说明的是,在不冲突的情况下,本申请的实施例中的特征可以相互结合。It should be noted that the features in the embodiments of the present application may be combined with each other under the condition of no conflict.
目前,采用传统激光焊接方法需要在两个玻璃之间引入不透光材料,才能进行焊接,这种焊接方式会降低焊接后的产品的透光性能,并且引入的异种材料可能由于热膨胀系数的差异会导致焊缝受到热应力的影响,从而导致焊缝失效,难以保证焊接质量。At present, the traditional laser welding method needs to introduce an opaque material between the two glasses before welding. This welding method will reduce the light transmission performance of the welded product, and the introduced dissimilar materials may be due to differences in thermal expansion coefficients. It will cause the weld to be affected by thermal stress, which will lead to the failure of the weld, and it is difficult to ensure the welding quality.
本申请实施例提供一种激光对射焊接装置,可以直接对两个玻璃材质或两个透明材质进行焊接,无需在两个玻璃之间设置不透光材料,焊接效率高。并且对玻璃焊接表面的要求低,焊接后不影响产品的透光性能,可提高焊接质量,并且在两个玻璃之间有较大间隙的情况下也能实现两者的焊接,既能满足焊接可靠要求,具有良好的剪切强度,又能实现焊接后产品的良好的密封性能,应用范围广泛。The embodiment of the present application provides a laser butt beam welding device, which can directly weld two glass materials or two transparent materials, without disposing an opaque material between the two glasses, and the welding efficiency is high. And the requirements for the glass welding surface are low, the light transmission performance of the product is not affected after welding, the welding quality can be improved, and the welding of the two glasses can also be realized when there is a large gap between them, which can meet the welding requirements. Reliable requirements, good shear strength, and good sealing performance of welded products, a wide range of applications.
请参考附图,本实施例提供了一种激光对射焊接装置,包括激光发生器6、第一聚焦镜15、第二聚焦镜18、样品台、未图示的位移台和工控机。激光发生器6配置成产生脉冲激光并作为第一脉冲激光2和第二脉冲激光3,样品台配置成放置第一玻璃4和第二玻璃5,第一玻璃4和第二玻璃5具有间隙地层叠设置。第一聚焦镜15设于激光发生器6和第一玻璃4之间,第一聚焦镜15配置成使第一脉冲激光2从第一玻璃4远离第二玻璃5的一侧入射至第一玻璃4和第二玻璃5之间的间隙处,从第一玻璃4入射的第一脉冲激光2的汇聚点可以位于该间隙处,也可以位于第一玻璃4上,还可以位于第二玻璃5上;第一脉冲激光2配置成在第一玻璃4靠近第二玻璃5的一侧产生等离子体来使第一玻璃4熔融,或在第二玻璃5靠近第一玻璃4的一侧产生等离子体来使第二玻璃5熔融,以焊接第一玻璃4 和第二玻璃5。第二聚焦镜18设于激光发生器6和第二玻璃5之间,第二聚焦镜18配置成使第二脉冲激光3从第二玻璃5远离第一玻璃4的一侧入射至第一玻璃4和第二玻璃5之间的间隙处,从第二玻璃5入射的第二脉冲激光3的汇聚点可以位于该间隙处,也可以位于第一玻璃4上,还可以位于第二玻璃5上;第二脉冲激光3配置成在第一玻璃4靠近第二玻璃5的一侧产生等离子体来使第一玻璃4熔融,或在第二玻璃5靠近第一玻璃4的一侧产生等离子体来使第二玻璃5熔融,以焊接第一玻璃4和第二玻璃5。可选地,本申请中的第一脉冲激光2和第二脉冲激光3分别为超短脉冲激光,超短脉冲激光主要指激光脉冲宽度小于纳秒的皮秒或飞秒脉冲激光,适用于间隙不大于5微米的玻璃或透光材质的焊接,超短脉冲激光波长可以为200nm至2000nm,脉宽可以小于或等于12ps,重复率可以大于等于1kHz。通过采用这样的超短脉冲激光,能够实现对玻璃的激光焊接。Referring to the drawings, this embodiment provides a laser butt beam welding device, including a laser generator 6 , a first focusing mirror 15 , a second focusing mirror 18 , a sample stage, a displacement stage not shown, and an industrial computer. The laser generator 6 is configured to generate pulsed laser light as the first pulsed laser light 2 and the second pulsed laser light 3, and the sample stage is configured to place the first glass 4 and the second glass 5 with a gap between the first glass 4 and the second glass 5. Cascading settings. The first focusing mirror 15 is arranged between the laser generator 6 and the first glass 4 , and the first focusing mirror 15 is configured so that the first pulsed laser 2 is incident on the first glass from the side of the first glass 4 away from the second glass 5 . At the gap between 4 and the second glass 5, the convergence point of the first pulsed laser 2 incident from the first glass 4 can be located at the gap, on the first glass 4, or on the second glass 5 The first pulsed laser 2 is configured to generate plasma on the side of the first glass 4 close to the second glass 5 to melt the first glass 4, or to generate plasma on the side of the second glass 5 close to the first glass 4 to The second glass 5 is melted to weld the first glass 4 and the second glass 5 . The second focusing mirror 18 is provided between the laser generator 6 and the second glass 5 , and the second focusing mirror 18 is configured so that the second pulsed laser 3 is incident on the first glass from the side of the second glass 5 away from the first glass 4 At the gap between 4 and the second glass 5, the convergence point of the second pulsed laser 3 incident from the second glass 5 can be located at the gap, on the first glass 4, or on the second glass 5 The second pulsed laser 3 is configured to generate plasma on the side of the first glass 4 close to the second glass 5 to melt the first glass 4, or to generate plasma on the side of the second glass 5 close to the first glass 4 to The second glass 5 is melted to weld the first glass 4 and the second glass 5 . Optionally, the first pulsed laser 2 and the second pulsed laser 3 in this application are respectively ultrashort pulsed lasers, and ultrashort pulsed lasers mainly refer to picosecond or femtosecond pulsed lasers with laser pulse widths less than nanoseconds, which are suitable for gaps. For welding of glass or light-transmitting materials not larger than 5 microns, the ultra-short pulse laser wavelength can be 200nm to 2000nm, the pulse width can be less than or equal to 12ps, and the repetition rate can be greater than or equal to 1kHz. By using such an ultra-short pulse laser, laser welding of glass can be realized.
需要说明的是,这里的层叠设置既可以是沿竖直方向叠放,如图1所示,叠放后第一玻璃4和第二玻璃5之间具有间隙并大致呈水平方向;也可以沿水平方向叠放,如图2所示,叠放后第一玻璃4和第二玻璃5之间具有间隙并大致呈竖直方向。当然,叠放后的第一玻璃4和第二玻璃5也可以相对水平方向具有一定的倾斜角度,这里不作具体限定。可选地,样品台上设有固定夹具1,配置成安装夹紧第一玻璃4和第二玻璃5。叠放后的第一玻璃4和第二玻璃5之间的间隙小于5微米,比如1微米、2微米、3微米或4微米等均可采用本实施例提供的激光对射焊接装置进行焊接。第一玻璃4和第二玻璃5可以是同种材质,也可以是异种材质。第一玻璃4和第二玻璃5之间的待焊接表面无需进行特殊的光学处理,降低了对玻璃表面质量的要求,无需光学接触条件,可直接进行焊接。It should be noted that the stacking arrangement here can either be stacked vertically, as shown in FIG. 1 , there is a gap between the first glass 4 and the second glass 5 after stacking and is approximately horizontal; When stacked in the horizontal direction, as shown in FIG. 2 , there is a gap between the first glass 4 and the second glass 5 after stacking, and the glass is approximately vertical. Of course, the stacked first glass 4 and the second glass 5 may also have a certain inclination angle relative to the horizontal direction, which is not specifically limited here. Optionally, a fixing fixture 1 is provided on the sample stage, which is configured to install and clamp the first glass 4 and the second glass 5 . The gap between the stacked first glass 4 and the second glass 5 is less than 5 microns, for example, 1 micron, 2 microns, 3 microns, or 4 microns, etc., can be welded by the laser beam welding device provided in this embodiment. The first glass 4 and the second glass 5 may be of the same material or may be of different materials. The surfaces to be welded between the first glass 4 and the second glass 5 do not need to be subjected to special optical treatment, which reduces the requirements for the quality of the glass surface, and can be directly welded without optical contact conditions.
可选地,第一脉冲激光2和第二脉冲激光3可以通过同一个激光发生器6产生,也可以通过两个激光发生器6分别产生。如图4所示,若第一脉冲激光2和第二脉冲激光3通过同一个激光发生器6产生,则在激光发生器6和第一玻璃4之间设有偏振分束镜13,即偏振分束镜13设于激光发生器6和样品台之间,偏振分束镜13配置成将激光发生器6发出的脉冲激光分为第一脉冲激光2和第二脉冲激光3。为了对激光发生器6发出的激光的光束直径和发散角进行调整,以优化光路结构,在激光发生器6和偏振分束镜13之间还可以设有扩束准直镜7。并且,在偏振分束镜13和第一聚焦镜15之间还可以设有第一导光镜14,以调整第一脉冲激光2的入射方向,第一聚焦镜15配置成调整第一脉冲激光2的汇聚点,以最大限度发挥第一脉冲激光2的能量进行焊接。在偏振分束镜13和第二聚焦镜18之间还设有第二导光镜16,以调整第二脉冲激光3的入射方向,第二聚焦镜18用于调整第二脉冲激光3的汇聚点,以最大限度发挥第二脉冲激光3的能量进行焊接。容易理解,根据激光发生器6、偏振分束镜13、第一玻璃4和第二玻璃5的相对位置关系,第一导光镜14和第二导光镜16的数量和位置均可以灵活调整,数量可以是一个或多个,这里不作 具体限定。Optionally, the first pulsed laser 2 and the second pulsed laser 3 may be generated by the same laser generator 6 , or may be generated by two laser generators 6 respectively. As shown in FIG. 4 , if the first pulsed laser 2 and the second pulsed laser 3 are generated by the same laser generator 6, a polarization beam splitter 13 is provided between the laser generator 6 and the first glass 4, that is, a polarization beam splitter 13 is provided. The beam splitter 13 is provided between the laser generator 6 and the sample stage, and the polarization beam splitter 13 is configured to divide the pulsed laser light emitted by the laser generator 6 into a first pulsed laser light 2 and a second pulsed laser light 3 . In order to adjust the beam diameter and divergence angle of the laser light emitted by the laser generator 6 to optimize the optical path structure, a beam expander collimator 7 may also be provided between the laser generator 6 and the polarization beam splitter 13 . In addition, a first light guide mirror 14 may also be provided between the polarization beam splitter 13 and the first focusing mirror 15 to adjust the incident direction of the first pulsed laser 2 , and the first focusing mirror 15 is configured to adjust the first pulsed laser 2, to maximize the energy of the first pulsed laser 2 for welding. A second light guide mirror 16 is further arranged between the polarization beam splitter 13 and the second focusing mirror 18 to adjust the incident direction of the second pulsed laser light 3 , and the second focusing mirror 18 is used to adjust the convergence of the second pulsed laser light 3 point to maximize the energy of the second pulsed laser 3 for welding. It is easy to understand that according to the relative positional relationship between the laser generator 6, the polarizing beam splitter 13, the first glass 4 and the second glass 5, the number and position of the first light guide mirror 14 and the second light guide mirror 16 can be flexibly adjusted , the number can be one or more, which is not specifically limited here.
这样,激光发生器6发出的光束经扩束准直镜7调整光束直径和发散角之后,到达偏振分束镜13,由偏振分束镜13分为第一脉冲激光2和第二脉冲激光3,第一脉冲激光2依次经过一个第一导光镜14和第一聚焦镜15,从第一玻璃4的表面入射,形成第一光路。进一步地,在第一光路中,第一导光镜14相对水平方向呈135度角设置,使第一脉冲激光2在第一导光镜14处发生偏折角为90度的反射,经第一聚焦镜15大致垂直地入射至第一玻璃4。第二脉冲激光3依次经过两个第二导光镜16和第二聚焦镜18,从第二玻璃5的表面入射,形成第二光路。进一步地,在第二光路中,两个第二导光镜16间隔设置,靠近偏振分束镜13的第二导光镜16(第一个第二导光镜16)相对水平方向呈135度角设置,使第二脉冲激光3在第一个第二导光镜16处发生偏折角为90度的反射,并到达第二个第二导光镜16(靠近第二聚焦镜18的第二导光镜16),第二个第二导光镜16相对水平方向呈45度角设置,使第二脉冲激光3在第二个第二导光镜16处发生偏折角为90度的反射,经第二聚焦镜18大致垂直地入射至第二玻璃5一侧。In this way, the beam emitted by the laser generator 6 reaches the polarization beam splitter 13 after adjusting the beam diameter and divergence angle by the beam expander collimator 7, and is divided into the first pulse laser 2 and the second pulse laser 3 by the polarization beam splitter 13 , the first pulsed laser 2 passes through a first light guide mirror 14 and a first focusing mirror 15 in sequence, and is incident from the surface of the first glass 4 to form a first optical path. Further, in the first optical path, the first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction, so that the first pulsed laser 2 is reflected at the first light guide mirror 14 with a deflection angle of 90 degrees. The focusing mirror 15 is incident on the first glass 4 approximately perpendicularly. The second pulsed laser 3 passes through the two second light guide mirrors 16 and the second focusing mirror 18 in sequence, and is incident from the surface of the second glass 5 to form a second optical path. Further, in the second optical path, two second light guide mirrors 16 are arranged at intervals, and the second light guide mirror 16 (the first second light guide mirror 16 ) close to the polarization beam splitter 13 is 135 degrees relative to the horizontal direction. The angle is set so that the second pulsed laser light 3 is reflected at the first second light guide mirror 16 with a deflection angle of 90 degrees, and reaches the second second light guide mirror 16 (the second one near the second focusing mirror 18). Light guide mirror 16), the second second light guide mirror 16 is arranged at an angle of 45 degrees relative to the horizontal direction, so that the second pulsed laser 3 is reflected at the second second light guide mirror 16 with a deflection angle of 90 degrees, It is incident on the side of the second glass 5 approximately vertically through the second focusing mirror 18 .
进一步地,第一脉冲激光2在第一玻璃4远离第二玻璃5的一侧入射至第一玻璃4的方向与第二脉冲激光3在第二玻璃5远离第一玻璃4的一侧入射至第二玻璃5的方向位于同一直线上,即如图1和图2所示,第一光路中的第一脉冲激光2从第一聚焦镜15到第一玻璃4的第一入射光路与第二光路中的第一脉冲激光3从第二聚焦镜18到第二玻璃5的第二入射光路位于同一直线上。即第一脉冲激光2的汇聚点和第二脉冲激光3的汇聚点为都位于该同一直线上。此外,第一脉冲激光2在第一玻璃4一侧的入射角可以大于0度且小于等于90度,第二脉冲激光3在第二玻璃5一侧的入射角可以大于0度且小于等于90度。本实施例中,第一脉冲激光2以大致垂直于第一玻璃4表面的角度入射,第二脉冲激光3以大致垂直于第二玻璃5表面的角度入射,这里不作具体限定。Further, the first pulsed laser 2 is incident on the first glass 4 on the side of the first glass 4 away from the second glass 5 and the second pulsed laser 3 is incident on the side of the second glass 5 away from the first glass 4 . The directions of the second glass 5 are located on the same straight line, that is, as shown in FIG. 1 and FIG. 2 , the first incident optical path of the first pulsed laser 2 in the first optical path from the first focusing mirror 15 to the first glass 4 and the second In the optical path, the second incident optical path of the first pulsed laser 3 from the second focusing mirror 18 to the second glass 5 is located on the same straight line. That is, the converging point of the first pulsed laser light 2 and the converging point of the second pulsed laser light 3 are both located on the same straight line. In addition, the incident angle of the first pulsed laser 2 on the side of the first glass 4 can be greater than 0 degrees and less than or equal to 90 degrees, and the incident angle of the second pulsed laser 3 on the side of the second glass 5 can be greater than 0 degrees and less than or equal to 90 degrees Spend. In this embodiment, the first pulsed laser 2 is incident at an angle substantially perpendicular to the surface of the first glass 4 , and the second pulsed laser 3 is incident at an angle substantially perpendicular to the surface of the second glass 5 , which is not specifically limited here.
另外,如图3A、3B所示,第一脉冲激光2的第一入射光路和第二脉冲激光3的第二入射光路也可以不位于同一条直线,可以相互平行,也可以是延长线交叉,所说的延长线交叉指,第一入射光路的延长线与第二入射光路的延长线交叉。在第一入射光路和第二入射光路相互平行的情况下,第一脉冲激光2的汇聚点和第二脉冲激光3的汇聚点在与第一玻璃4和第二玻璃5的排列方向垂直的方向上错开,在第一入射光路和第二入射光路延长线相互交叉的情况下,第一脉冲激光2的汇聚点和第二脉冲激光3的汇聚点在与第一玻璃4和第二玻璃5的排列方向垂直的方向上既可以位于同一高度,也可以相互错开。In addition, as shown in FIGS. 3A and 3B , the first incident optical path of the first pulsed laser 2 and the second incident optical path of the second pulsed laser 3 may not be located on the same straight line, but may be parallel to each other, or may be extended lines intersecting, The extension line crossing refers to that the extension line of the first incident light path intersects the extension line of the second incident light path. When the first incident light path and the second incident light path are parallel to each other, the converging point of the first pulsed laser light 2 and the converging point of the second pulsed laser light 3 are in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5 When the extension lines of the first incident optical path and the second incident optical path cross each other, the converging point of the first pulsed laser 2 and the converging point of the second pulsed laser The vertical direction of the arrangement direction can be located at the same height or staggered from each other.
如图5所示,若第一脉冲激光2和第二脉冲激光3通过两个激光发生器产生,则激光发生器6包括第一发生器8和第二发生器9,第一发生器8配置成产生第一脉冲激光2,第二发生器9配置成产生第二脉冲激光3。可选地,第一发生器8和第二发生器9分设于样 品台的两侧,即第一发生器8位于第一玻璃4一侧,第二发生器9位于第二玻璃5一侧。第一发生器8与第一玻璃4之间依次设有第一扩束准直镜10、两个第一导光镜14和一个第一聚焦镜15,第一发生器8发出的第一脉冲激光2经第一扩束准直镜10调整光束直径和发散角之后到达第一个第一导光镜14,该第一导光镜14相对水平方向呈135度角设置,使第一脉冲激光2在第一个第一导光镜14处发生偏折角为90度的反射,再到达第二个第一导光镜14,第二个第一导光镜14相对水平方向呈135度角设置,使第一脉冲激光2在第二个第一导光镜14处发生偏折角为90度的反射,经第一聚焦镜15后大致垂直地入射至第一玻璃4一侧。第二发生器9与第二玻璃5之间依次设有第二扩束准直镜20、两个第二导光镜16和一个第二聚焦镜18,第二发生器9发出的第二脉冲激光3经第二扩束准直镜20调整光束直径和发散角之后到达第一个第二导光镜16,该第二导光镜16相对水平方向呈45度角设置,使第一脉冲激光3在第一个第二导光镜16处发生偏折角为90度的反射,再射向第二个第二导光镜16,第二个第二导光镜16相对水平方向呈45度角设置,使第二脉冲激光3在第二个第二导光镜16处发生偏折角为90度的反射,经第二聚焦镜18后大致垂直地入射至第二玻璃5一侧。需要说明的是,若对第一发生器8的布设位置进行调整,使得第一发生器8发出的第一脉冲激光2垂直于第一玻璃4表面或以实际所需的预设角度入射,则可以省略第一导光镜14的设置。同理,若对第二发生器9的布设位置进行调整,使得第二发生器9发出的第二脉冲激光3垂直于第二玻璃5表面或以实际所需的预设角度入射,则可以省略第二导光镜16的设置。As shown in FIG. 5 , if the first pulsed laser 2 and the second pulsed laser 3 are generated by two laser generators, the laser generator 6 includes a first generator 8 and a second generator 9, and the first generator 8 is configured In order to generate the first pulsed laser light 2 , the second generator 9 is configured to generate the second pulsed laser light 3 . Optionally, the first generator 8 and the second generator 9 are respectively arranged on two sides of the sample stage, that is, the first generator 8 is located on the side of the first glass 4, and the second generator 9 is located on the side of the second glass 5. A first beam expander collimator 10, two first light guide mirrors 14 and a first focusing mirror 15 are arranged between the first generator 8 and the first glass 4 in sequence. The first pulse emitted by the first generator 8 The laser 2 reaches the first first light guide mirror 14 after adjusting the beam diameter and the divergence angle of the first beam expander collimator 10. The first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction, so that the first pulsed laser 2. A reflection with a deflection angle of 90 degrees occurs at the first first light guide mirror 14, and then reaches the second first light guide mirror 14. The second first light guide mirror 14 is arranged at an angle of 135 degrees relative to the horizontal direction , so that the first pulsed laser light 2 is reflected at the second first light guide mirror 14 with a deflection angle of 90 degrees, and after passing through the first focusing mirror 15 , it is incident on the side of the first glass 4 approximately vertically. A second beam expander collimator 20, two second light guide mirrors 16 and a second focusing mirror 18 are arranged between the second generator 9 and the second glass 5 in sequence. The second pulse emitted by the second generator 9 The laser 3 reaches the first second light guide mirror 16 after adjusting the beam diameter and the divergence angle of the second beam expander collimator 20. The second light guide mirror 16 is arranged at an angle of 45 degrees relative to the horizontal direction, so that the first pulsed laser 3. A reflection with a deflection angle of 90 degrees occurs at the first second light guide mirror 16, and then it is emitted to the second second light guide mirror 16, and the second second light guide mirror 16 is at an angle of 45 degrees relative to the horizontal direction. It is set so that the second pulsed laser 3 is reflected at the second second light guide mirror 16 with a deflection angle of 90 degrees, and is incident on the side of the second glass 5 approximately vertically after passing through the second focusing mirror 18 . It should be noted that, if the arrangement position of the first generator 8 is adjusted so that the first pulsed laser 2 emitted by the first generator 8 is perpendicular to the surface of the first glass 4 or incident at an actual required preset angle, then The provision of the first light guide mirror 14 may be omitted. Similarly, if the arrangement position of the second generator 9 is adjusted so that the second pulsed laser 3 emitted by the second generator 9 is perpendicular to the surface of the second glass 5 or incident at the actual required preset angle, it can be omitted. Arrangement of the second light guide mirror 16 .
可选地,样品台上设有固定夹具1,第一玻璃4和第二玻璃5安装在固定夹具1上。位移台与样品台连接,配置成调整样品台的位置。工控机分别与激光发生器6和位移台连接,并配置成控制激光发生器6发出第一脉冲激光2和第二脉冲激光3,控制位移台移动,调整第一脉冲激光2的频率、单脉冲能量以及在第一玻璃4表面的入射角度和速度等,调整第二脉冲激光3的频率、单脉冲能量以及在第二玻璃5表面的入射角度和速度等,实现自动、快速、精准的焊接。Optionally, a fixing fixture 1 is provided on the sample stage, and the first glass 4 and the second glass 5 are mounted on the fixing fixture 1 . The translation stage is connected to the sample stage and configured to adjust the position of the sample stage. The industrial computer is respectively connected with the laser generator 6 and the displacement stage, and is configured to control the laser generator 6 to emit the first pulsed laser 2 and the second pulsed laser 3, control the movement of the displacement stage, and adjust the frequency and single pulse of the first pulsed laser 2. The frequency and single-pulse energy of the second pulse laser 3 and the incident angle and speed on the surface of the second glass 5 are adjusted according to the energy and the incident angle and speed on the surface of the first glass 4 to achieve automatic, fast and accurate welding.
本申请实施例提供的激光对射焊接装置,其工作原理如下:The working principle of the laser butt beam welding device provided in the embodiment of the present application is as follows:
以图1所示的水平状态放置的第一玻璃4和第二玻璃5且第一入射光路与第二入射光路位于同一直线上为例,第一玻璃4为上层玻璃,第二玻璃5为下层玻璃。第一脉冲激光2从第一玻璃4的表面入射,第一脉冲激光2采用超短脉冲激光,第一脉冲激光2在第一聚焦镜15的作用下聚焦于第一玻璃4的靠间隙一侧的表面或内部,与第一玻璃4产生非线性相互作用而沉积激光能量并形成熔池,熔池内的熔融物在热压力和重力的挤压下会向第二玻璃5方向产生喷溅,并最终实现第一玻璃4与第二玻璃5之间的连接。Taking the first glass 4 and the second glass 5 placed in a horizontal state as shown in FIG. 1 and the first incident light path and the second incident light path are on the same line as an example, the first glass 4 is the upper glass, and the second glass 5 is the lower layer. Glass. The first pulsed laser 2 is incident from the surface of the first glass 4 , the first pulsed laser 2 adopts an ultra-short pulsed laser, and the first pulsed laser 2 is focused on the side of the first glass 4 near the gap under the action of the first focusing mirror 15 On the surface or inside of the glass, it interacts with the first glass 4 nonlinearly to deposit laser energy and form a molten pool. The molten material in the molten pool will splash in the direction of the second glass 5 under the extrusion of thermal pressure and gravity, and The connection between the first glass 4 and the second glass 5 is finally achieved.
类似地,第二脉冲激光3从第二玻璃5的表面入射,与第一脉冲激光2相同,第二脉 冲激光3与第二玻璃5产生非线性相互作用而沉积激光能量并形成熔池,通过第二玻璃5材料产生的喷溅来实现焊接第一玻璃4和第二玻璃5。容易理解,以往,利用激光从单侧对两玻璃进行焊接,由于焦点处产生的熔融物非常有限,因而能够连接的间隙也有限。而在本实施例中,采用第一脉冲激光2和第二脉冲激光3对射,在各自的汇聚点处产生更多的熔融物,能实现更大间隙的焊接,适用范围更广。Similarly, the second pulsed laser 3 is incident from the surface of the second glass 5, which is the same as the first pulsed laser 2. The second pulsed laser 3 interacts with the second glass 5 nonlinearly to deposit laser energy and form a molten pool. The splash generated by the material of the second glass 5 realizes the welding of the first glass 4 and the second glass 5 . It is easy to understand that in the past, when two glasses were welded from one side by a laser, the molten material generated at the focal point was very limited, and the gap that could be connected was also limited. However, in this embodiment, the first pulsed laser 2 and the second pulsed laser 3 are used in opposite directions to generate more melts at their respective convergence points, which can realize welding with a larger gap and have a wider application range.
另外,在第一入射光路与第二入射光路不位于同一直线而平行或延长线交叉的情况下,如图3A和图3B所示,第一脉冲激光2的汇聚点和第二脉冲激光3的汇聚点在与第一玻璃4和第二玻璃5的排列方向垂直的方向上错开或位于同一高度。在这种情况下,第一脉冲激光2在第一聚焦镜15的作用下聚焦于第一玻璃4的靠第二玻璃5一侧的表面或内部,或聚焦于第二玻璃5的靠第一玻璃4的一侧的表面或内部,第二脉冲激光3在第二聚焦镜18的作用下聚焦于第二玻璃5的靠第一玻璃4的一侧的表面或内部,或聚焦于第一玻璃4的靠第二玻璃5一侧的表面或内部,在第一脉冲激光2聚焦于第一玻璃4的靠第二玻璃5一侧的表面或内部,以及第二脉冲激光3聚焦于第二玻璃5的靠第一玻璃4的一侧的表面或内部的情况与上述相同,因此省略说明。In addition, when the first incident light path and the second incident light path are not located on the same straight line but intersect with parallel or extended lines, as shown in FIG. 3A and FIG. 3B , the convergence point of the first pulsed laser 2 and the second pulsed laser 3 The convergence points are staggered in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5 or are located at the same height. In this case, the first pulsed laser 2 is focused on the surface or inside of the first glass 4 on the side of the second glass 5 under the action of the first focusing mirror 15 , or on the second glass 5 on the side of the first glass 5 . On the surface or inside of one side of the glass 4, the second pulsed laser 3 is focused on the surface or inside of the second glass 5 on the side of the first glass 4 under the action of the second focusing mirror 18, or is focused on the first glass 4 on the surface or inside of the second glass 5 side, where the first pulsed laser 2 is focused on the surface or inside of the first glass 4 on the second glass 5 side, and the second pulsed laser 3 is focused on the second glass The case of the surface or the inside of the side close to the first glass 4 of 5 is the same as the above, so the description is omitted.
下面说明第一脉冲激光2聚焦于第二玻璃5的靠第一玻璃4的一侧的表面或内部,以及第二脉冲激光3聚焦于第一玻璃4的靠第二玻璃5的一侧的表面或内部的情况。在该情况下,第一脉冲激光2与第二玻璃5产生非线性相互作用而沉积激光能量并形成熔池,熔池内的熔融物在热压力和重力的挤压下会向第一玻璃4方向产生喷溅,并最终实现第一玻璃4与第二玻璃5之间的连接。也就是说,第一脉冲激光2与第二玻璃5产生非线性相互作用而产生等离子体,等离子体对激光具有强烈的吸收特性,会对后续的第一脉冲激光2产生屏蔽效应,使其无法穿透等离子体而作用于原来的焦点处,因而后续第一脉冲激光2的作用点就会高于之前的汇聚点,这又会导致第二玻璃5的该处再次被激光诱导产生等离子体。随着激光脉冲数量的增加,等离子体区将呈现从原来的汇聚点处向第一脉冲激光2的光源方向扩展的现象,即等离子体区域的扩展方向从第二玻璃5的靠间隙一侧向第一玻璃4方向即第一脉冲激光2的光源方向蔓延。同时,等离子体区会通过热扩散效应将能量传递给周围材料,形成外部的熔融改性区,使第二玻璃5的该区域熔融,在第一脉冲激光2和等离子体的双重作用下构成了水滴状双结构作用区,该双结构作用区域的最下端为第一脉冲激光2的原来的汇聚点位置。因此,采用超短脉冲激光聚焦于第二玻璃5实施焊接时,激光作用区总是从第一玻璃4开始向光源处发展,通过第二玻璃5材料产生的凸起或喷溅来实现第一玻璃4与第二玻璃5之间的连接,即第一脉冲激光2的作用区从第二玻璃5的靠间隙一侧表面向第一脉冲激光2的光源处发展,以焊接第一玻璃4和第二玻璃5。The following describes that the first pulsed laser 2 is focused on the surface or the inside of the second glass 5 on the side of the first glass 4 , and the second pulsed laser 3 is focused on the surface of the first glass 4 on the side of the second glass 5 . or internal conditions. In this case, the first pulsed laser 2 and the second glass 5 interact nonlinearly to deposit laser energy and form a molten pool, and the molten material in the molten pool will move towards the first glass 4 under the extrusion of thermal pressure and gravity Splashes are generated and the connection between the first glass 4 and the second glass 5 is finally achieved. That is to say, the first pulsed laser 2 interacts with the second glass 5 nonlinearly to generate plasma, and the plasma has strong absorption characteristics for the laser, which will have a shielding effect on the subsequent first pulsed laser 2, making it impossible to By penetrating the plasma and acting on the original focus, the acting point of the subsequent first pulsed laser 2 will be higher than the previous convergence point, which will cause the second glass 5 to be induced by the laser to generate plasma again. With the increase of the number of laser pulses, the plasma region will expand from the original convergence point to the light source direction of the first pulsed laser 2 , that is, the expansion direction of the plasma region will be from the gap side of the second glass 5 . The first glass 4 spreads in the direction of the light source of the first pulsed laser 2 . At the same time, the plasma area will transfer energy to the surrounding materials through the thermal diffusion effect, forming an external melting modification area, so that this area of the second glass 5 is melted. Under the dual action of the first pulsed laser 2 and the plasma, the The droplet-shaped double-structure action area, the lowermost end of the double-structure action area is the original converging point position of the first pulsed laser 2 . Therefore, when the ultra-short pulse laser is used to focus on the second glass 5 for welding, the laser action area always develops from the first glass 4 to the light source, and the first glass 5 is produced by protrusions or splashes generated by the second glass 5. The connection between the glass 4 and the second glass 5, that is, the action area of the first pulsed laser 2 develops from the surface of the second glass 5 near the gap to the light source of the first pulsed laser 2, so as to weld the first glass 4 and the second glass 5. The second glass 5 .
类似地,在第二脉冲激光3与第一脉冲激光2相同,第二脉冲激光3的作用区从第一 玻璃4的靠第二玻璃5的一侧的表面向第二脉冲激光3的光源处发展,通过第一玻璃4材料产生的凸起或喷溅来实现焊接第一玻璃4和第二玻璃5。容易理解,以往,利用激光从单侧对两玻璃进行焊接,由于焦点处产生的熔融物非常有限,因而能够连接的间隙也有限。而在本实施例中,采用第一脉冲激光2和第二脉冲激光3对射,在各自的汇聚点处产生更多的熔融物,能实现更大间隙的焊接,适用范围更广。Similarly, when the second pulsed laser 3 is the same as the first pulsed laser 2, the action area of the second pulsed laser 3 is from the surface of the first glass 4 on the side of the second glass 5 to the light source of the second pulsed laser 3 Development, the welding of the first glass 4 and the second glass 5 is achieved by bulges or splashes produced by the material of the first glass 4 . It is easy to understand that in the past, when two glasses were welded from one side by a laser, the molten material generated at the focal point was very limited, and the gap that could be connected was also limited. However, in this embodiment, the first pulsed laser 2 and the second pulsed laser 3 are used in opposite directions to generate more melts at their respective convergence points, which can realize welding with a larger gap and have a wider application range.
本申请实施例还提供一种激光对射焊接方法,由激光对射焊接装置执行,配置成实现第一玻璃4和第二玻璃5的焊接,第一玻璃4和第二玻璃5具有间隙地层叠设置,由激光对射焊接装置的未图示的控制器执行指令或命令来实现激光对射焊接方法的一下各步骤:Embodiments of the present application further provide a laser butt beam welding method, which is performed by a laser butt beam welding device and configured to realize welding of a first glass 4 and a second glass 5 that are stacked with a gap. The following steps of the laser butt-beam welding method are implemented by executing instructions or commands from the controller (not shown) of the laser-but-beam welding device:
从第一玻璃4远离第二玻璃5的一侧入射第一脉冲激光2,第一脉冲激光2聚焦于第一玻璃4或第二玻璃5;第一脉冲激光2配置成在第一玻璃4的靠第二玻璃5一侧产生等离子体并使第一玻璃4熔融或在第二玻璃5靠近第一玻璃4的一侧产生等离子体并使第二玻璃5熔融,以焊接第一玻璃4和第二玻璃5;从第二玻璃5远离第一玻璃4的一侧入射第二脉冲激光3,第二脉冲激光3聚焦于第一玻璃4或第二玻璃5;第二脉冲激光3配置成在第一玻璃4靠近第二玻璃5的一侧产生等离子体并使第一玻璃4熔融或在第二玻璃5靠近第一玻璃4的一侧产生等离子体并使第二玻璃5熔融,以焊接第一玻璃4和第二玻璃5。采用第一脉冲激光2和第二脉冲激光3对射的方式,第一脉冲激光2和第二脉冲激光3采用超短脉冲激光,可以在第一玻璃4和第二玻璃5之间形成更多的等离子体以及熔融物,实现更大间隙的玻璃焊接,焊接质量可靠,具有良好的剪切性能和密封性能。并且无需引入不透光材质,降低了对玻璃表面质量的要求,无需光学接触条件,焊接更加高效,不影响焊接后产品的透光性能。The first pulsed laser 2 is incident from the side of the first glass 4 away from the second glass 5 , and the first pulsed laser 2 is focused on the first glass 4 or the second glass 5 ; Generate plasma on the side of the second glass 5 and melt the first glass 4 or generate plasma on the side of the second glass 5 close to the first glass 4 and melt the second glass 5 to weld the first glass 4 and the second glass 5. Two glasses 5; the second pulsed laser 3 is incident from the side of the second glass 5 away from the first glass 4, and the second pulsed laser 3 is focused on the first glass 4 or the second glass 5; the second pulsed laser 3 is configured to A glass 4 near the second glass 5 generates plasma and melts the first glass 4 or generates plasma on the side of the second glass 5 near the first glass 4 and melts the second glass 5 to weld the first glass 5 Glass 4 and second glass 5. The first pulsed laser 2 and the second pulsed laser 3 are used against each other, and the first pulsed laser 2 and the second pulsed laser 3 are ultra-short pulsed lasers, which can form more The plasma and molten material can be used to realize glass welding with a larger gap. The welding quality is reliable, and it has good shear performance and sealing performance. In addition, there is no need to introduce opaque materials, which reduces the requirements for the quality of the glass surface, and does not require optical contact conditions. The welding is more efficient, and the light transmission performance of the welded product is not affected.
可选地,第一脉冲激光2经第一聚焦镜15后从第一玻璃4入射并聚焦于第一汇聚点,第二脉冲激光3经第二聚焦镜18后从第二玻璃5入射并聚焦于第二汇聚点,第一脉冲激光2的从第一聚焦镜15到第一玻璃4的第一入射光路与第二脉冲激光3的从第二聚焦镜18到第二玻璃5的第二入射光路位于同一直线上,第一汇聚点和第二汇聚点处于该同一直线上,第一汇聚点为第一玻璃4的靠间隙一侧的表面与上述的同一直线的交点,第二汇聚点为第二玻璃5的靠间隙一侧的表面与上述的同一直线的交点。Optionally, the first pulsed laser 2 is incident from the first glass 4 after passing through the first focusing mirror 15 and is focused on the first convergence point, and the second pulsed laser 3 is incident and focused from the second glass 5 after passing through the second focusing mirror 18 . At the second convergence point, the first incident light path of the first pulsed laser 2 from the first focusing mirror 15 to the first glass 4 and the second incident light path of the second pulsed laser 3 from the second focusing mirror 18 to the second glass 5 The optical paths are located on the same straight line, the first convergence point and the second convergence point are on the same straight line, the first convergence point is the intersection of the surface of the first glass 4 on the side of the gap and the above-mentioned same straight line, and the second convergence point is An intersection of the surface of the second glass 5 on the side of the gap and the same straight line described above.
另外,第一入射光路和第二入射光路也可以不在同一直线上,相互平行或交叉,第一汇聚点和第二汇聚点在与第一玻璃4和第二玻璃5的排列方向垂直的方向上错开,第一汇聚点为第一玻璃4的靠间隙一侧的表面与第一入射光路的交点或第二玻璃5的靠间隙一侧的表面与第一入射光路的交点,第二汇聚点为第一玻璃4的靠间隙一侧的表面与第二入射光路的交点或第二玻璃5的靠间隙一侧的表面与第二入射光路的交点;第一玻璃4和第二玻璃5可以是同种材质,也可以是不同材质,这里不作具体限定。进一步地,本实施例中, 第一脉冲激光2垂直于第一玻璃4表面入射,第二脉冲激光3垂直于第二玻璃5表面入射,以充分发挥第一脉冲激光2和第二脉冲激光3的能量,使其在第一汇聚点和第二汇聚点处沉积的能量更充分,产生更多的熔融物,提高焊接质量,适用更大间隙的第一玻璃4和第二玻璃5的焊接,增强焊接后产品的剪切性能和密封性能。In addition, the first incident light path and the second incident light path may not be on the same straight line, but parallel or intersect with each other, and the first converging point and the second converging point are in a direction perpendicular to the arrangement direction of the first glass 4 and the second glass 5 Staggered, the first convergence point is the intersection of the surface of the first glass 4 on the side of the gap and the first incident optical path or the intersection of the surface of the second glass 5 on the side of the gap and the first incident optical path, and the second convergence point is The intersection of the surface of the first glass 4 on the side of the gap and the second incident light path or the intersection of the surface of the second glass 5 on the side of the gap and the second incident light path; the first glass 4 and the second glass 5 may be the same It can also be a different material, which is not specifically limited here. Further, in this embodiment, the first pulsed laser 2 is incident perpendicular to the surface of the first glass 4, and the second pulsed laser 3 is incident perpendicular to the surface of the second glass 5, so as to give full play to the first pulsed laser 2 and the second pulsed laser 3. The energy deposited at the first convergence point and the second convergence point is more sufficient, more molten material is generated, the welding quality is improved, and the welding of the first glass 4 and the second glass 5 with a larger gap is suitable. Enhances shear and sealing properties of welded products.
以具体的试验例进行说明如下:The specific test examples are described as follows:
试验例1Test Example 1
待焊接的玻璃样品即第一玻璃4和第二玻璃5均为钠钙玻璃,利用固定夹具1以使间距约为2μm的方式固定第一玻璃4和第二玻璃5,所用超短脉冲激光波长为1030nm,脉宽为350fs,重复率1MHz、单脉冲能量0.6μJ、速度20mm/s,经测试,焊接后的产品可承受约20Kg的推拉力,气密性可达5×10 -10Pa.m 3/s,表明样品具备良好的剪切强度和密封性能。 The glass samples to be welded, that is, the first glass 4 and the second glass 5 are both soda lime glass, and the first glass 4 and the second glass 5 are fixed by the fixing fixture 1 so that the distance is about 2 μm, and the ultra-short pulse laser wavelength is used. It is 1030nm, the pulse width is 350fs, the repetition rate is 1MHz, the single pulse energy is 0.6μJ, and the speed is 20mm/s. After testing, the welded product can withstand a push-pull force of about 20Kg, and the air tightness can reach 5×10 -10 Pa. m 3 /s, indicating that the sample has good shear strength and sealing performance.
试验例2Test Example 2
待焊接的玻璃样品即第一玻璃4和第二玻璃5均为D263硼硅玻璃,利用固定夹具1以使间距约为3μm的方式固定第一玻璃4和第二玻璃5,所用超短脉冲激光波长为1030nm,脉宽为350fs,重复率1MHz、单脉冲能量1μJ、速度24mm/s,经测试,焊接后的产品可承受约15Kg的推拉力,气密性可达2×10 -10Pa.m 3/s,表明样品具备良好的剪切强度和密封性能。 The glass samples to be welded, that is, the first glass 4 and the second glass 5 are both D263 borosilicate glass, and the first glass 4 and the second glass 5 are fixed by the fixing fixture 1 in a way that the distance is about 3 μm, and the ultra-short pulse laser is used. The wavelength is 1030nm, the pulse width is 350fs, the repetition rate is 1MHz, the single pulse energy is 1μJ, and the speed is 24mm/s. After testing, the welded product can withstand a push-pull force of about 15Kg, and the air tightness can reach 2×10 -10 Pa. m 3 /s, indicating that the sample has good shear strength and sealing performance.
试验例3Test Example 3
待焊接的玻璃样品中,第一玻璃4为D263硼硅玻璃,第二玻璃5为石英玻璃,利用固定夹具1以使间距约为2μm的方式固定第一玻璃4和第二玻璃5,所用超短脉冲激光波长为1030nm,脉宽为350fs,重复率1MHz、单脉冲能量1μJ、速度12mm/s,经测试,焊接后的产品可承受约25Kg的推拉力,气密性可达8×10 -10Pa.m 3/s,表明样品具备良好的剪切强度和密封性能。 Among the glass samples to be welded, the first glass 4 is D263 borosilicate glass, and the second glass 5 is quartz glass. The first glass 4 and the second glass 5 are fixed by the fixing jig 1 so that the distance is about 2 μm. The short pulse laser wavelength is 1030nm, the pulse width is 350fs, the repetition rate is 1MHz, the single pulse energy is 1μJ, and the speed is 12mm/s. After testing, the welded product can withstand a push-pull force of about 25Kg, and the air tightness can reach 8×10 - 10 Pa.m 3 /s, indicating that the sample has good shear strength and sealing performance.
由此可以看出,通过本实施例提供的激光对射焊接装置和方法,能够适用于较大间隙即小于或等于5微米的玻璃焊接,降低了对玻璃表面质量的要求,无需光学接触条件,并具有良好的剪切强度和密封性能。无需单独引入不透光材料,提高了焊接效率和质量,同时降低了焊接工艺要求及焊接成本。It can be seen from this that the laser butt-beam welding device and method provided in this embodiment can be applied to glass welding with a large gap, that is, less than or equal to 5 microns, which reduces the requirements for the quality of the glass surface and does not require optical contact conditions. And has good shear strength and sealing performance. There is no need to introduce opaque materials separately, which improves welding efficiency and quality, and reduces welding process requirements and welding costs.
综上所述,本申请实施例提供了一种激光对射焊接装置和方法,具有以下几个方面的有益效果:To sum up, the embodiments of the present application provide a laser butt beam welding device and method, which have the following beneficial effects:
该激光对射焊接装置包括激光发生器、第一聚焦镜和第二聚焦镜,激光发生器发出的脉冲激光作为第一脉冲激光和第二脉冲激光分别从第一玻璃和第二玻璃的两侧对射,即第一脉冲激光从第一玻璃一侧入射至第一玻璃和第二玻璃之间的间隙处,第二脉冲激光从第二玻璃一侧入射至第一玻璃和第二玻璃之间的间隙处。第一脉冲激光在第一聚焦镜的作用 下聚焦于第二玻璃靠近第一玻璃的一侧或第一玻璃靠近第二玻璃的一侧,与第二玻璃或第一玻璃产生非线性相互作用而产生等离子体,等离子体对激光的强烈吸收,会对后续的第一脉冲激光产生屏蔽效应,使其无法穿透等离子体而作用于原来的焦点处。随着激光脉冲数量的增加,等离子体区将呈现从焦点处向第一脉冲激光的光源方向扩展的现象。同时,等离子体区会通过热扩散效应将能量传递给周围材料,形成外部的熔融改性区,以焊接第一玻璃和第二玻璃。并且,由于第一脉冲激光和第二脉冲激光对射,第二脉冲激光在第二聚焦镜的作用下聚焦于第一玻璃靠近第二玻璃的一侧或第二玻璃靠近第一玻璃的一侧,并与第一玻璃或第二玻璃产生非线性相互作用而产生等离子体,会对后续的第二脉冲激光产生屏蔽效应,使其无法穿透等离子体而作用于原来的焦点处,使得等离子体区将呈现从焦点处向第二脉冲激光的光源方向扩展的现象。并通过热扩散效应将能量传递给周围材料,形成外部的熔融改性区,以焊接第一玻璃和第二玻璃。这种对射焊接装置结构简单,无需在第一玻璃和第二玻璃之间引入不透光材料,对玻璃焊接表面的光学要求较低,能实现在具有较大间隙的情况下对第一玻璃和第二玻璃焊接,提高焊接质量和效率。The laser butt welding device includes a laser generator, a first focusing mirror and a second focusing mirror. The pulsed laser emitted by the laser generator is used as the first pulsed laser and the second pulsed laser from two sides of the first glass and the second glass respectively. Opposite radiation, that is, the first pulsed laser is incident from the first glass side to the gap between the first glass and the second glass, and the second pulsed laser is incident from the second glass side to the space between the first glass and the second glass the gap. The first pulsed laser is focused on the side of the second glass close to the first glass or the side of the first glass close to the second glass under the action of the first focusing mirror, and produces nonlinear interaction with the second glass or the first glass. Plasma is generated, and the strong absorption of the laser by the plasma will produce a shielding effect on the subsequent first pulsed laser, so that it cannot penetrate the plasma and act on the original focus. As the number of laser pulses increases, the plasma region will expand from the focal point to the light source direction of the first pulsed laser. At the same time, the plasma zone transfers energy to the surrounding material through thermal diffusion effects, forming an external melt-modified zone for welding the first glass and the second glass. And, because the first pulsed laser and the second pulsed laser are opposed to each other, the second pulsed laser is focused on the side of the first glass close to the second glass or the side of the second glass close to the first glass under the action of the second focusing mirror , and produce a non-linear interaction with the first glass or the second glass to generate plasma, which will have a shielding effect on the subsequent second pulsed laser, making it unable to penetrate the plasma and act on the original focus, making the plasma The zone will exhibit a phenomenon of expanding from the focal point towards the light source of the second pulsed laser. And through the thermal diffusion effect, the energy is transferred to the surrounding material to form an external melting modification zone to weld the first glass and the second glass. The through-beam welding device has a simple structure, does not need to introduce an opaque material between the first glass and the second glass, has low optical requirements on the glass welding surface, and can realize the welding of the first glass with a large gap. Welding with the second glass to improve welding quality and efficiency.
该激光对射焊接方法利用第一脉冲激光和第二脉冲激光从第一玻璃和第二玻璃的两侧分别入射,即形成对射,利用激光与玻璃材料产生非线性相互作用并产生等离子体,等离子体对激光的强烈吸收,会对后续的激光产生屏蔽效应,使其无法穿透等离子体而作用于原来的焦点处。随着激光脉冲数量的增加,等离子体区将呈现从焦点处向激光光源方向扩展的现象。同时,等离子体区会通过热扩散效应将能量传递给周围材料,形成外部的熔融改性区,以焊接第一玻璃和第二玻璃,这种焊接方法无需在第一玻璃和第二玻璃之间引入不透光材料,对玻璃焊接表面的光学要求较低,能实现在具有较大间隙的情况下对第一玻璃和第二玻璃焊接,提高焊接质量和效率,不影响焊接后产品的透光性能。The laser butt welding method utilizes the first pulsed laser and the second pulsed laser to be incident from the two sides of the first glass and the second glass respectively, that is to form an opposite beam, and uses the laser to generate nonlinear interaction with the glass material and generate plasma, The strong absorption of the laser by the plasma will have a shielding effect on the subsequent laser, making it impossible to penetrate the plasma and act on the original focus. As the number of laser pulses increases, the plasma region will expand from the focal point towards the laser source. At the same time, the plasma zone will transfer energy to the surrounding material through thermal diffusion effect, forming an external melting modification zone to weld the first glass and the second glass, this welding method does not need to be between the first glass and the second glass The introduction of opaque materials has lower optical requirements for the glass welding surface, which can realize the welding of the first glass and the second glass with a large gap, improve the welding quality and efficiency, and does not affect the light transmission of the welded product performance.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。The above are only specific embodiments of the present application, but the protection scope of the present application is not limited to this. Any person skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present application, All should be covered within the scope of protection of this application. Therefore, the protection scope of the present application should be subject to the protection scope of the claims.
工业实用性Industrial Applicability
本申请提供一种激光对射焊接装置和方法,涉及激光焊接技术领域。通过激光对射,在两玻璃各自的靠近间隙的一侧产生等离子体而形成融化物,以焊接两玻璃,提高焊接质量和效率。The present application provides a laser butt beam welding device and method, and relates to the technical field of laser welding. Through the laser irradiation, plasma is generated on the side of the two glasses near the gap to form a melt, so as to weld the two glasses and improve the welding quality and efficiency.

Claims (25)

  1. 一种激光对射焊接装置,其中,包括激光发生器、第一聚焦镜、第二聚焦镜和样品台;A laser beam welding device, comprising a laser generator, a first focusing mirror, a second focusing mirror and a sample stage;
    所述激光发生器配置成产生脉冲激光,所述样品台配置成放置第一玻璃和第二玻璃,所述第一玻璃和所述第二玻璃以具有间隙的方式层叠设置;the laser generator is configured to generate a pulsed laser light, the sample stage is configured to place a first glass and a second glass, the first glass and the second glass are stacked with a gap;
    所述第一聚焦镜设于所述激光发生器和所述第一玻璃之间,所述第一聚焦镜配置成将所述激光发生器产生的脉冲激光作为第一脉冲激光从所述第一玻璃远离所述第二玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;The first focusing mirror is provided between the laser generator and the first glass, and the first focusing mirror is configured to use the pulsed laser generated by the laser generator as the first pulsed laser from the first The side of the glass away from the second glass is incident on the gap between the first glass and the second glass; the first pulsed laser is configured so that the second glass is close to the first glass. generating plasma on one side and melting the second glass to weld the first glass and the second glass;
    所述第二聚焦镜设于所述激光发生器和所述第二玻璃之间,所述第二聚焦镜配置成将所述激光发生器产生的脉冲激光作为第二脉冲激光从所述第二玻璃远离所述第一玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。The second focusing mirror is provided between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as a second pulsed laser from the second The side of the glass away from the first glass is incident on the gap between the first glass and the second glass; the second pulsed laser is configured so that the first glass is close to the second glass. One side generates plasma and melts the first glass to weld the first glass and the second glass.
  2. 根据权利要求1所述的激光对射焊接装置,其中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。The laser butt beam welding device according to claim 1, wherein the first incident optical path of the first pulsed laser from the first focusing mirror to the first glass and the second pulsed laser have different paths. The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
  3. 根据权利要求1或2所述的激光对射焊接装置,其中,还包括偏振分束镜,所述偏振分束镜设于所述激光发生器和所述样品台之间,所述偏振分束镜配置成将所述激光发生器产生的脉冲激光分为所述第一脉冲激光和所述第二脉冲激光,所述第一脉冲激光配置成经所述第一聚焦镜后从所述第一玻璃入射,所述第二脉冲激光配置成经所述第二聚焦镜后从所述第二玻璃入射。The laser butt beam welding device according to claim 1 or 2, further comprising a polarization beam splitter, the polarization beam splitter is arranged between the laser generator and the sample stage, and the polarization beam splitter The mirror is configured to divide the pulsed laser light generated by the laser generator into the first pulsed laser light and the second pulsed laser light, and the first pulsed laser light is configured to pass through the first focusing mirror from the first pulsed laser light. The glass is incident, and the second pulsed laser is configured to be incident from the second glass after passing through the second focusing mirror.
  4. 根据权利要求1所述的激光对射焊接装置,其中,所述激光发生器包括第一发生器和第二发生器,所述第一发生器配置成产生所述第一脉冲激光,所述第二发生器配置成产生所述第二脉冲激光,所述第一脉冲激光配置成经所述第一聚焦镜后从所述第一玻璃入射,所述第二脉冲激光配置成经所述第二聚焦镜后从所述第二玻璃入射。The laser butt welding apparatus of claim 1, wherein the laser generator comprises a first generator and a second generator, the first generator being configured to generate the first pulsed laser, the first generator A second generator is configured to generate the second pulsed laser light, the first pulsed laser light is configured to be incident from the first glass after passing through the first focusing mirror, and the second pulsed laser light is configured to pass through the second After focusing mirror incident from the second glass.
  5. 根据权利要求1至4中任一项所述的激光对射焊接装置,其中,还包括对所述激光发生器产生的脉冲激光的光束直径和发散角进行调整的扩束准直镜,所述扩束准直镜设于所述激光发生器的所述脉冲激光的传播方向的下游。The laser butt beam welding device according to any one of claims 1 to 4, further comprising a beam expander collimator for adjusting the beam diameter and divergence angle of the pulsed laser generated by the laser generator, the The beam expander collimator is arranged downstream of the propagation direction of the pulsed laser light of the laser generator.
  6. 根据权利要求1至5中任一项所述的激光对射焊接装置,其中,还包括第一导光镜和第二导光镜,所述第一导光镜设于所述第一聚焦镜远离所述第一玻璃的一侧,所 述第二导光镜设于所述第二聚焦镜远离所述第二玻璃的一侧。The laser butt beam welding device according to any one of claims 1 to 5, further comprising a first light guide mirror and a second light guide mirror, the first light guide mirror being arranged on the first focusing mirror On the side away from the first glass, the second light guide mirror is arranged on the side of the second focusing mirror away from the second glass.
  7. 根据权利要求1至6中任一项所述的激光对射焊接装置,其中,还包括工控机和位移台,所述位移台与所述样品台连接,所述工控机分别与所述激光发生器和所述位移台连接,来控制所述激光发生器和所述位移台。The laser butt-beam welding device according to any one of claims 1 to 6, further comprising an industrial computer and a displacement stage, the displacement stage is connected to the sample stage, and the industrial computer is respectively connected to the laser A generator is connected with the displacement stage to control the laser generator and the displacement stage.
  8. 根据权利要求1至7中任一项所述的激光对射焊接装置,其中,所述样品台上设有固定夹具,所述固定夹具固定所述第一玻璃和所述第二玻璃。The laser butt-beam welding device according to any one of claims 1 to 7, wherein a fixing fixture is provided on the sample stage, and the fixing fixture fixes the first glass and the second glass.
  9. 根据权利要求1所述的激光对射焊接装置,其中,The laser butt beam welding device according to claim 1, wherein,
    所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线交叉。The first incident light path of the first pulsed laser light from the first focusing mirror to the first glass and the second incident light path of the second pulsed laser light from the second focusing mirror to the second glass Optical paths are parallel or extension lines cross.
  10. 根据权利要求9所述的激光对射焊接装置,其中,The laser butt beam welding device according to claim 9, wherein,
    所述第一聚焦镜配置成将所述第一脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部,the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the second glass on the side of the first glass,
    所述第二聚焦镜配置成将所述第二脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部。The second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the first glass on the side of the second glass.
  11. 一种激光对射焊接装置,其中,包括激光发生器、第一聚焦镜、第二聚焦镜和样品台;A laser beam welding device, comprising a laser generator, a first focusing mirror, a second focusing mirror and a sample stage;
    所述激光发生器配置成产生脉冲激光,所述样品台配置成放置第一玻璃和第二玻璃,所述第一玻璃和所述第二玻璃以具有间隙的方式层叠设置;the laser generator is configured to generate a pulsed laser light, the sample stage is configured to place a first glass and a second glass, the first glass and the second glass are stacked with a gap;
    所述第一聚焦镜设于所述激光发生器和所述第一玻璃之间,所述第一聚焦镜配置成将所述激光发生器产生的脉冲激光作为第一脉冲激光从所述第一玻璃远离所述第二玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;The first focusing mirror is provided between the laser generator and the first glass, and the first focusing mirror is configured to use the pulsed laser generated by the laser generator as the first pulsed laser from the first The side of the glass away from the second glass is incident on the gap between the first glass and the second glass; the first pulsed laser is configured so that the first glass is close to the second glass. generating plasma on one side and melting the first glass to weld the first glass and the second glass;
    所述第二聚焦镜设于所述激光发生器和所述第二玻璃之间,所述第二聚焦镜配置成将所述激光发生器产生的脉冲激光作为第二脉冲激光从所述第二玻璃远离所述第一玻璃的一侧入射至所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。The second focusing mirror is provided between the laser generator and the second glass, and the second focusing mirror is configured to use the pulsed laser generated by the laser generator as a second pulsed laser from the second The side of the glass away from the first glass is incident on the gap between the first glass and the second glass; the second pulsed laser is configured so that the second glass is close to the first glass. One side generates plasma and melts the second glass to weld the first glass and the second glass.
  12. 根据权利要求11所述的激光对射焊接装置,其中,所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。The laser butt beam welding device according to claim 11, wherein the first incident optical path of the first pulsed laser light from the first focusing mirror to the first glass and the second pulsed laser light from the The second incident light paths from the second focusing mirror to the second glass are located on the same straight line.
  13. 根据权利要求11所述的激光对射焊接装置,其中,所述第一脉冲激光的从所 述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线交叉。The laser butt beam welding device according to claim 11, wherein the first incident optical path of the first pulsed laser light from the first focusing mirror to the first glass and the second pulsed laser light from the The second incident light path from the second focusing mirror to the second glass is parallel or intersecting with an extension line.
  14. 根据权利要求11所述的激光对射焊接装置,其中,The laser butt beam welding device according to claim 11, wherein,
    所述第一聚焦镜配置成将所述第一脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部,the first focusing mirror is configured to focus the first pulsed laser light on the surface or inside of the first glass on the side of the second glass,
    所述第二聚焦镜配置成将所述第二脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部。The second focusing mirror is configured to focus the second pulsed laser light on a surface or inside of the second glass on the side of the first glass.
  15. 根据权利要求1至14中任一项所述的激光对射焊接装置,其中,The laser butt beam welding device according to any one of claims 1 to 14, wherein,
    所述第一玻璃和所述第二玻璃之间的间隙为5μm以下。The gap between the first glass and the second glass is 5 μm or less.
  16. 根据权利要求1至15中任一项所述的激光对射焊接装置,其中,The laser butt beam welding device according to any one of claims 1 to 15, wherein,
    所述第一脉冲激光和所述第二脉冲激光的波长为200nm至2000nm,脉宽为12ps以下,重复率为1kHz以上。The wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is 12 ps or less, and the repetition rate is 1 kHz or more.
  17. 一种激光对射焊接方法,其中,配置成实现第一玻璃和第二玻璃的焊接,所述第一玻璃和所述第二玻璃具有间隙地层叠设置;所述激光对射焊接方法包括:A laser butt beam welding method, wherein it is configured to realize welding of a first glass and a second glass, and the first glass and the second glass are laminated with a gap; the laser butt beam welding method comprises:
    从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光,所述第一脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;以及A first pulsed laser is incident from the side of the first glass away from the second glass, and the first pulsed laser is focused at the gap between the first glass and the second glass; the first pulsed laser a pulsed laser configured to generate a plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass; and
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光,所述第二脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass.
  18. 根据权利要求17所述的激光对射焊接方法,其中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;The laser butt beam welding method according to claim 17, wherein in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through a first focusing mirror then incident from the first glass;
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,In the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light is incident from the second glass after passing through the second focusing mirror,
    所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。The first incident light path of the first pulsed laser light from the first focusing mirror to the first glass and the second incident light path of the second pulsed laser light from the second focusing mirror to the second glass The optical paths are on the same straight line.
  19. 根据权利要求17所述的激光对射焊接方法,其中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;The laser butt beam welding method according to claim 17, wherein in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through a first focusing mirror then incident from the first glass;
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,In the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light is incident from the second glass after passing through the second focusing mirror,
    所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线相交。The first incident light path of the first pulsed laser light from the first focusing mirror to the first glass and the second incident light path of the second pulsed laser light from the second focusing mirror to the second glass Parallel or extended lines of light paths intersect.
  20. 根据权利要求19所述的激光对射焊接方法,其中,所述第一脉冲激光聚焦于所述第二玻璃的靠所述第一玻璃一侧的表面或内部,所述第二脉冲激光聚焦于所述第一玻璃的靠所述第二玻璃一侧的表面或内部。The laser butt welding method according to claim 19, wherein the first pulsed laser is focused on the surface or inside of the second glass on the side of the first glass, and the second pulsed laser is focused on The surface or interior of the first glass on the side of the second glass.
  21. 一种激光对射焊接方法,其中,配置成实现第一玻璃和第二玻璃的焊接,所述第一玻璃和所述第二玻璃具有间隙地层叠设置;所述激光对射焊接方法包括:A laser butt beam welding method, wherein it is configured to realize welding of a first glass and a second glass, and the first glass and the second glass are laminated with a gap; the laser butt beam welding method comprises:
    从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光,所述第一脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第一脉冲激光配置成在所述第一玻璃靠近所述第二玻璃的一侧产生等离子体并使所述第一玻璃熔融,以焊接所述第一玻璃和所述第二玻璃;以及A first pulsed laser is incident from the side of the first glass away from the second glass, and the first pulsed laser is focused at the gap between the first glass and the second glass; the first pulsed laser a pulsed laser configured to generate plasma on a side of the first glass adjacent to the second glass and to melt the first glass to weld the first glass and the second glass; and
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光,所述第二脉冲激光聚焦于所述第一玻璃和所述第二玻璃之间的间隙处;所述第二脉冲激光配置成在所述第二玻璃靠近所述第一玻璃的一侧产生等离子体并使所述第二玻璃熔融,以焊接所述第一玻璃和所述第二玻璃。A second pulsed laser is incident from the side of the second glass away from the first glass, and the second pulsed laser is focused on the gap between the first glass and the second glass; the second pulsed laser The pulsed laser is configured to generate plasma on a side of the second glass adjacent to the first glass and to melt the second glass to weld the first glass and the second glass.
  22. 根据权利要求21所述的激光对射焊接方法,其中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;The laser butt beam welding method according to claim 21, wherein, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through a first focusing mirror then incident from the first glass;
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,In the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light is incident from the second glass after passing through the second focusing mirror,
    所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路位于同一直线上。The first incident light path of the first pulsed laser light from the first focusing mirror to the first glass and the second incident light path of the second pulsed laser light from the second focusing mirror to the second glass The optical paths are on the same straight line.
  23. 根据权利要求21所述的激光对射焊接方法,其中,从所述第一玻璃远离所述第二玻璃的一侧入射第一脉冲激光的步骤中,所述第一脉冲激光经第一聚焦镜后从所述第一玻璃入射;The laser butt beam welding method according to claim 21, wherein, in the step of injecting the first pulsed laser light from the side of the first glass away from the second glass, the first pulsed laser light passes through a first focusing mirror then incident from the first glass;
    从所述第二玻璃远离所述第一玻璃的一侧入射第二脉冲激光的步骤中,所述第二脉冲激光经第二聚焦镜后从所述第二玻璃入射,In the step of injecting the second pulsed laser light from the side of the second glass away from the first glass, the second pulsed laser light is incident from the second glass after passing through the second focusing mirror,
    所述第一脉冲激光的从所述第一聚焦镜到所述第一玻璃的第一入射光路与所述第二脉冲激光的从所述第二聚焦镜到所述第二玻璃的第二入射光路平行或延长线相交。The first incident light path of the first pulsed laser light from the first focusing mirror to the first glass and the second incident light path of the second pulsed laser light from the second focusing mirror to the second glass Parallel or extended lines of light paths intersect.
  24. 根据权利要求21至23中任一项所述的激光对射焊接方法,其中,The laser butt beam welding method according to any one of claims 21 to 23, wherein,
    所述第一玻璃和所述第二玻璃之间的间隙为5μm以下。The gap between the first glass and the second glass is 5 μm or less.
  25. 根据权利要求21至24中任一项所述的激光对射焊接方法,其中,The laser butt beam welding method according to any one of claims 21 to 24, wherein,
    所述第一脉冲激光和所述第二脉冲激光的波长为200nm至2000nm,脉宽为12ps以下,重复率为1kHz以上。The wavelengths of the first pulsed laser and the second pulsed laser are 200 nm to 2000 nm, the pulse width is 12 ps or less, and the repetition rate is 1 kHz or more.
PCT/CN2021/096098 2020-12-31 2021-05-26 Laser opposing emission welding apparatus and method WO2022142100A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115417586A (en) * 2022-09-15 2022-12-02 华中科技大学 Glass laser welding method and device

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112828470B (en) * 2020-12-31 2021-12-03 武汉华工激光工程有限责任公司 Laser correlation welding device and method
CN115805367A (en) * 2021-09-14 2023-03-17 武汉大学 Metal nanowire impact welding device and method based on laser thermal coupling effect

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247321A (en) * 2000-03-06 2001-09-11 Japan Aviation Electronics Industry Ltd Method and apparatus for junction of glass by laser beam
CN101553340A (en) * 2006-09-22 2009-10-07 国立大学法人大阪大学 Substance joining method, substance joining device, joined body, and its manufacturing method
US20100304151A1 (en) * 2007-02-21 2010-12-02 Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. Method for laser-assisted bonding, substrates bonded in this manner and use thereof
JP2015063418A (en) * 2013-09-24 2015-04-09 三星ダイヤモンド工業株式会社 Method of fusing glass substrate by laser beam, and laser processing device
JP2015063417A (en) * 2013-09-24 2015-04-09 三星ダイヤモンド工業株式会社 Method of fusing glass substrate by laser beam, and laser processing device
CN110039177A (en) * 2019-04-10 2019-07-23 华中科技大学 A kind of glass capsulation welding method
CN112828470A (en) * 2020-12-31 2021-05-25 武汉华工激光工程有限责任公司 Laser correlation welding device and method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247321A (en) * 2000-03-06 2001-09-11 Japan Aviation Electronics Industry Ltd Method and apparatus for junction of glass by laser beam
CN101553340A (en) * 2006-09-22 2009-10-07 国立大学法人大阪大学 Substance joining method, substance joining device, joined body, and its manufacturing method
US20100304151A1 (en) * 2007-02-21 2010-12-02 Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. Method for laser-assisted bonding, substrates bonded in this manner and use thereof
JP2015063418A (en) * 2013-09-24 2015-04-09 三星ダイヤモンド工業株式会社 Method of fusing glass substrate by laser beam, and laser processing device
JP2015063417A (en) * 2013-09-24 2015-04-09 三星ダイヤモンド工業株式会社 Method of fusing glass substrate by laser beam, and laser processing device
CN110039177A (en) * 2019-04-10 2019-07-23 华中科技大学 A kind of glass capsulation welding method
CN112828470A (en) * 2020-12-31 2021-05-25 武汉华工激光工程有限责任公司 Laser correlation welding device and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115417586A (en) * 2022-09-15 2022-12-02 华中科技大学 Glass laser welding method and device

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