WO2022138008A1 - Tabac chauffé sans combustion et produit de tabac chauffé électriquement - Google Patents

Tabac chauffé sans combustion et produit de tabac chauffé électriquement Download PDF

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Publication number
WO2022138008A1
WO2022138008A1 PCT/JP2021/043770 JP2021043770W WO2022138008A1 WO 2022138008 A1 WO2022138008 A1 WO 2022138008A1 JP 2021043770 W JP2021043770 W JP 2021043770W WO 2022138008 A1 WO2022138008 A1 WO 2022138008A1
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Prior art keywords
tobacco
filter
less
segment
activated carbon
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PCT/JP2021/043770
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English (en)
Japanese (ja)
Inventor
哲哉 吉村
弘樹 中合
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日本たばこ産業株式会社
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Priority to JP2022572025A priority Critical patent/JPWO2022138008A1/ja
Priority to EP21910160.7A priority patent/EP4268632A1/fr
Publication of WO2022138008A1 publication Critical patent/WO2022138008A1/fr

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    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/20—Cigarettes specially adapted for simulated smoking devices
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/163—Carbon
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04—Tobacco smoke filters characterised by their shape or structure
    • A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives

Definitions

  • the present invention relates to non-combustion heated tobacco and electrically heated tobacco products.
  • non-combustion heat-not-burn tobacco that is used by inserting it into an electrically heated device
  • Patent Document 1 The non-combustion heat-not-burn tobacco generally includes a tobacco rod in which a material for producing tobacco nicks and flavor components is wrapped with rolling paper, a mouthpiece for sucking components generated from the tobacco rod by heating, and these. Equipped with a tip paper to wrap.
  • a non-combustion heated tobacco is inserted into an electrically heated device, and then the heater member is heated to heat the tobacco rod starting from a point in contact with the heater member.
  • the generated ingredients are delivered to the user.
  • the present invention provides a non-combustion heat-not-burn tobacco product and an electrically heat-not-burn tobacco product that can deliver a desired amount of a component produced by heating to a user and give a desired flavor to the user.
  • the task is to do.
  • the gist of the present invention is as follows.
  • a rod-shaped non-combustion heated tobacco having a tobacco rod portion and a mouthpiece portion.
  • the mouthpiece portion includes a cooling segment and a filter segment containing a filter filter medium, the tobacco rod portion and the cooling segment are adjacent to each other, activated carbon is added to the filter filter medium, and the non-combustion heating type cigarette is used.
  • the amount of activated carbon added is the following formula (1): BET specific surface area of activated carbon x weight of activated carbon / cross section in the direction perpendicular to the ventilation direction of the filter filter medium (1)
  • Non-combustion heat-not-burn tobacco added so that the value represented by is 15.0 m 2 / cm 2 or more and 80 m 2 / cm 2 or less.
  • Holes are concentrically provided in the circumferential direction of the cooling segment, and the holes are formed in a region of 4 mm or more and 7 mm or less in the direction toward the cooling segment from the boundary between the cooling segment and the filter segment.
  • the non-combustion heat-not-burn tobacco according to [1], which is present.
  • An electrically heated device including a heater member, a battery unit as a power source for the heater member, and a control unit for controlling the heater member is inserted so as to be in contact with the heater member.
  • An electrically heated tobacco product comprising the non-combustible heated tobacco according to any one of [1] to [5].
  • a non-combustion heat-not-burn tobacco product and an electrically heat-not-burn tobacco product capable of delivering a desired amount of a component produced by heating to a user and giving the user a desired flavor. can do.
  • the non-combustion heat-not-burn tobacco (also simply referred to as "non-combustion heat-not-burn tobacco") according to an embodiment of the present invention is a rod-shaped non-combustion heat-not-burn tobacco provided with a tobacco rod portion and a mouthpiece portion.
  • the mouthpiece portion includes a cooling segment and a filter segment containing a filter filter medium, the tobacco rod portion and the cooling segment are adjacent to each other, activated carbon is added to the filter filter medium, and the non-combustion heating type cigarette is used.
  • the amount of activated carbon added is the following formula (1): BET specific surface area of activated carbon x weight of activated carbon / cross section in the direction perpendicular to the ventilation direction of the filter filter medium (1) It is a non-combustion heat-not-burn tobacco added so that the value represented by is 15.0 m 2 / cm 2 or more and 80.0 m 2 / cm 2 or less. Unlike conventional cigarettes, non-combustion heat-not-burn tobacco does not involve combustion, so the types and amounts of components produced during use are limited. Therefore, the technical idea of adding activated carbon to the filter as in the present embodiment has not been recalled in the field of non-combustion heat-not-burn tobacco. An example of the non-combustion heat-not-burn tobacco according to the embodiment is shown in FIG. Hereinafter, the non-combustion heat-not-burn tobacco will be described with reference to FIG.
  • the non-combustion heat-not-burn tobacco 10 shown in FIG. 1 is a rod-shaped non-combustion heat-not-burn tobacco having a tobacco rod portion 11, a mouthpiece portion 14, and a chip paper 15 wrapped around these, and the mouthpiece.
  • the unit 14 includes a cooling segment 12 and a filter segment 13 including a filter filter medium, and the cooling segment 12 is the tobacco with respect to the axial direction (also referred to as “long axis direction”) of the non-combustion heat-not-burn tobacco 10.
  • the rod portion 11 and the filter segment 13 may be sandwiched adjacent to each other, and holes V may be provided concentrically in the circumferential direction of the cooling segment 12.
  • the filter segment 13 contains a filter filter medium, and activated carbon is added to the filter filter medium in a predetermined amount.
  • it is composed of a filter filter medium 13a to which activated carbon is added and a filter filter medium 13b to which activated carbon is not added. This point will be described later.
  • the opening V provided in the cooling segment 12 of the non-combustion heat-not-burn tobacco 10 shown in FIG. 1 is usually a hole for promoting the inflow of air from the outside due to the suction of the user, and the inflow of the air causes the inflow of tobacco.
  • the temperature of the components and air flowing in from the rod portion 11 can be lowered.
  • the opening V that may be provided in the present embodiment may be described as being present in a region of 4 mm or more in the direction toward the cooling segment from the boundary between the cooling segment 12 and the filter segment 13.
  • the component produced by heating examples include a flavor component derived from a fragrance, nicotine and tar derived from tobacco leaves, and an aerosol component derived from an aerosol base material.
  • the aerosol base material is a base material for producing an aerosol.
  • the rod-shaped non-combustion heat-not-burn tobacco 10 preferably has a columnar shape satisfying a shape having an aspect ratio of 1 or more as defined below.
  • Aspect ratio h / w w is the width of the bottom surface of the columnar body (in the present specification, the width of the bottom surface on the tobacco rod portion side), h is the height of the columnar body, and h ⁇ w is preferable.
  • the long axis direction is defined as the direction indicated by h. Therefore, even if w ⁇ h, the direction indicated by h is referred to as the major axis direction for convenience.
  • the shape of the bottom surface is not limited and may be a polygon, a polygon with rounded corners, a circle, an ellipse, or the like, and the width w is a diameter when the bottom surface is circular, a major axis when the bottom surface is elliptical, or a polygon or rounded corners. If it is a polygon, it is the diameter of the circumscribed circle or the major axis of the circumscribed ellipse.
  • the length h of the non-combustion heat-not-burn tobacco 10 in the major axis direction is not particularly limited, and is usually 40 mm or more, preferably 45 mm or more, and more preferably 50 mm or more.
  • the width w of the bottom surface of the columnar body of the non-combustion heat-not-burn tobacco 10 is not particularly limited, and is usually 5 mm or more, preferably 5.5 mm or more. Further, it is usually 10 mm or less, preferably 9 mm or less, and more preferably 8 mm or less.
  • the ratio of the length of the cooling segment and the length of the filter segment (cooling segment: filter segment) to the length in the long axis direction of the non-combustion heated cigarette is not particularly limited, but the delivery amount of the fragrance and the appropriate aerosol temperature are not particularly limited.
  • the cooling segment is long, atomization of aerosols and the like is promoted and a good flavor can be realized, but if it is too long, the passing substances will adhere to the inner wall.
  • the cooling effect By setting the ratio of the lengths of the cooling segment and the filter segment within the above range, the cooling effect, the effect of suppressing the loss of aerosol due to the adhesion of the generated vapor and aerosol to the inner wall of the cooling segment, and the amount of air in the filter and the amount of air in the filter and The flavor adjustment function is well-balanced, and good flavor and flavor intensity can be realized.
  • the aeration resistance in the long axis direction per 120 mm of the non-combustion heat-not-burn tobacco 10 is not particularly limited, but from the viewpoint of ease of suction, it is usually 8 mmH 2 O or more, preferably 10 mmH 2 O or more, and 12 mmH 2 It is more preferably O or more, and usually 100 mmH 2 O or less, preferably 80 mmH 2 O or less, and more preferably 60 mmH 2 O or less. Ventilation resistance is measured according to the ISO standard method (ISO 6565: 2015), for example, using a filter aeration resistance measuring instrument manufactured by Cerulean.
  • the ventilation resistance is a predetermined air flow rate (17.5 cc / min) from one end face (first end face) to the other end face (second end face) in a state where air is not permeated on the side surface of the non-combustion heat-not-burn tobacco 10.
  • the unit is generally expressed in mmH 2 O. It is known that the relationship between the aeration resistance and the length of non-combustion heat-not-burn tobacco is proportional in the length range (length 5 mm to 200 mm) that is usually carried out, and if the length is doubled, it is not.
  • the ventilation resistance of combustion-heated cigarettes is doubled.
  • the configuration of the mouthpiece portion 14 includes a cooling segment 12 and a filter segment 13 including a filter filter medium, and the cooling segment 12 is the tobacco rod portion 11 and the filter segment 13 with respect to the axial direction of the non-combustion heat-not-burn tobacco 10.
  • the filter segment and the cooling segment will be described in detail.
  • the filter segment 13 is not particularly limited as long as it has a function as a general filter.
  • a tow made of synthetic fibers (also simply referred to as “tow”) or a material such as paper is processed into a columnar shape. Things can be used.
  • the general functions of the filter include, for example, adjusting the amount of air mixed when sucking aerosols, reducing flavor, reducing nicotine and tar, etc., but it is not possible to have all of these functions. I don't need it.
  • the tobacco filling can be dropped while suppressing the filtration function. Preventing is also one of the important functions.
  • the filter segment of the present embodiment includes a filter filter medium, and activated carbon is added to at least a part of the filter filter medium, and the amount of the added carbon is the specific surface area of the activated carbon ⁇ the activated carbon in one non-combustion heating type cigarette.
  • the value of the cross-sectional area in the direction perpendicular to the ventilation direction of the weight / filter filter medium is 15.0 m 2 / cm 2 or more and 80.0 m 2 / cm 2 or less.
  • the above-mentioned "specific surface area of activated carbon x weight of activated carbon / cross-sectional area in the direction perpendicular to the ventilation direction of the filter filter medium" may be expressed as "surface area of activated carbon per unit cross-sectional area" for convenience.
  • the surface area of activated carbon per unit cross-sectional area can be calculated based on the specific surface area of activated carbon added to the filter filter medium of one non-combustion heat-not-burn tobacco, the weight of the added activated carbon, and the cross-sectional area of the filter filter medium. It should be noted that the activated carbon may not be uniformly dispersed in the filter filter medium to which it is added, and it is necessary to satisfy the above range in all the cross sections of the filter filter medium (cross section in the direction perpendicular to the ventilation direction). Not what you request. In the present embodiment, when the surface area of activated carbon per unit cross-section is within the above range, the component produced by heating can be delivered to the user in a desired amount, and the user can have a desired flavor. Can be given.
  • the surface area of activated carbon per unit cross-section is more preferably 17.0 m 2 / cm 2 or more, and even more preferably 35.0 m 2 / cm 2 or more. On the other hand, it is more preferably 77.0 m 2 / cm 2 or less, and further preferably 73.0 m 2 / cm 2 or less.
  • the surface area of activated carbon per unit cross-sectional area can be adjusted, for example, by adjusting the specific surface area of activated carbon and its addition amount, and the cross-sectional area in the direction perpendicular to the ventilation direction of the filter filter medium.
  • the surface area of activated carbon per unit cross-sectional area is calculated based on the filter medium to which activated carbon is added.
  • Examples of the activated carbon that can be used in the present embodiment include those made of wood, bamboo, palm husks, walnut husks, coal and the like as raw materials. Further, as the activated carbon that can be used in the present embodiment, one having a BET specific surface area of 1100 m 2 / g or more and 1600 m 2 / g or less can be used, and preferably 1200 m 2 / g or more and 1500 m 2 / /. Those having a g or less can be used, and more preferably, those having 1250 m 2 / g or more and 1380 m 2 / g or less can be used.
  • the BET specific surface area can be determined by the nitrogen gas adsorption method (BET multipoint method).
  • the activated carbon that can be used in the present embodiment, those having a pore volume of 400 ⁇ L / g or more and 800 ⁇ L / g or less can be used, and more preferably 500 ⁇ L / g or more and 750 ⁇ L / g or less. Some of them can be used, and more preferably 600 ⁇ L / g or more and 700 ⁇ L / g or less can be used.
  • the pore volume can be calculated from the maximum adsorption amount obtained by using the nitrogen gas adsorption method.
  • the amount of activated carbon added per unit length of the filter filter medium to which activated carbon is added is preferably 5 mg / cm or more and 50 mg / cm or less, preferably 8 mg / cm or more and 40 mg / cm. It is more preferably 10 mg / cm or more and 35 mg / cm or less.
  • the surface area of the activated carbon per unit cross-sectional area can be adjusted to a desired value.
  • the cumulative 10% by volume particle diameter (particle diameter D10) of the activated carbon particles is 250 ⁇ m or more and 1200 ⁇ m or less.
  • the cumulative 50% by volume particle size (particle size D50) of the activated carbon particles is preferably 350 ⁇ m or more and 1500 ⁇ m or less.
  • D10 and D50 are measured by a laser diffraction / scattering method.
  • an apparatus suitable for this measurement there is a laser diffraction / scattering type particle size distribution measuring apparatus "LA-950" manufactured by HORIBA, Ltd. The powder is poured into the cell of this device together with pure water, and the particle size is detected based on the light scattering information of the particles.
  • Measurement mode Manual flow mode cell
  • Measurement dispersion medium Ion exchange water dispersion method: Measured after 1 minute ultrasonic irradiation Refractive index: 1.92-0.00i (sample refraction) /1.33-0.00i (dispersion medium) Refractive index) Number of measurements: Measure twice with different samples
  • the method of adding activated carbon to the filter filter medium is not particularly limited, and the activated carbon may be added so as to be substantially uniformly dispersed in the filter filter medium to which the activated carbon is added.
  • the filter segment 13 for example, one manufactured by a manufacturing method described later may be used, or a commercially available product may be used.
  • the mode of the filter segment 13 is not particularly limited, and may be a filter including a single filter segment, a multi-segment filter including a plurality of filter segments such as a dual filter or a triple filter, and the like.
  • the filter filter medium to which activated carbon is added becomes the filter segment as it is.
  • the filter filter medium 13a made of the filter filter medium to which activated carbon is added is arranged on the upstream side of the filter filter medium 13b constituting the mouthpiece end.
  • activated carbon may be added to the filter filter medium constituting the filter segment constituting the mouthpiece end.
  • the length of the filter segment which is the reference for the amount of activated carbon added, is the length of the filter filter medium to which activated carbon is added.
  • the amount of activated carbon added may be, for example, 4.0 mg or more and 24.0 mg or less as the weight with respect to the entire filter segment, preferably 4.5 mg or more and 23.0 mg or less, and 10.5 mg or more. It is more preferably 22.0 mg or less.
  • the shape of the filter segment 13 is not particularly limited, and a known shape can be adopted, and usually a columnar shape can be adopted, and the following aspects can be used. Further, the filter segment 13 may be provided with a cavity (center hole or the like) or a recess or the like having a hollow cross section in the circumferential direction.
  • the cross-sectional shape of the filter segment 13 in the circumferential direction is substantially circular, and the diameter of the circle can be appropriately changed according to the size of the product, but is usually 4.0 mm or more and 9.0 mm or less. It is preferably 5 mm or more and 8.5 mm or less, and more preferably 5.0 mm or more and 8.0 mm or less. If the cross section is not circular, the diameter in the circle is applied when the above diameter is assumed to be a circle having the same area as the area of the cross section.
  • the circumferential length of the cross-sectional shape of the filter segment 13 in the circumferential direction can be appropriately changed according to the size of the product, but is usually 14.0 mm or more and 27.0 mm or less, and 15.0 mm or more and 26.0 mm or less. It is preferably 16.0 mm or more, and more preferably 25.0 mm or less.
  • the axial length of the filter segment 13 can be appropriately changed according to the size of the product, but is usually 15.0 mm or more and 35.0 mm or less, preferably 17.5 mm or more and 32.5 mm or less. It is more preferably 20.0 mm or more and 30.0 mm or less.
  • the ventilation resistance per 120 mm of the axial length of the filter segment 13 is not particularly limited, but is usually 40 mmH 2 O or more and 300 mmH 2 O or less, preferably 70 mmH 2 O or more and 280 mmH 2 O or less, and 90 mmH. It is more preferably 2 O or more and 260 mmH 2 O or less.
  • the above ventilation resistance is measured according to the ISO standard method (ISO6565), for example, using a filter ventilation resistance measuring instrument manufactured by Cerulean.
  • the ventilation resistance of the filter segment 13 is a predetermined air flow rate (17.5 cc /) from one end face (first end face) to the other end face (second end face) in a state where air is not permeated on the side surface of the filter segment 13.
  • the unit is generally expressed in mmH 2 O. It is known that the relationship between the ventilation resistance of the filter segment 13 and the length of the filter segment 13 is proportional to the length range (length 5 mm to 200 mm) that is normally carried out, and if the length is doubled, it is known. , The ventilation resistance of the filter segment 13 is doubled.
  • the filter segment 13 can be produced by a known method. For example, when a synthetic fiber such as cellulose acetate tow is used as a material for a filter filter medium, a polymer solution containing a polymer and a solvent is spun and crimped. It can be manufactured by the method. As the method, for example, the method described in International Publication No. 2013/067511 can be used.
  • the mode of the filter filter medium constituting the filter segment 13 is not particularly limited, and a known mode may be adopted.
  • a cellulose acetate tow processed into a columnar shape can be mentioned.
  • the single thread fineness and total fineness of the cellulose acetate tow are not particularly limited, but in the case of a mouthpiece member having a circumference of 22 mm, the single thread fineness is 5 g / 9000 m or more, 12 g / 9000 m or less, and the total fineness is 12000 g / 9000 m or more, 35000 g. It is preferably / 9000 m or less.
  • Examples of the cross-sectional shape of the fibers of the cellulose acetate tow include a circular shape, an elliptical shape, a Y-shape, an I-shape, and an R-shape.
  • triacetin may be added in an amount of 5% by weight or more and 10% by weight or less based on the weight of the cellulose acetate tow in order to improve the hardness of the filter.
  • a paper filter filled with sheet-shaped pulp paper may be used instead of the acetate filter.
  • the density of the filter media constituting the filter segment 13 is not particularly limited, but is usually 0.10 g / cm 3 or more and 0.25 g / cm 3 or less, and 0.11 g / cm 3 or more and 0.24 g / cm 3 It is preferably 0.12 g / cm 3 or more, and more preferably 0.23 g / cm 3 or less.
  • the filter segment 13 may further include a center hole segment having one or more hollow portions.
  • the center hole segment is usually arranged closer to the cooling segment than the filter medium to which activated carbon is added, and is preferably arranged adjacent to the cooling segment.
  • the center hole segment is composed of a packed layer having one or more hollow portions and an inner plug wrapper (inner wrapping paper) covering the packed layer.
  • the center hole segment is composed of a packed bed having a hollow portion and an inner plug wrapper covering the packed bed.
  • the center hole segment has a function of increasing the strength of the mouthpiece portion.
  • the packed bed has, for example, an inner diameter of ⁇ 1.0 mm or more and ⁇ 5.
  • the rod can be 0 mm or less. Since the packed bed has a high packing density of fibers, air and aerosol flow only in the hollow portion during suction, and hardly flow in the packed bed. Since the packed layer inside the center hole segment is a fiber-filled layer, the feeling of touch from the outside during use is less likely to cause discomfort to the user.
  • the center hole segment may not have an inner plug wrapper and its shape may be maintained by thermoforming.
  • the center hole segment and the filter filter medium may be connected by, for example, an outer plug wrapper (outer roll paper).
  • the outer plug wrapper can be, for example, cylindrical paper.
  • the tobacco rod portion 11, the cooling segment 12, and the connected center hole segment and filter filter medium may be connected by, for example, a mouthpiece lining paper.
  • glue such as vinyl acetate glue
  • the tobacco rod portion 11, the cooling segment 12, and the connected center hole segment and filter filter medium are put and wound. You can connect with. It should be noted that these may be connected in a plurality of times by a plurality of lining papers.
  • the filter segment 13 may include a winder paper (filter plug winder paper) for winding the material of the filter.
  • the aspect of the roll paper is not particularly limited and may include a seam containing one or more rows of adhesive.
  • the adhesive may include a hot melt adhesive, further the hot melt adhesive may contain polyvinyl alcohol.
  • the roll paper is wound by winding these two or more segments together.
  • the material of the roll paper is not particularly limited, and a known material can be used, and a filler such as calcium carbonate may be contained.
  • the thickness of the roll paper is not particularly limited, and is usually 20 ⁇ m or more and 140 ⁇ m or less, preferably 30 ⁇ m or more and 130 ⁇ m or less, and more preferably 30 ⁇ m or more and 120 ⁇ m or less.
  • the basis weight of the roll-up paper is not particularly limited, and is usually 20 gsm or more and 100 gsm or less, preferably 22 gsm or more and 95 gsm or less, and more preferably 23 gsm or more and 90 gsm or less.
  • the roll paper may or may not be coated, but it is preferably coated with a desired material from the viewpoint of imparting functions other than strength and structural rigidity.
  • the cooling segment 12 is a rod-shaped member that is sandwiched between the tobacco rod portion and the filter segment adjacent to each other and is usually provided with a cavity such as a cylinder having a hollow cross section in the circumferential direction.
  • the cooling segment 12 may be provided with holes V (also referred to as “ventilation filter (Vf)” in the present art) concentrically and in the circumferential direction thereof. ..
  • Vf ventilation filter
  • FIG. 2 eight openings V are arranged concentrically, but the number of openings V is not limited to this. Further, the opening may be present in a region of 4 mm or more in the direction toward the cooling segment from the boundary between the cooling segment and the filter segment.
  • the opening V Due to the presence of the opening V, air flows into the cooling portion from the outside during use, and the temperature of the components and air flowing in from the tobacco rod portion can be lowered. Furthermore, by setting the position where the cooling segment is provided within a region of 4 mm or more in the direction toward the cooling segment from the boundary between the cooling segment and the filter segment, not only the cooling capacity is improved, but also the components generated by heating are generated. Retention in the cooling segment can be suppressed and the delivery amount of the component can be improved.
  • the vapor containing the aerosol base material and the tobacco flavor component generated by heating the tobacco rod comes into contact with the air from the outside and the temperature drops. It can be liquefied and promote the formation of aerosols.
  • the open hole group may be one or two or more.
  • the perforated group is in the region less than 4 mm in the direction toward the cooling segment from the boundary between the cooling segment and the filter segment. It is preferable not to provide.
  • the non-combustion heat-not-burn tobacco 10 has an embodiment in which the tobacco rod portion 11, the cooling segment 12, and the filter segment 13 are wrapped with the chip paper 15, the chip paper 15 is provided with the cooling segment 12. It is preferable that the opening is provided at a position directly above the opening V.
  • a chip paper 15 having an opening that overlaps with the opening V may be prepared and wound, but from the viewpoint of ease of manufacture, the opening may be made. After producing the non-combustion heat-not-burn tobacco 10 using the cooling segment 12 having no V, it is preferable to make a hole through the cooling segment 12 and the chip paper 15 at the same time.
  • the opening is the air inflow ratio from the opening when sucked at 17.5 ml / sec with an automatic smoking machine (when the ratio of the air sucked from the mouthpiece end is 100% by volume, the air flowing in from the opening is
  • the volume ratio is preferably 10 to 90% by volume, preferably 50 to 80% by volume, more preferably 55 to 75% by volume, and for example, the number of holes V per opening group is set. It can be achieved by selecting from the range of 5 to 50 and selecting the diameter of the opening V from the range of 0.1 to 0.5 mm and combining these selections.
  • the above air inflow ratio can be measured by a method compliant with ISO9512 using an automatic smoking machine (for example, a single-barreling automatic smoking machine manufactured by Borgwald).
  • the region where the opening V exists is particularly limited as long as it is a region of 2 mm or more in the direction toward the cooling segment from the boundary between the cooling segment 12 and the filter segment 13 from the viewpoint of improving the delivery of the component generated by heating.
  • it is preferably 3 mm or more, preferably 4 mm or more, more preferably 5 mm or more, still more preferably 5.5 mm or more.
  • it is preferably 15 mm or less, more preferably 10 mm or less, and further preferably 6 mm or less.
  • the region where the opening V is present is preferably a region of 22 mm or more in the direction from the mouthpiece end of the non-combustion heated cigarette to the cooling segment side, preferably 23 mm or more, from the viewpoint of improving the delivery of the component generated by heating. It is preferably 24 mm or more, more preferably 25 mm or more, further preferably 25.5 mm or more, and 35 mm or less from the viewpoint of ensuring a cooling function. It is more preferably 30 mm or less, and even more preferably 26 mm or less. Further, considering the boundary between the cooling segment 12 and the tobacco rod portion 11 as a reference, when the axial length of the cooling segment 12 is 20 mm or more, the region where the opening V exists is a viewpoint of ensuring the cooling function.
  • the region is preferably 2 mm or more in the direction toward the cooling segment, more preferably 5 mm or more, further preferably 10 mm or more, and 14 It is particularly preferably 5.5 mm or more, and from the viewpoint of improving the delivery of the components produced by heating, it is preferably 18 mm or less, more preferably 16 mm or less, and 14.5 mm or less. Is even more preferable.
  • the diameter of the opening V is not particularly limited, but is preferably 100 ⁇ m or more and 1000 ⁇ m or less, more preferably 100 ⁇ m or more and 500 ⁇ m or less, and further preferably 300 ⁇ m or more and 800 ⁇ m or less.
  • the openings are preferably substantially circular or substantially elliptical, and in the case of a substantially elliptical shape, the diameter represents a major axis.
  • the length of the cooling segment in the major axis direction can be appropriately changed according to the size of the product, but is usually 15 mm or more, preferably 20 mm or more, more preferably 25 mm or more, and usually 40 mm. It is less than or equal to, preferably 35 mm or less, and more preferably 30 mm or less.
  • the total surface area of the cooling segment 12 is not particularly limited, and examples thereof include 300 mm 2 / mm or more and 1000 mm 2 / mm or less. This surface area is the surface area per length (mm) of the cooling segment 12 in the ventilation direction.
  • the total surface area of the cooling segment 12 is preferably 400 mm 2 / mm or more, more preferably 450 mm 2 / mm or more, while preferably 600 mm 2 / mm or less, preferably 550 mm 2 / mm or less. It is more preferable to have.
  • the cooling segment 12 has a large internal structure and has a large total surface area.
  • the cooling segment 12 may be wrinkled to form a channel and then formed by a sheet of pleated, gathered, and folded thin material. Folding or folds within a given volume of the element increases the total surface area of the cooling segment.
  • the thickness of the constituent material of the cooling segment 12 is not particularly limited, and may be, for example, 5 ⁇ m or more and 500 ⁇ m or less, and may be 10 ⁇ m or more and 250 ⁇ m or less.
  • the aspect of the tobacco rod portion 11 is not particularly limited as long as it is a known aspect, but it is usually an aspect in which the tobacco filler is wrapped with rolling paper. Further, the tobacco rod portion 11 may have a fitting portion with a heater member or the like for heating the tobacco product.
  • the tobacco rod portion 11 formed by wrapping the tobacco filler with rolling paper preferably has a columnar shape, and in this case, the long axis direction of the tobacco rod portion 11 with respect to the width of the bottom surface of the tobacco rod portion 11. It is preferable that the aspect ratio represented by the height of is 1 or more.
  • the shape of the bottom surface is not limited and may be a polygon, a rounded polygon, a circle, an ellipse, etc., and the width is a diameter when the bottom surface is circular, a major axis when the bottom surface is elliptical, a polygonal shape, or a rounded corner polygon.
  • the case is the diameter of the circumscribed circle or the major axis of the circumscribed ellipse.
  • the height of the tobacco filling material constituting the tobacco rod portion 11 is preferably about 10 to 70 mm, and the width is preferably about 4 to 9 mm.
  • the length of the tobacco rod portion in the long axis direction can be appropriately changed according to the size of the product, but is usually 10 mm or more, preferably 12 mm or more, more preferably 15 mm or more, and 18 mm or more. It is more preferably 70 mm or less, preferably 50 mm or less, more preferably 30 mm or less, still more preferably 25 mm or less. Further, the ratio of the length of the tobacco rod portion 11 to the total length h of the non-combustion heating type tobacco 10 in the major axis direction is not particularly limited, but is usually 10% or more from the viewpoint of the balance between the delivery amount and the aerosol temperature.
  • It is preferably 20% or more, more preferably 25% or more, further preferably 30% or more, and usually 80% or less, preferably 70% or less. It is more preferably 60% or less, further preferably 50% or less, particularly preferably 45% or less, and most preferably 40% or less.
  • the material for chopping tobacco contained in the first filling material is not particularly limited, and known materials such as lamina and middle bone can be used. Further, dried tobacco leaves are crushed so that the average particle size is 20 ⁇ m or more and 200 ⁇ m or less to obtain a crushed tobacco product, and the homogenized product is processed into a sheet (hereinafter, also simply referred to as a homogenized sheet). It may be chopped.
  • a so-called strand type may be used in which a uniformed sheet having a length similar to that in the longitudinal direction of the tobacco rod is chopped substantially horizontally with the longitudinal direction of the tobacco rod and filled in the tobacco rod.
  • the width of the tobacco notch is preferably 0.5 mm or more and 2.0 mm or less for filling the tobacco rod.
  • the content of the tobacco filling in the tobacco rod may be 200 mg / rod portion or more, 800 mg / rod portion or less, and 250 mg / rod portion or more, 600 mg / in the case of a tobacco rod having a circumference of 22 mm and a length of 20 mm.
  • the rod portion and below are preferable.
  • the tobacco leaves used for producing the tobacco chopped and the homogenized sheet various types of tobacco can be used. For example, yellow varieties, Burley varieties, Orient varieties, native varieties, other Nicotiana-Tabacam varieties, Nicotiana rustica varieties, and mixtures thereof can be mentioned. As for the mixture, each of the above varieties can be appropriately blended and used so as to obtain the desired taste. Details of the tobacco varieties are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31". There are a plurality of conventional methods for producing the homogenized sheet, that is, a method for crushing tobacco leaves and processing them into a homogenized sheet. The first is a method of producing a papermaking sheet using a papermaking process.
  • the second method is to mix an appropriate solvent such as water with crushed tobacco leaves to homogenize it, then cast the homogenized product thinly on a metal plate or metal plate belt and dry it to make a cast sheet.
  • the third method is to mix an appropriate solvent such as water with crushed tobacco leaves and extrude the homogenized one into a sheet to produce a rolled sheet. Details of the types of the homogenized sheet are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31".
  • the water content of the tobacco filling may be 10% by weight or more and 15% by weight or less, preferably 11% by weight or more and 13% by weight or less, based on the total amount of the tobacco filling. With such a water content, the occurrence of winding stains is suppressed, and the hoisting suitability at the time of manufacturing the tobacco rod is improved.
  • the size of the tobacco nicks contained in the first tobacco filling and the method for preparing the nicks For example, dried tobacco leaves may be chopped to a width of 0.5 mm or more and 2.0 mm or less.
  • a crushed product of a homogenized sheet When a crushed product of a homogenized sheet is used, dried tobacco leaves are crushed so that the average particle size is about 20 to 200 ⁇ m, and the homogenized product is processed into a sheet, which has a width of 0.5 mm or more, 2 Those chopped to 0.0 mm or less may be used.
  • the first tobacco filling may contain an aerosol substrate that produces aerosol smoke.
  • the type of the aerosol base material is not particularly limited, and extracts from various natural products and / or components thereof can be selected depending on the intended use.
  • the aerosol substrate include glycerin, propylene glycol, triacetin, 1,3-butanediol, and mixtures thereof.
  • the content of the aerosol base material in the first tobacco filling is not particularly limited, and is usually 5% by weight based on the total amount of the tobacco filling from the viewpoint of sufficiently producing an aerosol and imparting a good flavor.
  • the above is preferably 10% by weight or more, and usually 50% by weight or less, preferably 15% by weight or more and 25% by weight or less.
  • the first tobacco filling may contain a fragrance.
  • the type of the fragrance is not particularly limited, and from the viewpoint of imparting a good flavor, acetoanisol, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract, amyl alcohol, amyl butyrate, trans-annetol, and staranis oil.
  • Apple juice Peruvian balsam oil, Mitsurou absolute, benzaldehyde, benzoin resinoid, benzyl alcohol, benzyl benzoate, benzyl phenylacetate, benzyl propionate, 2,3-butandione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamon oil , Carob absolute, ⁇ -carotene, carrot juice, L-carboxyl, ⁇ -cariophyllene, cassia bark oil, cedarwood oil, celery seed oil, camomil oil, cinnamaldehyde, silicate syrup, cinnamyl alcohol, cinnamyl silicate, citronella Oil, DL-Citronellol, Clarisage Extract, Cocoa, Coffee, Cognac Oil, Coriander Oil, Cuminaldehyde, Davana Oil, ⁇ -Decalactone, ⁇ -Decalactone, Decanoic Acid, Dil
  • the content of the fragrance in the first tobacco filling is not particularly limited, and is usually 10,000 ppm or more, preferably 20,000 ppm or more, more preferably 25,000 ppm or more, and more preferably 25,000 ppm or more, from the viewpoint of imparting a good flavor. , Usually 70,000 ppm or less, preferably 50,000 ppm or less, more preferably 40,000 ppm or less, still more preferably 33,000 ppm or less.
  • the filling density in the first tobacco filling is not particularly limited, but is usually 250 mg / cm 3 or more, preferably 250 mg / cm 3 or more, from the viewpoint of ensuring the performance of the first non-combustible heat-not-burn tobacco and imparting a good flavor. It is 300 mg / cm 3 or more, and usually 400 mg / cm 3 or less, preferably 350 mg / cm 3 or less.
  • the first tobacco filling described above is wrapped with rolling paper so that it is on the inside to form the tobacco rod portion 11.
  • the second tobacco filling is composed of a tobacco sheet filled in the to be filled.
  • the number of tobacco sheets may be one or two or more.
  • the second tobacco filling is composed of one tobacco sheet
  • a tobacco sheet having one side having a length similar to the longitudinal direction of the filling is the filling.
  • a filling mode can be mentioned in a state where the tobacco is folded back in a plurality of directions horizontally with the longitudinal direction of the tobacco.
  • a tobacco sheet having one side having a length similar to that in the longitudinal direction of the object to be filled is wound in a direction orthogonal to the longitudinal direction of the object to be filled.
  • the second tobacco filling is composed of two or more tobacco sheets
  • a plurality of tobacco sheets having one side having a length similar to the longitudinal direction of the to be filled may be used.
  • Concentrically arranged means that the centers of all tobacco sheets are arranged so as to be substantially in the same position.
  • the number of cigarette sheets is not particularly limited, and examples thereof include two, three, four, five, six, or seven.
  • Two or more tobacco sheets may all have the same composition or physical properties, or some or all of the tobacco sheets may have different compositions or physical properties. Further, the thickness of each tobacco sheet may be the same or different.
  • a plurality of tobacco sheets having different widths are prepared, a laminated body is prepared in which the width decreases from the bottom to the top, and this is passed through a winding tube and rolled up.
  • the plurality of tobacco sheets extend in the longitudinal direction and are arranged concentrically about the longitudinal axis. Further, a fitting portion extending in the longitudinal direction may be formed between the longitudinal axis and the innermost layer of the tobacco sheet.
  • the laminate is prepared so that a non-contact portion is formed between the adjacent tobacco sheets after the winding molding. If there is a non-contact portion (gap) between the plurality of tobacco sheets that the tobacco sheet does not contact, the flavor flow path can be secured and the delivery efficiency of the flavor component can be enhanced. On the other hand, since the heat from the heater can be transferred to the outer tobacco sheet through the contact portions of the plurality of tobacco sheets, high heat transfer efficiency can be ensured.
  • an embossed tobacco sheet is used, and adjacent tobacco sheets are laminated without adhering the entire surfaces of the adjacent tobacco sheets.
  • a method of preparing a laminate by adhering a part of each other and laminating, or by slightly adhering and laminating the entire surface or a part of adjacent tobacco sheets so as to be peeled off after winding molding can be mentioned. ..
  • the above-mentioned wrapping paper may be arranged at the bottom of the laminated body.
  • a fitting portion can be formed by placing a tubular dummy such as a mandrel on the uppermost portion of the laminated body to form a second tobacco filler and then removing the dummy.
  • the filling density of the second tobacco filler is not particularly limited, but is usually 250 mg / cm 3 or more, preferably 300 mg / cm 3 or more, from the viewpoint of ensuring the performance of the tobacco product and imparting a good flavor. Yes, and usually 400 mg / cm 3 or less, preferably 350 mg / cm 3 or less.
  • the content of the second tobacco filler per to be filled is not particularly limited, but for example, in the case of a tobacco rod portion having a circumference of 22 mm and a length of 20 mm, the content is 200 mg / rod portion or more and 800 mg / rod portion or less. Examples thereof include 250 mg / rod portion or more and 600 mg / rod portion or less as suitable examples.
  • the tobacco sheet may contain an aerosol base material that produces aerosol smoke upon heating.
  • An aerosol source such as glycerin, propylene glycol, or a polyol such as 1,3-butanediol is added as an aerosol base material.
  • the amount of the aerosol base material added is preferably 5% by weight or more and 50% by weight or less, more preferably 15% by weight or more and 25% by weight or less, based on the dry weight of the tobacco sheet.
  • the tobacco sheet can be appropriately produced by a known method such as papermaking, slurry, rolling, or the like. It should be noted that the homogenizing sheet described in the first tobacco filling can also be used. In the case of papermaking, it can be manufactured by a method including the following steps. 1) Dried tobacco leaves are coarsely crushed, extracted with water and separated into a water extract and a residue. 2) The water extract is dried under reduced pressure and concentrated. 3) Pulp is added to the residue, fiberized with a refiner, and then made into paper. 4) Add a concentrated solution of water extract to the paper-made sheet and dry it to make a tobacco sheet. In this case, a step of removing a part of the components such as nitrosamine may be added (see Japanese Patent Publication No.
  • the slurry method it can be produced by a method including the following steps. 1) Mix water, pulp and binder with crushed tobacco leaves. 2) The mixture is thinly spread (cast) and dried. In this case, a step of removing some components such as nitrosamines by irradiating a slurry obtained by mixing water, pulp and a binder with crushed tobacco leaves with ultraviolet rays or X-rays may be added.
  • a non-woven fabric-like tobacco sheet produced by a method including the following steps can also be used. 1) Mix the powdered tobacco leaves and the binder. 2) The mixture is sandwiched between non-woven fabrics. 3) The laminate is formed into a constant shape by heat welding to obtain a non-woven fabric-like tobacco sheet.
  • the type of the raw material tobacco leaves used in each of the above methods the same types as those described in the first filling can be used.
  • the composition of the tobacco sheet is not particularly limited, but for example, the content of the tobacco raw material (tobacco leaf) is preferably 50% by weight or more and 95% by weight or less with respect to the total weight of the tobacco sheet.
  • the tobacco sheet may contain a binder, and examples of the binder include guar gum, xanthan gum, CMC (carboxymethyl cellulose), CMC-Na (sodium salt of carboxymethyl cellulose) and the like.
  • the amount of the binder is preferably 1% by weight or more and 10% by weight or less with respect to the total weight of the tobacco sheet.
  • the tobacco sheet may further contain other additives. Examples of the additive include a filler such as pulp. Although a plurality of tobacco sheets are used in the present embodiment, all of the tobacco sheets may have the same composition or physical properties, or some or all of the tobacco sheets may have different compositions or physical properties.
  • a plurality of tobacco sheets having different widths are prepared, a laminated body is prepared in which the width decreases from the bottom to the top, and this is passed through a winding tube and rolled up.
  • the plurality of tobacco sheets extend in the longitudinal direction and are arranged concentrically about the longitudinal axis. Further, a fitting portion extending in the longitudinal direction may be formed between the longitudinal axis and the innermost layer of the tobacco sheet.
  • the laminate is prepared so that a non-contact portion is formed between the adjacent tobacco sheets after the winding molding.
  • the flavor flow path can be secured and the delivery efficiency of the flavor component can be enhanced.
  • the heat from the heater can be transferred to the outer tobacco sheet through the contact portions of the plurality of tobacco sheets, so that high heat transfer efficiency can be ensured.
  • an embossed tobacco sheet is used, and adjacent tobacco sheets are laminated without adhering the entire surfaces of the adjacent tobacco sheets.
  • a method of preparing a laminate by adhering a part of each other and laminating, or by slightly adhering and laminating the entire surface or a part of adjacent tobacco sheets so as to be peeled off after winding molding can be mentioned. ..
  • the above-mentioned wrapping paper may be arranged at the bottom of the laminated body.
  • a fitting portion can be formed by placing a tubular dummy such as a mandrel on the uppermost portion of the laminated body to form a second tobacco filler and then removing the dummy.
  • the thickness of each tobacco sheet is not limited, but is preferably 150 ⁇ m or more and 1000 ⁇ m or less, and more preferably 200 ⁇ m or more and 600 ⁇ m or less, from the viewpoint of heat transfer efficiency and strength.
  • the thickness of each tobacco sheet may be the same or different.
  • the number of tobacco sheets constituting the second tobacco filler is not particularly limited, and examples thereof include 2, 3, 4, 5, 6, or 7 sheets.
  • the third tobacco filling is composed of tobacco granules.
  • the raw material of the third tobacco filling is not particularly limited, but at least one selected from the group consisting of (a) crushed tobacco material, (b) moisture, (c) potassium carbonate and sodium hydrogen carbonate.
  • a pH regulator and at least one binder selected from the group consisting of (d) purulan and hydroxypropyl cellulose can be mentioned.
  • the crushed tobacco material (component (a)) contained in the third tobacco filling includes crushed tobacco leaves, crushed tobacco sheets, and the like. Tobacco varieties include Burley, Yellow and Oriental varieties.
  • the tobacco material is preferably pulverized to a size of 200 ⁇ m or more and 300 ⁇ m or less.
  • the raw material mixture of the third tobacco filling usually contains crushed tobacco material in an amount of 20% by weight or more and 80% by weight or less.
  • Moisture (component (b)) contained in the third tobacco filling is for maintaining the integrity of the tobacco granules.
  • the raw material mixture of the third tobacco filling usually contains water in an amount of 3% by weight or more and 13% by weight or less.
  • the third tobacco filling can usually contain water in an amount of 5% by weight or more and 17% by weight in terms of dry weight loss. Dry weight loss is when a part of the sample is taken for measurement and the sample is completely dried by evaporating the total water content in the collected sample (for example, at a constant temperature (105 ° C.) for 15 minutes.
  • the pH adjuster (component (c)) contained in the third tobacco filler comprises potassium carbonate, sodium hydrogen carbonate or a mixture thereof. These pH regulators adjust the pH of the third tobacco filling to the alkaline side, thereby promoting the release of the flavor component contained in the third tobacco filling from the tobacco granules, which may be satisfactory to the user. Brings flavor.
  • the raw material mixture of the third tobacco filler may usually contain a pH adjuster in an amount of 5% by weight or more and 20% by weight or less.
  • the binder (component (d)) contained in the third tobacco filling is for binding the tobacco granule components to maintain the integrity of the tobacco granules.
  • the binder is composed of pullulan, hydroxypropyl cellulose (HPC) or a mixture thereof.
  • the raw material mixture of the third tobacco filling can usually contain the binder in an amount of 0.5% by weight or more and 15% by weight or less.
  • the third tobacco filling can consist of the above components (a), (b), (c) and (d), but can also include additional components.
  • Additional components include an aerosol substrate (component (e)).
  • the aerosol substrate is one that produces aerosol smoke.
  • the aerosol substrate is composed of a polyhydric alcohol, which may include glycerin, propylene glycol, sorbitol, xylitol and erythritol. These polyhydric alcohols can be used alone or in combination of two or more. When the raw material mixture of the third tobacco filling contains an aerosol substrate, it may be contained in an amount of 5 to 15% by weight.
  • examples of the additional component include (f) a flavoring material (solid or liquid) other than the flavoring component.
  • Such flavoring materials include sugar (sucrose, fructose, etc.), cocoa powder, carob powder, coriander powder, licorice powder, orange peel powder, rose pip powder, chamomile flower (flower) powder, lemon verbena powder, peppermint powder, leaf powder. , Sparemint flour, black tea flour, menthol, etc. are included. These flavoring materials can be used alone or in combination of two or more.
  • the raw material mixture of the third tobacco filling can usually contain the above flavoring material in an amount of 0.5% by weight or more and 30% by weight or less.
  • the flavoring material may be added to the ingredients by directly kneading the ingredients (a), (b), (c), and (d), or a known inclusion host compound such as cyclodextrin.
  • the clathrate compound may be prepared by supporting it in the above-mentioned component and then added to the above-mentioned component by kneading it with the above-mentioned component.
  • the raw material mixture of the third tobacco filling contains the component (a). , Usually, it may be contained in an amount of about 33% by weight or more (about 90% by weight or less).
  • the third tobacco filling is obtained by mixing the components (a), (c) and (d) and, if desired, the components (e) and (f), adding the component (b) to the mixture and kneading. It is obtained by granulating (long columnar) the kneaded material with a wet extruder granulator and then sizing it into short columns or spheres.
  • the average particle size (D50) of the obtained tobacco granules is usually 0.2 mm or more and 1.2 mm or less, preferably 0.2 mm or more and 1.0 mm or less, and 0.2 mm or more and 0.8 mm or less. The following is more preferable.
  • the kneaded product In extruding granulation, it is preferable to extrude the kneaded product at an ambient temperature and a pressure of 2 kN or more. Due to this high-pressure extrusion, the temperature of the kneaded product at the outlet of the extruder and granulator rises instantaneously from the ambient temperature to, for example, 90 to 100 ° C., and the water content and volatile components are 2% by weight or more and 4% by weight. It evaporates below. Therefore, the water to be blended to make the kneaded product can be used in an amount larger than the desired water content in the tobacco granules, which is the final product, by the amount of evaporation.
  • Tobacco granules obtained by extrusion granulation may be further dried if necessary for moisture adjustment. For example, if the dry weight loss of tobacco granules obtained by extruded granulation is measured and it is higher than the desired dry weight loss (eg 5% by weight or more, 17% by weight or less), the tobacco to obtain the desired dry weight loss.
  • the granules may be further dried.
  • the drying conditions (temperature and time) for obtaining the desired drying weight loss shall be set in advance based on the drying conditions (temperature and time) required to reduce the drying weight loss by a predetermined value. Can be done.
  • the third tobacco filling can consist only of the above tobacco granules, but can also contain additional tobacco material. Additional tobacco material is usually tobacco leaf chopped or finely ground. Additional tobacco materials can be used in admixture with tobacco granules.
  • the composition of the rolling paper is not particularly limited and can be a general embodiment, and examples thereof include those having pulp as a main component.
  • wood pulp such as coniferous tree pulp and broadleaf tree pulp
  • non-wood pulp commonly used for wrapping paper for tobacco products such as flax pulp, cannabis pulp, sisal hemp pulp, and esparto is mixed. It may be manufactured and obtained.
  • type of pulp chemical pulp by kraft cooking method, acidic / neutral / alkaline sulfite cooking method, soda salt cooking method, etc., gland pulp, chemi-grand pulp, thermomechanical pulp and the like can be used.
  • a wet paper strength enhancer may be added to impart water resistance to the wrapping paper, or a sizing agent may be added to adjust the printing condition of the wrapping paper.
  • papermaking additives such as aluminum sulfate bands, various anionic, cationic, nonionic or amphoteric yield improvers, drainage improvers, and paper strength enhancers, as well as dyes and pH adjusters. Papermaking additives such as defoaming agents, pitch control agents, and slime control agents can be added.
  • the basis weight of the rolling paper base paper is, for example, usually 20 gsm or more, preferably 25 gsm or more. On the other hand, the basis weight is usually 65 gsm or less, preferably 50 gsm or less, and more preferably 45 gsm or less.
  • the thickness of the rolling paper having the above characteristics is not particularly limited, and is usually 10 ⁇ m or more, preferably 20 ⁇ m or more, more preferably 30 ⁇ m or more, from the viewpoint of rigidity, breathability, and ease of adjustment during papermaking. It is usually 100 ⁇ m or less, preferably 75 ⁇ m or less, and more preferably 50 ⁇ m or less.
  • the non-combustion heat-not-burn tobacco wrapping paper may have a square or rectangular shape.
  • the length of one side can be about 12 to 70 mm, and the length of the other side is 15 to 28 mm.
  • a preferable length of one side is 22 to 24 mm, and a more preferable length is about 23 mm.
  • the rolling paper may contain a filler.
  • the content of the filler may be 10% by weight or more and less than 60% by weight, preferably 15% by weight or more and 45% by weight or less, based on the total weight of the wrapping paper.
  • the filler is preferably 15% by weight or more and 45% by weight or less in a preferable range of the basis weight (25 gsm or more and 45 gsm or less). Further, when the basis weight is 25 gsm or more and 35 gsm or less, the filler is preferably 15% by weight or more and 45% by weight or less, and when the basis weight is more than 35 gsm and 45 gsm or less, the filler is 25% by weight or more and 45 weight. % Or less is preferable.
  • the filler calcium carbonate, titanium dioxide, kaolin and the like can be used, but it is preferable to use calcium carbonate from the viewpoint of enhancing the flavor and whiteness.
  • the water resistance improver includes a wet paper strength enhancer (WS agent) and a sizing agent.
  • WS agent wet paper strength enhancer
  • PAE polyamide epichlorohydrin
  • sizing agents include rosin soap, alkyl ketene dimer (AKD), alkenyl succinic anhydride (ASA), and highly saponified polyvinyl alcohol having a saponification degree of 90% or more.
  • a paper strength enhancer may be added, and examples thereof include polyacrylamide, cation starch, oxidized starch, CMC, polyamide epichlorohydrin resin, polyvinyl alcohol and the like.
  • the air permeability of oxidized starch is improved by using a very small amount (Japanese Unexamined Patent Publication No. 2017-218699).
  • the rolling paper may be appropriately coated.
  • a coating agent may be added to at least one of the two front and back surfaces of the wrapping paper.
  • the coating agent is not particularly limited, but a coating agent capable of forming a film on the surface of paper and reducing the permeability of the liquid is preferable.
  • alginic acid and salts thereof eg sodium salt
  • polysaccharides such as pectin, ethyl cellulose, methyl cellulose, carboxymethyl cellulose, cellulose derivatives such as nitrocellulose, starch and derivatives thereof (eg carboxymethyl starch, hydroxyalkyl starch and cationic starch).
  • ether derivatives such as ether derivatives, ester derivatives such as starch acetate, starch phosphate and starch octenyl succinate).
  • the composition of the chip paper 15 is not particularly limited and can be a general embodiment, and examples thereof include those having pulp as a main component.
  • pulp in addition to being made from wood pulp such as coniferous tree pulp and broadleaf tree pulp, non-wood pulp commonly used for wrapping paper for tobacco articles such as flax pulp, cannabis pulp, sisal hemp pulp, and esparto is mixed. It may be manufactured and obtained. These pulps may be used alone or in combination of a plurality of types at any ratio.
  • the chip paper 15 may be composed of one sheet, but may be composed of a plurality of sheets or more.
  • the chip paper 15 may be manufactured by the manufacturing method described later or may be a commercially available product.
  • the shape of the chip paper 15 is not particularly limited and may be, for example, a square or a rectangle.
  • the basis weight of the chip paper 15 is not particularly limited, but is usually 32 gsm or more and 40 gsm or less, preferably 33 gsm or more and 39 gsm or less, and more preferably 34 gsm or more and 38 gsm or less.
  • the thickness of the chip paper 15 is not particularly limited, and is usually 20 ⁇ m or more and 140 ⁇ m or less, preferably 30 ⁇ m or more and 130 ⁇ m or less, and more preferably 30 ⁇ m or more and 120 ⁇ m or less.
  • the air permeability of the chip paper 15 is not particularly limited, but is usually 0 cholesterol unit or more and 30,000 cholesterol units or less, and 0 cholesterol unit or more and 10,000 cholesterol units or less is preferable.
  • the air permeability referred to in the present specification is a value measured in accordance with ISO 2965: 2009, and when the differential pressure on both sides of the paper is 1 kPa, the gas passing through an area of 1 cm 2 every minute. It is expressed by the flow rate (cm 3 ).
  • One cholesterol unit (1 C.U.) is cm 3 / (min ⁇ cm 2 ) under 1 kPa.
  • the chip paper 15 may contain a filler in addition to the above pulp, for example, metal carbonates such as calcium carbonate and magnesium carbonate, metal oxides such as titanium oxide, titanium dioxide and aluminum oxide, barium sulfate, and the like.
  • metal carbonates such as calcium carbonate and magnesium carbonate
  • metal oxides such as titanium oxide, titanium dioxide and aluminum oxide
  • barium sulfate and the like.
  • metal sulfates such as calcium sulfate, metal sulfides such as zinc sulfide, quartz, kaolin, talc, caestic soil, gypsum, etc.
  • calcium carbonate from the viewpoint of improving whiteness and opacity and increasing the heating rate.
  • these fillers may be used alone or in combination of two or more.
  • the chip paper 15 may have a water resistance improver in order to improve it.
  • the water resistance improver includes a wet paper strength enhancer (WS agent) and a sizing agent.
  • wet paper strength enhancer include urea formaldehyde resin, melamine formaldehyde resin, and polyamide epichlorohydrin (PAE).
  • PAE polyamide epichlorohydrin
  • sizing agents include rosin soap, alkyl ketene dimer (AKD), alkenyl succinic anhydride (ASA), and highly saponified polyvinyl alcohol having a saponification degree of 90% or more.
  • a coating agent may be added to at least one of the two front and back surfaces of the chip paper 15.
  • the coating agent is not particularly limited, but a coating agent capable of forming a film on the surface of paper and reducing the permeability of the liquid is preferable.
  • the above-mentioned non-combustion heating type tobacco production method is not particularly limited, and a known method can be applied.
  • it can be manufactured by winding the tobacco rod portion and the mouthpiece portion with chip paper.
  • An electrically heated tobacco product (also simply referred to as "electrically heated tobacco product") according to another embodiment of the present invention controls a heater member, a battery unit that is a power source of the heater member, and the heater member.
  • An electrically heated tobacco product comprising an electrically heated device provided with a control unit for heating and the above-mentioned non-combustion heated tobacco inserted so as to come into contact with the heater member.
  • the mode of the electrically heated tobacco product may be a mode of heating the outer peripheral surface of the non-combustion heated tobacco 10 as shown in FIG. 3, and the tobacco in the non-combustion heated tobacco 10 as shown in FIG. The mode may be such that heating is performed from the inside of the rod portion 11.
  • the electrically heated device 20 shown in FIGS. 3 and 4 is provided with an air introduction hole, but is not shown here.
  • the electrically heated tobacco product 30 will be described with reference to FIG. Regarding the non-combustion heat-not-burn tobacco 10 in FIGS. 3 and 4, the reference numerals representing the respective configurations shown in FIGS. 1 and 2 are partially omitted.
  • the heat-not-burn tobacco product 30 is used by being inserted into a heater member 21 arranged inside the heat-not-burn device 20 so that the non-combustion heat-not-burn tobacco 10 described above comes into contact with the heater member 21.
  • the electrically heating device 20 has, for example, a battery unit 22 and a control unit 23 inside a resinous skeleton 24.
  • the non-combustion heating type tobacco 10 When the non-combustion heating type tobacco 10 is inserted into the electric heating type device 20, the outer peripheral surface of the tobacco rod portion 11 comes into contact with the heater member 21 of the electric heating type device 20, and eventually the entire outer peripheral surface of the tobacco rod portion 11 and the chip paper A part of the outer peripheral surface of the above comes into contact with the heater member 21.
  • the heater member 21 of the electric heating type device 20 generates heat under the control of the control unit 23.
  • the heat is transferred to the tobacco rod portion 11 of the non-combustion heating type tobacco 10, the aerosol base material and the flavor component contained in the tobacco filling of the tobacco rod portion 11 volatilize.
  • the heater member 21 may be, for example, a sheet heater, a flat plate heater, or a tubular heater.
  • the sheet-shaped heater is a flexible sheet-shaped heater, and examples thereof include a heater containing a heat-resistant polymer film (thickness of about 20 to 225 ⁇ m) such as polyimide.
  • the flat plate heater is a rigid flat plate heater (thickness of about 200 to 500 ⁇ m), and examples thereof include a heater having a resistance circuit on a flat plate base material and using the portion as a heat generating portion.
  • the tubular heater is a hollow or solid cylindrical heater (thickness of about 200 to 500 ⁇ m), and examples thereof include a heater having a resistance circuit on the outer peripheral surface of a cylinder made of metal or the like and having the portion as a heat generating portion. .. Further, a rod-shaped heater made of metal or the like having a resistance circuit inside and having the portion as a heat generating portion, and a cone-shaped heater can also be mentioned.
  • the cross-sectional shape of the tubular heater may be a circle, an ellipse, a polygon, a polygon with rounded corners, or the like. In the embodiment of heating the outer peripheral surface of the non-combustion heating type cigarette 10 as shown in FIG.
  • the above-mentioned sheet-shaped heater, flat plate-shaped heater, and tubular heater can be used.
  • the above-mentioned flat plate heater, columnar heater, and conical heater can be used.
  • the length of the heater member 21 in the long axis direction can be within the range of L ⁇ 5.0 mm when the length of the tobacco rod portion 11 in the long axis direction is L mm.
  • the length of the heater member 21 in the major axis direction sufficiently transfers heat to the tobacco rod portion 11 and sufficiently volatilizes the aerosol base material, flavor components, etc.
  • L mm contained in the tobacco filling, that is, from the viewpoint of aerosol delivery, L mm.
  • L + 0.5 mm or less L + 1.0 mm or less, L + 1.5 mm or less, L + 2.0 mm or less, L + 2.5 mm or less, L + 3 It is preferably 0.0 mm or less, L + 3.5 mm or less, L + 4.0 mm or less, L + 4.5 mm or less, or L + 5.0 mm or less.
  • the heating intensity such as the heating time and the heating temperature of the non-combustion heating type tobacco 10 by the heater member 21 can be set in advance for each of the electric heating type tobacco products 30. For example, by inserting the non-combustion heating type tobacco 10 into the electric heating type device 20 and then performing preheating for a certain period of time, the outer periphery of the portion of the non-combustion heating type tobacco 10 inserted into the electric heating type device 20 is performed. It can be heated in advance until the surface temperature reaches X (° C.), and then the temperature is maintained at a constant temperature of X (° C.) or lower.
  • the X (° C.) is preferably 80 ° C. or higher and 400 ° C.
  • the steam containing components derived from the aerosol base material, components derived from the flavor component, etc. generated from the tobacco rod portion 11 by heating by the heater member 21 is passed through the mouthpiece portion 14 composed of the cooling segment 12, the filter segment 13, and the like to the user. Reach the oral cavity.
  • the opening V provided in the cooling segment 12 is cooled as shown in FIG. 5 from the viewpoint of promoting the inflow of air from the outside and suppressing the retention of components and air generated by heating in the cooling segment 12. It is preferable that the segment 12 is present on the mouthpiece end side rather than the mouthpiece end side end (point indicated by the arrow X in the figure) of the region in contact with the electrically heated device 20. Further, the insertion port of the non-combustion heating type cigarette 10 of the electric heating type device 20 may be tapered as shown in FIG. 6 in order to facilitate the insertion of the non-combustion heating type cigarette 10. The end portion on the mouthpiece end side of the region in contact with the electrically heated device 20 is the position indicated by the arrow Y in the figure. Regarding the non-combustion heat-not-burn tobacco 10 in FIGS. 5 and 6, some reference numerals representing the respective configurations shown in FIGS. 1 to 4 are omitted.
  • Example 1 As a tobacco filling, a mixture of 15 g / 100 g of glycerin and 4 g / 100 g of propylene glycol in small pieces of sheet tobacco was prepared in advance. Using a high-speed winder, the tobacco filling was wound up with rolling paper (manufactured by Nippon Paper Papylia, basis weight 35 g / m 2 , thickness 52 ⁇ m). The stepped weight per piece was 1.02 g, the winding circumference was 22 mm, and the winding length was 80 mm. The rolled-up tobacco rods were stored in plastic airtight containers with 200 pieces for each level.
  • the stored tobacco rod portion was cut to a length of 20 mm. After that, a tobacco rod portion, a 20 mm long paper tube, a center hole segment (5.8Y35000) having a 6 mm long hollow hole (4.5 mm in diameter), and a 7 mm long cellulose acetate fiber are filled.
  • a filter having a length of 7 mm in which activated carbon is substantially uniformly dispersed in cellulose acetate fibers and two filter segments consisting of a filter composed of cellulose acetate fibers having the same length are used.
  • the filter filter medium As a specific addition amount, 25 mg was added to the filter filter medium (length 10 mm).
  • the specific surface area of the added activated carbon was 1350 m 2 / g, and the pore volume was 0.71 mL / g.
  • the diameter of the opening was adjusted so that the air inflow ratio from the opening was 72% by volume when sucked at 17.5 ml / sec with a single-fenestra automatic smoking machine manufactured by Borgwaldt. This air inflow ratio was measured by a method compliant with ISO9512. Also in all the examples and comparative examples described later, the diameter of the opening was adjusted so that the air inflow ratio was 72% by volume.
  • Example 1 The same method as in Example 1 was applied except that activated carbon was not added to the filter medium, and the non-combustion heat-not-burn tobacco of Comparative Example 1 was prepared.
  • Example 2 The amount of activated carbon added to the filter filter medium was added so that the value of the surface area of the activated carbon per unit cross-sectional area was 12.0 m 2 / cm 2 (3.5 mg with respect to the filter filter medium (length 7 mm)). Except for this, the same method as in Example 1 was applied to prepare a non-combustion heat-not-burn tobacco of Comparative Example 2.
  • Example 1 and Comparative Examples 1 and 2 were subjected to a smoking test, and the delivery amount of the component produced by heating was evaluated.
  • the smoking test was conducted under the following conditions with reference to Canadian Intense Smoking (CIR). After inserting non-combustion heating type cigarettes using an electric heating type device that heats the outer circumference, the heater temperature is raised to 295 ° C within 21 seconds and lowered to 260 ° C within 5 seconds until the end of evaluation ( It was maintained at 260 ° C. (for about 330 seconds).
  • CIR Canadian Intense Smoking
  • the amount of activated carbon added to the filter filter medium is added so that the value of the surface area of the activated carbon per unit cross-sectional area is 0 to 59.7 m 2 / cm 2 (filter filter medium (length 7 mm). It was found that the non-combustion heat-not-burn tobacco according to Examples 1 and 2 to which 0 to 17.5 mg was added) had a sufficient delivery amount of nicotine, glycerin, and propylene glycol. On the other hand, it is added so that the surface area value of activated carbon per unit cross-sectional area is 83.6 to 107.4 m 2 / cm 2 (24.5 or 31.5 mg is added to the filter medium (length 7 mm)). In Comparative Examples 1 and 2, the delivery amounts of nicotine and propylene glycol were not sufficient.
  • the non-combustion heating type cigarettes of Examples 2 to 4 prepared by adjusting the amount of activated carbon added as shown in Table 1 are commercially available. Used by panelists by inserting into an electrically heated device. At that time, each item of discomfort, tobacco flavor, and charcoal odor felt by the panelists was evaluated. The number of panelists was 10, and the evaluation points were average points. As evaluation criteria, 1: it is functioning in the wrong direction, 2: it is functioning in the slightly bad direction, 3: it is unchanged, 4: it is functioning in the slightly better direction, and 5: it is functioning in the good direction. It was evaluated on a five-point scale.
  • a non-combustion heat-not-burn tobacco that can deliver a desired amount of a component produced by heating to a user and give a desired flavor to the user. And it can be seen that an electroheated tobacco product can be provided.
  • Non-combustion heating type tobacco 11 Tobacco rod part 12 Cooling segment 13 Filter segment 13a Filter filter medium with activated charcoal added 13b Filter filter medium without activated charcoal 14 Mouthpiece part 15 Chip paper V Opening 20 Electric heating type device 21 Heater member 22 Battery Unit 23 Control unit 24 Frame 30 Electric heating type tobacco products

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

L'invention concerne un tabac chauffé sans combustion pourvu d'une partie boudin de tabac et d'une partie embout. Ladite partie embout comprend un segment de refroidissement et un segment de filtre qui contient un matériau filtrant. La partie boudin de tabac et le segment de refroidissement sont disposés adjacents l'un à l'autre. Du charbon actif est ajouté au matériau filtrant. La quantité d'addition de charbon actif varie de 15,0 à 80 m2/cm2 lorsqu'elle est représentée par la valeur suivante : surface spécifique du charbon actif × poids du charbon actif/aire de section transversale du matériau filtrant dans la direction perpendiculaire à la direction du flux d'air.
PCT/JP2021/043770 2020-12-24 2021-11-30 Tabac chauffé sans combustion et produit de tabac chauffé électriquement WO2022138008A1 (fr)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013067511A2 (fr) 2011-11-03 2013-05-10 Celanese Acetate Llc Produits de rubans de câble à denier élevé par filament et à fin denier total
WO2014104078A1 (fr) 2012-12-28 2014-07-03 日本たばこ産業株式会社 Source de saveur pour produit de tabac du type à inhalation sans combustion, et produit de tabac du type à inhalation sans combustion
JP2017218699A (ja) 2016-06-09 2017-12-14 日本製紙パピリア株式会社 喫煙物品用巻紙
WO2019106798A1 (fr) * 2017-11-30 2019-06-06 日本たばこ産業株式会社 Article d'inhalation d'arôme
WO2020100928A1 (fr) * 2018-11-14 2020-05-22 日本たばこ産業株式会社 Produit à fumer non chauffé par combustion et système à fumer non chauffé par combustion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013067511A2 (fr) 2011-11-03 2013-05-10 Celanese Acetate Llc Produits de rubans de câble à denier élevé par filament et à fin denier total
WO2014104078A1 (fr) 2012-12-28 2014-07-03 日本たばこ産業株式会社 Source de saveur pour produit de tabac du type à inhalation sans combustion, et produit de tabac du type à inhalation sans combustion
JP2017218699A (ja) 2016-06-09 2017-12-14 日本製紙パピリア株式会社 喫煙物品用巻紙
WO2019106798A1 (fr) * 2017-11-30 2019-06-06 日本たばこ産業株式会社 Article d'inhalation d'arôme
WO2020100928A1 (fr) * 2018-11-14 2020-05-22 日本たばこ産業株式会社 Produit à fumer non chauffé par combustion et système à fumer non chauffé par combustion

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Encyclopedia of Tobacco", 31 March 2009, TOBACCO ACADEMIC STUDIES CENTER

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