WO2022127104A1 - 高牌号无取向硅钢及其生产方法 - Google Patents
高牌号无取向硅钢及其生产方法 Download PDFInfo
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- WO2022127104A1 WO2022127104A1 PCT/CN2021/107028 CN2021107028W WO2022127104A1 WO 2022127104 A1 WO2022127104 A1 WO 2022127104A1 CN 2021107028 W CN2021107028 W CN 2021107028W WO 2022127104 A1 WO2022127104 A1 WO 2022127104A1
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- Prior art keywords
- steel
- silicon steel
- cooling
- oriented silicon
- temperature
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- 229910000976 Electrical steel Inorganic materials 0.000 title claims abstract description 93
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 49
- 238000005096 rolling process Methods 0.000 claims abstract description 87
- 239000002253 acid Substances 0.000 claims abstract description 48
- 238000009749 continuous casting Methods 0.000 claims abstract description 38
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 32
- 239000000126 substance Substances 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 238000010606 normalization Methods 0.000 claims abstract description 21
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 21
- 229910052718 tin Inorganic materials 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 130
- 229910000831 Steel Inorganic materials 0.000 claims description 93
- 239000010959 steel Substances 0.000 claims description 93
- 238000001816 cooling Methods 0.000 claims description 82
- 229910052742 iron Inorganic materials 0.000 claims description 54
- 238000000137 annealing Methods 0.000 claims description 51
- 239000011572 manganese Substances 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 48
- 229910000859 α-Fe Inorganic materials 0.000 claims description 39
- 238000005554 pickling Methods 0.000 claims description 37
- 239000000243 solution Substances 0.000 claims description 32
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- 238000007670 refining Methods 0.000 claims description 21
- 238000005097 cold rolling Methods 0.000 claims description 20
- 238000003723 Smelting Methods 0.000 claims description 19
- 229910001566 austenite Inorganic materials 0.000 claims description 19
- 230000006698 induction Effects 0.000 claims description 19
- 230000009466 transformation Effects 0.000 claims description 18
- 238000010079 rubber tapping Methods 0.000 claims description 16
- 239000010936 titanium Substances 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052804 chromium Inorganic materials 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 229910052720 vanadium Inorganic materials 0.000 claims description 12
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 10
- 238000010583 slow cooling Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 239000002893 slag Substances 0.000 claims description 7
- 238000005261 decarburization Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 241001062472 Stokellia anisodon Species 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 5
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000008237 rinsing water Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract description 8
- 238000003825 pressing Methods 0.000 abstract 2
- 239000000047 product Substances 0.000 description 37
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000001953 recrystallisation Methods 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 238000005098 hot rolling Methods 0.000 description 9
- 230000009286 beneficial effect Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 230000008030 elimination Effects 0.000 description 3
- 238000003379 elimination reaction Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- -1 Si: 1.4 to 1.7% Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
- C23G3/027—Associated apparatus, e.g. for pretreating or after-treating
- C23G3/029—Associated apparatus, e.g. for pretreating or after-treating for removing the pickling fluid from the objects
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
- C22C2202/02—Magnetic
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention belongs to the technical field of iron and steel material preparation, relates to a high-grade non-oriented silicon steel, and also relates to a production method of the high-grade non-oriented silicon steel.
- Non-oriented silicon steel is the iron core material for the rotors of motors and generators that work in rotating magnetic fields, requiring good magnetic properties, including lower iron loss and higher magnetic induction. According to the technical standards and technical agreements of various countries, non-oriented silicon steel with iron loss P1.5/50 ⁇ 4.00W/kg is usually called high-grade non-oriented silicon steel. High-grade non-oriented silicon steel is mainly divided into 4 categories according to thickness specifications. : 0.35mm thickness series, 0.50mm thickness series, special thick specification series and special thin specification series. High-grade non-oriented silicon steel is mainly used in large motors, small and medium-sized high-efficiency motors, energy-saving home appliances and motors for electric vehicles, micro-special motors, precision instruments and other equipment products.
- Si element is the main element that affects the iron loss.
- the iron loss value of non-oriented silicon steel decreases, that is, the chemical composition of high-grade non-oriented silicon steel is usually For high silicon steel.
- the increase of Si content makes the austenite-ferrite transformation temperature higher, or there is no transformation. Therefore, in the production process of high-grade non-oriented silicon steel, finishing rolling is generally carried out in the low-temperature ferrite area. The deformed ferrite structure after rolling cannot be recrystallized, and a deformed fibrous structure is obtained. If the hot-rolled coil containing the fibrous structure is directly subjected to cold rolling and finished annealing, the resulting finished product will have fine grains, corrugated defects on the surface, and poor magnetic properties or even substandard.
- the existing effective solution to the above problems is the normalization treatment of the hot-rolled coil before cold rolling.
- the normalization treatment Through the normalization treatment, the deformed fiber structure of the ferrite can be recrystallized to improve the magnetic properties of the finished product and eliminate surface corrugation defects.
- adding a normalization treatment process not only makes the production process of high-grade non-oriented silicon steel more complicated and increases the difficulty of production, but also increases equipment investment and greatly increases production costs. It is not universal, and the universality is poor.
- the object of the present invention is to provide a production method of high-grade non-oriented silicon steel that does not require normalization treatment, and to provide a kind of using High-grade non-oriented silicon steel prepared by the production method.
- the thickness of the obtained non-oriented silicon steel product is 0.500 ⁇ 0.005mm, its iron loss P 1.5/50 ⁇ 3.8W/kg, and the magnetic induction intensity B 5000 ⁇ 1.71;
- the thickness of the obtained non-oriented silicon steel product is 0.350 ⁇ 0.004mm, the iron loss P 1.5/50 ⁇ 3.3W/kg, and the magnetic induction intensity B 5000 ⁇ 1.70.
- an embodiment of the present invention also provides a method for producing the high-grade non-oriented silicon steel, which comprises the following steps:
- step 2 2) continuous casting the molten steel obtained in step 1 into a continuous casting billet with a thickness of more than 200 mm;
- step 3 heating the continuous casting billet obtained in step 2 to 1120-1150 °C and keeping the temperature for more than 200min, then through multiple passes of rough rolling to obtain an intermediate billet with a thickness of 40 to 45 mm, and then through multiple passes of finishing rolling, cooling, and coiling to obtain Hot-rolled coils with a thickness of 2.50 ⁇ 0.1mm, the finishing temperature of finishing rolling is 890 ⁇ 15°C, the reduction of the last finishing rolling is ⁇ 30%, and the total reduction of the last two finishing rollings ⁇ 50%, the coiling temperature is 650 ⁇ 20°C;
- step 3 The hot-rolled coil obtained in step 3 is not subjected to normalization treatment and is sequentially subjected to uncoiling, pickling, rinsing, drying, cold rolling and coiling to obtain a chilled coil with a thickness of 0.500 ⁇ 0.005mm or 0.350 ⁇ 0.004mm ;
- step 5 Finish annealing of the chilled coil obtained in step 4 in a mixed atmosphere of H 2 +N 2 in a continuous annealing furnace, wherein the finished annealing temperature is 920-980° C., and the annealing time is 60 ⁇ 5s; the annealed steel strip After cooling, coating and finishing, the finished product of non-oriented silicon steel is obtained.
- step 3 the continuous casting slab obtained in step 2 is heated to 1130-1150° C. and kept for more than 200 minutes.
- step 3 the cooling process: two-stage cooling is performed on the steel sheet obtained by finish rolling, the first stage cooling is natural slow cooling without water cooling and lasts for 3-8s, and the second stage cooling is water cooling rapid cooling.
- the temperature of the molten iron after desulfurization is controlled to be greater than or equal to 1320°C and the content of S is less than or equal to 0.0015% in terms of mass percentage, and the slag removal rate is greater than or equal to 98%;
- the desulfurized molten iron mixed with scrap steel is smelted in the converter, wherein the mass ratio of the scrap steel to the total molten steel is 20-25%; in the tapping process, according to the Sn in the finished product: 0.015-0.035% to the steel Add enough tin ingots to the water; after tapping, add slag surface deoxidizer to the molten steel;
- HCl is used for three-stage pickling, wherein the concentration of the first-stage acid solution is 50-80 g/L and the concentration of Fe 2+ in the acid solution is ⁇ 130g/L, the second-stage acid concentration is 90-120g/L and the Fe 2+ concentration in the acid solution is ⁇ 90g/L, the third-stage acid solution is 140-160g/L and the Fe 2+ concentration in the acid solution ⁇ 50g/L;
- the temperature of the acid solution is 75-85°C
- the acid solution contains a silicon steel pickling accelerator
- the weight percentage of the silicon steel pickling accelerator in the acid solution is 0.05-0.10%
- the rinsing water temperature is 45-55°C, and the pickling and rinsing speeds are controlled at 100-180 mpm.
- step 5 three-stage cooling is used to cool the finished annealed steel strip, wherein: the first stage of cooling is slow cooling in the high-temperature section, and the steel strip is cooled from the annealing temperature at a cooling rate of ⁇ 5°C/s to 850°C; the second stage cooling is controlled cooling by circulating gas jet, the steel strip continues to cool from 850°C to below 350°C at a cooling rate of ⁇ 15°C/s; the third stage cooling is circulating water jet cooling, the steel strip is cooled from 350°C Continue to cool to below 100°C.
- the first stage of cooling is slow cooling in the high-temperature section, and the steel strip is cooled from the annealing temperature at a cooling rate of ⁇ 5°C/s to 850°C
- the second stage cooling is controlled cooling by circulating gas jet, the steel strip continues to cool from 850°C to below 350°C at a cooling rate of ⁇ 15°C/s
- the third stage cooling is circulating water jet cooling, the steel strip
- another embodiment of the present invention also provides a method for producing the high-grade non-oriented silicon steel, which comprises the following steps:
- step 2 2) continuous casting the molten steel obtained in step 1 into a continuous casting billet with a thickness of more than 200 mm;
- finishing temperature of finishing rolling is (A r1 -40) ⁇ 15°C
- a r1 represents the temperature of austenite to ferrite transformation
- the reduction of the last finishing rolling is greater than or equal to 30%
- the coiling temperature is 650 ⁇ 20°C.
- step 3 The hot-rolled coil obtained in step 3 is not subjected to normalization treatment and is sequentially subjected to uncoiling, pickling, rinsing, drying, cold rolling and coiling to obtain a chilled coil with a thickness of 0.500 ⁇ 0.005mm or 0.350 ⁇ 0.004mm ;
- step 5 Finish annealing of the chilled coil obtained in step 4 in a mixed atmosphere of H 2 +N 2 in a continuous annealing furnace, wherein the finished annealing temperature is 920-980° C., and the annealing time is 60 ⁇ 5s; the annealed steel strip After cooling, coating and finishing, the finished product of non-oriented silicon steel is obtained.
- step 3 the continuous casting slab obtained in step 2 is heated to 1130-1150° C. and kept for more than 200 minutes.
- step 3 A r1 is 933°C, and the finishing temperature of finish rolling is 893 ⁇ 15°C.
- the temperature of the molten iron after desulfurization is controlled to be greater than or equal to 1320°C and the content of S is less than or equal to 0.0015% in terms of mass percentage, and the slag removal rate is greater than or equal to 98%;
- the desulfurized molten iron mixed with scrap steel is smelted in the converter, wherein the mass ratio of the scrap steel to the total molten steel is 20-25%; in the tapping process, according to the Sn in the finished product: 0.015-0.035% to the steel Add enough tin ingots to the water; after tapping, add slag surface deoxidizer to the molten steel;
- HCl is used for three-stage pickling, wherein the concentration of the first-stage acid solution is 50-80 g/L and the concentration of Fe 2+ in the acid solution is ⁇ 130g/L, the second-stage acid concentration is 90-120g/L and the Fe 2+ concentration in the acid solution is ⁇ 90g/L, the third-stage acid solution is 140-160g/L and the Fe 2+ concentration in the acid solution ⁇ 50g/L;
- the temperature of the acid solution is 75-85°C
- the acid solution contains a silicon steel pickling accelerator
- the weight percentage of the silicon steel pickling accelerator in the acid solution is 0.05-0.10%
- the rinsing water temperature is 45-55°C, and the pickling and rinsing speeds are controlled at 100-180 mpm.
- step 5 three-stage cooling is used to cool the finished annealed steel strip, wherein: the first stage of cooling is slow cooling in the high-temperature section, and the steel strip is cooled from the annealing temperature at a cooling rate of ⁇ 5°C/s to 850°C; the second stage cooling is controlled cooling by circulating gas jet, the steel strip continues to cool from 850°C to below 350°C at a cooling rate of ⁇ 15°C/s; the third stage cooling is circulating water jet cooling, the steel strip is cooled from 350°C Continue to cool to below 100°C.
- the first stage of cooling is slow cooling in the high-temperature section, and the steel strip is cooled from the annealing temperature at a cooling rate of ⁇ 5°C/s to 850°C
- the second stage cooling is controlled cooling by circulating gas jet, the steel strip continues to cool from 850°C to below 350°C at a cooling rate of ⁇ 15°C/s
- the third stage cooling is circulating water jet cooling, the steel strip
- the non-oriented silicon steel product prepared by the production method is that the iron loss P 1.5/50 ⁇ 3.8W/kg of the finished product with a thickness of 0.50 mm, the magnetic induction intensity B 5000 ⁇ 1.71, and the specification is the finished product with a thickness of 0.35 mm
- the production line can be used for different grades of products of medium, low and high.
- the finishing rolling temperature of finishing rolling is controlled in the two-phase region.
- high-temperature ferrite area in order to form high-temperature ferrite and avoid the formation of the deformed fiber structure described in the background art, high-temperature ferrite constitutes the basic condition for subsequent recrystallization; further, combined with the last two passes of finishing rolling
- the high-temperature ferrite formed during final rolling has more internal storage energy, which is beneficial to the recrystallization of high-temperature ferrite and the elimination of fiber structure; at the same time, by controlling the low coiling temperature and finishing rolling
- the large reduction in the last two passes can also avoid the formation of dense oxide scale, so as not to increase the difficulty of oxide scale removal in subsequent pickling;
- Fig. 1 is the microscopic metallographic structure photograph of the hot-rolled coil of Example 1 provided by the present invention
- FIG. 2 is a microscopic metallographic photograph of the hot-rolled coil of Example 3 provided by the present invention.
- An embodiment of the present invention provides a method for producing high-grade non-oriented silicon steel, and a high-grade non-oriented silicon steel prepared by using the production method.
- the production method comprises the following steps in sequence: molten iron desulfurization, converter smelting, RH refining, continuous casting, hot rolling, acid rolling, annealing, cooling, coating and finishing, and no normalization treatment is required before acid rolling , and the obtained non-oriented silicon steel has good magnetic properties and no corrugated defects on the surface, which meets the needs of low-cost and high-grade non-oriented silicon steel.
- C In non-oriented silicon steel, it is generally considered that C is a harmful element. The increase of C content will lead to fine grains, high iron loss, low magnetic induction, and magnetic aging problems in the finished product. Therefore, the lower the C content is, the better Good; but in this embodiment, a small amount of C is contained in the chemical composition and the C content (in mass percentage) is controlled to be 0.002-0.004%, which can expand the austenite region and avoid the problem that the amount of alloy added caused by C is difficult to control during production. .
- Si It is an effective additive element to improve resistivity and reduce iron loss, but with the increase of Si content, the austenite region decreases. When Si>1.7%, there is no austenite transformation. In order to achieve low iron loss to ensure To obtain high-grade non-oriented silicon steel, the Si content (in mass percent) is controlled to 1.4-1.7%.
- Mn Adding an appropriate amount of Mn can suppress the hot brittleness caused by S.
- the solid solubility of MnS in austenite is lower than that in ferrite, which can promote the coarsening of MnS and facilitate grain growth; in this embodiment
- the austenite-ferrite transformation temperature that is, the austenite to ferrite transformation temperature A r1 described in the present invention
- S It is a harmful element.
- the increase of S will lead to the decrease of magnetic induction intensity and the increase of iron loss.
- the content of S in mass percentage is controlled not to exceed 0.003 %.
- P It has little effect on the magnetic properties.
- the increase of the P content can effectively improve the strength of the steel sheet and improve the punchability.
- the strength is sufficiently high due to the high content of Si and Mn, so there is no need to add P specially.
- the upper limit of the content of P does not need to be controlled too low, and can be controlled at not more than 0.03%.
- Sn is a grain boundary segregation element.
- adding Sn to the chemical composition and controlling the Sn content (in mass percentage) to 0.015-0.035% can significantly reduce the proportion of ⁇ 111 ⁇ unfavorable texture, which is beneficial to Improve the magnetic induction intensity of the finished product without normalizing.
- Nb, V, Ti, Mo, Cr, Ni, Cu, N the more these elements are, the more unfavorable the grain growth during the annealing process, and then deteriorate the magnetic properties of non-oriented silicon steel, resulting in increased iron loss and decreased magnetic induction , so the lower the content within the controllable range, the better, for example, Nb ⁇ 0.004%, V ⁇ 0.004%, Ti ⁇ 0.005%, Mo ⁇ 0.004%, Cr ⁇ 0.03%, Ni ⁇ 0.03%, Cu ⁇ 0.03%, N ⁇ 0.003%.
- the austenite-ferrite transformation temperature increases due to the increase of the austenite-ferrite transformation temperature.
- the austenite-ferrite transformation temperature is basically kept constant, in order to eliminate the ferrite through the control of the hot rolling process.
- the deformed fiber structure creates conditions, and then realizes the production process of canceling the normalization process; and, while designing the content of C, Si, and Mn, with the control of elements such as S and P, the precipitation of fine MnS in the hot rolling process is reduced. Probability, and control of Nb, V, Ti, Mo, Cr, Ni, Cu, N, Sn, to ensure magnetic properties, to achieve low iron loss, high magnetic induction intensity.
- the production method of the high-grade non-oriented silicon steel of this embodiment includes the following steps.
- This step includes the molten iron desulfurization process, the converter smelting process, and the RH refining process. Specifically, molten iron desulfurization, converter smelting, and RH refining are used in sequence to smelt steel according to the aforementioned chemical components, that is, the final result of this step is obtained.
- KR desulfurization technology can be used to desulfurize the molten iron, and the temperature of the molten iron after desulfurization is controlled to be greater than or equal to 1320° C. and the content of S is less than or equal to 0.0015% in mass percentage, that is, the desulfurization of the molten iron is carried out. process, so that the S content in the molten iron is less than or equal to 0.0015% by mass percentage; the slag removal rate of the molten iron after desulfurization is controlled to be greater than or equal to 98%.
- the tapping in the aforementioned molten iron desulfurization process (that is, the molten iron after desulfurization) is moved into the converter, and the scrap is mixed in the converter, and the molten iron mixed with the scrap after the desulfurization is carried out in the converter together.
- scrap steel can be clean scrap steel, and the mass ratio of scrap steel to the total molten steel is 20-25% (that is, the amount of scrap steel added accounts for 20-25% of the sum of scrap steel and molten iron); Lime is added to the molten steel, and then a sufficient amount of tin ingots are added to the molten steel according to the Sn: 0.015-0.035% in the finished product; after tapping, a slag surface deoxidizer is added to the molten steel.
- the decarburization treatment mode is adopted, and the treatment is performed in the order of pre-evacuation, decarburization, alloying, net circulation, and vacuum breaking;
- This step is also the continuous casting process.
- the tapping of the RH refining process is prepared by continuous casting equipment into a continuous casting billet with a thickness of more than 200 mm, preferably a thickness of 200 mm to 230 mm.
- the specific operation of this continuous casting process adopts All the existing feasible continuous casting technologies can be realized, and will not be repeated here.
- This step is also the hot rolling process, in which the continuous casting slab obtained in step 2 is sequentially heated, multi-pass rough rolling, multi-pass finishing rolling, cooling and coiling to prepare a hot-rolled coil.
- the continuous casting billet obtained in step 2 is first heated to 1120-1150° C. and kept for more than 200 minutes, and then an intermediate billet with a thickness of 40-45 mm is obtained through multiple passes of rough rolling, and then passes through multiple passes of finishing rolling, cooling and coiling. Take it to obtain a hot-rolled coil with a thickness of 2.50 ⁇ 0.1 mm.
- the finishing temperature of finishing rolling is (A r1 -40) ⁇ 15°C
- a r1 represents the temperature of austenite to ferrite transformation
- the reduction amount of the last finishing rolling is ⁇ 30% and the last two passes
- the total reduction of finishing rolling is ⁇ 50%
- the coiling temperature is 650 ⁇ 20°C.
- the production efficiency is guaranteed and the high temperature final rolling of the subsequent finishing rolling is beneficial.
- it reduces the probability of precipitation of fine MnS, and prevents the solid solution of MnS and other precipitates in the steel during the heating process; and, based on the design of elements such as Mn, C, Si and other elements in the aforementioned chemical composition, compared with the existing technology, the In the austenite region, the temperature A r1 of the transformation from austenite to ferrite is reduced, and A r1 can be maintained basically constant.
- the finishing rolling temperature of finishing rolling is controlled in the two-phase region or
- the high-temperature ferrite region is to facilitate the formation of high-temperature ferrite and avoid the formation of the deformed fiber structure described in the background art.
- the high-temperature ferrite constitutes the basic condition for subsequent recrystallization;
- the large reduction makes the high-temperature ferrite formed during final rolling have more internal storage energy, which is conducive to the recrystallization of high-temperature ferrite and the elimination of fiber structure; at the same time, by controlling the low coiling temperature and the final
- the large reduction of two passes can also avoid the formation of dense oxide scale, so as not to increase the difficulty of removing oxide scale in subsequent pickling.
- the purpose of normalizing treatment is not required before the subsequent cold rolling, and the hot-rolled coil without fibrous structure and difficult pickling can be obtained, so as to obtain a hot-rolled coil with good magnetic properties, High grade non-oriented silicon steel with no corrugated defects on the surface.
- the heating temperature of the continuous casting billet may preferably be 1130-1150°C, that is, the continuous casting billet obtained in step 2 is first heated to 1130-1150°C and kept for more than 200 minutes.
- the temperature Ar1 of austenite to ferrite transformation is basically maintained at about 930°C, for example: in an optional embodiment, The temperature A r1 of austenite to ferrite transformation is 933°C, that is, the finishing rolling temperature of finish rolling is 893 ⁇ 15°C; in another alternative embodiment, the temperature of austenite to ferrite transformation is The temperature A r1 was 930°C, that is, the finishing temperature of the finish rolling was 890 ⁇ 15°C.
- finishing temperature of finishing rolling is controlled in the two-phase region or the high-temperature ferrite region, so as to facilitate the formation of high-temperature ferrite and the formation of large grains.
- the steel sheet obtained by finish rolling is subjected to two-stage cooling, the first-stage cooling is natural slow cooling without water cooling and lasts for 3-8 s, and the second-stage cooling is water-cooling rapid cooling. cool down. Specifically, between finishing rolling and coiling, the steel plate that has just left the finishing rolling mill is not cooled by water but cooled naturally for about 3 to 8s, and then the water cooling is turned on to rapidly cool the steel plate to a coiling temperature of 650 ⁇ 20°C.
- the steel plate is conveyed backwards without turning on water cooling on the roller table of about 30-80m near the finishing mill, and the remaining 70 meters near the coiler
- a large amount of cooling water is used for rapid cooling on the ⁇ 20m roller table.
- the steel sheet obtained by final rolling can be maintained at a high temperature for at least 3-8 s to ensure the full occurrence of recrystallization, and then rapidly cooled to the coiling temperature to reduce or avoid the formation of dense oxide scale, thereby avoiding subsequent pickling. It is more difficult to remove the oxide skin.
- This step is also the continuous casting process, in which the hot-rolled coil obtained in step 3 is not subjected to normalization treatment, but is sequentially subjected to uncoiling, pickling, rinsing, drying, cold rolling and coiling to obtain a thickness of 0.500 ⁇ Chilled rolls of 0.005mm or 0.350 ⁇ 0.004mm. That is, the present embodiment can be used to prepare 0.50 mm high-grade non-oriented silicon steel, and can also be used to prepare 0.35 mm high-grade non-oriented silicon steel.
- step 3 After the hot-rolled coil obtained in step 3 is uncoiled, pickled with HCl, rinsed and dried, cold rolled and coiled to obtain chilled coils.
- the tertiary pickling is carried out with HCl.
- the concentration of the first-stage acid solution is 50-80g/L and the Fe 2+ concentration in the acid solution is ⁇ 130g/L
- the concentration of the second-stage acid solution is 90-120g/L and the Fe 2+ concentration in the acid solution is ⁇ 90g/L L
- the concentration of the third-stage acid solution is 140-160g/L and the Fe 2+ concentration in the acid solution is ⁇ 50g/L
- the acid solution temperature is 75-85°C
- the acid solution contains silicon steel to promote pickling
- the weight percentage of the silicon steel pickling accelerator in the acid solution is 0.05-0.10%
- the temperature of the rinsing water is 45-55°C
- the pickling and rinsing speeds are controlled at 100-180 mpm.
- This step includes the annealing process, the cooling process, the coating process, and the finishing process.
- the chilled coil obtained in step 4 is subjected to finished annealing in a continuous annealing furnace in a mixed atmosphere of H 2 +N 2 , wherein the finished annealing temperature is 920-980° C., and the annealing time is 60 ⁇ 5s; the annealed steel
- the strip is cooled, coated and finished to obtain high-grade non-oriented silicon steel finished products.
- three-stage cooling is used to cool the finished annealed steel strip, wherein: the first stage of cooling is slow cooling in the high-temperature section, and the steel strip is cooled from the annealing temperature at a cooling rate of ⁇ 5 °C/s to be cooled to 850°C; the second stage of cooling is controlled cooling by circulating gas injection, and the steel strip continues to cool from 850°C to below 350°C at a cooling rate of ⁇ 15°C/s; the third stage of cooling is circulating water jet cooling, The steel strip continues to cool from 350°C to below 100°C.
- Coating and finishing the steel plate cooled to below 100°C during annealing The specific operation can be achieved by using the existing feasible coating and finishing technology. No further details are given.
- the final thickness is 0.500 ⁇ 0.005mm or 0.350mm. ⁇ 0.004mm non-oriented silicon steel finished product.
- the thickness of the non-oriented silicon steel product when the thickness of the non-oriented silicon steel product is 0.500 ⁇ 0.005mm, its iron loss P 1.5/50 ⁇ 3.8W/kg, and the magnetic induction intensity B 5000 ⁇ 1.71; the thickness of the non-oriented silicon steel product is When the thickness is 0.350 ⁇ 0.004mm, the iron loss P 1.5/50 ⁇ 3.3W/kg, and the magnetic induction intensity B 5000 ⁇ 1.70. Both specifications of non-oriented silicon steel meet the standard requirements of high-grade non-oriented silicon steel.
- the non-oriented silicon steel finished product prepared by the production method has excellent magnetic properties, low iron loss and high magnetic induction intensity, and is suitable for the needs of high-grade non-oriented silicon steel with two specifications of 0.50mm and 0.35mm, and There is no need for normalization treatment before cold rolling, one process is reduced, and the production cost is low, which can meet the needs of low-cost and high-grade silicon steel sheets for electrical steel product upgrades and electrical product energy efficiency upgrades;
- the finishing rolling temperature of finishing rolling is controlled in the two-phase region.
- high-temperature ferrite region in order to form high-temperature ferrite and avoid the formation of deformed fiber structure described in the background art, high-temperature ferrite constitutes the basic condition for subsequent recrystallization; further, combined with the last two passes of finishing rolling
- the high-temperature ferrite formed during final rolling has more internal storage energy, which is conducive to the recrystallization of high-temperature ferrite and the elimination of fiber structure; at the same time, by controlling the low coiling temperature and the finishing rolling
- the large reduction in the last two passes can also avoid the formation of dense oxide scale, so as not to increase the difficulty of removing scale in the subsequent pickling.
- Examples 1 to 4 are in accordance with the aforementioned one embodiment of the present invention, and successively adopt molten iron desulfurization, converter smelting, and RH refining.
- the tapping in step 1 was prepared into a continuous casting slab with a thickness of 220 mm by using continuous casting equipment.
- the continuous casting slab obtained in step 2 is successively subjected to heating, multi-pass rough rolling, multi-pass finishing rolling, cooling and coiling to prepare a hot-rolled coil.
- the reduction amount of the last finishing rolling is ⁇ 30% and the total reduction amount of the last two finishing rollings is ⁇ 50%; Cooling, the first stage cooling is natural slow cooling without water cooling and lasts 3 to 8s, and the second stage cooling is water cooling rapid cooling; in addition, the heating temperature and holding time of the continuous casting slab before rough rolling, and the intermediate obtained after multiple passes of rough rolling.
- the thickness of the billet, the finishing temperature of finishing rolling, the coiling temperature and the thickness of the hot-rolled coil are shown in Table 2, respectively.
- Example 1 The microscopic metallographic structure of the hot-rolled coils obtained in Examples 1 to 4 was detected.
- Figure 1 and Figure 2 selected the microscopic metallographic structure photos of Example 1 and Example 3 respectively for illustration. After testing, it was found that, In Examples 1 to 4, the formation of high-temperature ferrite after finishing rolling can further obtain a recrystallized structure without forming a deformed fiber structure, which creates a premise that normalization treatment is not required before subsequent cold rolling.
- the hot-rolled coil obtained in step 3 was not subjected to normalization treatment, but was sequentially subjected to uncoiling, pickling, rinsing, drying, cold rolling and coiling to obtain thicknesses of 0.503mm, 0.350mm, Chilled rolls of 0.501mm and 0.349mm. Moreover, the hot-rolled coils in Examples 1 to 4 had little difficulty in removing scale during pickling, and had an ideal removal effect, and there was no abnormal situation in which the scale was dense and could not be effectively removed.
- the chilled coil obtained in step 4 was annealed in a continuous annealing furnace in a mixed atmosphere of H 2 +N 2 ; the annealed steel strip was cooled, coated and finished to obtain a finished product of non-oriented silicon steel.
- the finished annealing temperature and annealing time are shown in Table 3, respectively.
- the non-oriented silicon steel products obtained in Examples 1 to 4 have no corrugated defects on the surface, and they are respectively sampled and tested, and the measured magnetic properties are shown in Table 4.
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Abstract
Description
退火温度(℃) | 退火时间(s) | |
实施例1 | 935 | 61 |
实施例2 | 945 | 63 |
实施例3 | 935 | 60 |
实施例4 | 945 | 62 |
Claims (10)
- 一种高牌号无取向硅钢的生产方法,其特征在于,包括以下步骤,1)依次采用铁水脱硫、转炉冶炼、RH精炼进行冶钢,最终所得钢水化学成分以质量百分比计为:C:0.002~0.004%,S≤0.003%,Si:1.4~1.7%,Mn:0.7~0.95%,P≤0.03%,Sn:0.015~0.035%,Nb≤0.004%,V≤0.004%,Ti≤0.005%,Mo≤0.004%,Cr≤0.03%,Ni≤0.03%,Cu≤0.03%,N≤0.003%,余量为Fe及不可避免的夹杂,且11×([Si]-1.4%)=14×([Mn]-0.7%);2)将步骤1所得钢水连铸成厚度200mm以上的连铸坯;3)将步骤2所得连铸坯加热到1120~1150℃并保温200min以上,而后经过多道次粗轧得到厚度为40~45mm的中间坯,再经过多道次精轧、冷却、卷取得到厚度为2.50±0.1mm的热轧卷板,其中精轧的终轧温度为890±15℃,最后一道次精轧的压下量≥30%且最后两道次精轧的总压下量≥50%,卷取温度为650±20℃;4)将步骤3所得热轧卷板不进行常化处理而依次进行开卷、酸洗、漂洗、烘干、冷轧和卷取,得到厚度为0.500±0.005mm或0.350±0.004mm的冷硬卷;5)将步骤4所得冷硬卷采用连续退火炉在H 2+N 2的混合气氛中进行成品退火,其中,成品退火温度为920~980℃,退火时间为60±5s;退火后的钢带经冷却、涂层和精整得到无取向硅钢成品。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,所得无取向硅钢成品的厚度为0.500±0.005mm,其铁损P 1.5/50≤3.8W/kg,磁感应强度B 5000≥1.71;或,所得无取向硅钢成品的厚度为0.350±0.004mm,其铁损P 1.5/50≤3.3W/kg,磁感应强度B 5000≥1.70。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,在步骤3中,将步骤2所得连铸坯加热到1130~1150℃并保温200min以上。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,在步骤3中,所述冷却工序:将精轧的终轧所得钢板进行两阶段冷却,前段冷却为不采用水冷的自然缓慢冷却且持续3~8s,后段冷却为水冷急速冷却。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,在所述铁水脱硫工序中:控制脱硫后铁水的温度≥1320℃且以质量百分比计所含S≤0.0015%,扒渣率≥98%;在所述转炉冶炼工序中:将脱硫后铁水混合废钢在转炉中进行冶炼,其中废钢占总钢水的质量比为20~25%;出钢过程中,按照成品中Sn:0.015~0.035%向钢水中加入足量锡锭;出钢结束后,向钢水中加入渣面脱氧剂;在所述RH精炼工序中:在预抽真空的RH精炼炉中,对钢水进行脱碳处理,之后按照成品中Si:1.4~1.7%、Mn:0.7~0.95%且11×([Si]-1.4%)=14×([Mn]-0.7%)的合金化方案,向钢水中加入超低钛硅铁和金属锰,净循环7分钟以上后出钢,其中在净循环期间向钢水中添加脱硫剂以进行深脱硫处理。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,在酸洗工序中:将步骤3所得热轧卷板开卷之后,采用HCl进行三级酸洗,其中,第一级酸液浓度为50~80g/L且酸液中Fe 2+浓度≤130g/L,第二级酸液浓度为90~120g/L且酸液中Fe 2+浓度≤90g/L,第三级酸液浓度为140~160g/L且酸液中Fe 2+浓度≤50g/L;每一级酸洗时,酸液温度75~85℃,酸液中含硅钢酸洗促进剂,硅钢酸洗促进剂占酸液的重量百分比为0.05~0.10%;漂洗水温度45~55℃,酸洗和漂洗速度控制在100~180mpm。
- 根据权利要求1所述的高牌号无取向硅钢的生产方法,其特征在于,在步骤5中,采用三段式冷却对成品退火后的钢带进行冷却,其中:第一段冷却为高温段缓慢冷却,钢带从退火温度以冷速≤5℃/s进行冷却到850℃;第二段冷却为循环气体喷射控制冷却,钢带以冷速≤15℃/s从850℃继续冷却到350℃以下;第三段冷却为循环水喷射冷却,钢带从350℃继续冷却到100℃以下。
- 一种高牌号无取向硅钢的生产方法,其特征在于,包括以下步骤,1)依次采用铁水脱硫、转炉冶炼、RH精炼进行冶钢,最终所得钢水化学成分以质量百分比计为:C:0.002~0.004%,S≤0.003%,Si:1.4~1.7%,Mn:0.7~0.95%,P≤0.03%,Sn:0.015~0.035%,Nb≤0.004%,V≤0.004%,Ti≤0.005%,Mo≤0.004%,Cr≤0.03%,Ni≤0.03%,Cu≤0.03%,N≤0.003%,余量为Fe及不可避免的夹杂,且11×([Si]-1.4%)=14×([Mn]-0.7%);2)将步骤1所得钢水连铸成厚度200mm以上的连铸坯;3)将步骤2所得连铸坯加热到1120~1150℃并保温200min以上,而后经过多道次粗轧得到厚度为40~45mm的中间坯,再经过多道次精轧、卷取得到厚度为2.50±0.1mm的热轧卷板,其中精轧的终轧温度为(A r1-40)±15℃,A r1表示奥氏体向铁素体转变的温度,最后一道次精轧的压下量≥30%且最后两道次精轧的总压下量 ≥50%,卷取温度为650±20℃,将精轧的终轧所得钢板在卷取之前进行两阶段冷却,前段冷却为不采用水冷的自然缓慢冷却且持续3~8s,后段冷却为水冷急速冷却;4)将步骤3所得热轧卷板不进行常化处理而依次进行开卷、酸洗、漂洗、烘干、冷轧和卷取,得到厚度为0.500±0.005mm或0.350±0.004mm的冷硬卷;5)将步骤4所得冷硬卷采用连续退火炉在H 2+N 2的混合气氛中进行成品退火,其中,成品退火温度为920~980℃,退火时间为60±5s;退火后的钢带经冷却、涂层和精整得到无取向硅钢成品。
- 一种高牌号无取向硅钢,其特征在于,其采用权利要求1所述的生产方法制备而成。
- 根据权利要求9所述的高牌号无取向硅钢,其特征在于,所得无取向硅钢成品的厚度为0.500±0.005mm,其铁损P 1.5/50≤3.8W/kg,磁感应强度B 5000≥1.71;或,所得无取向硅钢成品的厚度为0.350±0.004mm,其铁损P 1.5/50≤3.3W/kg,磁感应强度B 5000≥1.70。
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