WO2022123387A1 - 表示装置および電子機器 - Google Patents

表示装置および電子機器 Download PDF

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Publication number
WO2022123387A1
WO2022123387A1 PCT/IB2021/061035 IB2021061035W WO2022123387A1 WO 2022123387 A1 WO2022123387 A1 WO 2022123387A1 IB 2021061035 W IB2021061035 W IB 2021061035W WO 2022123387 A1 WO2022123387 A1 WO 2022123387A1
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WIPO (PCT)
Prior art keywords
layer
transistor
display device
semiconductor
oxide
Prior art date
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Ceased
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PCT/IB2021/061035
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English (en)
French (fr)
Japanese (ja)
Inventor
山崎舜平
池田隆之
木村肇
大貫達也
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Semiconductor Energy Laboratory Co Ltd
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Semiconductor Energy Laboratory Co Ltd
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Filing date
Publication date
Application filed by Semiconductor Energy Laboratory Co Ltd filed Critical Semiconductor Energy Laboratory Co Ltd
Priority to US18/265,539 priority Critical patent/US20240029636A1/en
Priority to JP2022567715A priority patent/JPWO2022123387A1/ja
Publication of WO2022123387A1 publication Critical patent/WO2022123387A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
    • G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
    • G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
    • G09G3/30—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels
    • G09G3/32—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED]
    • G09G3/3208—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED]
    • G09G3/3225—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED] using an active matrix
    • G09G3/3233—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED] using an active matrix with pixel circuitry controlling the current through the light-emitting element
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
    • G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
    • G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
    • G09G3/30—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels
    • G09G3/32—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED]
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/02—Details
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00—Field-effect transistors [FET]
    • H10D30/60—Insulated-gate field-effect transistors [IGFET]
    • H10D30/67—Thin-film transistors [TFT]
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10—OLED displays
    • H10K59/12—Active-matrix OLED [AMOLED] displays
    • H10K59/121—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
    • H10K59/1213—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements the pixel elements being TFTs
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2300/00—Aspects of the constitution of display devices
    • G09G2300/04—Structural and physical details of display devices
    • G09G2300/0404—Matrix technologies
    • G09G2300/0417—Special arrangements specific to the use of low carrier mobility technology
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2300/00—Aspects of the constitution of display devices
    • G09G2300/04—Structural and physical details of display devices
    • G09G2300/0439—Pixel structures
    • G09G2300/0452—Details of colour pixel setup, e.g. pixel composed of a red, a blue and two green components
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2300/00—Aspects of the constitution of display devices
    • G09G2300/04—Structural and physical details of display devices
    • G09G2300/0439—Pixel structures
    • G09G2300/0465—Improved aperture ratio, e.g. by size reduction of the pixel circuit, e.g. for improving the pixel density or the maximum displayable luminance or brightness
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2300/00—Aspects of the constitution of display devices
    • G09G2300/08—Active matrix structure, i.e. with use of active elements, inclusive of non-linear two terminal elements, in the pixels together with light emitting or modulating elements
    • G09G2300/0809—Several active elements per pixel in active matrix panels
    • G09G2300/0842—Several active elements per pixel in active matrix panels forming a memory circuit, e.g. a dynamic memory with one capacitor
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2320/00—Control of display operating conditions
    • G09G2320/06—Adjustment of display parameters
    • G09G2320/0666—Adjustment of display parameters for control of colour parameters, e.g. colour temperature
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/19—Tandem OLEDs
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30—Devices specially adapted for multicolour light emission
    • H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
    • H10K59/351—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels comprising more than three subpixels, e.g. red-green-blue-white [RGBW]

Definitions

  • One aspect of the present invention relates to a display device.
  • the uniformity of the present invention relates to a method for manufacturing a display device.
  • one aspect of the present invention is not limited to the above technical fields.
  • the technical fields of one aspect of the present invention disclosed in the present specification and the like include semiconductor devices, display devices, light emitting devices, power storage devices, storage devices, electronic devices, lighting devices, input devices, input / output devices, and driving methods thereof. , Or their manufacturing methods, can be mentioned as an example.
  • Devices that require a high-definition display device include, for example, virtual reality (VR: Virtual Reality), augmented reality (AR: Augmented Reality), alternative reality (SR: Substitutional Reality), or mixed reality (MR: Mixed Reality).
  • VR Virtual Reality
  • AR Augmented Reality
  • SR Substitutional Reality
  • MR Mixed Reality
  • Display devices used in these devices are required to be miniaturized in addition to high definition.
  • a display device a liquid crystal display device, an organic EL (Electroluminescence) element, a light emitting device equipped with a light emitting element such as a light emitting diode (LED: Light Emitting Diode), an electron that displays by an electrophoresis method or the like is typically used. Examples include paper.
  • the basic configuration of an organic EL device is such that a layer containing a luminescent organic compound is sandwiched between a pair of electrodes. By applying a voltage to this device, light emission can be obtained from a luminescent organic compound. Since the display device to which such an organic EL element is applied does not require a backlight, which is required for a liquid crystal display device or the like, a thin, lightweight, high-contrast, and low-power consumption display device can be realized. For example, an example of a display device using an organic EL element is described in Patent Document 1.
  • a display device includes a display unit including a plurality of pixels and a peripheral drive circuit unit for supplying a video signal to a display area. Further, the drive circuit unit is provided on the outer peripheral portion of the display area.
  • One aspect of the present invention is to provide a display device having high emission brightness.
  • One aspect of the present invention is to provide a miniaturized display device.
  • One aspect of the present invention is to provide a display device having high color reproducibility.
  • One aspect of the present invention is to provide a high-definition display device.
  • One aspect of the present invention is to provide a highly reliable display device.
  • One aspect of the present invention is to provide a novel display device.
  • One aspect of the present invention is a display device having a display unit and a peripheral circuit unit that drives the display unit.
  • the display unit and the peripheral circuit unit have regions that overlap each other, and the display units are arranged in a matrix.
  • the peripheral circuit portion has a first transistor, the pixel has a second transistor, the composition of the first semiconductor layer included in the first transistor, and the second semiconductor layer included in the second transistor. It is a display device having a different composition.
  • the peripheral circuit unit includes, for example, a scanning line drive circuit and a signal line drive circuit.
  • Each of the plurality of pixels has a function of emitting light, and it is preferable that the light is emitted in a direction in which a peripheral circuit portion is not formed.
  • the pixel may have, for example, an EL element.
  • the first semiconductor layer may be a single crystal semiconductor or a polycrystalline semiconductor.
  • the second semiconductor layer may be an oxide semiconductor.
  • the first semiconductor layer may be formed of single crystal silicon and the second semiconductor layer may be formed of an oxide containing at least one of indium or zinc.
  • a display device having high emission brightness it is possible to provide a display device having high emission brightness.
  • a miniaturized display device can be provided.
  • a high-definition display device can be provided.
  • a highly reliable display device it is possible to provide a method of manufacturing the display device described above.
  • 1A to 1C are views for explaining a configuration example of a display device.
  • 2A and 2B1 to 2B5 are diagrams illustrating a configuration example of the display device.
  • 3A to 3C are diagrams for explaining a configuration example of a pixel circuit.
  • FIG. 4 is a diagram illustrating a configuration example of the display device.
  • 5A to 5F are diagrams illustrating an example of a method for manufacturing a display device.
  • 6A to 6G are diagrams illustrating an example of a method for manufacturing a display device.
  • 7A and 7B are diagrams illustrating an example of a method for manufacturing a display device.
  • 8A and 8B are diagrams illustrating an example of a method for manufacturing a display device.
  • FIGS. 9A to 9C are diagrams illustrating an example of a method for manufacturing a display device.
  • FIG. 10A is a diagram illustrating the classification of crystal structures.
  • FIG. 10B is a diagram illustrating an XRD spectrum of a CAAC-IGZO film.
  • FIG. 10C is a diagram illustrating a micro electron beam diffraction pattern of the CAAC-IGZO film.
  • 11A and 11B are diagrams illustrating a configuration example of the display module.
  • 12A and 12B are diagrams illustrating a configuration example of the display module.
  • 13A and 13B are layout diagrams of a display device made of a 12-inch wafer.
  • 14A to 14C are views for explaining a configuration example of the light emitting element.
  • 15A and 15B are diagrams illustrating a configuration example of an electronic device.
  • 16A to 16D are diagrams for explaining a configuration example of an electronic device.
  • the semiconductor device is a device utilizing semiconductor characteristics, and refers to a circuit including a semiconductor element (transistor, diode, photodiode, etc.), a device having the same circuit, and the like. It also refers to all devices that can function by utilizing semiconductor characteristics.
  • a semiconductor element transistor, diode, photodiode, etc.
  • the storage device, the display device, the light emitting device, the lighting device, the electronic device, and the like are themselves semiconductor devices, and may have a semiconductor device.
  • an element for example, a switch, a transistor, a capacitive element, an inductor, a resistance element, a diode, a display
  • One or more devices, light emitting devices, loads, etc. can be connected between X and Y.
  • the switch is controlled in an on state and an off state. That is, the switch is in a conducting state (on state) or a non-conducting state (off state), and has a function of controlling whether or not a current flows.
  • a circuit that enables functional connection between X and Y for example, a logic circuit (inverter, NAND circuit, NOR circuit, etc.), signal conversion) Circuits (digital-analog conversion circuit, analog-to-digital conversion circuit, gamma correction circuit, etc.), potential level conversion circuit (power supply circuit (boost circuit, step-down circuit, etc.), level shifter circuit that changes the signal potential level, etc.), voltage source, current source , Switching circuit, amplifier circuit (circuit that can increase signal amplitude or current amount, operational amplifier, differential amplifier circuit, source follower circuit, buffer circuit, etc.), signal generation circuit, storage circuit, control circuit, etc.), X and Y It is possible to connect one or more to and from. As an example, even if another circuit is sandwiched between X and Y, if the signal output from X is transmitted to Y, it is assumed that X and Y are functionally connected. do.
  • X and Y are electrically connected, it means that X and Y are electrically connected (that is, another element between X and Y). Or when they are connected with another circuit in between) and when X and Y are directly connected (that is, they are connected without sandwiching another element or another circuit between X and Y). If there is) and.
  • X and Y, the source (or the first terminal, etc.) and the drain (or the second terminal, etc.) of the transistor are electrically connected to each other, and the X, the source (or the second terminal, etc.) of the transistor are connected to each other. (1 terminal, etc.), the drain of the transistor (or the 2nd terminal, etc.), and Y are electrically connected in this order.
  • the source of the transistor (or the first terminal, etc.) is electrically connected to X
  • the drain of the transistor (or the second terminal, etc.) is electrically connected to Y
  • the X, the source of the transistor (such as the second terminal).
  • first terminal, etc.), the drain of the transistor (or the second terminal, etc.), and Y are electrically connected in this order.
  • X is electrically connected to Y via the source (or first terminal, etc.) and drain (or second terminal, etc.) of the transistor, and X, the source (or first terminal, etc.) of the transistor.
  • the terminals, etc.), the drain of the transistor (or the second terminal, etc.), and Y are provided in this connection order.
  • the source (or first terminal, etc.) and drain (or second terminal, etc.) of the transistor can be separated. Separately, the technical scope can be determined. It should be noted that these expression methods are examples, and are not limited to these expression methods.
  • X and Y are objects (for example, devices, elements, circuits, wirings, electrodes, terminals, conductive films, layers, etc.).
  • the circuit diagram shows that the independent components are electrically connected to each other, the case where one component has the functions of a plurality of components together.
  • one component has the functions of a plurality of components together.
  • one conductive film has both the function of the wiring and the function of the components of the function of the electrode. Therefore, the electrical connection in the present specification also includes the case where one conductive film has the functions of a plurality of components in combination.
  • the “capacitance element” means, for example, a circuit element having a capacitance value higher than 0F, a wiring region having a capacitance value higher than 0F, a parasitic capacitance, and a transistor. It can be the gate capacitance of. Therefore, in the present specification and the like, the “capacitive element” is not only a circuit element containing a pair of electrodes and a dielectric contained between the electrodes, but also a parasitic element generated between the wirings. It shall include the capacitance, the gate capacitance generated between the gate and one of the source or drain of the transistor, and the like.
  • capacitor element means “capacitive element”, “parasitic capacitance”, and “capacity”. It can be paraphrased into terms such as “gate capacitance”.
  • the term “pair of electrodes” of “capacity” can be paraphrased as "a pair of conductors", “a pair of conductive regions", “a pair of regions” and the like.
  • the value of the capacitance can be, for example, 0.05 fF or more and 10 pF or less. Further, for example, it may be 1 pF or more and 10 ⁇ F or less.
  • the transistor has three terminals called a gate, a source, and a drain.
  • the gate is a control terminal that controls the conduction state of the transistor.
  • the two terminals that act as sources or drains are the input and output terminals of the transistor.
  • One of the two input / output terminals becomes a source and the other becomes a drain depending on the potential applied to the conductive type (n-channel type, p-channel type) of the transistor and the three terminals of the transistor. Therefore, in the present specification and the like, the terms source and drain can be paraphrased.
  • the transistor when explaining the connection relationship of transistors, "one of the source or drain” (or the first electrode or the first terminal), “the other of the source or drain” (or the second electrode, or the second electrode, or The notation (second terminal) is used.
  • it may have a back gate in addition to the above-mentioned three terminals.
  • one of the gate or the back gate of the transistor may be referred to as a first gate
  • the other of the gate or the back gate of the transistor may be referred to as a second gate.
  • the terms “gate” and “backgate” may be interchangeable.
  • the respective gates When the transistor has three or more gates, the respective gates may be referred to as a first gate, a second gate, a third gate, and the like in the present specification and the like.
  • the "node” can be paraphrased as a terminal, a wiring, an electrode, a conductive layer, a conductor, an impurity region, etc., depending on the circuit configuration, device structure, and the like.
  • terminals, wiring, etc. can be paraphrased as "nodes”.
  • the ordinal numbers “first”, “second”, and “third” are added to avoid confusion of the constituent elements. Therefore, the number of components is not limited. Moreover, the order of the components is not limited. For example, the component referred to in “first” in one of the embodiments of the present specification and the like is assumed to be the component referred to in “second” in another embodiment or in the scope of claims. It is possible. Further, for example, the component referred to in “first” in one of the embodiments of the present specification and the like may be omitted in other embodiments, claims, and the like.
  • the terms indicating the arrangement such as “above”, “below”, “above”, or “below” explain the positional relationship between the components with reference to the drawings. In order to do so, it may be used for convenience. Further, the positional relationship between the constituent elements changes appropriately depending on the direction in which each configuration is depicted. Therefore, it is not limited to the words and phrases explained in the specification and the like, and can be appropriately paraphrased according to the situation. For example, in the expression of "insulator located on the upper surface of the conductor”, it can be paraphrased as "insulator located on the lower surface of the conductor” by rotating the direction of the drawing shown by 180 degrees.
  • the terms “upper” and “lower” do not limit the positional relationship of the components to be directly above or directly below and to be in direct contact with each other.
  • the electrode B does not have to be formed in direct contact with the insulating layer A, and another configuration is formed between the insulating layer A and the electrode B. Do not exclude those that contain elements.
  • membrane and layer can be interchanged with each other depending on the situation.
  • the terms “insulating layer” and “insulating film” may be changed to the term "insulator”.
  • Electrode may be used as part of a “wiring” and vice versa.
  • the term “electrode” or “wiring” also includes the case where a plurality of “electrodes” or “wiring” are integrally formed.
  • a “terminal” may be used as part of a “wiring” or “electrode” and vice versa.
  • the term “terminal” includes a case where a plurality of "electrodes", “wiring”, “terminals” and the like are integrally formed.
  • the "electrode” can be part of the “wiring” or “terminal”, and for example, the “terminal” can be part of the “wiring” or “electrode”.
  • terms such as “electrode”, “wiring”, and “terminal” may be replaced with terms such as "area” in some cases.
  • terms such as “wiring”, “signal line”, and “power line” can be interchanged with each other in some cases or depending on the situation.
  • the reverse is also true, and it may be possible to change terms such as “signal line” and “power line” to the term “wiring”.
  • a term such as “power line” may be changed to a term such as "signal line”.
  • a term such as “signal line” may be changed to a term such as “power line”.
  • the term “potential” applied to the wiring may be changed to a term such as “signal” in some cases or depending on the situation.
  • the reverse is also true, and terms such as “signal” may be changed to the term “potential”.
  • parallel means a state in which two straight lines are arranged at an angle of ⁇ 10 ° or more and 10 ° or less. Therefore, the case of ⁇ 5 ° or more and 5 ° or less is also included.
  • substantially parallel or approximately parallel means a state in which two straight lines are arranged at an angle of -30 ° or more and 30 ° or less.
  • vertical means a state in which two straight lines are arranged at an angle of 80 ° or more and 100 ° or less. Therefore, the case of 85 ° or more and 95 ° or less is also included.
  • substantially vertical or “approximately vertical” means a state in which two straight lines are arranged at an angle of 60 ° or more and 120 ° or less.
  • the size, layer thickness, or area may be exaggerated for clarity. Therefore, it is not necessarily limited to its size or aspect ratio.
  • the drawings schematically show ideal examples, and are not limited to the shapes or values shown in the drawings. For example, it is possible to include variations in the signal, voltage, or current due to noise, or variations in the signal, voltage, or current due to timing deviation.
  • FIG. 1A is a perspective view of a display device 100 according to an aspect of the present invention.
  • FIG. 1B is a top view of the display device 100.
  • FIG. 1C is a cross-sectional view of a portion shown by a dotted chain line of A1-A2 in FIG. 1B.
  • the display device 100 has a drive circuit 102, which is a kind of semiconductor device, on the substrate 101, and has a display unit 104 on the drive circuit 102.
  • the drive circuit 102 and the display unit 104 have regions that overlap each other.
  • a wiring group 103 is provided between the drive circuit 102 and the display unit 104.
  • the drive circuit 102 and the display unit 104 are electrically connected to each other via the wiring group 103.
  • the drive circuit 102 is electrically connected to the input / output terminal portion 106.
  • the display device 100 has a substrate 105 on the display unit 104.
  • arrows indicating the X direction, the Y direction, and the Z direction may be added.
  • the "X direction” is a direction along the X axis, and the forward direction and the reverse direction are not distinguished unless otherwise specified. The same applies to the "Y direction” and the "Z direction”.
  • the X direction, the Y direction, and the Z direction are directions in which they intersect with each other. More specifically, the X, Y, and Z directions are directions orthogonal to each other. In the present specification and the like, one of the X direction, the Y direction, or the Z direction may be referred to as a "first direction” or a "first direction”.
  • the other one may be referred to as a "second direction” or a "second direction”. Further, the remaining one may be referred to as a "third direction” or a “third direction”. In FIG. 1 and the like, the direction perpendicular to the surface of the substrate 101 is the Z direction.
  • FIG. 2A is a block diagram illustrating a connection relationship between the drive circuit 102 and the display unit 104.
  • the drive circuit 102 includes a first drive circuit 232 and a second drive circuit 233.
  • the drive circuit 102 is electrically connected to the input / output terminal portion 106.
  • the circuit included in the first drive circuit 232 functions as, for example, a scanning line drive circuit.
  • the circuit included in the first drive circuit 232 functions as, for example, a signal line drive circuit. It should be noted that some kind of circuit may be provided at a position facing the first drive circuit 232 with the display unit 104 in between. Some kind of circuit may be provided at a position facing the second drive circuit 233 across the display unit 104.
  • the drive circuit 102 may be referred to as a "peripheral drive circuit".
  • peripheral drive circuit various circuits such as a shift register, a level shifter, an inverter, a latch, an analog switch, and a logic circuit can be used.
  • Transistors, capacitive elements and the like can be used in the peripheral drive circuit.
  • the display device 100 includes m wires (m is an integer of 1 or more), each of which is arranged substantially in parallel and whose potential is controlled by the circuit included in the first drive circuit 232. It has n wires (n is an integer of 1 or more) 237 which are arranged substantially in parallel and whose potential is controlled by a circuit included in the second drive circuit 233.
  • the wiring 236 is electrically connected to the first drive circuit 232 via a part of the wiring group 103.
  • the wiring 237 is electrically connected to the second drive circuit 233 via a part of the wiring group 103.
  • the display unit 104 has a plurality of pixels 230 arranged in a matrix. Pixels 230 that control red light, pixels 230 that control green light, and pixels 230 that control blue light are collectively functioned as one pixel 240, and the amount of light emitted (emission brightness) of each pixel 230 is controlled. Therefore, full-color display can be realized. Therefore, each of the three pixels 230 functions as a sub-pixel. That is, each of the three sub-pixels controls the amount of light emitted from red light, green light, or blue light (see FIG. 2B1).
  • the color of light controlled by each of the three sub-pixels is not limited to the combination of red (R), green (G), and blue (B), but is cyan (C), magenta (M), and yellow (Y). It may be present (see FIG. 2B2).
  • the four sub-pixels may be collectively functioned as one pixel.
  • a sub-pixel that controls white light W
  • W white light
  • the brightness of the display area can be increased.
  • a sub-pixel for controlling yellow light may be added to the three sub-pixels for controlling red light, green light, and blue light (see FIG. 2B4).
  • a sub-pixel for controlling white light may be added to the three sub-pixels for controlling cyan light, magenta light, and yellow light (see FIG. 2B5).
  • the display device can reproduce color gamuts of various standards.
  • PAL Phase Alternate Line
  • NTSC National Television System Committee
  • sRGB standard RGB
  • ITU-R BT Standards
  • Adobe RGB Standards
  • HDTV High Definition Television
  • 709 International Television Union Radiocommunication Vector Broadcasting Service (Television) 709) standard
  • DCI-P3 Digital Cinema Projection
  • DCI-P3 Digital Cinema Projection
  • High-definition TV used in Ultra-High-Definition TV R BT. It is possible to reproduce a color gamut such as the 2020 (REC. 2020 (Recommendation 2020)) standard.
  • a display device 100 capable of full-color display at a so-called full high-definition also referred to as “2K resolution”, “2K1K”, “2K”, etc.
  • full high-definition also referred to as “2K resolution”, “2K1K”, “2K”, etc.
  • a display device 100 capable of full-color display at a so-called ultra-high definition also referred to as “4K resolution”, “4K2K”, “4K”, etc.
  • the display device 100 capable of full-color display at the resolution of so-called super high definition (also referred to as “8K resolution”, “8K4K”, “8K”, etc.)). Can be realized. By increasing the number of pixels 240, it is possible to realize a display device 100 capable of full-color display at a resolution of 16K or 32K.
  • FIG. 3A is a diagram showing a circuit configuration example of the pixel 230.
  • the pixel 230 has a pixel circuit 431 and a display element 432.
  • Each wiring 236 is electrically connected to n pixel circuits 431 arranged in any of the pixel circuits 431 arranged in m rows and n columns on the display unit 104. Further, each wiring 237 is electrically connected to m pixel circuits 431 arranged in any of the pixel circuits 431 arranged in m rows and n columns.
  • the pixel circuit 431 includes a transistor 436, a capacitive element 433, a transistor 251 and a transistor 434. Further, the pixel circuit 431 is electrically connected to the display element 432.
  • One of the source electrode and the drain electrode of the transistor 436 is electrically connected to a wiring (hereinafter referred to as a signal line DL_n) to which a data signal (also referred to as a “video signal”) is given. Further, the gate electrode of the transistor 436 is electrically connected to a wiring (hereinafter referred to as a scanning line GL_m) to which a gate signal is given.
  • the signal line DL_n and the scanning line GL_m correspond to the wiring 237 and the wiring 236, respectively.
  • the transistor 436 has a function of controlling the writing of the data signal to the node 435.
  • One of the pair of electrodes of the capacitive element 433 is electrically connected to the node 435 and the other is electrically connected to the node 437. Further, the other of the source electrode and the drain electrode of the transistor 436 is electrically connected to the node 435.
  • the capacitance element 433 has a function as a holding capacitance for holding the data written in the node 435.
  • One of the source electrode and the drain electrode of the transistor 251 is electrically connected to the potential supply line VL_a, and the other is electrically connected to the node 437. Further, the gate electrode of the transistor 251 is electrically connected to the node 435.
  • One of the source electrode and the drain electrode of the transistor 434 is electrically connected to the potential supply line V0, and the other is electrically connected to the node 437. Further, the gate electrode of the transistor 434 is electrically connected to the scanning line GL_m.
  • One of the anode or cathode of the display element 432 is electrically connected to the potential supply line VL_b and the other is electrically connected to the node 437.
  • an organic electroluminescence element also referred to as an organic EL element
  • the display element 432 is not limited to this, and for example, an inorganic EL element made of an inorganic material may be used.
  • the "organic EL element” and the “inorganic EL element” may be collectively referred to as an "EL element”.
  • the emission color of the EL element may be white, red, green, blue, cyan, magenta, yellow, or the like, depending on the material constituting the EL element.
  • a method of realizing color display there are a method of combining a display element 432 having a white emission color and a colored layer, and a method of providing a display element 432 having a different emission color for each pixel.
  • the former method is more productive than the latter method.
  • the latter method since it is necessary to make the display element 432 separately for each pixel, the productivity is inferior to that of the former method.
  • the latter method it is possible to obtain an emission color having higher color purity than the former method.
  • the color purity can be further improved by imparting a microcavity structure to the display element 432.
  • Either a low molecular weight compound or a high molecular weight compound can be used for the display element 432, and an inorganic compound may be contained.
  • the layers constituting the display element 432 can be formed by a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like, respectively.
  • the display element 432 may have an inorganic compound such as a quantum dot. For example, by using quantum dots in the light emitting layer, it can be made to function as a light emitting material.
  • the power supply potential for example, a potential on the relatively high potential side or a potential on the low potential side can be used.
  • the power potential on the high potential side is referred to as a high power potential (also referred to as "VDD")
  • the power potential on the low potential side is referred to as a low power potential (also referred to as "VSS").
  • the ground potential can be used as a high power supply potential or a low power supply potential.
  • the high power supply potential is the ground potential
  • the low power supply potential is lower than the ground potential
  • the low power supply potential is the ground potential
  • the high power supply potential is higher than the ground potential.
  • one of the potential supply line VL_a or the potential supply line VL_b is given a high power supply potential VDD, and the other is given a low power supply potential VSS.
  • the pixel circuit 431 of each row is sequentially selected by the circuit included in the first drive circuit 232, the transistor 436 and the transistor 434 are turned on, and the data signal is written to the node 435.
  • the pixel circuit 431 in which data is written to the node 435 is put into a holding state when the transistor 436 and the transistor 434 are turned off. Further, the amount of current flowing between the source electrode and the drain electrode of the transistor 251 is controlled according to the potential of the data written in the node 435, and the display element 432 emits light with brightness corresponding to the amount of flowing current. By doing this sequentially line by line, the image can be displayed.
  • FIG. 3B shows a modified example of the circuit configuration of the pixel 230 shown in FIG. 3A.
  • the circuit configuration shown in FIG. 3B has a configuration in which the transistor 434 and the potential supply line V0 are excluded from the circuit configuration shown in FIG. 3A.
  • Other configurations can be understood by referring to the explanation of the circuit configuration shown in FIG. 3A. Therefore, in order to reduce the repetition of the description, the detailed description of the circuit configuration shown in FIG. 3B will be omitted.
  • a part or all of the transistors constituting the pixel circuit 431 may be composed of a transistor having a back gate.
  • a transistor having a back gate in the transistor 436 may be used to electrically connect the back gate to the gate.
  • one of the back gate and the source or drain of the transistor may be electrically connected.
  • the structure of the transistor included in the display device is not particularly limited.
  • it may be a planar type transistor or a stagger type transistor.
  • a transistor structure having either a top gate structure or a bottom gate structure may be used.
  • gate electrodes may be provided above and below the channel.
  • the transistor included in the peripheral drive circuit and the transistor included in the pixel circuit may have the same structure or different structures.
  • the transistors included in the peripheral drive circuit may all have the same structure, or two or more types of structures may be used in combination.
  • the transistors included in the pixel circuit may all have the same structure, or two or more types of structures may be used in combination.
  • gate electrode When one of the gate electrodes provided above and below the channel is referred to as a "gate electrode”, the other is referred to as a "back gate electrode". Further, when one of the gate electrodes provided above and below the channel is referred to as a “gate”, the other is referred to as a "back gate”.
  • the gate electrode may be referred to as a "front gate electrode”. Similarly, a gate may be referred to as a "front gate”.
  • the semiconductor layer of the transistor can be electrically surrounded by the electric field generated from the gate electrode and the electric field generated from the back gate electrode.
  • the structure of the transistor that electrically surrounds the semiconductor layer on which the channel is formed by the electric field generated from the gate electrode and the back gate electrode can be called a Surrounded channel (S-channel) structure.
  • the backgate electrode can function in the same manner as the gate electrode.
  • the potential of the back gate electrode may be the same potential as that of the gate electrode, or may be a ground potential or an arbitrary potential. Further, the threshold voltage of the transistor can be changed by changing the potential of the back gate electrode independently without interlocking with the gate electrode.
  • the gate electrode and the back gate electrode By providing the gate electrode and the back gate electrode, and further, by setting both to the same potential, the region where the carrier flows in the semiconductor layer becomes larger in the film thickness direction, so that the amount of carrier movement increases. As a result, the on-current of the transistor increases and the field effect mobility increases.
  • the transistor can be a transistor having a large on-current with respect to the occupied area. That is, the occupied area of the transistor can be reduced with respect to the required on-current. Therefore, it is possible to realize a semiconductor device having a high degree of integration.
  • the gate electrode and the back gate electrode are formed of a conductive layer, it has a function of preventing an electric field generated outside the transistor from acting on the semiconductor layer in which a channel is formed (particularly, an electric field shielding function against static electricity). ..
  • the back gate electrode is formed larger than the semiconductor layer, and the semiconductor layer is covered with the back gate electrode, whereby the electric field shielding function can be enhanced.
  • the gate electrode and the back gate electrode each have a function of shielding an electric field from the outside, charges such as charged particles generated above and below the transistor do not affect the channel formation region of the semiconductor layer. As a result, deterioration of the stress test (for example, NGBT (Negative Gate Bias-Temperature) stress test (also referred to as “NBT” or “NBTS”) in which a negative voltage is applied to the gate) is suppressed.
  • the back gate electrode can cut off the electric field generated from the drain electrode so as not to act on the semiconductor layer. Therefore, it is possible to suppress the fluctuation of the rising voltage of the on-current due to the fluctuation of the drain voltage. This effect is remarkable when a potential is supplied to the gate electrode and the back gate electrode.
  • the fluctuation of the threshold voltage before and after the PGBT (Positive Gate Bias-Temperature) stress test (also referred to as “PBT” or “PBTS”) in which a positive voltage is applied to the gate is also observed. Smaller than a transistor without a backgate electrode.
  • the BT stress test such as NGBT and PGBT is a kind of accelerated test, and it is possible to evaluate the change in transistor characteristics (secular variation) caused by long-term use in a short time.
  • the fluctuation amount of the threshold voltage of the transistor before and after the BT stress test is an important index for examining the reliability. It can be said that the smaller the fluctuation amount of the threshold voltage is before and after the BT stress test, the higher the reliability of the transistor.
  • the fluctuation amount of the threshold voltage is reduced. Therefore, the variation in electrical characteristics among the plurality of transistors is also reduced at the same time.
  • the back gate electrode side when light is incident from the back gate electrode side, by forming the back gate electrode with a conductive film having a light-shielding property, it is possible to prevent light from being incident on the semiconductor layer from the back gate electrode side. Therefore, it is possible to prevent photodegradation of the semiconductor layer and prevent deterioration of electrical characteristics such as a shift of the threshold voltage of the transistor.
  • semiconductor material there are no major restrictions on the crystallinity of the semiconductor material used for the semiconductor layer of the transistor constituting the display device 100. Any of an amorphous semiconductor and a semiconductor having crystallinity (a microcrystalline semiconductor, a polycrystalline semiconductor, a single crystalline semiconductor, or a semiconductor having a partially crystalline region) may be used. It is preferable to use a semiconductor having crystallinity because deterioration of transistor characteristics can be suppressed.
  • silicon, germanium or the like can be used as the semiconductor material used for the semiconductor layer of the transistor.
  • compound semiconductors such as silicon carbide, gallium arsenide, metal oxides and nitride semiconductors, organic semiconductors and the like can be used.
  • polycrystalline silicon polysilicon
  • amorphous silicon amorphous silicon
  • oxide semiconductor oxide semiconductor
  • a metal oxide having an energy gap of 2 eV or more, preferably 2.5 eV or more, more preferably 3 eV or more can be used.
  • a typical example is a metal oxide containing indium, and for example, CAC-OS, which will be described later, can be used.
  • Transistors using metal oxides with a wider bandgap and lower carrier density than silicon retain the charge accumulated in the capacitive element connected in series with the transistor for a long period of time due to its low off-current. It is possible.
  • the semiconductor layer is represented by an In-M-Zn-based oxide containing, for example, indium, zinc and M (M is a metal such as aluminum, titanium, gallium, germanium, ittrium, zirconium, lanthanum, cerium, tin, neodymium or hafnium). Can be a film to be made.
  • M is a metal such as aluminum, titanium, gallium, germanium, ittrium, zirconium, lanthanum, cerium, tin, neodymium or hafnium.
  • the atomic number ratio of the metal element of the sputtering target used for forming the In-M-Zn oxide is In ⁇ M, Zn. It is preferable to satisfy ⁇ M.
  • the atomic number ratio of the semiconductor layer to be formed includes a variation of plus or minus 40% of the atomic number ratio of the metal element contained in the sputtering target.
  • the semiconductor layer As the semiconductor layer, a metal oxide film having a low carrier density is used.
  • the semiconductor layer has a carrier density of 1 ⁇ 10 17 / cm 3 or less, preferably 1 ⁇ 10 15 / cm 3 or less, more preferably 1 ⁇ 10 13 / cm 3 or less, and more preferably 1 ⁇ 10 11 / cm.
  • Metal oxides having a carrier density of 3 or less, more preferably less than 1 ⁇ 10 10 / cm 3 and a carrier density of 1 ⁇ 10 -9 / cm 3 or more can be used.
  • Such metal oxides are referred to as high-purity intrinsic or substantially high-purity intrinsic metal oxides. It can be said that the metal oxide has a low defect level density and has stable characteristics.
  • a metal oxide having an appropriate composition may be used according to the required semiconductor characteristics and electrical characteristics (field effect mobility, threshold voltage, etc.) of the transistor.
  • the carrier density, impurity concentration, defect density, atomic number ratio between metal element and oxygen, interatomic distance, density, etc. of the metal oxide used as the semiconductor layer are appropriate. Is preferable.
  • Metal oxide that can be used as an oxide semiconductor will be described.
  • the metal oxide used as the oxide semiconductor preferably contains at least indium or zinc. In particular, it preferably contains indium and zinc. In addition to them, it is preferable that aluminum, gallium, yttrium, tin and the like are contained. Further, one or more kinds selected from boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, magnesium, cobalt and the like may be contained.
  • the metal oxide is an In—M—Zn oxide having indium, the element M, and zinc.
  • the element M is aluminum, gallium, yttrium, or tin.
  • Other elements applicable to the element M include boron, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, magnesium, cobalt and the like.
  • the element M a plurality of the above-mentioned elements may be combined in some cases.
  • a metal oxide having nitrogen may also be generically referred to as a metal oxide. Further, the metal oxide having nitrogen may be referred to as a metal oxynitride.
  • FIG. 10A is a diagram illustrating the classification of the crystal structure of an oxide semiconductor, typically IGZO (a metal oxide containing In, Ga, and Zn).
  • IGZO a metal oxide containing In, Ga, and Zn
  • oxide semiconductors are roughly classified into “Amorphous”, “Crystalline”, and “Crystal”.
  • “Amorphous” includes “completable amorphous”.
  • the “Crystalline” includes CAAC (c-axis-aligned crystalline), nc (nanocrystalline), and CAC (cloud-aligned crystal) (excluding single crystal).
  • single crystal, poly crystal, and single crystal amorphous are excluded from the classification of "Crystalline”.
  • “Crystal” includes single crystal and poly crystal.
  • the structure in the thick frame shown in FIG. 10A is an intermediate state between "Amorphous” and “Crystal", and belongs to a new boundary region (New crystal line phase). .. That is, the structure can be rephrased as a structure completely different from the energetically unstable "Amorphous” and "Crystal".
  • the crystal structure of the film or substrate can be evaluated using an X-ray diffraction (XRD: X-Ray Diffraction) spectrum.
  • XRD X-ray diffraction
  • the GIXD method is also referred to as a thin film method or a Seemann-Bohlin method.
  • the XRD spectrum obtained by the GIXD measurement shown in FIG. 10B may be simply referred to as an XRD spectrum in the present specification.
  • the thickness of the CAAC-IGZO film shown in FIG. 10B is 500 nm.
  • the horizontal axis is 2 ⁇ [deg. ], And the vertical axis is intensity [a. u. ].
  • a peak showing clear crystallinity is detected in the XRD spectrum of the CAAC-IGZO film.
  • the crystal structure of the film or the substrate can be evaluated by a diffraction pattern (also referred to as a microelectron diffraction pattern) observed by a micro electron diffraction method (NBED: Nano Beam Electron Diffraction).
  • the diffraction pattern of the CAAC-IGZO film is shown in FIG. 10C.
  • FIG. 10C is a diffraction pattern observed by the NBED in which the electron beam is incident parallel to the substrate.
  • electron beam diffraction is performed with the probe diameter set to 1 nm.
  • oxide semiconductors When focusing on the crystal structure, oxide semiconductors may be classified differently from FIG. 10A.
  • oxide semiconductors are divided into single crystal oxide semiconductors and other non-single crystal oxide semiconductors.
  • the non-single crystal oxide semiconductor include the above-mentioned CAAC-OS and nc-OS.
  • the non-single crystal oxide semiconductor includes a polycrystal oxide semiconductor, a pseudo-amorphous oxide semiconductor (a-like OS: atomous-like oxide semiconductor), an amorphous oxide semiconductor, and the like.
  • CAAC-OS CAAC-OS
  • nc-OS nc-OS
  • a-like OS the details of the above-mentioned CAAC-OS, nc-OS, and a-like OS will be described.
  • CAAC-OS is an oxide semiconductor having a plurality of crystal regions, the plurality of crystal regions having the c-axis oriented in a specific direction.
  • the specific direction is the thickness direction of the CAAC-OS film, the normal direction of the surface to be formed of the CAAC-OS film, or the normal direction of the surface of the CAAC-OS film.
  • the crystal region is a region having periodicity in the atomic arrangement. When the atomic arrangement is regarded as a lattice arrangement, the crystal region is also a region in which the lattice arrangement is aligned. Further, the CAAC-OS has a region in which a plurality of crystal regions are connected in the ab plane direction, and the region may have distortion.
  • the strain refers to a region in which a plurality of crystal regions are connected in which the orientation of the lattice arrangement changes between a region in which the lattice arrangement is aligned and a region in which another grid arrangement is aligned. That is, CAAC-OS is an oxide semiconductor that is c-axis oriented and not clearly oriented in the ab plane direction.
  • Each of the plurality of crystal regions is composed of one or a plurality of minute crystals (crystals having a maximum diameter of less than 10 nm).
  • the maximum diameter of the crystal region is less than 10 nm.
  • the size of the crystal region may be about several tens of nm.
  • CAAC-OS has indium (In) and oxygen. It tends to have a layered crystal structure (also referred to as a layered structure) in which a layer (hereinafter, In layer) and a layer having elements M, zinc (Zn), and oxygen (hereinafter, (M, Zn) layer) are laminated. There is. Indium and element M can be replaced with each other. Therefore, the (M, Zn) layer may contain indium. In addition, the In layer may contain the element M. The In layer may contain Zn.
  • the layered structure is observed as a grid image, for example, in a high-resolution TEM image.
  • the position of the peak indicating the c-axis orientation may vary depending on the type and composition of the metal elements constituting CAAC-OS.
  • a plurality of bright spots are observed in the electron diffraction pattern of the CAAC-OS film. Note that a certain spot and another spot are observed at point-symmetrical positions with the spot of the incident electron beam transmitted through the sample (also referred to as a direct spot) as the center of symmetry.
  • the lattice arrangement in the crystal region is based on a hexagonal lattice, but the unit lattice is not limited to a regular hexagon and may be a non-regular hexagon. Further, in the above strain, it may have a lattice arrangement such as a pentagon or a heptagon.
  • a clear grain boundary cannot be confirmed even in the vicinity of strain. That is, it can be seen that the formation of grain boundaries is suppressed by the distortion of the lattice arrangement. This is because CAAC-OS can tolerate distortion due to the fact that the arrangement of oxygen atoms is not dense in the ab plane direction and that the bond distance between atoms changes due to the substitution of metal atoms. it is conceivable that.
  • CAAC-OS for which no clear crystal grain boundary is confirmed, is one of the crystalline oxides having a crystal structure suitable for the semiconductor layer of the transistor.
  • a configuration having Zn is preferable.
  • In-Zn oxide and In-Ga-Zn oxide are more suitable than In oxide because they can suppress the generation of grain boundaries.
  • CAAC-OS is an oxide semiconductor having high crystallinity and no clear grain boundary is confirmed. Therefore, it can be said that CAAC-OS is unlikely to cause a decrease in electron mobility due to grain boundaries. Further, since the crystallinity of the oxide semiconductor may be deteriorated due to the mixing of impurities, the generation of defects, etc., CAAC-OS can be said to be an oxide semiconductor having few impurities and defects (oxygen deficiency, etc.). Therefore, the oxide semiconductor having CAAC-OS has stable physical properties. Therefore, the oxide semiconductor having CAAC-OS is resistant to heat and has high reliability. CAAC-OS is also stable against high temperatures (so-called thermal budgets) in the manufacturing process. Therefore, if CAAC-OS is used for the OS transistor, the degree of freedom in the manufacturing process can be expanded.
  • nc-OS has periodicity in the atomic arrangement in a minute region (for example, a region of 1 nm or more and 10 nm or less, particularly a region of 1 nm or more and 3 nm or less).
  • nc-OS has tiny crystals. Since the size of the minute crystal is, for example, 1 nm or more and 10 nm or less, particularly 1 nm or more and 3 nm or less, the minute crystal is also referred to as a nanocrystal.
  • nc-OS has no regularity in crystal orientation between different nanocrystals. Therefore, no orientation is observed in the entire film.
  • nc-OS may be indistinguishable from a-like OS or amorphous oxide semiconductor depending on the analysis method.
  • a peak indicating crystallinity is not detected in the Out-of-plane XRD measurement using a ⁇ / 2 ⁇ scan.
  • electron beam diffraction also referred to as limited field electron diffraction
  • a diffraction pattern such as a halo pattern is performed. Is observed.
  • electron diffraction also referred to as nanobeam electron diffraction
  • an electron beam having a probe diameter for example, 1 nm or more and 30 nm or less
  • An electron diffraction pattern in which a plurality of spots are observed in a ring-shaped region centered on a direct spot may be acquired.
  • the a-like OS is an oxide semiconductor having a structure between nc-OS and an amorphous oxide semiconductor.
  • the a-like OS has a void or low density region. That is, a-like OS has lower crystallinity than nc-OS and CAAC-OS. In addition, a-like OS has a higher hydrogen concentration in the membrane than nc-OS and CAAC-OS.
  • CAC-OS relates to the material composition.
  • CAC-OS is, for example, a composition of a material in which the elements constituting the metal oxide are unevenly distributed in a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or in the vicinity thereof.
  • the metal oxide one or more metal elements are unevenly distributed, and the region having the metal element has a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or a size close thereto.
  • the mixed state is also called a mosaic shape or a patch shape.
  • the CAC-OS has a structure in which the material is separated into a first region and a second region to form a mosaic, and the first region is distributed in the film (hereinafter, also referred to as a cloud shape). It is said.). That is, the CAC-OS is a composite metal oxide having a structure in which the first region and the second region are mixed.
  • the atomic number ratios of In, Ga, and Zn with respect to the metal elements constituting CAC-OS in the In-Ga-Zn oxide are expressed as [In], [Ga], and [Zn], respectively.
  • the first region is a region where [In] is larger than [In] in the composition of the CAC-OS film.
  • the second region is a region in which [Ga] is larger than [Ga] in the composition of the CAC-OS film.
  • the first region is a region in which [In] is larger than [In] in the second region and [Ga] is smaller than [Ga] in the second region.
  • the second region is a region in which [Ga] is larger than [Ga] in the first region and [In] is smaller than [In] in the first region.
  • the first region is a region containing indium oxide, indium zinc oxide, or the like as a main component.
  • the second region is a region containing gallium oxide, gallium zinc oxide, or the like as a main component. That is, the first region can be rephrased as a region containing In as a main component. Further, the second region can be rephrased as a region containing Ga as a main component.
  • a region containing In as a main component (No. 1) by EDX mapping acquired by using energy dispersive X-ray spectroscopy (EDX: Energy Dispersive X-ray spectroscopy). It can be confirmed that the region (1 region) and the region containing Ga as a main component (second region) have a structure in which they are unevenly distributed and mixed.
  • EDX Energy Dispersive X-ray spectroscopy
  • the conductivity caused by the first region and the insulating property caused by the second region act in a complementary manner to switch the switching function (On / Off function).
  • the CAC-OS has a conductive function in a part of the material and an insulating function in a part of the material, and has a function as a semiconductor in the whole material. By separating the conductive function and the insulating function, both functions can be maximized. Therefore, by using CAC-OS for the transistor, high on -current (Ion), high field effect mobility ( ⁇ ), and good switching operation can be realized.
  • Oxide semiconductors have various structures, and each has different characteristics.
  • the oxide semiconductor of one aspect of the present invention has two or more of amorphous oxide semiconductor, polycrystalline oxide semiconductor, a-like OS, CAC-OS, nc-OS, and CAAC-OS. You may.
  • the oxide semiconductor as a transistor, a transistor having high field effect mobility can be realized. In addition, a highly reliable transistor can be realized.
  • the carrier concentration in the channel formation region of the oxide semiconductor is 1 ⁇ 10 17 cm -3 or less, preferably 1 ⁇ 10 15 cm -3 or less, more preferably 1 ⁇ 10 13 cm -3 or less, and more preferably 1 ⁇ . It is 10 11 cm -3 or less, more preferably 1 ⁇ 10 10 cm -3 or less, and 1 ⁇ 10 -9 cm -3 or more.
  • the impurity concentration in the oxide semiconductor film may be lowered to lower the defect level density.
  • a low impurity concentration and a low defect level density is referred to as high-purity intrinsic or substantially high-purity intrinsic.
  • An oxide semiconductor having a low carrier concentration may be referred to as a high-purity intrinsic or substantially high-purity intrinsic oxide semiconductor.
  • the trap level density may also be low.
  • the charge captured at the trap level of the oxide semiconductor takes a long time to disappear, and may behave as if it were a fixed charge. Therefore, a transistor in which a channel forming region is formed in an oxide semiconductor having a high trap level density may have unstable electrical characteristics.
  • impurities include hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel, silicon and the like.
  • the concentration of silicon and carbon in the channel formation region of the oxide semiconductor and the concentration of silicon or carbon near the interface with the channel formation region of the oxide semiconductor (secondary ion mass spectrometry (SIMS)). 2 ⁇ 10 18 atoms / cm 3 or less, preferably 2 ⁇ 10 17 atoms / cm 3 or less.
  • the oxide semiconductor contains an alkali metal or an alkaline earth metal
  • defect levels may be formed and carriers may be generated. Therefore, a transistor using an oxide semiconductor containing an alkali metal or an alkaline earth metal tends to have a normally-on characteristic. Therefore, the concentration of the alkali metal or alkaline earth metal in the channel formation region of the oxide semiconductor obtained by SIMS is set to 1 ⁇ 10 18 atoms / cm 3 or less, preferably 2 ⁇ 10 16 atoms / cm 3 or less. ..
  • the nitrogen concentration in the channel formation region of the oxide semiconductor obtained by SIMS is less than 5 ⁇ 10 19 atoms / cm 3 , preferably 5 ⁇ 10 18 atoms / cm 3 or less, more preferably 1 ⁇ 10 18 atoms. / Cm 3 or less, more preferably 5 ⁇ 10 17 atoms / cm 3 or less.
  • hydrogen contained in an oxide semiconductor reacts with oxygen bonded to a metal atom to become water, which may form an oxygen deficiency.
  • oxygen deficiency When hydrogen enters the oxygen deficiency, electrons that are carriers may be generated.
  • a part of hydrogen may be combined with oxygen that is bonded to a metal atom to generate an electron as a carrier. Therefore, a transistor using an oxide semiconductor containing hydrogen tends to have a normally-on characteristic. Therefore, it is preferable that hydrogen in the channel forming region of the oxide semiconductor is reduced as much as possible.
  • the hydrogen concentration obtained by SIMS is less than 1 ⁇ 10 20 atoms / cm 3 , preferably less than 5 ⁇ 10 19 atoms / cm 3 , more preferably 1 ⁇ 10. It should be less than 19 atoms / cm 3 , more preferably less than 5 ⁇ 10 18 atoms / cm 3 , and even more preferably less than 1 ⁇ 10 18 atoms / cm 3 .
  • the semiconductor material that can be used for the semiconductor layer of the transistor is not limited to the above-mentioned metal oxide.
  • a semiconductor material having a bandgap (a semiconductor material that is not a zero-gap semiconductor) may be used.
  • a semiconductor of a single element such as silicon, a compound semiconductor such as gallium arsenide, a layered substance (also referred to as an atomic layer material, a two-dimensional material, etc.) that functions as a semiconductor, and the like.
  • a layered substance that functions as a semiconductor as a semiconductor material it is preferable to use a layered substance that functions as a semiconductor as a semiconductor material.
  • the layered substance is a general term for a group of materials having a layered crystal structure.
  • a layered crystal structure is a structure in which layers formed by covalent or ionic bonds are laminated via bonds that are weaker than covalent or ionic bonds, such as van der Waals forces.
  • the layered material has high electrical conductivity in the unit layer, that is, high two-dimensional electrical conductivity.
  • Layered substances include graphene, silicene, chalcogenides and the like.
  • Chalcogenides are compounds containing chalcogens. Chalcogen is a general term for elements belonging to Group 16, and includes oxygen, sulfur, selenium, tellurium, polonium, and livermorium. Examples of chalcogenides include transition metal chalcogenides and group 13 chalcogenides.
  • transition metal chalcogenide that functions as a semiconductor.
  • Specific examples of transition metal chalcogenides applicable as semiconductor layers include molybdenum sulfide (typically MoS 2 ), molybdenum selenium (typically MoSe 2 ), and molybdenum tellurium (typically MoTe 2 ).
  • Tungsten sulfide typically WS 2
  • tungsten selenium typically WSe 2
  • tellurium tungsten typically WTe 2
  • hafnium sulfide typically HfS 2
  • hafnium selenium presentative
  • HfSe 2 zirconium sulfide
  • zirconium selenium typically ZrSe 2
  • the drive circuit 102 has a function of generating a signal for controlling the display unit 104 by using the control signal and the video signal supplied from the input / output terminal unit 106 and supplying the signal to the display unit 104.
  • the drive circuit 102 is required to operate at high speed. Therefore, it is preferable that the drive circuit 102 is composed of a transistor having a high operating speed. For example, it is preferable to form the drive circuit 102 with a crystalline semiconductor.
  • the transistor constituting the display unit 104 is preferably composed of a transistor (OS transistor) containing an oxide semiconductor in the semiconductor layer on which the channel is formed. Since the oxide semiconductor has an energy gap of 2 eV or more, the off-current of the transistor can be reduced. Therefore, it is preferable to use an OS transistor for the transistor 436 and / or the transistor 434.
  • OS transistor a transistor containing an oxide semiconductor in the semiconductor layer on which the channel is formed. Since the oxide semiconductor has an energy gap of 2 eV or more, the off-current of the transistor can be reduced. Therefore, it is preferable to use an OS transistor for the transistor 436 and / or the transistor 434.
  • the OS transistor has a high dielectric strength between the source and the drain.
  • the transistor 251 functions as a switch for supplying electric power to the display element 432, it is preferable to use a transistor having a high dielectric strength between the source and the drain as the transistor 251. Therefore, it is preferable to use an OS transistor for the transistor 251.
  • the reliability of the display device 100 is improved and the power consumption is improved. Reduction can be realized.
  • the semiconductor material used for the transistor constituting the drive circuit 102 and the semiconductor material used for the transistor constituting the display unit 104 may be the same.
  • the configuration of the display device 100 may be a laminated configuration of a drive circuit 102 made of a single crystal silicon substrate and a display unit 104 made of a single crystal silicon substrate.
  • the display device 100 can be downsized. Further, when the external dimensions of the display device 100 are constant, the area of the display unit 104 can be expanded. Therefore, the resolution of the display device 100 can be increased. Further, when the resolution of the pixels is constant, the occupied area per pixel can be increased. Therefore, the emission brightness of the display device can be increased.
  • the aperture ratio of the pixels can be increased. For example, the aperture ratio of the pixel can be 40% or more and less than 100%, preferably 50% or more and 95% or less, and more preferably 60% or more and 95% or less. Further, by increasing the occupied area per pixel, the current density supplied to the pixel can be reduced. Therefore, the load applied to the pixels is reduced, and the reliability of the display device 100 can be improved.
  • the display device 100 according to one aspect of the present invention can be suitably used for a device for VR such as a head-mounted display or a device for glasses-type AR.
  • the display device 100 according to one aspect of the present invention can easily improve the aperture ratio and has good visibility. Therefore, a device for VR or a device for AR using the display device 100 according to one aspect of the present invention can obtain a high immersive feeling.
  • the display device 100 according to one aspect of the present invention is not limited to the above-mentioned device, and can be suitably used for an electronic device having a relatively small display unit. For example, it can be suitably used for a display unit of a wearable electronic device such as a wristwatch.
  • the semiconductor device that can be provided on the substrate 101 is not limited to the drive circuit 102.
  • a storage device 113, a GPU 114, and / or a CPU 115 and the like may be provided on the substrate 101.
  • the display device 100A shown in FIG. 4 has a drive circuit 102, a storage device 113, a GPU 114, and a CPU 115 on the substrate 101.
  • the semiconductor device on the substrate 101 and the display unit 104 are displayed separately in order to make the configuration of the invention easy to understand. Further, in FIG. 4, the description of the wiring group 103 and the like is omitted.
  • the input / output terminal unit 106 may not be provided on the display unit 104 side, but may be provided on the lower surface of the substrate 101 by using TSV (Through Silicon Via) technology or the like.
  • Example of manufacturing method> An example of a method for manufacturing the display device 100 will be described with reference to the drawings. 5 and 6 are cross-sectional views for explaining a method of manufacturing the display device 100. 7 to 9 are perspective views for explaining a method of manufacturing the display device 100. In this embodiment, a manufacturing method for manufacturing a plurality of display devices 100 together will be described.
  • a semiconductor chip 120 is provided on the support substrate 111 (see FIG. 5A).
  • the semiconductor chip 120 is a drive circuit 102 provided on an SOI (Silicon on Insulator) substrate, and a drive circuit 102 including a transistor 123 is formed on a Si substrate 121 via a BOX layer 122 (BOX: Burid Oxide). There is.
  • the drive circuit 102 side is arranged so as to face the support substrate 111.
  • the transistor 123 is a top gate type transistor
  • the gate electrode of the transistor 123 is arranged so as to be closer to the support substrate 111 than to the semiconductor layer.
  • Step 2 Next, a polishing process is performed to remove the Si substrate 121 (see FIGS. 5B and 7A). The removal of the Si substrate 121 may be performed until the BOX layer 122 is exposed.
  • Step 3 Next, the insulating layer 124 is formed by covering the drive circuit 102 (see FIG. 5C).
  • the insulating layer 124 is flattened (see FIG. 5D).
  • the flattening treatment may be performed by a known method such as a chemical mechanical polishing (CMP) treatment.
  • CMP chemical mechanical polishing
  • the substrate 101 is bonded onto the insulating layer 124 and the drive circuit 102 (see FIG. 5E).
  • An insulating layer containing the same constituent elements as the insulating layer 124 may be provided on the bonded surface of the substrate 101.
  • the insulating layer it becomes easier for both to adhere to each other.
  • the insulating layer 124 is silicon oxide
  • silicon oxide may be provided on the bonded surface of the substrate 101.
  • Step 6 Next, the support substrate 111 is removed and the substrate 101 is on the lower side (see FIGS. 5F and 7B).
  • the drive circuit 102 including the transistor 123 is arranged so that the semiconductor layer of the transistor 123 is closer to the substrate 101 than to the gate electrode.
  • the support substrate 111 may be removed by a polishing process.
  • a peeling layer may be provided between the support substrate 111 and the drive circuit 102 in advance, and the support substrate 111 may be removed by a peeling process.
  • the wiring group 103 is formed on the insulating layer 124 and the drive circuit 102 (see FIG. 6A).
  • the wiring group 103 can be formed by appropriately combining various film forming methods, photolithography methods, etching methods, and the like.
  • the wiring group 103 has a plurality of wirings. At least a part of the wiring included in the wiring group 103 is electrically connected to at least a part of the transistors included in the drive circuit 102.
  • Step 8 Next, the insulating layer 125 is formed by covering the wiring group 103 (see FIG. 6B).
  • the insulating layer 125 is flattened (see FIGS. 6C and 8A).
  • the flattening process may be performed by a known method such as CMP process. By the flattening treatment, the heights of the upper surface of the insulating layer 125 and the exposed surface of the wiring group 103 are substantially the same.
  • the display unit 104 is formed on the insulating layer 125 and the wiring group 103 (see FIGS. 6D and 8B).
  • the display unit 104 can be formed by appropriately combining various film forming methods, photolithography methods, etching methods, and the like.
  • a top emission type display unit 104 using an organic EL element is formed.
  • the substrate 105 is formed on the display unit 104.
  • a color filter and / or a microlens may be formed on the substrate 105 (see FIGS. 6E and 9A).
  • a sealing material may be provided between the display unit 104 and the substrate 105. The sealing material may be provided along the outer peripheral portion of the region where the display unit 104 and the substrate 105 overlap, or may be provided on the entire surface of the region where the display unit 104 and the substrate 105 overlap.
  • Step 12 Next, the structures produced up to step 11 are separated for each display unit 104 (see FIGS. 6F and 9B).
  • Step 13 Next, a part of the substrate 105 is removed to expose the input / output terminal portion 106 (see FIGS. 6G and 9C). In this way, the display device 100 can be formed.
  • substrate There are no major restrictions on the materials used for the substrate 101, the substrate 105 and the support substrate 111. Depending on the purpose, it may be determined in consideration of the presence or absence of translucency and the heat resistance to the extent that it can withstand heat treatment. For example, glass substrates such as barium borosilicate glass and aluminoborosilicate glass, ceramic substrates, quartz substrates, sapphire substrates, and the like can be used. Further, a semiconductor substrate, a flexible substrate (flexible substrate), a laminated film, a base film, or the like may be used.
  • glass substrates such as barium borosilicate glass and aluminoborosilicate glass, ceramic substrates, quartz substrates, sapphire substrates, and the like can be used.
  • a semiconductor substrate, a flexible substrate (flexible substrate), a laminated film, a base film, or the like may be used.
  • the semiconductor substrate examples include a semiconductor substrate made of silicon or germanium, or a compound semiconductor substrate made of silicon carbide, silicon germanium, gallium phosphide, indium phosphide, zinc oxide, or gallium oxide. .. Further, the semiconductor substrate may be a single crystal semiconductor or a polycrystalline semiconductor.
  • a transparent substrate is used for the substrate 105. It is preferable to use materials having a similar coefficient of thermal expansion for the substrate 101 and the substrate 105. Therefore, it is preferable to use the same material for the substrate 101 and the substrate 105.
  • a flexible substrate flexible substrate
  • a laminated film a base film, or the like may be used for the substrate 101 and the substrate 105.
  • polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyacrylonitrile resins, acrylic resins, polyimide resins, and polymethylmethacrylates.
  • Resin polycarbonate (PC) resin, polyether sulfone (PES) resin, polyamide resin (nylon, aramid, etc.), polysiloxane resin, cycloolefin resin, polystyrene resin, polyamideimide resin, polyurethane resin, polyvinyl chloride resin, polychloride Vinylidene resin, polypropylene resin, polytetrafluoroethylene (PTFE) resin, ABS resin, cellulose nanofibers and the like can be used.
  • PC polycarbonate
  • PES polyether sulfone
  • polyamide resin nylon, aramid, etc.
  • polysiloxane resin cycloolefin resin
  • polystyrene resin polyamideimide resin
  • polyurethane resin polyurethane resin
  • polyvinyl chloride resin polychloride Vinylidene resin
  • polypropylene resin polytetrafluoroethylene (PTFE) resin
  • PTFE polytetrafluoroethylene
  • a lightweight display device can be provided. Further, by using the above material as the substrate, it is possible to provide a display device that is strong against impact. Further, by using the above material as the substrate, it is possible to provide a display device that is not easily damaged.
  • the flexible substrate used for the substrate 101 and the substrate 105 As for the flexible substrate used for the substrate 101 and the substrate 105, the lower the coefficient of linear expansion, the more the deformation due to the environment is suppressed, which is preferable.
  • the flexible substrate used for the substrate 101 and the substrate 105 is made of, for example, a material having a linear expansion coefficient of 1 ⁇ 10 -3 / K or less, 5 ⁇ 10 -5 / K or less, or 1 ⁇ 10 -5 / K or less. It may be used.
  • aramid has a low coefficient of linear expansion and is therefore suitable as a flexible substrate.
  • conductive materials that can be used for conductive layers such as various wiring and electrodes that make up display devices include aluminum, chromium, copper, silver, gold, platinum, tantalum, and nickel.
  • An alloy in which elements are combined can be used.
  • a semiconductor typified by polycrystalline silicon containing an impurity element such as phosphorus, and a silicide such as nickel silicide may be used.
  • the method for forming the conductive material is not particularly limited, and various forming methods such as a vapor deposition method, a CVD method, a sputtering method, and a spin coating method can be used.
  • conductive materials that can be used for the conductive layer indium tin oxide, indium oxide containing tungsten oxide, indium zinc oxide containing tungsten oxide, indium oxide containing titanium oxide, and indium tin containing titanium oxide.
  • Conductive materials having oxygen such as oxides, indium zinc oxides, and indium tin oxides to which silicon oxide is added can also be used.
  • a conductive material containing nitrogen such as titanium nitride, tantalum nitride, and tungsten nitride can also be used.
  • a laminated structure may be formed in which a conductive material having oxygen, a conductive material containing nitrogen, and a material containing the above-mentioned metal element are appropriately combined.
  • the conductive material that can be used for the conductive layer may be a single-layer structure or a laminated structure having two or more layers.
  • an aluminum alloy containing one or more elements selected from titanium, tantalum, tungsten, molybdenum, chromium, neodymium, and scandium may be used.
  • Each insulating layer is made of aluminum nitride, aluminum oxide, aluminum nitride oxide, aluminum nitride, magnesium oxide, silicon nitride, silicon oxide, silicon nitride oxide, silicon nitride nitride, gallium oxide, germanium oxide, yttrium oxide, zirconium oxide, and lanthanum oxide.
  • Neodim oxide, Hafnium oxide, Tantal oxide, Aluminum silicate, etc. are used in a single layer or in a laminated manner.
  • a material obtained by mixing a plurality of materials among an oxide material, a nitride material, an oxide nitride material, and a nitride oxide material may be used.
  • the nitride oxide refers to a compound having a higher nitrogen content than oxygen.
  • the oxidative nitride refers to a compound having a higher oxygen content than nitrogen.
  • the content of each element can be measured by using, for example, Rutherford backscattering method (RBS: Rutherford Backscattering Spectrum) or the like.
  • an OS transistor when used, it is preferable to cover or sandwich the OS transistor to form an insulating layer using an insulating material in which impurities are difficult to permeate.
  • an insulating material in which impurities are difficult to permeate.
  • Examples of insulating materials that are difficult for impurities to permeate include aluminum oxide, aluminum nitride, aluminum nitride, aluminum nitride, gallium oxide, germanium oxide, yttrium oxide, zirconium oxide, lanthanum oxide, neodymium oxide, hafnium oxide, and tantalum oxide.
  • Aluminum nitride and the like can be mentioned.
  • an organic material having heat resistance such as polyimide, acrylic resin, benzocyclobutene resin, polyamide, and epoxy resin can be used.
  • organic materials low dielectric constant materials (low-k materials), siloxane-based resins, PSG (phosphorus glass), BPSG (phosphorus glass) and the like can be used. A plurality of insulating layers formed of these materials may be laminated.
  • the siloxane-based resin corresponds to a resin containing a Si—O—Si bond formed from a siloxane-based material as a starting material.
  • an organic group for example, an alkyl group or an aryl group
  • a fluoro group may be used as the substituent of the siloxane-based resin. Further, the organic group may have a fluoro group.
  • the surface of the insulating layer or the like may be subjected to CMP treatment.
  • CMP treatment the unevenness of the surface can be reduced, and the covering property of the insulating layer and the conductive layer formed after that can be improved.
  • the insulating layer and semiconductor layer constituting the display device, as well as the electrodes and the conductive layer for forming the wiring, include a sputtering method, a chemical vapor deposition (CVD) method, a vacuum vapor deposition method, and a pulse laser. It can be formed by using a deposition (PLD: Pulsed Laser Deposition) method, an atomic layer deposition (ALD: Atomic Layer Deposition) method, a plasma ALD (PEALD: Plasma Enhanced ALD) method, or the like.
  • the CVD method may be a plasma chemical vapor deposition (PECVD) method or a thermal CVD method.
  • PECVD plasma chemical vapor deposition
  • MOCVD organometallic chemical vapor deposition
  • the insulating layer, semiconductor layer, electrodes, conductive layer for forming wiring, etc. that make up the display device include spin coating, dip, spray coating, inkjet, dispense, screen printing, offset printing, slit coating, and rolls. It may be formed by a method such as a coat, a curtain coat, or a knife coat.
  • the PECVD method provides a high quality film at a relatively low temperature.
  • a film forming method that does not use plasma during film formation such as a MOCVD method, an ALD method, or a thermal CVD method
  • damage to the surface to be formed is unlikely to occur.
  • wiring, electrodes, elements (transistors, capacitive elements, etc.) included in a semiconductor device may be charged up by receiving electric charges from plasma. At this time, the accumulated electric charge may destroy the wiring, electrodes, elements, and the like included in the semiconductor device.
  • plasma damage does not occur, so that the yield of the semiconductor device can be increased. Further, since plasma damage does not occur during film formation, a film having few defects can be obtained.
  • the CVD method and the ALD method are different from the film forming method in which particles emitted from a target or the like are deposited, and are film forming methods in which a film is formed by a reaction on the surface of an object to be treated. Therefore, it is a film forming method that is not easily affected by the shape of the object to be treated and has good step coverage.
  • the ALD method has excellent step covering property and excellent thickness uniformity, and is therefore suitable for covering the surface of an opening having a high aspect ratio.
  • the ALD method since the ALD method has a relatively slow film forming speed, it may be preferable to use it in combination with another film forming method such as a CVD method having a high film forming speed.
  • the composition of the obtained film can be controlled by the flow rate ratio of the raw material gas.
  • a film having an arbitrary composition can be formed depending on the flow rate ratio of the raw material gas.
  • a film having a continuously changed composition can be formed by changing the flow rate ratio of the raw material gas while forming the film.
  • the film formation temperature is preferably RT or higher and 500 ° C. or lower, more preferably RT or higher and 300 ° C. or lower, and further preferably RT or higher and 200 ° C. or lower.
  • the oxygen gas and the argon gas used as the sputtering gas are gases having a dew point of -40 ° C or lower, preferably -80 ° C or lower, more preferably -100 ° C or lower, and more preferably -120 ° C or lower. By using it, it is possible to prevent water and the like from being taken into the oxide semiconductor film as much as possible.
  • oxygen can be supplied to the cambium by using a sputtering gas containing oxygen.
  • the layer (thin film) constituting the display device When processing the layer (thin film) constituting the display device, it can be processed by using a photolithography method or the like. Alternatively, an island-shaped layer may be formed by a film forming method using a shielding mask. Alternatively, the layer may be processed by a nanoimprint method, a sandblast method, a lift-off method, or the like.
  • a photolithography method a resist mask is formed on a layer (thin film) to be processed, a resist mask is used as a mask, a part of the layer (thin film) is selectively removed, and then the resist mask is removed. There are a method and a method in which a layer having photosensitivity is formed, and then exposure and development are performed to process the layer into a desired shape.
  • the light used for exposure can be, for example, i-line (wavelength 365 nm), g-line (wavelength 436 nm), h-line (wavelength 405 nm), or a mixture thereof.
  • ultraviolet light, KrF laser light, ArF laser light, or the like can also be used.
  • the exposure may be performed by the immersion exposure technique.
  • extreme ultraviolet (EUV: Extreme Ultra-violet) light or X-rays may be used.
  • an electron beam can be used instead of the light used for exposure. It is preferable to use extreme ultraviolet light, X-rays or an electron beam because extremely fine processing is possible.
  • extreme ultraviolet light, X-rays or an electron beam because extremely fine processing is possible.
  • a dry etching method, a wet etching method, or the like can be used for removing (etching) the layer (thin film). Moreover, you may use these etching methods in combination.
  • the semiconductor chip 120 may be provided on the substrate 101 without using the support substrate 111. Specifically, the drive circuit 102 side of the semiconductor chip 120 is arranged so as to face the substrate 101. After that, the Si substrate 121 is removed, the insulating layer 124 is provided, and the heights of the upper surface of the insulating layer 124 and the exposed surface of the drive circuit 102 are substantially matched by the flattening treatment. Subsequent steps may be performed in the same manner as in steps 7 and subsequent steps.
  • FIG. 11A and 11B are schematic perspective views of the display module 300.
  • the display module 300 shown in FIG. 11A has a configuration in which the display device 100 is provided on the printed wiring board 301.
  • the printed wiring board 301 has a structure having wiring inside and / or on the surface of a substrate made of an insulator.
  • the input / output terminal portion 106 of the display device 100 and the terminal portion 302 of the printed wiring board 301 are electrically connected via the wire 303.
  • the wire 303 can be formed by a wire bonding method. After forming the wire 303, the wire 303 may be covered with a resin material or the like.
  • the electrical connection between the display device 100 and the printed wiring board 301 may be performed by a method other than the wire bonding method.
  • the display module 300 shown in FIG. 11A is electrically connected to the FPC 304 (FPC: Flexible printed circuits).
  • the FPC 304 has a structure in which wiring is provided on a film made of an insulator.
  • FPC304 has flexibility.
  • the FPC 304 functions as wiring for supplying a video signal and / or a power supply potential to the display device 100 from the outside.
  • the IC may be mounted on the FPC 304.
  • the printed wiring board 301 can be provided with various elements such as a resistance element, a capacitance element, and a semiconductor element. Further, by using the wiring formed on the printed wiring board 301, the distance (pitch) between the plurality of electrodes included in the input / output terminal portion 106 can be changed to the distance between the plurality of electrodes included in the terminal portion 302. That is, even when the pitch of the electrodes included in the input / output terminal 106 and the pitch of the electrodes included in the FPC 304 are different, the electrical connection between the two electrodes can be realized.
  • the display module 300 may directly connect the FPC 304 to the input / output terminal portion 106 of the display device 100.
  • the input / output terminal 106 and the FPC 304 may be electrically connected without using the printed wiring board 301.
  • the terminal portion 302 is electrically connected to the connection portion 305 provided on the lower surface of the printed wiring board 301 (the surface on the side where the display device 100 is not provided). May be good.
  • the connection portion 305 a socket type connection portion, the display module 300 can be easily attached to and detached from other devices.
  • the wiring provided in the display unit 104 and the wiring group 103 may be electrically connected via the wire 303.
  • the display unit 104 is formed of a crystalline silicon wafer (also referred to as a “Si wafer”).
  • ⁇ Number of display devices 100> When a 12-inch Si wafer was used as the substrate 101, the number of display devices 100 that could be manufactured by one substrate 101 was estimated. Table 1 shows the specifications used for the estimation.
  • the shot size is the size of a region (also referred to as an “exposure region”) that can be processed by one exposure in the photolithography method.
  • the distance between shots is the distance between adjacent exposure areas.
  • FIG. 13A shows a layout diagram of a display device 100 that can be manufactured on a substrate 101 that is a 12-inch Si wafer.
  • FIG. 13B is a diagram illustrating the correspondence between the specifications shown in Table 1 and the layout of the display device 100 manufactured from a 12-inch Si wafer.
  • 56 display devices 100 can be manufactured with one 12-inch Si wafer substrate.
  • FIG. 14A shows a diagram showing a light emitting device.
  • the light emitting device shown in FIG. 14A has a first electrode 181 and a second electrode 182 and an EL layer 183.
  • the light emitting device that can be used in one aspect of the present invention is typically a structure in which light emitting colors (for example, red (R), green (G), and blue (B)) are painted separately (SBS (SBS).
  • SBS SBS
  • a Side By Side) structure) or a tandem structure (also referred to as a tandem type element) described later can be used.
  • the SBS structure is suitable because the power consumption of the light emitting device can be suppressed.
  • the tandem structure is suitable because it can be a light emitting device with reduced manufacturing cost.
  • the EL layer 183 has a light emitting layer 193, and the light emitting layer 193 contains a light emitting material.
  • a hole injection layer 191 and a hole transport layer 192 are provided between the light emitting layer 193 and the first electrode 181.
  • the light emitting layer 193 may be configured to include a host material together with the light emitting material.
  • the host material is an organic compound having carrier transportability.
  • the host material may contain not only one kind but also a plurality of kinds.
  • the plurality of organic compounds are an organic compound having an electron transport property and an organic compound having a hole transport property because the carrier balance in the light emitting layer 193 can be adjusted.
  • the plurality of organic compounds may be organic compounds having electron transport properties together, but the electron transport properties in the light emitting layer 193 can be adjusted by different electron transport properties. By appropriately adjusting the carrier balance, it becomes possible to provide a light emitting device having a good life.
  • the configuration may be such that an excitation complex is formed between a plurality of organic compounds which are host materials or between a host material and a light emitting material.
  • an excitation complex having an appropriate emission wavelength, it is possible to realize effective energy transfer to a light emitting material and provide a light emitting device having high efficiency and good lifetime.
  • the EL layer 183 in addition to the light emitting layer 193, the hole injection layer 191 and the hole transport layer 192, the electron transport layer 194 and the electron transport layer 195 are shown, but the configuration of the light emitting device is shown. Is not limited to these. It is not necessary to form any of these layers, or it may have a layer having another function.
  • the first electrode 181 is preferably formed by using a metal having a large work function (specifically, 4.0 eV or more), an alloy, a conductive compound, a mixture thereof, or the like.
  • a metal having a large work function specifically, 4.0 eV or more
  • an alloy e.g., aluminum, copper, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium, magnesium magnesium, magnesium magnesium, magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium
  • the EL layer 183 preferably has a laminated structure, but the laminated structure is not particularly limited, and is a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, a carrier block layer, and excitons.
  • Various layer structures such as a block layer and a charge generation layer can be applied.
  • the configuration has an electron transport layer 194 and an electron transport layer 195 in addition to the hole injection layer 191 and the hole transport layer 192, and the light emitting layer 193, and is shown in FIG. 14B.
  • FIG. 14B As described above, two types of configurations having the electron transport layer 194 and the charge generation layer 196 in addition to the hole injection layer 191 and the hole transport layer 192 and the light emitting layer 193 will be described.
  • the materials constituting each layer are specifically shown below.
  • the hole injection layer 191 is a layer containing a substance having acceptability.
  • a substance having acceptability both an organic compound and an inorganic compound can be used.
  • a compound having an electron-withdrawing group (halogen group or cyano group) can be used, and 7,7,8,8-tetracyano-2,3,5,6-tetrafluoroquinodimethane can be used.
  • F4-TCNQ Chloranyl, 2,3,6,7,10,11-Hexaciano-1,4,5,8,9,12-Hexaazatriphenylene (abbreviation: HAT-CN), 1,3 , 4,5,7,8-Hexafluorotetracyano-naphthoquinodimethane (abbreviation: F6-TCNNQ), 2- (7-dicyanomethylene-1,3,4,5,6,8,9,10- Octafluoro-7H-pyrene-2-iriden) malononitrile and the like can be mentioned.
  • molybdenum oxide, vanadium oxide, ruthenium oxide, tungsten oxide, manganese oxide and the like can be used in addition to the organic compounds described above.
  • phthalocyanine-based complex compounds such as phthalocyanine (abbreviation: H2Pc) and copper phthalocyanine (abbreviation: CuPc), aromatic amine compounds, or poly (3,4-ethylenedioxythiophene) / (polystyrene sulfonic acid) (abbreviation).
  • the hole injection layer 191 can also be formed by a polymer such as PEDOT / PSS).
  • the acceptable substance can extract electrons from the adjacent hole transport layer (or hole transport material) by applying an electric field.
  • a composite material in which the acceptable substance is contained in a material having a hole transport property can also be used.
  • a composite material containing an acceptor-like substance in a material having a hole-transporting property it is possible to select a material for forming an electrode regardless of a work function. That is, not only a material having a large work function but also a material having a small work function can be used as the first electrode 181.
  • the material having a hole transport property used for the composite material various organic compounds such as an aromatic amine compound, a carbazole derivative, an aromatic hydrocarbon, and a polymer compound (oligomer, dendrimer, polymer, etc.) can be used.
  • the hole-transporting material used for the composite material is preferably a substance having a hole mobility of 1 ⁇ 10 -6 cm 2 / Vs or more.
  • the hole-transporting material used for the composite material is more preferably a substance having a relatively deep HOMO level of ⁇ 5.7 eV or more and ⁇ 5.4 eV or less. Since the hole-transporting material used for the composite material has a relatively deep HOMO level, it is easy to inject holes into the hole-transporting layer 192, and a light-emitting device having a good life can be obtained. Becomes easier.
  • the hole injection layer 191 By forming the hole injection layer 191, the hole injection property is improved, and a light emitting device having a small drive voltage can be obtained. Further, the organic compound having acceptability is an easy-to-use material because it is easy to deposit and form a film.
  • the hole transport layer 192 is formed containing a material having a hole transport property.
  • a material having a hole transport property it is preferable to have a hole mobility of 1 ⁇ 10 -6 cm 2 / Vs or more.
  • the material having a hole transporting property include 4,4'-bis [N- (1-naphthyl) -N-phenylamino] biphenyl (abbreviation: NPB) and N, N'-bis (3-methylphenyl).
  • TPD N'-diphenyl- [1,1'-biphenyl] -4,4'-diamine
  • BSPB 4,4'-bis [N- (spiro-9,9'-bifluoren-2-) Il) -N-Phenylamino] Biphenyl
  • the substance mentioned as the material having hole transportability used for the composite material of the hole injection layer 191 can also be suitably used as the material constituting the hole transport layer 192.
  • the light emitting layer 193 has a light emitting substance and a host material.
  • the light emitting layer 193 may contain other materials at the same time. Further, two layers having different compositions may be laminated.
  • the luminescent substance may be a fluorescent luminescent substance, a phosphorescent luminescent substance, a substance exhibiting thermal activated delayed fluorescence (TADF), or another luminescent substance.
  • TADF thermal activated delayed fluorescence
  • Examples of the material that can be used as the fluorescent light emitting substance in the light emitting layer 193 include 5,6-bis [4- (10-phenyl-9-anthryl) phenyl] -2,2'-bipyridine (abbreviation: PAP2BPy). ), 5,6-bis [4'-(10-phenyl-9-anthryl) biphenyl-4-yl] -2,2'-bipyridine (abbreviation: PAPP2BPy), N, N'-diphenyl-N, N' -Bis [4- (9-phenyl-9H-fluoren-9-yl) phenyl] pyrene-1,6-diamine (abbreviation: 1,6FLPAPrun) and the like. Further, other fluorescent light emitting substances can also be used.
  • examples of the material that can be used include an organometallic iridium complex having a 4H-triazole skeleton, an organometallic iridium complex having a 1H-triazole skeleton, and an imidazole skeleton.
  • examples thereof include an organometallic iridium complex having an electron-withdrawing group, and an organometallic iridium complex having a phenylpyridine derivative having an electron-withdrawing group as a ligand. These are compounds that exhibit blue phosphorescence and have emission wavelength peaks from 440 nm to 520 nm.
  • an organic metal iridium complex having a pyrimidine skeleton an organic metal iridium complex having a pyrazine skeleton, an organic metal iridium complex having a pyridine skeleton, tris (acetylacetonato) (monophenanthroline) terbium (III) (abbreviation: [Tb (acac)). ) 3 (Phen)]) and the like, such as rare earth metal complexes.
  • These are compounds that mainly exhibit green phosphorescence and have emission wavelength peaks from 500 nm to 600 nm.
  • the organometallic iridium complex having a pyrimidine skeleton is particularly preferable because it is remarkably excellent in reliability and luminous efficiency.
  • examples thereof include an organometallic iridium complex having a pyrimidine skeleton, an organometallic iridium complex having a pyrazine skeleton, an organometallic iridium complex having a pyridine skeleton, a platinum complex, and a rare earth metal complex.
  • organometallic iridium complex having a pyrimidine skeleton an organometallic iridium complex having a pyrazine skeleton
  • an organometallic iridium complex having a pyridine skeleton an organometallic iridium complex having a pyridine skeleton
  • platinum complex a platinum complex
  • a rare earth metal complex examples thereof include an organometallic iridium complex having a pyrimidine skeleton, an organometallic iridium complex having a pyrazine skeleton, an organometallic iridium complex having a pyridine skeleton, a platinum complex, and a rare earth metal
  • known phosphorescent luminescent substances may be selected and used.
  • TADF material fullerene and its derivatives, acridine and its derivatives, eosin derivatives and the like can be used.
  • examples thereof include metal-containing porphyrin containing magnesium (Mg), zinc (Zn), cadmium (Cd), tin (Sn), platinum (Pt), indium (In), palladium (Pd) and the like.
  • the TADF material is a material having a small difference between the S1 level and the T1 level and having a function of converting energy from triplet excitation energy to singlet excitation energy by crossing between inverse terms. Therefore, the triplet excited energy can be up-converted to the singlet excited energy (intersystem crossing) with a small amount of thermal energy, and the singlet excited state can be efficiently generated. In addition, triplet excitation energy can be converted into light emission.
  • an excited complex also referred to as an exciplex, an exciplex or an Exciplex
  • the difference between the S1 level and the T1 level is extremely small, and the triplet excitation energy is the singlet excitation energy. It has a function as a TADF material that can be converted into.
  • a phosphorescence spectrum observed at a low temperature may be used.
  • a tangent line is drawn at the hem on the short wavelength side of the fluorescence spectrum
  • the energy of the wavelength of the extrawire is set to the S1 level
  • a tangent line is drawn at the hem on the short wavelength side of the phosphorescence spectrum, and the extrapolation line is drawn.
  • the difference between S1 and T1 is preferably 0.3 eV or less, and more preferably 0.2 eV or less.
  • the S1 level of the host material is higher than the S1 level of the TADF material. Further, it is preferable that the T1 level of the host material is higher than the T1 level of the TADF material.
  • various carrier transport materials such as a material having an electron transport property, a material having a hole transport property, and the TADF material can be used.
  • an organic compound having an amine skeleton or a ⁇ -electron excess type heteroaromatic ring skeleton is preferable.
  • a compound having an aromatic amine skeleton, a compound having a carbazole skeleton, a compound having a thiophene skeleton, a compound having a furan skeleton, and the like can be mentioned.
  • the compound having an aromatic amine skeleton and the compound having a carbazole skeleton are preferable because they have good reliability, high hole transportability, and contribute to reduction of driving voltage.
  • a metal complex or an organic compound having a ⁇ -electron deficient heteroaromatic ring skeleton is preferable.
  • the organic compound having a ⁇ -electron deficient heteroarocyclic skeleton include a heterocyclic compound having a polyazole skeleton, a heterocyclic compound having a diazine skeleton, a heterocyclic compound having a triazine skeleton, and a heterocyclic compound having a pyridine skeleton. Can be mentioned.
  • the heterocyclic compound having a diazine skeleton, the heterocyclic compound having a triazine skeleton, and the heterocyclic compound having a pyridine skeleton are preferable because they have good reliability.
  • a heterocyclic compound having a diazine (pyrimidine or pyrazine) skeleton has high electron transport properties and contributes to a reduction in driving voltage.
  • the TADF material that can be used as the host material those listed above as the TADF material can also be used in the same manner.
  • the triplet excitation energy generated by the TADF material is converted to singlet excitation energy by crossing between inverse terms, and further energy is transferred to the light emitting material, thereby increasing the light emission efficiency of the light emitting device. be able to.
  • a material having an anthracene skeleton is suitable as the host material.
  • a substance having an anthracene skeleton is used as a host material for a fluorescent light emitting substance, it is possible to realize a light emitting layer having good luminous efficiency and durability.
  • the electron transport layer 194 is a layer containing a substance having an electron transport property.
  • the substance having electron transporting property the substance listed as the substance having electron transporting property which can be used for the above-mentioned host material can be used.
  • the electron transport layer 194 has an electron mobility of 1 ⁇ 10 -7 cm 2 / Vs or more and 5 ⁇ 10 -5 cm 2 / Vs or less when the square root of the electric field strength [V / cm] is 600. preferable. By reducing the electron transportability in the electron transport layer 194, the amount of electrons injected into the light emitting layer can be controlled, and the light emitting layer can be prevented from being in a state of excess electrons. Further, the electron transport layer preferably contains a material having electron transport properties and an alkali metal or a simple substance, compound or complex of an alkali metal.
  • the hole injection layer is formed as a composite material, and the HOMO level of the material having hole transportability in the composite material is -5.7 eV or more and -5.4 eV or less, which is a relatively deep HOMO level. It is particularly preferable that the substance has a good life. At this time, it is preferable that the HOMO level of the material having electron transportability is ⁇ 6.0 eV or more.
  • lithium fluoride (LiF), cesium fluoride (CsF), calcium fluoride (CaF 2 ), 8-hydroxyquinolinato-lithium A layer containing an alkali metal or an alkaline earth metal such as (abbreviation: Liq) or a compound thereof may be provided.
  • an alkali metal, an alkaline earth metal, or a compound thereof contained in a layer made of a substance having an electron transport property, or an electride may be used. Examples of the electride include a substance in which a high concentration of electrons is added to a mixed oxide of calcium and aluminum.
  • the electron transport layer 195 contains an electron transportable substance (preferably an organic compound having a bipyridine skeleton) at a concentration of the alkali metal or alkaline earth metal fluoride in a microcrystalline state (50 wt% or more). It is also possible to use an alkaline layer. Since the layer has a low refractive index, it is possible to provide a light emitting device having better external quantum efficiency.
  • an electron transportable substance preferably an organic compound having a bipyridine skeleton
  • a charge generation layer 196 may be provided instead of the electron transport layer 195 (FIG. 14B).
  • the charge generation layer 196 is a layer capable of injecting holes into the layer in contact with the cathode side and electrons into the layer in contact with the anode side by applying an electric potential.
  • the charge generation layer 196 includes at least a P-type layer 197.
  • the P-type layer 197 is preferably formed by using the composite material mentioned as the material that can form the hole injection layer 191 described above. Further, the P-type layer 197 may be formed by laminating a film containing the above-mentioned acceptor material and a film containing a hole transport material as a material constituting the composite material.
  • the organic compound according to one aspect of the present invention is an organic compound having a low refractive index, it is possible to obtain a light emitting device having good external quantum efficiency by using it for the P-type layer 197.
  • the charge generation layer 196 preferably has one or both of the electron relay layer 198 and the electron injection buffer layer 199 in addition to the P-type layer 197.
  • the electron relay layer 198 contains at least a substance having electron transportability, and has a function of preventing interaction between the electron injection buffer layer 199 and the P-type layer 197 and smoothly transferring electrons.
  • the LUMO level of the electron-transporting substance contained in the electron relay layer 198 is the LUMO level of the accepting substance in the P-type layer 197 and the substance contained in the layer in contact with the charge generating layer 196 in the electron transporting layer 194. It is preferably between the LUMO level.
  • the specific energy level of the LUMO level in the substance having electron transportability used in the electron relay layer 198 is preferably ⁇ 5.0 eV or higher, preferably ⁇ 5.0 eV or higher and ⁇ 3.0 eV or lower.
  • As the substance having electron transportability used in the electron relay layer 198 it is preferable to use a phthalocyanine-based material or a metal complex having a metal-oxygen bond and an aromatic ligand.
  • the electron injection buffer layer 199 includes alkali metals, alkaline earth metals, rare earth metals, and compounds thereof (alkali metal compounds (including oxides such as lithium oxide, halides, and carbonates such as lithium carbonate and cesium carbonate). , Alkaline earth metal compounds (including oxides, halides and carbonates), or rare earth metal compounds (including oxides, halides and carbonates)) and other highly electron-injectable substances can be used. Is.
  • the donor substance includes an alkali metal, an alkaline earth metal, a rare earth metal, and a compound thereof (as a donor substance).
  • Alkali metal compounds including oxides such as lithium oxide, halides, carbonates such as lithium carbonate and cesium carbonate
  • alkaline earth metal compounds including oxides, halides and carbonates
  • organic compounds such as tetrathianaphthalene (abbreviation: TTN), nickerosen, and decamethyl nickerosen can also be used.
  • TTN tetrathianaphthalene
  • nickerosen nickerosen
  • decamethyl nickerosen can also be used.
  • the substance having electron transportability it can be formed by using the same material as the material constituting the electron transport layer 194 described above.
  • a metal having a small work function (specifically, 3.8 eV or less), an alloy, an electrically conductive compound, a mixture thereof, or the like
  • a cathode material include alkali metals such as lithium (Li) and cesium (Cs), and Group 1 or Group 1 of the Periodic Table of the Elements such as magnesium (Mg), calcium (Ca), and strontium (Sr).
  • alkali metals such as lithium (Li) and cesium (Cs)
  • Group 1 or Group 1 of the Periodic Table of the Elements such as magnesium (Mg), calcium (Ca), and strontium (Sr).
  • MgAg, AlLi rare earth metals
  • Eu europium
  • Yb ytterbium
  • indium oxide-tin oxide containing Al, Ag, ITO, silicon or silicon oxide is provided regardless of the magnitude of the work function.
  • Various conductive materials such as the second electrode 182 can be used as the second electrode 182. These conductive materials can be formed into a film by using a dry method such as a vacuum vapor deposition method or a sputtering method, an inkjet method, a spin coating method, or the like. Further, it may be formed by a wet method using a sol-gel method, or may be formed by a wet method using a paste of a metal material.
  • a method for forming the EL layer 183 various methods can be used regardless of whether it is a dry method or a wet method.
  • a vacuum vapor deposition method, a gravure printing method, an offset printing method, a screen printing method, an inkjet method, a spin coating method, or the like may be used.
  • each electrode or each layer described above may be formed by using a different film forming method.
  • the structure of the layer provided between the first electrode 181 and the second electrode 182 is not limited to the above. However, holes and electrons are located away from the first electrode 181 and the second electrode 182 so that the quenching caused by the proximity of the light emitting region to the metal used for the electrode or carrier injection layer is suppressed. It is preferable to provide a light emitting region that recombines with and.
  • the hole transport layer and the electron transport layer in contact with the light emitting layer 193, particularly the carrier transport layer near the recombination region in the light emitting layer 193, suppresses the energy transfer from the excitons generated in the light emitting layer, so that the band gap thereof.
  • the first electrode 181 is formed by using a conductive material that efficiently reflects the light emitted by the EL layer 183, and the second electrode 182 transmits visible light. It is preferably formed using a conductive material.
  • the structure of the first electrode 181 is not limited to a single layer, and may be a laminated structure having a plurality of layers.
  • the layer in contact with the EL layer 183 is a layer having translucency such as indium tin oxide, and a layer having high reflectance (aluminum, aluminum) in contact with the layer is used. (Containing alloy, silver, etc.) may be provided.
  • Examples of the conductive material that reflects visible light include metal materials such as aluminum, gold, platinum, silver, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, or palladium, or alloys containing these metal materials. Can be used. Further, lanthanum, neodymium, germanium or the like may be added to the above metal material and / or alloy. Also, alloys containing aluminum such as alloys of aluminum and titanium, alloys of aluminum and nickel, alloys of aluminum and neodym (aluminum alloys), alloys of silver and copper, alloys of silver and palladium and copper, alloys of silver and magnesium, etc. It can be formed using an alloy containing silver.
  • metal materials such as aluminum, gold, platinum, silver, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, or palladium, or alloys containing these metal materials. Can be used. Further, lanthanum, neodymium, germanium or the
  • Alloys containing silver and copper are preferred because of their high heat resistance.
  • a metal film or an alloy film and a metal oxide film may be laminated. For example, by laminating a metal film or a metal oxide film so as to be in contact with the aluminum alloy film, oxidation of the aluminum alloy film can be suppressed.
  • Other examples of the metal film and the metal oxide film include titanium and titanium oxide.
  • a light-transmitting conductive film and a film made of a metal material may be laminated. For example, a laminated film of silver and indium tin oxide, a laminated film of an alloy of silver and magnesium and indium tin oxide (ITO: Indium Tin Oxide), and the like can be used.
  • the light emitting device is a light emitting element having a bottom emission structure (bottom emission structure)
  • a conductive material that transmits visible light is used for the first electrode 181 and visible light is reflected by the second electrode 182.
  • a conductive material may be used.
  • the light emitting device is a display device having a dual emission structure (double-sided injection structure)
  • a conductive material that transmits visible light may be used for both the first electrode 181 and the second electrode 182.
  • a light emitting device also referred to as a laminated element or a tandem type element having a configuration in which a plurality of light emitting units are laminated
  • This light emitting device is a light emitting device having a plurality of light emitting units between the anode and the cathode.
  • One light emitting unit has almost the same configuration as the EL layer 183 shown in FIG. 14A. That is, it can be said that the light emitting device shown in FIG. 14C is a light emitting device having a plurality of light emitting units, and the light emitting device shown in FIG. 14A or FIG. 14B is a light emitting device having one light emitting unit.
  • a first light emitting unit 511 and a second light emitting unit 512 are laminated between the anode 501 and the cathode 502, and between the first light emitting unit 511 and the second light emitting unit 512. Is provided with a charge generation layer 513.
  • the anode 501 and the cathode 502 correspond to the first electrode 181 and the second electrode 182 in FIG. 14A, respectively, and the same ones described in the description of FIG. 14A can be applied.
  • the first light emitting unit 511 and the second light emitting unit 512 may have the same configuration or different configurations.
  • the charge generation layer 513 has a function of injecting electrons into one light emitting unit and injecting holes into the other light emitting unit when a voltage is applied to the anode 501 and the cathode 502. That is, in FIG. 14C, when a voltage is applied so that the potential of the anode is higher than the potential of the cathode, the charge generation layer 513 injects electrons into the first light emitting unit 511 and the second light emitting unit. Anything that injects holes into 512 may be used.
  • the charge generation layer 513 is preferably formed with the same configuration as the charge generation layer 196 described with reference to FIG. 14B. Since the composite material of the organic compound and the metal oxide is excellent in carrier injection property and carrier transport property, low voltage drive and low current drive can be realized. When the surface of the light emitting unit on the anode side is in contact with the charge generating layer 513, the charge generating layer 513 can also serve as the hole injection layer of the light emitting unit, so that the light emitting unit uses the hole injection layer. It does not have to be provided.
  • the electron injection buffer layer 199 plays the role of the electron injection layer in the light emitting unit on the anode side, so that the electron injection layer is not necessarily provided in the light emitting unit on the anode side. There is no need to form.
  • FIG. 14C a light emitting device having two light emitting units has been described, but the same can be applied to a light emitting device in which three or more light emitting units are stacked.
  • a plurality of light emitting units partitioned by a charge generation layer 513 between a pair of electrodes as in the light emitting device according to the present embodiment, high-luminance light emission is possible while keeping the current density low, and further.
  • a long-life element can be realized.
  • each light emitting unit by making the emission color of each light emitting unit different, it is possible to obtain light emission of a desired color as the entire light emitting device. For example, in a light emitting device having two light emitting units, a light emitting device that emits white light as a whole by obtaining a red and green light emitting color from the first light emitting unit and a blue light emitting color from the second light emitting unit. It is also possible to get.
  • each layer such as the EL layer 183, the first light emitting unit 511, the second light emitting unit 512, and the charge generation layer and the electrodes are, for example, a vapor deposition method (including a vacuum vapor deposition method) and a droplet ejection method (inkjet). It can be formed by using a method such as a method), a coating method, or a gravure printing method. They may also include small molecule materials, medium molecule materials (including oligomers, dendrimers), or polymer materials.
  • the display device of one aspect of the present invention can be applied to the display unit of an electronic device. Therefore, it is possible to realize an electronic device having high display quality. Alternatively, an extremely high-definition electronic device can be realized. Alternatively, a highly reliable electronic device can be realized.
  • an electronic device using a display device can be used as a display device such as a television or a monitor, a lighting device, a desktop or notebook type personal computer, a word processor, a recording medium such as a DVD (Digital Versaille Disc).
  • Image playback device for playing stored still images or videos, portable CD player, radio, tape recorder, headphone stereo, stereo, table clock, wall clock, cordless telephone handset, transceiver, car phone, mobile phone, mobile information terminal, High frequency such as tablet terminals, portable game machines, fixed game machines such as pachinko machines, calculators, electronic notebooks, electronic book terminals, electronic translators, voice input devices, video cameras, digital still cameras, electric shavers, microwave ovens, etc.
  • industrial equipment such as guide lights, traffic lights, conveyor belts, elevators, escalators, industrial robots, power storage systems, power leveling and power storage devices for smart grids.
  • an engine using fuel or a moving body propelled by an electric motor using electric power from a storage body may also be included in the category of electronic devices.
  • Examples of the moving body include an electric vehicle (EV), a hybrid vehicle (HV) having both an internal combustion engine and an electric motor, a plug-in hybrid vehicle (PHV), a tracked vehicle in which these tire wheels are changed to an infinite track, and an electric assist.
  • EV electric vehicle
  • HV hybrid vehicle
  • PHS plug-in hybrid vehicle
  • Motorized bicycles including bicycles, motorcycles, electric wheelchairs, golf carts, small or large vessels, submarines, helicopters, aircraft, rockets, artificial satellites, space explorers, planetary explorers, spacecraft, etc.
  • the electronic device may have a secondary battery (battery), and it is preferable that the secondary battery can be charged by using non-contact power transmission.
  • a secondary battery battery
  • Examples of the secondary battery include a lithium ion secondary battery, a nickel hydrogen battery, a nicad battery, an organic radical battery, a lead storage battery, an air secondary battery, a nickel zinc battery, a silver zinc battery and the like.
  • the electronic device may have an antenna.
  • the display unit can display images, information, and the like.
  • the antenna may be used for non-contact power transmission.
  • the electronic device includes sensors (force, displacement, position, speed, acceleration, angular speed, rotation speed, distance, light, liquid, magnetism, temperature, chemical substance, voice, time, hardness, electric field, current). , Including the ability to measure voltage, power, radiation, flow rate, humidity, gradient, vibration, odor or infrared rays).
  • the electronic device can have various functions. For example, a function to display various information (still images, moving images, text images, etc.) on the display unit, a touch panel function, a calendar, a function to display a date or time, a function to execute various software (programs), wireless communication. It can have a function, a function of reading a program or data recorded on a recording medium, and the like.
  • an electronic device having a plurality of display units a function of mainly displaying image information on one display unit and mainly displaying character information on another display unit, or parallax is considered on a plurality of display units.
  • a function of displaying a three-dimensional image or the like it is possible to have a function of displaying a three-dimensional image or the like.
  • a function of shooting a still image or a moving image, a function of automatically or manually correcting the shot image, and a function of saving the shot image in a recording medium (external or built in the electronic device). It is possible to have a function of displaying the captured image on the display unit and the like.
  • the functions of the electronic device of one aspect of the present invention are not limited to these, and can have various functions.
  • the display device can be suitably used for a portable electronic device, a wearable electronic device (wearable device), an electronic book terminal, and the like. Further, it can be suitably used for VR (Virtual Reality) equipment, AR (Augmented Reality) equipment and the like.
  • VR Virtual Reality
  • AR Augmented Reality
  • FIG. 15A shows a perspective view of the glasses-type electronic device 700.
  • the electronic device 700 has a pair of display panels 701, a pair of housings 702, a pair of optical members 703, a pair of mounting portions 704, and the like.
  • the electronic device 700 can project the image displayed on the display panel 701 onto the display area 706 of the optical member 703. Further, since the optical member 703 has translucency, the user can see the image displayed in the display area 706 by superimposing it on the transmitted image visually recognized through the optical member 703. Therefore, the electronic device 700 is an electronic device capable of AR display.
  • one housing 702 is provided with a camera 705 capable of taking an image of the front.
  • one of the housings 702 is provided with a wireless receiver or a connector to which a cable can be connected, and a video signal or the like can be supplied to the housing 702.
  • an acceleration sensor such as a gyro sensor
  • the housing 702 is provided with a battery 707, in which case the battery 702 can be charged wirelessly or by wire.
  • a display panel 701, a lens 711, and a reflector 712 are provided inside the housing 702. Further, the portion corresponding to the display area 706 of the optical member 703 has a reflecting surface 713 that functions as a half mirror.
  • the light 715 emitted from the display panel 701 passes through the lens 711 and is reflected by the reflector 712 toward the optical member 703. Inside the optical member 703, the light 715 repeats total internal reflection at the end surface of the optical member 703 and reaches the reflective surface 713, so that an image is projected on the reflective surface 713. Thereby, the user can visually recognize both the light 715 reflected by the reflecting surface 713 and the transmitted light 716 transmitted through the optical member 703 (including the reflecting surface 713).
  • FIG. 15 shows an example in which the reflector 712 and the reflector 713 each have a curved surface.
  • the degree of freedom in optical design can be increased and the optical member 703 can be made thinner than in the case where these are flat surfaces.
  • the reflector 712 and the reflection surface 713 may be flat.
  • the reflector 712 a member having a mirror surface can be used, and it is preferable that the reflector has a high reflectance. Further, as the reflecting surface 713, a half mirror utilizing the reflection of the metal film may be used, but if a prism or the like utilizing total reflection is used, the transmittance of the transmitted light 716 can be increased.
  • the housing 702 has a mechanism for adjusting the distance between the lens 711 and the display panel 701, or an angle thereof. This makes it possible to perform pinning and adjustment, enlargement and reduction of the image, and the like.
  • the lens 711 and the display panel 701 may be configured to be movable in the optical axis direction.
  • the housing 702 has a mechanism capable of adjusting the angle of the reflector 712. By changing the angle of the reflector 712, it is possible to change the position of the display area 706 in which the image is displayed. This makes it possible to arrange the display area 706 at an optimum position according to the position of the user's eyes.
  • a display device can be applied to the display panel 701. Therefore, the electronic device 700 with high display quality can be obtained.
  • FIG. 16A and 16B show perspective views of the goggle-type electronic device 750.
  • FIG. 16A is a perspective view showing the front surface, the plane and the left side surface of the electronic device 750
  • FIG. 16B is a perspective view showing the back surface, the bottom surface, and the right side surface of the electronic device 750.
  • the electronic device 750 has a pair of display panels 751, a housing 752, a pair of mounting portions 754, a cushioning member 755, a pair of lenses 756, and the like.
  • the pair of display panels 751 are provided at positions inside the housing 752 that can be visually recognized through the lens 756.
  • the electronic device 750 is an electronic device for VR.
  • a user wearing the electronic device 750 can visually recognize the image displayed on the display panel 751 through the lens 756. Further, by displaying different images on the pair of display panels 751, it is possible to perform three-dimensional display using parallax.
  • an input terminal 757 and an output terminal 758 are provided on the back side of the housing 752.
  • a cable for supplying a video signal from a video output device or the like or power for charging a battery provided in the housing 752 can be connected to the input terminal 757.
  • the output terminal 758 functions as, for example, an audio output terminal, and earphones, headphones, and the like can be connected to it. If the audio data can be output by wireless communication, or if the audio is output from an external video output device, the audio output terminal may not be provided.
  • the housing 752 has a mechanism capable of adjusting the left and right positions of the lens 756 and the display panel 751 so as to be in the optimum positions according to the positions of the eyes of the user. .. Further, it is preferable to have a mechanism for adjusting the focus by changing the distance between the lens 756 and the display panel 751.
  • a display device can be applied to the display panel 751. Therefore, it is possible to obtain an electronic device 750 having a high display quality. This makes the user feel highly immersive.
  • the cushioning member 755 is a portion that comes into contact with the user's face (forehead, cheeks, etc.). When the cushioning member 755 is in close contact with the user's face, light leakage can be prevented and the immersive feeling can be further enhanced. It is preferable to use a soft material as the cushioning member 755 so that the user comes into close contact with the user's face when the electronic device 750 is attached.
  • a soft material for example, materials such as rubber, silicone rubber, urethane, and sponge can be used.
  • a sponge or the like is covered with cloth, leather (natural leather or synthetic leather), etc., a gap is unlikely to occur between the user's face and the cushioning member 755, and light leakage is suitably prevented. Can be done.
  • a member that comes into contact with the user's skin is preferably configured to be removable because it can be easily cleaned or replaced.
  • FIG. 16C shows the appearance of the camera 830 with the finder 840 attached.
  • the camera 830 has a housing 831, a display unit 832, an operation button 833, a shutter button 834, and the like.
  • a detachable lens 836 is attached to the camera 830.
  • the camera 830 has a configuration in which the lens 836 can be removed from the housing 831 and replaced, but the lens 836 and the housing may be integrated.
  • the camera 830 can take an image by pressing the shutter button 834.
  • the display unit 832 has a function as a touch panel, and it is possible to take an image by touching the display unit 832.
  • the housing 831 of the camera 830 has a mount having electrodes, and can be connected to a finder 840, a strobe device, or the like.
  • the finder 840 has a housing 841, a display unit 842, a button 843, and the like.
  • the housing 841 has a mount that engages with the mount of the camera 830, and the finder 840 can be attached to the camera 830. Further, the mount has an electrode, and an image or the like received from the camera 830 via the electrode can be displayed on the display unit 842.
  • the button 843 has a function as a power button. With the button 843, the display of the display unit 842 can be switched on / off.
  • the display device can be applied to the display unit 832 of the camera 830 and the display unit 842 of the finder 840.
  • the camera 830 and the finder 840 are separate electronic devices, and these are detachable.
  • the finder having the display device according to one aspect of the present invention is provided in the housing 831 of the camera 830. It may be built-in.
  • FIG. 16D shows an example of a wristwatch-type information terminal.
  • the information terminal 860 includes a housing 861, a display unit 862, a band 863, a buckle 864, an operation switch 865, an input / output terminal 866, and the like. Further, the information terminal 860 is provided with an antenna, a battery, and the like inside the housing 861.
  • the information terminal 860 can execute various applications such as mobile phone, e-mail, text viewing and writing, music playback, Internet communication, and computer games.
  • the display unit 862 is provided with a touch sensor and can be operated by touching the screen with a finger or a stylus.
  • the application can be started by touching the icon 867 displayed on the display unit 862.
  • the operation switch 865 can have various functions such as power on / off operation, wireless communication on / off operation, manner mode execution / cancellation, and power saving mode execution / cancellation. ..
  • the function of the operation switch 865 can be set by the operating system incorporated in the information terminal 860.
  • the information terminal 860 can execute short-range wireless communication standardized for communication. For example, by communicating with a headset capable of wireless communication, it is possible to make a hands-free call. Further, the information terminal 860 is provided with an input / output terminal 866, and data can be transmitted / received to / from another information terminal via the input / output terminal 866. It is also possible to charge via the input / output terminal 866. The charging operation may be performed by wireless power supply without going through the input / output terminal 866.

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PCT/IB2021/061035 2020-12-11 2021-11-29 表示装置および電子機器 Ceased WO2022123387A1 (ja)

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Citations (4)

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JP2013225620A (ja) * 2012-04-23 2013-10-31 Semiconductor Energy Lab Co Ltd 表示装置、表示装置の作製方法および電子機器
JP2018006729A (ja) * 2016-02-12 2018-01-11 株式会社半導体エネルギー研究所 半導体装置
JP2018110184A (ja) * 2017-01-04 2018-07-12 株式会社ジャパンディスプレイ 半導体装置およびその製造方法
WO2019215530A1 (ja) * 2018-05-11 2019-11-14 株式会社半導体エネルギー研究所 表示装置、及び表示装置の作製方法

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JP2008204966A (ja) * 2005-05-23 2008-09-04 Sharp Corp 半導体装置及びその製造方法並びに液晶表示装置
JP5227536B2 (ja) * 2006-04-28 2013-07-03 株式会社半導体エネルギー研究所 半導体集積回路の作製方法
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Publication number Priority date Publication date Assignee Title
JP2013225620A (ja) * 2012-04-23 2013-10-31 Semiconductor Energy Lab Co Ltd 表示装置、表示装置の作製方法および電子機器
JP2018006729A (ja) * 2016-02-12 2018-01-11 株式会社半導体エネルギー研究所 半導体装置
JP2018110184A (ja) * 2017-01-04 2018-07-12 株式会社ジャパンディスプレイ 半導体装置およびその製造方法
WO2019215530A1 (ja) * 2018-05-11 2019-11-14 株式会社半導体エネルギー研究所 表示装置、及び表示装置の作製方法

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