WO2022121197A1 - Thermal tuning semiconductor chip and preparation method therefor - Google Patents

Thermal tuning semiconductor chip and preparation method therefor Download PDF

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Publication number
WO2022121197A1
WO2022121197A1 PCT/CN2021/087279 CN2021087279W WO2022121197A1 WO 2022121197 A1 WO2022121197 A1 WO 2022121197A1 CN 2021087279 W CN2021087279 W CN 2021087279W WO 2022121197 A1 WO2022121197 A1 WO 2022121197A1
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Prior art keywords
layer
suspension
substrate
semiconductor chip
sacrificial layer
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PCT/CN2021/087279
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French (fr)
Chinese (zh)
Inventor
赵建宜
李景磊
张博
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武汉光迅科技股份有限公司
武汉电信器件有限公司
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Priority claimed from CN202011455817.XA external-priority patent/CN112563878B/en
Priority claimed from CN202011458418.9A external-priority patent/CN114628486A/en
Application filed by 武汉光迅科技股份有限公司, 武汉电信器件有限公司 filed Critical 武汉光迅科技股份有限公司
Publication of WO2022121197A1 publication Critical patent/WO2022121197A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/028Coatings ; Treatment of the laser facets, e.g. etching, passivation layers or reflecting layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/06Arrangements for controlling the laser output parameters, e.g. by operating on the active medium

Definitions

  • the present application relates to the technical field of semiconductors, and in particular, to a thermally tuned semiconductor chip and a preparation method thereof.
  • the linewidth of such chips is generally above several MHz, which cannot be achieved. Meet the requirements of the coherent transmission system for the chip line width.
  • thermal tuning chips based on thermal effects have been paid attention to by device manufacturers. Due to the thermal effect, the high frequency noise component is very small, so that the chip line width can be greatly improved.
  • the thermal power is easily dissipated through the substrate because the functional layer is at a certain distance from the thermally tuned electrodes, and the functional layer of the chip is physically connected to the substrate, and the thermal tuning efficiency is quite low.
  • the embodiments of the present application provide a thermally tuned semiconductor chip and a manufacturing method thereof to solve at least one problem existing in the background art.
  • an embodiment of the present application provides a thermally tuned semiconductor chip, including: a substrate, a sacrificial layer and a functional layer sequentially stacked on the substrate; the functional layer is used to provide a thermally tuned semiconductor chip to the thermally tuned semiconductor chip.
  • Thermally tuned electrodes transfer heat;
  • a suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a cavity structure penetrating the sacrificial layer and terminating inside the substrate, so that all parts above the cavity structure are formed.
  • the functional layer is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
  • the above scheme also includes:
  • suspension layer stacked on the substrate and between the sacrificial layer and the functional layer
  • the suspension region extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
  • the above scheme also includes:
  • the support layer includes at least a portion located above the cavity structure to support the functional layer located above the cavity structure.
  • the suspension area includes a first part located in the substrate, a second part located in the sacrificial layer and a third part located in the suspension layer, the depth of the first part is greater than the depth of the The sum of the depths of the second part and said third part.
  • the thickness of the suspension layer is greater than the thickness of the sacrificial layer; the depth of the third part of the suspension area located in the suspension layer is greater than the depth of the second part of the suspension area located in the sacrificial layer. depth.
  • the material of the suspension layer is the same as the material of the substrate.
  • the above scheme also includes:
  • Parts of the suspension layer and part of the sacrificial layer that have not been removed are included between any two of at least two of the openings.
  • the above scheme also includes:
  • the upper surface of the suspension area between any two of the at least two openings is a plane, and the plane is coplanar with the upper surface of the suspension layer.
  • the functional layer includes a first sub-functional layer, and the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer for etching the suspension layer to form the suspension region process as an etch barrier.
  • the above scheme also includes:
  • an etch stop layer stacked on the substrate and located between the suspension layer and the support layer, the lower surface of the etch stop layer is in contact with the upper surface of the suspension layer, the etch stop layer The layer acts as an etch stop during the process of etching the suspended layer to form the suspended region.
  • the lower surface of the sacrificial layer is in contact with the upper surface of the substrate.
  • the material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  • Another aspect of the embodiments of the present application provides a method for preparing a thermally tuned semiconductor chip, the method comprising:
  • the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip
  • the suspended area is a cavity structure that runs through the sacrificial layer and ends in the substrate, so that the cavity is located
  • the functional layer above the structure is isolated from the remaining part of the substrate below the cavity structure by the suspended region.
  • forming a sacrificial layer and a functional layer on the substrate in sequence specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, and forming a suspension layer on the suspension layer. the functional layer;
  • the through hole also penetrates the suspension layer
  • Forming the suspension area specifically includes: etching the sacrificial layer, the suspension layer and the substrate; the suspension area specifically extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
  • forming a sacrificial layer and a functional layer on the substrate in sequence specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, and forming a suspension layer on the suspension layer. a support layer, on which a functional layer is formed;
  • the through hole also penetrates the support layer; the support layer at least includes a portion located above the cavity structure to support the functional layer located above the cavity structure.
  • the method further includes:
  • An opening is formed at the bottom end of the mask layer, and the opening exposes part of the sacrificial layer.
  • forming the suspension area specifically includes:
  • the sacrificial layer is etched by a first etching process to expose a part of the upper surface of the substrate and a part of the lower surface of the suspension layer;
  • the substrate and the suspension layer are etched by a second etching process to form the suspension region.
  • the suspension area includes a first part located in the substrate, a second part located in the sacrificial layer and a third part located in the suspension layer, the depth of the first part is greater than the depth of the The sum of the depths of the second part and said third part.
  • the sacrificial layer has a first thickness
  • the suspension layer has a second thickness
  • the second thickness is greater than the first thickness
  • the forming of the suspension region specifically includes: the etching depth of the suspension layer is greater than the first thickness, so that the depth of the formed suspension region in the third part located in the suspension layer is greater than that in the suspension layer. the depth of the second portion within the sacrificial layer.
  • the material of the suspension layer is the same as the material of the substrate.
  • the forming through holes includes forming at least two through holes
  • the suspension layer and the substrate are located between any two of the at least two through holes. Parts are not completely removed.
  • forming a suspension layer on the sacrificial layer and forming the functional layer on the suspension layer specifically includes: after forming the suspension layer, forming the functional layer on the suspension layer The first sub-functional layer, the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer;
  • the forming of the suspension region includes: when the suspension layer is etched, using the first sub-functional layer as an etching barrier layer.
  • forming a suspension layer on the sacrificial layer and forming a support layer on the suspension layer specifically includes: after forming the suspension layer, forming an etching barrier layer on the suspension layer, and the etching The lower surface of the etch stop layer is in contact with the upper surface of the suspension layer, and the support layer is formed on the etch stop layer;
  • the forming of the suspension region includes: when the suspension layer is etched, the etching barrier layer prevents the etching reaction from proceeding toward one side of the support layer.
  • forming the sacrificial layer on the substrate specifically includes: directly forming the sacrificial layer on the substrate, so that the lower surface of the sacrificial layer is in contact with the upper surface of the substrate .
  • the material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  • the thermally tuned semiconductor chip includes: a substrate, and a sacrificial layer and a functional layer sequentially stacked on the substrate; In order to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip; a suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a thread running through the sacrificial layer and terminating inside the substrate A cavity structure, so that the functional layer located above the cavity structure and the remaining part of the substrate below the cavity structure are isolated by the floating region.
  • the suspended region has a greater depth, which includes not only the depth of the part greater than the thickness of the sacrificial layer obtained by penetrating the sacrificial layer, but also the depth of the part located in the substrate, Therefore, the functional layer located on the suspended area can be suspended on the substrate, and has a large air gap between the substrate and the substrate, so as to have better heat insulation and effectively reduce the amount of heat dissipated through the substrate. The situation occurs, so that most of the heat is conducted to the thermal tuning electrodes, which improves the thermal tuning efficiency of the chip.
  • FIG. 1 is a top view of a thermally tuned semiconductor chip provided by an embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
  • FIG. 2 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
  • FIG. 3 is a schematic flowchart of a method for preparing a thermally tuned semiconductor chip provided by an embodiment of the present application
  • FIGS. 4a to 4d are schematic cross-sectional structural views of the thermally tuned semiconductor chip provided in the embodiment of the present application during the preparation process;
  • FIG. 5 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
  • FIG. 6 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
  • FIG. 7 is a schematic flowchart of a method for manufacturing a thermally tuned semiconductor chip according to another embodiment of the present application.
  • FIGS. 8 a to 8 d are schematic cross-sectional structural views of a thermally tuned semiconductor chip in a manufacturing process according to another embodiment of the present application.
  • a ternary material layer such as an InGaAs layer, is pre-grown between the substrate and the functional layer, and then the layer is removed by lateral etching, so that the functional layer of the chip is removed. suspended above the substrate.
  • the ternary material InGaAs that matches the lattice of the substrate, especially the thicker InGaAs material, which can usually only grow several hundreds of nanometers.
  • a lower confinement layer is further provided between the ternary material layer and the substrate, and when the ternary material layer is etched laterally, the lower confinement layer will prevent the corrosion reaction from going downward (ie direction towards the substrate). Therefore, the floating space between the substrate and the functional layer formed by laterally etching the ternary material layer is small.
  • the thicker InGaAs material will greatly reduce the quality of the chip material, especially the quality of the quantum well structure in the active region.
  • the further improvement of chip thermal tuning efficiency and tuning response speed is limited.
  • the thermal power of the chip is constant, the thermal power is easily dissipated through the substrate, and less heat is conducted to the thermal tuning electrodes, resulting in a technical problem of low thermal tuning efficiency of the chip.
  • the embodiments of the present application first provide a thermally tuned semiconductor chip.
  • the thermally tuned semiconductor chip includes: a substrate, and a sacrificial layer and a functional layer sequentially stacked on the substrate; the functional layer is used for transferring heat to a thermally tuned electrode of the thermally tuned semiconductor chip; wherein, A suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a cavity structure penetrating the sacrificial layer and terminating inside the substrate, so that all parts above the cavity structure are formed.
  • the functional layer is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
  • the suspended region has a greater depth, which includes not only the depth of the part greater than the thickness of the sacrificial layer obtained by penetrating the sacrificial layer, but also the depth of the part located in the substrate, Therefore, the functional layer located on the suspended area can be suspended on the substrate, and has a large air gap between the substrate and the substrate, so as to have better heat insulation and effectively reduce the amount of heat dissipated through the substrate. The situation occurs, so that most of the heat is conducted to the thermal tuning electrodes, which improves the thermal tuning efficiency of the chip.
  • thermally tuned semiconductor chip provided by the embodiment of the present application will be described and explained in more detail with reference to FIG. 1 .
  • the thermally tuned semiconductor chip includes: a substrate 101, and a sacrificial layer 102, a suspension layer 103 and a functional layer 105 sequentially stacked on the substrate 101; wherein, on the substrate 101, A suspension region 109 is formed in the sacrificial layer 102 and the suspension layer 103 .
  • the substrate 101 is a semiconductor substrate, and its material may specifically include InP.
  • the thickness of the substrate 101 is, for example, greater than 150 ⁇ m.
  • the substrate includes a top surface on the front side and a bottom surface on the back side opposite the front side; the directions perpendicular to the top and bottom surfaces of the substrate are defined, ignoring the flatness of the top and bottom surfaces for the Z direction.
  • the Z direction is also the stacking direction of each layer structure subsequently deposited on the substrate, or the height direction of the chip.
  • the surface where the top surface and the bottom surface of the substrate are located, or strictly speaking, the central plane in the thickness direction of the substrate, is determined as the substrate plane; the direction parallel to the substrate plane is the direction along the substrate plane; the Z direction is is the direction perpendicular to the substrate plane.
  • Two X and Y directions that are perpendicular to each other are defined in the plane direction of the substrate.
  • At least one of the sacrificial layer 102, the suspension layer 103 and the functional layer 105 may be formed on the substrate 101 by deposition or evaporation.
  • the material of the sacrificial layer 102 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  • the material of the sacrificial layer 102 is different from the material of the substrate 101 .
  • the material of the sacrificial layer 102 is InGaAs; the materials of the substrate 101 and the suspension layer 103 are both InP.
  • the thickness of the sacrificial layer 102 ranges from 100 nm to 400 nm.
  • the lower surface of the sacrificial layer 102 is in contact with the upper surface of the substrate 101 .
  • no other material layers are included between the sacrificial layer 102 and the substrate 101 .
  • the suspension region extends to the inside of the substrate, thereby increasing the overall depth of the suspension region and improving the thermal insulation of the device .
  • the suspension layer 103 is stacked on the substrate 101 and is located between the sacrificial layer 102 and the functional layer 105 .
  • the material of the suspension layer 103 may include InP.
  • the material of the suspension layer 103 may be the same as the material of the substrate 101 ; the material of the suspension layer 103 is different from the material of the sacrificial layer 102 .
  • the thickness of the suspension layer 103 is, for example, greater than the thickness of the sacrificial layer 102 ; the thickness of the suspension layer 103 ranges from 450 nm to 550 nm, for example.
  • the suspension region 109 is a cavity structure extending from below the upper surface of the suspension layer 103, extending through the sacrificial layer 102, and terminating in the interior of the substrate 101, so that the The functional layer 105 above the cavity structure is isolated from the remaining part of the substrate 101 below the cavity structure by the suspension region 109 .
  • the depth of the suspended region 109 may be between 10-15 ⁇ m.
  • the suspension region 109 includes a first part located in the substrate 101, a second part located in the sacrificial layer 102 and a third part located in the suspension layer 103, the The depth of the first portion is greater than the sum of the depths of the second portion and the third portion.
  • the depth of the third portion of the suspension region 109 in the suspension layer 103 is greater than the depth of the second portion of the suspension region 109 in the sacrificial layer 102 .
  • the proportion of the first part in the floating area 109 is the largest; and, specifically, the depth of the first part>the depth of the third part>the depth of the second part.
  • the cross section of the suspension region 109 along the direction perpendicular to the plane of the substrate is hexagonal.
  • the distance of the sidewall of the suspension region 109 in a direction parallel to the plane of the substrate increases from the suspension layer 103 to the sacrificial layer 102 .
  • the distance between the sidewalls of the suspended region 109 in the direction parallel to the plane of the substrate Get the maximum in 101 and decrease down from the maximum position.
  • the thickness of the suspension region is much larger than the thickness of the sacrificial layer, so that in the direction perpendicular to the chip surface (ie, perpendicular to the substrate), there is a large gap between the upper and lower surfaces of the suspension region.
  • the functional layer 105 is used to transfer heat to a thermally tuned electrode (not shown in the figure) of the thermally tuned semiconductor chip.
  • the functional layer 105 may include a first sub-functional layer 1051, and the lower surface of the first sub-functional layer 1051 is in contact with the upper surface of the suspension layer 103 for etching the suspension layer 103 to form the
  • the suspended region 109 is used as an etching stopper in the process.
  • the material of the first sub-functional layer 1051 includes at least one of the following: InGaAs, InGaAsP, AlGaInAs; in other words, the underlying structure in the functional layer 105 in contact with the upper surface of the suspension layer 103 is InGaAs, InGaAsP, and/ or AlGaInAs material layer.
  • the material of the first sub-functional layer 1051 may be the same as the material of the sacrificial layer 102 .
  • the material of the first sub-functional layer 1051 is different from the material of the suspension layer 103; and, as an etching stopper for etching the suspension layer 103, the first sub-functional layer 1051 and the suspension layer 103 There should be a large etching selectivity ratio between etching processes.
  • the thickness of the first sub-functional layer 1051 is smaller than the thickness of the suspension layer 103 .
  • the area of the first sub-functional layer 1051 may be greater than or equal to the area of the suspension layer 103, so that the first sub-functional layer 1051 completely covers the suspension layer 103.
  • the first sub-functional layer 1051 is a quantum well layer.
  • the functional layer 105 may include a lower waveguide layer (such as InGaAsP), a waveguide core layer (such as InGaAsP), and an upper waveguide layer (such as InGaAsP) along the substrate 101 from bottom to top.
  • the material is, for example, InGaAsP
  • the functional layer 105 may further include a cladding layer (the material is, for example, InP) located on the upper waveguide layer. It may also include: an electrode contact layer (the material is, for example, InGaAs).
  • the lower waveguide layer is located on the first sub-functional layer 1051 .
  • the lower waveguide layer may only be located on a part of the first sub-functional layer 1051; in other words, the functional layer 105 only includes the first sub-functional layer 1051 in a part of the region, and includes the first sub-functional layer 1051 in another part of the region.
  • the thermally tuned semiconductor chip may further include vias 107 in communication with the floating region 109 .
  • the through hole 107 penetrates the functional layer 105 and the suspension layer 103 ; in the embodiment where the functional layer 105 includes the first sub-functional layer 1051 , it also penetrates the first sub-functional layer 1051 .
  • a mask layer 106 may also be covered on the sidewalls of the through holes 107 .
  • the mask layer 106 is used to protect the functional layer 105 and the suspension layer 103 within the mask layer 106 during the etching process of forming the suspension region.
  • the bottom end of the mask layer 106 has an opening 108 ; the opening 108 penetrates the mask layer 106 and communicates with the through hole 107 and the suspension area 109 .
  • the mask layer 106 may also cover the functional layer 105, which is not specifically limited here.
  • FIG. 1 shows the case where the opening size of the opening 108 is smaller than the opening size of the through hole 107; of course, the opening size of the opening 108 can also be equal to the opening size of the through hole 107, or more specifically It is equal to the opening size of the through hole 107 minus the thickness of the two sidewalls of the mask layer 106 .
  • the opening shapes of the through holes 107 and the openings 108 may be circular, square, diamond or other shapes, which can be designed according to actual conditions, which are not specifically limited herein.
  • the number of the through holes/the openings corresponding to one floating area may be two or more.
  • the number of the through holes 107/the openings 108 corresponding to one floating area 109 is specifically two; and the two through holes 107/the openings 108 may be They are arranged symmetrically on the suspension area 109 , specifically, they may be arranged symmetrically on the left and right sides along the central axis of the suspension area 109 .
  • the unremoved part of the suspension layer 103 may be included, and the unremoved part of the sacrificial layer 102 may also be included;
  • the top of the region 109 at least includes a first portion and a second portion exposing the functional layer 105 (specifically, the first sub-functional layer 1051 ), and may also include a portion located on the surface along a plane parallel to the substrate 101 .
  • the thermally tuned semiconductor chip may have a first portion of the sacrificial layer 102 and a first portion of the suspension layer 103 on one side of the suspension region 109 , and a second portion of the sacrificial layer 102 and a second portion of the suspension layer on the other side of the suspension region 109 layer 103 and the third part of the sacrificial layer 102 and the third part of the suspension layer 103 located in the suspension area 109; it should be understood that the sacrificial layer 102 and the suspension layer 103 of the above three parts are connected by areas not shown in the figure. In this way, the mechanical structural strength of the entire suspension area 109 is increased.
  • the thermally tuned semiconductor chip may further include: at least two openings communicated with the suspension area, and the suspension area is implemented by performing a process through the at least two openings. An etching process is performed; any two of the at least two openings include a part of the suspension layer that has not been removed and a part of the sacrificial layer that has not been removed.
  • a cross section of the unremoved part of the suspension layer and the unremoved part of the sacrificial layer in a direction perpendicular to the substrate is an inverted trapezoid.
  • the substrate 101 , the sacrificial layer 102 and the suspension layer 103 are arranged along the circumference of the suspension area 109 and constitute the side walls and bottom walls of the suspension area 109 , so that the functional layer 105 is suspended in the suspension area 109 . on the substrate 101 . Since there is a large air isolation interval between the functional layer 105 and the substrate 101, the heat dissipated from the substrate 101 can be reduced, thereby improving the thermal tuning efficiency of the thermally tuned semiconductor chip.
  • FIG. 2 is a top view of a thermally tuned semiconductor chip according to another embodiment of the present application and a cross-sectional view along two dotted lines in the top view.
  • the thermally tuned semiconductor chip includes a plurality of suspension regions 109 .
  • the thermally tuned semiconductor chip includes multiple groups of through holes (107, 107' in the figure) and openings (108, 108' in the figure). holes are explained.
  • the groups of through holes communicating with the plurality of suspension regions 109 may be arranged at equal intervals or at unequal intervals, depending on the actual situation.
  • a plurality of the suspension regions 109 may be distributed in an array, so that multiple groups of through holes/multiple groups of openings may also be distributed in an array.
  • the two through holes in the same row are connected to the corresponding suspension areas of the row
  • the two through holes of the other row are connected to the corresponding suspension areas of the row
  • the sacrificial layer 102 is between the through holes of adjacent rows.
  • the suspension layer 103 and the functional layer 105 are continuous in the direction (X direction) extending laterally of each layer, and the sacrificial layer 102, the suspension layer 103 and the functional layer 105 between the via holes in the same row are extending longitudinally along each layer It is continuous in the direction (Y direction), which ensures that the substrate 101, the sacrificial layer 102, and the suspension layer 103 located in the thermally tuned semiconductor chip are only hollowed out at the positions corresponding to the suspension area 109, and the suspension area 109 is circumferentially
  • the substrate 101, the sacrificial layer 102, and the suspension layer 103 are continuous in the extension direction along the substrate plane.
  • the suspended region 109 is continuous along the extension direction of the surface of the thermally tuned semiconductor chip, and is limited to the region near the through hole and the opening; the unetched structural layer (mask) in the region layer 106 , functional layer 105 , the unremoved part of the suspended layer 103 , sacrificial layer 102 and substrate 101 ) are connected to the out-of-area structure to ensure that the functional layers 105 can be connected together and then suspended on the substrate 101 .
  • the unetched structural layer (mask) in the region layer 106 , functional layer 105 , the unremoved part of the suspended layer 103 , sacrificial layer 102 and substrate 101 are connected to the out-of-area structure to ensure that the functional layers 105 can be connected together and then suspended on the substrate 101 .
  • the suspension regions corresponding to the through holes located in different rows may also communicate.
  • the entirety of the formed connected suspension areas can be understood as including a plurality of sub-suspended areas.
  • the part of the suspension layer that has not been removed may be included between two adjacent sub-suspension areas; in addition, the suspension layer that has not been removed may also be included Part of the sacrificial layer.
  • the top of the suspended region at least includes the first part and the third part exposing the functional layer (specifically, the first sub-functional layer)
  • a part of a suspension layer and a part of a sacrificial layer between the first part and the third part may also be included on a plane parallel to the substrate.
  • part of the suspension layer and part of the sacrificial layer located between the first part and the third part may be called "cantilever", and the cantilever and the unremoved part located between the two through holes in the X direction
  • the suspension layer can also enhance the mechanical strength.
  • the width of the floating region in the first direction (X direction) parallel to the substrate plane is smaller than the width along the second direction (Y direction) parallel to the substrate plane, and the second direction is perpendicular to the first direction direction.
  • the embodiment of the present application also provides a method for preparing a thermally tuned semiconductor chip; for details, please refer to FIG. 3 . As shown in Figure 3, the method includes the following steps:
  • Step 301 providing a substrate, and forming a sacrificial layer and a functional layer on the substrate in sequence; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
  • Step 302 forming a through hole, the through hole passing through the functional layer and exposing part of the sacrificial layer;
  • Step 303 Etch the sacrificial layer and the substrate to form a suspended area; the suspended area is a cavity structure that runs through the sacrificial layer and terminates inside the substrate, so that the The functional layer above the cavity structure is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
  • FIG. 1 the thermally tuned semiconductor chip and its manufacturing method shown in FIG. 1 will be further described in detail with reference to the schematic cross-sectional views of the structure in the manufacturing process of the thermally tuned semiconductor chip in FIGS. 4 a to 4 d .
  • a substrate 101 is provided on which a sacrificial layer 102 and a functional layer 105 are sequentially formed.
  • forming the sacrificial layer 102 on the substrate 101 specifically includes: directly forming the sacrificial layer 102 on the substrate 101, so that the lower surface of the sacrificial layer 102 and The upper surface of the substrate 101 is in contact. In other words, no other material layers are included between the sacrificial layer 102 and the substrate 101 .
  • the subsequent process of etching the substrate using the second etching process is easier to implement, and the formed floating region extends to all the Inside the substrate, the overall depth of the suspension region is increased, and the thermal insulation of the device is improved.
  • sequentially forming a sacrificial layer 102 and a functional layer 105 on the substrate 101 includes: forming the sacrificial layer 102 on the substrate 101 , and forming a suspension layer on the sacrificial layer 102 layer 103 , and the functional layer 105 is formed on the suspension layer 103 .
  • the sacrificial layer 102 , the suspension layer 103 and the functional layer 105 are sequentially formed on the substrate 101 .
  • forming the suspension layer 103 on the sacrificial layer 102 and forming the functional layer 105 on the suspension layer 103 specifically includes: after the suspension layer 103 is formed, on the A first sub-functional layer 1051 of the functional layer 105 is formed on the suspension layer 103, and the lower surface of the first sub-functional layer 1051 is in contact with the upper surface of the suspension layer 103; on the first sub-functional layer 1051 The functional layer 105 is formed; in this way, in the subsequent step of forming the suspension region, when the suspension layer 103 is etched, the first sub-functional layer 1051 is used as an etching barrier layer.
  • a sacrificial layer 102 is firstly formed on the substrate 101.
  • the material of the sacrificial layer 102 is, for example, InGaAsP, and the thickness is, for example, 0.02 ⁇ m+/0.05 ⁇ m;
  • the material of the suspension layer 103 is, for example, InP, and the thickness is, for example, 1 ⁇ m+/0.05 ⁇ m;
  • the material of the first sub-functional layer 1051 is, for example, InGaAs, and the thickness is, for example, 0.2 ⁇ m+/0.05 ⁇ m;
  • the material of the lower waveguide layer is, for example, InGaAsP, and the thickness is, for example, 0.1 ⁇ m+/0.05 ⁇ m;
  • the material of the waveguide core layer is, for example
  • the above-mentioned layers may be formed on the substrate 101 by deposition or evaporation. After the epitaxy of the above-mentioned layers is completed, the floating region 109 can be fabricated.
  • a patterned first mask layer 110 can be formed on the above-mentioned layers, and the first mask layer 110 defines the positions where the through holes 107 are subsequently formed.
  • the patterning of the first mask layer 110 can be achieved by photolithography.
  • a through hole 107 is formed, the through hole 107 penetrates the functional layer 105 and exposes a part of the sacrificial layer 102 .
  • a through hole 107 is formed through the functional layer 105 and the suspension layer 103, and the through hole 107 exposes a part of the sacrificial layer 102; that is, the through hole 107 also penetrates through the Suspended layer 103 .
  • etching holes ie, through holes 107 ) extending in the direction close to the substrate 101 are formed on the left and right sides of the thermally tuned semiconductor chip, wherein the etching holes are formed along the direction close to the substrate 101 .
  • the substrate 101 penetrates through the mask 106 , the functional layer 105 and the suspension layer 103 in sequence.
  • the through hole 107 may also pass through part of the sacrificial layer 102; that is, the through hole 107 may penetrate deep into the sacrificial layer 102 (this is not shown in the figure).
  • a corresponding etching hole pattern is defined on the surface of the thermally tuned semiconductor chip by means of photolithography, and etching is performed on the left and right sides of the thermally tuned semiconductor chip based on the defined etching hole pattern, such as reactive ion (RIE) etching. etching, thereby forming etching holes extending in a direction close to the substrate on the left and right sides of the thermally tuned semiconductor chip.
  • the opening of the etching hole may be a square, a circle, or other shapes.
  • the sacrificial layer 102 is etched to form a portion of the suspended region, that is, the second portion.
  • the method further includes: forming a mask layer 106, the mask layer 106 at least covers the Sidewall of the through hole 107 .
  • the mask layer 106 may also cover the top surface of the thermally tuned semiconductor chip, for example, the functional layer 105 .
  • an opening 108 is formed at the bottom end of the mask layer 106 , and the opening 108 exposes a part of the sacrificial layer 102 .
  • the opening 108 is located in the through hole 107 .
  • Fig. 4c shows the case where the opening size of the opening 108 is smaller than the opening size of the through hole 107; of course, the opening size of the opening 108 can also be equal to the opening size of the through hole 107, or more specifically It is equal to the opening size of the through hole 107 minus the thickness of the two sidewalls of the mask layer 106 .
  • etching holes ie, openings 108 ) extending in the direction close to the substrate are formed on the left and right sides of the thermally tuned semiconductor chip, and the etching holes penetrate in the direction close to the substrate the mask.
  • the first mask layer 110 is removed by using HF acid etching solution, and the mask layer 106 (also referred to as the second mask layer) is regrown.
  • a corresponding etching hole pattern is defined on the surface of the thermally tuned semiconductor chip by means of photolithography, and RIE etching is performed on the left and right sides of the thermally tuned semiconductor chip based on the defined etching hole pattern, so that the Etched holes extending in the direction close to the substrate are formed on the left and right sides.
  • the opening of the etching hole may be a square, a circle, or other shapes.
  • the sacrificial layer 102 is etched by a first etching process to expose a part of the upper surface of the substrate 101 and a part of the lower surface of the suspension layer 103 .
  • the first etching process may be a wet etching process.
  • the sacrificial layer 102 may be etched with a first etching solution.
  • the composition of the sacrificial layer 102 includes InGaAs material.
  • a portion of the sacrificial layer 102 is removed using a first etching solution, which is injected into the thermally tuned semiconductor chip through the opening 108 .
  • the first etching solution performs selective lateral etching on the InGaAs material in the sacrificial layer 102, so that part of the sacrificial layer 102 is removed.
  • the first etching solution may be a sulfuric acid-based etching solution, that is, the etching solution used in the first etching process may include a sulfuric acid-based solution; the sulfuric acid-based etching solution selectively etches the InGaAs material, while the InP material is There is no corrosion effect. Therefore, in the embodiment in which the substrate 101 and the suspension layer 103 are InP, the substrate 101 and the suspension layer 103 can remain in a non-etched state.
  • the size of the opening formed after the sacrificial layer 102 is etched is larger than the size of the opening of the through hole 107 .
  • the forming of the through holes includes forming at least two through holes; the etched regions corresponding to the adjacent two through holes 107 are not connected, that is, between the two adjacent through holes 107 , unremoved sacrificial parts are also included. layer 102 .
  • the suspension layer 103 and the substrate 101 are further etched to finally form the suspension region 109 .
  • the substrate is etched by the second etching process to form the suspension region.
  • the method further includes etching the suspension layer by using a second etching process; in other words, forming the suspension region specifically includes: etching the sacrificial layer, the The suspension layer and the substrate are etched; thus, the suspension region is formed specifically from below the upper surface of the suspension layer, extending through the sacrificial layer, and terminating inside the substrate.
  • the second etching process may be a wet etching process.
  • the suspension layer 103 and the substrate 101 can be etched with a second etching solution.
  • the second etching solution is injected into the thermally tuned semiconductor chip through the left and right etching holes and the channels connecting the etching holes, and the second etching solution selectively corrodes the InP material in the substrate and the suspended layer, A portion of the substrate and the suspended layer are removed, thereby forming a suspended region.
  • the second etching solution may be a hydrochloric acid-based etching solution, that is, the etching solution used in the second etching process may include a hydrochloric acid-based solution; since the hydrochloric acid-based solution cannot corrode the InGaAsP material, this step of etching will stop at Below the first sub-functional layer, the original layers of the thermally tuned semiconductor chip are protected from corrosion. At the same time, the thickness of the substrate layer is much larger than that of other layers, so controlling the etching time can ensure the stability of the structure of the thermally tuned semiconductor chip.
  • the second etching solution used to corrode the InP material has the characteristic of being able to corrode to a fixed corrosion angle.
  • the suspension region 109 is formed as a cavity structure extending from below the upper surface of the suspension layer 103, extending through the sacrificial layer 102, and terminating in the interior of the substrate 101, so that the cavity is located in the cavity.
  • the functional layer 105 above the structure is isolated from the remaining part of the substrate 101 below the cavity structure by the suspended region 109 .
  • the forming of the sacrificial layer, the suspension layer and the functional layer specifically includes: forming a sacrificial layer with a first thickness, and forming a suspension layer with a second thickness on the sacrificial layer, thus, the The sacrificial layer has a first thickness, and the suspension layer has a second thickness; the second thickness is greater than the first thickness; correspondingly, forming the suspension region specifically includes: the etching depth of the suspension layer is greater than The first thickness is such that the depth of the formed suspended region in the third portion located in the suspended layer is greater than the depth of the second portion located in the sacrificial layer.
  • part of the sacrificial layer 102 is first etched to define the pattern of the suspension region 109 in advance, and then a second etching solution is injected according to the predefined pattern of the suspension region 109 , and then part of the substrate 101 and the suspension layer 103 are etched to form Complete suspension area 109.
  • part of the sacrificial layer 102 is removed to form an etching channel, the contact area between the second etching solution and the substrate 101 and the suspension layer 103 is increased, the etching rate is increased, and the fabrication time is shortened.
  • a thicker thermal isolation layer can be formed, the thickness of which can be determined by the first sub-functional layer 1051 and the etching time It is decided that it is much larger than the thickness produced by the current commonly used method. Therefore, by the method, a thicker thermal isolation layer can be obtained without the influence of the thicker InGaAs layer on the growth quality of the thermally tuned semiconductor chip.
  • the depth of the suspension region 109 determines the thermal isolation effect of the thermally tuned semiconductor chip.
  • a deeper suspension region 109 can improve the thermal isolation effect of the thermally tuned semiconductor chip, improve the thermal tuning efficiency and thermal conductivity of the thermally tuned semiconductor chip.
  • the tuning response speed effectively solves the problem of low thermal tuning efficiency of the current thermal tuning semiconductor chip and positioning.
  • the etching hole is first defined on the surface of the thermally tuned semiconductor chip, the etching hole is square and the size is 5 ⁇ m*10 ⁇ m, and then the etching hole material is etched using an inductively coupled plasma (ICP) etching machine. The depth is between 3.00 ⁇ m and 3.02 ⁇ m.
  • ICP inductively coupled plasma
  • the suspended layer and the substrate form a suspended region.
  • the rest of the process of thermally tuning the semiconductor chip can be performed according to normal steps, which will not be repeated here.
  • the sacrificial layer 102 that has not been removed may be included between the two adjacent through holes 107, and then in the step of etching the suspension layer , the suspended layer that has not been removed may also be included between the two adjacent through holes 107; in other words, in the step of etching the sacrificial layer, the suspended layer and the substrate, the suspended layer The layer and the portion of the sacrificial layer located between any two of the at least two of the through holes are not completely removed.
  • the thermal tuning efficiency of the material is basically not affected by the material band gap
  • a material with a higher material band gap can be used as the passive waveguide region used for wavelength tuning to further reduce passive
  • the absorption loss of the material in the waveguide region reduces the chip threshold and reduces the laser linewidth.
  • the waveguide layer and the substrate are thermally isolated by air. Under the condition of constant thermal power of the chip, the thermal tuning efficiency and the tuning response speed are greatly improved.
  • FIG. 5 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view.
  • this embodiment specifically introduces the case where the thermally tuned semiconductor chip further includes a support layer between the suspension layer and the functional layer.
  • the thermally tuned semiconductor chip includes: a substrate 201, and a sacrificial layer 202, a suspension layer 203, a support layer 204 and a functional layer 205 stacked on the substrate 201 in sequence;
  • a suspension region 209 is formed in the substrate 201 , the sacrificial layer 202 and the suspension layer 203 .
  • the substrate 201 is a semiconductor substrate, and its material may specifically include InP.
  • the thickness of the substrate 201 is, for example, greater than 150 ⁇ m.
  • the substrate includes a top surface on the front side and a bottom surface on the back side opposite the front side; the directions perpendicular to the top and bottom surfaces of the substrate are defined, ignoring the flatness of the top and bottom surfaces for the Z direction.
  • the Z direction is also the stacking direction of each layer structure subsequently deposited on the substrate, or the height direction of the chip.
  • the surface where the top surface and the bottom surface of the substrate are located, or strictly speaking, the central plane in the thickness direction of the substrate, is determined as the substrate plane; the direction parallel to the substrate plane is the direction along the substrate plane; the Z direction is is the direction perpendicular to the substrate plane.
  • Two X and Y directions that are perpendicular to each other are defined in the plane direction of the substrate.
  • At least one of the sacrificial layer 202 , the suspension layer 203 , the support layer 204 and the functional layer 205 may be formed on the substrate 201 by deposition or evaporation.
  • the material of the sacrificial layer 202 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  • the material of the sacrificial layer 202 is different from the material of the substrate 201 .
  • the material of the sacrificial layer 202 is InGaAs; the material of the substrate 201 and the suspension layer 203 are both InP.
  • the thickness of the sacrificial layer 202 ranges from 100 nm to 400 nm.
  • the lower surface of the sacrificial layer 202 is in contact with the upper surface of the substrate 201 .
  • no other material layers are included between the sacrificial layer 202 and the substrate 201 .
  • the suspension region extends to the inside of the substrate, thereby increasing the overall depth of the suspension region and improving the thermal insulation of the device .
  • the material of the suspension layer 203 may include InP.
  • the material of the suspension layer 203 may be the same as the material of the substrate 201 ; the material of the suspension layer 203 is different from the material of the sacrificial layer 202 .
  • the thickness of the suspension layer 203 is, for example, greater than the thickness of the sacrificial layer 202 ; the thickness of the suspension layer 203 ranges from 200 nm to 500 nm, for example, and specifically ranges from 450 nm to 550 nm.
  • the suspension region 209 is a cavity structure extending from below the upper surface of the suspension layer 203, extending through the sacrificial layer 202, and terminating in the interior of the substrate 201, so that the The functional layer 205 above the cavity structure is isolated from the remaining part of the substrate 201 below the cavity structure by the suspension region 209 .
  • the depth of the suspended region 209 may be between 10-15 ⁇ m.
  • the suspended region 209 includes a first portion within the substrate 201, a second portion within the sacrificial layer 202, and a third portion within the suspended layer 203, the The depth of the first portion is greater than the sum of the depths of the second portion and the third portion.
  • the depth of the third portion of the suspension region 209 in the suspension layer 203 is greater than the depth of the second portion of the suspension region 209 in the sacrificial layer 202 .
  • the proportion of the first part in the floating area 209 is the largest; and, specifically, the depth of the first part>the depth of the third part>the depth of the second part.
  • the cross section of the suspension area 209 along the direction perpendicular to the plane of the substrate is hexagonal.
  • the distance of the sidewall of the suspension region 209 in a direction parallel to the plane of the substrate increases from the suspension layer 203 to the sacrificial layer 202 .
  • the distance between the sidewalls of the suspended region 209 in a direction parallel to the plane of the substrate Get the maximum in 201 and decrease down from the maximum position.
  • the thickness of the suspension region is much larger than the thickness of the sacrificial layer, so that in the direction perpendicular to the chip surface (ie, perpendicular to the substrate), there is a large gap between the upper and lower surfaces of the suspension region.
  • the material of the support layer 204 may be the same as the material of the substrate 201 .
  • the material of the support layer 204 includes InP.
  • the thickness of the support layer may be greater than that of the sacrificial layer.
  • the thickness of the support layer may be approximately the same as the thickness of the suspension layer; in an actual process, the thickness of the support layer ranges from 200 nm to 500 nm, for example.
  • the thermally tuned semiconductor chip further includes: an etch stop layer 2041 stacked on the substrate 201 and located between the suspension layer 203 and the support layer 204 , the lower surface of the etch stop layer 2041 is in contact with the upper surface of the suspension layer 203 , and the etch stop layer 2041 plays an etched role in the process of etching the suspension layer 203 to form the suspension region 209 Erosion blocking effect.
  • the material of the etch barrier layer should be different from the material of the support layer.
  • the material of the etch barrier layer may be the same as the material of the sacrificial layer.
  • the material of the etching barrier layer may be InGaAsP or AlGaInAs.
  • the functional layer 205 is used to transfer heat to a thermally tuned electrode (not shown in the figure) of the thermally tuned semiconductor chip.
  • the functional layer 205 may include a first sub-functional layer 2051 .
  • the material of the first sub-functional layer 2051 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  • the first sub-functional layer 2051 is a quantum well layer.
  • the specific structure of the functional layer 205 depends on the actual scene, and may be one of the following: a laser layered structure, a detector layered structure, a modulator layered structure or a passive waveguide layered structure.
  • the functional layer 205 may include a lower waveguide layer (such as InGaAsP) along the substrate 201 from bottom to top, a waveguide core layer (such as InGaAsP), and an upper waveguide layer ( The material is, for example, InGaAsP); the functional layer 205 may further include a cladding layer (the material is, for example, InP) located on the upper waveguide layer. It may also include: an electrode contact layer (the material is, for example, InGaAs).
  • the lower waveguide layer is located on the first sub-functional layer 2051 .
  • the lower waveguide layer may only be located on a part of the first sub-functional layer 2051; in other words, the functional layer 205 only includes the first sub-functional layer 2051 in a part of the region, and includes the first sub-functional layer 2051 in another part of the region.
  • the semiconductor chip may further include through holes 207 communicating with the floating region 209 .
  • the through hole 207 penetrates the functional layer 205 and the suspension layer 203 ; in the embodiment where the functional layer 205 includes the first sub-functional layer 2051 , it also penetrates the first sub-functional layer 2051 .
  • a mask layer 206 may also be covered on the sidewalls of the through holes 207 .
  • the mask layer 206 is used to protect the functional layer 205 and the suspension layer 203 within the mask layer 206 during the etching process for forming the suspension region.
  • the bottom end of the mask layer 206 has an opening 208 ; the opening 208 penetrates the mask layer 206 and communicates with the through hole 207 and the suspension area 209 .
  • the mask layer 206 may also cover the functional layer 205, which is not specifically limited here.
  • FIG. 5 shows the case where the opening size of the opening 208 is smaller than the opening size of the through hole 207; of course, the opening size of the opening 208 can also be equal to the opening size of the through hole 207, or more specifically It is equal to the opening size of the through hole 207 minus the thickness of the two sidewalls of the mask layer 206 .
  • the opening shape of the through hole 207 and the opening 208 may be a circle, a square, a diamond or other shapes, which can be designed according to the actual situation, which is not specifically limited here.
  • the number of the through holes/the openings corresponding to one floating area may be two or more.
  • the number of the through holes 207/the openings 208 corresponding to one floating area 209 is specifically two; and the two through holes 207/the openings 208 may be They are arranged symmetrically on the suspension area 209 , specifically, they may be arranged symmetrically on the left and right sides along the central axis of the suspension area 209 .
  • the suspension area 209 is between any two of the at least two openings (as shown in FIG.
  • the upper surface between the openings 208 ) is a plane, and the plane is coplanar with the upper surface of the suspension layer 203 .
  • the substrate 201, the sacrificial layer 202 and the suspension layer 203 are arranged along the circumference of the suspension area 209, and constitute the side wall and bottom wall of the suspension area 209, so that the functional layer 205 is suspended in the suspension area 209. on the substrate 201 . Since there is a large air isolation interval between the functional layer 205 and the substrate 201, the heat dissipated from the substrate 201 can be reduced, thereby improving the thermal tuning efficiency of the semiconductor chip.
  • the support layer 204 includes at least a portion above the cavity structure (ie, the suspension region 209 ) to support the functional layer 205 above the cavity structure, thereby enhancing the thermal tuning
  • the mechanical strength of the semiconductor chip is improved, and the etching process for forming the floating region 209 is easier to implement, thereby improving the product yield.
  • FIG. 6 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application, and a cross-sectional view along two dotted lines in the top view.
  • the present embodiment specifically introduces the case where the semiconductor chip includes a plurality of floating regions 209 .
  • the semiconductor chip includes multiple groups of through holes (207, 207' in the figure) and openings (208, 208' in the figure); since the openings correspond to the through holes one-to-one, only the through holes are used below. illustrate.
  • the groups of through holes communicating with the plurality of suspension regions 209 may be arranged at equal intervals or at unequal intervals, depending on the actual situation.
  • a plurality of the suspension regions 209 may be distributed in an array, so that groups of through holes/groups of openings may also be distributed in an array.
  • the two through holes in the same row are connected to the corresponding suspension area of the row
  • the two through holes of the other row are connected to the corresponding suspension area of the row
  • the sacrificial layer 202 is between the through holes of adjacent rows.
  • the suspension layer 203, the support layer 204 and the functional layer 205 are continuous in the direction (X direction) extending laterally along each layer, the sacrificial layer 202, the suspension layer 203, the support layer 204 and the function between the via holes in the same row
  • the layer 205 is continuous in the longitudinal extension direction (Y direction) of each layer, which ensures that the substrate 201, the sacrificial layer 202, and the suspension layer 203 located in the semiconductor chip are only hollowed out at the positions corresponding to the suspension area 209, and
  • the substrate 201 , the sacrificial layer 202 and the suspension layer 203 in the circumferential direction of the suspension region 209 are continuous in the extension direction along the substrate plane.
  • the suspended area 209 is continuous in the extension direction along the surface of the semiconductor chip, and is limited to the area near the through hole and the opening; the structural layer (mask layer 206) that is not etched in the area , the functional layer 205, the support layer 204, the unremoved part of the suspended layer 203, the sacrificial layer 202 and the substrate 201) are connected to the structure outside the area, so as to ensure that the functional layer 205 can be connected together, and then suspended on the substrate 201 .
  • the structural layer mask layer 206 that is not etched in the area , the functional layer 205, the support layer 204, the unremoved part of the suspended layer 203, the sacrificial layer 202 and the substrate 201
  • the suspension regions corresponding to the through holes located in different rows may also communicate.
  • the entirety of the formed connected suspension areas can be understood as including a plurality of sub-suspended areas.
  • the embodiment of the present application also provides a method for preparing a thermally tuned semiconductor chip; for details, please refer to FIG. 7 . As shown in Figure 7, the method includes the following steps:
  • Step 401 providing a substrate, and forming a sacrificial layer, a suspension layer, a support layer and a functional layer in sequence on the substrate; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
  • Step 402 forming a through hole, the through hole passing through the functional layer, the support layer and the suspension layer and exposing part of the sacrificial layer;
  • Step 403 Etch the sacrificial layer, the suspension layer, and the substrate to form a suspension area; the suspension area extends through the sacrificial layer from below the upper surface of the suspension layer, and a cavity structure terminating inside the substrate such that the functional layer above the cavity structure is isolated from the remaining portion of the substrate below the cavity structure by the suspension region; the support The layer includes at least a portion overlying the cavity structure to support the functional layer overlying the cavity structure.
  • thermally tuned semiconductor chip and its manufacturing method shown in FIG. 5 will be further described in detail with reference to the schematic cross-sectional views of the structure in the manufacturing process of the thermally tuned semiconductor chip in FIGS. 8 a to 8 d .
  • a substrate 201 is provided, on which a sacrificial layer 202, a suspension layer 203, a support layer 204 and a functional layer 205 are formed in sequence; the functional layer 205 is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip .
  • the material of the support layer may be the same as that of the substrate.
  • the material of the support layer includes InP.
  • the thickness of the support layer may be greater than that of the sacrificial layer.
  • the thickness of the support layer may be approximately the same as the thickness of the suspension layer; in an actual process, the thickness of the support layer ranges from 200 nm to 500 nm, for example.
  • forming the sacrificial layer 202 on the substrate 201 specifically includes: directly forming the sacrificial layer 202 on the substrate 201, so that the lower surface of the sacrificial layer 202 and The upper surface of the substrate 201 is in contact. In other words, no other material layers are included between the sacrificial layer 202 and the substrate 201 . In this way, in this embodiment, by omitting the lower confinement layer in the related art, the subsequent process of etching the substrate by the second etching process is easier to implement, and the formed floating region extends to all the Inside the substrate, the overall depth of the suspension region is increased, and the thermal insulation of the device is improved.
  • forming the sacrificial layer, the suspension layer, the support layer and the functional layer in sequence may specifically include: after forming the suspension layer 203, forming an etching barrier layer 2041 on the suspension layer 203, The lower surface of the etch stop layer 2041 is in contact with the upper surface of the suspension layer 203 , and the support layer 204 is formed on the etch stop layer 2041 .
  • the material of the etch barrier layer should be different from the material of the support layer.
  • the material of the etch barrier layer may be the same as the material of the sacrificial layer.
  • the material of the etching barrier layer may be InGaAsP or AlGaInAs.
  • a sacrificial layer 202 is firstly formed on the substrate 201.
  • the material of the sacrificial layer 202 is, for example, InGaAsP, and the thickness is, for example, 0.02 ⁇ m+/0.05 ⁇ m;
  • the material of 203 is, for example, InP, and the thickness is, for example, 1 ⁇ m+/0.05 ⁇ m;
  • the material of the etching barrier layer 2041 is, for example, InGaAs, and the thickness is, for example, 0.2 ⁇ m+/0.05 ⁇ m;
  • the layer 205 includes, for example, a first sub-functional layer 2051 and a lower waveguide layer, a waveguide core layer, a waveguide core layer, a cladding layer and an electrode contact layer located on the first sub-functional layer 2051;
  • the material of the first sub-functional layer 2051 is, for example, InGaAs, the thickness is for example 0.2 ⁇
  • the above-mentioned layers can be formed on the substrate 201 by deposition or evaporation. After the epitaxy of the above-mentioned layers is completed, the floating region 209 can be fabricated.
  • a patterned first mask layer 210 may be formed on the above-mentioned layers, and the first mask layer 210 defines the positions where the through holes 207 are subsequently formed.
  • the patterning of the first mask layer 210 can be achieved by photolithography.
  • a through hole 207 is formed, the through hole 207 penetrates the functional layer 205, the support layer 204 and the suspension layer 203 and exposes a part of the sacrificial layer 202.
  • the through hole 207 also penetrates the etch stop layer 2041 .
  • etching holes ie, through holes 207 ) extending in the direction close to the substrate 201 are formed on the left and right sides of the semiconductor chip, wherein the etching holes are formed along the direction close to the substrate
  • the mask 206 , the functional layer 205 , the support layer 204 and the suspension layer 203 are sequentially penetrated in the direction 201 .
  • the through hole 207 may also pass through part of the sacrificial layer 202; that is, the through hole 207 may penetrate deep into the sacrificial layer 202 (this is not shown in the figure).
  • a corresponding etching hole pattern is defined on the surface of the semiconductor chip by means of photolithography, and etching is performed on the left and right sides of the semiconductor chip based on the defined etching hole pattern, such as reactive ion (RIE) etching, so as to Etching holes extending in a direction close to the substrate are formed on the left and right sides of the semiconductor chip.
  • RIE reactive ion
  • the opening of the etching hole may be a square, a circle, or other shapes.
  • the sacrificial layer 202 is etched to form a portion of the suspended region, that is, the second portion.
  • the method further includes: forming a mask layer 206, the mask layer
  • the layer 206 covers at least the sidewalls of the through holes 207 .
  • the mask layer 206 may also cover the top surface of the semiconductor chip, for example, the functional layer 205 .
  • an opening 208 is formed at the bottom end of the mask layer 206 , and the opening 208 exposes a part of the sacrificial layer 202 .
  • the opening 208 is located in the through hole 207 .
  • Fig. 8c shows the case where the opening size of the opening 208 is smaller than the opening size of the through hole 207; of course, the opening size of the opening 208 can also be equal to the opening size of the through hole 207, or more specifically It is equal to the opening size of the through hole 207 minus the thickness of the two sidewalls of the mask layer 206 .
  • etching holes ie, openings 208 extending in a direction close to the substrate are formed on the left and right sides of the semiconductor chip, and the etching holes penetrate the substrate in a direction close to the substrate.
  • the first mask layer 210 is removed by using HF acid etching solution, and the mask layer 206 (also referred to as the second mask layer) is re-grown.
  • Corresponding etching hole patterns are defined on the surface of the semiconductor chip by means of photolithography, and RIE etching is performed on the left and right sides of the semiconductor chip based on the defined etching hole patterns, so that the left and right sides of the semiconductor chip are formed along the Etched holes extending in the direction of the substrate.
  • the opening of the etching hole may be a square, a circle, or other shapes.
  • the sacrificial layer 202 is etched by a first etching process to expose a part of the upper surface of the substrate 201 and a part of the lower surface of the suspension layer 203 .
  • the first etching process may be a wet etching process.
  • the sacrificial layer 202 can be etched with a first etching solution.
  • the composition of the sacrificial layer 202 includes InGaAs material.
  • Part of the sacrificial layer 202 is removed by using a first etching solution, and the first etching solution is injected into the semiconductor chip through the opening 208 .
  • the first etching solution performs selective lateral etching on the InGaAs material in the sacrificial layer 202, so that part of the sacrificial layer 202 is removed.
  • the first etching solution may be a sulfuric acid-based etching solution, that is, the etching solution used in the first etching process may include a sulfuric acid-based solution; the sulfuric acid-based etching solution selectively etches the InGaAs material, while the InP material is There is no corrosion effect. Therefore, in the embodiment in which the substrate 201 and the suspension layer 203 are InP, the substrate 201 and the suspension layer 203 can remain in a non-etched state.
  • the size of the opening formed after the sacrificial layer 202 is etched is larger than the size of the opening of the through hole 207 .
  • the thermally tuned semiconductor chip can have higher mechanical strength, so that when the sacrificial layer 202 is etched, the sacrificial layer 202 is located adjacent to two of the through holes. The portion between the hole 207/the opening 208 can be completely removed.
  • suspension layer 203 and the substrate 201 are further etched to finally form a suspension region 209 .
  • the suspension layer and the substrate are etched by the second etching process to form the suspension region.
  • the second etching process may be a wet etching process.
  • the suspension layer 203 and the substrate 201 may be etched with a second etching solution.
  • the second etching solution is injected into the semiconductor chip through the left and right etching holes and the channels connecting the etching holes, and the second etching solution selectively corrodes the InP material in the substrate and the suspension layer, so that some The substrate and suspended layer are removed, thereby forming a suspended region.
  • the second etching solution may be a hydrochloric acid-based etching solution, that is, the etching solution used in the second etching process may include a hydrochloric acid-based solution; since the hydrochloric acid-based solution cannot corrode the InGaAsP material, this step of etching will stop at Below the etching barrier layer, the materials of the original layers of the semiconductor chip are protected from corrosion. At the same time, the thickness of the substrate layer is much larger than that of other layers, so controlling the etching time can ensure the structural stability of the semiconductor chip.
  • the etching barrier layer 2041 blocks the etching reaction from proceeding toward the side of the support layer 204 .
  • the second etching solution used to corrode the InP material has the characteristic of being able to corrode to a fixed corrosion angle.
  • the formed suspension region 209 is a cavity structure extending from below the upper surface of the suspension layer 203, extending through the sacrificial layer 202, and terminating inside the substrate 201, so that the cavity is located in the cavity
  • the functional layer 205 above the structure is isolated from the remaining part of the substrate 201 below the cavity structure by the suspension region 209; the support layer 204 includes at least the part above the cavity structure to support The functional layer 205 located above the cavity structure.
  • part of the sacrificial layer 202 is first etched to define the pattern of the suspension region 209 in advance, and then a second etching solution is injected according to the predefined pattern of the suspension region 209, and then part of the substrate 201 and the suspension layer 203 are etched to form Complete suspension area 209.
  • part of the sacrificial layer 202 is removed to form an etching channel, the contact area between the second etching solution and the substrate 201 and the suspension layer 203 is increased, the etching rate is increased, and the fabrication time is shortened.
  • a thicker thermal isolation layer can be formed, the thickness of which can be determined by the etching barrier layer 2041 and the etching time , which is much larger than the thickness produced by the currently commonly used method. Therefore, through the method, a thicker thermal isolation layer can be obtained without the influence of the thicker InGaAs layer on the growth quality of the semiconductor chip.
  • the depth of the suspension area 209 determines the effect of thermal isolation of the semiconductor chip.
  • the deeper suspension area 209 can improve the effect of thermal isolation of the semiconductor chip, improve the thermal tuning efficiency and the thermal tuning response speed of the semiconductor chip, and effectively solve the problem. At present, the thermal tuning efficiency of semiconductor chips is low and localized.
  • the etching hole is first defined on the surface of the semiconductor chip, the etching hole is square and the size is 5 ⁇ m*10 ⁇ m, and then an inductively coupled plasma (ICP) etching machine is used to etch the etching hole material, and the etching depth is Between 3.00 ⁇ m and 3.02 ⁇ m.
  • ICP inductively coupled plasma
  • the suspended layer and the substrate form a suspended region.
  • the remaining processes of the semiconductor chip may be performed according to normal steps, which will not be repeated here.
  • the formation of the through holes includes the formation of at least two through holes 207
  • the step of etching the sacrificial layer 202, the suspension layer 203 and the substrate 201 in the step of etching the sacrificial layer 202, the suspension layer 203 and the substrate 201, Parts of the suspension layer 203 and the sacrificial layer 202 located between any two of the at least two through holes 207 are completely removed.
  • the thermal tuning efficiency of the material is basically not affected by the material band gap
  • a material with a higher material band gap can be used as the passive waveguide region used for wavelength tuning to further reduce passive
  • the absorption loss of the material in the waveguide region reduces the chip threshold and reduces the laser linewidth.
  • the waveguide layer and the substrate are thermally isolated by air. Under the condition of constant thermal power of the chip, the thermal tuning efficiency and the tuning response speed are greatly improved.
  • the embodiment of the thermally tuned semiconductor chip provided by the present application and the embodiment of the method for preparing a thermally tuned semiconductor chip belong to the same concept; the technical features in the technical solutions described in the embodiments are not in conflict with each other. , which can be combined arbitrarily.
  • the thermally tuned semiconductor chips provided by the embodiments of the present application can already solve the technical problems to be solved by the technical features of the thermally tuned semiconductor chips provided by the embodiments of the present application; therefore, the thermally tuned semiconductor chips provided by the embodiments of the present application can Restrictions on the preparation method of the thermally tuned semiconductor chip provided by the embodiment of the present application, any thermally tuned semiconductor chip prepared by the preparation method of the thermally tuned semiconductor chip structure provided by the embodiment of the present application is within the scope of the protection of the present application .

Abstract

Disclosed are a thermal tuning semiconductor chip and a preparation method therefor. The thermal tuning semiconductor chip comprises: a substrate, and a sacrificial layer and a functional layer, which are sequentially stacked on the substrate, the functional layer being used for transferring heat to a thermal tuning electrode of the thermal tuning semiconductor chip, wherein a floating area is formed in between the substrate and the sacrificial layer, and the floating area is a cavity structure that penetrates through the sacrificial layer and terminates inside the substrate, such that by means of the floating area, the functional layer located above the cavity structure is isolated from the remaining part of the substrate that is below the cavity structure.

Description

一种热调谐半导体芯片及其制备方法A thermally tuned semiconductor chip and preparation method thereof
相关申请的交叉引用CROSS-REFERENCE TO RELATED APPLICATIONS
本申请基于申请号为202011455817.X和202011458418.9、申请日为2020年12月10日的中国专利申请提出,并要求该中国专利申请的优先权,该中国专利申请的全部内容在此引入本申请作为参考。This application is based on the Chinese patent applications with application numbers 202011455817.X and 202011458418.9, and the filing date is December 10, 2020, and claims the priority of the Chinese patent application. The entire content of the Chinese patent application is hereby incorporated into the present application as refer to.
技术领域technical field
本申请涉及半导体技术领域,尤其涉及一种热调谐半导体芯片及其制备方法。The present application relates to the technical field of semiconductors, and in particular, to a thermally tuned semiconductor chip and a preparation method thereof.
背景技术Background technique
随着互联网的飞速发展,人们对网络带宽的需求越来越大。功能全面、性能强大、功耗低的单片集成芯片越来越受到重视。例如,单片集成可调谐激光器作为未来5G网络及智能光网络的核心芯片受到了重视。随着相干传输网络的传输速率越来越高,系统对激光器线宽的要求越来越高,目前典型的相干传输系统对可调谐激光器芯片线宽要求在300KHz以下。传统的可调谐激光器芯片是基于电注入调谐的,虽然调谐速度很快,但是由于存在电流散粒噪声以及其他寄生噪声,芯片线宽难以降低,一般该类芯片线宽普遍在数MHz以上,无法满足相干传输系统对芯片线宽的要求。为了解决上述问题,基于热效应的热调谐芯片受到了器件厂商的重视。由于热效应中,高频噪声分量很小,使得芯片线宽可以得到极大改善。With the rapid development of the Internet, people's demand for network bandwidth is increasing. Monolithic integrated chips with comprehensive functions, powerful performance and low power consumption have been paid more and more attention. For example, monolithically integrated tunable lasers have received attention as the core chips for future 5G networks and smart optical networks. As the transmission rate of the coherent transmission network is getting higher and higher, the system has higher and higher requirements for the laser linewidth. At present, the typical coherent transmission system requires the linewidth of the tunable laser chip to be below 300KHz. Traditional tunable laser chips are tuned based on electrical injection. Although the tuning speed is fast, the chip linewidth is difficult to reduce due to the existence of current shot noise and other parasitic noises. Generally, the linewidth of such chips is generally above several MHz, which cannot be achieved. Meet the requirements of the coherent transmission system for the chip line width. In order to solve the above problems, thermal tuning chips based on thermal effects have been paid attention to by device manufacturers. Due to the thermal effect, the high frequency noise component is very small, so that the chip line width can be greatly improved.
然而,基于热效应的热调谐芯片由于功能层距离热调谐电极存在一定的距离,同时芯片功能层与衬底存在物理连接,因此热功率极易通过衬底耗散掉,热调谐效率相当低。However, in thermally tuned chips based on thermal effects, the thermal power is easily dissipated through the substrate because the functional layer is at a certain distance from the thermally tuned electrodes, and the functional layer of the chip is physically connected to the substrate, and the thermal tuning efficiency is quite low.
发明内容SUMMARY OF THE INVENTION
有鉴于此,本申请实施例为解决背景技术中存在的至少一个问题而提供一种热调谐半导体芯片及其制备方法。In view of this, the embodiments of the present application provide a thermally tuned semiconductor chip and a manufacturing method thereof to solve at least one problem existing in the background art.
为达到上述目的,本申请的技术方案是这样实现的:In order to achieve the above-mentioned purpose, the technical scheme of the present application is achieved in this way:
本申请实施例一方面提供了一种热调谐半导体芯片,包括:衬底,以及依次层叠于所述衬底上的牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量;其中,In one aspect, an embodiment of the present application provides a thermally tuned semiconductor chip, including: a substrate, a sacrificial layer and a functional layer sequentially stacked on the substrate; the functional layer is used to provide a thermally tuned semiconductor chip to the thermally tuned semiconductor chip. Thermally tuned electrodes transfer heat; where,
在所述衬底和所述牺牲层内形成有悬浮区域,所述悬浮区域为贯穿所述牺牲层并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。A suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a cavity structure penetrating the sacrificial layer and terminating inside the substrate, so that all parts above the cavity structure are formed. The functional layer is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
上述方案中,还包括:The above scheme also includes:
层叠于所述衬底上并位于所述牺牲层和所述功能层之间的悬浮层;a suspension layer stacked on the substrate and between the sacrificial layer and the functional layer;
所述悬浮区域具体从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部。Specifically, the suspension region extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
上述方案中,还包括:The above scheme also includes:
位于所述悬浮层和所述功能层之间的支撑层;a support layer between the suspension layer and the functional layer;
所述支撑层至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层。The support layer includes at least a portion located above the cavity structure to support the functional layer located above the cavity structure.
上述方案中,所述悬浮区域包括位于所述衬底内的第一部分、位于所述牺牲层内的第二部分和位于所述悬浮层内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。In the above solution, the suspension area includes a first part located in the substrate, a second part located in the sacrificial layer and a third part located in the suspension layer, the depth of the first part is greater than the depth of the The sum of the depths of the second part and said third part.
上述方案中,所述悬浮层的厚度大于所述牺牲层的厚度;所述悬浮区域位于所述悬浮层内的第三部分的深度大于所述悬浮区域位于所述牺牲层内的第二部分的深度。In the above solution, the thickness of the suspension layer is greater than the thickness of the sacrificial layer; the depth of the third part of the suspension area located in the suspension layer is greater than the depth of the second part of the suspension area located in the sacrificial layer. depth.
上述方案中,所述悬浮层的材料与所述衬底的材料相同。In the above solution, the material of the suspension layer is the same as the material of the substrate.
上述方案中,还包括:The above scheme also includes:
与所述悬浮区域连通的至少两个开口,所述悬浮区域通过经由至少两个所述开口执行的刻蚀工艺而形成;at least two openings in communication with the suspended regions formed by an etching process performed through at least two of the openings;
至少两个所述开口中的任意两个之间包括未被去除的部分悬浮层和未被去除的部分牺牲层。Parts of the suspension layer and part of the sacrificial layer that have not been removed are included between any two of at least two of the openings.
上述方案中,还包括:The above scheme also includes:
与所述悬浮区域连通的至少两个开口,所述悬浮区域通过经由至少两个所述开口执行的刻蚀工艺而形成;at least two openings in communication with the suspended regions formed by an etching process performed through at least two of the openings;
所述悬浮区域在至少两个所述开口中的任意两个之间的上表面为平面,所述平面与所述悬浮层的上表面共面。The upper surface of the suspension area between any two of the at least two openings is a plane, and the plane is coplanar with the upper surface of the suspension layer.
上述方案中,所述功能层包括第一子功能层,所述第一子功能层的下表面与所述悬浮层的上表面接触,用于在刻蚀所述悬浮层以形成所述悬浮区域的工艺中作为刻蚀阻挡层。In the above solution, the functional layer includes a first sub-functional layer, and the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer for etching the suspension layer to form the suspension region process as an etch barrier.
上述方案中,还包括:The above scheme also includes:
层叠于所述衬底上并位于所述悬浮层和所述支撑层之间的刻蚀阻挡层,所述刻蚀阻挡层的下表面与所述悬浮层的上表面接触,所述刻蚀阻挡层在刻蚀所述悬浮层以形成所述悬浮区域的工艺中起到刻蚀阻挡作用。an etch stop layer stacked on the substrate and located between the suspension layer and the support layer, the lower surface of the etch stop layer is in contact with the upper surface of the suspension layer, the etch stop layer The layer acts as an etch stop during the process of etching the suspended layer to form the suspended region.
上述方案中,所述牺牲层的下表面与所述衬底的上表面接触。In the above solution, the lower surface of the sacrificial layer is in contact with the upper surface of the substrate.
上述方案中,所述牺牲层的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。In the above solution, the material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
本申请实施例另一方面提供了一种热调谐半导体芯片的制备方法,所述方法包括:Another aspect of the embodiments of the present application provides a method for preparing a thermally tuned semiconductor chip, the method comprising:
提供衬底,在所述衬底上依次形成牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量;providing a substrate on which a sacrificial layer and a functional layer are sequentially formed; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
形成通孔,所述通孔贯穿所述功能层并暴露出部分所述牺牲层;forming a through hole that penetrates the functional layer and exposes part of the sacrificial layer;
对所述牺牲层和所述衬底进行刻蚀,以形成悬浮区域;所述悬浮区域为贯穿所述牺牲层、并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。Etching the sacrificial layer and the substrate to form a suspended area; the suspended area is a cavity structure that runs through the sacrificial layer and ends in the substrate, so that the cavity is located The functional layer above the structure is isolated from the remaining part of the substrate below the cavity structure by the suspended region.
上述方案中,在所述衬底上依次形成牺牲层和功能层,具体包括:在所述衬底上形成所述牺牲层,在所述牺牲层上形成悬浮层,在所述悬浮层上形成所述功能层;In the above solution, forming a sacrificial layer and a functional layer on the substrate in sequence specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, and forming a suspension layer on the suspension layer. the functional layer;
所述通孔还贯穿所述悬浮层;The through hole also penetrates the suspension layer;
形成所述悬浮区域,具体包括:对所述牺牲层、所述悬浮层和所述衬底进行刻蚀;所述悬浮区域具体从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部。Forming the suspension area specifically includes: etching the sacrificial layer, the suspension layer and the substrate; the suspension area specifically extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
上述方案中,在所述衬底上依次形成牺牲层和功能层,具体包括:在所述衬底上形成所述牺牲层,在所述牺牲层上形成悬浮层,在所述悬浮层上形成支撑层,在所述支撑层上形成功能层;In the above solution, forming a sacrificial layer and a functional layer on the substrate in sequence specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, and forming a suspension layer on the suspension layer. a support layer, on which a functional layer is formed;
所述通孔还贯穿所述支撑层;所述支撑层至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层。The through hole also penetrates the support layer; the support layer at least includes a portion located above the cavity structure to support the functional layer located above the cavity structure.
上述方案中,在形成所述通孔后,所述方法还包括:In the above solution, after forming the through hole, the method further includes:
形成掩膜层,所述掩膜层至少覆盖所述通孔的侧壁;forming a mask layer covering at least the sidewall of the through hole;
在所述掩膜层底端形成开口,所述开口暴露出部分所述牺牲层。An opening is formed at the bottom end of the mask layer, and the opening exposes part of the sacrificial layer.
上述方案中,形成所述悬浮区域,具体包括:In the above scheme, forming the suspension area specifically includes:
采用第一刻蚀工艺对所述牺牲层进行刻蚀,暴露出所述衬底的部分上表面和所述悬浮层的部分下表面;The sacrificial layer is etched by a first etching process to expose a part of the upper surface of the substrate and a part of the lower surface of the suspension layer;
采用第二刻蚀工艺对所述衬底和所述悬浮层进行刻蚀,以形成所述悬浮区域。The substrate and the suspension layer are etched by a second etching process to form the suspension region.
上述方案中,所述悬浮区域包括位于所述衬底内的第一部分、位于所述牺牲层内的第二部分和位于所述悬浮层内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。In the above solution, the suspension area includes a first part located in the substrate, a second part located in the sacrificial layer and a third part located in the suspension layer, the depth of the first part is greater than the depth of the The sum of the depths of the second part and said third part.
上述方案中,所述牺牲层具有第一厚度,所述悬浮层具有第二厚度,所述第二厚度大于所述第一厚度;In the above solution, the sacrificial layer has a first thickness, the suspension layer has a second thickness, and the second thickness is greater than the first thickness;
形成所述悬浮区域,具体包括:对所述悬浮层的刻蚀深度大于所述第一厚度,以使形成的所述悬浮区域在位于所述悬浮层内的第三部分的深度大于在位于所述牺牲层内的第二部分的深度。The forming of the suspension region specifically includes: the etching depth of the suspension layer is greater than the first thickness, so that the depth of the formed suspension region in the third part located in the suspension layer is greater than that in the suspension layer. the depth of the second portion within the sacrificial layer.
上述方案中,所述悬浮层的材料与所述衬底的材料相同。In the above solution, the material of the suspension layer is the same as the material of the substrate.
上述方案中,所述形成通孔包括形成至少两个通孔;In the above solution, the forming through holes includes forming at least two through holes;
所述对所述牺牲层、所述悬浮层和所述衬底进行刻蚀的步骤中,所述悬浮层和所述牺牲层的位于至少两个所述通孔中的任意两个之间的部分未被完全去除。In the step of etching the sacrificial layer, the suspension layer and the substrate, the suspension layer and the sacrificial layer are located between any two of the at least two through holes. Parts are not completely removed.
上述方案中,所述在所述牺牲层上形成悬浮层,在所述悬浮层上形成所述功能层,具体包括:在形成所述悬浮层后,在所述悬浮层上形成所述功能层的第一子功能层,所述第一子功能层的下表面与所述悬浮层的上表面接触;In the above solution, forming a suspension layer on the sacrificial layer and forming the functional layer on the suspension layer specifically includes: after forming the suspension layer, forming the functional layer on the suspension layer The first sub-functional layer, the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer;
形成所述悬浮区域,包括:在对所述悬浮层进行刻蚀时,以所述第一子功能层作为刻蚀阻挡层。The forming of the suspension region includes: when the suspension layer is etched, using the first sub-functional layer as an etching barrier layer.
上述方案中,在所述牺牲层上形成悬浮层,在所述悬浮层上形成支撑层,具体包括:在形成所述悬浮层后,在所述悬浮层上形成刻蚀阻挡层,所述刻蚀阻挡层的下表面与所述悬浮层的上表面接触,在所述刻蚀阻挡层上形成所述支撑层;In the above solution, forming a suspension layer on the sacrificial layer and forming a support layer on the suspension layer specifically includes: after forming the suspension layer, forming an etching barrier layer on the suspension layer, and the etching The lower surface of the etch stop layer is in contact with the upper surface of the suspension layer, and the support layer is formed on the etch stop layer;
形成所述悬浮区域,包括:在对所述悬浮层进行刻蚀时,所述刻蚀阻挡层阻挡刻蚀反应朝向所述支撑层的一侧进行。The forming of the suspension region includes: when the suspension layer is etched, the etching barrier layer prevents the etching reaction from proceeding toward one side of the support layer.
上述方案中,在所述衬底上形成所述牺牲层,具体包括:在所述衬底上直接形成所述牺牲层,以使所述牺牲层的下表面与所述衬底的上表面接触。In the above solution, forming the sacrificial layer on the substrate specifically includes: directly forming the sacrificial layer on the substrate, so that the lower surface of the sacrificial layer is in contact with the upper surface of the substrate .
上述方案中,所述牺牲层的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。In the above solution, the material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
本申请实施例所提供的热调谐半导体芯片及其制备方法,其中,所述热调谐半导体芯片包括:衬底,以及依次层叠于所述衬底上的牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量;在所述衬底和所述牺牲层内形成有悬浮区域,所述悬浮区域为贯穿所述牺牲层并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。如此,所述悬浮区域具有较大的深度,该深度不仅包括借由贯穿所述牺牲层而获得的大于所述牺牲层厚度的部分深度,还包括了位于所述衬底内的部分的深度,因而,位于所述悬浮区域上的功能层可以悬浮在衬底上,并与衬底之间具有较大的空气间隔,从而具有较好的隔热性,有效减少了热量通过衬底耗散的情况的发生,从而将大部分热量传导至热调谐电极,提高了芯片的热调谐效率。The thermally tuned semiconductor chip and the preparation method thereof provided by the embodiments of the present application, wherein the thermally tuned semiconductor chip includes: a substrate, and a sacrificial layer and a functional layer sequentially stacked on the substrate; In order to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip; a suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a thread running through the sacrificial layer and terminating inside the substrate A cavity structure, so that the functional layer located above the cavity structure and the remaining part of the substrate below the cavity structure are isolated by the floating region. In this way, the suspended region has a greater depth, which includes not only the depth of the part greater than the thickness of the sacrificial layer obtained by penetrating the sacrificial layer, but also the depth of the part located in the substrate, Therefore, the functional layer located on the suspended area can be suspended on the substrate, and has a large air gap between the substrate and the substrate, so as to have better heat insulation and effectively reduce the amount of heat dissipated through the substrate. The situation occurs, so that most of the heat is conducted to the thermal tuning electrodes, which improves the thermal tuning efficiency of the chip.
本申请附加的方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本申请的实践了解到。Additional aspects and advantages of the present application will be set forth, in part, in the following description, and in part will be apparent from the following description, or learned by practice of the present application.
附图说明Description of drawings
图1为本申请一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图;1 is a top view of a thermally tuned semiconductor chip provided by an embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
图2为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图;2 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
图3为本申请实施例提供的热调谐半导体芯片的制备方法的流程示意 图;3 is a schematic flowchart of a method for preparing a thermally tuned semiconductor chip provided by an embodiment of the present application;
图4a至4d为本申请实施例提供的热调谐半导体芯片的制备过程中的结构剖面示意图;4a to 4d are schematic cross-sectional structural views of the thermally tuned semiconductor chip provided in the embodiment of the present application during the preparation process;
图5为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图;5 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
图6为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图;6 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view;
图7为本申请另一实施例提供的热调谐半导体芯片的制备方法的流程示意图;7 is a schematic flowchart of a method for manufacturing a thermally tuned semiconductor chip according to another embodiment of the present application;
图8a至8d为本申请另一实施例提供的热调谐半导体芯片的制备过程中的结构剖面示意图。FIGS. 8 a to 8 d are schematic cross-sectional structural views of a thermally tuned semiconductor chip in a manufacturing process according to another embodiment of the present application.
具体实施方式Detailed ways
下面将参照附图更详细地描述本申请公开的示例性实施方式。虽然附图中显示了本申请的示例性实施方式,然而应当理解,可以以各种形式实现本申请,而不应被这里阐述的具体实施方式所限制。相反,提供这些实施方式是为了能够更透彻地理解本申请,并且能够将本申请公开的范围完整的传达给本领域的技术人员。Exemplary embodiments disclosed in the present application will be described in more detail below with reference to the accompanying drawings. Although exemplary embodiments of the present application are shown in the drawings, it should be understood that the present application may be embodied in various forms and should not be limited by the specific embodiments set forth herein. Rather, these embodiments are provided so that the present application will be more thoroughly understood, and will fully convey the scope of the present disclosure to those skilled in the art.
在下文的描述中,给出了大量具体的细节以便提供对本申请更为彻底的理解。然而,对于本领域技术人员而言显而易见的是,本申请可以无需一个或多个这些细节而得以实施。在其他的例子中,为了避免与本申请发生混淆,对于本领域公知的一些技术特征未进行描述;即,这里不描述实际实施例的全部特征,不详细描述公知的功能和结构。In the following description, numerous specific details are set forth in order to provide a more thorough understanding of the present application. It will be apparent, however, to one skilled in the art that the present application may be practiced without one or more of these details. In other instances, some technical features that are well known in the art have not been described in order to avoid confusion with the present application; that is, not all features of an actual embodiment are described herein, and well-known functions and structures are not described in detail.
在附图中,为了清楚,层、区、元件的尺寸以及其相对尺寸可能被夸大。自始至终相同附图标记表示相同的元件。In the drawings, the sizes of layers, regions, elements, and their relative sizes may be exaggerated for clarity. The same reference numbers refer to the same elements throughout.
应当明白,当元件或层被称为“在……上”、“与……相邻”、“连接到” 或“耦合到”其它元件或层时,其可以直接地在其它元件或层上、与之相邻、连接或耦合到其它元件或层,或者可以存在居间的元件或层。相反,当元件被称为“直接在……上”、“与……直接相邻”、“直接连接到”或“直接耦合到”其它元件或层时,则不存在居间的元件或层。应当明白,尽管可使用术语第一、第二、第三等描述各种元件、部件、区、层和/或部分,这些元件、部件、区、层和/或部分不应当被这些术语限制。这些术语仅仅用来区分一个元件、部件、区、层或部分与另一个元件、部件、区、层或部分。因此,在不脱离本申请教导之下,下面讨论的第一元件、部件、区、层或部分可表示为第二元件、部件、区、层或部分。而当讨论的第二元件、部件、区、层或部分时,并不表明本申请必然存在第一元件、部件、区、层或部分。It will be understood that when an element or layer is referred to as being "on," "adjacent to," "connected to," or "coupled to" other elements or layers, it can be directly on the other elements or layers , adjacent thereto, connected or coupled to other elements or layers, or intervening elements or layers may be present. In contrast, when an element is referred to as being "directly on," "directly adjacent to," "directly connected to," or "directly coupled to" other elements or layers, there are no intervening elements or layers present. It will be understood that, although the terms first, second, third, etc. may be used to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the present application. However, the discussion of a second element, component, region, layer or section does not imply that the first element, component, region, layer or section is necessarily present in the present application.
空间关系术语例如“在……下”、“在……下面”、“下面的”、“在……之下”、“在……之上”、“上面的”等,在这里可为了方便描述而被使用从而描述图中所示的一个元件或特征与其它元件或特征的关系。应当明白,除了图中所示的取向以外,空间关系术语意图还包括使用和操作中的器件的不同取向。例如,如果附图中的器件翻转,然后,描述为“在其它元件下面”或“在其之下”或“在其下”元件或特征将取向为在其它元件或特征“上”。因此,示例性术语“在……下面”和“在……下”可包括上和下两个取向。器件可以另外地取向(旋转90度或其它取向)并且在此使用的空间描述语相应地被解释。Spatial relational terms such as "under", "below", "under", "under", "above", "above", etc., are used herein for convenience Description is used to describe the relationship of one element or feature to other elements or features shown in the figures. It should be understood that the spatially relative terms are intended to encompass different orientations of the device in use and operation in addition to the orientation shown in the figures. For example, if the device in the figures is turned over, then elements or features described as "below" or "beneath" or "beneath" other elements or features would then be oriented "above" the other elements or features. Thus, the exemplary terms "below" and "under" can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatial descriptors used herein interpreted accordingly.
在此使用的术语的目的仅在于描述具体实施例并且不作为本申请的限制。在此使用时,单数形式的“一”、“一个”和“所述/该”也意图包括复数形式,除非上下文清楚指出另外的方式。还应明白术语“组成”和/或“包括”,当在该说明书中使用时,确定所述特征、整数、步骤、操作、元件和/或部件的存在,但不排除一个或更多其它的特征、整数、步骤、操作、元 件、部件和/或组的存在或添加。在此使用时,术语“和/或”包括相关所列项目的任何及所有组合。The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the application. As used herein, the singular forms "a," "an," and "the/the" are intended to include the plural forms as well, unless the context clearly dictates otherwise. It should also be understood that the terms "compose" and/or "include", when used in this specification, identify the presence of stated features, integers, steps, operations, elements and/or components, but do not exclude one or more other The presence or addition of features, integers, steps, operations, elements, parts and/or groups. As used herein, the term "and/or" includes any and all combinations of the associated listed items.
为了彻底理解本申请,将在下列的描述中提出详细的步骤以及详细的结构,以便阐释本申请的技术方案。本申请的较佳实施例详细描述如下,然而除了这些详细描述外,本申请还可以具有其他实施方式。For a thorough understanding of the present application, detailed steps and detailed structures will be presented in the following description in order to explain the technical solutions of the present application. The preferred embodiments of the present application are described in detail below, however, the present application may have other embodiments in addition to these detailed descriptions.
由于基于热效应的热调谐芯片,功能层距离热调谐电极存在一定的距离,热量传导至热调谐电极所需要的时间较长;而功能层与衬底之间存在物理连接,导致热功率容易通过衬底耗散。为了解决上述技术问题,作为一种可行的方案是:在衬底与功能层之间预先生长一层三元材料层,如InGaAs层,而后通过侧向腐蚀的方式去除该层,使得芯片功能层悬浮在衬底之上。但是,由于生长与衬底晶格匹配的三元材料InGaAs较为困难,尤其是生长较厚的InGaAs材料存在一定难度,通常仅能生长数百纳米。此外,在相关技术中,该三元材料层与衬底之间还设置有下限制层,在对该三元材料层进行侧向腐蚀时,所述下限制层会阻止腐蚀反应向下(即朝向衬底的方向)进行。因此,通过侧向腐蚀该三元材料层而形成的位于衬底与功能层之间的悬浮间隔很小。而更厚的InGaAs材料会使得芯片材料质量大幅度降低,尤其会影响有源区量子阱结构的质量。Due to the thermal effect-based thermal tuning chip, there is a certain distance between the functional layer and the thermal tuning electrode, and it takes a long time for the heat to be conducted to the thermal tuning electrode; however, there is a physical connection between the functional layer and the substrate, which makes it easy for thermal power to pass through the substrate. bottom dissipation. In order to solve the above technical problems, as a feasible solution, a ternary material layer, such as an InGaAs layer, is pre-grown between the substrate and the functional layer, and then the layer is removed by lateral etching, so that the functional layer of the chip is removed. suspended above the substrate. However, it is difficult to grow the ternary material InGaAs that matches the lattice of the substrate, especially the thicker InGaAs material, which can usually only grow several hundreds of nanometers. In addition, in the related art, a lower confinement layer is further provided between the ternary material layer and the substrate, and when the ternary material layer is etched laterally, the lower confinement layer will prevent the corrosion reaction from going downward (ie direction towards the substrate). Therefore, the floating space between the substrate and the functional layer formed by laterally etching the ternary material layer is small. The thicker InGaAs material will greatly reduce the quality of the chip material, especially the quality of the quantum well structure in the active region.
因此,芯片热调谐效率及调谐响应速度的进一步提高受到了限制。在芯片热功率一定的情况下,热功率极易通过衬底耗散掉,而只有较少的热量传导至热调谐电极,导致出现芯片的热调谐效率的低的技术问题。Therefore, the further improvement of chip thermal tuning efficiency and tuning response speed is limited. When the thermal power of the chip is constant, the thermal power is easily dissipated through the substrate, and less heat is conducted to the thermal tuning electrodes, resulting in a technical problem of low thermal tuning efficiency of the chip.
因此,亟待解决无法在衬底与功能层之间获得更大的悬浮间隔的问题。Therefore, there is an urgent need to solve the problem that a larger floating space cannot be obtained between the substrate and the functional layer.
基于此,本申请实施例首先提供了一种热调谐半导体芯片。Based on this, the embodiments of the present application first provide a thermally tuned semiconductor chip.
所述热调谐半导体芯片,包括:衬底,以及依次层叠于所述衬底上的牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量;其中,在所述衬底和所述牺牲层内形成有悬浮区域,所述悬浮 区域为贯穿所述牺牲层并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。如此,所述悬浮区域具有较大的深度,该深度不仅包括借由贯穿所述牺牲层而获得的大于所述牺牲层厚度的部分深度,还包括了位于所述衬底内的部分的深度,因而,位于所述悬浮区域上的功能层可以悬浮在衬底上,并与衬底之间具有较大的空气间隔,从而具有较好的隔热性,有效减少了热量通过衬底耗散的情况的发生,从而将大部分热量传导至热调谐电极,提高了芯片的热调谐效率。The thermally tuned semiconductor chip includes: a substrate, and a sacrificial layer and a functional layer sequentially stacked on the substrate; the functional layer is used for transferring heat to a thermally tuned electrode of the thermally tuned semiconductor chip; wherein, A suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a cavity structure penetrating the sacrificial layer and terminating inside the substrate, so that all parts above the cavity structure are formed. The functional layer is isolated from the remaining part of the substrate below the cavity structure by the suspension region. In this way, the suspended region has a greater depth, which includes not only the depth of the part greater than the thickness of the sacrificial layer obtained by penetrating the sacrificial layer, but also the depth of the part located in the substrate, Therefore, the functional layer located on the suspended area can be suspended on the substrate, and has a large air gap between the substrate and the substrate, so as to have better heat insulation and effectively reduce the amount of heat dissipated through the substrate. The situation occurs, so that most of the heat is conducted to the thermal tuning electrodes, which improves the thermal tuning efficiency of the chip.
下面,将参考图1对本申请实施例提供的热调谐半导体芯片作更详细地描述和解释。Hereinafter, the thermally tuned semiconductor chip provided by the embodiment of the present application will be described and explained in more detail with reference to FIG. 1 .
图1为本申请一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图。如图所示,所述热调谐半导体芯片,包括:衬底101,以及依次层叠于所述衬底101上的牺牲层102、悬浮层103和功能层105;其中,在所述衬底101、所述牺牲层102和所述悬浮层103内形成有悬浮区域109。1 is a top view of a thermally tuned semiconductor chip according to an embodiment of the present application and a cross-sectional view along two dotted lines in the top view. As shown in the figure, the thermally tuned semiconductor chip includes: a substrate 101, and a sacrificial layer 102, a suspension layer 103 and a functional layer 105 sequentially stacked on the substrate 101; wherein, on the substrate 101, A suspension region 109 is formed in the sacrificial layer 102 and the suspension layer 103 .
这里,所述衬底101为半导体衬底,其材料具体可以包括InP。所述衬底101的厚度例如大于150μm。Here, the substrate 101 is a semiconductor substrate, and its material may specifically include InP. The thickness of the substrate 101 is, for example, greater than 150 μm.
可以理解地,所述衬底包括处于正面的顶表面以及处于与正面相对的背面的底表面;在忽略顶表面和底表面的平整度的情况下,定义垂直衬底顶表面和底表面的方向为Z方向。Z方向也为后续在衬底上沉积各层结构的层叠方向,或称芯片的高度方向。而衬底顶表面和底表面所在的面,或者严格意义上讲衬底厚度方向上的中心面,即确定为衬底平面;平行衬底平面的方向即为沿衬底平面方向;Z方向即为垂直衬底平面的方向。在所述衬底平面方向上定义两彼此垂直的X方向和Y方向。It is understood that the substrate includes a top surface on the front side and a bottom surface on the back side opposite the front side; the directions perpendicular to the top and bottom surfaces of the substrate are defined, ignoring the flatness of the top and bottom surfaces for the Z direction. The Z direction is also the stacking direction of each layer structure subsequently deposited on the substrate, or the height direction of the chip. The surface where the top surface and the bottom surface of the substrate are located, or strictly speaking, the central plane in the thickness direction of the substrate, is determined as the substrate plane; the direction parallel to the substrate plane is the direction along the substrate plane; the Z direction is is the direction perpendicular to the substrate plane. Two X and Y directions that are perpendicular to each other are defined in the plane direction of the substrate.
所述牺牲层102、所述悬浮层103和所述功能层105中的至少之一可以 通过沉积或蒸发的方式形成在所述衬底101上。At least one of the sacrificial layer 102, the suspension layer 103 and the functional layer 105 may be formed on the substrate 101 by deposition or evaporation.
所述牺牲层102的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。所述牺牲层102的材料与所述衬底101的材料不同。作为一种具体实施方式,所述牺牲层102的材料为InGaAs;所述衬底101和所述悬浮层103的材料均为InP。所述牺牲层102的厚度范围为100nm~400nm。The material of the sacrificial layer 102 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs. The material of the sacrificial layer 102 is different from the material of the substrate 101 . As a specific implementation manner, the material of the sacrificial layer 102 is InGaAs; the materials of the substrate 101 and the suspension layer 103 are both InP. The thickness of the sacrificial layer 102 ranges from 100 nm to 400 nm.
在一具体实施例中,所述牺牲层102的下表面与所述衬底101的上表面接触。换言之,所述牺牲层102与所述衬底101之间不包括其他材料层。如此,本实施例通过省去相关技术中的下限制层,而使得所述悬浮区域延伸扩展至所述衬底内部,从而增大了所述悬浮区域的整体深度,提高了器件的隔热性。In a specific embodiment, the lower surface of the sacrificial layer 102 is in contact with the upper surface of the substrate 101 . In other words, no other material layers are included between the sacrificial layer 102 and the substrate 101 . In this way, in this embodiment, by omitting the lower confinement layer in the related art, the suspension region extends to the inside of the substrate, thereby increasing the overall depth of the suspension region and improving the thermal insulation of the device .
在所述热调谐半导体芯片还包括所述悬浮层103的实施例中,所述悬浮层103层叠于所述衬底101上并位于所述牺牲层102和所述功能层105之间。所述悬浮层103的材料可以包括InP。所述悬浮层103的材料可以与所述衬底101的材料相同;所述悬浮层103的材料与所述牺牲层102的材料不同。所述悬浮层103的厚度例如大于所述牺牲层102的厚度;所述悬浮层103的厚度范围例如为450nm~550nm。In the embodiment in which the thermally tuned semiconductor chip further includes the suspension layer 103 , the suspension layer 103 is stacked on the substrate 101 and is located between the sacrificial layer 102 and the functional layer 105 . The material of the suspension layer 103 may include InP. The material of the suspension layer 103 may be the same as the material of the substrate 101 ; the material of the suspension layer 103 is different from the material of the sacrificial layer 102 . The thickness of the suspension layer 103 is, for example, greater than the thickness of the sacrificial layer 102 ; the thickness of the suspension layer 103 ranges from 450 nm to 550 nm, for example.
在本实施例中,所述悬浮区域109具体为从所述悬浮层103的上表面以下、延伸贯穿所述牺牲层102、并终止于所述衬底101内部的空腔结构,以使位于所述空腔结构上方的所述功能层105与所述空腔结构下方剩余的部分所述衬底101通过所述悬浮区域109隔离。In this embodiment, the suspension region 109 is a cavity structure extending from below the upper surface of the suspension layer 103, extending through the sacrificial layer 102, and terminating in the interior of the substrate 101, so that the The functional layer 105 above the cavity structure is isolated from the remaining part of the substrate 101 below the cavity structure by the suspension region 109 .
所述悬浮区域109的深度可以在10-15μm之间。The depth of the suspended region 109 may be between 10-15 μm.
在一具体实施例中,所述悬浮区域109包括位于所述衬底101内的第一部分、位于所述牺牲层102内的第二部分和位于所述悬浮层103内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。In a specific embodiment, the suspension region 109 includes a first part located in the substrate 101, a second part located in the sacrificial layer 102 and a third part located in the suspension layer 103, the The depth of the first portion is greater than the sum of the depths of the second portion and the third portion.
在一具体实施例中,所述悬浮区域109位于所述悬浮层103内的第三部分的深度大于所述悬浮区域109位于所述牺牲层102内的第二部分的深度。如此,所述第一部分在所述悬浮区域109中所占的比例是最大的;并且,具体地,所述第一部分的深度>第三部分的深度>第二部分的深度。In a specific embodiment, the depth of the third portion of the suspension region 109 in the suspension layer 103 is greater than the depth of the second portion of the suspension region 109 in the sacrificial layer 102 . In this way, the proportion of the first part in the floating area 109 is the largest; and, specifically, the depth of the first part>the depth of the third part>the depth of the second part.
请继续参考图1,所述悬浮区域109在沿垂直衬底平面方向上的剖面呈六边形。所述悬浮区域109的侧壁在平行衬底平面方向上的距离从所述悬浮层103到所述牺牲层102增大。在所述第一部分的深度大于所述第二部分和所述第三部分的深度之和的实施例中,所述悬浮区域109的侧壁在平行衬底平面方向上的距离在所述衬底101内获得最大,并从最大的位置处向下减小。Please continue to refer to FIG. 1 , the cross section of the suspension region 109 along the direction perpendicular to the plane of the substrate is hexagonal. The distance of the sidewall of the suspension region 109 in a direction parallel to the plane of the substrate increases from the suspension layer 103 to the sacrificial layer 102 . In the embodiment in which the depth of the first part is greater than the sum of the depths of the second part and the third part, the distance between the sidewalls of the suspended region 109 in the direction parallel to the plane of the substrate Get the maximum in 101 and decrease down from the maximum position.
在本申请实施例中,悬浮区域的厚度远大于牺牲层的厚度,从而在垂直于芯片表面(即垂直于衬底)的方向上,悬浮区域的上下表面之间存在较大空隙。In the embodiment of the present application, the thickness of the suspension region is much larger than the thickness of the sacrificial layer, so that in the direction perpendicular to the chip surface (ie, perpendicular to the substrate), there is a large gap between the upper and lower surfaces of the suspension region.
所述功能层105用于向所述热调谐半导体芯片的热调谐电极(图中未示出)传递热量。The functional layer 105 is used to transfer heat to a thermally tuned electrode (not shown in the figure) of the thermally tuned semiconductor chip.
所述功能层105可以包括第一子功能层1051,所述第一子功能层1051的下表面与所述悬浮层103的上表面接触,用于在刻蚀所述悬浮层103以形成所述悬浮区域109的工艺中作为刻蚀阻挡层。The functional layer 105 may include a first sub-functional layer 1051, and the lower surface of the first sub-functional layer 1051 is in contact with the upper surface of the suspension layer 103 for etching the suspension layer 103 to form the The suspended region 109 is used as an etching stopper in the process.
所述第一子功能层1051的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs;换言之,所述功能层105中与所述悬浮层103的上表面接触的底层结构是InGaAs、InGaAsP、和/或AlGaInAs材料层。所述第一子功能层1051的材料可以与所述牺牲层102的材料相同。所述第一子功能层1051的材料与所述悬浮层103的材料不同;并且,作为刻蚀所述悬浮层103的刻蚀阻挡层,所述第一子功能层1051与所述悬浮层103在刻蚀工艺中之间应当具有较大的刻蚀选择比。The material of the first sub-functional layer 1051 includes at least one of the following: InGaAs, InGaAsP, AlGaInAs; in other words, the underlying structure in the functional layer 105 in contact with the upper surface of the suspension layer 103 is InGaAs, InGaAsP, and/ or AlGaInAs material layer. The material of the first sub-functional layer 1051 may be the same as the material of the sacrificial layer 102 . The material of the first sub-functional layer 1051 is different from the material of the suspension layer 103; and, as an etching stopper for etching the suspension layer 103, the first sub-functional layer 1051 and the suspension layer 103 There should be a large etching selectivity ratio between etching processes.
所述第一子功能层1051的厚度小于所述悬浮层103的厚度。在沿平行所述衬底101的平面上,所述第一子功能层1051的面积可以大于或等于所述悬浮层103的面积,以使所述第一子功能层1051完全覆盖所述悬浮层103。The thickness of the first sub-functional layer 1051 is smaller than the thickness of the suspension layer 103 . On a plane parallel to the substrate 101, the area of the first sub-functional layer 1051 may be greater than or equal to the area of the suspension layer 103, so that the first sub-functional layer 1051 completely covers the suspension layer 103.
在一具体实施例中,所述第一子功能层1051为量子阱层。In a specific embodiment, the first sub-functional layer 1051 is a quantum well layer.
所述功能层105的具体结构依据实际场景而定,可以为以下之一:激光器层状结构、探测器层状结构、调制器层状结构或无源波导层状结构。作为一种具体的实施方式,所述功能层105可以包括沿所述衬底101从下向上的下波导层(材料例如为InGaAsP),波导芯层(材料例如为InGaAsP),以及上波导层(材料例如为InGaAsP);所述功能层105还可以包括位于上波导层上的包层(材料例如为InP)。还可以包括:电极接触层(材料例如为InGaAs)。The specific structure of the functional layer 105 depends on the actual scene, and may be one of the following: a laser layered structure, a detector layered structure, a modulator layered structure or a passive waveguide layered structure. As a specific implementation manner, the functional layer 105 may include a lower waveguide layer (such as InGaAsP), a waveguide core layer (such as InGaAsP), and an upper waveguide layer (such as InGaAsP) along the substrate 101 from bottom to top. The material is, for example, InGaAsP); the functional layer 105 may further include a cladding layer (the material is, for example, InP) located on the upper waveguide layer. It may also include: an electrode contact layer (the material is, for example, InGaAs).
在所述功能层105包括第一子功能层1051的实施例中,所述下波导层位于所述第一子功能层1051上。所述下波导层可能仅位于部分所述第一子功能层1051上;换言之,所述功能层105在一部分区域上仅包括所述第一子功能层1051,在另一部分区域上包括所述第一子功能层1051以及位于所述第一子功能层1051上的其他子功能层。In the embodiment in which the functional layer 105 includes a first sub-functional layer 1051 , the lower waveguide layer is located on the first sub-functional layer 1051 . The lower waveguide layer may only be located on a part of the first sub-functional layer 1051; in other words, the functional layer 105 only includes the first sub-functional layer 1051 in a part of the region, and includes the first sub-functional layer 1051 in another part of the region. A sub-functional layer 1051 and other sub-functional layers located on the first sub-functional layer 1051 .
所述热调谐半导体芯片还可以包括与所述悬浮区域109连通的通孔107。所述通孔107例如贯穿所述功能层105和所述悬浮层103;在所述功能层105包括第一子功能层1051的实施例中,还贯穿所述第一子功能层1051。The thermally tuned semiconductor chip may further include vias 107 in communication with the floating region 109 . For example, the through hole 107 penetrates the functional layer 105 and the suspension layer 103 ; in the embodiment where the functional layer 105 includes the first sub-functional layer 1051 , it also penetrates the first sub-functional layer 1051 .
在所述通孔107的侧壁上还可以覆盖有掩膜层106。所述掩膜层106用于在形成所述悬浮区域的刻蚀工艺中保护位于所述掩膜层106以内的功能层105和悬浮层103。所述掩膜层106底端具有开口108;所述开口108贯穿所述掩膜层106,连通所述通孔107和所述悬浮区域109。所述掩膜层106 还可以覆盖在所述功能层105上,这里并不做具体限定。A mask layer 106 may also be covered on the sidewalls of the through holes 107 . The mask layer 106 is used to protect the functional layer 105 and the suspension layer 103 within the mask layer 106 during the etching process of forming the suspension region. The bottom end of the mask layer 106 has an opening 108 ; the opening 108 penetrates the mask layer 106 and communicates with the through hole 107 and the suspension area 109 . The mask layer 106 may also cover the functional layer 105, which is not specifically limited here.
应当理解,所述开口108位于所述通孔107内。图1中示出了所述开口108的开口尺寸小于所述通孔107的开口尺寸的情况;当然,所述开口108的开口尺寸也可以等于所述通孔107的开口尺寸,或更具体地等于所述通孔107的开口尺寸减去所述掩膜层106的两边侧壁厚度。It should be understood that the opening 108 is located in the through hole 107 . FIG. 1 shows the case where the opening size of the opening 108 is smaller than the opening size of the through hole 107; of course, the opening size of the opening 108 can also be equal to the opening size of the through hole 107, or more specifically It is equal to the opening size of the through hole 107 minus the thickness of the two sidewalls of the mask layer 106 .
所述通孔107和所述开口108的开口形状可以为圆形、方形、菱形或者其他形状,依据实际情况设计即可,在此不做具体限定。The opening shapes of the through holes 107 and the openings 108 may be circular, square, diamond or other shapes, which can be designed according to actual conditions, which are not specifically limited herein.
与一个所述悬浮区域对应的所述通孔/所述开口的数量可以为两个以上。在图1对应的实施例中,与一个所述悬浮区域109对应的所述通孔107/所述开口108的数量具体为两个;并且,两个所述通孔107/所述开口108可以在所述悬浮区域109上对称布置,具体可以沿所述悬浮区域109的中轴线左右对称布置。The number of the through holes/the openings corresponding to one floating area may be two or more. In the embodiment corresponding to FIG. 1 , the number of the through holes 107/the openings 108 corresponding to one floating area 109 is specifically two; and the two through holes 107/the openings 108 may be They are arranged symmetrically on the suspension area 109 , specifically, they may be arranged symmetrically on the left and right sides along the central axis of the suspension area 109 .
两个以上所述通孔107/所述开口108中的任意两个之间,可以包括未被去除的部分悬浮层103,还可以包括未被去除的部分牺牲层102;换言之,在所述悬浮区域109的顶端至少包括暴露出所述功能层105(具体为所述第一子功能层1051)的第一部分和第二部分,在沿平行所述衬底101的平面上还可以包括位于所述第一部分和所述第二部分之间的部分牺牲层102和悬浮层103。所述热调谐半导体芯片可以具有位于所述悬浮区域109一侧的第一部分牺牲层102和第一部分悬浮层103、位于所述悬浮区域109另一侧的第二部分牺牲层102和第二部分悬浮层103以及位于所述悬浮区域109中的第三部分牺牲层102和第三部分悬浮层103;应当理解,上述三个部分的牺牲层102和悬浮层103通过图中未示出的区域连接。如此,增大了整个悬浮区域109的机械结构强度。Between any two of the two or more through holes 107/the openings 108, the unremoved part of the suspension layer 103 may be included, and the unremoved part of the sacrificial layer 102 may also be included; The top of the region 109 at least includes a first portion and a second portion exposing the functional layer 105 (specifically, the first sub-functional layer 1051 ), and may also include a portion located on the surface along a plane parallel to the substrate 101 . A part of the sacrificial layer 102 and the suspension layer 103 between the first part and the second part. The thermally tuned semiconductor chip may have a first portion of the sacrificial layer 102 and a first portion of the suspension layer 103 on one side of the suspension region 109 , and a second portion of the sacrificial layer 102 and a second portion of the suspension layer on the other side of the suspension region 109 layer 103 and the third part of the sacrificial layer 102 and the third part of the suspension layer 103 located in the suspension area 109; it should be understood that the sacrificial layer 102 and the suspension layer 103 of the above three parts are connected by areas not shown in the figure. In this way, the mechanical structural strength of the entire suspension area 109 is increased.
由此,作为本申请的一种可选实施例,所述热调谐半导体芯片还可以包括:与所述悬浮区域连通的至少两个开口,所述悬浮区域通过经由至少 两个所述开口执行的刻蚀工艺而形成;至少两个所述开口中的任意两个之间包括未被去除的部分悬浮层和未被去除的部分牺牲层。Therefore, as an optional embodiment of the present application, the thermally tuned semiconductor chip may further include: at least two openings communicated with the suspension area, and the suspension area is implemented by performing a process through the at least two openings. An etching process is performed; any two of the at least two openings include a part of the suspension layer that has not been removed and a part of the sacrificial layer that has not been removed.
所述未被去除的部分悬浮层和所述未被去除的部分牺牲层在沿垂直所述衬底的方向的剖面为倒梯形。A cross section of the unremoved part of the suspension layer and the unremoved part of the sacrificial layer in a direction perpendicular to the substrate is an inverted trapezoid.
所述衬底101、所述牺牲层102和所述悬浮层103沿悬浮区域109的周向设置,并构成所述悬浮区域109的侧壁和底壁,以使所述功能层105悬浮设置在所述衬底101上。由于功能层105与衬底101之间存在很大的空气隔离间隔,因此,可以减少从衬底101散发的热量,从而提高所述热调谐半导体芯片的热调谐效率。The substrate 101 , the sacrificial layer 102 and the suspension layer 103 are arranged along the circumference of the suspension area 109 and constitute the side walls and bottom walls of the suspension area 109 , so that the functional layer 105 is suspended in the suspension area 109 . on the substrate 101 . Since there is a large air isolation interval between the functional layer 105 and the substrate 101, the heat dissipated from the substrate 101 can be reduced, thereby improving the thermal tuning efficiency of the thermally tuned semiconductor chip.
下面,请参考图2。图2为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图。Below, please refer to Figure 2. FIG. 2 is a top view of a thermally tuned semiconductor chip according to another embodiment of the present application and a cross-sectional view along two dotted lines in the top view.
区别于图1对应的实施例,本实施例中具体介绍热调谐半导体芯片中包括多个悬浮区域109的情况。相应的,热调谐半导体芯片包括多组通孔(如图中107、107')和开口(如图中108、108');由于开口是与通孔一一对应的,因此,下面仅以通孔进行说明。与多个悬浮区域109连通的多组通孔之间(如图中107与107'之间)可以是等间距排列或者是不等间距排列,依据实际情况而定。多个所述悬浮区域109可以呈阵列分布,从而多组通孔/多组开口也可以呈阵列分布。Different from the embodiment corresponding to FIG. 1 , the present embodiment specifically introduces the case where the thermally tuned semiconductor chip includes a plurality of suspension regions 109 . Correspondingly, the thermally tuned semiconductor chip includes multiple groups of through holes (107, 107' in the figure) and openings (108, 108' in the figure). holes are explained. The groups of through holes communicating with the plurality of suspension regions 109 (between 107 and 107 ′ in the figure) may be arranged at equal intervals or at unequal intervals, depending on the actual situation. A plurality of the suspension regions 109 may be distributed in an array, so that multiple groups of through holes/multiple groups of openings may also be distributed in an array.
如图2中顶视图所示,同一行的两个通孔与该行对应悬浮区域连通,另一行的两个通孔与该行对应悬浮区域连通,相邻行的通孔之间牺牲层102、悬浮层103和功能层105在沿各层横向延展的方向(X方向)上是连续的,同一行的通孔之间的牺牲层102、悬浮层103和功能层105在沿各层纵向延展的方向(Y方向)上是连续的,保证了位于热调谐半导体芯片的衬底101、牺牲层102、悬浮层103只是与悬浮区域109对应的位置处被掏空,而悬浮区域109周向的衬底101、牺牲层102、悬浮层103在沿衬底平 面的延展方向上是连续。腐蚀形成所述悬浮区域109后,悬浮区域109在沿热调谐半导体芯片表面的延展方向上是连续的,并被限制在通孔和开口附近的区域;区域内未被腐蚀的结构层(掩膜层106、功能层105,未被去除的部分悬浮层103、牺牲层102和衬底101)与区域外结构相连接,从而保证功能层105能够连接在一起,进而悬浮在衬底101上。As shown in the top view in FIG. 2 , the two through holes in the same row are connected to the corresponding suspension areas of the row, the two through holes of the other row are connected to the corresponding suspension areas of the row, and the sacrificial layer 102 is between the through holes of adjacent rows. , The suspension layer 103 and the functional layer 105 are continuous in the direction (X direction) extending laterally of each layer, and the sacrificial layer 102, the suspension layer 103 and the functional layer 105 between the via holes in the same row are extending longitudinally along each layer It is continuous in the direction (Y direction), which ensures that the substrate 101, the sacrificial layer 102, and the suspension layer 103 located in the thermally tuned semiconductor chip are only hollowed out at the positions corresponding to the suspension area 109, and the suspension area 109 is circumferentially The substrate 101, the sacrificial layer 102, and the suspension layer 103 are continuous in the extension direction along the substrate plane. After etching to form the suspended region 109, the suspended region 109 is continuous along the extension direction of the surface of the thermally tuned semiconductor chip, and is limited to the region near the through hole and the opening; the unetched structural layer (mask) in the region layer 106 , functional layer 105 , the unremoved part of the suspended layer 103 , sacrificial layer 102 and substrate 101 ) are connected to the out-of-area structure to ensure that the functional layers 105 can be connected together and then suspended on the substrate 101 .
在一些实施例中,位于不同行的通孔所对应的悬浮区域也可以连通。如此,形成的连通的悬浮区域的整体可以理解为包括多个子悬浮区域。在所述悬浮区域包括多个(两个以上)子悬浮区域的实施例中,相邻两所述子悬浮区域之间可以包括未被去除的部分悬浮层;此外,还可以包括未被去除的部分牺牲层。换言之,在沿多个子悬浮区域的排布方向(Y方向)上,所述悬浮区域的顶端至少包括暴露出所述功能层(具体为所述第一子功能层)的第一部分和第三部分,在沿平行所述衬底的平面上还可以包括位于所述第一部分和所述第三部分之间的部分悬浮层和部分牺牲层。其中,位于所述第一部分和所述第三部分之间的部分悬浮层和部分牺牲层可以称为“悬臂”,所述悬臂与在X方向上位于两通孔之间的未被去除的部分悬浮层和部分牺牲层类似,也可以起到增强机械强度的作用。如此,所述悬浮区域在沿平行衬底平面的第一方向(X方向)的宽度小于沿平行衬底平面的第二方向(Y方向)的宽度,所述第二方向垂直于所述第一方向。In some embodiments, the suspension regions corresponding to the through holes located in different rows may also communicate. In this way, the entirety of the formed connected suspension areas can be understood as including a plurality of sub-suspended areas. In the embodiment in which the suspension area includes multiple (more than two) sub-suspension areas, the part of the suspension layer that has not been removed may be included between two adjacent sub-suspension areas; in addition, the suspension layer that has not been removed may also be included Part of the sacrificial layer. In other words, along the arrangement direction (Y direction) of the plurality of sub-suspended regions, the top of the suspended region at least includes the first part and the third part exposing the functional layer (specifically, the first sub-functional layer) , a part of a suspension layer and a part of a sacrificial layer between the first part and the third part may also be included on a plane parallel to the substrate. Wherein, part of the suspension layer and part of the sacrificial layer located between the first part and the third part may be called "cantilever", and the cantilever and the unremoved part located between the two through holes in the X direction Similar to some sacrificial layers, the suspension layer can also enhance the mechanical strength. In this way, the width of the floating region in the first direction (X direction) parallel to the substrate plane is smaller than the width along the second direction (Y direction) parallel to the substrate plane, and the second direction is perpendicular to the first direction direction.
本申请实施例还提供了一种热调谐半导体芯片的制备方法;具体请参见附图3。如图3所示,所述方法包括以下步骤:The embodiment of the present application also provides a method for preparing a thermally tuned semiconductor chip; for details, please refer to FIG. 3 . As shown in Figure 3, the method includes the following steps:
步骤301、提供衬底,在所述衬底上依次形成牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量; Step 301 , providing a substrate, and forming a sacrificial layer and a functional layer on the substrate in sequence; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
步骤302、形成通孔,所述通孔贯穿所述功能层并暴露出部分所述牺牲层; Step 302 , forming a through hole, the through hole passing through the functional layer and exposing part of the sacrificial layer;
步骤303、对所述牺牲层和所述衬底进行刻蚀,以形成悬浮区域;所述 悬浮区域为贯穿所述牺牲层、并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。Step 303: Etch the sacrificial layer and the substrate to form a suspended area; the suspended area is a cavity structure that runs through the sacrificial layer and terminates inside the substrate, so that the The functional layer above the cavity structure is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
下面,结合图4a至4d中热调谐半导体芯片的制备过程中的结构剖面示意图,对图1所示的热调谐半导体芯片及其制备方法再作进一步详细的说明。Next, the thermally tuned semiconductor chip and its manufacturing method shown in FIG. 1 will be further described in detail with reference to the schematic cross-sectional views of the structure in the manufacturing process of the thermally tuned semiconductor chip in FIGS. 4 a to 4 d .
首先,请参考图4a。提供衬底101,在所述衬底上依次形成牺牲层102和功能层105。First, please refer to Figure 4a. A substrate 101 is provided on which a sacrificial layer 102 and a functional layer 105 are sequentially formed.
在一具体实施例中,在所述衬底101上形成所述牺牲层102,具体包括:在所述衬底101上直接形成所述牺牲层102,以使所述牺牲层102的下表面与所述衬底101的上表面接触。换言之,所述牺牲层102与所述衬底101之间不包括其他材料层。如此,本实施例通过省去相关技术中的下限制层,而使得后续采用第二刻蚀工艺对所述衬底进行刻蚀的工序更容易实施,进而形成的所述悬浮区域延伸扩展至所述衬底内部,增大了所述悬浮区域的整体深度,提高了器件的隔热性。In a specific embodiment, forming the sacrificial layer 102 on the substrate 101 specifically includes: directly forming the sacrificial layer 102 on the substrate 101, so that the lower surface of the sacrificial layer 102 and The upper surface of the substrate 101 is in contact. In other words, no other material layers are included between the sacrificial layer 102 and the substrate 101 . In this way, in this embodiment, by omitting the lower confinement layer in the related art, the subsequent process of etching the substrate using the second etching process is easier to implement, and the formed floating region extends to all the Inside the substrate, the overall depth of the suspension region is increased, and the thermal insulation of the device is improved.
在一具体实施例中,在所述衬底101上依次形成牺牲层102和功能层105,具体包括:在所述衬底101上形成所述牺牲层102,在所述牺牲层102上形成悬浮层103,在所述悬浮层103上形成所述功能层105。换言之,在所述衬底101上依次形成牺牲层102、悬浮层103和功能层105。In a specific embodiment, sequentially forming a sacrificial layer 102 and a functional layer 105 on the substrate 101 includes: forming the sacrificial layer 102 on the substrate 101 , and forming a suspension layer on the sacrificial layer 102 layer 103 , and the functional layer 105 is formed on the suspension layer 103 . In other words, the sacrificial layer 102 , the suspension layer 103 and the functional layer 105 are sequentially formed on the substrate 101 .
在一具体实施例中,所述在所述牺牲层102上形成悬浮层103,在所述悬浮层103上形成所述功能层105,具体包括:在形成所述悬浮层103后,在所述悬浮层103上形成所述功能层105的第一子功能层1051,所述第一子功能层1051的下表面与所述悬浮层103的上表面接触;在所述第一子功能层1051上形成所述功能层105;如此,在后续形成悬浮区域的步骤中,在对所述悬浮层103进行刻蚀时,以所述第一子功能层1051作为刻蚀阻挡 层。In a specific embodiment, forming the suspension layer 103 on the sacrificial layer 102 and forming the functional layer 105 on the suspension layer 103 specifically includes: after the suspension layer 103 is formed, on the A first sub-functional layer 1051 of the functional layer 105 is formed on the suspension layer 103, and the lower surface of the first sub-functional layer 1051 is in contact with the upper surface of the suspension layer 103; on the first sub-functional layer 1051 The functional layer 105 is formed; in this way, in the subsequent step of forming the suspension region, when the suspension layer 103 is etched, the first sub-functional layer 1051 is used as an etching barrier layer.
下面,以热调谐半导体芯片为无源波导为例解释说明,在本实施例中,首先在衬底101上牺牲层102,牺牲层102的材料例如为InGaAsP,厚度例如为0.02μm+/0.05μm;悬浮层103的材料例如为InP,厚度例如为1μm+/0.05μm;第一子功能层1051的材料例如为InGaAs,厚度例如为0.2μm+/0.05μm;功能层105例如还包括位于所述第一子功能层1051上的下波导层、波导芯层、波导芯层、包层和电极接触层;下波导层的材料例如为InGaAsP,厚度例如为0.1μm+/0.05μm;波导芯层的材料例如为InGaAsP,厚度例如为0.2μm+/0.05μm;波导芯层的材料例如为InGaAsP,厚度例如为0.1μm+/0.05μm;包层的材料例如为InP,厚度例如为1.5μm+/0.05μm;以及电极接触层的材料例如为InGaAs,厚度例如为0.2μm+/0.05μm。In the following, the thermally tuned semiconductor chip is used as an example of a passive waveguide for explanation. In this embodiment, a sacrificial layer 102 is firstly formed on the substrate 101. The material of the sacrificial layer 102 is, for example, InGaAsP, and the thickness is, for example, 0.02 μm+/0.05 μm; The material of the suspension layer 103 is, for example, InP, and the thickness is, for example, 1 μm+/0.05 μm; the material of the first sub-functional layer 1051 is, for example, InGaAs, and the thickness is, for example, 0.2 μm+/0.05 μm; The lower waveguide layer, the waveguide core layer, the waveguide core layer, the cladding layer and the electrode contact layer on the functional layer 1051; the material of the lower waveguide layer is, for example, InGaAsP, and the thickness is, for example, 0.1 μm+/0.05 μm; the material of the waveguide core layer is, for example, InGaAsP , the thickness is, for example, 0.2 μm+/0.05 μm; the material of the waveguide core layer is, for example, InGaAsP, and the thickness is, for example, 0.1 μm+/0.05 μm; the material of the cladding layer is, for example, InP, the thickness is, for example, 1.5 μm+/0.05 μm; The material is, for example, InGaAs, and the thickness is, for example, 0.2 μm+/0.05 μm.
上述各层可以通过沉积或蒸发的方式形成在所述衬底101上。在完成上述各层的外延以后,即可进行悬浮区域109的制作。The above-mentioned layers may be formed on the substrate 101 by deposition or evaporation. After the epitaxy of the above-mentioned layers is completed, the floating region 109 can be fabricated.
为了形成悬浮区域109,可以在上述各层上形成图案化的第一掩膜层110,所述第一掩膜层110定义出后续形成通孔107的位置。所述第一掩膜层110的图案化可以通过光刻的方式实现。In order to form the suspended region 109 , a patterned first mask layer 110 can be formed on the above-mentioned layers, and the first mask layer 110 defines the positions where the through holes 107 are subsequently formed. The patterning of the first mask layer 110 can be achieved by photolithography.
接下来,请参考图4b。形成通孔107,所述通孔107贯穿所述功能层105并暴露出部分所述牺牲层102。Next, please refer to Figure 4b. A through hole 107 is formed, the through hole 107 penetrates the functional layer 105 and exposes a part of the sacrificial layer 102 .
在一具体实施例中,形成贯穿所述功能层105和所述悬浮层103的通孔107,所述通孔107暴露出部分所述牺牲层102;即,所述通孔107还贯穿所述悬浮层103。In a specific embodiment, a through hole 107 is formed through the functional layer 105 and the suspension layer 103, and the through hole 107 exposes a part of the sacrificial layer 102; that is, the through hole 107 also penetrates through the Suspended layer 103 .
在具体制备中,在所述热调谐半导体芯片的左右两侧形成沿靠近所述衬底101方向上延展的刻蚀孔(即通孔107),其中,所述刻蚀孔在沿靠近所述衬底101方向上依次穿透掩膜106、功能层105、悬浮层103。所述通孔107还可以穿过部分所述牺牲层102;即所述通孔107可以深入所述牺牲 层102内(图中未示出这种情况)。如此,通过光刻的方式在热调谐半导体芯片表面定义出相应的刻蚀孔图形,基于定义好的刻蚀孔图形在热调谐半导体芯片上左右两侧进行刻蚀,例如反应离子(RIE)刻蚀,从而在所述热调谐半导体芯片的左右两侧形成沿靠近所述衬底方向上延展的刻蚀孔。其中,刻蚀孔的开口可以是方形、圆形、或者其他图形。In the specific preparation, etching holes (ie, through holes 107 ) extending in the direction close to the substrate 101 are formed on the left and right sides of the thermally tuned semiconductor chip, wherein the etching holes are formed along the direction close to the substrate 101 . The substrate 101 penetrates through the mask 106 , the functional layer 105 and the suspension layer 103 in sequence. The through hole 107 may also pass through part of the sacrificial layer 102; that is, the through hole 107 may penetrate deep into the sacrificial layer 102 (this is not shown in the figure). In this way, a corresponding etching hole pattern is defined on the surface of the thermally tuned semiconductor chip by means of photolithography, and etching is performed on the left and right sides of the thermally tuned semiconductor chip based on the defined etching hole pattern, such as reactive ion (RIE) etching. etching, thereby forming etching holes extending in a direction close to the substrate on the left and right sides of the thermally tuned semiconductor chip. Wherein, the opening of the etching hole may be a square, a circle, or other shapes.
接下来,请参考图4c。对所述牺牲层102进行刻蚀,以形成悬浮区域的一部分,即所述第二部分。Next, please refer to Figure 4c. The sacrificial layer 102 is etched to form a portion of the suspended region, that is, the second portion.
具体地,在图4b中形成所述贯穿所述功能层105和所述悬浮层103的通孔107后,所述方法还包括:形成掩膜层106,所述掩膜层106至少覆盖所述通孔107的侧壁。此外,所述掩膜层106也可以覆盖在所述热调谐半导体芯片的顶面上,例如覆盖在所述功能层105上。Specifically, after forming the through hole 107 penetrating the functional layer 105 and the suspension layer 103 in FIG. 4b, the method further includes: forming a mask layer 106, the mask layer 106 at least covers the Sidewall of the through hole 107 . In addition, the mask layer 106 may also cover the top surface of the thermally tuned semiconductor chip, for example, the functional layer 105 .
接下来,在所述掩膜层106底端形成开口108,所述开口108暴露出部分所述牺牲层102。Next, an opening 108 is formed at the bottom end of the mask layer 106 , and the opening 108 exposes a part of the sacrificial layer 102 .
应当理解,所述开口108位于所述通孔107内。图4c中示出了所述开口108的开口尺寸小于所述通孔107的开口尺寸的情况;当然,所述开口108的开口尺寸也可以等于所述通孔107的开口尺寸,或更具体地等于所述通孔107的开口尺寸减去所述掩膜层106的两边侧壁厚度。It should be understood that the opening 108 is located in the through hole 107 . Fig. 4c shows the case where the opening size of the opening 108 is smaller than the opening size of the through hole 107; of course, the opening size of the opening 108 can also be equal to the opening size of the through hole 107, or more specifically It is equal to the opening size of the through hole 107 minus the thickness of the two sidewalls of the mask layer 106 .
在具体制备中,在所述热调谐半导体芯片的左右两侧形成沿靠近所述衬底方向上延展的腐蚀孔(即开口108),所述腐蚀孔在沿靠近所述衬底方向上穿透所述掩膜。在本实施例中,使用HF酸腐蚀液去除第一掩膜层110,重新生长掩膜层106(也可称为第二掩膜层)。通过光刻的方式在热调谐半导体芯片的表面定义出相应的腐蚀孔图形,基于定义好的腐蚀孔图形在热调谐半导体芯片上左右两侧进行RIE刻蚀,从而在所述热调谐半导体芯片的左右两侧形成沿靠近所述衬底方向上延展的腐蚀孔。其中,腐蚀孔的开口可以是方形、圆形、或者其他图形。In the specific preparation, etching holes (ie, openings 108 ) extending in the direction close to the substrate are formed on the left and right sides of the thermally tuned semiconductor chip, and the etching holes penetrate in the direction close to the substrate the mask. In this embodiment, the first mask layer 110 is removed by using HF acid etching solution, and the mask layer 106 (also referred to as the second mask layer) is regrown. A corresponding etching hole pattern is defined on the surface of the thermally tuned semiconductor chip by means of photolithography, and RIE etching is performed on the left and right sides of the thermally tuned semiconductor chip based on the defined etching hole pattern, so that the Etched holes extending in the direction close to the substrate are formed on the left and right sides. Wherein, the opening of the etching hole may be a square, a circle, or other shapes.
接下来,采用第一刻蚀工艺对所述牺牲层102进行刻蚀,暴露出所述衬底101的部分上表面和所述悬浮层103的部分下表面。Next, the sacrificial layer 102 is etched by a first etching process to expose a part of the upper surface of the substrate 101 and a part of the lower surface of the suspension layer 103 .
这里,所述第一刻蚀工艺可以为湿法刻蚀工艺。所述牺牲层102可以采用第一腐蚀液腐蚀。在实际应用场景中,所述牺牲层102的组成成分包括InGaAs材料。采用第一腐蚀液去除部分所述牺牲层102,所述第一腐蚀液通过开口108注入到热调谐半导体芯片中。第一腐蚀液对牺牲层102中的InGaAs材料进行选择性侧向腐蚀,使得部分牺牲层102被去除。其中,所述第一腐蚀液可以为硫酸系腐蚀液,即所述第一刻蚀工艺采用的刻蚀液可以包括硫酸系溶液;硫酸系腐蚀液对InGaAs材料进行选择性腐蚀,而对InP材料无腐蚀作用,因此,在衬底101和悬浮层103为的材料InP的实施例中,所述衬底101和所述悬浮层103能够保持非腐蚀状态。Here, the first etching process may be a wet etching process. The sacrificial layer 102 may be etched with a first etching solution. In a practical application scenario, the composition of the sacrificial layer 102 includes InGaAs material. A portion of the sacrificial layer 102 is removed using a first etching solution, which is injected into the thermally tuned semiconductor chip through the opening 108 . The first etching solution performs selective lateral etching on the InGaAs material in the sacrificial layer 102, so that part of the sacrificial layer 102 is removed. Wherein, the first etching solution may be a sulfuric acid-based etching solution, that is, the etching solution used in the first etching process may include a sulfuric acid-based solution; the sulfuric acid-based etching solution selectively etches the InGaAs material, while the InP material is There is no corrosion effect. Therefore, in the embodiment in which the substrate 101 and the suspension layer 103 are InP, the substrate 101 and the suspension layer 103 can remain in a non-etched state.
所述牺牲层102经过刻蚀后形成的开口尺寸大于所述通孔107的开口尺寸。The size of the opening formed after the sacrificial layer 102 is etched is larger than the size of the opening of the through hole 107 .
在一具体实施例中,所述形成通孔包括形成至少两个通孔;相邻两通孔107对应的腐蚀区域不连通,即在相邻两通孔107之间还包括未被去除的牺牲层102。In a specific embodiment, the forming of the through holes includes forming at least two through holes; the etched regions corresponding to the adjacent two through holes 107 are not connected, that is, between the two adjacent through holes 107 , unremoved sacrificial parts are also included. layer 102 .
接下来,请参考图4d。进一步对所述悬浮层103和所述衬底101进行刻蚀,以最终形成悬浮区域109。Next, please refer to Figure 4d. The suspension layer 103 and the substrate 101 are further etched to finally form the suspension region 109 .
具体地,在采用第一刻蚀工艺对所述牺牲层进行刻蚀后,采用第二刻蚀工艺对所述衬底进行刻蚀,以形成所述悬浮区域。在包括所述悬浮层的实施例中,所述方法还包括采用第二刻蚀工艺对所述悬浮层进行刻蚀;换言之,形成所述悬浮区域,具体包括:对所述牺牲层、所述悬浮层和所述衬底进行刻蚀;从而,形成的所述悬浮区域具体从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部。Specifically, after the sacrificial layer is etched by the first etching process, the substrate is etched by the second etching process to form the suspension region. In the embodiment including the suspension layer, the method further includes etching the suspension layer by using a second etching process; in other words, forming the suspension region specifically includes: etching the sacrificial layer, the The suspension layer and the substrate are etched; thus, the suspension region is formed specifically from below the upper surface of the suspension layer, extending through the sacrificial layer, and terminating inside the substrate.
这里,所述第二刻蚀工艺可以为湿法刻蚀工艺。所述悬浮层103和所 述衬底101可以采用第二腐蚀液腐蚀。在实际应用场景中,所述第二腐蚀液通过左右腐蚀孔以及连接腐蚀孔的通道注入道热调谐半导体芯片中,第二腐蚀液对所述衬底和悬浮层中的InP材料选择性腐蚀,使得部分所述衬底和悬浮层被去除,从而形成悬浮区域。其中,所述第二腐蚀液可以为盐酸系腐蚀液,即所述第二刻蚀工艺采用的刻蚀液可以包括盐酸系溶液;由于盐酸系溶液不能腐蚀InGaAsP材料,因此该步腐蚀会停止在第一子功能层以下,保护热调谐半导体芯片原各层材料不受腐蚀影响。同时,衬底层厚度远大于其他层厚度,因此控制腐蚀时间,可以保证热调谐半导体芯片的结构稳定。Here, the second etching process may be a wet etching process. The suspension layer 103 and the substrate 101 can be etched with a second etching solution. In a practical application scenario, the second etching solution is injected into the thermally tuned semiconductor chip through the left and right etching holes and the channels connecting the etching holes, and the second etching solution selectively corrodes the InP material in the substrate and the suspended layer, A portion of the substrate and the suspended layer are removed, thereby forming a suspended region. Wherein, the second etching solution may be a hydrochloric acid-based etching solution, that is, the etching solution used in the second etching process may include a hydrochloric acid-based solution; since the hydrochloric acid-based solution cannot corrode the InGaAsP material, this step of etching will stop at Below the first sub-functional layer, the original layers of the thermally tuned semiconductor chip are protected from corrosion. At the same time, the thickness of the substrate layer is much larger than that of other layers, so controlling the etching time can ensure the stability of the structure of the thermally tuned semiconductor chip.
在实际应用中,采用的所述第二腐蚀液腐蚀对InP材料的腐蚀具有能够腐蚀成固定腐蚀角度的特性。In practical applications, the second etching solution used to corrode the InP material has the characteristic of being able to corrode to a fixed corrosion angle.
从而,形成的所述悬浮区域109为从所述悬浮层103的上表面以下、延伸贯穿所述牺牲层102、并终止于所述衬底101内部的空腔结构,以使位于所述空腔结构上方的所述功能层105与所述空腔结构下方剩余的部分所述衬底101通过所述悬浮区域109隔离。Therefore, the suspension region 109 is formed as a cavity structure extending from below the upper surface of the suspension layer 103, extending through the sacrificial layer 102, and terminating in the interior of the substrate 101, so that the cavity is located in the cavity. The functional layer 105 above the structure is isolated from the remaining part of the substrate 101 below the cavity structure by the suspended region 109 .
在一具体实施例中,所述形成牺牲层、悬浮层和功能层,具体包括:形成具有第一厚度的牺牲层,在所述牺牲层上形成具有第二厚度的悬浮层,如此,所述牺牲层具有第一厚度,所述悬浮层具有第二厚度;所述第二厚度大于所述第一厚度;相应地,形成所述悬浮区域,具体包括:对所述悬浮层的刻蚀深度大于所述第一厚度,以使形成的所述悬浮区域在位于所述悬浮层内的第三部分的深度大于在位于所述牺牲层内的第二部分的深度。In a specific embodiment, the forming of the sacrificial layer, the suspension layer and the functional layer specifically includes: forming a sacrificial layer with a first thickness, and forming a suspension layer with a second thickness on the sacrificial layer, thus, the The sacrificial layer has a first thickness, and the suspension layer has a second thickness; the second thickness is greater than the first thickness; correspondingly, forming the suspension region specifically includes: the etching depth of the suspension layer is greater than The first thickness is such that the depth of the formed suspended region in the third portion located in the suspended layer is greater than the depth of the second portion located in the sacrificial layer.
在本实施例中,首先腐蚀部分牺牲层102以预先定义悬浮区域109的图形,而后在依据预先定义的悬浮区域109的图形注入第二腐蚀液,进而腐蚀部分衬底101和悬浮层103以形成完整的悬浮区域109。同时,由于部分牺牲层102去除后,形成腐蚀通道,加大了第二腐蚀液与衬底101和悬 浮层103的接触面积,提高了腐蚀的速率,缩短了制作时间。In this embodiment, part of the sacrificial layer 102 is first etched to define the pattern of the suspension region 109 in advance, and then a second etching solution is injected according to the predefined pattern of the suspension region 109 , and then part of the substrate 101 and the suspension layer 103 are etched to form Complete suspension area 109. At the same time, since part of the sacrificial layer 102 is removed to form an etching channel, the contact area between the second etching solution and the substrate 101 and the suspension layer 103 is increased, the etching rate is increased, and the fabrication time is shortened.
在本实施例中,通过去除部分所述牺牲层102、衬底101和悬浮层103形成悬浮区域109,可以形成一个较厚的热隔离层,其厚度可以由第一子功能层1051与腐蚀时间决定,远大于目前常用方法制作的厚度。因此通过所述方法,可以获得较厚的热隔离层,同时不受较厚InGaAs层对热调谐半导体芯片生长质量的影响。In this embodiment, by removing part of the sacrificial layer 102, the substrate 101 and the suspension layer 103 to form the suspension region 109, a thicker thermal isolation layer can be formed, the thickness of which can be determined by the first sub-functional layer 1051 and the etching time It is decided that it is much larger than the thickness produced by the current commonly used method. Therefore, by the method, a thicker thermal isolation layer can be obtained without the influence of the thicker InGaAs layer on the growth quality of the thermally tuned semiconductor chip.
在本实施例中,悬浮区域109的深度决定了热调谐半导体芯片的热隔离的效果,较深的悬浮区域109能够提高热调谐半导体芯片热隔离的效果,提高热调谐半导体芯片热调谐效率及热调谐响应速度,有效解决目前热调谐半导体芯片热调谐效率低定位问题。In this embodiment, the depth of the suspension region 109 determines the thermal isolation effect of the thermally tuned semiconductor chip. A deeper suspension region 109 can improve the thermal isolation effect of the thermally tuned semiconductor chip, improve the thermal tuning efficiency and thermal conductivity of the thermally tuned semiconductor chip. The tuning response speed effectively solves the problem of low thermal tuning efficiency of the current thermal tuning semiconductor chip and positioning.
在具体应用中,首先在热调谐半导体芯片表面定义出腐蚀孔,腐蚀孔为方形,大小为5μm*10μm,然后使用感应耦合等离子体(ICP)刻蚀机对腐蚀孔材料进行刻蚀,刻蚀深度为3.00μm~3.02μm之间。接下来,使用硫酸系溶液(如,硫酸:双氧水:水=5:1:1)进行腐蚀;再使用盐酸系溶液(如,HCl:H 3PO 4=3:1)进行再次腐蚀,去除部分悬浮层和衬底,形成悬浮区域。最后,热调谐半导体芯片的其余工艺按正常步骤进行即可,这里不再赘述。 In the specific application, the etching hole is first defined on the surface of the thermally tuned semiconductor chip, the etching hole is square and the size is 5μm*10μm, and then the etching hole material is etched using an inductively coupled plasma (ICP) etching machine. The depth is between 3.00 μm and 3.02 μm. Next, use a sulfuric acid-based solution (eg, sulfuric acid: hydrogen peroxide: water = 5:1:1) for etching; then use a hydrochloric acid-based solution (eg, HCl: H 3 PO 4 = 3: 1) for re-etching to remove parts The suspended layer and the substrate form a suspended region. Finally, the rest of the process of thermally tuning the semiconductor chip can be performed according to normal steps, which will not be repeated here.
可以理解地,在所述形成通孔包括形成至少两个通孔的实施例中,相邻两通孔107之间可以包括未被去除的牺牲层102,进而在对悬浮层刻蚀的步骤中,相邻两通孔107之间还可以包括未被去除的所述悬浮层;换言之,所述对所述牺牲层、所述悬浮层和所述衬底进行刻蚀的步骤中,所述悬浮层和所述牺牲层的位于至少两个所述通孔中的任意两个之间的部分未被完全去除。It can be understood that, in the embodiment in which the formation of the through holes includes the formation of at least two through holes, the sacrificial layer 102 that has not been removed may be included between the two adjacent through holes 107, and then in the step of etching the suspension layer , the suspended layer that has not been removed may also be included between the two adjacent through holes 107; in other words, in the step of etching the sacrificial layer, the suspended layer and the substrate, the suspended layer The layer and the portion of the sacrificial layer located between any two of the at least two of the through holes are not completely removed.
在本实施例中,由于材料的热调谐效率基本不受材料带隙的影响,因此在芯片设计中,可以使用材料带隙更高的材料作为波长调谐使用的无源波导区,进一步降低无源波导区材料的吸收损耗,降低芯片阈值,降低激 光器线宽。同时,波导层与衬底通过空气进行热隔离,在芯片热功率一定的情况下,热调谐效率及调谐的响应速度都得到了极大提高。In this embodiment, since the thermal tuning efficiency of the material is basically not affected by the material band gap, in the chip design, a material with a higher material band gap can be used as the passive waveguide region used for wavelength tuning to further reduce passive The absorption loss of the material in the waveguide region reduces the chip threshold and reduces the laser linewidth. At the same time, the waveguide layer and the substrate are thermally isolated by air. Under the condition of constant thermal power of the chip, the thermal tuning efficiency and the tuning response speed are greatly improved.
下面,请参考图5。图5为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图。Below, please refer to Figure 5. 5 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application and a cross-sectional view along two dotted lines in the top view.
区别于图1对应的实施例,本实施例中具体介绍热调谐半导体芯片中还包括位于所述悬浮层和所述功能层之间的支撑层的情况。Different from the embodiment corresponding to FIG. 1 , this embodiment specifically introduces the case where the thermally tuned semiconductor chip further includes a support layer between the suspension layer and the functional layer.
如图5所示,所述热调谐半导体芯片,包括:衬底201,以及依次层叠于所述衬底201上的牺牲层202、悬浮层203、支撑层204和功能层205;其中,在所述衬底201、所述牺牲层202和所述悬浮层203内形成有悬浮区域209。As shown in FIG. 5, the thermally tuned semiconductor chip includes: a substrate 201, and a sacrificial layer 202, a suspension layer 203, a support layer 204 and a functional layer 205 stacked on the substrate 201 in sequence; A suspension region 209 is formed in the substrate 201 , the sacrificial layer 202 and the suspension layer 203 .
这里,所述衬底201为半导体衬底,其材料具体可以包括InP。所述衬底201的厚度例如大于150μm。Here, the substrate 201 is a semiconductor substrate, and its material may specifically include InP. The thickness of the substrate 201 is, for example, greater than 150 μm.
可以理解地,所述衬底包括处于正面的顶表面以及处于与正面相对的背面的底表面;在忽略顶表面和底表面的平整度的情况下,定义垂直衬底顶表面和底表面的方向为Z方向。Z方向也为后续在衬底上沉积各层结构的层叠方向,或称芯片的高度方向。而衬底顶表面和底表面所在的面,或者严格意义上讲衬底厚度方向上的中心面,即确定为衬底平面;平行衬底平面的方向即为沿衬底平面方向;Z方向即为垂直衬底平面的方向。在所述衬底平面方向上定义两彼此垂直的X方向和Y方向。It is understood that the substrate includes a top surface on the front side and a bottom surface on the back side opposite the front side; the directions perpendicular to the top and bottom surfaces of the substrate are defined, ignoring the flatness of the top and bottom surfaces for the Z direction. The Z direction is also the stacking direction of each layer structure subsequently deposited on the substrate, or the height direction of the chip. The surface where the top surface and the bottom surface of the substrate are located, or strictly speaking, the central plane in the thickness direction of the substrate, is determined as the substrate plane; the direction parallel to the substrate plane is the direction along the substrate plane; the Z direction is is the direction perpendicular to the substrate plane. Two X and Y directions that are perpendicular to each other are defined in the plane direction of the substrate.
所述牺牲层202、所述悬浮层203、所述支撑层204和所述功能层205中的至少之一可以通过沉积或蒸发的方式形成在所述衬底201上。At least one of the sacrificial layer 202 , the suspension layer 203 , the support layer 204 and the functional layer 205 may be formed on the substrate 201 by deposition or evaporation.
所述牺牲层202的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。所述牺牲层202的材料与所述衬底201的材料不同。作为一种具体实施方式,所述牺牲层202的材料为InGaAs;所述衬底201和所述悬浮层203的材料均为InP。所述牺牲层202的厚度范围为100nm~400nm。The material of the sacrificial layer 202 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs. The material of the sacrificial layer 202 is different from the material of the substrate 201 . As a specific implementation manner, the material of the sacrificial layer 202 is InGaAs; the material of the substrate 201 and the suspension layer 203 are both InP. The thickness of the sacrificial layer 202 ranges from 100 nm to 400 nm.
在一具体实施例中,所述牺牲层202的下表面与所述衬底201的上表面接触。换言之,所述牺牲层202与所述衬底201之间不包括其他材料层。如此,本实施例通过省去相关技术中的下限制层,而使得所述悬浮区域延伸扩展至所述衬底内部,从而增大了所述悬浮区域的整体深度,提高了器件的隔热性。In a specific embodiment, the lower surface of the sacrificial layer 202 is in contact with the upper surface of the substrate 201 . In other words, no other material layers are included between the sacrificial layer 202 and the substrate 201 . In this way, in this embodiment, by omitting the lower confinement layer in the related art, the suspension region extends to the inside of the substrate, thereby increasing the overall depth of the suspension region and improving the thermal insulation of the device .
所述悬浮层203的材料可以包括InP。所述悬浮层203的材料可以与所述衬底201的材料相同;所述悬浮层203的材料与所述牺牲层202的材料不同。所述悬浮层203的厚度例如大于所述牺牲层202的厚度;所述悬浮层203的厚度范围例如为200nm~500nm,具体例如为450nm~550nm。The material of the suspension layer 203 may include InP. The material of the suspension layer 203 may be the same as the material of the substrate 201 ; the material of the suspension layer 203 is different from the material of the sacrificial layer 202 . The thickness of the suspension layer 203 is, for example, greater than the thickness of the sacrificial layer 202 ; the thickness of the suspension layer 203 ranges from 200 nm to 500 nm, for example, and specifically ranges from 450 nm to 550 nm.
在本实施例中,所述悬浮区域209具体为从所述悬浮层203的上表面以下、延伸贯穿所述牺牲层202、并终止于所述衬底201内部的空腔结构,以使位于所述空腔结构上方的所述功能层205与所述空腔结构下方剩余的部分所述衬底201通过所述悬浮区域209隔离。In this embodiment, the suspension region 209 is a cavity structure extending from below the upper surface of the suspension layer 203, extending through the sacrificial layer 202, and terminating in the interior of the substrate 201, so that the The functional layer 205 above the cavity structure is isolated from the remaining part of the substrate 201 below the cavity structure by the suspension region 209 .
所述悬浮区域209的深度可以在10-15μm之间。The depth of the suspended region 209 may be between 10-15 μm.
在一具体实施例中,所述悬浮区域209包括位于所述衬底201内的第一部分、位于所述牺牲层202内的第二部分和位于所述悬浮层203内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。In a specific embodiment, the suspended region 209 includes a first portion within the substrate 201, a second portion within the sacrificial layer 202, and a third portion within the suspended layer 203, the The depth of the first portion is greater than the sum of the depths of the second portion and the third portion.
在一具体实施例中,所述悬浮区域209位于所述悬浮层203内的第三部分的深度大于所述悬浮区域209位于所述牺牲层202内的第二部分的深度。如此,所述第一部分在所述悬浮区域209中所占的比例是最大的;并且,具体地,所述第一部分的深度>第三部分的深度>第二部分的深度。In a specific embodiment, the depth of the third portion of the suspension region 209 in the suspension layer 203 is greater than the depth of the second portion of the suspension region 209 in the sacrificial layer 202 . In this way, the proportion of the first part in the floating area 209 is the largest; and, specifically, the depth of the first part>the depth of the third part>the depth of the second part.
请继续参考图5,所述悬浮区域209在沿垂直衬底平面方向上的剖面呈六边形。所述悬浮区域209的侧壁在平行衬底平面方向上的距离从所述悬浮层203到所述牺牲层202增大。在所述第一部分的深度大于所述第二部 分和所述第三部分的深度之和的实施例中,所述悬浮区域209的侧壁在平行衬底平面方向上的距离在所述衬底201内获得最大,并从最大的位置处向下减小。Please continue to refer to FIG. 5 , the cross section of the suspension area 209 along the direction perpendicular to the plane of the substrate is hexagonal. The distance of the sidewall of the suspension region 209 in a direction parallel to the plane of the substrate increases from the suspension layer 203 to the sacrificial layer 202 . In the embodiment in which the depth of the first part is greater than the sum of the depths of the second part and the third part, the distance between the sidewalls of the suspended region 209 in a direction parallel to the plane of the substrate Get the maximum in 201 and decrease down from the maximum position.
在本申请实施例中,悬浮区域的厚度远大于牺牲层的厚度,从而在垂直于芯片表面(即垂直于衬底)的方向上,悬浮区域的上下表面之间存在较大空隙。In the embodiment of the present application, the thickness of the suspension region is much larger than the thickness of the sacrificial layer, so that in the direction perpendicular to the chip surface (ie, perpendicular to the substrate), there is a large gap between the upper and lower surfaces of the suspension region.
所述支撑层204的材料可以与所述衬底201的材料相同。在一具体实施例中,所述支撑层204的材料包括InP。The material of the support layer 204 may be the same as the material of the substrate 201 . In a specific embodiment, the material of the support layer 204 includes InP.
所述支撑层的厚度可以大于所述牺牲层的厚度。所述支撑层的厚度可以与所述悬浮层的厚度大致相同;在实际工艺中,所述支撑层的厚度范围例如为200nm~500nm。The thickness of the support layer may be greater than that of the sacrificial layer. The thickness of the support layer may be approximately the same as the thickness of the suspension layer; in an actual process, the thickness of the support layer ranges from 200 nm to 500 nm, for example.
请继续参考图5,在一实施例中,所述热调谐半导体芯片还包括:层叠于所述衬底201上并位于所述悬浮层203和所述支撑层204之间的刻蚀阻挡层2041,所述刻蚀阻挡层2041的下表面与所述悬浮层203的上表面接触,所述刻蚀阻挡层2041在刻蚀所述悬浮层203以形成所述悬浮区域209的工艺中起到刻蚀阻挡作用。Please continue to refer to FIG. 5 , in one embodiment, the thermally tuned semiconductor chip further includes: an etch stop layer 2041 stacked on the substrate 201 and located between the suspension layer 203 and the support layer 204 , the lower surface of the etch stop layer 2041 is in contact with the upper surface of the suspension layer 203 , and the etch stop layer 2041 plays an etched role in the process of etching the suspension layer 203 to form the suspension region 209 Erosion blocking effect.
容易理解地,为了起到刻蚀阻挡作用,所述刻蚀阻挡层的材料应当与所述支撑层的材料不同。在实际工艺中,所述刻蚀阻挡层的材料可以与所述牺牲层的材料相同。具体地,所述刻蚀阻挡层的材料可以为InGaAsP或AlGaInAs。It is easy to understand that, in order to function as an etch barrier, the material of the etch barrier layer should be different from the material of the support layer. In an actual process, the material of the etch barrier layer may be the same as the material of the sacrificial layer. Specifically, the material of the etching barrier layer may be InGaAsP or AlGaInAs.
所述功能层205用于向所述热调谐半导体芯片的热调谐电极(图中未示出)传递热量。The functional layer 205 is used to transfer heat to a thermally tuned electrode (not shown in the figure) of the thermally tuned semiconductor chip.
所述功能层205可以包括第一子功能层2051。所述第一子功能层2051的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。在一具体实施例中,所述第一子功能层2051为量子阱层。The functional layer 205 may include a first sub-functional layer 2051 . The material of the first sub-functional layer 2051 includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs. In a specific embodiment, the first sub-functional layer 2051 is a quantum well layer.
所述功能层205的具体结构依据实际场景而定,可以为以下之一:激光器层状结构、探测器层状结构、调制器层状结构或无源波导层状结构。作为一种具体的实施方式,所述功能层205可以包括沿所述衬底201从下向上的下波导层(材料例如为InGaAsP),波导芯层(材料例如为InGaAsP),以及上波导层(材料例如为InGaAsP);所述功能层205还可以包括位于上波导层上的包层(材料例如为InP)。还可以包括:电极接触层(材料例如为InGaAs)。The specific structure of the functional layer 205 depends on the actual scene, and may be one of the following: a laser layered structure, a detector layered structure, a modulator layered structure or a passive waveguide layered structure. As a specific implementation manner, the functional layer 205 may include a lower waveguide layer (such as InGaAsP) along the substrate 201 from bottom to top, a waveguide core layer (such as InGaAsP), and an upper waveguide layer ( The material is, for example, InGaAsP); the functional layer 205 may further include a cladding layer (the material is, for example, InP) located on the upper waveguide layer. It may also include: an electrode contact layer (the material is, for example, InGaAs).
在所述功能层205包括第一子功能层2051的实施例中,所述下波导层位于所述第一子功能层2051上。所述下波导层可能仅位于部分所述第一子功能层2051上;换言之,所述功能层205在一部分区域上仅包括所述第一子功能层2051,在另一部分区域上包括所述第一子功能层2051以及位于所述第一子功能层2051上的其他子功能层。In the embodiment in which the functional layer 205 includes a first sub-functional layer 2051 , the lower waveguide layer is located on the first sub-functional layer 2051 . The lower waveguide layer may only be located on a part of the first sub-functional layer 2051; in other words, the functional layer 205 only includes the first sub-functional layer 2051 in a part of the region, and includes the first sub-functional layer 2051 in another part of the region. A sub-functional layer 2051 and other sub-functional layers located on the first sub-functional layer 2051 .
所述半导体芯片还可以包括与所述悬浮区域209连通的通孔207。所述通孔207例如贯穿所述功能层205和所述悬浮层203;在所述功能层205包括第一子功能层2051的实施例中,还贯穿所述第一子功能层2051。The semiconductor chip may further include through holes 207 communicating with the floating region 209 . For example, the through hole 207 penetrates the functional layer 205 and the suspension layer 203 ; in the embodiment where the functional layer 205 includes the first sub-functional layer 2051 , it also penetrates the first sub-functional layer 2051 .
在所述通孔207的侧壁上还可以覆盖有掩膜层206。所述掩膜层206用于在形成所述悬浮区域的刻蚀工艺中保护位于所述掩膜层206以内的功能层205和悬浮层203。所述掩膜层206底端具有开口208;所述开口208贯穿所述掩膜层206,连通所述通孔207和所述悬浮区域209。所述掩膜层206还可以覆盖在所述功能层205上,这里并不做具体限定。A mask layer 206 may also be covered on the sidewalls of the through holes 207 . The mask layer 206 is used to protect the functional layer 205 and the suspension layer 203 within the mask layer 206 during the etching process for forming the suspension region. The bottom end of the mask layer 206 has an opening 208 ; the opening 208 penetrates the mask layer 206 and communicates with the through hole 207 and the suspension area 209 . The mask layer 206 may also cover the functional layer 205, which is not specifically limited here.
应当理解,所述开口208位于所述通孔207内。图5中示出了所述开口208的开口尺寸小于所述通孔207的开口尺寸的情况;当然,所述开口208的开口尺寸也可以等于所述通孔207的开口尺寸,或更具体地等于所述通孔207的开口尺寸减去所述掩膜层206的两边侧壁厚度。It should be understood that the opening 208 is located in the through hole 207 . FIG. 5 shows the case where the opening size of the opening 208 is smaller than the opening size of the through hole 207; of course, the opening size of the opening 208 can also be equal to the opening size of the through hole 207, or more specifically It is equal to the opening size of the through hole 207 minus the thickness of the two sidewalls of the mask layer 206 .
所述通孔207和所述开口208的开口形状可以为圆形、方形、菱形或 者其他形状,依据实际情况设计即可,在此不做具体限定。The opening shape of the through hole 207 and the opening 208 may be a circle, a square, a diamond or other shapes, which can be designed according to the actual situation, which is not specifically limited here.
与一个所述悬浮区域对应的所述通孔/所述开口的数量可以为两个以上。在图5对应的实施例中,与一个所述悬浮区域209对应的所述通孔207/所述开口208的数量具体为两个;并且,两个所述通孔207/所述开口208可以在所述悬浮区域209上对称布置,具体可以沿所述悬浮区域209的中轴线左右对称布置。The number of the through holes/the openings corresponding to one floating area may be two or more. In the embodiment corresponding to FIG. 5 , the number of the through holes 207/the openings 208 corresponding to one floating area 209 is specifically two; and the two through holes 207/the openings 208 may be They are arranged symmetrically on the suspension area 209 , specifically, they may be arranged symmetrically on the left and right sides along the central axis of the suspension area 209 .
在所述热调谐半导体芯片还包括与所述悬浮区域连通的至少两个开口的实施例中,所述悬浮区域209在至少两个所述开口中的任意两个之间(如图5中两个开口208之间)的上表面为平面,所述平面与所述悬浮层203的上表面共面。In the embodiment in which the thermally tuned semiconductor chip further includes at least two openings in communication with the suspension area, the suspension area 209 is between any two of the at least two openings (as shown in FIG. The upper surface between the openings 208 ) is a plane, and the plane is coplanar with the upper surface of the suspension layer 203 .
所述衬底201、所述牺牲层202和所述悬浮层203沿悬浮区域209的周向设置,并构成所述悬浮区域209的侧壁和底壁,以使所述功能层205悬浮设置在所述衬底201上。由于功能层205与衬底201之间存在很大的空气隔离间隔,因此,可以减少从衬底201散发的热量,从而提高所述半导体芯片的热调谐效率。The substrate 201, the sacrificial layer 202 and the suspension layer 203 are arranged along the circumference of the suspension area 209, and constitute the side wall and bottom wall of the suspension area 209, so that the functional layer 205 is suspended in the suspension area 209. on the substrate 201 . Since there is a large air isolation interval between the functional layer 205 and the substrate 201, the heat dissipated from the substrate 201 can be reduced, thereby improving the thermal tuning efficiency of the semiconductor chip.
此外,所述支撑层204至少包括位于所述空腔结构(即所述悬浮区域209)上方的部分,以支撑位于所述空腔结构上方的所述功能层205,从而增强了所述热调谐半导体芯片的机械强度,并且使得形成所述悬浮区域209的刻蚀工艺更容易实施,提高了产品良率。In addition, the support layer 204 includes at least a portion above the cavity structure (ie, the suspension region 209 ) to support the functional layer 205 above the cavity structure, thereby enhancing the thermal tuning The mechanical strength of the semiconductor chip is improved, and the etching process for forming the floating region 209 is easier to implement, thereby improving the product yield.
下面,请参考图6。图6为本申请另一实施例提供的热调谐半导体芯片的顶视图以及沿所述顶视图中两条虚线位置处的剖视图。Next, please refer to FIG. 6 . 6 is a top view of a thermally tuned semiconductor chip provided by another embodiment of the present application, and a cross-sectional view along two dotted lines in the top view.
区别于图5对应的实施例,本实施例中具体介绍半导体芯片中包括多个悬浮区域209的情况。相应的,半导体芯片包括多组通孔(如图中207、207')和开口(如图中208、208');由于开口是与通孔一一对应的,因此,下面仅以通孔进行说明。与多个悬浮区域209连通的多组通孔之间(如图 中207与207'之间)可以是等间距排列或者是不等间距排列,依据实际情况而定。多个所述悬浮区域209可以呈阵列分布,从而多组通孔/多组开口也可以呈阵列分布。Different from the embodiment corresponding to FIG. 5 , the present embodiment specifically introduces the case where the semiconductor chip includes a plurality of floating regions 209 . Correspondingly, the semiconductor chip includes multiple groups of through holes (207, 207' in the figure) and openings (208, 208' in the figure); since the openings correspond to the through holes one-to-one, only the through holes are used below. illustrate. The groups of through holes communicating with the plurality of suspension regions 209 (between 207 and 207' in the figure) may be arranged at equal intervals or at unequal intervals, depending on the actual situation. A plurality of the suspension regions 209 may be distributed in an array, so that groups of through holes/groups of openings may also be distributed in an array.
如图6中顶视图所示,同一行的两个通孔与该行对应悬浮区域连通,另一行的两个通孔与该行对应悬浮区域连通,相邻行的通孔之间牺牲层202、悬浮层203、支撑层204和功能层205在沿各层横向延展的方向(X方向)上是连续的,同一行的通孔之间的牺牲层202、悬浮层203、支撑层204和功能层205在沿各层纵向延展的方向(Y方向)上是连续的,保证了位于半导体芯片的衬底201、牺牲层202、悬浮层203只是与悬浮区域209对应的位置处被掏空,而悬浮区域209周向的衬底201、牺牲层202、悬浮层203在沿衬底平面的延展方向上是连续。腐蚀形成所述悬浮区域209后,悬浮区域209在沿半导体芯片表面的延展方向上是连续的,并被限制在通孔和开口附近的区域;区域内未被腐蚀的结构层(掩膜层206、功能层205、支撑层204,未被去除的部分悬浮层203、牺牲层202和衬底201)与区域外结构相连接,从而保证功能层205能够连接在一起,进而悬浮在衬底201上。As shown in the top view in FIG. 6 , the two through holes in the same row are connected to the corresponding suspension area of the row, the two through holes of the other row are connected to the corresponding suspension area of the row, and the sacrificial layer 202 is between the through holes of adjacent rows. , the suspension layer 203, the support layer 204 and the functional layer 205 are continuous in the direction (X direction) extending laterally along each layer, the sacrificial layer 202, the suspension layer 203, the support layer 204 and the function between the via holes in the same row The layer 205 is continuous in the longitudinal extension direction (Y direction) of each layer, which ensures that the substrate 201, the sacrificial layer 202, and the suspension layer 203 located in the semiconductor chip are only hollowed out at the positions corresponding to the suspension area 209, and The substrate 201 , the sacrificial layer 202 and the suspension layer 203 in the circumferential direction of the suspension region 209 are continuous in the extension direction along the substrate plane. After etching to form the suspended area 209, the suspended area 209 is continuous in the extension direction along the surface of the semiconductor chip, and is limited to the area near the through hole and the opening; the structural layer (mask layer 206) that is not etched in the area , the functional layer 205, the support layer 204, the unremoved part of the suspended layer 203, the sacrificial layer 202 and the substrate 201) are connected to the structure outside the area, so as to ensure that the functional layer 205 can be connected together, and then suspended on the substrate 201 .
在一些实施例中,位于不同行的通孔所对应的悬浮区域也可以连通。如此,形成的连通的悬浮区域的整体可以理解为包括多个子悬浮区域。In some embodiments, the suspension regions corresponding to the through holes located in different rows may also communicate. In this way, the entirety of the formed connected suspension areas can be understood as including a plurality of sub-suspended areas.
本申请实施例还提供了一种热调谐半导体芯片的制备方法;具体请参见附图7。如7图所示,所述方法包括以下步骤:The embodiment of the present application also provides a method for preparing a thermally tuned semiconductor chip; for details, please refer to FIG. 7 . As shown in Figure 7, the method includes the following steps:
步骤401、提供衬底,在所述衬底上依次形成牺牲层、悬浮层、支撑层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量; Step 401 , providing a substrate, and forming a sacrificial layer, a suspension layer, a support layer and a functional layer in sequence on the substrate; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
步骤402、形成通孔,所述通孔贯穿所述功能层、所述支撑层和所述悬浮层并暴露出部分所述牺牲层; Step 402 , forming a through hole, the through hole passing through the functional layer, the support layer and the suspension layer and exposing part of the sacrificial layer;
步骤403、对所述牺牲层、所述悬浮层和所述衬底进行刻蚀,以形成悬浮区域;所述悬浮区域为从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离;所述支撑层至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层。Step 403: Etch the sacrificial layer, the suspension layer, and the substrate to form a suspension area; the suspension area extends through the sacrificial layer from below the upper surface of the suspension layer, and a cavity structure terminating inside the substrate such that the functional layer above the cavity structure is isolated from the remaining portion of the substrate below the cavity structure by the suspension region; the support The layer includes at least a portion overlying the cavity structure to support the functional layer overlying the cavity structure.
下面,结合图8a至8d中热调谐半导体芯片的制备过程中的结构剖面示意图,对图5所示的热调谐半导体芯片及其制备方法再作进一步详细的说明。Next, the thermally tuned semiconductor chip and its manufacturing method shown in FIG. 5 will be further described in detail with reference to the schematic cross-sectional views of the structure in the manufacturing process of the thermally tuned semiconductor chip in FIGS. 8 a to 8 d .
首先,请参考图8a。提供衬底201,在所述衬底201上依次形成牺牲层202、悬浮层203、支撑层204和功能层205;所述功能层205用于向所述热调谐半导体芯片的热调谐电极传递热量。First, please refer to Figure 8a. A substrate 201 is provided, on which a sacrificial layer 202, a suspension layer 203, a support layer 204 and a functional layer 205 are formed in sequence; the functional layer 205 is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip .
这里,所述支撑层的材料可以与所述衬底的材料相同。在一具体实施例中,所述支撑层的材料包括InP。Here, the material of the support layer may be the same as that of the substrate. In a specific embodiment, the material of the support layer includes InP.
所述支撑层的厚度可以大于所述牺牲层的厚度。所述支撑层的厚度可以与所述悬浮层的厚度大致相同;在实际工艺中,所述支撑层的厚度范围例如为200nm~500nm。The thickness of the support layer may be greater than that of the sacrificial layer. The thickness of the support layer may be approximately the same as the thickness of the suspension layer; in an actual process, the thickness of the support layer ranges from 200 nm to 500 nm, for example.
在一具体实施例中,在所述衬底201上形成所述牺牲层202,具体包括:在所述衬底201上直接形成所述牺牲层202,以使所述牺牲层202的下表面与所述衬底201的上表面接触。换言之,所述牺牲层202与所述衬底201之间不包括其他材料层。如此,本实施例通过省去相关技术中的下限制层,而使得后续采用第二刻蚀工艺对所述衬底进行刻蚀的工序更容易实施,进而形成的所述悬浮区域延伸扩展至所述衬底内部,增大了所述悬浮区域的整体深度,提高了器件的隔热性。In a specific embodiment, forming the sacrificial layer 202 on the substrate 201 specifically includes: directly forming the sacrificial layer 202 on the substrate 201, so that the lower surface of the sacrificial layer 202 and The upper surface of the substrate 201 is in contact. In other words, no other material layers are included between the sacrificial layer 202 and the substrate 201 . In this way, in this embodiment, by omitting the lower confinement layer in the related art, the subsequent process of etching the substrate by the second etching process is easier to implement, and the formed floating region extends to all the Inside the substrate, the overall depth of the suspension region is increased, and the thermal insulation of the device is improved.
在一具体实施例中,所述依次形成牺牲层、悬浮层、支撑层和功能层, 具体可以包括:在形成所述悬浮层203后,在所述悬浮层203上形成刻蚀阻挡层2041,所述刻蚀阻挡层2041的下表面与所述悬浮层203的上表面接触,在所述刻蚀阻挡层2041上形成所述支撑层204。In a specific embodiment, forming the sacrificial layer, the suspension layer, the support layer and the functional layer in sequence may specifically include: after forming the suspension layer 203, forming an etching barrier layer 2041 on the suspension layer 203, The lower surface of the etch stop layer 2041 is in contact with the upper surface of the suspension layer 203 , and the support layer 204 is formed on the etch stop layer 2041 .
容易理解地,为了起到刻蚀阻挡作用,所述刻蚀阻挡层的材料应当与所述支撑层的材料不同。在实际工艺中,所述刻蚀阻挡层的材料可以与所述牺牲层的材料相同。具体地,所述刻蚀阻挡层的材料可以为InGaAsP或AlGaInAs。It is easy to understand that, in order to function as an etch barrier, the material of the etch barrier layer should be different from the material of the support layer. In an actual process, the material of the etch barrier layer may be the same as the material of the sacrificial layer. Specifically, the material of the etching barrier layer may be InGaAsP or AlGaInAs.
下面,以半导体芯片为无源波导为例解释说明,在本实施例中,首先在衬底201上牺牲层202,牺牲层202的材料例如为InGaAsP,厚度例如为0.02μm+/0.05μm;悬浮层203的材料例如为InP,厚度例如为1μm+/0.05μm;刻蚀阻挡层2041的材料例如为InGaAs,厚度例如为0.2μm+/0.05μm;支撑层204的材料例如为InP,厚度例如为500nm;功能层205例如包括第一子功能层2051以及位于所述第一子功能层2051上的下波导层、波导芯层、波导芯层、包层和电极接触层;第一子功能层2051的材料例如为InGaAs,厚度例如为0.2μm+/0.05μm;下波导层的材料例如为InGaAsP,厚度例如为0.1μm+/0.05μm;波导芯层的材料例如为InGaAsP,厚度例如为0.2μm+/0.05μm;波导芯层的材料例如为InGaAsP,厚度例如为0.1μm+/0.05μm;包层的材料例如为InP,厚度例如为1.5μm+/0.05μm;以及电极接触层的材料例如为InGaAs,厚度例如为0.2μm+/0.05μm。In the following, the semiconductor chip is used as a passive waveguide as an example for explanation. In this embodiment, a sacrificial layer 202 is firstly formed on the substrate 201. The material of the sacrificial layer 202 is, for example, InGaAsP, and the thickness is, for example, 0.02 μm+/0.05 μm; The material of 203 is, for example, InP, and the thickness is, for example, 1 μm+/0.05 μm; the material of the etching barrier layer 2041 is, for example, InGaAs, and the thickness is, for example, 0.2 μm+/0.05 μm; The layer 205 includes, for example, a first sub-functional layer 2051 and a lower waveguide layer, a waveguide core layer, a waveguide core layer, a cladding layer and an electrode contact layer located on the first sub-functional layer 2051; the material of the first sub-functional layer 2051 is, for example, InGaAs, the thickness is for example 0.2μm+/0.05μm; the material of the lower waveguide layer is InGaAsP, for example, the thickness is 0.1μm+/0.05μm; the material of the waveguide core layer is InGaAsP, for example, the thickness is 0.2μm+/0.05μm; the waveguide core The material of the layer is, for example, InGaAsP, and the thickness is, for example, 0.1 μm+/0.05 μm; the material of the cladding layer is, for example, InP, the thickness is, for example, 1.5 μm+/0.05 μm; and the material of the electrode contact layer is, for example, InGaAs, the thickness is, for example, 0.2 μm+/0.05 μm.
上述各层可以通过沉积或蒸发的方式形成在所述衬底201上。在完成上述各层的外延以后,即可进行悬浮区域209的制作。The above-mentioned layers can be formed on the substrate 201 by deposition or evaporation. After the epitaxy of the above-mentioned layers is completed, the floating region 209 can be fabricated.
为了形成悬浮区域209,可以在上述各层上形成图案化的第一掩膜层210,所述第一掩膜层210定义出后续形成通孔207的位置。所述第一掩膜层210的图案化可以通过光刻的方式实现。In order to form the floating region 209 , a patterned first mask layer 210 may be formed on the above-mentioned layers, and the first mask layer 210 defines the positions where the through holes 207 are subsequently formed. The patterning of the first mask layer 210 can be achieved by photolithography.
接下来,请参考图8b。形成通孔207,所述通孔207贯穿所述功能层 205、所述支撑层204和所述悬浮层203并暴露出部分所述牺牲层202。Next, please refer to Figure 8b. A through hole 207 is formed, the through hole 207 penetrates the functional layer 205, the support layer 204 and the suspension layer 203 and exposes a part of the sacrificial layer 202.
在所述方法具体包括在所述悬浮层203上形成刻蚀阻挡层2041的实施例中,所述通孔207还贯穿所述刻蚀阻挡层2041。In an embodiment in which the method specifically includes forming an etch stop layer 2041 on the suspension layer 203 , the through hole 207 also penetrates the etch stop layer 2041 .
在具体制备中,在所述半导体芯片的左右两侧形成沿靠近所述衬底201方向上延展的刻蚀孔(即通孔207),其中,所述刻蚀孔在沿靠近所述衬底201方向上依次穿透掩膜206、功能层205、支撑层204和悬浮层203。所述通孔207还可以穿过部分所述牺牲层202;即所述通孔207可以深入所述牺牲层202内(图中未示出这种情况)。如此,通过光刻的方式在半导体芯片表面定义出相应的刻蚀孔图形,基于定义好的刻蚀孔图形在半导体芯片上左右两侧进行刻蚀,例如反应离子(RIE)刻蚀,从而在所述半导体芯片的左右两侧形成沿靠近所述衬底方向上延展的刻蚀孔。其中,刻蚀孔的开口可以是方形、圆形、或者其他图形。In the specific preparation, etching holes (ie, through holes 207 ) extending in the direction close to the substrate 201 are formed on the left and right sides of the semiconductor chip, wherein the etching holes are formed along the direction close to the substrate The mask 206 , the functional layer 205 , the support layer 204 and the suspension layer 203 are sequentially penetrated in the direction 201 . The through hole 207 may also pass through part of the sacrificial layer 202; that is, the through hole 207 may penetrate deep into the sacrificial layer 202 (this is not shown in the figure). In this way, a corresponding etching hole pattern is defined on the surface of the semiconductor chip by means of photolithography, and etching is performed on the left and right sides of the semiconductor chip based on the defined etching hole pattern, such as reactive ion (RIE) etching, so as to Etching holes extending in a direction close to the substrate are formed on the left and right sides of the semiconductor chip. Wherein, the opening of the etching hole may be a square, a circle, or other shapes.
接下来,请参考图8c。对所述牺牲层202进行刻蚀,以形成悬浮区域的一部分,即所述第二部分。Next, please refer to Figure 8c. The sacrificial layer 202 is etched to form a portion of the suspended region, that is, the second portion.
具体地,在图8b中形成所述贯穿所述功能层205、所述支撑层204和所述悬浮层203的通孔207后,所述方法还包括:形成掩膜层206,所述掩膜层206至少覆盖所述通孔207的侧壁。此外,所述掩膜层206也可以覆盖在所述半导体芯片的顶面上,例如覆盖在所述功能层205上。Specifically, after forming the through hole 207 through the functional layer 205, the support layer 204 and the suspension layer 203 in FIG. 8b, the method further includes: forming a mask layer 206, the mask layer The layer 206 covers at least the sidewalls of the through holes 207 . In addition, the mask layer 206 may also cover the top surface of the semiconductor chip, for example, the functional layer 205 .
接下来,在所述掩膜层206底端形成开口208,所述开口208暴露出部分所述牺牲层202。Next, an opening 208 is formed at the bottom end of the mask layer 206 , and the opening 208 exposes a part of the sacrificial layer 202 .
应当理解,所述开口208位于所述通孔207内。图8c中示出了所述开口208的开口尺寸小于所述通孔207的开口尺寸的情况;当然,所述开口208的开口尺寸也可以等于所述通孔207的开口尺寸,或更具体地等于所述通孔207的开口尺寸减去所述掩膜层206的两边侧壁厚度。It should be understood that the opening 208 is located in the through hole 207 . Fig. 8c shows the case where the opening size of the opening 208 is smaller than the opening size of the through hole 207; of course, the opening size of the opening 208 can also be equal to the opening size of the through hole 207, or more specifically It is equal to the opening size of the through hole 207 minus the thickness of the two sidewalls of the mask layer 206 .
在具体制备中,在所述半导体芯片的左右两侧形成沿靠近所述衬底方 向上延展的腐蚀孔(即开口208),所述腐蚀孔在沿靠近所述衬底方向上穿透所述掩膜。在本实施例中,使用HF酸腐蚀液去除第一掩膜层210,重新生长掩膜层206(也可称为第二掩膜层)。通过光刻的方式在半导体芯片的表面定义出相应的腐蚀孔图形,基于定义好的腐蚀孔图形在半导体芯片上左右两侧进行RIE刻蚀,从而在所述半导体芯片的左右两侧形成沿靠近所述衬底方向上延展的腐蚀孔。其中,腐蚀孔的开口可以是方形、圆形、或者其他图形。In specific preparation, etching holes (ie, openings 208 ) extending in a direction close to the substrate are formed on the left and right sides of the semiconductor chip, and the etching holes penetrate the substrate in a direction close to the substrate. mask. In this embodiment, the first mask layer 210 is removed by using HF acid etching solution, and the mask layer 206 (also referred to as the second mask layer) is re-grown. Corresponding etching hole patterns are defined on the surface of the semiconductor chip by means of photolithography, and RIE etching is performed on the left and right sides of the semiconductor chip based on the defined etching hole patterns, so that the left and right sides of the semiconductor chip are formed along the Etched holes extending in the direction of the substrate. Wherein, the opening of the etching hole may be a square, a circle, or other shapes.
接下来,采用第一刻蚀工艺对所述牺牲层202进行刻蚀,暴露出所述衬底201的部分上表面和所述悬浮层203的部分下表面。Next, the sacrificial layer 202 is etched by a first etching process to expose a part of the upper surface of the substrate 201 and a part of the lower surface of the suspension layer 203 .
这里,所述第一刻蚀工艺可以为湿法刻蚀工艺。所述牺牲层202可以采用第一腐蚀液腐蚀。在实际应用场景中,所述牺牲层202的组成成分包括InGaAs材料。采用第一腐蚀液去除部分所述牺牲层202,所述第一腐蚀液通过开口208注入到半导体芯片中。第一腐蚀液对牺牲层202中的InGaAs材料进行选择性侧向腐蚀,使得部分牺牲层202被去除。其中,所述第一腐蚀液可以为硫酸系腐蚀液,即所述第一刻蚀工艺采用的刻蚀液可以包括硫酸系溶液;硫酸系腐蚀液对InGaAs材料进行选择性腐蚀,而对InP材料无腐蚀作用,因此,在衬底201和悬浮层203为的材料InP的实施例中,所述衬底201和所述悬浮层203能够保持非腐蚀状态。Here, the first etching process may be a wet etching process. The sacrificial layer 202 can be etched with a first etching solution. In a practical application scenario, the composition of the sacrificial layer 202 includes InGaAs material. Part of the sacrificial layer 202 is removed by using a first etching solution, and the first etching solution is injected into the semiconductor chip through the opening 208 . The first etching solution performs selective lateral etching on the InGaAs material in the sacrificial layer 202, so that part of the sacrificial layer 202 is removed. Wherein, the first etching solution may be a sulfuric acid-based etching solution, that is, the etching solution used in the first etching process may include a sulfuric acid-based solution; the sulfuric acid-based etching solution selectively etches the InGaAs material, while the InP material is There is no corrosion effect. Therefore, in the embodiment in which the substrate 201 and the suspension layer 203 are InP, the substrate 201 and the suspension layer 203 can remain in a non-etched state.
所述牺牲层202经过刻蚀后形成的开口尺寸大于所述通孔207的开口尺寸。The size of the opening formed after the sacrificial layer 202 is etched is larger than the size of the opening of the through hole 207 .
这里,由于支撑层204的存在,所述热调谐半导体芯片可以具有更高的机械强度,从而在对所述牺牲层202进行刻蚀时,所述牺牲层202的位于相邻两个所述通孔207/所述开口208之间的部分可以被完全去除。Here, due to the existence of the support layer 204, the thermally tuned semiconductor chip can have higher mechanical strength, so that when the sacrificial layer 202 is etched, the sacrificial layer 202 is located adjacent to two of the through holes. The portion between the hole 207/the opening 208 can be completely removed.
接下来,请参考图8d。进一步对所述悬浮层203和所述衬底201进行刻蚀,以最终形成悬浮区域209。Next, please refer to Figure 8d. The suspension layer 203 and the substrate 201 are further etched to finally form a suspension region 209 .
具体地,在采用第一刻蚀工艺对所述牺牲层进行刻蚀后,采用第二刻蚀工艺对所述悬浮层和所述衬底进行刻蚀,以形成所述悬浮区域。Specifically, after the sacrificial layer is etched by the first etching process, the suspension layer and the substrate are etched by the second etching process to form the suspension region.
这里,所述第二刻蚀工艺可以为湿法刻蚀工艺。所述悬浮层203和所述衬底201可以采用第二腐蚀液腐蚀。在实际应用场景中,所述第二腐蚀液通过左右腐蚀孔以及连接腐蚀孔的通道注入道半导体芯片中,第二腐蚀液对所述衬底和悬浮层中的InP材料选择性腐蚀,使得部分所述衬底和悬浮层被去除,从而形成悬浮区域。其中,所述第二腐蚀液可以为盐酸系腐蚀液,即所述第二刻蚀工艺采用的刻蚀液可以包括盐酸系溶液;由于盐酸系溶液不能腐蚀InGaAsP材料,因此该步腐蚀会停止在刻蚀阻挡层以下,保护半导体芯片原各层材料不受腐蚀影响。同时,衬底层厚度远大于其他层厚度,因此控制腐蚀时间,可以保证半导体芯片的结构稳定。Here, the second etching process may be a wet etching process. The suspension layer 203 and the substrate 201 may be etched with a second etching solution. In a practical application scenario, the second etching solution is injected into the semiconductor chip through the left and right etching holes and the channels connecting the etching holes, and the second etching solution selectively corrodes the InP material in the substrate and the suspension layer, so that some The substrate and suspended layer are removed, thereby forming a suspended region. Wherein, the second etching solution may be a hydrochloric acid-based etching solution, that is, the etching solution used in the second etching process may include a hydrochloric acid-based solution; since the hydrochloric acid-based solution cannot corrode the InGaAsP material, this step of etching will stop at Below the etching barrier layer, the materials of the original layers of the semiconductor chip are protected from corrosion. At the same time, the thickness of the substrate layer is much larger than that of other layers, so controlling the etching time can ensure the structural stability of the semiconductor chip.
如此,在本申请的一具体实施例中,在对所述悬浮层203进行刻蚀时,所述刻蚀阻挡层2041阻挡刻蚀反应朝向所述支撑层204的一侧进行。In this way, in a specific embodiment of the present application, when the suspension layer 203 is etched, the etching barrier layer 2041 blocks the etching reaction from proceeding toward the side of the support layer 204 .
在实际应用中,采用的所述第二腐蚀液腐蚀对InP材料的腐蚀具有能够腐蚀成固定腐蚀角度的特性。In practical applications, the second etching solution used to corrode the InP material has the characteristic of being able to corrode to a fixed corrosion angle.
从而,形成的所述悬浮区域209为从所述悬浮层203的上表面以下、延伸贯穿所述牺牲层202、并终止于所述衬底201内部的空腔结构,以使位于所述空腔结构上方的所述功能层205与所述空腔结构下方剩余的部分所述衬底201通过所述悬浮区域209隔离;所述支撑层204至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层205。Therefore, the formed suspension region 209 is a cavity structure extending from below the upper surface of the suspension layer 203, extending through the sacrificial layer 202, and terminating inside the substrate 201, so that the cavity is located in the cavity The functional layer 205 above the structure is isolated from the remaining part of the substrate 201 below the cavity structure by the suspension region 209; the support layer 204 includes at least the part above the cavity structure to support The functional layer 205 located above the cavity structure.
在本实施例中,首先腐蚀部分牺牲层202以预先定义悬浮区域209的图形,而后在依据预先定义的悬浮区域209的图形注入第二腐蚀液,进而腐蚀部分衬底201和悬浮层203以形成完整的悬浮区域209。同时,由于部分牺牲层202去除后,形成腐蚀通道,加大了第二腐蚀液与衬底201和悬浮层203的接触面积,提高了腐蚀的速率,缩短了制作时间。In this embodiment, part of the sacrificial layer 202 is first etched to define the pattern of the suspension region 209 in advance, and then a second etching solution is injected according to the predefined pattern of the suspension region 209, and then part of the substrate 201 and the suspension layer 203 are etched to form Complete suspension area 209. At the same time, since part of the sacrificial layer 202 is removed to form an etching channel, the contact area between the second etching solution and the substrate 201 and the suspension layer 203 is increased, the etching rate is increased, and the fabrication time is shortened.
在本实施例中,通过去除部分所述牺牲层202、衬底201和悬浮层203形成悬浮区域209,可以形成一个较厚的热隔离层,其厚度可以由刻蚀阻挡层2041与腐蚀时间决定,远大于目前常用方法制作的厚度。因此通过所述方法,可以获得较厚的热隔离层,同时不受较厚InGaAs层对半导体芯片生长质量的影响。In this embodiment, by removing part of the sacrificial layer 202, the substrate 201 and the suspension layer 203 to form the suspension region 209, a thicker thermal isolation layer can be formed, the thickness of which can be determined by the etching barrier layer 2041 and the etching time , which is much larger than the thickness produced by the currently commonly used method. Therefore, through the method, a thicker thermal isolation layer can be obtained without the influence of the thicker InGaAs layer on the growth quality of the semiconductor chip.
在本实施例中,悬浮区域209的深度决定了半导体芯片的热隔离的效果,较深的悬浮区域209能够提高半导体芯片热隔离的效果,提高半导体芯片热调谐效率及热调谐响应速度,有效解决目前半导体芯片热调谐效率低定位问题。In this embodiment, the depth of the suspension area 209 determines the effect of thermal isolation of the semiconductor chip. The deeper suspension area 209 can improve the effect of thermal isolation of the semiconductor chip, improve the thermal tuning efficiency and the thermal tuning response speed of the semiconductor chip, and effectively solve the problem. At present, the thermal tuning efficiency of semiconductor chips is low and localized.
在具体应用中,首先在半导体芯片表面定义出腐蚀孔,腐蚀孔为方形,大小为5μm*10μm,然后使用感应耦合等离子体(ICP)刻蚀机对腐蚀孔材料进行刻蚀,刻蚀深度为3.00μm~3.02μm之间。接下来,使用硫酸系溶液(如,硫酸:双氧水:水=5:1:1)进行腐蚀;再使用盐酸系溶液(如,HCl:H 3PO 4=3:1)进行再次腐蚀,去除部分悬浮层和衬底,形成悬浮区域。最后,半导体芯片的其余工艺按正常步骤进行即可,这里不再赘述。 In the specific application, the etching hole is first defined on the surface of the semiconductor chip, the etching hole is square and the size is 5μm*10μm, and then an inductively coupled plasma (ICP) etching machine is used to etch the etching hole material, and the etching depth is Between 3.00μm and 3.02μm. Next, use a sulfuric acid-based solution (eg, sulfuric acid: hydrogen peroxide: water = 5:1:1) for etching; then use a hydrochloric acid-based solution (eg, HCl: H 3 PO 4 = 3: 1) for re-etching to remove parts The suspended layer and the substrate form a suspended region. Finally, the remaining processes of the semiconductor chip may be performed according to normal steps, which will not be repeated here.
可以理解地,在所述形成通孔包括形成至少两个通孔207的实施例中,所述对所述牺牲层202、所述悬浮层203和所述衬底201进行刻蚀的步骤中,所述悬浮层203和所述牺牲层202的位于至少两个所述通孔207中的任意两个之间的部分被完全去除。It can be understood that, in the embodiment in which the formation of the through holes includes the formation of at least two through holes 207, in the step of etching the sacrificial layer 202, the suspension layer 203 and the substrate 201, Parts of the suspension layer 203 and the sacrificial layer 202 located between any two of the at least two through holes 207 are completely removed.
在本实施例中,由于材料的热调谐效率基本不受材料带隙的影响,因此在芯片设计中,可以使用材料带隙更高的材料作为波长调谐使用的无源波导区,进一步降低无源波导区材料的吸收损耗,降低芯片阈值,降低激光器线宽。同时,波导层与衬底通过空气进行热隔离,在芯片热功率一定的情况下,热调谐效率及调谐的响应速度都得到了极大提高。In this embodiment, since the thermal tuning efficiency of the material is basically not affected by the material band gap, in the chip design, a material with a higher material band gap can be used as the passive waveguide region used for wavelength tuning to further reduce passive The absorption loss of the material in the waveguide region reduces the chip threshold and reduces the laser linewidth. At the same time, the waveguide layer and the substrate are thermally isolated by air. Under the condition of constant thermal power of the chip, the thermal tuning efficiency and the tuning response speed are greatly improved.
需要说明的是,本申请提供的热调谐半导体芯片实施例与热调谐半导 体芯片的制备方法实施例属于同一构思;各实施例所记载的技术方案中各技术特征之间,在不冲突的情况下,可以任意组合。但需要进一步说明的是,本申请实施例提供的热调谐半导体芯片,其各技术特征组合已经可以解决本申请所要解决的技术问题;因而,本申请实施例所提供的热调谐半导体芯片可以不受本申请实施例提供的热调谐半导体芯片的制备方法的限制,任何能够形成本申请实施例所提供的热调谐半导体芯片结构的制备方法所制备的热调谐半导体芯片均在本申请保护的范围之内。It should be noted that the embodiment of the thermally tuned semiconductor chip provided by the present application and the embodiment of the method for preparing a thermally tuned semiconductor chip belong to the same concept; the technical features in the technical solutions described in the embodiments are not in conflict with each other. , which can be combined arbitrarily. However, it needs to be further explained that the thermally tuned semiconductor chips provided by the embodiments of the present application can already solve the technical problems to be solved by the technical features of the thermally tuned semiconductor chips provided by the embodiments of the present application; therefore, the thermally tuned semiconductor chips provided by the embodiments of the present application can Restrictions on the preparation method of the thermally tuned semiconductor chip provided by the embodiment of the present application, any thermally tuned semiconductor chip prepared by the preparation method of the thermally tuned semiconductor chip structure provided by the embodiment of the present application is within the scope of the protection of the present application .
以上所述,仅为本申请的较佳实施例而已,并非用于限定本申请的保护范围,凡在本申请的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本申请的保护范围之内。The above descriptions are only preferred embodiments of the present application, and are not intended to limit the protection scope of the present application. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present application shall be included in the within the scope of protection of this application.

Claims (25)

  1. 一种热调谐半导体芯片,包括:衬底,以及依次层叠于所述衬底上的牺牲层和功能层;所述功能层用于向所述热调谐半导体芯片的热调谐电极传递热量;其中,A thermally tuned semiconductor chip, comprising: a substrate, a sacrificial layer and a functional layer sequentially stacked on the substrate; the functional layer is used for transferring heat to a thermally tuned electrode of the thermally tuned semiconductor chip; wherein,
    在所述衬底和所述牺牲层内形成有悬浮区域,所述悬浮区域为贯穿所述牺牲层并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。A suspended area is formed in the substrate and the sacrificial layer, and the suspended area is a cavity structure penetrating the sacrificial layer and terminating inside the substrate, so that all parts above the cavity structure are formed. The functional layer is isolated from the remaining part of the substrate below the cavity structure by the suspension region.
  2. 根据权利要求1所述的热调谐半导体芯片,其中,还包括:The thermally tuned semiconductor chip of claim 1, further comprising:
    层叠于所述衬底上并位于所述牺牲层和所述功能层之间的悬浮层;a suspension layer stacked on the substrate and between the sacrificial layer and the functional layer;
    所述悬浮区域具体从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部。Specifically, the suspension region extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
  3. 根据权利要求2所述的热调谐半导体芯片,其中,还包括:The thermally tuned semiconductor chip of claim 2, further comprising:
    位于所述悬浮层和所述功能层之间的支撑层;a support layer between the suspension layer and the functional layer;
    所述支撑层至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层。The support layer includes at least a portion located above the cavity structure to support the functional layer located above the cavity structure.
  4. 根据权利要求2所述的热调谐半导体芯片,其中,The thermally tuned semiconductor chip of claim 2 wherein,
    所述悬浮区域包括位于所述衬底内的第一部分、位于所述牺牲层内的第二部分和位于所述悬浮层内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。The suspended region includes a first portion within the substrate, a second portion within the sacrificial layer, and a third portion within the suspended layer, the first portion having a depth greater than the second portion and The sum of the depths of the third part.
  5. 根据权利要求2所述的热调谐半导体芯片,其中,The thermally tuned semiconductor chip of claim 2 wherein,
    所述悬浮层的厚度大于所述牺牲层的厚度;所述悬浮区域位于所述悬浮层内的第三部分的深度大于所述悬浮区域位于所述牺牲层内的第二部分的深度。The thickness of the suspension layer is greater than the thickness of the sacrificial layer; the depth of the third portion of the suspension region located in the suspension layer is greater than the depth of the second portion of the suspension region located in the sacrificial layer.
  6. 根据权利要求2所述的热调谐半导体芯片,其中,所述悬浮层的材料与所述衬底的材料相同。The thermally tuned semiconductor chip of claim 2, wherein the material of the suspension layer is the same as the material of the substrate.
  7. 根据权利要求2所述的热调谐半导体芯片,其中,还包括:The thermally tuned semiconductor chip of claim 2, further comprising:
    与所述悬浮区域连通的至少两个开口,所述悬浮区域通过经由至少两个所述开口执行的刻蚀工艺而形成;at least two openings in communication with the suspended regions formed by an etching process performed through at least two of the openings;
    至少两个所述开口中的任意两个之间包括未被去除的部分悬浮层和未被去除的部分牺牲层。Parts of the suspension layer and part of the sacrificial layer that have not been removed are included between any two of at least two of the openings.
  8. 根据权利要求2所述的热调谐半导体芯片,其中,还包括:The thermally tuned semiconductor chip of claim 2, further comprising:
    与所述悬浮区域连通的至少两个开口,所述悬浮区域通过经由至少两个所述开口执行的刻蚀工艺而形成;at least two openings in communication with the suspended regions formed by an etching process performed through at least two of the openings;
    所述悬浮区域在至少两个所述开口中的任意两个之间的上表面为平面,所述平面与所述悬浮层的上表面共面。The upper surface of the suspension area between any two of the at least two openings is a plane, and the plane is coplanar with the upper surface of the suspension layer.
  9. 根据权利要求2所述的热调谐半导体芯片,其中,所述功能层包括第一子功能层,所述第一子功能层的下表面与所述悬浮层的上表面接触,用于在刻蚀所述悬浮层以形成所述悬浮区域的工艺中作为刻蚀阻挡层。The thermally tuned semiconductor chip of claim 2, wherein the functional layer comprises a first sub-functional layer, and the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer for etching The suspended layer is used as an etch stop layer in the process of forming the suspended region.
  10. 根据权利要求3所述的热调谐半导体芯片,其中,还包括:The thermally tuned semiconductor chip of claim 3, further comprising:
    层叠于所述衬底上并位于所述悬浮层和所述支撑层之间的刻蚀阻挡层,所述刻蚀阻挡层的下表面与所述悬浮层的上表面接触,所述刻蚀阻挡层在刻蚀所述悬浮层以形成所述悬浮区域的工艺中起到刻蚀阻挡作用。an etch stop layer stacked on the substrate and located between the suspension layer and the support layer, the lower surface of the etch stop layer is in contact with the upper surface of the suspension layer, the etch stop layer The layer acts as an etch stop during the process of etching the suspended layer to form the suspended region.
  11. 根据权利要求1所述的热调谐半导体芯片,其中,The thermally tuned semiconductor chip of claim 1 wherein,
    所述牺牲层的下表面与所述衬底的上表面接触。The lower surface of the sacrificial layer is in contact with the upper surface of the substrate.
  12. 根据权利要求1所述的热调谐半导体芯片,其中,The thermally tuned semiconductor chip of claim 1 wherein,
    所述牺牲层的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。The material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
  13. 一种热调谐半导体芯片的制备方法,所述方法包括:A preparation method of a thermally tuned semiconductor chip, the method comprising:
    提供衬底,在所述衬底上依次形成牺牲层和功能层;所述功能层用于 向所述热调谐半导体芯片的热调谐电极传递热量;providing a substrate on which a sacrificial layer and a functional layer are sequentially formed; the functional layer is used to transfer heat to the thermally tuned electrodes of the thermally tuned semiconductor chip;
    形成通孔,所述通孔贯穿所述功能层并暴露出部分所述牺牲层;forming a through hole that penetrates the functional layer and exposes part of the sacrificial layer;
    对所述牺牲层和所述衬底进行刻蚀,以形成悬浮区域;所述悬浮区域为贯穿所述牺牲层、并终止于所述衬底内部的空腔结构,以使位于所述空腔结构上方的所述功能层与所述空腔结构下方剩余的部分所述衬底通过所述悬浮区域隔离。The sacrificial layer and the substrate are etched to form a suspended area; the suspended area is a cavity structure that runs through the sacrificial layer and ends in the substrate, so that the cavity is located in the cavity The functional layer above the structure is isolated from the remaining part of the substrate below the cavity structure by the suspended region.
  14. 根据权利要求13所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 13, wherein:
    在所述衬底上依次形成牺牲层和功能层,具体包括:在所述衬底上形成所述牺牲层,在所述牺牲层上形成悬浮层,在所述悬浮层上形成所述功能层;Sequentially forming a sacrificial layer and a functional layer on the substrate specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, and forming the functional layer on the suspension layer ;
    所述通孔还贯穿所述悬浮层;The through hole also penetrates the suspension layer;
    形成所述悬浮区域,具体包括:对所述牺牲层、所述悬浮层和所述衬底进行刻蚀;所述悬浮区域具体从所述悬浮层的上表面以下、延伸贯穿所述牺牲层、并终止于所述衬底内部。Forming the suspension area specifically includes: etching the sacrificial layer, the suspension layer and the substrate; the suspension area specifically extends through the sacrificial layer from below the upper surface of the suspension layer, and terminates inside the substrate.
  15. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 14, wherein:
    在所述衬底上依次形成牺牲层和功能层,具体包括:在所述衬底上形成所述牺牲层,在所述牺牲层上形成悬浮层,在所述悬浮层上形成支撑层,在所述支撑层上形成功能层;Sequentially forming a sacrificial layer and a functional layer on the substrate specifically includes: forming the sacrificial layer on the substrate, forming a suspension layer on the sacrificial layer, forming a support layer on the suspension layer, A functional layer is formed on the support layer;
    所述通孔还贯穿所述支撑层;所述支撑层至少包括位于所述空腔结构上方的部分,以支撑位于所述空腔结构上方的所述功能层。The through hole also penetrates the support layer; the support layer at least includes a portion located above the cavity structure to support the functional layer located above the cavity structure.
  16. 根据权利要求13或14所述的热调谐半导体芯片的制备方法,其中,在形成所述通孔后,所述方法还包括:The method for manufacturing a thermally tuned semiconductor chip according to claim 13 or 14, wherein after forming the through hole, the method further comprises:
    形成掩膜层,所述掩膜层至少覆盖所述通孔的侧壁;forming a mask layer covering at least the sidewall of the through hole;
    在所述掩膜层底端形成开口,所述开口暴露出部分所述牺牲层。An opening is formed at the bottom end of the mask layer, and the opening exposes part of the sacrificial layer.
  17. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,形 成所述悬浮区域,具体包括:The method for preparing a thermally tuned semiconductor chip according to claim 14, wherein forming the suspended region specifically includes:
    采用第一刻蚀工艺对所述牺牲层进行刻蚀,暴露出所述衬底的部分上表面和所述悬浮层的部分下表面;The sacrificial layer is etched by a first etching process to expose a part of the upper surface of the substrate and a part of the lower surface of the suspension layer;
    采用第二刻蚀工艺对所述衬底和所述悬浮层进行刻蚀,以形成所述悬浮区域。The substrate and the suspension layer are etched by a second etching process to form the suspension region.
  18. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,所述悬浮区域包括位于所述衬底内的第一部分、位于所述牺牲层内的第二部分和位于所述悬浮层内的第三部分,所述第一部分的深度大于所述第二部分和所述第三部分的深度之和。The method for fabricating a thermally tuned semiconductor chip according to claim 14, wherein the suspended region comprises a first portion located in the substrate, a second portion located in the sacrificial layer, and a second portion located in the suspended layer. The third part, the depth of the first part is greater than the sum of the depths of the second part and the third part.
  19. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 14, wherein:
    所述牺牲层具有第一厚度,所述悬浮层具有第二厚度,所述第二厚度大于所述第一厚度;the sacrificial layer has a first thickness, the suspension layer has a second thickness, and the second thickness is greater than the first thickness;
    形成所述悬浮区域,具体包括:对所述悬浮层的刻蚀深度大于所述第一厚度,以使形成的所述悬浮区域在位于所述悬浮层内的第三部分的深度大于在位于所述牺牲层内的第二部分的深度。The forming of the suspension region specifically includes: the etching depth of the suspension layer is greater than the first thickness, so that the depth of the formed suspension region in the third part located in the suspension layer is greater than that in the suspension layer. the depth of the second portion within the sacrificial layer.
  20. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,所述悬浮层的材料与所述衬底的材料相同。The method for manufacturing a thermally tuned semiconductor chip according to claim 14, wherein the material of the suspension layer is the same as the material of the substrate.
  21. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 14, wherein:
    所述形成通孔包括形成至少两个通孔;The forming through holes includes forming at least two through holes;
    所述对所述牺牲层、所述悬浮层和所述衬底进行刻蚀的步骤中,所述悬浮层和所述牺牲层的位于至少两个所述通孔中的任意两个之间的部分未被完全去除。In the step of etching the sacrificial layer, the suspension layer and the substrate, the suspension layer and the sacrificial layer are located between any two of the at least two through holes. Parts are not completely removed.
  22. 根据权利要求14所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 14, wherein:
    所述在所述牺牲层上形成悬浮层,在所述悬浮层上形成所述功能层,具体包括:在形成所述悬浮层后,在所述悬浮层上形成所述功能层的第一 子功能层,所述第一子功能层的下表面与所述悬浮层的上表面接触;The forming of the suspension layer on the sacrificial layer and the formation of the functional layer on the suspension layer specifically include: after forming the suspension layer, forming a first sub-section of the functional layer on the suspension layer a functional layer, the lower surface of the first sub-functional layer is in contact with the upper surface of the suspension layer;
    形成所述悬浮区域,包括:在对所述悬浮层进行刻蚀时,以所述第一子功能层作为刻蚀阻挡层。The forming of the suspension region includes: when the suspension layer is etched, using the first sub-functional layer as an etching barrier layer.
  23. 根据权利要求15所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 15, wherein:
    在所述牺牲层上形成悬浮层,在所述悬浮层上形成支撑层,具体包括:在形成所述悬浮层后,在所述悬浮层上形成刻蚀阻挡层,所述刻蚀阻挡层的下表面与所述悬浮层的上表面接触,在所述刻蚀阻挡层上形成所述支撑层;Forming a suspension layer on the sacrificial layer, and forming a support layer on the suspension layer, specifically includes: after forming the suspension layer, forming an etching barrier layer on the suspension layer, the etching barrier layer is The lower surface is in contact with the upper surface of the suspension layer, and the support layer is formed on the etching barrier layer;
    形成所述悬浮区域,包括:在对所述悬浮层进行刻蚀时,所述刻蚀阻挡层阻挡刻蚀反应朝向所述支撑层的一侧进行。The forming of the suspension region includes: when the suspension layer is etched, the etching barrier layer prevents the etching reaction from proceeding toward one side of the support layer.
  24. 根据权利要求13所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 13, wherein:
    在所述衬底上形成所述牺牲层,具体包括:在所述衬底上直接形成所述牺牲层,以使所述牺牲层的下表面与所述衬底的上表面接触。Forming the sacrificial layer on the substrate specifically includes: directly forming the sacrificial layer on the substrate, so that the lower surface of the sacrificial layer is in contact with the upper surface of the substrate.
  25. 根据权利要求13所述的热调谐半导体芯片的制备方法,其中,The method for manufacturing a thermally tuned semiconductor chip according to claim 13, wherein:
    所述牺牲层的材料包括以下至少之一:InGaAs、InGaAsP、AlGaInAs。The material of the sacrificial layer includes at least one of the following: InGaAs, InGaAsP, and AlGaInAs.
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CN114927935A (en) * 2022-07-20 2022-08-19 度亘激光技术(苏州)有限公司 Heat sink and laser

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