WO2022095112A1 - Slider manufacturing method, slider and textile machine using same - Google Patents
Slider manufacturing method, slider and textile machine using same Download PDFInfo
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- WO2022095112A1 WO2022095112A1 PCT/CN2020/129022 CN2020129022W WO2022095112A1 WO 2022095112 A1 WO2022095112 A1 WO 2022095112A1 CN 2020129022 W CN2020129022 W CN 2020129022W WO 2022095112 A1 WO2022095112 A1 WO 2022095112A1
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- 239000004753 textile Substances 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 135
- 239000000843 powder Substances 0.000 claims abstract description 112
- 238000000034 method Methods 0.000 claims abstract description 71
- 238000007872 degassing Methods 0.000 claims abstract description 31
- 238000005245 sintering Methods 0.000 claims abstract description 29
- 238000005238 degreasing Methods 0.000 claims abstract description 28
- 238000010276 construction Methods 0.000 claims abstract description 21
- 239000008207 working material Substances 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 238000004663 powder metallurgy Methods 0.000 claims abstract description 8
- 238000007731 hot pressing Methods 0.000 claims description 24
- 239000000956 alloy Substances 0.000 claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 8
- 229920000620 organic polymer Polymers 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 239000011812 mixed powder Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 238000005056 compaction Methods 0.000 abstract description 2
- 238000011017 operating method Methods 0.000 abstract description 2
- 239000012254 powdered material Substances 0.000 abstract 10
- 239000010410 layer Substances 0.000 description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000000047 product Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000011112 process operation Methods 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
- B22F3/1021—Removal of binder or filler
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/06—Sliding surface mainly made of metal
- F16C33/12—Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
- F16C33/121—Use of special materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/06—Sliding surface mainly made of metal
- F16C33/14—Special methods of manufacture; Running-in
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/60—Ferrous alloys, e.g. steel alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2220/00—Shaping
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2340/00—Apparatus for treating textiles
Definitions
- a method for manufacturing a sliding member which adopts a powder metallurgy method to manufacture a bi-material or multi-material planar sliding member, at least including:
- the laid second powder material is Fe-based alloy powder or Fe-based mixed powder
- the laid first powder material is Fe-based self-lubricating material powder or Cu-based self-lubricating material powder.
- FIG. 1 is a schematic structural diagram of an interface construction template used in the methods of various embodiments of the present invention.
- FIG. 2 is a schematic diagram of the usage principle of the interface construction template adopted in the methods of various embodiments of the present invention.
- the material 2 and the first powder material 1 are removed, and after the interface construction template 3 is removed, the second powder material 2 and the first powder material 1 are individually metallurgically sintered to form a support material layer and a working material layer, a non-linear interface structure corresponding to the undulating structure shape of the interface structure template 3 is formed at the sintered interface of the support material layer and the working material layer.
- the laid second powder material 2 and the first powder material 1 are both non-bonded powders.
- Binder, interface structure template 3 selects a polyvinyl chloride sheet with a thickness of about 0.4mm, the degreasing temperature is 500°C, and the final sintering temperature of about 900°C is sintered for 3 hours according to the method of Example 2, and the maximum pressure applied during the period is 50MPa. Finally, a planar sliding part product with a density of more than 97% can also be obtained, and the non-linear interface structure at the material interface is uniform in shape.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
Abstract
A slider manufacturing method, comprising: manufacturing a bi-material or multi-material planar slider, such as a sliding bearing of a textile machine, by using a powder metallurgy method; using a second powdered material as a powdered raw material of a supporting material layer, and using a first powdered material as a raw material of a working material layer; laying the materials in sequence such that the second powdered material is below the first powdered material; placing a sheet that is of an undulating structure and is made of a thermally decomposable material between the second powdered material and the first powdered material as an interface construction template, wherein the interface construction template can be removed between the second powdered material and the first powdered material by means of degassing pre-sintering or degreasing, and after the interface construction template is removed, the second powdered material and the first powdered material are respectively metallurgically sintered to form the supporting material layer and the working material layer; and forming a non-linear interface structure corresponding to the undulating structure of the interface structure template in shape at a sintered interface of the supporting material layer and the working material layer. The method requires neither separate compaction of the powders nor the addition of an individual operating procedure for processing the interface.
Description
本发明涉及机械滑动零部件制造技术领域,具体涉及一种滑动件的制作方法、滑动件以及应用该滑动件的纺织机械。The invention relates to the technical field of manufacturing of mechanical sliding parts, in particular to a manufacturing method of a sliding part, a sliding part and a textile machine using the sliding part.
平面滑动件如滑动轴承是机械设备中用来承受滑动摩擦的部件,能够适应低速重载工作条件,可安装在机械设备中操作、维护不方便的特殊运转部位,特别是具有自润滑能力的滑动轴承由于避免了润滑油的使用,在纺织机械中作为摩擦副应用较为广泛。Plane sliding parts such as sliding bearings are parts used to withstand sliding friction in mechanical equipment. They can adapt to low-speed and heavy-load working conditions. They can be installed in special operating parts of mechanical equipment that are inconvenient to operate and maintain, especially those with self-lubricating ability. Bearings are widely used as friction pairs in textile machinery because they avoid the use of lubricating oil.
具有自润滑能力的平面轴承很多是双材料或多材料轴承,即包括一个起支撑作用的支撑材料层和至少一个起摩擦润滑作用的工作材料层,因此也可以采用粉末冶金工艺制作,例如在制作过程中使用铁基粉末材料作为支撑材料层粉末原料,使用具有自润滑能力的铜基粉末材料作为工作材料层原料,使用或不使用粘结剂,按顺序铺料,支撑材料层粉末原料在下,工作材料层粉末原料在上,冷压成预制坯后进行烧结,或者在压力下烧结,固化成型后成为双材料或多材料轴承毛坯产品,通过后续机械加工成为成品。Many plane bearings with self-lubricating ability are bi-material or multi-material bearings, that is, they include a support material layer that acts as a support and at least one working material layer that acts as a friction lubricator, so they can also be made by powder metallurgy processes. In the process, the iron-based powder material is used as the powder raw material for the support material layer, and the copper-based powder material with self-lubricating ability is used as the raw material for the working material layer. The powder raw material of the working material layer is on top, cold-pressed into a preform and then sintered, or sintered under pressure, solidified and formed into a bi-material or multi-material bearing blank product, which is processed into a finished product through subsequent machining.
上面所列举的平面滑动件,在粉末冶金工艺操作中,除了确保使所选粉末材料与所需摩擦系数匹配,以及确保使烧结参数与材料特性匹配外,还会通过对两种不同粉末界面的预先物理或化学处理以确保异种材料界面的烧结结合强度,例如以适当的界面咬合来减少材料层间结合失效风险,并阻断裂纹或脆性中间产物的延伸路径。目前对材料界面的这种预先处理往往对粉末冶金工艺的实施程序产生较大影响,例如不得不分别压制粉末或者不得不增加用于对界面进行处理的单独程序。The plane sliding parts listed above, in the powder metallurgy process operation, in addition to ensuring that the selected powder material is matched with the desired coefficient of friction, and the sintering parameters are matched with the material properties, but also through the interface between the two different powders. Preliminary physical or chemical treatment to ensure the sintered bond strength of dissimilar material interfaces, such as proper interfacial occlusion to reduce the risk of interlayer bond failures, and to block the extension paths of cracks or brittle intermediates. The current pretreatment of material interfaces tends to have a large impact on the implementation procedure of the powder metallurgy process, for example having to press the powder separately or having to add a separate procedure for the treatment of the interface.
发明内容SUMMARY OF THE INVENTION
为了解决上述提到的问题,本发明提供一种滑动件的制作方法,可通过简化的界面制造工艺在烧结双材料或多材料界面上制造出界面构造,尤其可用来制作例如纺织机械的滑动轴承部件。In order to solve the above-mentioned problems, the present invention provides a manufacturing method of a sliding member, which can manufacture an interface structure on a sintered bi-material or multi-material interface through a simplified interface manufacturing process, especially for manufacturing such as a sliding bearing for textile machinery part.
本发明的目的是通过以下技术方案实现的。The purpose of the present invention is achieved through the following technical solutions.
一种滑动件的制作方法,采用粉末冶金方法制作双材料或多材料平面滑动件,至少包括:A method for manufacturing a sliding member, which adopts a powder metallurgy method to manufacture a bi-material or multi-material planar sliding member, at least including:
使用第二粉末材料作为支撑材料层粉末原料,使用第一粉末材料作为工作材料层原料,按顺序铺料,作为支撑材料层粉末原料的第二粉末材料在下,作为工作材料层原料的第一粉末材料在上,在所述第二粉末材料和所述第一粉末材料之间放置一个界面构造模板,所述界面构造模板为具有起伏结构的、由可热分解的材料制作的薄板,能够以除气预烧或脱脂的方式在所述第二粉末材料和所述第一粉末材料之间去除,并在去除所述界面构造模板后,所述第二粉末材料和所述第一粉末材料各自冶金烧结形成支撑材料层和工作材料层,在支撑材料层和工作材料层的烧结界面处形成与所述界面构造模板的起伏结构形状相对应的非直线界面构造;Use the second powder material as the powder raw material of the support material layer, use the first powder material as the raw material of the working material layer, and spread the materials in order, the second powder material as the powder raw material of the supporting material layer is below, and the first powder as the raw material of the working material layer The material is above, and an interface construction template is placed between the second powder material and the first powder material, and the interface construction template is a thin plate made of a thermally decomposable material with an undulating structure, which can be divided into Gas pre-burning or debinding is removed between the second powder material and the first powder material, and after removal of the interface build-up template, the second powder material and the first powder material are individually metallurgical Sintering to form a support material layer and a working material layer, and forming a non-linear interface structure corresponding to the undulating structure shape of the interface structure template at the sintered interface of the support material layer and the working material layer;
其中,在所述按顺序铺料中:Wherein, in the described orderly paving:
所铺设的第二粉末材料和第一粉末材料均为非粘结粉末,在将所述第二粉末材料、界面构造模板、第一粉末材料依次铺设完成后进行加压、除气预烧和烧结,在所述除气预烧过程中使所述界面构造模板分解;或者,所铺设的第二粉末材料和第一粉末材料均与粘结剂混合,在将所述第二粉末材料、界面构造模板、第一粉末材料依次铺设完成后进行脱脂和烧结,在所述脱脂过程中使所述界面构造模板分解,与所述粘结剂一起被去除。The laid second powder material and the first powder material are both non-bonded powders, and after the second powder material, the interface structure template, and the first powder material are laid in sequence, pressurization, degassing, pre-firing and sintering are performed. , the interface structure template is decomposed during the degassing and pre-burning process; or, both the laid second powder material and the first powder material are mixed with a binder, and the second powder material and the interface structure are mixed together. After the template and the first powder material are laid in sequence, degreasing and sintering are performed. During the degreasing process, the interface structure template is decomposed and removed together with the binder.
如上所述的一种滑动件的制作方法,当采用所述除气预烧方式去除所述界面构造模板时,所述除气预烧温度不高于600℃;当采用所述脱脂方式去除所述界面构造模板时,所述脱脂温度不高于600℃。In the above-mentioned manufacturing method of a sliding member, when the interface structural template is removed by the degassing and pre-burning method, the degassing and pre-burning temperature is not higher than 600°C; When the interface constructs the template, the degreasing temperature is not higher than 600°C.
如上所述的一种滑动件的制作方法,当采用所述除气预烧方式去除所述界面构造模板时,所述加压、除气预烧和烧结的过程在热压模具中进行;当采用所述脱脂方式去除所述界面构造模板时,所述脱脂和烧结的过程在热压模具中进行;上述热压模具结构包括上模板、下模板和模具套,所述上模板、下模板和模具套围成所述滑动件的粉末原料加入腔和成型型腔。In the above-mentioned manufacturing method of a sliding part, when the interface structure template is removed by the degassing and pre-firing method, the processes of pressurization, degassing pre-firing and sintering are carried out in a hot pressing mold; when When the interface structure template is removed by the degreasing method, the process of degreasing and sintering is carried out in a hot pressing mold; the hot pressing mold structure includes an upper template, a lower template and a mold sleeve, the upper template, the lower template and the The mold covers the powder raw material feeding cavity and the forming cavity of the sliding part.
如上所述的一种滑动件的制作方法,在所述模具套上加工有排气孔。In the above-mentioned method for manufacturing a sliding piece, the die sleeve is machined with vent holes.
如上所述的一种滑动件的制作方法,在进行所述除气预烧或所述脱脂程序前施加压力将所述热压模具中的粉末装载体压实,在进行所述除气预烧或所述 脱脂程序时,对所述热压模具加载的压力不超过20MPa,在完成所述除气预烧或所述脱脂程序后,增加压力,进行烧结。A method of manufacturing a sliding part as described above, applying pressure to compact the powder carrier in the hot-pressing mold before performing the degassing pre-burning or the degreasing procedure, and then performing the degassing and pre-burning. Or during the degreasing procedure, the pressure loaded on the hot-pressing die is not more than 20 MPa, and after the degassing and pre-burning or the degreasing procedure is completed, the pressure is increased to perform sintering.
如上所述的一种滑动件的制作方法,所铺设的第二粉末材料为Fe基合金粉末或Fe基混合粉末,所铺设的第一粉末材料为Fe基自润滑材料粉末或Cu基自润滑材料粉末。A method of manufacturing a sliding part as described above, the laid second powder material is Fe-based alloy powder or Fe-based mixed powder, and the laid first powder material is Fe-based self-lubricating material powder or Cu-based self-lubricating material powder.
如上所述的一种滑动件的制作方法,所述界面构造模板的制作材料含有有机聚合物。In the above-mentioned manufacturing method of a sliding member, the manufacturing material of the interface structure template contains an organic polymer.
如上所述的一种滑动件的制作方法,所述有机聚合物包括聚乙烯、聚丙烯、聚氯乙烯、聚苯乙烯中的一种或多种。In the above-mentioned manufacturing method of a sliding member, the organic polymer includes one or more of polyethylene, polypropylene, polyvinyl chloride, and polystyrene.
本发明同时提供一种滑动件,通过如上所述的方法制作。The present invention also provides a sliding member, which is manufactured by the above-mentioned method.
本发明同时提供一种纺织机械,包含滑动轴承,所述滑动轴承中采用如上所述的滑动件。The present invention also provides a textile machine, which includes a sliding bearing, and the sliding member as described above is used in the sliding bearing.
本发明的有益效果在于:The beneficial effects of the present invention are:
本发明提供的一种滑动件的制作方法,可通过简化的界面制造工艺在烧结双材料或多材料界面上制造出界面构造,尤其可用来制作例如纺织机械的滑动轴承部件上面所列举的平面滑动件。通过使用第二粉末材料作为支撑材料层粉末原料,使用第一粉末材料作为工作材料层原料,在第二粉末材料和第一粉末材料之间放置具有起伏结构的、由可热分解的材料制作的界面构造模板,该界面构造模板能够以除气预烧或脱脂的方式在第二粉末材料和第一粉末材料之间去除,并在去除界面构造模板后,第二粉末材料和第一粉末材料各自冶金烧结形成支撑材料层和工作材料层,在支撑材料层和工作材料层的烧结界面处形成与界面构造模板的起伏结构形状相对应的非直线界面构造,这样的界面构造可以起到前面所说的以适当的界面咬合来减少材料层间结合失效风险,并阻断裂纹或脆性中间产物的延伸路径的作用,本发明的方法对粉末冶金工艺的实施程序基本没有影响,界面构造模板的去除在除气预烧或脱脂程序中自然进行,不需要分别压制粉末,也不用增加对界面进行处理的单独操作程序,通过对热压工艺的操作(例如除气预烧或脱脂程序中的压力加载和排气),可以获得与常规工艺同样致密且力学性能合格的制品。The present invention provides a method for manufacturing a sliding member, which can manufacture an interface structure on a sintered bi-material or multi-material interface through a simplified interface manufacturing process, and can especially be used to manufacture the plane sliding components listed above, such as a sliding bearing component of a textile machine. piece. By using the second powder material as the support material layer powder raw material and the first powder material as the working material layer raw material, a thermally decomposable material having an undulating structure is placed between the second powder material and the first powder material. an interface construction template that can be removed between the second powder material and the first powder material by degassing, burn-in or degreasing, and after removal of the interface construction template, the second powder material and the first powder material are each Metallurgical sintering forms a supporting material layer and a working material layer, and a non-linear interface structure corresponding to the undulating structure shape of the interface structure template is formed at the sintering interface of the supporting material layer and the working material layer. With proper interface occlusion to reduce the risk of interlayer bonding failure, and to block the extension path of cracks or brittle intermediate products, the method of the present invention has basically no effect on the implementation procedure of the powder metallurgy process. Naturally in the degassing or debinding procedure, without the need for separate compaction of the powders, and without adding a separate operating procedure for the interface treatment, through the operation of the hot pressing process (such as pressure loading and in the degassing preburning or debinding procedure exhaust), products with the same density and qualified mechanical properties as the conventional process can be obtained.
图1为本发明各实施例的方法中所采用的界面构造模板结构示意图。FIG. 1 is a schematic structural diagram of an interface construction template used in the methods of various embodiments of the present invention.
图2为本发明各实施例的方法中所采用的界面构造模板使用原理示意图。FIG. 2 is a schematic diagram of the usage principle of the interface construction template adopted in the methods of various embodiments of the present invention.
图3为本发明各实施例的方法中在热压模具中进行工艺操作的原理示意图。FIG. 3 is a schematic diagram of the principle of performing process operations in a hot pressing mold in the methods of various embodiments of the present invention.
图4为本发明各实施例的方法中在另一构造的热压模具中进行工艺操作的原理示意图。FIG. 4 is a schematic diagram showing the principle of performing a process operation in a hot pressing mold of another configuration in the method of various embodiments of the present invention.
图中各附图标记所代表的组件为:The components represented by each reference number in the figure are:
第一粉末材料-1,第二粉末材料-2,界面构造模板-3,上模板-4、下模板-5,模具套-6,排气孔-7。The first powder material-1, the second powder material-2, the interface structure template-3, the upper template-4, the lower template-5, the mold sleeve-6, the exhaust hole-7.
下面将参照附图更详细地描述本公开的示例性实施方式。Exemplary embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings.
实施例1Example 1
首先参见图3,本实施例在图3所示的热压模具中,采用粉末冶金方法制作双材料或多材料平面滑动件,该平面滑动件作为一种应用在纺织机械中的滑动轴承。热压模具结构包括上模板4、下模板5和模具套6,所述上模板4、下模板5和模具套6围成所述滑动件的粉末原料加入腔和成型型腔。Referring first to FIG. 3 , in this embodiment, in the hot pressing mold shown in FIG. 3 , a powder metallurgy method is used to manufacture a bi-material or multi-material planar sliding member, which is used as a sliding bearing in textile machinery. The hot-pressing die structure includes an upper die plate 4, a lower die plate 5 and a die sleeve 6, and the upper die plate 4, the lower die plate 5 and the die sleeve 6 enclose a powder feed cavity and a molding cavity of the sliding piece.
结合图1-图3,上述滑动件的制作方法包括:使用第二粉末材料2作为支撑材料层粉末原料,使用第一粉末材料1作为工作材料层原料,按顺序铺料,作为支撑材料层粉末原料的第二粉末材料2在下,作为工作材料层原料的第一粉末材料1在上,在所述第二粉末材料2和所述第一粉末材料1之间放置一个界面构造模板3,所述界面构造模板3为具有起伏结构的、由可热分解的材料制作的薄板(这里薄板原则上选择厚度1.5mm以下,优选0.5mm以下),能够以除气预烧的方式在所述第二粉末材料2和所述第一粉末材料1之间去除,并在去除所述界面构造模板3后,所述第二粉末材料2和所述第一粉末材料1各自冶金烧结形成支撑材料层和工作材料层,在支撑材料层和工作材料层的烧结界面处形成与所述界面构造模板3的起伏结构形状相对应的非直线界面构造。与本实施例的“除气预烧的方式”相对应,在所述按顺序铺料中:所铺设的第二粉末材料2和第一粉末材料1均为非粘结粉末,在将所述第二粉末材料2、界面构造模板3、第一粉末材料1依次铺设完成后进行加压、除气预烧和烧结,在所述除气预烧过程中使所述界面构造模板3分解。Referring to FIGS. 1 to 3 , the manufacturing method of the above-mentioned sliding member includes: using the second powder material 2 as the powder raw material of the support material layer, using the first powder material 1 as the raw material of the working material layer, and laying the materials in sequence as the powder material of the support material layer The second powder material 2 of the raw material is at the bottom, the first powder material 1 as the raw material of the working material layer is above, and an interface construction template 3 is placed between the second powder material 2 and the first powder material 1, and the The interface structure template 3 is a thin plate made of a thermally decomposable material with an undulating structure (here the thin plate is in principle selected to have a thickness of 1.5 mm or less, preferably 0.5 mm or less). The material 2 and the first powder material 1 are removed, and after the interface construction template 3 is removed, the second powder material 2 and the first powder material 1 are individually metallurgically sintered to form a support material layer and a working material layer, a non-linear interface structure corresponding to the undulating structure shape of the interface structure template 3 is formed at the sintered interface of the support material layer and the working material layer. Corresponding to the “method of degassing and pre-burning” in this embodiment, in the sequential laying: the laid second powder material 2 and the first powder material 1 are both non-bonded powders. After the second powder material 2 , the interface structure template 3 , and the first powder material 1 are laid in sequence, pressurization, degassing and pre-burning and sintering are performed, and the interface structure template 3 is decomposed during the degassing and pre-burning process.
本实施例上述除气预烧的最终温度以能够完全分解所述界面构造模板3为准,所述界面构造模板3的制作材料优选含有有机聚合物,所述有机聚合物包括聚乙烯、聚丙烯、聚氯乙烯、聚苯乙烯中的一种或多种,其热分解温度一般不高于600℃,另外,在有机材料中加入质量分数不低于5%、不超过30%的低熔点主元素粉末(即第二粉末材料2和第一粉末材料1中熔点相对较低的主元素),可在控制有机用量的前提下,很好促进两相材料的熔合。The final temperature of the degassing and pre-burning in this embodiment is based on the fact that the interface structural template 3 can be completely decomposed. The manufacturing material of the interface structural template 3 preferably contains an organic polymer, and the organic polymer includes polyethylene and polypropylene. , one or more of polyvinyl chloride and polystyrene, and its thermal decomposition temperature is generally not higher than 600 ° C. In addition, the mass fraction of not less than 5% and not more than 30% of low melting point main material is added to the organic material. The element powder (ie, the main element with relatively low melting point in the second powder material 2 and the first powder material 1) can well promote the fusion of the two-phase materials under the premise of controlling the organic amount.
如图3所示,本实施例加压、除气预烧和烧结的过程均在热压模具中进行,在进行所述除气预烧程序前施加压力将所述热压模具中的粉末装载体压实,在进行所述除气预烧程序时,对所述热压模具加载的压力不超过20MPa,在完成所述除气预烧程序后,增加压力,进行烧结。As shown in FIG. 3 , the processes of pressurization, degassing and pre-sintering and sintering in this embodiment are all performed in a hot-pressing mold. Before the degassing and pre-sintering process is performed, pressure is applied to pack the powder in the hot-pressing mold. The carrier is compacted. When the degassing and pre-sintering procedure is performed, the pressure loaded on the hot-pressing die is not more than 20 MPa. After the degassing and pre-sintering procedure is completed, the pressure is increased to perform sintering.
作为对进一步改进的举例而非限制,如图4所示,可以在热压模具的模具套6上加工出排气孔7,在热压模具封闭性较好的情况下,以便于分解气的顺利导出,排气孔7可以是如图所示的具有一个主通道和若干个分通道的结构。As an example but not a limitation for further improvement, as shown in FIG. 4 , vent holes 7 can be machined on the mold sleeve 6 of the hot-pressing mold. The exhaust hole 7 can be a structure with one main channel and several sub-channels as shown in the figure.
验证例1Verification Example 1
在含铜(约25wt%)、锡(约15wt%)的Fe基合金粉末中加入占Fe基合金粉末8wt%的润滑剂(石墨)作为第一粉末材料1,以含碳量约0.4wt%并含有约0.3wt%的硅、约0.6wt%的锰的铁基合金粉末作为第二粉末材料2,界面构造模板3选择厚度0.4mm左右的聚氯乙烯薄板,除气预烧温度280℃,按照实施例1的方法在约900℃的最终烧结温度下烧结3小时,期间所施加的最大压力50MPa。最后,可得到致密度约98%的平面滑动件制品,材料界面处的非直线界面构造形状均匀。In the Fe-based alloy powder containing copper (about 25wt%) and tin (about 15wt%), a lubricant (graphite) accounting for 8wt% of the Fe-based alloy powder was added as the first powder material 1, and the carbon content was about 0.4wt% And iron-based alloy powder containing about 0.3wt% of silicon and about 0.6wt% of manganese is used as the second powder material 2, the interface structure template 3 is selected as a polyvinyl chloride sheet with a thickness of about 0.4mm, and the degassing and pre-burning temperature is 280 ℃, Sintering was carried out according to the method of Example 1 at a final sintering temperature of about 900° C. for 3 hours, with a maximum pressure applied during this period of 50 MPa. Finally, a planar sliding part product with a density of about 98% can be obtained, and the non-linear interface structure at the material interface is uniform in shape.
实施例2Example 2
仍然参见图1-图4,本实施例与实施例1中的制备目标、所采用的热压模具和所采用的工艺基本相同,所采用的界面构造模板3也相同,不同之处在于在所述按顺序铺料中,所铺设的第二粉末材料2和第一粉末材料1均与体积含量为8%的粘结剂混合,在将所述第二粉末材料2、界面构造模板3、第一粉末材料1依次铺设完成后进行脱脂和烧结,在所述脱脂过程中使所述界面构造模板3分解,与所述粘结剂一起被去除。Still referring to Fig. 1-Fig. 4, this embodiment is basically the same as the preparation target, the hot-pressing mold used and the process used in the embodiment 1, and the interface structure template 3 used is also the same, the difference is that in the In the sequential laying described above, the laid second powder material 2 and the first powder material 1 are mixed with a binder with a volume content of 8%. After a powder material 1 is laid in sequence, degreasing and sintering are performed. During the degreasing process, the interface construction template 3 is decomposed and removed together with the binder.
本实施例上述脱脂过程的最终温度以能够完全分解所述粘结剂和所述界面 构造模板3为准,并且,本实施例加压、脱脂和烧结的过程均在热压模具中进行,在进行所述脱脂程序前施加压力将所述热压模具中的粉末装载体压实,在进行所述脱脂程序时,对所述热压模具加载的压力不超过20MPa,在完成所述脱脂程序后,增加压力,进行烧结,本实施例优选选择图4所示的带有排气孔7的热压模具。The final temperature of the above degreasing process in this embodiment is based on the ability to completely decompose the binder and the interface structure template 3, and in this embodiment, the processes of pressurization, degreasing and sintering are all performed in a hot pressing mold. Apply pressure to compact the powder carrier in the hot-pressing mold before performing the degreasing procedure. During the degreasing procedure, the pressure loaded on the hot-pressing mold does not exceed 20 MPa. After the degreasing procedure is completed , increase the pressure, and perform sintering. In this embodiment, the hot-pressing die with the vent hole 7 shown in FIG. 4 is preferably selected.
验证例2Verification example 2
在含铜(约25wt%)、锡(约15wt%)的Fe基合金粉末中加入占Fe基合金粉末8wt%的润滑剂(石墨)作为第一粉末材料1,以体积含量8%加入酚醛树脂基粘结剂,以含碳量约0.4wt%并含有约0.3wt%的硅、约0.6wt%的锰的铁基合金粉末作为第二粉末材料2,以体积含量8%加入酚醛树脂基粘结剂,界面构造模板3选择厚度0.4mm左右的聚氯乙烯薄板,脱脂温度500℃,按照实施例2的方法在约900℃的最终烧结温度下烧结3小时,期间所施加的最大压力50MPa。最后,也可得到致密度超过97%的平面滑动件制品,材料界面处的非直线界面构造形状均匀。In Fe-based alloy powder containing copper (about 25wt%) and tin (about 15wt%), a lubricant (graphite) accounting for 8wt% of Fe-based alloy powder is added as the first powder material 1, and phenolic resin is added with a volume content of 8% As the second powder material 2, the phenolic resin-based adhesive is added with a volume content of 8% by using an iron-based alloy powder with a carbon content of about 0.4 wt% and containing about 0.3 wt% of silicon and about 0.6 wt% of manganese as the second powder material 2. Binder, interface structure template 3 selects a polyvinyl chloride sheet with a thickness of about 0.4mm, the degreasing temperature is 500°C, and the final sintering temperature of about 900°C is sintered for 3 hours according to the method of Example 2, and the maximum pressure applied during the period is 50MPa. Finally, a planar sliding part product with a density of more than 97% can also be obtained, and the non-linear interface structure at the material interface is uniform in shape.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above description is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. Substitutions should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be based on the protection scope of the claims.
Claims (10)
- 一种滑动件的制作方法,采用粉末冶金方法制作双材料或多材料平面滑动件,其特征在于,至少包括:A method for manufacturing a sliding member, adopting a powder metallurgy method to manufacture a bi-material or multi-material planar sliding member, characterized in that it at least comprises:使用第二粉末材料(2)作为支撑材料层粉末原料,使用第一粉末材料(1)作为工作材料层原料,按顺序铺料,作为支撑材料层粉末原料的第二粉末材料(2)在下,作为工作材料层原料的第一粉末材料(1)在上,在所述第二粉末材料(2)和所述第一粉末材料(1)之间放置一个界面构造模板(3),所述界面构造模板(3)为具有起伏结构的、由可热分解的材料制作的薄板,能够以除气预烧或脱脂的方式在所述第二粉末材料(2)和所述第一粉末材料(1)之间去除,并在去除所述界面构造模板(3)后,所述第二粉末材料(2)和所述第一粉末材料(1)各自冶金烧结形成支撑材料层和工作材料层,在支撑材料层和工作材料层的烧结界面处形成与所述界面构造模板(3)的起伏结构形状相对应的非直线界面构造;The second powder material (2) is used as the powder raw material for the support material layer, the first powder material (1) is used as the raw material for the working material layer, and the materials are spread in order, and the second powder material (2) as the powder raw material for the support material layer is below, The first powder material (1) as the raw material of the working material layer is on top, and an interface construction template (3) is placed between the second powder material (2) and the first powder material (1), the interface The construction template (3) is a thin plate made of a thermally decomposable material with an undulating structure, which can be degassed, pre-fired or degreased between the second powder material (2) and the first powder material (1). ), and after removing the interface construction template (3), the second powder material (2) and the first powder material (1) are individually metallurgically sintered to form a support material layer and a working material layer, and the A non-linear interface structure corresponding to the undulating structure shape of the interface structure template (3) is formed at the sintering interface of the support material layer and the working material layer;其中,在所述按顺序铺料中:Wherein, in the described orderly paving:所铺设的第二粉末材料(2)和第一粉末材料(1)均为非粘结粉末,在将所述第二粉末材料(2)、界面构造模板(3)、第一粉末材料(1)依次铺设完成后进行加压、除气预烧和烧结,在所述除气预烧过程中使所述界面构造模板(3)分解;或者,所铺设的第二粉末材料(2)和第一粉末材料(1)均与粘结剂混合,在将所述第二粉末材料(2)、界面构造模板(3)、第一粉末材料(1)依次铺设完成后进行脱脂和烧结,在所述脱脂过程中使所述界面构造模板(3)分解,与所述粘结剂一起被去除。The laid second powder material (2) and the first powder material (1) are both non-bonded powders, and after combining the second powder material (2), the interface construction template (3), the first powder material (1) ) After the laying is completed in sequence, pressurization, degassing pre-firing and sintering are performed, and the interface construction template (3) is decomposed during the degassing prefiring process; or, the laid second powder material (2) and the first A powder material (1) is mixed with a binder, and degreasing and sintering are performed after the second powder material (2), the interface construction template (3), and the first powder material (1) are laid in sequence. During the degreasing process, the interface construction template (3) is decomposed and removed together with the binder.
- 根据权利要求1所述的一种滑动件的制作方法,其特征在于,当采用所述除气预烧方式去除所述界面构造模板(3)时,所述除气预烧温度不高于600℃;当采用所述脱脂方式去除所述界面构造模板(3)时,所述脱脂温度不高于600℃。The method for manufacturing a sliding member according to claim 1, wherein when the interface structural template (3) is removed by the degassing and pre-burning method, the degassing and pre-burning temperature is not higher than 600 °C °C; when the interface construction template (3) is removed by the degreasing method, the degreasing temperature is not higher than 600 °C.
- 根据权利要求1所述的一种滑动件的制作方法,其特征在于,当采用所述除气预烧方式去除所述界面构造模板(3)时,所述加压、除气预烧和烧结的过程在热压模具中进行;当采用所述脱脂方式去除所述界面构造模板(3)时,所述脱脂和烧结的过程在热压模具中进行;上述热压模具结构包括上模板(4)、下模板(5)和模具套(6),所述上模板(4)、下模板(5)和模具套(6)围成所述滑动件的粉末原料加入腔和成型型腔。The method for manufacturing a sliding member according to claim 1, characterized in that, when the interface structural template (3) is removed by the degassing and pre-firing method, the pressurizing, degassing prefiring and sintering are performed. The process of degreasing is carried out in a hot pressing mold; when the interface construction template (3) is removed by the degreasing method, the process of degreasing and sintering is carried out in a hot pressing mold; the above-mentioned hot pressing mold structure includes an upper template (4). ), a lower die plate (5) and a die sleeve (6), the upper die plate (4), the lower die plate (5) and the die set (6) enclose the powder feed cavity and the molding cavity of the sliding part.
- 根据权利要求3所述的一种滑动件的制作方法,其特征在于,在所述模具套(6)上加工有排气孔(7)。The method for manufacturing a sliding piece according to claim 3, characterized in that, an exhaust hole (7) is processed on the die sleeve (6).
- 根据权利要求3所述的一种滑动件的制作方法,其特征在于,在进行所述除气预烧或所述脱脂程序前施加压力将所述热压模具中的粉末装载体压实,在进行所述除气预烧或所述脱脂程序时,对所述热压模具加载的压力不超过20MPa,在完成所述除气预烧或所述脱脂程序后,增加压力,进行烧结。The method for manufacturing a sliding part according to claim 3, wherein, before the degassing and pre-burning or the degreasing procedure is performed, pressure is applied to compact the powder carrier in the hot-pressing mold, and When performing the degassing and pre-burning or the degreasing procedure, the pressure loaded on the hot-pressing mold is not more than 20 MPa. After the degassing and pre-burning or the degreasing procedure is completed, the pressure is increased to perform sintering.
- 根据权利要求1所述的一种滑动件的制作方法,其特征在于,所铺设的第二粉末材料(2)为Fe基合金粉末或Fe基混合粉末,所铺设的第一粉末材料(1)为Fe基自润滑材料粉末或Cu基自润滑材料粉末。The method for manufacturing a sliding member according to claim 1, wherein the laid second powder material (2) is Fe-based alloy powder or Fe-based mixed powder, and the laid first powder material (1) It is Fe-based self-lubricating material powder or Cu-based self-lubricating material powder.
- 根据权利要求1所述的一种滑动件的制作方法,其特征在于,所述界面构造模板(3)的制作材料含有有机聚合物。The method for manufacturing a sliding member according to claim 1, characterized in that, the manufacturing material of the interface structure template (3) contains an organic polymer.
- 根据权利要求7所述的一种滑动件的制作方法,其特征在于,所述有机聚合物包括聚乙烯、聚丙烯、聚氯乙烯、聚苯乙烯中的一种或多种。The method for manufacturing a sliding member according to claim 7, wherein the organic polymer comprises one or more of polyethylene, polypropylene, polyvinyl chloride, and polystyrene.
- 一种滑动件,通过权利要求1-8任一项所述的方法制作。A sliding part is manufactured by the method of any one of claims 1-8.
- 一种纺织机械,包含滑动轴承,所述滑动轴承中采用权利要求9所述的滑动件。A textile machine includes a sliding bearing, wherein the sliding element of claim 9 is used in the sliding bearing.
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