WO2022062311A1 - 一种胶黏剂、制备方法及阻燃玻璃纤维带的固化方法 - Google Patents

一种胶黏剂、制备方法及阻燃玻璃纤维带的固化方法 Download PDF

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WO2022062311A1
WO2022062311A1 PCT/CN2021/077550 CN2021077550W WO2022062311A1 WO 2022062311 A1 WO2022062311 A1 WO 2022062311A1 CN 2021077550 W CN2021077550 W CN 2021077550W WO 2022062311 A1 WO2022062311 A1 WO 2022062311A1
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adhesive
acrylate
flame retardant
flame
glass fiber
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PCT/CN2021/077550
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English (en)
French (fr)
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封玉龙
范利平
陈洁琼
季左
罗洪文
陈东
金兑佑
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中广核达胜加速器技术有限公司
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Publication of WO2022062311A1 publication Critical patent/WO2022062311A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21—Paper; Textile fabrics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/302—Applications of adhesives in processes or use of adhesives in the form of films or foils for bundling cables
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/14—Glass
    • C09J2400/143—Glass in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2471/00—Presence of polyether

Definitions

  • the invention relates to the production and manufacture of cables, in particular to an adhesive used for flame retardant glass fiber tapes, a preparation method of the adhesive and a curing method of the flame retardant glass fiber tape.
  • the flame retardant glass fiber tape is mainly used for wrapping and longitudinal wrapping between the components of optical cable, communication cable and power cable, and plays the role of fire isolation. It is an environmentally friendly heat-resistant and flame-retardant material. It is used to wrap the insulated wire core in the cable, to keep the structure of the insulated wire core stable, to ensure that the wire core is not loose and the insulation is not scratched, and to isolate the insulation layer from the outer sheath and the inner lining to prevent them from interacting with each other. Adhesion affects the mechanical, physical and electrical properties of the cable. When the cable is burned, the flame retardant glass fiber tape can absorb a lot of heat, and form a carbonized layer, isolate oxygen, and protect the insulating layer from burning, so that the loss of the fire will not be further enlarged.
  • the glue used in the domestic production of flame retardant glass fiber tapes is prepared by using resin, water, film-forming aids, flame retardants, and adhesives.
  • water-based glue is generally used, which cannot be used.
  • film-forming aids solvents
  • film-forming aids also pose a great threat to the health of operators; the production process of flame-retardant glass fiber tapes requires 30 minutes.
  • the meter-long oven is baked, because the specific heat capacity of water is large, the energy consumption is high, and the oven occupies a large area; the flame-retardant glass fiber tape is generally 10m/min due to the limitation of the dip coating speed and the baking speed. , the efficiency is relatively low.
  • the technical problem to be solved by the present invention is to provide a VOC-free, environmentally friendly, low energy consumption, high curing efficiency adhesive, a preparation method and a curing method for a flame retardant glass fiber tape.
  • a sizing agent comprising the following components according to mass percentage:
  • the polyether acrylate is one of difunctionality and trifunctionality, or a mixture of both.
  • the viscosity of the polyether acrylate is controlled between 100 and 2000 cps.
  • the acrylate diluting monomer is one of isobornyl acrylate, hydroxypropyl acrylate, hydroxyethyl acrylate and isooctyl acrylate.
  • the acrylic phosphoric acid ester is one of monofunctionality and difunctionality or a mixture of both.
  • the flame retardant filler is one or a mixture of two or more of magnesium hydroxide, aluminum hydroxide and calcium hydroxide.
  • a preparation method of an adhesive which comprises the steps of mixing polyether acrylate, acrylate diluting monomer, acrylic acid phosphate, triallyl isocyanurate, flame retardant filler and dispersant according to the proportion, and at room temperature Stir for 20 to 30 minutes.
  • a curing method of flame-retardant glass fiber tape is,
  • the flame-retardant glass fiber tape is irradiated by EB under nitrogen atmosphere;
  • the irradiation height of the EB irradiation in the step S2 is 20 mm
  • the conveying speed is 25 m/min
  • the energy is 400-600 keV
  • the curing dose is 30-60 kGy.
  • the beneficial effects of the present invention are: 1.
  • the production efficiency of the present invention is high, and the production speed of the traditional flame-retardant glass fiber tape production process is generally 10m/min because of the limitation of the site area, and the production speed of the EB-cured flame-retardant glass fiber tape can reach 25m/min or even higher; 2.
  • the adhesive does not need to use any volatile solvent, the solid content of the adhesive is 100%, it will not emit VOC into the air, and it will not affect the safety and health of workers; 3.
  • EB curing flame retardant glass fiber tape does not require baking, low energy consumption and energy saving.
  • Irradiation curing is the use of high-energy electron beams generated by an electron accelerator to bombard the insulating layer, breaking the molecular chain to form polymer free radicals, and then the polymer free radicals recombine cross-linking bonds, so that the original linear molecular structure becomes a three-dimensional network.
  • the molecular structure is formed to form crosslinks; an adhesive suitable for radiation curing is designed with the characteristics of radiation curing without baking, low energy consumption and energy saving.
  • An adhesive comprising the following components according to parts by mass:
  • the polyether acrylate is mixed with one or both of difunctionality and trifunctionality, while ensuring that the viscosity of the polyether acrylate is controlled between 100 and 2000cps; the acrylate is diluted
  • the monomer is one of isobornyl acrylate, hydroxypropyl acrylate, hydroxyethyl acrylate and isooctyl acrylate, all of which have good solubility and dilution;
  • the acrylate phosphate is monofunctional, bifunctional
  • the flame retardant filler is one or a mixture of two or more of magnesium hydroxide, aluminum hydroxide and calcium hydroxide.
  • a preparation method for preparing the above-mentioned adhesive, the polyether acrylate, acrylate diluent monomer, acrylic acid phosphate, triallyl isocyanurate, flame retardant filler and dispersant are mixed according to the proportion, at room temperature Stir at temperature for 20-30min.
  • the above-mentioned adhesive is applied to the flame-retardant glass fiber tape, and it is cured, and the curing method is as follows,
  • the flame retardant glass fiber tape is irradiated by EB in the atmosphere of nitrogen (oxygen concentration is lower than 200ppm), the irradiation height is 20mm, the conveying speed is 25m/min, the energy is 400 ⁇ 600keV, and the curing dose is 30 ⁇ 60kGy.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 500kev, EB curing dose: 50kgy), roll up and cut after irradiation.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 500kev, EB curing dose: 30kgy), roll up and cut after irradiation.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 500kev, EB curing dose: 50kgy), roll up and cut after irradiation.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 400kev, EB curing dose: 30kgy), roll up and cut after irradiation.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 400kev, EB curing dose: 50kgy), roll up and cut after irradiation.
  • alkali-free glass cloth is dipped into the glue tank of the adhesive, and the adhesive layer is applied to the reinforcing material layer through the dip coating process, and the amount of glue is 150g/m2;
  • the obtained alkali-free glass cloth containing the adhesive was cured by EB, and irradiated in an atmosphere of nitrogen (oxygen concentration lower than 200ppm), and the irradiation parameters were (irradiation height: 20mm, conveyor belt speed: 25m/min, EB Energy 600kev, EB curing dose: 30kgy), roll up and cut after irradiation.
  • this adhesive comprises EVA emulsion 30kg, aluminum hydroxide 50kg, aqueous dispersant 3kg, ethylene glycol butyl ether 5kg, deionized water 30kg, and prepare to form flame retardant glass fiber belt.
  • the 6 groups of examples are compared with the comparative examples.
  • the oxygen index and tensile strength of the adhesive prepared by this formula and the flame retardant glass fiber tape produced by the EB curing method are obviously higher than those of the prior art adhesive
  • the flame-retardant glass fiber tape prepared by the agent has obvious effect and will not cause pollution.
  • the present invention has high production efficiency. Due to the limitation of site area, the production speed of the traditional flame retardant glass fiber tape is generally 10m/min, while the production speed of EB cured flame retardant glass fiber tape can reach 25m/min or even. Higher; 2.
  • the adhesive does not need any volatile solvent, and the solid content of the adhesive is 100%, which will not emit VOC into the air, and will not affect the safety and health of workers; 3.
  • EB curing flame retardant The fiberglass tape does not need to be baked, and it consumes less energy and saves energy.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

本发明涉及一种胶黏剂、制备方法及阻燃玻璃纤维带的固化方法，制备方法，将聚醚丙烯酸酯、丙烯酸酯稀释单体、丙烯酸磷酸酯、三烯丙基异氰脲酸酯、阻燃填料以及分散剂按照比例进行混合，在室温温度下搅拌20～30min；固化方法为，S1、将无碱玻璃布浸入胶黏剂中，形成阻燃玻璃纤维带；S2、将阻燃玻璃纤维带在氮气氛围下进行EB辐照；S3、收卷分切。胶黏剂不会向空气中排放VOC，生产速率高；EB固化阻燃玻璃纤维带无需烘烤，耗能低，节省能源。

Description

一种胶黏剂、制备方法及阻燃玻璃纤维带的固化方法
本申请要求了申请日为2020年09月25日，申请号为202011023340.8，发明名称为“一种胶黏剂、制备方法及阻燃玻璃纤维带的固化方法”的发明专利申请的优先权，其全部内容通过引用结合在本申请中。
技术领域
本发明涉及电缆的生产与制造，尤其是涉及一种用于阻燃玻璃纤维带的胶黏剂、胶黏剂的制备方法以及阻燃玻璃纤维带的固化方法。
背景技术
阻燃玻璃纤维带主要用于光缆、通信电缆、电力电缆各部件之间绕包与纵包加工，起隔火作用，是一种环保型的耐热阻燃材料。它用于包扎电缆中的绝缘线芯，使绝缘线芯的结构保持稳定，确保线芯不松散和绝缘不被划伤，隔离绝缘层和外护层及内衬层，以防它们之间相互粘结而影响电缆的机械、物理、电性能等。当电缆遭到燃烧时，阻燃玻璃纤维带能够吸收大量的热量，并形成碳化层、隔绝氧气、保护绝缘层免受燃烧，使火灾的损失不致于进一步扩大化。
目前国内生产阻燃玻璃纤维带所用的胶水是通过使用树脂，水，成膜助剂，阻燃剂，配置成的胶黏剂，长期以来阻燃玻璃纤维带的制作，一般使用水性胶水，不可避免的需要使用成膜助剂(溶剂)帮助胶水的固化，对环境造成一定的污染，另外成膜助剂对作业人员的健康也有很大的威胁；阻燃玻璃纤维带在制作的过程需要30米长的烘箱烘烤，因为水的比热容较大，耗能较高，而且烘箱占地面积较大；阻燃玻璃纤维带因为浸涂速度以及烘烤速度的限制，线速度一般为10m/min,效率比较低。
发明内容
本发明所要解决的技术问题是提供一种无VOC、环保、低能耗、固化效率高的胶黏剂、制备方法及阻燃玻璃纤维带的固化方法。
本发明解决其技术问题所采取的技术方案是：一种胶黏剂，按照质量百分比包括以下组分：
Figure PCTCN2021077550-appb-000001
进一步具体的，按照质量份数包括以下组分：
Figure PCTCN2021077550-appb-000002
Figure PCTCN2021077550-appb-000003
进一步具体的，所述的聚醚丙烯酸酯为双官能度、三官能度中的其中一种或者两种混合。
进一步具体的，所述的聚醚丙烯酸酯的粘度控制在100～2000cps之间。
进一步具体的，所述的丙烯酸酯稀释单体为丙烯酸异冰片酯、丙烯酸羟丙酯、丙烯酸羟乙酯以及丙烯酸异辛酯中的一种。
进一步具体的，所述的丙烯酸磷酸酯为单官能度、双官能度中的其中一种或者两种混合。
进一步具体的，所述的阻燃填料为氢氧化镁、氢氧化铝以及氢氧化钙中的一种或者两种及两种以上混合。
一种胶黏剂的制备方法，将聚醚丙烯酸酯、丙烯酸酯稀释单体、丙烯酸磷酸酯、三烯丙基异氰脲酸酯、阻燃填料以及分散剂按照比例进行混合，在室温温度下搅拌20～30min。
一种阻燃玻璃纤维带的固化方法，该固化方法为，
S1、将无碱玻璃布浸入上述的胶黏剂中，形成阻燃玻璃纤维带；
S2、将阻燃玻璃纤维带在氮气氛围下进行EB辐照；
S3、收卷分切。
进一步具体的，所述的步骤S2中的EB辐照的辐照高度为20mm，输送速度为25m/min，能量为400～600keV，固化剂量为30～60kGy。
本发明的有益效果是：1.本发明生产效率高，传统阻燃玻璃纤维带生产工艺因为场地面积的限制，生产速度一般为10m/min,而EB固化的阻燃玻璃纤维带生产速度可以达到25m/min甚至更高；2.胶黏剂无需使用任何挥发性的溶剂，胶黏剂固含为100％,不会向空气中排放VOC，而且不会影响工人的安全和身体健康；3.EB固化阻燃玻璃纤维带无需烘烤，耗能低，节省能源。
具体实施方式
下面结合具体实施方式对本发明进行详细描述。
辐照固化是利用电子加速器产生的高能电子束轰击绝缘层，将分子链打断形成高分子自由基，然后高分子自由基重新组合成交联键，从而使原来的线性分子结构变成三维网状的分子结构而形成交联；以辐照固化无需烘烤、能耗低以及节省能源的特点设计一种适合辐照固化的胶黏剂。
一种胶黏剂，按照质量份数包括以下组分：
Figure PCTCN2021077550-appb-000004
Figure PCTCN2021077550-appb-000005
基于上述配方，优选按照质量份数包括以下组分：
Figure PCTCN2021077550-appb-000006
其中，所述的聚醚丙烯酸酯为双官能度、三官能度中的其中一种或者两种进行混合，同时保证聚醚丙烯酸酯的粘度控制在100～2000cps之间；所述的丙烯酸酯稀释单体为丙烯酸异冰片酯、丙烯酸羟丙酯、丙烯酸羟乙酯以及丙烯酸异辛酯中的一种，均具有良好的溶解性与稀释性；所述的丙烯酸磷酸酯为单官能度、双官能度中的其中一种或者两种混合；所述的阻燃填料为氢氧化镁、氢氧化铝以及氢氧化钙中的一种或者两种及两种以上混合。
一种制备上述胶黏剂的制备方法，将聚醚丙烯酸酯、丙烯酸酯稀释单体、丙烯酸磷酸酯、三烯丙基异氰脲酸酯、阻燃填料以及分散剂按照比例进行混合，在室温温度下搅拌20～30min。
将上述胶黏剂应用于阻燃玻璃纤维带上，对其固化，其固化方法为，
S1、首先将胶黏剂放入胶槽内，将无碱玻璃布浸入上述制作好的 胶黏剂中，通过浸涂工艺在无碱玻璃布上形成涂层，形成阻燃玻璃纤维带。
S2、将阻燃玻璃纤维带在氮气(氧气浓度低于200ppm)氛围下进行EB辐照，辐照高度为20mm，输送速度为25m/min，能量为400～600keV，固化剂量为30～60kGy。
S3、将阻燃玻璃纤维带收卷并分切为盘带。
下面举例对上述配方及方法进行说明。
实施例1：
制备胶黏剂，将双官聚醚丙烯酸酯10kg，丙烯酸异冰片酯20kg，单官丙烯酸磷酸酯5kg，三烯丙基异氰脲酸酯15kg，氢氧化铝50kg，分散剂3kg，投入到反应容器中，混合20分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量500kev，EB固化剂量：50kgy),辐照完之后收卷分切。
实施例2：
制备胶黏剂，将双官聚醚丙烯酸酯10kg，丙烯酸羟乙酯20kg，双官丙烯酸磷酸酯5kg，三烯丙基异氰脲酸酯15kg，氢氧化镁50kg，分散剂3kg，投入到反应容器中，混合20分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶 槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量500kev，EB固化剂量：30kgy),辐照完之后收卷分切。
实施例3：
制备胶黏剂，将双官聚醚丙烯酸酯10kg，丙烯酸羟丙酯20kg，单官丙烯酸磷酸酯5kg，三烯丙基异氰脲酸酯10kg，氢氧化钙55kg，分散剂3kg，投入到反应容器中，混合25分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量500kev，EB固化剂量：50kgy),辐照完之后收卷分切。
实施例4：
制备胶黏剂，将双官聚醚丙烯酸酯5kg，丙烯酸羟丙酯10kg，单官丙烯酸磷酸酯3kg，三烯丙基异氰脲酸酯20kg，氢氧化钙40kg，分散剂4kg，投入到反应容器中，混合25分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓 度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量400kev，EB固化剂量：30kgy),辐照完之后收卷分切。
实施例5：
制备胶黏剂，将双官聚醚丙烯酸酯20kg，丙烯酸羟丙酯30kg，单官丙烯酸磷酸酯8kg，三烯丙基异氰脲酸酯20kg，氢氧化钙45kg，分散剂5kg，投入到反应容器中，混合25分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量400kev，EB固化剂量：50kgy),辐照完之后收卷分切。
实施例6：
制备胶黏剂，将双官聚醚丙烯酸酯30kg，丙烯酸羟丙酯40kg，单官丙烯酸磷酸酯10kg，三烯丙基异氰脲酸酯20kg，氢氧化钙60kg，分散剂4kg，投入到反应容器中，混合20分钟，制得胶黏剂。
制备阻燃玻璃纤维带，将50g/m2的无碱玻璃布浸入胶黏剂的胶槽内，通过浸涂工艺为补强材料层上胶黏剂层，上胶量为150g/m2；将上述制得的含有胶黏剂的无碱玻璃布进行EB固化，在氮气(氧浓度低于200ppm)氛围下辐照，辐照参数为(辐照高度：20mm，输送带速度：25m/min，EB能量600kev，EB固化剂量：30kgy),辐照完之 后收卷分切。
对比例：采用现有技术制备胶黏剂，该胶黏剂包括EVA乳液30kg，氢氧化铝50kg，水性分散剂3kg，乙二醇丁醚5kg，去离子水30kg，并制备形成阻燃玻璃纤维带。
对上述6组实施例以及对比例进行测试，其测试结果如下：
Figure PCTCN2021077550-appb-000007
如上表所示，6组实施例与对比例进行对比，采用本配方制备的胶黏剂以及配合EB固化方式生产的阻燃玻璃纤维带的氧指数以及拉伸强度明显高于现有技术胶黏剂制备的阻燃玻璃纤维带，其效果明显且还不会产生污染。
综上，1.本发明生产效率高，传统阻燃玻璃纤维带生产工艺因为场地面积的限制，生产速度一般为10m/min,而EB固化的阻燃玻璃纤维带生产速度可以达到25m/min甚至更高；2.胶黏剂无需使用任 何挥发性的溶剂，胶黏剂固含为100％,不会向空气中排放VOC，而且不会影响工人的安全和身体健康；3.EB固化阻燃玻璃纤维带无需烘烤，耗能低，节省能源。
需要强调的是：以上仅是本发明的较佳实施例而已，并非对本发明作任何形式上的限制，凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明技术方案的范围内。

Claims (10)

  1. 一种胶黏剂，其特征在于，按照质量百分比包括以下组分：
    Figure PCTCN2021077550-appb-100001
  2. 根据权利要求1所述的胶黏剂，其特征在于，按照质量份数包括以下组分：
    Figure PCTCN2021077550-appb-100002
  3. 根据权利要求1或2所述的胶黏剂，其特征在于，所述的聚醚丙烯酸酯为双官能度、三官能度中的其中一种或者两种混合。
  4. 根据权利要求1或2所述的胶黏剂，其特征在于，所述的聚醚丙烯酸酯的粘度控制在100～2000cps之间。
  5. 根据权利要求1或2所述的胶黏剂，其特征在于，所述的丙烯酸酯稀释单体为丙烯酸异冰片酯、丙烯酸羟丙酯、丙烯酸羟乙酯以及丙烯酸异辛酯中的一种。
  6. 根据权利要求1或2所述的胶黏剂，其特征在于，所述的丙烯酸磷酸酯为单官能度、双官能度中的其中一种或者两种混合。
  7. 根据权利要求1或2所述的胶黏剂，其特征在于，所述的阻燃填 料为氢氧化镁、氢氧化铝以及氢氧化钙中的一种或者两种及两种以上混合。
  8. 一种权利要求1或2所述的胶黏剂的制备方法，其特征在于，将聚醚丙烯酸酯、丙烯酸酯稀释单体、丙烯酸磷酸酯、三烯丙基异氰脲酸酯、阻燃填料以及分散剂按照比例进行混合，在室温温度下搅拌20～30min。
  9. 一种阻燃玻璃纤维带的固化方法，其特征在于，该固化方法为，
    S1、将无碱玻璃布浸入权利要求1或2所述的胶黏剂中，形成阻燃玻璃纤维带；
    S2、将阻燃玻璃纤维带在氮气氛围下进行EB辐照；
    S3、收卷分切。
  10. 根据权利要求9所述的固化方法，其特征在于，所述的步骤S2中的EB辐照的辐照高度为20mm，输送速度为25m/min，能量为400～600keV，固化剂量为30～60kGy。
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