WO2022037175A1 - 一种船用5Ni钢埋弧焊接方法 - Google Patents
一种船用5Ni钢埋弧焊接方法 Download PDFInfo
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- WO2022037175A1 WO2022037175A1 PCT/CN2021/097059 CN2021097059W WO2022037175A1 WO 2022037175 A1 WO2022037175 A1 WO 2022037175A1 CN 2021097059 W CN2021097059 W CN 2021097059W WO 2022037175 A1 WO2022037175 A1 WO 2022037175A1
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- Prior art keywords
- welding
- submerged arc
- marine
- steel
- arc welding
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- 238000003466 welding Methods 0.000 title claims abstract description 97
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 39
- 239000010959 steel Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 18
- 230000004907 flux Effects 0.000 claims abstract description 10
- 238000005452 bending Methods 0.000 claims abstract description 9
- 239000011229 interlayer Substances 0.000 claims abstract description 5
- 239000011324 bead Substances 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 3
- 239000010953 base metal Substances 0.000 claims description 11
- 229910001563 bainite Inorganic materials 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 8
- 229910001566 austenite Inorganic materials 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 230000004927 fusion Effects 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 210000001503 joint Anatomy 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 241000446313 Lamella Species 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005120 petroleum cracking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3033—Ni as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K33/00—Specially-profiled edge portions of workpieces for making soldering or welding connections; Filling the seams formed thereby
- B23K33/004—Filling of continuous seams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3033—Ni as the principal constituent
- B23K35/304—Ni as the principal constituent with Cr as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/18—Submerged-arc welding
- B23K9/186—Submerged-arc welding making use of a consumable electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/235—Preliminary treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/32—Accessories
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/056—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
Definitions
- the invention relates to a welding method of high Ni steel, in particular to a welding method of marine 5Ni steel.
- liquefied petroleum gas ships liquefied ethylene ships and propane ships obtained by petroleum cracking and liquefaction are usually constructed of 5Ni steel with high strength, good low temperature toughness, high elongation and low remanence.
- the Ni content of 5Ni steel is between 4.7% and 5.3%. Due to the high Ni content of 5Ni steel, it not only brings a series of difficulties to the production of steel, but also brings application problems to subsequent manufacturers in welding and forming.
- a few domestic steel companies have successfully developed marine 5Ni steel that successfully meets the requirements of classification societies, and are slowly starting to put them on the market.
- welding especially in submerged arc welding, there are still low temperature toughness and unstable cold bending performance after welding, which makes it difficult to meet the requirements of classification societies for weldability tests.
- Chinese patent CN10852661A discloses a nickel-based solid wire gas shielded welding method to realize gas shielded welding of 5Ni steel and 9Ni steel, but only 9Ni steel welding has been described in the document with an example, as for 5Ni steel, this method is used How the welding effect is, there is no specific description. Solving the problem of poor weldability of 5Ni steel is an important part of the development of the shipping industry.
- the present invention selects suitable 5Ni steel plates, matches the matching welding consumables and the corresponding submerged arc butt welding process, and conducts a series of weldability mechanical performance tests. Sex test requirements.
- the purpose of the present invention is to provide a submerged arc welding process of marine 5Ni steel, which does not require preheating before welding and does not require heat treatment after welding, as follows
- the submerged arc welding groove of the splicing material adopts K-type groove, the groove angle is 45°, and the blunt edge is 5mm;
- welding parameters welding current is 410 ⁇ 10A, welding voltage is 32 ⁇ 1V, welding speed is 27 ⁇ 2cm/min, and welding line energy is 30 ⁇ 3KJ/cm. Weld until the weld is filled, and clean the weld bead with a wire brush after each pass; the flux baking system is 350°C ⁇ 1h; the interlayer temperature is controlled at ⁇ 80°C.
- the welding method of the present application is suitable for the splicing material with a thickness of 40 mm to 50 mm.
- the chemical composition and mass percentage of the welding wire used for welding are: C: ⁇ 0.03%, Si: 0.10-0.40%, Mn: 0.2-1.0%, P: ⁇ 0.020%, S: ⁇ 0.030%, Cr: 14 to 18%, Ni: 53 to 60%, W: 3.0 to 4.5%, Fe: 4.0 to 7.0%, Mo: 15.0 to 17.0%, and the remainder are unavoidable impurity elements.
- the toughness value is stable, of which the weld ⁇ 70J, the fusion line ⁇ 60J, HAZ ⁇ 100J, and the base metal ⁇ 180J, which meets the weldability certification and production requirements of the classification society, which is significantly higher than the -110 °C required by the classification society
- the ultra-low temperature transverse impact toughness value is ⁇ 27J.
- microstructure of the weld zone of the welded joint of the two spliced base metals obtained by the above-mentioned marine 5Ni steel submerged arc welding method is austenite structure, and the structure of the heat-affected zone is lower bainite structure, wherein the lower bainite structure has fine lamellae , thereby possessing good extremely low temperature toughness.
- Submerged arc welding has reached a high level of impact absorption energy values such as tensile strength of welded joints, welds of welded joints, fusion lines, and heat-affected zones.
- the welded joints have excellent low-temperature impact toughness and cold bending properties.
- the HAZ structure of the heat-affected zone of the welded joint of the present invention is mainly lower bainite structure, the bainite lamella is small, and the welding metal is mainly austenite structure, so that the weld has excellent strength and extremely low temperature toughness performance and Cold bending properties.
- Figure 1 is a schematic diagram of the welding pass of the 50mm+50mm submerged arc welding of the spliced base metal combination.
- FIG. 2 shows the weld structure of the welded joint in Example 1 of the present invention, which is an austenite structure.
- Example 3 shows the fusion line structure of the welded joint in Example 1 of the present invention, one side is austenite structure, the other side is lower bainite structure, and the bainite lamellae are fine.
- Example 4 shows the structure of the HAZ area of the welded joint 3 mm from the fusion line in Example 1 of the present invention, which is a lower bainite structure with fine lamellae, and the initial austenite structure is smaller than the initial austenite structure in FIG. 3 .
- Base material Marine 5Ni steel with tensile strength of 653MPa, transverse impact toughness value at -130°C extremely low temperature ⁇ 180J, thick plate combination 50mm+50mm.
- the size of each test plate for butt welding is 1300mm ⁇ 300mm ⁇ 50mm, and the submerged arc welding groove adopts K-type groove, the groove angle is 45°, and the blunt edge is 5mm;
- Welding wire Its chemical composition and mass percentage are: C: 0.02%, Si: 0.15%, Mn: 0.4%, P: 0.015%, S: 0.01%, Cr: 16.4%, Ni: 57%, W: 3.5% , Fe: 5.50%, Mo: 16.0%, and the remainder is inevitable impurity elements.
- the wire diameter is And matched with sintered flux INCOFLUX 9 for welding, the mechanical properties of the deposited metal are: yield strength Rp 0.2 : 407MPa, tensile strength Rm: 665MPa, elongation A: 42.0%, Z-direction shrinkage: 38%, -110 °C AKv shock absorption energy value: 92J, 89J, 77J.
- the welding process parameters are: welding current 410 ⁇ 10A, welding voltage 32 ⁇ 1V, welding speed 27 ⁇ 2cm/min, welding line energy 30KJ/cm; flux baking system is 350°C ⁇ 1h; interlayer temperature is controlled at 50- 70°C. See Figure 1 for the welding pass.
- Base material marine 5Ni steel with tensile strength of 639MPa, thick plate combination of 40mm+40mm.
- the size of each test plate for butt welding is 1300mm ⁇ 300mm ⁇ 40mm, and the submerged arc welding groove adopts K-type groove, the groove angle is 45°, and the blunt edge is 5mm;
- Welding wire its chemical composition and mass percentage are: C: 0.02%, Si: 0.20%, Mn: 0.45%, P: 0.013%, S: 0.01%, Cr: 16.8%, Ni: 58%, W: 3.3% , Fe: 5.80%, Mo: 16.5%, and the remainder is an unavoidable impurity element.
- the wire diameter is And matched with sintered flux INCOFLUX 9 for welding, the mechanical properties of the deposited metal are: yield strength Rp 0.2 : 513MPa, tensile strength Rm: 660MPa, elongation A: 32.0%, Z-direction shrinkage: 51%, -110 °C AKv shock absorption energy value: 93J, 109J, 84J.
- the welding process parameters are: welding current 410 ⁇ 10A, welding voltage 32 ⁇ 1V, welding speed 27 ⁇ 2cm/min, welding line energy 30KJ/cm; flux baking system is 350°C ⁇ 1h; interlayer temperature is controlled at 50- 70°C.
- the marine 5Ni steel welded by the above welding method has been tested on the mechanical properties of the welded joints, and the results of the tensile test, impact test and cold bending test are shown in Table 1, Table 2 and Table 3, respectively.
- the tensile strength of the welded joint of the steel plate is between 620 and 660MPa
- the positive and negative cold bending at 180 °C is qualified
- the weld seam, fusion line, and HAZ zone are extremely low temperature transverse impact at -130 °C
- the toughness value is stable and fully meets the weldability certification and production requirements of the classification society.
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- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Arc Welding In General (AREA)
- Nonmetallic Welding Materials (AREA)
- Butt Welding And Welding Of Specific Article (AREA)
Abstract
Description
Claims (7)
- 一种船用5Ni钢埋弧焊接方法,其特征在于:(1)以抗拉强度为630~670MPa的船用5Ni钢作为拼接母材,拼接母材的-130℃横向冲击韧性值≥180J;匹配的焊接材料:焊接材料抗拉强度630~710MPa,焊丝直径为φ2.4mm以上,牌号为INCO-WELD Filler Metal C-276,焊剂为INCOFLUX 9;(2)拼接材料的埋弧焊接坡口采用K型坡口;(3)焊接参数:焊接电流410±10A、焊接电压为32±1V、焊接速度为27±2cm/min、焊接线能量30±3KJ/cm,连续对相同板厚的拼接母材的对接接头施焊,直至焊缝填满为止,并在每道次焊接后采用钢丝刷清理焊道;焊剂烘烤制度为350℃×1h;层间温度控制在≤80℃。
- 根据权利要求1所述的船用5Ni钢埋弧焊接方法,其特征在于:所述拼接材料的厚度为40mm~50mm。
- 根据权利要求1所述的船用5Ni钢埋弧焊接方法,其特征在于:所述K型坡口的坡口角度为45°,钝边为5mm。
- 根据权利要求1所述的船用5Ni钢埋弧焊接方法,其特征在于:所述焊丝的化学组分及质量百分比为,C:≤0.03%,Si:0.10~0.40%,Mn:0.2~1.0%,P:≤0.020%,S:≤0.030%,Cr:14~18%,Ni:53~60%,W:3.0~4.5%,Fe:4.0~7.0%,Mo:15.0~17.0%,余量为不可避免的杂质元素。
- 根据权利要求4所述的船用5Ni钢埋弧焊接方法,其特征在于:两拼接母材的焊接接头经试验焊缝超声波探伤结果达到GB/T 11345-1989标准规定的要求I级要求。
- 根据权利要求4所述的船用5Ni钢埋弧焊接方法,其特征在于:两拼接母材的焊接接头的抗拉强度介于620~660MPa,弯心直径D=4a,180℃正反冷弯合格,-130℃极低温横向冲击韧性值稳定:焊缝处的横向冲击韧性值≥70J、熔合线的横向冲击韧性值≥60J、HAZ的横向冲击韧性值≥100J、母材的横向冲击韧性值≥180J,满足船级社可焊性认证及生产要求。
- 根据权利要求4所述的船用5Ni钢埋弧焊接方法,其特征在于:两拼接母材的焊接接头的焊缝区组织为奥氏体组织,热影响区组织为下贝氏体组织,其中,下贝氏体组织片层细小,由此具备良好的极低温韧性。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA3189684A CA3189684A1 (en) | 2020-08-18 | 2021-05-30 | A submerged arc welding method of 5ni steel for shipbuilding |
KR1020237009105A KR20230048558A (ko) | 2020-08-18 | 2021-05-30 | 선박용 5Ni 강 서브머지드 아크 용접 방법 |
JP2023512130A JP7482319B2 (ja) | 2020-08-18 | 2021-05-30 | 船用5Ni鋼サブマージアーク溶接方法 |
EP21857276.6A EP4180164A4 (en) | 2020-08-18 | 2021-05-30 | 5NI SHIPBUILDING STEEL POWDER SUBSUB ARC WELDING PROCESS |
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CN202010832616.0 | 2020-08-18 | ||
CN202010832616.0A CN112192001B (zh) | 2020-08-18 | 2020-08-18 | 一种船用5Ni钢埋弧焊接方法 |
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EP (1) | EP4180164A4 (zh) |
JP (1) | JP7482319B2 (zh) |
KR (1) | KR20230048558A (zh) |
CN (1) | CN112192001B (zh) |
CA (1) | CA3189684A1 (zh) |
WO (1) | WO2022037175A1 (zh) |
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CN114833531A (zh) * | 2022-04-18 | 2022-08-02 | 恒谦科技(广州)有限公司 | 一种低温高锰钢t型接头的焊接方法 |
CN115178839A (zh) * | 2022-07-14 | 2022-10-14 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种提高QStE钢板焊接接头弯曲性能的方法 |
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CN112192001B (zh) * | 2020-08-18 | 2022-05-06 | 江阴兴澄特种钢铁有限公司 | 一种船用5Ni钢埋弧焊接方法 |
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- 2021-05-30 EP EP21857276.6A patent/EP4180164A4/en active Pending
- 2021-05-30 KR KR1020237009105A patent/KR20230048558A/ko unknown
- 2021-05-30 JP JP2023512130A patent/JP7482319B2/ja active Active
- 2021-05-30 CA CA3189684A patent/CA3189684A1/en active Pending
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114833531A (zh) * | 2022-04-18 | 2022-08-02 | 恒谦科技(广州)有限公司 | 一种低温高锰钢t型接头的焊接方法 |
CN114833531B (zh) * | 2022-04-18 | 2024-04-05 | 广州市洲航船舶设备有限公司 | 一种低温高锰钢t型接头的焊接方法 |
CN115178839A (zh) * | 2022-07-14 | 2022-10-14 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种提高QStE钢板焊接接头弯曲性能的方法 |
CN115178839B (zh) * | 2022-07-14 | 2024-03-19 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种提高QStE钢板焊接接头弯曲性能的方法 |
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Publication number | Publication date |
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EP4180164A1 (en) | 2023-05-17 |
EP4180164A4 (en) | 2023-12-20 |
CA3189684A1 (en) | 2022-02-24 |
JP2023539123A (ja) | 2023-09-13 |
CN112192001A (zh) | 2021-01-08 |
CN112192001B (zh) | 2022-05-06 |
JP7482319B2 (ja) | 2024-05-13 |
KR20230048558A (ko) | 2023-04-11 |
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