WO2022028054A1 - Electrowetting display device structure and packaging method therefor - Google Patents

Electrowetting display device structure and packaging method therefor Download PDF

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Publication number
WO2022028054A1
WO2022028054A1 PCT/CN2021/096281 CN2021096281W WO2022028054A1 WO 2022028054 A1 WO2022028054 A1 WO 2022028054A1 CN 2021096281 W CN2021096281 W CN 2021096281W WO 2022028054 A1 WO2022028054 A1 WO 2022028054A1
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substrate
polar liquid
display device
lower substrate
device structure
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PCT/CN2021/096281
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French (fr)
Chinese (zh)
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周国富
唐彪
魏妙杨
冯豪
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华南师范大学
深圳市国华光电科技有限公司
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Publication of WO2022028054A1 publication Critical patent/WO2022028054A1/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/004Optical devices or arrangements for the control of light using movable or deformable optical elements based on a displacement or a deformation of a fluid
    • G02B26/005Optical devices or arrangements for the control of light using movable or deformable optical elements based on a displacement or a deformation of a fluid based on electrowetting

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  • the present invention relates to the technical field of electrowetting, and in particular, to an electrowetting display device structure and a packaging method thereof.
  • Electrowetting refers to changing the wettability of the droplet on the substrate by changing the voltage between the droplet and the hydrophobic dielectric layer, that is, changing the contact angle to deform the droplet. , the phenomenon of displacement.
  • the electrowetting display is a reflective display device based on the electrowetting principle, which reflects the external light source through inks with different colors, thereby realizing a full-color display effect.
  • Electrowetting displays have the advantages of low energy consumption, wide color gamut, high response, high contrast, and visual health, so they are considered to be one of the mainstream display technologies in the future. In recent years, the demand for foldability and convenience of display devices has been increasing, and research on flexible display devices has also increased.
  • the pixel structure in electrowetting devices is driven by soft materials such as oil and water. Electrowetting display devices have natural advantages and potential in the field of flexibility.
  • the basic structure of the electrowetting device consists of two upper and lower substrates and two immiscible polar liquids 10' and a non-polar solution 9' filled in a sealed cavity formed by opposing the two substrates.
  • the lower substrate contains The structure includes a lower support plate 4', a first electrode 5', a hydrophobic insulating layer (or an insulating layer coated with a hydrophobic material on the surface) 6', and a pixel wall 7'.
  • the upper substrate includes an upper support plate 1', a second electrode 2', a sealant frame 3', and a support column structure 8'.
  • the pixel grid area enclosed between the pixel walls is the display area.
  • the hydrophobicity of the material of the pixel wall 7' is lower than that of the hydrophobic insulating layer 6', and the pixel wall 7' is suitable for the polar liquid 10' and the non-polar solution 9. ', so that the wettability of the polar liquid 10' on the surface of the pixel wall 7' is better, so that the non-polar solution 9' can be filled in each pixel grid and the hydrophilicity of the pixel wall 7' can be controlled.
  • the non-polar liquid 9' in each pixel is isolated.
  • the materials used in the electrowetting device are generally transparent materials, except that the non-polar solution 9' is mostly colored opaque materials or materials with low light transmittance, where the light transmittance of the material generally depends on the application direction of the electrowetting device.
  • the preparation process for the above-mentioned flexible electrowetting device structure is to coat a hydrophobic insulating layer 6 on the lower support plate 4' with the first electrode 5' by methods such as spin coating, screen printing, slit coating, etc. '. Then a layer of photoresist is coated on the surface of the hydrophobic insulating layer 6' to prepare pixel walls, but because the surface energy of the hydrophobic insulating layer 6' is very low and has a very low contact angle hysteresis, such as Teflon AF1600, the advancing contact angle is 124 ⁇ 2 °, the receding contact angle is 113 ⁇ 2°, so it is difficult to coat a uniform photoresist film on the surface of the hydrophobic insulating layer 6'.
  • the method used by most electrowetting devices at present is to change the hydrophilicity of the surface of the hydrophobic insulating layer 6' by plasma modification to make it easier to coat the photoresist on its surface.
  • the contact angle hysteresis of the hydrophobic insulating layer 6' increases, the surface adhesion increases, and it is easier for photoresist to form a film on its surface.
  • the photoresist film formation, curing, photolithography, and development are completed, in order to restore the hydrophobicity of the modified surface of the hydrophobic insulating layer 6', it is necessary to reflow the fresh fluororesin material at the bottom of the hydrophobic insulating layer 6' by heating at a high temperature. to the surface, and reflow the fluororesin material with poor surface hydrophobicity to the bottom, and at the same time restore the flatness of the surface at high temperature to restore the hydrophobicity of the surface of the hydrophobic insulating layer 6'.
  • the current traditional electrowetting devices need to involve the modification of the surface of the hydrophobic insulating layer 6' in the preparation process, so as to ensure that the photoresist is more easily coated on the surface of the hydrophobic layer to form a uniform film, so the pixel wall 7' is After completion, a high temperature reflow method needs to be used to restore the hydrophobicity of the surface of the hydrophobic insulating layer 6'.
  • a high temperature reflow method needs to be used to restore the hydrophobicity of the surface of the hydrophobic insulating layer 6'.
  • the surface of the hydrophobic insulating layer covered by the pixel wall 7' is different from the surface of the hydrophobic insulating layer 6' exposed in the cavity. , and impurities remaining in the development process of the pixel wall 7' can cause the failure of the electrowetting device.
  • a support column structure 8' is usually set on the upper support plate 1'. Due to the limitation of process accuracy, the positioning of the packaging is easily caused by the dislocation of the support column structure 8' and the pixel wall 7', which affects the flatness of the upper and lower substrates, and thus affects the performance stability and yield of the device.
  • the present invention aims to solve at least one of the technical problems existing in the prior art. Therefore, the present invention proposes an electrowetting display device structure and a packaging method thereof, which can avoid the defects caused by surface modification of the hydrophobic insulating layer material and high temperature reflow, and completely ensure that the original characteristics of the surface of the hydrophobic insulating layer are not damaged. , in order to improve the reliability of electrowetting optics.
  • an electrowetting display device structure comprising an upper substrate and a lower substrate disposed opposite to each other, and the upper substrate sequentially includes a first substrate, a first electrode and a lower substrate along a direction toward the lower substrate.
  • a conductive pixel wall, the conductive pixel wall encloses a pixel grid
  • the lower substrate sequentially includes a second substrate, a second electrode and a hydrophobic insulating layer along the direction toward the upper substrate, the upper substrate and the lower substrate
  • An adjustment area is formed therebetween, the adjustment area is filled with mutually immiscible polar liquid and non-polar liquid, and the end of the conductive pixel wall protrudes into the non-polar liquid.
  • the above-mentioned hydrophobic insulating layer may be a single layer, for example, formed of a material having hydrophobic insulating properties; it may also be constituted by disposing a hydrophobic layer on the insulating layer, for example, coating a hydrophobic material on the insulating layer.
  • the first substrate and the second substrate are flexible substrates.
  • a sealant frame is disposed between the upper substrate and the lower substrate.
  • the sealant frame is a flexible sealant frame.
  • the material of the sealant frame is pressure-sensitive adhesive.
  • the first electrode and the second electrode are connected with a power supply component.
  • the way of connecting the power supply components can be that the first electrode and the second electrode are independently connected to different power supply components, and by controlling the power supply components connected to the first electrode, the on-off state of the first electrode is controlled, and then the power supply components connected to the first electrode are controlled.
  • the conductive pixel wall controls the switching state of the second electrode by controlling the power supply component connected to the second electrode, thereby controlling the wettability of the hydrophobic insulating layer, thereby realizing the switching of the pixel; it can also be through the circuit of the same power supply component.
  • the control of the first electrode and the second electrode is realized in the middle, and the driving of the device is further realized.
  • a second aspect of the present invention provides a method for encapsulating the above-mentioned electrowetting display device structure, comprising the following steps:
  • the liquid level of the non-polar liquid is higher than the height of the conductive pixel wall;
  • the substrate is removed, and a sealant frame is arranged on the lower substrate, the sealant frame has an opening, and the lower substrate is covered above the upper substrate;
  • the opening is sealed.
  • the process of applying pressure to the lower substrate includes: first applying a first pressure to a central area of the lower substrate, and then applying a first pressure to a center area of the lower substrate. A second pressure is applied to the surrounding area, and the first pressure is greater than the second pressure.
  • the encapsulation method of the electrowetting display device structure further includes the step of volatilizing part of the polar liquid before the step of filling the non-polar liquid over the polar liquid.
  • the method of volatilizing part of the polar liquid is any one of heating, vacuum evaporation, and adding a volatile solvent to volatilize.
  • the volatile solvent includes at least one of ethylene glycol and methanol.
  • the embodiment of the present invention provides an electrowetting display device structure, which cancels the traditional method of constructing a pixel wall structure on a hydrophobic insulating layer, avoids the influence of high temperature reflow on the substrate, and the hydrophobic insulating layer does not need to be formed and cured after film formation.
  • the surface modification and recovery treatment are then carried out to completely ensure that the original characteristics of the surface of the hydrophobic insulating layer are not destroyed, maintain the hydrophobic characteristics of the surface of the hydrophobic insulating layer, and keep the surface hysteresis angle of the hydrophobic insulating layer to a minimum, which is conducive to the opening of the pixels of the electrowetting device.
  • the closing process improves the reliability of electrowetting optical devices, and at the same time separates and shrinks the non-polar solution through the conductive pixel walls and electrodes, solving the problem that the pixel wall structure is built on the surface of the hydrophobic insulating layer and destroys its original characteristics. risk of device failure.
  • the conductive pixel wall is arranged on the upper substrate in the embodiment of the present invention, the surface structure of the hydrophobic insulating layer is not damaged, so impurities will not remain on the surface of the hydrophobic insulating layer due to the developing process of the conductive pixel wall, which reduces the failure risk of the device. .
  • the conductive pixel wall is directly connected to the first electrode, and the first electrode is energized, so that the conductive pixel wall can freely cut the non-polar liquid, and the conductive pixel wall also acts as a support.
  • the role of the column replaces the pixel wall and support column structure in the traditional electrowetting device, avoiding the traditional electrowetting device that requires the precise alignment of the pixel wall and the support column structure and the dislocation of the support column structure and the pixel wall.
  • the present invention can realize the bonding package without precise alignment, can realize self-support, improve the bending performance and yield of the device, and has certain advantages in flexibility, in addition to opening the first electrode
  • the non-polar liquid can be separated, and the non-polar liquid shrinks and reduces a certain spreading area, so the threshold value of the applied voltage required by the second electrode of the lower substrate will be correspondingly reduced, which reduces the threshold voltage to a certain extent, and realizes the device. faster response.
  • FIG. 1 is a schematic structural diagram of a conventional electrowetting device
  • FIG. 2 is a schematic structural diagram of the electrowetting display device according to the first embodiment of the present invention.
  • FIG. 3 is a schematic diagram of separation of non-polar liquids in an electrowetting display device structure when the first electrode of the upper substrate is opened;
  • FIG. 4 is a schematic diagram of shrinkage of a non-polar liquid when the second electrode of the lower substrate in the electrowetting display device structure is opened;
  • FIG. 5 is a schematic diagram of a pixel opening process of an electrowetting display device structure
  • Fig. 6 is the filling schematic diagram of polar liquid and non-polar liquid
  • FIG. 7 is a schematic diagram of the arrangement of the sealant frame of the lower substrate.
  • FIG. 8 is a schematic diagram of encapsulation of the upper substrate and the lower substrate.
  • the azimuth description such as the azimuth or position relationship indicated by up, down, front, rear, left, right, etc.
  • the azimuth description is based on the azimuth or position relationship shown in the drawings, only In order to facilitate the description of the present invention and simplify the description, it is not indicated or implied that the indicated device or element must have a particular orientation, be constructed and operated in a particular orientation, and therefore should not be construed as limiting the present invention.
  • the electrowetting display device structure according to the first embodiment of the present invention is shown, including an upper substrate 10 and a lower substrate 20 .
  • the upper substrate 10 sequentially includes a first substrate 11 , a first electrode 12 and a conductive pixel wall 13 along the direction toward the lower substrate 20 .
  • the first substrate 11 is a flexible substrate, and the flexible substrate can be exemplified by PEN (poly ethylene phthalate) or flexible glass
  • the first electrode 12 is an ITO electrode
  • the conductive pixel wall 13 encloses a pixel grid
  • the conductive pixel wall 13 is made of conductive photoresist
  • the conductive pixel wall 13 is used as the pixel electrode and the first pixel.
  • An electrode 12 is directly conductive.
  • the lower substrate 20 sequentially includes a second substrate 21 , a second electrode 22 and a hydrophobic insulating layer 23 along the direction toward the upper substrate 10 .
  • the second substrate 21 is a flexible substrate
  • the second electrode 22 is an ITO electrode.
  • An adjustment area is formed between the upper substrate 10 and the lower substrate 20 , the adjustment area is filled with the polar liquid 30 and the non-polar liquid 40 that are immiscible with each other, and the end 14 of the conductive pixel wall 13 extends into the non-polar liquid 40 , but not in contact with the hydrophobic insulating layer 23 of the lower substrate 20 , that is, there is a distance between the conductive pixel wall 13 and the hydrophobic insulating layer 23 , and the distance is smaller than the average thickness of the non-polar liquid 40 , the end 14 of the conductive pixel wall 13 A non-polar liquid region 41 is formed between the hydrophobic insulating layer 23 .
  • the conductive pixel wall 13 (with a certain degree of hydrophilicity) has the characteristics of the equipotential body, so that the thinner non-polar liquid region 41 under it is subjected to a greater electric field strength, resulting in the non-polarity
  • the non-polar liquid in the liquid region 41 is preferentially broken and moved, so as to achieve the effect of display pixel segmentation.
  • FIG. 3 a schematic diagram of the separation of the non-polar liquid in the open state of the first electrode of the upper substrate in the electrowetting display device structure is shown.
  • the first electrode 12 When the first electrode 12 is open (ie, when it is energized), the non-polar liquid at the thin non-polar liquid region 41 under the conductive pixel wall 13 is ruptured and separated, and the conductive pixel wall 13 also acts on the upper and lower substrates of the device.
  • the support function prevents the device from collapsing, and the non-polar liquid 40 is divided in advance due to the electric field, which reduces the threshold voltage required for the non-polar liquid 40 to shrink, and reduces the threshold voltage for pixel turn-on, thereby improving the device response speed.
  • FIG. 4 there is shown a schematic diagram of the shrinkage of the non-polar liquid in the open state of the second electrode of the lower substrate in the electrowetting display device structure.
  • the open state of the second electrode 22 ie, when energized
  • the second electrode 22 is applied to A certain voltage, according to the principle of electrowetting, the voltage causes the change of the surface tension, and the non-polar liquid 40 is pushed to one pass, thereby realizing the optical switch.
  • the driving method of the above electrowetting display structure is as follows: the first electrode 12 is connected to the conductive pixel wall 13, and the electric field of the conductive pixel wall 13 is directly affected by the first electrode 12.
  • FIG. 5 the electrowetting display structure is shown. Pixel turn on process.
  • the first electrode 12 and the second electrode 22 are in a pixel-off state, and the non-polar liquid 40 is in a spreading state.
  • the first electrode 12 is in an open state.
  • the surface wettability of the conductive pixel wall 13 changes, the electric field at the bottom of the conductive pixel wall 13 becomes stronger, and the polar liquid 30 flows toward the conductive pixel.
  • the non-polar liquid region 41 at the bottom end of the wall 13 accumulates, thereby causing the non-polar liquid 40 to rupture.
  • a certain driving voltage is applied to the second electrode 22 .
  • the surface tension of the hydrophobic insulating layer 23 of the lower substrate 20 changes due to the change in wettability, so that the non-polar liquid 40 changes in surface tension. shrink, thereby enabling electrowetting optical switches.
  • An embodiment of the present invention also provides a method for encapsulating the above electrowetting display structure, comprising the following steps:
  • the first electrode 12 is prepared on the first substrate 11 .
  • the electrode film forming technology is widely used in industrial production and will not be repeated here.
  • a layer of photoresist material is coated on the surface of the first electrode 12 to prepare the conductive pixel wall 13, and the coating methods include but are not limited to slit coating, spin coating, screen printing, flexible printing and other methods.
  • the surface of the resist is covered with a mask, exposed by ultraviolet light, and finally obtained by developing a conductive pixel wall 13, and the conductive pixel wall is surrounded by a pixel grid.
  • the upper substrate 10 is turned upside down (the side with the conductive pixel walls 13 is facing upward), and the pixel grids surrounded by the conductive pixel walls 13 are filled with a polar liquid 30.
  • the polar liquid 30 is a polar electrolyte solution.
  • the horizontal height of the polar liquid 30 is lower than the height of the conductive pixel wall 13 , so as to facilitate the subsequent filling of the non-polar liquid 40 .
  • the second electrode 22 is prepared on the second substrate 21 by using the existing means, and the hydrophobic insulating layer 23 is coated with a solution of a hydrophobic material by spin coating, dip coating, screen printing, flexographic printing, etc. The surface of the second electrode 22 is finally cured in a high temperature environment.
  • the embodiment of the present invention proposes the following methods:
  • a sealant frame 50 is disposed on the hydrophobic insulating layer of the lower substrate 20 , the material of the sealant frame 50 can be a pressure-sensitive adhesive material, and the sealant frame 50 has at least one opening 51 , as shown in FIG. 6 , at 4 There are openings 51 at different positions, the purpose is to allow excess non-polar liquid to flow out through the openings 51 during the packaging process;
  • the lower substrate 20 is then covered on the upper substrate 10 , the upper substrate 10 and the lower substrate 20 are kept horizontal, and then pressure is applied to the lower substrate 20 , and the excess non-polar liquid 40 is removed from the sealant frame 50 .
  • the openings flow out, then seal the openings with encapsulating materials such as UV acrylate, and finally press and dry to complete the encapsulation of the entire device.
  • the process of applying pressure to the lower substrate 20 is as follows: first, a relatively large first pressure 61 is applied to the central area of the lower substrate 20 . Due to the uneven force on the lower substrate 20 , the central area of the lower substrate 20 will contact the non-polarity first. liquid 40, and then apply a small second pressure 62 to the surrounding area of the lower substrate 20, the lower substrate 20 is less deformed, the contact area with the non-polar liquid 40 increases, and the excess non-polar liquid 40 passes through the sealant frame 50 openings flow out. After the lower substrate 20 is completely in contact with the non-polar liquid 40, the opening is sealed with ultraviolet acrylate or the like, and finally the entire device is packaged by pressing and drying.
  • the level of the filled polar liquid 30 is made lower than the height of the conductive pixel wall 13 by volatilizing part of the polar liquid.
  • Ways to volatilize part of the polar liquid include but are not limited to heating, vacuum evaporation, and volatilization by adding a volatile solvent. Since the volatilization process is carried out simultaneously on the entire liquid surface, when part of the polar liquid is volatilized, the entire liquid surface is still horizontal.
  • the method of adding a volatile solvent to volatilize can add some organic solvents such as ethylene glycol or methanol with higher volatility than the polar electrolyte solution to the polar electrolyte solution, and volatilize the polar electrolyte solution without violent volatilization. In this way, the amount of liquid level drop can be precisely controlled by controlling the content of the added volatile solvent. After the volatilization process is completed, no organic components will remain in the polar electrolyte solution.

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Abstract

Disclosed are an electrowetting display device structure and a packaging method thereof. The electrowetting display device structure comprises an upper substrate and a lower substrate which are oppositely disposed; the upper substrate sequentially comprises a first substrate, a first electrode, and conductive pixel walls along a direction towards the lower substrate; the conductive pixel walls define pixel grids; the lower substrate sequentially comprises a second substrate, a second electrode, and a hydrophobic insulating layer along a direction towards the upper substrate; an adjusting region is formed between the upper substrate and the lower substrate; the adjusting region is filled with polar liquid and non-polar liquid which are immiscible; and end portions of the conductive pixel walls extend into the non-polar liquid. According to the present invention, by disposing the conductive pixel walls on the upper substrate, defects caused by surface modification and high-temperature backflow of the material of a hydrophobic insulating layer can be avoided, and the original characteristics of the surface of the hydrophobic insulating layer are completely ensured to be not damaged, thereby improving the reliability of an electrowetting optical device.

Description

电润湿显示器件结构及其封装方法Electrowetting display device structure and packaging method thereof 技术领域technical field
本发明涉及电润湿技术领域,尤其是涉及一种电润湿显示器件结构及其封装方法。The present invention relates to the technical field of electrowetting, and in particular, to an electrowetting display device structure and a packaging method thereof.
背景技术Background technique
电润湿:电润湿(Electrowetting,EW)是指通过改变液滴与疏水介电层之间的电压,来改变液滴在基板上的润湿性,即改变接触角,使液滴发生形变、位移的现象。电润湿显示器是一种基于电润湿原理的反射式显示装置,其通过具有不同颜色的油墨对外界的光源进行反射,从而实现全色彩的显示效果。电润湿显示器具有能耗低、色域广、高响应、高对比度、视觉健康等优点,因此被认为是未来的主流显示技术之一。近年来,显示器件可折叠与便捷性的需求日益高涨,对柔性显示器件的研究也就越来越多。而电润湿器件中像素结构所驱动的是油水等软性材料,电润湿显示器件在柔性化领域具有天然的优势和潜力。Electrowetting: Electrowetting (EW) refers to changing the wettability of the droplet on the substrate by changing the voltage between the droplet and the hydrophobic dielectric layer, that is, changing the contact angle to deform the droplet. , the phenomenon of displacement. The electrowetting display is a reflective display device based on the electrowetting principle, which reflects the external light source through inks with different colors, thereby realizing a full-color display effect. Electrowetting displays have the advantages of low energy consumption, wide color gamut, high response, high contrast, and visual health, so they are considered to be one of the mainstream display technologies in the future. In recent years, the demand for foldability and convenience of display devices has been increasing, and research on flexible display devices has also increased. The pixel structure in electrowetting devices is driven by soft materials such as oil and water. Electrowetting display devices have natural advantages and potential in the field of flexibility.
参见图1,电润湿器件的基本结构由上下两个基板以及两个基板相对形成的密封腔中填充的两种不互溶的极性液体10’和非极性溶液9’组成,下基板包含结构有下支撑板4’、第一电极5’、疏水绝缘层(或在表面涂覆疏水材料的绝缘层)6’、像素墙7’。上基板包含结构有上支撑板1’、第二电极2’和密封胶框3’以及支撑柱结构8’。像素墙之间围成的像素格区域为显示区域,像素墙7’材料的疏水性低于疏水绝缘层6’的疏水性,并且像素墙7’对于极性液体10’和非极性溶液9’的亲疏性,使得极性液体10’在像素墙7’表面的润湿性更好,这样就可以控制非极性溶液9’填充在每个像素格内并且像素墙7’的亲水性将每个像素中的非极性液体9’隔断开。电润湿器件中所用材料一般均为透明材料,除了非极性溶液9’多为彩色不透明材料或低透光性材料,这里材料的透光性一般取决于电润湿器件的应用方向。对于上述的柔性电润湿器件结构的制备工艺是通过旋涂、丝网印刷、狭缝涂布等方法在带有第一电极5’的下支撑板4’上涂覆一层疏水绝缘层6’。然后在疏水绝缘层6’表面涂覆一层光刻胶来制备像素墙,但是由于疏水绝缘层6’表面的表面能很低并且具有很低的接触角滞后例如Teflon AF1600前进接触角124±2°,后退接触角113±2°,因此很难在疏水绝缘层6’表面涂覆一层均匀的光刻胶薄膜。目前大多数电润湿器所采用的方法是通过plasma改性的方法,改变疏水绝缘层6’表面的亲水性来使光刻胶更容易涂覆在其表面。表面改性后,疏水绝缘层6’接触角滞后增大,表面粘附性增加,更加易于光刻胶在其表面成膜。等光刻胶成膜固化、光刻、显影一系列流程完成之后,为了恢复改性后疏水绝缘层6’表面的疏水 性,需要通过高温加热使疏水绝缘层6’底层新鲜的氟树脂材料回流到表面,并将表面疏水性差的氟树脂材料回流到下面,同时高温恢复表面的平整度来恢复疏水绝缘层6’表面的疏水性。Referring to FIG. 1, the basic structure of the electrowetting device consists of two upper and lower substrates and two immiscible polar liquids 10' and a non-polar solution 9' filled in a sealed cavity formed by opposing the two substrates. The lower substrate contains The structure includes a lower support plate 4', a first electrode 5', a hydrophobic insulating layer (or an insulating layer coated with a hydrophobic material on the surface) 6', and a pixel wall 7'. The upper substrate includes an upper support plate 1', a second electrode 2', a sealant frame 3', and a support column structure 8'. The pixel grid area enclosed between the pixel walls is the display area. The hydrophobicity of the material of the pixel wall 7' is lower than that of the hydrophobic insulating layer 6', and the pixel wall 7' is suitable for the polar liquid 10' and the non-polar solution 9. ', so that the wettability of the polar liquid 10' on the surface of the pixel wall 7' is better, so that the non-polar solution 9' can be filled in each pixel grid and the hydrophilicity of the pixel wall 7' can be controlled. The non-polar liquid 9' in each pixel is isolated. The materials used in the electrowetting device are generally transparent materials, except that the non-polar solution 9' is mostly colored opaque materials or materials with low light transmittance, where the light transmittance of the material generally depends on the application direction of the electrowetting device. The preparation process for the above-mentioned flexible electrowetting device structure is to coat a hydrophobic insulating layer 6 on the lower support plate 4' with the first electrode 5' by methods such as spin coating, screen printing, slit coating, etc. '. Then a layer of photoresist is coated on the surface of the hydrophobic insulating layer 6' to prepare pixel walls, but because the surface energy of the hydrophobic insulating layer 6' is very low and has a very low contact angle hysteresis, such as Teflon AF1600, the advancing contact angle is 124±2 °, the receding contact angle is 113±2°, so it is difficult to coat a uniform photoresist film on the surface of the hydrophobic insulating layer 6'. The method used by most electrowetting devices at present is to change the hydrophilicity of the surface of the hydrophobic insulating layer 6' by plasma modification to make it easier to coat the photoresist on its surface. After the surface modification, the contact angle hysteresis of the hydrophobic insulating layer 6' increases, the surface adhesion increases, and it is easier for photoresist to form a film on its surface. After the photoresist film formation, curing, photolithography, and development are completed, in order to restore the hydrophobicity of the modified surface of the hydrophobic insulating layer 6', it is necessary to reflow the fresh fluororesin material at the bottom of the hydrophobic insulating layer 6' by heating at a high temperature. to the surface, and reflow the fluororesin material with poor surface hydrophobicity to the bottom, and at the same time restore the flatness of the surface at high temperature to restore the hydrophobicity of the surface of the hydrophobic insulating layer 6'.
可见目前传统的电润湿器件在制备过程中都需要涉及到疏水绝缘层6’表面的改性,进而保证光刻胶更加容易涂覆在疏水层的表面形成均匀薄膜,因此像素墙7’在完成之后需要采用高温回流的方法恢复疏水绝缘层6’表面的疏水性。通过将改性后的薄膜加热到熔点以上,薄膜中低表面能的组分就从主体向表面运动,含有氧原子的组分从表面向主体运动,这就导致新鲜的疏水基团暴露在表面,疏水性恢复。然而高温回流并不能将疏水绝缘层6’的疏水性完全恢复到改性前的特性,会导致滞后角增大。这就导致了器件在打开和关闭的过程中非极性溶液9’的收缩和铺展产生问题。同时高温回流的温度较高,下支撑板4’容易受到高温影响而变形弯曲从而影响柔性电润湿显示器件的弯折性能。高温回流的操作还容易造成像素墙7’结构的变形进而影响器件的光电性能以及稳定性,像素墙7’所覆盖的疏水绝缘层表面和暴露在腔体内的疏水绝缘层6’表面的特性差异,以及像素墙7’显影过程中残留下的杂质都能造成电润湿器件的失效。It can be seen that the current traditional electrowetting devices need to involve the modification of the surface of the hydrophobic insulating layer 6' in the preparation process, so as to ensure that the photoresist is more easily coated on the surface of the hydrophobic layer to form a uniform film, so the pixel wall 7' is After completion, a high temperature reflow method needs to be used to restore the hydrophobicity of the surface of the hydrophobic insulating layer 6'. By heating the modified film above the melting point, components with low surface energy in the film move from the bulk to the surface, and components containing oxygen atoms move from the surface to the bulk, which results in the exposure of fresh hydrophobic groups on the surface , the hydrophobicity is restored. However, high temperature reflow cannot completely restore the hydrophobicity of the hydrophobic insulating layer 6' to the properties before modification, which will lead to an increase in the hysteresis angle. This causes problems with shrinking and spreading of the non-polar solution 9' during device opening and closing. At the same time, the temperature of high-temperature reflow is relatively high, and the lower support plate 4' is easily affected by high temperature and deforms and bends, thereby affecting the bending performance of the flexible electrowetting display device. The operation of high temperature reflow is also likely to cause deformation of the structure of the pixel wall 7', thereby affecting the optoelectronic performance and stability of the device. The surface of the hydrophobic insulating layer covered by the pixel wall 7' is different from the surface of the hydrophobic insulating layer 6' exposed in the cavity. , and impurities remaining in the development process of the pixel wall 7' can cause the failure of the electrowetting device.
另外传统的电润湿器件为了防止器件在弯折过程中层间串流导致的器件短路问题,通常会在上支撑板1’上设置支撑柱结构8’,为保证器件性能,需上下基板精密对位实现封装,受工艺精准性的限制,容易出现支撑柱结构8’与像素墙7’错位的情况,从而影响上下基板的平整度,器件的性能稳定性以及出品率会因此受到影响。In addition, in order to prevent the short circuit of the device caused by the interlayer flow during the bending process of the traditional electrowetting device, a support column structure 8' is usually set on the upper support plate 1'. Due to the limitation of process accuracy, the positioning of the packaging is easily caused by the dislocation of the support column structure 8' and the pixel wall 7', which affects the flatness of the upper and lower substrates, and thus affects the performance stability and yield of the device.
发明内容SUMMARY OF THE INVENTION
本发明旨在至少解决现有技术中存在的技术问题之一。为此,本发明提出一种电润湿显示器件结构及其封装方法,能够规避掉疏水绝缘层材料表面改性及高温回流所带来的缺陷,完全保证疏水绝缘层表面的原始特性不被破坏,以此来提高电润湿光学器件的可靠性。The present invention aims to solve at least one of the technical problems existing in the prior art. Therefore, the present invention proposes an electrowetting display device structure and a packaging method thereof, which can avoid the defects caused by surface modification of the hydrophobic insulating layer material and high temperature reflow, and completely ensure that the original characteristics of the surface of the hydrophobic insulating layer are not damaged. , in order to improve the reliability of electrowetting optics.
本发明所采取的技术方案是:The technical scheme adopted by the present invention is:
本发明的第一方面,提供一种电润湿显示器件结构,包括相对设置的上基板和下基板,所述上基板沿着朝向所述下基板的方向依次包括第一基板、第一电极和导电像素墙,所述导电像素墙围成像素格,所述下基板沿着朝向所述上基板的方向依次包括第二基板、第二电极和疏水绝缘层,所述上基板与所述下基板之间形成调节区,所述调节区内填充有互不相溶的极性液体和非极性液体,所述导电像素墙的端部伸入至所述非极性液体中。In a first aspect of the present invention, an electrowetting display device structure is provided, comprising an upper substrate and a lower substrate disposed opposite to each other, and the upper substrate sequentially includes a first substrate, a first electrode and a lower substrate along a direction toward the lower substrate. A conductive pixel wall, the conductive pixel wall encloses a pixel grid, the lower substrate sequentially includes a second substrate, a second electrode and a hydrophobic insulating layer along the direction toward the upper substrate, the upper substrate and the lower substrate An adjustment area is formed therebetween, the adjustment area is filled with mutually immiscible polar liquid and non-polar liquid, and the end of the conductive pixel wall protrudes into the non-polar liquid.
上述疏水绝缘层可以是单层,例如由具有疏水绝缘性的材料形成;也可以由绝缘层上设置疏水层构成,例如在绝缘层上涂覆疏水性材料。The above-mentioned hydrophobic insulating layer may be a single layer, for example, formed of a material having hydrophobic insulating properties; it may also be constituted by disposing a hydrophobic layer on the insulating layer, for example, coating a hydrophobic material on the insulating layer.
根据本发明的一些实施例的电润湿显示器件结构,所述第一基板和所述第二基板为柔性基板。According to the electrowetting display device structure of some embodiments of the present invention, the first substrate and the second substrate are flexible substrates.
根据本发明的一些实施例的电润湿显示器件结构,所述上基板与所述下基板之间设置有密封胶框。在一些实施例中,密封胶框为柔性密封胶框。According to the electrowetting display device structure of some embodiments of the present invention, a sealant frame is disposed between the upper substrate and the lower substrate. In some embodiments, the sealant frame is a flexible sealant frame.
根据本发明的一些实施例的电润湿显示器件结构,所述密封胶框的材料为压敏胶。According to the electrowetting display device structure of some embodiments of the present invention, the material of the sealant frame is pressure-sensitive adhesive.
根据本发明的一些实施例的电润湿显示器件结构,所述第一电极和所述第二电极连接有电源组件。连接电源组件的方式可以是第一电极和第二电极分别独立地连接不同的电源组件,通过控制连接第一电极的电源组件,来控制第一电极的开关状态,进而控制与第一电极连接的导电像素墙,通过控制连接在第二电极的电源组件,来控制第二电极的开关状态,进而控制疏水绝缘层的润湿性,从而实现像素的开关;也可以是通过在同一电源组件的电路中实现对第一电极和第二电极的分别控制,进而实现对器件的驱动。According to the electrowetting display device structure of some embodiments of the present invention, the first electrode and the second electrode are connected with a power supply component. The way of connecting the power supply components can be that the first electrode and the second electrode are independently connected to different power supply components, and by controlling the power supply components connected to the first electrode, the on-off state of the first electrode is controlled, and then the power supply components connected to the first electrode are controlled. The conductive pixel wall controls the switching state of the second electrode by controlling the power supply component connected to the second electrode, thereby controlling the wettability of the hydrophobic insulating layer, thereby realizing the switching of the pixel; it can also be through the circuit of the same power supply component. The control of the first electrode and the second electrode is realized in the middle, and the driving of the device is further realized.
本发明的第二方面,提供上述的电润湿显示器件结构的封装方法,包括以下步骤:A second aspect of the present invention provides a method for encapsulating the above-mentioned electrowetting display device structure, comprising the following steps:
取上基板,在所述像素格内填充极性液体;Take the upper substrate, and fill the polar liquid in the pixel grid;
在所述极性液体的上方填充非极性液体,所述非极性液体的液面高度高于所述导电像素墙的高度;Filling a non-polar liquid above the polar liquid, the liquid level of the non-polar liquid is higher than the height of the conductive pixel wall;
取下基板,在所述下基板上设置密封胶框,所述密封胶框具有开口,将所述下基板盖在所述上基板的上方;The substrate is removed, and a sealant frame is arranged on the lower substrate, the sealant frame has an opening, and the lower substrate is covered above the upper substrate;
对所述下基板施加压力,使得多余的非极性液体从所述开口处流出;applying pressure to the lower substrate so that excess non-polar liquid flows out of the opening;
密封所述开口。The opening is sealed.
根据本发明的一些实施例的电润湿显示器件结构的封装方法,对所述下基板施加压力的过程包括:先对所述下基板的中心区域施加第一压力,然后对所述下基板的四周区域施加第二压力,所述第一压力大于所述第二压力。According to the encapsulation method of the electrowetting display device structure according to some embodiments of the present invention, the process of applying pressure to the lower substrate includes: first applying a first pressure to a central area of the lower substrate, and then applying a first pressure to a center area of the lower substrate. A second pressure is applied to the surrounding area, and the first pressure is greater than the second pressure.
根据本发明的一些实施例的电润湿显示器件结构的封装方法,在所述极性液体上方填充非极性液体的步骤之前,还包括挥发部分极性液体的步骤。According to some embodiments of the present invention, the encapsulation method of the electrowetting display device structure further includes the step of volatilizing part of the polar liquid before the step of filling the non-polar liquid over the polar liquid.
根据本发明的一些实施例的电润湿显示器件结构的封装方法,挥发部分极性液体的方式为加热、真空蒸发、加入挥发性溶剂挥发中的任一种。According to the encapsulation method of the electrowetting display device structure according to some embodiments of the present invention, the method of volatilizing part of the polar liquid is any one of heating, vacuum evaporation, and adding a volatile solvent to volatilize.
根据本发明的一些实施例的电润湿显示器件结构的封装方法,所述挥发性溶剂包括乙二醇、甲醇中的至少一种。According to the encapsulation method of the electrowetting display device structure according to some embodiments of the present invention, the volatile solvent includes at least one of ethylene glycol and methanol.
本发明实施例的有益效果是:The beneficial effects of the embodiments of the present invention are:
本发明实施例提供了一种电润湿显示器件结构,取消了传统的在疏水绝缘层上构建像素 墙结构的方式,避免了高温回流对基板的影响,疏水绝缘层在成膜固化后不需要再进行表面改性和恢复处理,完全保证疏水绝缘层表面的原始特性不被破坏,保持了疏水绝缘层表面的疏水特性,使疏水绝缘层表面滞后角保持最小,有利于电润湿器件像素打开和关闭过程,提高了电润湿光学器件的可靠性,同时通过导电像素墙和电极进行非极性溶液的分离和收缩,解决像素墙结构构建在疏水绝缘层表面破坏了其原有特性所带来的器件失效风险。并且由于本发明实施例将导电像素墙设置在上基板上,没有破坏疏水绝缘层的表面结构,因而不会因为导电像素墙的显影过程残留杂质在疏水绝缘层的表面,降低了器件的失效风险。此外,本发明实施例的电润湿显示器件结构中导电像素墙与第一电极直接相连,利用第一电极通电,使得导电像素墙能够自由切割非极性液体,导电像素墙同时还起到了支撑柱的作用,代替了传统的电润湿器件中的像素墙和支撑柱结构,避免了传统的电润湿器件需要像素墙与支撑柱结构精准对位以及支撑柱结构与像素墙错位带来的弯折稳定性影响的问题,本发明无需精密对位就可实现贴合封装,可以实现自支撑,提高器件的弯折性能和出品率,在可柔性化方面具有一定优势,另外开启第一电极能够使得非极性液体分离,非极性液体收缩减少了一定的铺展面积,因而下基板的第二电极所需要的的施加电压的阈值会相应减小,一定程度上降低了门槛电压,实现器件的更快速响应。The embodiment of the present invention provides an electrowetting display device structure, which cancels the traditional method of constructing a pixel wall structure on a hydrophobic insulating layer, avoids the influence of high temperature reflow on the substrate, and the hydrophobic insulating layer does not need to be formed and cured after film formation. The surface modification and recovery treatment are then carried out to completely ensure that the original characteristics of the surface of the hydrophobic insulating layer are not destroyed, maintain the hydrophobic characteristics of the surface of the hydrophobic insulating layer, and keep the surface hysteresis angle of the hydrophobic insulating layer to a minimum, which is conducive to the opening of the pixels of the electrowetting device. And the closing process improves the reliability of electrowetting optical devices, and at the same time separates and shrinks the non-polar solution through the conductive pixel walls and electrodes, solving the problem that the pixel wall structure is built on the surface of the hydrophobic insulating layer and destroys its original characteristics. risk of device failure. In addition, since the conductive pixel wall is arranged on the upper substrate in the embodiment of the present invention, the surface structure of the hydrophobic insulating layer is not damaged, so impurities will not remain on the surface of the hydrophobic insulating layer due to the developing process of the conductive pixel wall, which reduces the failure risk of the device. . In addition, in the electrowetting display device structure of the embodiment of the present invention, the conductive pixel wall is directly connected to the first electrode, and the first electrode is energized, so that the conductive pixel wall can freely cut the non-polar liquid, and the conductive pixel wall also acts as a support. The role of the column replaces the pixel wall and support column structure in the traditional electrowetting device, avoiding the traditional electrowetting device that requires the precise alignment of the pixel wall and the support column structure and the dislocation of the support column structure and the pixel wall. For the problem of the influence of bending stability, the present invention can realize the bonding package without precise alignment, can realize self-support, improve the bending performance and yield of the device, and has certain advantages in flexibility, in addition to opening the first electrode The non-polar liquid can be separated, and the non-polar liquid shrinks and reduces a certain spreading area, so the threshold value of the applied voltage required by the second electrode of the lower substrate will be correspondingly reduced, which reduces the threshold voltage to a certain extent, and realizes the device. faster response.
附图说明Description of drawings
图1为传统电润湿器件的结构示意图;1 is a schematic structural diagram of a conventional electrowetting device;
图2为本发明第一实施例的电润湿显示器件结构示意图;FIG. 2 is a schematic structural diagram of the electrowetting display device according to the first embodiment of the present invention;
图3为电润湿显示器件结构中上基板的第一电极打开状态下非极性液体分离示意图;3 is a schematic diagram of separation of non-polar liquids in an electrowetting display device structure when the first electrode of the upper substrate is opened;
图4为电润湿显示器件结构中下基板的第二电极打开状态下非极性液体收缩示意图;4 is a schematic diagram of shrinkage of a non-polar liquid when the second electrode of the lower substrate in the electrowetting display device structure is opened;
图5为电润湿显示器件结构的像素打开过程的示意图;5 is a schematic diagram of a pixel opening process of an electrowetting display device structure;
图6为极性液体和非极性液体的填充示意图;Fig. 6 is the filling schematic diagram of polar liquid and non-polar liquid;
图7为下基板的密封胶框的设置示意图;FIG. 7 is a schematic diagram of the arrangement of the sealant frame of the lower substrate;
图8为上基板和下基板进行封装的示意图。FIG. 8 is a schematic diagram of encapsulation of the upper substrate and the lower substrate.
具体实施方式detailed description
以下将结合实施例对本发明的构思及产生的技术效果进行清楚、完整地描述,以充分地理解本发明的目的、特征和效果。显然,所描述的实施例只是本发明的一部分实施例,而不是全部实施例,基于本发明的实施例,本领域的技术人员在不付出创造性劳动的前提下所获得的其他实施例,均属于本发明保护的范围。The concept of the present invention and the technical effects produced will be clearly and completely described below with reference to the embodiments, so as to fully understand the purpose, characteristics and effects of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, other embodiments obtained by those skilled in the art without creative efforts are all within the scope of The scope of protection of the present invention.
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或 类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。The following describes in detail the embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein the same or similar reference numerals refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary, only used to explain the present invention, and should not be construed as a limitation of the present invention.
在本发明的描述中,需要理解的是,涉及到方位描述,例如上、下、前、后、左、右等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the azimuth description, such as the azimuth or position relationship indicated by up, down, front, rear, left, right, etc., is based on the azimuth or position relationship shown in the drawings, only In order to facilitate the description of the present invention and simplify the description, it is not indicated or implied that the indicated device or element must have a particular orientation, be constructed and operated in a particular orientation, and therefore should not be construed as limiting the present invention.
在本发明的描述中,如果有描述到第一、第二只是用于区分技术特征为目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量或者隐含指明所指示的技术特征的先后关系。In the description of the present invention, if it is described that the first and the second are only for the purpose of distinguishing technical features, it should not be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features or implicitly indicating The order of the indicated technical features.
本发明的描述中,除非另有明确的限定,设置、安装、连接等词语应做广义理解,所属技术领域技术人员可以结合技术方案的具体内容合理确定上述词语在本发明中的具体含义。In the description of the present invention, unless otherwise clearly defined, words such as setting, installation, connection should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above words in the present invention in combination with the specific content of the technical solution.
参照图2,示出了本发明第一实施例的电润湿显示器件结构,包括上基板10和下基板20。上基板10沿着朝向下基板20的方向依次包括第一基板11、第一电极12和导电像素墙13,本实施例中第一基板11为柔性基板,柔性基板可以例举的有PEN(聚苯二甲酸乙二醇酯)或柔性玻璃,第一电极12为ITO电极,导电像素墙13围成像素格,导电像素墙13选用导电光刻胶制成,导电像素墙13作为像素电极与第一电极12直接导通。下基板20沿着朝向上基板10的方向依次包括第二基板21、第二电极22和疏水绝缘层23,本实施例中第二基板21为柔性基板,第二电极22为ITO电极。上基板10和下基板20之间形成调节区,调节区中填充有互不相溶的极性液体30和非极性液体40,导电像素墙13的端部14伸入至非极性液体40中,但未与下基板20的疏水绝缘层23接触,即导电像素墙13与疏水绝缘层23之间存在间距,并且间距小于非极性液体40的平均厚度,导电像素墙13的端部14与疏水绝缘层23之间形成了非极性液体区域41。在通电状态下,导电像素墙13(具有一定的亲水性)因等电势体的特性,使得施加在其下方较薄的非极性液体区域41承受更大的电场强度,导致该非极性液体区域41的非极性液体优先破裂而运动,从而实现显示像素分割的效果参照图3,示出了电润湿显示器件结构中上基板的第一电极打开状态下非极性液体分离示意图,第一电极12打开状态下(即通电时),导电像素墙13下方较薄的非极性液体区域41处的非极性液体破裂而分离,同时导电像素墙13还对器件的上下基板起到支撑作用以避免器件塌陷,并且非极性液体40由于电场实现提前分割,减少了非极性液体40收缩所需的阈值电压,降低了像素开启的门槛电压,从而提高了器件响应速度。参照图4,示出了电润湿显示器件结构中下基板的第二电极打开状态下非极性液体收缩示意图,第二电极22打开状态下(即通电时),第二电 极22被施予一定电压,根据电润湿原理,电压引起表面张力的变化,非极性液体40被推向一遍,从而实现光学开关。Referring to FIG. 2 , the electrowetting display device structure according to the first embodiment of the present invention is shown, including an upper substrate 10 and a lower substrate 20 . The upper substrate 10 sequentially includes a first substrate 11 , a first electrode 12 and a conductive pixel wall 13 along the direction toward the lower substrate 20 . In this embodiment, the first substrate 11 is a flexible substrate, and the flexible substrate can be exemplified by PEN (poly ethylene phthalate) or flexible glass, the first electrode 12 is an ITO electrode, the conductive pixel wall 13 encloses a pixel grid, the conductive pixel wall 13 is made of conductive photoresist, and the conductive pixel wall 13 is used as the pixel electrode and the first pixel. An electrode 12 is directly conductive. The lower substrate 20 sequentially includes a second substrate 21 , a second electrode 22 and a hydrophobic insulating layer 23 along the direction toward the upper substrate 10 . In this embodiment, the second substrate 21 is a flexible substrate, and the second electrode 22 is an ITO electrode. An adjustment area is formed between the upper substrate 10 and the lower substrate 20 , the adjustment area is filled with the polar liquid 30 and the non-polar liquid 40 that are immiscible with each other, and the end 14 of the conductive pixel wall 13 extends into the non-polar liquid 40 , but not in contact with the hydrophobic insulating layer 23 of the lower substrate 20 , that is, there is a distance between the conductive pixel wall 13 and the hydrophobic insulating layer 23 , and the distance is smaller than the average thickness of the non-polar liquid 40 , the end 14 of the conductive pixel wall 13 A non-polar liquid region 41 is formed between the hydrophobic insulating layer 23 . In the energized state, the conductive pixel wall 13 (with a certain degree of hydrophilicity) has the characteristics of the equipotential body, so that the thinner non-polar liquid region 41 under it is subjected to a greater electric field strength, resulting in the non-polarity The non-polar liquid in the liquid region 41 is preferentially broken and moved, so as to achieve the effect of display pixel segmentation. Referring to FIG. 3, a schematic diagram of the separation of the non-polar liquid in the open state of the first electrode of the upper substrate in the electrowetting display device structure is shown, When the first electrode 12 is open (ie, when it is energized), the non-polar liquid at the thin non-polar liquid region 41 under the conductive pixel wall 13 is ruptured and separated, and the conductive pixel wall 13 also acts on the upper and lower substrates of the device. The support function prevents the device from collapsing, and the non-polar liquid 40 is divided in advance due to the electric field, which reduces the threshold voltage required for the non-polar liquid 40 to shrink, and reduces the threshold voltage for pixel turn-on, thereby improving the device response speed. Referring to FIG. 4, there is shown a schematic diagram of the shrinkage of the non-polar liquid in the open state of the second electrode of the lower substrate in the electrowetting display device structure. In the open state of the second electrode 22 (ie, when energized), the second electrode 22 is applied to A certain voltage, according to the principle of electrowetting, the voltage causes the change of the surface tension, and the non-polar liquid 40 is pushed to one pass, thereby realizing the optical switch.
上述电润湿显示结构的驱动方式为:第一电极12与导电像素墙13连接,直接通过第一电极12来影响导电像素墙13的电场情况,参见图5,示出了电润湿显示结构的像素打开过程。当未施加电压情况下,结合图2,第一电极12和第二电极22处于像素关闭状态,非极性液体40处于铺展状态。当施加电压给第一电极12后,第一电极12处于打开状态,结合图3,导电像素墙13表面润湿性改变,导电像素墙13的底端电场变强,极性液体30往导电像素墙13底端的非极性液体区域41处聚集,从而使得非极性液体40破裂。非极性液体40破裂而分离后,给第二电极22施加一定的驱动电压,结合图4,下基板20的疏水绝缘层23润湿性发生改变导致的表面张力改变,使得非极性液体40收缩,从而实现电润湿光学开关。当完成像素的打开过程知乎,撤掉第二电极22的电压,此时疏水绝缘层23的疏水性恢复,非极性液体40重新铺展,像素区域关闭,最后撤掉第一电极12的电压,此时导电像素墙13的润湿性恢复,非极性液体40重新铺展,填满了非极性液体区域41,像素实现关闭。The driving method of the above electrowetting display structure is as follows: the first electrode 12 is connected to the conductive pixel wall 13, and the electric field of the conductive pixel wall 13 is directly affected by the first electrode 12. Referring to FIG. 5, the electrowetting display structure is shown. Pixel turn on process. When no voltage is applied, referring to FIG. 2 , the first electrode 12 and the second electrode 22 are in a pixel-off state, and the non-polar liquid 40 is in a spreading state. When a voltage is applied to the first electrode 12, the first electrode 12 is in an open state. Referring to FIG. 3, the surface wettability of the conductive pixel wall 13 changes, the electric field at the bottom of the conductive pixel wall 13 becomes stronger, and the polar liquid 30 flows toward the conductive pixel. The non-polar liquid region 41 at the bottom end of the wall 13 accumulates, thereby causing the non-polar liquid 40 to rupture. After the non-polar liquid 40 is ruptured and separated, a certain driving voltage is applied to the second electrode 22 . Referring to FIG. 4 , the surface tension of the hydrophobic insulating layer 23 of the lower substrate 20 changes due to the change in wettability, so that the non-polar liquid 40 changes in surface tension. shrink, thereby enabling electrowetting optical switches. When the opening process of the pixel is completed, the voltage of the second electrode 22 is removed, the hydrophobicity of the hydrophobic insulating layer 23 is restored, the non-polar liquid 40 is re-spread, the pixel area is closed, and finally the voltage of the first electrode 12 is removed. , at this time, the wettability of the conductive pixel wall 13 is restored, the non-polar liquid 40 spreads again, fills the non-polar liquid area 41 , and the pixel is turned off.
本发明实施例还提供上述电润湿显示结构的封装方法,包括以下步骤:An embodiment of the present invention also provides a method for encapsulating the above electrowetting display structure, comprising the following steps:
(1)制备上基板10:在第一基板11上制备第一电极12,电极成膜技术在工业生产中广泛应用,在此不做赘述。在第一电极12表面涂覆一层光刻胶材料制备导电像素墙13,涂覆方式包含但不限于狭缝涂布、旋涂、丝网印刷、柔性印刷等方法,经过热固化之后在光刻胶表面覆盖一个掩膜版,通过紫外光进行曝光,最后通过显影得到导电像素墙13,导电像素墙围成像素格。(1) Preparation of the upper substrate 10 : the first electrode 12 is prepared on the first substrate 11 . The electrode film forming technology is widely used in industrial production and will not be repeated here. A layer of photoresist material is coated on the surface of the first electrode 12 to prepare the conductive pixel wall 13, and the coating methods include but are not limited to slit coating, spin coating, screen printing, flexible printing and other methods. The surface of the resist is covered with a mask, exposed by ultraviolet light, and finally obtained by developing a conductive pixel wall 13, and the conductive pixel wall is surrounded by a pixel grid.
将上基板10倒置(具有导电像素墙13的一侧朝上),在导电像素墙13围成的像素格内填充极性液体30,本实施例中极性液体30为极性电解质溶液,填充后的极性液体30的水平高度低于导电像素墙13的高度,以便于后续填充非极性液体40。The upper substrate 10 is turned upside down (the side with the conductive pixel walls 13 is facing upward), and the pixel grids surrounded by the conductive pixel walls 13 are filled with a polar liquid 30. In this embodiment, the polar liquid 30 is a polar electrolyte solution. The horizontal height of the polar liquid 30 is lower than the height of the conductive pixel wall 13 , so as to facilitate the subsequent filling of the non-polar liquid 40 .
(2)参见图6,继续在极性液体30的上方填充非极性液体40,非极性液体40的水平高度要高于导电像素墙13的高度,确保非极性液体40的容量对于电润湿显示结构是足够的。(2) Referring to FIG. 6, continue to fill the non-polar liquid 40 above the polar liquid 30. The level of the non-polar liquid 40 is higher than the height of the conductive pixel wall 13, so as to ensure that the capacity of the non-polar liquid 40 is suitable for the electric It is sufficient to wet the display structure.
(3)制备下基板20:采用现有的手段在第二基板21上制备第二电极22,疏水绝缘层23通过旋涂、浸涂、丝网印刷、柔性印刷等方法将疏水材料溶液涂覆在第二电极22的表面,最后在高温环境下进行固化。(3) Preparation of the lower substrate 20: the second electrode 22 is prepared on the second substrate 21 by using the existing means, and the hydrophobic insulating layer 23 is coated with a solution of a hydrophobic material by spin coating, dip coating, screen printing, flexographic printing, etc. The surface of the second electrode 22 is finally cured in a high temperature environment.
填充非极性液体40后需要将下基板20盖在上基板10上面完成封装过程,封装的过程中需要注意的问题是如何避免残留气泡在电润湿显示结构中。针对此问题本发明实施例提出如下方式:After the non-polar liquid 40 is filled, the lower substrate 20 needs to be covered on the upper substrate 10 to complete the encapsulation process. The problem to be paid attention to during the encapsulation process is how to avoid residual air bubbles in the electrowetting display structure. Aiming at this problem, the embodiment of the present invention proposes the following methods:
参见图7,在下基板20的疏水绝缘层上设置密封胶框50,密封胶框50的材料可采用压敏胶材料,密封胶框50留有至少一个开口51,如图6所示是在4个不同位置留有开口51,目的是在封装过程中可以让多余的非极性液体通过开口51流出;Referring to FIG. 7 , a sealant frame 50 is disposed on the hydrophobic insulating layer of the lower substrate 20 , the material of the sealant frame 50 can be a pressure-sensitive adhesive material, and the sealant frame 50 has at least one opening 51 , as shown in FIG. 6 , at 4 There are openings 51 at different positions, the purpose is to allow excess non-polar liquid to flow out through the openings 51 during the packaging process;
参见图8,然后将下基板20盖在上基板10的上方,将上基板10和下基板20保持水平放置,然后对下基板20施加压力,多余的非极性液体40从密封胶框50的开口处流出,然后用紫外丙烯酸酯等封装胶材料密封开口,最后压合干燥完成整个器件的封装。Referring to FIG. 8 , the lower substrate 20 is then covered on the upper substrate 10 , the upper substrate 10 and the lower substrate 20 are kept horizontal, and then pressure is applied to the lower substrate 20 , and the excess non-polar liquid 40 is removed from the sealant frame 50 . The openings flow out, then seal the openings with encapsulating materials such as UV acrylate, and finally press and dry to complete the encapsulation of the entire device.
在一些实施例中,对下基板20施加压力的过程为:先对下基板20的中心区域施加较大的第一压力61,下基板20由于受力不均匀,中心区域会先接触非极性液体40,然后给下基板20的四周区域施加较小的第二压力62,下基板20形变较小,与非极性液体40的接触面积增大,多余的非极性液体40通过密封胶框50的开口流出。等下基板20完全接触非极性液体40后,用紫外丙烯酸酯等密封开口,最后压合干燥完成整个器件的封装。In some embodiments, the process of applying pressure to the lower substrate 20 is as follows: first, a relatively large first pressure 61 is applied to the central area of the lower substrate 20 . Due to the uneven force on the lower substrate 20 , the central area of the lower substrate 20 will contact the non-polarity first. liquid 40, and then apply a small second pressure 62 to the surrounding area of the lower substrate 20, the lower substrate 20 is less deformed, the contact area with the non-polar liquid 40 increases, and the excess non-polar liquid 40 passes through the sealant frame 50 openings flow out. After the lower substrate 20 is completely in contact with the non-polar liquid 40, the opening is sealed with ultraviolet acrylate or the like, and finally the entire device is packaged by pressing and drying.
在一些实施例中,步骤(1)中通过挥发部分极性液体的方式,使得填充后的极性液体30的水平高度低于导电像素墙13的高度。挥发部分极性液体的方式包含但不限于加热、真空蒸发、加入挥发性溶剂挥发,由于挥发过程是在整个液面上同时进行,所以挥发掉部分极性液体时,整个液面还是水平的。其中加入挥发性溶剂挥发的方式,例如可以通过在极性电解质溶液中添加部分乙二醇或甲醇等挥发性比极性电解质溶液高的有机溶剂,在极性电解质溶液挥发不剧烈的情况下挥发掉有机成分,此种方式可以通过控制加入的挥发性溶剂的含量来精准控制液面下降量,等挥发过程完成后,不会残留有机成分在极性电解质溶液中。In some embodiments, in step (1), the level of the filled polar liquid 30 is made lower than the height of the conductive pixel wall 13 by volatilizing part of the polar liquid. Ways to volatilize part of the polar liquid include but are not limited to heating, vacuum evaporation, and volatilization by adding a volatile solvent. Since the volatilization process is carried out simultaneously on the entire liquid surface, when part of the polar liquid is volatilized, the entire liquid surface is still horizontal. The method of adding a volatile solvent to volatilize, for example, can add some organic solvents such as ethylene glycol or methanol with higher volatility than the polar electrolyte solution to the polar electrolyte solution, and volatilize the polar electrolyte solution without violent volatilization. In this way, the amount of liquid level drop can be precisely controlled by controlling the content of the added volatile solvent. After the volatilization process is completed, no organic components will remain in the polar electrolyte solution.

Claims (10)

  1. 一种电润湿显示器件结构,其特征在于,包括相对设置的上基板和下基板,所述上基板沿着朝向所述下基板的方向依次包括第一基板、第一电极和导电像素墙,所述导电像素墙围成像素格,所述下基板沿着朝向所述上基板的方向依次包括第二基板、第二电极和疏水绝缘层,所述上基板与所述下基板之间形成调节区,所述调节区内填充有互不相溶的极性液体和非极性液体,所述导电像素墙的端部伸入至所述非极性液体中。An electrowetting display device structure is characterized in that it comprises an upper substrate and a lower substrate arranged oppositely, and the upper substrate sequentially includes a first substrate, a first electrode and a conductive pixel wall along a direction toward the lower substrate, The conductive pixel wall forms a pixel grid, the lower substrate sequentially includes a second substrate, a second electrode and a hydrophobic insulating layer along the direction toward the upper substrate, and an adjustment is formed between the upper substrate and the lower substrate The adjustment region is filled with mutually immiscible polar liquid and non-polar liquid, and the end of the conductive pixel wall protrudes into the non-polar liquid.
  2. 根据权利要求1所述的电润湿显示器件结构,其特征在于,所述第一基板和所述第二基板为柔性基板。The electrowetting display device structure according to claim 1, wherein the first substrate and the second substrate are flexible substrates.
  3. 根据权利要求1所述的电润湿显示器件结构,其特征在于,所述上基板与所述下基板之间设置有密封胶框。The electrowetting display device structure according to claim 1, wherein a sealant frame is disposed between the upper substrate and the lower substrate.
  4. 根据权利要求3所述的电润湿显示器件结构,其特征在于,所述密封胶框的材料为压敏胶。The electrowetting display device structure according to claim 3, wherein the material of the sealant frame is pressure-sensitive adhesive.
  5. 根据权利要求1至4任一项所述的电润湿显示器件结构,其特征在于,所述第一电极和所述第二电极连接有电源组件。The electrowetting display device structure according to any one of claims 1 to 4, wherein a power supply component is connected to the first electrode and the second electrode.
  6. 一种权利要求1至5任一项所述的电润湿显示器件结构的封装方法,其特征在于,包括以下步骤:A method for encapsulating an electrowetting display device structure according to any one of claims 1 to 5, characterized in that it comprises the following steps:
    取上基板,在所述像素格内填充极性液体;Take the upper substrate, and fill the polar liquid in the pixel grid;
    在所述极性液体的上方填充非极性液体,所述非极性液体的液面高度高于所述导电像素墙的高度;Filling a non-polar liquid above the polar liquid, the liquid level of the non-polar liquid is higher than the height of the conductive pixel wall;
    取下基板,在所述下基板上设置密封胶框,所述密封胶框具有开口,将所述下基板盖在所述上基板的上方;The substrate is removed, and a sealant frame is arranged on the lower substrate, the sealant frame has an opening, and the lower substrate is covered above the upper substrate;
    对所述下基板施加压力,使得多余的非极性液体从所述开口处流出;applying pressure to the lower substrate so that excess non-polar liquid flows out of the opening;
    密封所述开口。The opening is sealed.
  7. 根据权利要求6所述的电润湿显示器件结构的封装方法,其特征在于,对所述下基板施加压力的过程包括:先对所述下基板的中心区域施加第一压力,然后对所述下基板的四周区域施加第二压力,所述第一压力大于所述第二压力。The method for encapsulating an electrowetting display device structure according to claim 6, wherein the process of applying pressure to the lower substrate comprises: first applying a first pressure to a central area of the lower substrate, and then applying pressure to the lower substrate. A second pressure is applied to the surrounding area of the lower substrate, and the first pressure is greater than the second pressure.
  8. 根据权利要求6所述的电润湿显示器件结构的封装方法,其特征在于,在所述极性液体上方填充非极性液体的步骤之前,还包括挥发部分极性液体的步骤。The method for encapsulating an electrowetting display device structure according to claim 6, wherein before the step of filling the non-polar liquid above the polar liquid, it further comprises the step of volatilizing part of the polar liquid.
  9. 根据权利要求8所述的电润湿显示器件结构的封装方法,其特征在于,挥发部分极性液体的方式为加热、真空蒸发、加入挥发性溶剂挥发中的任一种。The method for encapsulating an electrowetting display device structure according to claim 8, wherein the method of volatilizing part of the polar liquid is any one of heating, vacuum evaporation, and volatilization by adding a volatile solvent.
  10. 根据权利要求9所述的电润湿显示器件结构的封装方法,其特征在于,所述挥发性溶剂包 括乙二醇、甲醇中的至少一种。The method for encapsulating an electrowetting display device structure according to claim 9, wherein the volatile solvent comprises at least one of ethylene glycol and methanol.
PCT/CN2021/096281 2020-08-03 2021-05-27 Electrowetting display device structure and packaging method therefor WO2022028054A1 (en)

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