CN108828849A - The preparation method of flexible liquid crystal lens and its resistance gradual change electrode - Google Patents
The preparation method of flexible liquid crystal lens and its resistance gradual change electrode Download PDFInfo
- Publication number
- CN108828849A CN108828849A CN201810583182.8A CN201810583182A CN108828849A CN 108828849 A CN108828849 A CN 108828849A CN 201810583182 A CN201810583182 A CN 201810583182A CN 108828849 A CN108828849 A CN 108828849A
- Authority
- CN
- China
- Prior art keywords
- electrode
- region
- resistance
- liquid crystal
- gradual change
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000008859 change Effects 0.000 title claims abstract description 179
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 134
- 238000002360 preparation method Methods 0.000 title claims abstract description 48
- 239000004020 conductor Substances 0.000 claims abstract description 100
- 239000000126 substance Substances 0.000 claims abstract description 15
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- 230000006378 damage Effects 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims description 138
- 150000001875 compounds Chemical class 0.000 claims description 14
- 230000005611 electricity Effects 0.000 claims description 12
- 238000005516 engineering process Methods 0.000 claims description 9
- 229920002120 photoresistant polymer Polymers 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 238000005286 illumination Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- 238000005530 etching Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000059 patterning Methods 0.000 claims description 3
- 230000005684 electric field Effects 0.000 abstract description 40
- 238000000034 method Methods 0.000 description 33
- 239000000463 material Substances 0.000 description 16
- -1 for example Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 239000002253 acid Substances 0.000 description 6
- 210000001508 eye Anatomy 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000010148 water-pollination Effects 0.000 description 5
- 230000009471 action Effects 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000001259 photo etching Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 238000001039 wet etching Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 210000005252 bulbus oculi Anatomy 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229960002796 polystyrene sulfonate Drugs 0.000 description 2
- 239000011970 polystyrene sulfonate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005264 High molar mass liquid crystal Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004988 Nematic liquid crystal Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical class C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011173 biocomposite Substances 0.000 description 1
- 210000000746 body region Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003098 cholesteric effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 239000012955 diaryliodonium Substances 0.000 description 1
- 125000005520 diaryliodonium group Chemical group 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 238000010329 laser etching Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical group CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/134309—Electrodes characterised by their geometrical arrangement
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/0101—Head-up displays characterised by optical features
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B30/00—Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images
- G02B30/20—Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images by providing first and second parallax images to an observer's left and right eyes
- G02B30/26—Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images by providing first and second parallax images to an observer's left and right eyes of the autostereoscopic type
- G02B30/27—Optical systems or apparatus for producing three-dimensional [3D] effects, e.g. stereoscopic images by providing first and second parallax images to an observer's left and right eyes of the autostereoscopic type involving lenticular arrays
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133305—Flexible substrates, e.g. plastics, organic film
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/134309—Electrodes characterised by their geometrical arrangement
- G02F1/134318—Electrodes characterised by their geometrical arrangement having a patterned common electrode
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Geometry (AREA)
- Liquid Crystal (AREA)
Abstract
The invention discloses the preparation method of flexible liquid crystal lens and its resistance gradual change electrode, which includes：At least one of first electrode layer and the second electrode lay of the flexible liquid crystal lens are patterned, forms the region that hydrophilic and hydrophobic is different or line width is different, applying conductive material forms resistance gradual change electrode over the region；Or, using optics and chemical means, spatially at least one of the first electrode layer to the flexible liquid crystal lens or the second electrode lay generate gradual change type destruction, cause resistance to generate the difference in spatial distribution, form resistance gradual change electrode.The embodiment of the present invention realizes the independent modulation of the electric field extreme value between flexible liquid crystal lens or the change rate of electric field gradual change, expands the modulation range of flexible liquid crystal lens.
Description
Technical field
The present embodiments relate to technical field of liquid crystal display more particularly to flexible liquid crystal lens and its resistance gradual change electrodes
Preparation method.
Background technique
Currently, in augmented reality, virtual reality and mixed reality field, people are to view with the development that nearly eye is shown
Feel that the requirement of quality is higher and higher, and traditional nearly eye 3D display equipment is eyes formula structure, needs eyes to receive different
Image, since target imaging distance is easy to make one to feel dizzy etc. not equal to screen actual range there are focusing-parallax conflict
It is uncomfortable.
In existing technology, liquid crystal lens array has broad prospects on solving this key request, because with general
Logical microlens array is compared, and liquid crystal lens can freely carry out the switching of 2D/3D by on-load voltage, by partial shape
At 3D picture, the naked eye 3D display of AR is realized.Existing liquid crystal lens array is rigid array, and array does not allow to be bent,
So light by lens enter eyeball this during, need to carry out a large amount of optics amendment on lens, just be able to satisfy
The requirement of display quality in eyeball, but the hardware burden of equipment can be greatly increased in this way, the huge inconvenience of equipment volume, and need
Optics corrected and be designed, whole design difficulty can be improved, and can feel that degree of immersing is not high in the experience of user,
Influence using effect.
Liquid crystal lens are equivalent to the adjustable zoom lens of voltage, and under the action of voltage, liquid crystal can deflect, voltage
Difference, the angle that liquid crystal deflects is also different, causes refractive index of the light after lens different.In stereoscopic display, need
To apply different suitable voltages on liquid crystal lens, so that suitable deflection occurs for liquid crystal, realize that nearly eye is shown.Currently, answering
Used in liquid crystal lens array electrode drive structure there are mainly two types of, one kind be multi-electrode driving structure, another kind be single side electricity
Pole and high impedance layer combine driving structure.
In multi-electrode driving structure, figure dissolves a plurality of electrode on liquid crystal lens electrode, each of them or several
Electrode connects an individual power drives, each liquid crystal lens in this way will be driven by the different power supply of multiple voltages
It is dynamic, the voltage change trend of gradual change is obtained, to carry out gradual change type driving to liquid crystal, obtains the variations in refractive index of gradual change, is formed
Liquid crystal lens array.Driving method very simple from principle, however be unusual very complicated in actual process preparation
, due to a plurality of mutually independent circuit connection of needs to different power supplys, circuit trace becomes sufficiently complex.Liquid crystal is saturating simultaneously
The peripheral driver of mirror also can be further intricate with the increase of liquid crystal lens quantity, it is difficult to realize；In single-side electrode and height
Impedance layer combines driving structure, i.e., does not pattern on liquid crystal lens electrode, or do region on liquid crystal lens array electrode
Change face electrode, and deposition plates one layer of material with high impedance on electrode layer.The function of the high impedance layer is will be originally sharp
The field distribution of benefit becomes flat, and has widened field distribution region while having reduced the extreme value of electric field strength, to be put down
The field distribution of sliding gradual change obtains the variations in refractive index of gradual change to carry out gradual change type driving to liquid crystal, forms liquid crystal lens battle array
Column.Which enormously simplifies preparation process, and drives simple, however the structure is when changing the impedance value of high impedance layer, liquid
The electric field magnitude and electric field change rate of brilliant lens change simultaneously, and the extreme value or electric field that cannot achieve individual modulated electric fields are gradually
The change rate of change limits the modulation range of liquid crystal lens to cannot achieve miscellaneous field distribution curve.
Summary of the invention
The present invention provides the preparation method of flexible liquid crystal lens and its resistance gradual change electrode, to realize the electricity between liquid crystal lens
The independent modulation of field extreme value or the change rate of electric field gradual change, expands the modulation range of liquid crystal lens.
In a first aspect, the embodiment of the invention provides a kind of preparation sides of the resistance gradual change electrode in flexible liquid crystal lens
Method, the preparation method include：
At least one of first electrode layer and the second electrode lay of the flexible liquid crystal lens are patterned, hydrophobe is formed
Property different or different line width region, applying conductive material forms resistance gradual change electrode over the region；Or,
Using optics and chemical means spatially to the first electrode layer or the second electrode lay of the flexible liquid crystal lens
At least one generate gradual change type destroy, cause resistance generate spatial distribution on difference, formed resistance gradual change electrode.
Second aspect, the embodiment of the invention also provides a kind of flexible liquid crystal lens, which is characterized in that including：
First flexible substrate；
Second flexible substrate, the second flexible substrate are above the first flexible substrate and opposite at a predetermined interval
Setting；
First electrode layer, the first electrode layer are formed in the first flexible substrate upper surface；
The second electrode lay, the second electrode lay are formed in the second flexible substrate lower surface；
Wherein, at least one of the first electrode layer and the second electrode lay are resistance gradual change electrode, the electricity
Gradual change electrode is hindered to be made according to the preparation method of above-mentioned flexible liquid crystal lens resistance gradual change electrode；
Liquid crystal layer, the liquid crystal layer are sealed between the first flexible substrate and the second flexible substrate；And
Interval body, the interval body is for keeping between making a reservation between the first flexible substrate and the second flexible substrate
Away from.
The flexible liquid crystal lens of above-mentioned offer and its preparation method of the resistance gradual change electrode flexible liquid crystal lens preparation side
Method includes：At least one of first electrode layer and the second electrode lay of the flexible liquid crystal lens are patterned, hydrophobe is formed
Property different or different line width region, applying conductive material forms resistance gradual change electrode over the region；Or, using optics with
Spatially at least one of the first electrode layer to the flexible liquid crystal lens or the second electrode lay generate gradual change to chemical means
Formula is destroyed, and resistance is caused to generate the difference in spatial distribution, forms resistance gradual change electrode, by adjusting resistance gradual change electrode layer
The distribution of resistance of different zones is expanded with realizing the independent modulation of the electric field extreme value between liquid crystal lens or the change rate of electric field gradual change
The modulation range of big liquid crystal lens.
Detailed description of the invention
Fig. 1 is the preparation method of the resistance gradual change electrode in a kind of flexible liquid crystal lens provided by Embodiment 2 of the present invention
Flow chart；
Fig. 2 is the preparation method of the resistance gradual change electrode in a kind of flexible liquid crystal lens that the embodiment of the present invention three provides
Flow chart；
Fig. 3 is the preparation method of the resistance gradual change electrode in a kind of flexible liquid crystal lens that the embodiment of the present invention four provides
Flow chart；
Fig. 4 is the preparation method of the resistance gradual change electrode in a kind of flexible liquid crystal lens that the embodiment of the present invention five provides
Flow chart；
Fig. 5 is the structural schematic diagram for the flexible liquid crystal lens that the embodiment of the present invention six provides.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples.It is understood that this place is retouched
The specific embodiment stated is used only for explaining the present invention rather than limiting the invention.It also should be noted that in order to just
Only the parts related to the present invention are shown in description, attached drawing rather than entire infrastructure.
Embodiment one
Present embodiments provide a kind of preparation method of the resistance gradual change electrode in flexible liquid crystal lens, the preparation method packet
It includes：At least one of first electrode layer and the second electrode lay of the flexible liquid crystal lens are patterned, forms hydrophilic and hydrophobic not
Same or different line width region, applying conductive material forms resistance gradual change electrode over the region；Or,
Using optics and chemical means spatially to the first electrode layer or the second electrode lay of the flexible liquid crystal lens
At least one generate gradual change type destroy, cause resistance generate spatial distribution on difference, formed resistance gradual change electrode.
Illustratively, the first electrode layer and second electricity are patterned by way of solution state processing procedure or vacuum process
At least one of pole layer forms resistance gradual change electrode, and resistance gradual change electrode, second electrode can be formed in first electrode layer
Forming face electrode on layer, can also in first electrode layer forming face electrode, on the second electrode layer formed resistance gradual change electrode,
Resistance gradual change electrode can also be formed simultaneously in first electrode layer and electrode layer.Wherein, each region of resistance gradual change electrode
Interior resistance is not identical.
Wherein, resistance gradual change electrode is the electrode of patterned multiple conductive region compositions, the resistance of different conductive regions
Difference, main the connecing by the line width of conductive region, the density of conductive material and conductive material of the resistance difference of resistance gradual change electrode
What touching degree determined.At least one on patterned first electrodes layer and the second electrode lay forms resistance gradual change electrode specifically can be with
For：If other conditions are the same, the density for preparing conductive region line width difference or conductive material is different, or conductive
The different conductive region of the exposure level of material.If other conditions are the same, outlet is prepared by different mask plates
The different conductive region of width, the line width of the conductive region is bigger, then the resistance of the corresponding conductive region is smaller；Or at it
In the identical situation of his condition, handled by carrying out different degrees of hydrophilic and hydrophobic to different conductive regions, so that difference is led
The ability that conductive material is adsorbed in electric region is different, prepares the different conductive region of conductive material density, which inhales
The ability of attached conductive material is stronger, then the density of the conductive material of the conductive region is bigger, and corresponding resistance is smaller；Or
In the identical situation of other conditions, by the conductive region with identical line width and same conductive density, using difference
Technology of breaking at physically or chemically quarter, destroy the exposure level of conductive material, form the different conduction region of conductive material contacts degree
Domain, the conductive material of the conductive region is carved, and disconnected degree is smaller, and the exposure level of conductive material is better, the corresponding conduction
The resistance in region is smaller, wherein physics carves disconnected technology can break for laser incising, freeze fracture, knife saw separate etc.；Chemistry carves disconnected skill
Art can be the chemical corrosion methods such as wet etching, light acid etch.
It should be noted that solution state processing procedure described in the embodiment of the present invention, refers to each film prepared in flexible device
The general name of the method for the various solution used when layer, for example, solution state processing procedure may include spin-coating method, knife coating, EFI coating
It is method, slit coating method, strip rubbing method, dipping formula rubbing method, drum-type rubbing method, ink jet printing method, nozzle printing method, convex
Plate print process etc..Specifically, these solution state processing procedures belong to the prior art, and those skilled in the art can have according to the actual situation
Body selects the parameters in preparation process, and the embodiment of the present invention no longer retouches the specific operation process of its every kind method in detail
It states.
At least one in first electrode layer and the second electrode lay of the present embodiment by patterning the flexible liquid crystal lens
Person forms the region that hydrophilic and hydrophobic is different or line width is different, and applying conductive material forms resistance gradual change electrode over the region；
Or, using optics and chemical means, spatially the first electrode layer to the flexible liquid crystal lens or the second electrode lay be at least
One generates gradual change type and destroys, and resistance is caused to generate the difference in spatial distribution, forms resistance gradual change electrode, gradually by the resistance
The preparation method of variable electrode adjusts the size of the resistance of the different zones of resistance gradual change electrode layer and the variation tendency of resistance value,
To realize the independent modulation of the electric field extreme value between liquid crystal lens or the change rate of electric field gradual change, expand the modulation model of liquid crystal lens
It encloses.
Embodiment two
The present embodiment in above-described embodiment preparation method " pattern the flexible liquid crystal lens first electrode layer and
At least one of the second electrode lay forms the region that hydrophilic and hydrophobic is different or line width is different, over the region applying conductive
Material forms resistance gradual change electrode " it is described in detail, Fig. 1 is a kind of flexible liquid crystal lens provided by Embodiment 2 of the present invention
In resistance gradual change electrode preparation method flow chart, as shown in Figure 1, the preparation method can be：
The spaced different area of line width is formed at least one of first flexible substrate and second flexible substrate
Domain, and the hydrophilicity-imparting treatment of same degree is carried out to the region；
The applying conductive material in the region forms the identical conductive region of conductive material density, prepares resistance gradually
Variable electrode.
Wherein, in the present embodiment, covering first is covered at least one of first flexible substrate and second flexible substrate
Film version, the open area of first mask plate are the pattered region on first electrode layer or the second electrode lay, the open region
The line width in domain is not identical, the first flexible substrate and/or second flexible substrate that are placed with the first mask plate is placed on same
The hydrophilicity-imparting treatment of same degree is carried out under environment, thus in first flexible substrate and second flexible substrate upper shape at least one
The different corresponding region of the line width being arranged at interval.Conductive material is dispersed in deionized water or organic solvent, by parent
The region of hydration process is rich in hydrophilic radical, which attracts each other with the hydrophilic radical in conductive material dispersion liquid, from
And conductive material is made to rest on the region.The even spread conductive material on the region Jing Guo hydrophilicity-imparting treatment, due to the area
The hydrophiling degree in domain is identical, so the amount that conductive material is adsorbed is also identical, to be formed, conductive material density is identical to be led
Electric region.Since the line width of conductive region is different, according to R=pL/S it is found that the line width of conductive region is smaller, the resistance in the region
It is bigger, to form resistance gradual change electrode.
Wherein, conductive material can be metal or conducting polymer, they are specifically including but not limited to, golden (Au), silver
(Ag), aluminium (Al), molybdenum (Mo), nickel (Ni), tungsten (W), indium tin oxide (ITO), polythiophene, polyaniline, polyacetylene, polypyrrole,
Polyphenylene ethylene and according to ethene dioxythiophene (PEDOT)/polystyrenesulfonate (PSS) mixture, graphene, carbon nanometer material
Material etc., the form of conductive material can be nano particle, nano wire, nanotube, nanometer blocks etc..
In a preferred embodiment of the present embodiment, by least the one of first flexible substrate and second flexible substrate
Person carries out hexamethyldisilazane (Hexamethyldisilazane, HMDS) and fumigates, and obtains hydrophobic surface, then above it
The first mask plate is covered, is placed in UV ozone or corona treatment instrument and hydrophilicity-imparting treatment is carried out with 55% intensity
5 minutes, then mobile first mask plate, can be obtained the hydrophilic region of image conversion.Even spread is received on the flexible base board
Rice silver wire dispersion liquid, obtains corresponding electrode pattern, to form resistance gradual change electrode.The different exposure regions of first mask plate
The line width in domain is not identical.In the present embodiment, silicic acid anhydride is first carried out on flexible substrates, then obtain hydrophilic area
Domain, its object is to：So that the boundary of conductive region and non-conducting areas is more obvious, in the process for being coated conductive material
In, conductive material all concentrates on hydrophilic region, and non-conducting areas because hydrophobicity without conductive material, to improve
The preparation quality of resistance gradual change electrode.
It should be noted that patterned due to needing to prepare at least one of first flexible substrate and the second substrate
Resistance gradual change electrode, so need at least one mask plate to assist preparing the different conductive region of resistance, the mask plate
Material, the size of mask plate, the aperture position of mask plate, opening area or opening direction may be different, so that in the first flexibility
The region that pattern is different or surface property is different is formed at least one of substrate and second flexible substrate, to prepare resistance
Gradual change electrode.
The embodiment of the present invention at least one of first flexible substrate and second flexible substrate by forming interval setting
The different region of line width, and the hydrophilicity-imparting treatment of same degree is carried out to the region, applying conductive material in the area,
The identical conductive region of conductive material density is formed, resistance gradual change electrode is prepared, passes through the preparation side of the resistance gradual change electrode
Method adjusts the size of the resistance of the different zones of resistance gradual change electrode layer and the variation tendency of resistance value, to realize liquid crystal lens
Between electric field extreme value or electric field gradual change change rate independent modulation, expand the modulation range of liquid crystal lens.
Embodiment three
The present embodiment in above-described embodiment preparation method " pattern the flexible liquid crystal lens first electrode layer and
At least one of the second electrode lay forms the region that hydrophilic and hydrophobic is different or line width is different, over the region applying conductive
Material forms resistance gradual change electrode " another detailed description is carried out, Fig. 2 is a kind of flexible hydraulic that the embodiment of the present invention three provides
The flow chart of the preparation method of resistance gradual change electrode in brilliant lens, as shown in Fig. 2, the preparation method can also be：
The identical region of spaced line width is formed at least one of first flexible substrate and second flexible substrate,
Different degrees of hydrophilicity-imparting treatment is carried out to the region；
The applying conductive material in the region forms the different conductive region of conductive material density, prepares resistance gradual change
Electrode.
In the present embodiment, the second mask plate is covered at least one of first flexible substrate and second flexible substrate,
And the flexible base board is subjected to hydrophilicity-imparting treatment with the first intensity；Third mask plate is covered on the flexible base board later, and will
The flexible base board carries out hydrophilicity-imparting treatment with the second intensity, and so on, multiple and different exposure masks is used on the flexible base board
Version carries out the hydrophilicity-imparting treatment of varying strength respectively, to obtain the region that line width is identical and hydrophilicity is different, wherein first
Intensity is not equal to the second intensity, wherein multiple mask plates such as the first mask plate and the second mask plate are common on the flexible base board
The pattern prepared collectively constitutes pattered region, and the line width of each mask plate is identical.Illustratively, in UV ozone instrument
Processing 10,15,20 obtained the different region of hydrophily with 25 minutes respectively, or in plasma instrument respectively with 35%,
45%, it 55% is handled to obtain the different region of hydrophily with 65% intensity.
The even spread conductive material on the different region of the hydrophily, because hydrophily is different, different zones
The adsorption capacity of hydrophilic radical is different, causes the density of the conductive material in the strong region of hydrophily bigger, resistance is smaller, hydrophilic
The density of the conductive material in the weak region of property is smaller, and resistance is bigger, to form gradual change electrode.
It should be noted that patterned due to needing to prepare at least one of first flexible substrate and the second substrate
Resistance gradual change electrode, so need at least one mask plate to assist out preparing the different conductive region of resistance, the mask plate
Material, the size of mask plate, the aperture position of mask plate, opening area or opening direction may be different, so that in the first flexibility
The region that pattern is different or surface property is different is formed at least one of substrate and second flexible substrate, to prepare resistance
Gradual change electrode.
The embodiment of the present invention at least one of first flexible substrate and second flexible substrate by forming interval setting
The identical region of line width, different degrees of hydrophilicity-imparting treatment is carried out to the region, in the area applying conductive material, formed
The different conductive region of conductive material density prepares resistance gradual change electrode, by the preparation method of the resistance gradual change electrode, adjusts
The size of the resistance of the different zones of resistance gradual change electrode layer and the variation tendency of resistance value, to realize the electric field between liquid crystal lens
The independent modulation of extreme value or the change rate of electric field gradual change, expands the modulation range of liquid crystal lens.
Example IV
The present embodiment is to the preparation method in above-described embodiment " using optics and chemical means spatially to the flexibility
The first electrode layer of liquid crystal lens or at least one generation gradual change type of the second electrode lay destroy, and resistance is caused to generate spatial distribution
On difference, formed resistance gradual change electrode " be described in detail, Fig. 3 be the embodiment of the present invention four provide a kind of flexible hydraulic
The flow chart of the preparation method of resistance gradual change electrode in brilliant lens, as shown in figure 3, the preparation method can be：
The identical region of spaced line width is formed at least one of first flexible substrate and second flexible substrate,
To conductive material is coated in the region, conductive region is formed；
The conductive material of the conductive region break at different degrees of quarter to the conductive region using laser technology
Processing forms resistance gradual change electrode.
In the present embodiment, the 4th mask plate is covered at least one of first flexible substrate and second flexible substrate,
The open area of 4th mask plate is the pattered region on first electrode layer or the second electrode lay, the line of the open area
Width is identical, and the first flexible substrate and/or second flexible substrate that are placed with the 4th mask plate are placed under same environment and carried out
The hydrophilicity-imparting treatment of same degree, to form interval setting first flexible substrate and second flexible substrate are upper at least one
Line width is identical, the identical corresponding region of hydrophilicity.
The conductive material of the conductive region is carried out the disconnected processing of different degrees of laser incising, illustratively, to the first conduction
Region carries out a laser incising and breaks, and carries out laser incising twice to the second conductive region and breaks, is swashed three times to third conductive region
Photoetching is disconnected, and so on.In the present embodiment, the intensity of etching is adjusted to some strength, so that being not enough to once carve disconnected nanometer
Silver wire needs repeatedly can just carve completely disconnected.Because the formed conductive network of conductive material is broken by different degrees of destruction,
Etching number is more, and conductive network is broken off more serious, and the resistance in the region is bigger, to form resistance gradual change electrode.
It should be noted that patterned due to needing to prepare at least one of first flexible substrate and the second substrate
Resistance gradual change electrode, so need at least one mask plate to assist preparing the different conductive region of resistance, the mask plate
Material, the size of mask plate, the aperture position of mask plate, opening area or opening direction may be different, so that in the first flexibility
The region that pattern is different or surface property is different is formed at least one of substrate and second flexible substrate, to prepare resistance
Gradual change electrode.
The embodiment of the present invention at least one of first flexible substrate and second flexible substrate by forming interval setting
The identical region of line width form conductive region to conductive material is coated in the region, to the conductive material of the conductive region into
Row carves disconnected processing, forms resistance gradual change electrode, by the preparation method of the resistance gradual change electrode, adjusts resistance gradual change electrode layer
The size of the resistance of different zones and the variation tendency of resistance value, to realize electric field extreme value between liquid crystal lens or electric field gradual change
The independent modulation of change rate, expands the modulation range of liquid crystal lens.
Embodiment five
The present embodiment in above-described embodiment preparation method " pattern the flexible liquid crystal lens first electrode layer and
At least one of the second electrode lay forms the region that hydrophilic and hydrophobic is different or line width is different, over the region applying conductive
Material forms resistance gradual change electrode " another detailed description is carried out, Fig. 4 is a kind of flexible hydraulic that the embodiment of the present invention five provides
The flow chart of the preparation method of resistance gradual change electrode in brilliant lens, as shown in figure 4, the preparation method can also be：
Conductive material and light-sensitive compound mixing are coated at least one of first flexible substrate and second flexible substrate
Liquid；
Grayscale illumination mask plate is placed above the mixed liquor and is exposed processing, then is placed in setting bad border and is carried out
Heat treatment carries out different degrees of destruction to the contact of the conductive material by way of chemical attack and handles, prepares electricity
Hinder gradual change electrode.
Wherein, which is the cationic light-sensitive compound that heat can activate, including but not limited to Diaryl iodonium
The salt of salt, triarylsulfonium salt and diazonium salt.These light-sensitive compounds are generally soluble in polar solvent and are degraded to acid through light irradiation,
The concentration of acid caused by usually is not enough to destroy metal Nano structure.On the other hand, when there is no light irradiation
When heating, which is degraded to the corrosive substance that can destroy metal Nano structure, thus reduces metal nano knot
The electric conductivity and interconnectivity of structure.
Wherein, grayscale illumination mask plate is the ultraviolet photomask board of grayscale, is also possible to other visible lights or non-visible light
Gray level mask plate, such as：White light, blue light, feux rouges, infrared light etc., in different grayscale, this kind of light penetrates illumination mask plate
Degree it is different.The present embodiment is illustrated by taking the ultraviolet photomask board of grayscale as an example.The ultraviolet photomask board of the grayscale is a kind of tool
There is the mask plate of multiple grayscale, the ability that different greyscale levels blocks ultraviolet light is different, so that ultraviolet light full impregnated is crossed, part is saturating
It crosses or zero penetrates.Set environment, which refers to, carries out equipment so that light-sensitive compound obtains difference to the ambient humidity, light and temperature in environment
The thermal degradation of degree.Light-sensitive compound is influenced by other illumination during heat treatment in order to prevent, preferably in dark
It is carried out in environment, for treatment temperature preferably at 120~150 DEG C, the processing time is preferably 60~90 seconds.
Conductive material and light-sensitive compound mixing are coated at least one of first flexible substrate and second flexible substrate
Liquid, and the ultraviolet photomask board of grayscale is placed above it, first carry out ultraviolet photoetching processing.In the region for being exposed to light irradiation
Light-sensitive compound degradation or self-destruction without influence conductive material structure, under the influence of grayscale ultraviolet photomask board, ultraviolet light
Different in the amount that different zones pass through, the degree that light-sensitive compound is degraded is different.Again being coated with conductive material and photosensitive
The first flexible substrate and/or second flexible substrate of compound are placed in dark environment and are heat-treated, and pass through hot activation
In the remaining light-sensitive compound that the region being previously blanked is not degraded, corrosive thermal degradation substance is generated, effectively
The structure of etching conductive material causes the resistance for covering region to get higher.It is different due under the action of grayscale ultraviolet photomask board
The amount of the remaining light-sensitive compound in region is different, and the amount of the corrosive thermal degradation substance generated after heat treatment is different, and corrosion is led
The degree of electric material structure is also different, to form resistance gradual change electrode layer.On the other hand, do not cover resistance in region not by
It influences, because initial ultraviolet light has destroyed the light-sensitive compound that any heat therein can activate.
It should be noted that patterned due to needing to prepare at least one of first flexible substrate and the second substrate
Resistance gradual change electrode, so need at least one mask plate to assist preparing the different conductive region of resistance, the mask plate
Material, the size of mask plate, the aperture position of mask plate, opening area or opening direction may be different, so that in the first flexibility
The region that pattern is different or surface property is different is formed at least one of substrate and second flexible substrate, to prepare resistance
Gradual change electrode.
The embodiment of the present invention at least one of first flexible substrate and second flexible substrate by coating conductive material
It with light-sensitive compound mixed liquor, first covers the ultraviolet photomask board of grayscale and carries out uv-exposure processing, then be placed in dark bad border
It is heat-treated, forms the different conductive region of the exposure level of conductive material, prepared resistance gradual change electrode, pass through the resistance
The preparation method of gradual change electrode, the variation for adjusting the size and resistance value of the resistance of the different zones of resistance gradual change electrode layer become
Gesture expands the modulation of liquid crystal lens to realize the independent modulation of the electric field extreme value between liquid crystal lens or the change rate of electric field gradual change
Range.
Embodiment six
Fig. 5 is the structural schematic diagram for the flexible liquid crystal lens that the embodiment of the present invention six provides.As shown in Figure 1, liquid crystal lens
Including：First flexible substrate 11；The second flexible substrate being oppositely arranged above first flexible substrate 11 and at a predetermined interval
12；It is formed in the first electrode layer 13 of 11 upper surface of first flexible substrate；It is formed in the second of 12 lower surface of second flexible substrate
Electrode layer 14；Wherein, at least one of first electrode layer 13 and the second electrode lay 14 are patterned resistance gradual change electrode；It is close
The liquid crystal layer 15 being encapsulated between first flexible substrate 11 and the second flexible substrate 11；And for keeping first flexible substrate
The interval body 16 of preset space length between 11 and second flexible substrate 12.
Wherein, the material of first flexible substrate 11 and second flexible substrate 12 can be polyethylene terephthalate
(PET), polyethylene naphthalate (PEN), polyimides, polymethacrylates, polyacrylonitrile, polyether-ether-ketone, polyethers
Sulfone, vinyl alcohol, polycarbonate, acetal resin, polyurethane, polyolefin, polyethylene kind, metal foil, ultra-thin glass, papery lining
Bottom, silk fabrics material or Biocomposite material etc..First flexible substrate, which can be, is close to display panel installation in liquid crystal lens
Flexible base board is also possible to the flexible base board in liquid crystal lens far from display panel；First electrode layer can be face electrode, can also
To be patterned electrode.Second flexible substrate can be the flexible base board for being close to display panel installation in liquid crystal lens, this
Two flexible base boards are also possible to the flexible base board in liquid crystal lens far from display panel；The second electrode lay can be face electrode,
It can be patterned electrode.
It is patterned by way of solution state processing procedure or vacuum process in the first electrode layer and the second electrode lay
At least one forms resistance gradual change electrode, can form resistance gradual change electrode in first electrode layer, be formed on the second electrode lay
Face electrode, can also in first electrode layer forming face electrode, form resistance gradual change electrode on the second electrode layer, can also be
Resistance gradual change electrode is formed simultaneously in first electrode layer and electrode layer.Wherein, the resistance in each region of resistance gradual change electrode
It is not identical.
Wherein, resistance gradual change electrode is the electrode of patterned multiple conductive region compositions, the resistance of different conductive regions
Difference, main the connecing by the line width of conductive region, the density of conductive material and conductive material of the resistance difference of resistance gradual change electrode
What touching degree determined.At least one on patterned first electrodes layer and the second electrode lay forms resistance gradual change electrode specifically can be with
For：If other conditions are the same, the density for preparing conductive region line width difference or conductive material is different, or conductive
The different conductive region of the exposure level of material.If other conditions are the same, outlet is prepared by different mask plates
The different conductive region of width, the line width of the conductive region is bigger, then the resistance of the corresponding conductive region is smaller；Or at it
In the identical situation of his condition, handled by carrying out different degrees of hydrophilic and hydrophobic to different conductive regions, so that difference is led
The ability that conductive material is adsorbed in electric region is different, prepares the different conductive region of conductive material density, which inhales
The ability of attached conductive material is stronger, then the density of the conductive material of the conductive region is bigger, and corresponding resistance is smaller；Or
In the identical situation of other conditions, by the conductive region with identical line width and same conductive density, using difference
Technology of breaking at physically or chemically quarter, destroy the exposure level of conductive material, form the different conduction region of conductive material contacts degree
Domain, the conductive material of the conductive region is carved, and disconnected degree is smaller, and the exposure level of conductive material is better, the corresponding conduction
The resistance in region is smaller, wherein physics carves disconnected technology can break for laser incising, freeze fracture, knife saw separate etc.；Chemistry carves disconnected skill
Art can be the chemical corrosion methods such as wet etching, light acid etch.
As shown in figure 5, in a preferred embodiment of the present invention, first electrode layer 13 is patterned resistance gradual change
Electrode, the second electrode lay 14 are face electrode, wherein interval body is prepared on area electrode or on resistance gradual change electrode.
In another preferred embodiment of the present invention, first electrode layer 13 is face electrode, and the second electrode lay 14 is figure
The resistance gradual change electrode of case, wherein interval body is prepared on area electrode or on resistance gradual change electrode, can also be prepared the
On one flexible base board or second flexible substrate.
In the present embodiment, the resistance of the different zones of resistance gradual change electrode is different, so when the first of liquid crystal lens
Between electrode layer and the second electrode lay apply voltage when, patterned resistance gradual change electrode due to different zones distribution of resistance not
The field distribution of gradual change is generated together, and the liquid crystal molecule in liquid crystal layer is turned to along direction of an electric field to be distributed, and lens effect is showed.Electricity
Field is bigger, and the angle of liquid crystal molecule deflection is bigger, and the polarisation ability of liquid crystal lens is bigger.Under the action of gradual change electric field, it is in
The deflection that liquid crystal molecule in different zones in liquid crystal layer occurs along direction of an electric field is different, not so as to cause refracting light incident rate
Together.By the distribution of resistance mode of each region of adjusting resistance gradual change electrode, change the field distribution situation of different zones, from
And change the deflection angle extreme value and change rate of liquid crystal molecule.Pass through the potential difference of adjusting first electrode layer and the second electrode lay again
And frequency, change electric field strength and refractive index, adjusts the diopter of liquid crystal lens.
Wherein, the pattern of the patterned resistance gradual change electrode can for strip, circle, triangle, quadrangle or
One or more of hexagon.
Liquid crystal lens further include the liquid crystal layer 15 being sealed between first flexible substrate 11 and second flexible substrate 12.Liquid crystal
After layer 15 can be by engaging first flexible substrate 11 and second flexible substrate 12, then liquid crystal is injected into from reserved entrance
It is formed between two flexible base boards.Liquid crystal is nematic liquid crystal, smectic liquid crystal, blue phase liquid crystal, polymer liquid crystal, cholesteric phase
One or more of liquid crystal, photolytic activity reactive liquid crystals.
The interval body 16 can be prepared in first flexible substrate or second flexible substrate, can also be prepared in the first electricity
Pole layer is above or on the second electrode lay, it is preferred that and interval body is prepared on the flexible base board where face electrode or face electrode, when
Interval body is prepared when on the flexible base board where the electrode of face, and flexible base board surface is all in addition to the occupied region of interval body
Region forming face electrode, or complete face electrode is prepared on flexible substrates, and prepares interval body on the electrode of face.Certainly,
It can also prepare on the flexible base board where resistance gradual change electrode or resistance gradual change electrode.Interval body 16 and the first flexible base
It is bonding relationship between plate 11 and second flexible substrate 12, in liquid crystal lens bending process, is limited by the relationship of bonding curved
Song makes the distance between first flexible substrate and second flexible substrate keep identical, avoids stretching caused by because of bending so that two
Distance in flexible base board is different and leads to the collapsing or deformation of internal structure, ensure that internal liquid crystal structure in bending process
In in the normal working environment.
Interval body outstanding can be prepared in first flexible substrate or second flexible substrate, can also be prepared first
On electrode layer or on the second electrode lay.Preferably, interval body preparation is on the flexible base board where face electrode or face electrode.
In first flexible substrate perhaps second flexible substrate or in first electrode layer or second electrode by way of photoetching
Prepare photoresist interval body on layer, interval body with a thickness of 4 microns.In first flexible substrate or second flexible substrate or first
One layer photoresist of spin coating on electrode layer or the second electrode lay, and uv-exposure processing is carried out after placing a mask plate on a photoresist
Afterwards, the graphic structure on mask plate is transferred to first flexible substrate or second flexible substrate or first electrode layer or second electrode
On layer, then there are the first flexible substrate of photoresist or second flexible substrate to develop the spin coating, remaining patterned structures
Photoresist is photoresist interval body.
Interval body can also be polymer wall, which is connected with each other, and polymer wall is the knot of wall connection
Structure, it is internal to form multiple hollow structures, it is internally provided with liquid crystal in hollow, because hollow structure is relatively independent
, the mobilization of liquid crystal in normal work can be reduced, whole imaging effect is enhanced, is in addition connected with each other using wall
Structure, can be to provide more steady corbeling in bending process, to guarantee the stability of inner space.
Polymer wall monomer material be diacrylate diethylene glycol (DEG) ester, diacrylate triethyleneglycol ester, diacrylate tetraethylene glycol ester,
Allyl methacrylate, poly(ethylene glycol) dimethacrylate, poly(ethylene glycol) dimethacrylate, Ethoxylated bisphenol
A diacrylate, Ethoxylated bisphenol A dimethylacrylate, polyurethane diacrylate, methacrylic acid β hydroxyl second
Ester, methyl acrylate, isobornyl methacrylate, isobornyl acrylate, ethyl methacrylate, 2- (2- ethyoxyl second
Oxygroup) ethyl propylene acid esters, acrylic acid -3,5,5- trimethyl one or more of ester.
It should be noted that when the material of liquid crystal layer is nematic crystal, first electrode layer and the second electrode lay and liquid
Both alignment layers are also respectively provided between crystal layer.Adding for both alignment layers is because liquid crystal has to increased knot when being nematic crystal
Structure can make nematic crystal work normally.
It, can be by the way that first flexible substrate and second flexible substrate be connect in a preferred embodiment of the present embodiment
Liquid crystal is injected between two flexible base boards again from reserved entrance after conjunction and forms liquid crystal layer.
In another preferred embodiment of the present embodiment, liquid crystal layer can also be flexible by the way that liquid crystal is coated in first
Sealing is clamped to be formed using another flexible base board after on substrate or second flexible substrate.
Wherein, engagement refers to that first flexible substrate and second flexible substrate make it mutually in succession one by fixed device
It rises, which can be clip, frame glue or other adhesion agents.
It should be noted that patterned due to needing to prepare at least one of first flexible substrate and the second substrate
Resistance gradual change electrode, so need at least one mask plate to assist preparing the different conductive region of resistance, the mask plate
Material, the size of mask plate, the aperture position of mask plate, opening area or opening direction may be different, so that in the first flexibility
The region that pattern is different or surface property is different is formed at least one of substrate and second flexible substrate, to prepare resistance
Gradual change electrode.
It should be noted that traditional liquid crystal lens realize electric field using the structure that face electrode and high impedance layer combine
Distribution, make it possible to using smaller electrical power by the center of field distribution to area of the pattern, and make voltage of electric field song
Line is more smooth.The structure that the face electrode and high impedance layer combine is equivalent to the concatenated structure of multiple same resistances, wherein often
The resistance value of a resistance is identical, the relating to parameters in the resistance value of the equivalent resistance and the material of high impedance layer and preparation process.When
Certain one or more influence factor for changing high impedance layer, can change the resistance value of equivalent resistance corresponding to high impedance layer, thus shadow
Ring the electric field level of liquid crystal lens and the situation of change of field distribution.By taking this influence factor of the thickness of high impedance layer as an example, when
When using traditional scheme by changing electric field extreme value of the thickness of high impedance layer to change liquid crystal lens, due to the electricity of liquid crystal lens
The change rate and electric field level of field gradual change are non-linear variation, and the electric field change of liquid crystal lens also results in electric field gradual change
The change of change rate, therefore cannot achieve the independent modulation of the change rate of electric field extreme value or electric field gradual change.In the embodiment of the present invention
In, the control respectively of the resistance value size and resistance change trend of different zones is realized using resistance gradual change electrode, i.e., not only
Can allow different zones resistance and meanwhile increase or reduce, can also individually adjust the resistance of regional area, formed
Different resistance change trend.By adjusting the size relation of the resistance of the different zones of resistance gradual change resistance, this hair
Bright embodiment realizes the individually electric field extreme value of modulation liquid crystal lens or the change rate of electric field gradual change, or modulates liquid crystal lens simultaneously
The change rate of electric field extreme value and electric field gradual change realizes the field distribution curve of a variety of variations, expands the modulation model of liquid crystal lens
It encloses.
The embodiment of the present invention is by providing a kind of liquid crystal lens, including first flexible substrate；It is flexible positioned at described first
The second flexible substrate being oppositely arranged above substrate and at a predetermined interval；It is formed in the first of the first flexible substrate upper surface
Electrode layer；It is formed in the second electrode lay of the second flexible substrate lower surface；Wherein, the first electrode layer and described second
At least one of electrode layer is patterned resistance gradual change electrode；It is sealed in the first flexible substrate and second flexibility
Liquid crystal layer between substrate；And for keeping preset space length between the first flexible substrate and the second flexible substrate
Interval body, the resistance by the Different electrodes region of liquid crystal lens is different, so that the liquid crystal point in liquid crystal layer in different zones
Because of different electric field actions different degrees of deflection occurs for son；By the size for changing the resistance value on resistance gradual change electrode
The independent modulation of the change rate of electric field extreme value or electric field gradual change is realized in distribution.
On the basis of the above embodiments, resistance gradual change electrode is the electrode of patterned multiple conductive region compositions,
In, the resistance of different conductive regions is different, line width of the difference of the resistance of resistance gradual change electrode by conductive region, conductive material
Density and conductive material exposure level determine.
In a preferred embodiment of the present invention, when the line width of the conductive region, the exposure level of conductive material
When identical, the density of the conductive material in the conductive region is different.
In all identical situation of other conditions, when the density of the conductive material in a region is bigger, the conductive region
Resistance it is smaller；When the density of the conductive material in a region is smaller, the resistance of the conductive region is bigger.Change can be passed through
The hydrophilic and hydrophobic of conductive region enhances the adsorption capacity to conductive material, so that more conductive materials are attracted to conduction region
On domain, to increase the density of conductive material in the region.In a preferred embodiment of the present invention, when the conduction region
When the exposure level of conductive material in domain is identical with density, the line width of the conductive region is different.
In all identical situation of other conditions, when the line width in a region is bigger, the resistance of the conductive region is smaller；
When the line width in a region is smaller, the resistance of the conductive region is bigger.By taking strip conductive region as an example, according to formula R=pL/
S, wherein p is conductive region resistivity, and L is the length of conductive region, and S is the cross-sectional area of conductive region, the cross-sectional area etc.
In the product of length and line width, R is the resistance sizes of conductive region.When the length of strip conductive region is identical, line width is got over
Greatly, the area of conductive region is bigger, and the resistance of conductive region is smaller.
In a preferred embodiment of the present invention, when the line width of the conductive region and the density of conductive material are identical
When, the exposure level of the conductive material in the conductive region is different.
In all identical situation of other conditions, the line width in region and the conduction region that conductive material density is all the same are prepared
Domain, the resistance of each conductive region is all the same at this time.Pass through the conductive network to the conductive material composition in these conductive regions
Different degrees of fracture processing is carried out, destroys the integrality of conductive material, so that conductive network is broken, conductive material is connect
Different degrees of variation occurs for touching degree, to change the resistance of each conductive region, forms resistance gradual change electrode.The breaking part
Reason include but is not limited to laser etching techniques, wet etching technique, light acid etch technology, one kind of surface hydrophobe technology or
It is a variety of.
It should be noted that the pattern of resistance gradual change electrode is not necessarily to be arranged at equal intervals, it can also be according to scheduled
Rule is arranged according to the interval of agreement.
Note that the above is only a better embodiment of the present invention and the applied technical principle.It will be appreciated by those skilled in the art that
The invention is not limited to the specific embodiments described herein, be able to carry out for a person skilled in the art it is various it is apparent variation,
It readjusts and substitutes without departing from protection scope of the present invention.Therefore, although being carried out by above embodiments to the present invention
It is described in further detail, but the present invention is not limited to the above embodiments only, without departing from the inventive concept, also
It may include more other equivalent embodiments, and the scope of the invention is determined by the scope of the appended claims.
Claims (13)
1. a kind of preparation method of the resistance gradual change electrode in flexible liquid crystal lens, which is characterized in that the preparation method includes：
At least one of first electrode layer and the second electrode lay of the flexible liquid crystal lens are patterned, forms hydrophilic and hydrophobic not
Same or different line width region, applying conductive material forms resistance gradual change electrode over the region；Or,
Using optics and chemical means, spatially the first electrode layer to the flexible liquid crystal lens or the second electrode lay be extremely
Few one generates gradual change type and destroys, and resistance is caused to generate the difference in spatial distribution, forms resistance gradual change electrode.
2. preparation method according to claim 1, which is characterized in that the first of the patterning flexible liquid crystal lens
At least one of electrode layer and the second electrode lay form the region that hydrophilic and hydrophobic is different or line width is different, over the region
Applying conductive material forms resistance gradual change electrode, specially：
The spaced different region of line width is formed at least one of first flexible substrate and second flexible substrate, and
The hydrophilicity-imparting treatment of same degree is carried out to the region；
The applying conductive material in the region forms the identical conductive region of conductive material density, prepares resistance gradual change electricity
Pole.
3. preparation method according to claim 1, which is characterized in that the first of the patterning flexible liquid crystal lens
At least one of electrode layer and the second electrode lay form the region that hydrophilic and hydrophobic is different or line width is different, over the region
Applying conductive material forms resistance gradual change electrode, specially：
The identical region of spaced line width is formed at least one of first flexible substrate and second flexible substrate, to institute
It states region and carries out different degrees of hydrophilicity-imparting treatment；
The applying conductive material in the region forms the different conductive region of conductive material density, prepares resistance gradual change electrode.
4. preparation method according to claim 1, which is characterized in that described spatially right using optics and chemical means
The first electrode layer of the flexible liquid crystal lens or at least one generation gradual change type of the second electrode lay destroy, and resistance is caused to generate
Difference in spatial distribution forms resistance gradual change electrode, specially：
The identical region of spaced line width is formed at least one of first flexible substrate and second flexible substrate, to institute
Coating conductive material in region is stated, conductive region is formed；
The disconnected processing of different degrees of quarter is carried out to the conductive region using laser technology to the conductive material of the conductive region,
Form resistance gradual change electrode.
5. preparation method according to claim 1, which is characterized in that described spatially right using optics and chemical means
The first electrode layer of the flexible liquid crystal lens or at least one generation gradual change type of the second electrode lay destroy, and resistance is caused to generate
Difference in spatial distribution forms resistance gradual change electrode, specially：
Conductive material and light-sensitive compound mixed liquor are coated at least one of first flexible substrate and second flexible substrate；
Grayscale illumination mask plate is placed above the mixed liquor and is exposed processing, then is placed in setting bad border and is carried out hot place
Reason carries out different degrees of destruction to the contact of the conductive material by way of chemical attack and handles, prepares resistance gradually
Variable electrode.
6. preparation method according to claim 1-5, which is characterized in that the preparation method further includes：
At least one mask plate is placed at least one of the first flexible substrate and the second flexible substrate.
7. a kind of flexible liquid crystal lens, which is characterized in that including：
First flexible substrate；
Second flexible substrate, the second flexible substrate are located above the first flexible substrate and set relatively at a predetermined interval
It sets；
First electrode layer, the first electrode layer are formed in the first flexible substrate upper surface；
The second electrode lay, the second electrode lay are formed in the second flexible substrate lower surface；
Wherein, at least one of the first electrode layer and the second electrode lay are resistance gradual change electrode, and the resistance is gradually
Variable electrode is made according to the preparation method of flexible liquid crystal lens resistance gradual change electrode as described in any one in claim 1-5；
Liquid crystal layer, the liquid crystal layer are sealed between the first flexible substrate and the second flexible substrate；And
Interval body, the interval body is for keeping preset space length between the first flexible substrate and the second flexible substrate.
8. flexible liquid crystal lens according to claim 7, which is characterized in that the resistance gradual change electrode is patterned more
The electrode of a conductive region composition, wherein the resistance of the different conductive regions is different.
9. flexible liquid crystal lens according to claim 7, which is characterized in that the difference of the resistance of the resistance gradual change electrode
It is determined by the exposure level of the line width of conductive region, the density of conductive material and conductive material.
10. flexible liquid crystal lens according to claim 7, which is characterized in that the electricity of the different conductive region
Resistance is different, including：
When the exposure level of the line width of the conductive region, conductive material is identical, conductive material in the conductive region
Density is different.
11. flexible liquid crystal lens according to claim 7, which is characterized in that the electricity of the different conductive region
Resistance is different, including：
When the exposure level of the conductive material in the conductive region is identical with density, the line width of the conductive region is different.
12. flexible liquid crystal lens according to claim 7, which is characterized in that the electricity of the different conductive region
Resistance is different, including：
When the line width of the conductive region is identical with the density of conductive material, the contact of the conductive material in the conductive region
Degree is different.
13. flexible liquid crystal lens according to claim 7, which is characterized in that the interval body is spin-coated on institute by etching
It states the photoresist on first flexible substrate or second flexible substrate or first electrode layer or the second electrode lay and is formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810583182.8A CN108828849A (en) | 2018-06-05 | 2018-06-05 | The preparation method of flexible liquid crystal lens and its resistance gradual change electrode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810583182.8A CN108828849A (en) | 2018-06-05 | 2018-06-05 | The preparation method of flexible liquid crystal lens and its resistance gradual change electrode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108828849A true CN108828849A (en) | 2018-11-16 |
Family
ID=64144338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810583182.8A Pending CN108828849A (en) | 2018-06-05 | 2018-06-05 | The preparation method of flexible liquid crystal lens and its resistance gradual change electrode |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108828849A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110389452A (en) * | 2018-04-18 | 2019-10-29 | 三菱电机株式会社 | Display device and its manufacturing method |
| CN112684638A (en) * | 2019-10-18 | 2021-04-20 | 北京小米移动软件有限公司 | Display panel and electronic device |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009157145A (en) * | 2007-12-27 | 2009-07-16 | Citizen Electronics Co Ltd | Liquid crystal lens apparatus |
| CN201662671U (en) * | 2010-04-24 | 2010-12-01 | 华映光电股份有限公司 | Liquid crystal lens |
| CN102193202A (en) * | 2010-03-17 | 2011-09-21 | 三星电子株式会社 | Image display device using diffractive lens |
| CN102812393A (en) * | 2009-12-23 | 2012-12-05 | 凌威光电公司 | Image Stabilization And Shifting In A Liquid Crystal Lens |
| CN103616787A (en) * | 2013-12-04 | 2014-03-05 | 中航华东光电有限公司 | Liquid crystal lens and stereo display device with same |
| CN105892178A (en) * | 2016-05-06 | 2016-08-24 | 友达光电股份有限公司 | Liquid crystal lens |
-
2018
- 2018-06-05 CN CN201810583182.8A patent/CN108828849A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009157145A (en) * | 2007-12-27 | 2009-07-16 | Citizen Electronics Co Ltd | Liquid crystal lens apparatus |
| CN102812393A (en) * | 2009-12-23 | 2012-12-05 | 凌威光电公司 | Image Stabilization And Shifting In A Liquid Crystal Lens |
| CN102193202A (en) * | 2010-03-17 | 2011-09-21 | 三星电子株式会社 | Image display device using diffractive lens |
| CN201662671U (en) * | 2010-04-24 | 2010-12-01 | 华映光电股份有限公司 | Liquid crystal lens |
| CN103616787A (en) * | 2013-12-04 | 2014-03-05 | 中航华东光电有限公司 | Liquid crystal lens and stereo display device with same |
| CN105892178A (en) * | 2016-05-06 | 2016-08-24 | 友达光电股份有限公司 | Liquid crystal lens |
Non-Patent Citations (1)
| Title |
|---|
| 吕文明: "梯形凸起电极液晶变焦透镜", 《液晶与显示》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110389452A (en) * | 2018-04-18 | 2019-10-29 | 三菱电机株式会社 | Display device and its manufacturing method |
| CN112684638A (en) * | 2019-10-18 | 2021-04-20 | 北京小米移动软件有限公司 | Display panel and electronic device |
| CN112684638B (en) * | 2019-10-18 | 2022-10-11 | 北京小米移动软件有限公司 | Display panel and electronic device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105425502B (en) | Optical element and the display device using the optical element, electronic equipment, lighting device | |
| US8693086B2 (en) | Appearance-modifying device, method for manufacturing such a device, and appliance covered by such a device | |
| TWI282951B (en) | Liquid crystal display device | |
| TWI431320B (en) | Electrically switchable light modulating cells and methods for manufacturing the same, light modulating devices and methods for manufacturing the same, three-dimensional image display devices, and image display systems | |
| WO2019019618A1 (en) | Array substrate and preparation method therefor, display panel, and display device | |
| KR102062255B1 (en) | Microlens array and method for fabricating thereof | |
| JPH1039799A (en) | Color display device formed by using electric capillary color display sheet | |
| US20110085227A1 (en) | Appearance-modifying device, method for manufacturing such a device, and method for operating such a device | |
| KR20060107873A (en) | Method of forming a pad electrode, method of manufacturing liquid crystal display device using the same, and liquid crystal display device manufactured by the method | |
| CN108828849A (en) | The preparation method of flexible liquid crystal lens and its resistance gradual change electrode | |
| KR20100065615A (en) | Liquid crystal display, panel therefor, and manufacturing method thereof | |
| TWI624695B (en) | Flexible Liquid Crystal Lens Array | |
| WO2022028054A1 (en) | Electrowetting display device structure and packaging method therefor | |
| CN106647065A (en) | Display panel, control method thereof and display device | |
| CN106125291A (en) | A kind of bistable state electric moistening display and preparation method thereof | |
| CN111751911A (en) | Preparation method of zoom liquid microlens array based on patterned hydrophobic layer | |
| CN107942591A (en) | A kind of array base palte and liquid crystal display panel | |
| TWI399568B (en) | An electrical control light valve apparatus having liquid gallium | |
| CN109633890B (en) | Display panel, manufacturing method thereof and display device | |
| US20200075873A1 (en) | Flexible fiber substrate and flexible display device including the same | |
| CN111781775A (en) | Preparation method of liquid crystal micro-lens array based on thickness gradient distribution orientation film | |
| JP2005189444A (en) | Optical element | |
| JP6192926B2 (en) | Alignment film manufacturing method for liquid crystal, liquid crystal element manufacturing method, liquid crystal element | |
| CN115864009A (en) | Super surface unit and reconfigurable electromagnetic super surface | |
| WO2008010444A1 (en) | Display panel and display apparatus using same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181116 |