WO2021196282A1 - 液晶显示面板及其制备方法 - Google Patents

液晶显示面板及其制备方法 Download PDF

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Publication number
WO2021196282A1
WO2021196282A1 PCT/CN2020/084747 CN2020084747W WO2021196282A1 WO 2021196282 A1 WO2021196282 A1 WO 2021196282A1 CN 2020084747 W CN2020084747 W CN 2020084747W WO 2021196282 A1 WO2021196282 A1 WO 2021196282A1
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Prior art keywords
color
sub
substrate
liquid crystal
layer
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PCT/CN2020/084747
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English (en)
French (fr)
Inventor
卢马才
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深圳市华星光电半导体显示技术有限公司
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Priority to US16/764,221 priority Critical patent/US20220107528A1/en
Publication of WO2021196282A1 publication Critical patent/WO2021196282A1/zh

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133516Methods for their manufacture, e.g. printing, electro-deposition or photolithography
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1334Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
    • G02F1/13345Network or three-dimensional gels
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1334Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133512Light shielding layers, e.g. black matrix
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133519Overcoatings
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1341Filling or closing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1343Electrodes
    • G02F1/13439Electrodes characterised by their electrical, optical, physical properties; materials therefor; method of making
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/1368Active matrix addressed cells in which the switching element is a three-electrode device
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2201/00Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
    • G02F2201/50Protective arrangements

Definitions

  • This application relates to the field of display technology, in particular to a liquid crystal display panel and a preparation method thereof.
  • transparent display can be used in goods display cabinets, electronic bulletin boards, head-up displays and other fields, and has received extensive attention.
  • the traditional liquid crystal display panel which is designed with red, green, blue and white pixels to improve its transmittance, but the transmittance is still low (less than 20%); the other is
  • active light-emitting technology such as OLED, which has a high transmittance, but the defects in contrast and brightness greatly limit its application.
  • the liquid crystal material used in it is significantly different from ordinary liquid crystal materials.
  • the polymer network liquid crystal display is a liquid crystal polymer composite material.
  • the polymer In the polymer network liquid crystal, the polymer is distributed in the liquid crystal with a network texture, and the liquid crystal exists in a continuous phase.
  • the transmittance can be controlled by applying an electric field to the PNLC, which is widely used. Used in new displays such as smart windows and other fields.
  • the existing PLNC display there is still a problem of low contrast.
  • the present application provides a liquid crystal display panel and a preparation method thereof.
  • the flexible display panel can effectively improve the dark-state light leakage phenomenon and the problems of low contrast.
  • the present invention provides a liquid crystal display panel, the liquid crystal display panel comprising:
  • a second substrate, the second substrate and the first substrate are arranged in a pair, and a second color resist layer is disposed on the second substrate;
  • the polymer network liquid crystal layer is disposed between the first substrate and the second substrate,
  • the first color resist layer includes a plurality of first sub-color resists
  • the second color resist layer includes a plurality of first sub-color resists in the first color resist layer respectively corresponding in color and position. Set multiple second sub-color resistors.
  • any adjacent two of the plurality of first sub-color resistors have different colors.
  • the first color resist layer is disposed on the side of the first substrate close to the polymer network liquid crystal layer
  • the second color resist layer is disposed on the The side of the second substrate facing away from the polymer network liquid crystal layer.
  • a plurality of first sub-color resistors in the first color-resist layer are arranged at intervals, and a plurality of second sub-color resistors in the second color-resist layer are adjacent to each other. set up.
  • the area of the second sub-color resistor is 5-15% larger than the area of the corresponding first sub-color resistor.
  • the orthographic projection of any one of the plurality of first sub-color resistors on the first substrate is located at the corresponding second sub-color resistor. Inside the orthographic projection area on the first substrate.
  • the plurality of first sub-color resistors include a plurality of first red sub-color resistors, a plurality of first green sub-color resistors, and a plurality of first blue sub-color resistors .
  • the plurality of first sub-color resistors include a plurality of first red sub-color resistors, a plurality of first green sub-color resistors, and a plurality of first blue sub-color resistors. And multiple first white sub-color resistors.
  • the number of the first white sub-color resistors accounts for 25% or 50% of the total number of the first sub-color resistors.
  • the second color resist layer and the protective layer are sequentially stacked and arranged.
  • the protective layer is a transparent organic polymer film or a silicon nitride film.
  • the first substrate is adjacent to the polymer network liquid crystal layer, and a thin film transistor layer, a first color resist layer, a pixel electrode layer, and a first Alignment film.
  • a black matrix layer, a common electrode layer, and a second alignment film are sequentially stacked on the side surface of the second substrate close to the polymer network liquid crystal layer.
  • the present invention also provides a method for manufacturing a liquid crystal display panel, the manufacturing method includes:
  • a first substrate is provided, and a thin film transistor layer, a first color resist layer, a pixel electrode layer, and a first alignment film are sequentially formed on the first substrate, and the first color resist layer includes a plurality of first sub-color resists ;
  • a second substrate is provided, and a second color resist layer and a protective layer are sequentially formed on the first surface of the second substrate.
  • the second color resist layer includes a plurality of first color resist layers.
  • the sub-color resistors respectively correspond to a plurality of second sub-color resistors set;
  • the step of forming the protective layer includes forming a transparent organic polymer film by a coating process, or using chemical vapor deposition A layer of silicon nitride film is formed.
  • a plurality of first sub-color resistors in the first color-resist layer are arranged at intervals, and a plurality of second sub-color resistors in the second color-resist layer are arranged at intervals.
  • the color resistance is arranged adjacently.
  • the orthographic projection of any one of the plurality of first sub-color resistors on the first substrate is located on the corresponding second
  • the sub-color resist is inside the orthographic projection area on the first substrate.
  • the present invention provides a polymer network liquid crystal display panel, by arranging color filters on both the first substrate and the second substrate, two layers of color filters are correspondingly arranged, and the polymer network
  • the color filters of different colors in the adjacent sub-pixels are used to absorb the scattered light of its adjacent pixels to reduce the degree of light leakage in the dark state, for example, when each sub-pixel is in the dark state (scattered state) .
  • the scattered light will be absorbed by the adjacent sub-pixels of the color film of different colors, reducing the scattered light through the front glass substrate, that is, reducing the dark state light leakage, thereby improving the contrast.
  • FIG. 1 is a schematic diagram of a cross-sectional structure of a liquid crystal display panel provided in the prior art of the present invention
  • FIG. 2 is a schematic diagram of a cross-sectional structure of a liquid crystal display panel provided by an embodiment of the present invention
  • 3A-3D are schematic diagrams of the structure flow of a method for manufacturing a liquid crystal display panel provided by an embodiment of the present invention.
  • first and second are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features. Therefore, the features defined with “first” and “second” may explicitly or implicitly include one or more of the features. In the description of the present invention, “plurality” means two or more than two, unless otherwise specifically defined.
  • FIG. 1 provides a cross-sectional film layer of an existing conventional polymer network liquid crystal display panel.
  • the structure diagram specifically, includes:
  • a first substrate 11 on which a thin film transistor layer 111, a color resist layer 112, an insulating layer 113, a pixel electrode layer 114, and a first alignment film 115 are sequentially arranged on the first substrate 11;
  • the second substrate 12 has a black matrix layer 121, a common electrode layer 122, a second alignment film 123, and a spacer layer 124 sequentially arranged on the second substrate 12;
  • the polymer network liquid crystal layer 13 is disposed between the first substrate 11 and the second substrate 12 that have been fabricated.
  • the light when the power is not applied, the light is in a scattered state. Except for the light partially blocked by the black matrix layer, most of the light is emitted, that is, a serious dark state light leakage phenomenon is formed, which leads to a lower Contrast.
  • an embodiment of the present invention provides a display panel. Please refer to FIG. 2 for a cross-sectional structure of the display panel, including:
  • a second substrate 22, the second substrate 22 and the first substrate 21 are arranged in a pair, and a second color resist layer 225 is disposed on the second substrate 22;
  • the polymer network liquid crystal layer 23 is disposed between the first substrate 21 and the second substrate 22,
  • the first color resist layer 212 includes a plurality of first sub-color resists
  • the second color resist layer 225 includes a plurality of first sub-color resists in the first color resist layer in color and position, respectively.
  • a plurality of second sub-color resistors correspondingly set on the above, that is, any one of the first sub-color resistors in the first color-resist layer 212, a second sub-color resistor of the same color is set in the corresponding position.
  • the corresponding position described here refers to any first sub-color resistor and its corresponding second sub-color resistor, and the projections of the two sub-color resistors on the first substrate 21 overlap or partially overlap.
  • the first substrate is an array substrate
  • the second substrate is a color filter substrate
  • the colors of any two adjacent first sub-color resistors in the plurality of first sub-color resistors are different.
  • the light emitted by the backlight passes through the first color-resist layer 212 to form a specific color of light.
  • the dark state the light in the pixel It is scattered at various angles, where the light scattered to the adjacent sub-pixels will be filtered by the adjacent second color resist layer 225 with different colors, thereby reducing the dark state light leakage to a certain extent and improving the contrast.
  • the second color resist layer 225 and the first color resist layer 212 are respectively disposed correspondingly, the second color resist layer 225 has the same sub-color resist arrangement, which will not be repeated here. .
  • the first color resist layer 212 is disposed on the side of the first substrate 21 close to the polymer network liquid crystal layer 23, and the second color resist layer 225 is disposed on the second substrate 22 on the side facing away from the polymer network liquid crystal layer 23, because the second substrate 22 has a certain thickness, the second color resist layer 225 is disposed on the second substrate 22 away from the polymer network liquid crystal layer 23 That is, the second color resist layer 225 is arranged on the outer side of the second substrate 22 along the light emitting direction. In this way, the second color resist layer 225 can be used to filter out larger angles in the dark state. The scattered light also filters out a larger proportion of the scattered light, and further reduces the degree of light leakage in the dark state.
  • a plurality of first sub-color resistors in the first color resist layer are sequentially spaced apart, and a plurality of second sub-color resistors in the second color resist layer are sequentially arranged adjacent to each other.
  • the area of the second sub-color resistor is larger than that of the corresponding first sub-color resistor 5-15%.
  • the orthographic projection of any one of the plurality of first sub-color resistors on the first substrate is located on the second sub-color resistor corresponding to the first sub-color resistor Inside the orthographic projection area on the first substrate.
  • the plurality of first sub-color resistors includes a plurality of first red sub-color resistors, a plurality of first green sub-color resistors, and a plurality of first blue sub-color resistors.
  • the multiple first sub-color resistors include multiple first red sub-color resistors, multiple first green sub-color resistors, multiple first blue sub-color resistors, and multiple first white sub-color resistors.
  • Color resistors wherein the number of the first white sub-color resistors accounts for 25% or 50% of the total number of the first sub-color resistors. For example, in a pixel, it is arranged according to R/G/B/W or R/W/G/W/B/W.
  • a second color resist layer 225 and a protective layer 226 are stacked in sequence, wherein the protective layer 226 is effectively arranged.
  • the protective layer usually can be a transparent organic polymer film or a silicon nitride film.
  • the first substrate 21 is close to the polymer network liquid crystal layer 23, and a thin film transistor layer 211, a first color resist layer 212, an insulating layer 213, a pixel electrode layer 214, and The first alignment film 215,
  • the thin film transistor layer 211 includes a plurality of thin film transistors arranged in an array, usually including an active layer, a gate electrode, a source electrode, a drain electrode, and an interlayer insulating layer, each of the thin film transistors and the upper pixel electrode layer
  • the corresponding pixel electrodes in 214 are electrically connected one by one (not shown in the figure).
  • a black matrix layer 221, a common electrode layer 222, and a second alignment film 223 are sequentially stacked.
  • the black matrix layer 221 includes a plurality of black matrices, which are arranged at corresponding positions of each sub-pixel interval area in the first color resist layer 212,
  • the common electrode layer 222 is usually an indium tin oxide film layer on the entire surface, and cooperates with the pixel electrode layer 214 to form an electric field to drive the deflection of the liquid crystal.
  • the polymer network liquid crystal layer 23 further includes a spacer layer 224.
  • the spacer layer 224 includes a plurality of supporting pillars, and is arranged in a non-pixel area to provide a stable polymer network liquid crystal layer 23. space.
  • another embodiment of the present invention also provides a method for manufacturing the above-mentioned liquid crystal display panel, including:
  • a first substrate 21 is provided, and a thin film transistor layer 211, a first color resist layer 212, an insulating layer 213, a pixel electrode layer 214, and a first alignment film 215 are sequentially formed on the first substrate 21.
  • the first color The resist layer 212 includes a plurality of first sub-color resists, that is, forms a structure as shown in FIG. 3A;
  • a second substrate 22 is provided.
  • a second color resist layer 225 and a protective layer 226 are sequentially formed on the first surface of the second substrate 22.
  • the second color resist layer 225 includes the first color resist layer 212
  • the plurality of first sub-color resistors are respectively corresponding to the plurality of second sub-color resistors, which form a structure as shown in FIG. 3B.
  • the step of forming the protective layer 226 usually includes forming a transparent organic polymer film by a coating process, or forming a silicon nitride film by chemical vapor deposition;
  • a polymer network liquid crystal layer 23 is formed between the first substrate 21 and the second substrate 22. Specifically, the polymer network liquid crystal layer 23 is disposed on the first alignment film 215 and the first alignment film 215 and the second substrate 22. Between two alignment films 223.
  • liquid crystal display panel provided by the embodiment of the present invention may also include any other necessary The specific structure is not limited here.

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Liquid Crystal (AREA)
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Abstract

一种液晶显示面板及其制备方法,液晶显示面板包括第一基板(21),第一基板(21)上配置有第一色阻层(212);与第一基板(21)对组设置的第二基板(22),第二基板(22)上配置有第二色阻层(225);以及聚合物网络液晶层(23)。其中,第一色阻层(212)包括多个第一子色阻,第二色阻层(225)包括与多个第一子色阻分别在颜色与位置上对应设置的多个第二子色阻。

Description

液晶显示面板及其制备方法 技术领域
本申请涉及显示技术领域,具体涉及一种液晶显示面板及其制备方法。
背景技术
随着显示技术的发展,各种新兴技术不断涌现并丰富了各种新的显示应用场景。其中,透明显示可以用于货物展示柜,电子公告牌,抬头显示器等领域,受到了广泛的关注。目前实现透明显示的技术路线主要有两种,一种是传统的液晶显示面板,通过红绿蓝白像素设计,提高其穿透率,但透过率还是较低(小于20%);另一种是利用OLED等主动式发光技术,这种技术穿透率较高,但在对比度,亮度上的缺陷大大限制了其应用。
基于此,聚合物网络液晶显示(polymer network liquid crystal,PNLC)应运而生,其所使用的液晶材料与普通液晶材料有着明显不一样,聚合物网络液晶显示是一种液晶聚合物复合材料。在聚合物网络液晶中,聚合物以网络织构分布在液晶中,而液晶以一种连续相形态存在。当液晶与聚合物折射率不匹配时,会发生强烈的散射呈现不透明态,而两者的折射率匹配时呈现透明态,因此可以通过对PNLC施加电场控制透过率的高低,从而被广泛的应用在智能窗户等领域等新型显示。但,在现有的PLNC显示其中,仍存在对比度不高的问题。
技术问题
本申请提供一种液晶显示面板及其制备方法,该柔性显示面板可有效改善暗态漏光现象以及对比度较低的问题。
技术解决方案
为解决上述问题,第一方面,本发明提供一种液晶显示面板,所述液晶显示面板包括:
第一基板,所述第一基板上配置有第一色阻层;
第二基板,所述第二基板与所述第一基板对组设置,所述第二基板上配置有第二色阻层;以及
聚合物网络液晶层,配置于所述第一基板与所述第二基板之间,
其中,所述第一色阻层包括多个第一子色阻,所述第二色阻层包括与所述第一色阻层中的多个第一子色阻分别在颜色与位置上对应设置的多个第二子色阻。
在本发明实施例提供的一液晶显示面板中,所述多个第一子色阻中任意相邻的两者之间颜色相异。
在本发明实施例提供的一液晶显示面板中,所述第一色阻层配置于所述第一基板靠近所述聚合物网络液晶层的一侧,所述第二色阻层配置于所述第二基板背离所述聚合物网络液晶层的一侧。
在本发明实施例提供的一液晶显示面板中,所述第一色阻层中的多个第一子色阻间隔设置,所述第二色阻层中的多个第二子色阻相邻设置。
在本发明实施例提供的一液晶显示面板中,所述第二子色阻的面积相较对应的所述第一子色阻的面积大5-15%。
在本发明实施例提供的一液晶显示面板中,所述多个第一子色阻之间的任意一者在所述第一基板上的正投影,位于对应的所述第二子色阻在所述第一基板上的正投影区域内部。
在本发明实施例提供的一液晶显示面板中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻以及多个第一蓝色子色阻。
在本发明实施例提供的一液晶显示面板中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻、多个第一蓝色子色阻以及多个第一白色子色阻。
在本发明实施例提供的一液晶显示面板中,所述第一白色子色阻的个数占所述第一子色阻总个数的25%或50%。
在本发明实施例提供的一液晶显示面板中,所述第二基板背离所述聚合物网络液晶层的侧面上,依次层叠配置有所述第二色阻层以及保护层。
在本发明实施例提供的一液晶显示面板中,所述保护层为透明的有机聚合物薄膜或者氮化硅薄膜。
在本发明实施例提供的一液晶显示面板中,所述第一基板靠近所述聚合物网络液晶层的一侧,依次层叠配置有薄膜晶体管层、第一色阻层、像素电极层以及第一配向膜。
在本发明实施例提供的一液晶显示面板中,所述第二基板靠近所述聚合物网络液晶层的侧面上,依次层叠配置有黑色矩阵层、公共电极层以及第二配向膜。
另一方面,本发明还提供了一种液晶显示面板的制备方法,所述制备方法包括:
S01:提供第一基板,在所述第一基板上依次形成薄膜晶体管层、第一色阻层、像素电极层以及第一配向膜,所述第一色阻层包括多个第一子色阻;
S02:提供第二基板,在所述第二基板的第一表面依次形成第二色阻层与保护层,所述第二色阻层包括与所述第一色阻层中的多个第一子色阻分别对应设置的多个第二子色阻;
S03:翻转所述第二基板,在所述第二基板的第二表面依次形成黑色矩阵层、公共电极层、第二配向膜以及间隔层;
S04:将所述第一基板对向所述第二基板的第二表面对组成盒;以及
S05: 在所述第一基板与所述第二基板之间形成聚合物网络液晶层。
在本发明实施例提供的一液晶显示面板的制备方法中中,在所述S02中,形成所述保护层的步骤包括采用涂布工艺形成一层透明的有机聚合物薄膜,或使用化学气相沉积形成一层氮化硅薄膜。
在本发明实施例提供的一液晶显示面板的制备方法中中,所述第一色阻层中的多个第一子色阻间隔设置,所述第二色阻层中的多个第二子色阻相邻设置。
在本发明实施例提供的一液晶显示面板的制备方法中中,所述多个第一子色阻之间的任意一者在所述第一基板上的正投影,位于对应的所述第二子色阻在所述第一基板上的正投影区域内部。
有益效果
相较于现有技术,本发明提供了一种聚合物网络液晶显示面板,通过在第一基板与第二基板上均设置彩色滤光片,两层彩色滤光片对应设置,在聚合物网络液晶处于散射模式时,利用相邻的子像素中不同颜色的彩色滤光片对其相邻像素散射光的吸收效应,降低暗态漏光程度,如,各子像素处于暗态(散射态)时,其散射光将会被相邻不同颜色的彩膜的子像素吸收,减少散射光透过前玻璃基板,即降低暗态漏光,从而提升对比度。
附图说明
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。
图1是本发明现有技术中提供一种液晶显示面板的截面结构示意图;
图2是本发明实施例提供一种液晶显示面板的截面结构示意图;
图3A-3D是本发明实施例提供一种液晶显示面板的制备方法的结构流程示意图。
本发明的实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个所述特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。
聚合物网络液晶显示因其特殊的显示模式,已被广泛的应用于智能窗户等新兴的显示模式中,请参阅图1,提供了一种现有常规的聚合物网络液晶显示面板的截面膜层结构示意图,具体地,包括:
第一基板11,在所述第一基板11上依次配置有薄膜晶体管层111、色阻层112、绝缘层113、像素电极层114以及第一配向膜115;
第二基板12,在所述第二基板12上依次配置有黑色矩阵层121、公共电极层122、第二配向膜123以及间隔层124;
聚合物网络液晶层13,配置于所述制作完成的第一基板11与第二基板12之间。
在该聚合物网络液晶中,未通电时,光线呈现散射状态,除部分被黑色矩阵层遮挡的光线外,大多光线均射出,即形成了较严重的暗态漏光现象,即导致了较低的对比度。
基于此,为了改善这种暗态漏光现象,本发明实施例提供了一种显示面板,该显示面板的截面结构请参阅图2,包括:
第一基板21,所述第一基板21上配置有第一色阻层212;
第二基板22,所述第二基板22与所述第一基板21对组设置,所述第二基板22上配置有第二色阻层225;以及
聚合物网络液晶层23,配置于所述第一基板21与所述第二基板22之间,
其中,所述第一色阻层212包括多个第一子色阻,所述第二色阻层225包括与所述第一色阻层中的多个第一子色阻分别在颜色与位置上对应设置的多个第二子色阻,即第一色阻层212中的任意一个第一子色阻,在对应的位置均设置了一个相同颜色的第二子色阻,需要补充的是,此处描述的对应位置是指任意第一子色阻与其对应的第二子色阻,两者在第一基板21上的投影重合或部分重合。
在一些实施例中,所述第一基板为阵列基板,所述第二基板为彩膜基板。
在一些实施例中,所述多个第一子色阻中任意相邻的两个第一子色阻之间颜色相异。通过这种颜色互异的色阻排布方式,在任意一子像素中,背光发出的光线经过第一色阻层212后形成某一特定颜色的光,在暗态时,该像素内的光线向各个角度散射,其中,散射至相邻子像素的光,会被相邻的颜色相异的第二色阻层225过滤,从而在一定程度上降低了暗态漏光,提升对比度。可以理解的是,因所述第二色阻层225与所述第一色阻层212分别对应设置,故所述第二色阻层225具有相同的子色阻排布,在此不再赘述。
在一些实施例中,所述第一色阻层212配置于所述第一基板21靠近所述聚合物网络液晶层23的一侧,所述第二色阻层225配置于所述第二基板22背离所述聚合物网络液晶层23的一侧,因第二基板22具有一定的厚度,将所述第二色阻层225配置于所述第二基板22背离所述聚合物网络液晶层23的一侧,即将所述第二色阻层225配置于所述第二基板22沿出光方向的外侧,如此一来,即可利用第二色阻层225过滤掉暗态时的更大角度的散射光,便也过滤掉了更大比例的散射光,更进一步降低暗态漏光的程度
在一些实施例中,所述第一色阻层中的多个第一子色阻之间依次间隔设置,所述第二色阻层中的多个第二子色阻之间依次相邻设置,以便获得更大面积的第二子色阻,过滤暗态时更多的散射光,通常情况下,所述第二子色阻的面积相较对应的所述第一子色阻的面积大5-15%。
在一些实施例中,所述多个第一子色阻之间的任意一者在所述第一基板上的正投影,位于与所述第一子色阻对应的所述第二子色阻在所述第一基板上的正投影区域内部。
在一些实施例中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻以及多个第一蓝色子色阻。
在一些实施例中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻、多个第一蓝色子色阻以及多个第一白色子色阻,其中,所述第一白色子色阻的个数占所述第一子色阻总个数的25%或50%。例如在一个像素内,按照R/G/B/W或R/W/G/W/B/W排列。
在一些实施例中,所述第二基板22背离所述聚合物网络液晶层23的侧面上,依次层叠配置有第二色阻层225以及保护层226,其中,所述保护层226的设置有效避免了第二色阻层225发生划伤的问题,所述保护层通常可以为透明的有机聚合物薄膜或者氮化硅薄膜。
在一些实施例中,所述第一基板21靠近所述聚合物网络液晶层23的一侧,依次层叠配置有薄膜晶体管层211、第一色阻层212、绝缘层213、像素电极层214以及第一配向膜215,
其中,所述薄膜晶体管层211包括阵列排布的多个薄膜晶体管,通常包括有源层、栅极、源极、漏极以及层间绝缘层,每一所述的薄膜晶体管与上层像素电极层214中对应的像素电极一一电性连接(图中未示出)。
在一些实施例中,所述第二基板22靠近所述聚合物网络液晶层23的侧面上,依次层叠配置有黑色矩阵层221、公共电极层222以及第二配向膜223,
其中,所述黑色矩阵层221包括多个黑色矩阵,设置于所述第一色阻层212中各个子像素间隔区域的对应位置,
所述公共电极层222通常为整面的氧化铟锡膜层,与所述像素电极层214共同作用形成电场驱动液晶的偏转。
在一些实施例中,所述聚合物网络液晶层23中还包括间隔层224,所述间隔层224包括多个支撑柱,设于非像素区域,为所述聚合物网络液晶层23提供稳定的空间。
请参阅图3A-3D,本发明另一实施例还提供了上述液晶显示面板的制备方法,包括:
S01:提供第一基板21,在所述第一基板21上依次形成薄膜晶体管层211、第一色阻层212、绝缘层213、像素电极层214以及第一配向膜215,所述第一色阻层212包括多个第一子色阻,即形成如图3A所示的结构;
S02:提供第二基板22,在所述第二基板22的第一表面依次形成第二色阻层225与保护层226,所述第二色阻层225包括与所述第一色阻层212中的多个第一子色阻分别对应设置的多个第二子色阻,即形成如图3B所示的结构,
其中,形成所述保护层226的步骤通常包括采用涂布工艺形成一层透明的有机聚合物薄膜,或使用化学气相沉积形成一层氮化硅薄膜;
S03:翻转所述第二基板22,在所述第二基板22的第二表面依次形成黑色矩阵层221、公共电极层222、第二配向膜223以及间隔层224,即形成如图3C所示的结构;
S04:将所述第一基板21对向所述第二基板22的第二表面对组成盒;
S05: 在所述第一基板21与所述第二基板22之间形成聚合物网络液晶层23,具体地,所述聚合物网络液晶层23配置于所述第一配向膜215与所述第二配向膜223之间。
可以理解的是,上述的各个功能层按照本领域常规的工艺分别形成,在此不再赘述。
需要说明的是,上述液晶显示面板实施例中仅描述了上述结构,可以理解的是,除了上述结构之外,本发明实施例提供的液晶显示显示面板中,还可以根据需要包括任何其他的必要结构,具体此处不作限定。
以上对本发明实施例所提供的一种液晶显示面板及其制备方法进行了详细介绍,本文中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有改变之处,综上所述,本说明书内容不应理解为对本发明的限制。

Claims (17)

  1. 一种液晶显示面板,其中,所述液晶显示面板包括:
    第一基板,所述第一基板上配置有第一色阻层;
    第二基板,所述第二基板与所述第一基板对组设置,所述第二基板上配置有第二色阻层;以及
    聚合物网络液晶层,配置于所述第一基板与所述第二基板之间,
    其中,所述第一色阻层包括多个第一子色阻,所述第二色阻层包括与所述第一色阻层中的多个第一子色阻分别在颜色与位置上对应设置的多个第二子色阻。
  2. 如权利要求1所述的液晶显示面板,其中,所述多个第一子色阻中任意相邻的两者之间颜色相异。
  3. 如权利要求1所述的液晶显示面板,其中,所述第一色阻层配置于所述第一基板靠近所述聚合物网络液晶层的一侧,所述第二色阻层配置于所述第二基板背离所述聚合物网络液晶层的一侧。
  4. 如权利要求1所述的液晶显示面板,其中,所述第一色阻层中的多个第一子色阻间隔设置,所述第二色阻层中的多个第二子色阻相邻设置。
  5. 如权利要求4所述的液晶显示面板,其中,所述第二子色阻的面积相较对应的所述第一子色阻的面积大5-15%。
  6. 如权利要求4所述的液晶显示面板,其中,所述多个第一子色阻之间的任意一者在所述第一基板上的正投影,位于对应的所述第二子色阻在所述第一基板上的正投影区域内部。
  7. 如权利要求1所述的液晶显示面板,其中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻以及多个第一蓝色子色阻。
  8. 如权利要求1所述的液晶显示面板,其中,所述多个第一子色阻包括多个第一红色子色阻、多个第一绿色子色阻、多个第一蓝色子色阻以及多个第一白色子色阻。
  9. 如权利要求8所述的液晶显示面板,其中,所述第一白色子色阻的个数占所述第一子色阻总个数的25%或50%。
  10. 如权利要求1所述的液晶显示面板,其中,所述第二基板背离所述聚合物网络液晶层的侧面上,依次层叠配置有所述第二色阻层以及保护层。
  11. 如权利要求10所述的液晶显示面板,其中,所述保护层为透明的有机聚合物薄膜或者氮化硅薄膜。
  12. 如权利要求1所述的液晶显示面板,其中,所述第一基板靠近所述聚合物网络液晶层的一侧,依次层叠配置有薄膜晶体管层、第一色阻层、像素电极层以及第一配向膜。
  13. 如权利要求1所述的液晶显示面板,其中,所述第二基板靠近所述聚合物网络液晶层的侧面上,依次层叠配置有黑色矩阵层、公共电极层以及第二配向膜。
  14. 一种液晶显示面板的制备方法,其中,所述制备方法包括:
    S01:提供第一基板,在所述第一基板上依次形成薄膜晶体管层、第一色阻层、像素电极层以及第一配向膜,所述第一色阻层包括多个第一子色阻;
    S02:提供第二基板,在所述第二基板的第一表面依次形成第二色阻层与保护层,所述第二色阻层包括与所述第一色阻层中的多个第一子色阻分别对应设置的多个第二子色阻;
    S03:翻转所述第二基板,在所述第二基板的第二表面依次形成黑色矩阵层、公共电极层、第二配向膜以及间隔层;
    S04:将所述第一基板对向所述第二基板的第二表面对组成盒;以及
    S05: 在所述第一基板与所述第二基板之间形成聚合物网络液晶层。
  15. 如权利要求14所述的液晶显示面板的制备方法,其中,在所述S02中,形成所述保护层的步骤包括采用涂布工艺形成一层透明的有机聚合物薄膜,或使用化学气相沉积形成一层氮化硅薄膜。
  16. 如权利要求14所述的液晶显示面板的制备方法,其中,所述第一色阻层中的多个第一子色阻间隔设置,所述第二色阻层中的多个第二子色阻相邻设置。
  17. 如权利要求16所述的液晶显示面板的制备方法,其中,所述多个第一子色阻之间的任意一者在所述第一基板上的正投影,位于对应的所述第二子色阻在所述第一基板上的正投影区域内部。
PCT/CN2020/084747 2020-04-02 2020-04-14 液晶显示面板及其制备方法 WO2021196282A1 (zh)

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