WO2021177823A1 - Dispositif électrochimique, système et procédé de récupération et/ou de régénération électrochimique de dioxyde de carbone à partir d'un courant - Google Patents

Dispositif électrochimique, système et procédé de récupération et/ou de régénération électrochimique de dioxyde de carbone à partir d'un courant Download PDF

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Publication number
WO2021177823A1
WO2021177823A1 PCT/NL2021/050143 NL2021050143W WO2021177823A1 WO 2021177823 A1 WO2021177823 A1 WO 2021177823A1 NL 2021050143 W NL2021050143 W NL 2021050143W WO 2021177823 A1 WO2021177823 A1 WO 2021177823A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
compartment
exchange resin
ion exchange
resin bed
Prior art date
Application number
PCT/NL2021/050143
Other languages
English (en)
Inventor
Hubertus Victor Marie Hamelers
Michele Alessandro TEDESCO
Qingdian SHU
Original Assignee
Stichting Wetsus, European Centre Of Excellence For Sustainable Water Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stichting Wetsus, European Centre Of Excellence For Sustainable Water Technology filed Critical Stichting Wetsus, European Centre Of Excellence For Sustainable Water Technology
Publication of WO2021177823A1 publication Critical patent/WO2021177823A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • C02F1/4695—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis electrodeionisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B01D53/965—Regeneration, reactivation or recycling of reactants including an electrochemical process step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/46—Apparatus therefor
    • B01D61/48—Apparatus therefor having one or more compartments filled with ion-exchange material, e.g. electrodeionisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/52—Accessories; Auxiliary operation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/206—Ion exchange resins
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46128—Bipolar electrodes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/46115—Electrolytic cell with membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4618—Supplying or removing reactants or electrolyte
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4619—Supplying gas to the electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • C0 2 for example dissolved C0 2 and/or C0 2 analogues, such as (bi)carbonate ions, more specific sodium bicarbonate (NaHC0 (aq)) and/or sodium carbonate (Na 2 C0 (aq)).
  • Other preferred embodiments comprise potassium bicarbonate (KHC0 (aq)) and/or potassium carbonate (K 2 C0 (aq)).
  • the C0 2 gas-liquid separator further comprises a C0 2 gas release, wherein the C0 2 is recovered from the C0 2 gas-liquid separator as a gas stream with a purity of at least 85%, preferably of at least 90%, and more preferably of at least 95%. Separating the C0 2 gas from the stream provides a C0 2 gas stream at high purity.
  • the gas stream can be collected from the release.
  • the collected gas can be directly and/or indirectly used for (high end) applications such as steel production, plant growth and the like. This renders the electrochemical system according to the invention even more effective.
  • an electrochemical device according to the invention could be provided on site, close to the where the C0 2 is needed.
  • operating such an electrochemical device comprises providing a stream comprising C0 2 or C0 2 analogues and electricity. Therefore, to operate the electrochemical device requires limited operating handlings.
  • the H 2 generated at the cathode can be recirculated and consumed at the anode, thus avoiding the need of external supply of H 2 and further reducing operational costs.
  • a regeneration solution from an ion exchange resin bed can be regenerated by the system according to the invention and used to wash and regenerate the ion exchange resin bed.
  • the ion exchange resin bed comprises an anion exchange resin bed and/or size exclusion ion exchange resin bed.
  • An advantage of a wet regeneration solution is that the solution and resin can contain water and drying with for example chemicals such as sodium sulphate and magnesium sulphate or heat is avoided.
  • the washing solution can be provided to ion exchange resin bed housing 6 via connector 96.
  • Connector 96 is operatively coupled with ion exchange resin bed fluid inlet 52 that is configured for providing a fluid to ion exchange resin bed 50, such as a washing solution and/or solvent comprising C0 2 , such as C0 2 rich solvent and/or C0 2 rich washing solution.
  • Ion exchange resin bed 50 comprising beads 48, is able to adsorb and release C0 2 and/or C0 2 analogues.
  • Ion exchange resin bed 50 can be charged/loaded via ion exchange resin bed gas inlet 58 that is configured for providing a gas comprising C0 2 , such as C0 2 rich gas, to the ion exchange resin bed.
  • System 2 further comprises switching means 60 that are configured for switching between a C0 2 adsorption state and a regeneration state, and sensor 62 that is configured for measuring the C0 2 input and/or H 2 input and/or C0 2 output and/or H 2 output and/or C0 2 purity.
  • sensor 62 is used for the switching between the states with switching means 60.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

L'invention concerne un dispositif électrochimique, un système et un procédé de récupération et/ou de régénération électrochimique de dioxyde de carbone (CO2) à partir d'un courant, tel qu'une solution de régénération provenant d'un lit de résine échangeuse d'ions. Le dispositif électrochimique selon l'invention comprend un boîtier de dispositif électrochimique comportant : un compartiment d'anode, muni d'au moins une entrée de compartiment d'anode qui est configurée pour fournir un liquide et/ou un gaz au compartiment d'anode ; un compartiment de cathode, muni d'au moins une entrée de compartiment de cathode qui est configurée pour fournir un liquide et/ou un gaz au compartiment de cathode, et muni d'au moins une sortie de compartiment de cathode qui est configurée pour retirer un liquide et/ou un gaz du compartiment de cathode ; et un compartiment intermédiaire, prévu entre le compartiment d'anode et le compartiment de cathode, muni d'au moins une entrée de compartiment intermédiaire qui est configurée pour fournir le courant au compartiment intermédiaire, et muni d'au moins une sortie de compartiment intermédiaire ; un ensemble d'électrodes reliant fonctionnellement le compartiment d'anode et le compartiment de cathode, et comprenant au moins une anode et une cathode ; une alimentation électrique, pour fournir de l'électricité à l'ensemble d'électrodes ; et un séparateur gaz-liquide CO2, le séparateur gaz-liquide CO2 étant couplé fonctionnellement à la sortie du compartiment intermédiaire et à l'entrée du compartiment de cathode.
PCT/NL2021/050143 2020-03-04 2021-03-03 Dispositif électrochimique, système et procédé de récupération et/ou de régénération électrochimique de dioxyde de carbone à partir d'un courant WO2021177823A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL2025044A NL2025044B1 (en) 2020-03-04 2020-03-04 Electrochemical device, system and method for electrochemically recovery and/or regeneration of carbon dioxide from a stream
NL2025044 2020-03-04

Publications (1)

Publication Number Publication Date
WO2021177823A1 true WO2021177823A1 (fr) 2021-09-10

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PCT/NL2021/050143 WO2021177823A1 (fr) 2020-03-04 2021-03-03 Dispositif électrochimique, système et procédé de récupération et/ou de régénération électrochimique de dioxyde de carbone à partir d'un courant

Country Status (2)

Country Link
NL (1) NL2025044B1 (fr)
WO (1) WO2021177823A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114515494A (zh) * 2022-01-21 2022-05-20 浙江大学 具有精准离子控制的直接空气捕集二氧化碳节能系统和方法
US11471829B2 (en) * 2019-01-14 2022-10-18 Skyre, Inc. Electrochemical carbon dioxide recovery system
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0699037A (ja) * 1991-02-04 1994-04-12 Mitsubishi Heavy Ind Ltd アルカリ液中の炭酸ガスの回収方法
WO2004011141A1 (fr) 2002-07-26 2004-02-05 Applera Corporation Particule d'echange ionique a exclusion de dimension
US20170072361A1 (en) * 2014-03-07 2017-03-16 Korea Institute Of Energy Research Carbon dioxide collecting apparatus and method using independent power generation means

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0699037A (ja) * 1991-02-04 1994-04-12 Mitsubishi Heavy Ind Ltd アルカリ液中の炭酸ガスの回収方法
WO2004011141A1 (fr) 2002-07-26 2004-02-05 Applera Corporation Particule d'echange ionique a exclusion de dimension
US20170072361A1 (en) * 2014-03-07 2017-03-16 Korea Institute Of Energy Research Carbon dioxide collecting apparatus and method using independent power generation means

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11471829B2 (en) * 2019-01-14 2022-10-18 Skyre, Inc. Electrochemical carbon dioxide recovery system
CN114515494A (zh) * 2022-01-21 2022-05-20 浙江大学 具有精准离子控制的直接空气捕集二氧化碳节能系统和方法
CN114515494B (zh) * 2022-01-21 2022-11-25 浙江大学 具有精准离子控制的直接空气捕集二氧化碳节能系统和方法
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11563229B1 (en) 2022-05-09 2023-01-24 Rahul S Nana Reverse electrodialysis cell with heat pump
US11611099B1 (en) 2022-05-09 2023-03-21 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11699803B1 (en) 2022-05-09 2023-07-11 Rahul S Nana Reverse electrodialysis cell with heat pump
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

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Publication number Publication date
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