WO2021161059A1 - Composition détergente sous forme de pastille effervescente - Google Patents

Composition détergente sous forme de pastille effervescente Download PDF

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Publication number
WO2021161059A1
WO2021161059A1 PCT/IB2020/000153 IB2020000153W WO2021161059A1 WO 2021161059 A1 WO2021161059 A1 WO 2021161059A1 IB 2020000153 W IB2020000153 W IB 2020000153W WO 2021161059 A1 WO2021161059 A1 WO 2021161059A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
mixing
homogenize
tablet
sulfate
Prior art date
Application number
PCT/IB2020/000153
Other languages
English (en)
Inventor
Sergio de Magalhães Neto
Gabriella de Oliveira Santos Ribeiro
Original Assignee
Wash To Go, Unipessoal, Lda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wash To Go, Unipessoal, Lda filed Critical Wash To Go, Unipessoal, Lda
Priority claimed from US16/791,087 external-priority patent/US11248196B2/en
Publication of WO2021161059A1 publication Critical patent/WO2021161059A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines or polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Definitions

  • This disclosure relates generally an effervescent tableted portable detergent comprising of detergent, softener, microbial and enzymatic technology containing active oxygen which make rising of clothing after washing unnecessary.
  • Detergent tablets are known in the art and can provide significant advantages to the consumer compared with conventional powder detergents. However, it is highly desirable to provide an effervescent detergent tablet that is a complete washing solution, portable, and robust formulated with detergent, softener, microbial and enzymatic technology containing active oxygen thereby making the removal of stains easy while not requiring any rinsing. Detergent tablets are usually focused at the home market, designed to be used primarily in washing machines along with many different products. The present invention comprises all the characteristics of a complete washing solution for clothes without the need of a washing machine or rinsing.
  • a detergent tablet that includes a microbial and enzymatic technology that works together to optimize the efficiency of the detergent agents in low water temperatures and short laundry cycles while keeping the garments free of microbes through the use of biguanides.
  • the disclosed embodiment further provides for the release of oxygen through the use of effervescent components which provides for the deep cleaning of stains using the controlled release of effervescence from the tablet
  • the disclosed embodiment may also include antibacterial and antifungal action as well as whitening and softening components.
  • each detergent tablet is used in conjunction with 1500ml of water and the clothing is immersed in the solution for 15 (fifteen) minutes.
  • a detergent tablet comprising, sodium laureth sulfate, citric acid, sodium bicarbonate, fragrance, Stepantex VT 90 (Methyl bis[ethyl (tallowate)] -2- hydroxyethyl ammonium methyl sulfate), polyhexamethylene biguanide, stearic acid, enzyme mix, silicon dioxide, Stearic Acid, Polyethylene glycol 4000, Long Brite (Disodium Distyrylbiphenyl Disulfonate and for the SPORT and ARMY versions Nabion 15 (Carbon- Disilicate co- granulate).
  • the present invention comes in 6 (six) different versions: ORIGINAL (regular formula), BABY (designed for baby clothes), DELICATE (designed for underwear), SPORT (designed for sportswear), ARMY (design for extra cleaning), TENNIS (designed for footwear).
  • ORIGINAL regular formula
  • BABY designed for baby clothes
  • DELICATE designed for underwear
  • SPORT designed for sportswear
  • ARMY design for extra cleaning
  • TENNIS designed for footwear.
  • the main difference of each version is the quantities of each component in the formula.
  • Figure 1 is a flow chart depicting the cleaning process according to an exemplary embodiment.
  • Figure 2 is a flow chart depicting the manufacturing process according to an exemplary embodiment.
  • An exemplary embodiment of the detergent tablet is comprised of (a) an enzymatic cleaning technology, (b) an effervescent cleaning technology, (c) a bleaching and softening technology, and (d) an antimicrobial technology.
  • the specific components of the exemplary embodiment are calcium carbonate, sodium laureth sulfate, citric acid, sodium bicarbonate, fragrance, Stepantex VT 90 (Methyl bis[ethyl (tallowate)] -2- hydroxyethyl ammonium methyl sulfate), polyhexamethylene, biguanide (PHMB), silicon dioxide, enzymes mix, Long Brite (Disodium Distyrylbiphenyl Disulfonate) , Stearic Acid, Polyethylene glycol 4000 and for the SPORT and ARMY versions Nabion 15 (Carbon-Disilicate co- granulate).
  • Polyethylene glycol 4000 is is a polyether compound with many applications, used as an excipient.
  • Sodium laureth sulfate is a tensoactive. It is a powerful surfactant/detergent which allows for the actual cleaning of a garment. It also is an effective degreaser.
  • citric acid and sodium bicarbonate work as a carrier of other active cleaning ingredients.
  • Organic acids and a carbonated base are the necessary components of an effervescent soap formula.
  • Citric acid is provided as the organic acid component and sodium bicarbonate is provided as the carbonated base.
  • the detergent table comes into contact with water, the water breaks the acid molecules thereby creating ions.
  • This ionization process generates carbonic acid (H 2 CO 3 ) which is unstable and disperses very rapidly. The result is the creation of CO 2 bubbles which expel the cleaning particles and dirt from the fabric of the garment that is being washed. This process allows for a washing process without the need to rinse.
  • Fragrance is designed to give washed garments a fresh scent.
  • Stepantex VT 90 is a cationic tensoactive responsible for softening the washed garments .
  • PHMB polyhexamethyiene biguanide
  • Silicon dioxide is an anti-humectant that protects against the detergent tablet absorbing humidity from the air.
  • the enzyme mix is used to optimize the efficiency of the detergent agents. It allows the cleaning process to occur at low temperatures and in a short period of time. When used in detergents, enzymes facilitate the removal of stains.
  • the enzyme mix concentration is less than 1% of the total volume and, as bio catalyzers, they are not consumed during the washing process.
  • Long brite (disodium distyrylbiphenyl disulfonate) is an optical bleaching agent that neutralizes yellow satins and intensifies color brightness in garments.
  • Stearic acid is a lubricant designed to reduce waste in the manufacturing process which assists in ensuring that the detergent tablets do not adhere to a compression machine used in the manufacturing process.
  • Nabion 15 is a Carbon-Disilicate co- granulate, dispersing and anti-redepositing agent in cleanser and bleach formulations. Nabion 15 is a composite of sodium carbonate and amorphous alkali metal silicate.
  • FIG. 1 a flow chart depicting the cleaning process according to an exemplary embodiment is shown. As shown in Figure 1, the washing process begins in step 101 with the insertion of a detergent tablet into 1500 ml of water.
  • step 103 an ionization process begins in step 103 in which broken CO 2 particles release ions into the water.
  • step 104 creates an effervescent effect as a result of the creation of carbonic acid (H 2 CO 3 ).
  • FIG. 2 a flow chart depicting the manufacturing process according to an exemplary embodiment is shown.
  • the manufacturing process begins in step 201 with sifting a mix of silicon dioxide, polyhexamethylene biguanide, Stepantex VT 90 (Methyl bis[ethyl (tallowate)] -2- hydroxyethyl ammonium methyl sulfate) and fragrance through a 1mm sieve.
  • Stepantex VT 90 Method for sifting a mix of silicon dioxide, polyhexamethylene biguanide, Stepantex VT 90 (Methyl bis[ethyl (tallowate)] -2- hydroxyethyl ammonium methyl sulfate) and fragrance through a 1mm sieve.
  • step 203 we mix their combination in step 203.
  • step 203 the Enzyme mix is added and mixed again in step 204
  • step 204 we sift the Long brite (disodium distyrylbiphenyl disulfonate), the Sodium laureth sulfate and the Nabion 15 (Carbon-Disilicate co- granulate), if applicable, through a 1mm sieve and mix the combination again in step 205.
  • step 206 Once mixed we sieve the Stearic Acid and the Polyethylene glycol 4000 through a lmm sieve and add it to the combination and start compression in step 206
  • step 207 and the resulting combination is compressed into a tablet form.
  • each of the mixture steps are mixed for a period of at least ten minutes.
  • Table 1 depicts the components of the ORIGINAL formula.
  • Table 2 depicts the components of the BABY formula.
  • Table 3 depicts the components of the DELICATE formula.
  • Table 4 depicts the components of the ARMY formula.
  • Table 5 depicts the components of the SPORT formula.
  • Table 6 depicts the components of the TENNIS formula.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Une pastille de détergent effervescente comprenant du laureth sulfate de sodium, de l'acide citrique, du bicarbonate de soude, un parfum, du Stepantex VT-90 (sulfate de méthyl bis [éthyl(tallowate)]-2-hydroxyéthyl ammonium et de méthyle), du polyhexaméthylène biguanide (PHMB), du dioxyde de silicium, un mélange d'enzymes, du Long Brite (disodium-distyrylbiphényl-disulfonate), de l'acide stéarique, du Nation 15 (co-granulat de disilicate-carbone) et du polyéthylène glycol 4000.
PCT/IB2020/000153 2020-02-14 2020-02-14 Composition détergente sous forme de pastille effervescente WO2021161059A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/791,087 2020-02-14
US16/791,087 US11248196B2 (en) 2017-06-15 2020-02-14 Detergent composition in effervescent tablet form

Publications (1)

Publication Number Publication Date
WO2021161059A1 true WO2021161059A1 (fr) 2021-08-19

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PCT/IB2020/000153 WO2021161059A1 (fr) 2020-02-14 2020-02-14 Composition détergente sous forme de pastille effervescente

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1232241B1 (fr) * 1999-11-26 2004-04-21 Unilever N.V. Compositions detergentes
CN101914415A (zh) * 2010-08-27 2010-12-15 郭俊华 一种泡腾洗涤剂及其制备方法
US20180362901A1 (en) * 2017-06-15 2018-12-20 WASH TO GO, Unipessoal Lda. Detergent composition in effervescent tablet form

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1232241B1 (fr) * 1999-11-26 2004-04-21 Unilever N.V. Compositions detergentes
CN101914415A (zh) * 2010-08-27 2010-12-15 郭俊华 一种泡腾洗涤剂及其制备方法
US20180362901A1 (en) * 2017-06-15 2018-12-20 WASH TO GO, Unipessoal Lda. Detergent composition in effervescent tablet form

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