WO2021115470A1 - Light-emitting diode - Google Patents

Light-emitting diode Download PDF

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Publication number
WO2021115470A1
WO2021115470A1 PCT/CN2020/136033 CN2020136033W WO2021115470A1 WO 2021115470 A1 WO2021115470 A1 WO 2021115470A1 CN 2020136033 W CN2020136033 W CN 2020136033W WO 2021115470 A1 WO2021115470 A1 WO 2021115470A1
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WO
WIPO (PCT)
Prior art keywords
light
semiconductor layer
emitting diode
light emitting
electrode
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PCT/CN2020/136033
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French (fr)
Chinese (zh)
Inventor
闫春辉
蒋振宇
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深圳第三代半导体研究院
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Publication of WO2021115470A1 publication Critical patent/WO2021115470A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/26Materials of the light emitting region
    • H01L33/30Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table
    • H01L33/32Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table containing nitrogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
    • H01L33/387Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape with a plurality of electrode regions in direct contact with the semiconductor body and being electrically interconnected by another electrode layer

Definitions

  • This application relates to the field of semiconductors, especially a light-emitting diode.
  • Light-emitting diodes are solid-state components that convert electrical energy into light. Light-emitting diodes have the advantages of small size, high efficiency, and long life, and are widely used in traffic indications, outdoor full-color displays and other fields. In particular, the use of high-power light-emitting diodes can realize semiconductor solid-state lighting, which has caused a revolution in the history of human lighting, and has gradually become a research hotspot in the current electronics field.
  • the current of the light-emitting diode is generally injected into the active light-emitting layer by a lateral diffusion method, and this lateral diffusion method has a natural non-uniform current distribution characteristic, resulting in excessive current density in a local area. Excessive current density in a local area can easily cause two problems:
  • the present application provides a light emitting diode that can improve the uniformity of current distribution, so that the light emitting diode can withstand a higher working current, thereby improving the lumen efficiency and lumen density of the light emitting diode, and reducing the lumen cost.
  • the present application provides a light-emitting diode, including: a substrate; a light-emitting epitaxial layer, including a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer that are sequentially stacked on the substrate; A second electrode, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first The electrode is a surface electrode, and the projections of multiple second electrodes on the substrate fall within the projections of the first electrodes on the substrate and are spaced apart from each other. The shortest distance between two adjacent second electrodes is not greater than the lateral threshold.
  • the horizontal critical electrode spacing refers to the shortest when the dynamic slope of the change curve of the working voltage of the light-emitting diode with the average current density in a certain working current section where the average current density is greater than 1A/mm 2 is not greater than 0.18 ⁇ mm 2
  • the maximum allowable value of the sum of the separation distance, the light-emitting diode works in the operating current section
  • the first semiconductor layer and the second semiconductor layer are made of materials based on the three-nitride system; the materials based on the three-nitride system include GaN , At least one of Alx 1 Gay 1 N, InGaN, Alx 2 Iny 2 Gaz 2 N.
  • the present application provides a light-emitting diode, including: a substrate; a light-emitting epitaxial layer, including a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer stacked on the substrate in sequence; a first electrode and A plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer;
  • One electrode is a surface electrode, the projections of the multiple second electrodes on the substrate fall inside the projections of the first electrode on the substrate and are arranged at intervals.
  • Any light-emitting point in at least part of the light-emitting area of the light-emitting epitaxial layer is on the substrate.
  • the sum of the shortest distance between the projection on the bottom and the projection of the two adjacent second electrodes on the substrate is not greater than the lateral critical electrode spacing.
  • the lateral critical electrode spacing refers to ensuring that the operating voltage of the light-emitting diode changes with the average current density
  • the dynamic slope of the curve in a certain working current section with an average current density greater than 1A/mm 2 is not greater than 0.18 ⁇ mm 2 the maximum allowable value of the sum of the shortest separation distances, the light emitting diode works in the working current section, and the first Both the semiconductor layer and the second semiconductor layer are made of materials based on the Group III nitride system.
  • the present application provides a light emitting diode, including: a substrate; a light emitting epitaxial layer, including a first semiconductor layer, an active light emitting layer, and a second semiconductor layer stacked on the substrate in sequence; a first electrode and A plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer;
  • One electrode is a surface electrode, the projections of multiple second electrodes on the substrate fall inside the projections of the first electrodes on the substrate and are spaced apart from each other, and the shortest distance between two adjacent second electrodes is not greater than the lateral Critical electrode spacing, horizontal critical electrode spacing means to ensure that the dynamic slope of the light-emitting diode operating voltage with the average current density in a certain operating current section where the average current density is greater than 1A/mm 2 is
  • the beneficial effect of the present application is: different from the state of the art, the present application sets a lateral critical electrode spacing based on the slope of the change of the working voltage with the average current density, and sets any light-emitting point in at least a part of the light-emitting area of the light-emitting epitaxial layer
  • the sum of the shortest distance between the projection on the substrate and the projection of the two adjacent second electrodes on the substrate is not greater than the lateral critical electrode spacing, which effectively improves the uniformity of current distribution so that the light-emitting diode can withstand higher
  • the working current can improve the lumen efficiency and lumen density of the light-emitting diode.
  • the life and reliability of the light-emitting diode are high, and no complicated package design is required for heat dissipation, which reduces the lumen cost of the light-emitting diode.
  • Fig. 1 is a top view of a light emitting diode according to a first embodiment of the present application
  • Fig. 2 is a schematic partial cross-sectional view taken along the A1-A1 direction of Fig. 1;
  • FIG. 3 is a schematic diagram showing the variation of the operating voltage with the average current density of the blue light emitting diode adopting the structure shown in FIG. 1 under different lengths of L1+L2;
  • Fig. 4 is a schematic diagram showing the change of the dynamic slope of each change curve shown in Fig. 3 with the average current density;
  • Fig. 5 is a top view of a light emitting diode according to a second embodiment of the present application.
  • Fig. 6 is a schematic partial cross-sectional view along the A2-A2 direction of Fig. 5;
  • Fig. 7 is a top view of a light emitting diode according to a third embodiment of the present application.
  • Fig. 8 is a schematic partial cross-sectional view taken along the A3-A3 direction of Fig. 7;
  • Fig. 9 is a top view of a light emitting diode according to a fourth embodiment of the present application.
  • Fig. 10 is a schematic partial cross-sectional view taken along the B-B direction of Fig. 5.
  • the light-emitting diode includes a substrate 11, a light-emitting epitaxial layer 12, a first electrode 13 and a second electrode 14.
  • the light-emitting epitaxial layer 12 further sequentially stacks a first semiconductor layer 121, an active light-emitting layer 122 and a second semiconductor layer 123 disposed on the substrate 11.
  • the substrate 11 can be made of conductive materials such as Si, Ge, Cu, and CuW.
  • the first semiconductor layer 121 is a P-type semiconductor layer (for example, P-type GaN), and the corresponding first electrode 13 is also referred to as a P-type electrode.
  • the second semiconductor layer 123 is an N-type semiconductor layer (for example, N-type GaN), and the corresponding second electrode 14 is also referred to as an N-type electrode.
  • the first semiconductor layer 121 and the second semiconductor layer 123 may be a single-layer or multi-layer structure of any other suitable material having different conductivity types.
  • the first electrode 13 is a surface electrode
  • the plurality of second electrodes 14 are strip-shaped electrodes
  • the projections on the substrate 11 fall on the first electrode 13 on the substrate 11.
  • the second electrodes 14 are finger electrodes extending along the first direction D1 and spaced apart from each other along the second direction D2 perpendicular to the first direction D1, so that the second electrodes 14 are The projections on the substrate 11 are spaced apart from each other along the second direction D2.
  • the first electrode 13 and the second electrode 14 are further connected to a first pad (not shown) and a second pad 16, and are further connected to an external circuit through the first pad and the second pad 16.
  • the light-emitting diode is a vertical light-emitting diode
  • the second electrode 14 and the first electrode 13 are respectively located on opposite sides of the light-emitting epitaxial layer 120.
  • the second electrode 14 is disposed on the side of the second semiconductor layer 123 away from the active light emitting layer 122, and the second electrode 14 is electrically connected to the second semiconductor layer 123.
  • the second electrode 14 is connected to the second semiconductor layer 123.
  • the two semiconductor layers 123 are electrically connected by direct contact.
  • the first electrode 13 is arranged on the side of the substrate 11 away from the light-emitting epitaxial layer 12 and forms an electrical connection with the first semiconductor layer 121 through the substrate 11. Furthermore, a reflector 18 and a metal bonding layer 17 may be further provided between the substrate 11 and the first semiconductor layer 121.
  • the reflector 18 is used to reflect the light generated by the active light-emitting layer 122, and further remove the light from the second semiconductor layer. Light is emitted from the side where the layer 123 is located, and the metal bonding layer 17 is used to improve the adhesion with the substrate 11.
  • the projection of the second electrode 14 on the substrate 11 and the projection of the first electrode 13 on the substrate 11 overlap each other, and then fall within the projection of the first electrode 13 on the substrate 11.
  • the inside of the projection of the first electrode 13 on the substrate 11 referred to in the present application includes both the overlap with the projection of the first electrode 13 on the substrate 11 shown in FIG. 2 and the subsequent The one shown in Figures 9-10 is surrounded by the projection of the first electrode on the substrate.
  • the current formed by holes is directly injected into the active light-emitting layer 122 from the first electrode 13 through the substrate 11, the mirror 18, and the metal bonding layer 17 along the stacking direction, and the current formed by electrons is from the second
  • the electrode 14 is injected into the second semiconductor layer 123 and diffuses laterally along the second semiconductor layer 123 and injected into the active light emitting layer 122.
  • the electrons and holes undergo radiation recombination in the active light-emitting layer 122 and generate photons, thereby forming light emission.
  • the distance at which the current in the light-emitting epitaxial layer 12 spreads laterally is determined by the lateral distance between adjacent second electrodes 14.
  • the lateral spacing between adjacent second electrodes 14 is set too large, resulting in poor uniformity of the current density distribution of the current injected into the active light-emitting layer 122, which in turn leads to the above-mentioned background art. Describe the problem.
  • the shortest distance between the projection of any light-emitting point A in at least part of the light-emitting area of the light-emitting epitaxial layer 12 on the substrate 11 and the projection of the two adjacent second electrodes 14 on the substrate 11 They are L1 and L2 respectively.
  • the sum of the two shortest separation distances is L1+L2.
  • lateral critical electrode spacing Lc The physical definition of the lateral critical electrode spacing Lc will be described in detail below. Specifically, this embodiment has determined the influence of the average current density on the operating voltage through a large number of experiments, and defined the key parameter that affects the performance of the LED chip: "lateral critical electrode spacing Lc", and the shortest distance is determined by the lateral critical electrode spacing Lc. The sum of the separation distance L1+L2 is limited, so that the performance of the LED chip is greatly improved.
  • a blue light emitting diode refers to a light emitting diode with a peak wavelength between 440 nm and 480 nm during operation.
  • FIG. 3 shows a schematic diagram of the variation of the operating voltage of the blue light emitting diode with the average current density under different L1+L2, and FIG. 4 shows the schematic diagram of the dynamic slope of each variation curve shown in FIG. 3 as a function of the average current density.
  • the selected values of L1+L2 include 230 micrometers, 105 micrometers, 80 micrometers, 50 micrometers, and 30 micrometers, and the unit of the working voltage V F is volts (ie, V), and the average current density
  • the unit of the dynamic slope of the change curve shown in Figure 4 is ohm square millimeter (ie, ⁇ mm 2 ).
  • the average current density J is the ratio between the working current of the light-emitting diode and the light-emitting area of the light-emitting diode.
  • the Y axis in FIG. 4 is expressed in logarithmic coordinates.
  • the lateral critical electrode spacing Lc is defined as ensuring that the operating voltage V F of the light emitting diode varies with the average current density J within a certain operating current section where the average current density J is greater than 1A/mm 2
  • the maximum allowable value of the sum of the above-mentioned shortest separation distances L1+L2 when the dynamic slope S d is not greater than 0.18 ⁇ mm 2.
  • the lateral critical electrode spacing can be defined as the maximum allowable value of the sum of the shortest separation distances L1+L2 when the dynamic slope in the above-mentioned operating current section is not greater than 0.15 ⁇ mm 2, and it can even be further defined as no greater than the maximum allowable value 0.1,0.06,0.03 ⁇ ⁇ mm 2 in.
  • the light-emitting diode is a constant current component, its working voltage is directly related to the lumen density and lumen efficiency. Therefore, when L1+L2 is set to be no greater than Lc and the light-emitting diode works in the above-mentioned operating current range, the performance of the light-emitting diode begins to be greatly improved, and the greater the operating current, the more obvious the improvement effect. At the same time, due to the significant reduction of the operating voltage, the thermal effect is also significantly reduced, so that light-emitting diodes with better life and reliability can be obtained, thereby increasing the lumen cost of the light-emitting diodes.
  • the 230 microns, 105 microns, 80 microns, 50 microns, and 30 microns mentioned above are parameters used in the design of specific light-emitting epitaxial layer structures and materials, and cannot be used as critical parameters for the lateral direction.
  • At least part of the light-emitting area constrained by Lc covers the entire light-emitting area of the light-emitting epitaxial layer 12.
  • the above-mentioned at least part of the light-emitting area is a partial area of the entire light-emitting area of the light-emitting epitaxial layer 12.
  • the area ratio of the set of all at least part of the light-emitting regions that meet the above constraint conditions to the total light-emitting regions on the light-emitting epitaxial layer 12 is not less than 50%.
  • the area ratio of the set of all at least part of the light-emitting regions that meet the above constraint conditions to the total light-emitting regions on the light-emitting epitaxial layer 12 may be further not less than 60%, 70%, 80%, or 90%.
  • the restriction method for the sum of the shortest separation distances L1+L2 in this embodiment is particularly suitable for high-power light-emitting diodes.
  • the average current density J during operation of the light emitting diode is set to be not less than 1A/mm 2 . In other specific embodiments, the average current density J during operation of the light emitting diode can be further set to not less than 1.5, 2, 3, 5, 10, 20 A/mm 2.
  • the first semiconductor layer and the second semiconductor layer of the blue light-emitting diode described in FIGS. 1-2 above are both based on Group III nitride system materials. Therefore, the lateral critical electrode spacing Lc is also applicable to light-emitting diodes of other wavelengths based on the III-nitride system, such as 365nm-400nm, 400nm-440nm, 440nm-480nm, 480nm-540nm, 540nm-560nm, 560nm-600nm or 600nm- 700nm.
  • the sum of the shortest separation distances L1+L2 in this embodiment is actually limited by the shortest separation distance between the projections of two adjacent second electrodes 14 on the substrate 11. Therefore, in this embodiment and In other embodiments, the shortest separation distance between the projections of two adjacent second electrodes 14 on the substrate 11 can be restricted by using Lc.
  • the shortest distance between the projections of two adjacent second electrodes 14 on the substrate 11 is set to be no greater than the lateral critical electrode spacing, which refers to ensuring that the operating voltage of the light emitting diode varies with the average current
  • the maximum allowable value of the shortest separation distance when the dynamic slope of the density change curve in a certain operating current section where the average current density is greater than 1A/mm 2 is not greater than 0.18 ⁇ mm 2 or the maximum allowable value under the above-mentioned other dynamic slope limits .
  • the uniformity of the current distribution is effectively improved, so that the light-emitting diode can withstand a higher working current, thereby improving the lumen efficiency and lumen density of the light-emitting diode.
  • the life and reliability of the light-emitting diode are high, and no complicated package design is required for heat dissipation, which reduces the lumen cost of the light-emitting diode.
  • the light emitting diode according to the second embodiment of the present application is a modification of the vertical light emitting diode shown in FIGS. 1 and 2.
  • the light-emitting diode also includes a first electrode 23, a substrate 21, a mirror 28, a metal bonding layer 27, a first semiconductor layer 221, and an active layer similar to the light-emitting diode shown in FIG. 1 and FIG.
  • the light emitting layer 222, the second semiconductor layer 223, and the second electrode 24 is:
  • the first semiconductor layer 221, the second semiconductor layer 123 and the active light emitting layer 122 are provided with trenches 224, and the trenches 224 arrange the first semiconductor layer 221, the second semiconductor layer 223 and the active light emitting layer 222 at intervals.
  • An insulating layer 291 and a current diffusion layer 292 are formed in the sidewall of the mesa structure 225 and the exposed area of the mesa structure 225.
  • Two adjacent second electrodes 242 are respectively disposed in the trenches 224 on both sides of the mesa structure 225, and are electrically connected to the second semiconductor layer 223 through the current diffusion layer 292. At this time, as shown in FIG.
  • any light-emitting point A'in at least a part of the light-emitting region of the light-emitting epitaxial layer formed by the first semiconductor layer 221, the second semiconductor layer 123 and the active light-emitting layer 122 is on the substrate 11
  • the shortest distance between the projection on the upper surface and the projection of the two adjacent second electrodes 24 on the substrate 21 are respectively L1' and L2'.
  • the sum of the two shortest separation distances is L1'+L2'.
  • the light emitting diode according to the third embodiment of the present application is a further modification of the vertical type light emitting diode shown in FIGS. 5 and 6.
  • the light-emitting diode also includes a first electrode 33, a substrate 31, a mirror 38, a metal bonding layer 37, a first semiconductor layer 321, and an active layer similar to the light-emitting diode shown in FIG. 5 and FIG.
  • the light emitting layer 322, the second semiconductor layer 323, and the second electrode 34 are examples of the light emitting diode according to the third embodiment of the present application.
  • the light-emitting diode also includes a first electrode 33, a substrate 31, a mirror 38, a metal bonding layer 37, a first semiconductor layer 321, and an active layer similar to the light-emitting diode shown in FIG. 5 and FIG.
  • the light emitting layer 322, the second semiconductor layer 323, and the second electrode 34 are examples of the light emitting diode according to the third embodiment of the present application.
  • first semiconductor layer 321, the active light emitting layer 322, and the second semiconductor layer 323 are also divided into mesa structures 325 spaced from each other by the trenches 324, and are formed on the sidewalls of the mesa structures 325 and the exposed regions of the mesa structures 325 There is an insulating layer 391.
  • the difference between this embodiment and the light emitting diode shown in FIG. 5 and FIG. 6 is:
  • a part of the second electrode 34 is disposed in the trench 324 in the form of a main electrode 343, and another part of the second electrode 34 is extended to the top of the mesa structure 325 in the form of a branch electrode 344, and is in contact with the second semiconductor layer 323 and formed Electric connection.
  • any light-emitting point A" in at least a part of the light-emitting region of the light-emitting epitaxial layer formed by the first semiconductor layer 321, the second semiconductor layer 323 and the active light-emitting layer 322 is on the substrate 11
  • the shortest distance between the projection on the upper surface and the projection of the two adjacent second electrodes 24 on the substrate 21 are respectively L1" and L2'.
  • the sum of the two shortest separation distances is L1"+L2".
  • the light-emitting diode according to the fourth embodiment of the present application is a flip-chip light-emitting diode, which includes a substrate 41, a light-emitting epitaxial layer 42, a first electrode 43 and a second electrode 44.
  • the first electrode 43 is a surface electrode
  • the number of the second electrode 44 is multiple, and the two are located on the same side of the light emitting diode.
  • the light-emitting epitaxial layer 42 further sequentially stacks a first semiconductor layer 421, an active light-emitting layer 422, and a second semiconductor layer 423 disposed on the substrate 41.
  • the first electrode 43 is disposed on a side of the second semiconductor layer 423 away from the substrate 41 and is electrically connected to the second semiconductor layer 423.
  • a mirror 49 is further provided between the first electrode 43 and the second semiconductor layer 423 to reflect the light generated by the active light-emitting layer 422, and then emit light from the side where the substrate 41 is located.
  • the surface of the first electrode 43 is provided with a plurality of grooves 424, and the grooves 424 extend to the first semiconductor layer 421 via the mirror 49, the second semiconductor layer 423 and the active light emitting layer 422.
  • the plurality of second electrodes 44 are respectively disposed in the corresponding grooves 424 and are electrically connected to the first semiconductor layer 421.
  • the first semiconductor layer 421 is an N-type semiconductor layer (for example, N-type GaN), and the corresponding second electrode 44 is also called an N-type electrode.
  • the second semiconductor layer 423 is a P-type semiconductor layer (for example, P-type GaN), and the corresponding first electrode 43 is also referred to as a P-type electrode.
  • the first semiconductor layer 421 and the second semiconductor layer 423 may be a single-layer or multi-layer structure of any other suitable materials with different conductivity types.
  • the projection of any light-emitting point A"' in at least part of the light-emitting area of the light-emitting epitaxial layer 42 on the substrate 41 and the projection of the two adjacent second electrodes 44 on the substrate 41 are the shortest
  • the separation distances are respectively L1”' and L2”'.
  • the sum of the two shortest separation distances is L1”'+L2”'.
  • first electrode and the second electrode of the first embodiment and the second embodiment of the present application are in a grid-like structure, which improves performance while reducing production line upgrade costs.
  • the third embodiment and the fourth embodiment of the present application have a uniform dot structure, which can improve the uniformity of lateral current spreading.
  • the shapes of the first electrode and the second electrode are not limited, and can be selected according to actual needs.
  • Both the first electrode and the second electrode are composed of conductive materials, and the materials are aluminum, copper, tungsten, molybdenum, gold, titanium, silver, nickel, palladium or any combination thereof.
  • the first electrode and the second electrode have at least one layer structure .
  • the first electrode may be a P-type electrode, and the second electrode may be an N-type electrode; or, the first electrode may be an N-type electrode, and the second electrode may be a P-type electrode.
  • the active light-emitting layer formed between the first semiconductor layer and the second semiconductor layer can emit light with a certain energy according to the recombination of electrons and holes, and can have a multiple quantum well (MQW) structure in which quantum wells and quantum barriers are alternately superimposed .
  • the active light-emitting layer may have a multi-quantum InGaN/GaN formed by injecting trimethylgallium gas (TMGa), ammonia (NH 3 ), nitrogen (N 2 ), trimethyl indium gas (TMIn), etc.
  • TMGa trimethylgallium gas
  • NH 3 ammonia
  • N 2 nitrogen
  • TIn trimethyl indium gas
  • the first and second semiconductor layers and the active light-emitting layer can be formed by using semiconductor layer growth processes known in the art, such as metal organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), hydride vapor phase Epitaxy (HVPE) and so on. And has an energy determined by the intrinsic energy band of the active light-emitting layer material.
  • MOCVD metal organic chemical vapor deposition
  • MBE molecular beam epitaxy
  • HVPE hydride vapor phase Epitaxy
  • the Group III nitride material mentioned above may specifically include GaN, Al x1 Ga y1 N, InGaN, Al x2 In y2 Ga z2 N.
  • the mole fractions x1 and x2 of Al are respectively less than 10%.

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Abstract

Disclosed in the present application is a light-emitting diode, comprising a substrate, a light-emitting epitaxial layer, a first electrode, and a plurality of second electrodes. The light-emitting epitaxial layer comprises a first semiconductor layer, an active light-emitting layer and a second semiconductor layer sequentially stacked on one another and disposed on the substrate. The first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the second electrode is electrically connected to the other of the first semiconductor layer and the second semiconductor layer. The first electrode is a planar electrode. The projection of the plurality of second electrodes on the substrate falls within the projection of the first electrode on the substrate and the plurality of second electrodes are disposed to be spaced apart from one another. The sum of the shortest distances between the projection of any of light-emitting points in at least part of light-emitting regions of the light-emitting epitaxial layer on the substrate and the projections of the two adjacent second electrodes on the substrate is not greater than a transverse critical electrode spacing. The above configuration of the present application can effectively improve the distribution uniformity of electrical currents and thus increase lumen density and lumen efficiency of light-emitting diodes, thereby reducing lumen costs.

Description

一种发光二极管A light-emitting diode 【技术领域】【Technical Field】
本申请涉及半导体领域,特别是一种发光二极管。This application relates to the field of semiconductors, especially a light-emitting diode.
【背景技术】【Background technique】
发光二极管是将电能转换为光的固态元件,发光二极管具有体积小、效率高和寿命长等优点,在交通指示、户外全色显示等领域有着广泛的应用。尤其是利用大功率发光二极管可以实现半导体固态照明,引起人类照明史的革命,从而逐渐成为目前电子学领域的研究热点。Light-emitting diodes are solid-state components that convert electrical energy into light. Light-emitting diodes have the advantages of small size, high efficiency, and long life, and are widely used in traffic indications, outdoor full-color displays and other fields. In particular, the use of high-power light-emitting diodes can realize semiconductor solid-state lighting, which has caused a revolution in the history of human lighting, and has gradually become a research hotspot in the current electronics field.
目前,发光二极管的电流一般采用横向扩散方式注入至有源发光层,而这种横向扩散方式具有天然的电流非均匀分布的特性,导致局部区域的电流密度过大。局部区域的电流密度过大容易引起两方面问题:At present, the current of the light-emitting diode is generally injected into the active light-emitting layer by a lateral diffusion method, and this lateral diffusion method has a natural non-uniform current distribution characteristic, resulting in excessive current density in a local area. Excessive current density in a local area can easily cause two problems:
1.局部电流过大容易引起电光转换效率下降,导致流明效率和流明密度的下降;1. Excessive local current can easily cause the electro-optical conversion efficiency to drop, resulting in a drop in lumen efficiency and lumen density;
2.局部电流过大容易引起局部过热,导致发光二极管的使用寿命和可靠性的下降,并需要通过复杂的封装设计来实现散热,提高了流明成本。2. Excessive local current can easily cause local overheating, leading to a decrease in the service life and reliability of the light-emitting diode, and it is necessary to achieve heat dissipation through a complex package design, which increases the cost of lumen.
【发明内容】[Summary of the invention]
本申请提供一种发光二极管,能够改善电流分布均匀性,以使发光二极管能够承受更高的工作电流,进而提升发光二极管的流明效率和流明密度,并降低流明成本。The present application provides a light emitting diode that can improve the uniformity of current distribution, so that the light emitting diode can withstand a higher working current, thereby improving the lumen efficiency and lumen density of the light emitting diode, and reducing the lumen cost.
一方面,本申请提供了一种发光二极管,包括:衬底;发光外延层,包括依次层叠设置于衬底上的第一半导体层、有源发光层以及第二半导体层;第一电极和多个第二电极,第一电极与第一半导体层和第二半导体层中的一个电连接,多个第二电极与第一半导体层和第二半导体层中的另一个电连接;其中,第一电极为面电极,多个第二电极在衬底上的投影落在第一电极在衬底上的投影内部且彼此间隔设置,相邻的两个第二电极之间最短间隔距离不大于横向临界电极间距,横向临界电极间距是指确保发光二极管的工作电压随平均电流密度的变化曲线在平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时最短间隔距离之和的最大容许值,发光二极管工作于工作电流区段,且第一半导体层和第二半导体层均是采用基于三族氮化物体系的材料;基于三族氮化物体系的材料包括GaN、Alx 1Gay 1N、InGaN、Alx 2Iny 2Gaz 2N中的至少一种。 In one aspect, the present application provides a light-emitting diode, including: a substrate; a light-emitting epitaxial layer, including a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer that are sequentially stacked on the substrate; A second electrode, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first The electrode is a surface electrode, and the projections of multiple second electrodes on the substrate fall within the projections of the first electrodes on the substrate and are spaced apart from each other. The shortest distance between two adjacent second electrodes is not greater than the lateral threshold. Electrode spacing, the horizontal critical electrode spacing refers to the shortest when the dynamic slope of the change curve of the working voltage of the light-emitting diode with the average current density in a certain working current section where the average current density is greater than 1A/mm 2 is not greater than 0.18Ω·mm 2 The maximum allowable value of the sum of the separation distance, the light-emitting diode works in the operating current section, and the first semiconductor layer and the second semiconductor layer are made of materials based on the three-nitride system; the materials based on the three-nitride system include GaN , At least one of Alx 1 Gay 1 N, InGaN, Alx 2 Iny 2 Gaz 2 N.
另一方面,本申请提供了一种发光二极管,包括:衬底;发光外延层,包括依次层叠设置于衬底上的第一半导体层、有源发光层以及第二 半导体层;第一电极和多个第二电极,第一电极与第一半导体层和第二半导体层中的一个电连接,多个第二电极与第一半导体层和第二半导体层中的另一个电连接;其中,第一电极为面电极,多个第二电极在衬底上的投影落在第一电极在衬底上的投影内部且彼此间隔设置,发光外延层的至少部分发光区域内的任意一发光点在衬底上的投影与相邻的两个第二电极在衬底上的投影的最短间隔距离之和不大于横向临界电极间距,横向临界电极间距是指确保发光二极管的工作电压随平均电流密度的变化曲线在平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时最短间隔距离之和的最大容许值,发光二极管工作于工作电流区段,且第一半导体层和第二半导体层均是采用基于三族氮化物体系的材料。 On the other hand, the present application provides a light-emitting diode, including: a substrate; a light-emitting epitaxial layer, including a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer stacked on the substrate in sequence; a first electrode and A plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer; One electrode is a surface electrode, the projections of the multiple second electrodes on the substrate fall inside the projections of the first electrode on the substrate and are arranged at intervals. Any light-emitting point in at least part of the light-emitting area of the light-emitting epitaxial layer is on the substrate. The sum of the shortest distance between the projection on the bottom and the projection of the two adjacent second electrodes on the substrate is not greater than the lateral critical electrode spacing. The lateral critical electrode spacing refers to ensuring that the operating voltage of the light-emitting diode changes with the average current density When the dynamic slope of the curve in a certain working current section with an average current density greater than 1A/mm 2 is not greater than 0.18Ω·mm 2 the maximum allowable value of the sum of the shortest separation distances, the light emitting diode works in the working current section, and the first Both the semiconductor layer and the second semiconductor layer are made of materials based on the Group III nitride system.
又一方面,本申请提供了一种发光二极管,包括:衬底;发光外延层,包括依次层叠设置于衬底上的第一半导体层、有源发光层以及第二半导体层;第一电极和多个第二电极,第一电极与第一半导体层和第二半导体层中的一个电连接,多个第二电极与第一半导体层和第二半导体层中的另一个电连接;其中,第一电极为面电极,多个第二电极在衬底上的投影落在第一电极在衬底上的投影内部且彼此间隔设置,相邻的两个第二电极之间最短间隔距离不大于横向临界电极间距,横向临界电极间距是指确保发光二极管的工作电压随平均电流密度的变化曲线在平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时最短间隔距离之和的最大容许值,发光二极管工作于工作电流区段,且第一半导体层和第二半导体层均是采用基于三族氮化物体系的材料。 In another aspect, the present application provides a light emitting diode, including: a substrate; a light emitting epitaxial layer, including a first semiconductor layer, an active light emitting layer, and a second semiconductor layer stacked on the substrate in sequence; a first electrode and A plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are electrically connected to the other of the first semiconductor layer and the second semiconductor layer; wherein, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer; One electrode is a surface electrode, the projections of multiple second electrodes on the substrate fall inside the projections of the first electrodes on the substrate and are spaced apart from each other, and the shortest distance between two adjacent second electrodes is not greater than the lateral Critical electrode spacing, horizontal critical electrode spacing means to ensure that the dynamic slope of the light-emitting diode operating voltage with the average current density in a certain operating current section where the average current density is greater than 1A/mm 2 is not greater than 0.18Ω·mm 2 The maximum allowable value of the sum of the shortest separation distance, the light emitting diode works in the operating current section, and the first semiconductor layer and the second semiconductor layer are both made of materials based on the group III nitride system.
本申请的有益效果是:区别于现有技术的情况,本申请通过工作电压随平均电流密度的变化斜率设置一横向临界电极间距,并将发光外延层的至少部分发光区域内的任意一发光点在衬底上的投影与相邻的两个第二电极在衬底上的投影的最短间隔距离之和不大于横向临界电极间距,有效改善电流分布的均匀性,以使发光二极管能够承受更高的工作电流,进而提升发光二极管的流明效率和流明密度。同时,发光二极管的寿命和可靠性高,不需要复杂的封装设计来进行散热,降低了发光二极管的流明成本。The beneficial effect of the present application is: different from the state of the art, the present application sets a lateral critical electrode spacing based on the slope of the change of the working voltage with the average current density, and sets any light-emitting point in at least a part of the light-emitting area of the light-emitting epitaxial layer The sum of the shortest distance between the projection on the substrate and the projection of the two adjacent second electrodes on the substrate is not greater than the lateral critical electrode spacing, which effectively improves the uniformity of current distribution so that the light-emitting diode can withstand higher The working current can improve the lumen efficiency and lumen density of the light-emitting diode. At the same time, the life and reliability of the light-emitting diode are high, and no complicated package design is required for heat dissipation, which reduces the lumen cost of the light-emitting diode.
【附图说明】【Explanation of the drawings】
为了更清楚地说明本申请实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。其中:In order to more clearly describe the technical solutions in the embodiments of the present application, the following will briefly introduce the drawings that need to be used in the description of the embodiments. Obviously, the drawings in the following description are only some embodiments of the present application. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without creative work. among them:
图1是根据本申请第一实施例的发光二极管的俯视图;Fig. 1 is a top view of a light emitting diode according to a first embodiment of the present application;
图2是沿图1的A1-A1方向的局部截面示意图;Fig. 2 is a schematic partial cross-sectional view taken along the A1-A1 direction of Fig. 1;
图3是用于显示采用图1所示结构的蓝光发光二极管在不同的L1+L2长度下的工作电压随平均电流密度变化的曲线示意图;FIG. 3 is a schematic diagram showing the variation of the operating voltage with the average current density of the blue light emitting diode adopting the structure shown in FIG. 1 under different lengths of L1+L2;
图4是用于显示图3所示的各变化曲线的动态斜率随平均电流密度变化的曲线示意图;Fig. 4 is a schematic diagram showing the change of the dynamic slope of each change curve shown in Fig. 3 with the average current density;
图5是根据本申请第二实施例的发光二极管的俯视图;Fig. 5 is a top view of a light emitting diode according to a second embodiment of the present application;
图6是沿图5的A2-A2方向的局部截面示意图;Fig. 6 is a schematic partial cross-sectional view along the A2-A2 direction of Fig. 5;
图7是根据本申请第三实施例的发光二极管的俯视图;Fig. 7 is a top view of a light emitting diode according to a third embodiment of the present application;
图8是沿图7的A3-A3方向的局部截面示意图;Fig. 8 is a schematic partial cross-sectional view taken along the A3-A3 direction of Fig. 7;
图9是根据本申请第四实施例的发光二极管的俯视图;Fig. 9 is a top view of a light emitting diode according to a fourth embodiment of the present application;
图10是沿图5的B-B方向的局部截面示意图。Fig. 10 is a schematic partial cross-sectional view taken along the B-B direction of Fig. 5.
【具体实施方式】【Detailed ways】
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性的劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。The technical solutions in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments are only a part of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of this application.
如图1和图2所示,根据本申请第一实施例的发光二极管包括衬底11、发光外延层12、第一电极13和第二电极14。发光外延层12进一步依次层叠设置于衬底11上的第一半导体层121、有源发光层122以及第二半导体层123。在本实施例中,衬底11可以采用例如Si、Ge、Cu、CuW等导电材料。第一半导体层121为P型半导体层(例如P型GaN),对应的第一电极13也称为P型电极。第二半导体层123为N型半导体层(例如N型GaN),对应的第二电极14也称为N型电极。在其他实施例中,第一半导体层121和第二半导体层123可以是具有不同导电类型的其他任意适当材料的单层或多层结构。As shown in FIGS. 1 and 2, the light-emitting diode according to the first embodiment of the present application includes a substrate 11, a light-emitting epitaxial layer 12, a first electrode 13 and a second electrode 14. The light-emitting epitaxial layer 12 further sequentially stacks a first semiconductor layer 121, an active light-emitting layer 122 and a second semiconductor layer 123 disposed on the substrate 11. In this embodiment, the substrate 11 can be made of conductive materials such as Si, Ge, Cu, and CuW. The first semiconductor layer 121 is a P-type semiconductor layer (for example, P-type GaN), and the corresponding first electrode 13 is also referred to as a P-type electrode. The second semiconductor layer 123 is an N-type semiconductor layer (for example, N-type GaN), and the corresponding second electrode 14 is also referred to as an N-type electrode. In other embodiments, the first semiconductor layer 121 and the second semiconductor layer 123 may be a single-layer or multi-layer structure of any other suitable material having different conductivity types.
进一步,如图1和图2所示,第一电极13为面电极,多个第二电极14分别为条形电极,并在衬底11上的投影落在第一电极13在衬底11上的投影内部且彼此间隔设置。具体而言,在本实施例中,第二电极14分别为沿第一方向D1延伸且沿垂直于第一方向D1的第二方向D2彼此间隔设置的指状电极,进而使得第二电极14在衬底11上的投影沿第二方向D2彼此间隔设置。第一电极13和第二电极14进一步连接第一焊盘(未图示)和第二焊盘16,进而通过第一焊盘和第二焊盘16与外部电路进行连接。Further, as shown in FIGS. 1 and 2, the first electrode 13 is a surface electrode, and the plurality of second electrodes 14 are strip-shaped electrodes, and the projections on the substrate 11 fall on the first electrode 13 on the substrate 11. The projections inside and spaced apart from each other. Specifically, in this embodiment, the second electrodes 14 are finger electrodes extending along the first direction D1 and spaced apart from each other along the second direction D2 perpendicular to the first direction D1, so that the second electrodes 14 are The projections on the substrate 11 are spaced apart from each other along the second direction D2. The first electrode 13 and the second electrode 14 are further connected to a first pad (not shown) and a second pad 16, and are further connected to an external circuit through the first pad and the second pad 16.
进一步,在本实施中,发光二极管为垂直发光二极管,第二电极14以及第一电极13分别位于发光外延层120的相对两侧。其中,第二电极14设置于第二半导体层123远离有源发光层122的一侧,且第二电 极14与第二半导体层123电连接,例如在本实施例中,第二电极14与第二半导体层123通过直接接触的方式形成电连接。Furthermore, in this embodiment, the light-emitting diode is a vertical light-emitting diode, and the second electrode 14 and the first electrode 13 are respectively located on opposite sides of the light-emitting epitaxial layer 120. Wherein, the second electrode 14 is disposed on the side of the second semiconductor layer 123 away from the active light emitting layer 122, and the second electrode 14 is electrically connected to the second semiconductor layer 123. For example, in this embodiment, the second electrode 14 is connected to the second semiconductor layer 123. The two semiconductor layers 123 are electrically connected by direct contact.
第一电极13设置在衬底11远离发光外延层12的一侧,通过衬底11与第一半导体层121形成电连接。进一步,衬底11与第一半导体层121之间还可以设有反射镜18和金属键合层17,反射镜18用于对有源发光层122所产生的光进行反射,进而从第二半导体层123所在一侧出光,金属键合层17用于提高与衬底11的附着力。The first electrode 13 is arranged on the side of the substrate 11 away from the light-emitting epitaxial layer 12 and forms an electrical connection with the first semiconductor layer 121 through the substrate 11. Furthermore, a reflector 18 and a metal bonding layer 17 may be further provided between the substrate 11 and the first semiconductor layer 121. The reflector 18 is used to reflect the light generated by the active light-emitting layer 122, and further remove the light from the second semiconductor layer. Light is emitted from the side where the layer 123 is located, and the metal bonding layer 17 is used to improve the adhesion with the substrate 11.
在本实施例中,第二电极14在衬底11上的投影与第一电极13在衬底11上的投影彼此重叠,进而落在第一电极13在衬底11上的投影内部。此处值得注意的是,本申请所指的落在第一电极13在衬底11上的投影内部既包括图2所示的与第一电极13在衬底11上的投影重叠,也包括后续图9-10所示的被第一电极在衬底上的投影所包围。In this embodiment, the projection of the second electrode 14 on the substrate 11 and the projection of the first electrode 13 on the substrate 11 overlap each other, and then fall within the projection of the first electrode 13 on the substrate 11. It is worth noting here that the inside of the projection of the first electrode 13 on the substrate 11 referred to in the present application includes both the overlap with the projection of the first electrode 13 on the substrate 11 shown in FIG. 2 and the subsequent The one shown in Figures 9-10 is surrounded by the projection of the first electrode on the substrate.
通过上述结构,由空穴形成的电流从第一电极13经衬底11、反射镜18和金属键合层17沿其层叠方向直接注入有源发光层122,而由电子形成的电流从第二电极14注入第二半导体层123,并沿第二半导体层123横向扩散并注入有源发光层122。电子和空穴在有源发光层122内进行辐射复合,并产生光子,进而形成发光。With the above structure, the current formed by holes is directly injected into the active light-emitting layer 122 from the first electrode 13 through the substrate 11, the mirror 18, and the metal bonding layer 17 along the stacking direction, and the current formed by electrons is from the second The electrode 14 is injected into the second semiconductor layer 123 and diffuses laterally along the second semiconductor layer 123 and injected into the active light emitting layer 122. The electrons and holes undergo radiation recombination in the active light-emitting layer 122 and generate photons, thereby forming light emission.
如上述结构可知,发光外延层12内的电流进行横向扩散的距离由相邻的第二电极14之间的横向间距决定。在现有技术中,相邻的第二电极14之间的横向间距设置得过大,导致注入有源发光层122的电流的电流密度分布的均匀性较差,进而产生上文背景技术中所描述的问题。As can be seen from the above structure, the distance at which the current in the light-emitting epitaxial layer 12 spreads laterally is determined by the lateral distance between adjacent second electrodes 14. In the prior art, the lateral spacing between adjacent second electrodes 14 is set too large, resulting in poor uniformity of the current density distribution of the current injected into the active light-emitting layer 122, which in turn leads to the above-mentioned background art. Describe the problem.
在本实施例中,发光外延层12的至少部分发光区域内的任意一发光点A在衬底11上的投影与相邻的两个第二电极14在衬底11上的投影的最短间隔距离分别为L1、L2。两个最短间隔距离之和为L1+L2。In this embodiment, the shortest distance between the projection of any light-emitting point A in at least part of the light-emitting area of the light-emitting epitaxial layer 12 on the substrate 11 and the projection of the two adjacent second electrodes 14 on the substrate 11 They are L1 and L2 respectively. The sum of the two shortest separation distances is L1+L2.
下面将对横向临界电极间距Lc的物理定义进行详细描述。具体来说,本实施例通过大量实验,确定了平均电流密度对工作电压的影响,定义了影响LED芯片性能的关键参数:“横向临界电极间距Lc”,并通过横向临界电极间距Lc来对最短间隔距离之和L1+L2进行限制,以使得LED芯片的性能得到一个巨大的提升。The physical definition of the lateral critical electrode spacing Lc will be described in detail below. Specifically, this embodiment has determined the influence of the average current density on the operating voltage through a large number of experiments, and defined the key parameter that affects the performance of the LED chip: "lateral critical electrode spacing Lc", and the shortest distance is determined by the lateral critical electrode spacing Lc. The sum of the separation distance L1+L2 is limited, so that the performance of the LED chip is greatly improved.
下面将参照图3和图4对蓝光发光二极管中的横向临界电极间距Lc进行详细描述。在本申请中,蓝光发光二极管是指在工作时峰值波长介于440nm-480nm之间的发光二极管。The lateral critical electrode spacing Lc in the blue light emitting diode will be described in detail below with reference to FIGS. 3 and 4. In this application, a blue light emitting diode refers to a light emitting diode with a peak wavelength between 440 nm and 480 nm during operation.
图3显示了在不同的L1+L2下蓝光发光二极管的工作电压随平均电流密度变化的曲线示意图,图4显示了图3所示的各变化曲线的动态斜率随平均电流密度变化的曲线示意图。在图3和图4中,所选取的L1+L2值包括230微米、105微米、80微米、50微米和30微米,并且工作电压V F的单位为伏特(即,V),而平均电流密度J的单位为安培每平方毫米(即,A/mm 2),动态斜率S d=dV F/dJ,此时图4所示的变化曲线的 动态斜率的单位为欧姆平方毫米(即,Ω·mm 2)。平均电流密度J为发光二极管的工作电流与发光二极管的发光面积之间的比值。进一步,在图4中为了体现各变化曲线的动态斜率之间的差异,图4中的Y轴以对数坐标表示。 FIG. 3 shows a schematic diagram of the variation of the operating voltage of the blue light emitting diode with the average current density under different L1+L2, and FIG. 4 shows the schematic diagram of the dynamic slope of each variation curve shown in FIG. 3 as a function of the average current density. In Figures 3 and 4, the selected values of L1+L2 include 230 micrometers, 105 micrometers, 80 micrometers, 50 micrometers, and 30 micrometers, and the unit of the working voltage V F is volts (ie, V), and the average current density The unit of J is ampere per square millimeter (ie, A/mm 2 ), and the dynamic slope S d =dV F /dJ. At this time, the unit of the dynamic slope of the change curve shown in Figure 4 is ohm square millimeter (ie, Ω· mm 2 ). The average current density J is the ratio between the working current of the light-emitting diode and the light-emitting area of the light-emitting diode. Furthermore, in order to reflect the difference between the dynamic slopes of the various change curves in FIG. 4, the Y axis in FIG. 4 is expressed in logarithmic coordinates.
首先,如图3所示,当L1+L2=230微米时,从其所对应的变化曲线可以看出,工作电压V F随平均电流密度J的增大而急剧上升,并从图4中可以看出该变化曲线所有范围内的动态斜率均不小于0.19Ω·mm 2。然而,在当L1+L2下降至105微米时,从图3可以看出,工作电压V F随平均电流密度J的上升趋势明显变缓,并从图4中可以看出,在平均电流密度J大于一定值后,曲线的动态斜率下降至0.18Ω·mm 2,并随着平均电流密度J的增大在一定范围内持续保持在0.18Ω·mm 2以下,且能够下降到0.07Ω·mm 2。在当L1+L2下降至80微米时,工作电压V F随平均电流密度J的上升趋势进一步变缓,并且在平均电流密度J大于一定值后,曲线的动态斜率下降至0.18Ω·mm 2,并随着平均电流密度J的增大在一定范围内持续保持在0.18Ω·mm 2以下,且能够下降到0.05Ω·mm 2。当L1+L2下降至50和30微米时,工作电压V F随平均电流密度J的上升趋势进一步变缓,并且在平均电流密度J大于一定值后,曲线的动态斜率下降至0.18Ω·mm 2,并随着平均电流密度J的增大而一直持续保持在0.18Ω·mm 2以下,且能够下降到0.02Ω·mm 2和0.005Ω·mm 2以下。由此可见,随L1+L2长度的减少,LED的动态斜率随电流密度的增加而迅速减少,且有效工作的电流密度也迅速增加,因此可以提升LED芯片单位面积下的流明输出,从而降低流明成本。 First, as shown in Figure 3, when L1+L2=230 microns, it can be seen from the corresponding change curve that the working voltage V F rises sharply with the increase of the average current density J, and it can be seen from Figure 4 It can be seen that the dynamic slope in all ranges of the change curve is not less than 0.19Ω·mm 2 . However, when L1+L2 drops to 105 microns, it can be seen from Figure 3 that the rising trend of the working voltage V F with the average current density J obviously slows down, and it can be seen from Figure 4 that the average current density J When the value is greater than a certain value, the dynamic slope of the curve drops to 0.18Ω·mm 2 , and with the increase of the average current density J, it continues to remain below 0.18Ω·mm 2 within a certain range, and can drop to 0.07Ω·mm 2 . When L1+L2 drops to 80 microns, the rising trend of the working voltage V F with the average current density J further slows down, and when the average current density J is greater than a certain value, the dynamic slope of the curve drops to 0.18Ω·mm 2 , And with the increase of the average current density J, it is continuously maintained below 0.18Ω·mm 2 within a certain range, and can be reduced to 0.05Ω·mm 2 . When L1+L2 drops to 50 and 30 microns, the rising trend of the working voltage V F with the average current density J further slows down, and when the average current density J is greater than a certain value, the dynamic slope of the curve drops to 0.18Ω·mm 2 , And with the increase of the average current density J, it has been continuously maintained below 0.18Ω·mm 2 and can be reduced to below 0.02Ω·mm 2 and 0.005Ω·mm 2 . It can be seen that as the length of L1+L2 decreases, the dynamic slope of the LED decreases rapidly with the increase of current density, and the current density for effective operation also increases rapidly. Therefore, the lumen output per unit area of the LED chip can be increased, thereby reducing the lumen. cost.
因此,在本实施例中,将横向临界电极间距Lc定义为确保发光二极管的工作电压V F随平均电流密度J的变化曲线在平均电流密度J大于1A/mm 2的一定工作电流区段内的动态斜率S d不大于0.18Ω·mm 2时上述最短间隔距离之和L1+L2的最大容许值。 Therefore, in this embodiment, the lateral critical electrode spacing Lc is defined as ensuring that the operating voltage V F of the light emitting diode varies with the average current density J within a certain operating current section where the average current density J is greater than 1A/mm 2 The maximum allowable value of the sum of the above-mentioned shortest separation distances L1+L2 when the dynamic slope S d is not greater than 0.18Ω·mm 2.
在其他实施例中,可以将横向临界电极间距定义为确保上述工作电流区段内的动态斜率不大于0.15Ω·mm 2时最短间隔距离之和L1+L2的最大容许值,甚至可以进一步定义为不大于0.1、0.06、0.03Ω·mm 2时的最大容许值。 In other embodiments, the lateral critical electrode spacing can be defined as the maximum allowable value of the sum of the shortest separation distances L1+L2 when the dynamic slope in the above-mentioned operating current section is not greater than 0.15Ω·mm 2, and it can even be further defined as no greater than the maximum allowable value 0.1,0.06,0.03Ω · mm 2 in.
由于发光二极管为恒流元件,其工作电压直接关系到流明密度和流明效率。因此,当L1+L2设置成不大于Lc,并使得发光二极管工作于上述工作电流区段时,发光二极管的性能开始有巨大改善,并且工作电流越大,改善效果越明显。同时,由于工作电压的显著降低,热效应也显著降低,进而可以获得寿命和可靠性更佳的发光二极管,进而提供了发光二极管的流明成本。Since the light-emitting diode is a constant current component, its working voltage is directly related to the lumen density and lumen efficiency. Therefore, when L1+L2 is set to be no greater than Lc and the light-emitting diode works in the above-mentioned operating current range, the performance of the light-emitting diode begins to be greatly improved, and the greater the operating current, the more obvious the improvement effect. At the same time, due to the significant reduction of the operating voltage, the thermal effect is also significantly reduced, so that light-emitting diodes with better life and reliability can be obtained, thereby increasing the lumen cost of the light-emitting diodes.
需要进一步说明的是,在上文中提到的230微米、105微米、80微米、50微米和30微米是针对特定的发光外延层结构和材料进行设计时 所采用的参数,并不能作为对横向临界电极间距Lc的实际限定。在实际应用中,横向临界电极间距Lc随着发光二极管的具体结构和具体材料发生变化。It should be further clarified that the 230 microns, 105 microns, 80 microns, 50 microns, and 30 microns mentioned above are parameters used in the design of specific light-emitting epitaxial layer structures and materials, and cannot be used as critical parameters for the lateral direction. The actual limit of the electrode spacing Lc. In practical applications, the lateral critical electrode spacing Lc varies with the specific structure and specific material of the light-emitting diode.
在本实施例中,受Lc约束的至少部分发光区域涵盖了发光外延层12的全部发光区域。在其他实施例中,上述至少部分发光区域为发光外延层12的全部发光区域的局部区域。在一具体实施方式中,满足上述约束条件的所有至少部分发光区域的集合与发光外延层12上的全部发光区域的面积比不小于50%。在其他具体实施方式中,满足上述约束条件的所有至少部分发光区域的集合与发光外延层12上的全部发光区域的面积比可以进一步不小于60%、70%、80%、90%。In this embodiment, at least part of the light-emitting area constrained by Lc covers the entire light-emitting area of the light-emitting epitaxial layer 12. In other embodiments, the above-mentioned at least part of the light-emitting area is a partial area of the entire light-emitting area of the light-emitting epitaxial layer 12. In a specific embodiment, the area ratio of the set of all at least part of the light-emitting regions that meet the above constraint conditions to the total light-emitting regions on the light-emitting epitaxial layer 12 is not less than 50%. In other specific embodiments, the area ratio of the set of all at least part of the light-emitting regions that meet the above constraint conditions to the total light-emitting regions on the light-emitting epitaxial layer 12 may be further not less than 60%, 70%, 80%, or 90%.
进一步,如图3和图4所示,工作电流越大,发光二极管性能的改善效果越明显。因此,本实施例的针对最短间隔距离之和L1+L2的约束方式特别适用于大功率发光二极管。在一具体实施方式中,发光二极管工作时的平均电流密度J设置成不小于1A/mm 2。在其他具体实施方式中,发光二极管工作时的平均电流密度J可以进一步设置成不小于1.5、2、3、5、10、20A/mm 2Furthermore, as shown in FIGS. 3 and 4, the greater the operating current, the more obvious the improvement effect of the light-emitting diode performance. Therefore, the restriction method for the sum of the shortest separation distances L1+L2 in this embodiment is particularly suitable for high-power light-emitting diodes. In a specific embodiment, the average current density J during operation of the light emitting diode is set to be not less than 1A/mm 2 . In other specific embodiments, the average current density J during operation of the light emitting diode can be further set to not less than 1.5, 2, 3, 5, 10, 20 A/mm 2.
需要注意的是,在上述图1-2所描述的蓝光发光二极管的第一半导体层和第二半导体层均是基于三族氮化物体系的材料。因此,横向临界电极间距Lc同样适用于基于三族氮化物体系的其他波长的发光二极管,例如365nm-400nm、400nm-440nm、440nm-480nm、480nm-540nm、540nm-560nm、560nm-600nm或600nm-700nm。It should be noted that the first semiconductor layer and the second semiconductor layer of the blue light-emitting diode described in FIGS. 1-2 above are both based on Group III nitride system materials. Therefore, the lateral critical electrode spacing Lc is also applicable to light-emitting diodes of other wavelengths based on the III-nitride system, such as 365nm-400nm, 400nm-440nm, 440nm-480nm, 480nm-540nm, 540nm-560nm, 560nm-600nm or 600nm- 700nm.
需要注意的是,本实施例中的最短间隔距离之和L1+L2实际上受相邻两个第二电极14在衬底11的投影之间的最短间隔距离的限制,因此在本实施例以及其他实施例中,可以通过利用Lc对相邻两个第二电极14在衬底11的投影之间的最短间隔距离进行约束。具体来说,将相邻两个第二电极14在衬底11的投影之间的最短间隔距离设置成不大于横向临界电极间距,该横向临界电极间距是指确保发光二极管的工作电压随平均电流密度的变化曲线在平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时最短间隔距离的最大容许值,或者上述其他动态斜率限制下的最大容许值。 It should be noted that the sum of the shortest separation distances L1+L2 in this embodiment is actually limited by the shortest separation distance between the projections of two adjacent second electrodes 14 on the substrate 11. Therefore, in this embodiment and In other embodiments, the shortest separation distance between the projections of two adjacent second electrodes 14 on the substrate 11 can be restricted by using Lc. Specifically, the shortest distance between the projections of two adjacent second electrodes 14 on the substrate 11 is set to be no greater than the lateral critical electrode spacing, which refers to ensuring that the operating voltage of the light emitting diode varies with the average current The maximum allowable value of the shortest separation distance when the dynamic slope of the density change curve in a certain operating current section where the average current density is greater than 1A/mm 2 is not greater than 0.18Ω·mm 2 or the maximum allowable value under the above-mentioned other dynamic slope limits .
综上,通过上述设置方式,有效改善电流分布的均匀性,以使发光二极管能够承受更高的工作电流,进而提升发光二极管的流明效率和流明密度。同时,发光二极管的寿命和可靠性高,不需要复杂的封装设计来进行散热,降低了发光二极管的流明成本。In summary, through the above arrangement, the uniformity of the current distribution is effectively improved, so that the light-emitting diode can withstand a higher working current, thereby improving the lumen efficiency and lumen density of the light-emitting diode. At the same time, the life and reliability of the light-emitting diode are high, and no complicated package design is required for heat dissipation, which reduces the lumen cost of the light-emitting diode.
下面将对同样适用上述横向临界电极间距约束的其他结构的发光二极管进行描述。In the following, light-emitting diodes of other structures that are also applicable to the above-mentioned lateral critical electrode spacing constraint will be described.
如图5和图6所示,根据本申请第二实施例的发光二极管为图1和2所示的垂直型发光二极管的一种变型。在本实施例中,发光二极管同 样包括与图1和图2所示的发光二极管类似的第一电极23、衬底21、反射镜28、金属键合层27、第一半导体层221、有源发光层222、第二半导体层223和第二电极24。本实施例与图1和图2所示的发光二极管的区别之处在于:As shown in FIGS. 5 and 6, the light emitting diode according to the second embodiment of the present application is a modification of the vertical light emitting diode shown in FIGS. 1 and 2. In this embodiment, the light-emitting diode also includes a first electrode 23, a substrate 21, a mirror 28, a metal bonding layer 27, a first semiconductor layer 221, and an active layer similar to the light-emitting diode shown in FIG. 1 and FIG. The light emitting layer 222, the second semiconductor layer 223, and the second electrode 24. The difference between this embodiment and the light-emitting diode shown in FIG. 1 and FIG. 2 is:
第一半导体层221、第二半导体层123和有源发光层122上设置有沟槽224,沟槽224将第一半导体层221、第二半导体层223和有源发光层222彼此间隔排布的台面结构(Mesa)225。台面结构225的侧壁以及台面结构225的外露区域内形成有绝缘层291和电流扩散层292。相邻的两个第二电极242分别设置在台面结构225两侧的沟槽224内,且通过电流扩散层292与第二半导体层223电连接。此时,如图6所示,由第一半导体层221、第二半导体层123和有源发光层122所形成的发光外延层的至少部分发光区域内的任意一发光点A'在衬底11上的投影与相邻的两个第二电极24在衬底21上的投影的最短间隔距离分别为L1'、L2'。两个最短间隔距离之和为L1'+L2'。The first semiconductor layer 221, the second semiconductor layer 123 and the active light emitting layer 122 are provided with trenches 224, and the trenches 224 arrange the first semiconductor layer 221, the second semiconductor layer 223 and the active light emitting layer 222 at intervals. Mesa structure (Mesa) 225. An insulating layer 291 and a current diffusion layer 292 are formed in the sidewall of the mesa structure 225 and the exposed area of the mesa structure 225. Two adjacent second electrodes 242 are respectively disposed in the trenches 224 on both sides of the mesa structure 225, and are electrically connected to the second semiconductor layer 223 through the current diffusion layer 292. At this time, as shown in FIG. 6, any light-emitting point A'in at least a part of the light-emitting region of the light-emitting epitaxial layer formed by the first semiconductor layer 221, the second semiconductor layer 123 and the active light-emitting layer 122 is on the substrate 11 The shortest distance between the projection on the upper surface and the projection of the two adjacent second electrodes 24 on the substrate 21 are respectively L1' and L2'. The sum of the two shortest separation distances is L1'+L2'.
进一步,如图7和图8所示,根据本申请第三实施例的发光二极管为图5和6所示的垂直型发光二极管的进一步变型。在本实施例中,发光二极管同样包括与图5和图6所示的发光二极管类似的第一电极33、衬底31、反射镜38、金属键合层37、第一半导体层321、有源发光层322、第二半导体层323和第二电极34。此外,第一半导体层321、有源发光层322、第二半导体层323同样通过沟槽324划分成彼此间隔的台面结构325,并在台面结构325的侧壁以及台面结构325的外露区域内形成有绝缘层391。本实施例与图5和图6所示的发光二极管的区别之处在于:Furthermore, as shown in FIGS. 7 and 8, the light emitting diode according to the third embodiment of the present application is a further modification of the vertical type light emitting diode shown in FIGS. 5 and 6. In this embodiment, the light-emitting diode also includes a first electrode 33, a substrate 31, a mirror 38, a metal bonding layer 37, a first semiconductor layer 321, and an active layer similar to the light-emitting diode shown in FIG. 5 and FIG. The light emitting layer 322, the second semiconductor layer 323, and the second electrode 34. In addition, the first semiconductor layer 321, the active light emitting layer 322, and the second semiconductor layer 323 are also divided into mesa structures 325 spaced from each other by the trenches 324, and are formed on the sidewalls of the mesa structures 325 and the exposed regions of the mesa structures 325 There is an insulating layer 391. The difference between this embodiment and the light emitting diode shown in FIG. 5 and FIG. 6 is:
第二电极34的一部分以主干电极343的形式设置于沟槽324内,第二电极34的另一部分以分支电极344的形式延伸至台面结构325的顶部,并与第二半导体层323接触并形成电连接。此时,如图8所示,由第一半导体层321、第二半导体层323和有源发光层322所形成的发光外延层的至少部分发光区域内的任意一发光点A”在衬底11上的投影与相邻的两个第二电极24在衬底21上的投影的最短间隔距离分别为L1”、L2'。两个最短间隔距离之和为L1”+L2”。A part of the second electrode 34 is disposed in the trench 324 in the form of a main electrode 343, and another part of the second electrode 34 is extended to the top of the mesa structure 325 in the form of a branch electrode 344, and is in contact with the second semiconductor layer 323 and formed Electric connection. At this time, as shown in FIG. 8, any light-emitting point A" in at least a part of the light-emitting region of the light-emitting epitaxial layer formed by the first semiconductor layer 321, the second semiconductor layer 323 and the active light-emitting layer 322 is on the substrate 11 The shortest distance between the projection on the upper surface and the projection of the two adjacent second electrodes 24 on the substrate 21 are respectively L1" and L2'. The sum of the two shortest separation distances is L1"+L2".
如图9和图10所示,根据本申请第四实施例的发光二极管为一种倒装发光二极管,包括衬底41、发光外延层42、第一电极43和第二电极44,第一电极43为面电极,第二电极44的数量为多个,且二者位于发光二极管的同一侧。发光外延层42进一步依次层叠设置于衬底41上的第一半导体层421、有源发光层422以及第二半导体层423。第一电极43设置于第二半导体层423远离衬底41的一侧,并与第二半导体层423电连接。在第一电极43与第二半导体层423之间进一步设置反射镜49,以反射有源发光层422所产生的光,进而从衬底41所在一侧进行 出光。第一电极43的表面设置有多个凹槽424,该凹槽424经反射镜49、第二半导体层423和有源发光层422延伸至第一半导体层421。该多个第二电极44分别设置于对应的凹槽424内,并与第一半导体层421电连接。在本实施例中,第一半导体层421为N型半导体层(例如N型GaN),对应的第二电极44也称为N型电极。第二半导体层423为P型半导体层(例如P型GaN),对应的第一电极43也称为P型电极。在其他实施例中,第一半导体层421和第二半导体层423可以是具有不同导电类型的其他任意适当材料的单层或多层结构。在本实施例中,发光外延层42的至少部分发光区域内的任意一发光点A”'在衬底41上的投影与相邻的两个第二电极44在衬底41上的投影的最短间隔距离分别为L1”'、L2”'。两个最短间隔距离之和L1”'+L2”'。As shown in FIGS. 9 and 10, the light-emitting diode according to the fourth embodiment of the present application is a flip-chip light-emitting diode, which includes a substrate 41, a light-emitting epitaxial layer 42, a first electrode 43 and a second electrode 44. The first electrode 43 is a surface electrode, the number of the second electrode 44 is multiple, and the two are located on the same side of the light emitting diode. The light-emitting epitaxial layer 42 further sequentially stacks a first semiconductor layer 421, an active light-emitting layer 422, and a second semiconductor layer 423 disposed on the substrate 41. The first electrode 43 is disposed on a side of the second semiconductor layer 423 away from the substrate 41 and is electrically connected to the second semiconductor layer 423. A mirror 49 is further provided between the first electrode 43 and the second semiconductor layer 423 to reflect the light generated by the active light-emitting layer 422, and then emit light from the side where the substrate 41 is located. The surface of the first electrode 43 is provided with a plurality of grooves 424, and the grooves 424 extend to the first semiconductor layer 421 via the mirror 49, the second semiconductor layer 423 and the active light emitting layer 422. The plurality of second electrodes 44 are respectively disposed in the corresponding grooves 424 and are electrically connected to the first semiconductor layer 421. In this embodiment, the first semiconductor layer 421 is an N-type semiconductor layer (for example, N-type GaN), and the corresponding second electrode 44 is also called an N-type electrode. The second semiconductor layer 423 is a P-type semiconductor layer (for example, P-type GaN), and the corresponding first electrode 43 is also referred to as a P-type electrode. In other embodiments, the first semiconductor layer 421 and the second semiconductor layer 423 may be a single-layer or multi-layer structure of any other suitable materials with different conductivity types. In this embodiment, the projection of any light-emitting point A"' in at least part of the light-emitting area of the light-emitting epitaxial layer 42 on the substrate 41 and the projection of the two adjacent second electrodes 44 on the substrate 41 are the shortest The separation distances are respectively L1”' and L2”'. The sum of the two shortest separation distances is L1”'+L2”'.
上述几种发光二极管结构以及其他类似结构的两个最短间隔距离之和L1'+L2'、L1”+L2”和L1”'+L2”'均受上述横向临界电极间距Lc。The sums of the two shortest separation distances L1'+L2', L1"+L2" and L1"'+L2"' of the above-mentioned several light-emitting diode structures and other similar structures are all affected by the above-mentioned lateral critical electrode spacing Lc.
需要注意的是,本申请第一实施例、第二实施例的第一电极和第二呈栅线状结构,在提高性能的同时,降低产线升级成本。而本申请第三实施例、第四实施例呈均匀的点状结构,能够改善横向电流扩散均匀性。It should be noted that the first electrode and the second electrode of the first embodiment and the second embodiment of the present application are in a grid-like structure, which improves performance while reducing production line upgrade costs. However, the third embodiment and the fourth embodiment of the present application have a uniform dot structure, which can improve the uniformity of lateral current spreading.
在其他实施例中,第一电极和第二电极的形状不限,可根据实际需要进行选择。第一电极、第二电极均由导电材料组成,其材料为铝、铜、钨、钼、金、钛、银、镍、钯或其任意组合,第一电极、第二电极至少为一层结构。其中,第一电极可以为P型电极,第二电极可以为N型电极;或者,第一电极可以为N型电极,第二电极可以为P型电极。In other embodiments, the shapes of the first electrode and the second electrode are not limited, and can be selected according to actual needs. Both the first electrode and the second electrode are composed of conductive materials, and the materials are aluminum, copper, tungsten, molybdenum, gold, titanium, silver, nickel, palladium or any combination thereof. The first electrode and the second electrode have at least one layer structure . Wherein, the first electrode may be a P-type electrode, and the second electrode may be an N-type electrode; or, the first electrode may be an N-type electrode, and the second electrode may be a P-type electrode.
形成于第一半导体层与第二半导体层之间的有源发光层可以根据电子空穴复合而发射具有一定能量的光,并且可具有量子阱和量子屏障交替叠加的多量子阱(MQW)结构。例如,有源发光层可具有通过注入三甲基镓气体(TMGa)、氨气(NH 3)、氮气(N 2)和三甲基铟气体(TMIn)等而形成的InGaN/GaN的多量子阱结构。同时,第一半导体层和第二半导体层以及有源发光层可通过利用本领域公知的半导体层生长工艺而形成,诸如有机金属化学气相沉淀(MOCVD)、分子束外延(MBE)、氢化物气相外延(HVPE)等。且具有由有源发光层材料的本征能带所确定的能量。 The active light-emitting layer formed between the first semiconductor layer and the second semiconductor layer can emit light with a certain energy according to the recombination of electrons and holes, and can have a multiple quantum well (MQW) structure in which quantum wells and quantum barriers are alternately superimposed . For example, the active light-emitting layer may have a multi-quantum InGaN/GaN formed by injecting trimethylgallium gas (TMGa), ammonia (NH 3 ), nitrogen (N 2 ), trimethyl indium gas (TMIn), etc. Well structure. At the same time, the first and second semiconductor layers and the active light-emitting layer can be formed by using semiconductor layer growth processes known in the art, such as metal organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), hydride vapor phase Epitaxy (HVPE) and so on. And has an energy determined by the intrinsic energy band of the active light-emitting layer material.
上文所提到的三族氮化物材料具体可包括GaN、Al x1Ga y1N、InGaN、Al x2In y2Ga z2N。其中Al的摩尔分数x1和x2分别小于10%。 The Group III nitride material mentioned above may specifically include GaN, Al x1 Ga y1 N, InGaN, Al x2 In y2 Ga z2 N. The mole fractions x1 and x2 of Al are respectively less than 10%.
以上仅为本申请的实施方式,并非因此限制本申请的专利范围,凡是利用本申请说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本申请的专利保护范围内。The above are only implementations of this application, and do not limit the scope of this application. Any equivalent structure or equivalent process transformation made using the content of the description and drawings of this application, or directly or indirectly applied to other related technical fields, The same reasoning is included in the scope of patent protection of this application.

Claims (20)

  1. 一种发光二极管,其中,所述发光二极管包括:A light emitting diode, wherein the light emitting diode includes:
    衬底;Substrate
    发光外延层,包括依次层叠设置于所述衬底上的第一半导体层、有源发光层以及第二半导体层;The light-emitting epitaxial layer includes a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer stacked on the substrate in sequence;
    第一电极和多个第二电极,所述第一电极与所述第一半导体层和第二半导体层中的一个电连接,所述多个第二电极与所述第一半导体层和第二半导体层中的另一个电连接;A first electrode and a plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are connected to the first semiconductor layer and the second semiconductor layer. Another electrical connection in the semiconductor layer;
    其中,所述第一电极为面电极,所述多个第二电极在所述衬底上的投影落在所述第一电极在所述衬底上的投影内部且彼此间隔设置,相邻的两个所述第二电极之间最短间隔距离不大于横向临界电极间距,所述横向临界电极间距是指确保所述发光二极管的工作电压随平均电流密度的变化曲线在所述平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时所述最短间隔距离之和的最大容许值,所述发光二极管工作于所述工作电流区段,且所述第一半导体层和所述第二半导体层均是采用基于三族氮化物体系的材料; Wherein, the first electrode is a surface electrode, and the projections of the plurality of second electrodes on the substrate fall within the projections of the first electrodes on the substrate and are spaced apart from each other. The shortest distance between the two second electrodes is not greater than the lateral critical electrode spacing. The lateral critical electrode spacing refers to ensuring that the operating voltage of the light-emitting diode varies with the average current density curve when the average current density is greater than 1A. /mm 2 when the dynamic slope in a certain working current section is not greater than 0.18Ω·mm 2 the maximum allowable value of the sum of the shortest separation distance, the light emitting diode works in the working current section, and the first Both the first semiconductor layer and the second semiconductor layer are made of materials based on the Group III nitride system;
    所述基于三族氮化物体系的材料包括GaN、Al x1Ga y1N、InGaN、Al x2In y2Ga z2N中的至少一种。 The group III nitride system-based material includes at least one of GaN, Al x1 Ga y1 N, InGaN, and Al x2 In y2 Ga z2 N.
  2. 一种发光二极管,其中,所述发光二极管包括:A light emitting diode, wherein the light emitting diode includes:
    衬底;Substrate
    发光外延层,包括依次层叠设置于所述衬底上的第一半导体层、有源发光层以及第二半导体层;The light-emitting epitaxial layer includes a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer stacked on the substrate in sequence;
    第一电极和多个第二电极,所述第一电极与所述第一半导体层和第二半导体层中的一个电连接,所述多个第二电极与所述第一半导体层和第二半导体层中的另一个电连接;A first electrode and a plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are connected to the first semiconductor layer and the second semiconductor layer. Another electrical connection in the semiconductor layer;
    其中,所述第一电极为面电极,所述多个第二电极在所述衬底上的投影落在所述第一电极在所述衬底上的投影内部且彼此间隔设置,所述发光外延层的至少部分发光区域内的任意一发光点在所述衬底上的投影与相邻的两个所述第二电极在所述衬底上的投影的最短间隔距离之和不大于横向临界电极间距,所述横向临界电极间距是指确保所述发光二极管的工作电压随平均电流密度的变化曲线在所述平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时所述最短间隔距离之和的最大容许值,所述发光二极管工作于所述工作电流区段,且所述第一半导体层和所述第二半导体层均是采用基于三族氮化物体系的材料。 Wherein, the first electrode is a surface electrode, the projections of the plurality of second electrodes on the substrate fall within the projections of the first electrodes on the substrate and are spaced apart from each other, and the light-emitting The sum of the shortest distance between the projection of any light-emitting point on the substrate and the projection of the two adjacent second electrodes on the substrate in at least part of the light-emitting area of the epitaxial layer is not greater than the lateral critical The electrode spacing, the horizontal critical electrode spacing refers to ensuring that the dynamic slope of the light-emitting diode operating voltage with the average current density variation curve in a certain operating current section where the average current density is greater than 1A/mm 2 is not greater than 0.18 Ω·mm 2 is the maximum allowable value of the sum of the shortest separation distance, the light-emitting diode works in the operating current section, and the first semiconductor layer and the second semiconductor layer are both based on three groups Nitride system materials.
  3. 根据权利要求2所述的发光二极管,其中,所述发光二极管在工作时的峰值波长介于365nm-400nm、400nm-440nm、440nm-480nm、480nm-540nm、540nm-560nm、560nm-600nm或600nm-700nm。The light-emitting diode according to claim 2, wherein the peak wavelength of the light-emitting diode during operation is between 365nm-400nm, 400nm-440nm, 440nm-480nm, 480nm-540nm, 540nm-560nm, 560nm-600nm, or 600nm- 700nm.
  4. 根据权利要求2所述的发光二极管,其中,所述横向临界电极间距是指确保所述工作电流区段内的动态斜率不大于0.15Ω·mm 2时所述最短间隔距离之和的最大容许值。 The light emitting diode according to claim 2, wherein the lateral critical electrode spacing refers to the maximum allowable value of the sum of the shortest separation distance when ensuring that the dynamic slope in the operating current section is not greater than 0.15Ω·mm 2 .
  5. 根据权利要求2所述的发光二极管,其中,所述横向临界电极间距是指确保所述工作电流区段内的动态斜率不大于0.1Ω·mm 2时所述最短间隔距离之和的最大容许值。 The light emitting diode according to claim 2, wherein the lateral critical electrode spacing refers to the maximum allowable value of the sum of the shortest separation distance when ensuring that the dynamic slope in the operating current section is not greater than 0.1Ω·mm 2 .
  6. 根据权利要求2所述的发光二极管,其中,所述横向临界电极间距是指确保所述工作电流区段内的动态斜率不大于0.06Ω·mm 2时所述最短间隔距离之和的最大容许值。 The light-emitting diode according to claim 2, wherein the lateral critical electrode spacing refers to the maximum allowable value of the sum of the shortest separation distance when ensuring that the dynamic slope in the operating current section is not greater than 0.06Ω·mm 2 .
  7. 根据权利要求2所述的发光二极管,其中,所述横向临界电极间距是指确保所述工作电流区段内的动态斜率不大于0.03Ω·mm 2时所述最短间隔距离之和的最大容许值。 The light emitting diode according to claim 2, wherein the lateral critical electrode spacing refers to the maximum allowable value of the sum of the shortest separation distance when ensuring that the dynamic slope in the operating current section is not greater than 0.03Ω·mm 2 .
  8. 根据权利要求2所述的发光二极管,其中,所述发光二极管为垂直发光二极管,所述第一电极位于所述第一半导体层远离所述有源发光层的一侧,所述第二电极位于所述第二半导体层远离所述有源发光层的一侧,或者所述第二半导体层和所述有源发光层上设置有沟槽,所述沟槽将所述第二半导体层和所述有源发光层划分成彼此间隔的至少两个台面结构,并暴露部分所述第一半导体层,所述第二电极至少部分设置于所述沟槽内并通过分支电极或电流扩散层电连接至所述第二半导体层,所述多个第二电极在所述衬底上的投影与所述第一电极在所述衬底上的投影重叠。The light emitting diode of claim 2, wherein the light emitting diode is a vertical light emitting diode, the first electrode is located on a side of the first semiconductor layer away from the active light emitting layer, and the second electrode is located The second semiconductor layer is far away from the active light-emitting layer, or the second semiconductor layer and the active light-emitting layer are provided with grooves, and the grooves connect the second semiconductor layer and the active light-emitting layer. The active light-emitting layer is divided into at least two mesa structures spaced apart from each other, and a part of the first semiconductor layer is exposed, and the second electrode is at least partially disposed in the trench and electrically connected by a branch electrode or a current diffusion layer To the second semiconductor layer, the projections of the plurality of second electrodes on the substrate overlap with the projections of the first electrodes on the substrate.
  9. 根据权利要求2所述的发光二极管,其中,所述发光二极管为倒装发光二极管,所述第一电极设置于所述第二半导体层远离所述衬底的一侧,所述第一电极上设置有延伸至所述第一半导体层的多个凹槽,所述多个第二电极设置于对应的所述凹槽内并电连接至所述第二半导体层,所述多个第二电极在所述衬底上的投影落在所述凹槽在所述衬底上的投影的内部。The light-emitting diode according to claim 2, wherein the light-emitting diode is a flip-chip light-emitting diode, the first electrode is disposed on a side of the second semiconductor layer away from the substrate, and the first electrode is A plurality of grooves extending to the first semiconductor layer are provided, the plurality of second electrodes are arranged in the corresponding grooves and are electrically connected to the second semiconductor layer, the plurality of second electrodes The projection on the substrate falls inside the projection of the groove on the substrate.
  10. 根据权利要求2所述的发光二极管,其中,所述发光外延层上的所有所述至少部分发光区域的集合与所述发光外延层上的全部发光区域的面积比不小于50%。3. The light emitting diode according to claim 2, wherein the area ratio of the set of all the at least part of the light emitting regions on the light emitting epitaxial layer to all the light emitting regions on the light emitting epitaxial layer is not less than 50%.
  11. 根据权利要求2所述的发光二极管,其中,所述发光外延层上的所有所述至少部分发光区域的集合与所述发光外延层上的全部发光区域的面积比不小于60%。3. The light emitting diode according to claim 2, wherein the area ratio of the set of all the at least part of the light emitting regions on the light emitting epitaxial layer to all the light emitting regions on the light emitting epitaxial layer is not less than 60%.
  12. 根据权利要求2所述的发光二极管,其中,所述发光外延层上的所有所述至少部分发光区域的集合与所述发光外延层上的全部发光区域的面积比不小于70%。3. The light emitting diode according to claim 2, wherein the area ratio of the collection of all the at least part of the light emitting regions on the light emitting epitaxial layer to all the light emitting regions on the light emitting epitaxial layer is not less than 70%.
  13. 根据权利要求2所述的发光二极管,其中,所述发光外延层上的所有所述至少部分发光区域的集合与所述发光外延层上的全部发光区 域的面积比不小于80%。The light-emitting diode according to claim 2, wherein the area ratio of the collection of all the at least part of the light-emitting regions on the light-emitting epitaxial layer to the total light-emitting regions on the light-emitting epitaxial layer is not less than 80%.
  14. 根据权利要求2所述的发光二极管,其中,所述发光外延层上的所有所述至少部分发光区域的集合与所述发光外延层上的全部发光区域的面积比不小于90%。3. The light emitting diode according to claim 2, wherein the area ratio of the collection of all the at least part of the light emitting regions on the light emitting epitaxial layer to all the light emitting regions on the light emitting epitaxial layer is not less than 90%.
  15. 根据权利要求2所述的发光二极管,其中,所述发光二极管工作时的所述平均电流密度不小于1A/mm 2The light emitting diode according to claim 2, wherein the average current density when the light emitting diode is in operation is not less than 1 A/mm 2 .
  16. 根据权利要求2所述的发光二极管,其中,所述发光二极管工作时的所述平均电流密度不小于2A/mm 2The light emitting diode according to claim 2, wherein the average current density when the light emitting diode is in operation is not less than 2A/mm 2 .
  17. 根据权利要求2所述的发光二极管,其中,所述发光二极管工作时的所述平均电流密度不小于5A/mm 2The light emitting diode according to claim 2, wherein the average current density when the light emitting diode is in operation is not less than 5A/mm 2 .
  18. 根据权利要求2所述的发光二极管,其中,所述发光二极管工作时的所述平均电流密度不小于10A/mm 2The light emitting diode according to claim 2, wherein the average current density when the light emitting diode is in operation is not less than 10 A/mm 2 .
  19. 根据权利要求2所述的发光二极管,其中,所述发光二极管工作时的所述平均电流密度不小于20A/mm 2The light emitting diode according to claim 2, wherein the average current density when the light emitting diode is in operation is not less than 20 A/mm 2 .
  20. 一种发光二极管,其中,所述发光二极管包括:A light emitting diode, wherein the light emitting diode includes:
    衬底;Substrate
    发光外延层,包括依次层叠设置于所述衬底上的第一半导体层、有源发光层以及第二半导体层;The light-emitting epitaxial layer includes a first semiconductor layer, an active light-emitting layer, and a second semiconductor layer stacked on the substrate in sequence;
    第一电极和多个第二电极,所述第一电极与所述第一半导体层和第二半导体层中的一个电连接,所述多个第二电极与所述第一半导体层和第二半导体层中的另一个电连接;A first electrode and a plurality of second electrodes, the first electrode is electrically connected to one of the first semiconductor layer and the second semiconductor layer, and the plurality of second electrodes are connected to the first semiconductor layer and the second semiconductor layer. Another electrical connection in the semiconductor layer;
    其中,所述第一电极为面电极,所述多个第二电极在所述衬底上的投影落在所述第一电极在所述衬底上的投影内部且彼此间隔设置,相邻的两个所述第二电极之间最短间隔距离不大于横向临界电极间距,所述横向临界电极间距是指确保所述发光二极管的工作电压随平均电流密度的变化曲线在所述平均电流密度大于1A/mm 2的一定工作电流区段内的动态斜率不大于0.18Ω·mm 2时所述最短间隔距离之和的最大容许值,所述发光二极管工作于所述工作电流区段,且所述第一半导体层和所述第二半导体层均是采用基于三族氮化物体系的材料。 Wherein, the first electrode is a surface electrode, and the projections of the plurality of second electrodes on the substrate fall within the projections of the first electrodes on the substrate and are spaced apart from each other. The shortest distance between the two second electrodes is not greater than the lateral critical electrode spacing. The lateral critical electrode spacing refers to ensuring that the operating voltage of the light-emitting diode varies with the average current density curve when the average current density is greater than 1A. /mm 2 when the dynamic slope in a certain working current section is not greater than 0.18Ω·mm 2 the maximum allowable value of the sum of the shortest separation distance, the light emitting diode works in the working current section, and the first Both the first semiconductor layer and the second semiconductor layer are made of materials based on the Group III nitride system.
PCT/CN2020/136033 2019-12-13 2020-12-14 Light-emitting diode WO2021115470A1 (en)

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