WO2021083358A8 - 用于制备烯烃-极性单体共聚物的方法 - Google Patents

用于制备烯烃-极性单体共聚物的方法 Download PDF

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Publication number
WO2021083358A8
WO2021083358A8 PCT/CN2020/125433 CN2020125433W WO2021083358A8 WO 2021083358 A8 WO2021083358 A8 WO 2021083358A8 CN 2020125433 W CN2020125433 W CN 2020125433W WO 2021083358 A8 WO2021083358 A8 WO 2021083358A8
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WO
WIPO (PCT)
Prior art keywords
olefin
polar monomer
monomer copolymer
preparing
preparing olefin
Prior art date
Application number
PCT/CN2020/125433
Other languages
English (en)
French (fr)
Other versions
WO2021083358A1 (zh
Inventor
高榕
赖菁菁
郭子芳
苟清强
周俊领
宋文波
李昕阳
张晓帆
林洁
刘东兵
张军辉
王洪涛
张师军
顾元宁
安京燕
赵慧
黄廷杰
马冬
王如恩
徐世媛
傅捷
Original Assignee
中国石油化工股份有限公司
中国石油化工股份有限公司北京化工研究院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201911049580.2A external-priority patent/CN112745425B/zh
Priority claimed from CN201911049604.4A external-priority patent/CN112745428B/zh
Priority claimed from CN201911049602.5A external-priority patent/CN112745426B/zh
Priority claimed from CN201911049603.XA external-priority patent/CN112745427B/zh
Priority claimed from CN201911049567.7A external-priority patent/CN112745424B/zh
Priority claimed from CN201911049566.2A external-priority patent/CN112745423B/zh
Priority claimed from CN201911049741.8A external-priority patent/CN112745429B/zh
Priority claimed from CN201911049900.4A external-priority patent/CN112745430B/zh
Priority to US17/755,542 priority Critical patent/US20220396646A1/en
Priority to CA3159659A priority patent/CA3159659A1/en
Priority to EP20880543.2A priority patent/EP4053174A4/en
Application filed by 中国石油化工股份有限公司, 中国石油化工股份有限公司北京化工研究院 filed Critical 中国石油化工股份有限公司
Priority to JP2022525809A priority patent/JP2023500504A/ja
Priority to BR112022008300A priority patent/BR112022008300A2/pt
Priority to KR1020227018606A priority patent/KR20220097939A/ko
Publication of WO2021083358A1 publication Critical patent/WO2021083358A1/zh
Publication of WO2021083358A8 publication Critical patent/WO2021083358A8/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7095—Cobalt, nickel or compounds thereof
    • C08F4/7098—Nickel or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F216/04—Acyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C08F220/64—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Abstract

一种用于制备烯烃-烯烃醇共聚物的方法及由所述方法制备的烯烃-烯烃醇共聚物。所述用于制备烯烃-烯烃醇共聚物的方法中使用的催化剂包含式I所示的二亚胺金属配合物。根据制备方法的优选实施方式制得的球形和/或类球形聚合物在工业应用中具有良好的前景。
PCT/CN2020/125433 2019-10-31 2020-10-30 用于制备烯烃-极性单体共聚物的方法 WO2021083358A1 (zh)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020227018606A KR20220097939A (ko) 2019-10-31 2020-10-30 올레핀-극성 단량체 공중합체의 제조 방법
BR112022008300A BR112022008300A2 (pt) 2019-10-31 2020-10-30 Método para preparar um copolímero de monômero de olefina polar e copolímero de monômero de olefina polar
JP2022525809A JP2023500504A (ja) 2019-10-31 2020-10-30 オレフィン－極性モノマーコポリマーの調製方法
US17/755,542 US20220396646A1 (en) 2019-10-31 2020-10-30 Method for preparing olefin-polar monomer copolymer
EP20880543.2A EP4053174A4 (en) 2019-10-31 2020-10-30 METHOD FOR PRODUCING POLAR OLEFIN MONOMER COPOLYMERS
CA3159659A CA3159659A1 (en) 2019-10-31 2020-10-30 Method for preparing olefin-polar monomer copolymer

Applications Claiming Priority (16)

Application Number Priority Date Filing Date Title
CN201911049604.4 2019-10-31
CN201911049580.2 2019-10-31
CN201911049580.2A CN112745425B (zh) 2019-10-31 2019-10-31 用于制备烯烃-烯烃醇共聚物的方法
CN201911049900.4A CN112745430B (zh) 2019-10-31 2019-10-31 烯烃-不饱和羧酸共聚物的制备方法
CN201911049741.8A CN112745429B (zh) 2019-10-31 2019-10-31 用于制备烯烃-不饱和羧酸共聚物的方法
CN201911049602.5 2019-10-31
CN201911049566.2A CN112745423B (zh) 2019-10-31 2019-10-31 一种烯烃-不饱和羧酸共聚物的制备方法、烯烃-不饱和羧酸共聚物及其应用
CN201911049900.4 2019-10-31
CN201911049567.7A CN112745424B (zh) 2019-10-31 2019-10-31 一种用于制备烯烃-不饱和羧酸共聚物的方法
CN201911049567.7 2019-10-31
CN201911049741.8 2019-10-31
CN201911049603.X 2019-10-31
CN201911049603.XA CN112745427B (zh) 2019-10-31 2019-10-31 一种用于制备烯烃-烯烃醇共聚物的方法
CN201911049566.2 2019-10-31
CN201911049602.5A CN112745426B (zh) 2019-10-31 2019-10-31 用于制备烯烃-烯烃醇共聚物的方法
CN201911049604.4A CN112745428B (zh) 2019-10-31 2019-10-31 一种烯烃-烯烃醇共聚物的制备方法

Publications (2)

Publication Number Publication Date
WO2021083358A1 WO2021083358A1 (zh) 2021-05-06
WO2021083358A8 true WO2021083358A8 (zh) 2022-05-27

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PCT/CN2020/125433 WO2021083358A1 (zh) 2019-10-31 2020-10-30 用于制备烯烃-极性单体共聚物的方法

Country Status (7)

Country Link
US (1) US20220396646A1 (zh)
EP (1) EP4053174A4 (zh)
JP (1) JP2023500504A (zh)
KR (1) KR20220097939A (zh)
BR (1) BR112022008300A2 (zh)
CA (1) CA3159659A1 (zh)
WO (1) WO2021083358A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4053138A4 (en) * 2019-10-31 2023-11-15 China Petroleum & Chemical Corporation AMINO-IMINE METAL COMPLEX AS WELL AS ITS PREPARATION PROCESS AND ITS APPLICATION
CA3159655A1 (en) * 2019-10-31 2021-05-06 China Petroleum & Chemical Corporation Diimine metal complex, preparation method therefor, and application thereof
WO2022227933A1 (zh) * 2021-04-28 2022-11-03 中国石油化工股份有限公司 一种聚合物的制备方法及所得到的聚合物

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6403738B1 (en) * 1998-07-29 2002-06-11 E. I. Du Pont De Nemours And Company Polymerization of olefins
CN106397264B (zh) 2015-07-31 2018-07-20 中国石油化工股份有限公司 一种二亚胺配体化合物、配合物及应用
CN106397259B (zh) * 2015-07-31 2018-07-20 中国石油化工股份有限公司 一种二亚胺配体、二亚胺镍配合物及应用
US20180105478A1 (en) * 2016-10-19 2018-04-19 Chevron Phillips Chemical Company Lp Process for Reducing the Light Oligomer Content of Polypropylene Oils
CN109694436A (zh) * 2017-10-24 2019-04-30 中国石油化工股份有限公司 一种烯烃-烯烃醇聚合物及其制备方法
CN109694435A (zh) * 2017-10-24 2019-04-30 中国石油化工股份有限公司 一种烯烃-不饱和羧酸聚合物及其制备方法

Also Published As

Publication number Publication date
BR112022008300A2 (pt) 2022-08-09
CA3159659A1 (en) 2021-05-06
EP4053174A4 (en) 2023-11-15
EP4053174A1 (en) 2022-09-07
JP2023500504A (ja) 2023-01-06
KR20220097939A (ko) 2022-07-08
US20220396646A1 (en) 2022-12-15
WO2021083358A1 (zh) 2021-05-06

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