WO2021083245A1 - 包含n-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用 - Google Patents

包含n-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用 Download PDF

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WO2021083245A1
WO2021083245A1 PCT/CN2020/124587 CN2020124587W WO2021083245A1 WO 2021083245 A1 WO2021083245 A1 WO 2021083245A1 CN 2020124587 W CN2020124587 W CN 2020124587W WO 2021083245 A1 WO2021083245 A1 WO 2021083245A1
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methyl
evaluation
mixed
actual control
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PCT/CN2020/124587
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French (fr)
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彭学岗
张景远
赵德
崔琦
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江苏清原农冠杂草防治有限公司
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Priority to JP2022520325A priority Critical patent/JP7551743B2/ja
Publication of WO2021083245A1 publication Critical patent/WO2021083245A1/zh

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
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    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
    • A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
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Definitions

  • the invention belongs to the field of pesticides, and specifically relates to a herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylformamide compounds and applications thereof.
  • Chemical weed control is the most economical and effective method for the control of weeds in farmland.
  • long-term continuous high-dose use of chemical herbicides of a single species or a single mode of action is likely to cause problems such as weed resistance and resistance evolution.
  • Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems.
  • the patent CN103596946A discloses N-(1,3,4-oxadiazol-2-yl) arylformamide and its use as a herbicide, but the production still needs to develop high safety, broad herbicidal spectrum, and A variety of herbicidal compositions that produce synergistic effects and solve the problem of resistant weeds.
  • the present invention provides a herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylformamide compounds and applications thereof.
  • the composition can effectively prevent and control cyperaceae weeds such as special-shaped sedge, cardamine sedge, firefly, barnyardgrass, crabgrass, barnyardgrass, stephengrass and other gramineous weeds in crop fields, as well as duck's diffusa and wild grass.
  • the problem of broad-leaved weeds such as Cigu, Polygonum syringae and Alisma orientalis has the characteristics of expanding the weed-killing spectrum, reducing the amount of application, being able to produce synergistic effects and solving resistant weeds.
  • a herbicidal composition containing an N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compound comprising a herbicidal effective amount of active ingredient A and active ingredient B, wherein,
  • Active ingredient A is Or its salt
  • the active ingredient B is selected from one or more of the following compounds and their salts/esters:
  • HPPD inhibitors sulcotrione (CAS number: 99105-77-8), mesotrione (CAS number: 104206-82-8), mesotrione (CAS number: 210631-68-8) , Cyclosulfone (CAS number: 335104-84-2), fluopyron (CAS number: 352010-68-5), fursotrione (CAS number: 473278-76-1), bicyclic sulcotrione (CAS number: 473278-76-1) CAS number: 156963-66-5), fentrazone (CAS number: 1622908-18-2), ciclopyr (CAS number: 1855929-45-1), trifentrazone (CAS number: 1911613-97-2), flufentrazone (CAS number: 1992017-55-6), sulfenylpyrazole (CAS number: 365400-11-9), pyrazolide (CAS number: 58011-68- 0), metazotrione (CAS number: 82692-44-2), tolpyralate (
  • PDS inhibitors flurochloridone (CAS number: 61213-25-0), fluridone (CAS number: 96525-23-4), diflufenican (CAS number: 83164-33-4) ), fluroxyfen (CAS number: 137641-05-5), fluroxypyr (CAS number: 1131614-08-7), fluroxypyr (CAS number: 27314-13-2), fluroxypyr Oxalidone (CAS number: 59756-60-4);
  • DOXP inhibitors clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);
  • ALS inhibitors tribensulfuron-methyl (CAS number: 101200-48-0), thifensulfuron-methyl (CAS number: 79277-27-3), bensulfuron-methyl (CAS number: 83055-99-6), Pyrimsulfuron (CAS No.: 93697-74-6), Thioxasulfuron (CAS No.: 317815-83-1), Chlorpyrisulfuron (CAS No.
  • ACCase inhibitors clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8), clethodim (CAS number: 99129-21-2), Enoxypyr (CAS number: 74051-80-2), quizalofop-ethyl (CAS number: 100646-51-3), oximetrazone (CAS number: 87820-88-0), difluoxyfop (CAS No. 69806-50-4), High-efficiency fluroxypyr (CAS No. 72619-32-0), Promethalin (CAS No.
  • PPO inhibitors oxyfluorfen (CAS number: 42874-03-3), fomesafen (CAS number: 72178-02-0), oxadiazon (CAS number: 19666-30-9) ), Oxachlor (CAS Number: 39807-15-3), Sulfentrazone (CAS Number: 122836-35-5), Pafentrazone (CAS Number: 158353-15-2), Propyne Flumetsulam (CAS number: 103361-09-7), cyclopentoxazone (CAS number: 110956-75-7), tiafenacil (CAS number: 1220411-29-9), saflufenacil (CAS number) :372137-35-4), Metazachlor (CAS Number: 129630-19-9), Carfentrazone (CAS Number: 128639-02-1), Fluprofen-ethyl (CAS Number: 134605-64-4) ), acifluorfen ethyl (CAS number: 131086-42-5), acifluorfen (CAS number:
  • PSII inhibitors atrazine (CAS number: 1912-24-9), promethoxin (CAS number: 7287-19-6), xicaojing (CAS number: 1014-70-6), special Dingjin (CAS Number: 5915-41-3), Terbutryn (CAS Number: 886-50-0), Atmidine (CAS Number: 834-12-8), Isopropion (CAS Number: 4147- 51-7), Caojing (CAS Number: 845-52-3), Dicaojing (CAS Number: 1014-69-3), Simazin (CAS Number: 122-34-9), Trimethoprim (CAS number: 21087-64-9), ethazine (CAS number: 64529-56-2), amicarbazone (CAS number: 129909-90-6), fentrazone (CAS number: 41394) -05-2), cyanuron (CAS number: 21725-46-2), chlorotoluron (CAS number: 15545-48-9), isoproturon (CAS number: 34123-59-6),
  • Inhibitors of microtubule assembly trifluralin (CAS number: 1582-09-8), tributaline (CAS number: 33629-47-9), pendimethalin (CAS number: 40487-42-1) ), fluthiopyr (CAS number: 97886-45-8), buteneflurane (CAS number: 55283-68-6), metsulfalin (CAS number: 19044-88-3), fluroxypyr (CAS number: 19044-88-3) Amine (CAS number: 1861-40-1), dimethoprim (CAS number: 117718-60-2), nacorte (CAS number: 23950-58-5), diquat (CAS number: 1861-32) -1), Isophos (CAS number: 36335-67-8);
  • Microtubule combination inhibitor fenacet (CAS number: 16118-49-3);
  • VLCFA inhibitors acetochlor (CAS number: 34256-82-1), butachlor (CAS number: 23184-66-9), pretilachlor (CAS number: 51218-49-6), iso Metolachlor (CAS Number: 51218-45-2), Mefenacet (CAS Number: 73250-68-7), Refined Metolachlor (CAS Number: 87392-12-9), Flufenacet Metrachlor (CAS number: 142459-58-3), napachlor (CAS number: 15299-99-7), sulfonepyridin (CAS number: 447399-55-5), saraphos (CAS number: 64249) -01-0), Xylenfenacet (CAS Number: 87674-68-8), Tetrafenacet (CAS Number: 158237-07-1), Trifenacet (CAS Number: 212201-70) -2), carfentrazone (CAS number: 125306-83-4), mesofen (CAS number: 24151-93-7), prop
  • Inhibitors of lipid synthesis (non-acetyl-CoA carboxylase): Promethazine (CAS No. 52888-80-9), He Caodi (CAS No. 2212-67-1), He Caodi (CAS No. 2212-67-1) CAS number: 28249-77-6), furfural yellow (CAS number: 68505-69-1), ethoxyfuralox yellow (CAS number: 26225-79-6), wild dicamba (CAS number: 2303-17- 5), Mie Caodi (CAS No.: 1929-77-7), Butachlor (CAS No.: 2008-41-5), Huan Caodi (CAS No.: 1134-23-2), Diachlor (CAS No.: 1134-23-2) No. 61432-55-1), Pencaodan (CAS No. 85785-20-2);
  • EPSPS inhibitors glyphosate (CAS number: 1071-83-6), glufosinate (CAS number: 81591-81-3);
  • GS inhibitors glufosinate-ammonium (CAS number: 77182-82-2), bialaphos (CAS number: 35597-43-4), glufosinate-ammonium (CAS number: 73777-50-1) ;
  • PSI inhibitors Paraquat (CAS Number: 1910-42-5), Diquat (CAS Number: 6385-62-2);
  • DHP inhibitor sulfentrazone (CAS number: 3337-71-1);
  • Inhibitors of cellulose synthesis triazine (CAS number: 131475-57-5), indanazine (CAS number: 950782-86-2);
  • herbicides oxazimone (CAS number: 153197-14-9), cyprofen (CAS number: 87818-31-3), indoxazone (CAS number: 133220-30-1) , Quinclofen (CAS number: 1350901-36-8), quinturone (CAS number: 1639426-14-4), probenuron (CAS number: 99485-76-4), meturon (CAS number: 1639426-14-4) No.: 150-68-5), tetflupyrolimet (CAS No.: 2053901-33-8).
  • the abbreviated form of the common name of the active compound all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, especially One or more commercially available forms.
  • the generic name indicates an ester or salt, it also includes all other conventional derivatives in each case, such as other esters and salts, free acids and neutral compounds, as well as isomers, especially optical isomers, especially Is one or more commercially available forms.
  • the chemical name of the given compound indicates at least one compound covered by the generic name, and is usually the preferred compound.
  • the weight ratio of A and B is 1:600-200:1 and 1:500-100:1; preferably 1:300-80:1 and 1:200-60:1; more preferably 1:150- 50:1 and 1:120-30:1; more preferably 1:100-20:1 and 1:80-15:1; even more preferably 1:50-10:1, 1:30-5:1 , 1:10 ⁇ 4:1 and 1:5 ⁇ 1:1.
  • the present invention also lists the following specific combinations of component A and component B:
  • component A in the above table is replaced with the corresponding salt.
  • the salt of the compound is preferably in the form of the respective alkali metal salt, alkaline earth metal salt or ammonium salt (such as dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc.), preferably each
  • the form of the alkali metal salt of is more preferably the form of the respective sodium salt or potassium salt, and most preferably the form of the respective sodium salt.
  • the mass percentage of A and B in the herbicidal composition accounts for 1-95%, preferably 10-80% of the total.
  • the herbicidal composition also contains conventional adjuvants, and the conventional adjuvants include carriers and surfactants.
  • carrier refers to an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient.
  • the carrier is generally inert and must be agriculturally acceptable, especially acceptable to the plants being treated.
  • the carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon, liquefied gas, etc.
  • the surfactant may include an emulsifier, dispersant or wetting agent, and it may be ionic or non-ionic. Examples that may be mentioned are the salts of polyacrylic acid, lignosulfonate, phenolsulfonic acid or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (in particular Alkylphenol or arylphenol) polymers, sulfosuccinates, taurine derivatives (especially taurine alkane esters) and alcohol phosphate esters or polyhydroxyethylated phenol phosphate esters, Alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl, heptadecyl and stearyl alcohols and sulf
  • composition may also contain various other components, such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants and polymers.
  • composition of the present invention can be mixed with the following active substances, such as "Encyclopedia of World Pesticide New Variety Technologies", China Agricultural Science and Technology Press, 2010.9 and known substances in the literature cited here.
  • the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, and the code when appropriate): acetochlor, butachlor, Alachlor, Propolachlor, Metolachlor, Refined Metolachlor, Pretilachlor, Tetrachlor, Metochlor, Napropionate, R-Naphtochlor, Propanochlor , Mefenacet, difenacet, diflufenican, chlorfenazone, flubutazone, bromobutyrazamide, dimethenamid, high-efficiency dimethenamid, ethoxylate Apifenacet, flufenacet, metolachlor, metazachlor,
  • the herbicidal composition further includes at least one safener selected from:
  • Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl Ethyl-2-pyrazoline-3-carboxylate (S1-1, mefenpyr-diethyl, PM, p. 594-595), and described in, for example, WO91/07874 and PM (p. 594-595) 594-595 pages) related compounds.
  • Dichlorophenylpyrazole carboxylic acid derivatives the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-Dichlorophenyl)-5-(1 ,1-Dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4), 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • Triazole carboxylic acid (S1) compounds the preferred compound is, for example, fenchlorazole, namely 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1 , 2,4-Triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
  • 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid compound preferably
  • the compound is, for example, 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid Ethyl acid (S1-8) and related compounds described in WO91/08202, or 5,5-diphenyl-2-isoxazoline described in patent application (WO-A-95/07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline
  • S2 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (pages 195-196), (1,3-dimethylbut-1-yl)(5-chloro-8-quinolinoxy)acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy) Yl) acetate (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5), (5-chloro-8-quinolinoxy) methyl acetate (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2-(2-propylene iminooxy)-1-ethyl (5-chloro-8-
  • 5-Chloro-8-quinolinyloxy)malonic acid compounds preferred compounds are, for example, (5-chloro-8-quinolinyloxy)diethyl malonate, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy)-malonate methyl ethyl ester and related compounds described in EP-A-0582198.
  • Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acid active compounds such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
  • the safener is preferably dibenzoxazole acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolone (CAS: 135590-91-9), detox quinine (CAS : 99607-70-2), one or more of gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
  • composition of the present invention can be diluted or used directly by the user before use.
  • the formulation can be prepared by the usual processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, then adding one or more of surfactants such as dispersing agents, stabilizers, wetting agents, adhesives, defoamers, etc. kind.
  • the specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules (dry suspensions), water emulsions, and microemulsions.
  • the composition of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations.
  • the amount of effective ingredients used is also different.
  • the external conditions are, for example, temperature, humidity, and the nature of the herbicide used. It can have a large variation range, for example, between 0.001 and 1.0 kg/ha, or more active substances, but preferably between 0.005 and 750 g/ha, especially between 0.005 and 500 g/ha.
  • the present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling unwanted plant growth, which comprises applying the herbicidal composition to plants, plant parts, plant seeds or The area where the plant grows.
  • composition of the present invention can be applied to the leaves of plants to be treated by spraying, that is, applied to weeds, especially on the surfaces that are infested or easily affected by weeds.
  • the herbicidal composition of the present invention When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities of a single herbicide and the activity of a single herbicide.
  • the synergistic effect is manifested by reduced application rate, wider weed control spectrum, faster and more lasting weeding action, these characteristics are required in the process of weed control practice.
  • these new compositions are significantly superior to existing herbicides, achieve reduced usage, and are more environmentally friendly.
  • composition of the present invention is environmentally friendly and is easily degraded in the environment.
  • the herbicidal composition of the present invention has low cost and convenient use, and its popularization and application have huge economic and social benefits.
  • A1+Mesotrione (4+1: represents 4%A1+1%Mesotrione, the same below) dispersible oil suspension concentrate
  • polycarboxylate 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+1% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
  • the above-mentioned water suspension agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned water suspension agent processing process put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally cut uniformly in the shearing machine, and transfer to the storage after the test is qualified. Can filling.
  • dispersible oil suspension agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned dispersible oil suspension agent processing process put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally shear evenly in the shearing machine. After the test is qualified, transfer To the storage tank for filling.
  • Special-shaped sedges are collected from Jingzhou, Hubei, Cardamine sedges are collected from Shangrao, Jiangxi, Coatgrass is collected from Changsha, Hunan, Barnyardgrass is collected from Fuyuan, Heilongjiang, Ye Cigu is collected from Yingkou, Liaoning, Firefly is collected from Hulin, Heilongjiang, Polygonum cloves It was collected from Changsha, Hunan, Matang was collected from Tianchang, Anhui, and Alisma orientale was collected from Shenyang, Liaoning.
  • the above-mentioned weeds are cultivated in pots. They are placed in an enamel dish in a 180 ⁇ 140mm plastic nutrient bowl.
  • the top soil (4/5) collected from the farmland is air-dried and sieved.
  • the soil moisture is controlled at 20% at the initial stage.
  • 3WP-2000 walking spray tower Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
  • the required active ingredient B includes fentrazone, cifentrazone, flufentrazone, trifentrazone, It is produced by the company, and the others are purchased by the reagent company.
  • the original medicines all use acetone as the solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and are now diluted.
  • the action characteristics and toxicity of the two drugs should be measured, and the main purpose of the formulation should also be considered.
  • the single and mixed dosages of A and B active ingredients are shown in the table respectively. Use water without medicament and with the same solvent and emulsifier as a blank control.
  • Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown in each pot, and a total of 60 plants per treatment.
  • the whole seedlings of the living weeds were cut along the soil surface with a blade, and the fresh weight of the weeds was weighed with an analytical balance. For weeds that have died, the fresh weight is zero.
  • E-E0 value greater than 10% is synergistic effect, less than -10% is antagonistic effect, and between -10% and 10% is additive effect.
  • X is the fresh weight inhibition rate when the amount of active ingredient A is P
  • Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
  • Table 1-223 The statistical results are shown in Table 1-223 below.
  • Table 200 The actual control effect and joint effect evaluation of A2 potassium salt mixed with sarranosin on fire rush
  • Table 207 The actual control effect and combined effect evaluation of A2 blended oxaprop-p-ethyl on crabgrass
  • the herbicidal compositions prepared in Examples 1-68 were used for field weed effect tests. In 2017, a demonstration test was carried out at the Poyang test site in Jiangxi.
  • the main weeds that occur in the field are: barnyardgrass, stephanotis, duck tongue, heteromorphic sedge, and Polygonum lilac.
  • Test method Stem and leaf treatment-when the weeds are in the 2-3 leaf stage, use a manual sprayer, with a water volume of 30 kg/667m 2 , and spray evenly with stem and leaf spray.
  • the specific test agents and dosages are shown in Table 224.
  • the plot area is 20 square meters and each treatment is repeated 3 times. See Table 224 for the investigation of the control effect 20 days after application.
  • the present invention unexpectedly found that the composition is used for the prevention and control of special-shaped sedge, cardamine sedge, duck tongue, rice barnyard, wild sedge, firefly, polygonum lilac, crabgrass, Alisma, Weeds such as barnyardgrass and stephanotis have surprising and unexpected synergistic effects.
  • This synergistic effect is more pronounced at low doses, which can reduce the amount of medicine used, reduce environmental pollution, and reasonably recover
  • the formulation reduces agricultural costs, is highly effective against ALS and ACCase inhibitor-resistant weeds, and has a good application prospect.

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Abstract

一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用。所述组合物包括除草有效量的活性成分A和活性成分B，其中，活性成分A为 A1、A2或其盐；活性成分B选自以下化合物及其盐/酯中的一种或多种：HPPD抑制剂、PDS抑制剂、DOXP抑制剂、ALS抑制剂、ACCase抑制剂、PPO抑制剂、PSII抑制剂、微管组装抑制剂等。该组合物能有效防除作物田中的异型莎草、碎米莎草、萤蔺等莎草科杂草，稻稗、马唐、稗草、千金子等禾本科杂草，以及鸭舌草、野慈姑、丁香蓼、泽泻等阔叶杂草问题，具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。

Description

包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用 技术领域
本发明属于农药领域，具体涉及一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用。
背景技术
化学除草是农田杂草防除中最为经济、有效的手段，但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂，容易造成杂草耐药和抗性演化等问题。除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点，是解决上述问题的最为有效的方法之一。如专利CN103596946A公开了N-(1,3,4-噁二唑-2-基)芳基甲酰胺及其作为除草剂的用途，而生产上仍需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。
发明内容
为解决现有技术中存在的上述问题，本发明提供一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用。该组合物能有效防除作物田中的异型莎草、碎米莎草、萤蔺等莎草科杂草，稻稗、马唐、稗草、千金子等禾本科杂草，以及鸭舌草、野慈姑、丁香蓼、泽泻等阔叶杂草问题，具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。
一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，包括除草有效量的活性成分A和活性成分B，其中，
活性成分A为
Figure PCTCN2020124587-appb-000001
或其盐；
活性成分B选自以下化合物及其盐/酯中的一种或多种：
(1)HPPD抑制剂：磺草酮(CAS号:99105-77-8)、硝磺草酮(CAS号:104206-82-8)、苯唑草酮(CAS号:210631-68-8)、环磺酮(CAS号:335104-84-2)、氟吡草酮(CAS号:352010-68-5)、呋喃磺草酮(CAS号:473278-76-1)、双环磺草酮(CAS号:156963-66-5)、双唑草酮(CAS号:1622908-18-2)、环吡氟草酮(CAS号:1855929-45-1)、三唑磺草酮(CAS号:1911613-97-2)、苯唑氟草酮(CAS号:1992017-55-6)、磺酰草吡唑(CAS号:365400-11-9)、吡唑特(CAS号:58011-68-0)、吡草酮(CAS号:82692-44-2)、tolpyralate(CAS号:1101132-67-5)、 fenquinotrione(CAS号:1342891-70-6)、异噁唑草酮(CAS号:141112-29-0)、苄草唑(CAS号:71561-11-0)、
Figure PCTCN2020124587-appb-000002
(2)PDS抑制剂：氟咯草酮(CAS号:61213-25-0)、呋草酮(CAS号:96525-23-4)、吡氟酰草胺(CAS号:83164-33-4)、氟吡酰草胺(CAS号:137641-05-5)、氟丁酰草胺(CAS号:113614-08-7)、氟草敏(CAS号:27314-13-2)、氟啶草酮(CAS号:59756-60-4)；
(3)DOXP抑制剂：异噁草松(CAS号:81777-89-1)、bixlozone(CAS号:81777-95-9)；
(4)ALS抑制剂：苯磺隆(CAS号:101200-48-0)、噻吩磺隆(CAS号:79277-27-3)、苄嘧磺隆(CAS号:83055-99-6)、吡嘧磺隆(CAS号:93697-74-6)、噻酮磺隆(CAS号:317815-83-1)、氯吡嘧磺隆(CAS号:100784-20-1)、丙嗪嘧磺隆(CAS号:570415-88-2)、嗪吡嘧磺隆(CAS号:868680-84-6)、砜嘧磺隆(CAS号:122931-48-0)、乙氧磺隆(CAS号:126801-58-9)、嘧苯胺磺隆(CAS号:213464-77-8)、氟唑磺隆(CAS号:181274-17-9)、甲基二磺隆(CAS号:208465-21-8)、烟嘧磺隆(CAS号:111991-09-4)、甲酰胺磺隆(CAS号:173159-57-4)、唑嘧磺草胺(CAS号:98967-40-9)、氟酮磺草胺(CAS号:874195-61-6)、五氟磺草胺(CAS号:219714-96-2)、氯酯磺草胺(CAS号:147150-35-4)、啶磺草胺(CAS号:422556-08-9)、甲氧咪草烟(CAS号:114311-32-9)、甲咪唑烟酸(CAS号:104098-48-8)、灭草烟(CAS号:81334-34-1)、嘧草醚(CAS号:147411-69-6)、双氟磺草胺(CAS号:145701-23-1)、环酯草醚(CAS号:135186-78-6)、嘧啶肟草醚(CAS号:168088-61-7)、丙苯磺隆(CAS号:181274-15-7)、咪草烟(CAS号:81335-77-5)、氯磺隆(CAS号:64902-72-3)、醚磺隆(CAS号:94593-91-6)、环丙嘧磺隆(CAS号:136849-15-5)、酰嘧磺隆(CAS号:120923-37-7)、醚苯磺隆(CAS号:82097-50-5)、碘甲磺隆钠盐(CAS号:144550-36-7)、氟啶嘧磺隆(CAS号:144740-54-5)、氟吡磺隆(CAS号:412928-75-7)、甲磺隆(CAS号:74223-64-6)、三氟甲磺隆(CAS号:142469-14-5)、磺酰磺隆(CAS号:141776-32-1)、唑吡嘧磺隆(CAS号:122548-33-8)、双草醚(CAS号:125401-92-5)、磺草唑胺(CAS号:139528-85-1)；
(5)ACCase抑制剂：炔草酯(CAS号:105512-06-9)、唑啉草酯(CAS号:243973-20-8)、烯草酮(CAS号:99129-21-2)、烯禾啶(CAS号:74051-80-2)、精喹禾灵(CAS号:100646-51-3)、肟草酮(CAS号:87820-88-0)、吡氟禾草灵(CAS号:69806-50-4)、高效氟吡甲禾灵(CAS号:72619-32-0)、禾草灵(CAS号:51338-27-3)、精噁唑禾草灵(CAS号:71283-80-2)、氰氟草酯(CAS号:122008-85-9)、环苯草酮(CAS号:139001-49-3)、噁唑酰草胺(CAS号:256412-89-2)、噁草酸(CAS号:111479-05-1)；
(6)PPO抑制剂：乙氧氟草醚(CAS号:42874-03-3)、氟磺胺草醚(CAS号:72178-02-0)、噁草酮(CAS号:19666-30-9)、丙炔噁草酮(CAS号:39807-15-3)、甲磺草胺(CAS号:122836-35-5)、双唑草腈(CAS号:158353-15-2)、丙炔氟草胺(CAS号:103361-09-7)、环戊噁草酮(CAS号:110956-75-7)、tiafenacil(CAS号:1220411-29-9)、苯嘧磺草胺(CAS号:372137-35-4)、吡草醚(CAS号:129630-19-9)、唑草酮(CAS号:128639-02-1)、氟丙嘧草酯(CAS号:134605-64-4)、氯氟草醚乙酯(CAS号:131086-42-5)、乙羧氟草醚(CAS号:77501-60-1)、三氟羧草醚(CAS号:62476-59-9)、trifludimoxazin(CAS号:1258836-72-4)、嗪草酸甲酯(CAS号:117337-19-6)、Epyrifenacil(CAS号:353292-31-6)；
(7)PSII抑制剂：莠去津(CAS号:1912-24-9)、扑草净(CAS号:7287-19-6)、西草净(CAS号:1014-70-6)、特丁津(CAS号:5915-41-3)、特丁净(CAS号:886-50-0)、莠灭净(CAS号:834-12-8)、异丙净(CAS号:4147-51-7)、害草净(CAS号:845-52-3)、敌草净(CAS号:1014-69-3)、西玛津(CAS号:122-34-9)、嗪草酮(CAS号:21087-64-9)、乙嗪草酮(CAS号:64529-56-2)、氨唑草酮(CAS号:129909-90-6)、苯嗪草酮(CAS号:41394-05-2)、氰草津(CAS号:21725-46-2)、绿麦隆(CAS号:15545-48-9)、异丙隆(CAS号:34123-59-6)、敌草隆(CAS号:330-54-1)、氟草隆(CAS号:2164-17-2)、利谷隆(CAS号:330-55-2)、丁噻隆(CAS号:34014-18-1)、莎扑隆(CAS号:42609-52-9)、绿谷隆(CAS号:1746-81-2)、溴谷隆(CAS号:3060-89-7)、草不隆(CAS号:555-37-3)、哒嗪醇(CAS号:40020-01-7)、环嗪酮(CAS号:51235-04-2)、异戊乙净(CAS号:22936-75-0)、草达津(CAS号:1912-26-1)、除草定(CAS号:314-40-9)、环草定(CAS号:2164-08-1)、特草定(CAS号:5902-51-2)、甲基苯噻隆(CAS号:18691-97-9)、环草隆(CAS号:1982-49-6)、异噁隆(CAS号:55861-78-4)、甲氧隆(CAS号:19937-59-8)、枯草隆(CAS号:1982-47-4)、三氟草嗪(CAS号:1258836-72-4)、Cyclopyrimorate(CAS号:499231-24-2)、敌稗(CAS号:709-98-8)、哒草特(CAS号:55512-33-9)、甜菜安(CAS号:13684-56-5)、甜菜宁(CAS号:13684-63-4)、灭草松(CAS号:25057-89-0)、辛酰溴苯腈(CAS号:1689-99-2)、溴苯腈(CAS号:1689-84-5)、碘苯腈(CAS号:1689-83-4)；
(8)微管组装抑制剂：氟乐灵(CAS号:1582-09-8)、仲丁灵(CAS号:33629-47-9)、二甲戊灵(CAS号:40487-42-1)、氟硫草定(CAS号:97886-45-8)、乙丁烯氟灵(CAS号:55283-68-6)、氨磺乐灵(CAS号:19044-88-3)、氟草胺(CAS号:1861-40-1)、噻草啶(CAS号:117718-60-2)、拿草特(CAS号:23950-58-5)、敌草索(CAS号:1861-32-1)、抑草磷(CAS号:36335-67-8)；
(9)微管组合抑制剂：双酰草胺(CAS号:16118-49-3)；
(10)VLCFA抑制剂：乙草胺(CAS号:34256-82-1)、丁草胺(CAS号:23184-66-9)、丙草胺(CAS号:51218-49-6)、异丙甲草胺(CAS号:51218-45-2)、苯噻酰草胺(CAS号:73250-68-7)、 精异丙甲草胺(CAS号:87392-12-9)、氟噻草胺(CAS号:142459-58-3)、敌草胺(CAS号:15299-99-7)、砜吡草唑(CAS号:447399-55-5)、莎稗磷(CAS号:64249-01-0)、二甲酚草胺(CAS号:87674-68-8)、四唑酰草胺(CAS号:158237-07-1)、三唑酰草胺(CAS号:212201-70-2)、唑草胺(CAS号:125306-83-4)、哌草磷(CAS号:24151-93-7)、异丙草胺(CAS号:86763-47-5)、甲草胺(CAS号:15972-60-8)、吡唑草胺(CAS号:67129-08-2)、毒草胺(CAS号:1918-16-7)、烯草胺(CAS号:106700-29-2)、Dimesulfazet(CAS号:1215111-77-5)、Fenoxasulfone(CAS号:639826-16-7)；
(11)脂类合成(非乙酰辅酶A羧化酶)抑制剂：苄草丹(CAS号:52888-80-9)、禾草敌(CAS号:2212-67-1)、禾草丹(CAS号:28249-77-6)、呋草黄(CAS号:68505-69-1)、乙氧呋草黄(CAS号:26225-79-6)、野麦畏(CAS号:2303-17-5)、灭草敌(CAS号:1929-77-7)、丁草特(CAS号:2008-41-5)、环草敌(CAS号:1134-23-2)、哌草丹(CAS号:61432-55-1)、戊草丹(CAS号:85785-20-2)；
(12)合成激素类：二氯喹啉酸(CAS号:84087-01-4)、氯氟吡氧乙酸(CAS号:69377-81-7)、氯氟吡氧乙酸异辛酯(CAS号:81406-37-3)、氟氯吡啶酯(CAS号:943831-98-9)、三氯吡氧乙酸(CAS号:55335-06-3)、二氯吡啶酸(CAS号:1702-17-6)、氨氯吡啶酸(CAS号:1918-02-1)、氯氨吡啶酸(CAS号:150114-71-9)、麦草畏(CAS号:1918-00-9)、氯氟吡啶酯(CAS号:1390661-72-9)、2-甲基-4-氯苯氧乙酸(CAS号:94-74-6)、2-甲基-4-氯-苯酚乙硫酯(CAS号:25319-90-8)、MCPB(CAS号:94-81-5)、2-甲基-4-氯苯氧丙酸(CAS号:93-65-2)、2-甲基-4-氯苯氧乙酸钠(CAS号:3653-48-3)、2-甲基-4-氯苯氧乙酸异辛酯(CAS号:26544-20-7)、2,4-二氯苯氧乙酸丁酯(CAS号:94-80-4)、2,4-二氯苯氧乙酸异辛酯(CAS号:25168-26-7)、2,4-二氯苯氧基乙酸(CAS号:94-75-7)、氯甲喹啉酸(CAS号:90717-03-6)、2甲4氯二甲铵盐(CAS号:2039-46-5)、2,4-滴丙酸(CAS号:120-36-5)、2,4-滴丁酸(CAS号:94-82-6)、草除灵(CAS号:25059-80-7)、环丙嘧啶酸(CAS号:858956-08-8)、
Figure PCTCN2020124587-appb-000003
(13)EPSPS抑制剂：草甘膦(CAS号:1071-83-6)、草硫膦(CAS号:81591-81-3)；
(14)GS抑制剂：草铵膦(CAS号:77182-82-2)、双丙氨膦(CAS号:35597-43-4)、精草铵膦(CAS号:73777-50-1)；
(15)PSI抑制剂:百草枯(CAS号:1910-42-5)、敌草快(CAS号:6385-62-2)；
(16)DHP抑制剂：磺草灵(CAS号:3337-71-1)；
(17)纤维素合成抑制剂：三嗪氟草胺(CAS号:131475-57-5)、茚嗪氟草胺(CAS号:950782-86-2)；
(18)其他除草剂：噁嗪草酮(CAS号:153197-14-9)、环庚草醚(CAS号:87818-31-3)、茚草酮(CAS号:133220-30-1)、二氯喹啉草酮(CAS号:1350901-36-8)、喹草酮(CAS号:1639426-14-4)、苄草隆(CAS号:99485-76-4)、灭草隆(CAS号:150-68-5)、tetflupyrolimet(CAS号:2053901-33-8)。
在本说明书的上下文中，如果使用活性化合物的通用名称的缩写形式，则在每种情况下包括所有的常规衍生物，例如酯和盐，以及异构体，特别是光学异构体，特别是一种或多种市售形式。如果通用名称表示酯或盐，则在每种情况下还包括所有其他的常规衍生物，例如其他的酯和盐、游离酸和中性化合物，以及异构体，特别是光学异构体，特别是一种或多种市售形式。给出的化合物的化学名称表示至少一种被通用名称涵盖的化合物，通常是优选的化合物。在磺酰胺如磺酰脲的情况下，盐还包括通过阳离子与磺酰胺基团中的氢原子交换而形成的盐。例如，2甲4氯衍生物包含但不限于：2甲4氯钠盐、钾盐、二甲铵盐、异丙胺盐等，以及2甲4氯甲酯、乙酯、异辛酯、乙硫酯等；2,4-D衍生物包含但不限于：2,4-D盐如钠盐、钾盐、二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等，以及2,4-D酯如甲酯、乙酯、丁酯、异辛酯等。
其中，A、B的重量比为1:600～200:1和1:500～100:1；优选为1:300～80:1和1:200～60:1；更优选为1:150～50:1和1:120～30:1；进一步优选为1:100～20:1和1:80～15:1；更进一步优选为1:50～10:1、1:30～5:1、1:10～4:1和1:5～1:1。
在一具体实施方案中，本发明还列出了下述组分A和组分B的特定组合：
Figure PCTCN2020124587-appb-000004
Figure PCTCN2020124587-appb-000005
Figure PCTCN2020124587-appb-000006
Figure PCTCN2020124587-appb-000007
Figure PCTCN2020124587-appb-000008
Figure PCTCN2020124587-appb-000009
Figure PCTCN2020124587-appb-000010
Figure PCTCN2020124587-appb-000011
Figure PCTCN2020124587-appb-000012
Figure PCTCN2020124587-appb-000013
Figure PCTCN2020124587-appb-000014
在另一具体实施方案中，上述表格中组分A分别替换为相应的盐。
在本发明的上下文中，化合物的盐优选为各自的碱金属盐、碱土金属盐或铵盐(如二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等)的形式，优选为各自的碱金属盐的形式，更优选为各自的钠盐或钾盐的形式，最优选为各自的钠盐的形式。
所述除草组合物中A、B的质量百分含量占总量的1-95％，优选10-80％。
所述除草组合物中还包含常规助剂，所述常规助剂包括载体、表面活性剂。
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的施用，该载体一般是惰性的且必须是农业上可接受的，特别是被处理的植物所接受。载体可以是固体的，如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等；或者液体的，如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。
表面活性剂可包括乳化剂、分散剂或润湿剂，它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐，以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚，此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基 聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、木素亚硫酸盐废液，以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在，以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。
上述组合物也可含有各种其他的组分，如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。
另外，本发明的组合物可以与以下活性物质混合，例如《世界农药新品种技术大全》，中国农业科学技术出版社，2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活性物质，(备注:化合物的名称，或者为根据国际标准化组织(ISO)的普通名称，或者为化学名称，适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、氯磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯 噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、 地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、三唑磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489，LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。
所述除草组合物进一步包括至少一种安全剂，其选自：
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物，优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1，吡唑解草酯(mefenpyr-diethyl)，PM，第594-595页)，以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。
b)二氯苯基吡唑羧酸衍生物，优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5)，以及记载于EP-A-333131和EP-A-269806中的相关化合物。
c)三唑羧酸(S1)类化合物，优选的化合物为例如解草唑(fenchlorazole)，即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物，优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物，或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9，双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。
e)8-喹啉氧基乙酸(S2)类化合物，优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1，解 毒喹(cloquintocet-mexyl)，如PM(第195-196页)，(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2)，4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3)，1-烯丙基氧基丙-2-基(5-氯-8-喹啉氧基)乙酸酯(S2-4)，(5-氯-8-喹啉氧基)乙酸乙酯(S2-5)，(5-氯-8-喹啉氧基)乙酸甲酯(S2-6)，(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7)，2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8)，2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9)，以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。
f)(5-氯-8-喹啉氧基)丙二酸类化合物，优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物，例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。
h)嘧啶类活性化合物，例如“解草啶(fenclorim)”(PM，第386-387页)(＝4,6-二氯-2-苯基嘧啶)，
i)二氯乙酰胺类活性化合物，其常用作苗前安全剂(作用于土壤的安全剂)，例如“二氯丙烯胺(dichloromid)”(PM，第270-271页)(＝N,N-二烯丙基-2,2-二氯乙酰胺)，“AR-29148”(＝3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮，购自Stauffer)，“解草嗪(benoxacor)”(PM，第74-75页)(＝4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪)，“APPG-1292”(＝N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺，购自PPG Industries)，“ADK-24”(＝N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺，购自Sagro-Chem)，“AAD-67”或“AMON4660”(＝3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷，购自Nitrokemia或Monsanto)，“diclonon”或“ABAS145138”或“ALAB145138”(＝(＝3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷，购自BASF)，和“furilazol”或“AMON13900”(参见PM，482-483)(＝(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮)，
j)二氯丙酮衍生物类活性化合物，例如，“AMG191”(CAS登记号96420-72-3)(＝2-二氯甲基-2-甲基-1,3-二氧戊环，购自Nitrokemia)，
k)氧基亚氨基化合物类活性化合物，其被称为拌种材料，例如，“解草腈(oxabetrinil)”(PM，第689页)(＝(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，“氟草肟(fluxofenim)”(PM，第467-468页)(＝1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM，第983页)(＝(Z)- 氰基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，
l)噻唑羧酸酯类活性化合物，其被称为拌种材料，例如“解草安(flurazol)”(PM，第450-451页)(＝2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯)，其在拌种中被称为安全剂，以防止甲草胺(alachlor)和异丙甲草胺的损害，
m)萘二羧酸衍生物类活性化合物，其被称为拌种剂，例如“萘二甲酸酐”(PM，第1009-1010页)(＝1,8-萘二甲酸酐)，其在玉米拌种中称为安全剂，以防止硫代氨基甲酸酯除草剂的损害，
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物，例如，“ACL304415”(CAS登记号31541-57-8)(＝2-84-羧基色满-4-基)乙酸，购自AmericanCyanamid)，
o)除了对有害植物具有除草作用外还对植物具有安全剂作用的活性化合物，例如，“哌草丹(dimepiperate)”或“AMY-93”(PM，第302-303页)(＝S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯)，“杀草隆(daimuron)”或“ASK23”(PM，第247页)(＝1-(1-甲基-1-苯基乙基)-3-对甲苯基脲)，“苄草隆(cumyluron)”＝“AJC-940”(＝3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲，参见JP-A-60087254)，“苯甲酮(methoxyphenon)”或“ANK049”(＝3,3'-二甲基-4-甲氧基-二苯甲酮)，“CSB”(＝1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4，购自Kumiai)。
所述安全剂优选双苯噁唑酸(CAS：163520-33-0)、cyprosulfamide(CAS：221667-31-8)、吡唑解草酯(CAS：135590-91-9)、解毒喹(CAS：99607-70-2)、赤霉酸(CAS：7-06-5)、furilazole(CAS：121776-33-8)、metcamifen(CAS：129531-12-0)中的一种或多种。
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备，即将活性物质与液体溶剂或固体载体混合后，再加入表面活性剂如分散剂、稳定剂、湿润剂、粘合剂、消泡剂等中的一种或几种。
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。
简而言之，本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。随着外部条件的变化，有效成分的使用量也不同，外部条件为，例如温度、湿度、使用的除草剂的性质等等。它可以有大的变化幅度，例如在0.001到1.0kg/ha之间，或更多的活性物质，但优选在0.005到750g/ha之间，特别是在0.005到500g/ha之间。
本发明还提供一种所述除草组合物在防治杂草上的应用；以及提供一种防治不想要的植物生长的方法，其包括将所述除草组合物施用于植物、植物部位、植物种子或植物生长的区域。
另外，本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上，即施用于杂草， 特别是杂草侵扰或易侵扰影响的表面上。
当施用本发明的除草组合物时，获得了预料不到的增效效果，并且除草活性比使用单个除草剂的活性预期总和，以及单个除草剂的活性更为显著。增效效果表现为施用量减少、更宽的杂草控制谱、除草作用更快、更持久，这些特性是杂草控制实践过程中所需要的。就所描述的特性来说，这些新组合物明显地优越于现有的除草剂，达到减量使用，对环境更友好。
本发明的增效除草组合物还具有下述优点:
(1)本发明的组合物为环境友好型，在环境中均易于降解。
(2)本发明的除草组合物成本低、使用方便，其推广应用有巨大的经济效益和社会效益。
具体实施方式
下列实施例并非限制本发明，而只是用来说明本发明是如何实现的。对于某些杂草，这些实施例显示出特别显著的有效性。举例如下：
A)实施例
1.A1+硝磺草酮(4+1：代表4％A1+1％硝磺草酮，下同)可分散油悬浮剂
A1+硝磺草酮+0.3％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
2.A1+苯唑草酮(3+1)可分散油悬浮剂
A1+苯唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
3.A1+双唑草酮(3+1)可分散油悬浮剂
A1+双唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
4.A1+苯唑氟草酮(4+4)可分散油悬浮剂
A1+苯唑氟草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
5.A1+异噁唑草酮(4+4)可分散油悬浮剂
A1+异噁唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
6.A1+异噁草松(4+4)可分散油悬浮剂
A1+异噁草松+4％十二烷基苯磺酸钙+6％腰果酚聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有机膨润土+5％100#溶剂油+油酸甲酯补足
7.A1+吡嘧磺隆(4+2)可分散油悬浮剂
A1+吡嘧磺隆+0.5％尿素+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
8.A1+五氟磺草胺(4+1)可分散油悬浮剂
A1+五氟磺草胺+5％十二烷基苯磺酸钙+6％失水山梨醇单油酸酯聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
9.A1+甲氧咪草烟(4+1)可分散油悬浮剂
A1+甲氧咪草烟+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
10.A1+甲咪唑烟酸(4+1)可分散油悬浮剂
A1+甲咪唑烟酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
11.A1+双草醚(4+1)可分散油悬浮剂
A1+双草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
12.A1+烯草酮(4+2)可分散油悬浮剂
A1+烯草酮+5％十二烷基苯磺酸钙+8％失水山梨醇单油酸酯聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
13.A1+烯禾啶(4+2)可分散油悬浮剂
A1+烯禾啶+5％十二烷基苯磺酸钙+8％失水山梨醇单油酸酯聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
14.A1+精喹禾灵(4+2)可分散油悬浮剂
A1+精喹禾灵+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
15.A1+乙氧氟草醚(3+1)可分散油悬浮剂
A1+乙氧氟草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
16.A1+噁草酮(3+1)可分散油悬浮剂
A1+噁草酮+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+5％100#溶剂油+油酸甲酯补足
17.A1+丙炔噁草酮(3+1)可分散油悬浮剂
A1+丙炔噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％ 有机膨润土+2％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
18.A1+莠去津(3+5)水悬浮剂
A1+莠去津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.25％黄原胶+2.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
19.A1+特丁津(3+3)水悬浮剂
A1+特丁津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.25％黄原胶+2.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
20.A1+敌稗(2+20)水悬浮剂
A1+敌稗+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
21.A1+灭草松(4+30)水悬浮剂
A1+灭草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
22.A1+仲丁灵(4+21)可分散油悬浮剂
A1+仲丁灵+10％癸酰胺+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
23.A1+二甲戊灵(4+21)可分散油悬浮剂
A1+二甲戊灵+10％癸酰胺+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
24.A1+丁草胺(4+6)可分散油悬浮剂
A1+丁草胺+6％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+3％有机膨润土+3％气相法白炭黑+油酸甲酯补足
25.A1+丙草胺(2+4)可分散油悬浮剂
A1+丙草胺+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+3％有机膨润土+3％气相法白炭黑+油酸甲酯补足
26.A1+莎稗磷(4+2)可分散油悬浮剂
A1+莎稗磷+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
27.A1+二氯喹啉酸(2+10)可分散油悬浮剂
A1+二氯喹啉酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
28.A1+氯氟吡氧乙酸(2+3)可分散油悬浮剂
A1+氯氟吡氧乙酸+5％十二烷基苯磺酸钙+8％苯乙基苯酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
29.A1+氯氟吡啶酯(3+1)可分散油悬浮剂
A1+氯氟吡啶酯+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+油酸甲酯补足
30.A1+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂
A1+2-甲基-4-氯苯氧乙酸+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2％有机膨润土+2.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
31.A1+草甘膦(4+16)水悬浮剂
A1+草甘膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
32.A1+草铵膦(3+15)水悬浮剂
A1+草铵膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
33.A1+敌草快(4+15)水悬浮剂
A1+敌草快+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
34.A1+环庚草醚(4+1)可分散油悬浮剂
A1+环庚草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
35.A2+硝磺草酮(4+1)可分散油悬浮剂
A2+硝磺草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
36.A2+苯唑草酮(3+1)可分散油悬浮剂
A2+苯唑草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
37.A2+双唑草酮(3+1)可分散油悬浮剂
A2+双唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
38.A2+苯唑氟草酮(4+4)可分散油悬浮剂
A2+苯唑氟草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
39.A2+异噁唑草酮(4+4)可分散油悬浮剂
A2+异噁唑草酮+0.3％柠檬酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
40.A2+异噁草松(4+4)可分散油悬浮剂
A2+异噁草松+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+10％100#溶剂油+油酸甲酯补足
41.A2+吡嘧磺隆(4+2)可分散油悬浮剂
A2+吡嘧磺隆+0.5％尿素+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
42.A2+五氟磺草胺(4+1)可分散油悬浮剂
A2+五氟磺草胺+5％十二烷基苯磺酸钙+9％失水山梨醇单油酸酯聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
43.A2+甲氧咪草烟(4+1)可分散油悬浮剂
A2+甲氧咪草烟+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
44.A2+甲咪唑烟酸(4+1)可分散油悬浮剂
A2+甲咪唑烟酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
45.A2+双草醚(4+1)可分散油悬浮剂
A2+双草醚+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
46.A2+烯草酮(4+2)可分散油悬浮剂
A2+烯草酮+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
47.A2+烯禾啶(4+2)可分散油悬浮剂
A2+烯禾啶+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
48.A2+精喹禾灵(4+2)可分散油悬浮剂
A2+精喹禾灵+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有 机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
49.A2+乙氧氟草醚(3+1)可分散油悬浮剂
A2+乙氧氟草醚+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
50.A2+噁草酮(3+1)可分散油悬浮剂
A2+噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+5％100#溶剂油+油酸甲酯补足
51.A2+丙炔噁草酮(3+1)可分散油悬浮剂
A2+丙炔噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
52.A2+莠去津(3+5)水悬浮剂
A2+莠去津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.22％黄原胶+2.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
53.A2+特丁津(3+3)水悬浮剂
A2+特丁津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.26％黄原胶+2.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
54.A2+敌稗(2+20)水悬浮剂
A2+敌稗+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18％黄原胶+1.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
55.A2+灭草松(4+30)水悬浮剂
A2+灭草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
56.A2+仲丁灵(4+21)可分散油悬浮剂
A2+仲丁灵+10％癸酰胺+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
57.A2+二甲戊灵(4+21)可分散油悬浮剂
A2+二甲戊灵+10％癸酰胺+6％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
58.A2+丁草胺(4+6)可分散油悬浮剂
A2+丁草胺+6％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+油酸甲酯补足
59.A2+丙草胺(2+4)可分散油悬浮剂
A2+丙草胺+5％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+油酸甲酯补足
60.A2+莎稗磷(4+2)可分散油悬浮剂
A2+莎稗磷+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
61.A2+二氯喹啉酸(2+10)可分散油悬浮剂
A2+二氯喹啉酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+10％100#溶剂油+油酸甲酯补足
62.A2+氯氟吡氧乙酸(2+3)可分散油悬浮剂
A2+氯氟吡氧乙酸+5％十二烷基苯磺酸钙+9％苯乙基苯酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
63.A2+氯氟吡啶酯(3+1)可分散油悬浮剂
A2+氯氟吡啶酯+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
64.A2+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂
A2+2-甲基-4-氯苯氧乙酸+6％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2％有机膨润土+1％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
65.A2+草甘膦(4+16)水悬浮剂
A2+草甘膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
66.A2+草铵膦(3+15)水悬浮剂
A2+草铵膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
67.A2+敌草快(4+15)水悬浮剂
A2+敌草快+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
68.A2+环庚草醚(4+1)可分散油悬浮剂
A2+环庚草醚+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
上述水悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。
上述水悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。
上述可分散油悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。
上述可分散油悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。
B)药效试验
苗后茎叶喷雾处理:
1)试验条件
1.1)、供试靶标
异型莎草采自湖北荆州、碎米莎草采自江西上饶、鸭舌草采自湖南长沙、稻稗采自黑龙江抚远、野慈姑采自辽宁营口、萤蔺采自黑龙江虎林、丁香蓼采自湖南长沙、马唐采自安徽天长、泽泻采自辽宁沈阳。上述杂草采用盆栽法培养，用180х140mm塑料营养钵，摆放于搪瓷盘中，内装从农田采回经风干过筛的表层土壤(4/5处)，土壤湿度初期均控制在20％，挑选籽粒饱满均一的杂草种子，用25℃温水浸泡6小时，在28℃生化培养箱(黑暗)中催芽，将刚刚露白的杂草种子均匀摆放在土壤表面，根据种子粒径大小然后覆土0.5-1cm。
1.2)、培养条件
在可控日光温室内进行，温度20～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％，pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。1.3)、仪器设备
3WP-2000型行走式喷雾塔，农业部南京农业机械研究所。GA10型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)。
2)试验设计
2.1)、试剂
所需活性成分A来自于专利CN201911014193.5，其具体制备过程如下所示：
(1)化合物A1的合成：
(1.1)在30毫升的DMF中依次加入Cpd 1(3g,16mmol,1.0eq)，NaOH(0.72g,18mmol,1.1eq)然后在0℃条件下逐滴加入Cpd 2(1.28g,16.8mmol,1.05eq)，然后反应液在0℃条件下搅拌1小时。LCMS检测显示原料基本反应完毕，有一个主要的新峰。将反应液倒入30毫升水中，分液，水相用50毫升乙酸乙酯萃取一次，有机相用饱和食盐水(50ml)洗三次，干燥，旋干，柱层析分离得到Cpd 3(3.6g,91％收率)(无色的油)。
Figure PCTCN2020124587-appb-000015
(1.2)在30毫升的THF中加入Cpd 3(3.1g,13mmol,1.0eq)，然后在-78℃条件下缓慢加入n-BuLi(6.42ml,2.5M,16mmol,1.2eq)，然后反应液在-78℃条件下搅拌0.5小时后缓慢通入CO 2，通入10min后反应液缓慢升到室温。LCMS检测到产品。往反应液中倒入20毫升水，分液，水相用30毫升乙酸乙酯萃取一次，水相用浓盐酸逐渐调到pH＝4-5，过滤，干燥得到Cpd 4(3.2g,87％收率)(白色固体)。
Figure PCTCN2020124587-appb-000016
(1.3)在30毫升的吡啶中依次加入Cpd 4(3.1g,11mmol,1.0eq)，Cpd 5(1.66g,16.8mmol,1.5eq),DMAP(0.13g,1.1mmol,0.1eq)。然后在0℃条件下缓慢加入SOCl 2(2.0g,16.8mmol,1.5eq)，然后反应液在室温条件下搅拌3小时。LCMS检测到产品。浓缩除掉吡啶后往反应液倒入30毫升水，分液，水相用30毫升乙酸乙酯萃取三次，有机相用饱和食盐水(50ml)洗三次，干燥，旋干，柱层析分离得到化合物Cpd 6(2.5g,63％收率)(白色固体)。
Figure PCTCN2020124587-appb-000017
(1.4)在10毫升的二氯甲烷中依次加入Cpd 6(1g,2.8mmol,1.0eq)，m-CPBA(0.54g,3.1mmol,1.1eq)。然后反应液在室温条件下搅拌1小时。LCMS检测到产品，原料基本反应完毕。将反应液倒入10毫升水中，用亚硫酸氢钠淬灭，分液，水相用30毫升二氯甲烷萃取三次，有机相用饱和食盐水(30ml)洗一次，干燥，旋干，柱层析分离得到化合物A1(0.85g,82％收率)(灰白色的固体)。
1H NMR(500MHz,DMSO-d 6)12.57(s,1H),8.07(dd,J＝8.0,7.0Hz,1H),7.82(d,J＝8.0Hz,1H),3.57-3.47(m,2H),2.48(s,3H),1.70-1.52(m,2H),1.08-0.93(m,3H).
Figure PCTCN2020124587-appb-000018
(2)化合物A2的合成：
化合物A1(0.5g,98％purity)通过手性HPLC(Column：CHIRALPAK IG；Column Size：3cm x 25cm,5um；Injection：3.0ml；Mobile phase：Hex(0.2％FA)：IPA＝50：50；Flow rate：28ml/min；Wavelength:UV 254nm；Temperature:25℃；Sample solution：70mg/ml in EtOH/DCM；Run time＝60mins)拆分之后浓缩，经单晶衍射确定得到白色固体A2(R构型)(0.16g,Rt＝10.51min,100％ee,纯度为98％)。
Figure PCTCN2020124587-appb-000019
所需活性成分B中双唑草酮、环吡氟草酮、苯唑氟草酮、三唑磺草酮、
Figure PCTCN2020124587-appb-000020
为本公司生产，其他由试剂公司购买。原药均采用丙酮作溶剂，用含量0.1％乳化剂吐温-80水溶液稀释，现用现稀释。
其中，
Figure PCTCN2020124587-appb-000021
来自专利CN201911321469.4，其制备方法如下：
1)将化合物a(0.5g，2.13mmol)，化合物b(313mg，2.55mmol)，催化量的TBAB(10mg)，DMF(10mL)置于圆底烧瓶中，室温15℃下搅拌24小时。液质检测少量原料剩余，即可处理。将反应液倒入到50mL水中，用甲基叔丁基醚萃取2次(50mL x 2)，有机相干燥，浓缩，经柱层析分离纯化，得到化合物c(300mg，收率50％)。化合物c为白色固体。
Figure PCTCN2020124587-appb-000022
(2)将化合物c(0.3g，1.06mmol)、甲醇(20mL)置于100mL单口瓶中，氢氧化锂(44.5mg，1.06mmol)溶解在2mL水中，室温下缓慢滴加到单口瓶中，室温搅拌12小时。液质检测原料反应完，用0.5M稀盐酸调pH至5-6，浓缩，用水和乙酸乙酯萃取。有机相干燥、浓缩得到化合物d(200mg，收率70％)，化合物d为白色固体。
Figure PCTCN2020124587-appb-000023
(3)将化合物d(200mg，0.74mmol)，化合物e(75mg，0.74mmol)，DCC(152mg，0.74mmol)，无水DCM(20mL)置于100mL圆底烧瓶中，室温反应12小时。液质检测原料反应完，将反应液浓缩，经柱层析分离得到目标化合物(200mg，收率77％)，其为白色固体。
Figure PCTCN2020124587-appb-000024
1H NMR(500MHz,Chloroform-d)δ5.28(q,J＝7.0Hz,1H),5.15(s,2H),4.27–4.07(m,3H),3.91–3.73(m,2H),2.04–1.82(m,3H),1.66(d,J＝7.0Hz,3H),1.59-1.54(m,1H).
2.2)、试验处理
2.2.1)、剂量设置
在确定A与活性成分B配比或含量时，应从两种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上，设A、B活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。
2.2.2)、试验重复
每处理重复4次，每次处理3盆，每盆播种杂草种子20粒，每处理共60株。
2.3)、处理方式
2.3.1)、处理时间和次数
试验共用药1次。待杂草1～1.5叶期，间苗，保持每盆内杂草15株，每处理保留45株，然后继续培养至2-3叶进行处理。
2.3.2)、使用器械和用药方法
将培养好的试材均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔茎叶喷雾，喷液量按450公斤/公顷计，喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。
3)试验方法
采用盆栽法。杂草培养见1.1)，参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2)，采用茎叶处理法。处理后移入温室常规培养。
4)数据调查与统计分析
4.1)、调查方法
采用绝对数调查法，用刀片沿土壤表面切断存活杂草整株幼苗，用分析天平称量杂草鲜重。对于已经死亡的杂草，按鲜重为零计。
4.2)、调查时间和次数
处理后15天调查，共调查1次。
4.3)、数据统计分析
用Gowing法计算各处理混合组合的理论鲜重抑制率(E0＝X+Y-X*Y/100)，然后与实测抑制率(E)相比较，评价二者混用对杂草的联合作用类型，当E-E0值大于10％为增效作用、小于-10％为拮抗作用、在-10％～10％之间为加成作用。并根据实际防效和除草剂特点、配方的平衡性等因素确定最佳配比。式中X为活性成分A用量为P时的鲜重抑制率；Y为活性成分B用量为Q时的鲜重抑制率。统计结果见下表1-223。
表1 A1混配硝磺草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000025
表2 A1混配苯唑草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000026
表3 A1混配环磺酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000027
表4 A1混配氟吡草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000028
表5 A1混配呋喃磺草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000029
表6 A1混配双环磺草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000030
表7 A1混配双唑草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000031
表8 A1混配环吡氟草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000032
表9 A1混配三唑磺草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000033
表10 A1混配苯唑氟草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000034
表11 A1混配异噁唑草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000035
Figure PCTCN2020124587-appb-000036
表12 A1混配吡氟酰草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000037
表13 A1混配氟吡酰草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000038
表14 A1混配异噁草松对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000039
表15 A1混配噻吩磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000040
表16 A1混配苄嘧磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000041
表17 A1混配吡嘧磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000042
表18 A1混配噻酮磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000043
Figure PCTCN2020124587-appb-000044
表19 A1混配氯吡嘧磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000045
表20 A1混配砜嘧磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000046
表21 A1混配氟唑磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000047
表22 A1混配甲基二磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000048
表23 A1混配烟嘧磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000049
表24 A1混配甲酰胺磺隆对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000050
表25 A1混配唑嘧磺草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000051
表26 A1混配氟酮磺草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000052
表27 A1混配五氟磺草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000053
表28 A1混配氯酯磺草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000054
Figure PCTCN2020124587-appb-000055
表29 A1混配啶磺草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000056
表30 A1混配甲氧咪草烟对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000057
表31 A1混配甲咪唑烟酸对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000058
表32 A1混配碘甲磺隆钠盐对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000059
表33 A1混配双草醚对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000060
表34 A1混配唑啉草酯对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000061
表35 A1混配烯草酮对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000062
Figure PCTCN2020124587-appb-000063
表36 A1混配烯禾啶对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000064
表37 A1混配精喹禾灵对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000065
表38 A1混配高效氟吡甲禾灵对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000066
表39 A1混配环苯草酮对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000067
表40 A1混配噁唑酰草胺对稻稗的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000068
表41 A1混配乙氧氟草醚对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000069
表42 A1混配氟磺胺草醚对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000070
表43 A1混配噁草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000071
表44 A1混配丙炔噁草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000072
表45 A1混配甲磺草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000073
表46 A1混配双唑草腈对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000074
表47 A1混配丙炔氟草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000075
表48 A1混配环戊噁草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000076
表49 A1混配tiafenacil对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000077
表50 A1混配苯嘧磺草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000078
表51 A1混配唑草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000079
表52 A1混配乙羧氟草醚对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000080
表53 A1混配三氟羧草醚对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000081
表54 A1混配trifludimoxazin对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000082
表55 A1混配莠去津对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000083
表56 A1混配特丁津对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000084
表57 A1混配莠灭净对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000085
表58 A1混配嗪草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000086
表59 A1混配氨唑草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000087
表60 A1混配绿麦隆对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000088
表61 A1混配异丙隆对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000089
表62 A1混配除草定对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000090
表63 A1混配三氟草嗪对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000091
表64 A1混配cyclopyrimorate对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000092
表65 A1混配敌稗对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000093
表66 A1混配哒草特对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000094
表67 A1混配灭草松对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000095
Figure PCTCN2020124587-appb-000096
表68 A1混配溴苯腈对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000097
表69 A1混配仲丁灵对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000098
表70 A1混配二甲戊灵对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000099
表71 A1混配丁草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000100
表72 A1混配丙草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000101
表73 A1混配精异丙甲草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000102
Figure PCTCN2020124587-appb-000103
表74 A1混配氟噻草胺对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000104
表75 A1混配砜吡草唑对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000105
表76 A1混配莎稗磷对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000106
表77 A1混配苄草丹对碎米莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000107
表78 A1混配禾草敌对碎米莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000108
表79 A1混配禾草丹对碎米莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000109
表80 A1混配二氯喹啉酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000110
表81 A1混配氯氟吡氧乙酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000111
Figure PCTCN2020124587-appb-000112
表82 A1混配氟氯吡啶酯对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000113
表83 A1混配三氯吡氧乙酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000114
表84 A1混配二氯吡啶酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000115
表85 A1混配氨氯吡啶酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000116
表86 A1混配氯氨吡啶酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000117
表87 A1混配麦草畏对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000118
表88 A1混配氯氟吡啶酯对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000119
表89 A1混配2-甲基-4-氯苯氧乙酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000120
Figure PCTCN2020124587-appb-000121
表90 A1混配环丙嘧啶酸对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000122
表91 A1混配草甘膦对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000123
表92 A1混配草铵膦对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000124
表93 A1混配精草铵膦对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000125
表94 A1混配敌草快对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000126
表95 A1混配三嗪氟草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000127
表96 A1混配茚嗪氟草胺对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000128
表97 A1混配噁嗪草酮对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000129
表98 A1混配环庚草醚对鸭舌草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000130
表99 A2混配硝磺草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000131
表100 A2混配苯唑草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000132
表101 A2混配环磺酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000133
表102 A2混配氟吡草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000134
表103 A2混配呋喃磺草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000135
表104 A2混配双环磺草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000136
表105 A2混配双唑草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000137
表106 A2混配环吡氟草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000138
表107 A2混配三唑磺草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000139
表108 A2混配苯唑氟草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000140
表109 A2混配异噁唑草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000141
表110 A2混配吡氟酰草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000142
表111 A2混配氟吡酰草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000143
表112 A2混配异噁草松对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000144
表113 A2混配噻吩磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000145
表114 A2混配苄嘧磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000146
表115 A2混配吡嘧磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000147
Figure PCTCN2020124587-appb-000148
表116 A2混配噻酮磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000149
表117 A2混配氯吡嘧磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000150
表118 A2混配砜嘧磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000151
表119 A2混配氟唑磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000152
表120 A2混配甲基二磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000153
表121 A2混配烟嘧磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000154
表122 A2混配甲酰胺磺隆对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000155
表123 A2混配唑嘧磺草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000156
表124 A2混配氟酮磺草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000157
Figure PCTCN2020124587-appb-000158
表125 A2混配五氟磺草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000159
表126 A2混配氯酯磺草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000160
表127 A2混配啶磺草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000161
表128 A2混配甲氧咪草烟对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000162
表129 A2混配甲咪唑烟酸对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000163
表130 A2混配碘甲磺隆钠盐对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000164
Figure PCTCN2020124587-appb-000165
表131 A2混配双草醚对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000166
表132 A2混配唑啉草酯对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000167
表133 A2混配烯草酮对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000168
表134 A2混配烯禾啶对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000169
表135 A2混配精喹禾灵对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000170
Figure PCTCN2020124587-appb-000171
表136 A2混配高效氟吡甲禾灵对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000172
表137 A2混配环苯草酮对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000173
表138 A2混配噁唑酰草胺对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000174
表139 A2混配乙氧氟草醚对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000175
表140 A2混配氟磺胺草醚对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000176
表141 A2混配噁草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000177
表142 A2混配丙炔噁草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000178
Figure PCTCN2020124587-appb-000179
表143 A2混配甲磺草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000180
表144 A2混配双唑草腈对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000181
表145 A2混配丙炔氟草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000182
表146 A2混配环戊噁草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000183
表147 A2混配tiafenacil对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000184
表148 A2混配苯嘧磺草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000185
表149 A2混配唑草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000186
表150 A2混配乙羧氟草醚对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000187
Figure PCTCN2020124587-appb-000188
表151 A2混配三氟羧草醚对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000189
表152 A2混配trifludimoxazin对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000190
表153 A2混配莠去津对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000191
表154 A2混配特丁津对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000192
表155 A2混配莠灭净对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000193
表156 A2混配嗪草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000194
表157 A2混配氨唑草酮对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000195
表158 A2混配绿麦隆对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000196
Figure PCTCN2020124587-appb-000197
表159 A2混配异丙隆对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000198
表160 A2混配除草定对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000199
表161 A2混配三氟草嗪对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000200
表162 A2混配cyclopyrimorate对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000201
表163 A2混配敌稗对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000202
表164 A2混配哒草特对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000203
表165 A2混配灭草松对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000204
表166 A2混配溴苯腈对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000205
Figure PCTCN2020124587-appb-000206
表167 A2混配仲丁灵对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000207
表168 A2混配二甲戊灵对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000208
表169 A2混配丁草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000209
表170 A2混配丙草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000210
表171 A2混配精异丙甲草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000211
表172 A2混配氟噻草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000212
表173 A2混配砜吡草唑对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000213
表174 A2混配莎稗磷对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000214
表175 A2混配苄草丹对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000215
表176 A2混配禾草敌对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000216
表177 A2混配禾草丹对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000217
表178 A2混配二氯喹啉酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000218
表179 A2混配氯氟吡氧乙酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000219
表180 A2混配氟氯吡啶酯对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000220
表181 A2混配三氯吡氧乙酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000221
表182 A2混配二氯吡啶酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000222
表183 A2混配氨氯吡啶酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000223
表184 A2混配氯氨吡啶酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000224
表185 A2混配麦草畏对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000225
表186 A2混配氯氟吡啶酯对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000226
表187 A2混配2-甲基-4-氯苯氧乙酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000227
Figure PCTCN2020124587-appb-000228
表188 A2混配环丙嘧啶酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000229
表189 A2混配草甘膦对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000230
表190 A2混配草铵膦对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000231
表19 A2混配精草铵膦对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000232
表192 A2混配敌草快对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000233
表193 A2混配三嗪氟草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000234
表194 A2混配茚嗪氟草胺对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000235
Figure PCTCN2020124587-appb-000236
表195 A2混配噁嗪草酮对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000237
表196 A2混配环庚草醚对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000238
表197 A1钠盐混配三唑磺草酮对异型莎草的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000239
表198 A1钠盐混配氯氟吡啶酯对野慈姑的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000240
表199 A2钠盐混配敌稗对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000241
表200 A2钾盐混配莎稗磷对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000242
Figure PCTCN2020124587-appb-000243
表201 A2钾盐混配2-甲基-4-氯苯氧乙酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000244
表202 A2混配Fenquinotrione对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000245
表203 A2混配氟丁酰草胺对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000246
表204 A2混配氟啶草酮对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000247
表205 A2混配Bixlozone对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000248
表206 A2混配嗪吡嘧磺隆对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000249
Figure PCTCN2020124587-appb-000250
表207 A2混配精噁唑禾草灵对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000251
表208 A2混配氰氟草酯对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000252
表209 A2混配扑草净对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000253
表210 A2混配西草净对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000254
表211 A2混配辛酰溴苯腈对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000255
表212 A2混配氟硫草定对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000256
表213 A2混配苯噻酰草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000257
表214 A2混配四唑酰草胺对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000258
表215 A2混配氯氟吡氧乙酸异辛酯对丁香蓼的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000259
表216 A2混配2,4-二氯苯氧基乙酸对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000260
表217 A2混配磺草灵对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000261
表218 A2混配Tetflupyrolimet对马唐的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000262
表219 A2混配Fenoxasulfone对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000263
Figure PCTCN2020124587-appb-000264
表220 A2混配
Figure PCTCN2020124587-appb-000265
对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000266
表221 A2混配
Figure PCTCN2020124587-appb-000267
对泽泻的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000268
表222 A2混配Dimesulfazet对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000269
表223 A2混配Epyrifenacil对萤蔺的实际防效与联合作用评价
Figure PCTCN2020124587-appb-000270
C)大田示范
利用实施例1-68制得的除草组合物进行田间杂草效果试验。2017年在江西鄱阳试验点进行示范性推广试验。田间发生的杂草主要有：稗草、千金子、鸭舌草、异型莎草、丁香蓼等。
试验方法：茎叶处理--待杂草处于2-3叶期，手动喷雾器，兑水量30公斤/667m 2，采用茎叶喷雾均匀喷雾。具体试验药剂及剂量详见表224，小区面积20平方米，每处理重复3次。施药后20天调查防除效果见表224。
Figure PCTCN2020124587-appb-000271
表224所述复配组合物的大田示范效果情况
药剂 用药量(g a.i./ha) 株防效(％)
1.A1+硝磺草酮(4+1)可分散油悬浮剂 75 93.6
2.A1+苯唑草酮(3+1)可分散油悬浮剂 60 98.7
3.A1+双唑草酮(3+1)可分散油悬浮剂 60 97.6
4.A1+苯唑氟草酮(4+4)可分散油悬浮剂 120 92.2
5.A1+异噁唑草酮(4+4)可分散油悬浮剂 120 92.4
6.A1+异噁草松(4+4)可分散油悬浮剂 120 95.9
7.A1+吡嘧磺隆(4+2)可分散油悬浮剂 90 94.6
8.A1+五氟磺草胺(4+1)可分散油悬浮剂 75 95.8
9.A1+甲氧咪草烟(4+1)可分散油悬浮剂 75 91.1
10.A1+甲咪唑烟酸(4+1)可分散油悬浮剂 75 90.6
11.A1+双草醚(4+1)可分散油悬浮剂 75 95.6
12.A1+烯草酮(4+2)可分散油悬浮剂 90 90.5
13.A1+烯禾啶(4+2)可分散油悬浮剂 90 92.8
14.A1+精喹禾灵(4+2)可分散油悬浮剂 90 93.1
15.A1+乙氧氟草醚(3+1)可分散油悬浮剂 60 89.6
16.A1+噁草酮(3+1)可分散油悬浮剂 60 89.8
17.A1+丙炔噁草酮(3+1)可分散油悬浮剂 60 90.2
18.A1+莠去津(3+5)水悬浮剂 120 85.4
19.A1+特丁津(3+3)水悬浮剂 90 81.5
20.A1+敌稗(2+20)水悬浮剂 330 88.7
21.A1+灭草松(4+30)水悬浮剂 510 87.3
22.A1+仲丁灵(4+21)可分散油悬浮剂 375 88.4
23.A1+二甲戊灵(4+21)可分散油悬浮剂 375 95.7
24.A1+丁草胺(4+6)可分散油悬浮剂 150 90.1
25.A1+丙草胺(2+4)可分散油悬浮剂 90 92.9
26.A1+莎稗磷(4+2)可分散油悬浮剂 90 98.6
27.A1+二氯喹啉酸(2+10)可分散油悬浮剂 180 94.0
28.A1+氯氟吡氧乙酸(2+3)可分散油悬浮剂 75 92.5
29.A1+氯氟吡啶酯(3+1)可分散油悬浮剂 60 96.0
30.A1+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂 195 91.4
31.A1+草甘膦(4+16)水悬浮剂 300 94.4
32.A1+草铵膦(3+15)水悬浮剂 270 93.7
33.A1+敌草快(4+15)水悬浮剂 285 96.0
34.A1+环庚草醚(4+1)可分散油悬浮剂 75 90.8
35.A2+硝磺草酮(4+1)可分散油悬浮剂 60 96.4
36.A2+苯唑草酮(3+1)可分散油悬浮剂 48 99.7
37.A2+双唑草酮(3+1)可分散油悬浮剂 48 98.6
38.A2+苯唑氟草酮(4+4)可分散油悬浮剂 96 95.0
39.A2+异噁唑草酮(4+4)可分散油悬浮剂 96 95.2
40.A2+异噁草松(4+4)可分散油悬浮剂 96 98.8
41.A2+吡嘧磺隆(4+2)可分散油悬浮剂 72 97.4
42.A2+五氟磺草胺(4+1)可分散油悬浮剂 60 98.7
43.A2+甲氧咪草烟(4+1)可分散油悬浮剂 60 93.8
44.A2+甲咪唑烟酸(4+1)可分散油悬浮剂 60 93.3
45.A2+双草醚(4+1)可分散油悬浮剂 60 98.5
46.A2+烯草酮(4+2)可分散油悬浮剂 72 93.2
47.A2+烯禾啶(4+2)可分散油悬浮剂 72 95.6
48.A2+精喹禾灵(4+2)可分散油悬浮剂 72 95.9
49.A2+乙氧氟草醚(3+1)可分散油悬浮剂 48 92.3
50.A2+噁草酮(3+1)可分散油悬浮剂 48 92.5
51.A2+丙炔噁草酮(3+1)可分散油悬浮剂 48 92.9
52.A2+莠去津(3+5)水悬浮剂 96 88.0
53.A2+特丁津(3+3)水悬浮剂 72 83.9
54.A2+敌稗(2+20)水悬浮剂 264 91.4
55.A2+灭草松(4+30)水悬浮剂 408 89.9
56.A2+仲丁灵(4+21)可分散油悬浮剂 300 91.1
57.A2+二甲戊灵(4+21)可分散油悬浮剂 300 98.6
58.A2+丁草胺(4+6)可分散油悬浮剂 120 92.8
59.A2+丙草胺(2+4)可分散油悬浮剂 72 95.7
60.A2+莎稗磷(4+2)可分散油悬浮剂 72 99.6
61.A2+二氯喹啉酸(2+10)可分散油悬浮剂 144 96.8
62.A2+氯氟吡氧乙酸(2+3)可分散油悬浮剂 60 95.3
63.A2+氯氟吡啶酯(3+1)可分散油悬浮剂 48 98.9
64.A2+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂 156 94.1
65.A2+草甘膦(4+16)水悬浮剂 240 97.2
66.A2+草铵膦(3+15)水悬浮剂 216 96.5
67.A2+敌草快(4+15)水悬浮剂 228 98.9
68.A2+环庚草醚(4+1)可分散油悬浮剂 60 93.5
经过大量试验和探索，本发明意外地发现，所述组合物用于防除异型莎草、碎米莎草、鸭舌草、稻稗、野慈姑、萤蔺、丁香蓼、马唐、泽泻、稗草、千金子等杂草，具有令人惊讶的、意想不到的增效作用，这种增效作用在低剂量下表现更为显著，可降低用药量，降低对环境的污染，且合理复配降低了农用成本，对ALS、ACCase抑制剂抗性杂草高效，具有很好的应用前景。同时经过测试在小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等植物显示良好的选择性和优异的增效作用，可以开发成具有广泛市场价值的除草剂混剂。

Claims (10)

  1. 一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，包括除草有效量的活性成分A和活性成分B，其中，
    活性成分A为
    Figure PCTCN2020124587-appb-100001
    或其盐；
    活性成分B选自以下化合物及其盐/酯中的一种或多种：
    (1)HPPD抑制剂：磺草酮、硝磺草酮、苯唑草酮、环磺酮、氟吡草酮、呋喃磺草酮、双环磺草酮、双唑草酮、环吡氟草酮、三唑磺草酮、苯唑氟草酮、磺酰草吡唑、吡唑特、吡草酮、tolpyralate、fenquinotrione、异噁唑草酮、苄草唑、
    Figure PCTCN2020124587-appb-100002
    (2)PDS抑制剂：氟咯草酮、呋草酮、吡氟酰草胺、氟吡酰草胺、氟丁酰草胺、氟草敏、氟啶草酮；
    (3)DOXP抑制剂：异噁草松、bixlozone；
    (4)ALS抑制剂：苯磺隆、噻吩磺隆、苄嘧磺隆、吡嘧磺隆、噻酮磺隆、氯吡嘧磺隆、丙嗪嘧磺隆、嗪吡嘧磺隆、砜嘧磺隆、乙氧磺隆、嘧苯胺磺隆、氟唑磺隆、甲基二磺隆、烟嘧磺隆、甲酰胺磺隆、唑嘧磺草胺、氟酮磺草胺、五氟磺草胺、氯酯磺草胺、啶磺草胺、甲氧咪草烟、甲咪唑烟酸、灭草烟、嘧草醚、双氟磺草胺、环酯草醚、嘧啶肟草醚、丙苯磺隆、咪草烟、氯磺隆、醚磺隆、环丙嘧磺隆、酰嘧磺隆、醚苯磺隆、碘甲磺隆钠盐、氟啶嘧磺隆、氟吡磺隆、甲磺隆、三氟甲磺隆、磺酰磺隆、唑吡嘧磺隆、双草醚、磺草唑胺；
    (5)ACCase抑制剂：炔草酯、唑啉草酯、烯草酮、烯禾啶、精喹禾灵、肟草酮、吡氟禾草灵、高效氟吡甲禾灵、禾草灵、精噁唑禾草灵、氰氟草酯、环苯草酮、噁唑酰草胺、噁草酸；
    (6)PPO抑制剂：乙氧氟草醚、氟磺胺草醚、噁草酮、丙炔噁草酮、甲磺草胺、双唑草腈、丙炔氟草胺、环戊噁草酮、tiafenacil、苯嘧磺草胺、吡草醚、唑草酮、氟丙嘧草酯、氯氟草醚乙酯、乙羧氟草醚、三氟羧草醚、trifludimoxazin、嗪草酸甲酯、Epyrifenacil；
    (7)PSII抑制剂：莠去津、扑草净、西草净、特丁津、特丁净、莠灭净、异丙净、害草净、敌草净、西玛津、嗪草酮、乙嗪草酮、氨唑草酮、苯嗪草酮、氰草津、绿麦隆、异丙隆、敌草隆、氟草隆、利谷隆、丁噻隆、莎扑隆、绿谷隆、溴谷隆、草不隆、哒嗪醇、环嗪酮、异戊乙净、草达津、除草定、环草定、特草定、甲基苯噻隆、环草隆、异噁隆、甲氧隆、枯 草隆、三氟草嗪、Cyclopyrimorate、敌稗、哒草特、甜菜安、甜菜宁、灭草松、辛酰溴苯腈、溴苯腈、碘苯腈；
    (8)微管组装抑制剂：氟乐灵、仲丁灵、二甲戊灵、氟硫草定、乙丁烯氟灵、氨磺乐灵、氟草胺、噻草啶、拿草特、敌草索、抑草磷；
    (9)微管组合抑制剂：双酰草胺；
    (10)VLCFA抑制剂：乙草胺、丁草胺、丙草胺、异丙甲草胺、苯噻酰草胺、精异丙甲草胺、氟噻草胺、敌草胺、砜吡草唑、莎稗磷、二甲酚草胺、四唑酰草胺、三唑酰草胺、唑草胺、哌草磷、异丙草胺、甲草胺、吡唑草胺、毒草胺、烯草胺、Dimesulfazet、Fenoxasulfone；
    (11)脂类合成(非乙酰辅酶A羧化酶)抑制剂：苄草丹、禾草敌、禾草丹、呋草黄、乙氧呋草黄、野麦畏、灭草敌、丁草特、环草敌、哌草丹、戊草丹；
    (12)合成激素类：二氯喹啉酸、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、氟氯吡啶酯、三氯吡氧乙酸、二氯吡啶酸、氨氯吡啶酸、氯氨吡啶酸、麦草畏、氯氟吡啶酯、2-甲基-4-氯苯氧乙酸、2-甲基-4-氯-苯酚乙硫酯、MCPB、2-甲基-4-氯苯氧丙酸、2-甲基-4-氯苯氧乙酸钠、2-甲基-4-氯苯氧乙酸异辛酯、2,4-二氯苯氧乙酸丁酯、2,4-二氯苯氧乙酸异辛酯、2,4-二氯苯氧基乙酸、氯甲喹啉酸、2甲4氯二甲铵盐、2,4-滴丙酸、2,4-滴丁酸、草除灵、环丙嘧啶酸、
    Figure PCTCN2020124587-appb-100003
    (13)EPSPS抑制剂：草甘膦、草硫膦；
    (14)GS抑制剂：草铵膦、双丙氨膦、精草铵膦；
    (15)PSI抑制剂:百草枯、敌草快；
    (16)DHP抑制剂：磺草灵；
    (17)纤维素合成抑制剂：三嗪氟草胺、茚嗪氟草胺；
    (18)其他除草剂：噁嗪草酮、环庚草醚、茚草酮、二氯喹啉草酮、喹草酮、苄草隆、灭草隆、tetflupyrolimet。
  2. 根据权利要求1所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物中A、B的重量比为1:600～200:1和1:500～100:1；优选为1:300～80:1和1:200～60:1；更优选为1:150～50:1和1:120～30:1；进一步优选为1:100～20:1和1:80～15:1；更进一步优选为1:50～10:1、1:30～5:1、1:10～4:1和1:5～1:1。
  3. 根据权利要求1或2所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除 草组合物，其特征在于，所述除草组合物中A和B的质量百分含量占总量的1-95％，优选10-80％。
  4. 根据权利要求1至3任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物中还包括常规助剂。
  5. 根据权利要求4所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述常规助剂包括载体或表面活性剂。
  6. 根据权利要求1至5任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物进一步包括至少一种安全剂。
  7. 根据权利要求6所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述安全剂选自双苯噁唑酸、cyprosulfamide、吡唑解草酯、解毒喹、赤霉酸、furilazole、metcamifen中的一种或多种。
  8. 根据权利要求1至7任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。
  9. 如权利要求1至8任意一项所述包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物在防治杂草上的应用。
  10. 一种防治不想要的植物生长的方法，其包括将权利要求1至8任意一项所述包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物施用于植物、植物部位、植物种子或植物生长的区域。
PCT/CN2020/124587 2019-10-30 2020-10-29 包含n-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用 WO2021083245A1 (zh)

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