WO2021082666A1 - Maltose syrup-containing condensed milk and preparation method therefor - Google Patents

Maltose syrup-containing condensed milk and preparation method therefor Download PDF

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Publication number
WO2021082666A1
WO2021082666A1 PCT/CN2020/110773 CN2020110773W WO2021082666A1 WO 2021082666 A1 WO2021082666 A1 WO 2021082666A1 CN 2020110773 W CN2020110773 W CN 2020110773W WO 2021082666 A1 WO2021082666 A1 WO 2021082666A1
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maltose syrup
condensed milk
milk
syrup
white sugar
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PCT/CN2020/110773
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French (fr)
Chinese (zh)
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李锡安
梁世排
梁世赞
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熊猫乳品集团股份有限公司
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Publication of WO2021082666A1 publication Critical patent/WO2021082666A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/005Condensed milk; Sugared condensed milk
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/156Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners

Definitions

  • the invention relates to a milk product, in particular to a condensed milk containing maltose syrup and a preparation method thereof.
  • Condensed milk is a kind of dairy product. It is a viscous product made from fresh cow (goat) milk or reconstituted milk, with or without auxiliary materials, after sterilization and concentration. According to adding or not adding auxiliary materials, it is divided into: full fat evaporated milk, full fat sweetened condensed milk, flavored/modulated condensed milk, and formula condensed milk. Its characteristic is that it can be stored for a long time. Condensed milk is a kind of "condensed milk”. It is made by vacuum concentration or other methods to remove most of the water, and concentrate to about 25% to 40% of the original volume of dairy products, and then add 40% sucrose to cans.
  • sucrose in sweetened condensed milk should be ⁇ 45g/100g.
  • sucrose has a high osmotic pressure effect, thereby achieving the purpose of controlling microbial proliferation and long-term preservation of condensed milk.
  • many consumers are discouraged. This is mainly because people's living standards have improved, consumption awareness and health awareness have greatly increased, and the desire to eat well and healthy is also increasing. strong.
  • sucrose in condensed milk not only causes health problems for consumers, but because it is solid at room temperature and may bring risks of impurities such as metals, sugar and filtration processes need to be added during the production of condensed milk, thereby increasing production Links and increased costs. At the same time, sucrose tends to breed mites during storage, which increases biological hazards.
  • maltose syrup instead of sucrose as raw materials for production are mainly reflected in 4 aspects: 1. In terms of taste, maltose has a lower sweetness than sucrose and a more mellow taste, and syrup can be used in condensed milk products in any ratio with white sugar. Blending and using to achieve the best taste; 2. In terms of economy, maltose syrup exists in liquid form and can be directly blended and used without the need for sugar conversion technology, which reduces production costs. The replacement of white sugar by maltose syrup can reduce the market for white sugar. The impact of price fluctuations can greatly reduce costs at the same time; 3. In terms of production efficiency, the control system is simplified, one person can control the entire sugar supply system, and the line change is simple, and one beverage line can produce multiple products; 4.
  • the storage time of the syrup in the storage tank can be appropriately extended without worrying about food safety and quality issues such as microbial growth and discoloration.
  • the closed transportation container and pipeline ensure that the syrup is not cross-contaminated by the outside world.
  • maltose and sucrose are disaccharides, which can also maintain the high osmotic pressure characteristics of condensed milk products and control microbial value added.
  • the purpose of the present invention is to provide a condensed milk containing maltose syrup and a preparation method thereof in order to overcome the above-mentioned defects in the prior art.
  • the present invention provides a condensed milk containing maltose syrup, which is prepared from the following raw materials: liquid milk raw materials with a milk solid content of not more than 70%, white sugar, maltose syrup, monoglyceride and carrageenan;
  • the quality of white granulated sugar is 20-45% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan
  • the quality of maltose syrup is liquid milk raw materials, white sugar, maltose syrup, monoglyceride and 20 ⁇ 45% of the total mass of carrageenan
  • the mass of monoglyceride is 0.03 ⁇ 0.05% of the total mass of liquid milk raw material
  • the mass of carrageenan is liquid milk raw material
  • white 0.002 ⁇ 0.004% of the total mass of sugar, maltose syrup, monoglyceride and carrageenan is liquid milk raw material
  • the components contained in the condensed milk include: fat mass percentage ⁇ 8%, protein mass percentage ⁇ 4.6%, water mass percentage ⁇ 35%, acidity ⁇ 48°T, and sugar content of 68.0-72.0 Brix.
  • the condensed milk has a uniform milky white color, a glossy viscous semi-solid, a fine structure, a uniform texture, and a milky flavor.
  • the liquid milk raw material is selected from one or more of fresh milk, reconstituted milk or concentrated reconstituted milk.
  • the maltose syrup is prepared by the following method: using corn starch, rice starch, tapioca starch or potato starch as raw materials, crushing, sieving (70-80 mesh), mixing, and liquefying , Cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration and concentration;
  • the physical and chemical indicators of the maltose syrup Brix 70-80 Brix, pH 3.5-4.5, DE value 50-65, transmittance 90-99.
  • the conditions for the liquefaction are: using a high-temperature resistant ⁇ -amylase, a temperature of 90-100°C, an amount of enzyme added of 10-15 U/g, and a liquefaction time of 10-20 min;
  • the saccharification conditions are as follows: ⁇ -amylase and pullulanase are used, the temperature is 50-60°C, the pH is 3.5-4.5, the saccharification time is 40-50h, and ⁇ -amylase is added. The amount is 90 ⁇ 110U/g, and the amount of pullulanase is 15 ⁇ 45U/g;
  • the enzyme inactivation condition is 100°C for 5 min;
  • the conditions for the decolorization are: adding activated carbon of 1-2% by weight of the filtered liquid, and treating at 75-85°C for 30 minutes.
  • Maltose syrup is an important factor affecting the Maillard reaction.
  • the carbonyl compounds in maltose syrup, especially unsaturated aldehydes, are the easiest to react;
  • alkaline conditions are conducive to the progress of the Maillard reaction. Therefore, in the production process of the maltose syrup of the present invention, the production of carbonyl compounds can be reduced by controlling the process conditions while maintaining the pH at 3.5-4.5 under acidic conditions.
  • the present invention further provides a method for preparing the maltose syrup-containing condensed milk.
  • the liquid milk raw material with a milk solid content of not more than 70% is taken, and white sugar, maltose syrup, monoglyceride and carrageenan are added separately for mixing, and they are filtered in sequence , Homogenization, pasteurization, flash evaporation, concentration, and crystallization to obtain condensed milk containing maltose syrup. Subsequent processes such as filling can be carried out.
  • the temperature is maintained at 55-65° C. during mixing or batching, and the mixing or batching is carried out for 20-30 min.
  • the filtration adopts a double filtration method, and the filtration accuracy is required to be 40-80 mesh.
  • the homogenization process includes temperature: 65-75°C; pressure: 40-220bar.
  • the pasteurization conditions are: 92-98°C, flow rate 4-6m3/h.
  • the flash feed and discharge temperature of the flash concentration is adjusted according to the difference between the product dry matter and the discharge temperature.
  • the crystallization treatment conditions are: seed crystal addition amount 0.15-0.3 ⁇ , crystallization time ⁇ 3h, and crystallization temperature 25-30°C.
  • the condition for the subsequent filling process is to use iron cans for filling, with good packaging integrity, compactness ⁇ 50%, overlap rate ⁇ 50%, and cover hook integrity rate ⁇ 50%.
  • the invention prepares special syrup, which can partially replace the white sugar in the condensed milk, maintains good color, stable texture and high-quality flavor.
  • the present invention has the following advantages and beneficial effects:
  • maltose syrup is lower than that of sucrose, so it can increase the quality and taste
  • Figure 1 shows the results of the accelerated test.
  • left white granulated sugar
  • middle 50% syrup
  • right 25% syrup.
  • Figure 2 shows the comparison of changes in normal temperature for 2 months.
  • left whole white sugar
  • middle 25% syrup
  • right 50% syrup.
  • Figure 3 shows the comparison of changes in room temperature for 6 months.
  • left whole white sugar
  • middle 50% syrup
  • right 25% syrup.
  • Figure 4 shows the comparison of changes in normal temperature for 8 months.
  • left whole white sugar
  • middle 50% syrup
  • right 25% syrup.
  • Figure 5 shows the comparison of changes in normal temperature for 10 months.
  • left whole white sugar
  • middle 50% syrup
  • right 25% syrup.
  • Figure 6 shows the comparison of changes in 12 months at room temperature.
  • left whole white sugar
  • middle 50% syrup
  • right 25% syrup.
  • a condensed milk containing maltose syrup prepared from the following raw materials: liquid milk raw materials with a milk solids content of not more than 70%, white sugar, maltose syrup, monoglyceride and carrageenan; wherein the quality of white sugar is liquid milk raw materials,
  • the total mass of white sugar, maltose syrup, monoglyceride and carrageenan is 20-45%.
  • the mass of maltose syrup is 20-45% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan.
  • the quality of glycerin is 0.03-0.05% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan, and the quality of carrageenan is liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan. 0.002 ⁇ 0.004% of the total mass.
  • the components contained in the condensed milk include: fat mass percentage ⁇ 8%, protein mass percentage ⁇ 4.6%, moisture mass percentage ⁇ 35%, acidity ⁇ 48°T, and sugar content of 68.0-72.0 Brix.
  • the condensed milk has a uniform milky white color, a glossy viscous semi-solid, a fine structure, a uniform texture, and a milky flavor.
  • the liquid milk raw material is selected from one or more of fresh milk, reconstituted milk or concentrated reconstituted milk.
  • the maltose syrup is prepared by the following method: using corn starch, rice starch, tapioca starch or potato starch as raw materials, pulverizing, sieving (70-80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, and filtration , Decolorization, filtration, and concentration;
  • the liquefaction conditions are: use high-temperature resistant ⁇ -amylase, temperature 90-100 °C, enzyme amount 10-15 U/g, liquefaction time 10-20min;
  • the saccharification conditions The conditions are: use ⁇ -amylase, pullulanase, temperature 50-60°C, pH 3.5-4.5, saccharification time 40-50h, add ⁇ -amylase amount 90-110U/g, add pullulanase amount It is 15-45 U/g;
  • the enzyme inactivation condition is 100° C., 5 min;
  • the decolorization condition is: adding activated carbon of 1-2% by weight of the filtered liquid, and treating at
  • the physical and chemical indicators of the maltose syrup Brix 70-80 Brix, pH 3.5-4.5, DE value 50-65, transmittance 90-99.
  • the preparation method of the maltose syrup-containing condensed milk is to take liquid milk raw materials with a milk solids content of not more than 70%, add white sugar, maltose syrup, monoglyceride and carrageenan respectively for mixing, and then go through filtration, homogenization, Pasteurization, flash evaporation, concentration, and crystallization to obtain condensed milk containing maltose syrup. Subsequent processes such as filling can be carried out.
  • the temperature is maintained at 55-65°C during mixing or batching, and circulating stirring is carried out for 20-30 minutes during mixing or batching.
  • the filtration adopts the double filtration method, and the filtration accuracy is required to be 40 to 80 mesh.
  • the homogenization treatment includes temperature: 65-75°C; pressure: 40-220bar.
  • the pasteurization conditions are: 92-98°C, flow rate 4-6m3/h.
  • the flash feed and discharge temperature of the flash concentration is adjusted according to the difference between the product dry matter and the discharge temperature.
  • the crystallization treatment conditions are: seed crystal addition amount 0.15-0.3 ⁇ , crystallization time ⁇ 3h, crystallization temperature 25-30°C.
  • the condition for the subsequent filling process is to use iron cans for filling, with good packaging integrity, compactness ⁇ 50%, overlap rate ⁇ 50%, and cover hook integrity rate ⁇ 50%.
  • the required raw material formula: white sugar 44.5%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, and the balance is water.
  • the content of each component in the raw material is the percentage of the total mass of the raw material.
  • Preparation method Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70°C; pressure 120bar), pasteurization (95°C, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2 ⁇ , the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup.
  • follow-up can be filled with iron cans, with good packaging integrity, tightness ⁇ 50%, overlap rate ⁇ 50%, and cover hook integrity rate ⁇ 50%.
  • the required raw material formula: white sugar 22.25%, maltose syrup 30%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, the balance is water.
  • the content of each component in the raw material is the percentage of the total mass of the raw material.
  • Preparation method Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70°C; pressure 120bar), pasteurization (95°C, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2 ⁇ , the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup.
  • follow-up can be filled with iron cans, with good packaging integrity, tightness ⁇ 50%, overlap rate ⁇ 50%, and cover hook integrity rate ⁇ 50%.
  • the maltose syrup is prepared by the following method: corn starch is used as a raw material, and it is obtained after crushing, sieving (80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration, and concentration.
  • Maltose syrup among them, the steps of crushing, sieving, pulping, cooling, filtering, and concentration are all conventional steps. Conventional process conditions can be used.
  • the liquefaction conditions for preparing maltose syrup are: use high temperature resistant ⁇ - Amylase, temperature 95°C, enzyme amount 12U/g, liquefaction time 15min; saccharification conditions for preparing maltose syrup: use ⁇ -amylase, pullulanase, temperature 55°C, pH4.0, saccharification time 45h ,
  • the amount of ⁇ -amylase added is 100U/g, and the amount of pullulanase added is 30U/g;
  • the enzyme inactivation conditions for preparing maltose syrup are 100°C, 5min;
  • the conditions for decolorizing maltose syrup are: adding filtered liquid 1.5% by weight activated carbon, treated at 80°C for 30 minutes.
  • the physical and chemical indicators of the maltose syrup are: a sugar content of 75 Brix, a pH of 4.0, a DE value of 60, and a transmittance of 95.
  • the required raw material formula white sugar 33.38%, maltose syrup 14.83%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, the balance is water.
  • Preparation method Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70°C; pressure 120bar), pasteurization (95°C, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2 ⁇ , the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup.
  • follow-up can be filled with iron cans, with good packaging integrity, tightness ⁇ 50%, overlap rate ⁇ 50%, and cover hook integrity rate ⁇ 50%.
  • the maltose syrup is prepared by the following method: corn starch is used as a raw material, and it is obtained after crushing, sieving (80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration, and concentration.
  • Maltose syrup among them, the steps of crushing, sieving, pulping, cooling, filtering, and concentration are all conventional steps. Conventional process conditions can be used.
  • the liquefaction conditions for preparing maltose syrup are: use high temperature resistant ⁇ - Amylase, temperature 95°C, enzyme amount 12U/g, liquefaction time 15min; saccharification conditions for preparing maltose syrup: use ⁇ -amylase, pullulanase, temperature 55°C, pH4.0, saccharification time 45h ,
  • the amount of ⁇ -amylase added is 100U/g, and the amount of pullulanase added is 30U/g;
  • the enzyme inactivation conditions for preparing maltose syrup are 100°C, 5min;
  • the conditions for decolorizing maltose syrup are: adding filtered liquid 1.5% by weight activated carbon, treated at 80°C for 30 minutes.
  • the physical and chemical indicators of the maltose syrup are: a sugar content of 75 Brix, a pH of 4.0, a DE value of 60, and a transmittance of 95.
  • Example 1 Example 2
  • Example 3 White sugar 44.5 22.25 33.38
  • Viscosity* cp 12600 15,800 13,800 pH value 6.25 6.22 6.23
  • Viscosity* The testing equipment is Brookfield DVII, the conditions are 64 rotors, 1 revolution/min, and room temperature is about 25°C.
  • Test method The condensed milk samples obtained in Examples 1-3 were all placed in a room temperature environment, and the changes of the samples were observed for 2 months, 6 months, 8 months, 10 months, and 12 months, respectively.
  • the comparison of changes in normal temperature for 2 months is shown in Figure 2.
  • FIG 3 left: whole white sugar; middle: 50% syrup; right: 25% syrup.
  • the comparison of changes in normal temperature for 8 months is shown in Figure 4.

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Abstract

A maltose syrup-containing condensed milk and a preparation method therefor: taking a liquid milk raw material of which the solid content is no more than 70%, respectively adding white sugar, maltose syrup, monoglyceride, and carrageenan for mixing, sequentially undergoing filtration, homogenization, pasteurization, flash concentration, and crystallization to produce the maltose syrup-containing condensed milk. In order to reduce the amount of white sugar used in the condensed milk and the product sweetness, a specific variety of maltose syrup is used to partly replace the white sugar in the condensed milk, thus, in addition to ensuring the osmotic pressure of the condensed milk product, the sweetness of the product is reduced, a great color, stable texture, and excellent flavor are maintained; an observation of a sample over a shelf life period exceeding 12 months shows no significant color difference from a white sugar sample and stable overall quality.

Description

一种含麦芽糖浆的炼乳及其制备方法Condensed milk containing maltose syrup and preparation method thereof 技术领域Technical field
本发明涉及一种奶制品,尤其是涉及一种含麦芽糖浆的炼乳及其制备方法。The invention relates to a milk product, in particular to a condensed milk containing maltose syrup and a preparation method thereof.
背景技术Background technique
炼乳是一种乳制品,是以生鲜牛(羊)乳或复原乳为主要原料,添加或不添加辅料,经杀菌、浓缩,制成的粘稠态产品。按照添加或不添加辅料,分为:全脂淡炼乳、全脂加糖炼乳、调味/调制炼乳、配方炼乳。它的特点是可贮存较长时间。炼乳是“浓缩奶”的一种,经真空浓缩或其他方法除去大部分的水分,浓缩至原体积25%~40%左右的乳制品,再加入40%的蔗糖装罐制成的。按现行国家标准甜炼乳中的蔗糖含量应≤45g/100g,其蔗糖除了赋予炼乳的甜味外,更重要的是产生了高渗透压作用,从而达到了控制微生物增殖,长期保存炼乳的目的。然而由于炼乳中蔗糖含量偏高,令许多消费者望而却步,这主要是因为人们生活水平提高了,消费意识和健康意识也大大增强了,既要吃得好,又要吃得健康的愿望也越发强烈。故而既要保留甜炼乳的醇厚甜味,又要降低蔗糖含量,同时又不失抑制微生物的高渗透压作用,是当前国内,及至世界性的技术难题,也成为了目前甜炼乳最主要的关键技术。Condensed milk is a kind of dairy product. It is a viscous product made from fresh cow (goat) milk or reconstituted milk, with or without auxiliary materials, after sterilization and concentration. According to adding or not adding auxiliary materials, it is divided into: full fat evaporated milk, full fat sweetened condensed milk, flavored/modulated condensed milk, and formula condensed milk. Its characteristic is that it can be stored for a long time. Condensed milk is a kind of "condensed milk". It is made by vacuum concentration or other methods to remove most of the water, and concentrate to about 25% to 40% of the original volume of dairy products, and then add 40% sucrose to cans. According to current national standards, the content of sucrose in sweetened condensed milk should be ≤45g/100g. In addition to giving the sweetness of condensed milk, its sucrose has a high osmotic pressure effect, thereby achieving the purpose of controlling microbial proliferation and long-term preservation of condensed milk. However, due to the high content of sucrose in condensed milk, many consumers are discouraged. This is mainly because people's living standards have improved, consumption awareness and health awareness have greatly increased, and the desire to eat well and healthy is also increasing. strong. Therefore, maintaining the mellow and sweet taste of sweetened condensed milk while reducing the sucrose content while still inhibiting the high osmotic pressure of microorganisms is a current domestic and worldwide technical problem, and it has also become the most important key to sweetened condensed milk. technology.
炼乳中的蔗糖除了给消费者带来健康困扰外,由于其在常温条件下为固态以及可能会带来金属等杂质风险,因此在生产炼乳过程中需要增加化糖和过滤工艺,从而增加了生产环节和提高了成本。同时,蔗糖在贮存过程中容易滋生螨虫,增加了生物危害。The sucrose in condensed milk not only causes health problems for consumers, but because it is solid at room temperature and may bring risks of impurities such as metals, sugar and filtration processes need to be added during the production of condensed milk, thereby increasing production Links and increased costs. At the same time, sucrose tends to breed mites during storage, which increases biological hazards.
以麦芽糖浆代替蔗糖作为生产原料,其优势主要体现在4个方面:1、在口感方面,麦芽糖甜度相对于蔗糖较低,口感更醇厚,且糖浆可在炼乳产品中与白砂糖以任何比例调配使用,达到最佳口感;2、在经济方面,麦芽糖浆以液态形式存在,不需经过化糖工艺,可直接调配使用,降低了生产成本,麦芽糖浆替换白砂糖,可以减少白砂糖的市场价格波动带来的影响,同时可大幅降低成本;3、在生产效率方面,控制系统简化,一人可控制整个供糖系统,换线清洁简单,一条饮料线可以生产多种产品;4、在安全方面,可适当延长糖浆在储罐内的保存时间,而不必担 心微生物生长,变色等食品安全和质量问题,密闭的运输容器和管路确保了糖浆不受外界的交叉污染。麦芽糖和蔗糖均为二糖,同样可以保持炼乳产品的高渗透压特性,控制微生物增值。The advantages of using maltose syrup instead of sucrose as raw materials for production are mainly reflected in 4 aspects: 1. In terms of taste, maltose has a lower sweetness than sucrose and a more mellow taste, and syrup can be used in condensed milk products in any ratio with white sugar. Blending and using to achieve the best taste; 2. In terms of economy, maltose syrup exists in liquid form and can be directly blended and used without the need for sugar conversion technology, which reduces production costs. The replacement of white sugar by maltose syrup can reduce the market for white sugar. The impact of price fluctuations can greatly reduce costs at the same time; 3. In terms of production efficiency, the control system is simplified, one person can control the entire sugar supply system, and the line change is simple, and one beverage line can produce multiple products; 4. In terms of safety On the one hand, the storage time of the syrup in the storage tank can be appropriately extended without worrying about food safety and quality issues such as microbial growth and discoloration. The closed transportation container and pipeline ensure that the syrup is not cross-contaminated by the outside world. Both maltose and sucrose are disaccharides, which can also maintain the high osmotic pressure characteristics of condensed milk products and control microbial value added.
但是麦芽糖作为还原性糖,在炼乳生产过程中容易形成美拉德反应,从而影响产品色泽。However, as a reducing sugar, maltose easily forms Maillard reaction during the production of condensed milk, which affects the color of the product.
发明内容Summary of the invention
本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种含麦芽糖浆的炼乳及其制备方法。The purpose of the present invention is to provide a condensed milk containing maltose syrup and a preparation method thereof in order to overcome the above-mentioned defects in the prior art.
本发明的目的可以通过以下技术方案来实现:The purpose of the present invention can be achieved through the following technical solutions:
本发明提供一种含麦芽糖浆的炼乳,以下原料制备而成:乳固体含量不超过70%的液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶;The present invention provides a condensed milk containing maltose syrup, which is prepared from the following raw materials: liquid milk raw materials with a milk solid content of not more than 70%, white sugar, maltose syrup, monoglyceride and carrageenan;
其中,白砂糖的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,麦芽糖浆的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,单甘脂的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.03~0.05%,卡拉胶的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.002~0.004%。Among them, the quality of white granulated sugar is 20-45% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan, and the quality of maltose syrup is liquid milk raw materials, white sugar, maltose syrup, monoglyceride and 20~45% of the total mass of carrageenan, the mass of monoglyceride is 0.03~0.05% of the total mass of liquid milk raw material, white sugar, maltose syrup, monoglyceride and carrageenan, the mass of carrageenan is liquid milk raw material, white 0.002~0.004% of the total mass of sugar, maltose syrup, monoglyceride and carrageenan.
进一步地,所述炼乳所含成分包括:脂肪质量百分比≥8%,蛋白质量百分比≥4.6%,水分质量百分比≤35%,酸度≤48°T,糖度68.0-72.0Brix。Further, the components contained in the condensed milk include: fat mass percentage ≥ 8%, protein mass percentage ≥ 4.6%, water mass percentage ≤ 35%, acidity ≤ 48°T, and sugar content of 68.0-72.0 Brix.
进一步地,所述炼乳呈均匀的乳白色,为有光泽的粘稠半固体,组织细腻,质地均匀,具有乳香味。Further, the condensed milk has a uniform milky white color, a glossy viscous semi-solid, a fine structure, a uniform texture, and a milky flavor.
在本发明的一个实施方式中,所述液态乳原料选自鲜奶、复原乳或浓缩复原乳中的一种或多种。In one embodiment of the present invention, the liquid milk raw material is selected from one or more of fresh milk, reconstituted milk or concentrated reconstituted milk.
在本发明的一个实施方式中,所述麦芽糖浆采用以下方法制备得到:以玉米淀粉、大米淀粉、木薯淀粉或者马铃薯淀粉为原料,经粉碎、过筛(70~80目)、调浆、液化、冷却、糖化、灭酶、过滤、脱色、过滤、浓缩后得到;In one embodiment of the present invention, the maltose syrup is prepared by the following method: using corn starch, rice starch, tapioca starch or potato starch as raw materials, crushing, sieving (70-80 mesh), mixing, and liquefying , Cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration and concentration;
所述麦芽糖浆的理化指标:糖度70~80Brix,pH3.5~4.5,DE值50~65,透射比90~99。The physical and chemical indicators of the maltose syrup: Brix 70-80 Brix, pH 3.5-4.5, DE value 50-65, transmittance 90-99.
在本发明的一个实施方式中,所述液化的条件为:使用耐高温α-淀粉酶,温度90~100℃、加酶量10~15U/g,液化时间10~20min;In one embodiment of the present invention, the conditions for the liquefaction are: using a high-temperature resistant α-amylase, a temperature of 90-100°C, an amount of enzyme added of 10-15 U/g, and a liquefaction time of 10-20 min;
在本发明的一个实施方式中,所述糖化条件的条件为:使用β-淀粉酶、普鲁兰酶,温度50~60℃,pH 3.5~4.5,糖化时间40~50h,加β-淀粉酶量为90~110U/g,加普鲁兰酶量为15~45U/g;In one embodiment of the present invention, the saccharification conditions are as follows: β-amylase and pullulanase are used, the temperature is 50-60°C, the pH is 3.5-4.5, the saccharification time is 40-50h, and β-amylase is added. The amount is 90~110U/g, and the amount of pullulanase is 15~45U/g;
在本发明的一个实施方式中,所述灭酶的条件为100℃,5min;In one embodiment of the present invention, the enzyme inactivation condition is 100°C for 5 min;
在本发明的一个实施方式中,所述脱色的条件为:加入过滤后液体重量1-2%的活性炭,75~85℃下处理30min。In one embodiment of the present invention, the conditions for the decolorization are: adding activated carbon of 1-2% by weight of the filtered liquid, and treating at 75-85°C for 30 minutes.
麦芽糖浆是影响美拉德反应的重要因素,一、麦芽糖浆中的羰基类化合物,尤其是不饱和醛类,最容易发生反应;二、碱性条件有利于美拉德反应的进行。因此在本发明麦芽糖浆生产过程中,通过工艺条件的控制,降低羰基类化合物的产生,同时保持pH在3.5~4.5偏酸条件下进行。Maltose syrup is an important factor affecting the Maillard reaction. First, the carbonyl compounds in maltose syrup, especially unsaturated aldehydes, are the easiest to react; second, alkaline conditions are conducive to the progress of the Maillard reaction. Therefore, in the production process of the maltose syrup of the present invention, the production of carbonyl compounds can be reduced by controlling the process conditions while maintaining the pH at 3.5-4.5 under acidic conditions.
本发明进一步提供所述含麦芽糖浆的炼乳的制备方法,取乳固体含量不超过70%的液态乳原料,分别加入白砂糖、麦芽糖浆、单甘脂和卡拉胶进行混料,并依次经过过滤、均质、巴氏杀菌、闪蒸浓缩、结晶,得到含麦芽糖浆的炼乳。后续可以进行灌装等工序。The present invention further provides a method for preparing the maltose syrup-containing condensed milk. The liquid milk raw material with a milk solid content of not more than 70% is taken, and white sugar, maltose syrup, monoglyceride and carrageenan are added separately for mixing, and they are filtered in sequence , Homogenization, pasteurization, flash evaporation, concentration, and crystallization to obtain condensed milk containing maltose syrup. Subsequent processes such as filling can be carried out.
在本发明的一个实施方式中,混料或配料时保持温度55-65℃,混料或配料时进行循环搅拌20-30min。In one embodiment of the present invention, the temperature is maintained at 55-65° C. during mixing or batching, and the mixing or batching is carried out for 20-30 min.
在本发明的一个实施方式中,过滤采用双联过滤的方式,过滤的精度要求为40~80目。In one embodiment of the present invention, the filtration adopts a double filtration method, and the filtration accuracy is required to be 40-80 mesh.
在本发明的一个实施方式中,均质处理时包括温度:65-75℃;压力:40-220bar。In one embodiment of the present invention, the homogenization process includes temperature: 65-75°C; pressure: 40-220bar.
在本发明的一个实施方式中,巴氏杀菌的条件是:92-98℃,流量4-6m3/h。In one embodiment of the present invention, the pasteurization conditions are: 92-98°C, flow rate 4-6m3/h.
在本发明的一个实施方式中,闪蒸浓缩的闪蒸进料、出料温度根据产品干物质和出料温差进行调整。In one embodiment of the present invention, the flash feed and discharge temperature of the flash concentration is adjusted according to the difference between the product dry matter and the discharge temperature.
在本发明的一个实施方式中,结晶的处理条件为:晶种添加量0.15-0.3‰、结晶时间≥3h、结晶温度25-30℃。In one embodiment of the present invention, the crystallization treatment conditions are: seed crystal addition amount 0.15-0.3‰, crystallization time ≥ 3h, and crystallization temperature 25-30°C.
在本发明的一个实施方式中,后续进行灌装工艺的条件是采用铁罐灌装,包装完整性良好,紧密度≥50%、迭接率≥50%、盖钩完整率≥50%。In one embodiment of the present invention, the condition for the subsequent filling process is to use iron cans for filling, with good packaging integrity, compactness ≥50%, overlap rate ≥50%, and cover hook integrity rate ≥50%.
本发明为了解决麦芽糖在炼乳生产过程中容易形成美拉德反应的问题,配制特种糖浆,该糖浆可以部分替代炼乳中的白砂糖,保持良的好颜色,稳定的质构和优质的风味。In order to solve the problem that maltose is easy to form Maillard reaction in the condensed milk production process, the invention prepares special syrup, which can partially replace the white sugar in the condensed milk, maintains good color, stable texture and high-quality flavor.
与现有技术相比,本发明具有以下优点及有益效果:Compared with the prior art, the present invention has the following advantages and beneficial effects:
1、降低了炼乳中的蔗糖含量和甜度;1. Reduce the sucrose content and sweetness in condensed milk;
2、避免了原料中带入异物风险;2. Avoid the risk of foreign matter in the raw materials;
3、生产中减少了了化糖和过滤工艺,降低生产成本;3. Reduced sugar and filtration process during production, reducing production cost;
4、麦芽糖浆甜度比蔗糖低,因此可增加品质和口感;4. The sweetness of maltose syrup is lower than that of sucrose, so it can increase the quality and taste;
5、对样品超过12个月货架期观察,与白砂糖样品的颜色无显著差异,整体品质稳定。5. Observing the shelf life of the samples over 12 months, there is no significant difference in color from the white granulated sugar samples, and the overall quality is stable.
附图说明Description of the drawings
图1为加速试验结果,图1中,左:全白砂糖;中:50%糖浆;右:25%糖浆。Figure 1 shows the results of the accelerated test. In Figure 1, left: white granulated sugar; middle: 50% syrup; right: 25% syrup.
图2为常温2个月变化对比情况,图2中左:全白砂糖;中:25%糖浆;右:50%糖浆。Figure 2 shows the comparison of changes in normal temperature for 2 months. In Figure 2, left: whole white sugar; middle: 25% syrup; right: 50% syrup.
图3为常温6个月变化对比情况,图3中左:全白砂糖;中:50%糖浆;右:25%糖浆。Figure 3 shows the comparison of changes in room temperature for 6 months. In Figure 3, left: whole white sugar; middle: 50% syrup; right: 25% syrup.
图4为常温8个月变化对比情况,图4中左:全白砂糖;中:50%糖浆;右:25%糖浆。Figure 4 shows the comparison of changes in normal temperature for 8 months. In Figure 4, left: whole white sugar; middle: 50% syrup; right: 25% syrup.
图5为常温10个月变化对比情况,图5中左:全白砂糖;中:50%糖浆;右:25%糖浆。Figure 5 shows the comparison of changes in normal temperature for 10 months. In Figure 5, left: whole white sugar; middle: 50% syrup; right: 25% syrup.
图6为常温12个月变化对比情况,图6中左:全白砂糖;中:50%糖浆;右:25%糖浆。Figure 6 shows the comparison of changes in 12 months at room temperature. In Figure 6, left: whole white sugar; middle: 50% syrup; right: 25% syrup.
具体实施方式Detailed ways
一种含麦芽糖浆的炼乳,以下原料制备而成:乳固体含量不超过70%的液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶;其中,白砂糖的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,麦芽糖浆的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,单甘脂的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.03~0.05%,卡拉胶的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.002~0.004%。A condensed milk containing maltose syrup, prepared from the following raw materials: liquid milk raw materials with a milk solids content of not more than 70%, white sugar, maltose syrup, monoglyceride and carrageenan; wherein the quality of white sugar is liquid milk raw materials, The total mass of white sugar, maltose syrup, monoglyceride and carrageenan is 20-45%. The mass of maltose syrup is 20-45% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan. The quality of glycerin is 0.03-0.05% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan, and the quality of carrageenan is liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan. 0.002~0.004% of the total mass.
所述炼乳所含成分包括:脂肪质量百分比≥8%,蛋白质量百分比≥4.6%,水分质量百分比≤35%,酸度≤48°T,糖度68.0-72.0Brix。所述炼乳呈均匀的乳白色,为有光泽的粘稠半固体,组织细腻,质地均匀,具有乳香味。The components contained in the condensed milk include: fat mass percentage ≥ 8%, protein mass percentage ≥ 4.6%, moisture mass percentage ≤ 35%, acidity ≤ 48°T, and sugar content of 68.0-72.0 Brix. The condensed milk has a uniform milky white color, a glossy viscous semi-solid, a fine structure, a uniform texture, and a milky flavor.
所述液态乳原料选自鲜奶、复原乳或浓缩复原乳中的一种或多种。The liquid milk raw material is selected from one or more of fresh milk, reconstituted milk or concentrated reconstituted milk.
所述麦芽糖浆采用以下方法制备得到:以玉米淀粉、大米淀粉、木薯淀粉或者马铃薯淀粉为原料,经粉碎、过筛(70~80目)、调浆、液化、冷却、糖化、灭酶、过滤、脱色、过滤、浓缩后得到;所述液化的条件为:使用耐高温α-淀粉酶,温度90~100℃、加酶量10~15U/g,液化时间10~20min;所述糖化条件的条件为:使用β-淀粉酶、普鲁兰酶,温度50~60℃,pH 3.5~4.5,糖化时间40~50h,加β-淀粉酶量为90~110U/g,加普鲁兰酶量为15~45U/g;所述灭酶的条件为100℃,5min;所述脱色的条件为:加入过滤后液体重量1-2%的活性炭,75~85℃下处理30min。The maltose syrup is prepared by the following method: using corn starch, rice starch, tapioca starch or potato starch as raw materials, pulverizing, sieving (70-80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, and filtration , Decolorization, filtration, and concentration; the liquefaction conditions are: use high-temperature resistant α-amylase, temperature 90-100 ℃, enzyme amount 10-15 U/g, liquefaction time 10-20min; the saccharification conditions The conditions are: use β-amylase, pullulanase, temperature 50-60℃, pH 3.5-4.5, saccharification time 40-50h, add β-amylase amount 90-110U/g, add pullulanase amount It is 15-45 U/g; the enzyme inactivation condition is 100° C., 5 min; the decolorization condition is: adding activated carbon of 1-2% by weight of the filtered liquid, and treating at 75-85° C. for 30 min.
所述麦芽糖浆的理化指标:糖度70~80Brix,pH3.5~4.5,DE值50~65,透射比90~99。The physical and chemical indicators of the maltose syrup: Brix 70-80 Brix, pH 3.5-4.5, DE value 50-65, transmittance 90-99.
所述含麦芽糖浆的炼乳的制备方法,取乳固体含量不超过70%的液态乳原料,分别加入白砂糖、麦芽糖浆、单甘脂和卡拉胶进行混料,并依次经过过滤、均质、巴氏杀菌、闪蒸浓缩、结晶,得到含麦芽糖浆的炼乳。后续可以进行灌装等工序。The preparation method of the maltose syrup-containing condensed milk is to take liquid milk raw materials with a milk solids content of not more than 70%, add white sugar, maltose syrup, monoglyceride and carrageenan respectively for mixing, and then go through filtration, homogenization, Pasteurization, flash evaporation, concentration, and crystallization to obtain condensed milk containing maltose syrup. Subsequent processes such as filling can be carried out.
其中,混料或配料时保持温度55-65℃,混料或配料时进行循环搅拌20-30min。Among them, the temperature is maintained at 55-65°C during mixing or batching, and circulating stirring is carried out for 20-30 minutes during mixing or batching.
其中,过滤采用双联过滤的方式,过滤的精度要求为40~80目。Among them, the filtration adopts the double filtration method, and the filtration accuracy is required to be 40 to 80 mesh.
其中,均质处理时包括温度:65-75℃;压力:40-220bar。Among them, the homogenization treatment includes temperature: 65-75°C; pressure: 40-220bar.
其中,巴氏杀菌的条件是:92-98℃,流量4-6m3/h。Among them, the pasteurization conditions are: 92-98℃, flow rate 4-6m3/h.
其中,闪蒸浓缩的闪蒸进料、出料温度根据产品干物质和出料温差进行调整。Among them, the flash feed and discharge temperature of the flash concentration is adjusted according to the difference between the product dry matter and the discharge temperature.
其中,结晶的处理条件为:晶种添加量0.15-0.3‰、结晶时间≥3h、结晶温度25-30℃。Among them, the crystallization treatment conditions are: seed crystal addition amount 0.15-0.3‰, crystallization time ≥ 3h, crystallization temperature 25-30°C.
其中,后续进行灌装工艺的条件是采用铁罐灌装,包装完整性良好,紧密度≥50%、迭接率≥50%、盖钩完整率≥50%。Among them, the condition for the subsequent filling process is to use iron cans for filling, with good packaging integrity, compactness ≥50%, overlap rate ≥50%, and cover hook integrity rate ≥50%.
下面结合附图和具体实施例对本发明进行详细说明。The present invention will be described in detail below with reference to the drawings and specific embodiments.
实施例1Example 1
以白砂糖为主要原料的炼乳制备Preparation of condensed milk with white sugar as the main raw material
所需原料配方:白砂糖44.5%,全脂奶粉19.6%,植物油4.7%,乳清粉2.9%,单甘脂0.04%,卡拉胶0.003%,余量为水。原料中各成分的含量均为原料总质量的百分比。The required raw material formula: white sugar 44.5%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, and the balance is water. The content of each component in the raw material is the percentage of the total mass of the raw material.
制备方法:将原料进行混料,混料时保持温度60℃,混料时进行循环搅拌25min,并依次经过双联过滤(过滤的精度要求为40~80目)、均质(均质处理时 温度70℃;压力120bar)、巴氏杀菌(95℃,流量5m3/h)、闪蒸浓缩(闪蒸进料、出料温度根据产品干物质和出料温差进行调整)、结晶(晶种添加量0.2‰、结晶时间3.5h、结晶温度27℃),得到含麦芽糖浆的炼乳。后续可以采用铁罐灌装,包装完整性良好,紧密度≥50%、迭接率≥50%、盖钩完整率≥50%。Preparation method: Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70℃; pressure 120bar), pasteurization (95℃, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2‰, the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup. Follow-up can be filled with iron cans, with good packaging integrity, tightness ≥50%, overlap rate ≥50%, and cover hook integrity rate ≥50%.
实施例2Example 2
以麦芽糖浆代替50%白砂糖为主要原料的炼乳制备Preparation of condensed milk with maltose syrup instead of 50% white sugar as the main raw material
所需原料配方:白砂糖22.25%,麦芽糖浆30%,全脂奶粉19.6%,植物油4.7%,乳清粉2.9%,单甘脂0.04%,卡拉胶0.003%,余量为水。原料中各成分的含量均为原料总质量的百分比。The required raw material formula: white sugar 22.25%, maltose syrup 30%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, the balance is water. The content of each component in the raw material is the percentage of the total mass of the raw material.
制备方法:将原料进行混料,混料时保持温度60℃,混料时进行循环搅拌25min,并依次经过双联过滤(过滤的精度要求为40~80目)、均质(均质处理时温度70℃;压力120bar)、巴氏杀菌(95℃,流量5m3/h)、闪蒸浓缩(闪蒸进料、出料温度根据产品干物质和出料温差进行调整)、结晶(晶种添加量0.2‰、结晶时间3.5h、结晶温度27℃),得到含麦芽糖浆的炼乳。后续可以采用铁罐灌装,包装完整性良好,紧密度≥50%、迭接率≥50%、盖钩完整率≥50%。Preparation method: Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70℃; pressure 120bar), pasteurization (95℃, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2‰, the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup. Follow-up can be filled with iron cans, with good packaging integrity, tightness ≥50%, overlap rate ≥50%, and cover hook integrity rate ≥50%.
本实施例中,麦芽糖浆采用以下方法制备得到:以玉米淀粉为原料,经粉碎、过筛(80目)、调浆、液化、冷却、糖化、灭酶、过滤、脱色、过滤、浓缩后得到麦芽糖浆;其中,粉碎、过筛、调浆、冷却、过滤、浓缩的步骤均为常规步骤,采用常规工艺条件即可,需要说明的是制备麦芽糖浆的液化的条件为:使用耐高温α-淀粉酶,温度95℃、加酶量12U/g,液化时间15min;制备麦芽糖浆的糖化条件的条件为:使用β-淀粉酶、普鲁兰酶,温度55℃,pH4.0,糖化时间45h,加β-淀粉酶量为100U/g,加普鲁兰酶量为30U/g;制备麦芽糖浆的灭酶的条件为100℃,5min;制备麦芽糖浆的脱色的条件为:加入过滤后液体重量1.5%的活性炭,80℃下处理30min。本实施例中,所述麦芽糖浆的理化指标:糖度75Brix,pH4.0,DE值60,透射比95。In this embodiment, the maltose syrup is prepared by the following method: corn starch is used as a raw material, and it is obtained after crushing, sieving (80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration, and concentration. Maltose syrup; among them, the steps of crushing, sieving, pulping, cooling, filtering, and concentration are all conventional steps. Conventional process conditions can be used. It should be noted that the liquefaction conditions for preparing maltose syrup are: use high temperature resistant α- Amylase, temperature 95℃, enzyme amount 12U/g, liquefaction time 15min; saccharification conditions for preparing maltose syrup: use β-amylase, pullulanase, temperature 55℃, pH4.0, saccharification time 45h , The amount of β-amylase added is 100U/g, and the amount of pullulanase added is 30U/g; the enzyme inactivation conditions for preparing maltose syrup are 100°C, 5min; the conditions for decolorizing maltose syrup are: adding filtered liquid 1.5% by weight activated carbon, treated at 80°C for 30 minutes. In this embodiment, the physical and chemical indicators of the maltose syrup are: a sugar content of 75 Brix, a pH of 4.0, a DE value of 60, and a transmittance of 95.
实施例3Example 3
以麦芽糖浆代替25%白砂糖为主要原料的炼乳制备Preparation of condensed milk with maltose syrup instead of 25% white sugar as the main raw material
所需原料配方:白砂糖33.38%,麦芽糖浆14.83%,全脂奶粉19.6%,植物油4.7%,乳清粉2.9%,单甘脂0.04%,卡拉胶0.003%,余量为水。The required raw material formula: white sugar 33.38%, maltose syrup 14.83%, whole milk powder 19.6%, vegetable oil 4.7%, whey powder 2.9%, monoglyceride 0.04%, carrageenan 0.003%, the balance is water.
制备方法:将原料进行混料,混料时保持温度60℃,混料时进行循环搅拌 25min,并依次经过双联过滤(过滤的精度要求为40~80目)、均质(均质处理时温度70℃;压力120bar)、巴氏杀菌(95℃,流量5m3/h)、闪蒸浓缩(闪蒸进料、出料温度根据产品干物质和出料温差进行调整)、结晶(晶种添加量0.2‰、结晶时间3.5h、结晶温度27℃),得到含麦芽糖浆的炼乳。后续可以采用铁罐灌装,包装完整性良好,紧密度≥50%、迭接率≥50%、盖钩完整率≥50%。Preparation method: Mix the raw materials, keep the temperature at 60°C during mixing, circulate and stir for 25 minutes during mixing, and then go through double filtration (the filtration accuracy is required to be 40-80 mesh) and homogenization (for homogenization treatment) Temperature 70℃; pressure 120bar), pasteurization (95℃, flow rate 5m3/h), flash concentration (flash feed and discharge temperature are adjusted according to product dry matter and discharge temperature difference), crystallization (seed addition The amount is 0.2‰, the crystallization time is 3.5h, and the crystallization temperature is 27°C) to obtain condensed milk containing maltose syrup. Follow-up can be filled with iron cans, with good packaging integrity, tightness ≥50%, overlap rate ≥50%, and cover hook integrity rate ≥50%.
本实施例中,麦芽糖浆采用以下方法制备得到:以玉米淀粉为原料,经粉碎、过筛(80目)、调浆、液化、冷却、糖化、灭酶、过滤、脱色、过滤、浓缩后得到麦芽糖浆;其中,粉碎、过筛、调浆、冷却、过滤、浓缩的步骤均为常规步骤,采用常规工艺条件即可,需要说明的是制备麦芽糖浆的液化的条件为:使用耐高温α-淀粉酶,温度95℃、加酶量12U/g,液化时间15min;制备麦芽糖浆的糖化条件的条件为:使用β-淀粉酶、普鲁兰酶,温度55℃,pH4.0,糖化时间45h,加β-淀粉酶量为100U/g,加普鲁兰酶量为30U/g;制备麦芽糖浆的灭酶的条件为100℃,5min;制备麦芽糖浆的脱色的条件为:加入过滤后液体重量1.5%的活性炭,80℃下处理30min。本实施例中,所述麦芽糖浆的理化指标:糖度75Brix,pH4.0,DE值60,透射比95。In this embodiment, the maltose syrup is prepared by the following method: corn starch is used as a raw material, and it is obtained after crushing, sieving (80 mesh), slurrying, liquefaction, cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration, and concentration. Maltose syrup; among them, the steps of crushing, sieving, pulping, cooling, filtering, and concentration are all conventional steps. Conventional process conditions can be used. It should be noted that the liquefaction conditions for preparing maltose syrup are: use high temperature resistant α- Amylase, temperature 95℃, enzyme amount 12U/g, liquefaction time 15min; saccharification conditions for preparing maltose syrup: use β-amylase, pullulanase, temperature 55℃, pH4.0, saccharification time 45h , The amount of β-amylase added is 100U/g, and the amount of pullulanase added is 30U/g; the enzyme inactivation conditions for preparing maltose syrup are 100°C, 5min; the conditions for decolorizing maltose syrup are: adding filtered liquid 1.5% by weight activated carbon, treated at 80°C for 30 minutes. In this embodiment, the physical and chemical indicators of the maltose syrup are: a sugar content of 75 Brix, a pH of 4.0, a DE value of 60, and a transmittance of 95.
实施例1-3所得炼乳的相关性能数据如表1所示。The relevant performance data of the condensed milk obtained in Examples 1-3 are shown in Table 1.
表1实施例1-3所得炼乳的相关性能Table 1 Related properties of condensed milk obtained in Examples 1-3
原料raw material 实施例1Example 1 实施例2Example 2 实施例3Example 3
白砂糖White sugar 44.544.5 22.2522.25 33.3833.38
麦芽糖浆Maltose syrup ———— 30.0030.00 14.8314.83
黏度*,cpViscosity*, cp 1260012600 1580015,800 1380013,800
pH值pH value 6.256.25 6.226.22 6.236.23
水分活度Water activity 0.80580.8058 0.81060.8106 0.80890.8089
Brix,%Brix,% 71.571.5 71.871.8 71.771.7
粘度*:检测设备为Brookfield DVII,条件为64转子,1转/min,室温约25℃。Viscosity*: The testing equipment is Brookfield DVII, the conditions are 64 rotors, 1 revolution/min, and room temperature is about 25°C.
对实施例1-3所述炼乳进行性能测试Perform performance tests on the condensed milk described in Examples 1-3
1加速实验1 accelerated experiment
试验方法:将实施例1-3所得炼乳样品均置于37℃环境中,放置2个月,观察样品变化情况。加速试验结果如图1所示,图1中,左:全白砂糖;中:50%糖浆;右:25%糖浆。从图1可以看出,添加糖浆50%(右)和25%(中)替换样品与对比全白砂糖样品(左)的颜色无显著差异。Test method: All the condensed milk samples obtained in Examples 1-3 were placed in an environment of 37°C for 2 months, and the changes in the samples were observed. The results of the accelerated test are shown in Figure 1. In Figure 1, left: whole white sugar; middle: 50% syrup; right: 25% syrup. It can be seen from Figure 1 that there is no significant difference in color between the 50% (right) and 25% (middle) syrup replacement samples and the comparison whole white sugar sample (left).
2货架期考察实验2 Shelf life inspection experiment
试验方法:将实施例1-3所得炼乳样品均置于室温环境中,分别观察2个月、6个月、8个月、10个月和12个月的样品变化情况。常温2个月变化对比情况如图2所示,图2中,左:全白砂糖;中:25%糖浆;右:50%糖浆。从图2可以看出,添加糖浆50%(右)和25%(中)替换样品与对比全白砂糖样品(左)的颜色无显著差异。常温6个月变化对比情况如图3所示,图3中,左:全白砂糖;中:50%糖浆;右:25%糖浆。常温8个月变化对比情况如图4所示,图4中左:全白砂糖;中:50%糖浆;右:25%糖浆。从图3、4可以看出,添加糖浆50%替换样品(中),糖浆25%替换样品(右)与对比全白砂糖样品(左)颜色无显著差异。由长期的货架期观察可知,嘉吉特种糖浆替换部分白砂糖(糖浆25%和50%替换),与对比样品的颜色、质构状态无显著差异。常温10个月变化对比情况如图5所示,图5中左:全白砂糖;中:50%糖浆;右:25%糖浆。常温12个月变化对比情况如图6所示,图6中左:全白砂糖;中:50%糖浆;右:25%糖浆。从图5、图6可以看出,静置于室温的样品10个月和12个月,添加糖浆50%替换样品(中),糖浆25%替换样品(右)与对比全白砂糖样品(左)颜色无显著差异。由长期的货架期观察可知,嘉吉特种糖浆替换部分白砂糖(糖浆25%和50%替换),与对比样品的颜色、质构状态无显著差异。Test method: The condensed milk samples obtained in Examples 1-3 were all placed in a room temperature environment, and the changes of the samples were observed for 2 months, 6 months, 8 months, 10 months, and 12 months, respectively. The comparison of changes in normal temperature for 2 months is shown in Figure 2. In Figure 2, left: whole white sugar; middle: 25% syrup; right: 50% syrup. It can be seen from Figure 2 that there is no significant difference in color between the 50% (right) and 25% (middle) added syrup replacement samples and the comparison whole white sugar sample (left). The comparison of changes in room temperature for 6 months is shown in Figure 3. In Figure 3, left: whole white sugar; middle: 50% syrup; right: 25% syrup. The comparison of changes in normal temperature for 8 months is shown in Figure 4. In Figure 4, the left side: whole white sugar; middle: 50% syrup; right: 25% syrup. From Figures 3 and 4, it can be seen that the 50% syrup replacement sample (middle), the 25% syrup replacement sample (right) and the comparison whole white sugar sample (left) have no significant difference in color. From long-term shelf life observation, it can be seen that Cargill special syrup replaced part of white sugar (25% and 50% syrup replacement), and the color and texture state of the comparison sample were not significantly different. The comparison of changes in normal temperature for 10 months is shown in Figure 5. The left in Figure 5: whole white sugar; middle: 50% syrup; right: 25% syrup. The 12-month comparison of normal temperature changes is shown in Figure 6. The left side of Figure 6: whole white sugar; middle: 50% syrup; right: 25% syrup. It can be seen from Figure 5 and Figure 6 that the samples left at room temperature for 10 months and 12 months, 50% syrup replacement sample (middle), 25% syrup replacement sample (right) and comparison whole white sugar sample (left) ) There is no significant difference in color. From long-term shelf life observation, it can be seen that Cargill special syrup replaced part of white sugar (25% and 50% syrup replacement), and the color and texture state of the comparison sample were not significantly different.
上述的对实施例的描述是为便于该技术领域的普通技术人员能理解和使用发明。熟悉本领域技术的人员显然可以容易地对这些实施例做出各种修改,并把在此说明的一般原理应用到其他实施例中而不必经过创造性的劳动。因此,本发明不限于上述实施例,本领域技术人员根据本发明的揭示,不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。The foregoing description of the embodiments is to facilitate those of ordinary skill in the technical field to understand and use the invention. It is obvious that those skilled in the art can easily make various modifications to these embodiments, and apply the general principles described here to other embodiments without creative work. Therefore, the present invention is not limited to the above-mentioned embodiments. According to the disclosure of the present invention by those skilled in the art, all improvements and modifications made without departing from the scope of the present invention should fall within the protection scope of the present invention.

Claims (10)

  1. 一种含麦芽糖浆的炼乳,其特征在于,由以下原料制备而成:乳固体含量不超过70%的液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶;A condensed milk containing maltose syrup, characterized in that it is prepared from the following raw materials: liquid milk raw materials with a milk solids content of not more than 70%, white sugar, maltose syrup, monoglyceride and carrageenan;
    其中,白砂糖的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,麦芽糖浆的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的20~45%,单甘脂的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.03~0.05%,卡拉胶的质量为液态乳原料、白砂糖、麦芽糖浆、单甘脂和卡拉胶总质量的0.002~0.004%。Among them, the quality of white granulated sugar is 20-45% of the total mass of liquid milk raw materials, white sugar, maltose syrup, monoglyceride and carrageenan, and the quality of maltose syrup is liquid milk raw materials, white sugar, maltose syrup, monoglyceride and 20~45% of the total mass of carrageenan, the mass of monoglyceride is 0.03~0.05% of the total mass of liquid milk raw material, white sugar, maltose syrup, monoglyceride and carrageenan, the mass of carrageenan is liquid milk raw material, white 0.002~0.004% of the total mass of sugar, maltose syrup, monoglyceride and carrageenan.
  2. 根据权利要求1所述的一种含麦芽糖浆的炼乳,其特征在于,所述炼乳所含成分包括:脂肪质量百分比≥8%,蛋白质量百分比≥4.6%,水分质量百分比≤35%,酸度≤48°T,糖度68.0-72.0Brix。The condensed milk containing maltose syrup according to claim 1, wherein the components contained in the condensed milk include: fat mass percentage ≥ 8%, protein mass percentage ≥ 4.6%, moisture mass percentage ≤ 35%, acidity ≤ 48°T, Brix 68.0-72.0Brix.
  3. 根据权利要求1所述的一种含麦芽糖浆的炼乳,其特征在于,所述液态乳原料选自鲜奶、复原乳或浓缩复原乳中的一种或多种。The condensed milk containing maltose syrup according to claim 1, wherein the liquid milk raw material is selected from one or more of fresh milk, reconstituted milk or concentrated reconstituted milk.
  4. 根据权利要求1所述的一种含麦芽糖浆的炼乳,其特征在于,所述麦芽糖浆采用以下方法制备得到:以玉米淀粉、大米淀粉、木薯淀粉或者马铃薯淀粉为原料,经粉碎、过筛、调浆、液化、冷却、糖化、灭酶、过滤、脱色、过滤、浓缩后得到;The condensed milk containing maltose syrup according to claim 1, wherein the maltose syrup is prepared by the following method: using corn starch, rice starch, tapioca starch or potato starch as raw materials, crushing, sieving, After mixing, liquefaction, cooling, saccharification, enzyme inactivation, filtration, decolorization, filtration and concentration;
    所述麦芽糖浆的理化指标:糖度70~80Brix,pH3.5~4.5,DE值50~65,透射比90~99。The physical and chemical indicators of the maltose syrup: Brix 70-80 Brix, pH 3.5-4.5, DE value 50-65, transmittance 90-99.
  5. 根据权利要求4所述的一种含麦芽糖浆的炼乳,其特征在于,所述液化的条件为:使用耐高温α-淀粉酶,温度90~100℃、加酶量10~15U/g,液化时间10~20min;The condensed milk containing maltose syrup according to claim 4, characterized in that the conditions for liquefaction are: using high-temperature resistant α-amylase, temperature 90-100°C, enzyme amount 10-15 U/g, liquefaction Time 10~20min;
    所述糖化条件的条件为:使用β-淀粉酶、普鲁兰酶,温度50~60℃,pH 3.5~4.5,糖化时间40~50h,加β-淀粉酶量为90~110U/g,加普鲁兰酶量为15~45U/g;The conditions of the saccharification conditions are as follows: β-amylase and pullulanase are used, the temperature is 50-60°C, the pH is 3.5-4.5, the saccharification time is 40-50h, and the amount of β-amylase added is 90-110 U/g. The amount of pullulanase is 15~45U/g;
    所述灭酶的条件为100℃,5min;The enzyme-inactivating conditions are 100°C, 5 min;
    所述脱色的条件为:加入过滤后液体重量1-2%的活性炭,75~85℃下处理30min。The conditions for the decolorization are: adding activated carbon of 1-2% by weight of the filtered liquid, and treating at 75-85°C for 30 minutes.
  6. 如权利要求1所述含麦芽糖浆的炼乳的制备方法,其特征在于,取乳固体含量不超过70%的液态乳原料,分别加入白砂糖、麦芽糖浆、单甘脂和卡拉胶进 行混料,并依次经过过滤、均质、巴氏杀菌、闪蒸浓缩、结晶,得到含麦芽糖浆的炼乳。The method for preparing maltose syrup-containing condensed milk according to claim 1, wherein the liquid milk raw materials with a milk solids content of not more than 70% are taken, and white sugar, maltose syrup, monoglyceride and carrageenan are added separately for mixing. Then, it is filtered, homogenized, pasteurized, flashed and concentrated, and crystallized to obtain condensed milk containing maltose syrup.
  7. 根据权利要求6所述含麦芽糖浆的炼乳的制备方法,其特征在于,混料或配料时保持温度55-65℃,混料或配料时进行循环搅拌20-30min。The preparation method of maltose syrup-containing condensed milk according to claim 6, characterized in that the temperature is maintained at 55-65°C during mixing or ingredient, and the mixing or ingredient is cyclically stirred for 20-30 minutes.
  8. 根据权利要求6所述含麦芽糖浆的炼乳的制备方法,其特征在于,过滤采用双联过滤的方式,过滤的精度要求为40~80目。The preparation method of maltose syrup-containing condensed milk according to claim 6, characterized in that the filtration adopts a duplex filtration method, and the filtration accuracy is required to be 40-80 mesh.
  9. 根据权利要求6所述含麦芽糖浆的炼乳的制备方法,其特征在于,均质处理时包括温度:65-75℃;压力:40-220bar。The preparation method of maltose syrup-containing condensed milk according to claim 6, characterized in that the homogenization process includes temperature: 65-75°C; pressure: 40-220 bar.
  10. 根据权利要求6所述含麦芽糖浆的炼乳的制备方法,其特征在于,巴氏杀菌的条件是:92-98℃,流量4-6m 3/;结晶的处理条件为:晶种添加量0.15-0.3‰、结晶时间≥3h、结晶温度25-30℃。 The preparation method of maltose syrup-containing condensed milk according to claim 6, characterized in that the pasteurization conditions are: 92-98°C, the flow rate is 4-6m 3 /; the crystallization processing conditions are: the addition amount of seed crystals is 0.15- 0.3‰, crystallization time ≥3h, crystallization temperature 25-30℃.
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