WO2021082345A1 - Herbicidal composition comprising n-(1,3,4-oxadiazole-2-yl) aryl formamide compounds and application of herbicidal composition - Google Patents

Herbicidal composition comprising n-(1,3,4-oxadiazole-2-yl) aryl formamide compounds and application of herbicidal composition Download PDF

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WO2021082345A1
WO2021082345A1 PCT/CN2020/081646 CN2020081646W WO2021082345A1 WO 2021082345 A1 WO2021082345 A1 WO 2021082345A1 CN 2020081646 W CN2020081646 W CN 2020081646W WO 2021082345 A1 WO2021082345 A1 WO 2021082345A1
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彭学岗
张景远
赵德
崔琦
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江苏清原农冠杂草防治有限公司
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
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    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
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    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
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    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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Abstract

The present invention relates to the field of agricultural chemicals, and in particular, to a herbicidal composition comprising N-(1,3,4-oxadiazole-2-yl) aryl formamide compounds and an application of the herbicidal composition. The composition comprises herbicidally effective amounts of active ingredient A and active ingredient B. The active ingredient A is A1, A2, or salts thereof; the active ingredient B is selected from one or more of the following compounds and salts/esters thereof: an HPPD inhibitor, a PDS inhibitor, a DOXP inhibitor, an ALS inhibitor, an ACCase inhibitor, a PPO inhibitor, a PSII inhibitor, and a microtubule assembly inhibitor and the like. The composition can effectively prevent and eliminate the problems of sedge weeds such as Cyperus difformis, Cyperus microiria, and Scirpus juncoides Roxb, grassy weeds such as Echinochloa crusgalli, crab grass, barnyard grass, and moleplant seed, and broadleaf weeds such as Monochoria vaginalis, Sagittaria trifolia, false loosestrife, and rhizoma alismatis in crop fields, and has the characteristics of expanding a weed control spectrum, reducing an application amount, being capable of yielding a synergistic effect and solving the problem of resistant weeds, and the like.

Description

包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用Herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylformamide compound and application thereof 技术领域Technical field
本发明属于农药领域，具体涉及一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用。The invention belongs to the field of pesticides, and specifically relates to a herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylformamide compounds and applications thereof.
背景技术Background technique
化学除草是农田杂草防除中最为经济、有效的手段，但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂，容易造成杂草耐药和抗性演化等问题。除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点，是解决上述问题的最为有效的方法之一。如专利CN103596946A公开了N-(1,3,4-噁二唑-2-基)芳基甲酰胺及其作为除草剂的用途，而生产上仍需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。Chemical weed control is the most economical and effective method for the control of weeds in farmland. However, long-term continuous high-dose use of chemical herbicides of a single species or a single mode of action is likely to cause problems such as weed resistance and resistance evolution. Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems. For example, the patent CN103596946A discloses N-(1,3,4-oxadiazol-2-yl) arylformamide and its use as a herbicide, but the production still needs to develop high safety, broad herbicidal spectrum, and A variety of herbicidal compositions that produce synergistic effects and solve the problem of resistant weeds.
发明内容Summary of the invention
为解决现有技术中存在的上述问题，本发明提供一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用。该组合物能有效防除作物田中的异型莎草、碎米莎草、萤蔺等莎草科杂草，稻稗、马唐、稗草、千金子等禾本科杂草，以及鸭舌草、野慈姑、丁香蓼、泽泻等阔叶杂草问题，具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。In order to solve the above-mentioned problems in the prior art, the present invention provides a herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylformamide compounds and applications thereof. The composition can effectively prevent and control cyperaceae weeds such as special-shaped sedge, cardamine sedge, firefly, barnyardgrass, crabgrass, barnyardgrass, stephengrass and other gramineous weeds in crop fields, as well as duck's diffusa and wild grass. The problem of broad-leaved weeds such as Cigu, Polygonum syringae and Alisma orientalis has the characteristics of expanding the weed-killing spectrum, reducing the amount of application, being able to produce synergistic effects and solving resistant weeds.
一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition containing an N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compound, comprising a herbicidal effective amount of active ingredient A and active ingredient B, wherein,
活性成分A为
Figure PCTCN2020081646-appb-000001
或其盐； Active ingredient A is
Figure PCTCN2020081646-appb-000001
Or its salt;
活性成分B选自以下化合物及其盐/酯中的一种或多种：The active ingredient B is selected from one or more of the following compounds and their salts/esters:
(1)HPPD抑制剂：磺草酮(CAS号:99105-77-8)、硝磺草酮(CAS号:104206-82-8)、苯唑草酮(CAS号:210631-68-8)、环磺酮(CAS号:335104-84-2)、氟吡草酮(CAS号:352010-68-5)、呋喃磺草酮(CAS号:473278-76-1)、双环磺草酮(CAS号:156963-66-5)、双唑草酮(CAS号:1622908-18-2)、环吡氟草酮(CAS号:1855929-45-1)、三唑磺草酮(CAS号:1911613-97-2)、苯唑氟草酮(CAS号:1992017-55-6)、磺酰草吡唑(CAS号:365400-11-9)、吡唑特(CAS号:58011-68-0)、吡草酮(CAS号:82692-44-2)、tolpyralate(CAS号:1101132-67-5)、 fenquinotrione(CAS号:1342891-70-6)、异噁唑草酮(CAS号:141112-29-0)、苄草唑(CAS号:71561-11-0)、
Figure PCTCN2020081646-appb-000002
(1) HPPD inhibitors: sulcotrione (CAS number: 99105-77-8), mesotrione (CAS number: 104206-82-8), mesotrione (CAS number: 210631-68-8) , Cyclosulfone (CAS number: 335104-84-2), fluopyron (CAS number: 352010-68-5), fursotrione (CAS number: 473278-76-1), bicyclic sulcotrione (CAS number: 473278-76-1) CAS number: 156963-66-5), fentrazone (CAS number: 1622908-18-2), ciclopyr (CAS number: 1855929-45-1), trifentrazone (CAS number: 1911613-97-2), flufentrazone (CAS number: 1992017-55-6), sulfenylpyrazole (CAS number: 365400-11-9), pyrazolide (CAS number: 58011-68- 0), metazotrione (CAS number: 82692-44-2), tolpyralate (CAS number: 1101132-67-5), fenquinotrione (CAS number: 1342891-70-6), isoxaflutole (CAS number: 141112-29-0), Probenzazole (CAS Number: 71561-11-0),
Figure PCTCN2020081646-appb-000002
(2)PDS抑制剂：氟咯草酮(CAS号:61213-25-0)、呋草酮(CAS号:96525-23-4)、吡氟酰草胺(CAS号:83164-33-4)、氟吡酰草胺(CAS号:137641-05-5)、氟丁酰草胺(CAS号:113614-08-7)、氟草敏(CAS号:27314-13-2)、氟啶草酮(CAS号:59756-60-4)；(2) PDS inhibitors: flurochloridone (CAS number: 61213-25-0), fluridone (CAS number: 96525-23-4), diflufenican (CAS number: 83164-33-4) ), fluroxyfen (CAS number: 137641-05-5), fluroxypyr (CAS number: 1131614-08-7), fluroxypyr (CAS number: 27314-13-2), fluroxypyr Oxalidone (CAS number: 59756-60-4);
(3)DOXP抑制剂：异噁草松(CAS号:81777-89-1)、bixlozone(CAS号:81777-95-9)；(3) DOXP inhibitors: clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);
(4)ALS抑制剂：苯磺隆(CAS号:101200-48-0)、噻吩磺隆(CAS号:79277-27-3)、苄嘧磺隆(CAS号:83055-99-6)、吡嘧磺隆(CAS号:93697-74-6)、噻酮磺隆(CAS号:317815-83-1)、氯吡嘧磺隆(CAS号:100784-20-1)、丙嗪嘧磺隆(CAS号:570415-88-2)、嗪吡嘧磺隆(CAS号:868680-84-6)、砜嘧磺隆(CAS号:122931-48-0)、乙氧磺隆(CAS号:126801-58-9)、嘧苯胺磺隆(CAS号:213464-77-8)、氟唑磺隆(CAS号:181274-17-9)、甲基二磺隆(CAS号:208465-21-8)、烟嘧磺隆(CAS号:111991-09-4)、甲酰胺磺隆(CAS号:173159-57-4)、唑嘧磺草胺(CAS号:98967-40-9)、氟酮磺草胺(CAS号:874195-61-6)、五氟磺草胺(CAS号:219714-96-2)、氯酯磺草胺(CAS号:147150-35-4)、啶磺草胺(CAS号:422556-08-9)、甲氧咪草烟(CAS号:114311-32-9)、甲咪唑烟酸(CAS号:104098-48-8)、咪唑乙烟酸(CAS号:81385-77-5)、灭草烟(CAS号:81334-34-1)、嘧草醚(CAS号:147411-69-6)、双氟磺草胺(CAS号:145701-23-1)、环酯草醚(CAS号:135186-78-6)、嘧啶肟草醚(CAS号:168088-61-7)、丙苯磺隆(CAS号:145026-81-9)、咪草烟(CAS号:81335-77-5)、氯磺隆(CAS号:64902-72-3)、醚磺隆(CAS号:94593-91-6)、环丙嘧磺隆(CAS号:136849-15-5)、酰嘧磺隆(CAS号:120923-37-7)、醚苯磺隆(CAS号:82097-50-5)、碘甲磺隆钠盐(CAS号:144550-36-7)、氟啶嘧磺隆(CAS号:144740-54-5)、氟吡磺隆(CAS号:412928-75-7)、甲磺隆(CAS号:74223-64-6)、三氟甲磺隆(CAS号:142469-14-5)、磺酰磺隆(CAS号:141776-32-1)、唑吡嘧磺隆(CAS号:122548-33-8)、双草醚(CAS号:125401-92-5)、磺草唑胺(CAS号:139528-85-1)；(4) ALS inhibitors: tribensulfuron-methyl (CAS number: 101200-48-0), thifensulfuron-methyl (CAS number: 79277-27-3), bensulfuron-methyl (CAS number: 83055-99-6), Pyrimsulfuron (CAS No.: 93697-74-6), Thioxasulfuron (CAS No.: 317815-83-1), Chlorpyrisulfuron (CAS No. 100784-20-1), Promazine Sulfuron (CAS number: 570415-88-2), pyrisulfuron-methyl (CAS number: 868680-84-6), sulfonimsulfuron (CAS number: 122931-48-0), ethoxysulfuron (CAS number: 868680-84-6) :126801-58-9), sulfasulfuron (CAS number: 213464-77-8), fluzosulfuron (CAS number: 181274-17-9), methamsulfuron (CAS number: 208465-21) -8), Nicotinsulfuron (CAS Number: 111991-09-4), Carboxamide Sulfen-methyl (CAS Number: 173159-57-4), Flumesulfuron (CAS Number: 98967-40-9), Sulfentrazone (CAS number: 874195-61-6), Penoxsulam (CAS number: 219714-96-2), Chlorampurazine (CAS number: 147150-35-4), Penoxsulam (CAS number: 147150-35-4), Penoxsulam (CAS number: 219714-96-2), Methoxypyr (CAS number: 422556-08-9), imazamox (CAS number: 114311-32-9), imidazole nicotinic acid (CAS number: 104098-48-8), imidazolium nicotinic acid (CAS number: 81385) -77-5), mediaxan (CAS number: 81334-34-1), sulfentrazone (CAS number: 147411-69-6), sulfentrazone (CAS number: 145701-23-1), Cyfentrazone (CAS Number: 135186-78-6), Saflufenacil (CAS Number: 168088-61-7), Probensulfuron (CAS Number: 145026-81-9), Imazethapyr (CAS Number: 81335-77-5), Chlorsulfuron (CAS Number: 64902-72-3), Trisulfuron (CAS Number: 94593-91-6), Cyprosulfuron (CAS Number: 136849-15- 5), sulfamesulfuron-methyl (CAS number: 120923-37-7), triasulfuron-methyl (CAS number: 82097-50-5), iodosulfuron-methyl sodium salt (CAS number: 144550-36-7), Fluflusulfuron (CAS Number: 144740-54-5), Flufensulfuron (CAS Number: 41928-75-7), Metsulfuron (CAS Number: 74223-64-6), Triflusulfuron-methyl (CAS Number: 142464-14-5), Sulfosulfuron (CAS Number: 141776-32-1), Zolpyrimesulfuron (CAS Number: 122548-33-8), Bispyri-methyl (CAS Number: 125401) -92-5) , Sulfentrazone (CAS number: 139528-85-1);
(5)ACCase抑制剂：炔草酯(CAS号:105512-06-9)、唑啉草酯(CAS号:243973-20-8)、烯草酮(CAS号:99129-21-2)、烯禾啶(CAS号:74051-80-2)、精喹禾灵(CAS号:100646-51-3)、肟草酮(CAS号:87820-88-0)、吡氟禾草灵(CAS号:69806-50-4)、高效氟吡甲禾灵(CAS号:72619-32-0)、禾草灵(CAS号:51338-27-3)、精噁唑禾草灵(CAS号:113158-40-0)、氰氟草酯(CAS号:122008-85-9)、环苯草酮(CAS号:139001-49-3)、噁唑酰草胺(CAS号:256412-89-2)、 噁草酸(CAS号:111479-05-1)；(5) ACCase inhibitors: clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8), clethodim (CAS number: 99129-21-2), Enoxypyr (CAS number: 74051-80-2), quizalofop-ethyl (CAS number: 100646-51-3), oximetrazone (CAS number: 87820-88-0), difluoxyfop (CAS No. 69806-50-4), High-efficiency fluroxypyr (CAS No. 72619-32-0), Promethalin (CAS No. 51338-27-3), Fenoxaprop-p-ethyl (CAS No.: 113158-40-0), cyhalofop-butyl (CAS number: 122008-85-9), cyclofenone (CAS number: 139001-49-3), oxadifen (CAS number: 256412-89- 2) Oxoxalic acid (CAS number: 111479-05-1);
(6)PPO抑制剂：乙氧氟草醚(CAS号:42874-03-3)、氟磺胺草醚(CAS号:72178-02-0)、噁草酮(CAS号:19666-30-9)、丙炔噁草酮(CAS号:39807-15-3)、甲磺草胺(CAS号:122836-35-5)、双唑草腈(CAS号:158353-15-2)、丙炔氟草胺(CAS号:103361-09-7)、环戊噁草酮(CAS号:110956-75-7)、tiafenacil(CAS号:1220411-29-9)、苯嘧磺草胺(CAS号:372137-35-4)、吡草醚(CAS号:129630-19-9)、唑草酮(CAS号:128621-72-7)、氟丙嘧草酯(CAS号:134605-64-4)、氯氟草醚乙酯(CAS号:131086-42-5)、乙羧氟草醚(CAS号:77501-60-1)、三氟羧草醚(CAS号:50594-66-6)、trifludimoxazin(CAS号:1258836-72-4)、嗪草酸甲酯(CAS号:117337-19-6)；(6) PPO inhibitors: oxyfluorfen (CAS number: 42874-03-3), fomesafen (CAS number: 72178-02-0), oxadiazon (CAS number: 19666-30-9) ), Oxachlor (CAS Number: 39807-15-3), Sulfentrazone (CAS Number: 122836-35-5), Pafentrazone (CAS Number: 158353-15-2), Propyne Flumetsulam (CAS number: 103361-09-7), cyclopentoxazone (CAS number: 110956-75-7), tiafenacil (CAS number: 1220411-29-9), saflufenacil (CAS number) :372137-35-4), Metazachlor (CAS Number: 129630-19-9), Carfentrazone (CAS Number: 128621-72-7), Fluprofen-ethyl (CAS Number: 134605-64-4) ), acifluorfen ethyl (CAS number: 131086-42-5), acifluorfen (CAS number: 77501-60-1), acifluorfen (CAS number: 50594-66-6) , Trifludimoxazin (CAS number: 1258836-72-4), methyl oxalate (CAS number: 117337-19-6);
(7)PSII抑制剂：莠去津(CAS号:1912-24-9)、扑草净(CAS号:7287-19-6)、西草净(CAS号:1014-70-6)、特丁津(CAS号:5915-41-3)、特丁净(CAS号:886-50-0)、莠灭净(CAS号:834-12-8)、异丙净(CAS号:4147-51-7)、害草净(CAS号:845-52-3)、敌草净(CAS号:1014-69-3)、西玛津(CAS号:122-34-9)、嗪草酮(CAS号:21087-64-9)、乙嗪草酮(CAS号:64529-56-2)、氨唑草酮(CAS号:129909-90-6)、苯嗪草酮(CAS号:41394-05-2)、氰草津(CAS号:21725-46-2)、绿麦隆(CAS号:15545-48-9)、异丙隆(CAS号:34123-59-6)、敌草隆(CAS号:330-54-1)、氟草隆(CAS号:2164-17-2)、利谷隆(CAS号:330-55-2)、丁噻隆(CAS号:34014-18-1)、莎扑隆(CAS号:42609-52-9)、绿谷隆(CAS号:1746-81-2)、溴谷隆(CAS号:3060-89-7)、草不隆(CAS号:555-37-3)、哒嗪醇(CAS号:40020-01-7)、环嗪酮(CAS号:51235-04-2)、异戊乙净(CAS号:22936-75-0)、草达津(CAS号:1912-26-1)、除草定(CAS号:314-40-9)、环草定(CAS号:2164-08-1)、特草定(CAS号:5902-51-2)、甲基苯噻隆(CAS号:18691-97-9)、环草隆(CAS号:1982-49-6)、异噁隆(CAS号:55861-78-4)、甲氧隆(CAS号:19937-59-8)、枯草隆(CAS号:1982-47-4)、三氟草嗪(CAS号:1258836-72-4)、Cyclopyrimorate(CAS号:499231-24-2)、敌稗(CAS号:709-98-8)、哒草特(CAS号:55512-33-9)、甜菜安(CAS号:13684-56-5)、甜菜宁(CAS号:13684-63-4)、灭草松(CAS号:25057-89-0)、辛酰溴苯腈(CAS号:1689-99-2)、溴苯腈(CAS号:1689-84-5)、碘苯腈(CAS号:1689-83-4)；(7) PSII inhibitors: atrazine (CAS number: 1912-24-9), promethoxin (CAS number: 7287-19-6), xicaojing (CAS number: 1014-70-6), special Dingjin (CAS Number: 5915-41-3), Terbutryn (CAS Number: 886-50-0), Atmidine (CAS Number: 834-12-8), Isopropion (CAS Number: 4147- 51-7), Caojing (CAS Number: 845-52-3), Dicaojing (CAS Number: 1014-69-3), Simazin (CAS Number: 122-34-9), Trimethoprim (CAS number: 21087-64-9), ethazine (CAS number: 64529-56-2), amicarbazone (CAS number: 129909-90-6), fentrazone (CAS number: 41394) -05-2), cyanuron (CAS number: 21725-46-2), chlorotoluron (CAS number: 15545-48-9), isoproturon (CAS number: 34123-59-6), diuron (CAS number: 330-54-1), fluroxypyr (CAS number: 2164-17-2), liguron (CAS number: 330-55-2), buthirone (CAS number: 34014-18-1) , Sapuron (CAS No.: 42609-52-9), Lugulong (CAS No.: 1746-81-2), Bromaguron (CAS No.: 3060-89-7), Cabulong (CAS No.: 555-37-3), pyridazinol (CAS number: 40020-01-7), cyprozinone (CAS number: 51235-04-2), isoprene (CAS number: 22936-75-0), Kusadajin (CAS number: 1912-26-1), chloridin (CAS number: 314-40-9), cycladin (CAS number: 2164-08-1), tercuridin (CAS number: 5902 51-2), methylbenthirone (CAS number: 18691-97-9), cyclamate (CAS number: 1982-49-6), isoxarone (CAS number: 55861-78-4), A Oxalon (CAS Number: 19937-59-8), Cyclopyr (CAS Number: 1982-47-4), Triflurazine (CAS Number: 1258836-72-4), Cyclopyrimorate (CAS Number: 499231-24- 2), Dibaran (CAS number: 709-98-8), pyridate (CAS number: 55512-33-9), beetan (CAS number: 13684-56-5), beetinin (CAS number: 13684) -63-4), fenoxazone (CAS number: 25057-89-0), octanoyl bromoxynil (CAS number: 1689-99-2), bromoxynil (CAS number: 1689-84-5), Iodobenzonitrile (CAS number: 1689-83-4);
(8)微管组装抑制剂：氟乐灵(CAS号:1582-09-8)、仲丁灵(CAS号:33629-47-9)、二甲戊灵(CAS号:40487-42-1)、氟硫草定(CAS号:97886-45-8)、乙丁烯氟灵(CAS号:55283-68-6)、氨磺乐灵(CAS号:19044-88-3)、氟草胺(CAS号:1861-40-1)、噻草啶(CAS号:117718-60-2)、拿草特(CAS号:23950-58-5)、敌草索(CAS号:1861-32-1)、抑草磷(CAS号:36335-67-8)；(8) Inhibitors of microtubule assembly: trifluralin (CAS number: 1582-09-8), tributaline (CAS number: 33629-47-9), pendimethalin (CAS number: 40487-42-1) ), fluthiopyr (CAS number: 97886-45-8), buteneflurane (CAS number: 55283-68-6), metsulfalin (CAS number: 19044-88-3), fluroxypyr (CAS number: 19044-88-3) Amine (CAS number: 1861-40-1), dimethoprim (CAS number: 117718-60-2), nacorte (CAS number: 23950-58-5), diquat (CAS number: 1861-32) -1), Isophos (CAS number: 36335-67-8);
(9)微管组合抑制剂：双酰草胺(CAS号:16118-49-3)；(9) Microtubule combination inhibitor: fenacet (CAS number: 16118-49-3);
(10)VLCFA抑制剂：乙草胺(CAS号:34256-82-1)、丁草胺(CAS号:23184-66-9)、丙草胺(CAS号:51218-49-6)、异丙甲草胺(CAS号:87392-12-9)、苯噻酰草胺(CAS号:73250-68-7)、 精异丙甲草胺(CAS号:178961-20-1)、氟噻草胺(CAS号:142459-58-3)、敌草胺(CAS号:15299-99-7)、砜吡草唑(CAS号:447399-55-5)、莎稗磷(CAS号:64249-01-0)、二甲酚草胺(CAS号:87674-68-8)、四唑酰草胺(CAS号:158237-07-1)、三唑酰草胺(CAS号:212201-70-2)、唑草胺(CAS号:125306-83-4)、哌草磷(CAS号:24151-93-7)、异丙草胺(CAS号:86763-47-5)、甲草胺(CAS号:15972-60-8)、吡唑草胺(CAS号:67129-08-2)、毒草胺(CAS号:1918-16-7)、烯草胺(CAS号:106700-29-2)；(10) VLCFA inhibitors: acetochlor (CAS number: 34256-82-1), butachlor (CAS number: 23184-66-9), pretilachlor (CAS number: 51218-49-6), iso Metolachlor (CAS Number: 87392-12-9), Mefenacet (CAS Number: 73250-68-7), Refined Metolachlor (CAS Number: 178961-20-1), Fluoxachlor Metrachlor (CAS number: 142459-58-3), napachlor (CAS number: 15299-99-7), sulfonepyridin (CAS number: 447399-55-5), saraphos (CAS number: 64249) -01-0), Xylenfenacet (CAS Number: 87674-68-8), Tetrafenacet (CAS Number: 158237-07-1), Trifenacet (CAS Number: 212201-70) -2), carfentrazone (CAS number: 125306-83-4), mesofen (CAS number: 24151-93-7), propisochlor (CAS number: 86763-47-5), alachlor (CAS Number: 15972-60-8), Metatrachlor (CAS Number: 67129-08-2), Tetrachloride (CAS Number: 1918-16-7), Clethachlor (CAS Number: 106700-29- 2);
(11)脂类合成(非乙酰辅酶A羧化酶)抑制剂：苄草丹(CAS号:52888-80-9)、禾草敌(CAS号:2212-67-1)、禾草丹(CAS号:28249-77-6)、呋草黄(CAS号:68505-69-1)、乙氧呋草黄(CAS号:26225-79-6)、野麦畏(CAS号:2303-17-5)、灭草敌(CAS号:1929-77-7)、丁草特(CAS号:2008-41-5)、环草敌(CAS号:1134-23-2)、哌草丹(CAS号:61432-55-1)、戊草丹(CAS号:85785-20-2)；(11) Inhibitors of lipid synthesis (non-acetyl-CoA carboxylase): Promethazine (CAS No. 52888-80-9), He Caodi (CAS No. 2212-67-1), He Caodi (CAS No. 2212-67-1) CAS number: 28249-77-6), furfural yellow (CAS number: 68505-69-1), ethoxyfuralox yellow (CAS number: 26225-79-6), wild dicamba (CAS number: 2303-17- 5), Mie Caodi (CAS No.: 1929-77-7), Butachlor (CAS No.: 2008-41-5), Huan Caodi (CAS No.: 1134-23-2), Diachlor (CAS No.: 1134-23-2) No. 61432-55-1), Pencaodan (CAS No. 85785-20-2);
(12)合成激素类：二氯喹啉酸(CAS号:84087-01-4)、氯氟吡氧乙酸(CAS号:69377-81-7)、氯氟吡氧乙酸异辛酯(CAS号:81406-37-3)、氟氯吡啶酯(CAS号:943831-98-9)、三氯吡氧乙酸(CAS号:55335-06-3)、二氯吡啶酸(CAS号:1702-17-6)、氨氯吡啶酸(CAS号:1918-02-1)、氯氨吡啶酸(CAS号:150114-71-9)、麦草畏(CAS号:1918-00-9)、氯氟吡啶酯(CAS号:1390661-72-9)、2-甲基-4-氯苯氧乙酸(CAS号:94-74-6)、2-甲基-4-氯-苯酚乙硫酯(CAS号:25319-90-8)、MCPB(CAS号:94-81-5)、2-甲基-4-氯苯氧丙酸(CAS号:93-65-2)、2-甲基-4-氯苯氧乙酸钠(CAS号:3653-48-3)、2-甲基-4-氯苯氧乙酸异辛酯(CAS号:29450-45-1)、2,4-二氯苯氧乙酸丁酯(CAS号:94-80-4)、2,4-二氯苯氧乙酸异辛酯(CAS号:25168-26-7)、2,4-二氯苯氧基乙酸(CAS号:94-75-7)、氯甲喹啉酸(CAS号:90717-03-6)、2甲4氯二甲铵盐(CAS号:2039-46-5)、2,4-滴丙酸(CAS号:120-36-5)、2,4-滴丁酸(CAS号:94-82-6)、草除灵(CAS号:25059-80-7)、环丙嘧啶酸(CAS号:858956-08-8)；(12) Synthetic hormones: Quinclorac (CAS number: 84087-01-4), fluroxypyr (CAS number: 69377-81-7), fluroxypyr isooctyl (CAS number: 81406-37-3), fluclopyridine ester (CAS number: 943831-98-9), triclopyr (CAS number: 55335-06-3), diclopyridine acid (CAS number: 1702-17- 6), Ampirelic acid (CAS No.: 1918-02-1), Ampirelic acid (CAS No.: 150114-71-9), Dicamba (CAS No.: 1918-00-9), flupyridine ester (CAS number: 1390661-72-9), 2-methyl-4-chlorophenoxyacetic acid (CAS number: 94-74-6), 2-methyl-4-chloro-phenol ethyl thioester (CAS number: 25319-90-8), MCPB (CAS number: 94-81-5), 2-methyl-4-chlorophenoxypropionic acid (CAS number: 93-65-2), 2-methyl-4-chloro Sodium phenoxyacetate (CAS number: 3653-48-3), 2-methyl-4-chlorophenoxyacetate isooctyl (CAS number: 29450-45-1), 2,4-dichlorophenoxyacetate Esters (CAS Number: 94-80-4), Isooctyl 2,4-Dichlorophenoxyacetate (CAS Number: 25168-26-7), 2,4-Dichlorophenoxyacetic Acid (CAS Number: 94 -75-7), quinclorac (CAS number: 90717-03-6), 2 methyl 4 chlorodimethyl ammonium salt (CAS number: 2039-46-5), 2,4-dpropionic acid (CAS No.: 120-36-5), 2,4-D butyric acid (CAS No.: 94-82-6), Meclofen (CAS No.: 25059-80-7), Cipropyridine (CAS No.: 858956) -08-8);
(13)EPSPS抑制剂：草甘膦(CAS号:1071-83-6)、草硫膦(CAS号:81591-81-3)；(13) EPSPS inhibitors: glyphosate (CAS number: 1071-83-6), glufosinate (CAS number: 81591-81-3);
(14)GS抑制剂：草铵膦(CAS号:77182-82-2)、双丙氨膦(CAS号:35597-43-4)、精草铵膦(CAS号:35597-44-5)；(14) GS inhibitors: glufosinate-ammonium (CAS number: 77182-82-2), bialaphos (CAS number: 35597-43-4), glufosinate-ammonium (CAS number: 35597-44-5) ；
(15)PSI抑制剂:百草枯(CAS号:1910-42-5)、敌草快(CAS号:6385-62-2)；(15) PSI inhibitors: Paraquat (CAS Number: 1910-42-5), Diquat (CAS Number: 6385-62-2);
(16)DHP抑制剂：磺草灵(CAS号:3337-71-1)；(16) DHP inhibitor: sulfentrazone (CAS number: 3337-71-1);
(17)纤维素合成抑制剂：三嗪氟草胺(CAS号:131475-57-5)、茚嗪氟草胺(CAS号:950782-86-2)；(17) Inhibitors of cellulose synthesis: triazine (CAS number: 131475-57-5), indanazine (CAS number: 950782-86-2);
(18)其他除草剂：噁嗪草酮(CAS号:153197-14-9)、环庚草醚(CAS号:87818-31-3)、茚草酮(CAS号:133220-30-1)、二氯喹啉草酮(CAS号:130901-36-8)、喹草酮(CAS 号:1639426-14-4)、苄草隆(CAS号:99485-76-4)、灭草隆(CAS号:150-68-5)、tetflupyrolimet(CAS号:2053901-33-8)。(18) Other herbicides: oxazimone (CAS number: 153197-14-9), cyprofen (CAS number: 87818-31-3), indoxazone (CAS number: 133220-30-1) , Quinclofen (CAS Number: 130901-36-8), Quinazone (CAS Number: 1639426-14-4), Probenuron (CAS Number: 99485-76-4), Meturon (CAS No.: 150-68-5), tetflupyrolimet (CAS No.: 2053901-33-8).
在本说明书的上下文中，如果使用活性化合物的通用名称的缩写形式，则在每种情况下包括所有的常规衍生物，例如酯和盐，以及异构体，特别是光学异构体，特别是一种或多种市售形式。如果通用名称表示酯或盐，则在每种情况下还包括所有其他的常规衍生物，例如其他的酯和盐、游离酸和中性化合物，以及异构体，特别是光学异构体，特别是一种或多种市售形式。给出的化合物的化学名称表示至少一种被通用名称涵盖的化合物，通常是优选的化合物。在磺酰胺如磺酰脲的情况下，盐还包括通过阳离子与磺酰胺基团中的氢原子交换而形成的盐。例如，2甲4氯衍生物包含但不限于：2甲4氯钠盐、钾盐、二甲铵盐、异丙胺盐等，以及2甲4氯甲酯、乙酯、异辛酯、乙硫酯等；2,4-D衍生物包含但不限于：2,4-D盐如钠盐、钾盐、二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等，以及2,4-D酯如甲酯、乙酯、丁酯、异辛酯等。In the context of this specification, if the abbreviated form of the common name of the active compound is used, all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, especially One or more commercially available forms. If the generic name indicates an ester or salt, it also includes all other conventional derivatives in each case, such as other esters and salts, free acids and neutral compounds, as well as isomers, especially optical isomers, especially Is one or more commercially available forms. The chemical name of the given compound indicates at least one compound covered by the generic name, and is usually the preferred compound. In the case of sulfonamides such as sulfonylureas, salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2 methyl 4 chloro derivatives include but are not limited to: 2 methyl 4 chloride sodium salt, potassium salt, dimethyl ammonium salt, isopropylamine salt, etc., and 2 methyl 4 chloro methyl, ethyl, isooctyl ester, ethyl sulfide Esters, etc.; 2,4-D derivatives include but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc., and 2,4 -D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester, etc.
其中，A、B的重量比为1:600～200:1和1:500～100:1；优选为1:300～80:1和1:200～60:1；更优选为1:150～50:1和1:120～30:1；进一步优选为1:100～20:1和1:80～15:1；更进一步优选为1:50～10:1、1:30～5:1、1:10～4:1和1:5～1:1。Among them, the weight ratio of A and B is 1:600-200:1 and 1:500-100:1; preferably 1:300-80:1 and 1:200-60:1; more preferably 1:150- 50:1 and 1:120-30:1; more preferably 1:100-20:1 and 1:80-15:1; even more preferably 1:50-10:1, 1:30-5:1 , 1:10～4:1 and 1:5～1:1.
在一具体实施方案中，本发明还列出了下述组分A和组分B的特定组合：In a specific embodiment, the present invention also lists the following specific combinations of component A and component B:
Figure PCTCN2020081646-appb-000003
Figure PCTCN2020081646-appb-000003
Figure PCTCN2020081646-appb-000004
Figure PCTCN2020081646-appb-000004
Figure PCTCN2020081646-appb-000005
Figure PCTCN2020081646-appb-000005
Figure PCTCN2020081646-appb-000006
Figure PCTCN2020081646-appb-000006
Figure PCTCN2020081646-appb-000007
Figure PCTCN2020081646-appb-000007
Figure PCTCN2020081646-appb-000008
Figure PCTCN2020081646-appb-000008
Figure PCTCN2020081646-appb-000009
Figure PCTCN2020081646-appb-000009
Figure PCTCN2020081646-appb-000010
Figure PCTCN2020081646-appb-000010
Figure PCTCN2020081646-appb-000011
Figure PCTCN2020081646-appb-000011
Figure PCTCN2020081646-appb-000012
Figure PCTCN2020081646-appb-000012
在另一具体实施方案中，上述表格中组分A分别替换为相应的盐。In another specific embodiment, component A in the above table is replaced with the corresponding salt.
在本发明的上下文中，化合物的盐优选为各自的碱金属盐、碱土金属盐或铵盐(如二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等)的形式，优选为各自的碱金属盐的形式，更优选为各自的钠盐或钾盐的形式，最优选为各自的钠盐的形式。In the context of the present invention, the salt of the compound is preferably in the form of the respective alkali metal salt, alkaline earth metal salt or ammonium salt (such as dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc.), preferably each The form of the alkali metal salt of is more preferably the form of the respective sodium salt or potassium salt, and most preferably the form of the respective sodium salt.
所述除草组合物中A、B的质量百分含量占总量的1-95％，优选10-80％。The mass percentage of A and B in the herbicidal composition accounts for 1-95%, preferably 10-80% of the total.
所述除草组合物中还包含常规助剂，所述常规助剂包括载体、表面活性剂。The herbicidal composition also contains conventional adjuvants, and the conventional adjuvants include carriers and surfactants.
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的施用，该载体一般是惰性的且必须是农业上可接受的，特别是被处理的植物所接受。载体可以是固体的，如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等；或者液体的，如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。The term "carrier" herein refers to an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient. The carrier is generally inert and must be agriculturally acceptable, especially acceptable to the plants being treated. The carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon, liquefied gas, etc.
表面活性剂可包括乳化剂、分散剂或润湿剂，它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐，以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚，此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、木素亚硫酸盐废液，以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在，以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。The surfactant may include an emulsifier, dispersant or wetting agent, and it may be ionic or non-ionic. Examples that may be mentioned are the salts of polyacrylic acid, lignosulfonate, phenolsulfonic acid or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (in particular Alkylphenol or arylphenol) polymers, sulfosuccinates, taurine derivatives (especially taurine alkane esters) and alcohol phosphate esters or polyhydroxyethylated phenol phosphate esters, Alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl, heptadecyl and stearyl alcohols and sulfated fatty alcohols Glycol ether, in addition to naphthalene or naphthalene sulfonic acid and phenol and formaldehyde condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol or nonyl phenol, alkyl benzene Base polyethylene glycol ether, tributyl phenyl polyethylene glycol ether, tristearyl phenyl polyethylene glycol ether, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide condensate, ethoxy group Castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol polyethylene glycol ether acetal, sorbitol ester, lignin sulfite waste liquid, as well as protein, denatured protein, polysaccharide (such as Methyl cellulose), hydrophobically modified starch, polyvinyl alcohol, polycarboxylate, polyalkoxylate, polyvinylamine, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to facilitate the dispersion of the active ingredients in water and facilitate their proper application to plants.
上述组合物也可含有各种其他的组分，如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。The above composition may also contain various other components, such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants and polymers.
另外，本发明的组合物可以与以下活性物质混合，例如《世界农药新品种技术大全》，中国农业科学技术出版社，2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活性物质，(备注:化合物的名称，或者为根据国际标准化组织(ISO)的普通名称，或者为化学名称，适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔 草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、氯磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、 异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、三唑磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489，LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。In addition, the composition of the present invention can be mixed with the following active substances, such as "Encyclopedia of World Pesticide New Variety Technologies", China Agricultural Science and Technology Press, 2010.9 and known substances in the literature cited here. For example, the herbicide active substances mentioned below, (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, and the code when appropriate): acetochlor, butachlor, Alachlor, Propolachlor, Metolachlor, Refined Metolachlor, Pretilachlor, Tetrachlor, Metochlor, Napropionate, R-Naphtochlor, Propanochlor , Mefenacet, difenacet, diflufenican, chlorfenazone, flubutazone, bromobutyrazamide, dimethenamid, high-efficiency dimethenamid, ethoxylate Apifenacet, flufenacet, metolachlor, metazachlor, clomazone, high-efficiency wheat straw voltambufen, high-efficiency wheat straw vopropion ester, propenicamide, clenamid, butachlor, Ciprofen, Fometochlor, Enantholac, Ibutachlor, Propitrazone, Terbutachlor, Dimethochlor, Dimethochlor, Tolchlor, Trimethochlor, Chlorine Carbachlor, propargyl, propachlor, valericola, carbachlor, new Yanling, tricyclic chlorfenachlor, butenamid, formachlor, promethazine, quinolachlor, fenfluramide , Naprolamine, Acetolachlor, Naphthochlor, Fenoxamide, Mefentrazone, Promethazine, Mecrazol, Chlorophthalimide, Butamidine, Flumetazol, Atrazine, Simazine, promethazine, cyanochloride, sichuanjing, atrazine, promethazine, promethazine, fluroxypyr, terbutazone, terbutazone, triazine, fluroxypyr, cyproteren, glycine Protoxine, oxadine, tetradone, simatong, azide, diquat, isoprene, cyproterenol, meton, other dingjin, tributin, terbutin, methoxine Jing, cyanochloride, indosulfuron, colasin, atrtoton, metoxetone, glycyrrhizin, cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron-methyl, bensulfuron-methyl, chlorsulfuron-methyl, benzenesulfuron Trisulfuron, Thisulfuron-methyl, Pyrimsulfuron-methyl, Mesosulfuron-methyl, Iodosulfuron-methyl sodium salt, Formamisulfuron-methyl, Trisulfuron-methyl, Trisulfuron-methyl, Mesulfuron-methyl, Nicosulfuron-methyl , Sulfamesulfuron, sulfamesulfuron, ethoxysulfuron, ciprosulfuron, sulfonesulfuron, tetrazosulfuron, flazasulfuron, monosulfuron, monosulfuron, fluoro Zolsulfuron, fluflusulfuron-methyl, flufensulfuron-methyl, episulfuron-methyl, zoflusulfuron-methyl, flumisulfuron-methyl, propitrifosulfuron, trifluprosulfuron, sulfenylsulfuron, three Flufensulfuron, fluasulfuron-methyl, triflusulfuron-methyl, metsulfuron-methyl sodium salt, flufenuron-methyl, metsulfuron-methyl, sulfasulfuron-methyl, Propyrisulfuron (propyrisulfuron), pyripyrazine Sulfur-methyl, acifluorfen, fomesafen, lactofop-p-ethyl, oxyfluorfen, oxyfluorfen, cyflufen, aclofen, chloroflufen-ethyl, carbaryl Ether, fenflufen, methoxyfen, fenflufen, fluorfen, fenflufen, fenfen, chlorfenpyr, dimethyl fluoride, flufenoxafen, flufenopyr Ester, Halosafen, Chlorotoluron, Isoproturon, Liururon, Diuron, Saprouron, Flururon, Benthiuron, Tribenthiuron, Probenuron, Sulthiuron, Isoxauron, Tebuthiouron, clodinafop, chlorobromuron, metoxyuron, oxyuron, metoxyuron, bromosulfuron, methoxuron, chlorosulfuron, meturon, cycluron, Fenuron, trifluthuron, sulfuron, chloruron , Caowanlong, Isofuron, Cyclomethuron, Thiefuron, Buthiuron, Cyclomethuron, Parafluon, Metthiazolone, Protonate, Trimethylisourea, Oxazolon, Monisouron, Anisuron, Methiuron , Chloreturon, Tetraflon, Betanin, Betanin-ethyl ester, Betalan, Sulfentrazone, Teraline, Omatyl, Aniline, Chloropheniramine, Diclofenac, Mediafen, Chloromethalin , Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, butachlor, chlorprocarb, dimethoate, straw, dicamba, dimethoprim, chlorocarba, barnyard grass, ring grass enemy, oatmeal , Jundamid, ethionate, Pingcaodan, Kecaomeng, Promethoprim, Zhongcaodan, Sulfenoxan, Methiophene, Isopolinate, Methiobencarb, 2,4-D isooctyl butyl ester, 2 methyl 4 sodium chloride, 2,4-D isooctyl isooctyl ester, 2 methyl 4 chloro isooctyl ester, 2,4-D isooctyl sodium salt, 2,4-D isooctyl dimethylamine salt, 2 methyl 4 chloro ethyl thioester, 2 methyl 4 chloro, 2,4-D isooctyl propionate, high 2,4-D isooctyl propionate, 2,4-D isooctyl butyrate, 2 methyl 4-chloropropionic acid, 2-methyl 4-chloropropionate, 2-methyl 4-chlorobutyric acid, 2,4,5-dichloropropionic acid, 2,4,5-dichloropropionic acid, 2,4,5-dichlorobutyric acid, 2-methyl 4 chloramine salt, dicamba, imidacloprid, fenoxac, saysone, triclofenac, diclofenac, methicillin, dimethoprim, difluoxyp-ethyl, pyridoxine Propoxypyr, fluroxypyr, high-efficiency fluroxypyr, quizalofop, quizalofop-p-ethyl, fenoxaprop-p-ethyl, fenoxaprop-p-ethyl, oxachlor-butyl, cyhalofop-ethyl, oxazole Axachlor, clodinafop, thiazoxyprop-p-ethyl, propafen-diop-ethyl, pentoxyprop-p-ethyl, triflufop-oxime, clomazone, paraquat, diquat, sulfafenpyr, ethalofop-p-ethyl, Isoprofen, Methalpropalin, Ciproflurazin, Profenflurane, Ebuflurazin, Chloridefluren, Ethiflufen, Didilotin, Chloridedilotin, Methalpropalin, Pronidol , Glyphosate, saraphos, glufosinate-ammonium, methamidophos, glufosinate, piperphosate, bialaphos, disanphos, glufosinate, tridolin, valonate, dimethylamine Glufosinate, glufosinate, imazapyr, imazamox, imazaquin, imazamox, imazamox ammonium salt, imazamox, imazamox, fluroxypyr, fluroxypyr Isooctyl oxyacetate, diclopyralid, pyridine acid, piclopyroxyacetic acid, fluthiopyr, halolachlor, triclopyr, thiaclopyr, flupyridin, clopyralid, Fluroxypyr, butoxyethyl triclopyr, Cliodinate, sethoxydim, clethodim, thiadiazone, dimethoprim, cyclofenone, buclofen, oxatrione, pyran Oxalazin, Buthidazole, Mesotrione, Cyclozinone, Meclotrim, Ethazin, Ametridione, Amibuzin, Bromoxynil, Bromoxynil, Caprylyl iodobenzonitrile, Iodobenzonitrile, Dioxynil , Diphenylacetonitrile, difentrazone, acetonitrile, Iodobonil, flumetsulam, flumetsulam, penoxsulam, sulfentrazone, chlorfentrazone, flumetsulam, flumetsulam, flumetsulam, bispyrifen, Saflufenacil, cyfentrazone, sulfentrazone, sulfentrazone, bicyclic sulcotrione, mesotrione, sulcotrione, tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlor Methiozolin, Fenoxasulfone, Methiozolin, Fenoxasulfone, Metazachlor, Pyrazolate, Pyridoxine, Prozac, Metazachlor, Mechlorfenazone, Pyrasulfotole, Fenoxasulfone, Pyroxasulfone, Carfentrazone , Flufentrazone, chlorfenazone, amicarbazone, fentrazone, flufentrazone, sulfentrazone, Bencarbazone, difentrazone, fluprofen-ethyl, clomazone, clomazone , Cyclofen, Teroxalin, Flupropacil, Indoxacil, flufenoxalic acid, flumioxazin, clodinafop, phthalobenzyl ether, Flumezin, pentachlorophenol (sodium), dioxal, Tetra Phenol, tromethoxetate, pentonitrophenol, dinitrophenol, chloronitrophenol, dioxin, dioxin, oxadiazon, oxadiazon, penoxazone, flufentrazone, fenoxalic acid Ester, Tetrafentrazone, Fluridazep-ethyl, Fluroxypyr, Bromoatramine, Dimethachlor, Pyridoxazone, Fluridone, Trichlorfon, Pyridazole, Pyridafol, Quinclorac , Quinclorac, Bentasone, pyridachlor, oxazimione, chlordiazepoxide, clomazone, cyprofen, isoprofen, propylafen, indoxazone, chlorine Sodium, thatchquat, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, forage fast, bromophenol oxime, triazole sulfonate, metoxazole, furachlor, sulfachlor, sulfachlor , Sulfentrazone, chlorophthalic acid, flurochloridone, barnyardzein, acrolein, promethazine, dimethacin, oatester, thiadimethalin, mesamine, oxytodone, methoxyphenone , Saflufenacil, Phosphosinate, Trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, Methiophene, Cambendichlor, Cipronic acid , Thiocyanamide, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, pyrazolam, and furanolysis Oxazole, oxachlor, oxazole acid, dichloropropenamine, fluclopyridine, DOW fluclopyridine, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC- 330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482 , PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
所述除草组合物进一步包括至少一种安全剂，其选自：The herbicidal composition further includes at least one safener selected from:
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物，优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1，吡唑解草酯(mefenpyr-diethyl)，PM，第594-595页)，以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。a) Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds, the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl Ethyl-2-pyrazoline-3-carboxylate (S1-1, mefenpyr-diethyl, PM, p. 594-595), and described in, for example, WO91/07874 and PM (p. 594-595) 594-595 pages) related compounds.
b)二氯苯基吡唑羧酸衍生物，优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5)，以及记载于EP-A-333131和EP-A-269806中的相关化合物。b) Dichlorophenylpyrazole carboxylic acid derivatives, the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-Dichlorophenyl)-5-(1 ,1-Dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4), 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
c)三唑羧酸(S1)类化合物，优选的化合物为例如解草唑(fenchlorazole)，即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。c) Triazole carboxylic acid (S1) compounds, the preferred compound is, for example, fenchlorazole, namely 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1 , 2,4-Triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物，优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物，或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9，双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。d) 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid compound, preferably The compound is, for example, 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid Ethyl acid (S1-8) and related compounds described in WO91/08202, or 5,5-diphenyl-2-isoxazoline described in patent application (WO-A-95/07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-11).
e)8-喹啉氧基乙酸(S2)类化合物，优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1，解毒喹(cloquintocet-mexyl)，如PM(第195-196页)，(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2)，4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3)，1-烯丙基氧基丙-2-基(5-氯-8-喹啉氧基)乙酸酯(S2-4)，(5-氯-8-喹啉氧基)乙酸乙酯(S2-5)，(5-氯-8-喹啉氧基)乙酸甲酯(S2-6)，(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7)，2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8)，2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9)，以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。e) 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (pages 195-196), (1,3-dimethylbut-1-yl)(5-chloro-8-quinolinoxy)acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy) Yl) acetate (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5), (5-chloro-8-quinolinoxy) methyl acetate (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2-(2-propylene iminooxy)-1-ethyl (5-chloro-8- Quinolinoxy) acetate (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy) acetate (S2-9), and described in EP-A -86750, EP-A-94349 and EP-A-191736 or EP-A-0492366 related compounds.
f)(5-氯-8-喹啉氧基)丙二酸类化合物，优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。f) (5-Chloro-8-quinolinyloxy)malonic acid compounds, preferred compounds are, for example, (5-chloro-8-quinolinyloxy)diethyl malonate, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy)-malonate methyl ethyl ester and related compounds described in EP-A-0582198.
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物，例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acid active compounds, such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
h)嘧啶类活性化合物，例如“解草啶(fenclorim)”(PM，第386-387页)(＝4,6-二氯-2-苯基嘧啶)，h) Pyrimidine active compounds, such as "fenclorim" (PM, pages 386-387) (=4,6-dichloro-2-phenylpyrimidine),
i)二氯乙酰胺类活性化合物，其常用作苗前安全剂(作用于土壤的安全剂)，例如“二氯丙 烯胺(dichloromid)”(PM，第270-271页)(＝N,N-二烯丙基-2,2-二氯乙酰胺)，“AR-29148”(＝3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮，购自Stauffer)，“解草嗪(benoxacor)”(PM，第74-75页)(＝4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪)，“APPG-1292”(＝N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺，购自PPG Industries)，“ADK-24”(＝N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺，购自Sagro-Chem)，“AAD-67”或“AMON4660”(＝3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷，购自Nitrokemia或Monsanto)，“diclonon”或“ABAS145138”或“ALAB145138”(＝(＝3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷，购自BASF)，和“furilazol”或“AMON13900”(参见PM，482-483)(＝(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮)，i) Dichloroacetamide active compounds, which are often used as pre-emergence safeners (safeners acting on soil), such as "dichloromid" (PM, pages 270-271) (=N, N -Diallyl-2,2-dichloroacetamide), "AR-29148" (=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidinone, purchase From Stauffer), "benoxacor" (PM, pages 74-75) (=4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzo Oxazine), "APPG-1292" (=N-allyl-N[(1,3-dioxolane-2-yl)-methyl]dichloroacetamide, purchased from PPG Industries), "ADK -24" (=N-allyl-N-[(allylaminocarbonyl)-methyl]-dichloroacetamide, purchased from Sagro-Chem), "AAD-67" or "AMON4660" (=3 -Dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane, purchased from Nitrokemia or Monsanto), "diclonon" or "ABAS145138" or "ALAB145138" (=(=3-two Chloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonane, purchased from BASF), and "furilazol" or "AMON13900" (see PM, 482-483 )(=(RS)-3-Dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidinone),
j)二氯丙酮衍生物类活性化合物，例如，“AMG191”(CAS登记号96420-72-3)(＝2-二氯甲基-2-甲基-1,3-二氧戊环，购自Nitrokemia)，j) Active compounds of dichloroacetone derivatives, for example, "AMG191" (CAS Registration No. 96420-72-3) (=2-Dichloromethyl-2-methyl-1,3-dioxolane, purchased From Nitrokemia),
k)氧基亚氨基化合物类活性化合物，其被称为拌种材料，例如，“解草腈(oxabetrinil)”(PM，第689页)(＝(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，“氟草肟(fluxofenim)”(PM，第467-468页)(＝1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM，第983页)(＝(Z)-氰基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，k) Oxyimino compound-type active compounds, which are called seed dressing materials, for example, "oxabetrinil" (PM, page 689) (=(Z)-1,3-dioxolane -2-ylmethoxyimino (phenyl)acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor, "fluxofenim" (PM, Pages 467-468) (=1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3-dioxolane-2-ylmethyl)- Oxime, which is called a safener in seed dressing to prevent metolachlor damage, and "cyometrinil" or "A-CGA-43089" (PM, p. 983) (=(Z)-cyanomethoxyimino(phenyl)acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor,
l)噻唑羧酸酯类活性化合物，其被称为拌种材料，例如“解草安(flurazol)”(PM，第450-451页)(＝2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯)，其在拌种中被称为安全剂，以防止甲草胺(alachlor)和异丙甲草胺的损害，1) Thiazole carboxylate active compounds, which are called seed dressing materials, such as "flurazol" (PM, pages 450-451) (=2-chloro-4-trifluoromethyl-1 , 3-thiazole-5-carboxylic acid benzyl ester), which is called a safener in seed dressing to prevent the damage of alachlor and metolachlor,
m)萘二羧酸衍生物类活性化合物，其被称为拌种剂，例如“萘二甲酸酐”(PM，第1009-1010页)(＝1,8-萘二甲酸酐)，其在玉米拌种中称为安全剂，以防止硫代氨基甲酸酯除草剂的损害，m) Active compounds of naphthalenedicarboxylic acid derivatives, which are called seed dressing agents, such as "naphthalenedicarboxylic acid anhydride" (PM, pages 1009-1010) (=1,8-naphthalenedicarboxylic acid anhydride), which is It is called a safener in corn dressing to prevent the damage of thiocarbamate herbicides.
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物，例如，“ACL304415”(CAS登记号31541-57-8)(＝2-84-羧基色满-4-基)乙酸，购自AmericanCyanamid)，n) Active compounds of chromaneacetic acid derivatives, for example, "ACL304415" (CAS registration number 31541-57-8) (=2-84-carboxychroman-4-yl)acetic acid, purchased from AmericanCyanamid),
o)除了对有害植物具有除草作用外还对植物具有安全剂作用的活性化合物，例如，“哌草丹(dimepiperate)”或“AMY-93”(PM，第302-303页)(＝S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯)，“杀草隆(daimuron)”或“ASK23”(PM，第247页)(＝1-(1-甲基-1-苯基乙基)-3-对甲苯基脲)，“苄草隆(cumyluron)”＝“AJC-940”(＝3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲，参见JP-A-60087254)，“苯甲酮(methoxyphenon)”或“ANK049”(＝3,3'-二甲基-4-甲氧基-二苯甲酮)，“CSB”(＝1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4，购自Kumiai)。o) In addition to having herbicidal effects on harmful plants, active compounds that also have safener effects on plants, for example, "dimepiperate" or "AMY-93" (PM, pages 302-330) (=S- 1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "daimuron" or "ASK23" (PM, p. 247) (=1-(1-methyl -1-phenylethyl)-3-p-tolylurea), "cumyluron (cumyluron)"="AJC-940" (=3-(2-chlorophenylmethyl)-1-(1 -Methyl-1-phenyl-ethyl)urea, see JP-A-60087254), "methoxyphenon" or "ANK049" (=3,3'-dimethyl-4-methoxy -Benzophenone), "CSB" (= 1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Registry Number 54091-06-4, purchased from Kumiai).
所述安全剂优选双苯噁唑酸(CAS：163520-33-0)、cyprosulfamide(CAS：221667-31-8)、吡唑解草酯(CAS：135590-91-9)、解毒喹(CAS：99607-70-2)、赤霉酸(CAS：7-06-5)、furilazole(CAS：121776-33-8)、metcamifen(CAS：129531-12-0)中的一种或多种。The safener is preferably dibenzoxazole acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolone (CAS: 135590-91-9), detox quinine (CAS : 99607-70-2), one or more of gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备，即将活性物质与液体溶剂或固体载体混合后，再加入表面活性剂如分散剂、稳定剂、湿润剂、粘合剂、消泡剂等中的一种或几种。The composition of the present invention can be diluted or used directly by the user before use. The formulation can be prepared by the usual processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, then adding one or more of surfactants such as dispersing agents, stabilizers, wetting agents, adhesives, defoamers, etc. Kind.
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。The specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules (dry suspensions), water emulsions, and microemulsions.
简而言之，本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。随着外部条件的变化，有效成分的使用量也不同，外部条件为，例如温度、湿度、使用的除草剂的性质等等。它可以有大的变化幅度，例如在0.001到1.0kg/ha之间，或更多的活性物质，但优选在0.005到750g/ha之间，特别是在0.005到500g/ha之间。In short, the composition of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations. As the external conditions change, the amount of effective ingredients used is also different. The external conditions are, for example, temperature, humidity, and the nature of the herbicide used. It can have a large variation range, for example, between 0.001 and 1.0 kg/ha, or more active substances, but preferably between 0.005 and 750 g/ha, especially between 0.005 and 500 g/ha.
本发明还提供一种所述除草组合物在防治杂草上的应用；以及提供一种防治不想要的植物生长的方法，其包括将所述除草组合物施用于植物、植物部位、植物种子或植物生长的区域。The present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling unwanted plant growth, which comprises applying the herbicidal composition to plants, plant parts, plant seeds or The area where the plant grows.
另外，本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上，即施用于杂草，特别是杂草侵扰或易侵扰影响的表面上。In addition, the composition of the present invention can be applied to the leaves of plants to be treated by spraying, that is, applied to weeds, especially on the surfaces that are infested or easily affected by weeds.
当施用本发明的除草组合物时，获得了预料不到的增效效果，并且除草活性比使用单个除草剂的活性预期总和，以及单个除草剂的活性更为显著。增效效果表现为施用量减少、更宽的杂草控制谱、除草作用更快、更持久，这些特性是杂草控制实践过程中所需要的。就所描述的特性来说，这些新组合物明显地优越于现有的除草剂，达到减量使用，对环境更友好。When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities of a single herbicide and the activity of a single herbicide. The synergistic effect is manifested by reduced application rate, wider weed control spectrum, faster and more lasting weeding action, these characteristics are required in the process of weed control practice. In terms of the described characteristics, these new compositions are significantly superior to existing herbicides, achieve reduced usage, and are more environmentally friendly.
本发明的增效除草组合物还具有下述优点:The synergistic herbicidal composition of the present invention also has the following advantages:
(1)本发明的组合物为环境友好型，在环境中均易于降解。(1) The composition of the present invention is environmentally friendly and is easily degraded in the environment.
(2)本发明的除草组合物成本低、使用方便，其推广应用有巨大的经济效益和社会效益。(2) The herbicidal composition of the present invention has low cost and convenient use, and its popularization and application have huge economic and social benefits.
具体实施方式Detailed ways
下列实施例并非限制本发明，而只是用来说明本发明是如何实现的。对于某些杂草，这些实施例显示出特别显著的有效性。举例如下：The following embodiments do not limit the present invention, but merely illustrate how the present invention is implemented. For certain weeds, these examples show particularly significant effectiveness. Examples are as follows:
A)实施例A) Example
1.A1+硝磺草酮(4+1：代表4％A1+1％硝磺草酮，下同)可分散油悬浮剂1. A1+Mesotrione (4+1: represents 4%A1+1%Mesotrione, the same below) dispersible oil suspension concentrate
A1+硝磺草酮+0.3％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1 + Mesotrione + 0.3% citric acid + 5% calcium dodecylbenzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed white carbon Black+5%100#Solvent oil+Methyl oleate make up
2.A1+苯唑草酮(3+1)可分散油悬浮剂2. A1 + oxaflutole (3+1) dispersible oil suspension concentrate
A1+苯唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Mefentrazone+5% calcium dodecylbenzenesulfonate+6% fatty alcohol polyoxyethylene ether+8% cardanol oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100 #Solvent oil + methyl oleate supplement
3.A1+双唑草酮(3+1)可分散油悬浮剂3.A1+Bifentrazone (3+1) dispersible oil suspension concentrate
A1+双唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Bifentrazone+0.2% citric acid+5% calcium dodecylbenzenesulfonate+6% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon Black+5%100#Solvent oil+Methyl oleate make up
4.A1+苯唑氟草酮(4+4)可分散油悬浮剂4.A1+Fenoxazone (4+4) dispersible oil suspension concentrate
A1+苯唑氟草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Fenoxazone+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% cardanol oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100# solvent oil + methyl oleate supplement
5.A1+异噁唑草酮(4+4)可分散油悬浮剂5.A1+ Isoxaflutole (4+4) dispersible oil suspension concentrate
A1+异噁唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1 + Isoxaflutole + 0.2% citric acid + 5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% gas phase method white Carbon black + 5% 100# solvent oil + methyl oleate supplement
6.A1+异噁草松(4+4)可分散油悬浮剂6.A1+ clomazone (4+4) dispersible oil suspension concentrate
A1+异噁草松+4％十二烷基苯磺酸钙+6％腰果酚聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有机膨润土+5％100#溶剂油+油酸甲酯补足A1+Clomazone+4% calcium dodecylbenzenesulfonate+6% cardanol polyoxyethylene ether+8% castor oil oxyethylene ether+2.5% organic bentonite+5%100#solvent oil+methyl oleate Make up
7.A1+吡嘧磺隆(4+2)可分散油悬浮剂7.A1+pyrsulfuron-methyl (4+2) dispersible oil suspension concentrate
A1+吡嘧磺隆+0.5％尿素+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+pyrimsulfuron+0.5% urea+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed silica +5%100#solvent oil+methyl oleate supplement
8.A1+五氟磺草胺(4+1)可分散油悬浮剂8.A1+Penoxsulam (4+1) dispersible oil suspension concentrate
A1+五氟磺草胺+5％十二烷基苯磺酸钙+6％失水山梨醇单油酸酯聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Penoxsulam+5% calcium dodecylbenzenesulfonate+6% sorbitan monooleate polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% gas phase method White carbon black + 5% 100# solvent oil + methyl oleate supplement
9.A1+甲氧咪草烟(4+1)可分散油悬浮剂9.A1+Imazethapyr (4+1) dispersible oil suspension concentrate
A1+甲氧咪草烟+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Imazethapyr+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% cardanol oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100# solvent oil + methyl oleate supplement
10.A1+甲咪唑烟酸(4+1)可分散油悬浮剂10. A1 + cimetazole nicotinic acid (4+1) dispersible oil suspension concentrate
A1+甲咪唑烟酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％腰果酚氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Mimidazole nicotinic acid+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% cardanol oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100 #Solvent oil + methyl oleate supplement
11.A1+双草醚(4+1)可分散油悬浮剂11.A1+Bispyrifen (4+1) dispersible oil suspension concentrate
A1+双草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A1+Bispyrifen+5% calcium dodecylbenzene sulfonate+8% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5%100# Solvent oil + methyl oleate supplement
12.A1+烯草酮(4+2)可分散油悬浮剂12.A1+Clethodim (4+2) dispersible oil suspension concentrate
A1+烯草酮+5％十二烷基苯磺酸钙+8％失水山梨醇单油酸酯聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足A1+Clethodim+5% calcium dodecylbenzenesulfonate+8% sorbitan monooleate polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon Black+20％100#Solvent oil+Methyl oleate make up
13.A1+烯禾啶(4+2)可分散油悬浮剂13.A1+ Enoxydim (4+2) dispersible oil suspension concentrate
A1+烯禾啶+5％十二烷基苯磺酸钙+8％失水山梨醇单油酸酯聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足A1+Enoxydim+5% calcium dodecylbenzenesulfonate+8% sorbitan monooleate polyoxyethylene ether+7% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon Black+6%100#Solvent oil+Methyl oleate make up
14.A1+精喹禾灵(4+2)可分散油悬浮剂14.A1 + quizalofop-p-ethyl (4+2) dispersible oil suspension concentrate
A1+精喹禾灵+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A1 + quizalofop-p-ethyl + 5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 5% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed silica + 10% 100 #Solvent oil + methyl oleate supplement
15.A1+乙氧氟草醚(3+1)可分散油悬浮剂15.A1 + oxyfluorfen (3+1) dispersible oil suspension concentrate
A1+乙氧氟草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足A1 + oxyfluorfen + 5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed white carbon black + 20% 100# solvent oil + methyl oleate supplement
16.A1+噁草酮(3+1)可分散油悬浮剂16.A1+oxadiazon (3+1) dispersible oil suspension concentrate
A1+噁草酮+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+5％100#溶剂油+油酸甲酯补足A1+oxadiazon+5% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+5%100#solvent oil+methyl oleate supplement
17.A1+丙炔噁草酮(3+1)可分散油悬浮剂17.A1+oxachlor (3+1) dispersible oil suspension concentrate
A1+丙炔噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+15％100#溶剂油+油酸甲酯补足A1+oxadiazon+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+15% 100# solvent oil + methyl oleate supplement
18.A1+莠去津(3+5)水悬浮剂18.A1+Atrazine (3+5) water suspension concentrate
A1+莠去津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.25％黄原胶+2.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+Atrazine+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.25% xanthan gum+2.5% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
19.A1+特丁津(3+3)水悬浮剂19.A1+terbucin (3+3) water suspension concentrate
A1+特丁津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.25％黄原胶+2.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+terbucin+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.25% xanthan gum+2.5% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
20.A1+敌稗(2+20)水悬浮剂20.A1 + propanil (2+20) water suspension
A1+敌稗+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1 + propanil + 5% polycarboxylate + 2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt + 0.16% xanthan gum + 1.6% magnesium aluminum silicate + 0.1% antifoaming agent + 3% ethylene dichloride Alcohol + water
21.A1+灭草松(4+30)水悬浮剂21.A1+Metazone (4+30) water suspension
A1+灭草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+Metazone+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.1% xanthan gum+1.2% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
22.A1+仲丁灵(4+21)可分散油悬浮剂22.A1+Secondazole (4+21) dispersible oil suspension concentrate
A1+仲丁灵+10％癸酰胺+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯 醚+1％有机膨润土+1％气相法白炭黑+15％100#溶剂油+油酸甲酯补足A1+sec-butyryl+10% decanamide+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+1% organic bentonite+1% fumed silica +15％100#Solvent oil+methyl oleate supplement
23.A1+二甲戊灵(4+21)可分散油悬浮剂23.A1+ pendimethalin (4+21) dispersible oil suspension concentrate
A1+二甲戊灵+10％癸酰胺+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A1 + pendimethalin + 10% decylamide + 6% calcium dodecylbenzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 5% castor oil oxyethylene ether + 1% organic bentonite + 1% fumed white carbon Black+10％100#Solvent oil+Methyl oleate make up
24.A1+丁草胺(4+6)可分散油悬浮剂24.A1+Butachlor (4+6) dispersible oil suspension concentrate
A1+丁草胺+6％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+3％有机膨润土+3％气相法白炭黑+油酸甲酯补足A1 + Butachlor + 6% calcium dodecyl benzene sulfonate + 6% fatty alcohol polyoxyethylene ether + 8% cardanol oxyethylene ether + 3% organic bentonite + 3% fumed white carbon black + methyl oleate Make up
25.A1+丙草胺(2+4)可分散油悬浮剂25.A1+ pretilachlor (2+4) dispersible oil suspension concentrate
A1+丙草胺+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+8％腰果酚氧乙烯醚+3％有机膨润土+3％气相法白炭黑+油酸甲酯补足A1+Precachlor+5% calcium dodecylbenzenesulfonate+6% fatty alcohol polyoxyethylene ether+8% cardanol oxyethylene ether+3% organic bentonite+3% fumed white carbon black+methyl oleate Make up
26.A1+莎稗磷(4+2)可分散油悬浮剂26.A1+Sarbanphos (4+2) Dispersible Oil Suspension Concentrate
A1+莎稗磷+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A1+Saraphos+5% calcium dodecylbenzene sulfonate+8% cardanol polyoxyethylene ether+7% castor oil oxyethylene ether+3% organic bentonite+3% fumed silica+12％100# Solvent oil + methyl oleate supplement
27.A1+二氯喹啉酸(2+10)可分散油悬浮剂27.A1+quinclorac (2+10) dispersible oil suspension concentrate
A1+二氯喹啉酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A1 + Quinclorac + 5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.0% organic bentonite + 2.0% fumed white carbon black + 10% 100 #Solvent oil + methyl oleate supplement
28.A1+氯氟吡氧乙酸(2+3)可分散油悬浮剂28.A1 + fluroxypyr (2+3) dispersible oil suspension concentrate
A1+氯氟吡氧乙酸+5％十二烷基苯磺酸钙+8％苯乙基苯酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A1+Chloropyroxyacetic acid+5% calcium dodecylbenzenesulfonate+8% phenethyl phenol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+3% fumed silica+ 10％100# solvent oil + methyl oleate supplement
29.A1+氯氟吡啶酯(3+1)可分散油悬浮剂29.A1+chlorofluoropyridine ester (3+1) dispersible oil suspension concentrate
A1+氯氟吡啶酯+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+油酸甲酯补足A1+chlorofluoropyridine ester+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+methyl oleate Ester supplement
30.A1+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂30.A1+2-Methyl-4-chlorophenoxyacetic acid (3+10) dispersible oil suspension concentrate
A1+2-甲基-4-氯苯氧乙酸+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2％有机膨润土+2.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A1+2-Methyl-4-chlorophenoxyacetic acid+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+6% castor oil oxyethylene ether+2% organic bentonite+2.5% gas phase French white carbon black+12％100#solvent oil+methyl oleate supplement
31.A1+草甘膦(4+16)水悬浮剂31.A1+glyphosate (4+16) water suspension
A1+草甘膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+glyphosate+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+2.0% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
32.A1+草铵膦(3+15)水悬浮剂32.A1+ glufosinate-ammonium (3+15) water suspending agent
A1+草铵膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+Glufosinate-ammonium+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+2.0% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
33.A1+敌草快(4+15)水悬浮剂33.A1+diquat (4+15) water suspension
A1+敌草快+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+2.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A1+diquat+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+2.0% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
34.A1+环庚草醚(4+1)可分散油悬浮剂34.A1+ Cyprofen (4+1) dispersible oil suspension concentrate
A1+环庚草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A1+cycloheptafen+5% calcium dodecylbenzene sulfonate+8% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+12%100 #Solvent oil + methyl oleate supplement
35.A2+硝磺草酮(4+1)可分散油悬浮剂35.A2+Mesotrione (4+1) dispersible oil suspension concentrate
A2+硝磺草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Mesotrione+0.2% citric acid+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon Black+5%100#Solvent oil+Methyl oleate make up
36.A2+苯唑草酮(3+1)可分散油悬浮剂36.A2+oxaflutole (3+1) dispersible oil suspension concentrate
A2+苯唑草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Mefentrazone+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100 #Solvent oil + methyl oleate supplement
37.A2+双唑草酮(3+1)可分散油悬浮剂37.A2+Bifentrazone (3+1) dispersible oil suspension concentrate
A2+双唑草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2 + Bifentrazone + 0.2% citric acid + 5% calcium dodecylbenzene sulfonate + 9% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed white carbon Black+5%100#Solvent oil+Methyl oleate make up
38.A2+苯唑氟草酮(4+4)可分散油悬浮剂38.A2+Fenoxazone (4+4) dispersible oil suspension concentrate
A2+苯唑氟草酮+0.2％柠檬酸+5％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Fenoxazone+0.2% citric acid+5% calcium dodecylbenzenesulfonate+9% cardanol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white Carbon black + 5% 100# solvent oil + methyl oleate supplement
39.A2+异噁唑草酮(4+4)可分散油悬浮剂39.A2+ Isoxaflutole (4+4) dispersible oil suspension concentrate
A2+异噁唑草酮+0.3％柠檬酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2 + Isoxaflutole + 0.3% citric acid + 5% calcium dodecyl benzene sulfonate + 9% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% gas phase method white Carbon black + 5% 100# solvent oil + methyl oleate supplement
40.A2+异噁草松(4+4)可分散油悬浮剂40.A2+ clomazone (4+4) dispersible oil suspension concentrate
A2+异噁草松+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+2.5％有机膨润土+10％100#溶剂油+油酸甲酯补足A2+Clomazone+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+2.5% organic bentonite+10%100#solvent oil+methyl oleate Make up
41.A2+吡嘧磺隆(4+2)可分散油悬浮剂41.A2+pyrsulfuron-methyl (4+2) dispersible oil suspension concentrate
A2+吡嘧磺隆+0.5％尿素+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+pyrimsulfuron+0.5% urea+5% calcium dodecylbenzenesulfonate+7% fatty alcohol polyoxyethylene ether+8% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed silica +5%100#solvent oil+methyl oleate supplement
42.A2+五氟磺草胺(4+1)可分散油悬浮剂42.A2+Penoxsulam (4+1) dispersible oil suspension concentrate
A2+五氟磺草胺+5％十二烷基苯磺酸钙+9％失水山梨醇单油酸酯聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Penoxsulam+5% calcium dodecylbenzenesulfonate+9% sorbitan monooleate polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% gas phase method White carbon black + 5% 100# solvent oil + methyl oleate supplement
43.A2+甲氧咪草烟(4+1)可分散油悬浮剂43.A2+Imazethapyr (4+1) dispersible oil suspension concentrate
A2+甲氧咪草烟+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Imazethapyr+5% calcium dodecylbenzene sulfonate+9% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5% 100# solvent oil + methyl oleate supplement
44.A2+甲咪唑烟酸(4+1)可分散油悬浮剂44.A2 + cimetazole nicotinic acid (4+1) dispersible oil suspension concentrate
A2+甲咪唑烟酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Mimidazole nicotinic acid+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5%100 #Solvent oil + methyl oleate supplement
45.A2+双草醚(4+1)可分散油悬浮剂45.A2+ Bispyrifen (4+1) dispersible oil suspension concentrate
A2+双草醚+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+5％100#溶剂油+油酸甲酯补足A2+Bispyrifen+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+2.5% organic bentonite+2% fumed white carbon black+5%100# Solvent oil + methyl oleate supplement
46.A2+烯草酮(4+2)可分散油悬浮剂46.A2+Clethodim (4+2) dispersible oil suspension concentrate
A2+烯草酮+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足A2+Clethodim+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+20％100# Solvent oil + methyl oleate supplement
47.A2+烯禾啶(4+2)可分散油悬浮剂47.A2+ Enoxydim (4+2) dispersible oil suspension concentrate
A2+烯禾啶+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足A2+Enhydropyridine+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+6%100# Solvent oil + methyl oleate supplement
48.A2+精喹禾灵(4+2)可分散油悬浮剂48.A2 + quizalofop-p-ethyl (4+2) dispersible oil suspension concentrate
A2+精喹禾灵+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+8％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足A2 + quizalofop-p-ethyl+5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 8% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed white carbon black + 6% 100 #Solvent oil + methyl oleate supplement
49.A2+乙氧氟草醚(3+1)可分散油悬浮剂49.A2+ oxyfluorfen (3+1) dispersible oil suspension concentrate
A2+乙氧氟草醚+5％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足A2 + oxyfluorfen + 5% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 6% castor oil oxyethylene ether + 3% organic bentonite + 2% fumed white carbon black + 20% 100# solvent oil + methyl oleate supplement
50.A2+噁草酮(3+1)可分散油悬浮剂50.A2+oxadiazon (3+1) dispersible oil suspension concentrate
A2+噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+5％100#溶剂油+油酸甲酯补足A2+oxadiazon+5% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+5%100#solvent oil+methyl oleate supplement
51.A2+丙炔噁草酮(3+1)可分散油悬浮剂51.A2+ Oxachlor (3+1) dispersible oil suspension concentrate
A2+丙炔噁草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+15％100#溶剂油+油酸甲酯补足A2 + Oxachlor + 5% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil oxyethylene ether + 2.5% organic bentonite + 2% fumed white carbon black + 15% 100# solvent oil + methyl oleate supplement
52.A2+莠去津(3+5)水悬浮剂52.A2+Atrazine (3+5) water suspension concentrate
A2+莠去津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.22％黄原胶+2.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+Atrazine+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.22% xanthan gum+2.2% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
53.A2+特丁津(3+3)水悬浮剂53.A2+terbucin (3+3) water suspension concentrate
A2+特丁津+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.26％黄原胶 +2.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+terbucin+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.26% xanthan gum+2.2% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
54.A2+敌稗(2+20)水悬浮剂54.A2 + propanil (2+20) water suspension
A2+敌稗+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18％黄原胶+1.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2 + propanil + 5% polycarboxylate + 2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt + 0.18% xanthan gum + 1.8% magnesium aluminum silicate + 0.1% antifoaming agent + 3% ethylene dichloride Alcohol + water
55.A2+灭草松(4+30)水悬浮剂55.A2+Metazone (4+30) water suspension
A2+灭草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+Metazone+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+0.12% xanthan gum+1.5% magnesium aluminum silicate+0.1% defoamer+3% ethyl Glycol + water
56.A2+仲丁灵(4+21)可分散油悬浮剂56.A2+Secondazole (4+21) dispersible oil suspension concentrate
A2+仲丁灵+10％癸酰胺+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A2+sec-butyryl+10% decanamide+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+1% organic bentonite+1% fumed silica +10％100#Solvent oil+methyl oleate supplement
57.A2+二甲戊灵(4+21)可分散油悬浮剂57.A2+ pendimethalin (4+21) dispersible oil suspension concentrate
A2+二甲戊灵+10％癸酰胺+6％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1％有机膨润土+1％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A2+ pendimethalin+10% decanamide+6% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+5% castor oil oxyethylene ether+1% organic bentonite+1% fumed white carbon Black+10％100#Solvent oil+Methyl oleate make up
58.A2+丁草胺(4+6)可分散油悬浮剂58.A2+Butachlor (4+6) dispersible oil suspension concentrate
A2+丁草胺+6％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+油酸甲酯补足A2+Butachlor+6% calcium dodecylbenzenesulfonate+9% cardanol polyoxyethylene ether+7% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+methyl oleate Make up
59.A2+丙草胺(2+4)可分散油悬浮剂59.A2+ pretilachlor (2+4) dispersible oil suspension concentrate
A2+丙草胺+5％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+油酸甲酯补足A2+Precachlor+5% calcium dodecylbenzenesulfonate+9% cardanol polyoxyethylene ether+7% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+methyl oleate Make up
60.A2+莎稗磷(4+2)可分散油悬浮剂60.A2+Saraphos (4+2) dispersible oil suspension concentrate
A2+莎稗磷+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+7％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A2+Saraphos+5% calcium dodecylbenzene sulfonate+9% fatty alcohol polyoxyethylene ether+7% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+12％100# Solvent oil + methyl oleate supplement
61.A2+二氯喹啉酸(2+10)可分散油悬浮剂61.A2+ Quinclorac (2+10) dispersible oil suspension concentrate
A2+二氯喹啉酸+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+10％100#溶剂油+油酸甲酯补足A2+quinclorac+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2.5% organic bentonite+10%100#solvent oil+methyl oleate Make up
62.A2+氯氟吡氧乙酸(2+3)可分散油悬浮剂62.A2+Chloropyroxyacetic acid (2+3) dispersible oil suspension concentrate
A2+氯氟吡氧乙酸+5％十二烷基苯磺酸钙+9％苯乙基苯酚聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+3％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A2+Chloropyroxyacetic acid+5% calcium dodecylbenzene sulfonate+9% phenethyl phenol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+3% fumed silica+ 10％100# solvent oil + methyl oleate supplement
63.A2+氯氟吡啶酯(3+1)可分散油悬浮剂63.A2+chlorofluoropyridine ester (3+1) dispersible oil suspension concentrate
A2+氯氟吡啶酯+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A2+chlorofluoropyridine ester+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+12%100 #Solvent oil + methyl oleate supplement
64.A2+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂64.A2+2-Methyl-4-chlorophenoxyacetic acid (3+10) dispersible oil suspension concentrate
A2+2-甲基-4-氯苯氧乙酸+6％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2％有机膨润土+1％气相法白炭黑+12％100#溶剂油+油酸甲酯补足A2+2-Methyl-4-chlorophenoxyacetic acid+6% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+2% organic bentonite+1% gas phase French white carbon black+12％100#solvent oil+methyl oleate supplement
65.A2+草甘膦(4+16)水悬浮剂65.A2+glyphosate (4+16) water suspension
A2+草甘膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+glyphosate+5% polycarboxylate+2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+1% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
66.A2+草铵膦(3+15)水悬浮剂66.A2+ glufosinate-ammonium (3+15) water suspending agent
A2+草铵膦+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+Glufosinate-ammonium+5% polycarboxylate+2% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+1% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
67.A2+敌草快(4+15)水悬浮剂67.A2+diquat (4+15) water suspension
A2+敌草快+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％丙二醇嵌段聚醚+0.2％耐盐黄原胶+1％硅酸镁铝+0.1％消泡剂+3％乙二醇+水A2+diquat+5% polycarboxylate+2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+3% propylene glycol block polyether+0.2% salt-tolerant xanthan gum+1% magnesium aluminum silicate +0.1% defoamer + 3% ethylene glycol + water
68.A2+环庚草醚(4+1)可分散油悬浮剂68.A2+ Cyprofen (4+1) dispersible oil suspension concentrate
A2+环庚草醚+5％十二烷基苯磺酸钙+9％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3％有机膨润土+2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足A2+cycloheptafen+5% calcium dodecylbenzenesulfonate+9% fatty alcohol polyoxyethylene ether+6% castor oil oxyethylene ether+3% organic bentonite+2% fumed white carbon black+10%100 #Solvent oil + methyl oleate supplement
上述水悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned water suspension agent processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述水悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。The above-mentioned water suspension agent processing process: put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally cut uniformly in the shearing machine, and transfer to the storage after the test is qualified. Can filling.
上述可分散油悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned dispersible oil suspension agent processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述可分散油悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。The above-mentioned dispersible oil suspension agent processing process: put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally shear evenly in the shearing machine. After the test is qualified, transfer To the storage tank for filling.
B)药效试验B)Efficacy test
苗后茎叶喷雾处理:Spray treatment of stems and leaves after seedling:
1)试验条件1) Test conditions
1.1)、供试靶标1.1), test target
异型莎草采自湖北荆州、碎米莎草采自江西上饶、鸭舌草采自湖南长沙、稻稗采自黑龙江抚远、野慈姑采自辽宁营口、萤蔺采自黑龙江虎林、丁香蓼采自湖南长沙、马唐采自安徽天长、泽泻采自辽宁沈阳。上述杂草采用盆栽法培养，用180х140mm塑料营养钵，摆放于搪瓷盘中，内装从农田采回经风干过筛的表层土壤(4/5处)，土壤湿度初期均控制在20％，挑选籽粒饱满均一的杂草种子，用25℃温水浸泡6小时，在28℃生化培养箱(黑暗)中催芽，将刚刚露白的杂草种子均匀摆放在土壤表面，根据种子粒径大小然后覆土0.5-1cm。Special-shaped sedges are collected from Jingzhou, Hubei, Cardamine sedges are collected from Shangrao, Jiangxi, Coatgrass is collected from Changsha, Hunan, Barnyardgrass is collected from Fuyuan, Heilongjiang, Ye Cigu is collected from Yingkou, Liaoning, Firefly is collected from Hulin, Heilongjiang, Polygonum cloves It was collected from Changsha, Hunan, Matang was collected from Tianchang, Anhui, and Alisma orientale was collected from Shenyang, Liaoning. The above-mentioned weeds are cultivated in pots. They are placed in an enamel dish in a 180х140mm plastic nutrient bowl. The top soil (4/5) collected from the farmland is air-dried and sieved. The soil moisture is controlled at 20% at the initial stage. Weed seeds with full and uniform grains, soaked in warm water at 25°C for 6 hours, incubate germination in a biochemical incubator (dark) at 28°C, and evenly place the white weed seeds on the surface of the soil, and cover with 0.5 soil according to the size of the seed. -1cm.
1.2)、培养条件1.2), culture conditions
在可控日光温室内进行，温度20～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％，pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。It is carried out in a controllable solar greenhouse, with a temperature of 20 to 30°C, natural light, and a relative humidity of 57% to 72%. The soil type is loam, organic matter content is 1.63%, pH=7.1, alkali hydrolyzable nitrogen 84.3mg/kg, available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.
1.3)、仪器设备1.3), equipment
3WP-2000型行走式喷雾塔，农业部南京农业机械研究所。GA10型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)。3WP-2000 walking spray tower, Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
2)试验设计2) Experimental design
2.1)、试剂2.1), reagent
所需活性成分A来自于专利CN201911014193.5，其具体制备过程如下所示：The required active ingredient A comes from patent CN201911014193.5, and its specific preparation process is as follows:
(1)化合物A1的合成：(1) Synthesis of compound A1:
(1.1)在30毫升的DMF中依次加入Cpd 1(3g,16mmol,1.0eq)，NaOH(0.72g,18mmol,1.1eq)然后在0℃条件下逐滴加入Cpd 2(1.28g,16.8mmol,1.05eq)，然后反应液在0℃条件下搅拌1小时。LCMS检测显示原料基本反应完毕，有一个主要的新峰。将反应液倒入30毫升水中，分液，水相用50毫升乙酸乙酯萃取一次，有机相用饱和食盐水(50ml)洗三次，干燥，旋干，柱层析分离得到Cpd 3(3.6g,91％收率)(无色的油)。(1.1) Add Cpd 1 (3g, 16mmol, 1.0eq), NaOH (0.72g, 18mmol, 1.1eq) to 30 ml of DMF in sequence, then add Cpd 2 (1.28g, 16.8mmol, 1.05eq), and then the reaction solution was stirred at 0°C for 1 hour. LCMS detection showed that the reaction of the raw materials was basically completed, and there was a major new peak. The reaction solution was poured into 30 ml of water and separated. The aqueous phase was extracted once with 50 ml of ethyl acetate. The organic phase was washed three times with saturated brine (50 ml), dried, spin-dried, and separated by column chromatography to obtain Cpd 3 (3.6 g , 91% yield) (colorless oil).
Figure PCTCN2020081646-appb-000013
Figure PCTCN2020081646-appb-000013
(1.2)在30毫升的THF中加入Cpd 3(3.1g,13mmol,1.0eq)，然后在-78℃条件下缓慢加入n-BuLi(6.42ml,2.5M,16mmol,1.2eq)，然后反应液在-78℃条件下搅拌0.5小时后缓慢通入CO 2，通入10min后反应液缓慢升到室温。LCMS检测到产品。往反应液中倒入20毫升水，分液，水相用30毫升乙酸乙酯萃取一次，水相用浓盐酸逐渐调到pH＝4-5，过滤，干燥得到Cpd 4(3.2g,87％收率)(白色固体)。 (1.2) Add Cpd 3 (3.1g, 13mmol, 1.0eq) to 30ml of THF, then slowly add n-BuLi (6.42ml, 2.5M, 16mmol, 1.2eq) at -78℃, then the reaction solution After stirring at -78°C for 0.5 hours, CO 2 was slowly introduced. After 10 minutes, the reaction solution was slowly raised to room temperature. LCMS detects the product. Pour 20 ml of water into the reaction solution, separate the layers, extract the aqueous phase with 30 ml of ethyl acetate once, and gradually adjust the aqueous phase to pH=4-5 with concentrated hydrochloric acid, filter, and dry to obtain Cpd 4 (3.2g, 87%) Yield) (white solid).
Figure PCTCN2020081646-appb-000014
Figure PCTCN2020081646-appb-000014
(1.3)在30毫升的吡啶中依次加入Cpd 4(3.1g,11mmol,1.0eq)，Cpd 5(1.66g,16.8mmol,1.5eq),DMAP(0.13g,1.1mmol,0.1eq)。然后在0℃条件下缓慢加入SOCl 2(2.0g,16.8 mmol,1.5eq)，然后反应液在室温条件下搅拌3小时。LCMS检测到产品。浓缩除掉吡啶后往反应液倒入30毫升水，分液，水相用30毫升乙酸乙酯萃取三次，有机相用饱和食盐水(50ml)洗三次，干燥，旋干，柱层析分离得到化合物Cpd 6(2.5g,63％收率)(白色固体)。 (1.3) Cpd 4 (3.1 g, 11 mmol, 1.0 eq), Cpd 5 (1.66 g, 16.8 mmol, 1.5 eq), DMAP (0.13 g, 1.1 mmol, 0.1 eq) were sequentially added to 30 ml of pyridine. Then SOCl 2 (2.0 g, 16.8 mmol, 1.5 eq) was slowly added at 0° C., and then the reaction solution was stirred at room temperature for 3 hours. LCMS detects the product. After concentrating to remove the pyridine, pour 30 ml of water into the reaction solution and separate the layers. The aqueous phase was extracted three times with 30 ml ethyl acetate. The organic phase was washed three times with saturated brine (50 ml), dried, spin-dried, and separated by column chromatography. Compound Cpd 6 (2.5 g, 63% yield) (white solid).
Figure PCTCN2020081646-appb-000015
Figure PCTCN2020081646-appb-000015
(1.4)在10毫升的二氯甲烷中依次加入Cpd 6(1g,2.8mmol,1.0eq)，m-CPBA(0.54g,3.1mmol,1.1eq)。然后反应液在室温条件下搅拌1小时。LCMS检测到产品，原料基本反应完毕。将反应液倒入10毫升水中，用亚硫酸氢钠淬灭，分液，水相用30毫升二氯甲烷萃取三次，有机相用饱和食盐水(30ml)洗一次，干燥，旋干，柱层析分离得到化合物A1(0.85g,82％收率)(灰白色的固体)。(1.4) Add Cpd 6 (1g, 2.8mmol, 1.0eq) and m-CPBA (0.54g, 3.1mmol, 1.1eq) to 10ml of dichloromethane. Then the reaction solution was stirred at room temperature for 1 hour. The product is detected by LCMS, and the reaction of the raw materials is basically completed. The reaction solution was poured into 10 ml of water, quenched with sodium bisulfite, and separated. The aqueous phase was extracted three times with 30 ml of dichloromethane. The organic phase was washed once with saturated brine (30 ml), dried, spin-dried, and the column layer The compound A1 (0.85 g, 82% yield) (off-white solid) was obtained by analysis and separation.
1H NMR(500MHz,DMSO-d 6)12.57(s,1H),8.07(dd,J＝8.0,7.0Hz,1H),7.82(d,J＝8.0Hz,1H),3.57-3.47(m,2H),2.48(s,3H),1.70-1.52(m,2H),1.08-0.93(m,3H). 1 H NMR (500MHz, DMSO-d 6 ) 12.57 (s, 1H), 8.07 (dd, J = 8.0, 7.0 Hz, 1H), 7.82 (d, J = 8.0 Hz, 1H), 3.57-3.47 (m, 2H), 2.48 (s, 3H), 1.70-1.52 (m, 2H), 1.08-0.93 (m, 3H).
Figure PCTCN2020081646-appb-000016
Figure PCTCN2020081646-appb-000016
(2)化合物A2的合成：(2) Synthesis of compound A2:
化合物A1(0.5g,98％purity)通过手性HPLC(Column：CHIRALPAK IG；Column Size：3cm x 25cm,5um；Injection：3.0ml；Mobile phase：Hex(0.2％FA)：IPA＝50：50；Flow rate：28ml/min；Wavelength:UV 254nm；Temperature:25℃；Sample solution：70mg/ml in EtOH/DCM；Run time＝60mins)拆分之后浓缩，经单晶衍射确定得到白色固体A2(R构型)(0.16g,Rt＝10.51min,100％ee,纯度为98％)。Compound A1 (0.5g, 98% purity) passed chiral HPLC (Column: CHIRALPAK IG; Column Size: 3cm x 25cm, 5um; Injection: 3.0ml; Mobile phase: Hex (0.2% FA): IPA=50:50; Flow rate: 28ml/min; Wavelength: UV 254nm; Temperature: 25°C; Sample solution: 70mg/ml in EtOH/DCM; Run time=60mins) After separation and concentration, it is confirmed by single crystal diffraction to obtain a white solid A2(R Type) (0.16g, Rt = 10.51min, 100%ee, 98% purity).
Figure PCTCN2020081646-appb-000017
Figure PCTCN2020081646-appb-000017
所需活性成分B中双唑草酮、环吡氟草酮、苯唑氟草酮、三唑磺草酮为本公司生产，其他由试剂公司购买。原药均采用丙酮作溶剂，用含量0.1％乳化剂吐温-80水溶液稀释，现用现稀释。Among the required active ingredients B, fentrazone, cifentrazone, flufentrazone, and trifentrazone are produced by the company, and the others are purchased by the reagent company. The original medicines all use acetone as the solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and are now diluted.
2.2)、试验处理2.2), test treatment
2.2.1)、剂量设置2.2.1), dose setting
在确定A与活性成分B配比或含量时，应从两种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上，设A、B活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。When determining the ratio or content of A and active ingredient B, the action characteristics and toxicity of the two drugs should be measured, and the main purpose of the formulation should also be considered. In this study, based on the preliminary test, the single and mixed dosages of A and B active ingredients are shown in the table respectively. Use water without medicament and with the same solvent and emulsifier as a blank control.
2.2.2)、试验重复2.2.2), test repeat
每处理重复4次，每次处理3盆，每盆播种杂草种子20粒，每处理共60株。Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown in each pot, and a total of 60 plants per treatment.
2.3)、处理方式2.3), processing method
2.3.1)、处理时间和次数2.3.1), processing time and frequency
试验共用药1次。待杂草1～1.5叶期，间苗，保持每盆内杂草15株，每处理保留45株，然后继续培养至2-3叶进行处理。Test shared medicine once. At the 1 to 1.5 leaf stage of the weeds, thin the seedlings, keep 15 weeds in each pot, keep 45 weeds per treatment, and then continue to cultivate until 2-3 leaves for treatment.
2.3.2)、使用器械和用药方法2.3.2), the use of equipment and methods of medication
将培养好的试材均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔茎叶喷雾，喷液量按450公斤/公顷计，喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。 Place the cultivated test materials evenly on a platform with an area of 0.5m 2 and spray them with 3WP-2000 walking spray tower stems and leaves. The spray volume is 450 kg/ha and the spray pressure is 0.3 MPa. After all the liquid medicine is sprayed, close the air valve, 30 seconds later, open the spray tower door and take out the nutrient bowl. Then open the air valve, spray 50mL of clean water, and clean the spray tube.
3)试验方法3) Test method
采用盆栽法。杂草培养见1.1)，参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2)，采用茎叶处理法。处理后移入温室常规培养。Use potted plants. See 1.1) for weed cultivation, refer to the "Pesticide Indoor Bioassay Test Guidelines for Herbicides". See 2.3.2) for the medication method, and adopt the stem and leaf treatment method. After treatment, they were transferred to the greenhouse for routine cultivation.
4)数据调查与统计分析4) Data investigation and statistical analysis
4.1)、调查方法4.1), survey method
采用绝对数调查法，用刀片沿土壤表面切断存活杂草整株幼苗，用分析天平称量杂草鲜重。对于已经死亡的杂草，按鲜重为零计。Using the absolute number survey method, the whole seedlings of the living weeds were cut along the soil surface with a blade, and the fresh weight of the weeds was weighed with an analytical balance. For weeds that have died, the fresh weight is zero.
4.2)、调查时间和次数4.2), survey time and frequency
处理后15天调查，共调查1次。The investigation was conducted 15 days after the treatment, and the investigation was conducted once.
4.3)、数据统计分析4.3), statistical analysis of data
用Gowing法计算各处理混合组合的理论鲜重抑制率(E0＝X+Y-X*Y/100)，然后与实测抑制率(E)相比较，评价二者混用对杂草的联合作用类型，当E-E0值大于10％为增效作用、小于-10％为拮抗作用、在-10％～10％之间为加成作用。并根据实际防效和除草剂特点、配 方的平衡性等因素确定最佳配比。式中X为活性成分A用量为P时的鲜重抑制率；Y为活性成分B用量为Q时的鲜重抑制率。统计结果见下表1-201。The Gowing method was used to calculate the theoretical fresh weight inhibition rate (E0=X+YX*Y/100) of each treatment mixture, and then compared with the measured inhibition rate (E) to evaluate the combined effect of the two mixed use on weeds. When E-E0 value greater than 10% is synergistic effect, less than -10% is antagonistic effect, and between -10% and 10% is additive effect. And according to the actual control effect, the characteristics of herbicides, the balance of the formula and other factors to determine the best ratio. Where X is the fresh weight inhibition rate when the amount of active ingredient A is P; Y is the fresh weight inhibition rate when the amount of active ingredient B is Q. The statistical results are shown in Table 1-201 below.
表1 A1混配硝磺草酮对异型莎草的实际防效与联合作用评价Table 1 Evaluation of actual control effect and joint effect of A1 mixed mesotrione on heterotypic sedge
Figure PCTCN2020081646-appb-000018
Figure PCTCN2020081646-appb-000018
表2 A1混配苯唑草酮对异型莎草的实际防效与联合作用评价Table 2 Evaluation of the actual control effect and joint effect of A1 mixed with fentrazone on heterotypic sedge
Figure PCTCN2020081646-appb-000019
Figure PCTCN2020081646-appb-000019
表3 A1混配环磺酮对异型莎草的实际防效与联合作用评价Table 3 Evaluation of actual control effect and joint effect of A1 mixed cyclosulfone on heterotypic sedge
Figure PCTCN2020081646-appb-000020
Figure PCTCN2020081646-appb-000020
表4 A1混配氟吡草酮对异型莎草的实际防效与联合作用评价Table 4 Evaluation of actual control effect and combined effect of A1 mixed fluopyron on heterotypic sedge
Figure PCTCN2020081646-appb-000021
Figure PCTCN2020081646-appb-000021
表5 A1混配呋喃磺草酮对异型莎草的实际防效与联合作用评价Table 5 Evaluation of actual control effect and joint effect of A1 mixed fursotrione on heterotypic sedge
Figure PCTCN2020081646-appb-000022
Figure PCTCN2020081646-appb-000022
表6 A1混配双环磺草酮对异型莎草的实际防效与联合作用评价Table 6 The actual control effect and joint effect evaluation of A1 mixed sulcotrione on heterotypic sedge
Figure PCTCN2020081646-appb-000023
Figure PCTCN2020081646-appb-000023
表7 A1混配双唑草酮对异型莎草的实际防效与联合作用评价Table 7 The actual control effect and joint effect evaluation of A1 mixed fentrazone on heterotypic sedge
Figure PCTCN2020081646-appb-000024
Figure PCTCN2020081646-appb-000024
Figure PCTCN2020081646-appb-000025
Figure PCTCN2020081646-appb-000025
表8 A1混配环吡氟草酮对异型莎草的实际防效与联合作用评价Table 8 Evaluation of the actual control effect and combined effect of A1 mixed ciclofenac on heterotypic sedge
Figure PCTCN2020081646-appb-000026
Figure PCTCN2020081646-appb-000026
表9 A1混配三唑磺草酮对异型莎草的实际防效与联合作用评价Table 9 Evaluation of actual control effect and joint effect of A1 mixed triazuron on heterotypic sedge
Figure PCTCN2020081646-appb-000027
Figure PCTCN2020081646-appb-000027
表10 A1混配苯唑氟草酮对异型莎草的实际防效与联合作用评价Table 10 Evaluation of the actual control effect and joint effect of A1 mixed oxaflutole on heterotypic sedge
Figure PCTCN2020081646-appb-000028
Figure PCTCN2020081646-appb-000028
表11 A1混配异噁唑草酮对异型莎草的实际防效与联合作用评价Table 11 Evaluation of actual control effect and joint effect of A1 mixed isoxaflutole on heterotypic sedge
Figure PCTCN2020081646-appb-000029
Figure PCTCN2020081646-appb-000029
表12 A1混配吡氟酰草胺对异型莎草的实际防效与联合作用评价Table 12 Evaluation of actual control effect and joint effect of A1 mixed diflufenican on heterotypic sedge
Figure PCTCN2020081646-appb-000030
Figure PCTCN2020081646-appb-000030
表13 A1混配氟吡酰草胺对异型莎草的实际防效与联合作用评价Table 13 The actual control effect and joint effect evaluation of A1 mixed with flufenacet on heterotypic sedge
Figure PCTCN2020081646-appb-000031
Figure PCTCN2020081646-appb-000031
表14 A1混配异噁草松对异型莎草的实际防效与联合作用评价Table 14 Evaluation of actual control effect and joint effect of A1 mixed clomazone on heteromorphic sedge
Figure PCTCN2020081646-appb-000032
Figure PCTCN2020081646-appb-000032
Figure PCTCN2020081646-appb-000033
Figure PCTCN2020081646-appb-000033
表15 A1混配噻吩磺隆对鸭舌草的实际防效与联合作用评价Table 15 The actual control effect and joint effect evaluation of A1 mixed thifensulfuron on Diffusa
Figure PCTCN2020081646-appb-000034
Figure PCTCN2020081646-appb-000034
表16 A1混配苄嘧磺隆对鸭舌草的实际防效与联合作用评价Table 16 Evaluation of actual control effect and joint effect of A1 mixed bensulfuron-methyl on Diffusa
Figure PCTCN2020081646-appb-000035
Figure PCTCN2020081646-appb-000035
表17 A1混配吡嘧磺隆对鸭舌草的实际防效与联合作用评价Table 17 Evaluation of actual control effect and joint effect of A1 mixed pyrsulfuron-methyl on Diffusa
Figure PCTCN2020081646-appb-000036
Figure PCTCN2020081646-appb-000036
表18 A1混配噻酮磺隆对鸭舌草的实际防效与联合作用评价Table 18 Evaluation of actual control effect and combined effect of A1 mixed thioketone sulfuron on Diffusa
Figure PCTCN2020081646-appb-000037
Figure PCTCN2020081646-appb-000037
表19 A1混配氯吡嘧磺隆对鸭舌草的实际防效与联合作用评价Table 19 Evaluation of the actual control effect and combined effect of A1 mixed chlorpyrisulfuron on Diffusa
Figure PCTCN2020081646-appb-000038
Figure PCTCN2020081646-appb-000038
表20 A1混配砜嘧磺隆对鸭舌草的实际防效与联合作用评价Table 20 The actual control effect and joint effect evaluation of A1 mixed sulfensulfuron-methyl on Diffusa
Figure PCTCN2020081646-appb-000039
Figure PCTCN2020081646-appb-000039
表21 A1混配氟唑磺隆对鸭舌草的实际防效与联合作用评价Table 21 Evaluation of the actual control effect and combined effect of A1 mixed with fluazosulfuron on Diffusa
Figure PCTCN2020081646-appb-000040
Figure PCTCN2020081646-appb-000040
表22 A1混配甲基二磺隆对鸭舌草的实际防效与联合作用评价Table 22 Evaluation of actual control effect and joint effect of A1 mixed with disulfuron-methyl on Diffusa
Figure PCTCN2020081646-appb-000041
Figure PCTCN2020081646-appb-000041
表23 A1混配烟嘧磺隆对鸭舌草的实际防效与联合作用评价Table 23 Evaluation of actual control effect and joint effect of A1 mixed nicosulfuron on Diffusa
Figure PCTCN2020081646-appb-000042
Figure PCTCN2020081646-appb-000042
表24 A1混配甲酰胺磺隆对鸭舌草的实际防效与联合作用评价Table 24 Evaluation of actual control effect and joint effect of A1 mixed formamide sulfuron on Diffusa
Figure PCTCN2020081646-appb-000043
Figure PCTCN2020081646-appb-000043
表25 A1混配唑嘧磺草胺对鸭舌草的实际防效与联合作用评价Table 25 The actual control effect and joint effect evaluation of A1 mixed flumetsulam on Diffusa
Figure PCTCN2020081646-appb-000044
Figure PCTCN2020081646-appb-000044
表26 A1混配氟酮磺草胺对鸭舌草的实际防效与联合作用评价Table 26 Evaluation of the actual control effect and joint effect of A1 mixed flumetsulam on Diffusa
Figure PCTCN2020081646-appb-000045
Figure PCTCN2020081646-appb-000045
表27 A1混配五氟磺草胺对鸭舌草的实际防效与联合作用评价Table 27 The actual control effect and joint effect evaluation of A1 mixed penoxsulam on Diffusa
Figure PCTCN2020081646-appb-000046
Figure PCTCN2020081646-appb-000046
表28 A1混配氯酯磺草胺对鸭舌草的实际防效与联合作用评价Table 28 The actual control effect and joint effect evaluation of A1 mixed chlorfentrazone on Diffusa
Figure PCTCN2020081646-appb-000047
Figure PCTCN2020081646-appb-000047
表29 A1混配啶磺草胺对鸭舌草的实际防效与联合作用评价Table 29 The actual control effect and joint effect evaluation of A1 mixed flufentrazone on Diffusa
Figure PCTCN2020081646-appb-000048
Figure PCTCN2020081646-appb-000048
表30 A1混配甲氧咪草烟对鸭舌草的实际防效与联合作用评价Table 30 Evaluation of actual control effect and combined effect of A1 mixed imazamox on the duck's diffusa
Figure PCTCN2020081646-appb-000049
Figure PCTCN2020081646-appb-000049
表31 A1混配甲咪唑烟酸对鸭舌草的实际防效与联合作用评价Table 31 The actual control effect and joint effect evaluation of A1 mixed with metazolium nicotinic acid on Diffusa
Figure PCTCN2020081646-appb-000050
Figure PCTCN2020081646-appb-000050
表32 A1混配碘甲磺隆钠盐对鸭舌草的实际防效与联合作用评价Table 32 The actual control effect and joint effect evaluation of A1 mixed with iodometsulfuron-methyl sodium salt on the grass
Figure PCTCN2020081646-appb-000051
Figure PCTCN2020081646-appb-000051
表33 A1混配双草醚对鸭舌草的实际防效与联合作用评价Table 33 The actual control effect and joint effect evaluation of A1 mixed bispyribac on the duck's diffusa
Figure PCTCN2020081646-appb-000052
Figure PCTCN2020081646-appb-000052
表34 A1混配唑啉草酯对稻稗的实际防效与联合作用评价Table 34 Evaluation of actual control effect and joint effect of A1 mixed pinoxaden on rice barnyardgrass
Figure PCTCN2020081646-appb-000053
Figure PCTCN2020081646-appb-000053
表35 A1混配烯草酮对稻稗的实际防效与联合作用评价Table 35 Evaluation of actual control effect and joint effect of A1 mixed clethodim on rice barnyardgrass
Figure PCTCN2020081646-appb-000054
Figure PCTCN2020081646-appb-000054
表36 A1混配烯禾啶对稻稗的实际防效与联合作用评价Table 36 Evaluation of actual control effect and joint effect of A1 mixed enoxypyr on rice barnyardgrass
Figure PCTCN2020081646-appb-000055
Figure PCTCN2020081646-appb-000055
表37 A1混配精喹禾灵对稻稗的实际防效与联合作用评价Table 37 Evaluation of actual control effect and joint effect of A1 mixed quizalofop on rice barnyardgrass
Figure PCTCN2020081646-appb-000056
Figure PCTCN2020081646-appb-000056
表38 A1混配高效氟吡甲禾灵对稻稗的实际防效与联合作用评价Table 38 Evaluation of actual control effect and joint effect of A1 mixed high-efficiency fluroxypyr on rice barnyardgrass
Figure PCTCN2020081646-appb-000057
Figure PCTCN2020081646-appb-000057
表39 A1混配环苯草酮对稻稗的实际防效与联合作用评价Table 39 Evaluation of actual control effect and joint effect of A1 mixed cyclofenone on rice barnyardgrass
Figure PCTCN2020081646-appb-000058
Figure PCTCN2020081646-appb-000058
表40 A1混配噁唑酰草胺对稻稗的实际防效与联合作用评价Table 40 Evaluation of actual control effect and joint effect of A1 mixed oxfenacet on rice barnyardgrass
Figure PCTCN2020081646-appb-000059
Figure PCTCN2020081646-appb-000059
表41 A1混配乙氧氟草醚对异型莎草的实际防效与联合作用评价Table 41 Evaluation of actual control effect and joint effect of A1 mixed oxyfluorfen on heterotypic sedge
Figure PCTCN2020081646-appb-000060
Figure PCTCN2020081646-appb-000060
表42 A1混配氟磺胺草醚对异型莎草的实际防效与联合作用评价Table 42 Evaluation of actual control effect and joint effect of A1 blended fomesafen on heterotypic sedge
Figure PCTCN2020081646-appb-000061
Figure PCTCN2020081646-appb-000061
表43 A1混配噁草酮对异型莎草的实际防效与联合作用评价Table 43 Evaluation of actual control effect and joint effect of A1 mixed oxadiazon on heterotypic sedge
Figure PCTCN2020081646-appb-000062
Figure PCTCN2020081646-appb-000062
表44 A1混配丙炔噁草酮对异型莎草的实际防效与联合作用评价Table 44 Evaluation of the actual control effect and joint effect of A1 mixed propinyl propinone on hetero-type sedge
Figure PCTCN2020081646-appb-000063
Figure PCTCN2020081646-appb-000063
表45 A1混配甲磺草胺对异型莎草的实际防效与联合作用评价Table 45 Evaluation of actual control effect and joint effect of A1 mixed sulfentrazone on heterotypic sedge
Figure PCTCN2020081646-appb-000064
Figure PCTCN2020081646-appb-000064
Figure PCTCN2020081646-appb-000065
Figure PCTCN2020081646-appb-000065
表46 A1混配双唑草腈对异型莎草的实际防效与联合作用评价Table 46 Evaluation of actual control effect and joint effect of A1 mixed pyrenpyril on heterotypic sedge
Figure PCTCN2020081646-appb-000066
Figure PCTCN2020081646-appb-000066
表47 A1混配丙炔氟草胺对异型莎草的实际防效与联合作用评价Table 47 The actual control effect and joint effect evaluation of A1 mixed flumioxazin on heterotypic sedge
Figure PCTCN2020081646-appb-000067
Figure PCTCN2020081646-appb-000067
表48 A1混配环戊噁草酮对异型莎草的实际防效与联合作用评价Table 48 Evaluation of actual control effect and joint effect of A1 mixed cyclopentoxin on heterotypic sedge
Figure PCTCN2020081646-appb-000068
Figure PCTCN2020081646-appb-000068
表49 A1混配tiafenacil对异型莎草的实际防效与联合作用评价Table 49 Evaluation of actual control effect and joint effect of A1 mixed tiafenacil on heterotypic sedge
Figure PCTCN2020081646-appb-000069
Figure PCTCN2020081646-appb-000069
表50 A1混配苯嘧磺草胺对异型莎草的实际防效与联合作用评价Table 50 Evaluation of actual control effect and joint effect of A1 mixed with saflufenacil on heterotypic sedge
Figure PCTCN2020081646-appb-000070
Figure PCTCN2020081646-appb-000070
表51 A1混配唑草酮对异型莎草的实际防效与联合作用评价Table 51 Evaluation of actual control effect and joint effect of A1 mixed carfentrazone on heterotypic sedge
Figure PCTCN2020081646-appb-000071
Figure PCTCN2020081646-appb-000071
表52 A1混配乙羧氟草醚对异型莎草的实际防效与联合作用评价Table 52 Evaluation of the actual control effect and combined effect of A1 mixed oxyfluorfen on heterotypic sedge
Figure PCTCN2020081646-appb-000072
Figure PCTCN2020081646-appb-000072
表53 A1混配三氟羧草醚对异型莎草的实际防效与联合作用评价Table 53 Evaluation of actual control effect and combined effect of A1 mixed acifluorfen on heterotypic sedge
Figure PCTCN2020081646-appb-000073
Figure PCTCN2020081646-appb-000073
表54 A1混配trifludimoxazin对异型莎草的实际防效与联合作用评价Table 54 Evaluation of actual control effect and joint effect of A1 mixed trifludimoxazin on heterotypic sedge
Figure PCTCN2020081646-appb-000074
Figure PCTCN2020081646-appb-000074
表55 A1混配莠去津对异型莎草的实际防效与联合作用评价Table 55 Evaluation of actual control effect and joint effect of A1 mixed atrazine on heterotypic sedge
Figure PCTCN2020081646-appb-000075
Figure PCTCN2020081646-appb-000075
表56 A1混配特丁津对异型莎草的实际防效与联合作用评价Table 56 Evaluation of actual control effect and joint effect of A1 mixed terbuthine on heterotypic sedge
Figure PCTCN2020081646-appb-000076
Figure PCTCN2020081646-appb-000076
表57 A1混配莠灭净对异型莎草的实际防效与联合作用评价Table 57 Evaluation of actual control effect and joint effect of A1 mixed Ammoniacea on hetero-type sedge
Figure PCTCN2020081646-appb-000077
Figure PCTCN2020081646-appb-000077
表58 A1混配嗪草酮对异型莎草的实际防效与联合作用评价Table 58 Evaluation of actual control effect and joint effect of A1 mixed oxatrione on heterotypic sedge
Figure PCTCN2020081646-appb-000078
Figure PCTCN2020081646-appb-000078
表59 A1混配氨唑草酮对异型莎草的实际防效与联合作用评价Table 59 The actual control effect and joint effect evaluation of A1 mixed amicarbazone on heterotypic sedge
Figure PCTCN2020081646-appb-000079
Figure PCTCN2020081646-appb-000079
表60 A1混配绿麦隆对异型莎草的实际防效与联合作用评价Table 60 Evaluation of actual control effect and joint effect of A1 mixed chlorotoluron on hetero-type sedge
Figure PCTCN2020081646-appb-000080
Figure PCTCN2020081646-appb-000080
表61 A1混配异丙隆对异型莎草的实际防效与联合作用评价Table 61 Evaluation of the actual control effect and joint effect of A1 mixed isoproturon on heterotypic sedge
Figure PCTCN2020081646-appb-000081
Figure PCTCN2020081646-appb-000081
表62 A1混配除草定对异型莎草的实际防效与联合作用评价Table 62 Evaluation of the actual control effect and joint effect of A1 mixed sedge on heteromorphic sedge
Figure PCTCN2020081646-appb-000082
Figure PCTCN2020081646-appb-000082
表63 A1混配三氟草嗪对异型莎草的实际防效与联合作用评价Table 63 The actual control effect and joint effect evaluation of A1 mixed triflurazine on heterotypic sedge
Figure PCTCN2020081646-appb-000083
Figure PCTCN2020081646-appb-000083
Figure PCTCN2020081646-appb-000084
Figure PCTCN2020081646-appb-000084
表64 A1混配cyclopyrimorate对异型莎草的实际防效与联合作用评价Table 64 The actual control effect and joint effect evaluation of A1 mixed cyclopyrimorate on heterotypic sedge
Figure PCTCN2020081646-appb-000085
Figure PCTCN2020081646-appb-000085
表65 A1混配敌稗对异型莎草的实际防效与联合作用评价Table 65 Evaluation of actual control effect and joint effect of A1 mixed propanil on heterotypic sedge
Figure PCTCN2020081646-appb-000086
Figure PCTCN2020081646-appb-000086
表66 A1混配哒草特对异型莎草的实际防效与联合作用评价Table 66 The actual control effect and joint effect evaluation of A1 mixed Pyridoxacin on heterotypic sedge
Figure PCTCN2020081646-appb-000087
Figure PCTCN2020081646-appb-000087
表67 A1混配灭草松对异型莎草的实际防效与联合作用评价Table 67 Evaluation of the actual control effect and joint effect of A1 mixed sedge on heteromorphic sedge
Figure PCTCN2020081646-appb-000088
Figure PCTCN2020081646-appb-000088
表68 A1混配溴苯腈对异型莎草的实际防效与联合作用评价Table 68 Actual control effect and joint effect evaluation of A1 mixed bromoxynil on heterotypic sedge
Figure PCTCN2020081646-appb-000089
Figure PCTCN2020081646-appb-000089
表69 A1混配仲丁灵对异型莎草的实际防效与联合作用评价Table 69 Evaluation of actual control effect and joint effect of A1 mixed Zhongdingling on heteromorphic sedge
Figure PCTCN2020081646-appb-000090
Figure PCTCN2020081646-appb-000090
表70 A1混配二甲戊灵对异型莎草的实际防效与联合作用评价Table 70 Evaluation of actual control effect and joint effect of A1 mixed pendimethalin on heterotypic sedge
Figure PCTCN2020081646-appb-000091
Figure PCTCN2020081646-appb-000091
Figure PCTCN2020081646-appb-000092
Figure PCTCN2020081646-appb-000092
表71 A1混配丁草胺对异型莎草的实际防效与联合作用评价Table 71 Evaluation of actual control effect and joint effect of A1 mixed butachlor on heterotypic sedge
Figure PCTCN2020081646-appb-000093
Figure PCTCN2020081646-appb-000093
表72 A1混配丙草胺对异型莎草的实际防效与联合作用评价Table 72 Evaluation of actual control effect and joint effect of A1 mixed pretilachlor on heterotypic sedge
Figure PCTCN2020081646-appb-000094
Figure PCTCN2020081646-appb-000094
表73 A1混配精异丙甲草胺对异型莎草的实际防效与联合作用评价Table 73 The actual control effect and joint effect evaluation of A1 mixed refined metolachlor on heterotypic sedge
Figure PCTCN2020081646-appb-000095
Figure PCTCN2020081646-appb-000095
表74 A1混配氟噻草胺对异型莎草的实际防效与联合作用评价Table 74 The actual control effect and joint effect evaluation of A1 mixed flufenacet on heterotypic sedge
Figure PCTCN2020081646-appb-000096
Figure PCTCN2020081646-appb-000096
表75 A1混配砜吡草唑对异型莎草的实际防效与联合作用评价Table 75 The actual control effect and combined effect evaluation of A1 mixed sulfoxizazole on heterotypic sedge
Figure PCTCN2020081646-appb-000097
Figure PCTCN2020081646-appb-000097
表76 A1混配莎稗磷对异型莎草的实际防效与联合作用评价Table 76 Evaluation of actual control effect and joint effect of A1 mixed sageron on heteromorphic sedge
Figure PCTCN2020081646-appb-000098
Figure PCTCN2020081646-appb-000098
表77 A1混配苄草丹对碎米莎草的实际防效与联合作用评价Table 77 Evaluation of the actual control effect and joint effect of A1 blended Promethazine on Cardamine Sedge
Figure PCTCN2020081646-appb-000099
Figure PCTCN2020081646-appb-000099
Figure PCTCN2020081646-appb-000100
Figure PCTCN2020081646-appb-000100
表78 A1混配禾草敌对碎米莎草的实际防效与联合作用评价Table 78 Actual control effect and joint effect evaluation of A1 mixed grass against Cardamine sedge
Figure PCTCN2020081646-appb-000101
Figure PCTCN2020081646-appb-000101
表79 A1混配禾草丹对碎米莎草的实际防效与联合作用评价Table 79 Evaluation of actual control effect and joint effect of A1 mixed Hecao Dan on Cardamine Sedge
Figure PCTCN2020081646-appb-000102
Figure PCTCN2020081646-appb-000102
表80 A1混配二氯喹啉酸对野慈姑的实际防效与联合作用评价Table 80 The actual control effect and joint effect evaluation of A1 mixed Quinclorac on Ye Cigu
Figure PCTCN2020081646-appb-000103
Figure PCTCN2020081646-appb-000103
表81 A1混配氯氟吡氧乙酸对野慈姑的实际防效与联合作用评价Table 81 The actual control effect and combined effect evaluation of A1 mixed with fluroxypyr on Ye Cigu
Figure PCTCN2020081646-appb-000104
Figure PCTCN2020081646-appb-000104
表82 A1混配氟氯吡啶酯对野慈姑的实际防效与联合作用评价Table 82 Evaluation of the actual control and combined effects of A1 mixed with fluclopyridine on Ye Cigu
Figure PCTCN2020081646-appb-000105
Figure PCTCN2020081646-appb-000105
表83 A1混配三氯吡氧乙酸对野慈姑的实际防效与联合作用评价Table 83 The actual control effect and combined effect evaluation of A1 mixed with Triclopyr on Ye Cigu
Figure PCTCN2020081646-appb-000106
Figure PCTCN2020081646-appb-000106
表84 A1混配二氯吡啶酸对野慈姑的实际防效与联合作用评价Table 84 Evaluation of actual control effect and combined effect of A1 mixed clopyralid on Ye Cigu
Figure PCTCN2020081646-appb-000107
Figure PCTCN2020081646-appb-000107
表85 A1混配氨氯吡啶酸对野慈姑的实际防效与联合作用评价Table 85 Evaluation of the actual control effect and combined effect of A1 mixed with Amlodipine on Ye Cigu
Figure PCTCN2020081646-appb-000108
Figure PCTCN2020081646-appb-000108
Figure PCTCN2020081646-appb-000109
Figure PCTCN2020081646-appb-000109
表86 A1混配氯氨吡啶酸对野慈姑的实际防效与联合作用评价Table 86 The actual control effect and combined effect evaluation of A1 mixed clospyridin on Ye Cigu
Figure PCTCN2020081646-appb-000110
Figure PCTCN2020081646-appb-000110
表87 A1混配麦草畏对野慈姑的实际防效与联合作用评价Table 87 The actual control effect and joint effect evaluation of A1 mixed dicamba on Ye Cigu
Figure PCTCN2020081646-appb-000111
Figure PCTCN2020081646-appb-000111
表88 A1混配氯氟吡啶酯对野慈姑的实际防效与联合作用评价Table 88 The actual control effect and combined effect evaluation of A1 mixed chlorofluoropyridine ester on Ye Cigu
Figure PCTCN2020081646-appb-000112
Figure PCTCN2020081646-appb-000112
表89 A1混配2-甲基-4-氯苯氧乙酸对野慈姑的实际防效与联合作用评价Table 89 Evaluation of the actual control and joint effects of A1 mixed with 2-methyl-4-chlorophenoxyacetic acid on Ye Cigu
Figure PCTCN2020081646-appb-000113
Figure PCTCN2020081646-appb-000113
表90 A1混配环丙嘧啶酸对野慈姑的实际防效与联合作用评价Table 90 Evaluation of the actual control and combined effects of A1 mixed ciprofenic acid on Ye Cigu
Figure PCTCN2020081646-appb-000114
Figure PCTCN2020081646-appb-000114
表91 A1混配草甘膦对鸭舌草的实际防效与联合作用评价Table 91 Evaluation of actual control effect and joint effect of A1 mixed glyphosate on Diffusa
Figure PCTCN2020081646-appb-000115
Figure PCTCN2020081646-appb-000115
表92 A1混配草铵膦对鸭舌草的实际防效与联合作用评价Table 92 Evaluation of actual control effect and joint effect of A1 blended glufosinate on Diffusa
Figure PCTCN2020081646-appb-000116
Figure PCTCN2020081646-appb-000116
Figure PCTCN2020081646-appb-000117
Figure PCTCN2020081646-appb-000117
表93 A1混配精草铵膦对鸭舌草的实际防效与联合作用评价Table 93 Evaluation of actual control effect and joint effect of A1 blended refined glufosinate on Diffusa
Figure PCTCN2020081646-appb-000118
Figure PCTCN2020081646-appb-000118
表94 A1混配敌草快对鸭舌草的实际防效与联合作用评价Table 94 Evaluation of the actual control effect and joint effect of A1 mixed diquat on the duck diffusa
Figure PCTCN2020081646-appb-000119
Figure PCTCN2020081646-appb-000119
表95 A1混配三嗪氟草胺对鸭舌草的实际防效与联合作用评价Table 95 Evaluation of the actual control effect and combined effect of A1 mixed triazine and flumifen on Diffusa
Figure PCTCN2020081646-appb-000120
Figure PCTCN2020081646-appb-000120
表96 A1混配茚嗪氟草胺对鸭舌草的实际防效与联合作用评价Table 96 Evaluation of the actual control effect and combined effect of A1 mixed indanazine and flumioxan on the grass
Figure PCTCN2020081646-appb-000121
Figure PCTCN2020081646-appb-000121
表97 A1混配噁嗪草酮对鸭舌草的实际防效与联合作用评价Table 97 The actual control effect and combined effect evaluation of A1 mixed oxazimone on the grass
Figure PCTCN2020081646-appb-000122
Figure PCTCN2020081646-appb-000122
表98 A1混配环庚草醚对鸭舌草的实际防效与联合作用评价Table 98 Evaluation of actual control effect and joint effect of A1 mixed cyprofen on Diffusa
Figure PCTCN2020081646-appb-000123
Figure PCTCN2020081646-appb-000123
表99 A2混配硝磺草酮对萤蔺的实际防效与联合作用评价Table 99 The actual control effect and joint effect evaluation of A2 mixed mesotrione on lucid rush
Figure PCTCN2020081646-appb-000124
Figure PCTCN2020081646-appb-000124
Figure PCTCN2020081646-appb-000125
Figure PCTCN2020081646-appb-000125
表100 A2混配苯唑草酮对萤蔺的实际防效与联合作用评价Table 100 Evaluation of actual control effect and combined effect of A2 mixed with oxaflutole on lucid rush
Figure PCTCN2020081646-appb-000126
Figure PCTCN2020081646-appb-000126
表101 A2混配环磺酮对萤蔺的实际防效与联合作用评价Table 101 The actual control effect and joint effect evaluation of A2 mixed cyclosulfone on lucid rush
Figure PCTCN2020081646-appb-000127
Figure PCTCN2020081646-appb-000127
表102 A2混配氟吡草酮对萤蔺的实际防效与联合作用评价Table 102 Evaluation of actual control effect and combined effect of A2 mixed with fluroxypyr on lucid rush
Figure PCTCN2020081646-appb-000128
Figure PCTCN2020081646-appb-000128
表103 A2混配呋喃磺草酮对萤蔺的实际防效与联合作用评价Table 103 Actual control effect and combined effect evaluation of A2 mixed fursotrione on lucid rush
Figure PCTCN2020081646-appb-000129
Figure PCTCN2020081646-appb-000129
表104 A2混配双环磺草酮对萤蔺的实际防效与联合作用评价Table 104 The actual control effect and joint effect evaluation of A2 mixed sulcotrione on lucid rush
Figure PCTCN2020081646-appb-000130
Figure PCTCN2020081646-appb-000130
表105 A2混配双唑草酮对萤蔺的实际防效与联合作用评价Table 105 The actual control effect and combined effect evaluation of A2 mixed pyrenpyrin on lucid rush
Figure PCTCN2020081646-appb-000131
Figure PCTCN2020081646-appb-000131
Figure PCTCN2020081646-appb-000132
Figure PCTCN2020081646-appb-000132
表106 A2混配环吡氟草酮对萤蔺的实际防效与联合作用评价Table 106 The actual control effect and joint effect evaluation of A2 mixed ciclopyrifon on lucid rush
Figure PCTCN2020081646-appb-000133
Figure PCTCN2020081646-appb-000133
表107 A2混配三唑磺草酮对萤蔺的实际防效与联合作用评价Table 107 The actual control effect and joint effect evaluation of A2 mixed triazole sulcotrione on rush of rush
Figure PCTCN2020081646-appb-000134
Figure PCTCN2020081646-appb-000134
表108 A2混配苯唑氟草酮对萤蔺的实际防效与联合作用评价Table 108 The actual control effect and combined effect evaluation of A2 mixed oxaflutole on lucid rush
Figure PCTCN2020081646-appb-000135
Figure PCTCN2020081646-appb-000135
表109 A2混配异噁唑草酮对萤蔺的实际防效与联合作用评价Table 109 The actual control effect and joint effect evaluation of A2 mixed isoxaflutole on lucid rush
Figure PCTCN2020081646-appb-000136
Figure PCTCN2020081646-appb-000136
表110 A2混配吡氟酰草胺对萤蔺的实际防效与联合作用评价Table 110 The actual control effect and joint effect evaluation of A2 mixed diflufenican on lucid rush
Figure PCTCN2020081646-appb-000137
Figure PCTCN2020081646-appb-000137
表111 A2混配氟吡酰草胺对萤蔺的实际防效与联合作用评价Table 111 The actual control effect and joint effect evaluation of A2 mixed with flufenacet on lucid rush
Figure PCTCN2020081646-appb-000138
Figure PCTCN2020081646-appb-000138
表112 A2混配异噁草松对萤蔺的实际防效与联合作用评价Table 112 Evaluation of actual control effect and joint effect of A2 mixed clomazone on firefly
Figure PCTCN2020081646-appb-000139
Figure PCTCN2020081646-appb-000139
Figure PCTCN2020081646-appb-000140
Figure PCTCN2020081646-appb-000140
表113 A2混配噻吩磺隆对丁香蓼的实际防效与联合作用评价Table 113 The actual control effect and joint effect evaluation of A2 mixed with Thifensulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000141
Figure PCTCN2020081646-appb-000141
表114 A2混配苄嘧磺隆对丁香蓼的实际防效与联合作用评价Table 114 The actual control effect and joint effect evaluation of A2 blended bensulfuron-methyl on Polygonum syringae
Figure PCTCN2020081646-appb-000142
Figure PCTCN2020081646-appb-000142
表115 A2混配吡嘧磺隆对丁香蓼的实际防效与联合作用评价Table 115 The actual control effect and joint effect evaluation of A2 mixed pyrsulfuron-methyl on Polygonum syringae
Figure PCTCN2020081646-appb-000143
Figure PCTCN2020081646-appb-000143
表116 A2混配噻酮磺隆对丁香蓼的实际防效与联合作用评价Table 116 The actual control effect and joint effect evaluation of A2 mixed thioketone sulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000144
Figure PCTCN2020081646-appb-000144
表117 A2混配氯吡嘧磺隆对丁香蓼的实际防效与联合作用评价Table 117 The actual control effect and combined effect evaluation of A2 mixed with chlorpyrisulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000145
Figure PCTCN2020081646-appb-000145
表118 A2混配砜嘧磺隆对丁香蓼的实际防效与联合作用评价Table 118 The actual control effect and joint effect evaluation of A2 mixed sulfonsulfuron-methyl on Polygonum syringae
Figure PCTCN2020081646-appb-000146
Figure PCTCN2020081646-appb-000146
表119 A2混配氟唑磺隆对丁香蓼的实际防效与联合作用评价Table 119 The actual control effect and joint effect evaluation of A2 mixed with fluzosulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000147
Figure PCTCN2020081646-appb-000147
Figure PCTCN2020081646-appb-000148
Figure PCTCN2020081646-appb-000148
表120 A2混配甲基二磺隆对丁香蓼的实际防效与联合作用评价Table 120 Evaluation of actual control effect and joint effect of A2 mixed with methyl disulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000149
Figure PCTCN2020081646-appb-000149
表121 A2混配烟嘧磺隆对丁香蓼的实际防效与联合作用评价Table 121 The actual control effect and joint effect evaluation of A2 mixed nicosulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000150
Figure PCTCN2020081646-appb-000150
表122 A2混配甲酰胺磺隆对丁香蓼的实际防效与联合作用评价Table 122 The actual control effect and joint effect evaluation of A2 mixed formamidesulfuron on Polygonum syringae
Figure PCTCN2020081646-appb-000151
Figure PCTCN2020081646-appb-000151
表123 A2混配唑嘧磺草胺对丁香蓼的实际防效与联合作用评价Table 123 The actual control effect and joint effect evaluation of A2 mixed flumetsulam on Polygonum syringae
Figure PCTCN2020081646-appb-000152
Figure PCTCN2020081646-appb-000152
表124 A2混配氟酮磺草胺对丁香蓼的实际防效与联合作用评价Table 124 The actual control effect and joint effect evaluation of A2 mixed with fluoxsulam on Polygonum syringae
Figure PCTCN2020081646-appb-000153
Figure PCTCN2020081646-appb-000153
表125 A2混配五氟磺草胺对丁香蓼的实际防效与联合作用评价Table 125 Actual control effect and joint effect evaluation of A2 mixed penoxsulam on Polygonum syringae
Figure PCTCN2020081646-appb-000154
Figure PCTCN2020081646-appb-000154
表126 A2混配氯酯磺草胺对丁香蓼的实际防效与联合作用评价Table 126 The actual control effect and joint effect evaluation of A2 mixed chlorfentrazone on Polygonum syringae
Figure PCTCN2020081646-appb-000155
Figure PCTCN2020081646-appb-000155
表127 A2混配啶磺草胺对丁香蓼的实际防效与联合作用评价Table 127 The actual control effect and joint effect evaluation of A2 blended flumetsulam on Polygonum syringae
Figure PCTCN2020081646-appb-000156
Figure PCTCN2020081646-appb-000156
Figure PCTCN2020081646-appb-000157
Figure PCTCN2020081646-appb-000157
表128 A2混配甲氧咪草烟对丁香蓼的实际防效与联合作用评价Table 128 Actual control effect and combined effect evaluation of A2 mixed imazamox on Polygonum syringae
Figure PCTCN2020081646-appb-000158
Figure PCTCN2020081646-appb-000158
表129 A2混配甲咪唑烟酸对丁香蓼的实际防效与联合作用评价Table 129 The actual control effect and combined effect evaluation of A2 mixed with cimetazole nicotinic acid on Polygonum syringae
Figure PCTCN2020081646-appb-000159
Figure PCTCN2020081646-appb-000159
表130 A2混配碘甲磺隆钠盐对丁香蓼的实际防效与联合作用评价Table 130 Actual control effect and joint effect evaluation of A2 mixed with iodomethsulfuron-methyl sodium salt on Polygonum syringae
Figure PCTCN2020081646-appb-000160
Figure PCTCN2020081646-appb-000160
表131 A2混配双草醚对丁香蓼的实际防效与联合作用评价Table 131 The actual control effect and joint effect evaluation of A2 mixed Bispyri on Polygonum syringae
Figure PCTCN2020081646-appb-000161
Figure PCTCN2020081646-appb-000161
表132 A2混配唑啉草酯对马唐的实际防效与联合作用评价Table 132 Evaluation of actual control effect and joint effect of A2 mixed pinoxaden on crabgrass
Figure PCTCN2020081646-appb-000162
Figure PCTCN2020081646-appb-000162
表133 A2混配烯草酮对马唐的实际防效与联合作用评价Table 133 Evaluation of actual control effect and joint effect of A2 mixed clethodim on crabgrass
Figure PCTCN2020081646-appb-000163
Figure PCTCN2020081646-appb-000163
Figure PCTCN2020081646-appb-000164
Figure PCTCN2020081646-appb-000164
表134 A2混配烯禾啶对马唐的实际防效与联合作用评价Table 134 Evaluation of actual control effect and joint effect of A2 mixed enoxypyr on crabgrass
Figure PCTCN2020081646-appb-000165
Figure PCTCN2020081646-appb-000165
表135 A2混配精喹禾灵对马唐的实际防效与联合作用评价Table 135 Evaluation of actual control effect and joint effect of A2 mixed quizalofop on crabgrass
Figure PCTCN2020081646-appb-000166
Figure PCTCN2020081646-appb-000166
表136 A2混配高效氟吡甲禾灵对马唐的实际防效与联合作用评价Table 136 Evaluation of actual control effect and combined effect of A2 mixed high-efficiency fluroxypyr on crabgrass
Figure PCTCN2020081646-appb-000167
Figure PCTCN2020081646-appb-000167
表137 A2混配环苯草酮对马唐的实际防效与联合作用评价Table 137 The actual control effect and joint effect evaluation of A2 mixed cyclofenone on crabgrass
Figure PCTCN2020081646-appb-000168
Figure PCTCN2020081646-appb-000168
表138 A2混配噁唑酰草胺对马唐的实际防效与联合作用评价Table 138 The actual control effect and combined effect evaluation of A2 mixed oxfenacet on crabgrass
Figure PCTCN2020081646-appb-000169
Figure PCTCN2020081646-appb-000169
表139 A2混配乙氧氟草醚对萤蔺的实际防效与联合作用评价Table 139 Evaluation of actual control effect and joint effect of A2 mixed oxyfluorfen on lucid rush
Figure PCTCN2020081646-appb-000170
Figure PCTCN2020081646-appb-000170
Figure PCTCN2020081646-appb-000171
Figure PCTCN2020081646-appb-000171
表140 A2混配氟磺胺草醚对萤蔺的实际防效与联合作用评价Table 140 Evaluation of the actual control effect and joint effect of A2 blended fomesafen on rushes
Figure PCTCN2020081646-appb-000172
Figure PCTCN2020081646-appb-000172
表141 A2混配噁草酮对萤蔺的实际防效与联合作用评价Table 141 Evaluation of actual control effect and joint effect of A2 mixed oxadiazon on lucid rush
Figure PCTCN2020081646-appb-000173
Figure PCTCN2020081646-appb-000173
表142 A2混配丙炔噁草酮对萤蔺的实际防效与联合作用评价Table 142 Evaluation of actual control effect and combined effect of A2 mixed propinyl propinone on lucid rush
Figure PCTCN2020081646-appb-000174
Figure PCTCN2020081646-appb-000174
表143 A2混配甲磺草胺对萤蔺的实际防效与联合作用评价Table 143 Evaluation of the actual control effect and joint effect of A2 mixed sulfentrazone on lucid rush
Figure PCTCN2020081646-appb-000175
Figure PCTCN2020081646-appb-000175
表144 A2混配双唑草腈对萤蔺的实际防效与联合作用评价Table 144 The actual control effect and joint effect evaluation of A2 mixed pyrenpyril on the ginger rush
Figure PCTCN2020081646-appb-000176
Figure PCTCN2020081646-appb-000176
表145 A2混配丙炔氟草胺对萤蔺的实际防效与联合作用评价Table 145 The actual control effect and joint effect evaluation of A2 mixed flumioxamide on lucid rush
Figure PCTCN2020081646-appb-000177
Figure PCTCN2020081646-appb-000177
表146 A2混配环戊噁草酮对萤蔺的实际防效与联合作用评价Table 146 The actual control effect and combined effect evaluation of A2 mixed cyclopentoxazone on lucid rush
Figure PCTCN2020081646-appb-000178
Figure PCTCN2020081646-appb-000178
Figure PCTCN2020081646-appb-000179
Figure PCTCN2020081646-appb-000179
表147 A2混配tiafenacil对萤蔺的实际防效与联合作用评价Table 147 Evaluation of actual control effect and joint effect of A2 mixed tiafenacil on rushes
Figure PCTCN2020081646-appb-000180
Figure PCTCN2020081646-appb-000180
表148 A2混配苯嘧磺草胺对萤蔺的实际防效与联合作用评价Table 148 The actual control effect and joint effect evaluation of A2 mixed with saflufenacil on lucid rush
Figure PCTCN2020081646-appb-000181
Figure PCTCN2020081646-appb-000181
表149 A2混配唑草酮对萤蔺的实际防效与联合作用评价Table 149 The actual control effect and joint effect evaluation of A2 mixed carfentrazone on lucid rush
Figure PCTCN2020081646-appb-000182
Figure PCTCN2020081646-appb-000182
表150 A2混配乙羧氟草醚对萤蔺的实际防效与联合作用评价Table 150 Evaluation of the actual control effect and combined effect of A2 mixed with acifluorfen on lucid rush
Figure PCTCN2020081646-appb-000183
Figure PCTCN2020081646-appb-000183
表151 A2混配三氟羧草醚对萤蔺的实际防效与联合作用评价Table 151 Evaluation of the actual control effect and combined effect of A2 mixed acifluorfen on lucid rush
Figure PCTCN2020081646-appb-000184
Figure PCTCN2020081646-appb-000184
表152 A2混配trifludimoxazin对萤蔺的实际防效与联合作用评价Table 152 The actual control effect and joint effect evaluation of A2 mixed trifludimoxazin on rushes
Figure PCTCN2020081646-appb-000185
Figure PCTCN2020081646-appb-000185
表153 A2混配莠去津对萤蔺的实际防效与联合作用评价Table 153 The actual control effect and joint effect evaluation of A2 mixed atrazine on firefly
Figure PCTCN2020081646-appb-000186
Figure PCTCN2020081646-appb-000186
表154 A2混配特丁津对萤蔺的实际防效与联合作用评价Table 154 Evaluation of actual control effect and joint effect of A2 mixed terbuthine on firefly
Figure PCTCN2020081646-appb-000187
Figure PCTCN2020081646-appb-000187
Figure PCTCN2020081646-appb-000188
Figure PCTCN2020081646-appb-000188
表155 A2混配莠灭净对萤蔺的实际防效与联合作用评价Table 155 The actual control effect and joint effect evaluation of A2 mixed Ammiejing on lucid rush
Figure PCTCN2020081646-appb-000189
Figure PCTCN2020081646-appb-000189
表156 A2混配嗪草酮对萤蔺的实际防效与联合作用评价Table 156 Evaluation of the actual control effect and combined effect of A2 mixed mesotrione on ginger rush
Figure PCTCN2020081646-appb-000190
Figure PCTCN2020081646-appb-000190
表157 A2混配氨唑草酮对萤蔺的实际防效与联合作用评价Table 157 Evaluation of actual control effect and combined effect of A2 mixed amicarbazone on ginger rush
Figure PCTCN2020081646-appb-000191
Figure PCTCN2020081646-appb-000191
表158 A2混配绿麦隆对萤蔺的实际防效与联合作用评价Table 158 Evaluation of the actual control effect and joint effect of A2 mixed chlorotoluron on firefly
Figure PCTCN2020081646-appb-000192
Figure PCTCN2020081646-appb-000192
表159 A2混配异丙隆对萤蔺的实际防效与联合作用评价Table 159 Evaluation of the actual control effect and joint effect of A2 mixed isoproturon on lucid rush
Figure PCTCN2020081646-appb-000193
Figure PCTCN2020081646-appb-000193
表160 A2混配除草定对萤蔺的实际防效与联合作用评价Table 160 Evaluation of the actual control effect and joint effect of A2 mixed chlordizidine on lucid rush
Figure PCTCN2020081646-appb-000194
Figure PCTCN2020081646-appb-000194
表161 A2混配三氟草嗪对萤蔺的实际防效与联合作用评价Table 161 Evaluation of the actual control effect and combined effect of A2 mixed triflurazine on lucid rush
Figure PCTCN2020081646-appb-000195
Figure PCTCN2020081646-appb-000195
表162 A2混配cyclopyrimorate对萤蔺的实际防效与联合作用评价Table 162 The actual control effect and joint effect evaluation of A2 mixed cyclopyrimorate on rushes
Figure PCTCN2020081646-appb-000196
Figure PCTCN2020081646-appb-000196
表163 A2混配敌稗对萤蔺的实际防效与联合作用评价Table 163 Evaluation of the actual control effect and joint effect of A2 mixed propanil on firefly
Figure PCTCN2020081646-appb-000197
Figure PCTCN2020081646-appb-000197
Figure PCTCN2020081646-appb-000198
Figure PCTCN2020081646-appb-000198
表164 A2混配哒草特对萤蔺的实际防效与联合作用评价Table 164 Evaluation of the actual control effect and joint effect of A2 mixed pyridazto on firefly
Figure PCTCN2020081646-appb-000199
Figure PCTCN2020081646-appb-000199
表165 A2混配灭草松对萤蔺的实际防效与联合作用评价Table 165 Evaluation of the actual control effect and joint effect of A2 mixed with Dioxapine on Firefly
Figure PCTCN2020081646-appb-000200
Figure PCTCN2020081646-appb-000200
表166 A2混配溴苯腈对萤蔺的实际防效与联合作用评价Table 166 The actual control effect and joint effect evaluation of A2 mixed bromoxynil on fluorescens
Figure PCTCN2020081646-appb-000201
Figure PCTCN2020081646-appb-000201
表167 A2混配仲丁灵对萤蔺的实际防效与联合作用评价Table 167 Evaluation of the actual control effect and joint effect of A2 mixed tributing ling on firefly
Figure PCTCN2020081646-appb-000202
Figure PCTCN2020081646-appb-000202
表168 A2混配二甲戊灵对萤蔺的实际防效与联合作用评价Table 168 The actual control effect and joint effect evaluation of A2 mixed pendimethalin on firefly
Figure PCTCN2020081646-appb-000203
Figure PCTCN2020081646-appb-000203
表169 A2混配丁草胺对萤蔺的实际防效与联合作用评价Table 169 Evaluation of the actual control effect and joint effect of A2 mixed butachlor on lucid rush
Figure PCTCN2020081646-appb-000204
Figure PCTCN2020081646-appb-000204
Figure PCTCN2020081646-appb-000205
Figure PCTCN2020081646-appb-000205
表170 A2混配丙草胺对萤蔺的实际防效与联合作用评价Table 170 Evaluation of the actual control effect and joint effect of A2 mixed pretilachlor on rushes
Figure PCTCN2020081646-appb-000206
Figure PCTCN2020081646-appb-000206
表171 A2混配精异丙甲草胺对萤蔺的实际防效与联合作用评价Table 171 Evaluation of the actual control effect and combined effect of A2 blended refined metolachlor on lucid rush
Figure PCTCN2020081646-appb-000207
Figure PCTCN2020081646-appb-000207
表172 A2混配氟噻草胺对萤蔺的实际防效与联合作用评价Table 172 The actual control effect and joint effect evaluation of A2 mixed flufenacet on lucid rush
Figure PCTCN2020081646-appb-000208
Figure PCTCN2020081646-appb-000208
表173 A2混配砜吡草唑对萤蔺的实际防效与联合作用评价Table 173 The actual control effect and joint effect evaluation of A2 mixed sulfone metazole on lucid rush
Figure PCTCN2020081646-appb-000209
Figure PCTCN2020081646-appb-000209
表174 A2混配莎稗磷对萤蔺的实际防效与联合作用评价Table 174 The actual control effect and joint effect evaluation of A2 mixed sarbifosate on fire rush
Figure PCTCN2020081646-appb-000210
Figure PCTCN2020081646-appb-000210
表175 A2混配苄草丹对萤蔺的实际防效与联合作用评价Table 175 Evaluation of the actual control effect and combined effect of A2 blended bencaodan on Yinglin
Figure PCTCN2020081646-appb-000211
Figure PCTCN2020081646-appb-000211
表176 A2混配禾草敌对萤蔺的实际防效与联合作用评价Table 176 The actual control effect and joint effect evaluation of A2 mixed grass against the firefly
Figure PCTCN2020081646-appb-000212
Figure PCTCN2020081646-appb-000212
表177 A2混配禾草丹对萤蔺的实际防效与联合作用评价Table 177 Evaluation of actual control effect and joint effect of A2 mixed Hecao Dan on Ying Lin
Figure PCTCN2020081646-appb-000213
Figure PCTCN2020081646-appb-000213
Figure PCTCN2020081646-appb-000214
Figure PCTCN2020081646-appb-000214
表178 A2混配二氯喹啉酸对泽泻的实际防效与联合作用评价Table 178 The actual control effect and joint effect evaluation of A2 mixed Quinclorac on Alisma
Figure PCTCN2020081646-appb-000215
Figure PCTCN2020081646-appb-000215
表179 A2混配氯氟吡氧乙酸对泽泻的实际防效与联合作用评价Table 179 The actual control effect and joint effect evaluation of A2 mixed with fluroxypyr on Alisma
Figure PCTCN2020081646-appb-000216
Figure PCTCN2020081646-appb-000216
表180 A2混配氟氯吡啶酯对泽泻的实际防效与联合作用评价Table 180 Evaluation of the actual control effect and joint effect of A2 mixed with fluclopyridine on Alisma
Figure PCTCN2020081646-appb-000217
Figure PCTCN2020081646-appb-000217
表181 A2混配三氯吡氧乙酸对泽泻的实际防效与联合作用评价Table 181 Evaluation of the actual control effect and combined effect of A2 mixed with triclopidine on Alisma
Figure PCTCN2020081646-appb-000218
Figure PCTCN2020081646-appb-000218
表182 A2混配二氯吡啶酸对泽泻的实际防效与联合作用评价Table 182 Evaluation of actual control effect and combined effect of A2 mixed clopyralid on Alisma
Figure PCTCN2020081646-appb-000219
Figure PCTCN2020081646-appb-000219
表183 A2混配氨氯吡啶酸对泽泻的实际防效与联合作用评价Table 183 Evaluation of the actual control effect and joint effect of A2 mixed with Amlodipine on Alisma
Figure PCTCN2020081646-appb-000220
Figure PCTCN2020081646-appb-000220
表184 A2混配氯氨吡啶酸对泽泻的实际防效与联合作用评价Table 184 Evaluation of actual control effect and joint effect of A2 mixed clospyridin on Alisma
Figure PCTCN2020081646-appb-000221
Figure PCTCN2020081646-appb-000221
表185 A2混配麦草畏对泽泻的实际防效与联合作用评价Table 185 Evaluation of actual control effect and joint effect of A2 mixed dicamba on Alisma
Figure PCTCN2020081646-appb-000222
Figure PCTCN2020081646-appb-000222
表186 A2混配氯氟吡啶酯对泽泻的实际防效与联合作用评价Table 186 The actual control effect and joint effect evaluation of A2 mixed with chlorofluoropyridine ester on Alisma
Figure PCTCN2020081646-appb-000223
Figure PCTCN2020081646-appb-000223
表187 A2混配2-甲基-4-氯苯氧乙酸对泽泻的实际防效与联合作用评价Table 187 The actual control effect and joint effect evaluation of A2 mixed with 2-methyl-4-chlorophenoxyacetic acid on Alisma
Figure PCTCN2020081646-appb-000224
Figure PCTCN2020081646-appb-000224
表188 A2混配环丙嘧啶酸对泽泻的实际防效与联合作用评价Table 188 Evaluation of actual control effect and combined effect of A2 mixed cyprodinil on Alisma
Figure PCTCN2020081646-appb-000225
Figure PCTCN2020081646-appb-000225
表189 A2混配草甘膦对丁香蓼的实际防效与联合作用评价Table 189 The actual control effect and joint effect evaluation of A2 mixed glyphosate on Polygonum syringae
Figure PCTCN2020081646-appb-000226
Figure PCTCN2020081646-appb-000226
表190 A2混配草铵膦对丁香蓼的实际防效与联合作用评价Table 190 Evaluation of actual control effect and joint effect of A2 blended glufosinate on Polygonum syringae
Figure PCTCN2020081646-appb-000227
Figure PCTCN2020081646-appb-000227
表191 A2混配精草铵膦对丁香蓼的实际防效与联合作用评价Table 191 The actual control effect and joint effect evaluation of A2 blended refined glufosinate on Polygonum syringae
Figure PCTCN2020081646-appb-000228
Figure PCTCN2020081646-appb-000228
表192 A2混配敌草快对丁香蓼的实际防效与联合作用评价Table 192 Evaluation of actual control effect and joint effect of A2 mixed diquat on Polygonum syringae
Figure PCTCN2020081646-appb-000229
Figure PCTCN2020081646-appb-000229
表193 A2混配三嗪氟草胺对丁香蓼的实际防效与联合作用评价Table 193 Actual control effect and combined effect evaluation of A2 mixed triazine and flumifen on Polygonum syringae
Figure PCTCN2020081646-appb-000230
Figure PCTCN2020081646-appb-000230
表194 A2混配茚嗪氟草胺对丁香蓼的实际防效与联合作用评价Table 194 Evaluation of actual control effect and joint effect of A2 mixed indanazine and flumioxan on Polygonum syringae
Figure PCTCN2020081646-appb-000231
Figure PCTCN2020081646-appb-000231
表195 A2混配噁嗪草酮对丁香蓼的实际防效与联合作用评价Table 195 Actual control effect and combined effect evaluation of A2 mixed oxazimone on Polygonum syringae
Figure PCTCN2020081646-appb-000232
Figure PCTCN2020081646-appb-000232
表196 A2混配环庚草醚对丁香蓼的实际防效与联合作用评价Table 196 Actual control effect and joint effect evaluation of A2 mixed cyclopeptol on Polygonum syringae
Figure PCTCN2020081646-appb-000233
Figure PCTCN2020081646-appb-000233
表197 A1钠盐混配三唑磺草酮对异型莎草的实际防效与联合作用评价Table 197 The actual control effect and joint effect evaluation of A1 sodium salt mixed with trifentrazone on heterotypic sedge
Figure PCTCN2020081646-appb-000234
Figure PCTCN2020081646-appb-000234
表198 A1钠盐混配氯氟吡啶酯对野慈姑的实际防效与联合作用评价Table 198 Evaluation of actual control effect and combined effect of A1 sodium salt mixed with chlorofluoropyridine on Ye Cigu
Figure PCTCN2020081646-appb-000235
Figure PCTCN2020081646-appb-000235
Figure PCTCN2020081646-appb-000236
Figure PCTCN2020081646-appb-000236
表199 A2钠盐混配敌稗对萤蔺的实际防效与联合作用评价Table 199 Evaluation of the actual control effect and joint effect of A2 sodium salt mixed with propanil on fire rush
Figure PCTCN2020081646-appb-000237
Figure PCTCN2020081646-appb-000237
表200 A2钾盐混配莎稗磷对萤蔺的实际防效与联合作用评价Table 200 The actual control effect and joint effect evaluation of A2 potassium salt mixed with sarranosin on fire rush
Figure PCTCN2020081646-appb-000238
Figure PCTCN2020081646-appb-000238
表201 A2钾盐混配2-甲基-4-氯苯氧乙酸对泽泻的实际防效与联合作用评价Table 201 Evaluation of actual control effect and joint effect of A2 potassium salt mixed with 2-methyl-4-chlorophenoxyacetic acid on Alisma
Figure PCTCN2020081646-appb-000239
Figure PCTCN2020081646-appb-000239
C)大田示范C) Daejeon Demonstration
利用实施例1-68制得的除草组合物进行田间杂草效果试验。2017年在江西鄱阳试验点进行示范性推广试验。田间发生的杂草主要有：稗草、千金子、鸭舌草、异型莎草、丁香蓼等。The herbicidal compositions prepared in Examples 1-68 were used for field weed effect tests. In 2017, a demonstration test was carried out at the Poyang test site in Jiangxi. The main weeds that occur in the field are: barnyardgrass, stephanotis, duck tongue, heteromorphic sedge, and Polygonum lilac.
试验方法：茎叶处理--待杂草处于2-3叶期，手动喷雾器，兑水量30公斤/667m 2，采用茎叶喷雾均匀喷雾。具体试验药剂及剂量详见表202，小区面积20平方米，每处理重复3次。施药后20天调查防除效果见表202。 Test method: Stem and leaf treatment-when the weeds are in the 2-3 leaf stage, use a manual sprayer, with a water volume of 30 kg/667m 2 , and spray evenly with stem and leaf spray. The specific test agents and dosages are shown in Table 202. The plot area is 20 square meters and each treatment is repeated 3 times. See Table 202 for the investigation of the control effect 20 days after application.
Figure PCTCN2020081646-appb-000240
Figure PCTCN2020081646-appb-000240
表202所述复配组合物的大田示范效果情况Field demonstration effect of the compound composition described in Table 202
药剂Pharmacy 用药量(g a.i./ha)Dosage amount (g a.i./ha) 株防效(％)Plant control effect (%)
1.A1+硝磺草酮(4+1)可分散油悬浮剂1.A1+Mesotrione (4+1) dispersible oil suspension concentrate 7575 93.693.6
2.A1+苯唑草酮(3+1)可分散油悬浮剂2. A1 + oxaflutole (3+1) dispersible oil suspension concentrate 6060 98.798.7
3.A1+双唑草酮(3+1)可分散油悬浮剂3.A1+Bifentrazone (3+1) dispersible oil suspension concentrate 6060 97.697.6
4.A1+苯唑氟草酮(4+4)可分散油悬浮剂4.A1+Fenoxazone (4+4) dispersible oil suspension concentrate 120120 92.292.2
5.A1+异噁唑草酮(4+4)可分散油悬浮剂5.A1+ Isoxaflutole (4+4) dispersible oil suspension concentrate 120120 92.492.4
6.A1+异噁草松(4+4)可分散油悬浮剂6.A1+ clomazone (4+4) dispersible oil suspension concentrate 120120 95.995.9
7.A1+吡嘧磺隆(4+2)可分散油悬浮剂7.A1+pyrsulfuron-methyl (4+2) dispersible oil suspension concentrate 9090 94.694.6
8.A1+五氟磺草胺(4+1)可分散油悬浮剂8.A1+Penoxsulam (4+1) dispersible oil suspension concentrate 7575 95.895.8
9.A1+甲氧咪草烟(4+1)可分散油悬浮剂9.A1+Imazethapyr (4+1) dispersible oil suspension concentrate 7575 91.191.1
10.A1+甲咪唑烟酸(4+1)可分散油悬浮剂10. A1 + cimetazole nicotinic acid (4+1) dispersible oil suspension concentrate 7575 90.690.6
11.A1+双草醚(4+1)可分散油悬浮剂11.A1+Bispyrifen (4+1) dispersible oil suspension concentrate 7575 95.695.6
12.A1+烯草酮(4+2)可分散油悬浮剂12.A1+Clethodim (4+2) dispersible oil suspension concentrate 9090 90.590.5
13.A1+烯禾啶(4+2)可分散油悬浮剂13.A1+ Enoxydim (4+2) dispersible oil suspension concentrate 9090 92.892.8
14.A1+精喹禾灵(4+2)可分散油悬浮剂14.A1 + quizalofop-p-ethyl (4+2) dispersible oil suspension concentrate 9090 93.193.1
15.A1+乙氧氟草醚(3+1)可分散油悬浮剂15.A1 + oxyfluorfen (3+1) dispersible oil suspension concentrate 6060 89.689.6
16.A1+噁草酮(3+1)可分散油悬浮剂16.A1+oxadiazon (3+1) dispersible oil suspension concentrate 6060 89.889.8
17.A1+丙炔噁草酮(3+1)可分散油悬浮剂17.A1+oxachlor (3+1) dispersible oil suspension concentrate 6060 90.290.2
18.A1+莠去津(3+5)水悬浮剂18.A1+Atrazine (3+5) water suspension concentrate 120120 85.485.4
19.A1+特丁津(3+3)水悬浮剂19.A1+terbucin (3+3) water suspension concentrate 9090 81.581.5
20.A1+敌稗(2+20)水悬浮剂20.A1 + propanil (2+20) water suspension 330330 88.788.7
21.A1+灭草松(4+30)水悬浮剂21.A1+Metazone (4+30) water suspension 510510 87.387.3
22.A1+仲丁灵(4+21)可分散油悬浮剂22.A1+Secondazole (4+21) dispersible oil suspension concentrate 375375 88.488.4
23.A1+二甲戊灵(4+21)可分散油悬浮剂23.A1+ pendimethalin (4+21) dispersible oil suspension concentrate 375375 95.795.7
24.A1+丁草胺(4+6)可分散油悬浮剂24.A1+Butachlor (4+6) dispersible oil suspension concentrate 150150 90.190.1
25.A1+丙草胺(2+4)可分散油悬浮剂25.A1+ pretilachlor (2+4) dispersible oil suspension concentrate 9090 92.992.9
26.A1+莎稗磷(4+2)可分散油悬浮剂26.A1+Sarbanphos (4+2) Dispersible Oil Suspension Concentrate 9090 98.698.6
27.A1+二氯喹啉酸(2+10)可分散油悬浮剂27.A1+quinclorac (2+10) dispersible oil suspension concentrate 180180 94.094.0
28.A1+氯氟吡氧乙酸(2+3)可分散油悬浮剂28.A1 + fluroxypyr (2+3) dispersible oil suspension concentrate 7575 92.592.5
29.A1+氯氟吡啶酯(3+1)可分散油悬浮剂29.A1+chlorofluoropyridine ester (3+1) dispersible oil suspension concentrate 6060 96.096.0
30.A1+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂30.A1+2-Methyl-4-chlorophenoxyacetic acid (3+10) dispersible oil suspension concentrate 195195 91.491.4
31.A1+草甘膦(4+16)水悬浮剂31.A1+glyphosate (4+16) water suspension 300300 94.494.4
32.A1+草铵膦(3+15)水悬浮剂32.A1+ glufosinate-ammonium (3+15) water suspending agent 270270 93.793.7
33.A1+敌草快(4+15)水悬浮剂33.A1+diquat (4+15) water suspension 285285 96.096.0
34.A1+环庚草醚(4+1)可分散油悬浮剂34.A1+ Cyprofen (4+1) dispersible oil suspension concentrate 7575 90.890.8
35.A2+硝磺草酮(4+1)可分散油悬浮剂35.A2+Mesotrione (4+1) dispersible oil suspension concentrate 6060 96.496.4
36.A2+苯唑草酮(3+1)可分散油悬浮剂36.A2+oxaflutole (3+1) dispersible oil suspension concentrate 4848 99.799.7
37.A2+双唑草酮(3+1)可分散油悬浮剂37.A2+Bifentrazone (3+1) dispersible oil suspension concentrate 4848 98.698.6
38.A2+苯唑氟草酮(4+4)可分散油悬浮剂38.A2+Fenoxazone (4+4) dispersible oil suspension concentrate 9696 95.095.0
39.A2+异噁唑草酮(4+4)可分散油悬浮剂39.A2+ Isoxaflutole (4+4) dispersible oil suspension concentrate 9696 95.295.2
40.A2+异噁草松(4+4)可分散油悬浮剂40.A2+ clomazone (4+4) dispersible oil suspension concentrate 9696 98.898.8
41.A2+吡嘧磺隆(4+2)可分散油悬浮剂41.A2+pyrsulfuron-methyl (4+2) dispersible oil suspension concentrate 7272 97.497.4
42.A2+五氟磺草胺(4+1)可分散油悬浮剂42.A2+Penoxsulam (4+1) dispersible oil suspension concentrate 6060 98.798.7
43.A2+甲氧咪草烟(4+1)可分散油悬浮剂43.A2+Imazethapyr (4+1) dispersible oil suspension concentrate 6060 93.893.8
44.A2+甲咪唑烟酸(4+1)可分散油悬浮剂44.A2 + cimetazole nicotinic acid (4+1) dispersible oil suspension concentrate 6060 93.393.3
45.A2+双草醚(4+1)可分散油悬浮剂45.A2+ Bispyrifen (4+1) dispersible oil suspension concentrate 6060 98.598.5
46.A2+烯草酮(4+2)可分散油悬浮剂46.A2+Clethodim (4+2) dispersible oil suspension concentrate 7272 93.293.2
47.A2+烯禾啶(4+2)可分散油悬浮剂47.A2+ Enoxydim (4+2) dispersible oil suspension concentrate 7272 95.695.6
48.A2+精喹禾灵(4+2)可分散油悬浮剂48.A2 + quizalofop-p-ethyl (4+2) dispersible oil suspension concentrate 7272 95.995.9
49.A2+乙氧氟草醚(3+1)可分散油悬浮剂49.A2+ oxyfluorfen (3+1) dispersible oil suspension concentrate 4848 92.392.3
50.A2+噁草酮(3+1)可分散油悬浮剂50.A2+oxadiazon (3+1) dispersible oil suspension concentrate 4848 92.592.5
51.A2+丙炔噁草酮(3+1)可分散油悬浮剂51.A2+ Oxachlor (3+1) dispersible oil suspension concentrate 4848 92.992.9
52.A2+莠去津(3+5)水悬浮剂52.A2+Atrazine (3+5) water suspension concentrate 9696 88.088.0
53.A2+特丁津(3+3)水悬浮剂53.A2+terbucin (3+3) water suspension concentrate 7272 83.983.9
54.A2+敌稗(2+20)水悬浮剂54.A2 + propanil (2+20) water suspension 264264 91.491.4
55.A2+灭草松(4+30)水悬浮剂55.A2+Metazone (4+30) water suspension 408408 89.989.9
56.A2+仲丁灵(4+21)可分散油悬浮剂56.A2+Secondazole (4+21) dispersible oil suspension concentrate 300300 91.191.1
57.A2+二甲戊灵(4+21)可分散油悬浮剂57.A2+ pendimethalin (4+21) dispersible oil suspension concentrate 300300 98.698.6
58.A2+丁草胺(4+6)可分散油悬浮剂58.A2+Butachlor (4+6) dispersible oil suspension concentrate 120120 92.892.8
59.A2+丙草胺(2+4)可分散油悬浮剂59.A2+ pretilachlor (2+4) dispersible oil suspension concentrate 7272 95.795.7
60.A2+莎稗磷(4+2)可分散油悬浮剂60.A2+Saraphos (4+2) dispersible oil suspension concentrate 7272 99.699.6
61.A2+二氯喹啉酸(2+10)可分散油悬浮剂61.A2+ Quinclorac (2+10) dispersible oil suspension concentrate 144144 96.896.8
62.A2+氯氟吡氧乙酸(2+3)可分散油悬浮剂62.A2+Chloropyroxyacetic acid (2+3) dispersible oil suspension concentrate 6060 95.395.3
63.A2+氯氟吡啶酯(3+1)可分散油悬浮剂63.A2+chlorofluoropyridine ester (3+1) dispersible oil suspension concentrate 4848 98.998.9
64.A2+2-甲基-4-氯苯氧乙酸(3+10)可分散油悬浮剂64.A2+2-Methyl-4-chlorophenoxyacetic acid (3+10) dispersible oil suspension concentrate 156156 94.194.1
65.A2+草甘膦(4+16)水悬浮剂65.A2+glyphosate (4+16) water suspension 240240 97.297.2
66.A2+草铵膦(3+15)水悬浮剂66.A2+ glufosinate-ammonium (3+15) water suspending agent 216216 96.596.5
67.A2+敌草快(4+15)水悬浮剂67.A2+diquat (4+15) water suspension 228228 98.998.9
68.A2+环庚草醚(4+1)可分散油悬浮剂68.A2+ Cyprofen (4+1) dispersible oil suspension concentrate 6060 93.593.5
经过大量试验和探索，本发明意外地发现，所述组合物用于防除异型莎草、碎米莎草、鸭舌草、稻稗、野慈姑、萤蔺、丁香蓼、马唐、泽泻、稗草、千金子等杂草，具有令人惊讶的、意想不到的增效作用，这种增效作用在低剂量下表现更为显著，可降低用药量，降低对环境的污染，且合理复配降低了农用成本，对ALS、ACCase抑制剂抗性杂草高效，具有很好的应用前景。同时经过测试在小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等植物显示良好的选择性和优异的增效作用，可以开发成具有广泛市场价值的除草剂混剂。After a lot of experiments and explorations, the present invention unexpectedly found that the composition is used for the prevention and control of special-shaped sedge, cardamine sedge, duck tongue, rice barnyard, wild sedge, firefly, polygonum lilac, crabgrass, Alisma, Weeds such as barnyardgrass and stephanotis have surprising and unexpected synergistic effects. This synergistic effect is more pronounced at low doses, which can reduce the amount of medicine used, reduce environmental pollution, and reasonably recover The formulation reduces agricultural costs, is highly effective against ALS and ACCase inhibitor-resistant weeds, and has a good application prospect. At the same time, it has been tested in wheat fields, corn fields, rice fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, Zoysia grass and other plants showing good selectivity and excellence The synergistic effect can be developed into a herbicide mixture with broad market value.

Claims (10)

  1. 一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition containing N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds, characterized in that it comprises a herbicidal effective amount of active ingredient A and active ingredient B, wherein,
    活性成分A为
    Figure PCTCN2020081646-appb-100001
    或其盐；     Active ingredient A is
    Figure PCTCN2020081646-appb-100001
    Or its salt;
    活性成分B选自以下化合物及其盐/酯中的一种或多种：The active ingredient B is selected from one or more of the following compounds and their salts/esters:
    (1)HPPD抑制剂：磺草酮、硝磺草酮、苯唑草酮、环磺酮、氟吡草酮、呋喃磺草酮、双环磺草酮、双唑草酮、环吡氟草酮、三唑磺草酮、苯唑氟草酮、磺酰草吡唑、吡唑特、吡草酮、tolpyralate、fenquinotrione、异噁唑草酮、苄草唑、
    Figure PCTCN2020081646-appb-100002
    (1) HPPD inhibitors: Sulcotrione, Mesotrione, Mesotrione, Mesotrione, Cyclosulfone, Fluopyzone, Fursotrione, Sulcotrione, Bifentrazone, Cicloflutodone , Trifentrazone, flufentrazone, sulfentrazone, pyrazot, metazachlor, tolpyralate, fenquinotrione, isoxaflutole, benazole,
    Figure PCTCN2020081646-appb-100002
    (2)PDS抑制剂：氟咯草酮、呋草酮、吡氟酰草胺、氟吡酰草胺、氟丁酰草胺、氟草敏、氟啶草酮；(2) PDS inhibitors: flurochloridone, fluridone, diflufenican, flufentrazone, flubutyrazamide, fluroxypyr, fluflumizone;
    (3)DOXP抑制剂：异噁草松、bixlozone；(3) DOXP inhibitors: clomazone, bixlozone;
    (4)ALS抑制剂：苯磺隆、噻吩磺隆、苄嘧磺隆、吡嘧磺隆、噻酮磺隆、氯吡嘧磺隆、丙嗪嘧磺隆、嗪吡嘧磺隆、砜嘧磺隆、乙氧磺隆、嘧苯胺磺隆、氟唑磺隆、甲基二磺隆、烟嘧磺隆、甲酰胺磺隆、唑嘧磺草胺、氟酮磺草胺、五氟磺草胺、氯酯磺草胺、啶磺草胺、甲氧咪草烟、甲咪唑烟酸、咪唑乙烟酸、灭草烟、嘧草醚、双氟磺草胺、环酯草醚、嘧啶肟草醚、丙苯磺隆、咪草烟、氯磺隆、醚磺隆、环丙嘧磺隆、酰嘧磺隆、醚苯磺隆、碘甲磺隆钠盐、氟啶嘧磺隆、氟吡磺隆、甲磺隆、三氟甲磺隆、磺酰磺隆、唑吡嘧磺隆、双草醚、磺草唑胺；(4) ALS inhibitors: trifensulfuron-methyl, thifensulfuron-methyl, bensulfuron-methyl, pyrazosulfuron-methyl, thiensulfuron-methyl, chlorpyrisulfuron-methyl, promethasulfuron-methyl, pyrazosulfuron-methyl, sulfensulfuron Sulfur-methyl, ethoxysulfuron-methyl, sulfensulfuron-methyl, fluzosulfuron-methyl, mesosulfuron-methyl, nicosulfuron-methyl, formamisulfuron-methyl, flumesulfuron, flumesulfuron, penoxsulam Amine, chlorfentrazone, flufentrazone, imazamox, imazafen, imazapyr, imazapyr, sulfentrazone, diflufentrazone, pyrifenpyr, saflufenacil, Promethsulfuron, Imazethapyr, Chlorsulfuron, Ethsulfuron, Ciprosulfuron, Amiduron-methyl, Trifensulfuron, Iodosulfuron-methyl sodium salt, Fluflusulfuron-methyl, Flufenuron-methyl , Metsulfuron-methyl, Trifluoromethanesulfuron-methyl, Sulfosulfuron-methyl, Zolpyrimesulfuron-methyl, Bispyrifen, Sulfentrazone;
    (5)ACCase抑制剂：炔草酯、唑啉草酯、烯草酮、烯禾啶、精喹禾灵、肟草酮、吡氟禾草灵、高效氟吡甲禾灵、禾草灵、精噁唑禾草灵、氰氟草酯、环苯草酮、噁唑酰草胺、噁草酸；(5) ACCase inhibitors: clodinafop-propargyl, pinoxaden, clethodim, enoxypyr, quizalofop-p-ethyl, oxenamid, fluoxyfop, high-efficiency fluoxyp-ethyl, propoxypyr, Fenoxaprop-p-ethyl, cyhalofop-butyl, cyclofenazone, oxfenacet, and oxalic acid;
    (6)PPO抑制剂：乙氧氟草醚、氟磺胺草醚、噁草酮、丙炔噁草酮、甲磺草胺、双唑草腈、丙炔氟草胺、环戊噁草酮、tiafenacil、苯嘧磺草胺、吡草醚、唑草酮、氟丙嘧草酯、氯氟草醚乙酯、乙羧氟草醚、三氟羧草醚、trifludimoxazin、嗪草酸甲酯；(6) PPO inhibitors: oxyfluorfen, fomesafen, oxadiazon, propinyl oxachlor, sulfentrazone, fentrazone, flufentrazone, pentoxazone, tiafenacil, saflufenacil, metafentrazone, carfentrazone, fluprofen-ethyl, fenflufen-ethyl, acifluorfen, acifluorfen, trifludimoxazin, methyl oxalate;
    (7)PSII抑制剂：莠去津、扑草净、西草净、特丁津、特丁净、莠灭净、异丙净、害草净、敌草净、西玛津、嗪草酮、乙嗪草酮、氨唑草酮、苯嗪草酮、氰草津、绿麦隆、异丙隆、敌草隆、氟草隆、利谷隆、丁噻隆、莎扑隆、绿谷隆、溴谷隆、草不隆、哒嗪醇、环嗪酮、 异戊乙净、草达津、除草定、环草定、特草定、甲基苯噻隆、环草隆、异噁隆、甲氧隆、枯草隆、三氟草嗪、Cyclopyrimorate、敌稗、哒草特、甜菜安、甜菜宁、灭草松、辛酰溴苯腈、溴苯腈、碘苯腈；(7) PSII inhibitors: atrazine, promethoxin, xicaojing, terbutazone, terbutazone, atramisole, isopropion, tetrabutazone, diquat, simazine, and trimethoprim , Acetoflutole, amicarbazone, fentrazone, cyanazine, chlorotoluron, isoproturon, diuron, fluroxyuron, liururon, buthirone, saprolon, chlorsulfuron, bromine Sulfuron, sulfuron, pyridazinol, cyprozinone, isoproterenol, chlordazin, chlordiazepoxide, cyclazone, terchloridine, metthiazion, cyclazone, isoxanol, methyl Oxalon, Cyclopyr, Triflurazine, Cyclopyrimorate, Propanic, Pyracotide, Betalan, Betanin, Trimethoprim, Bromoxynil, Bromoxynil, Iodobenzonitrile;
    (8)微管组装抑制剂：氟乐灵、仲丁灵、二甲戊灵、氟硫草定、乙丁烯氟灵、氨磺乐灵、氟草胺、噻草啶、拿草特、敌草索、抑草磷；(8) Inhibitors of microtubule assembly: trifluralin, sec-butaline, pendimethalin, fluthiopyr, ethalofen, sulfenoxypyr, fluoxamide, thiadimethoxazole, nattochlor, Diquat, ibufen;
    (9)微管组合抑制剂：双酰草胺；(9) Microtubule combination inhibitor: fenacet;
    (10)VLCFA抑制剂：乙草胺、丁草胺、丙草胺、异丙甲草胺、苯噻酰草胺、精异丙甲草胺、氟噻草胺、敌草胺、砜吡草唑、莎稗磷、二甲酚草胺、四唑酰草胺、三唑酰草胺、唑草胺、哌草磷、异丙草胺、甲草胺、吡唑草胺、毒草胺、烯草胺；(10) VLCFA inhibitors: acetochlor, butachlor, pretilachlor, metolachlor, mefenacet, fine metolachlor, flufenacet, napachlor, sulfoxifen Azole, sulfachlor, xylenfenacet, tetrafenpyr, trifentrazone, carfentrazone, mefenacet, propisochlor, alachlor, metafentrazone, chlorfenachlor, ene Grass amine
    (11)脂类合成(非乙酰辅酶A羧化酶)抑制剂：苄草丹、禾草敌、禾草丹、呋草黄、乙氧呋草黄、野麦畏、灭草敌、丁草特、环草敌、哌草丹、戊草丹；(11) Lipid synthesis (non-acetyl-Coenzyme A carboxylase) inhibitors: Prosopran, Promethazine, Promethazine, Formazan, Ethoxyfuraz, Dicamba, Dimethoate, Butachlor , Huancaodi, mediachlor, pentochlor;
    (12)合成激素类：二氯喹啉酸、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、氟氯吡啶酯、三氯吡氧乙酸、二氯吡啶酸、氨氯吡啶酸、氯氨吡啶酸、麦草畏、氯氟吡啶酯、2-甲基-4-氯苯氧乙酸、2-甲基-4-氯-苯酚乙硫酯、MCPB、2-甲基-4-氯苯氧丙酸、2-甲基-4-氯苯氧乙酸钠、2-甲基-4-氯苯氧乙酸异辛酯、2,4-二氯苯氧乙酸丁酯、2,4-二氯苯氧乙酸异辛酯、2,4-二氯苯氧基乙酸、氯甲喹啉酸、2甲4氯二甲铵盐、2,4-滴丙酸、2,4-滴丁酸、草除灵、环丙嘧啶酸；(12)Synthetic hormones: Quinclorac, fluroxypyr, isooctyl fluroxypyr, fluclopyr, triclopyr, clopyridine, pyridine acid, chloramine Picolinic acid, dicamba, chlorofluoropyridine ester, 2-methyl-4-chlorophenoxyacetic acid, 2-methyl-4-chloro-phenol ethyl thioester, MCPB, 2-methyl-4-chlorophenoxypropane Acid, sodium 2-methyl-4-chlorophenoxyacetate, 2-methyl-4-chlorophenoxyacetate isooctyl, 2,4-dichlorophenoxyacetate butyl, 2,4-dichlorophenoxyacetate Isooctyl acetate, 2,4-dichlorophenoxy acetic acid, quinclorac, 2-methyl-4-chlorodimethylammonium salt, 2,4-dpropionic acid, 2,4-dbutyric acid, and pyraclosporin , Cipromidic acid;
    (13)EPSPS抑制剂：草甘膦、草硫膦；(13) EPSPS inhibitors: glyphosate, glufosinate;
    (14)GS抑制剂：草铵膦、双丙氨膦、精草铵膦；(14) GS inhibitors: glufosinate-ammonium, bialaphos, and glufosinate-ammonium;
    (15)PSI抑制剂:百草枯、敌草快；(15) PSI inhibitors: Paraquat, Diquat;
    (16)DHP抑制剂：磺草灵；(16) DHP inhibitor: Sulfentrazone;
    (17)纤维素合成抑制剂：三嗪氟草胺、茚嗪氟草胺；(17) Cellulose synthesis inhibitors: triazine and flumioxazin;
    (18)其他除草剂：噁嗪草酮、环庚草醚、茚草酮、二氯喹啉草酮、喹草酮、苄草隆、灭草隆、tetflupyrolimet。(18) Other herbicides: oxazimone, cyprofen, indoxazone, chlorfenazone, quinazone, promethuron, imazapyr, tetflupyrolimet.
  2. 根据权利要求1所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物中A、B的重量比为1:600～200:1和1:500～100:1；优选为1:300～80:1和1:200～60:1；更优选为1:150～50:1和1:120～30:1；进一步优选为1:100～20:1和1:80～15:1；更进一步优选为1:50～10:1、1:30～5:1、1:10～4:1和1:5～1:1。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to claim 1, characterized in that in the herbicidal composition A, The weight ratio of B is 1:600-200:1 and 1:500-100:1; preferably 1:300-80:1 and 1:200-60:1; more preferably 1:150-50:1 and 1:120-30:1; more preferably 1:100-20:1 and 1:80-15:1; still more preferably 1:50-10:1, 1:30-5:1, 1:10 ～4:1 and 1:5～1:1.
  3. 根据权利要求1或2所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物中A和B的质量百分含量占总量的1-95％，优选10-80％。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to claim 1 or 2, characterized in that, in the herbicidal composition The mass percentage of A and B accounts for 1-95% of the total amount, preferably 10-80%.
  4. 根据权利要求1至3任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化 合物的除草组合物，其特征在于，所述除草组合物中还包括常规助剂。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to any one of claims 1 to 3, wherein the herbicidal composition The composition also includes conventional adjuvants.
  5. 根据权利要求4所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述常规助剂包括载体或表面活性剂。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to claim 4, wherein the conventional adjuvant comprises a carrier or Surfactant.
  6. 根据权利要求1至5任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物进一步包括至少一种安全剂。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to any one of claims 1 to 5, wherein the herbicidal composition The composition further includes at least one safener.
  7. 根据权利要求6所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述安全剂选自双苯噁唑酸、cyprosulfamide、吡唑解草酯、解毒喹、赤霉酸、furilazole、metcamifen中的一种或多种。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to claim 6, wherein the safener is selected from diphenyl One or more of oxazole acid, cyprosulfamide, pyrazolone, Jieduquine, gibberellic acid, furilazole, and metcamifen.
  8. 根据权利要求1至7任意一项所述的一种包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物，其特征在于，所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。The herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to any one of claims 1 to 7, wherein the herbicidal composition The specific preparation of the composition is a dispersible oil suspension, water suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, water emulsion or microemulsion.
  9. 如权利要求1至8任意一项所述包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物在防治杂草上的应用。The application of the herbicidal composition comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compounds according to any one of claims 1 to 8 for controlling weeds.
  10. 一种防治不想要的植物生长的方法，其包括将权利要求1至8任意一项所述包含N-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物施用于植物、植物部位、植物种子或植物生长的区域。A method for preventing and controlling the growth of unwanted plants, which comprises controlling the herbicidal compound comprising N-(1,3,4-oxadiazol-2-yl)arylcarboxamide according to any one of claims 1 to 8 The composition is applied to the plant, plant part, plant seed or area where the plant grows.
PCT/CN2020/081646 2019-10-30 2020-03-27 Herbicidal composition comprising n-(1,3,4-oxadiazole-2-yl) aryl formamide compounds and application of herbicidal composition WO2021082345A1 (en)

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