WO2020047890A1 - Herbicidal composition comprising heterocyclic amide compound and use thereof - Google Patents

Herbicidal composition comprising heterocyclic amide compound and use thereof Download PDF

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Publication number
WO2020047890A1
WO2020047890A1 PCT/CN2018/105699 CN2018105699W WO2020047890A1 WO 2020047890 A1 WO2020047890 A1 WO 2020047890A1 CN 2018105699 W CN2018105699 W CN 2018105699W WO 2020047890 A1 WO2020047890 A1 WO 2020047890A1
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Prior art keywords
polyoxyethylene ether
herbicidal composition
acid
methyl
amide compound
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PCT/CN2018/105699
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French (fr)
Chinese (zh)
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张景远
彭学岗
金涛
赵德
王志田
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青岛清原化合物有限公司
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Publication of WO2020047890A1 publication Critical patent/WO2020047890A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Definitions

  • the invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing a heterocyclic amide compound and an application thereof.
  • Chemical weed control is the most economical and effective method for controlling weeds in farmland.
  • long-term continuous high-dose use of a single variety or single action chemical herbicide can easily cause problems such as resistance and evolution of weeds.
  • Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems.
  • Patents CN105229005A, JP2016025116, and JP2017246933 each disclose a heterocyclic amide compound Or its salts and related herbicidal compositions.
  • the present invention provides a herbicidal composition containing a heterocyclic amide compound and an application thereof.
  • the composition can effectively prevent weed problems such as rice sedge, tang, sedge, multi-flower ryegrass, yarrow, stellaria, quiche, etc., and has the advantages of expanding the herbicidal spectrum, reducing the application amount, and generating synergies. Acts and resolves characteristics such as resistant weeds.
  • a herbicidal composition comprising a heterocyclic amide compound, comprising an herbicidally effective amount of active ingredient A and active ingredient B, wherein,
  • Active ingredient A is selected from one or more of the following compounds:
  • R 1 represents SEt and R 2 represents H, it is A1
  • R 1 represents CH 2 S (i-Pr) and R 2 represents Me, it is A2,
  • R 1 represents CH 2 SO 2 (i-Pr) and R 2 represents Me, it is A3,
  • R 1 represents CH 2 SO 2 Et and R 2 represents Me, it is A4;
  • the active ingredient B is selected from one or more of the following compounds and derivatives thereof:
  • Organophosphorus saraphos (CAS number: 64249-01-0), pipenidron (CAS number: 24151-93-7), and glufosinate (CAS number: 35597-44-5);
  • Triazabenzenes Xicaojing (CAS number: 1014-70-6), Prometryn (CAS number: 7287-19-6), Amicarbazone (CAS number: 129909-90-6) , Dicotol (CAS No .: 55512-33-9), Dingjin (CAS No .: 5915-41-3), Difenjing (CAS No .: 834-12-8), Herbicidin (CAS No .: 314 -40-9), oxadiazon (CAS number: 21087-64-9), atrazine (CAS number: 1912-24-9);
  • Triketones oxadiazone (CAS No .: 1622908-18-2), triazolam (CAS No .: 1911613-97-2), flubendicarb (CAS No .: 1992017-55) -6), sulfonyluprazole (CAS number: 365400-11-9), ciclopirox (CAS number: 1855929-45-1);
  • Aryloxyphenoxy propionates refined quinoxaline (CAS number: 100646-51-3), trimethoprim (CAS number: 105512-06-9), azoxystrobin (CAS number: 243973) -20-8);
  • Cyclohexanone Cyclobenone (CAS No .: 139001-49-3), Methodimone (CAS No .: 99129-21-2), Oxalone (CAS No .: 87820-88-0) );
  • Sulfonamides Sulfamethoxam (CAS No. 422556-08-9), Diflusulfuron (CAS No. 145701-23-1), Sulfachlor (CAS No. 147150-35) -4), saflufenacil (CAS number: 98967-40-9);
  • Sulfonyls Sulfamethoxam (CAS number: 3337-71-1);
  • the common name of the active compound all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, in particular One or more commercially available forms. If the common name indicates an ester or salt, all other conventional derivatives are also included in each case, such as other esters and salts, free acids and neutral compounds, and isomers, especially optical isomers, especially It is one or more commercially available forms.
  • the given chemical name of a compound represents at least one compound that is covered by a common name and is usually the preferred compound.
  • salts also include salts formed by the exchange of a cation with a hydrogen atom in a sulfonamide group.
  • the salt of the compound is preferably in the form of a respective alkali metal salt, alkaline earth metal salt or ammonium salt, preferably in the form of a respective alkali metal salt, more preferably in the form of a respective sodium or potassium salt, Most preferred is the form of the respective sodium salt.
  • 2,4-dibutyric acid derivatives include, but are not limited to, 2,4-dibutyric acid salts such as sodium, potassium, dimethylammonium, triethanolammonium, isopropylamine, choline, and the like, and 2,4-Diobutyric acid esters such as methyl, ethyl, butyl, isooctyl and the like.
  • the weight ratio of A and B is 1 to 200: 200 to 1 and 1 to 150: 150 to 1; preferably 1 to 120: 120 to 1 and 1 to 100: 100 to 1; more preferably 1 to 80:80 to 1 and 1 to 50: 50 to 1; more preferably 1 to 30: 30 to 1 and 1 to 10: 10 to 1.
  • the mass percentage of A and B in the herbicidal composition accounts for 1-95% of the total, preferably 10-80%.
  • the herbicidal composition further includes a conventional auxiliary agent, and the conventional auxiliary agent includes a carrier and a surfactant.
  • carrier herein means an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carriers are generally inert and must be agriculturally acceptable, especially by the treated plants.
  • the carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc .; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon replacement, liquefied gas, etc.
  • the surfactant may include an emulsifier, a dispersant, or a wetting agent, and it may be ionic or non-ionic.
  • examples which may be mentioned are salts of polyacrylic acid, lignin sulfonates, phenol sulfonic acids or naphthalene sulfonic acids, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (particularly Is an alkylphenol or an arylphenol) polymer, a sulfosuccinate, a taurine derivative (especially an taurine alkyl ester), and a phosphate of an alcohol or a polyhydroxyethylated phenol, Alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl-, hepta-
  • composition may also contain various other components such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
  • composition of the present invention can be mixed with the following active substances, for example, "World Encyclopedia of New Pesticide Technology", China Agricultural Science and Technology Press, 2010.9 and the known substances in the literature cited here.
  • the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, with a code when appropriate): acetochlor, butachlor, Alachlor, Promethachlor, Metolachlor, Prometachlor, Promechlor, Toxachlor, Chlortochlor, Naproxyl, R-Lonaphal , Fenoxadi, fenoxyfen, fenflufen, chlorfenapyr, flubutyramide, bromobutyramide, methacetamide, high-efficiency methacetamide, ethoxylate Acetochlor, fluoxadi, methachlor, imazapyr, clomazone, high-performance dicamba, high-performance
  • the herbicidal composition further includes at least one safener selected from:
  • Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds and preferred compounds are, for example, 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl Ethyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, pages 594-595), as well as described in, for example, WO91 / 07874 and PM (page 594-595).
  • Dichlorophenylpyrazolecarboxylic acid derivatives are, for example, 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1- (2,4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1 1,1-Dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4-dichlorophenyl) -5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • Triazolecarboxylic acid (S1) compounds and preferred compounds are, for example, fenchlorazole, that is, 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1 , 2,4-triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
  • 5-benzyl- or 5-phenyl-2-isooxazoline-3-carboxylic acids or 5,5-diphenyl-2-isooxazoline-3-carboxylic acids preferably
  • the compound is, for example, 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isooxazoline-3-carboxylic acid Ethyl Ester (S1-8) and related compounds described in WO91 / 08202, or 5,5-diphenyl-2-isooxazoline- described in patent application (WO-A-95 / 07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5- (4-fluorophenyl) -5-phenyl
  • S2 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (p.195-196), (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy Methyl) acetate (S2-4), (5-chloro-8-quinolinyloxy) ethyl acetate (S2-5), (5-chloro-8-quinolinyloxy) acetic acid methyl ester (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2- (2-propyleneiminooxy) -1-eth
  • 5-chloro-8-quinolinyloxy) malonic acid compounds and preferred compounds are, for example, (5-chloro-8-quinolinyloxy) malonic acid diethyl ester, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy) -methyl malonate and related compounds described in EP-A-0582198.
  • phenoxyacetic acid phenoxypropionic acid or aromatic carboxylic acid active compounds, such as 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba) .
  • Corn seed dressings are called safeners to prevent damage from thiourethane herbicides
  • Specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water-dispersible granules (dry suspensions), water emulsions, and microemulsions.
  • the present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling unwanted plant growth, which comprises applying the herbicidal composition to a plant, plant part, plant seed, or Area of plant growth
  • composition of the present invention can be applied to the leaves of the plant to be treated by spraying, that is, to the weeds, especially to the surface that is affected or easily affected by weeds.
  • the herbicidal composition of the present invention When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities using a single herbicide, and the activity of a single herbicide.
  • the synergistic effects are reduced application rates, wider weed control spectrum, faster and longer-lasting weed control, these characteristics are required during weed control practice.
  • these new compositions are clearly superior to existing herbicides, achieving reduced use and being more environmentally friendly.
  • composition of the present invention is environmentally friendly and easily degrades in the environment.
  • dispersable oil suspending agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned dispersible oil suspending agent processing process Put all the materials into the mixing tank, mix and pass the colloid mill, then enter the sand mill three-stage sand mill, and finally cut it uniformly in the shearing machine. After passing the test, transfer Fill to the tank.
  • 3WP-2000 walking spray tower Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 type one ten thousandth electronic balance (Germany); ZDR2000 intelligent data logger (Hangzhou Zeda Instrument Co., Ltd.); SPX intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
  • the required active ingredients are diflufenone, cimiflufenone, flufenazone, and triazolam.
  • the other active ingredients are purchased by the reagent company.
  • the original drugs all use acetone as the solvent, and are diluted with 0.1% emulsifier Tween-80 aqueous solution.
  • Each treatment was repeated 4 times, each treatment was 3 pots, and 20 weed seeds were sown in each pot, for a total of 60 plants per treatment.
  • Absolute number survey method was used to cut the whole seedlings of surviving weeds along the soil surface with a blade, and the fresh weeds were weighed with an analytical balance. For dead weeds, the fresh weight is zero.
  • the herbicide composition prepared in Examples 59-64 was used for field weed effect test.
  • Stem and leaf treatment until the weeds are in the 3-4 leaf stage, use a hand sprayer with a water volume of 30 kg / 667m 2 , and spray uniformly with the stem and leaf spray.
  • test agents and dosages are shown in Table 72.
  • the plot area is 50 square meters, and each treatment is repeated 4 times. Investigate the control effect 20 days after application
  • the present invention unexpectedly found that the composition is used for controlling weeds such as rice paddy, tangs, sedges, ryegrass, yarrow, stellaria, and agave
  • weeds such as rice paddy, tangs, sedges, ryegrass, yarrow, stellaria, and agave
  • this synergistic effect is more significant at low doses, which can reduce drug use, reduce environmental pollution, and rationally reduce agricultural costs, and inhibit ALS and ACCase
  • the agent-resistant weeds are highly effective and have good application prospects.
  • it has been tested in wheat, corn, rice, peanut, sugarcane, sorghum, millet, potato, rape, soybean, cotton, vegetables, bluegrass, tall fescue, zoysia and other plants. Synergistic effects can be developed into herbicide blends with broad market value.

Abstract

Disclosed are a herbicidal composition comprising a heterocyclic amide compound and the use thereof. The herbicidal composition comprises a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from one or more of compounds of the following general formula: A1, when R 1 represents SEt, R 2 represents H; A2, when R 1 represents CH 2S(i-Pr), R 2 represents Me; A3, when R 1 represents CH 2SO 2(i-Pr), R 2 represents Me; and A4, when R 1 represents CH 2SO 2Et, R 2 represents Me; and the active ingredient B is selected from one or more of the following compounds and salts/ethers thereof: organophosphorus; triazines; substituted ureas; and triketones, etc. The composition can effectively prevent weed problems, such as rice tares, digitaria sanguinalis (L. ) scop., cyperus difformis, Italian rye grass, dayflower, starwort, monochoria vaginalis, etc., and has the characteristics of expanding the herbicidal spectrum, reducing the application rate, being able to produce synergistic effects and solving the problem of resistant weeds.

Description

包含杂环酰胺类化合物的除草组合物及其应用Herbicidal composition containing heterocyclic amide compound and application thereof 技术领域Technical field
本发明属于农药领域，具体涉及一种包含杂环酰胺类化合物的除草组合物及其应用。The invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing a heterocyclic amide compound and an application thereof.
背景技术Background technique
化学除草是农田杂草防除中最为经济、有效的手段，但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂，容易造成杂草耐药和抗性演化等问题。除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点，是解决上述问题的最为有效的方法之一。专利CN105229005A、JP2016025116、JP2017246933分别公开了一种杂环酰胺化合物
Figure PCTCN2018105699-appb-000001
或其盐及相关除草组合物。而生产上仍需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。 Chemical weed control is the most economical and effective method for controlling weeds in farmland. However, long-term continuous high-dose use of a single variety or single action chemical herbicide can easily cause problems such as resistance and evolution of weeds. Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems. Patents CN105229005A, JP2016025116, and JP2017246933 each disclose a heterocyclic amide compound
Figure PCTCN2018105699-appb-000001
Or its salts and related herbicidal compositions. However, we still need to develop a variety of herbicidal compositions with high safety, broad herbicidal spectrum, which can produce synergistic effects and solve the problem of resistant weeds.
发明内容Summary of the Invention
为解决现有技术中存在的上述问题，本发明提供一种包含杂环酰胺类化合物的除草组合物及其应用。该组合物能有效防除稻稗、马唐、异型莎草、多花黑麦草、鸭跖草、繁缕、鸭舌草等杂草问题，具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。In order to solve the above problems in the prior art, the present invention provides a herbicidal composition containing a heterocyclic amide compound and an application thereof. The composition can effectively prevent weed problems such as rice sedge, tang, sedge, multi-flower ryegrass, yarrow, stellaria, quiche, etc., and has the advantages of expanding the herbicidal spectrum, reducing the application amount, and generating synergies. Acts and resolves characteristics such as resistant weeds.
一种包含杂环酰胺类化合物的除草组合物，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition comprising a heterocyclic amide compound, comprising an herbicidally effective amount of active ingredient A and active ingredient B, wherein,
活性成分A选自以下通式化合物中的一种或多种：
Figure PCTCN2018105699-appb-000002
Active ingredient A is selected from one or more of the following compounds:
Figure PCTCN2018105699-appb-000002
当R 1代表SEt，R 2代表H时为A1， When R 1 represents SEt and R 2 represents H, it is A1,
当R 1代表CH 2S(i-Pr)，R 2代表Me时为A2， When R 1 represents CH 2 S (i-Pr) and R 2 represents Me, it is A2,
当R 1代表CH 2SO 2(i-Pr)，R 2代表Me时为A3， When R 1 represents CH 2 SO 2 (i-Pr) and R 2 represents Me, it is A3,
当R 1代表CH 2SO 2Et，R 2代表Me时为A4； When R 1 represents CH 2 SO 2 Et and R 2 represents Me, it is A4;
活性成分B选自以下化合物及其盐/酯等衍生物中的一种或多种：The active ingredient B is selected from one or more of the following compounds and derivatives thereof:
(1)有机磷类：莎稗磷(CAS号：64249-01-0)、哌草磷(CAS号：24151-93-7)、精草铵膦(CAS号：35597-44-5)；(1) Organophosphorus: saraphos (CAS number: 64249-01-0), pipenidron (CAS number: 24151-93-7), and glufosinate (CAS number: 35597-44-5);
(2)三氮苯类：西草净(CAS号：1014-70-6)、扑草净(CAS号：7287-19-6)、胺唑草酮(CAS号：129909-90-6)、哒草特(CAS号：55512-33-9)、特丁津(CAS号：5915-41-3)、 莠灭净(CAS号：834-12-8)、除草定(CAS号：314-40-9)、嗪草酮(CAS号：21087-64-9)、莠去津(CAS号：1912-24-9)；(2) Triazabenzenes: Xicaojing (CAS number: 1014-70-6), Prometryn (CAS number: 7287-19-6), Amicarbazone (CAS number: 129909-90-6) , Dicotol (CAS No .: 55512-33-9), Dingjin (CAS No .: 5915-41-3), Difenjing (CAS No .: 834-12-8), Herbicidin (CAS No .: 314 -40-9), oxadiazon (CAS number: 21087-64-9), atrazine (CAS number: 1912-24-9);
(3)取代脲类：绿麦隆(CAS号：15545-48-9)、异丙隆(CAS号：34123-59-6)、敌草隆(CAS号：330-54-1)、利谷隆(CAS号：330-55-2)；(3) Substituted ureas: green wheat (CAS number: 15545-48-9), isoprolong (CAS number: 34123-59-6), diuron (CAS number: 330-54-1), Lee Gu Long (CAS number: 330-55-2);
(4)三酮类：双唑草酮(CAS号：1622908-18-2)、三唑磺草酮(CAS号：1911613-97-2)、苯唑氟草酮(CAS号：1992017-55-6)、磺酰草吡唑(CAS号：365400-11-9)、环吡氟草酮(CAS号：1855929-45-1)；(4) Triketones: oxadiazone (CAS No .: 1622908-18-2), triazolam (CAS No .: 1911613-97-2), flubendicarb (CAS No .: 1992017-55) -6), sulfonyluprazole (CAS number: 365400-11-9), ciclopirox (CAS number: 1855929-45-1);
(5)吡啶羧酸类：氟氯吡啶酯(CAS号：943831-98-9)、氯氟吡氧乙酸(CAS号：69377-81-7)、2,4-滴丁酸(CAS号：94-75-7)、二氯吡啶酸(CAS号：1702-17-6)、氨氯吡啶酸(CAS号：1918-02-1)、三氯吡氧乙酸(CAS号：55335-06-3)、二氯喹啉草酮(CAS号：1350901-36-8)；(5) Pyridine carboxylic acids: fluchloropyridine ester (CAS No .: 943831-98-9), fluflurane acetic acid (CAS No. 69377-81-7), 2,4-dibutyric acid (CAS No .: 94-75-7), dichloropyridic acid (CAS number: 1702-17-6), aminochloropyridic acid (CAS number: 1918-02-1), trichloropyroxyacetic acid (CAS number: 55335-06- 3). Dichloroquinolinone (CAS No .: 1350901-36-8);
(6)二硝基苯胺类：仲丁灵(CAS号：33629-47-9)、氟乐灵(CAS号：1582-09-8)；(6) Dinitroanilines: succinate (CAS number: 33629-47-9), fluloride (CAS number: 1582-09-8);
(7)酰胺类：砜吡草唑(CAS号：447399-55-5)、异丙草胺(CAS号：86763-47-5)；(7) Amides: sulfamethoxazole (CAS number: 447399-55-5), isoprofen (CAS number: 86763-47-5);
(8)芳氧苯氧丙酸酯类：精喹禾灵(CAS号：100646-51-3)、炔草酯(CAS号：105512-06-9)、唑啉草酯(CAS号：243973-20-8)；(8) Aryloxyphenoxy propionates: refined quinoxaline (CAS number: 100646-51-3), trimethoprim (CAS number: 105512-06-9), azoxystrobin (CAS number: 243973) -20-8);
(9)环己烯酮类：环苯草酮(CAS号：139001-49-3)、烯草酮(CAS号：99129-21-2)、肟草酮(CAS号：87820-88-0)；(9) Cyclohexanone: Cyclobenone (CAS No .: 139001-49-3), Methodimone (CAS No .: 99129-21-2), Oxalone (CAS No .: 87820-88-0) );
(10)磺酰脲类：甲基二磺隆(CAS号：208465-21-8)、氟唑磺隆(CAS号：181274-17-9)、环酯草醚(CAS号：135186-78-6)；(10) Sulfonylureas: methyldisulfuron (CAS number: 208465-21-8), flusulfuron (CAS number: 181274-17-9), ciprofen (CAS number: 135186-78) -6);
(11)磺酰胺类：啶磺草胺(CAS号：422556-08-9)、双氟磺草胺(CAS号：145701-23-1)、氯酯磺草胺(CAS号：147150-35-4)、唑嘧磺草胺(CAS号：98967-40-9)；(11) Sulfonamides: Sulfamethoxam (CAS No. 422556-08-9), Diflusulfuron (CAS No. 145701-23-1), Sulfachlor (CAS No. 147150-35) -4), saflufenacil (CAS number: 98967-40-9);
(12)氨磺酰类：磺草灵(CAS号：3337-71-1)；(12) Sulfonyls: Sulfamethoxam (CAS number: 3337-71-1);
(13)其他：呋咯草酮(CAS号：61213-25-0)、吡氟酰草胺(CAS号：83164-33-4)、氟丁酰草胺(CAS号：113614-08-7)、氟草敏(CAS号：27314-13-2)、唑草酮(CAS号：128621-72-7)、氟磺胺草醚(CAS号：72178-02-0)、苯嘧磺草胺(CAS号：372137-35-4)、吡草醚(CAS号：129630-19-9)。(13) Others: Furazone (CAS No .: 61213-25-0), flufenamid (CAS No .: 83164-33-4), fluoxalox (CAS No .: 113614-08-7) ), Fluroxypyr (CAS number: 27314-13-2), oxaflutole (CAS number: 128621-72-7), flusulfuron (CAS number: 72178-02-0), saflufenacil (CAS number: 372137-35-4), imazapyrrol (CAS number: 129630-19-9).
在本说明书的上下文中，如果使用活性化合物的通用名称的缩写形式，则在每种情况下包括所有的常规衍生物，例如酯和盐，以及异构体，特别是光学异构体，特别是一种或多种市售形式。如果通用名称表示酯或盐，则在每种情况下还包括所有其他的常规衍生物，例如其他的酯和盐、游离酸和中性化合物，以及异构体，特别是光学异构体，特别是一种或多种市售形式。给出的化合物的化学名称表示至少一种被通用名称涵盖的化合物，通常是优选的 化合物。在磺酰胺如磺酰脲的情况下，盐还包括通过阳离子与磺酰胺基团中的氢原子交换而形成的盐。In the context of this description, if the abbreviated form of the common name of the active compound is used, all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, in particular One or more commercially available forms. If the common name indicates an ester or salt, all other conventional derivatives are also included in each case, such as other esters and salts, free acids and neutral compounds, and isomers, especially optical isomers, especially It is one or more commercially available forms. The given chemical name of a compound represents at least one compound that is covered by a common name and is usually the preferred compound. In the case of sulfonamides such as sulfonylureas, salts also include salts formed by the exchange of a cation with a hydrogen atom in a sulfonamide group.
在本发明的上下文中，化合物的盐优选为各自的碱金属盐、碱土金属盐或铵盐的形式，优选为各自的碱金属盐的形式，更优选为各自的钠盐或钾盐的形式，最优选为各自的钠盐的形式。In the context of the present invention, the salt of the compound is preferably in the form of a respective alkali metal salt, alkaline earth metal salt or ammonium salt, preferably in the form of a respective alkali metal salt, more preferably in the form of a respective sodium or potassium salt, Most preferred is the form of the respective sodium salt.
例如，2,4-滴丁酸衍生物包含但不限于：2,4-滴丁酸盐如钠盐、钾盐、二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等，以及2,4-滴丁酸酯如甲酯、乙酯、丁酯、异辛酯等。For example, 2,4-dibutyric acid derivatives include, but are not limited to, 2,4-dibutyric acid salts such as sodium, potassium, dimethylammonium, triethanolammonium, isopropylamine, choline, and the like, and 2,4-Diobutyric acid esters such as methyl, ethyl, butyl, isooctyl and the like.
A、B的重量比为1～200:200～1和1～150:150～1；优选为1～120:120～1和1～100:100～1；更优选为1～80:80～1和1～50:50～1；进一步优选为1～30:30～1和1～10:10～1。The weight ratio of A and B is 1 to 200: 200 to 1 and 1 to 150: 150 to 1; preferably 1 to 120: 120 to 1 and 1 to 100: 100 to 1; more preferably 1 to 80:80 to 1 and 1 to 50: 50 to 1; more preferably 1 to 30: 30 to 1 and 1 to 10: 10 to 1.
所述除草组合物中A、B的质量百分含量占总量的1-95％，优选10-80％。The mass percentage of A and B in the herbicidal composition accounts for 1-95% of the total, preferably 10-80%.
所述除草组合物中还包含常规助剂，所述常规助剂包括载体、表面活性剂。The herbicidal composition further includes a conventional auxiliary agent, and the conventional auxiliary agent includes a carrier and a surfactant.
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的施用，该载体一般是惰性的且必须是农业上可接受的，特别是被处理的植物所接受。载体可以是固体的，如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等；或者液体的，如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。The term "carrier" herein means an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carriers are generally inert and must be agriculturally acceptable, especially by the treated plants. The carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc .; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon replacement, liquefied gas, etc.
表面活性剂可包括乳化剂、分散剂或润湿剂，它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐，以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚，此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、木素亚硫酸盐废液，以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在，以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。The surfactant may include an emulsifier, a dispersant, or a wetting agent, and it may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acid, lignin sulfonates, phenol sulfonic acids or naphthalene sulfonic acids, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (particularly Is an alkylphenol or an arylphenol) polymer, a sulfosuccinate, a taurine derivative (especially an taurine alkyl ester), and a phosphate of an alcohol or a polyhydroxyethylated phenol, Alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl-, hepta- and stearyl alcohols and sulfated fatty alcohols Glycol ethers, in addition to the condensation products of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylbenzene Polyglycol ether, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohols and fatty alcohol / ethylene oxide condensates, ethoxy Castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol ester, lignin sulfite waste liquid, and Proteins, denatured proteins, polysaccharides (such as methyl cellulose), hydrophobically modified starches, polyvinyl alcohol, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone, and copolymers thereof. At least one surfactant is required to facilitate dispersion of the active ingredients in water and to enable them to be properly applied to plants.
上述组合物也可含有各种其他的组分，如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。The above composition may also contain various other components such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
另外，本发明的组合物可以与以下活性物质混合，例如《世界农药新品种技术大全》，中国农业科学技术出版社，2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活 性物质，(备注:化合物的名称，或者为根据国际标准化组织(ISO)的普通名称，或者为化学名称，适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、绿磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D 异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、三唑磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙 嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489，LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。In addition, the composition of the present invention can be mixed with the following active substances, for example, "World Encyclopedia of New Pesticide Technology", China Agricultural Science and Technology Press, 2010.9 and the known substances in the literature cited here. For example, the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, with a code when appropriate): acetochlor, butachlor, Alachlor, Promethachlor, Metolachlor, Prometachlor, Promechlor, Toxachlor, Chlortochlor, Naproxyl, R-Lonaphal , Fenoxadi, fenoxyfen, fenflufen, chlorfenapyr, flubutyramide, bromobutyramide, methacetamide, high-efficiency methacetamide, ethoxylate Acetochlor, fluoxadi, methachlor, imazapyr, clomazone, high-performance dicamba, high-performance triclopap, dipropachlor, methachlor, butachlor, Cyclopramide, Flusulfuron, Hesaclopyr, Isobutachlor, Promethachlor, Terbutachlor, Xyluron, Metformamide, Paracetamol, Trimethoprim, Chloride Formamide, fenpropenil, valprofen, carbaminox, neosalin, tricyclopyridamine, butenamide, herbicide, benomyl, quinamidamine, fenflufen Naphthalene Amine, acetochlor, nalacet, chlorpyramid, cyperamide, chlorpyrrolam, chlorpyramid, chlorthalimide, butamidine, flumechlor, atrazine, semapar Hydrazine, prochloraz, cyanoxamine, xicaoxing, fenprozine, chlorfenazine, isopropylazine, fluroxypramine, terbutin, terbutin, triazoxystromine, ciprofloxacin, ganprozine , Crotazine, chlorbutrazine, simmatone, azide, diazepam, isoprene, ciprofloxacin, fenprothin, other diazepam, zhongdingtong, terbutine, trimethoprim, Cyanuric acid, oxadiazine, colazine, atrazine, dicamba, licorice, cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron, chlorosulfuron, bensulfuron, Thisulfuron, pyrimisulfuron, methyldisulfuron, sodium iodosulfuron-methyl, formamisulfuron-methyl, ethersulfuron-methyl, ethersulfuron-methyl, sulfsulfuron-methyl, sulfsulfuron-methyl, trimethosulfuron-methyl Besulfuron-methyl, acylsulfuron-methyl, ethoxysulfuron-methyl, ciprosulfuron-methyl, sulfasulfuron-methyl, sulfasulfuron-methyl, tetrasulfuron-methyl, sulfasulfuron-methyl, sulfasulfuron-methyl, sulfasulfuron-methyl, sulfasulfuron-methyl, trisulfuron-methyl , Flusulfuron, Flusulfuron, Epimesulfuron, Zolpidem Sulfonuron, Flusulfuron-methyl, Probensulfuron-methyl, Trifluorosulfuron-methyl, Trisulfuron-methyl, Trisulfuron-methyl, Triflusulfuron-methyl, Flusulfuron-methyl, Trisulfuron-methyl, Trisulfuron-methyl, Triflusulfuron-methyl Promethol, methiosulfuron, pyrisulfuron, propyrisulfuron, prosulfuron, triflufenuron, triflufenacil, saflufenacil, acetofluorfen Ethoxyfluorfen, chlorpyrrol, acetochlor, chlorfenuron ethyl, methylcarboxenid, triflufenacil, trimethoprim, triflufenacil, fluorinated herbicide, fluoride Furafen, herbicidal, acetochlor, dimethylgrass, oxamethoxam, fluoxafen, Halosafen, green wheat, isopropylon, liguron, diuron, saponon, fluoren Chlorsulfuron, fenthalon, methylphenotholon, bensulfuron-methyl, sulfsulfuron-methyl, isoxuron, tebutrazuron, acetyluron-methyl, chlorobromolone, methylpheniron-methyl, sulfuron-methyl Oxycarburon, bromogluturon, metholuron, green glutaron, chlorfenuron, cypersulfuron, non-caprolone, flusulfuron, chlorbuturon, chloropyron, chlorphenanthrene, chlorphenanthrene, cyclam Pycnogenol, Teflon, Butylthionon, Cuminon, Parafluoromethane, Methylamine Thiazuron, Longurat, Trimethylisourea, Oxazolone, Monisouron, Anisuron, Methiuron, Chloreturon, Tetrafluuron, Betanine, Betanin-ethyl, Betan, Sulfamethoxam, Tetrazol, Oatrin, Aniline, chloraniline, diclofenac, chlorfenuron, chlorpheniramine, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, dicamba, chloracetin, chlorfendron, chloracet, yarrow Acacia, piperacetam, oxadiazine, scopolamine, cyperchlore, oatmeal, bacteriochlor, ethionbute, pingcaodan, kecaomen, benzaprol, zhongcaotan, thiocale , Grass, powder, Isopolinate, Methiobencarb, 2,4-D isooctyl butyl ester, 2 methyl 4-chlorosodium, 2,4-D isooctyl isooctyl, 2 methyl 4 chloroisooctyl, 2,4- D isooctyl sodium salt, 2,4-D isooctyl dimethylamine salt, 2 methyl 4 chloroethyl thioester, 2 methyl 4 chloro, 2, 4-D isooctyl propionic acid, high 2,4-D Isooctyl propionate, 2,4-D isooctyl butyric acid, 2 methyl 4 chloropropionic acid, 2 methyl 4 chloropropionic acid, 2 methyl 4 chlorobutyric acid, 2, 4, 5 4,5-Alanthanoic acid, 2,4,5-Alanthanoic acid, 2 methyl 4-chloramine salt, dicamba, humulone, valeric, saison, trichlorobenzoic acid Amino dichlorobenzoic acid, methoxytrichlorobenzoic acid, grass grass, pilofluazone, fine fluafluline, flunafluazone, high-efficiency fluafluoxaline, quinafluline, fine quinachlor Ling, oxazocarb, oxoxacarb, oxapropionate, cyflumetazone, oxafluoxamine, trimethoprim, thiazoline, trimethoprim, valprofen, trifluoride Grass grass oxime, clomaphene, paraquat, diquat, sulfenim, ethenylfluoxin, isoprorrolin, mesosulfurin, ciprofloxacin, aminoprofluline, etbuflufen , Chlorethalin, aminoethalin, dilorin, chlorhexidine, methalpropalin, propofol, glyphosate, salinate, glufosinate, methylglyphosate, glufosinate, piperazine Glyphosate, Dialanphos, Diphosphine, Proton, Phytophos, Phosphos, Dimethophos, Zotophos, Imidacid, Imidacid, Imidacloquinic Acid, Mimipyr, Azamethoxam, imiprazole nicotinic acid, imazamester, clofloxacin, isooctyl clofloxylate, dichloropyridic acid, ampicolinic acid, trichloropyroxyacetic acid, fluorosulfuric acid Duradimine, Trimethoprim, Trichloropyridine Phenol, thiamethoxin, fluoxastrone, chlorpyrimidin, flupyrimid, trichloropyroxybutoxyethyl, Cliodinate, oxadiazine, clethodim, thiamethionone, gramine, Syringazone, Butazone, Trimethazone, Pyranone, Buthidazole, Triazolidin, Cymazinone, Triazolidin, Acetrione, Ametridione, Amibuzin, Bromoxynil, Caprylyl Bromide Benzonitrile, capryloyl iodobenzonitrile, iodobenzonitrile, dipropionitrile, diphenylacetonitrile, bisoxacillin, hydroxydipropionitrile, Iodobonil, flubensulfuron, diflufenacil, pentaflufenacil Sulfamethoxam, Chlorfenacil, Sulfamethoxam, Disulfachlor, Diflufenazone, Dichlorfen, Pyrimethazone, Cyprofen, Dimethoprim, Pyrimethazone, Dicyclotrione, mesotrione, mesotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, isoxaflutole, clomazone, Fenoxasulfone, Methiozolin, imiproxamate, proxafen, pyrazole Tetraspermum, fenaxantrum, benhumidazole, pramifen, mecloxacil, Pyrasulfotole, oxaflutole, Pyroxasulfone, fluoxadi, flufenacil, chlorfenquat, ammonia Oxadiazon, oxadiazon, fluoxazone, mesotrichlor, bencarbazone, diflufenazone, flufenacil, humectin, isopropacil, cyclosamidime, tetridin, Flupropacil, Indoxazone, flufenoxal, propoxyflutosin, flufenoxamine, phthalbenzyl ether, Flumezin, pentachlorophenol (sodium), deloxyl, triclofen, triclofen, pentosin, Nifedipine, Chloroquinol, Diloxif, Diloxad, Propargyxone, Oxazone, Cyclopentazone, Fluoxazol, Methyloxazolate, Tetrazolofen, Fludazine Chloracetate, chlorfenmin, bromopyramine, dallachlor, pyridazol, chlorpyrrolidone, chlorpyrazine, chlorpyrazine, Pyridafol, chloroquinolinic acid, chloroquinolinic acid, bentazon, Pyridoxant, oxadiazon, herbicide, clomazone, cycloheptazone, isopropylacetazone, propylacetazone, indrinone, sodium chlorate, dicamba, trichloroacetic acid, a Chloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, forage herb, bromophenol oxime, triazolesulfuron, metronidazole, furazone, furazone, acetofuran, azamethoxam, chlorophthalic acid, flurrol Humulone, humulose, acrolein, benzyl Ring, oat esters, thiadiachlor, gostigmine, oxymethodone, methoxyphenone, saflufenacil, chloramiprifos, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, Methiosulfurin, Cambendichlor, Ciprofloxacin, Thioaniline, Herbazone, Herbazone, Herbazone, Herbazone, Herbaquine, Herbaquine Nitrile, oxamethoxam, oxamethoxazole, oxamethoxene, pymepyr, fumepyr, oxamethoxam, bisoxoxalic acid, dichloropropenylamine, chlorochloropyridine, DOW chlorofluoropyridine Ester, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600 , MBH-001, KIH-9201, ET-751, KIH-6127, and KIH-2023.
所述除草组合物进一步包括至少一种安全剂，其选自：The herbicidal composition further includes at least one safener selected from:
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物，优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1，吡唑解草酯(mefenpyr-diethyl)，PM，第594-595页)，以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。a) Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds, and preferred compounds are, for example, 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl Ethyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, pages 594-595), as well as described in, for example, WO91 / 07874 and PM (page 594-595).
b)二氯苯基吡唑羧酸衍生物，优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5)，以及记载于EP-A-333131和EP-A-269806中的相关化合物。b) Dichlorophenylpyrazolecarboxylic acid derivatives, and preferred compounds are, for example, 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1- (2,4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1 1,1-Dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4-dichlorophenyl) -5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
c)三唑羧酸(S1)类化合物，优选的化合物为例如解草唑(fenchlorazole)，即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。c) Triazolecarboxylic acid (S1) compounds, and preferred compounds are, for example, fenchlorazole, that is, 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1 , 2,4-triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物，优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物，或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9，双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。d) 5-benzyl- or 5-phenyl-2-isooxazoline-3-carboxylic acids or 5,5-diphenyl-2-isooxazoline-3-carboxylic acids, preferably The compound is, for example, 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isooxazoline-3-carboxylic acid Ethyl Ester (S1-8) and related compounds described in WO91 / 08202, or 5,5-diphenyl-2-isooxazoline- described in patent application (WO-A-95 / 07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-11).
e)8-喹啉氧基乙酸(S2)类化合物，优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1，解毒喹(cloquintocet-mexyl)，如PM(第195-196页)，(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2)，4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3)，1-烯丙基氧基丙-2-基(5-氯-8-喹啉氧基)乙酸酯(S2-4)，(5-氯-8-喹啉氧基)乙酸乙酯(S2-5)，(5-氯-8-喹啉氧基)乙酸甲酯(S2-6)，(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7)，2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8)，2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9)，以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。e) 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (p.195-196), (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy Methyl) acetate (S2-4), (5-chloro-8-quinolinyloxy) ethyl acetate (S2-5), (5-chloro-8-quinolinyloxy) acetic acid methyl ester (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2- (2-propyleneiminooxy) -1-ethyl (5-chloro-8- Quinolineoxy) acetate (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy) acetate (S2-9), and described in EP-A -86750, EP-A-94349 and related compounds in EP-A-191736 or EP-A-0492366.
f)(5-氯-8-喹啉氧基)丙二酸类化合物，优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。f) (5-chloro-8-quinolinyloxy) malonic acid compounds, and preferred compounds are, for example, (5-chloro-8-quinolinyloxy) malonic acid diethyl ester, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy) -methyl malonate and related compounds described in EP-A-0582198.
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物，例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。g) phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acid active compounds, such as 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba) .
h)嘧啶类活性化合物，例如“解草啶(fenclorim)”(PM，第386-387页)(＝4,6-二氯-2-苯基嘧啶)，h) pyrimidine-type active compounds, such as "fenclorim" (PM, pages 386-387) (= 4,6-dichloro-2-phenylpyrimidine),
i)二氯乙酰胺类活性化合物，其常用作苗前安全剂(作用于土壤的安全剂)，例如“二氯丙烯胺(dichloromid)”(PM，第270-271页)(＝N,N-二烯丙基-2,2-二氯乙酰胺)，“AR-29148”(＝3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮，购自Stauffer)，“解草嗪(benoxacor)”(PM，第74-75页)(＝4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪)，“APPG-1292”(＝N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺，购自PPG Industries)，“ADK-24”(＝N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺，购自Sagro-Chem)，“AAD-67”或“AMON4660”(＝3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷，购自Nitrokemia或Monsanto)，“diclonon”或“ABAS145138”或“ALAB145138”(＝(＝3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷，购自BASF)，和“furilazol”或“AMON13900”(参见PM，482-483)(＝(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮)，i) Dichloroacetamide-type active compounds, which are often used as pre-emergent safeners (safety agents for soils), such as "dichloromid" (PM, pages 270-271) (= N, N -Diallyl-2,2-dichloroacetamide), "AR-29148" (= 3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidinone, purchased From Stauffer), "benoxacor" (PM, pages 74-75) (= 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzo Oxazine), "APPG-1292" (= N-allyl-N [(1,3-dioxolane-2-yl) -methyl] dichloroacetamide, purchased from PPG Industries), "ADK -24 "(= N-allyl-N-[(allylaminocarbonyl) -methyl] -dichloroacetamide, purchased from Sagro-Chem)," AAD-67 "or" AMON4660 "(= 3 -Dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane, purchased from Nitrokemia or Monsanto), "diclonon" or "ABAS145138" or "ALAB145138" (= (= 3-di Chloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo [4.3.0] nonane, purchased from BASF), and "furilazol" or "AMON13900" (see PM, 482-483 ) (= (RS) -3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazolidinone),
j)二氯丙酮衍生物类活性化合物，例如，“AMG191”(CAS登记号96420-72-3)(＝2-二氯甲基-2-甲基-1,3-二氧戊环，购自Nitrokemia)，j) Active compounds of dichloroacetone derivatives, for example, "AMG191" (CAS accession number 96420-72-3) (= 2-dichloromethyl-2-methyl-1,3-dioxolane, purchased From Nitrokemia),
k)氧基亚氨基化合物类活性化合物，其被称为拌种材料，例如，“解草腈(oxabetrinil)”(PM，第689页)(＝(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，“氟草肟(fluxofenim)”(PM，第467-468页)(＝1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM，第983页)(＝(Z)-氰基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，k) An oxyimino compound-type active compound, which is called a seed dressing material, for example, "oxabetrinil" (PM, page 689) (= (Z) -1,3-dioxolane 2-ylmethoxyimino (phenyl) acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor, "fluxofenim" (PM, Pp. 467-468) (= 1- (4-chlorophenyl) -2,2,2-trifluoro-1-ethyl ketone O- (1,3-dioxolane-2-ylmethyl)- Oxime, which is called a safener in seed dressings to prevent damage to metolachlor, and "cyometrinil" or "A-CGA-43089" (PM, page 983) (= (Z) -cyanomethoxyimino (phenyl) acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor,
l)噻唑羧酸酯类活性化合物，其被称为拌种材料，例如“解草安(flurazol)”(PM，第450-451页)(＝2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯)，其在拌种中被称为安全剂，以防止甲草胺(alachlor)和异丙甲草胺的损害，l) Thiazole carboxylate active compounds, which are called seed dressing materials, such as "flurazol" (PM, pages 450-451) (= 2-chloro-4-trifluoromethyl-1 , Benzyl 3-thiazole-5-carboxylate), which is known as a safener in seed dressings to prevent damage to alachlor and metolachlor,
m)萘二羧酸衍生物类活性化合物，其被称为拌种剂，例如“萘二甲酸酐”(PM，第1009-1010页)(＝1,8-萘二甲酸酐)，其在玉米拌种中称为安全剂，以防止硫代氨基甲酸酯除草剂的损害，m) Naphthalenedicarboxylic acid derivative active compounds, which are called seed dressing agents, such as "naphthalenedicarboxylic anhydride" (PM, pages 1009-1010) (= 1,8-naphthalenedicarboxylic anhydride) Corn seed dressings are called safeners to prevent damage from thiourethane herbicides,
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物，例如，“ACL304415”(CAS登记号31541-57-8)(＝2-84-羧基色满-4-基)乙酸，购自AmericanCyanamid)，n) chromaneaceticacid derivative active compounds, for example, "ACL304415" (CAS registration number 31541-57-8) (= 2-84-carboxychroman-4-yl) acetic acid, purchased from American Cyanamid),
o)除了对有害植物具有除草作用外还对植物具有安全剂作用的活性化合物，例如，“哌草丹(dimepiperate)”或“AMY-93”(PM，第302-303页)(＝S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯)，“杀草隆(daimuron)”或“ASK23”(PM，第247页)(＝1-(1-甲基-1-苯基乙基)-3-对甲苯基脲)，“苄草隆(cumyluron)”＝“AJC-940”(＝3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲，参见JP-A-60087254)，“苯甲酮(methoxyphenon)”或“ANK049”(＝3,3'-二甲基-4-甲氧基-二苯甲酮)，“CSB”(＝1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4，购自Kumiai)。o) Active compounds which have a safener effect on plants in addition to having herbicidal effects on harmful plants, for example, "dimepiperate" or "AMY-93" (PM, pages 302-303) (= S- 1-methyl-1-phenylethylpiperidine-1-thiocarboxylic acid ester), "daimuron" or "ASK23" (PM, p. 247) (= 1- (1-methyl Phenyl-1-phenylethyl) -3-p-tolyl urea), "cumyluron" = "AJC-940" (= 3- (2-chlorophenylmethyl) -1- (1 -Methyl-1-phenyl-ethyl) urea, see JP-A-60087254), "methoxyphenon" or "ANK049" (= 3,3'-dimethyl-4-methoxy -Benzophenone), "CSB" (= 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS registration number 54091-06-4, purchased from Kumiai).
所述安全剂优选双苯噁唑酸(CAS：163520-33-0)、cyprosulfamide(CAS：221667-31-8)、吡唑解草酯(CAS：135590-91-9)、解毒喹(CAS：99607-70-2)、赤霉酸(CAS：7-06-5)、furilazole(CAS：121776-33-8)、metcamifen(CAS：129531-12-0)中的一种或多种。The safener is preferably dibenzoxazolic acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolidin (CAS: 135590-91-9), and detoxification quinone (CAS) : 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备，即将活性物质与液体溶剂或固体载体混合后，再加入表面活性剂如分散剂、稳定剂、湿润剂、粘合剂、消泡剂等中的一种或几种。The composition of the present invention can be diluted or used directly by the user before use. The formulation can be prepared by ordinary processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, and then adding one or more of a surfactant such as a dispersant, a stabilizer, a wetting agent, a binder, and an antifoaming agent. Species.
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。Specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water-dispersible granules (dry suspensions), water emulsions, and microemulsions.
简而言之，本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。In short, the compositions of the present invention can be mixed with solid and liquid additives conventionally used in formulations of the prior art.
本发明还提供一种所述除草组合物在防治杂草上的应用；以及提供一种防治不想要的植物生长的方法，其包括将所述除草组合物施用于植物、植物部位、植物种子或植物生长的区域
Figure PCTCN2018105699-appb-000003
The present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling unwanted plant growth, which comprises applying the herbicidal composition to a plant, plant part, plant seed, or Area of plant growth
Figure PCTCN2018105699-appb-000003
另外，本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上，即施用于杂草，特别是杂草侵扰或易侵扰影响的表面上。In addition, the composition of the present invention can be applied to the leaves of the plant to be treated by spraying, that is, to the weeds, especially to the surface that is affected or easily affected by weeds.
当施用本发明的除草组合物时，获得了预料不到的增效效果，并且除草活性比使用单个除草剂的活性预期总和，以及单个除草剂的活性更为显著。增效效果表现为施用量减少、更宽的杂草控制谱、除草作用更快、更持久，这些特性是杂草控制实践过程中所需要的。就所描述的特性来说，这些新组合物明显地优越于现有的除草剂，达到减量使用，对环境更友好。When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities using a single herbicide, and the activity of a single herbicide. The synergistic effects are reduced application rates, wider weed control spectrum, faster and longer-lasting weed control, these characteristics are required during weed control practice. With regard to the properties described, these new compositions are clearly superior to existing herbicides, achieving reduced use and being more environmentally friendly.
本发明的增效除草组合物还具有下述优点:The synergistic herbicidal composition of the present invention also has the following advantages:
(1)本发明的组合物为环境友好型，在环境中均易于降解。(1) The composition of the present invention is environmentally friendly and easily degrades in the environment.
(2)本发明的除草组合物成本低、使用方便，其推广应用有巨大的经济效益和社会效益。(2) The herbicidal composition of the present invention has low cost and convenient use, and its promotion and application has huge economic and social benefits.
具体实施方式detailed description
下列实施例并非限制本发明，而只是用来说明本发明是如何实现的。对于某些杂草，这些实施例显示出特别显著的有效性。举例如下:The following examples are not intended to limit the invention, but merely to illustrate how the invention is implemented. For certain weeds, these examples show particularly significant effectiveness. Examples are as follows:
A)实施例A) Examples
1、A1+莎稗磷OD(6+3)1.A1 + Saline Phosphorus OD (6 + 3)
6％A1+3％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A1 + 3% salarphos + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
2、A1+西草净OD(6+3)2.A1 + West grass net OD (6 + 3)
6％A1+3％西草净+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A1 + 3% dicamba net + 5% calcium dodecylbenzenesulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
3、A1+异丙隆OD(5+3)3.A1 + Isoprolone OD (5 + 3)
5％A1+3％异丙隆+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A1 + 3% isoprolong + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
4、A1+双唑草酮OD(4+3)4, A1 + oxadiazon OD (4 + 3)
4％A1+3％双唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A1 + 3% diazoxynone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
5、A1+三唑磺草酮OD(1+9)5.A1 + triazolidone OD (1 + 9)
1％A1+9％三唑磺草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足1% A1 + 9% Trisulcotrione + 5% Calcium Dodecylbenzene Sulfonate + 5% Fatty Alcohol Polyoxyethylene Ether + 4% Castor Oil Polyoxyethylene Ether + 5% 150 # Solvent Oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
6、A1+氯氟吡氧乙酸OD(5+5)6.A1 + clofloxyacetic acid OD (5 + 5)
5％A1+5％氯氟吡氧乙酸+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A1 + 5% chlorofluoropyroxyacetic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
7、A2+莎稗磷OD(6+2)7, A2 + salarphos OD (6 + 2)
6％A2+2％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A2 + 2% salarphos + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
8、A2+异丙隆OD(6+3)8.A2 + isoprolong OD (6 + 3)
6％A2+3％异丙隆+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A2 + 3% isopropylron + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
9、A2+双唑草酮OD(4+3)9.A2 + oxadiazon OD (4 + 3)
4％A2+3％双唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A2 + 3% diazoxynone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
10、A2+三唑磺草酮OD(2+6)10.A2 + trisulcotrione OD (2 + 6)
2％A2+6％三唑磺草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足2% A2 + 6% trisulcotrione + 5% dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
11、A2+氯氟吡氧乙酸OD(6+4)11.A2 + chlorofluoropyroxyacetic acid OD (6 + 4)
6％A2+4％氯氟吡氧乙酸+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足6% A2 + 4% clofluroxyacetic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
12、A3+莎稗磷OD(3+6)12.A3 + Saline Phosphorus OD (3 + 6)
3％A3+6％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 6% salarphos + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
13、A3+西草净OD(4+4)13, A3 + xicao net OD (4 + 4)
4％A3+4％西草净+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 4% dicamba, 5% calcium dodecylbenzenesulfonate, 8% fatty alcohol polyoxyethylene ether, 6% castor oil polyoxyethylene ether, 5% 150 # solvent oil, and 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
14、A3+扑草净OD(4+4)14.A3 + Proton net OD (4 + 4)
4％A3+4％扑草净+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 4% prometryn + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
15、A3+胺唑草酮OD(3+10)15.A3 + Amidazolone OD (3 + 10)
3％A3+10％胺唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+7％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 10% Amidazolone + 5% Calcium Dodecylbenzene Sulfonate + 6% Fatty Alcohol Polyoxyethylene Ether + 7% Castor Oil Polyoxyethylene Ether + 5% 150 # Solvent Oil + 2.5% Organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
16、A3+异丙隆OD(3+5)16.A3 + Isoprolong OD (3 + 5)
3％A3+5％异丙隆+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 5% isopropylron + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
17、A3+哒草特OD(3+10)17.A3 + pyridox OD (3 + 10)
3％A3+10％哒草特+6％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 10% pyridote + 6% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
18、A3+特丁津OD(3+15)18.A3 + Tertinjin OD (3 + 15)
3％A3+15％哒草特+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 15% pyridote + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
19、A3+莠灭净OD(4+12)19.A3 + annihilation net OD (4 + 12)
4％A3+12％莠灭净+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 12% fenfenthion + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
20、A3+利谷隆OD(3+9)20.A3 + Li Gulong OD (3 + 9)
3％A3+9％胺唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 9% Amidazolone + 5% Calcium Dodecylbenzene Sulfonate + 6% Fatty Alcohol Polyoxyethylene Ether + 6% Castor Oil Polyoxyethylene Ether + 5% 150 # Solvent Oil + 2.0% Organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
21、A3+环吡氟草酮OD(6+4)21.A3 + cycloflufenone OD (6 + 4)
6％A3+4％环吡氟草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+7％蓖麻油聚氧乙烯醚 +5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足6% A3 + 4% ciclopiromone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 7% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
22、A3+绿麦隆OD(4+6)22.A3 + green wheat OD (4 + 6)
4％A3+6％绿麦隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 6% green malon + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica, 10% soybean oil + methyl oleate
23、A3+敌草隆OD(2+10)23.A3 + Diuron OD (2 + 10)
2％A3+10％敌草隆+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足2% A3 + 10% diuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
24、A3+除草定OD(4+10)24.A3 + herbicide OD (4 + 10)
4％A3+10％除草定+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+8％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 10% herbicidin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 8% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, 10% soybean oil + methyl oleate
25、A3+哒草特OD(4+12)25.A3 + pyrrolidine OD (4 + 12)
4％A3+12％哒草特+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 12% pyridote + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
26、A3+嗪草酮OD(3+5)26.A3 + oxadiazon OD (3 + 5)
3％A3+5％嗪草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 5% oxadiazonone + 5% calcium dodecylbenzenesulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
27、A3+双唑草酮OD(3+3)27.A3 + oxadiazone OD (3 + 3)
3％A3+3％双唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 3% bisoxadiazon + 5% dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
28、A3+三唑磺草酮OD(1+9)28.A3 + triazosulone OD (1 + 9)
1％A3+9％三唑磺草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足1% A3 + 9% trisulcotrione + 5% dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
29、A3+苯唑氟草酮OD(1+6)29.A3 + fluflutole OD (1 + 6)
1％A3+6％苯唑氟草酮+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足1% A3 + 6% oxaflutole + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
30、A3+磺酰草吡唑OD(3+3)30.A3 + sulfurylpyrazole OD (3 + 3)
3％A3+3％磺酰草吡唑+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 3% sulfonyluprazole + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
31、A3+呋咯草酮OD(3+10)31, A3 + furfurone OD (3 + 10)
3％A3+10％呋咯草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 10% furfurone, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol polyoxyethylene ether, 6% castor oil polyoxyethylene ether, 5% 150 # solvent oil, and 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
32、A3+吡氟酰草胺OD(3+15)32.A3 + flufenamid OD (3 + 15)
3％A3+15％吡氟酰草胺+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 15% piracetam + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
33、A3+氟丁酰草胺OD(5+9)33.A3 + Fluoxalox OD (5 + 9)
5％A3+9％氟丁酰草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 9% flubutyramide + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
34、A3+氟草敏OD(3+6)34.A3 + fluroxypyr OD (3 + 6)
3％A3+6％氟草敏+4％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 6% fluroxypyr + 4% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
35、A3+唑草酮OD(5+1)35.A3 + oxadiazone OD (5 + 1)
5％A3+1％唑草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 1% oxadiazon + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
36、A3+氟氯吡啶酯OD(5+1)36.A3 + fluorochloropyridine ester OD (5 + 1)
5％A3+1％氟氯吡啶酯+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 1% chlorochloropyridine ester + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
37、A3+氯氟吡氧乙酸OD(5+5)37.A3 + clofloxyacetic acid OD (5 + 5)
5％A3+5％氯氟吡氧乙酸+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 5% chlorofluoropyroxyacetic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
38、A3+2,4-滴丁酸OD(5+10)38.A3 + 2,4-dibutyric acid OD (5 + 10)
5％A3+10％2,4-滴丁酸+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 10% 2,4-dibutyric acid + 5% dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, 10% soybean oil + methyl oleate
39、A3+二氯吡啶酸OD(5+4)39.A3 + dichloropic acid OD (5 + 4)
5％A3+4％二氯吡啶酸+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 4% dichloropic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
40、A3+氨氯吡啶酸OD(5+4)40, A3 + aminochloropicolinic acid OD (5 + 4)
5％A3+4％氨氯吡啶酸+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 4% Aminochloropic acid + 5% Calcium dodecylbenzenesulfonate + 7% Fatty alcohol polyoxyethylene ether + 6% Castor oil polyoxyethylene ether + 5% 150 # Solvent oil + 2.5% Organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
41、A3+三氯吡氧乙酸OD(5+4)41.A3 + trichloropyroxyacetic acid OD (5 + 4)
5％A3+4％三氯吡氧乙酸+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 4% trichloropyroxyacetic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
42、A3+环酯草醚OD(3+10)42, A3 + cyclic ester oxamethoxamine OD (3 + 10)
3％A3+10％环酯草醚+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 10% cyclic ester oxamethoxane + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
43、A3+仲丁灵OD(2+20)43.A3 + Zhongdingling OD (2 + 20)
2％A3+20％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+20％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足2% A3 + 20% sec-buterol + 5% dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 20% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica and methyl oleate
44、A3+氟乐灵OD(2+20)44 、 A3 + Fluralin OD (2 + 20)
2％A3+20％氟乐灵+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+20％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足2% A3 + 20% fluloren + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 20% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica and methyl oleate
45、A3+磺草灵OD(3+15)45.A3 + sulfuron OD (3 + 15)
3％A3+15％磺草灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+20％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足3% A3 + 15% sulfuril + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 20% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica and methyl oleate
46、A3+精草铵膦OD(6+10)46, A3 + refined glufosinate OD (6 + 10)
6％A3+10％精草铵膦+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+20％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足6% A3 + 10% refined glufosinate + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 20% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + methyl oleate
47、A3+氟磺胺草醚OD(3+5)47.A3 + flusulfazone OD (3 + 5)
3％A3+5％氟磺胺草醚+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 5% sulfamethoxam + 5% calcium dodecylbenzenesulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
48、A3+苯嘧磺草胺OD(3+1)48.A3 + flubenazamide OD (3 + 1)
3％A3+1％苯嘧磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 1% saflufenacil + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
49、A3+吡草醚OD(5+1)49. A3 + pymechlor OD (5 + 1)
5％A3+1％吡草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 1% fenpropidin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
50、A3+哌草磷OD(5+10)50, A3 + piperidin OD (5 + 10)
5％A3+10％哌草磷+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 10% piperidin + 5% dodecylbenzenesulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.0% organic bentonite + 2.0% fumed silica, + 10% soybean oil + methyl oleate
51、A3+砜吡草唑OD(4+6)51.A3 + Sulfomeprazole OD (4 + 6)
4％A3+6％砜吡草唑+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.0％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 6% Sulfomeprazole + 5% Calcium Dodecylbenzene Sulfonate + 5% Fatty Alcohol Polyoxyethylene Ether + 6% Castor Oil Polyoxyethylene Ether + 5% 150 # Solvent Oil + 2.0% Organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
52、A3+异丙草胺OD(3+10)52.A3 + Isoprochloride OD (3 + 10)
3％A3+10％异丙草胺+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚 +5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 10% isoprochloride + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
53、A3+精喹禾灵OD(3+2)53.A3 + refined quinoxaline OD (3 + 2)
3％A3+2％精喹禾灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 2% refined quinoxaline + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
54、A3+环苯草酮OD(3+1)54.A3 + cyclobenzophenone OD (3 + 1)
3％A3+1％环苯草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 1% cyprobenone + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
55、A3+烯草酮OD(3+2)55, A3 + acetodim OD (3 + 2)
3％A3+2％烯草酮+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足3% A3 + 2% methodimone + 5% calcium dodecylbenzenesulfonate + 8% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
56、A3+炔草酯OD(4+1)56.A3 + cetochlor OD (4 + 1)
4％A3+1％炔草酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 1% trimethoprim + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
57、A3+唑啉草酯OD(4+2)57.A3 + azoxystrobin OD (4 + 2)
4％A3+2％唑啉草酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 2% azoxystrobin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
58、A3+肟草酮OD(5+1)58.A3 + Oxalone OD (5 + 1)
5％A3+1％肟草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 1% oxime ketone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
59、A3+甲基二磺隆OD(5+0.5)59.A3 + methyldisulfuron OD (5 + 0.5)
5％A3+0.5％甲基二磺隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 0.5% methyldisulfuron + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
60、A3+啶磺草胺OD(5+1)60.A3 + flubendiamide OD (5 + 1)
5％A3+1％啶磺草胺+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A3 + 1% saflufenacil + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
61、A3+双氟磺草胺OD(4+0.25)61.A3 + diflusulfuron OD (4 + 0.25)
4％A3+0.25％双氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 0.25% diflusulfuron + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
62、A3+氟唑磺隆OD(4+0.5)62.A3 + fluazosulfuron OD (4 + 0.5)
4％A3+0.5％氟唑磺隆+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 0.5% fluazosulfuron + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
63、A3+氯酯磺草胺OD(4+1)63.A3 + Chlorfenazone OD (4 + 1)
4％A3+1％氯酯磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 1% chlorester sulfachlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
64、A3+唑嘧磺草胺OD(4+0.5)64.A3 + flusulfuron OD (4 + 0.5)
4％A3+0.5％唑嘧磺草胺+5％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 0.5% Sulfomelam, 5% Calcium Dodecylbenzene Sulfonate, 8% Fatty Alcohol Polyoxyethylene Ether, 6% Castor Oil Polyoxyethylene Ether, 5% 150 # Solvent Oil, 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
65、A3+二氯喹啉草酮OD(4+15)65.A3 + dichloroquinolinone OD (4 + 15)
4％A3+15％二氯喹啉草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足4% A3 + 15% dichloroquinolinone + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
66、A4+莎稗磷OD(5+4)66 、 A4 + Salphate OD (5 + 4)
5％A4+4％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+10％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足5% A4 + 4% salarphos + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 10% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
67、A4+异丙隆OD(6+3)67.A4 + Isoprolone OD (6 + 3)
6％A4+3％异丙隆+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A4 + 3% isoprolong + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.5% fumed silica, 10% soybean oil + methyl oleate
68、A4+双唑草酮OD(6+2)68.A4 + oxadiazon OD (6 + 2)
6％A4+2％双唑草酮+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.5％气相法白炭黑+10％豆油+油酸甲酯补足6% A4 + 2% diazoxynone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.5% fumed silica + 10% soybean oil + methyl oleate
69、A4+三唑磺草酮OD(1+9)69.A4 + triazolidone OD (1 + 9)
1％A4+9％三唑磺草酮+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足1% A4 + 9% trisulcotrione + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% Organic bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
70、A4+苯唑氟草酮OD(6+1)70.A4 + Afluoxazone OD (6 + 1)
6％A4+1％苯唑氟草酮+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足6% A4 + 1% oxaflutole + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic Bentonite + 2.0% fumed silica + 10% soybean oil + methyl oleate
71、A4+莠去津OD(3+15)71.A4 + atrazine OD (3 + 15)
3％A4+15％莠去津+5％十二烷基苯磺酸钙+5％脂肪酸聚氧乙烯酯+6％蓖麻油聚氧乙烯醚+5％150#溶剂油+2.5％有机膨润土+2.0％气相法白炭黑+10％豆油+油酸甲酯补足3% A4 + 15% atrazine + 5% calcium dodecylbenzenesulfonate + 5% fatty acid polyoxyethylene ester + 6% castor oil polyoxyethylene ether + 5% 150 # solvent oil + 2.5% organic bentonite + 2.0% fumed silica, 10% soybean oil + methyl oleate
上述可分散油悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned dispersable oil suspending agent processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述可分散油悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。The above-mentioned dispersible oil suspending agent processing process: Put all the materials into the mixing tank, mix and pass the colloid mill, then enter the sand mill three-stage sand mill, and finally cut it uniformly in the shearing machine. After passing the test, transfer Fill to the tank.
B)药效试验B) efficacy test
苗后茎叶喷雾处理:Post-emergence stem and leaf spray treatment:
1)试验条件1) Test conditions
1.1)、供试靶标1.1) Test target
鸭舌草、稻稗、异型莎草采自黑龙江前哨农场；马唐、多花黑麦草采自江苏淮安；繁缕、鸭跖草山东泰安。上述杂草采用盆栽法培养，用180х140mm塑料营养钵，摆放于搪瓷盘中，内装从农田采回经风干过筛的表层土壤(4/5处)，土壤湿度初期均控制在20％，挑选籽粒饱满均一的杂草种子，用25℃温水浸泡6小时，在28℃生化培养箱(黑暗)中催芽，将刚刚露白的杂草种子均匀摆放在土壤表面，根据种子粒径大小然后覆土0.5-1cm。Pteridium, paddy owl, and sedges were collected from the Heilongjiang outpost farm; horse tang and ryegrass were collected from Huai'an, Jiangsu; and Stellaria, Apocara spp. Were from Tai'an, Shandong. The above weeds were cultivated in a pot method. They were placed in plastic enamel dishes with 180х140mm plastic nutrition bowls, and the surface soil (4/5 places) collected from the farmland was air-dried and sieved. The initial humidity of the soil was controlled at 20%. The grains are full and uniform, soaked in warm water at 25 ° C for 6 hours, and germinated in a 28 ° C biochemical incubator (dark). The freshly weed seeds that are just white are evenly placed on the soil surface, and then covered with soil 0.5 -1cm.
1.2)、培养条件1.2) Culture conditions
在可控日光温室内进行，温度20～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％，pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。It is carried out in a controlled sunlight greenhouse with a temperature of 20-30 ° C, natural light, and a relative humidity of 57% -72%. The soil type is loam soil, the content of organic matter is 1.63%, pH = 7.1, alkali-hydrolyzed nitrogen is 84.3mg / kg, available phosphorus is 38.5mg / kg, and available potassium is 82.1mg / kg.
1.3)、仪器设备1.3) Equipment
3WP-2000型行走式喷雾塔，农业部南京农业机械研究所。GA10型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)。3WP-2000 walking spray tower, Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 type one ten thousandth electronic balance (Germany); ZDR2000 intelligent data logger (Hangzhou Zeda Instrument Co., Ltd.); SPX intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
2)试验设计2) Experiment design
2.1)、试剂2.1), reagents
所需活性成分双唑草酮、环吡氟草酮、苯唑氟草酮、三唑磺草酮为本公司生产，其他由试剂公司购买。原药均采用丙酮作溶剂，用含量0.1％乳化剂吐温-80水溶液稀释，现用现稀释。The required active ingredients are diflufenone, cimiflufenone, flufenazone, and triazolam. The other active ingredients are purchased by the reagent company. The original drugs all use acetone as the solvent, and are diluted with 0.1% emulsifier Tween-80 aqueous solution.
2.2)、试验处理2.2) Test treatment
2.2.1)、剂量设置2.2.1), dose setting
在确定A与活性成分B配比或含量时，应从两种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上，设A、B活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。In determining the ratio or content of A and active ingredient B, the characteristics of the two agents and their virulence should be measured, and the main purpose of the formula should also be considered. Based on the preliminary test in this study, the single and mixed dosages of A and B active ingredients are shown in the table. Water containing no drugs and the same solvents and emulsifiers was used as a blank control.
2.2.2)、试验重复2.2.2), test repeat
每处理重复4次，每次每处理3盆，每盆播种杂草种子20粒，每处理共60株。Each treatment was repeated 4 times, each treatment was 3 pots, and 20 weed seeds were sown in each pot, for a total of 60 plants per treatment.
2.3)、处理方式2.3) Processing method
2.3.1)、处理时间和次数2.3.1), processing time and frequency
试验共用药1次。待杂草1叶期，间苗，保持每盆内杂草15株，每处理保留45株，然后继续培养至2-3叶进行处理。The trial shared the drug once. When the weeds are in the 1-leaf stage, we need to maintain 15 plants of weeds in each pot and 45 plants per treatment, and then continue to grow to 2-3 leaves for treatment.
2.3.2)、使用器械和用药方法2.3.2), use of equipment and medication
将培养好的试材均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔茎叶喷雾，喷液量按30公斤/公顷计。喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。 The cultured test material was evenly placed on a platform with an area of 0.5 m 2 , and sprayed with the stems and leaves of a 3WP-2000 walking spray tower, and the spray volume was 30 kg / ha. Spray pressure is 0.3MPa. After spraying all the chemicals, close the gas valve. After 30 seconds, open the spray tower door and remove the nutrition bowl. Then open the air valve, spray 50mL of clean water, and clean the spray tube.
3)试验方法3) Test method
采用盆栽法。杂草培养见1.1，参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2，采用茎叶处理法。处理后移入温室常规培养，试验期间始终保持1-2cm水层。Use the pot method. See 1.1 for weed culture, and refer to the “Guidelines for Pesticides for Laboratory Bioassay of Pesticides”. For the method of treatment, see 2.3.2, using stem and leaf treatment. After treatment, it was transferred to the greenhouse for conventional cultivation, and the 1-2cm water layer was always maintained during the test.
4)数据调查与统计分析4) Data survey and statistical analysis
4.1)、调查方法4.1) Survey method
采用绝对数调查法，用刀片沿土壤表面切断存活杂草整株幼苗，用分析天平称量杂草鲜重。对于已经死亡的杂草，按鲜重为零计。Absolute number survey method was used to cut the whole seedlings of surviving weeds along the soil surface with a blade, and the fresh weeds were weighed with an analytical balance. For dead weeds, the fresh weight is zero.
4.2)、调查时间和次数4.2) Survey time and frequency
处理后20天调查，共调查1次。20 days after treatment, a total of 1 investigation.
4.3)、数据统计分析4.3), statistical analysis of data
用Gowing法计算各处理混合组合的理论鲜重抑制率(E0＝X+Y-X*Y/100)，然后与实测抑制率(E)相比较，评价二者混用对杂草的联合作用类型，当E-E0值大于10％为增效作用、小于-10％为拮抗作用、在-10％～10％之间为加成作用。并根据实际防效和除草剂特点、配方的平衡性等因素确定最佳配比。式中X为活性成分A用量为P时的鲜重抑制率；Y为活性成分B用量为Q时的鲜重抑制率。The Gowing method was used to calculate the theoretical fresh weight inhibition rate (E0 = X + YX * Y / 100) of each combination of treatments, and then compared with the measured inhibition rate (E) to evaluate the type of combined action of the two on weeds. E-E0 values greater than 10% are synergistic effects, less than -10% are antagonistic effects, and between -10% and 10% are additive effects. And determine the optimal ratio according to the actual control effect, the characteristics of the herbicide, the balance of the formula and other factors. In the formula, X is the fresh weight inhibition rate when the amount of active ingredient A is P; Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
统计结果见下表1-71。The statistical results are shown in Table 1-71 below.
表1 A1混配莎稗磷对鸭舌草的实际防效及联合作用评价Table 1 Evaluation of the actual control effect and combined effect of A1 mixed with saraphos on calla
Figure PCTCN2018105699-appb-000004
Figure PCTCN2018105699-appb-000004
表2 A1混配西草净对稻稗的实际防效及联合作用评价Table 2 Evaluation of the actual control effect and joint effect of A1 mixed with Xicaojing on rice dipper
Figure PCTCN2018105699-appb-000005
Figure PCTCN2018105699-appb-000005
表3 A1混配异丙隆对稻稗实际防效及联合作用评价Table 3 Evaluation of actual control effect and joint effect of A1 mixed isoprolongon on rice indica
Figure PCTCN2018105699-appb-000006
Figure PCTCN2018105699-appb-000006
表4 A1混配双唑草酮对马唐实际防效及联合作用评价Table 4 Evaluation of the actual control effect and combined effect of A1 mixed diazolofen on Matang
Figure PCTCN2018105699-appb-000007
Figure PCTCN2018105699-appb-000007
表5 A1混配三唑磺草酮对鸭舌草实际防效及联合作用评价Table 5 Evaluation of the actual control effect and combined effect of triazosulone on the plant
Figure PCTCN2018105699-appb-000008
Figure PCTCN2018105699-appb-000008
表6 A1混配氯氟吡氧乙酸对鸭舌草实际防效及联合作用评价Table 6 Evaluation of the actual control effect and combined effect of A1 mixed clofloxyacetic acid on the plant
Figure PCTCN2018105699-appb-000009
Figure PCTCN2018105699-appb-000009
表7 A2混配莎稗磷对鸭舌草的实际防效及联合作用评价Table 7 Evaluation of the actual control effect and combined effect of A2 mixed with saraphos on calla
Figure PCTCN2018105699-appb-000010
Figure PCTCN2018105699-appb-000010
表8 A2混配异丙隆对稻稗实际防效及联合作用评价Table 8 Evaluation of actual control effect and combined effect of A2 blended isoprolongon on rice indica
Figure PCTCN2018105699-appb-000011
Figure PCTCN2018105699-appb-000011
表9 A2混配双唑草酮对稻稗实际防效及联合作用评价Table 9 Evaluation of the actual control effect and joint effect of A2 blended diazoxynone on rice crickets
Figure PCTCN2018105699-appb-000012
Figure PCTCN2018105699-appb-000012
表10 A2混配三唑磺草酮对鸭舌草实际防效及联合作用评价Table 10 Evaluation of the actual control effect and combined effect of triazosulone on A.
Figure PCTCN2018105699-appb-000013
Figure PCTCN2018105699-appb-000013
表11 A2混配氯氟吡氧乙酸对鸭舌草实际防效及联合作用评价Table 11 Evaluation of the actual control effect and combined effect of A2 mixed clofloxyacetic acid on the plant
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 15+0.1515 + 0.15 70.570.5 4.64.6 83.983.9 71.971.9 12.012.0
75:175: 1 15+0.215 + 0.2 70.570.5 5.15.1 86.386.3 72.072.0 14.314.3
50:150: 1 15+0.315 + 0.3 70.570.5 6.76.7 87.987.9 72.572.5 15.415.4
30:130: 1 15+0.515 + 0.5 70.570.5 18.318.3 90.690.6 75.975.9 14.714.7
5：15: 1 15+315 + 3 70.570.5 52.352.3 9797 85.985.9 11.111.1
1：11: 1 1+11 + 1 8.98.9 26.326.3 52.552.5 32.932.9 19.619.6
1：51: 5 0.8+40.8 + 4 7.57.5 66.466.4 89.589.5 68.968.9 20.620.6
1：201:20 0.2+40.2 + 4 3.23.2 66.466.4 86.586.5 67.567.5 19.019.0
1：501:50 0.08+40.08 + 4 0.590.59 66.466.4 83.283.2 66.666.6 16.616.6
1：801:80 0.05+40.05 + 4 0.380.38 66.466.4 80.580.5 66.566.5 14.014.0
1：1001: 100 0.04+40.04 + 4 0.180.18 66.466.4 78.978.9 66.566.5 12.412.4
表12 A3混配莎稗磷对鸭舌草的实际防效及联合作用评价Table 12 Evaluation of the actual control effect and combined effect of A3 mixed saraphos on the plant
Figure PCTCN2018105699-appb-000014
Figure PCTCN2018105699-appb-000014
表13 A3混配西草净对稻稗的实际防效及联合作用评价Table 13 Evaluation of the actual control effect and joint effect of A3 mixed with Xicaojing on rice dipper
Figure PCTCN2018105699-appb-000015
Figure PCTCN2018105699-appb-000015
表14 A3混配扑草净对稻稗的实际防效及联合作用评价Table 14 Evaluation of the actual control effect and combined effect of A3 blended prochloraz on rice borer
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 65.665.6 2.82.8 85.685.6 66.666.6 19.019.0
75:175: 1 3+0.043 + 0.04 65.665.6 5.55.5 86.986.9 67.567.5 19.419.4
50:150: 1 3+0.063 + 0.06 65.665.6 10.810.8 92.792.7 69.369.3 23.423.4
30:130: 1 3+0.13 + 0.1 65.665.6 13.213.2 93.993.9 70.170.1 23.823.8
5：15: 1 3+0.63 + 0.6 65.665.6 22.522.5 90.690.6 73.373.3 17.317.3
1：11: 1 3+33 + 3 65.665.6 33.833.8 94.594.5 77.277.2 17.317.3
1：51: 5 3+153 + 15 65.665.6 55.655.6 97.197.1 84.784.7 12.412.4
1：201:20 1+201 + 20 43.643.6 77.577.5 98.698.6 87.387.3 11.311.3
1：501:50 0.3+150.3 + 15 28.228.2 45.645.6 79.479.4 60.960.9 18.518.5
1：801:80 0.25+200.25 + 20 22.422.4 77.577.5 95.595.5 82.582.5 13.013.0
1：1001: 100 0.2+200.2 + 20 18.718.7 77.577.5 93.293.2 81.781.7 11.511.5
表15 A3混配胺唑草酮对鸭舌草实际防效及联合作用评价Table 15 Evaluation of the actual control effect and combined effect of A3 mixed with azamethone
Figure PCTCN2018105699-appb-000016
Figure PCTCN2018105699-appb-000016
表16 A3混配异丙隆对稻稗实际防效及联合作用评价Table 16 Evaluation of the actual control effect and combined effect of A3 mixed isoprolongon on rice indica
Figure PCTCN2018105699-appb-000017
Figure PCTCN2018105699-appb-000017
表17 A3混配哒草特对稻稗实际防效及联合作用评价Table 17 Evaluation of the actual control effect and combined effect of A3 mixed pyridate on rice dipper
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 65.665.6 0.80.8 78.678.6 65.965.9 12.712.7
75:175: 1 3+0.043 + 0.04 65.665.6 3.23.2 80.180.1 66.766.7 13.413.4
50:150: 1 3+0.063 + 0.06 65.665.6 6.86.8 81.581.5 67.967.9 13.613.6
30:130: 1 3+0.13 + 0.1 65.665.6 8.38.3 83.683.6 68.568.5 15.115.1
5：15: 1 3+0.63 + 0.6 65.665.6 12.312.3 85.685.6 69.869.8 15.815.8
1：11: 1 3+33 + 3 65.665.6 25.625.6 88.588.5 74.474.4 14.114.1
1：51: 5 3+153 + 15 65.665.6 46.946.9 9494 81.781.7 12.312.3
1：201:20 0.75+150.75 + 15 43.643.6 46.946.9 88.688.6 70.170.1 18.518.5
1：501:50 0.3+150.3 + 15 28.228.2 46.946.9 76.876.8 61.961.9 14.914.9
1：751:75 0.2+150.2 + 15 18.718.7 46.946.9 73.573.5 56.856.8 16.716.7
1：1001: 100 0.15+150.15 + 15 12.212.2 46.946.9 68.268.2 53.453.4 14.814.8
表18 A3混配特丁津对异型莎草实际防效及联合作用评价Table 18 Evaluation of the actual control effect and joint effect of A3 mixed terbutin on heterocyte
Figure PCTCN2018105699-appb-000018
Figure PCTCN2018105699-appb-000018
表19 A3混配莠灭净对异型莎草实际防效及联合作用评价Table 19 Evaluation of the actual control effect and combined effect of A3 mixed annihilation on sedge
Figure PCTCN2018105699-appb-000019
Figure PCTCN2018105699-appb-000019
表20 A3混配利谷隆对马唐实际防效及联合作用评价Table 20 Evaluation of the actual control effect and joint effect of Ligulong on Matang
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 71.671.6 0.30.3 83.383.3 71.771.7 11.611.6
75:175: 1 3+0.043 + 0.04 71.671.6 0.70.7 85.385.3 71.871.8 13.513.5
50:150: 1 3+0.063 + 0.06 71.671.6 0.90.9 87.687.6 71.971.9 15.715.7
15:115: 1 3+0.23 + 0.2 71.671.6 3.23.2 89.889.8 72.572.5 17.317.3
5：15: 1 3+0.63 + 0.6 71.671.6 5.15.1 91.591.5 73.073.0 18.518.5
1：11: 1 3+33 + 3 71.671.6 15.315.3 93.293.2 75.975.9 17.317.3
1：51: 5 3+153 + 15 71.671.6 38.238.2 9696 82.482.4 13.613.6
1：201:20 1.5+301.5 + 30 40.140.1 62.762.7 91.791.7 77.777.7 14.014.0
1：501:50 0.6+300.6 + 30 20.620.6 62.762.7 86.286.2 70.470.4 15.815.8
1：751:75 0.4+300.4 + 30 15.315.3 62.762.7 82.982.9 68.468.4 14.514.5
1：1001: 100 0.3+300.3 + 30 8.28.2 62.762.7 79.379.3 65.865.8 13.513.5
表21 A3混配环吡氟草酮对马唐实际防效及联合作用评价Table 21 Evaluation of the actual control effect and combined effect of A3 mixed ciclopirox on Matang
Figure PCTCN2018105699-appb-000020
Figure PCTCN2018105699-appb-000020
表22 A3混配绿麦隆对稻稗实际防效及联合作用评价Table 22 Evaluation of the actual control effect and joint effect of A3 mixed green wheat on rice dipper
Figure PCTCN2018105699-appb-000021
Figure PCTCN2018105699-appb-000021
表23 A3混配敌草隆对马唐实际防效及联合作用评价Table 23 Evaluation of actual defense effect and joint effect of A3 mixed diuron on Matang
Figure PCTCN2018105699-appb-000022
Figure PCTCN2018105699-appb-000022
Figure PCTCN2018105699-appb-000023
Figure PCTCN2018105699-appb-000023
表24 A3混配除草定对稻稗实际防效及联合作用评价Table 24 Evaluation of the actual control effect and combined effect of A3 mixed herbicide on rice borer
Figure PCTCN2018105699-appb-000024
Figure PCTCN2018105699-appb-000024
表25 A3混配哒草特对异型莎草实际防效及联合作用评价Table 25 Evaluation of the actual control effect and combined effect of A3 mixed pyridate on sedge
Figure PCTCN2018105699-appb-000025
Figure PCTCN2018105699-appb-000025
表26 A3混配嗪草酮对稻稗实际防效及联合作用评价Table 26 Evaluation of the actual control effect and combined effect of A3 mixed with oxadiazon on rice dander
Figure PCTCN2018105699-appb-000026
Figure PCTCN2018105699-appb-000026
Figure PCTCN2018105699-appb-000027
Figure PCTCN2018105699-appb-000027
表27 A3混配双唑草酮对马唐实际防效及联合作用评价Table 27 Evaluation of the actual control effect and combined effect of A3 mixed diazatofen on Matang
Figure PCTCN2018105699-appb-000028
Figure PCTCN2018105699-appb-000028
表28 A3混配三唑磺草酮对鸭舌草实际防效及联合作用评价Table 28 Evaluation of the actual control effect and combined effect of triazosulbone on A. trilobata
Figure PCTCN2018105699-appb-000029
Figure PCTCN2018105699-appb-000029
表29 A3混配苯唑氟草酮对鸭舌草实际防效及联合作用评价Table 29 Evaluation of the actual control effect and combined effect of A3 mixed with flufenazone on the plant
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 65.665.6 0.50.5 82.282.2 65.865.8 16.416.4
75:175: 1 3+0.043 + 0.04 65.665.6 1.31.3 83.983.9 66.066.0 17.917.9
50:150: 1 3+0.063 + 0.06 65.665.6 3.13.1 85.185.1 66.766.7 18.418.4
15:115: 1 3+0.23 + 0.2 65.665.6 8.68.6 87.587.5 68.668.6 18.918.9
5：15: 1 3+0.63 + 0.6 65.665.6 13.513.5 90.590.5 70.270.2 20.320.3
1：11: 1 3+33 + 3 65.665.6 29.129.1 93.393.3 75.675.6 17.717.7
1：51: 5 1.2+61.2 + 6 45.145.1 50.450.4 8787 72.872.8 14.214.2
1：201:20 0.3+60.3 + 6 28.228.2 50.450.4 83.783.7 64.464.4 19.319.3
1：501:50 0.12+60.12 + 6 9.89.8 50.450.4 73.873.8 55.355.3 18.518.5
1：751:75 0.08+60.08 + 6 55 50.450.4 68.868.8 52.952.9 15.915.9
1：1001: 100 0.06+60.06 + 6 4.14.1 50.450.4 67.367.3 52.452.4 14.914.9
表30 A3混配磺酰草吡唑对稻稗实际防效及联合作用评价Table 30 Evaluation of the actual control effect and combined effect of A3 mixed sulfonyluprazole on rice paddy
Figure PCTCN2018105699-appb-000030
Figure PCTCN2018105699-appb-000030
表31 A3混配呋咯草酮对稻稗实际防效及联合作用评价Table 31 Evaluation of actual control effect and combined effect of A3 mixed furfurone on rice borer
Figure PCTCN2018105699-appb-000031
Figure PCTCN2018105699-appb-000031
表32 A3混配吡氟酰草胺对稻稗实际防效及联合作用评价Table 32 Evaluation of the actual control effect and combined effect of A3 mixed with fluoxamid on rice crickets
Figure PCTCN2018105699-appb-000032
Figure PCTCN2018105699-appb-000032
表33 A3混配氟丁酰草胺对鸭舌草实际防效及联合作用评价Table 33 Evaluation of the actual control effect and combined effect of A3 mixed flubutachlor on the plant
Figure PCTCN2018105699-appb-000033
Figure PCTCN2018105699-appb-000033
表34 A3混配氟草敏对稻稗实际防效及联合作用评价Table 34 Evaluation of the actual control effect and combined effect of A3 mixed fluroxypyr on rice indica
Figure PCTCN2018105699-appb-000034
Figure PCTCN2018105699-appb-000034
Figure PCTCN2018105699-appb-000035
Figure PCTCN2018105699-appb-000035
表35 A3混配唑草酮对鸭舌草实际防效及联合作用评价Table 35 Evaluation of the actual control effect and combined effect of A3 mixed oxadiazone on the plant
Figure PCTCN2018105699-appb-000036
Figure PCTCN2018105699-appb-000036
表36 A3混配氟氯吡啶酯对稻稗实际防效及联合作用评价Table 36 Evaluation of actual control effect and combined effect of A3 mixed fluchloropyridyl esters on rice paddy
Figure PCTCN2018105699-appb-000037
Figure PCTCN2018105699-appb-000037
表37 A3混配氯氟吡氧乙酸对鸭舌草实际防效及联合作用评价Table 37 Evaluation of the actual control effect and combined effect of A3 mixed clofloxacin on calla
Figure PCTCN2018105699-appb-000038
Figure PCTCN2018105699-appb-000038
Figure PCTCN2018105699-appb-000039
Figure PCTCN2018105699-appb-000039
表38 A3混配2,4-滴丁酸对鸭舌草实际防效及联合作用评价Table 38 Evaluation of actual control effect and combined effect of 2,3-dibutyric acid on A3
Figure PCTCN2018105699-appb-000040
Figure PCTCN2018105699-appb-000040
表39 A3混配二氯吡啶酸对鸭舌草实际防效及联合作用评价Table 39 Evaluation of the actual control effect and combined effect of A3 mixed dichloropyridic acid on calla
Figure PCTCN2018105699-appb-000041
Figure PCTCN2018105699-appb-000041
表40 A3混配氨氯吡啶酸对鸭舌草实际防效及联合作用评价Table 40 Evaluation of the actual control effect and combined effect of A3 mixed aminochloropic acid on the plant
Figure PCTCN2018105699-appb-000042
Figure PCTCN2018105699-appb-000042
Figure PCTCN2018105699-appb-000043
Figure PCTCN2018105699-appb-000043
表41 A3混配三氯吡氧乙酸对鸭舌草实际防效及联合作用评价Table 41 Evaluation of the actual control effect and combined effect of triclopyroxyacetic acid on the plant
Figure PCTCN2018105699-appb-000044
Figure PCTCN2018105699-appb-000044
表42 A3混配环酯草醚对稻稗实际防效及联合作用评价Table 42 Evaluation of the actual control effect and combined effect of A3 mixed cyclic ciprofen on rice borer
Figure PCTCN2018105699-appb-000045
Figure PCTCN2018105699-appb-000045
表43 A3混配仲丁灵对异型莎草实际防效及联合作用评价Table 43 Evaluation of actual control effect and joint effect of A3 mixed Zhongdingling on sedge
Figure PCTCN2018105699-appb-000046
Figure PCTCN2018105699-appb-000046
Figure PCTCN2018105699-appb-000047
Figure PCTCN2018105699-appb-000047
表44 A3混配氟乐灵对异型莎草实际防效及联合作用评价Table 44 Evaluation of the actual control effect and joint effect of A3 mixed fluroxyline on sedge
Figure PCTCN2018105699-appb-000048
Figure PCTCN2018105699-appb-000048
表45 A3混配磺草灵对稻稗实际防效及联合作用评价Table 45 Evaluation of the actual control effect and combined effect of Sulfuricin and A3 on rice indica
Figure PCTCN2018105699-appb-000049
Figure PCTCN2018105699-appb-000049
表46 A3混配精草铵膦对稻稗实际防效及联合作用评价Table 46 Evaluation of the actual control effect and combined effect of A3 blended refined glufosinate on rice paddy
Figure PCTCN2018105699-appb-000050
Figure PCTCN2018105699-appb-000050
Figure PCTCN2018105699-appb-000051
Figure PCTCN2018105699-appb-000051
表47 A3混配氟磺胺草醚对鸭舌草实际防效及联合作用评价Table 47 Evaluation of the actual control effect and combined effect of A3 mixed with sulfafenap
Figure PCTCN2018105699-appb-000052
Figure PCTCN2018105699-appb-000052
表48 A3混配苯嘧磺草胺对鸭舌草实际防效及联合作用评价Table 48 Evaluation of the actual control effect and combined effect of A3 mixed with saflufenacil on the plant
Figure PCTCN2018105699-appb-000053
Figure PCTCN2018105699-appb-000053
表49 A3混配吡草醚对鸭舌草实际防效及联合作用评价Table 49 Evaluation of the actual control effect and combined effect of A3 mixed with chlorfenaprol on quiche
Figure PCTCN2018105699-appb-000054
Figure PCTCN2018105699-appb-000054
Figure PCTCN2018105699-appb-000055
Figure PCTCN2018105699-appb-000055
表50 A3混配哌草磷对鸭舌草实际防效及联合作用评价Table 50 Evaluation of the actual control effect and combined effect of A3 mixed with pipenphos on quiche
Figure PCTCN2018105699-appb-000056
Figure PCTCN2018105699-appb-000056
表51 A3混配砜吡草唑对鸭舌草实际防效及联合作用评价Table 51 Evaluation of the actual control effect and combined effect of A3 mixed with sulfamethoxazole on the plant
Figure PCTCN2018105699-appb-000057
Figure PCTCN2018105699-appb-000057
表52 A3混配异丙草胺对马唐实际防效及联合作用评价Table 52 Evaluation of actual control effect and combined effect of A3 mixed with isopropylchlor on Matang
Figure PCTCN2018105699-appb-000058
Figure PCTCN2018105699-appb-000058
Figure PCTCN2018105699-appb-000059
Figure PCTCN2018105699-appb-000059
表53 A3混配精喹禾灵对稻稗实际防效及联合作用评价Table 53 Evaluation of the actual control effect and combined effect of A3 blended refined quinoxaline on rice indica
Figure PCTCN2018105699-appb-000060
Figure PCTCN2018105699-appb-000060
表54 A3混配环苯草酮对马唐实际防效及联合作用评价Table 54 Evaluation of the actual control effect and combined effect of A3 mixed cyclofenone on Matang
Figure PCTCN2018105699-appb-000061
Figure PCTCN2018105699-appb-000061
表55 A3混配烯草酮对稻稗实际防效及联合作用评价Table 55 Evaluation of the actual control effect and combined effect of A3 mixed dimethodone on rice cricket
Figure PCTCN2018105699-appb-000062
Figure PCTCN2018105699-appb-000062
Figure PCTCN2018105699-appb-000063
Figure PCTCN2018105699-appb-000063
表56 A3混配炔草酯对稻稗实际防效及联合作用评价Table 56 Evaluation of the actual control effect and combined effect of A3 mixed with trimethoprim on rice indica
Figure PCTCN2018105699-appb-000064
Figure PCTCN2018105699-appb-000064
表57 A3混配唑啉草酯对稻稗实际防效及联合作用评价Table 57 Evaluation of the actual control effect and combined effect of A3 mixed with pyraclopyr on rice paddy
Figure PCTCN2018105699-appb-000065
Figure PCTCN2018105699-appb-000065
表58 A3混配肟草酮对稻稗实际防效及联合作用评价Table 58 Evaluation of the actual control effect and combined effect of A3 mixed oxime humulone on rice indica
Figure PCTCN2018105699-appb-000066
Figure PCTCN2018105699-appb-000066
Figure PCTCN2018105699-appb-000067
Figure PCTCN2018105699-appb-000067
表59 A3混配甲基二磺隆对多花黑麦草实际防效及联合作用评价Table 59 Evaluation of the actual control effect and combined effect of A3 mixed with methyldisulfuron on ryegrass multiflorum
Figure PCTCN2018105699-appb-000068
Figure PCTCN2018105699-appb-000068
表60 A3混配啶磺草胺对多花黑麦草实际防效及联合作用评价Table 60 Evaluation of the actual control effect and combined effect of A3 mixed with saflufenacil on ryegrass multiflorum
Figure PCTCN2018105699-appb-000069
Figure PCTCN2018105699-appb-000069
表61 A3混配双氟磺草胺对繁缕实际防效及联合作用评价Table 61 Evaluation of the actual control effect and joint effect of A3 mixed with diflusulfuron on Stellaria
Figure PCTCN2018105699-appb-000070
Figure PCTCN2018105699-appb-000070
Figure PCTCN2018105699-appb-000071
Figure PCTCN2018105699-appb-000071
表62 A3混配氟唑磺隆对多花黑麦草实际防效及联合作用评价Table 62 Evaluation of the actual control effect and combined effect of A3 blended fluazosulfuron on ryegrass multiflorum
Figure PCTCN2018105699-appb-000072
Figure PCTCN2018105699-appb-000072
表63 A3混配氯酯磺草胺对鸭跖草实际防效及联合作用评价Table 63 Evaluation of the actual control effect and combined effect of A3 mixed with chlorsulfuron-methyl
Figure PCTCN2018105699-appb-000073
Figure PCTCN2018105699-appb-000073
表64 A3混配唑嘧磺草胺对繁缕实际防效及联合作用评价Table 64 Evaluation of the actual control effect and joint effect of A3 mixed flufenacil on Stellaria
Figure PCTCN2018105699-appb-000074
Figure PCTCN2018105699-appb-000074
表65 A3混配二氯喹啉草酮对稻稗实际防效及联合作用评价Table 65 Evaluation of the actual control effect and combined effect of A3 mixed dichloroquinolinone on rice borer
Figure PCTCN2018105699-appb-000075
Figure PCTCN2018105699-appb-000075
Figure PCTCN2018105699-appb-000076
Figure PCTCN2018105699-appb-000076
表66 A4混配莎稗磷对鸭舌草的实际防效及联合作用评价Table 66 Evaluation of the actual control effect and joint effect of A4 mixed with saraphos on the plant
Figure PCTCN2018105699-appb-000077
Figure PCTCN2018105699-appb-000077
表67 A4混配异丙隆对稻稗实际防效及联合作用评价Table 67 Evaluation of actual control effect and joint effect of A4 mixed isoprolongon on rice indica
Figure PCTCN2018105699-appb-000078
Figure PCTCN2018105699-appb-000078
表68 A4混配双唑草酮对稻稗实际防效及联合作用评价Table 68 Evaluation of the actual control effect and combined effect of A4 mixed diazolofen on rice paddy
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 32.632.6 0.30.3 53.253.2 32.832.8 20.420.4
75:175: 1 3+0.043 + 0.04 32.632.6 1.21.2 59.359.3 33.433.4 25.925.9
50:150: 1 3+0.063 + 0.06 32.632.6 2.12.1 60.360.3 34.034.0 26.326.3
15:115: 1 3+0.23 + 0.2 32.632.6 55 62.262.2 36.036.0 26.226.2
5：15: 1 3+0.63 + 0.6 32.632.6 7.87.8 63.563.5 37.937.9 25.625.6
1：11: 1 3+33 + 3 32.632.6 30.230.2 65.665.6 53.053.0 12.612.6
1：51: 5 1.6+81.6 + 8 13.113.1 75.975.9 9595 79.179.1 15.915.9
1：201:20 0.4+80.4 + 8 4.64.6 75.975.9 92.292.2 77.077.0 15.215.2
1：501:50 0.16+80.16 + 8 2.32.3 75.975.9 89.889.8 76.576.5 13.313.3
1：801:80 0.1+80.1 + 8 0.650.65 75.975.9 88.388.3 76.176.1 12.212.2
1：1001: 100 0.08+80.08 + 8 0.320.32 75.975.9 87.987.9 76.076.0 11.911.9
表69 A4混配三唑磺草酮对鸭舌草实际防效及联合作用评价Table 69 Evaluation of the actual control effect and combined effect of triazosulone on A. trilobata
Figure PCTCN2018105699-appb-000079
Figure PCTCN2018105699-appb-000079
表70 A4混配苯唑氟草酮对稻稗实际防效及联合作用评价Table 70 Evaluation of the actual control effect and combined effect of A4 mixed with flufenazone on rice paddy
Figure PCTCN2018105699-appb-000080
Figure PCTCN2018105699-appb-000080
表71 A4混配莠去津对稻稗实际防效及联合作用评价Table 71 Evaluation of the actual control effect and combined effect of A4 mixed atrazine on rice indica
A:BA: B A+B剂量A + B dose A对应剂量单A corresponding dose list B对应剂量单B corresponding dose list A+B防效A + B prevention effect E0(％)E0 (%) E-E0(％)E-E0 (%)
 Zh g a.i./hag a.i./ha 用防效(％)Effectiveness (%) 用防效(％)Effectiveness (%) (％)，E(%), E  Zh  Zh
100:1100: 1 3+0.033 + 0.03 32.632.6 0.280.28 46.446.4 32.832.8 13.613.6
75:175: 1 3+0.043 + 0.04 32.632.6 0.320.32 50.950.9 32.832.8 18.118.1
50:150: 1 3+0.063 + 0.06 32.632.6 0.40.4 56.356.3 32.932.9 23.423.4
30:130: 1 3+0.13 + 0.1 32.632.6 0.80.8 58.958.9 33.133.1 25.825.8
5：15: 1 3+0.63 + 0.6 32.632.6 2.32.3 61.661.6 34.234.2 27.427.4
1：11: 1 3+33 + 3 32.632.6 9.39.3 70.570.5 38.938.9 31.631.6
1：51: 5 3+153 + 15 32.632.6 33.633.6 80.480.4 55.255.2 25.225.2
1：201:20 0.75+150.75 + 15 8.78.7 33.633.6 72.672.6 39.439.4 33.233.2
1：501:50 0.3+150.3 + 15 3.33.3 33.633.6 68.368.3 35.835.8 32.532.5
1：751:75 0.2+150.2 + 15 2.82.8 33.633.6 60.160.1 35.535.5 24.624.6
C)大田示范C) Field demonstration
利用实施例1-58、65-71制得的除草剂组合物进行田间杂草效果试验。The herbicide compositions prepared in Examples 1-58 and 65-71 were used for field weed effect tests.
2017年在黑龙江前哨农场试验点进行示范性推广试验。田间发生的杂草主要有：稻稗、马唐、异型莎草、鸭舌草等等。In 2017, a demonstration extension experiment was conducted at the Heilongjiang outpost farm test site. The main weeds that occur in the field are: rice paddy, tang, sedge, and quaker.
利用实施例59-64制得的除草剂组合物进行田间杂草效果试验。The herbicide composition prepared in Examples 59-64 was used for field weed effect test.
2017年在山东泰安场试验点进行示范性推广试验。田间发生的杂草主要有：多花黑麦草、鸭跖草、繁缕等等。In 2017, a demonstration promotion test was conducted at the test site in Tai'an, Shandong. The weeds that occur in the field are: ryegrass multiflorum, duckweed, stellaria, etc.
试验方法:experiment method:
茎叶处理:待杂草处于3-4叶期，手动喷雾器，兑水量30公斤/667m 2，采用茎叶喷雾均匀喷雾。 Stem and leaf treatment: until the weeds are in the 3-4 leaf stage, use a hand sprayer with a water volume of 30 kg / 667m 2 , and spray uniformly with the stem and leaf spray.
具体试验药剂及剂量详见表72，小区面积50平方米，每处理重复4次。施药后20天调查防除效果The specific test agents and dosages are shown in Table 72. The plot area is 50 square meters, and each treatment is repeated 4 times. Investigate the control effect 20 days after application
Figure PCTCN2018105699-appb-000081
Figure PCTCN2018105699-appb-000081
表72 所述复配组合物的大田示范效果情况Table 72 Demonstration effect of the compound composition in the field
Figure PCTCN2018105699-appb-000082
Figure PCTCN2018105699-appb-000082
Figure PCTCN2018105699-appb-000083
Figure PCTCN2018105699-appb-000083
Figure PCTCN2018105699-appb-000084
Figure PCTCN2018105699-appb-000084
Figure PCTCN2018105699-appb-000085
Figure PCTCN2018105699-appb-000085
Figure PCTCN2018105699-appb-000086
Figure PCTCN2018105699-appb-000086
经过大量试验和探索，本发明意外地发现，所述组合物用于防除稻稗、马唐、异型莎草、多花黑麦草、鸭跖草、繁缕、鸭舌草等杂草，具有令人惊讶的、意想不到的增效作用，这种增效作用在低剂量下表现更为显著，可降低用药量，降低对环境的污染，且合理复配降低了农用成本，对ALS、ACCase抑制剂抗性杂草高效，具有很好的应用前景。同时经过测试在小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等植物显示良好的选择性和优异的增效作用，可以开发成具有广泛市场价值的除草剂混剂。After a large number of tests and explorations, the present invention unexpectedly found that the composition is used for controlling weeds such as rice paddy, tangs, sedges, ryegrass, yarrow, stellaria, and agave Surprising and unexpected synergistic effect, this synergistic effect is more significant at low doses, which can reduce drug use, reduce environmental pollution, and rationally reduce agricultural costs, and inhibit ALS and ACCase The agent-resistant weeds are highly effective and have good application prospects. At the same time, it has been tested in wheat, corn, rice, peanut, sugarcane, sorghum, millet, potato, rape, soybean, cotton, vegetables, bluegrass, tall fescue, zoysia and other plants. Synergistic effects can be developed into herbicide blends with broad market value.

Claims (9)

  1. 一种包含杂环酰胺类化合物的除草组合物，其特征在于，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition comprising a heterocyclic amide compound, characterized in that it comprises an active ingredient A and an active ingredient B in an herbicidally effective amount.
    活性成分A选自以下通式化合物中的一种或多种：
    Figure PCTCN2018105699-appb-100001
    Active ingredient A is selected from one or more of the following compounds:
    Figure PCTCN2018105699-appb-100001
    当R 1代表SEt，R 2代表H时为A1， When R 1 represents SEt and R 2 represents H, it is A1,
    当R 1代表CH 2S(i-Pr)，R 2代表Me时为A2， When R 1 represents CH 2 S (i-Pr) and R 2 represents Me, it is A2,
    当R 1代表CH 2SO 2(i-Pr)，R 2代表Me时为A3， When R 1 represents CH 2 SO 2 (i-Pr) and R 2 represents Me, it is A3,
    当R 1代表CH 2SO 2Et，R 2代表Me时为A4； When R 1 represents CH 2 SO 2 Et and R 2 represents Me, it is A4;
    活性成分B选自以下化合物及其盐/酯中的一种或多种：Active ingredient B is selected from one or more of the following compounds and their salts / esters:
    (1)有机磷类：莎稗磷、哌草磷、精草铵膦；(1) Organophosphorus: saraphos, piperidin, and glufosinate;
    (2)三氮苯类：西草净、扑草净、胺唑草酮、哒草特、特丁津、莠灭净、除草定、嗪草酮、莠去津；(2) Triazines: Xicaojing, Prometryn, Amicarbazone, Pyridoxant, Terbutin, Tefenjing, Herbadin, Triazolidin, Atrazine;
    (3)取代脲类：绿麦隆、异丙隆、敌草隆、利谷隆；(3) Substituted ureas: green wheat, isopropylon, diuron, liguron;
    (4)三酮类：双唑草酮、三唑磺草酮、苯唑氟草酮、磺酰草吡唑、环吡氟草酮；(4) Triketones: diflufenazone, triflufenazone, flufenazone, sulfamethoxazole, and flufenazone;
    (5)吡啶羧酸类：氟氯吡啶酯、氯氟吡氧乙酸、2,4-滴丁酸、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、二氯喹啉草酮；(5) pyridine carboxylic acids: fluchloropyridine ester, clofloxypyroxyacetic acid, 2,4-dibutyric acid, dichloropyridic acid, aminochloropyridic acid, trichloropyroxyacetic acid, dichloroquinolinone
    (6)二硝基苯胺类：仲丁灵、氟乐灵；(6) Dinitroanilines: Zhongbuling, fluloride;
    (7)酰胺类：砜吡草唑、异丙草胺；(7) Amides: sulfamethoxazole, isopromide;
    (8)芳氧苯氧丙酸酯类：精喹禾灵、炔草酯、唑啉草酯；(8) Aryloxyphenoxy propionates: refined quinoxaline, trimethoprim, azoxystrobin;
    (9)环己烯酮类：环苯草酮、烯草酮、肟草酮；(9) Cyclohexanone: Cyclobenone, Dimethenone, Oxatrione;
    (10)磺酰脲类：甲基二磺隆、氟唑磺隆、环酯草醚；(10) Sulfonylureas: methyldisulfuron, flusulfuron, ciprofen;
    (11)磺酰胺类：啶磺草胺、双氟磺草胺、氯酯磺草胺、唑嘧磺草胺；(11) Sulfonamides: saflufenacil, diflusulfuron, chlormetrazol, and saflufenacil;
    (12)氨磺酰类：磺草灵；(12) Sulfonyls: Sulfamethoxam;
    (13)其他：呋咯草酮、吡氟酰草胺、氟丁酰草胺、氟草敏、唑草酮、氟磺胺草醚、苯嘧磺草胺、吡草醚。(13) Others: furazone, flufenamid, flubutacil, fluoxamin, oxaflutole, flusulfazone, saflufenacil, and flumefen.
  2. 根据权利要求1所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于，A、B的重量比为1～200:200～1和1～150:150～1；优选为1～120:120～1和1～100:100～1；更优选为1～80:80～1和1～50:50～1；进一步优选为1～30:30～1和1～10:10～1。The herbicidal composition comprising a heterocyclic amide compound according to claim 1, wherein the weight ratio of A and B is 1 to 200: 200 to 1 and 1 to 150: 150 to 1; preferably 1 ～ 120: 120 ～ 1 and 1 ～ 100: 100 ～ 1; more preferably 1 ～ 80: 80 ～ 1 and 1 ～ 50: 50 ～ 1; even more preferably 1 ～ 30: 30 ～ 1 and 1 ～ 10: 10 ~ 1.
  3. 根据权利要求1或2所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于， 所述除草组合物中A、B的质量百分含量占总量的1-95％，优选10-80％。The herbicidal composition comprising a heterocyclic amide compound according to claim 1 or 2, characterized in that the mass percentage content of A and B in the herbicidal composition accounts for 1-95% of the total, preferably 10-80%.
  4. 根据权利要求1至3任意一项所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于，所述除草组合物中还包括常规助剂。The herbicidal composition comprising a heterocyclic amide compound according to any one of claims 1 to 3, wherein the herbicidal composition further comprises a conventional auxiliary agent.
  5. 根据权利要求4所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于，所述常规助剂包括载体、表面活性剂。The herbicidal composition comprising a heterocyclic amide compound according to claim 4, wherein the conventional auxiliary agent comprises a carrier and a surfactant.
  6. 根据权利要求1至5任意一项所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于，所述除草组合物进一步包括至少一种安全剂。The herbicidal composition comprising a heterocyclic amide compound according to any one of claims 1 to 5, wherein the herbicidal composition further comprises at least one safener.
  7. 根据权利要求1至6任意一项所述的一种包含杂环酰胺类化合物的除草组合物，其特征在于，所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。The herbicidal composition comprising a heterocyclic amide compound according to any one of claims 1 to 6, characterized in that the specific formulation of the herbicidal composition is a dispersible oil suspension agent, an aqueous suspension agent, a suspoemulsion , Wettable powder, emulsifiable concentrate, water-dispersible granules, water emulsion or microemulsion.
  8. 如权利要求1至7任意一项所述包含杂环酰胺类化合物的除草组合物在防治杂草上的应用。The use of a herbicidal composition comprising a heterocyclic amide compound according to any one of claims 1 to 7 for controlling weeds.
  9. 一种防治不想要的植物生长的方法，其包括将权利要求1至7任意一项所述包含杂环酰胺类化合物的除草组合物施用于植物、植物部位、植物种子或植物生长的区域。A method for controlling unwanted plant growth, comprising applying a herbicidal composition comprising a heterocyclic amide compound according to any one of claims 1 to 7 to a plant, a plant part, a plant seed, or a plant growing area.
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