JP2016153397A - Herbicidal composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide novel herbicidal compositions and weeding methods.SOLUTION: A herbicidal composition comprises a component A comprising a heterocyclic amide compound represented by the following formula, and one or more compound selected from components B represented by butachlor, fentrazamide, mefenacet, pyrazosulfuron-ethyl and the like (Ris H, a halogen atom, C-Calkyl and the like, Ris a halogen atom, C-Calkyl and the like, Ris a hydrogen atom and the like, Ris H, C-Calkyl and the like, n is an integer of 0-3).SELECTED DRAWING: None

Description

  The present invention relates to a herbicidal composition excellent in effect and a herbicidal method, which contains a specific heterocyclic amide compound and a known herbicide as an active ingredient.

  The heterocyclic amide compound represented by the formula (1) described below and the salt thereof are known compounds having herbicidal activity (see, for example, Patent Document 1).

International Publication No. 2014/192936

  At present, many compounds have been put to practical use as herbicides for paddy rice, but existing drugs are not necessarily completely effective against the weeds to be controlled.

  As a result of diligent research to solve the above problems, the present inventors antagonized each other when the heterocyclic amide compound represented by the formula (1) and a salt thereof are mixed with a certain herbicide. However, they found out that they complemented each other's slaughter spectrum and completed the present invention. That is, the present invention relates to the herbicidal composition described in the following [1] to [4] (hereinafter referred to as the present composition) and the herbicidal method described in [5] to [7] (hereinafter referred to as the method of the present invention). .).

[1]
[Component A] selected from the group consisting of the heterocyclic amide compound represented by the formula (1) described below and a salt thereof, and [Component B] described below as active ingredients A herbicidal composition.
[Component A]

[Wherein Q represents an aromatic heterocycle represented by any one of Q-1 to Q-7,

  W represents an aromatic heterocycle represented by W-1, W-2 or W-3,

X represents an oxygen atom or a sulfur atom,
R 1a is a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 6 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 6 (C 3 ~C 6) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkenyl, -C (O) R 8, -C (O) OR 16, cyano, -OR 9, -S (O) m1 R 10, -N (R 11) R 12, -C (= NR 12b) R 8b, phenyl, phenyl substituted by (R 7) p, naphthyl or U-1 To any of U-25 groups,
R 1b is a hydrogen atom, C 1 -C 6 alkyl, optionally substituted by R 6 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, optionally substituted by R 6 (C 3 ~ C 6 ) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, phenyl, (R 7 ) phenyl substituted by p , naphthyl, 5-6 membered heteroaryl, (by R 28 and R 28a Represents optionally substituted) 5-6 membered heteroaryl, 3-7 membered heterocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a );
R 1c represents C 1 -C 6 alkyl,
R 2a is a halogen atom, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, -C (O) R 18, -C (O) OR 24, cyano, nitro, -OR 19, -S (O) m3 R 20 , —N (R 21 ) R 22 , phenyl, or phenyl substituted by (R 7 ) p , and when n represents an integer of 2 or more, each R 2a may be the same as or In addition, when two R 2a are adjacent to each other, the two adjacent R 2a form —CH═CH—CH═CH— to bond each R 2a You may form a 6-membered ring with a carbon atom,
R 2c represents C 1 -C 6 haloalkyl,
R 3 is a hydrogen atom, C 1 -C 6 alkyl, (C 1 -C 6 ) alkyl optionally substituted by R 27 , C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 represents alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, -C (O) R 25 or -C (O) oR 26,
R 4a is a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 27 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 27 (C 3 ~C 6) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cycloalkenyl, -NH 2 , C 1 -C 6 alkylamino, di (C 1 -C 6 alkyl) amino, —NHC (O) R 8 , phenyl, phenyl substituted by (R 28 ) r , 5-6 membered heteroaryl, ( 5-6 membered heteroaryl, optionally substituted by R 28 and R 28a ), 3-7 membered heterocyclyl, or 3-7 membered hete (optionally substituted by R 28 and R 28a ) Represents Rocyclyl,
R 4b is a hydrogen atom, halogen atom, cyano, nitro, C 1 -C 6 alkyl, (C 1 -C 6 ) alkyl optionally substituted with R 27 , C 3 -C 6 cycloalkyl, optional with R 27 (C 3 -C 6 ) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cyclo alkenyl, -C (O) OR 16, -OR 38, -S (O) m3 R 20, -NH 2, C 1 ~C 6 alkyl amino, di (C 1 -C 6 alkyl) amino, -NHC (O ) R 8 , phenyl, phenyl substituted by (R 28 ) r , 5-6 membered heteroaryl, 5-6 membered heteroaryl (optionally substituted by R 28 and R 28a ), 3-7 membered Terocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a );
R 4c represents a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 27 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 27 (C 3 -C 6) cycloalkyl, heteroaryl, phenyl substituted by (R 28) r, heteroaryl 5-6 membered, the (optionally substituted by R 28 and R 28a) 5-6 membered, 3-7 membered heterocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a ),
R 4d , R 4e , R 4f , R 4g and R 4h each independently represent a hydrogen atom, C 1 -C 6 alkyl or (C 1 -C 6 ) alkyl optionally substituted with R 35 ,
U-1 to U-6, U-6a, U-7 to U-10, U-10a, U-11, U-11a, U-12, U-12a, U-13, U-13a, U- 14 to U-22, U-22a, U-23, U-24, U-25 and U-26 each represent a heterocyclic ring represented by the following structure;

R ^5a and R ^5b are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C _{6 halocycloalkyl,} C 2 -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} C 3 -C ₆ cycloalkenyl, phenyl or ^(R _{28) r} Represents phenyl substituted by
R ^5c represents a hydrogen atom, C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁶ , or R ^5c represents R ^4d and — (CH ₂ ) ₄ — or By forming —CH═CH—CH═CH—, a 6-membered ring may be formed together with the nitrogen atom to which R ^5c is bonded and the carbon atom to which R ^4d is bonded;
R ⁶ is a halogen atom, cyano, C ₃ -C ₆ cycloalkyl, —C (O) R ⁸ , —C (O) OR ¹⁶ , —OR ¹³ , —S (O) _{m 2} R ¹⁴ , phenyl or (R ⁷ ) represents phenyl substituted by _p ;
R ⁷ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocyclo. _alkyl, C 2 -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} C 3 -C _{6 cycloalkenyl,} C 1 -C ₆ alkylcarbonyl, _{C 3} -C _{6 cycloalkylcarbonyl,} C 1 -C _{6 haloalkylcarbonyl,} C 3 -C ₆ halocycloalkyl _carbonyl, C 1 -C _{6 alkoxycarbonyl,} C 1 -C _{6 haloalkoxycarbonyl,} C 1 -C ₆ alkylaminocarbonyl , _C 1 -C ₆ haloalkylcarbonyl aminocarbonyl, di _(C 1 -C ₆ alkylamino) carbonyl, ^{-OR 15 _{, -S (O) m3 R 20}} , C 1 ~C 6 alkylaminosulfonyl, di _(C 1 -C ₆ alkyl) _{aminosulfonyl,} -NH _2, C 1 ~C ₆ alkyl amino, di _(C 1 -C ₆ Alkyl) amino, 5-6 membered heteroaryl, optionally substituted by 5-6 membered heteroaryl (optionally substituted by R ²⁸ and R ^28a ), 3-7 membered heterocyclyl, or (optionally substituted by R ²⁸ and R ^28a ) Represents a 3-7 membered heterocyclyl,
R ⁸ represents a hydrogen atom, C ₁ -C ₆ alkyl or —N (R ^11a ) R ^12a ,
R ^8b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ⁹ represents a hydrogen atom, C ₁ -C ₆ alkyl or phenyl,
R ¹⁰ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ represents _alkenyl, C 2 -C _{6 haloalkenyl,} a C 2 -C ₆ alkynyl or _C 2 -C ₆ haloalkynyl,
R ¹¹ and R ¹² are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C ₆ haloalkynyl, phenylsulfonyl, phenyl, phenyl substituted by (R ⁷ ) _p , U-7, U-8, U-9 or U-14 to U-19, or R ¹¹ together with R ¹² to form a C ₂ -C ₆ alkylene chain, whereby a nitrogen atom to which R ¹¹ and R ¹² are bonded And the alkylene chain may contain one O, S, S (O), S (O) ₂ or N (R ³³ ), and By an oxo or thioxo group It may be substituted,
R ^11a and R ^12a each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or phenyl, or R ^11a together with R ^12a forms a C ₂ -C ₆ alkylene chain. , R ^11a and R ^12a may form a 3- to 7-membered ring together with the nitrogen atom to which R ^12a is bonded, and at this time, the alkylene chain is O, S, S (O), S (O) ₂ or N ( R ³³ ) and may be substituted by an oxo group or a thioxo group,
R ^12b represents -OR ^19b ;
R ¹³ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C Represents ₆ alkynyl, C ₂ -C ₆ haloalkynyl, —C (O) R ⁸ or phenyl,
R ¹⁴ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C _{6 alkynyl,} C 2 -C ₆ haloalkynyl or phenyl,
R ¹⁵ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ represents _alkenyl, C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C ₆ haloalkynyl or _C 3 -C ₆ cycloalkenyl,
R ¹⁶ represents a hydrogen atom, C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁷ ,
R ¹⁸ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ¹⁹ represents a hydrogen atom, C ₁ -C ₆ alkyl or phenyl,
R ^19b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²⁰ is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C represents ₆ haloalkynyl or _C 3 -C ₆ cycloalkenyl,
R ²¹ and R ²² each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or phenyl, or R ²¹ together with R ²² forms a C ₂ -C ₆ alkylene chain. , R ²¹ and R ²² may form a 3- to 7-membered ring together with the nitrogen atom to which R ²¹ and R ²² are bonded. At this time, this alkylene chain is O, S, S (O), S (O) ₂ or N ( R ³⁹ ) and may be substituted by an oxo group or a thioxo group,
R ²⁴ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²⁵ and R ²⁶ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C _2- C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C ₆ haloalkynyl, C ₃ -C ₆ cycloalkenyl or phenyl,
R ²⁷ is halogen atom, cyano, nitro, ^{phenyl, (R} ₂₈₎ phenyl substituted by _{^{r, -C (O) OR 16}} , -OR 29, -S (O) m4 R 30, the 5-6 membered heteroaryl represents heteroaryl, ^(optionally substituted by ^{R 28} and ^{R 28a)} 3-7 membered heterocyclyl or 3-7 membered heterocyclyl to ^(optionally substituted by ^{R 28} and ^{R 28a)} 5-6 membered,
R ²⁸ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} a _(C 1 -C _{6 alkoxy)} C 1 -C ₆ alkyl, ^{-OR 31} or -S _(O) m4 ^{R 30} When t2, t3, t4, t5, t7, t8 or t9 represent an integer of 2 or more, each R ²⁸ may be the same as or different from each other, and two R ²⁸ are adjacent to each other. when, by two adjacent ^{R 28} are forming a -CH = CH-CH = CH- together, may form a 6-membered ring together with the carbon atom to which each ^{R 28} is bonded ,
R ^28a represents C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, (C ₁ -C ₆ alkoxy) C ₁ -C ₆ alkyl or (C ₁ -C ₆ alkylthio) C ₁ -C ₆ alkyl,
R ²⁹ , R ³⁰ and R ³¹ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C ₆ represents _alkynyl, C 2 -C _{6 haloalkynyl,} a C 3 -C ₆ cycloalkenyl or phenyl,
R ³³ is R ³⁴ represents a hydrogen atom or a _C 1 -C ₆ alkyl, halogen atom, _cyano, C 3 -C ₆ ^{cycloalkyl, -C (O) R 8,} -C (O) OR 16, -OR _{^{33, -S (O) m6 R}} 33, phenyl, (R ⁷⁾ phenyl substituted by _{p, U-1, U-} 3, U-7, U-8, U-9 , or U-14 through U- 25,
R ³⁵ represents a halogen atom or C ₁ -C ₆ alkoxy;
R ³⁶ represents a halogen atom or C ₁ -C ₆ alkoxy;
R ³⁷ represents C ₁ -C ₆ alkoxy;
R ³⁸ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C ₆ represents _alkynyl, C 2 -C _{6 haloalkynyl,} a C 3 -C ₆ cycloalkenyl or phenyl,
R ³⁹ represents a hydrogen atom or C ₁ -C ₆ alkyl,
t1 represents an integer of 0 or 1, m1, m2, m3, m4, m6 and t2 each independently represents an integer of 0, 1 or 2;
n and t3 each independently represents an integer of 0, 1, 2, or 3,
p and r each independently represents an integer of 1, 2, 3, 4 or 5;
t4 represents an integer of 0, 1, 2, 3 or 4;
t5 represents an integer of 0, 1, 2, 3, 4 or 5,
t7 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
t8 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7 or 8;
t9 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7, 8, or 9. ]
[Component B]
Acifluorfen, acloniphene, aloxidim, aloxidim sodium, ametrine, amicarbazone, amidosulfuron, aminocyclopyrachlor, aminocyclopyracrol salts and esters, aminopyralide, aminopyralide salts and esters, amiprophosmethyl, amitrolol, anilophos , Ashram, azaphenidine, azimusulfuron, beflubutamide, benazoline ethyl, bencarbazone, benfluralin, benfrate, bensulfuron methyl, bensulide, bentazone sodium, salt of bentazone, beniocarb, benzfendizone, benzobicyclon, benzofenap, bialaphos, bialaphos sodium , Bicyclopyrone, bifenox, bispyribac, bromacil, bromobutide, bro Phenoxime, bromoxynyl, bromoxynil salts and esters, butaphenacyl, butamifos, butenachlor, butralin, butroxidim, butyrate, caffefentrol, carbetamido, clomethoxyphene, clomethoxynyl, chloramben, chloramben salts and esters, chloransrammethyl, chlorflurenol methyl, Chloridazone, chlorimuron ethyl, chlorobromulone, chlorotoluron, chloroxuron, chlorphthalim, chlorpropam, chloro IPC, chlorsulfuron, chlortaldimethyl, chlorthiamid, sinidone ethyl, cinmesrin, sinosulfurone, cletodim, clodinahop, clodinahop propargyl, clomazone , Clomeprop, clopyralid, clopyralid salt and es , CNP, cumyluron, cyanazine, cycloate, cyclopyrimolate, cyclosulfamlone, cycloxydim, DAH-500, darapon, dazomet, desmedifam, desmethrin, dicamba salts and esters, diclobenil, diclohop, diclohopmethyl, Dichlorprop, Dichlorprop salt and ester, P Dichlorprop, P Dichlorprop salt and ester, Diclosram, Difenzocote, Diflufenican, Diflufenzopyr, Diflufenzopyr sodium, Dimepiperate, Dimethachlor, Dimethenamide, P Dimethenamide, dimesipine, dinitroamine, dinoseb, dinoterb, DNOC, diphenamide, diquat, dithiopyr, diuron, DSMA, dimron, endtal , EPTC, ethalfluralin, ethamethsulfuron methyl, etofumesate, ettobenzanide, ethoxysulfuron, flazasulfuron, phenoxaprop, phenoxapropethyl, phenoxasulfone, fenquinotrione, flamprop, flazasulfuron, flurothram, Fluazifop, fluazifop butyl, fluazolate, flucarbazone sodium, flucetosulfuron, fluchloraline, flufenpyrethyl, flumetram, flumicrolacpentyl, fluometuron, fluoroglycopheneethyl, flupyrsulfuron, flupoxam, flulenol, fluridone, full Lochloridone, fluroxypyr, ester of fluroxypyr, fluprimidol, flutamon, flutiaset methyl, fomesafe , Foramsulfuron, fosamine, glufosinate ammonium, glyphosate ammonium, glyphosate isopropylamine, glyphosate potassium, glyphosate sodium, glyphosate trimesium, haloxifene, haloxifene salts and esters, halosafene, halosulfuron, haloxyhop, haloxyhop methyl , Hexazinone, imazametabenzmethyl, imazamox, imazapic, imazapyr, imazetapyr, imazaquin, imazosulfuron, indazifram, iodosulfuronmethyl sodium, ioxynil, salts and esters of ioxonyl, ipfencarbazone, isoproturon, isouron, isoxaben, Carbutyrate, lactofen, lenacyl, linuron, maleic acid hydride Zido, MCPA, MCPA salts and esters, MCPB, MCPB salts and esters, mecoprop, mecoprop salts and esters, P mecoprop, P mecoprop salts and esters, mefluidide, mesosulfuron methyl, metam, metamihop, metamitron, metazachlor , Metabenzthiazurone, Methiozoline, Methyl azide, Methyl bromide, Methyl diimron, Methyl iodide, Metobenzuron, Metolachlor, Methoslam, Metribuzin, Metsulfuron methyl, Metoxuron, Monolinuron, Monosulfuron, Monosulfuron methyl, MSMA, Naproanilide, Napropamide , Naptaram, sodium naptalam, nebulon, norflurazon, OK-701, oleic acid, olvencurve, orthosulfamlone, o Rizarin, oxasulfuron, oxyfluorphene, paraquat, pelargonic acid, pentanochlor, pentoxazone, petoxamide, phenmedifamethyl, picloram, picroram salt and ester, picolinaphene, pinoxaden, piperophos, pretilachlor, primisulfurone methyl, prodiamine , Profluazole, Profoxydim, Prometon, Promethrin, Propacrol, Propoxahop, Propazine, Profam, Propisochlor, Propoxycarbazone sodium, Propyrisulfuron, Propizzamid, Pullsulfocarb, Prosulfuron, Pyraclonil, Pyraflufenethyl , Pyrasulfotol, pyrazolinate, pyrazosulfuron, pyrazoxifene, pyribenzoxime, pyributicarb Pyridafol, pyridate, pyriftalide, pyriminobacmethyl, pyrimisulphan, sodium pyrithiobac, piroxislam, kimmelac, quinocuramin, quizalofop, quizalofopethyl, xyzalofep tefryl, Pxalofop, Pxallohopethyl, P Quizalofoptefril, saflufenacyl, cetoxidim, cidurone, simazine, cimetrin, SL-261, sulfentrazone, sulfometuron methyl, sulfosulfuron, TCBA, TCBA salts and esters, TCTP, tebutam, tebutiurone, tefril Trione, tepraloxidim, terbacil, terbumetone, terbuthylazine, terbutrine, tetrapion, tenylchlor, thiazaflulone, thiazopyr, thiadimine, thiazulone, chi Jensulflon methyl, tolpyralate, tolalkoxydim, triafamon, triarate, triasulfuron, triadifram, tribenuronmethyl, triclopyr, triclopyr salts and esters, tridifane, trietadine, trifludimoxazine, trifloxysulfuron, trifluralin , Triflusulfuron methyl, tritosulfuron, 2,4-PA, 2,4-PA salt and ester, 2,4-DB, 2,4-DB salt and ester, butachlor, fentolazamide, mefenacet, pyrazos Ruflon ethyl, halosulfuron methyl, metazosulfuron, penoxsulam, bispyribac sodium, carfentrazone ethyl, oxadiazone, oxadialgyl, quinclolac, esprocarb, molinay , Dimetamethrin, propanyl, bentazone, cihalohop butyl, indanophan, oxadiclomephone, acetochlor, alachlor, S-metolachlor, fluphenacet, pyroxasulfone, nicosulfuron, rimsulfuron, thiencarbazone methyl, flumioxazin, Tembotrione, toprazone, mesotrione, isoxaflutole, sulcotrione, dicamba, 2,4-D, atrazine, glyphosate, glufosinate and pendimethalin.

[2]
Q represents Q-1 or Q-3,
W represents W-1,
X represents an oxygen atom,
R ^1a is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ⁶ , -S (O) _m1 R ¹⁰ , -N (R ¹¹ ) R ¹² , U-5 or Represents U-8,
R ^2a represents C ₁ -C ₆ haloalkyl,
R ³ represents a hydrogen atom,
R ^4a represents a hydrogen atom or C ₁ -C ₆ alkyl;
R ^5a represents C ₁ -C ₆ alkyl;
R ⁶ represents phenyl substituted by —S (O) _m2 R ¹⁴ or (R ⁷ ) _p ;
R ⁷ represents -OR ¹⁵ ;
R ¹⁰ represents C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ ,
R ¹¹ and R ¹² each independently represent C _{1 to} C ₆ alkyl, or R ¹¹ together with R ¹² forms a C ₅ alkylene chain, whereby R ¹¹ and R ¹² are bonded. Represents that a 6-membered ring may be formed together with the nitrogen atom, and this alkylene chain may contain one S (O) ₂ ,
R ¹⁴ and R ¹⁵ each independently represent C ₁ -C ₆ alkyl;
R ²⁸ represents C ₁ -C ₆ alkyl or —OR ³¹ ,
R ³¹ and R ³³ each independently represent C ₁ -C ₆ alkyl, R ³⁴ represents —S (O) _m6 R ³³ ,
m1 and m2 each independently represent an integer of 0 or 2,
m6 is the herbicidal composition according to the above [1], which represents an integer of 0.

[3]
Component B is butachlor, fentrazamide, mefenacet, pyrazosulfuron ethyl, halosulfuron methyl, metazosulfuron, penoxthram, bispyribac sodium, carfentrazone ethyl, oxadiazone, oxadiargyl, quinclolac, esprocarb, molinate, dimetamethrin, propanyl, bentazone, Cihalohop butyl, indanophan, oxadichromephone, acetochlor, alachlor, S-metolachlor, fluphenacet, pyroxasulfone, nicosulfuron, rimsulfuron, thiencarbazone methyl, flumioxazin, tembotrione, topramone, mesotrione, isoxa Frutol, sulcotrione, dicamba, 2,4-D, atrazine, glyphosate, glufosinate and And herbicidal composition according to [1] or [2] above, which is pendimethalin.

[4]
Any one of [1] to [3] above, wherein the amount of one or more compounds selected from component B is 0.01 to 30 parts by mass relative to 1 part by mass of one or more compounds selected from component A. The herbicidal composition according to item.

[5]
One or more compounds selected from the component A described in the above [1] and one or more compounds selected from the component B described in the above [1] are treated simultaneously or close in time. Weeding method.

[6]
The weeding method according to the above [5], wherein the weeding method is a weeding method of paddy field weeds.

[7]
The weeding method according to the above [5], wherein the weeding method is a weeding method for upland weeds.

  According to the present invention, the mixture of Compound A, which is an active ingredient of a herbicide, and a herbicide selected from Group B, complement each other in the herbicidal spectrum without antagonizing, and also exhibits a synergistic effect. For these reasons, the utility of the present invention in practical use is extremely high.

  Specific examples of each substituent shown in the present specification are shown below. Here, n- represents normal, i- represents iso, s- represents secondary, and tert- represents tertiary, and Ph represents phenyl.

  Examples of the halogen atom in the present specification include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. In the present specification, the notation “halo” also represents these halogen atoms.

The notation of C _a -C _b alkyl in the present specification represents a linear or branched hydrocarbon group having a carbon number of _a to _b , for example, methyl group, ethyl group, n-propyl group, Specific examples include i-propyl group, n-butyl group, i-butyl group, s-butyl group, tert-butyl group, n-pentyl group, 1,1-dimethylpropyl group, n-hexyl group, and the like. Each selected range of carbon atoms is selected.

In the present specification, C _a -C _b cycloalkyl represents a cyclic hydrocarbon group having a carbon number of _a to _b , and forms a monocyclic or complex ring structure having 3 to 6 members. I can do it. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms. Specific examples include, for example, cyclopropyl group, 1-methylcyclopropyl group, 2-methylcyclopropyl group, 2,2-dimethylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group and the like. Selected in a range of numbers.

The notation of C _a -C _b halocycloalkyl in the present specification represents a cyclic hydrocarbon group having _a to _b carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom. Monocyclic or complex ring structures from 3 to 10-membered rings can be formed. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms, and the substitution with a halogen atom may be a ring structure part, a side chain part, They may be both, and when they are substituted by two or more halogen atoms, the halogen atoms may be the same as or different from each other. For example, 2,2-difluorocyclopropyl group, 2,2-dichlorocyclopropyl group, 2,2-dibromocyclopropyl group, 2,2-difluoro-1-methylcyclopropyl group, 2,2-dichloro-1-methyl Specific examples include cyclopropyl group, 2,2-dibromo-1-methylcyclopropyl group, 2,2,3,3-tetrafluorocyclobutyl group, etc., each selected within the range of the specified number of carbon atoms. The

In the present specification, C _a -C _b alkenyl is a linear or branched chain composed of _a to _b carbon atoms and has one or more double bonds in the molecule. Represents a saturated hydrocarbon group, for example, vinyl group, 1-propenyl group, 2-propenyl group, 1-methylethenyl group, 2-butenyl group, 2-methyl-2-propenyl group, 3-methyl-2-butenyl group, 1 , 1-dimethyl-2-propenyl group and the like are listed as specific examples, and each is selected within the range of the designated number of carbon atoms.

In the present specification, C _a -C _b haloalkenyl is a linear or branched chain in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom, and the number of carbon atoms is ab. And an unsaturated hydrocarbon group having one or more double bonds in the molecule. At this time, when substituted by two or more halogen atoms, these halogen atoms may be the same as or different from each other. For example, 2,2-dichlorovinyl group, 2-fluoro-2-propenyl group, 2-chloro-2-propenyl group, 3-chloro-2-propenyl group, 2-bromo-2-propenyl group, 3,3-difluoro -2-propenyl group, 2,3-dichloro-2-propenyl group, 3,3-dichloro-2-propenyl group, 2,3,3-trifluoro-2-propenyl group, 2,3,3-trichloro- 2-propenyl group, 1- (trifluoromethyl) ethenyl group, 4,4-difluoro-3-butenyl group, 3,4,4-trifluoro-3-butenyl group, 3-chloro-4,4,4- Specific examples include a trifluoro-2-butenyl group and the like, and each is selected within the range of the designated number of carbon atoms.

The notation of C _a -C _b cycloalkenyl in the present specification represents a cyclic unsaturated hydrocarbon group having 1 to 2 carbon atoms and having 1 or 2 or more double bonds. A monocyclic or complex ring structure from a member ring to a 6-member ring can be formed. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms, and the double bond may be either endo- or exo-. Specific examples include 1-cyclopenten-1-yl group, 2-cyclopenten-1-yl group, 1-cyclohexen-1-yl group, 2-cyclohexen-1-yl group, and the like. Selected in a range of numbers.

In the present specification, C _a -C _b alkynyl is a linear or branched chain composed of _a to _b carbon atoms and has one or more triple bonds in the molecule. Represents a hydrocarbon group, for example, ethynyl group, 1-propynyl group, 2-propynyl group, 1-butynyl group, 2-butynyl group, 3-butynyl group, 1,1-dimethyl-2-propynyl group, etc. Each of which is selected for each specified number of carbon atoms.

In the present specification, C _a -C _b haloalkynyl represents a linear or branched chain in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom, and the number of carbon atoms is a to b. And an unsaturated hydrocarbon group having one or more triple bonds in the molecule. At this time, when substituted by two or more halogen atoms, these halogen atoms may be the same as or different from each other. Specific examples include 2-chloroethynyl group, 2-bromoethynyl group, 2-iodoethynyl group, 3-chloro-2-propynyl group, 3-bromo-2-propynyl group, 3-iodo-2-propynyl group and the like. Each of which is selected for each specified number of carbon atoms.

In the present specification, C _a -C _b haloalkyl is represented by a linear or branched chain having _a to _b carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom. Represents a hydrocarbon group, and when substituted by two or more halogen atoms, the halogen atoms may be the same as or different from each other. For example, fluoromethyl group, chloromethyl group, bromomethyl group, iodomethyl group, difluoromethyl group, dichloromethyl group, trifluoromethyl group, chlorodifluoromethyl group, trichloromethyl group, bromodifluoromethyl group, 2-fluoroethyl group, 2- Chloroethyl group, 2-bromoethyl group, 2,2-difluoroethyl group, 2,2,2-trifluoroethyl group, 2-chloro-2,2-difluoroethyl group, 2,2,2-trichloroethyl group, 1 , 1,2,2-tetrafluoroethyl group, 2-chloro-1,1,2-trifluoroethyl group, pentafluoroethyl group, 3,3,3-trifluoropropyl group, 2,2,3,3 , 3-pentafluoropropyl group, 1,1,2,3,3,3-hexafluoropropyl group, heptafluoropropyl group 2,2,2-trifluoro-1- (trifluoromethyl) ethyl group, 1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl group, 2,2,3,3,4, Specific examples include 4,4-heptafluorobutyl group, nonafluorobutyl group and the like, and each is selected within the range of the number of carbon atoms designated.

The notation of C _a -C _b alkoxy in the present specification represents an alkyl-O— group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methoxy group, ethoxy group, n-propyloxy group, Specific examples include an i-propyloxy group, an n-butyloxy group, an i-butyloxy group, an s-butyloxy group, a tert-butyloxy group, and the like, and each is selected within the range of the designated number of carbon atoms.

The notation of C _a -C _b alkylthio in the present specification represents an alkyl-S-group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylthio group, ethylthio group, n-propylthio group, i Specific examples include -propylthio group, n-butylthio group, i-butylthio group, s-butylthio group, tert-butylthio group and the like, which are selected within the range of the number of carbon atoms specified.

The notation of C _a -C _b alkylcarbonyl in the present specification represents an alkyl-C (O) -group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, acetyl group, propionyl group, butyryl group. , Isobutyryl group, valeryl group, isovaleryl group, 2-methylbutanoyl group, pivaloyl group, hexanoyl group, heptanoyl group, and the like, and specific examples thereof are selected within the range of the number of carbon atoms designated.

The notation of C _a -C _b haloalkylcarbonyl in the present specification represents a haloalkyl-C (O) -group having the above-mentioned meaning consisting of _a to _b carbon atoms, such as a fluoroacetyl group, a chloroacetyl group, Difluoroacetyl group, dichloroacetyl group, trifluoroacetyl group, chlorodifluoroacetyl group, bromodifluoroacetyl group, trichloroacetyl group, pentafluoropropionyl group, heptafluorobutanoyl group, 3-chloro-2,2-dimethylpropanoyl group Etc. are given as specific examples, and each is selected within the range of the designated number of carbon atoms.

The notation of C _a -C _b cycloalkylcarbonyl in the present specification represents a cycloalkyl-C (O) -group having the above-mentioned meaning consisting of _a to _b carbon atoms, such as cyclopropylcarbonyl group, 2 Specific examples include -methylcyclopropylcarbonyl group, cyclobutylcarbonyl group, etc., and each is selected within the range of the designated number of carbon atoms.

In the present specification, the expression C _a -C _b halocycloalkylcarbonyl represents a halocycloalkyl-C (O) — group having the above-mentioned meaning consisting of _a to _b carbon atoms. Specific examples include a dichlorocyclopropylcarbonyl group, a 2,2-dichloro-1-methylcyclopropylcarbonyl group, and the like, which are selected in the range of the designated number of carbon atoms.

The notation of C _a -C _b alkoxycarbonyl in the present specification represents an alkyl-O—C (O) — group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methoxycarbonyl group, ethoxycarbonyl Group, n-propyloxycarbonyl group, i-propyloxycarbonyl group, n-butoxycarbonyl group, i-butoxycarbonyl group, tert-butoxycarbonyl group and the like, and specific ranges of the number of carbon atoms are designated. Selected.

The notation of C _a -C _b haloalkoxycarbonyl in the present specification represents a haloalkyl-O—C (O) — group having the above-mentioned meaning consisting of _a to _b carbon atoms, such as a chloromethoxycarbonyl group, Specific examples include 2-chloroethoxycarbonyl group, 2,2-difluoroethoxycarbonyl group, 2,2,2-trifluoroethoxycarbonyl group, 2,2,2-trichloroethoxycarbonyl group, and the like. Selected in the range of the number of carbon atoms.

The notation of C _a -C _b alkylaminocarbonyl in the present specification represents a carbamoyl group in which one of the hydrogen atoms is substituted with an alkyl group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylcarbamoyl Group, ethylcarbamoyl group, n-propylcarbamoyl group, i-propylcarbamoyl group, n-butylcarbamoyl group, i-butylcarbamoyl group, s-butylcarbamoyl group, tert-butylcarbamoyl group, etc. Selected within the range of the number of carbon atoms specified

In the present specification, the expression C _a -C _b haloalkylaminocarbonyl represents a carbamoyl group in which one of the hydrogen atoms is substituted with a haloalkyl group having the above-described meaning consisting of _a to _b carbon atoms, for example, 2-fluoro Specific examples include ethylcarbamoyl group, 2-chloroethylcarbamoyl group, 2,2-difluoroethylcarbamoyl group, 2,2,2-trifluoroethylcarbamoyl group, etc. Is done.

In the present specification, the notation of di (C _a -C _b alkyl) aminocarbonyl means in the above-mentioned meaning that the number of carbon atoms which may be the same or different from each other may be ab. Represents a carbamoyl group substituted by an alkyl group, for example, N, N-dimethylcarbamoyl group, N-ethyl-N-methylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-di (n-propyl) carbamoyl Specific examples include a group, an N, N-di (n-butyl) carbamoyl group, and the like, and each is selected within the range of the designated number of carbon atoms.

In the present specification, C _a -C _b alkylaminosulfonyl represents a sulfamoyl group in which one of the hydrogen atoms is substituted with an alkyl group having the above-mentioned meaning consisting of _a to _b carbon atoms. Famoyl group, ethylsulfamoyl group, n-propylsulfamoyl group, i-propylsulfamoyl group, n-butylsulfamoyl group, i-butylsulfamoyl group, s-butylsulfamoyl group, Specific examples include a tert-butylsulfamoyl group and the like, and each is selected within the range of the designated number of carbon atoms.

In the present specification, the notation of di (C _a -C _b alkyl) aminosulfonyl means in the above meaning that the number of carbon atoms which may be the same or different from each other is _a to _b. Represents a sulfamoyl group substituted by an alkyl group, such as N, N-dimethylsulfamoyl group, N-ethyl-N-methylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-di- Specific examples include (n-propyl) sulfamoyl group, N, N-di (n-butyl) sulfamoyl group and the like, and each is selected within the range of the designated number of carbon atoms.

The notation of C _a -C _b alkylamino in the present specification represents an amino group in which one of the hydrogen atoms is substituted with an alkyl group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, a methylamino group , Ethylamino group, n-propylamino group, i-propylamino group, n-butylamino group, i-butylamino group, tert-butylamino group and the like. Selected by range.

In the present specification, the notation of di (C _a -C _b alkyl) amino has the above-mentioned meaning that the number of carbon atoms which may be the same or different from each other is ab. Represents an amino group substituted by an alkyl group, such as dimethylamino group, ethyl (methyl) amino group, diethylamino group, n-propyl (methyl) amino group, i-propyl (methyl) amino group, di (n-propyl) Specific examples include an amino group, a di (n-butyl) amino group, and the like, and each is selected within the range of the designated number of carbon atoms.

Optionally substituted by ^{R 6} herein _(C a _{~C b)} ^alkyl, optionally substituted by ^{R 27} _(C a _{~C b)} ^alkyl, optionally substituted by ^{R 34} _(C a ~ C _b) ^alkyl, optionally substituted by ^{R 35} _(C a ^~C _b) ^alkyl, optionally substituted by ^{R 36} _(C a ^~C _b) optionally substituted by alkyl or ^{R 37} _{(C a} -C _b) notation alkyl or the like, by any ^{R 6, R 27, R 34} , R 35, R 36 or ^{R 37,} the carbon atoms bonded to hydrogen atoms are optionally substituted carbon atoms a~ It represents an alkyl group as defined above consisting of b, and is selected in the range of the respective designated number of carbon atoms. At this time, when two or more substituents R ⁶ , R ²⁷ , R ³⁴ , R ³⁵ , R ³⁶ or R ³⁷ on each (C _a -C _b ) alkyl group are present, each R ⁶ , R ²⁷ , R ³⁴ , R ³⁵ , R ³⁶ or R ³⁷ may be the same as or different from each other.

Optionally substituted by ^{R 6} herein _(C a _{~C b)} optionally substituted by cycloalkyl or ^{R 27} _(C a _{~C b)} notation cycloalkyl or the like, any of ^{R 6} or R ²⁷ represents a cycloalkyl group as defined above, wherein the number of carbon atoms optionally substituted with hydrogen atoms bonded to carbon atoms is ab, and is selected within the respective specified number of carbon atoms . At this time, when two or more substituents R ⁶ or R ²⁷ on each (C _a -C _b ) cycloalkyl group are present, each R ⁶ or R ²⁷ may be the same as or different from each other, and further substituted The position may be a ring structure moiety, a side chain moiety, or both.

In the present specification, “R ¹¹ may form a C ₂ -C ₆ alkylene chain together with R ¹² to form a 3- to 7-membered ring together with the nitrogen atom to which R ¹¹ and R ¹² are bonded. In this case, this alkylene chain may contain one O, S, S (O), S (O) ₂ or N (R ³³ ), and may be substituted by an oxo group or a thioxo group ”,“ R ^11a may form a C ₂ -C ₆ alkylene chain together with R ^12a to form a 3- to 7-membered ring with the nitrogen atom to which R ^11a and R ^12a are bonded. Wherein the alkylene chain may contain one O, S, S (O), S (O) ₂ or N (R ³³ ) and may be substituted by an oxo or thioxo group ”and “R ²¹ is with R ²² This means that by forming a C ₂ -C ₆ alkylene chain, a 3- to 7-membered ring may be formed together with the nitrogen atom to which R ²¹ and R ²² are bonded. , S (O), S (O) ₂ or N (R ³⁹ ) may be substituted by an oxo group or a thioxo group ”, for example, aziridine, azetidine , Azetidin-2-one, pyrrolidine, pyrrolidin-2-one, oxazolidine, oxazolidine-2-one, oxazolidine-2-thione, thiazolidine, thiazolidine-2-one, thiazolidine-2-thione, imidazolidine, imidazolidine-2 -One, imidazolidine-2-thione, piperidine, piperidin-2-one, piperidine-2-thione, 2H-3,4,5 6-tetrahydro-1,3-oxazin-2-one, 2H-3,4,5,6-tetrahydro-1,3-oxazin-2-thione, morpholine, 2H-3,4,5,6-tetrahydro- 1,3-thiazin-2-one, 2H-3,4,5,6-tetrahydro-1,3-thiazin-2-thione, thiomorpholine, thiomorpholine-1-oxide, thiomorpholine-1,1-dioxide , Perhydropyrimidin-2-one, piperazine, homopiperidine, homopiperidin-2-one, heptamethyleneimine, and the like, and each is selected in the range of the specified number of atoms.

In the present specification, (C _a -C _b alkoxy) C _d -C _e alkyl or (C _a -C _b alkylthio) C _d -C _e alkyl and the like are represented by any C _a -C having the above-mentioned meanings, respectively. _b represents a linear or branched hydrocarbon group consisting of de to e carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted by an alkoxy group or a C _{a to} C _b alkylthio group, Each selected range of carbon atoms is selected.

  The term “5-6 membered aromatic heterocycle” in the present specification means that the number of atoms constituting the ring is 5 to 6, and 1 to 5 heteroatoms (the heteroatoms in the atoms constituting the ring). Is a monocyclic aromatic heterocyclic ring containing a nitrogen atom, an oxygen atom or a sulfur atom.) Specific examples include pyrrole, pyrazole, imidazole, triazole, tetrazole, pyridine, Examples include pyridazine, pyrimidine, pyrazine, triazine, furan, thiophene, thiazole, isothiazole, oxazole, isoxazole, oxadiazole, thiadiazole and the like.

  Further, when the “5-6 membered aromatic heterocycle” has a C═N double bond, the nitrogen atom may be an N-oxide.

  The term “5-6-membered heteroaryl” in the present specification means a monovalent substituent obtained by removing one hydrogen atom at any position from the above-mentioned definition “5-6-membered aromatic heterocycle”. In addition, those coupling positions are not particularly limited, and may be coupled at a desired position.

As used herein, “3-7 membered non-aromatic heterocycle”
1) The number of atoms constituting the ring is 3 to 7,
2) 1 to 3 heteroatoms (the hetero atom means a nitrogen atom, an oxygen atom or a sulfur atom) in the atoms constituting the ring,
3) The ring may contain a carbonyl group, a thiocarbonyl group, a double bond or a triple bond,
4) When a sulfur atom is contained in the atoms constituting the ring, the sulfur atom may be a sulfinyl group or a sulfonyl group.
Means a monocyclic non-aromatic heterocyclic ring, and specific examples thereof include, Examples thereof include diazepine, oxetane, tetrahydrofuran, 1,3-dioxolane, tetrahydropyran, 1,4-dioxane, oxepane, homomorpholine and the like.

  The “3-7 membered heterocyclyl” in the present specification means a monovalent substituent obtained by removing one hydrogen atom at any position from the above-mentioned definition “3-7 membered non-aromatic heterocycle”. In addition, those coupling positions are not particularly limited, and may be coupled at a desired position.

As used herein, “5-6-membered heteroaryl optionally substituted with R ²⁸ and R ^28a ” means a hydrogen atom on a carbon atom that forms the ring of “5-6-membered heteroaryl”. Represents a “5-6-membered heteroaryl” optionally substituted on a carbon atom by an arbitrary R ²⁸ , wherein the atoms constituting the ring of the “5-6-membered heteroaryl” have nitrogen If present and the nitrogen atom can assume the NH structure, the hydrogen atom on the nitrogen atom may be optionally substituted on the nitrogen atom by any R ^28a within the range of the number of hydrogen present. "5-6 membered heteroaryl". At this time, the substituent R ²⁸ on the carbon atom constituting the ring of each “5-6 membered heteroaryl” and the substituent R ^28a substituted with the nitrogen atom capable of forming the NH structure constituting the ring are independent of each other. Each of R ²⁸ and R ^28a may be the same or different from each other, and when two R ²⁸ are adjacent to each other, the two adjacent R ²⁸ are combined together to form —CH═ By forming CH—CH═CH—, a 6-membered ring may be formed together with the carbon atom to which each R ²⁸ is bonded.

As used herein, “3-7 membered heterocyclyl optionally substituted with R ²⁸ and R ^28a ” refers to the number of hydrogen atoms present on the carbon atom that constitutes the ring of “3-7 membered heterocyclyl”. Represents a “3-7 membered heterocyclyl” optionally substituted on a carbon atom by any R ^{28 in} the range wherein nitrogen is present in the atoms constituting the ring of “3-7 membered heterocyclyl”, and If the nitrogen atom can take the NH structure, the hydrogen atom on the nitrogen atom may be optionally substituted on the nitrogen atom by any R ^28a within the number of hydrogens present. “Heterocyclyl”. At this time, the substituent R ²⁸ on the carbon atom constituting the ring of each “3-7 membered heterocyclyl” and the substituent R ^28a substituted with the nitrogen atom capable of forming the NH structure constituting the ring are independently represented. When two or more are present, each R ²⁸ and R ^28a may be the same as or different from each other, and when two R ²⁸ are adjacent to each other, the two adjacent R ²⁸ together are —CH═CH By forming —CH═CH—, a 6-membered ring may be formed together with the carbon atom to which each R ²⁸ is bonded.

  The heterocyclic amide compound represented by the formula (1) used as component A of the herbicidal composition of the present invention is a known compound described in International Patent Application Publication (WO2014 / 192936), specifically, The compounds of Table 1 and Table 2 are mentioned. However, the heterocyclic amide compound used as component A of the herbicidal composition of the present invention is not limited to these.

  In the table, “Me” represents a methyl group, and similarly, Et represents an ethyl group, Pr represents a propyl group, Ph represents a phenyl group, and i- represents iso.

  Moreover, the substituent represented by D-1, D-8i, and D-34 in a table | surface represents the following structures.

  [Table 1]

――――――――――――――――――――――――――――――――――――――
No. R ^1a (R ^2a ) _n XR ³ R ^4a Melting point (° C)
――――――――――――――――――――――――――――――――――――――
A-1 SEt 5-CF ₃ OHH 189-191
A-3 D-1 5-CF ₃ OH Me 235-238
A-5 S (O) ₂ Et 5-CF ₃ OHH 221-225
A-7 NMe ₂ 5-CF ₃ OH Me 184-185
A-8 CH ₂ S (i-Pr) 5-CF ₃ OH Me 156-157
A-12 CH ₂ S (O) ₂ (i-Pr) 5-CF ₃ OH Me 182-184
――――――――――――――――――――――――――――――――――――――
[Table 2]

――――――――――――――――――――――――――――――――――――――
No. R ^1a (R ^2a ) _n XR ³ R ^5a Melting point (° C)
――――――――――――――――――――――――――――――――――――――
A-2 S (CH ₂ ) ₂ SMe 5-CF ₃ OH Me 132-135
A-4 i-Pr 5-CF ₃ OH Me 215-220
A-6 CH ₂ SMe 5-CF ₃ OH Me 189-191
A-9 CH ₂ (4-MeO-Ph) 5-CF ₃ OH Me 167-168
A-10 D-8i 5-CF ₃ OH Me 201-204
A-11 D-34 5-CF ₃ OH Me 73-74
――――――――――――――――――――――――――――――――――――――
The herbicidal composition of the present invention can be used as a herbicide for paddy fields in any treatment method of soil treatment and foliage treatment under flooded water. As paddy field weeds, for example, weeping family (Potamogetonaceatiaceae) represented by Potamogeton distinctus, etc. ) Weed, Azegaya (Leptochloa chinensis), Echinochloa crus-galli, Echinochloa oryzicola, Ashiaki (Homalocenchrus japonocus) Gramineae weed, Kurowai (Eleocharis kuroguwai), Firefly (Sirpus juncoides), Shizuus sarius (Cirpus sarius) Cyperaceae weeds, Spirodella polyrhiza, Lemna paucicostata, and other species such as Lemnaceae weeds, and Dendrobinous weeds (Murdannia coesae). Nochoria korsakowii) and scallops (Pontederiaceae) and other species such as the mosquito family (Elatine triamdra) Lythaceae weeds represented by, Lythigia epilobioides weeds, Oenotheraceae weeds, Dopatrium junceum, Graonilop olia, Azena (Lindernia pyxidaria), American Azena (Lindernia dubia), and the like, Agrocynoceae (Rosaceae), rosaneceae (Aesyomenine indica), etc. Examples thereof include Compositae weeds represented by Bidens tripartita.

  In addition, the herbicidal composition of the present invention can be used as a herbicide for field and orchard in any treatment method of soil treatment, soil admixture treatment, and foliage treatment. Examples of upland weeds include Solanasae weeds represented by Solanum nigrum, Datura stramonium, etc., Siberaceae weeds, and Sida spinois represented by Sida spinosa. Convolvulaceae weeds, Convolvulaceaeus weeds, such as Ipomoea spps. And Convolvulaceaeus Awes, which are typified by Carystegia spus. Amaranthaceae (Ama) typified by retroflexus anthaceae) weeds, cocklebur (xanthium pensylvanicum), ragweed (Ambrosia artemisiaefolia), sunflower (Helianthus annuus), galinsoga quadriradiata (Galinsoga ciliata), western thorns thistle (Cirsium arvense), representative in Senecio vulgaris (Senecio vulgaris) and Himejon (Erigeron annus), etc. Compositae weed, Rupippa indica, Shirapi (Sinapis arvensis), Raspberry (Caspella Bursapastoris) weed, Cypiferae weed, m Blumei and Polygonum convolvulus, and the like, Polygonaceae weeds, Porphyra oleacea and the like, and Fumeriaceae (Pulcaceae) Weeds represented by Cephalodiaceae (Chenopodiaceae) represented by Kochia scoparaia, Weeds represented by Stellaria media (Caryophyllaceae), and by Veronica ceres Cyprinaceae (Commelinaceae) weeds represented by weeds, Commelina communis, etc., Cyprinaceae (Labium purpum), and Cyprinaceae (Labium purpum), representatives of Lamino purpum, etc. Euphorbiaceae weeds represented by (Euforbia maculata) and the like, Rubaceae weeds represented by and such as Virhamis and Viures Violaceae weeds and the United States Leguminosae weeds, represented by Sesbania exaltata, Cassia obtusifolia, etc. Oxaldaceae leaves, represented by Oxsalis ederaedae, Wild sorghum (Sorgham dichotomiflorum), Johnson grass (Sorghum halo chilli), Echinochloa cru-galli var. Crus-galli , Barnyard grass (Digitaria ciliaris), oats (Avena fatua), blackgrass (Alopecurus myosuroides), barnyard grass (Eleusine indica), Enocologia (Sateria viridis), Akinosae faberi) and water foxtail (Alopecurus aegualis) gramineous weeds (Graminaceous weeds typified etc.) and Cyperus (Cyperus rotundus, Cyperus esculentus) Cyperaceae weeds (Cyperaceous weeds typified like).

  Furthermore, the herbicidal composition of the present invention includes, for example, land for industrial facilities such as bank slopes, riverbeds, road shoulders and slopes, railroads, park green spaces, grounds, parking lots, airports, factories and storage facilities, Can weed a wide range of weeds in non-agricultural lands that need to control the growth of weeds, such as fallow land or city-paid land, or in orchards, pastures, lawns, forestry areas, etc. . As the weeds, in addition to those mentioned in field and orchard weeds, Poa annua, Taraxacum officinale, Conyza olma swordfish, Cardamine swordfish, (Hydrocotyl sibthorpioides), Plantago asiatica, Cyperus brevifolia, Kyllinga brevifolia, Equisetum arvense and the like.

  The herbicidal composition of the present invention can be applied to a useful plant, or a place where the useful plant is intended to grow or grow, or a non-agricultural land by acting simultaneously or dividedly. In contrast, undesirable plant growth can be controlled. The useful plants include field crops, paddy field crops, horticultural crops, turf, fruit trees and the like.

  The useful plant as used in the present invention specifically includes, for example, corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane and tobacco. Agricultural crops: Eggplants, tomatoes, peppers, peppers, potatoes, cucurbits, pumpkins, zucchini, watermelons, melons, cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, Cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (leek, onion, garlic, asparagus), seriaceae vegetables (carrot, parsley, celery, American boofish) Etc.), red crustaceae vegetables (spinach, fu Vegetables such as licorice, perilla (vegetables such as perilla, mint, basil), vegetables such as strawberries, sweet potatoes, yam and taro; berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, Plum, Nectarine, Ume, Sweet cherry, Apricot, Prunes, etc.), Citrus (Satsuma mandarin, Orange, Lemon, Lime, Grapefruit, etc.), Fruits (Chestnut, Walnut, Hazel, Almond, Pistachio, Cashew nut, Macadamia nut, etc.), Liquid Fruits such as fruits (blueberries, cranberries, blackberries, raspberries, etc.), grapes, oysters, olives, loquats, bananas, coffee, date palms, coconut palms and oil palms; tea, mulberry, roadside trees (ash, birch, dogwood, eucalyptus) , Ginkgo, lilac, maple Oaks, poplars, redwoods, fus, platanus, zelkova, blackfish, Japanese amberjack, eels, pine, pine, spruce, yew, elm, redwood, etc.), coral jug, dogwood, cedar, cypress, croton, masaki and kanamochi Trees: Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Gyogishiba, etc.), Bentgrass (Ponus, Hykonukagusa, Itokonukagusa, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Onishinokegusa, Ito) Lawn grasses, such as oxgrass, cynomolgus, etc.), ryegrass (rats, barleys, etc.), camouflage and prickly frogs; oil crops, such as oil palm and oilseed moth; flowers (roses, carnations, chrysanthemum, eustoma, gypsophila, moths) -Vera, Marigold, Salvia, Petunia, Verbena, Tulip, Aster, Gentian, Lily, Pansy, Cyclamen, Orchid, Lily of the valley, Lavender, Stock, Habutton, Primula, Poinsettia, Gladiolus, Cattleya, Daisy, Verbena, Symbidium, Begonia, etc.) A foliage plant and the like can be mentioned, but the invention is not limited thereto.

  In addition, useful plants referred to in the present invention include HPPD inhibitors such as isoxaflutol, ALS inhibitors such as imazetapyr and thifensulfuron methyl, EPSP synthase inhibitors such as glyphosate, and glutamine synthetase inhibitors such as glufosinate. , Plants that have been given resistance to acetyl-CoA carboxylase inhibitors such as cetoxydim, PPO inhibitors such as flumioxazin, herbicides such as bromoxynil, dicamba and 2,4-D by classical breeding methods and gene recombination techniques Is also included.

  Examples of “agricultural and horticultural plants” that have been given resistance by classical breeding methods include rapeseed, wheat, sunflower, rice, and corn that are resistant to imidazolinone-based ALS-inhibiting herbicides such as imazetapil. It is already sold under the product name>.

  Similarly, there are soybeans that are resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron methyl by classical breeding methods and are already sold under the trade name STS soybeans. Similarly, SR corn and the like are examples of agricultural and horticultural plants to which resistance has been imparted to acetyl CoA carboxylase inhibitors such as trion oxime and aryloxyphenoxypropionic acid herbicides by classical breeding methods. Agro-horticultural plants tolerated by acetyl-CoA carboxylase inhibitors are the Proceedings of the National Academy of Sciences of the United States of America (Proc.Natl.Acad .Sci. USA) 87, 7175-7179 (1990). A mutant acetyl CoA carboxylase resistant to an acetyl CoA carboxylase inhibitor has been reported in Weed Science 53, 728-746 (2005). A plant resistant to an acetyl-CoA carboxylase inhibitor can be produced by introducing a mutation into the plant acetyl-CoA carboxylase or introducing a mutation associated with imparting resistance into the plant. Furthermore, a nucleic acid introduced with a base substitution mutation represented by chimera plastic technology (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318) is introduced into a plant cell to produce a crop (acetyl CoA carboxylase / herbicide). Plants that are resistant to acetyl-CoA carboxylase inhibitors / herbicides can be created by inducing site-specific amino acid substitution mutations in the target) gene.

  Examples of agricultural and horticultural plants imparted with resistance by genetic recombination technology include glyphosate-resistant corn, soybean, cotton, rapeseed, sugar beet varieties, Roundup Ready (registered trademark), Aglisher GT ( (Agriculture GT) <registered trademark> and the like. Similarly, there are corn, soybean, cotton and rapeseed varieties that are resistant to glufosinate by genetic recombination technology, and are already sold under trade names such as LibertyLink (registered trademark). Similarly, bromoxynyl-resistant cotton by gene recombination technology is already sold under the trade name BXN.

  The “agricultural and horticultural plant” includes a plant that can synthesize, for example, a selective toxin known in the genus Bacillus using a gene recombination technique.

  Examples of insecticidal toxins expressed in such transgenic plants include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1 Ab derived from Bacillus thuringiensis , Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, etc., insecticidal proteins such as VIP1, VIP2, VIP3 or VIP3A; nematicidal insecticidal protein; scorpion toxin, spider toxin, bee toxin or Toxins produced by animals such as insect-specific neurotoxins; filamentous fungi toxins; plant lectins; agglutinins; trypsin inhibitors, serine protease inhibitors, protease inhibitors such as patatin, cystatin, papain inhibitors; ricin, Ribosome inactivating protein (RIP) such as sorghum-RIP, abrin, saporin, bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdysone inhibitor; HMG-CoA Reductase; ion channel inhibitors such as sodium channel inhibitor and calcium channel inhibitor; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase;

  Moreover, as toxins expressed in such genetically modified plants, Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C and other δ-endotoxin proteins, VIP1, VIP2, VIP3 or VIP3A and other insecticidal proteins Hybrid toxins, partially defective toxins, and modified toxins are also included. Hybrid toxins are produced by new combinations of different domains of these proteins using recombinant techniques. As a toxin lacking a part, Cry1Ab lacking a part of the amino acid sequence is known. In the modified toxin, one or more amino acids of the natural toxin are substituted.

  Examples of these toxins and recombinant plants capable of synthesizing these toxins include, for example, EP-A-0374753, WO93 / 07278, WO95 / 34656, EP-A-0427529, EP-A-451878, WO03 / 052073, etc. It is described in the patent literature. Toxins contained in these recombinant plants particularly confer resistance to Coleoptera, Diptera pests, and Lepidoptera pests.

  In addition, genetically modified plants that contain one or more insecticidal pest resistance genes and express one or more toxins are already known and some are commercially available. Examples of these genetically modified plants include Yieldgard (registered trademark) (a corn variety that expresses Cry1Ab toxin), YieldGuard rootworm (registered trademark) (a corn variety that expresses Cry3Bb1 toxin), YieldGuard Plus (registered trademark) (a corn variety expressing Cry1Ab and Cry3Bb1 toxin), Herculex I (registered trademark) (phosphino to confer resistance to Cry1Fa2 toxin and glufosinate Corn varieties expressing tricine N-acetyltransferase (PAT)), NuCOTN33B <registered trademark> (cotton varieties expressing Cry1Ac toxin), Bolger I (Bollgard I) (registered trademark) (cotton varieties expressing Cry1Ac toxin), Volgard II (Bollgard II) (registered trademark) (cotton varieties expressing Cry1Ac and Cry2Ab toxin), VIPCOT (registered trademark) (VIP toxin Cotton cultivated), NewLeaf <registered trademark> (potato cultivar expressing Cry3A toxin), Natureguard AGuresure GT Advantage (NatureGuard <registered trademark> Agriureture <registered trademark> GT Advantage) (GA21 glyphosate resistant trait) ), Aglisher CB Advantage (Agriuree® CB Advantage) (Bt11 corn borer (CB) trait), Protector (Protecta) Trademark> and the like.

  The useful plants include those that have been imparted with the ability to produce an anti-pathogenic substance having a selective action using genetic recombination techniques.

  Examples of anti-pathogenic substances include PR proteins (described in PRPs, EP-A-0392225); sodium channel inhibitors, calcium channel inhibitors (virus-produced KP1, KP4, KP6 toxins, etc.) Stilbene synthase; bibenzyl synthase; chitinase; glucanase; peptide antibiotics, heterocyclic antibiotics, protein factors involved in plant disease resistance (called plant disease resistance genes) And the like, which are produced by microorganisms such as those described in WO 03/000906). Such anti-pathogenic substances and genetically modified plants that produce them are described in EP-A-0392225, WO95 / 33818, EP-A-0353191, and the like.

  The useful plants include crops to which useful traits such as oil component modification and amino acid content enhancing traits have been imparted using genetic recombination techniques. Examples include VISTIVE <(R)> (low linolenic soybeans with reduced linolenic content) or high-lysine (high wheel) corn (corn with increased lysine or oil content).

  In addition, the above-mentioned classic herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, anti-pathogenic substance production genes, oil component modification and amino acid content enhancement traits Combined stack varieties are also included.

Examples of known herbicidal active compounds used as component B of the composition of the present invention include the following compounds.
Acifluorfen (aciflufen / generic name), aclonifen (aclonifen / generic name), alloxidim (alloxydim / generic name), sodium aloxidim (alloxydim-sodium / generic name), ametrine (generic name), amicarbazone (amicalon) (Generic name), amidosulfuron (amidosulfuron / generic name), aminocyclopyrachlor (aminocyclopirachlor / generic name), salts and esters of aminocyclopyrachlor (salts and esters), aminopyralid (generic name) Salts and Esters of Aminopyrido-salts and asters), amiprophosmethyl (amiprophos-methyl / generic name), amitrol (amitrol / generic name), anilofos (anilofos / generic name), ashram (asulam / generic name), azaphenidin (generic name), azimuths Ruflon (azimsulfuron / generic name), beflubutamide (beflubutamid / generic name), benazoline-ethyl (benazolin-ethyl / generic name), bencarbazone (generic name), benfluralin (general name), ), Bensulfuron-methyl (generic name), Bensuri (Bensulide / generic name), sodium bentazone (bentazole-sodium / generic name), salt of bentazone (bentazole-salts), beniocarb (benthiocarb / generic name), benzfendizone (generic name), benzobicyclon ( benzobicyclon / generic name), benzofenap (benzofenap / generic name), bialaphos (bialaphos / generic name), bialaphos sodium (bialaphos-sodium / generic name), bicyclopyrone (bicyclopyrone / generic name), bifenox / bifenox (bifenox / bifen name) ), Bispyribac (bispyribac / generic name), Bromasil (generic name), bromobutide (Bromobutide / generic name), bromophenoxime (generic name), bromoxynil (generic name), salts and esters of bromoxynil (broxynil-salts and esters), butachlor (butaclor / f) (Generic name), butamifos (butamifos / generic name), butenachlor (butenachlor / generic name), butralin (butralin / generic name), butroxydim (butoxydim / generic name), butyrate (butyrate / generic name), caffentrol (cafenstrole / generic name) ), Carbetamide (common name), clomethoxyphene (c lomethoxyfen / generic name), chloromethoxynil (generic name), chloramben (generic name), chloramben salts and esters (chloramben-salts and esters), chloranthrammethyl (full name), chloranthram-methyl / full name Rhenolmethyl (chlorfluorol-methyl / generic name), chloridazone (chloridazon / generic name), chlorimuron-ethyl (common name), chlorobromuron (generic name), chlorotoluron / generic name, Chloroxuron (generic name), chlorphthalim Chlorphtalim / generic name), chlorprofam (generic name), chloro IPC (chlorprofam / generic name), chlorsulfuron / general name, chlorthal-dimethyl / chloridamide (chlorthiamid) / Common name), sinidone ethyl (cinidon-ethyl / generic name), simmesulin (cinmethyllin / generic name), sinosulfuron (cinosulfuron / generic name), cletodim (clethodidim / generic name), clodinahop (clodinafop / generic name), clodinahop Propargyl (clodinafop-propargyl / generic name), clomazone (clomaz) ne / generic name), clomeprop (generic name), clopyralid (clopyralid / generic name), salts and esters of clopyralid (clopyralid-salts and esters), CNP (generic name), cumyluron / generic name, cyanazine (Cyanazin / generic name), cycloate (cycloate / generic name), cyclopyrimoleate (cyclopyrimorate / generic name, SW-065 / study name), cyclosulfamuron (cyclosulfamuron / generic name), cycloxydim (cycloxydim / generic name) ), DAH-500 (test name), dalapon (dalapon / generic name), dazomet (generic name), desmedifim (desmedif) am / generic name), desmethrin (generic name), dicamba salts and esters (dicamba-salts and esters), diclobenil (generic name), diclohop (common name), diclohop-methy / Generic name), dichloroprop / generic name, dichloroprop-salts and esters, P dichloroprop-P / generic name, P dichloroprop salt and ester Esters (dichlorprop-P-salts and esters), diclosram (generic name), difenzo coat (difenzo) uat / generic name), diflufenican (diflufenican / generic name), diflufenzopyr (diflufenzopyr / generic name), diflufenzopyr sodium (generic name), dimepiperate / common name dithichlor / Generic name), dimethenamide (dimethenamide / generic name), P-dimethenamide (dimethylenamide-p / generic name), dimesipine (dimethipine / generic name), dinitroamine (dinitramine / generic name), dinoceb (generic name), dinoteb (Dinoterb / generic name), DNOC (generic name), diphenamide (diphenamid / generic name), diqua (Diqut / generic name), dithiopyr (dithiopyl / generic name), diuron (diuron / generic name), DSMA (generic name), diimron (generic name), endtal (endothal / generic name), EPTC (general name) Name), ethalfluralin (ethalfluralin / generic name), ethamethsulfuron-methyl (ethamesulfuron-methyl / generic name), etofumesate (ethofumesate / generic name), ettobenzanid (ethobenzandid / generic name), ethoxysulfuron (ulonoxysyl) ), Flazasulfuron (generic name), phenoxaprop (generic name), phenoxapropethyl (fenox) aprop-ethyl / generic name), fenoxasulfone (generic name), fenquinotrione (generic name), fentrazamide (general name), flampprop (generic name), flazasulfuron (flazulflon) / Common name), florasulam (common name), fluazifop (fluazifop / generic name), fluazifop butyl (fluazifop-butyl / generic name), fluazolate (fluazolate / generic name), flucarbazone-sodium / Generic name), flucetosulfuron (generic name), fluchloraline (fl chloralin (generic name), flufenpyrethyl (flufenpyl-ethyl / generic name), flumeturum (flumetsulam / generic name), flumicrolacpentyl (generic name), fluometuron (generic name), fluoroglyco Phenethyl (fluoroglycofen-ethyl / generic name), flupirsulfuron (flupyrsulfuron / generic name), flupoxam (fluoxam / generic name), flulenol (flulenol / generic name), fluridone (fluridone / generic name), flurochloridone (flurochloridone) / Generic name), fluroxypyr (generic name), ester of fluroxypyr (f fluoxypyr-esters), fluprimidol (flurprimidol / generic name), flutamon (flutatamone / generic name), fluthiacet-methyl (generic name), fomesafen (formafenen / generic name), foramsulfuron (foramsulfuron) Name), fosamine (fosamine / generic name), glufosinate-ammonium (generic name), glyphosate ammonium (glyphosate-ammonium / generic name), glyphosate-isopropylamine (glyphosate-iso-propylammonium / generic name), glyphosate glyphosate-potassium Generic name), glyphosate sodium (glyphosate-sodium / generic name), glyphosate-trimesium (glyphosate-trimesium / generic name), haloxifene / generic name, haloxifene-salts and esters ), Halosafene (halosafen / generic name), halosulfuron (halosulfuron / generic name), haloxyhop (haloxyfop / generic name), haloxyhop-methyl (generic name), hexazinone (generic name), imaza Metabenzmethyl (imazamethabenz-methyl / generic name), imazamox (imazamox / one Common name), imazapic (common name), imazapyr (common name), imazetapyr (common name), imazaquin (common name), imazaquin (general name), imazasulfuron (common name) ), Iodosulfuron methyl sodium (iodosulfuron-methyl-sodium / generic name), ioxynyl (ioxynil octanoate / generic name), salts and esters of ioxonyl (ioxynil-salts and esters), ipfencarbazone (ipfencarz / generic name) , Isoproturon (generic name), isouron (isouron / one) Name), isoxaben (isoxaben / generic name), Karubuchireto (karbutilate / generic name), lactofen (lactofen / generic name), lenacil (lenacil / generic name), linuron (linuron / generic name
), Maleic hydrazide (generic name), MCPA (generic name), MCPA salts and esters (MCPA-salts and esters), MCPB (generic name), MCPB salts and esters (MCPB-salts and esters) , Mecoprop (MCPP / generic name), mecoprop salts and esters (mecoprop-salts and esters), P mecoprop (P, MCPP-P / generic name), P mecoprop salts and esters (mecoprop-P- salts and esters, mefluidide (generic name), mesosulfuron-methyl (generic name), metam (metam) (Generic name), metamihop (metamihop / generic name), metamitron (metamitron / generic name), metazachlor (metazachlor / generic name), metabenzthiazuron (generic name), methiozoline (generic name), methylazido (Methyl azide / generic name), methyl bromide / generic name, methyl dimron / generic name, methyl iodide / generic name, metbenzuron / generic name, metolachlor (Metolachlor / generic name), methotram (metosuram / generic name), metribuzin (generic name), Sulfuron-methyl (metsulfuron-methyl / generic name), methoxuron (metoxuron / generic name), monolinuron (monolinuron / generic name), monosulfuron (monosulfuron / generic name), monosulfuron-methyl (monosulfuron-methyl / generic name), MSMA (Generic name), naproanilide (generic name), napropamide (general name), naptalam (naptalam / generic name), naptalam-sodium (generic name), nebulon (generic name), norflurazon norflurazon / generic name), OK-701 (test name), oleic acid (oleic acid / generic name), ol Curve (orbencarb / generic name), orthosulfamuron (generic name), oryzalin (oryzalin / generic name), oxasulfuron (oxalsulfuron / generic name), oxyfluorfen (oxygen / generic name), paraquat / General name), pelargonic acid (general name), pentanochlor (pentanochlor / generic name), pentoxazone (general name), petoxamide (general name), phenmedifam-ethyl / generic name ), Picloram (picloram / generic name), picloram salts and esters (picloram-salt) and esters), picolinafene (generic name), pinoxaden (generic name), piperophos (generic name), pretilachlor (generic name), primisulfuron methyl (primisulfuron-methyl) Diamine (prodiamin / generic name), Profluazole (profluazole / generic name), Proxidim (profoxydim / generic name), Prometon (promethon / generic name), Promethrin (prometrin / generic name), Propaclor (propaplor / generic name) , Propakizahop (propaquizafop / generic name), propazine (propazin / generic name) Profam (propharm / generic name), propisochlor (propisochlor / generic name), sodium propoxycarbazone (propoxycarbazone-sodium / generic name), propyrisulfuron (generic name), propizamide (general name) Sulfocarb (prosulfocarb / generic name), prosulfuron (prosulfuron / generic name), pyraclonyl (pyraclonil / generic name), pyraflufen-ethyl (pyrasulfen-ethyl / generic name), pyrasulfotol (pyrasulfofol / generic name), pyrazolinate (Pyrazolinate / generic name), pyrazosulfuron / Common name), pyrazoxifene (general name), pyribenzoxim (pyribenzoxim / generic name), pyributicalcarb (general name), pyridafol (generic name), pyridate / general name pylid ), Pyriminobac-methyl (generic name), pyrimisulfan (pyrimisulfan / generic name), pyrithiobac sodium (pyrithiobac-sodium / generic name), piroxislam (generic name), quinmerac (quinerac) / Generic name), quinoclamin / generic name, quizalofop op / generic name), quizalofop-ethyl / common name, quizalofop-tefuryl (generic name), P quizalofop-P / generic name, P quizalofop-P / generic name quizalofop-P-ethyl / generic name), P quizalofop-tefuryl (quizalofop-P-tefuryl / generic name), saflufenacil (safrefenacil / generic name), cetoxydim (sethoxydim / generic name), ciduron (siduron / generic name) ), Simazine (simazine / generic name), simethrin (simmetrin / generic name), SL-261 (test name), sulfentrazone (sulfentrazone / generic name), sulfometuronme (Sulfomethuron-methyl / generic name), sulfosulfuron (generic name), TCBA (2,3,6-TBA / generic name), TCBA salts and esters (2,3,6-TBA-salts and esters), TCTP (chlorthal-dimethyl, tetrachlorothiophene / generic name), tebutam (tebutamur / generic name), tebuthiuron / generic name, tefuryltrione / general name, tepraloxym , Terbacil (generic name), terbumeton (generic name), terbuthylazine / general Name), terbutrin (terbutryn / generic name), tetrapion (tetrapion / flupropanate / generic name), tenylchlor (tenylchlor / generic name), thiafluuron (general name), thiazopyr (generic name), thiapyr (generic name), i Name), thiazuron / generic name, thifensulfuron-methyl / generic name, tolpyralate / generic name, tolalkoxydim / generic name, triafamone / generic name Rate (triallate / generic name), triasulfuron (triasul) uron / generic name, triaziflam / generic name, tribenuron-methyl / generic name, triclopyr / generic name, triclopyr-salts and esters, tripyr-salts and esters Diffane (trifiphane / generic name), trietadine (trietazine / generic name), trifludimoxazine (trifludimoxadin / generic name), trifloxysulfuron / generic name, trifluralin / trisulfurin / generic name Methyl (triflusulfuron-methyl / generic name), tritosulfuron (tritosulfuron) / Generic name), 2,4-PA (generic name), salts and esters of 2,4-PA (2,4-PA-salts and esters), 2,4-DB (generic name), 2,4- DB salts and esters (2,4-DB-salts and esters), butachlor (butachlor / generic name, hereinafter referred to as compound (1)), fentolazamide (fentrazamide / generic name, hereinafter referred to as compound (2)), mefenacet (Mefenacet / generic name, hereinafter referred to as compound (3)), pyrazosulfuron ethyl (pyrazosulfuron-ethyl / generic name, hereinafter referred to as compound (4)), halosulfuron methyl (halossulfuron-methyl / generic name, hereinafter referred to as compound ( 5)), metazosulfuron (metazosulfur) ron / generic name, hereinafter referred to as compound (6)), penoxsulam (penoxsuram / generic name, hereinafter referred to as compound (7)), bispyribac sodium (bispyribac-sodium / generic name, hereinafter referred to as compound (8)) , Carfentrazone-ethyl (carfentrazone-ethyl / generic name, hereinafter referred to as compound (9)), oxadiazone (oxadiazon / generic name, hereinafter referred to as compound (10)), oxadiaargyl (oxadiargyl / generic name, hereinafter referred to as compound (11) ), Quinclorac (quinclorac / generic name, hereinafter referred to as compound (12)), esprocarb (generic name / hereinafter referred to as compound (13)), molinate (molinate / generic name, hereinafter referred to as compound (14)) And described , Dimetamethrin (dimethametrin / generic name, hereinafter referred to as compound (15)), propanil (propanil / generic name, hereinafter referred to as compound (16)), bentazone (bentazone / generic name, hereinafter referred to as compound (17)), citron Halohop butyl (cyhalofop-butyl / generic name, hereinafter referred to as compound (18)), indanophan (indanofan / generic name, hereinafter referred to as compound (19)), oxadichromemephone (oxaziclomephone / generic name, hereinafter referred to as compound (20) ), Acetochlor (acetochlor / generic name, hereinafter referred to as compound (21)), alachlor (alachlor / generic name, hereinafter referred to as compound (22)), S-metolachlor (metolachlor-S / generic name, hereinafter referred to as compound) Product (23)), flufenacet (flufenacet / generic name, hereinafter referred to as compound (24)), pyroxasulfone (pyroxasulphone / generic name, hereinafter referred to as compound (25)), nicosulfuron / general Name, hereinafter referred to as compound (26)), rimsulfuron (rimsulfuron / generic name, hereinafter referred to as compound (27)), thiencarbazone-methyl / generic name (hereinafter referred to as compound (28)), Furumi Oxazine (flumioxazin / generic name, hereinafter referred to as compound (29)), tembotrione (tembotrione / generic name, hereinafter referred to as compound (30)), topramezone (topramzone / generic name, hereinafter referred to as compound (31)), meso Trione (Mesotrione / generic name, the following compounds (32) and wherein), isoxaflutole (Isoxaflutole / generic name, the following compounds (33) and wherein), sulcotrione (Sulcotrione / generic name, the following compounds
(34)), dicamba (generic name / generic name, hereinafter referred to as compound (35)), 2,4-D (generic name, hereinafter referred to as compound (36)), atrazine / generic name (hereinafter referred to as compound (36)) (37)), glyphosate (glyphosate / generic name, hereinafter referred to as compound (38)), glufosinate (glufosinate / generic name, hereinafter referred to as compound (39)), pendimethalin / generic name (hereinafter referred to as compound) (Described as (40)).

Examples of preferable known herbicidal active compounds used as component B of the composition of the present invention include the following compounds.
Butachlor, fentolazamide, mefenacet, pyrazosulfuron ethyl, halosulfuron methyl, metazosulfuron, penoxsulam, bispyrivac sodium, carfentrazone ethyl, oxadiazone, oxadiargyl, quinchlorac, eprocarb, molinate, dimetamethrin, propanyl, bentazone, cihalohop Butyl, indanophan, oxadichromephone, acetochlor, alachlor, S-metolachlor, fluphenacet, pyroxasulfone, nicosulfuron, rimsulfuron, thiencarbazone methyl, flumioxazin, tembotrione, toprazone, mesotrione, isoxaflutol, Sulcotrione, dicamba, 2,4-D, atrazine, glyphosate, glufosinate and pende Imetaline.

  The suitable mixing ratio of [Component A] and [Component B] in the composition of the present invention and the method of the present invention is generally 0.001 to 1000 parts by weight of Component B with respect to 1 part by weight of Component A Preferably, it is 0.01-100 mass parts, More preferably, it is 0.1-10 mass parts.

  In the composition of the present invention and the method of the present invention, the preferred treatment amount of each active ingredient depends on the target grass species to be controlled and the like, but usually the component A is 0.1 to 1000 ga.i./ha, the ingredient B is 0.1 to 1000 ga.i./ha, preferably component A is 1 to 300 ga.i./ha and component B is 1 to 300 ga.i./ha.

  The composition of the present invention may be mixed and applied with other types of herbicides, various insecticides, fungicides, plant growth regulators, synergists, etc., as necessary, during formulation or spraying.

  In particular, when mixed with other herbicides, cost reduction due to a decrease in the amount of applied medicine, expansion of the herbicidal spectrum due to the synergistic action of the mixed drugs, and higher herbicidal effects can be expected. At this time, a combination with a plurality of known herbicides is also possible. In the present invention, in applying, each compound may be applied individually or as a mixed composition. When each is applied individually, it may be applied at the same time or may be processed separately as long as they are close in time, and both cases are included in the method of the present invention.

  Examples of the herbicidal composition of the present invention are as shown in Table 3 below.

[Table 3]
――――――――――――――――――――
Compound A-1 + Compound (1)
Compound A-1 + Compound (2)
Compound A-1 + Compound (3)
Compound A-1 + Compound (4)
Compound A-1 + Compound (5)
Compound A-1 + Compound (6)
Compound A-1 + Compound (7)
Compound A-1 + Compound (8)
Compound A-1 + Compound (9)
Compound A-1 + Compound (10)
Compound A-1 + Compound (11)
Compound A-1 + Compound (12)
Compound A-1 + Compound (13)
Compound A-1 + Compound (14)
Compound A-1 + Compound (15)
Compound A-1 + Compound (16)
Compound A-1 + Compound (17)
Compound A-1 + Compound (18)
Compound A-1 + Compound (19)
Compound A-1 + Compound (20)
Compound A-1 + Compound (21)
Compound A-1 + Compound (22)
Compound A-1 + Compound (23)
Compound A-1 + Compound (24)
Compound A-1 + Compound (25)
Compound A-1 + Compound (26)
Compound A-1 + Compound (27)
Compound A-1 + Compound (28)
Compound A-1 + Compound (29)
Compound A-1 + Compound (30)
Compound A-1 + Compound (31)
Compound A-1 + Compound (32)
Compound A-1 + Compound (33)
Compound A-1 + Compound (34)
Compound A-1 + Compound (35)
Compound A-1 + Compound (36)
Compound A-1 + Compound (37)
Compound A-1 + Compound (38)
Compound A-1 + Compound (39)
Compound A-1 + Compound (40)
Compound A-2 + Compound (1)
Compound A-2 + Compound (2)
Compound A-2 + Compound (3)
Compound A-2 + Compound (4)
Compound A-2 + Compound (5)
Compound A-2 + Compound (6)
Compound A-2 + Compound (7)
Compound A-2 + Compound (8)
Compound A-2 + Compound (9)
Compound A-2 + Compound (10)
Compound A-2 + Compound (11)
Compound A-2 + Compound (12)
Compound A-2 + Compound (13)
Compound A-2 + Compound (14)
Compound A-2 + Compound (15)
Compound A-2 + Compound (16)
Compound A-2 + Compound (17)
Compound A-2 + Compound (18)
Compound A-2 + Compound (19)
Compound A-2 + Compound (20)
Compound A-2 + Compound (21)
Compound A-2 + Compound (22)
Compound A-2 + Compound (23)
Compound A-2 + Compound (24)
Compound A-2 + Compound (25)
Compound A-2 + Compound (26)
Compound A-2 + Compound (27)
Compound A-2 + Compound (28)
Compound A-2 + Compound (29)
Compound A-2 + Compound (30)
Compound A-2 + Compound (31)
Compound A-2 + Compound (32)
Compound A-2 + Compound (33)
Compound A-2 + Compound (34)
Compound A-2 + Compound (35)
Compound A-2 + Compound (36)
Compound A-2 + Compound (37)
Compound A-2 + Compound (38)
Compound A-2 + Compound (39)
Compound A-2 + Compound (40)
Compound A-3 + Compound (1)
Compound A-3 + Compound (2)
Compound A-3 + Compound (3)
Compound A-3 + Compound (4)
Compound A-3 + Compound (5)
Compound A-3 + Compound (6)
Compound A-3 + Compound (7)
Compound A-3 + Compound (8)
Compound A-3 + Compound (9)
Compound A-3 + Compound (10)
Compound A-3 + Compound (11)
Compound A-3 + Compound (12)
Compound A-3 + Compound (13)
Compound A-3 + Compound (14)
Compound A-3 + Compound (15)
Compound A-3 + Compound (16)
Compound A-3 + Compound (17)
Compound A-3 + Compound (18)
Compound A-3 + Compound (19)
Compound A-3 + Compound (20)
Compound A-3 + Compound (21)
Compound A-3 + Compound (22)
Compound A-3 + Compound (23)
Compound A-3 + Compound (24)
Compound A-3 + Compound (25)
Compound A-3 + Compound (26)
Compound A-3 + Compound (27)
Compound A-3 + Compound (28)
Compound A-3 + Compound (29)
Compound A-3 + Compound (30)
Compound A-3 + Compound (31)
Compound A-3 + Compound (32)
Compound A-3 + Compound (33)
Compound A-3 + Compound (34)
Compound A-3 + Compound (35)
Compound A-3 + Compound (36)
Compound A-3 + Compound (37)
Compound A-3 + Compound (38)
Compound A-3 + Compound (39)
Compound A-3 + Compound (40)
Compound A-4 + Compound (1)
Compound A-4 + Compound (2)
Compound A-4 + Compound (3)
Compound A-4 + Compound (4)
Compound A-4 + Compound (5)
Compound A-4 + Compound (6)
Compound A-4 + Compound (7)
Compound A-4 + Compound (8)
Compound A-4 + Compound (9)
Compound A-4 + Compound (10)
Compound A-4 + Compound (11)
Compound A-4 + Compound (12)
Compound A-4 + Compound (13)
Compound A-4 + Compound (14)
Compound A-4 + Compound (15)
Compound A-4 + Compound (16)
Compound A-4 + Compound (17)
Compound A-4 + Compound (18)
Compound A-4 + Compound (19)
Compound A-4 + Compound (20)
Compound A-4 + Compound (21)
Compound A-4 + Compound (22)
Compound A-4 + Compound (23)
Compound A-4 + Compound (24)
Compound A-4 + Compound (25)
Compound A-4 + Compound (26)
Compound A-4 + Compound (27)
Compound A-4 + Compound (28)
Compound A-4 + Compound (29)
Compound A-4 + Compound (30)
Compound A-4 + Compound (31)
Compound A-4 + Compound (32)
Compound A-4 + Compound (33)
Compound A-4 + Compound (34)
Compound A-4 + Compound (35)
Compound A-4 + Compound (36)
Compound A-4 + Compound (37)
Compound A-4 + Compound (38)
Compound A-4 + Compound (39)
Compound A-4 + Compound (40)
Compound A-5 + Compound (1)
Compound A-5 + Compound (2)
Compound A-5 + Compound (3)
Compound A-5 + Compound (4)
Compound A-5 + Compound (5)
Compound A-5 + Compound (6)
Compound A-5 + Compound (7)
Compound A-5 + Compound (8)
Compound A-5 + Compound (9)
Compound A-5 + Compound (10)
Compound A-5 + Compound (11)
Compound A-5 + Compound (12)
Compound A-5 + Compound (13)
Compound A-5 + Compound (14)
Compound A-5 + Compound (15)
Compound A-5 + Compound (16)
Compound A-5 + Compound (17)
Compound A-5 + Compound (18)
Compound A-5 + Compound (19)
Compound A-5 + Compound (20)
Compound A-5 + Compound (21)
Compound A-5 + Compound (22)
Compound A-5 + Compound (23)
Compound A-5 + Compound (24)
Compound A-5 + Compound (25)
Compound A-5 + Compound (26)
Compound A-5 + Compound (27)
Compound A-5 + Compound (28)
Compound A-5 + Compound (29)
Compound A-5 + Compound (30)
Compound A-5 + Compound (31)
Compound A-5 + Compound (32)
Compound A-5 + Compound (33)
Compound A-5 + Compound (34)
Compound A-5 + Compound (35)
Compound A-5 + Compound (36)
Compound A-5 + Compound (37)
Compound A-5 + Compound (38)
Compound A-5 + Compound (39)
Compound A-5 + Compound (40)
Compound A-6 + Compound (1)
Compound A-6 + Compound (2)
Compound A-6 + Compound (3)
Compound A-6 + Compound (4)
Compound A-6 + Compound (5)
Compound A-6 + Compound (6)
Compound A-6 + Compound (7)
Compound A-6 + Compound (8)
Compound A-6 + Compound (9)
Compound A-6 + Compound (10)
Compound A-6 + Compound (11)
Compound A-6 + Compound (12)
Compound A-6 + Compound (13)
Compound A-6 + Compound (14)
Compound A-6 + Compound (15)
Compound A-6 + Compound (16)
Compound A-6 + Compound (17)
Compound A-6 + Compound (18)
Compound A-6 + Compound (19)
Compound A-6 + Compound (20)
Compound A-6 + Compound (21)
Compound A-6 + Compound (22)
Compound A-6 + Compound (23)
Compound A-6 + Compound (24)
Compound A-6 + Compound (25)
Compound A-6 + Compound (26)
Compound A-6 + Compound (27)
Compound A-6 + Compound (28)
Compound A-6 + Compound (29)
Compound A-6 + Compound (30)
Compound A-6 + Compound (31)
Compound A-6 + Compound (32)
Compound A-6 + Compound (33)
Compound A-6 + Compound (34)
Compound A-6 + Compound (35)
Compound A-6 + Compound (36)
Compound A-6 + Compound (37)
Compound A-6 + Compound (38)
Compound A-6 + Compound (39)
Compound A-6 + Compound (40)
Compound A-7 + Compound (1)
Compound A-7 + Compound (2)
Compound A-7 + Compound (3)
Compound A-7 + Compound (4)
Compound A-7 + Compound (5)
Compound A-7 + Compound (6)
Compound A-7 + Compound (7)
Compound A-7 + Compound (8)
Compound A-7 + Compound (9)
Compound A-7 + Compound (10)
Compound A-7 + Compound (11)
Compound A-7 + Compound (12)
Compound A-7 + Compound (13)
Compound A-7 + Compound (14)
Compound A-7 + Compound (15)
Compound A-7 + Compound (16)
Compound A-7 + Compound (17)
Compound A-7 + Compound (18)
Compound A-7 + Compound (19)
Compound A-7 + Compound (20)
Compound A-7 + Compound (21)
Compound A-7 + Compound (22)
Compound A-7 + Compound (23)
Compound A-7 + Compound (24)
Compound A-7 + Compound (25)
Compound A-7 + Compound (26)
Compound A-7 + Compound (27)
Compound A-7 + Compound (28)
Compound A-7 + Compound (29)
Compound A-7 + Compound (30)
Compound A-7 + Compound (31)
Compound A-7 + Compound (32)
Compound A-7 + Compound (33)
Compound A-7 + Compound (34)
Compound A-7 + Compound (35)
Compound A-7 + Compound (36)
Compound A-7 + Compound (37)
Compound A-7 + Compound (38)
Compound A-7 + Compound (39)
Compound A-7 + Compound (40)
Compound A-8 + Compound (1)
Compound A-8 + Compound (2)
Compound A-8 + Compound (3)
Compound A-8 + Compound (4)
Compound A-8 + Compound (5)
Compound A-8 + Compound (6)
Compound A-8 + Compound (7)
Compound A-8 + Compound (8)
Compound A-8 + Compound (9)
Compound A-8 + Compound (10)
Compound A-8 + Compound (11)
Compound A-8 + Compound (12)
Compound A-8 + Compound (13)
Compound A-8 + Compound (14)
Compound A-8 + Compound (15)
Compound A-8 + Compound (16)
Compound A-8 + Compound (17)
Compound A-8 + Compound (18)
Compound A-8 + Compound (19)
Compound A-8 + Compound (20)
Compound A-8 + Compound (21)
Compound A-8 + Compound (22)
Compound A-8 + Compound (23)
Compound A-8 + Compound (24)
Compound A-8 + Compound (25)
Compound A-8 + Compound (26)
Compound A-8 + Compound (27)
Compound A-8 + Compound (28)
Compound A-8 + Compound (29)
Compound A-8 + Compound (30)
Compound A-8 + Compound (31)
Compound A-8 + Compound (32)
Compound A-8 + Compound (33)
Compound A-8 + Compound (34)
Compound A-8 + Compound (35)
Compound A-8 + Compound (36)
Compound A-8 + Compound (37)
Compound A-8 + Compound (38)
Compound A-8 + Compound (39)
Compound A-8 + Compound (40)
Compound A-9 + Compound (1)
Compound A-9 + Compound (2)
Compound A-9 + Compound (3)
Compound A-9 + Compound (4)
Compound A-9 + Compound (5)
Compound A-9 + Compound (6)
Compound A-9 + Compound (7)
Compound A-9 + Compound (8)
Compound A-9 + Compound (9)
Compound A-9 + Compound (10)
Compound A-9 + Compound (11)
Compound A-9 + Compound (12)
Compound A-9 + Compound (13)
Compound A-9 + Compound (14)
Compound A-9 + Compound (15)
Compound A-9 + Compound (16)
Compound A-9 + Compound (17)
Compound A-9 + Compound (18)
Compound A-9 + Compound (19)
Compound A-9 + Compound (20)
Compound A-9 + Compound (21)
Compound A-9 + Compound (22)
Compound A-9 + Compound (23)
Compound A-9 + Compound (24)
Compound A-9 + Compound (25)
Compound A-9 + Compound (26)
Compound A-9 + Compound (27)
Compound A-9 + Compound (28)
Compound A-9 + Compound (29)
Compound A-9 + Compound (30)
Compound A-9 + Compound (31)
Compound A-9 + Compound (32)
Compound A-9 + Compound (33)
Compound A-9 + Compound (34)
Compound A-9 + Compound (35)
Compound A-9 + Compound (36)
Compound A-9 + Compound (37)
Compound A-9 + Compound (38)
Compound A-9 + Compound (39)
Compound A-9 + Compound (40)
Compound A-10 + Compound (1)
Compound A-10 + Compound (2)
Compound A-10 + Compound (3)
Compound A-10 + Compound (4)
Compound A-10 + Compound (5)
Compound A-10 + Compound (6)
Compound A-10 + Compound (7)
Compound A-10 + Compound (8)
Compound A-10 + Compound (9)
Compound A-10 + Compound (10)
Compound A-10 + Compound (11)
Compound A-10 + Compound (12)
Compound A-10 + Compound (13)
Compound A-10 + Compound (14)
Compound A-10 + Compound (15)
Compound A-10 + Compound (16)
Compound A-10 + Compound (17)
Compound A-10 + Compound (18)
Compound A-10 + Compound (19)
Compound A-10 + Compound (20)
Compound A-10 + Compound (21)
Compound A-10 + Compound (22)
Compound A-10 + Compound (23)
Compound A-10 + Compound (24)
Compound A-10 + Compound (25)
Compound A-10 + Compound (26)
Compound A-10 + Compound (27)
Compound A-10 + Compound (28)
Compound A-10 + Compound (29)
Compound A-10 + Compound (30)
Compound A-10 + Compound (31)
Compound A-10 + Compound (32)
Compound A-10 + Compound (33)
Compound A-10 + Compound (34)
Compound A-10 + Compound (35)
Compound A-10 + Compound (36)
Compound A-10 + Compound (37)
Compound A-10 + Compound (38)
Compound A-10 + Compound (39)
Compound A-10 + Compound (40)
Compound A-11 + Compound (1)
Compound A-11 + Compound (2)
Compound A-11 + Compound (3)
Compound A-11 + Compound (4)
Compound A-11 + Compound (5)
Compound A-11 + Compound (6)
Compound A-11 + Compound (7)
Compound A-11 + Compound (8)
Compound A-11 + Compound (9)
Compound A-11 + Compound (10)
Compound A-11 + Compound (11)
Compound A-11 + Compound (12)
Compound A-11 + Compound (13)
Compound A-11 + Compound (14)
Compound A-11 + Compound (15)
Compound A-11 + Compound (16)
Compound A-11 + Compound (17)
Compound A-11 + Compound (18)
Compound A-11 + Compound (19)
Compound A-11 + Compound (20)
Compound A-11 + Compound (21)
Compound A-11 + Compound (22)
Compound A-11 + Compound (23)
Compound A-11 + Compound (24)
Compound A-11 + Compound (25)
Compound A-11 + Compound (26)
Compound A-11 + Compound (27)
Compound A-11 + Compound (28)
Compound A-11 + Compound (29)
Compound A-11 + Compound (30)
Compound A-11 + Compound (31)
Compound A-11 + Compound (32)
Compound A-11 + Compound (33)
Compound A-11 + Compound (34)
Compound A-11 + Compound (35)
Compound A-11 + Compound (36)
Compound A-11 + Compound (37)
Compound A-11 + Compound (38)
Compound A-11 + Compound (39)
Compound A-11 + Compound (40)
Compound A-12 + Compound (1)
Compound A-12 + Compound (2)
Compound A-12 + Compound (3)
Compound A-12 + Compound (4)
Compound A-12 + Compound (5)
Compound A-12 + Compound (6)
Compound A-12 + Compound (7)
Compound A-12 + Compound (8)
Compound A-12 + Compound (9)
Compound A-12 + Compound (10)
Compound A-12 + Compound (11)
Compound A-12 + Compound (12)
Compound A-12 + Compound (13)
Compound A-12 + Compound (14)
Compound A-12 + Compound (15)
Compound A-12 + Compound (16)
Compound A-12 + Compound (17)
Compound A-12 + Compound (18)
Compound A-12 + Compound (19)
Compound A-12 + Compound (20)
Compound A-12 + Compound (21)
Compound A-12 + Compound (22)
Compound A-12 + Compound (23)
Compound A-12 + Compound (24)
Compound A-12 + Compound (25)
Compound A-12 + Compound (26)
Compound A-12 + Compound (27)
Compound A-12 + Compound (28)
Compound A-12 + Compound (29)
Compound A-12 + Compound (30)
Compound A-12 + Compound (31)
Compound A-12 + Compound (32)
Compound A-12 + Compound (33)
Compound A-12 + Compound (34)
Compound A-12 + Compound (35)
Compound A-12 + Compound (36)
Compound A-12 + Compound (37)
Compound A-12 + Compound (38)
Compound A-12 + Compound (39)
Compound A-12 + Compound (40)
――――――――――――――――――――
When the composition of the present invention is used in paddy fields, it may be subjected to simultaneous rice planting treatment in addition to the usual treatment before and after rice planting.

  Examples of the safener that can be used with the herbicidal composition of the present invention include, for example, AD-67, benoxacol (benoxacor / generic name), cloquintocet-mexyl (generic name), and ciomethinil (generic name). Name), dichlormide (dichromid / generic name), dicyclonone (dicycloneone / generic name), cyprosulfamide (cyprosulfamide / generic name), dietolate (diethylate / generic name), DKA-24, dimron / generic name, Fenchlorazole-ethyl (fenchlorazole-ethyl / generic name), fenchlorim (fenclorim / generic name), hexim (HEXIM / generic name), flurazole (fl razole / generic name), floxophenim (fluxofenim / generic name), flirazole (furilazole / generic name), isoxadifen (isoxadifen / generic name), isoxadifen-ethyl (isoxadifen-ethyl / generic name), MCPA, mecoprop / mecroprop (Generic name), mefenpyr (mefenpyr / generic name), mefenpyrethyl (mefenpyr-ethyl / generic name), mefenpyr-diethyl (mefenpyr-diethyl / generic name), mephenate (mephenate / generic name), MG-191, NA (Naphthalic anhydride), OM (Octamethylene-diamine), Oxabetalinil (generic name) ), PPG-1292, R-29148, and the like. These components can be used alone or in admixture of two or more, and the ratio in the case of mixing can also be freely selected.

  The composition of the present invention is usually mixed with a suitable solid carrier or liquid carrier, and if necessary, a surfactant, penetrant, spreading agent, thickener, antifreeze agent, binder, anti-caking agent, disintegrant. , Antifoaming agents, antiseptics or anti-decomposition agents, etc., and adding soluble concentrate, emulsion (emulsifiable concentrate), wettable powder, water soluble powder, granular wettable powder ( water dispersible granule, water soluble granule, suspension concentrate, concentrated emulsion, suspoemulsion, microemulsion, dustable powder, granule It can be practically used in preparations of any dosage form such as a granule and a gel. In addition, from the viewpoint of labor saving and safety improvement, the preparation of any dosage form can be enclosed in a water-soluble package. If necessary, it can be used in combination with a plurality of other herbicides, insecticides, fungicides, plant growth regulators, fertilizers and the like during preparation or spraying.

  Examples of solid carriers include quartz, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, and diatomaceous earth, and other minerals, calcium carbonate, ammonium sulfate, sodium sulfate, and potassium chloride. Examples include salts, synthetic silicic acid and synthetic silicates.

  Examples of the liquid carrier include alcohols such as ethylene glycol, propylene glycol and isopropanol, aromatic hydrocarbons such as xylene, alkylbenzene and alkylnaphthalene, ethers such as butyl cellosolve, ketones such as cyclohexanone, and esters such as γ-butyrolactone. And acid amides such as N-methylpyrrolidone and N-octylpyrrolidone, vegetable oils such as soybean oil, rapeseed oil, cottonseed oil and castor oil, and water.

  These solid and liquid carriers may be used alone or in combination of two or more.

  Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene fatty acid ester, sorbitan fatty acid ester and polyoxyethylene sorbitan. Nonionic surfactant such as fatty acid ester, alkyl sulfate, alkylbenzene sulfonate, lignin sulfonate, alkyl sulfosuccinate, naphthalene sulfonate, alkyl naphthalene sulfonate, salt of formalin condensate of naphthalene sulfonate, Salt of formalin condensate of alkylnaphthalenesulfonic acid, polyoxyethylene alkylaryl ether sulfate and phosphate, polyoxyethylene polystyrene Anionic surfactants such as phenyl ether sulfate and phosphate, polycarboxylate and polystyrene sulfonate, cationic surfactants such as alkylamine salt and alkyl quaternary ammonium salt, and amphoteric interfaces such as amino acid type and betaine type An activator is mentioned.

  The content of these surfactants is not particularly limited, but is usually preferably in the range of 0.05 to 20 parts by mass with respect to 100 parts by mass of the composition of the present invention. These surfactants may be used alone or in combination of two or more.

  At this time, a plurality of other herbicides, insecticides, fungicides, plant growth regulators, fertilizers and the like can be used in combination. In particular, by blending one or more other herbicides, it becomes possible to broaden the herbicidal spectrum, and the effects of the present invention can be made more stable.

  Next, formulation examples of the composition of the present invention will be shown. However, the present invention is not limited to these. In the following formulation examples, “part” means part by mass.

[Wettable powder]
Compound A and Compound B 0.1-80 parts Solid carrier 5-98.9 parts Surfactant 1-10 parts Others 0-5 parts Others include, for example, anti-caking agents and decomposition inhibitors.

[Emulsifiable concentrate]
Compound A and Compound B 0.1-30 parts Liquid carrier 45-95 parts Surfactant 4.9-15 parts Others 0-10 parts Others include, for example, spreading agents, decomposition inhibitors and the like.

[Suspension concentrate]
Compound A and Compound B 0.1 to 70 parts Liquid carrier 15 to 98.89 parts Surfactant 1 to 12 parts Others 0.01 to 30 parts Others include, for example, antifreezing agents and thickeners.

[Granular wettable powder (water dispersible granule)]
Compound A and Compound B 0.1 to 90 parts Solid carrier 0 to 98.9 parts Surfactant 1 to 20 parts Others 0 to 10 parts Others include, for example, binders and decomposition inhibitors.

[Soluble concentrate]
Compound A and Compound B 0.01 to 70 parts Liquid carrier 20 to 99.99 parts Others 0 to 10 parts Others include, for example, antifreezing agents and spreading agents.

[Granule]
Compound A and Compound B 0.01-80 parts Solid carrier 10-99.99 parts Others 0-10 parts Others include, for example, binders, decomposition inhibitors and the like.

[Dustable powder]
Compound A and Compound B 0.01-30 parts Solid carrier 65-99.99 parts Others 0-5 parts Others include, for example, drift inhibitors and decomposition inhibitors.

  In use, the above preparation is diluted 1 to 10,000 times with water or without dilution, and sprayed so that the active ingredient is 0.001 to 50 kg, preferably 0.01 to 10 kg per hectare (ha). .

[Formulation example]
Next, although an example of an agrochemical formulation is shown concretely, it is not limited only to these. In the following formulation examples, “part” means part by mass.

[Formulation 1] wettable powder
Compound A-1 10 parts Compound (1) 3 parts Pyrophyllite 81 parts Solpol 5039 4 parts (mixture with nonionic surfactant and anionic surfactant: manufactured by Toho Chemical Industry Co., Ltd.)
Carplex # 80D 2 parts (Synthetic hydrous silicic acid: manufactured by Shionogi & Co.)
The above is uniformly mixed and ground to obtain a wettable powder.

[Formulation Example 2] Emulsifiable concentrate
Compound A-2 1 part compound (15) 10 parts xylene 69 parts N-methylpyrrolidone 15 parts Solpol 2680 5 parts (mixture with nonionic surfactant and anionic surfactant: manufactured by Toho Chemical Co., Ltd.)
The above is uniformly mixed to obtain an emulsion.

[Composition Example 3] Suspension concentrate
Compound A-3 10 parts Compound (25) 6 parts Agrisol S-710 10 parts (nonionic surfactant: manufactured by Kao Corporation)
Lnox 1000C 0.5 part (anionic surfactant: manufactured by Toho Chemical Co., Ltd.)
Xanthan gum 0.2 parts Water 73.3 parts After uniformly mixing the above, wet pulverize to make a suspension.

[Formulation 4] Granule wettable powder (water dispersible granule)
Compound A-4 20 parts Compound (29) 60 parts Hytenol NE-15 5 parts (anionic surfactant: manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)
Vanillex N 7.5 parts (anionic surfactant: manufactured by Nippon Paper Industries Co., Ltd.)
Carplex # 80D 7.5 parts (synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd. trade name)
After uniformly mixing and pulverizing the above, a small amount of water is added, stirred and mixed, granulated with an extrusion granulator, and dried to obtain a granulated wettable powder.

[Formulation Example 5] Granule
Compound A-5 2 parts Compound (6) 4 parts Bentonite 50 parts Talc 44 parts Use granules.

[Formulation 6] dustable powder
Compound A-6 1 part Compound (4) 2 parts Carplex # 80D 0.5 part (Synthetic hydrous silicic acid: manufactured by Shionogi & Co.)
Kaolinite 95 parts Diisopropyl phosphate 1.5 parts or more uniformly mixed and pulverized to obtain a powder.

[Formulation Example 7] wettable powder
Compound A-8 5 parts Compound (22) 15 parts Pyrophyllite 74 parts Solpol 5039 4 parts (mixture with nonionic surfactant and anionic surfactant: manufactured by Toho Chemical Industry Co., Ltd.)
Carplex # 80D 2 parts (Synthetic hydrous silicic acid: manufactured by Shionogi & Co.)
The above is uniformly mixed and ground to obtain a wettable powder.

[Formulation Example 8] Emulsifiable concentrate
Compound A-9 1 part compound (14) 6 parts xylene 73 parts N-methylpyrrolidone 15 parts Solpol 2680 5 parts (mixture with nonionic surfactant and anionic surfactant: manufactured by Toho Chemical Co., Ltd.)
In use, each preparation is diluted 1 to 20000 times with water and sprayed so that the active ingredient is 0.005 to 50 kg per hectare (ha), preferably 0.05 to 10 kg. .

  The above is uniformly mixed to obtain an emulsion.

  Next, the usefulness of the present invention will be specifically described in the following test examples. However, the present invention is not limited to these.

[Test Example 1] Herbicidal effect test on paddy field weeds by foliar treatment After alluvial soil was put into a 1/10000 are Wagner pot, water was added and mixed, so that the water depth was 0.1 cm to 0.5 cm. The amount of was adjusted. After seeding Inubibie, Azegaya, Kogomegatsutsu and rice seeds on alluvial soil, plants were grown by placing a Wagner pot in a greenhouse at 25 ° C to 30 ° C. After growing for 10 days, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dose, and uniformly treated with a small spray on the foliage. Two weeks after the drug treatment, the effects on various plants were investigated according to the following criteria. The results are shown in Table 5.

Judgment criteria 5 ... 90% or more of the killing rate (almost completely dead)
4 ... Herbicide rate 70% or more and less than 90% 3 ... Herbicide rate 40% or more and less than 70% 2 ... Herbicide rate 20% or more and less than 40% 1 ... Herbicide rate 5% or more and less than 20% 0 ..Harvicide rate of 5% or less (almost no effect)
Note that the description in Table 5 will be described using the description in Table 4 which is a table for illustration. The expression “compound AQ + (T)” in the “compound” column means a combination of compound AQ and compound (T). The notation of “q + t” in the “treatment drug amount (g / ha)” column is a treatment drug in which q (g / ha) of compound A-Q and t (g / ha) of compound (T) are mixed. Means quantity. The description of “z” in the “Inubiae, Azegaya, Kogomegatsutsu, Rice” column means that the herbicidal effect on various plants was z. More specifically, when the value in the “rice” column is “0”, it means that the herbicidal effect on rice when the corresponding drug is treated is zero.

In addition, compound AQ represents any one compound of compounds A-1 to A-12, and compound (T) represents any one compound of compounds (1) to compound (40). “Z” represents an integer of 0 to 5. Moreover, ha of the treatment dose (g / ha) represents hectares (10000 m ² ).

[Table 4]
――――――――――――――――――――――――――――――――――――――――
Compound Treatment dose Inuvie Azegaya Kogomegayatsu Rice
(g / ha)
――――――――――――――――――――――――――――――――――――――――
Compound A-Q + (T) q + tzzz 0
――――――――――――――――――――――――――――――――――――――――
[Table 5]
――――――――――――――――――――――――――――――――――――――――
Compound Treatment dose Inuvie Azegaya Kogomegayatsu Rice
(g / ha)
――――――――――――――――――――――――――――――――――――――――
Compound (1) 750 0 3 5 1
Compound (2) 300 4 5 5 1
Compound (3) 1200 5 5 5 0
Compound (4) 30 4 0 5 2
Compound (5) 60 4 0 5 2
Compound (6) 100 5 0 5 0
Compound (7) 23 5 0 5 1
Compound (8) 25 5 4 5 0
Compound (9) 35 4 0 5 3
Compound (10) 240 4 3 5 2
Compound (11) 200 5 5 5 4
Compound (12) 100 5 0 0 0
Compound (13) 1200 4 4 4 2
Compound (14) 2000 3 0 4 0
Compound (15) 60 3 2 4 0
Compound (16) 2500 4 2 4 0
Compound (17) 2000 0 0 5 0
Compound (18) 120 5 5 0 0
Compound (19) 300 5 5 4 5
Compound (20) 80 5 4 3 0
Compound (21) 2000 5 4 5 5
Compound (22) 1720 4 5 5 5
Compound (23) 2000 5 5 4 5
Compound (24) 600 5 5 5 5
Compound (25) 200 5 5 5 4
Compound (26) 60 5 5 5 5
Compound (27) 15 5 5 5 5
Compound (28) 25 5 5 5 4
Compound (29) 25 4 5 5 4
Compound (30) 100 5 5 5 4
Compound (31) 54 5 5 5 5
Compound (32) 150 5 5 5 4
Compound (33) 100 5 5 4 5
Compound (34) 450 2 3 4 0
Compound (35) 250 3 4 5 3
Compound (36) 1000 3 4 4 4
Compound (37) 900 5 3 5 5
Compound (38) 2400 5 5 5 5
Compound (39) 925 5 5 5 5
Compound (40) 900 5 4 4 0
Compound A-1 50 5 5 4 0
Compound A-1 + (1) 50 + 750 5 5 5 3
Compound A-1 + (2) 50 + 300 5 5 5 4
Compound A-1 + (3) 50 + 1200 5 5 5 0
Compound A-1 + (4) 50 + 30 5 5 5 2
Compound A-1 + (5) 50 + 60 5 5 5 2
Compound A-1 + (6) 50 + 100 5 5 5 0
Compound A-1 + (7) 50 + 23 5 5 5 1
Compound A-1 + (8) 50 + 25 5 5 5 0
Compound A-1 + (9) 50 + 35 5 5 5 3
Compound A-1 + (10) 50 + 240 5 5 5 3
Compound A-1 + (11) 50 + 200 5 5 5 5
Compound A-1 + (12) 50 + 100 5 5 4 0
Compound A-1 + (13) 50 + 1200 5 5 4 0
Compound A-1 + (14) 50 + 2000 5 5 5 4
Compound A-1 + (15) 50 + 60 5 5 4 2
Compound A-1 + (16) 50 + 2500 5 5 5 0
Compound A-1 + (17) 50 + 2000 5 5 5 0
Compound A-1 + (18) 50 + 120 5 5 5 0
Compound A-1 + (19) 50 + 300 5 5 4 5
Compound A-1 + (20) 50 + 80 5 5 4 2
Compound A-1 + (21) 50 + 2000 5 5 5 5
Compound A-1 + (22) 50 + 1720 5 5 5 5
Compound A-1 + (23) 50 + 2000 5 5 5 5
Compound A-1 + (24) 50 + 600 5 5 5 5
Compound A-1 + (25) 50 + 200 5 5 5 5
Compound A-1 + (26) 50 + 60 5 5 5 5
Compound A-1 + (27) 50 + 15 5 5 5 5
Compound A-1 + (28) 50 + 25 5 5 5 4
Compound A-1 + (29) 50 + 25 5 5 5 4
Compound A-1 + (30) 50 + 100 5 5 5 5
Compound A-1 + (31) 50 + 54 5 5 5 5
Compound A-1 + (32) 50 + 150 5 5 5 5
Compound A-1 + (33) 50 + 100 5 5 5 5
Compound A-1 + (34) 50 + 450 5 5 5 2
Compound A-1 + (35) 50 + 250 5 5 5 3
Compound A-1 + (36) 50 + 1000 5 5 5 5
Compound A-1 + (37) 50 + 900 5 5 5 5
Compound A-1 + (38) 50 + 2400 5 5 5 5
Compound A-1 + (39) 50 + 925 5 5 5 5
Compound A-1 + (40) 50 + 900 5 5 4 2
Compound A-2 50 4 5 5 0
Compound A-2 + (1) 50 + 750 5 5 5 0
Compound A-2 + (2) 50 + 300 5 5 5 1
Compound A-2 + (3) 50 + 1200 5 5 5 1
Compound A-2 + (4) 50 + 30 4 5 5 1
Compound A-2 + (5) 50 + 60 4 5 5 0
Compound A-2 + (6) 50 + 100 5 5 5 1
Compound A-2 + (7) 50 + 23 5 5 5 1
Compound A-2 + (8) 50 + 25 5 5 5 0
Compound A-2 + (9) 50 + 35 5 5 5 3
Compound A-2 + (10) 50 + 240 5 5 5 1
Compound A-2 + (11) 50 + 200 5 5 5 4
Compound A-2 + (12) 50 + 100 5 5 4 0
Compound A-2 + (13) 50 + 1200 5 5 5 1
Compound A-2 + (14) 50 + 2000 5 5 5 0
Compound A-2 + (15) 50 + 60 4 5 4 1
Compound A-2 + (16) 50 + 2500 4 5 5 0
Compound A-2 + (17) 50 + 2000 4 5 5 1
Compound A-2 + (18) 50 + 120 5 5 5 0
Compound A-2 + (19) 50 + 300 5 5 5 0
Compound A-2 + (20) 50 + 80 5 5 5 0
Compound A-2 + (21) 50 + 2000 5 5 5 5
Compound A-2 + (22) 50 + 1720 5 5 5 5
Compound A-2 + (23) 50 + 2000 5 5 5 5
Compound A-2 + (24) 50 + 600 5 5 5 5
Compound A-2 + (25) 50 + 200 5 5 5 5
Compound A-2 + (26) 50 + 60 5 5 5 5
Compound A-2 + (27) 50 + 15 5 5 5 5
Compound A-2 + (28) 50 + 25 5 5 5 5
Compound A-2 + (29) 50 + 25 5 5 5 5
Compound A-2 + (30) 50 + 100 5 5 5 5
Compound A-2 + (31) 50 + 54 5 5 5 5
Compound A-2 + (32) 50 + 150 5 5 5 5
Compound A-2 + (33) 50 + 100 5 5 5 5
Compound A-2 + (34) 50 + 450 5 5 5 1
Compound A-2 + (35) 50 + 250 5 5 5 5
Compound A-2 + (36) 50 + 1000 5 5 5 5
Compound A-2 + (37) 50 + 900 5 5 5 5
Compound A-2 + (38) 50 + 2400 5 5 4 5
Compound A-2 + (39) 50 + 925 5 5 5 5
Compound A-2 + (40) 50 + 900 5 5 5 5
Compound A-3 50 5 5 4 1
Compound A-3 + (1) 50 + 750 5 5 5 2
Compound A-3 + (2) 50 + 300 5 5 5 2
Compound A-3 + (3) 50 + 1200 5 5 5 1
Compound A-3 + (4) 50 + 30 5 5 5 1
Compound A-3 + (5) 50 + 60 5 5 5 1
Compound A-3 + (6) 50 + 100 5 5 5 1
Compound A-3 + (7) 50 + 23 5 5 5 2
Compound A-3 + (8) 50 + 25 5 5 5 2
Compound A-3 + (9) 50 + 35 5 5 5 1
Compound A-3 + (10) 50 + 240 5 5 5 1
Compound A-3 + (11) 50 + 200 5 5 5 3
Compound A-3 + (12) 50 + 100 5 5 4 1
Compound A-3 + (13) 50 + 1200 5 5 4 2
Compound A-3 + (14) 50 + 2000 5 5 5 2
Compound A-3 + (15) 50 + 60 5 5 4 2
Compound A-3 + (16) 50 + 2500 5 5 4 1
Compound A-3 + (17) 50 + 2000 5 5 5 1
Compound A-3 + (18) 50 + 120 5 5 4 1
Compound A-3 + (19) 50 + 300 5 5 5 4
Compound A-3 + (20) 50 + 80 5 5 5 1
Compound A-3 + (21) 50 + 2000 5 5 5 5
Compound A-3 + (22) 50 + 1720 5 5 5 5
Compound A-3 + (23) 50 + 2000 5 5 5 5
Compound A-3 + (24) 50 + 600 5 5 5 5
Compound A-3 + (25) 50 + 200 5 5 5 5
Compound A-3 + (26) 50 + 60 5 5 5 5
Compound A-3 + (27) 50 + 15 5 5 5 5
Compound A-3 + (28) 50 + 25 5 5 5 5
Compound A-3 + (29) 50 + 25 5 5 5 5
Compound A-3 + (30) 50 + 100 5 5 5 5
Compound A-3 + (31) 50 + 54 5 5 5 5
Compound A-3 + (32) 50 + 150 5 5 5 5
Compound A-3 + (33) 50 + 100 5 5 5 5
Compound A-3 + (34) 50 + 450 5 5 5 1
Compound A-3 + (35) 50 + 250 5 5 5 4
Compound A-3 + (36) 50 + 1000 5 5 5 5
Compound A-3 + (37) 50 + 900 5 5 5 5
Compound A-3 + (38) 50 + 2400 5 5 5 5
Compound A-3 + (39) 50 + 925 5 5 4 5
Compound A-3 + (40) 50 + 900 5 5 5 5
Compound A-4 50 5 5 5 2
Compound A-4 + (1) 50 + 750 5 5 5 3
Compound A-4 + (2) 50 + 300 5 5 5 4
Compound A-4 + (3) 50 + 1200 5 5 5 3
Compound A-4 + (4) 50 + 30 5 5 5 3
Compound A-4 + (5) 50 + 60 5 5 5 4
Compound A-4 + (6) 50 + 100 5 5 5 2
Compound A-4 + (7) 50 + 23 5 5 5 3
Compound A-4 + (8) 50 + 25 5 5 5 3
Compound A-4 + (9) 50 + 35 5 5 5 4
Compound A-4 + (10) 50 + 240 5 5 5 3
Compound A-4 + (11) 50 + 200 5 5 5 3
Compound A-4 + (12) 50 + 100 5 5 5 2
Compound A-4 + (13) 50 + 1200 5 5 5 3
Compound A-4 + (14) 50 + 2000 5 5 5 4
Compound A-4 + (15) 50 + 60 5 5 5 4
Compound A-4 + (16) 50 + 2500 5 5 5 3
Compound A-4 + (17) 50 + 2000 5 5 5 4
Compound A-4 + (18) 50 + 120 5 5 5 2
Compound A-4 + (19) 50 + 300 5 5 5 3
Compound A-4 + (20) 50 + 80 5 5 5 3
Compound A-4 + (21) 50 + 2000 5 5 5 5
Compound A-4 + (22) 50 + 1720 5 5 5 5
Compound A-4 + (23) 50 + 2000 5 5 5 5
Compound A-4 + (24) 50 + 600 5 5 5 5
Compound A-4 + (25) 50 + 200 5 5 5 5
Compound A-4 + (26) 50 + 60 5 5 5 5
Compound A-4 + (27) 50 + 15 5 5 5 5
Compound A-4 + (28) 50 + 25 5 5 5 4
Compound A-4 + (29) 50 + 25 5 5 5 5
Compound A-4 + (30) 50 + 100 5 5 5 5
Compound A-4 + (31) 50 + 54 5 5 5 5
Compound A-4 + (32) 50 + 150 5 5 5 5
Compound A-4 + (33) 50 + 100 5 5 5 5
Compound A-4 + (34) 50 + 450 5 5 5 4
Compound A-4 + (35) 50 + 250 5 5 5 4
Compound A-4 + (36) 50 + 1000 5 5 5 5
Compound A-4 + (37) 50 + 900 5 5 5 5
Compound A-4 + (38) 50 + 2400 5 5 5 5
Compound A-4 + (39) 50 + 925 5 5 5 5
Compound A-4 + (40) 50 + 900 5 5 5 5
Compound A-5 50 5 5 4 0
Compound A-5 + (1) 50 + 750 5 5 5 2
Compound A-5 + (2) 50 + 300 5 5 5 3
Compound A-5 + (3) 50 + 1200 5 5 5 0
Compound A-5 + (4) 50 + 30 5 4 5 1
Compound A-5 + (5) 50 + 60 5 5 5 0
Compound A-5 + (6) 50 + 100 5 5 5 2
Compound A-5 + (7) 50 + 23 5 5 5 0
Compound A-5 + (8) 50 + 25 5 4 5 2
Compound A-5 + (9) 50 + 35 5 5 5 2
Compound A-5 + (10) 50 + 240 5 5 5 3
Compound A-5 + (11) 50 + 200 5 5 5 4
Compound A-5 + (12) 50 + 100 5 5 4 0
Compound A-5 + (13) 50 + 1200 5 5 4 2
Compound A-5 + (14) 50 + 2000 5 5 5 3
Compound A-5 + (15) 50 + 60 5 5 5 3
Compound A-5 + (16) 50 + 2500 5 5 5 1
Compound A-5 + (17) 50 + 2000 5 5 5 3
Compound A-5 + (18) 50 + 120 5 5 4 1
Compound A-5 + (19) 50 + 300 5 5 5 1
Compound A-5 + (20) 50 + 80 5 5 5 2
Compound A-5 + (21) 50 + 2000 5 5 5 5
Compound A-5 + (22) 50 + 1720 5 5 5 5
Compound A-5 + (23) 50 + 2000 5 5 5 5
Compound A-5 + (24) 50 + 600 5 5 5 5
Compound A-5 + (25) 50 + 200 5 5 5 5
Compound A-5 + (26) 50 + 60 5 5 5 5
Compound A-5 + (27) 50 + 15 5 5 5 5
Compound A-5 + (28) 50 + 25 5 5 5 4
Compound A-5 + (29) 50 + 25 5 5 5 5
Compound A-5 + (30) 50 + 100 5 5 5 5
Compound A-5 + (31) 50 + 54 5 5 5 5
Compound A-5 + (32) 50 + 150 5 5 5 5
Compound A-5 + (33) 50 + 100 5 5 5 5
Compound A-5 + (34) 50 + 450 5 5 5 1
Compound A-5 + (35) 50 + 250 5 4 5 3
Compound A-5 + (36) 50 + 1000 5 4 4 5
Compound A-5 + (37) 50 + 900 5 5 5 5
Compound A-5 + (38) 50 + 2400 5 5 5 5
Compound A-5 + (39) 50 + 925 5 5 5 5
Compound A-5 + (40) 50 + 900 5 5 4 3
Compound A-6 50 5 5 5 2
Compound A-6 + (1) 50 + 750 5 5 5 4
Compound A-6 + (2) 50 + 300 5 5 5 4
Compound A-6 + (3) 50 + 1200 5 5 5 2
Compound A-6 + (4) 50 + 30 5 5 5 3
Compound A-6 + (5) 50 + 60 5 5 5 3
Compound A-6 + (6) 50 + 100 5 5 5 1
Compound A-6 + (7) 50 + 23 5 5 5 1
Compound A-6 + (8) 50 + 25 5 5 5 3
Compound A-6 + (9) 50 + 35 5 5 5 1
Compound A-6 + (10) 50 + 240 5 5 5 2
Compound A-6 + (11) 50 + 200 5 5 5 5
Compound A-6 + (12) 50 + 100 5 5 5 3
Compound A-6 + (13) 50 + 1200 5 5 5 3
Compound A-6 + (14) 50 + 2000 5 5 5 2
Compound A-6 + (15) 50 + 60 5 5 5 2
Compound A-6 + (16) 50 + 2500 5 5 5 2
Compound A-6 + (17) 50 + 2000 5 5 5 2
Compound A-6 + (18) 50 + 120 5 5 5 3
Compound A-6 + (19) 50 + 300 5 5 5 5
Compound A-6 + (20) 50 + 80 5 5 5 2
Compound A-6 + (21) 50 + 2000 5 5 5 5
Compound A-6 + (22) 50 + 1720 5 5 5 5
Compound A-6 + (23) 50 + 2000 5 5 5 5
Compound A-6 + (24) 50 + 600 5 5 5 5
Compound A-6 + (25) 50 + 200 5 5 5 5
Compound A-6 + (26) 50 + 60 5 5 5 5
Compound A-6 + (27) 50 + 15 5 5 5 5
Compound A-6 + (28) 50 + 25 5 5 5 4
Compound A-6 + (29) 50 + 25 5 5 5 5
Compound A-6 + (30) 50 + 100 5 5 5 5
Compound A-6 + (31) 50 + 54 5 5 5 5
Compound A-6 + (32) 50 + 150 5 5 5 5
Compound A-6 + (33) 50 + 100 5 5 5 5
Compound A-6 + (34) 50 + 450 5 5 5 2
Compound A-6 + (35) 50 + 250 5 5 5 5
Compound A-6 + (36) 50 + 1000 5 5 5 5
Compound A-6 + (37) 50 + 900 5 5 5 5
Compound A-6 + (38) 50 + 2400 5 5 5 5
Compound A-6 + (39) 50 + 925 5 5 5 5
Compound A-6 + (40) 50 + 900 5 5 5 5
Compound A-7 50 4 5 3 0
Compound A-7 + (1) 50 + 750 4 4 4 0
Compound A-7 + (2) 50 + 300 5 5 5 0
Compound A-7 + (3) 50 + 1200 4 5 3 0
Compound A-7 + (4) 50 + 30 4 5 5 0
Compound A-7 + (5) 50 + 60 4 4 5 0
Compound A-7 + (6) 50 + 100 5 5 5 0
Compound A-7 + (7) 50 + 23 5 5 5 0
Compound A-7 + (8) 50 + 25 5 5 5 0
Compound A-7 + (9) 50 + 35 4 5 5 1
Compound A-7 + (10) 50 + 240 5 5 5 4
Compound A-7 + (11) 50 + 200 5 5-5
Compound A-7 + (12) 50 + 100 5 5 4 1
Compound A-7 + (13) 50 + 1200 4 5 5 0
Compound A-7 + (14) 50 + 2000 5 5 5 3
Compound A-7 + (15) 50 + 60 5 5 5 3
Compound A-7 + (16) 50 + 2500 5 5 5 0
Compound A-7 + (17) 50 + 2000 5 5 5 0
Compound A-7 + (18) 50 + 120 5 5 5 0
Compound A-7 + (19) 50 + 300 5 5 5 3
Compound A-7 + (20) 50 + 80 4 5 5 0
Compound A-7 + (21) 50 + 2000 5 5 5 5
Compound A-7 + (22) 50 + 1720 5 5 5 4
Compound A-7 + (23) 50 + 2000 5 5 5 5
Compound A-7 + (24) 50 + 600 5 5 5 5
Compound A-7 + (25) 50 + 200 5 5 5 5
Compound A-7 + (26) 50 + 60 5 5 5 5
Compound A-7 + (27) 50 + 15 5 5 5 5
Compound A-7 + (28) 50 + 25 5 5 5 4
Compound A-7 + (29) 50 + 25 5 5 5 5
Compound A-7 + (30) 50 + 100 5 5 5 5
Compound A-7 + (31) 50 + 54 5-5 5
Compound A-7 + (32) 50 + 150 5 5 5 5
Compound A-7 + (33) 50 + 100 5 5 5 5
Compound A-7 + (34) 50 + 450 4 5-5
Compound A-7 + (35) 50 + 250 5-5 5
Compound A-7 + (36) 50 + 1000 5-5 5
Compound A-7 + (37) 50 + 900 5 5 5 5
Compound A-7 + (38) 50 + 2400 5 5 5 5
Compound A-7 + (39) 50 + 925 5 5 5 5
Compound A-7 + (40) 50 + 900 5-5 4
Compound A-8 50 5 5 5 1
Compound A-8 + (1) 50 + 750 5 5 5 0
Compound A-8 + (2) 50 + 300 5 5-3
Compound A-8 + (3) 50 + 1200 5 5-0
Compound A-8 + (4) 50 + 30 5 5-0
Compound A-8 + (5) 50 + 60 5 5-0
Compound A-8 + (6) 50 + 100 5 5 5 0
Compound A-8 + (7) 50 + 23 5 5 5 0
Compound A-8 + (8) 50 + 25 5 4-0
Compound A-8 + (9) 50 + 35 5 5 4 0
Compound A-8 + (10) 50 + 240 5 5 5 1
Compound A-8 + (11) 50 + 200 5 5-3
Compound A-8 + (12) 50 + 100 5 5 5 0
Compound A-8 + (13) 50 + 1200 5 5 5 0
Compound A-8 + (14) 50 + 2000 5 5 5 3
Compound A-8 + (15) 50 + 60 0 5 5 0
Compound A-8 + (16) 50 + 2500 5 5-0
Compound A-8 + (17) 50 + 2000 5 5-0
Compound A-8 + (18) 50 + 120 5 5 5 0
Compound A-8 + (19) 50 + 300 5 5 5 0
Compound A-8 + (20) 50 + 80 5 5-0
Compound A-8 + (21) 50 + 2000 5 5 5 4
Compound A-8 + (22) 50 + 1720 5 5 5 5
Compound A-8 + (23) 50 + 2000 5 5 5 4
Compound A-8 + (24) 50 + 600 5 5 5 5
Compound A-8 + (25) 50 + 200 5 5-5
Compound A-8 + (26) 50 + 60 5 5 5 5
Compound A-8 + (27) 50 + 15 5 5 5 5
Compound A-8 + (28) 50 + 25 5 5 5 4
Compound A-8 + (29) 50 + 25 5 5-5
Compound A-8 + (30) 50 + 100 5 5 5 5
Compound A-8 + (31) 50 + 54 5 5-5
Compound A-8 + (32) 50 + 150 5 5 5 5
Compound A-8 + (33) 50 + 100 5 5 5 5
Compound A-8 + (34) 50 + 450 5 5 5 5
Compound A-8 + (35) 50 + 250 5 5 5 4
Compound A-8 + (36) 50 + 1000 5 5 5 4
Compound A-8 + (37) 50 + 900 5 5 5 5
Compound A-8 + (38) 50 + 2400 5 5 5 5
Compound A-8 + (39) 50 + 925 5 5 5 5
Compound A-8 + (40) 50 + 900 5 5 5 4
Compound A-9 50 5 4 5 1
Compound A-9 + (1) 50 + 750 5 5 5 1
Compound A-9 + (2) 50 + 300 5 5 5 4
Compound A-9 + (3) 50 + 1200 5 5-0
Compound A-9 + (4) 50 + 30 5 5 5 1
Compound A-9 + (5) 50 + 60 5 5-1
Compound A-9 + (6) 50 + 100 5 4 5 0
Compound A-9 + (7) 50 + 23 5 4 5 0
Compound A-9 + (8) 50 + 25 5 5 5 2
Compound A-9 + (9) 50 + 35 5 5-1
Compound A-9 + (10) 50 + 240 5 5-2
Compound A-9 + (11) 50 + 200 5 5 5 3
Compound A-9 + (12) 50 + 100 5 5 5 3
Compound A-9 + (13) 50 + 1200 5 5 5 1
Compound A-9 + (14) 50 + 2000 5 5 5 4
Compound A-9 + (15) 50 + 60 2 3 5 0
Compound A-9 + (16) 50 + 2500 5 5 5 2
Compound A-9 + (17) 50 + 2000 5 5-1
Compound A-9 + (18) 50 + 120 5 5 5 0
Compound A-9 + (19) 50 + 300 5 5 5 3
Compound A-9 + (20) 50 + 80 5 5 5 1
Compound A-9 + (21) 50 + 2000 5 5 5 4
Compound A-9 + (22) 50 + 1720 5 5-4
Compound A-9 + (23) 50 + 2000 5 5 5 5
Compound A-9 + (24) 50 + 600 5 5 5 5
Compound A-9 + (25) 50 + 200 5 5 5 5
Compound A-9 + (26) 50 + 60 5 5 5 5
Compound A-9 + (27) 50 + 15 5 5 5 4
Compound A-9 + (28) 50 + 25 5 5-5
Compound A-9 + (29) 50 + 25 5 5 5 5
Compound A-9 + (30) 50 + 100 5 5 5 5
Compound A-9 + (31) 50 + 54 5 5 5 5
Compound A-9 + (32) 50 + 150 5 5 5 5
Compound A-9 + (33) 50 + 100 5 5 5 5
Compound A-9 + (34) 50 + 450 2 5 5 3
Compound A-9 + (35) 50 + 250 4 5-5
Compound A-9 + (36) 50 + 1000 5 5 5 5
Compound A-9 + (37) 50 + 900 5 5 5 5
Compound A-9 + (38) 50 + 2400 5 5 5 5
Compound A-9 + (39) 50 + 925 5 5 5 3
Compound A-9 + (40) 50 + 900 5 5 5 2
Compound A-10 50 4 4 5 3
Compound A-10 + (1) 50 + 750 5 5-4
Compound A-10 + (2) 50 + 300 5 5 5 4
Compound A-10 + (3) 50 + 1200 5 5 4 2
Compound A-10 + (4) 50 + 30 5 5 5 4
Compound A-10 + (5) 50 + 60 5 5 5 4
Compound A-10 + (6) 50 + 100 5 5 5 4
Compound A-10 + (7) 50 + 23 5 5 5 5
Compound A-10 + (8) 50 + 25 5 5 5 4
Compound A-10 + (9) 50 + 35 5 5 5 5
Compound A-10 + (10) 50 + 240 5 5 5 4
Compound A-10 + (11) 50 + 200 5 5 5 5
Compound A-10 + (12) 50 + 100 5 5 5 4
Compound A-10 + (13) 50 + 1200 5 5 5 4
Compound A-10 + (14) 50 + 2000 5 5 5 5
Compound A-10 + (15) 50 + 60 4 5 5 4
Compound A-10 + (16) 50 + 2500 5 5 5 5
Compound A-10 + (17) 50 + 2000 5 5 5 4
Compound A-10 + (18) 50 + 120 5 5 5 4
Compound A-10 + (19) 50 + 300 5 5 5 4
Compound A-10 + (20) 50 + 80 5 5 5 4
Compound A-10 + (21) 50 + 2000 5 5 5 5
Compound A-10 + (22) 50 + 1720 5 5 5 4
Compound A-10 + (23) 50 + 2000 5 5 5 5
Compound A-10 + (24) 50 + 600 5 5-5
Compound A-10 + (25) 50 + 200 5 5 5 5
Compound A-10 + (26) 50 + 60 5 5 5 5
Compound A-10 + (27) 50 + 15 5 5 5 5
Compound A-10 + (28) 50 + 25 5 5 5 4
Compound A-10 + (29) 50 + 25 5 5 5 5
Compound A-10 + (30) 50 + 100 5 5 5 5
Compound A-10 + (31) 50 + 54 5 5 5 5
Compound A-10 + (32) 50 + 150 5 5 5 5
Compound A-10 + (33) 50 + 100 5 5 5 5
Compound A-10 + (34) 50 + 450 5 5 5 5
Compound A-10 + (35) 50 + 250 5 5 5 5
Compound A-10 + (36) 50 + 1000 5 5--
Compound A-10 + (37) 50 + 900 5 5 5 5
Compound A-10 + (38) 50 + 2400 5 5 5 5
Compound A-10 + (39) 50 + 925 5 5 5 5
Compound A-10 + (40) 50 + 900 5 5 5 5
Compound A-11 50 5 5-3
Compound A-11 + (1) 50 + 750 5 5 5 5
Compound A-11 + (2) 50 + 300 5 5 5 4
Compound A-11 + (3) 50 + 1200 5 5-5
Compound A-11 + (4) 50 + 30 5 5 5 4
Compound A-11 + (5) 50 + 60 5 5 5 5
Compound A-11 + (6) 50 + 100 5 5 5 4
Compound A-11 + (7) 50 + 23 5 5-5
Compound A-11 + (8) 50 + 25 5 5 4 5
Compound A-11 + (9) 50 + 35 5 5-4
Compound A-11 + (10) 50 + 240 5 5 5 5
Compound A-11 + (11) 50 + 200 5 5-4
Compound A-11 + (12) 50 + 100 5 5 5 5
Compound A-11 + (13) 50 + 1200 5 5-5
Compound A-11 + (14) 50 + 2000 5 5 5 5
Compound A-11 + (15) 50 + 60 5 5 5 4
Compound A-11 + (16) 50 + 2500 5 5-5
Compound A-11 + (17) 50 + 2000 5 5 5 4
Compound A-11 + (18) 50 + 120 5 5 5 5
Compound A-11 + (19) 50 + 300 5 5-5
Compound A-11 + (20) 50 + 80 5 5 5 5
Compound A-11 + (21) 50 + 2000 5 5 5 5
Compound A-11 + (22) 50 + 1720 5 5 5 5
Compound A-11 + (23) 50 + 2000 5 5 5 5
Compound A-11 + (24) 50 + 600 5 5 5 5
Compound A-11 + (25) 50 + 200 5-5 5
Compound A-11 + (26) 50 + 60 5 5 5 5
Compound A-11 + (27) 50 + 15 5 5 5 5
Compound A-11 + (28) 50 + 25 5 5 5 5
Compound A-11 + (29) 50 + 25 5 5 5 5
Compound A-11 + (30) 50 + 100 5-5 5
Compound A-11 + (31) 50 + 54 5 5 5 5
Compound A-11 + (32) 50 + 150 5 5 5 5
Compound A-11 + (33) 50 + 100 5 5 5 5
Compound A-11 + (34) 50 + 450 5 5 5 4
Compound A-11 + (35) 50 + 250 5-5 5
Compound A-11 + (36) 50 + 1000 5 5 5 5
Compound A-11 + (37) 50 + 900 5 5 5 5
Compound A-11 + (38) 50 + 2400 5 5 5 5
Compound A-11 + (39) 50 + 925 5 5 5 5
Compound A-11 + (40) 50 + 900 5 5 5 5
Compound A-12 50 5 5 5 0
Compound A-12 + (1) 50 + 750 5 5 5 3
Compound A-12 + (2) 50 + 300 5 5 5 5
Compound A-12 + (3) 50 + 1200 5 5 5 3
Compound A-12 + (4) 50 + 30 5 5 5 3
Compound A-12 + (5) 50 + 60 4 5 5 3
Compound A-12 + (6) 50 + 100 5 5 5 0
Compound A-12 + (7) 50 + 23 5 5 5 0
Compound A-12 + (8) 50 + 25 5 5 5 2
Compound A-12 + (9) 50 + 35 5 5 5 1
Compound A-12 (10) 50 + 240 5 5 5 4
Compound A-12 + (11) 50 + 200 5 5 5 5
Compound A-12 + (12) 50 + 100 5 5 5 0
Compound A-12 + (13) 50 + 1200 5 5 5 5
Compound A-12 + (14) 50 + 2000 5 5 5 4
Compound A-12 + (15) 50 + 60 5 5 5 1
Compound A-12 (16) 50 + 2500 5 5 5 0
Compound A-12 + (17) 50 + 2000 5 5 5 3
Compound A-12 + (18) 50 + 120 5 5 5 0
Compound A-12 (19) 50 + 300 5 5 5 5
Compound A-12 (20) 50 + 80 5 5 5 3
Compound A-12 + (21) 50 + 2000 5 5 5 5
Compound A-12 + (22) 50 + 1720 5 5 5 5
Compound A-12 + (23) 50 + 2000 5 5 5 5
Compound A-12 (24) 50 + 600 5 5 5 5
Compound A-12 (25) 50 + 200 5 5 5 5
Compound A-12 (26) 50 + 60 5 5 5 5
Compound A-12 + (27) 50 + 15 5 5 5 5
Compound A-12 + (28) 50 + 25 5 5 5 5
Compound A-12 (29) 50 + 25 5 5 5 5
Compound A-12 (30) 50 + 100 5 5 5 5
Compound A-12 (31) 50 + 54 5 5 5 5
Compound A-12 + (32) 50 + 150 5 5 5 5
Compound A-12 (33) 50 + 100 5 5 5 5
Compound A-12 + (34) 50 + 450 5 5 5 5
Compound A-12 (35) 50 + 250 5 5 5 4
Compound A-12 + (36) 50 + 1000 5 5 5 5
Compound A-12 (37) 50 + 900 5 5 5 5
Compound A-12 (38) 50 + 2400 5 5 5 5
Compound A-12 (39) 50 + 925 5 5 5 5
Compound A-12 (40) 50 + 900 5 5 5 4
――――――――――――――――――――――――――――――――――――――――
[Test Example 2] Herbicidal effect test on upland field weeds by foliar treatment A sterilized piled soil was placed in a plastic box 21 cm long, 13 cm wide and 7 cm deep. Spotted seeds of barnyard beetle, green crocodile, blue-headed dragonfly, ibis, white-leaf and corn were each sown in the soil. After covering the seeded soil to a height of about 1.5 cm, plants were grown in a greenhouse at 25 to 30 ° C. After growing for 10 days, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dosage, and uniformly treated with a small spray on the foliage. Two weeks after the drug treatment, the influence on various plants was investigated according to the criteria of Test Example 1. The results are shown in Table 6.

Regarding the description in Table 6, the description in the “compound” column and the “treatment drug amount (g / ha)” column has the same meaning as described above, and the symbols have the following meanings.
A: Bark beetle, B: Enocologosa, C: Blue-headed toe, D: Ichibi, E: Shiroza, F: Corn [Table 6]
―――――――――――――――――――――――――――――――――――――
Compound Treatment dose ABCD EF
(g / ha)
―――――――――――――――――――――――――――――――――――――
Compound (1) 750 0 0 0 0 0 0
Compound (2) 300 4 2 0 0 0 0
Compound (3) 1200 1 3 0 0 0 0
Compound (4) 30 0 2 5 5 3 4
Compound (5) 60 2 2 5 5 4 4
Compound (6) 100 4 3 5 5 4 4
Compound (7) 23 4 5 5 5 4 3
Compound (8) 25 3 5 5 4 4 4
Compound (9) 35 0 2 5 5 5 0
Compound (10) 240 4 4 5 5 5 0
Compound (11) 200 5 5 5 5 5 1
Compound (12) 100 4 4 2 2 4 0
Compound (13) 1200 2 3 1 0 3 0
Compound (14) 2000 1 0 0 0 0 0
Compound (15) 60 4 3 5 4 4 0
Compound (16) 2500 5 5 5 5 5 2
Compound (17) 2000 0 0 5 5 5 0
Compound (18) 120 5 5 0 0 0 5
Compound (19) 300 3 4 0 0 2 0
Compound (20) 80 4 3 3 3 1 0
Compound (21) 2000 4 4 2 0 0 0
Compound (22) 1720 4 4 0 0 0 0
Compound (23) 2000 5 4 2 0 1 0
Compound (24) 600 4 4 1 0 1 0
Compound (25) 200 4 4 4 4 4 0
Compound (26) 60 5 5 5 4 4 0
Compound (27) 15 5 5 5 5 5 0
Compound (28) 25 5 5 5 5 4 4
Compound (29) 25 4 4 5 5 5 1
Compound (30) 100 5 4 5 5 5 0
Compound (31) 54 5 5 4 4 5 0
Compound (32) 150 5 3 5 5 5 0
Compound (33) 100 5 5 5 4 4 3
Compound (34) 450 3 3 2 4 5 0
Compound (35) 250 0 0 5 5 5 0
Compound (36) 1000 0 3 5 5 5 2
Compound (37) 900 0 5 5 3 3 0
Compound (38) 2400 5 5 5 5 5 5
Compound (39) 925 5 5 5 5 5 5
Compound (40) 900 4 4 2 4 3 0
Compound A-1 50 5 5 4 4 5 0
Compound A-1 + (1) 50 + 750 5 5 4 4 5 0
Compound A-1 + (2) 50 + 300 5 5 5 5 5 0
Compound A-1 + (3) 50 + 1200 5 5 5 5 5 0
Compound A-1 + (4) 50 + 30 5 5 5 5 5 5
Compound A-1 + (5) 50 + 60 5 5 5 5 5 3
Compound A-1 + (6) 50 + 100 5 5 5 5 5 4
Compound A-1 + (7) 50 + 23 5 5 5 5 5 3
Compound A-1 + (8) 50 + 25 5 5 5 5 5 4
Compound A-1 + (9) 50 + 35 5 5 5 5 5 0
Compound A-1 + (10) 50 + 240 5 5 5 5 5 0
Compound A-1 + (11) 50 + 200 5 5 5 5 5 1
Compound A-1 + (12) 50 + 100 5 5 5 5 5 0
Compound A-1 + (13) 50 + 1200 5 5 4 4 5 0
Compound A-1 + (14) 50 + 2000 5 5 4 4 5 0
Compound A-1 + (15) 50 + 60 5 5 5 5 5 0
Compound A-1 + (16) 50 + 2500 5 5 5 5 5 0
Compound A-1 + (17) 50 + 2000 5 5 5 5 5 0
Compound A-1 + (18) 50 + 120 5 5 5 4 5 5
Compound A-1 + (19) 50 + 300 5 5 5 5 5 0
Compound A-1 + (20) 50 + 80 5 5 4 4 5 0
Compound A-1 + (21) 50 + 2000 5 5 4 4 5 0
Compound A-1 + (22) 50 + 1720 5 5 4 4 4 0
Compound A-1 + (23) 50 + 2000 5 5 4 4 5 0
Compound A-1 + (24) 50 + 600 5 5 4 4 5 0
Compound A-1 + (25) 50 + 200 5 5 5 5 5 0
Compound A-1 + (26) 50 + 60 5 5 5 4 4 0
Compound A-1 + (27) 50 + 15 5 5 5 5 5 0
Compound A-1 + (28) 50 + 25 5 5 5 5 5 4
Compound A-1 + (29) 50 + 25 5 5 5 5 5 1
Compound A-1 + (30) 50 + 100 5 5 5 5 5 0
Compound A-1 + (31) 50 + 54 5 5 5 5 5 0
Compound A-1 + (32) 50 + 150 5 5 5 5 5 0
Compound A-1 + (33) 50 + 100 5 5 4 5 5 3
Compound A-1 + (34) 50 + 450 5 5 4 4 5 0
Compound A-1 + (35) 50 + 250 5 5 5 5 5 0
Compound A-1 + (36) 50 + 1000 5 5 5 5 5 3
Compound A-1 + (37) 50 + 900 5 5 5 5 5 0
Compound A-1 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-1 + (39) 50 + 925 5 5 5 5 5 5
Compound A-1 + (40) 50 + 900 5 5 5 5 5 0
Compound A-2 50 5 4 5 5 5 0
Compound A-2 + (1) 50 + 750 5 4 5 5 5 0
Compound A-2 + (2) 50 + 300 5 5 5 5 5 0
Compound A-2 + (3) 50 + 1200 5 5 5 5 5 0
Compound A-2 + (4) 50 + 30 5 4 5 5 5 5
Compound A-2 + (5) 50 + 60 5 4 5 5 5 0
Compound A-2 + (6) 50 + 100 5 4 5 5 5 0
Compound A-2 + (7) 50 + 23 5 4 5 5 5 0
Compound A-2 + (8) 50 + 25 5 5 5 5 5 1
Compound A-2 + (9) 50 + 35 5 5 5 5 5 0
Compound A-2 + (10) 50 + 240 5 5 5 5 5 3
Compound A-2 + (11) 50 + 200 5 5 5 5 5 4
Compound A-2 + (12) 50 + 100 5 5 5 5 5 0
Compound A-2 + (13) 50 + 1200 5 5 5 5 5 0
Compound A-2 + (14) 50 + 2000 5 4 5 5 5 0
Compound A-2 + (15) 50 + 60 5 5 5 5 5 0
Compound A-2 + (16) 50 + 2500 5 5 5 5 5 0
Compound A-2 + (17) 50 + 2000 5 4 5 5 5 0
Compound A-2 + (18) 50 + 120 5 5 5 5 5 5
Compound A-2 + (19) 50 + 300 5 4 5 5 5 0
Compound A-2 + (20) 50 + 80 5 4 5 5 5 0
Compound A-2 + (21) 50 + 2000 5 5 5 5 5 0
Compound A-2 + (22) 50 + 1720 5 5 5 5 5 0
Compound A-2 + (23) 50 + 2000 5 5 5 5 5 0
Compound A-2 + (24) 50 + 600 5 5 5 5 5 0
Compound A-2 + (25) 50 + 200 5 5 5 5 5 0
Compound A-2 + (26) 50 + 60 5 5 5 5 5 0
Compound A-2 + (27) 50 + 15 5 5 5 5 5 1
Compound A-2 + (28) 50 + 25 5 5 5 5 5 2
Compound A-2 + (29) 50 + 25 5 5 5 5 5 0
Compound A-2 + (30) 50 + 100 5 4 5 5 5 0
Compound A-2 + (31) 50 + 54 5 5 5 5 5 0
Compound A-2 + (32) 50 + 150 5 5 5 5 5 1
Compound A-2 + (33) 50 + 100 5 5 5 5 5 3
Compound A-2 + (34) 50 + 450 5 5 5 5 5 0
Compound A-2 + (35) 50 + 250 5 5 5 5 5 0
Compound A-2 + (36) 50 + 1000 5 5 5 5 5 2
Compound A-2 + (37) 50 + 900 5 5 5 5 5 1
Compound A-2 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-2 + (39) 50 + 925 5 5 5 5 5 5
Compound A-2 + (40) 50 + 900 5 5 5 5 5 0
Compound A-3 50 5 4 5 4 5 3
Compound A-3 + (1) 50 + 750 5 5 5 4 5 3
Compound A-3 + (2) 50 + 300 5 4 5 4 5 3
Compound A-3 + (3) 50 + 1200 5 4 5 4 5 3
Compound A-3 + (4) 50 + 30 5 4 5 5 5 4
Compound A-3 + (5) 50 + 60 5 4 5 5 5 2
Compound A-3 + (6) 50 + 100 5 4 5 5 5 3
Compound A-3 + (7) 50 + 23 5 4 5 5 5 3
Compound A-3 + (8) 50 + 25 5 5 5 5 5 3
Compound A-3 + (9) 50 + 35 5 5 5 5 5 1
Compound A-3 + (10) 50 + 240 5 4 5 5 5 1
Compound A-3 + (11) 50 + 200 5 5 5 5 5 1
Compound A-3 + (12) 50 + 100 5 5 5 5 5 2
Compound A-3 + (13) 50 + 1200 5 5 5 5 5 2
Compound A-3 + (14) 50 + 2000 5 4 5 4 5 3
Compound A-3 + (15) 50 + 60 5 5 5 5 5 1
Compound A-3 + (16) 50 + 2500 5 5 5 5 5 1
Compound A-3 + (17) 50 + 2000 5 5 5 5 5 0
Compound A-3 + (18) 50 + 120 5 5 5 5 5 3
Compound A-3 + (19) 50 + 300 5 5 5 5 5 1
Compound A-3 + (20) 50 + 80 5 5 5 5 5 3
Compound A-3 + (21) 50 + 2000 5 5 5 4 5 3
Compound A-3 + (22) 50 + 1720 5 5 5 4 5 3
Compound A-3 + (23) 50 + 2000 5 5 5 4 5 3
Compound A-3 + (24) 50 + 600 5 5 5 5 5 3
Compound A-3 + (25) 50 + 200 5 5 5 5 5 3
Compound A-3 + (26) 50 + 60 5 5 5 4 5 3
Compound A-3 + (27) 50 + 15 5 5 5 5 5 4
Compound A-3 + (28) 50 + 25 5 5 5 5 5 4
Compound A-3 + (29) 50 + 25 5 4 5 5 5 1
Compound A-3 + (30) 50 + 100 5 4 5 5 5 3
Compound A-3 + (31) 50 + 54 5 5 5 5 5 3
Compound A-3 + (32) 50 + 150 5 4 5 5 5 3
Compound A-3 + (33) 50 + 100 5 5 5 5 5 3
Compound A-3 + (34) 50 + 450 5 4 5 5 5 3
Compound A-3 + (35) 50 + 250 5 5 5 5 5 3
Compound A-3 + (36) 50 + 1000 5 5 5 5 5 3
Compound A-3 + (37) 50 + 900 5 5 5 5 5 3
Compound A-3 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-3 + (39) 50 + 925 5 5 5 5 5 5
Compound A-3 + (40) 50 + 900 5 5 5 4 5 4
Compound A-4 50 4 5 4 4 5 0
Compound A-4 + (1) 50 + 750 5 5 4 4 5 2
Compound A-4 + (2) 50 + 300 4 4 4 4 5 0
Compound A-4 + (3) 50 + 1200 4 5 4 4 5 0
Compound A-4 + (4) 50 + 30 4 4 4 5 5 4
Compound A-4 + (5) 50 + 60 4 4 5 5 5 0
Compound A-4 + (6) 50 + 100 3 4 4 5 5 4
Compound A-4 + (7) 50 + 23 4 4 5 5 5 0
Compound A-4 + (8) 50 + 25 4 5 4 5 5 1
Compound A-4 + (9) 50 + 35 5 5 5 5 5 0
Compound A-4 + (10) 50 + 240 5 5 5 5 5 1
Compound A-4 + (11) 50 + 200 5 5 5 5 5 0
Compound A-4 + (12) 50 + 100 4 5 4 5 5 1
Compound A-4 + (13) 50 + 1200 5 5 4 5 5 0
Compound A-4 + (14) 50 + 2000 4 4 4 4 5 1
Compound A-4 + (15) 50 + 60 5 5 5 5 5 0
Compound A-4 + (16) 50 + 2500 5 5 5 5 5 1
Compound A-4 + (17) 50 + 2000 5 5 5 5 5 0
Compound A-4 + (18) 50 + 120 5 5 4 4 5 4
Compound A-4 + (19) 50 + 300 4 5 4 5 5 0
Compound A-4 + (20) 50 + 80 4 5 4 5 5 1
Compound A-4 + (21) 50 + 2000 5 5 5 4 5 3
Compound A-4 + (22) 50 + 1720 5 5 5 5 5 2
Compound A-4 + (23) 50 + 2000 5 5 5 4 5 2
Compound A-4 + (24) 50 + 600 5 5 5 4 5 3
Compound A-4 + (25) 50 + 200 5 5 5 5 5 2
Compound A-4 + (26) 50 + 60 5 5 5 4 5 1
Compound A-4 + (27) 50 + 15 5 5 5 5 5 2
Compound A-4 + (28) 50 + 25 5 5 5 5 5 2
Compound A-4 + (29) 50 + 25 5 5 5 5 5 1
Compound A-4 + (30) 50 + 100 4 4 5 5 5 2
Compound A-4 + (31) 50 + 54 5 5 5 5 5 2
Compound A-4 + (32) 50 + 150 5 5 5 4 5 3
Compound A-4 + (33) 50 + 100 5 5 5 5 5 4
Compound A-4 + (34) 50 + 450 5 5 5 4 5 2
Compound A-4 + (35) 50 + 250 4 4 5 5 5 1
Compound A-4 + (36) 50 + 1000 4 5 5 5 5 2
Compound A-4 + (37) 50 + 900 5 5 5 5 5 2
Compound A-4 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-4 + (39) 50 + 925 5 5 5 5 5 5
Compound A-4 + (40) 50 + 900 5 5 5 5 5 3
Compound A-5 50 4 4 4 4 5 0
Compound A-5 + (1) 50 + 750 5 5 5 5 5 0
Compound A-5 + (2) 50 + 300 5 4 5 5 5 0
Compound A-5 + (3) 50 + 1200 4 4 5 5 5 0
Compound A-5 + (4) 50 + 30 4 4 5 5 5 4
Compound A-5 + (5) 50 + 60 4 4 5 5 5 0
Compound A-5 + (6) 50 + 100 4 3 5 5 5 4
Compound A-5 + (7) 50 + 23 5 4 5 5 5 0
Compound A-5 + (8) 50 + 25 4 5 5 5 5 4
Compound A-5 + (9) 50 + 35 4 4 5 5 5 1
Compound A-5 + (10) 50 + 240 5 5 5 5 5 0
Compound A-5 + (11) 50 + 200 5 5 5 5 5 3
Compound A-5 + (12) 50 + 100 5 5 4 4 5 1
Compound A-5 + (13) 50 + 1200 4 4 5 5 5 0
Compound A-5 + (14) 50 + 2000 5 4 5 4 5 0
Compound A-5 + (15) 50 + 60 5 5 5 5 5 0
Compound A-5 + (16) 50 + 2500 5 5 5 5 5 3
Compound A-5 + (17) 50 + 2000 5 5 5 5 5 0
Compound A-5 + (18) 50 + 120 5 5 4 4 5 4
Compound A-5 + (19) 50 + 300 5 4 4 4 5 0
Compound A-5 + (20) 50 + 80 5 5 4 4 5 0
Compound A-5 + (21) 50 + 2000 5 5 5 4 5 1
Compound A-5 + (22) 50 + 1720 5 5 5 4 5 1
Compound A-5 + (23) 50 + 2000 5 4 4 4 5 0
Compound A-5 + (24) 50 + 600 5 4 4 4 5 0
Compound A-5 + (25) 50 + 200 5 5 5 5 5 2
Compound A-5 + (26) 50 + 60 5 5 5 4 5 1
Compound A-5 + (27) 50 + 15 5 5 5 5 5 0
Compound A-5 + (28) 50 + 25 5 5 5 5 5 0
Compound A-5 + (29) 50 + 25 5 5 5 5 5 3
Compound A-5 + (30) 50 + 100 5 5 5 5 5 0
Compound A-5 + (31) 50 + 54 5 5 5 5 5 1
Compound A-5 + (32) 50 + 150 5 5 5 5 5 1
Compound A-5 + (33) 50 + 100 5 5 5 5 5 3
Compound A-5 + (34) 50 + 450 5 4 5 5 5 1
Compound A-5 + (35) 50 + 250 5 4 5 5 5 1
Compound A-5 + (36) 50 + 1000 4 4 5 5 5 2
Compound A-5 + (37) 50 + 900 5 5 5 5 5 1
Compound A-5 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-5 + (39) 50 + 925 5 5 5 5 5 5
Compound A-5 + (40) 50 + 900 5 5 4 4 5 3
Compound A-6 50 4 4 4 4 5 0
Compound A-6 + (1) 50 + 750 5 4 4 4 5 0
Compound A-6 + (2) 50 + 300 5 5 5 5 5 0
Compound A-6 + (3) 50 + 1200 5 5 5 5 5 2
Compound A-6 + (4) 50 + 30 5 4 5 5 5 5
Compound A-6 + (5) 50 + 60 5 5 5 5 5 0
Compound A-6 + (6) 50 + 100 4 4 5 5 5 4
Compound A-6 + (7) 50 + 23 5 4 5 5 5 2
Compound A-6 + (8) 50 + 25 5 5 5 5 5 3
Compound A-6 + (9) 50 + 35 5 5 5 5 5 0
Compound A-6 + (10) 50 + 240 5 5 5 5 5 2
Compound A-6 + (11) 50 + 200 5 5 5 5 5 4
Compound A-6 + (12) 50 + 100 5 4 5 4 5 0
Compound A-6 + (13) 50 + 1200 5 5 5 5 5 0
Compound A-6 + (14) 50 + 2000 5 4 4 4 5 0
Compound A-6 + (15) 50 + 60 5 5 5 5 5 3
Compound A-6 + (16) 50 + 2500 5 5 5 5 5 1
Compound A-6 + (17) 50 + 2000 5 4 5 5 5 0
Compound A-6 + (18) 50 + 120 5 5 5 4 5 4
Compound A-6 + (19) 50 + 300 5 5 5 4 5 0
Compound A-6 + (20) 50 + 80 5 5 4 4 5 0
Compound A-6 + (21) 50 + 2000 5 5 5 5 5 0
Compound A-6 + (22) 50 + 1720 5 5 5 5 5 1
Compound A-6 + (23) 50 + 2000 5 5 5 4 5 0
Compound A-6 + (24) 50 + 600 5 5 5 5 5 0
Compound A-6 + (25) 50 + 200 5 5 5 5 5 0
Compound A-6 + (26) 50 + 60 5 5 5 4 5 0
Compound A-6 + (27) 50 + 15 5 5 5 5 5 0
Compound A-6 + (28) 50 + 25 5 5 5 5 5 2
Compound A-6 + (29) 50 + 25 5 5 5 5 5 2
Compound A-6 + (30) 50 + 100 5 5 5 5 5 0
Compound A-6 + (31) 50 + 54 5 5 5 5 5 0
Compound A-6 + (32) 50 + 150 5 5 5 5 5 1
Compound A-6 + (33) 50 + 100 5 5 5 5 5 3
Compound A-6 + (34) 50 + 450 5 5 5 5 5 0
Compound A-6 + (35) 50 + 250 5 5 5 5 5 0
Compound A-6 + (36) 50 + 1000 5 5 5 5 5 2
Compound A-6 + (37) 50 + 900 5 5 5 5 5 0
Compound A-6 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-6 + (39) 50 + 925 5 5 5 5 5 5
Compound A-6 + (40) 50 + 900 5 5 5 5 5 0
Compound A-7 50 4 4 3 3 5 1
Compound A-7 + (1) 50 + 750 4 3 3 4-1
Compound A-7 + (2) 50 + 300 4 3 2 3-1
Compound A-7 + (3) 50 + 1200 4 4 3 2 5 1
Compound A-7 + (4) 50 + 30 4 2 3-4 1
Compound A-7 + (5) 50 + 60 4 3 2 5-1
Compound A-7 + (6) 50 + 100 4 2 3 5-3
Compound A-7 + (7) 50 + 23 4 3-4-1
Compound A-7 + (8) 50 + 25 4 5 3 4-2
Compound A-7 + (9) 50 + 35 4 4 5 5 5 2
Compound A-7 + (10) 50 + 240 5 5-5-3
Compound A-7 + (11) 50 + 200 5 5 5 5-3
Compound A-7 + (12) 50 + 100 5 5-4-0
Compound A-7 + (13) 50 + 1200 4 3 1 3-1
Compound A-7 + (14) 50 + 2000 4 3-0-2
Compound A-7 + (15) 50 + 60 5 5 5 5 5 1
Compound A-7 + (16) 50 + 60 5 5 5 5 5 3
Compound A-7 + (17) 50 + 2500 4 3-5 5 1
Compound A-7 + (18) 50 + 2000 5 5-0-5
Compound A-7 + (19) 50 + 120 5 4-4-0
Compound A-7 + (20) 50 + 300 5 5 1 3 4 0
Compound A-7 + (21) 50 + 80 4 3 1 1 4 2
Compound A-7 + (22) 50 + 2000 5 5-3-1
Compound A-7 + (23) 50 + 1720 5 5--5 0
Compound A-7 + (24) 50 + 2000 5 5 3 3 5 1
Compound A-7 + (25) 50 + 600 5 5-5-0
Compound A-7 + (26) 50 + 200 5 5-4-1
Compound A-7 + (27) 50 + 60 5 5-5-1
Compound A-7 + (28) 50 + 15 5 5 5 5-1
Compound A-7 + (29) 50 + 25 5 5 5 5 5 2
Compound A-7 + (30) 50 + 25 5 5 4 4 5 0
Compound A-7 + (31) 50 + 100 5 5 5 4-1
Compound A-7 + (32) 50 + 54 5 4 5 5 5 0
Compound A-7 + (33) 50 + 150 5 5 4 4 4 3
Compound A-7 + (34) 50 + 100 5 4 5 4 5 1
Compound A-7 + (35) 50 + 450 4 4 5 5-1
Compound A-7 + (36) 50 + 250 4 5 5 5 5 1
Compound A-7 + (37) 50 + 1000 5 5 5 5 5 1
Compound A-7 + (38) 50 + 900 5 5 5 5 5 5
Compound A-7 + (39) 50 + 2400 5 5 5 5 5 3
Compound A-7 + (40) 50 + 925 5 5 4 4 5 2
Compound A-8 50 5 4-4-1
Compound A-8 + (1) 50 + 750 5 5-5-1
Compound A-8 + (2) 50 + 300 5 5-5-1
Compound A-8 + (3) 50 + 1200 5 5-4-2
Compound A-8 + (4) 50 + 30 5 3-5-5
Compound A-8 + (5) 50 + 60 5 4-5-0
Compound A-8 + (6) 50 + 100 5 4-5-3
Compound A-8 + (7) 50 + 23 5 4-5-2
Compound A-8 + (8) 50 + 25 5 5-5-3
Compound A-8 + (9) 50 + 35 5 5-5-1
Compound A-8 + (10) 50 + 240 5 5-5-2
Compound A-8 + (11) 50 + 200 5 5-5-1
Compound A-8 + (12) 50 + 100 5 5-5-0
Compound A-8 + (13) 50 + 1200 5 5-5-2
Compound A-8 + (14) 50 + 2000 5 5-5-2
Compound A-8 + (15) 50 + 60 4 2-5-0
Compound A-8 + (16) 50 + 2500 5 5-5-3
Compound A-8 + (17) 50 + 2000 5 4-5-1
Compound A-8 + (18) 50 + 120 5 5-5-5
Compound A-8 + (19) 50 + 300 5 5-5-3
Compound A-8 + (20) 50 + 80 5 5-5-2
Compound A-8 + (21) 50 + 2000 5 5 5 4 5 4
Compound A-8 + (22) 50 + 1720 5 5 5 4 5 0
Compound A-8 + (23) 50 + 2000 5 5 5 4 5 2
Compound A-8 + (24) 50 + 600 5 5 5 5 5 3
Compound A-8 + (25) 50 + 200 5 5 5 5 5 3
Compound A-8 + (26) 50 + 60 5 5 5 5 5 4
Compound A-8 + (27) 50 + 15 5 5 5 5 5 3
Compound A-8 + (28) 50 + 25 5 5 5 5 5 3
Compound A-8 + (29) 50 + 25 5 5 5 5 5 4
Compound A-8 + (30) 50 + 100 5 5 5 5 5 3
Compound A-8 + (31) 50 + 54 5 5 5 4 5 2
Compound A-8 + (32) 50 + 150 5 4 5 5 5 1
Compound A-8 + (33) 50 + 100 5 5 5 5 5 3
Compound A-8 + (34) 50 + 450 5 5 5 5 5 3
Compound A-8 + (35) 50 + 250 5 5 5 5 5 2
Compound A-8 + (36) 50 + 1000 4 5 5 5 5 2
Compound A-8 + (37) 50 + 900 5 5 5 5 5 1
Compound A-8 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-8 + (39) 50 + 925 5 5 5 5 5 5
Compound A-8 + (40) 50 + 900 5 5 5 5 5 4
Compound A-9 50 5 4-5-0
Compound A-9 + (1) 50 + 750 5 3-5-0
Compound A-9 + (2) 50 + 300 5 4-4-0
Compound A-9 + (3) 50 + 1200 5 4-5-0
Compound A-9 + (4) 50 + 30 5 2-5-5
Compound A-9 + (5) 50 + 60 5 2-5-0
Compound A-9 + (6) 50 + 100 4 3 5 5-3
Compound A-9 + (7) 50 + 23 5 4-5-0
Compound A-9 + (8) 50 + 25 5 5-5-2
Compound A-9 + (9) 50 + 35 5 4-5-0
Compound A-9 + (10) 50 + 240 5 5-5-1
Compound A-9 + (11) 50 + 200 5 5-5-1
Compound A-9 + (12) 50 + 100 5 5-4-0
Compound A-9 + (13) 50 + 1200 5 4-4 5 0
Compound A-9 + (14) 50 + 2000 5 5-4-0
Compound A-9 + (15) 50 + 60 5 3-5-0
Compound A-9 + (16) 50 + 2500 5 5-5-3
Compound A-9 + (17) 50 + 2000 5 4-5-0
Compound A-9 + (18) 50 + 120 5 5-4-5
Compound A-9 + (19) 50 + 300 5 5-5-0
Compound A-9 + (20) 50 + 80 5 5 4 5 4 0
Compound A-9 + (21) 50 + 2000 5 5 5 4 5 0
Compound A-9 + (22) 50 + 1720 5 5 5 4 5 0
Compound A-9 + (23) 50 + 2000 5 5 5 4 5 1
Compound A-9 + (24) 50 + 600 5 5 5 5 5 1
Compound A-9 + (25) 50 + 200 5 5 5 5 5 0
Compound A-9 + (26) 50 + 60 5 5 5 5 5 0
Compound A-9 + (27) 50 + 15 5 5 5 5 5 0
Compound A-9 + (28) 50 + 25 5 5 5 5 5 1
Compound A-9 + (29) 50 + 25 5 5 5 5 5 2
Compound A-9 + (30) 50 + 100 5 5 5 5 5 0
Compound A-9 + (31) 50 + 54 5 5 5 5 5 0
Compound A-9 + (32) 50 + 150 5 5 5 5 5 0
Compound A-9 + (33) 50 + 100 5 5 5 5 5 3
Compound A-9 + (34) 50 + 450 5 5 5 5 5 1
Compound A-9 + (35) 50 + 250 5 5 5 5 5 1
Compound A-9 + (36) 50 + 1000 4 5 5 5 5 2
Compound A-9 + (37) 50 + 900 5 5 5 5 5 0
Compound A-9 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-9 + (39) 50 + 925 5 5 5 5 5 5
Compound A-9 + (40) 50 + 900 5 5 5 5 5 2
Compound A-10 50 5 4 3 4 5 1
Compound A-10 + (1) 50 + 750 5 4 3 4-1
Compound A-10 + (2) 50 + 300 5 4-4-2
Compound A-10 + (3) 50 + 1200 5 4-3 5 1
Compound A-10 + (4) 50 + 30 5 3-5-3
Compound A-10 + (5) 50 + 60 5 3-5-1
Compound A-10 + (6) 50 + 100 4 2-5 5 3
Compound A-10 + (7) 50 + 23 5 4-5-2
Compound A-10 + (8) 50 + 25 4 5 3 5-2
Compound A-10 + (9) 50 + 35 5 5-5 5 1
Compound A-10 + (10) 50 + 240 5 5-5 5 3
Compound A-10 + (11) 50 + 200 5 5 5 5 5 3
Compound A-10 + (12) 50 + 100 5 5-4-1
Compound A-10 + (13) 50 + 1200 5 4 1 3-2
Compound A-10 + (14) 50 + 2000 5 4-5 5 2
Compound A-10 + (15) 50 + 60 5 5 5 5-2
Compound A-10 + (16) 50 + 2500 5 5 5 5 5 3
Compound A-10 + (17) 50 + 2000 5 4 5 5 5 1
Compound A-10 + (18) 50 + 120 5 5 2 3 4 5
Compound A-10 + (19) 50 + 300 5 5-4-2
Compound A-10 + (20) 50 + 80 5 5 1 3-2
Compound A-10 + (21) 50 + 2000 5 4-4-2
Compound A-10 + (22) 50 + 1720 5 5-3 5 2
Compound A-10 + (23) 50 + 2000 5 4 1-5 1
Compound A-10 + (24) 50 + 600 5 5-4-2
Compound A-10 + (25) 50 + 200 5 5-5 5 2
Compound A-10 + (26) 50 + 60 5 5 3 2 4 2
Compound A-10 + (27) 50 + 15 5 5-5 4 1
Compound A-10 + (28) 50 + 25 5 5 5 5-1
Compound A-10 + (29) 50 + 25 5 5 5 5 5 2
Compound A-10 + (30) 50 + 100 5 5 4 4 5 0
Compound A-10 + (31) 50 + 54 5 5 4 4 4 1
Compound A-10 + (32) 50 + 150 5 4 4 5 4 1
Compound A-10 + (33) 50 + 100 5 5-4-3
Compound A-10 + (34) 50 + 450 5 4 4 4 5 1
Compound A-10 + (35) 50 + 250 5 4---1
Compound A-10 + (36) 50 + 1000 5 5 5 5 5 1
Compound A-10 + (37) 50 + 900 5 5 5 5 5 1
Compound A-10 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-10 + (39) 50 + 925 5 5 5 5 5 3
Compound A-10 + (40) 50 + 900 5 5 4 4 5 2
Compound A-11 50 5 4-4-3
Compound A-11 + (1) 50 + 750 5 5 3 4-3
Compound A-11 + (2) 50 + 300 5 5 2 4 5 3
Compound A-11 + (3) 50 + 1200 5 5 4 4-2
Compound A-11 + (4) 50 + 30 5 4-5-3
Compound A-11 + (5) 50 + 60 5 5 2 5-3
Compound A-11 + (6) 50 + 100 5 4 3 5-3
Compound A-11 + (7) 50 + 23 5 3-5-3
Compound A-11 + (8) 50 + 25 4 5-5-3
Compound A-11 + (9) 50 + 35 5 5-5 5 3
Compound A-11 + (10) 50 + 240 5 5-5-3
Compound A-11 + (11) 50 + 200 5 5-5 5 4
Compound A-11 + (12) 50 + 100 5 5-4-2
Compound A-11 + (13) 50 + 1200 5 5 3 4-3
Compound A-11 + (14) 50 + 2000 5 5-4 5 3
Compound A-11 + (15) 50 + 60 5 5 5 5-2
Compound A-11 + (16) 50 + 2500 5 5 5 5 5 3
Compound A-11 + (17) 50 + 2000 4 4-5 5 1
Compound A-11 + (18) 50 + 120 5 5---5
Compound A-11 + (19) 50 + 300 5 5 4 5 5 3
Compound A-11 + (20) 50 + 80 5 5-4 4 3
Compound A-11 + (21) 50 + 2000 5 5-5-3
Compound A-11 + (22) 50 + 1720 5 5 3 4 4 3
Compound A-11 + (23) 50 + 2000 5 5 1-5 3
Compound A-11 + (24) 50 + 600 5 5 4 5 5 3
Compound A-11 + (25) 50 + 200 5 5 5 5 5 3
Compound A-11 + (26) 50 + 60 5 5 3 5 4 3
Compound A-11 + (27) 50 + 15 5 5 4 5 5 3
Compound A-11 + (28) 50 + 25 5 5 5 5 5 3
Compound A-11 + (29) 50 + 25 5 5 5 5 5 3
Compound A-11 + (30) 50 + 100 5 5-5-1
Compound A-11 + (31) 50 + 54 5 5 5 5 5 3
Compound A-11 + (32) 50 + 150 5 5 5 5-2
Compound A-11 + (33) 50 + 100 5 5 4 5-4
Compound A-11 + (34) 50 + 450 5 5-5 5 4
Compound A-11 + (35) 50 + 250 5 5 5 5-3
Compound A-11 + (36) 50 + 1000 5 5 5 5 5 2
Compound A-11 + (37) 50 + 900 5 5 5 5 5 3
Compound A-11 + (38) 50 + 2400 5 5 5 5 5 5
Compound A-11 + (39) 50 + 925 5 5 5 5 5 3
Compound A-11 + (40) 50 + 900 5 5 4 5 5 3
Compound A-12 50 5 4 4 3 5 3
Compound A-12 + (1) 50 + 750 5 4 4 3 3 3
Compound A-12 + (2) 50 + 300 5 3 5 3 5 3
Compound A-12 + (3) 50 + 1200 5 4 5 4 5 3
Compound A-12 + (4) 50 + 30 5 1 4 5 5 3
Compound A-12 (5) 50 + 60 5 3 4 5 3 3
Compound A-12 + (6) 50 + 100 5 3 5 5 4 3
Compound A-12 + (7) 50 + 23 5 2 5 5 5 2
Compound A-12 + (8) 50 + 25 5 5 4 3 4 3
Compound A-12 (9) 50 + 35 5 3 5 5 5 3
Compound A-12 (10) 50 + 240 5 5 5 5 5 3
Compound A-12 + (11) 50 + 200 5 5 5 5 5-
Compound A-12 + (12) 50 + 100 5 5 5 5 5 3
Compound A-12 + (13) 50 + 1200 5 4 5 4 5 2
Compound A-12 + (14) 50 + 2000 5 4 5 3 5 3
Compound A-12 (15) 50 + 60 5 5 5 5 5 2
Compound A-12 (16) 50 + 2500 5 5 5 5 5 5
Compound A-12 (17) 50 + 2000 5 3 5 5 5 1
Compound A-12 (18) 50 + 120 5 5 5 4 5 4
Compound A-12 (19) 50 + 300 5 4 5 4 5 2
Compound A-12 (20) 50 + 80 5 4 5 4 5 2
Compound A-12 + (21) 50 + 2000 5 5 5 5 5 4
Compound A-12 + (22) 50 + 1720 5 5 5 5 4 2
Compound A-12 + (23) 50 + 2000 5 5 5 5 5 3
Compound A-12 (24) 50 + 600 5 5 5 3 5 1
Compound A-12 (25) 50 + 200 5 5 5 5 5 1
Compound A-12 (26) 50 + 60 5 5 4 3 5 2
Compound A-12 (27) 50 + 15 5 5 5 5 5 2
Compound A-12 (28) 50 + 25 5 5 4 4 5 1
Compound A-12 (29) 50 + 25 5 5 5 5 5 4
Compound A-12 (30) 50 + 100 5 4 5 5 5 1
Compound A-12 (31) 50 + 54 5 5 5 5 5 1
Compound A-12 (32) 50 + 150 5 4 5 5 5 3
Compound A-12 (33) 50 + 100 5 5 5 5 5 3
Compound A-12 (34) 50 + 450 5 4 5 5 5 3
Compound A-12 (35) 50 + 250 5 4 5 5 5 3
Compound A-12 (36) 50 + 1000 5 3 5 5 5 1
Compound A-12 (37) 50 + 900 5 4 5 5 5 3
Compound A-12 (38) 50 + 2400 5 5 5 4 5 3
Compound A-12 (39) 50 + 925 5 5 5 4 5 3
Compound A-12 (40) 50 + 900 5 5 5 5 5 3
―――――――――――――――――――――――――――――――――――――

  The composition of the present invention is useful as a herbicide for paddy fields. In addition, it is useful in soil treatment, soil mixing treatment, and foliage treatment methods in the field of agriculture and horticulture such as upland and orchards, and in non-cultivated land such as turf, playground, open space, roadsides, and track ends.

Claims (7)

[Component A] selected from the group consisting of the heterocyclic amide compound represented by the formula (1) described below and a salt thereof, and [Component B] described below as active ingredients A herbicidal composition [component A]

[Wherein Q represents an aromatic heterocycle represented by any one of Q-1 to Q-7,

W represents an aromatic heterocycle represented by W-1, W-2 or W-3,

X represents an oxygen atom or a sulfur atom,
R 1a is a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 6 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 6 (C 3 ~C 6) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkenyl, -C (O) R 8, -C (O) OR 16, cyano, -OR 9, -S (O) m1 R 10, -N (R 11) R 12, -C (= NR 12b) R 8b, phenyl, phenyl substituted by (R 7) p, naphthyl or U-1 To any of U-25 groups,
R 1b is a hydrogen atom, C 1 -C 6 alkyl, optionally substituted by R 6 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, optionally substituted by R 6 (C 3 ~ C 6 ) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, phenyl, (R 7 ) phenyl substituted by p , naphthyl, 5-6 membered heteroaryl, (by R 28 and R 28a Represents optionally substituted) 5-6 membered heteroaryl, 3-7 membered heterocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a );
R 1c represents C 1 -C 6 alkyl,
R 2a is a halogen atom, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, -C (O) R 18, -C (O) OR 24, cyano, nitro, -OR 19, -S (O) m3 R 20 , —N (R 21 ) R 22 , phenyl, or phenyl substituted by (R 7 ) p , and when n represents an integer of 2 or more, each R 2a may be the same as or In addition, when two R 2a are adjacent to each other, the two adjacent R 2a form —CH═CH—CH═CH— to bond each R 2a You may form a 6-membered ring with a carbon atom,
R 2c represents C 1 -C 6 haloalkyl,
R 3 is a hydrogen atom, C 1 -C 6 alkyl, (C 1 -C 6 ) alkyl optionally substituted by R 27 , C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 represents alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, -C (O) R 25 or -C (O) oR 26,
R 4a is a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 27 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 27 (C 3 ~C 6) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cycloalkenyl, -NH 2 , C 1 -C 6 alkylamino, di (C 1 -C 6 alkyl) amino, —NHC (O) R 8 , phenyl, phenyl substituted by (R 28 ) r , 5-6 membered heteroaryl, ( 5-6 membered heteroaryl, optionally substituted by R 28 and R 28a ), 3-7 membered heterocyclyl, or 3-7 membered hete (optionally substituted by R 28 and R 28a ) Represents Rocyclyl,
R 4b is a hydrogen atom, halogen atom, cyano, nitro, C 1 -C 6 alkyl, (C 1 -C 6 ) alkyl optionally substituted with R 27 , C 3 -C 6 cycloalkyl, optional with R 27 (C 3 -C 6 ) cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cyclo alkenyl, -C (O) OR 16, -OR 38, -S (O) m3 R 20, -NH 2, C 1 ~C 6 alkyl amino, di (C 1 -C 6 alkyl) amino, -NHC (O ) R 8 , phenyl, phenyl substituted by (R 28 ) r , 5-6 membered heteroaryl, 5-6 membered heteroaryl (optionally substituted by R 28 and R 28a ), 3-7 membered Terocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a );
R 4c represents a hydrogen atom, a halogen atom, optionally substituted by C 1 -C 6 alkyl, optionally substituted by R 27 (C 1 ~C 6) alkyl, C 3 -C 6 cycloalkyl, R 27 (C 3 -C 6) cycloalkyl, heteroaryl, phenyl substituted by (R 28) r, heteroaryl 5-6 membered, the (optionally substituted by R 28 and R 28a) 5-6 membered, 3-7 membered heterocyclyl or 3-7 membered heterocyclyl (optionally substituted by R 28 and R 28a ),
R 4d , R 4e , R 4f , R 4g and R 4h each independently represent a hydrogen atom, C 1 -C 6 alkyl or (C 1 -C 6 ) alkyl optionally substituted with R 35 ,
U-1 to U-6, U-6a, U-7 to U-10, U-10a, U-11, U-11a, U-12, U-12a, U-13, U-13a, U- 14 to U-22, U-22a, U-23, U-24, U-25 and U-26 each represent a heterocyclic ring represented by the following structure;

R ^5a and R ^5b are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C _{6 halocycloalkyl,} C 2 -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} C 3 -C ₆ cycloalkenyl, phenyl or ^(R _{28) r} Represents phenyl substituted by
R ^5c represents a hydrogen atom, C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁶ , or R ^5c represents R ^4d and — (CH ₂ ) ₄ — or By forming —CH═CH—CH═CH—, a 6-membered ring may be formed together with the nitrogen atom to which R ^5c is bonded and the carbon atom to which R ^4d is bonded;
R ⁶ is a halogen atom, cyano, C ₃ -C ₆ cycloalkyl, —C (O) R ⁸ , —C (O) OR ¹⁶ , —OR ¹³ , —S (O) _{m 2} R ¹⁴ , phenyl or (R ⁷ ) represents phenyl substituted by _p ;
R ⁷ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocyclo. _alkyl, C 2 -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} C 3 -C _{6 cycloalkenyl,} C 1 -C ₆ alkylcarbonyl, _{C 3} -C _{6 cycloalkylcarbonyl,} C 1 -C _{6 haloalkylcarbonyl,} C 3 -C ₆ halocycloalkyl _carbonyl, C 1 -C _{6 alkoxycarbonyl,} C 1 -C _{6 haloalkoxycarbonyl,} C 1 -C ₆ alkylaminocarbonyl , _C 1 -C ₆ haloalkylcarbonyl aminocarbonyl, di _(C 1 -C ₆ alkylamino) carbonyl, ^{-OR 15 _{, -S (O) m3 R 20}} , C 1 ~C 6 alkylaminosulfonyl, di _(C 1 -C ₆ alkyl) _{aminosulfonyl,} -NH _2, C 1 ~C ₆ alkyl amino, di _(C 1 -C ₆ Alkyl) amino, 5-6 membered heteroaryl, optionally substituted by 5-6 membered heteroaryl (optionally substituted by R ²⁸ and R ^28a ), 3-7 membered heterocyclyl, or (optionally substituted by R ²⁸ and R ^28a ) Represents a 3-7 membered heterocyclyl,
R ⁸ represents a hydrogen atom, C ₁ -C ₆ alkyl or —N (R ^11a ) R ^12a ,
R ^8b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ⁹ represents a hydrogen atom, C ₁ -C ₆ alkyl or phenyl,
R ¹⁰ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ represents _alkenyl, C 2 -C _{6 haloalkenyl,} a C 2 -C ₆ alkynyl or _C 2 -C ₆ haloalkynyl,
R ¹¹ and R ¹² are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C ₆ haloalkynyl, phenylsulfonyl, phenyl, phenyl substituted by (R ⁷ ) _p , U-7, U-8, U-9 or U-14 to U-19, or R ¹¹ together with R ¹² to form a C ₂ -C ₆ alkylene chain, whereby a nitrogen atom to which R ¹¹ and R ¹² are bonded And the alkylene chain may contain one O, S, S (O), S (O) ₂ or N (R ³³ ), and By an oxo or thioxo group It may be substituted,
R ^11a and R ^12a each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or phenyl, or R ^11a together with R ^12a forms a C ₂ -C ₆ alkylene chain. , R ^11a and R ^12a may form a 3- to 7-membered ring together with the nitrogen atom to which R ^12a is bonded, and at this time, the alkylene chain is O, S, S (O), S (O) ₂ or N ( R ³³ ) and may be substituted by an oxo group or a thioxo group,
R ^12b represents -OR ^19b ;
R ¹³ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C Represents ₆ alkynyl, C ₂ -C ₆ haloalkynyl, —C (O) R ⁸ or phenyl,
R ¹⁴ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C _{6 alkynyl,} C 2 -C ₆ haloalkynyl or phenyl,
R ¹⁵ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ²⁷ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ represents _alkenyl, C 2 -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C ₆ haloalkynyl or _C 3 -C ₆ cycloalkenyl,
R ¹⁶ represents a hydrogen atom, C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁷ ,
R ¹⁸ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ¹⁹ represents a hydrogen atom, C ₁ -C ₆ alkyl or phenyl,
R ^19b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²⁰ is C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C represents ₆ haloalkynyl or _C 3 -C ₆ cycloalkenyl,
R ²¹ and R ²² each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or phenyl, or R ²¹ together with R ²² forms a C ₂ -C ₆ alkylene chain. , R ²¹ and R ²² may form a 3- to 7-membered ring together with the nitrogen atom to which R ²¹ and R ²² are bonded. At this time, this alkylene chain is O, S, S (O), S (O) ₂ or N ( R ³⁹ ) and may be substituted by an oxo group or a thioxo group,
R ²⁴ represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²⁵ and R ²⁶ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C _2- C ₆ alkenyl, C ₂ -C ₆ haloalkenyl, C ₂ -C ₆ alkynyl, C ₂ -C ₆ haloalkynyl, C ₃ -C ₆ cycloalkenyl or phenyl,
R ²⁷ is halogen atom, cyano, nitro, ^{phenyl, (R} ₂₈₎ phenyl substituted by _{^{r, -C (O) OR 16}} , -OR 29, -S (O) m4 R 30, the 5-6 membered heteroaryl represents heteroaryl, ^(optionally substituted by ^{R 28} and ^{R 28a)} 3-7 membered heterocyclyl or 3-7 membered heterocyclyl to ^(optionally substituted by ^{R 28} and ^{R 28a)} 5-6 membered,
R ²⁸ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C ₆ alkenyl, C ₂ -C _{6 haloalkenyl,} C 2 -C _{6 alkynyl,} C 2 -C _{6 haloalkynyl,} a _(C 1 -C _{6 alkoxy)} C 1 -C ₆ alkyl, ^{-OR 31} or -S _(O) m4 ^{R 30} When t2, t3, t4, t5, t7, t8 or t9 represent an integer of 2 or more, each R ²⁸ may be the same as or different from each other, and two R ²⁸ are adjacent to each other. when, by two adjacent ^{R 28} are forming a -CH = CH-CH = CH- together, may form a 6-membered ring together with the carbon atom to which each ^{R 28} is bonded ,
R ^28a represents C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, (C ₁ -C ₆ alkoxy) C ₁ -C ₆ alkyl or (C ₁ -C ₆ alkylthio) C ₁ -C ₆ alkyl,
R ²⁹ , R ³⁰ and R ³¹ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C ₆ represents _alkynyl, C 2 -C _{6 haloalkynyl,} a C 3 -C ₆ cycloalkenyl or phenyl,
R ³³ is R ³⁴ represents a hydrogen atom or a _C 1 -C ₆ alkyl, halogen atom, _cyano, C 3 -C ₆ ^{cycloalkyl, -C (O) R 8,} -C (O) OR 16, -OR _{^{33, -S (O) m6 R}} 33, phenyl, (R ⁷⁾ phenyl substituted by _{p, U-1, U-} 3, U-7, U-8, U-9 , or U-14 through U- 25,
R ³⁵ represents a halogen atom or C ₁ -C ₆ alkoxy;
R ³⁶ represents a halogen atom or C ₁ -C ₆ alkoxy;
R ³⁷ represents C ₁ -C ₆ alkoxy;
R ³⁸ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ , C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl, C ₂ -C _{6 alkenyl,} C 2 -C _{6 haloalkenyl,} C 2 -C ₆ represents _alkynyl, C 2 -C _{6 haloalkynyl,} a C 3 -C ₆ cycloalkenyl or phenyl,
R ³⁹ represents a hydrogen atom or C ₁ -C ₆ alkyl,
t1 represents an integer of 0 or 1, m1, m2, m3, m4, m6 and t2 each independently represents an integer of 0, 1 or 2;
n and t3 each independently represents an integer of 0, 1, 2, or 3,
p and r each independently represents an integer of 1, 2, 3, 4 or 5;
t4 represents an integer of 0, 1, 2, 3 or 4;
t5 represents an integer of 0, 1, 2, 3, 4 or 5,
t7 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
t8 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7 or 8;
t9 represents an integer of 0, 1, 2, 3, 4, 5, 6, 7, 8, or 9. ]
[Component B]
Acifluorfen, acloniphene, aloxidim, aloxidim sodium, ametrine, amicarbazone, amidosulfuron, aminocyclopyrachlor, aminocyclopyracrol salts and esters, aminopyralide, aminopyralide salts and esters, amiprophosmethyl, amitrolol, anilophos , Ashram, azaphenidine, azimusulfuron, beflubutamide, benazoline ethyl, bencarbazone, benfluralin, benfrate, bensulfuron methyl, bensulide, bentazone sodium, salt of bentazone, beniocarb, benzfendizone, benzobicyclon, benzofenap, bialaphos, bialaphos sodium , Bicyclopyrone, bifenox, bispyribac, bromacil, bromobutide, bro Phenoxime, bromoxynyl, bromoxynil salts and esters, butaphenacyl, butamifos, butenachlor, butralin, butroxidim, butyrate, caffefentrol, carbetamido, clomethoxyphene, clomethoxynyl, chloramben, chloramben salts and esters, chloransrammethyl, chlorflurenol methyl, Chloridazone, chlorimuron ethyl, chlorobromulone, chlorotoluron, chloroxuron, chlorphthalim, chlorpropam, chloro IPC, chlorsulfuron, chlortaldimethyl, chlorthiamid, sinidone ethyl, cinmesrin, sinosulfurone, cletodim, clodinahop, clodinahop propargyl, clomazone , Clomeprop, clopyralid, clopyralid salt and es , CNP, cumyluron, cyanazine, cycloate, cyclopyrimolate, cyclosulfamlone, cycloxydim, DAH-500, darapon, dazomet, desmedifam, desmethrin, dicamba salts and esters, diclobenil, diclohop, diclohopmethyl, Dichlorprop, Dichlorprop salt and ester, P Dichlorprop, P Dichlorprop salt and ester, Diclosram, Difenzocote, Diflufenican, Diflufenzopyr, Diflufenzopyr sodium, Dimepiperate, Dimethachlor, Dimethenamide, P Dimethenamide, dimesipine, dinitroamine, dinoseb, dinoterb, DNOC, diphenamide, diquat, dithiopyr, diuron, DSMA, dimron, endtal , EPTC, ethalfluralin, ethamethsulfuron methyl, etofumesate, ettobenzanide, ethoxysulfuron, flazasulfuron, phenoxaprop, phenoxapropethyl, phenoxasulfone, fenquinotrione, flamprop, flazasulfuron, flurothram, Fluazifop, fluazifop butyl, fluazolate, flucarbazone sodium, flucetosulfuron, fluchloraline, flufenpyrethyl, flumetram, flumicrolacpentyl, fluometuron, fluoroglycopheneethyl, flupyrsulfuron, flupoxam, flulenol, fluridone, full Lochloridone, fluroxypyr, ester of fluroxypyr, fluprimidol, flutamon, flutiaset methyl, fomesafe , Foramsulfuron, fosamine, glufosinate ammonium, glyphosate ammonium, glyphosate isopropylamine, glyphosate potassium, glyphosate sodium, glyphosate trimesium, haloxifene, haloxifene salts and esters, halosafene, halosulfuron, haloxyhop, haloxyhop methyl , Hexazinone, imazametabenzmethyl, imazamox, imazapic, imazapyr, imazetapyr, imazaquin, imazosulfuron, indazifram, iodosulfuronmethyl sodium, ioxynil, salts and esters of ioxonyl, ipfencarbazone, isoproturon, isouron, isoxaben, Carbutyrate, lactofen, lenacyl, linuron, maleic acid hydride Zido, MCPA, MCPA salts and esters, MCPB, MCPB salts and esters, mecoprop, mecoprop salts and esters, P mecoprop, P mecoprop salts and esters, mefluidide, mesosulfuron methyl, metam, metamihop, metamitron, metazachlor , Metabenzthiazurone, Methiozoline, Methyl azide, Methyl bromide, Methyl diimron, Methyl iodide, Metobenzuron, Metolachlor, Methoslam, Metribuzin, Metsulfuron methyl, Metoxuron, Monolinuron, Monosulfuron, Monosulfuron methyl, MSMA, Naproanilide, Napropamide , Naptaram, sodium naptalam, nebulon, norflurazon, OK-701, oleic acid, olvencurve, orthosulfamlone, o Rizarin, oxasulfuron, oxyfluorphene, paraquat, pelargonic acid, pentanochlor, pentoxazone, petoxamide, phenmedifamethyl, picloram, picroram salt and ester, picolinaphene, pinoxaden, piperophos, pretilachlor, primisulfurone methyl, prodiamine , Profluazole, Profoxydim, Prometon, Promethrin, Propacrol, Propoxahop, Propazine, Profam, Propisochlor, Propoxycarbazone sodium, Propyrisulfuron, Propizzamid, Pullsulfocarb, Prosulfuron, Pyraclonil, Pyraflufenethyl , Pyrasulfotol, pyrazolinate, pyrazosulfuron, pyrazoxifene, pyribenzoxime, pyributicarb Pyridafol, pyridate, pyriftalide, pyriminobacmethyl, pyrimisulphan, sodium pyrithiobac, piroxislam, kimmelac, quinocuramin, quizalofop, quizalofopethyl, xyzalofep tefryl, Pxalofop, Pxallohopethyl, P Quizalofoptefril, saflufenacyl, cetoxidim, cidurone, simazine, cimetrin, SL-261, sulfentrazone, sulfometuron methyl, sulfosulfuron, TCBA, TCBA salts and esters, TCTP, tebutam, tebutiurone, tefril Trione, tepraloxidim, terbacil, terbumetone, terbuthylazine, terbutrine, tetrapion, tenylchlor, thiazaflulone, thiazopyr, thiadimine, thiazulone, chi Jensulflon methyl, tolpyralate, tolalkoxydim, triafamon, triarate, triasulfuron, triadifram, tribenuronmethyl, triclopyr, triclopyr salts and esters, tridifane, trietadine, trifludimoxazine, trifloxysulfuron, trifluralin , Triflusulfuron methyl, tritosulfuron, 2,4-PA, 2,4-PA salt and ester, 2,4-DB, 2,4-DB salt and ester, butachlor, fentolazamide, mefenacet, pyrazos Ruflon ethyl, halosulfuron methyl, metazosulfuron, penoxsulam, bispyribac sodium, carfentrazone ethyl, oxadiazone, oxadialgyl, quinclolac, esprocarb, molinay , Dimetamethrin, propanyl, bentazone, cihalohop butyl, indanophan, oxadiclomephone, acetochlor, alachlor, S-metolachlor, fluphenacet, pyroxasulfone, nicosulfuron, rimsulfuron, thiencarbazone methyl, flumioxazin, Tembotrione, toprazone, mesotrione, isoxaflutole, sulcotrione, dicamba, 2,4-D, atrazine, glyphosate, glufosinate and pendimethalin. Q represents Q-1 or Q-3,
W represents W-1,
X represents an oxygen atom,
R ^1a is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted by R ⁶ , -S (O) _m1 R ¹⁰ , -N (R ¹¹ ) R ¹² , U-5 or Represents U-8,
R ^2a represents C ₁ -C ₆ haloalkyl,
R ³ represents a hydrogen atom,
R ^4a represents a hydrogen atom or C ₁ -C ₆ alkyl;
R ^5a represents C ₁ -C ₆ alkyl;
R ⁶ represents phenyl substituted by —S (O) _m2 R ¹⁴ or (R ⁷ ) _p ;
R ⁷ represents -OR ¹⁵ ;
R ¹⁰ represents C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted by R ³⁴ ,
R ¹¹ and R ¹² each independently represent C _{1 to} C ₆ alkyl, or R ¹¹ together with R ¹² forms a C ₅ alkylene chain, whereby R ¹¹ and R ¹² are bonded. Represents that a 6-membered ring may be formed together with the nitrogen atom, and this alkylene chain may contain one S (O) ₂ ,
R ¹⁴ and R ¹⁵ each independently represent C ₁ -C ₆ alkyl;
R ²⁸ represents C ₁ -C ₆ alkyl or —OR ³¹ ,
R ³¹ and R ³³ each independently represent C ₁ -C ₆ alkyl, R ³⁴ represents —S (O) _m6 R ³³ ,
m1 and m2 each independently represent an integer of 0 or 2,
The herbicidal composition according to claim 1, wherein m6 represents an integer of 0.   Component B is butachlor, fentrazamide, mefenacet, pyrazosulfuron ethyl, halosulfuron methyl, metazosulfuron, penoxthram, bispyribac sodium, carfentrazone ethyl, oxadiazone, oxadiargyl, quinclolac, esprocarb, molinate, dimetamethrin, propanyl, bentazone, Cihalohop butyl, indanophan, oxadichromephone, acetochlor, alachlor, S-metolachlor, fluphenacet, pyroxasulfone, nicosulfuron, rimsulfuron, thiencarbazone methyl, flumioxazin, tembotrione, toprazone, mesotrione, isoxa Frutol, sulcotrione, dicamba, 2,4-D, atrazine, glyphosate, glufosinate and The herbicidal composition according to claim 1 or 2, which is pendimethalin.   4. One or more compounds selected from Component B are 0.01 to 30 parts by mass with respect to 1 part by mass of one or more compounds selected from Component A. 5. A herbicidal composition as described in 1. above.   A herbicidal method comprising treating one or more compounds selected from component A according to claim 1 and one or more compounds selected from component B according to claim 1 simultaneously or close in time. .   The weeding method according to claim 5, wherein the weeding method is a weeding method of paddy field weeds.   The weeding method according to claim 5, wherein the weeding method is a weeding method for upland weeds.