WO2021036251A1 - Herbicidal composition containing r-type pyridyloxy carboxylic acid derivatives and application thereof - Google Patents

Herbicidal composition containing r-type pyridyloxy carboxylic acid derivatives and application thereof Download PDF

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Publication number
WO2021036251A1
WO2021036251A1 PCT/CN2020/081644 CN2020081644W WO2021036251A1 WO 2021036251 A1 WO2021036251 A1 WO 2021036251A1 CN 2020081644 W CN2020081644 W CN 2020081644W WO 2021036251 A1 WO2021036251 A1 WO 2021036251A1
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Prior art keywords
salt
alkyl
polyoxyethylene ether
methyl
evaluation
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PCT/CN2020/081644
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French (fr)
Chinese (zh)
Inventor
彭学岗
赵德
金涛
张景远
刘娜
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青岛清原化合物有限公司
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Publication of WO2021036251A1 publication Critical patent/WO2021036251A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/18—Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
    • C07D295/03—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring with the ring nitrogen atoms directly attached to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Definitions

  • R" each independently represents a C1-C16 alkyl group, and is selected from one or more groups of halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, and hydroxy C1-C6 alkoxy.
  • Substituted C1-C16 alkyl preferably C1-C6 alkyl
  • C2-C12 alkenyl preferably C2-C6 alkenyl
  • C2-C12 alkynyl preferably C2-C6 alkynyl
  • C3-C12 cycloalkane Group unsubstituted or substituted by C1-C6 alkyl phenyl or benzyl
  • C1-C6 alkyl phenyl or benzyl preferably C1-C6 alkyl group, and is selected from one or more groups of halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, and hydroxy C1-C6 alkoxy.
  • Z stands for And unsubstituted or substituted by at least one group selected from C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, halogenated C1-C6 alkyl, cyano and halogen Phenyl, tetrahydrofuranyl, pyridyl, pyrazolyl, thienyl, furanyl or naphthyl;
  • R 7 represents C1-C6 alkyl, C2-C6 alkenyl,
  • the active ingredient B is selected from one or more of the following compounds and their salts/esters:
  • ALS inhibitors Penoxsulam (CAS Number: 219714-96-2), Bispyrifen (CAS Number: 125401-92-5), Pyrimsulfuron (CAS Number: 93697-74-6) ), Nicosulfuron (CAS Number: 111991-09-4), Fenoxsulam (CAS Number: 145701-23-1), Susulfuron-methyl (CAS Number: 122931-48-0), Imazethapyr Tobacco (CAS Number: 81335-77-5), Imazethapyr (CAS Number: 104098-48-8), Imazethapyr (CAS Number: 114311-32-9), Metsulfuron (CAS No.: 74222-97-2), Chlorfentrazone (CAS No.: 147150-35-4);
  • HPPD inhibitors ciclofenac (CAS number: 1855929-45-1), fentrazone (CAS number: 1622908-18-2), flufentrazone (CAS number: 1992017-55) -6), mesotrione (CAS number: 1911613-97-2), fursotrione (CAS number: 473278-76-1), mesotrione (CAS number: 104206-82-8), Cyclosulfone (CAS number: 335104-84-2), oxaflutole (CAS number: 210631-68-8), isoxaflutole (CAS number: 141112-29-0), bicyclazone ( CAS number: 156963-66-5);
  • Q represents methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, Methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2,2,2-trifluoroethyl, hydroxymethyl, Benzyl, naphthyl Furanyl Pyridyl Pyrimidinyl And unsubstituted or chloro-substituted thiazolyl Thienyl unsubstituted or substituted by fluorine Unsubstituted or substituted by methyl or fluorine Unsubstituted or substituted by at least one of methyl, trifluoromethyl, chlorine and methoxy;
  • M represents methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, ten Monoalkyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2, 2-Difluoroethyl, 2,2,2-trifluoroethyl, 4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl Group, cyclopentyl, cyclohexyl, allyl, 2-propynyl, meth
  • the preparation method of the active ingredient A includes the following steps:
  • W represents hydrogen or alkali metal, preferably K, Na;
  • Hal represents halogen, preferably Br, Cl;
  • the reaction is carried out in the presence of a catalyst and a solvent, preferably, the catalyst is TBAB, and the solvent is DCM, One or more combinations of DCE, ACN, THF, and DMF.
  • the solvent is selected from one or more combinations of methanol, ethanol, and isopropanol.
  • the reaction is carried out in the presence of a dehydrating agent and a solvent.
  • the dehydrating agent is DCC
  • the solvent is selected from the group consisting of dichloromethane, dichloroethane, acetonitrile, and N,N-dimethylformamide , N,N-dimethylacetamide, dimethylsulfoxide, tetrahydrofuran, toluene, xylene, one or more combinations.
  • the halogenated compound is preferably a chlorinated compound or a brominated compound; the reaction is carried out in the presence of a base and a solvent, and the base is selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate and cesium carbonate.
  • the solvent is selected from one of THF, 1,4-dioxane, toluene, 1,2-dichloroethane, ethyl acetate, acetonitrile, DMF, acetone, dichloromethane and chloroform
  • a catalyst can also be added during the reaction process, preferably DMAP.
  • the salt is a pesticide acceptable salt, preferably the R-type pyridyloxy carboxylic acid compound of the present invention is formed by reacting with a chemically acceptable basic compound.
  • the above-mentioned pharmaceutically acceptable salts are easy to separate and can be purified by conventional separation methods, such as solvent extraction, dilution, recrystallization, column chromatography and preparative thin layer chromatography.
  • the mass percentage of A and B in the herbicidal composition accounts for 1-95%, preferably 10-80% of the total.
  • the herbicidal composition also contains conventional adjuvants, and the conventional adjuvants include carriers and surfactants.
  • carrier refers to an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient.
  • the carrier is generally inert and must be agriculturally acceptable, especially acceptable to the plants being treated.
  • the carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon, liquefied gas, etc.
  • the surfactant may include an emulsifier, dispersant or wetting agent, and it may be ionic or non-ionic. Examples that may be mentioned are the salts of polyacrylic acid, lignosulfonate, phenolsulfonic acid or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (in particular Alkylphenol or arylphenol) polymers, sulfosuccinates, taurine derivatives (especially taurine alkane esters) and alcohol phosphate esters or polyhydroxyethylated phenol phosphate esters, Alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl, heptadecyl and stearyl alcohols and sulf
  • composition may also contain various other components, such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants and polymers.
  • composition of the present invention can be mixed with the following active substances, such as "Encyclopedia of World Pesticide New Variety Technologies", China Agricultural Science and Technology Press, 2010.9 and known substances in the literature cited here.
  • the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, and the code when appropriate): acetochlor, butachlor, Alachlor, Propolachlor, Metolachlor, Refined Metolachlor, Pretilachlor, Tetrachlor, Metochlor, Napropionate, R-Naphtochlor, Propanochlor , Mefenacet, difenacet, diflufenican, chlorfenazone, flubutazone, bromobutyrazamide, dimethenamid, high-efficiency dimethenamid, ethoxylate Apifenacet, flufenacet, metolachlor, metazachlor,
  • the herbicidal composition further includes at least one safener selected from:
  • Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl Ethyl-2-pyrazoline-3-carboxylate (S1-1, mefenpyr-diethyl, PM, p. 594-595), and described in, for example, WO91/07874 and PM (p. 594-595) 594-595 pages) related compounds.
  • Dichlorophenylpyrazole carboxylic acid derivatives the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-Dichlorophenyl)-5-(1 ,1-Dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4), 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid compound preferably
  • the compound is, for example, 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid Ethyl acid (S1-8) and related compounds described in WO91/08202, or 5,5-diphenyl-2-isoxazoline described in patent application (WO-A-95/07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline
  • S2 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (pages 195-196), (1,3-dimethylbut-1-yl)(5-chloro-8-quinolinoxy)acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy) Yl) acetate (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5), (5-chloro-8-quinolinoxy) methyl acetate (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2-(2-propylene iminooxy)-1-ethyl (5-chloro-8-
  • Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acid active compounds such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
  • the safener is preferably dibenzoxazole acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolone (CAS: 135590-91-9), detox quinine (CAS : 99607-70-2), one or more of gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
  • the abbreviated form of the common name of the active compound all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, especially One or more commercially available forms.
  • the generic name indicates an ester or salt, it also includes all other conventional derivatives in each case, such as other esters and salts, free acids and neutral compounds, as well as isomers, especially optical isomers, especially Is one or more commercially available forms.
  • the chemical name of the given compound indicates at least one compound covered by the generic name, and is usually the preferred compound.
  • salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group.
  • 2 methyl 4 chloro derivatives include but are not limited to: 2 methyl 4 chloride sodium salt, potassium salt, dimethyl ammonium salt, isopropylamine salt, etc., and 2 methyl 4 chloro methyl, ethyl, isooctyl ester, ethyl sulfide Esters, etc.
  • 2,4-D derivatives include but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc., and 2,4 -D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester, etc.
  • the salt of the compound is preferably in the form of the respective alkali metal salt, alkaline earth metal salt or ammonium salt, preferably in the form of the respective alkali metal salt, more preferably in the form of the respective sodium salt or potassium salt, It is most preferably in the form of the respective sodium salt.
  • composition of the present invention can be diluted or used directly by the user before use.
  • the formulation can be prepared by the usual processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, then adding one or more of surfactants such as dispersing agents, stabilizers, wetting agents, adhesives, defoamers, etc. kind.
  • the specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules (dry suspensions), water emulsions, and microemulsions.
  • composition of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations.
  • composition of the present invention can be applied to the leaves of plants to be treated by spraying, that is, applied to weeds, especially on the surfaces that are infested or easily affected by weeds.
  • the present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling the growth of unwanted plants, which includes applying the herbicidal composition to plants, plant parts, and plants.
  • the herbicidal composition is used to selectively control weeds in useful crops. More preferably, the useful crops are transgenic crops or crops processed by genome editing technology.
  • the compounds of the invention can be used to treat all plants and plant parts.
  • Plant varieties and cultivated lines can be obtained through conventional propagation and breeding methods or through genetic engineering methods.
  • Genetically modified plants are those in which a heterologous gene (transgene) has been stably integrated into the genome of the plant.
  • the transgene defined by its specific position in the plant genome is called a transformation event or a transgenic event.
  • the genetically modified plant cultivars that can be treated according to the present invention include those resistant to one or more biotic stresses (pests, such as nematodes, insects, mites, fungi, etc.) or abiotic stresses (drought, low temperature, soil salinization) Etc.), or it contains other desired features. Plants can be genetically modified to exhibit traits, such as herbicide tolerance, insect tolerance, modified oil characteristics, or drought tolerance. Available genetically modified plants containing a single genetic transformation event or a combination of transformation events are listed in Table 1. Additional information about the genetic modifications listed in Table 1 can be obtained from publicly available databases maintained, for example, through the United States Department of Agriculture.
  • T1 to T37 are used for the traits in Table 1. "-" means that the entry is not available.
  • the herbicidal composition of the present invention When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities of a single herbicide and the activity of a single herbicide.
  • the synergistic effect is manifested by reduced application rate, wider weed control spectrum, faster and longer weeding action, these characteristics are required in the process of weed control practice.
  • these new compositions are significantly superior to existing herbicides, achieve reduced usage, and are more environmentally friendly.
  • composition of the present invention is environmentally friendly and is easily degraded in the environment.
  • the herbicidal composition of the present invention has low cost and convenient use, and its popularization and application have huge economic and social benefits.
  • dispersible oil suspension agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned dispersible oil suspension agent processing process put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally shear evenly in the shearing machine. After the test is qualified, transfer To the storage tank for filling.
  • the above-mentioned water suspension agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned water suspension agent processing process put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally cut uniformly in the shearing machine, and transfer to the storage after the test is qualified. Can filling.
  • suspoemulsion processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • suspoemulsion processing process put part of the materials and additives into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and transfer to the intermediate tank as the water phase after the sand mill is completed; Put part of the original medicine and cosolvent into the batching kettle, stir and dissolve until it is completely transparent, and stir evenly into the oil phase; finally, open the shear in the shearing kettle, and slowly drip the oil phase into the water phase, after all the materials are dripped , Continue to cut for 1 hour, after passing the test, transfer to the storage tank for filling.
  • the above-mentioned water emulsion processing equipment vacuum pump, batching kettle, storage tank, shearing kettle.
  • the above-mentioned water emulsion processing process Put the original medicine and solvent into the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir evenly into the oil phase, and then pump the glycol, defoamer and deionized water into the shear In the kettle, finally, under the shearing state, the oil phase is slowly drawn into the shearing kettle. After all the materials are drawn in, continue to shear for 1 hour. After passing the test, transfer to the storage tank for filling.
  • microemulsion processing equipment vacuum pump, batching kettle, storage tank.
  • microemulsion processing process put the original drug and solvent into the batching kettle, stir and dissolve until completely transparent, then add the emulsifier, stir evenly, finally add deionized water, stir until the solution is completely transparent, and transfer to the storage tank after the test Filling.
  • the above-mentioned emulsifiable concentrate processing process put the original medicine and solvent into the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir evenly until the solution is completely transparent, and transfer to the storage tank for filling after passing the test.
  • liquid processing equipment vacuum pump, batching kettle, storage tank.
  • the above-mentioned water preparation process put the original medicine and deionized in the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir until the solution is completely transparent, and transfer to the storage tank for filling after passing the test.
  • the above-mentioned weeds are cultivated in pots. They are placed in an enamel tray in a 180 ⁇ 140mm plastic nutrient bowl, containing the top soil (4/5) collected from the farmland and air-dried and sieved. The soil moisture is initially controlled at 20%. Select Weed seeds with full and uniform grains, soaked in warm water at 25°C for 6 hours, incubate germination in a biochemical incubator (dark) at 28°C, evenly place the white weed seeds on the soil surface, and cover with 0.5 soil according to the size of the seed. -1cm.
  • 3WP-2000 walking spray tower Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
  • the required active ingredient A comes from the patent CN201911321469.4.
  • the preparation examples of representative compounds are as follows, and the synthesis methods of other compounds are similar, so they will not be repeated.
  • the required active ingredients B, cicloflurzone, carfentrazone, flufentrazone, and trifentrazone are produced by the company, and the others are purchased by the reagent company.
  • the original medicines all use acetone as the solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and are now diluted.
  • the action characteristics and toxicities of the two agents should be measured, and the main purpose of the formulation should also be considered.
  • the single and mixed dosages of A and B active ingredients are shown in the table respectively. Use water without medicament and with the same solvent and emulsifier as a blank control.
  • Each treatment was repeated 4 times, 3 pots per treatment each time, 20 weed seeds were sown in each pot, and a total of 60 plants per treatment.
  • the whole seedling of the surviving weed was cut along the soil surface with a blade, and the fresh weight of the weed was weighed with an analytical balance. For weeds that have died, the fresh weight is zero.
  • E-E0 value greater than 10% is synergistic effect, less than -10% is antagonistic effect, and between -10% and 10% is additive effect.
  • X is the fresh weight inhibition rate when the amount of active ingredient A is P
  • Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
  • the test soil is quantitatively filled to 3/4 of the pot, and then watered from the bottom of the pot to make the soil completely wet to a saturated state. Spread the pretreated weed seeds evenly and quantitatively on the surface, cover 0.5-2cm of soil according to the seed size, and reserve 24 hours after sowing.
  • GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory), pipettes, etc.
  • Table 17 The actual control effect and joint effect evaluation of A2 mixed quizalofop-p-ethyl on barnyardgrass
  • Table 128 The actual control effect and joint effect evaluation of A3 mixed pyrenpyrazone on wild rape
  • Table 130 The actual control effect and joint effect evaluation of A4 mixed triazole sulcotrione on paddy field barnyardgrass
  • Table 135 The actual control effect and joint effect evaluation of A4 mixed isoxaflutole on paddy field barnyardgrass
  • the herbicide composition prepared in Examples 1-150 was used to conduct field weed effect tests.
  • Stem and leaf treatment When the weeds are in the 3-5 leaf stage, use a manual sprayer, with a water volume of 30 kg/667m 2 , and use stem and leaf spray treatment.
  • Table 151 The specific test agents and doses are shown in Table 151.
  • the plot area is 50 square meters, and each treatment is repeated 4 times. See Table 151 for the investigation of the control effect 45 days after application.
  • Example number Dosage (g a.i./ha) Fresh weight control effect (%) 1 150 97.8 2 180 95.6 3 210 93.8 4 150 98.3 5 180 95.2 6 210 94.6 7 150 97.5 8 180 96.7 9 210 94.9 10 180 96.6 11 210 96.7 12 240 94.1 13 124.5 97.1 14 154.5 96.3 15 184.5 94.9 16 150 96.3 17 180 97.8 18 210 95.2 19 210 95.4 20 240 97.8 twenty one 270 94.4 twenty two 270 95.9 twenty three 300 97.4 twenty four 330 95.2 25 180 95.1 26 210 98.9 27 240 95.5 28 270 94.2
  • the present invention unexpectedly discovered that the composition is used for the prevention and control of Amaranthus amaranthus, Amaranthus retroflexus, Amaranthus amaranthus, Solanum vulgaris, Channa intestines, Pork Salmon, Eleutherococcus sp Mother-in-law, Arabian mother-in-law, cow chickweed, chickweed, wild rape, Polygonum clove, Moshangcai, cocory, sorrel, chinensis, cocklebur, artemisia sowing, quinoa, dayflower, round Leaf morning glory and other broad-leaved weeds, Kan Mai Niang, Japanese Mai Niang, Chrysanthemum japonicum, Western barnyardgrass, Paddy barnyardgrass, Echinochloa crusgalli, Setaria viridis, Green Setaria, Golden Setaria, Crabgrass, gooseweed, Sawgrass Grasses and other gramineous weeds have surprising and unexpected synergistic effects

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Abstract

The present invention relates to the field of pesticides, and specifically relates to a herbicidal composition containing R-type pyridyloxy carboxylic acid derivatives and an application thereof. The composition comprises an active ingredient A and an active ingredient B that have an effective amount of herbicide, wherein the active ingredient A is selected from one or more of an R-type pyridyloxy carboxylic acid as shown in formula I as well as salts and ester derivatives thereof: (I) wherein R1 and R2 independently represent halogen, C1-C6 alkyl, halo C1-C6 alkyl and C3-C6 cycloalkyl respectively; R3 represents hydrogen, halogen, C1-C6 alkyl and halogenated C1-C6 alkyl; Q represents C1-C6 alkyl or the like; and Y represents amino or the like. The active ingredient B is selected from one or more of the following compounds and salts/esters thereof: ALS inhibitor, ACCase inhibitor, PSII inhibitor, HPPD inhibitor, PDS inhibitor, DOXP inhibitor and PPO inhibitor. The described composition may effectively control various weed problems such as gramineae or broadleaf in crop fields, and has the characteristics of expanding the weed-killing spectrum, reducing the application amount, being able to produce synergistic effects and disposing of resistant weeds.

Description

一种包含R型吡啶氧基羧酸衍生物的除草组合物及其应用Herbicidal composition containing R-type pyridyloxy carboxylic acid derivative and application thereof 技术领域Technical field
本发明属于农药领域，具体涉及一种包含R型吡啶氧基羧酸衍生物的除草组合物及其应用。The invention belongs to the field of pesticides, and specifically relates to a herbicidal composition containing an R-type pyridyloxy carboxylic acid derivative and an application thereof.
背景技术Background technique
化学除草是农田杂草防除中最为经济、有效的手段，但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂，容易造成杂草耐药和抗性演化等问题。除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点，是解决上述问题的最为有效的方法之一。因此生产上仍需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。Chemical weed control is the most economical and effective method for the control of weeds in farmland. However, long-term continuous high-dose use of chemical herbicides of a single species or a single mode of action is likely to cause problems such as weed resistance and resistance evolution. Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems. Therefore, there is still a need to develop herbicidal composition varieties with high safety, wide herbicidal spectrum, synergistic effect and solving the problem of resistant weeds in production.
发明内容Summary of the invention
为解决现有技术中存在的上述问题，本发明提供一种包含R型吡啶氧基羧酸衍生物的除草组合物及其应用。该组合物能有效防除作物田中的禾本科或阔叶类等各种杂草问题，具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。In order to solve the above-mentioned problems in the prior art, the present invention provides a herbicidal composition containing an R-type pyridyloxy carboxylic acid derivative and its application. The composition can effectively control various weed problems such as gramineous or broadleaf in crop fields, and has the characteristics of expanding the weed-killing spectrum, reducing the application amount, being able to produce synergistic effects, and solving resistant weeds.
一种包含R型吡啶氧基羧酸衍生物的除草组合物，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition containing an R-type pyridyloxy carboxylic acid derivative, comprising an effective amount of herbicidal active ingredient A and active ingredient B, wherein,
活性成分A选自如式Ⅰ所示的R型吡啶氧基羧酸及其盐、酯衍生物中的一种或多种：The active ingredient A is selected from one or more of the R-type pyridyloxy carboxylic acid and its salts and ester derivatives as shown in formula I:
Figure PCTCN2020081644-appb-000001
Figure PCTCN2020081644-appb-000001
其中，R 1、R 2分别独立地代表卤素、C1-C6烷基、卤代C1-C6烷基、C3-C6环烷基； Wherein, R 1 and R 2 each independently represent halogen, C1-C6 alkyl, halogenated C1-C6 alkyl, and C3-C6 cycloalkyl;
R 3代表氢、卤素、C1-C6烷基、卤代C1-C6烷基； R 3 represents hydrogen, halogen, C1-C6 alkyl, halogenated C1-C6 alkyl;
Q代表C1-C6烷基，卤代C1-C6烷基，C3-C6环烷基，C2-C6烯基，C2-C6炔基，卤素，氰基，氨基，硝基，甲酰基，C1-C6烷氧基，C1-C6烷硫基，C1-C6烷氧羰基，羟基C1-C6烷基，C1-C6烷氧基C1-C6烷基，氰基C1-C6烷基，C1-C6烷氨基C1-C6烷基，以及未取代或被选自C1-C6烷基、氰基、卤代C1-C6烷基、C1-C6烷基氨基、卤素和C1-C6烷氧基中的至少一个基团所取代的苯基、苄基、萘基、呋喃基、噻吩基、噻唑基、吡唑基、吡啶基或嘧啶基；Q represents C1-C6 alkyl, halogenated C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, halogen, cyano, amino, nitro, formyl, C1- C6 alkoxy, C1-C6 alkylthio, C1-C6 alkoxycarbonyl, hydroxy C1-C6 alkyl, C1-C6 alkoxy C1-C6 alkyl, cyano C1-C6 alkyl, C1-C6 alkane Amino C1-C6 alkyl group, and at least one unsubstituted or selected from C1-C6 alkyl group, cyano group, halogenated C1-C6 alkyl group, C1-C6 alkylamino group, halogen, and C1-C6 alkoxy group Phenyl, benzyl, naphthyl, furyl, thienyl, thiazolyl, pyrazolyl, pyridyl or pyrimidinyl substituted by the group;
Y代表氨基，C1-C6烷基氨基，C1-C6烷基羰基氨基，以及未取代或被选自C1-C6烷基、卤素、氰基、C1-C6烷基氨基、C1-C6烷氧基和卤代C1-C6烷基中的至少一个基团所取代的苯基羰基氨基、苄基氨基或呋喃基亚甲基氨基；Y represents amino, C1-C6 alkylamino, C1-C6 alkylcarbonylamino, and unsubstituted or selected from C1-C6 alkyl, halogen, cyano, C1-C6 alkylamino, C1-C6 alkoxy And a phenylcarbonylamino, benzylamino or furylmethyleneamino group substituted by at least one of the halogenated C1-C6 alkyl groups;
所述盐为金属盐、铵盐NH 4 +、伯胺盐R”NH 2、仲胺盐(R”) 2NH、叔胺盐(R”) 3N、季胺盐(R”) 4N +、多元胺盐、吗啉盐、N-甲基吗啉盐、哌啶盐、吡啶盐、氨基丙基吗啉盐、Jeff胺D-230盐、2,4,6-三(二甲基氨基甲基)苯酚和氢氧化钠的盐、C1-C16烷基锍盐(优选C1-C6烷基锍盐)、C1-C16烷基氧化锍盐(优选C1-C6烷基氧化锍盐)、C1-C16烷基鏻盐(优选C1-C6烷基鏻盐)或C1-C16烷醇鏻盐(优选C1-C6烷醇鏻盐)； The salt is metal salt, ammonium salt NH 4 + , primary amine salt R”NH 2 , secondary amine salt (R”) 2 NH, tertiary amine salt (R”) 3 N, quaternary amine salt (R”) 4 N + , polyamine salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropyl morpholine salt, Jeff amine D-230 salt, 2,4,6-tris(dimethyl Aminomethyl) phenol and sodium hydroxide salt, C1-C16 alkyl sulfonium salt (preferably C1-C6 alkyl sulfonium salt), C1-C16 alkyl sulfonium oxide salt (preferably C1-C6 alkyl sulfonium oxide salt), C1-C16 alkyl phosphonium salt (preferably C1-C6 alkyl phosphonium salt) or C1-C16 alkanol phosphonium salt (preferably C1-C6 alkyl phosphonium salt);
其中，R”分别独立地代表C1-C16烷基，被选自卤素、羟基、C1-C6烷氧基、C1-C6烷硫基、羟基C1-C6烷氧基中的一个或多个基团所取代的C1-C16烷基(优选C1-C6烷基)，C2-C12烯基(优选C2-C6烯基)，C2-C12炔基(优选C2-C6炔基)，C3-C12环烷基，未取代或被C1-C6烷基取代的苯基或苄基；Wherein, R" each independently represents a C1-C16 alkyl group, and is selected from one or more groups of halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, and hydroxy C1-C6 alkoxy. Substituted C1-C16 alkyl (preferably C1-C6 alkyl), C2-C12 alkenyl (preferably C2-C6 alkenyl), C2-C12 alkynyl (preferably C2-C6 alkynyl), C3-C12 cycloalkane Group, unsubstituted or substituted by C1-C6 alkyl phenyl or benzyl;
所述酯为
Figure PCTCN2020081644-appb-000002
其中，X代表O或S； The ester is
Figure PCTCN2020081644-appb-000002
Among them, X represents O or S;
M代表C1-C18烷基，卤代C1-C8烷基，未取代或被C1-C6烷基取代的C3-C6环烷基，C2-C6烯基，卤代C2-C6烯基，C2-C6炔基，C1-C6烷氧基，C1-C6烷氧羰基，C1-C6烷基磺酰基，氰基C1-C6烷基，硝基C1-C6烷基，C1-C6烷氧基C1-C6烷基，-(C1-C6烷基)-Z，
Figure PCTCN2020081644-appb-000003
以及未取代或被选自C1-C6烷基、卤代C1-C6烷基、氰基、C1-C6烷基氨基、卤素和C1-C6烷氧基中的至少一个基团所取代的苯基、
Figure PCTCN2020081644-appb-000004
四氢呋喃基、吡啶基、萘基、呋喃基、噻吩基、吡咯基、吡唑基或咪唑基； M represents C1-C18 alkyl, halogenated C1-C8 alkyl, C3-C6 cycloalkyl that is unsubstituted or substituted by C1-C6 alkyl, C2-C6 alkenyl, halogenated C2-C6 alkenyl, C2- C6 alkynyl, C1-C6 alkoxy, C1-C6 alkoxycarbonyl, C1-C6 alkylsulfonyl, cyano C1-C6 alkyl, nitro C1-C6 alkyl, C1-C6 alkoxy C1- C6 alkyl, -(C1-C6 alkyl)-Z,
Figure PCTCN2020081644-appb-000003
And unsubstituted or substituted with at least one group selected from C1-C6 alkyl, halogenated C1-C6 alkyl, cyano, C1-C6 alkylamino, halogen, and C1-C6 alkoxy ,
Figure PCTCN2020081644-appb-000004
Tetrahydrofuryl, pyridyl, naphthyl, furyl, thienyl, pyrrolyl, pyrazolyl or imidazolyl;
Z代表
Figure PCTCN2020081644-appb-000005
以及未取代或被选自C1-C6烷基、C1-C6烷氧基、C1-C6烷基氨基、卤代C1-C6烷基、氰基和卤素中的至少一个基团所取代的
Figure PCTCN2020081644-appb-000006
苯基、四氢呋喃基、吡啶基、吡唑基、噻吩基、呋喃基或萘基； Z stands for
Figure PCTCN2020081644-appb-000005
And unsubstituted or substituted by at least one group selected from C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, halogenated C1-C6 alkyl, cyano and halogen
Figure PCTCN2020081644-appb-000006
Phenyl, tetrahydrofuranyl, pyridyl, pyrazolyl, thienyl, furanyl or naphthyl;
R 4、R 5、R 6分别独立地代表氢，C1-C6烷基，C1-C6烷氧基羰基，以及未取代或被选自C1-C6烷基、C1-C6烷氧基、C1-C6烷基氨基、卤代C1-C6烷基、氰基和卤素中的至少一个基团所取代的苯基； R 4 , R 5 , and R 6 each independently represent hydrogen, C1-C6 alkyl, C1-C6 alkoxycarbonyl, and unsubstituted or selected from C1-C6 alkyl, C1-C6 alkoxy, C1- Phenyl substituted by at least one of C6 alkylamino, halogenated C1-C6 alkyl, cyano and halogen;
R 7代表C1-C6烷基、C2-C6烯基、
Figure PCTCN2020081644-appb-000007
R 7 represents C1-C6 alkyl, C2-C6 alkenyl,
Figure PCTCN2020081644-appb-000007
活性成分B选自以下化合物及其盐/酯中的一种或多种：The active ingredient B is selected from one or more of the following compounds and their salts/esters:
(1)ALS抑制剂：五氟磺草胺(CAS号:219714-96-2)、双草醚(CAS号:125401-92-5)、吡嘧磺隆(CAS号:93697-74-6)、烟嘧磺隆(CAS号:111991-09-4)、双氟磺草胺(CAS号:145701-23-1)、砜嘧磺隆(CAS号:122931-48-0)、咪草烟(CAS号:81335-77-5)、甲基咪草烟(CAS号:104098-48-8)、甲氧咪草烟(CAS号:114311-32-9)、甲嘧磺隆(CAS号:74222-97-2)、氯酯磺草胺(CAS号:147150-35-4)；(1) ALS inhibitors: Penoxsulam (CAS Number: 219714-96-2), Bispyrifen (CAS Number: 125401-92-5), Pyrimsulfuron (CAS Number: 93697-74-6) ), Nicosulfuron (CAS Number: 111991-09-4), Fenoxsulam (CAS Number: 145701-23-1), Susulfuron-methyl (CAS Number: 122931-48-0), Imazethapyr Tobacco (CAS Number: 81335-77-5), Imazethapyr (CAS Number: 104098-48-8), Imazethapyr (CAS Number: 114311-32-9), Metsulfuron (CAS No.: 74222-97-2), Chlorfentrazone (CAS No.: 147150-35-4);
(2)ACCase抑制剂：氰氟草酯(CAS号:122008-85-9)、炔草酯(CAS号:105512-06-9)、唑啉草酯(CAS号:243973-20-8)、烯草酮(CAS号:99129-21-2)、烯禾啶(CAS号:74051-80-2)、精喹禾灵(CAS号:100646-51-3)、精吡氟禾草灵(CAS号:79241–46–6)、高效氟吡甲禾灵(CAS号:72619-32-0)；(2) ACCase inhibitors: cyhalofop-butyl (CAS number: 122008-85-9), clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8) , Clethodim (CAS number: 99129-21-2), enoxydim (CAS number: 74051-80-2), quizalofop (CAS number: 100646-51-3), diflufenaop-ethyl (CAS number: 100646-51-3) (CAS number: 79241–46-6), high-efficiency fluroxypyr (CAS number: 72619-32-0);
(3)PSII抑制剂：莠去津(CAS号:1912-24-9)、异丙隆(CAS号:34123-59-6)、绿麦隆(CAS号:15545-48-9)、敌草隆(CAS号:330-54-1)、灭草松(CAS号:25057-89-0)、溴苯腈(CAS号:1689-84-5)、敌稗(CAS号:709-98-8)；(3) PSII inhibitors: atrazine (CAS number: 1912-24-9), isoproteron (CAS number: 34123-59-6), chlorotoluron (CAS number: 15545-48-9), enemy Caolong (CAS Number: 330-54-1), Benzoxon (CAS Number: 25057-89-0), Bromoxynil (CAS Number: 1689-84-5), Dilanopsis (CAS Number: 709-98) -8);
(4)HPPD抑制剂：环吡氟草酮(CAS号:1855929-45-1)、双唑草酮(CAS号:1622908-18-2)、苯唑氟草酮(CAS号:1992017-55-6)、三唑磺草酮(CAS号:1911613-97-2)、呋喃磺草酮(CAS号:473278-76-1)、硝磺草酮(CAS号:104206-82-8)、环磺酮(CAS号:335104-84-2)、苯唑草酮(CAS号:210631-68-8)、异噁唑草酮(CAS号:141112-29-0)、双环磺草酮(CAS号:156963-66-5)；(4) HPPD inhibitors: ciclofenac (CAS number: 1855929-45-1), fentrazone (CAS number: 1622908-18-2), flufentrazone (CAS number: 1992017-55) -6), mesotrione (CAS number: 1911613-97-2), fursotrione (CAS number: 473278-76-1), mesotrione (CAS number: 104206-82-8), Cyclosulfone (CAS number: 335104-84-2), oxaflutole (CAS number: 210631-68-8), isoxaflutole (CAS number: 141112-29-0), bicyclazone ( CAS number: 156963-66-5);
(5)PDS抑制剂：吡氟酰草胺(CAS号:83164-33-4)、氟咯草酮(CAS号:61213-25-0)；(5) PDS inhibitors: diflufenican (CAS number: 83164-33-4), flurochloridone (CAS number: 61213-25-0);
(6)DOXP抑制剂：异噁草松(CAS号:81777-89-1)；(6) DOXP inhibitor: clomazone (CAS number: 81777-89-1);
(7)PPO抑制剂：唑草酮(CAS号:128621-72-7)、氟磺胺草醚(CAS号:72178-02-0)、乙羧氟草醚(CAS号:77501-60-1)、乙氧氟草醚(CAS号:42874-03-3)、乳氟禾草灵(CAS号:77501-63-4)、三氟羧草醚(CAS号:50594-66-6)、丙炔氟草胺(CAS号:103361-09-7)、甲磺草胺(CAS号:122836-35-5)、苯嘧磺草胺(CAS号:372137-35-4)、噁草酮(CAS号:19666-30-9)、丙炔噁草酮(CAS号:39807-15-3)。(7) PPO inhibitors: carfentrazone (CAS number: 128621-72-7), fomesafen (CAS number: 72178-02-0), acifluorfen (CAS number: 77501-60-1) ), oxyfluorfen (CAS number: 42874-03-3), lactofen (CAS number: 77501-63-4), acifluorfen (CAS number: 50594-66-6), Flumetsulam (CAS Number: 103361-09-7), Sulfentrazone (CAS Number: 122836-35-5), Safentrazone (CAS Number: 372137-35-4), Oxachlor (CAS Number: 19666-30-9), Oxachlor (CAS Number: 39807-15-3).
优选地，R 1、R 2分别独立地代表氟、氯、溴、碘、甲基、乙基、丙基、异丙基、三氟甲基、环丙基； Preferably, R 1 and R 2 each independently represent fluorine, chlorine, bromine, iodine, methyl, ethyl, propyl, isopropyl, trifluoromethyl, and cyclopropyl;
R 3代表氢、氟、氯、溴、碘、甲基、三氟甲基； R 3 represents hydrogen, fluorine, chlorine, bromine, iodine, methyl, trifluoromethyl;
Q代表甲基，乙基，丙基，异丙基，环丙基，乙烯基，乙炔基，氟，氯，溴，氰基，氨基，硝基，甲酰基，甲氧基，甲硫基，甲氧羰基，一氯甲基，一氟甲基，二氟甲基，三氟甲基，2-氯乙基，2,2,2-三氟乙基，羟基甲基，
Figure PCTCN2020081644-appb-000008
苄基，萘基
Figure PCTCN2020081644-appb-000009
呋喃基
Figure PCTCN2020081644-appb-000010
吡啶基
Figure PCTCN2020081644-appb-000011
嘧啶基
Figure PCTCN2020081644-appb-000012
以及未取代或被氯取代的噻唑基
Figure PCTCN2020081644-appb-000013
未取代或被氟取代的噻吩基
Figure PCTCN2020081644-appb-000014
未取代或被甲基或氟取代的
Figure PCTCN2020081644-appb-000015
Figure PCTCN2020081644-appb-000016
未取代或被甲基、三氟甲基、氯和甲氧基中的至少一个基团所取代的苯基； Q represents methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, Methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2,2,2-trifluoroethyl, hydroxymethyl,
Figure PCTCN2020081644-appb-000008
Benzyl, naphthyl
Figure PCTCN2020081644-appb-000009
Furanyl
Figure PCTCN2020081644-appb-000010
Pyridyl
Figure PCTCN2020081644-appb-000011
Pyrimidinyl
Figure PCTCN2020081644-appb-000012
And unsubstituted or chloro-substituted thiazolyl
Figure PCTCN2020081644-appb-000013
Thienyl unsubstituted or substituted by fluorine
Figure PCTCN2020081644-appb-000014
Unsubstituted or substituted by methyl or fluorine
Figure PCTCN2020081644-appb-000015
Figure PCTCN2020081644-appb-000016
Unsubstituted or substituted by at least one of methyl, trifluoromethyl, chlorine and methoxy;
Y代表NH 2、
Figure PCTCN2020081644-appb-000017
Y stands for NH 2 ,
Figure PCTCN2020081644-appb-000017
所述盐为碱金属(如钠、锂、钾、铯和铷)盐，碱土金属(如钙、镁、钡和锶)盐，以及锑、铋、镉、铈、铬、钴、钪、钛、锰、铜、铁、银、金、锌、铝等金属的盐，胺盐例如铵盐、四甲基铵盐、四乙基铵盐、四丙基铵盐、四丁基铵盐、N-十六烷基三甲基胺盐、N-苄基三甲基铵盐、苄基三乙基铵盐、胆碱盐、一甲胺盐、二甲胺盐、三甲胺盐、一乙胺盐、二乙胺盐、三乙胺盐、正丙胺盐、二丙胺盐、三丙胺盐、一异丙胺盐、二异丙胺盐、三异丙胺盐、正丁胺盐、二丁胺盐、三丁胺盐、异丁胺盐、叔丁胺盐、戊胺盐、己胺盐、庚胺盐、辛胺盐、十二烷基胺盐、十四烷基胺盐、二烯丙基胺盐、环己胺盐、环十二烷基胺盐、苯胺盐、邻甲苯胺盐、间甲苯胺盐、对甲苯胺盐、二苯胺盐、苄胺盐、单乙醇胺盐、N-甲基单乙醇胺盐、N,N-二甲基乙醇胺盐、N-乙基单乙醇胺盐、N,N-二乙基乙醇胺盐、N-丙基单乙醇胺盐、N,N-二正丙基乙醇胺盐、N-丁基单乙醇胺盐、二乙醇胺盐、N-甲基二乙醇胺盐、N-乙基二乙醇胺盐、N-丙基二乙醇胺盐、N-丁基二乙醇胺盐、N,N-二丁基乙醇胺盐、三乙醇胺盐、三丙醇胺盐、三异丙醇胺盐、三(2-羟基丙基)胺盐、二甘醇胺盐、多元胺盐(如六亚甲基四胺盐、乙二胺盐、二亚乙基三胺盐、二甲基氨基丙胺盐、1,2-丙二胺盐、三乙烯二胺盐、三乙烯四胺盐、联苯胺盐、N,N-双[氨基丙基]甲胺盐)、2-甲基硫基丙胺盐、2-丁氧基乙胺盐、AEPD
Figure PCTCN2020081644-appb-000018
盐、三(羟甲基)氨基甲烷
Figure PCTCN2020081644-appb-000019
盐、吗啉盐、N-甲基吗啉盐、哌啶盐、吡啶盐、氨基丙基吗啉
Figure PCTCN2020081644-appb-000020
盐、Jeff胺D-230(
Figure PCTCN2020081644-appb-000021
n为2或3)盐、2,4,6-三(二甲基氨基甲基)苯酚和氢氧化钠的盐，锍盐如烷基锍盐(如三甲基锍盐、三乙基锍盐)、烷基氧化锍盐，鏻盐如烷基鏻盐或烷醇鏻盐； The salt is alkali metal (such as sodium, lithium, potassium, cesium and rubidium) salt, alkaline earth metal (such as calcium, magnesium, barium and strontium) salt, and antimony, bismuth, cadmium, cerium, chromium, cobalt, scandium, titanium , Manganese, copper, iron, silver, gold, zinc, aluminum and other metal salts, amine salts such as ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutylammonium salt, N -Cetyltrimethylamine salt, N-benzyltrimethylammonium salt, benzyltriethylammonium salt, choline salt, monomethylamine salt, dimethylamine salt, trimethylamine salt, monoethylamine Salt, diethylamine salt, triethylamine salt, n-propylamine salt, dipropylamine salt, tripropylamine salt, monoisopropylamine salt, diisopropylamine salt, triisopropylamine salt, n-butylamine salt, dibutylamine salt, three Butylamine salt, isobutylamine salt, tert-butylamine salt, pentylamine salt, hexylamine salt, heptylamine salt, octylamine salt, dodecylamine salt, tetradecylamine salt, diallylamine salt, ring Hexylamine salt, cyclododecylamine salt, aniline salt, o-toluidine salt, m-toluidine salt, p-toluidine salt, diphenylamine salt, benzylamine salt, monoethanolamine salt, N-methyl monoethanolamine salt, N,N-dimethylethanolamine salt, N-ethylmonoethanolamine salt, N,N-diethylethanolamine salt, N-propylmonoethanolamine salt, N,N-di-n-propylethanolamine salt, N-butyl Monoethanolamine salt, diethanolamine salt, N-methyldiethanolamine salt, N-ethyldiethanolamine salt, N-propyldiethanolamine salt, N-butyldiethanolamine salt, N,N-dibutylethanolamine salt , Triethanolamine salt, tripropanolamine salt, triisopropanolamine salt, tris(2-hydroxypropyl)amine salt, diglycolamine salt, polyamine salt (such as hexamethylenetetramine salt, ethylene two Amine salt, diethylenetriamine salt, dimethylaminopropylamine salt, 1,2-propanediamine salt, triethylenediamine salt, triethylenetetramine salt, benzidine salt, N,N-bis(amino Propyl]methylamine salt), 2-methylthiopropylamine salt, 2-butoxyethylamine salt, AEPD
Figure PCTCN2020081644-appb-000018
Salt, tris(hydroxymethyl)aminomethane
Figure PCTCN2020081644-appb-000019
Salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropyl morpholine
Figure PCTCN2020081644-appb-000020
Salt, Jeff Amine D-230 (
Figure PCTCN2020081644-appb-000021
n is 2 or 3) salt, salt of 2,4,6-tris(dimethylaminomethyl)phenol and sodium hydroxide, sulfonium salt such as alkylsulfonium salt (such as trimethylsulfonium salt, triethylsulfonium Salt), alkyl sulfonium oxide salt, phosphonium salt such as alkyl phosphonium salt or alkanol phosphonium salt;
所述Ⅰ-1中X代表O或S；X in said I-1 represents O or S;
M代表甲基，乙基，正丙基，异丙基，正丁基，仲丁基，异丁基，叔丁基，戊基，己基，庚基，辛基，壬基，癸基，十一烷基，十二烷基，十八烷基，三氟甲基，五氟乙基，3-氯丁基，2-氟乙基，2-氯乙基，2-溴乙基，2,2-二氟乙基，2,2,2-三氟乙基，4,4,4-三氟丁基，2,2,3,3,3-五氟丙基，环丙基，环丁基，环戊基，环己基，烯丙基，2-丙炔基，甲氧基，乙氧羰基，甲基磺酰基，
Figure PCTCN2020081644-appb-000022
Figure PCTCN2020081644-appb-000023
四氢呋喃基
Figure PCTCN2020081644-appb-000024
四氢呋喃基亚甲基
Figure PCTCN2020081644-appb-000025
吡啶基
Figure PCTCN2020081644-appb-000026
Figure PCTCN2020081644-appb-000027
吡啶基亚甲基
Figure PCTCN2020081644-appb-000028
萘基
Figure PCTCN2020081644-appb-000029
萘基亚甲 基
Figure PCTCN2020081644-appb-000030
呋喃基
Figure PCTCN2020081644-appb-000031
呋喃基亚甲基
Figure PCTCN2020081644-appb-000032
噻吩基
Figure PCTCN2020081644-appb-000033
噻吩基亚甲基
Figure PCTCN2020081644-appb-000034
Figure PCTCN2020081644-appb-000035
以及未取代或甲基取代的
Figure PCTCN2020081644-appb-000036
Figure PCTCN2020081644-appb-000037
未取代或被甲基、二甲基氨基、氯、甲氧基、三氟甲基或异丙基取代的苯基，未取代或被三氟甲基、溴、氯、氟、甲氧基、氰基或甲基取代的苄基； M represents methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, ten Monoalkyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2, 2-Difluoroethyl, 2,2,2-trifluoroethyl, 4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl Group, cyclopentyl, cyclohexyl, allyl, 2-propynyl, methoxy, ethoxycarbonyl, methylsulfonyl,
Figure PCTCN2020081644-appb-000022
Figure PCTCN2020081644-appb-000023
Tetrahydrofuranyl
Figure PCTCN2020081644-appb-000024
Tetrahydrofurylmethylene
Figure PCTCN2020081644-appb-000025
Pyridyl
Figure PCTCN2020081644-appb-000026
Figure PCTCN2020081644-appb-000027
Pyridylmethylene
Figure PCTCN2020081644-appb-000028
Naphthyl
Figure PCTCN2020081644-appb-000029
Naphthylmethylene
Figure PCTCN2020081644-appb-000030
Furanyl
Figure PCTCN2020081644-appb-000031
Furylmethylene
Figure PCTCN2020081644-appb-000032
Thienyl
Figure PCTCN2020081644-appb-000033
Thienyl methylene
Figure PCTCN2020081644-appb-000034
Figure PCTCN2020081644-appb-000035
And unsubstituted or methyl substituted
Figure PCTCN2020081644-appb-000036
Figure PCTCN2020081644-appb-000037
Unsubstituted or substituted by methyl, dimethylamino, chlorine, methoxy, trifluoromethyl or isopropyl phenyl, unsubstituted or substituted by trifluoromethyl, bromine, chlorine, fluorine, methoxy, Cyano or methyl substituted benzyl;
R’代表氢、甲基、乙基、二氟甲基。R'represents hydrogen, methyl, ethyl, difluoromethyl.
更优选地，活性成分A选自以下化合物中的一种或多种：More preferably, the active ingredient A is selected from one or more of the following compounds:
Figure PCTCN2020081644-appb-000038
Figure PCTCN2020081644-appb-000038
Figure PCTCN2020081644-appb-000039
Figure PCTCN2020081644-appb-000039
Figure PCTCN2020081644-appb-000040
Figure PCTCN2020081644-appb-000040
Figure PCTCN2020081644-appb-000041
Figure PCTCN2020081644-appb-000041
Figure PCTCN2020081644-appb-000042
Figure PCTCN2020081644-appb-000042
Figure PCTCN2020081644-appb-000043
Figure PCTCN2020081644-appb-000043
Figure PCTCN2020081644-appb-000044
Figure PCTCN2020081644-appb-000044
Figure PCTCN2020081644-appb-000045
Figure PCTCN2020081644-appb-000045
Figure PCTCN2020081644-appb-000046
Figure PCTCN2020081644-appb-000046
Figure PCTCN2020081644-appb-000047
Figure PCTCN2020081644-appb-000047
Figure PCTCN2020081644-appb-000048
Figure PCTCN2020081644-appb-000048
Figure PCTCN2020081644-appb-000049
Figure PCTCN2020081644-appb-000049
Figure PCTCN2020081644-appb-000050
Figure PCTCN2020081644-appb-000050
Figure PCTCN2020081644-appb-000051
Figure PCTCN2020081644-appb-000051
Figure PCTCN2020081644-appb-000052
Figure PCTCN2020081644-appb-000052
Figure PCTCN2020081644-appb-000053
Figure PCTCN2020081644-appb-000053
所述活性成分A的制备方法包括以下步骤：The preparation method of the active ingredient A includes the following steps:
将通式Ⅲ所示的化合物与通式Ⅱ所示的化合物进行反应制得通式I-1-1所示的化合物；其反应方程式如下：The compound represented by general formula III and the compound represented by general formula II are reacted to prepare the compound represented by general formula I-1-1; the reaction equation is as follows:
Figure PCTCN2020081644-appb-000054
Figure PCTCN2020081644-appb-000054
其中，W代表氢或碱金属，优选K、Na；Hal代表卤素，优选Br、Cl；所述反应在催化剂和溶剂的存在下进行，优选地，所述催化剂为TBAB，所述溶剂为DCM、DCE、ACN、THF、DMF中的一种或多种组合。Wherein, W represents hydrogen or alkali metal, preferably K, Na; Hal represents halogen, preferably Br, Cl; the reaction is carried out in the presence of a catalyst and a solvent, preferably, the catalyst is TBAB, and the solvent is DCM, One or more combinations of DCE, ACN, THF, and DMF.
将通式I-1-1所示的化合物在氢氧化锂水溶液和溶剂的存在下进行反应，制得通式I所示的化合物；其反应方程式如下：The compound represented by the general formula I-1-1 is reacted in the presence of a lithium hydroxide aqueous solution and a solvent to prepare the compound represented by the general formula I; the reaction equation is as follows:
Figure PCTCN2020081644-appb-000055
Figure PCTCN2020081644-appb-000055
优选地，所述溶剂选自甲醇、乙醇、异丙醇中的一种或多种组合。Preferably, the solvent is selected from one or more combinations of methanol, ethanol, and isopropanol.
将通式I所示的化合物与M-SH进行反应制得通式I-1-2所示的化合物；其反应方程式如下：The compound represented by general formula I is reacted with M-SH to prepare the compound represented by general formula I-1-2; the reaction equation is as follows:
Figure PCTCN2020081644-appb-000056
Figure PCTCN2020081644-appb-000056
其中，所述反应在脱水剂和溶剂的存在下进行，优选地，所述脱水剂为DCC，所述溶剂选自二氯甲烷、二氯乙烷、乙腈、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺、二甲亚砜、四氢呋喃、甲苯、二甲苯中的一种或多种组合。Wherein, the reaction is carried out in the presence of a dehydrating agent and a solvent. Preferably, the dehydrating agent is DCC, and the solvent is selected from the group consisting of dichloromethane, dichloroethane, acetonitrile, and N,N-dimethylformamide , N,N-dimethylacetamide, dimethylsulfoxide, tetrahydrofuran, toluene, xylene, one or more combinations.
或者当Y代表NR 1R 2(R 1、R 2不同时为氢)时，将通式I-2所示的化合物
Figure PCTCN2020081644-appb-000057
或通式I-1-3所示的化合物
Figure PCTCN2020081644-appb-000058
与相应卤代物进行反应制得； Or when Y represents NR 1 R 2 (R 1 and R 2 are not hydrogen at the same time), the compound represented by the general formula I-2
Figure PCTCN2020081644-appb-000057
Or the compound represented by the general formula I-1-3
Figure PCTCN2020081644-appb-000058
Prepared by reacting with corresponding halogenated substances;
其中，卤代物优选氯代物或溴代物；所述反应在碱和溶剂的存在下进行，所述碱选自氢氧化钠、氢氧化钾、碳酸钠、碳酸钾、碳酸氢钠和碳酸铯中的一种或两种以上；溶剂选自THF、1,4-二氧六环、甲苯、1,2-二氯乙烷、乙酸乙酯、乙腈、DMF、丙酮、二氯甲烷和氯仿中的一种或多种组合；所述反应过程中也可加入催化剂，优选DMAP。Among them, the halogenated compound is preferably a chlorinated compound or a brominated compound; the reaction is carried out in the presence of a base and a solvent, and the base is selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate and cesium carbonate. One or more than two; the solvent is selected from one of THF, 1,4-dioxane, toluene, 1,2-dichloroethane, ethyl acetate, acetonitrile, DMF, acetone, dichloromethane and chloroform One or more combinations; a catalyst can also be added during the reaction process, preferably DMAP.
所述盐为农药学上可接受的盐，较佳的为本发明所述R型吡啶氧基羧酸化合物与化学上可接受的碱性化合物反应生成。上述药学上可接受的盐容易分离，可采用常规分离方法提纯，如溶剂萃取、稀释、重结晶、柱色谱和制备薄层色谱等。The salt is a pesticide acceptable salt, preferably the R-type pyridyloxy carboxylic acid compound of the present invention is formed by reacting with a chemically acceptable basic compound. The above-mentioned pharmaceutically acceptable salts are easy to separate and can be purified by conventional separation methods, such as solvent extraction, dilution, recrystallization, column chromatography and preparative thin layer chromatography.
其中，A、B的重量比为1:100～100:1或1:50～50:1；优选为1:30～30:1或1:20～20:1；更优选为1:10～10:1或1:8～8:1；进一步优选为1:5～5:1或1:1～2:1。Among them, the weight ratio of A and B is 1:100-100:1 or 1:50-50:1; preferably 1:30-30:1 or 1:20-20:1; more preferably 1:10- 10:1 or 1:8 to 8:1; more preferably 1:5 to 5:1 or 1:1 to 2:1.
所述除草组合物中A和B的质量百分含量占总量的1-95％，优选10-80％。The mass percentage of A and B in the herbicidal composition accounts for 1-95%, preferably 10-80% of the total.
所述除草组合物中还包含常规助剂，所述常规助剂包括载体、表面活性剂。The herbicidal composition also contains conventional adjuvants, and the conventional adjuvants include carriers and surfactants.
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的施用，该载体一般是惰性的且必须是农业上可接受的，特别是被处理的植物所接受。载体可以是固体的，如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等；或者液体的，如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。The term "carrier" herein refers to an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient. The carrier is generally inert and must be agriculturally acceptable, especially acceptable to the plants being treated. The carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon, liquefied gas, etc.
表面活性剂可包括乳化剂、分散剂或润湿剂，它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐，以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚，此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、 木素亚硫酸盐废液，以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在，以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。The surfactant may include an emulsifier, dispersant or wetting agent, and it may be ionic or non-ionic. Examples that may be mentioned are the salts of polyacrylic acid, lignosulfonate, phenolsulfonic acid or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (in particular Alkylphenol or arylphenol) polymers, sulfosuccinates, taurine derivatives (especially taurine alkane esters) and alcohol phosphate esters or polyhydroxyethylated phenol phosphate esters, Alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl, heptadecyl and stearyl alcohols and sulfated fatty alcohols Glycol ether, in addition to naphthalene or naphthalene sulfonic acid and phenol and formaldehyde condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol or nonyl phenol, alkyl benzene Base polyethylene glycol ether, tributyl phenyl polyethylene glycol ether, tristearyl phenyl polyethylene glycol ether, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide condensate, ethoxy group Castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol polyethylene glycol ether acetal, sorbitol ester, lignin sulfite waste liquid, as well as protein, denatured protein, polysaccharide (such as Methyl cellulose), hydrophobically modified starch, polyvinyl alcohol, polycarboxylate, polyalkoxylate, polyvinylamine, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to facilitate the dispersion of the active ingredients in water and facilitate their proper application to plants.
上述组合物也可含有各种其他的组分，如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。The above composition may also contain various other components, such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants and polymers.
另外，本发明的组合物可以与以下活性物质混合，例如《世界农药新品种技术大全》，中国农业科学技术出版社，2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活性物质，(备注:化合物的名称，或者为根据国际标准化组织(ISO)的普通名称，或者为化学名称，适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、氯磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、 草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二 甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、三唑磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489，LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。In addition, the composition of the present invention can be mixed with the following active substances, such as "Encyclopedia of World Pesticide New Variety Technologies", China Agricultural Science and Technology Press, 2010.9 and known substances in the literature cited here. For example, the herbicide active substances mentioned below, (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, and the code when appropriate): acetochlor, butachlor, Alachlor, Propolachlor, Metolachlor, Refined Metolachlor, Pretilachlor, Tetrachlor, Metochlor, Napropionate, R-Naphtochlor, Propanochlor , Mefenacet, difenacet, diflufenican, chlorfenazone, flubutazone, bromobutyrazamide, dimethenamid, high-efficiency dimethenamid, ethoxylate Apifenacet, flufenacet, metolachlor, metazachlor, clomazone, high-efficiency wheat straw voltambufen, high-efficiency wheat straw vopropion ester, propenicamide, clenamid, butachlor, Ciprofen, Fometochlor, Enantholac, Ibutachlor, Propitrazone, Terbutachlor, Dimethochlor, Dimethochlor, Tolchlor, Trimethochlor, Chlorine Carbachlor, propargyl, propachlor, valericola, carbachlor, new Yanling, tricyclic chlorfenachlor, butenamid, formachlor, promethazine, quinolachlor, fenfluramide , Naprolamine, Acetolachlor, Naphthochlor, Fenoxamide, Mefentrazone, Promethazine, Mecrazol, Chlorophthalimide, Butamidine, Flumetazol, Atrazine, Simazine, promethazine, cyanochloride, sichuanjing, atrazine, promethazine, promethazine, fluroxypyr, terbutazone, terbutazone, triazine, fluroxypyr, cyproteren, glycine Protoxine, oxadine, tetradone, simatong, azide, diquat, isoprene, cyproterenol, meton, other dingjin, tributin, terbutin, methoxine Jing, cyanochloride, indosulfuron, colasin, atrtoton, metoxetone, glycyrrhizin, cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron-methyl, bensulfuron-methyl, chlorsulfuron-methyl, benzenesulfuron Trisulfuron, Thisulfuron-methyl, Pyrimsulfuron-methyl, Disulfuron-methyl, Mesosulfuron-methyl sodium salt, Formamisulfuron-methyl, Trisulfuron-methyl, Trisulfuron-methyl, Mesulfuron-methyl, Nicosulfuron , Sulfamesulfuron, sulfamesulfuron, ethoxysulfuron, ciprosulfuron, sulfonesulfuron, tetrazosulfuron, flazasulfuron, monosulfuron, monosulfuron, fluoro Zolsulfuron, fluflusulfuron-methyl, flufensulfuron-methyl, episulfuron-methyl, zoflusulfuron-methyl, flumisulfuron-methyl, propitrifosulfuron, trifluprosulfuron, sulfenylsulfuron, three Flufensulfuron, fluasulfuron-methyl, triflusulfuron-methyl, metsulfuron-methyl sodium salt, flufenuron-methyl, metsulfuron-methyl, sulfasulfuron-methyl, Propyrisulfuron (propyrisulfuron), pyripyrazine Sulfur-methyl, acifluorfen, fomesafen, lactofop-p-ethyl, oxyfluorfen, oxyfluorfen, cyflufen, aclofen, chloroflufen-ethyl, carbaryl Ether, fenflufen, methoxyfen, fenflufen, fluorfen, fenflufen, fenfen, chlorfenpyr, dimethyl fluoride, flufenoxafen, flufenopyr Ester, Halosafen, Chlorotoluron, Isoproturon, Liururon, Diuron, Saprouron, Flururon, Benthiuron, Tribenthiuron, Probenuron, Sulthiuron, Isoxauron, Tebuthiouron, clodinafop, chlorobromuron, metoxyuron, oxyuron, metoxyuron, bromosulfuron, methoxuron, chlorosulfuron, meturon, cycluron, Fenuron, fluthiouron, sulfuron, chloruron, Chloropyron, Isofluron, Cyclomethuron, Thiefuron, Buthiuron, Cyclomethuron, P-Furon, Metthiazolone, Proponol, Trimethurea, Oxazolon, Monosouron, Anisuron, Methiuron, Chloreturon, Tetrafluron, Betanin, Betanin-Ethyl, Betalan, Sulfentrazone, Teraline, Omatyl, Aniline, Chlorophenazine, Diclofenac, Mediafen, Chlorinyl, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, butachlor, chlorprocarb, dimethoate, chlorpyrifolia, dicamba, dimethoprim, chlorpyrifos, barnyardgrass, cyclamate, oatmeal, Jundamid, ethionate, Pingcaodan, Kecaomeng, Prosoprin, Zhongcaodan, Thiochloride, Methiophene, Isopolinate, Methiobencarb, 2,4-D isooctyl butyl ester, 2 Methane 4-sodium chloride, 2,4-D isooctyl isooctyl ester, 2-methyl 4-chloro isooctyl ester, 2,4-D isooctyl sodium salt, 2,4-D isooctyl dimethylamine salt, 2 Methyl 4-chloroethyl thioester, 2-methyl 4-chloro, 2,4-D isooctyl propionate, high 2,4-D isooctyl propionate, 2,4-D isooctyl butyrate, 2-methyl-4 Chloropropionic acid, 2-methyl 4-chloropropionate, 2-methyl 4-chlorobutyric acid, 2,4,5-chlorobutyric acid, 2,4,5-butyropropionic acid, 2,4,5-butyric acid, 2-methyl-4 Chloramine salt, dicamba, imidacloprid, fenoxac, thysson, triclofenac, diclofenac, methicillin, dimethoprim, difluoxyfop, diflufenop-fon Meclofen, fluroxypyr, high-efficiency fluoxyfop, quizalofop, quizalofop-p-ethyl, fenoxaprop-p-ethyl, fenoxaprop-p-ethyl, oxalofop-ethyl, cyhalofop-ethyl, oxazoyl Meclopropamide, clodinafop-propargyl, thiazoxyprop-p-ethyl, propaprofen, pentoxyprop-p-ethyl, fluoropropoxime, clomazone, paraquat, diquat, fensulfa-ethyl, ethalofop-p-ethyl, isopropanol Propiralin, Methalpropalin, Ciprofluramide, Alanoflurane, Ebutaflupine, Chlorideflurane, Aceflurane, Dilotin, Chloridedilotin, Methalpropalin, Pronofol, Propanidol, Methalpropalin, Propiflurazin, Methalpropalin, Propiflurazin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Methalpropalin, Glyphosate, barnylphosate, glufosinate-ammonium, methamidophos, glufosinate, fenoxaphos, bialaphos, diazin, glufosinate, tridolin, valonate, and methamphetamine Phosphorus, glufosinate, imidazole nicotinic acid, imazapyr, imazaquin acid, imazamox, imazamox ammonium salt, imazamox, imazamox, fluroxypyr, fluroxypyr Isooctyl acetate, diclopyralic acid, pyralidine acid, piclopyroxyacetic acid, fluthiopyr, halodichlor, triclopyr, thiaclopyr, flupyridin, clopyralid, fluorine Metatrazone, Butoxyethyl Triclopyr, Cliodinate, Sethoxydim, Clethodim, Thiochlor, Mefenacet, Cyclofenone, Buclofenone, Ometrione, Pyramid Ketone, Buthidazole, Mesotrione, Ciclozinone, Mefentrazone, Eetazimone, Ametridione, Amibuzin, Bromoxynil, Bromoxynil, Caprylyl iodobenzonitrile, Iodobenzonitrile, Dioxalon, Diphenylacetonitrile, difentrazone, acetonitrile, I odobonil, flumetsulam, flumetsulam, penoxsulam, sulfentrazone, chlorfentrazone, flumetsulam, flumetsulam, flumetsulam, sulfentrazone, Saflufenacil, cyfentrazone, safentrazone, sulfentrazone, bicyclazone, mesotrione, sulcotrione, tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlor Methiozolin, Fenoxasulfone, Methiozolin, Fenoxasulfone, Metatrachlor, Pyrazolate, Pyrenoxazole, Prozac, Metazachlor, Metachlorfen, Pyrasulfotole, Fenoxasulfone, Pyroxasulfone, Carfentrazone , Flufentrazone, chlorfenazone, amicarbazone, fentrazone, flufentrazone, sulfentrazone, Bencarbazone, difentrazone, fluprofen-ethyl, clomazone, clomazone , Cyclofen, Teroxalin, Flupropacil, Indoxacil, flufenoxalic acid, flumioxazin, clodinafop, phthalobenzyl ether, Flumezin, pentachlorophenol (sodium), dioxal, Tetra Phenol, tromethoxetate, pentonitrophenol, dinitrophenol, chloronitrophenol, dioxin, dioxin, oxadiazon, oxadiazon, penoxazone, flufentrazone, fenoxalic acid Ester, Tetrafentrazone, Fluridazep-ethyl, Fluroxypyr, Bromoatramine, Dimethachlor, Pyridoxazone, Fluridone, Trichlorfon, Pyridazole, Pyridafol, Quinclorac , Quinclorac, Bentasone, pyridachlor, oxazimione, chlordiazepoxide, clomazone, cyprofen, isoprofen, propylafen, indoxazone, chlorine Sodium, thatchquat, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, forage fast, bromophenol oxime, triazole sulfonate, metoxazole, furachlor, sulfachlor, sulfachlor , Sulfentrazone, chlorophthalic acid, flurochloridone, barnyardzein, acrolein, promethazine, dimethacin, oatester, thiadimethalin, mesamine, oxytodone, methoxyphenone , Saflufenazone, Phosphosinate, Trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, Methiopyridine, Cambendichlor, Cipronic acid , Thiocyanamide, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, chlorfenazone, pyrazolam, and furanolysis Oxazole, oxachlor, oxazole acid, dichloropropenamine, fluclopyridine, DOW fluclopyridine, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC- 330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482 , PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
所述除草组合物进一步包括至少一种安全剂，其选自：The herbicidal composition further includes at least one safener selected from:
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物，优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1，吡唑解草酯(mefenpyr-diethyl)，PM，第594-595页)，以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。a) Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds, the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl Ethyl-2-pyrazoline-3-carboxylate (S1-1, mefenpyr-diethyl, PM, p. 594-595), and described in, for example, WO91/07874 and PM (p. 594-595) 594-595 pages) related compounds.
b)二氯苯基吡唑羧酸衍生物，优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5)，以及记载于EP-A-333131和EP-A-269806中的相关化合物。b) Dichlorophenylpyrazole carboxylic acid derivatives, the preferred compound is, for example, 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-Dichlorophenyl)-5-(1 ,1-Dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4), 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
c)三唑羧酸(S1)类化合物，优选的化合物为例如解草唑(fenchlorazole)，即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。c) Triazole carboxylic acid (S1) compounds, the preferred compound is, for example, fenchlorazole, namely 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1 , 2,4-Triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物，优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物，或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9，双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。d) 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid compound, preferably The compound is, for example, 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid Ethyl acid (S1-8) and related compounds described in WO91/08202, or 5,5-diphenyl-2-isoxazoline described in patent application (WO-A-95/07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-11).
e)8-喹啉氧基乙酸(S2)类化合物，优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1，解毒喹(cloquintocet-mexyl)，如PM(第195-196页)，(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2)，4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3)，1-烯丙基氧基丙-2-基(5-氯-8-喹 啉氧基)乙酸酯(S2-4)，(5-氯-8-喹啉氧基)乙酸乙酯(S2-5)，(5-氯-8-喹啉氧基)乙酸甲酯(S2-6)，(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7)，2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8)，2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9)，以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。e) 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (pages 195-196), (1,3-dimethylbut-1-yl)(5-chloro-8-quinolinoxy)acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy) Yl) acetate (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5), (5-chloro-8-quinolinoxy) methyl acetate (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2-(2-propylene iminooxy)-1-ethyl (5-chloro-8- Quinolinoxy) acetate (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy) acetate (S2-9), and described in EP-A -86750, EP-A-94349 and EP-A-191736 or EP-A-0492366 related compounds.
f)(5-氯-8-喹啉氧基)丙二酸类化合物，优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。f) (5-Chloro-8-quinolinyloxy)malonic acid compounds, preferred compounds are, for example, (5-chloro-8-quinolinyloxy)diethyl malonate, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy)-malonate methyl ethyl ester and related compounds described in EP-A-0582198.
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物，例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acid active compounds, such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
h)嘧啶类活性化合物，例如“解草啶(fenclorim)”(PM，第386-387页)(＝4,6-二氯-2-苯基嘧啶)，h) Pyrimidine active compounds, such as "fenclorim" (PM, pages 386-387) (=4,6-dichloro-2-phenylpyrimidine),
i)二氯乙酰胺类活性化合物，其常用作苗前安全剂(作用于土壤的安全剂)，例如“二氯丙烯胺(dichloromid)”(PM，第270-271页)(＝N,N-二烯丙基-2,2-二氯乙酰胺)，“AR-29148”(＝3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮，购自Stauffer)，“解草嗪(benoxacor)”(PM，第74-75页)(＝4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪)，“APPG-1292”(＝N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺，购自PPG Industries)，“ADK-24”(＝N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺，购自Sagro-Chem)，“AAD-67”或“AMON4660”(＝3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷，购自Nitrokemia或Monsanto)，“diclonon”或“ABAS145138”或“ALAB145138”(＝(＝3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷，购自BASF)，和“furilazol”或“AMON13900”(参见PM，482-483)(＝(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮)，i) Dichloroacetamide active compounds, which are often used as pre-emergence safeners (safeners acting on soil), such as "dichloromid" (PM, pages 270-271) (=N, N -Diallyl-2,2-dichloroacetamide), "AR-29148" (=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidinone, purchase From Stauffer), "benoxacor" (PM, pages 74-75) (=4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzo Oxazine), "APPG-1292" (=N-allyl-N[(1,3-dioxolane-2-yl)-methyl]dichloroacetamide, purchased from PPG Industries), "ADK -24" (=N-allyl-N-[(allylaminocarbonyl)-methyl]-dichloroacetamide, purchased from Sagro-Chem), "AAD-67" or "AMON4660" (=3 -Dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane, purchased from Nitrokemia or Monsanto), "diclonon" or "ABAS145138" or "ALAB145138" (=(=3-two Chloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonane, purchased from BASF), and "furilazol" or "AMON13900" (see PM, 482-483 )(=(RS)-3-Dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidinone),
j)二氯丙酮衍生物类活性化合物，例如，“AMG191”(CAS登记号96420-72-3)(＝2-二氯甲基-2-甲基-1,3-二氧戊环，购自Nitrokemia)，j) Active compounds of dichloroacetone derivatives, for example, "AMG191" (CAS Registration No. 96420-72-3) (=2-Dichloromethyl-2-methyl-1,3-dioxolane, purchased From Nitrokemia),
k)氧基亚氨基化合物类活性化合物，其被称为拌种材料，例如，“解草腈(oxabetrinil)”(PM，第689页)(＝(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，“氟草肟(fluxofenim)”(PM，第467-468页)(＝1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM，第983页)(＝(Z)-氰基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，k) Oxyimino compound-type active compounds, which are called seed dressing materials, for example, "oxabetrinil" (PM, page 689) (=(Z)-1,3-dioxolane -2-ylmethoxyimino (phenyl)acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor, "fluxofenim" (PM, Pages 467-468) (=1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3-dioxolane-2-ylmethyl)- Oxime, which is called a safener in seed dressing to prevent metolachlor damage, and "cyometrinil" or "A-CGA-43089" (PM, p. 983) (=(Z)-cyanomethoxyimino(phenyl)acetonitrile), which is called a safener in seed dressing to prevent the damage of metolachlor,
l)噻唑羧酸酯类活性化合物，其被称为拌种材料，例如“解草安(flurazol)”(PM，第450-451页)(＝2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯)，其在拌种中被称为安全剂，以防止甲草胺(alachlor)和异丙甲草胺的损害，1) Thiazole carboxylate active compounds, which are called seed dressing materials, such as "flurazol" (PM, pages 450-451) (=2-chloro-4-trifluoromethyl-1 , 3-thiazole-5-carboxylic acid benzyl ester), which is called a safener in seed dressing to prevent the damage of alachlor and metolachlor,
m)萘二羧酸衍生物类活性化合物，其被称为拌种剂，例如“萘二甲酸酐”(PM，第1009-1010页)(＝1,8-萘二甲酸酐)，其在玉米拌种中称为安全剂，以防止硫代氨基甲酸酯除草剂的损害，m) Active compounds of naphthalenedicarboxylic acid derivatives, which are called seed dressing agents, such as "naphthalenedicarboxylic acid anhydride" (PM, pages 1009-1010) (=1,8-naphthalenedicarboxylic acid anhydride), which is It is called a safener in corn dressing to prevent the damage of thiocarbamate herbicides.
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物，例如，“ACL304415”(CAS登记号31541-57-8)(＝2-84-羧基色满-4-基)乙酸，购自AmericanCyanamid)，n) Active compounds of chromaneacetic acid derivatives, for example, "ACL304415" (CAS registration number 31541-57-8) (=2-84-carboxychroman-4-yl)acetic acid, purchased from AmericanCyanamid),
o)除了对有害植物具有除草作用外还对植物具有安全剂作用的活性化合物，例如，“哌草丹(dimepiperate)”或“AMY-93”(PM，第302-303页)(＝S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯)，“杀草隆(daimuron)”或“ASK23”(PM，第247页)(＝1-(1-甲基-1-苯基乙基)-3-对甲苯基脲)，“苄草隆(cumyluron)”＝“AJC-940”(＝3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲，参见JP-A-60087254)，“苯甲酮(methoxyphenon)”或“ANK049”(＝3,3'-二甲基-4-甲氧基-二苯甲酮)，“CSB”(＝1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4，购自Kumiai)。o) In addition to having herbicidal effects on harmful plants, active compounds that also have safener effects on plants, for example, "dimepiperate" or "AMY-93" (PM, pages 302-330) (=S- 1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "daimuron" or "ASK23" (PM, p. 247) (=1-(1-methyl -1-phenylethyl)-3-p-tolylurea), "cumyluron (cumyluron)"="AJC-940" (=3-(2-chlorophenylmethyl)-1-(1 -Methyl-1-phenyl-ethyl)urea, see JP-A-60087254), "methoxyphenon" or "ANK049" (=3,3'-dimethyl-4-methoxy -Benzophenone), "CSB" (= 1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Registry Number 54091-06-4, purchased from Kumiai).
所述安全剂优选双苯噁唑酸(CAS：163520-33-0)、cyprosulfamide(CAS：221667-31-8)、吡唑解草酯(CAS：135590-91-9)、解毒喹(CAS：99607-70-2)、赤霉酸(CAS：7-06-5)、furilazole(CAS：121776-33-8)、metcamifen(CAS：129531-12-0)中的一种或多种。The safener is preferably dibenzoxazole acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolone (CAS: 135590-91-9), detox quinine (CAS : 99607-70-2), one or more of gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
在本说明书的上下文中，如果使用活性化合物的通用名称的缩写形式，则在每种情况下包括所有的常规衍生物，例如酯和盐，以及异构体，特别是光学异构体，特别是一种或多种市售形式。如果通用名称表示酯或盐，则在每种情况下还包括所有其他的常规衍生物，例如其他的酯和盐、游离酸和中性化合物，以及异构体，特别是光学异构体，特别是一种或多种市售形式。给出的化合物的化学名称表示至少一种被通用名称涵盖的化合物，通常是优选的化合物。在磺酰胺如磺酰脲的情况下，盐还包括通过阳离子与磺酰胺基团中的氢原子交换而形成的盐。例如，2甲4氯衍生物包含但不限于：2甲4氯钠盐、钾盐、二甲铵盐、异丙胺盐等，以及2甲4氯甲酯、乙酯、异辛酯、乙硫酯等；2,4-D衍生物包含但不限于：2,4-D盐如钠盐、钾盐、二甲铵盐、三乙醇铵盐、异丙胺盐、胆碱等，以及2,4-D酯如甲酯、乙酯、丁酯、异辛酯等。In the context of this specification, if the abbreviated form of the common name of the active compound is used, all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, especially One or more commercially available forms. If the generic name indicates an ester or salt, it also includes all other conventional derivatives in each case, such as other esters and salts, free acids and neutral compounds, as well as isomers, especially optical isomers, especially Is one or more commercially available forms. The chemical name of the given compound indicates at least one compound covered by the generic name, and is usually the preferred compound. In the case of sulfonamides such as sulfonylureas, salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2 methyl 4 chloro derivatives include but are not limited to: 2 methyl 4 chloride sodium salt, potassium salt, dimethyl ammonium salt, isopropylamine salt, etc., and 2 methyl 4 chloro methyl, ethyl, isooctyl ester, ethyl sulfide Esters, etc.; 2,4-D derivatives include but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc., and 2,4 -D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester, etc.
在本发明的上下文中，化合物的盐优选为各自的碱金属盐、碱土金属盐或铵盐的形式，优选为各自的碱金属盐的形式，更优选为各自的钠盐或钾盐的形式，最优选为各自的钠盐的形式。In the context of the present invention, the salt of the compound is preferably in the form of the respective alkali metal salt, alkaline earth metal salt or ammonium salt, preferably in the form of the respective alkali metal salt, more preferably in the form of the respective sodium salt or potassium salt, It is most preferably in the form of the respective sodium salt.
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备，即将活性物质与液体溶剂或固体载体混合后，再加入表面活性剂如分散剂、稳定剂、 湿润剂、粘合剂、消泡剂等中的一种或几种。The composition of the present invention can be diluted or used directly by the user before use. The formulation can be prepared by the usual processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, then adding one or more of surfactants such as dispersing agents, stabilizers, wetting agents, adhesives, defoamers, etc. Kind.
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。The specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules (dry suspensions), water emulsions, and microemulsions.
简而言之，本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。In short, the composition of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations.
另外，本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上，即施用于杂草，特别是杂草侵扰或易侵扰影响的表面上。In addition, the composition of the present invention can be applied to the leaves of plants to be treated by spraying, that is, applied to weeds, especially on the surfaces that are infested or easily affected by weeds.
进一步，本发明还提供一种所述除草组合物在防治杂草上的应用；以及提供一种防治不想要的植物生长的方法，其包括将所述除草组合物施用于植物、植物部位、植物种子或植物生长的区域。优选地，将所述的除草组合物用于选择性防除有用作物中的杂草，更优选地，所述有用作物为转基因作物或者基因组编辑技术处理过的作物。Furthermore, the present invention also provides an application of the herbicidal composition for controlling weeds; and a method for controlling the growth of unwanted plants, which includes applying the herbicidal composition to plants, plant parts, and plants. The area where seeds or plants grow. Preferably, the herbicidal composition is used to selectively control weeds in useful crops. More preferably, the useful crops are transgenic crops or crops processed by genome editing technology.
本发明化合物可用于处理所有植株和植株部分。植株品种和栽培品系可通过常规的繁殖和育种方法或通过基因工程方法获得。经基因修饰的植株(转基因植物)为其中异源性基因(转基因)已被稳定整合进植株的基因组的那些。由它在植物基因组中的特定位置所限定的转基因被称为转化事件或转基因事件。The compounds of the invention can be used to treat all plants and plant parts. Plant varieties and cultivated lines can be obtained through conventional propagation and breeding methods or through genetic engineering methods. Genetically modified plants (transgenic plants) are those in which a heterologous gene (transgene) has been stably integrated into the genome of the plant. The transgene defined by its specific position in the plant genome is called a transformation event or a transgenic event.
经基因修饰的可根据本发明处理的植株栽培品系包括抵抗一种或多种生物胁迫的那些(害虫，诸如线虫动物、昆虫、螨虫、真菌等)或非生物胁迫(干旱、低温、土壤盐化等)，或其包含其它期望的特征。植株可经基因修饰以表现出性状，例如除草剂耐受性、昆虫耐受性、修饰的油特征或耐旱性。包含单个基因转化事件或转化事件的组合的可用的经基因修饰的植株列于表1中。关于在表1中所列的基因修饰的另外的信息可得自例如通过美国农业部保持的公共可得的数据库。The genetically modified plant cultivars that can be treated according to the present invention include those resistant to one or more biotic stresses (pests, such as nematodes, insects, mites, fungi, etc.) or abiotic stresses (drought, low temperature, soil salinization) Etc.), or it contains other desired features. Plants can be genetically modified to exhibit traits, such as herbicide tolerance, insect tolerance, modified oil characteristics, or drought tolerance. Available genetically modified plants containing a single genetic transformation event or a combination of transformation events are listed in Table 1. Additional information about the genetic modifications listed in Table 1 can be obtained from publicly available databases maintained, for example, through the United States Department of Agriculture.
下列缩写T1至T37用于表1的性状。“-”表示条目不可用。The following abbreviations T1 to T37 are used for the traits in Table 1. "-" means that the entry is not available.
Figure PCTCN2020081644-appb-000059
Figure PCTCN2020081644-appb-000059
表1经基因修饰的植株Table 1 Genetically modified plants
Figure PCTCN2020081644-appb-000060
Figure PCTCN2020081644-appb-000060
Figure PCTCN2020081644-appb-000061
Figure PCTCN2020081644-appb-000061
Figure PCTCN2020081644-appb-000062
Figure PCTCN2020081644-appb-000062
Figure PCTCN2020081644-appb-000063
Figure PCTCN2020081644-appb-000063
Figure PCTCN2020081644-appb-000064
Figure PCTCN2020081644-appb-000064
Figure PCTCN2020081644-appb-000065
Figure PCTCN2020081644-appb-000065
Figure PCTCN2020081644-appb-000066
Figure PCTCN2020081644-appb-000066
*阿根廷油菜(甘蓝型油菜(Brassica napus))，**波兰白菜(芜菁(B.rapa))，#茄子。*Argentine rape (Brassica napus), **Polish cabbage (turnip (B.rapa)), #蛋plant.
当施用本发明的除草组合物时，获得了预料不到的增效效果，并且除草活性比使用单个除草剂的活性预期总和，以及单个除草剂的活性更为显著。增效效果表现为施用量减少、更 宽的杂草控制谱、除草作用更快、更持久，这些特性是杂草控制实践过程中所需要的。就所描述的特性来说，这些新组合物明显地优越于现有的除草剂，达到减量使用，对环境更友好。When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more significant than the expected sum of the activities of a single herbicide and the activity of a single herbicide. The synergistic effect is manifested by reduced application rate, wider weed control spectrum, faster and longer weeding action, these characteristics are required in the process of weed control practice. In terms of the described characteristics, these new compositions are significantly superior to existing herbicides, achieve reduced usage, and are more environmentally friendly.
本发明的增效除草组合物还具有下述优点:The synergistic herbicidal composition of the present invention also has the following advantages:
(1)本发明的组合物为环境友好型，在环境中均易于降解。(1) The composition of the present invention is environmentally friendly and is easily degraded in the environment.
(2)本发明的除草组合物成本低、使用方便，其推广应用有巨大的经济效益和社会效益。(2) The herbicidal composition of the present invention has low cost and convenient use, and its popularization and application have huge economic and social benefits.
具体实施方式detailed description
下列实施例并非限制本发明，而只是用来说明本发明是如何实现的。对于某些杂草，这些实施例显示出特别显著的有效性。举例如下：The following embodiments do not limit the present invention, but merely illustrate how the present invention is implemented. For certain weeds, these examples show particularly significant effectiveness. Examples are as follows:
A)实施例A) Example
1、10％五氟磺草胺·A1可分散油悬浮剂(2+8)1. 10% Penoxsulam·A1 dispersible oil suspension agent (2+8)
2％五氟磺草胺+8％A1+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Penoxsulam + 8% A1 + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 200# solvent oil + 2.5% Organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
2、12％五氟磺草胺·A2可分散油悬浮剂(2+10)2. 12% Penoxsulam·A2 dispersible oil suspension concentrate (2+10)
2％五氟磺草胺+10％A2+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Penoxsulam + 10% A2 + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 200# solvent oil + 2.0% Organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
3、14％五氟磺草胺·A4可分散油悬浮剂(2+12)3. 14% Penoxsulam·A4 dispersible oil suspension agent (2+12)
2％五氟磺草胺+12％A4+5％十二烷基苯磺酸钙+7％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Penoxsulam + 12% A4 + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 5% 200# solvent oil + 2.0% Organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
4、10％双草醚·A1可分散油悬浮剂(2+8)4. 10% Bispyrifen·A1 dispersible oil suspension agent (2+8)
2％双草醚+8％A1+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Bispyrifen+8%A1+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+5% 200#solvent oil+2.5% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
5、12％双草醚·A2可分散油悬浮剂(2+10)5. 12% Bispyrifen·A2 dispersible oil suspension agent (2+10)
2％双草醚+10％A2+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Bispyriphene+10%A2+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+5% 200#solvent oil+2.0% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
6、14％双草醚·A4可分散油悬浮剂(2+12)6. 14% Bispyrifen·A4 dispersible oil suspension agent (2+12)
2％双草醚+12％A4+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％200#溶剂油+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Bispyriphene+12%A4+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+5% 200#solvent oil+2.0% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
7、10％吡嘧磺隆·A1可分散油悬浮剂(2+8)7. 10% Pyrimsulfuron·A1 dispersible oil suspension agent (2+8)
2％吡嘧磺隆+8％A1+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% pyrazosulfuron + 8% A1 + 1% urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.5% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
8、12％吡嘧磺隆·A2可分散油悬浮剂(2+10)8. 12% Pyrimsulfuron·A2 Dispersible Oil Suspension Concentrate (2+10)
2％吡嘧磺隆+10％A2+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% pyrazosulfuron + 10% A2 + 1% urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
9、14％吡嘧磺隆·A3可分散油悬浮剂(2+12)9. 14% Pyrimsulfuron·A3 Dispersible Oil Suspension Concentrate (2+12)
2％吡嘧磺隆+12％A3+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Pyrimsulfuron + 12% A3 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
10、12％烟嘧磺隆·A1可分散油悬浮剂(4+8)10. 12% Nicosulfuron·A1 dispersible oil suspension concentrate (4+8)
4％烟嘧磺隆+8％A1+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% Nicosulfuron+8%A1+1% Urea+6% Calcium Dodecylbenzene Sulfonate+8% Fatty Alcohol Polyoxyethylene Ether+4% Castor Oil Polyoxyethylene Ether+2.2% Organic Bentonite+1.5 % Fumed white carbon black + methyl oleate supplement
11、14％烟嘧磺隆·A2可分散油悬浮剂(4+10)11. 14% Nicosulfuron·A2 dispersible oil suspension agent (4+10)
4％烟嘧磺隆+10％A2+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% Nicosulfuron+10% A2+1% Urea+6% Calcium Dodecylbenzene Sulfonate+8% Fatty Alcohol Polyoxyethylene Ether+4% Castor Oil Polyoxyethylene Ether+2.0% Organic Bentonite+1.5 % Fumed white carbon black + methyl oleate supplement
12、16％烟嘧磺隆·A4可分散油悬浮剂(4+12)12. 16% Nicosulfuron·A4 Dispersible Oil Suspension Concentrate (4+12)
4％烟嘧磺隆+12％A4+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% Nicosulfuron + 12% A4 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
13、8.3％双氟磺草胺·A1可分散油悬浮剂(0.3+8)13. 8.3% Bissulam·A1 dispersible oil suspension concentrate (0.3+8)
0.3％双氟磺草胺+8％A1+1％尿素+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足0.3%Sulfentrazone+8%A1+1%Urea+6%Calcium dodecylbenzenesulfonate+8%Sorbitan fatty acid ester polyoxyethylene ether+4%Castor oil polyoxyethylene ether+ 2.5% organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
14、10.3％双氟磺草胺·A2可分散油悬浮剂(0.3+10)14. 10.3% Bissulam·A2 dispersible oil suspension agent (0.3+10)
0.3％双氟磺草胺+10％A2+1％尿素+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足0.3% Fenoxsulam + 10% A2 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.2% organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
15、12.3％双氟磺草胺·A3可分散油悬浮剂(0.3+12)15. 12.3% Fenoxsulam·A3 dispersible oil suspension concentrate (0.3+12)
0.3％双氟磺草胺+12％A3+1％尿素+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足0.3% Fenoxsulam + 12% A3 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5% fumed white carbon black + methyl oleate supplement
16、10％砜嘧磺隆·A1可分散油悬浮剂(2+8)16. 10% Sulfonsulfuron·A1 dispersible oil suspension agent (2+8)
2％砜嘧磺隆+8％A1+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfonsulfuron + 8% A1 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.5% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
17、12％砜嘧磺隆·A2可分散油悬浮剂(2+10)17. 12% Sulfonsulfuron·A2 Dispersible Oil Suspension Concentrate (2+10)
2％砜嘧磺隆+10％A2+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfonsulfuron + 10% A2 + 1% Urea + 6% calcium dodecylbenzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
18、14％砜嘧磺隆·A4可分散油悬浮剂(2+12)18. 14% Sulfonsulfuron·A4 Dispersible Oil Suspension Concentrate (2+12)
2％砜嘧磺隆+12％A4+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油 聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfonsulfuron + 12% A4 + 1% Urea + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5 % Fumed white carbon black + methyl oleate supplement
19、14％咪草烟·A1可分散油悬浮剂(6+8)19. 14% imazethapyr·A1 dispersible oil suspension (6+8)
6％咪草烟+8％A1+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足6% imazethapyr+8%A1+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5% fumed white carbon Black + methyl oleate supplement
20、16％咪草烟·A2可分散油悬浮剂(6+10)20. 16% imazethapyr·A2 dispersible oil suspension (6+10)
6％咪草烟+10％A2+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足6% imazethapyr+10%A2+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5% fumed white carbon Black + methyl oleate supplement
21、18％咪草烟·A4可分散油悬浮剂(6+12)21. 18% imazethapyr·A4 dispersible oil suspension (6+12)
6％咪草烟+12％A4+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足6% imazethapyr+12%A4+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite+1.5% fumed white carbon Black + methyl oleate supplement
22、18％甲基咪草烟·A1可分散油悬浮剂(10+8)22. 18% Imazethapyr·A1 dispersible oil suspension (10+8)
10％甲基咪草烟+8％A1+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% Imazethapyr + 8% A1 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
23、20％甲基咪草烟·A2可分散油悬浮剂(10+10)23. 20% Imazethapyr·A2 dispersible oil suspension (10+10)
10％甲基咪草烟+10％A2+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% Imazethapyr + 10% A2 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
24、22％甲基咪草烟·A4可分散油悬浮剂(10+12)24. 22% Imazethapyr·A4 dispersible oil suspension (10+12)
10％甲基咪草烟+12％A4+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% Imazethapyr + 12% A4 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
25、12％甲氧咪草烟·A1可分散油悬浮剂(4+8)25. 12% Methotrex·A1 Dispersible Oil Suspension Concentrate (4+8)
4％甲氧咪草烟+8％A1+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% imazamox + 8% A1 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.2% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
26、14％甲氧咪草烟·A2可分散油悬浮剂(4+10)26. 14% Metoxypyr·A2 Dispersible Oil Suspension Concentrate (4+10)
4％甲氧咪草烟+10％A2+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% imazamox + 10% A2 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
27、16％甲氧咪草烟·A4可分散油悬浮剂(4+12)27. 16% Metoxypyr·A4 dispersible oil suspension agent (4+12)
4％甲氧咪草烟+12％A4+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足4% imazamox + 12% A4 + 6% calcium dodecyl benzene sulfonate + 8% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.5% gas phase method White carbon black + methyl oleate supplement
28、18％甲嘧磺隆·A1可分散油悬浮剂(10+8)28. 18% Mesulfuron-methyl·A1 dispersible oil suspension agent (10+8)
10％甲嘧磺隆+8％A1+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% metsulfuron+8%A1+1% urea+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5 % Fumed white carbon black + methyl oleate supplement
29、20％甲嘧磺隆·A2可分散油悬浮剂(10+10)29. 20% Mesulfuron-methyl·A2 dispersible oil suspension agent (10+10)
10％甲嘧磺隆+10％A2+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% metsulfuron+10%A2+1% urea+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite+1.5 % Fumed white carbon black + methyl oleate supplement
30、22％甲嘧磺隆·A4可分散油悬浮剂(10+12)30, 22% metsulfuron·A4 dispersible oil suspension agent (10+12)
10％甲嘧磺隆+12％A4+1％尿素+6％十二烷基苯磺酸钙+8％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足10% metsulfuron+12%A4+1% urea+6% calcium dodecylbenzenesulfonate+8% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.6% organic bentonite+1.5 % Fumed white carbon black + methyl oleate supplement
31、10％氯酯磺草胺·A1可分散油悬浮剂(2+8)31. 10% Chlorpropamide·A1 Dispersible Oil Suspension Concentrate (2+8)
2％氯酯磺草胺+8％A1+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfentrazone + 8% A1 + 6% calcium dodecylbenzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.5% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
32、12％氯酯磺草胺·A2可分散油悬浮剂(2+10)32. 12% Chlorpropamide·A2 Dispersible Oil Suspension Concentrate (2+10)
2％氯酯磺草胺+10％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfentrazone + 10% A2 + 6% calcium dodecyl benzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.2% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
33、14％氯酯磺草胺·A3可分散油悬浮剂(2+12)33. 14% Chlorpropamide·A3 Dispersible Oil Suspension Concentrate (2+12)
2％氯酯磺草胺+12％A3+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足2% Sulfentrazone + 12% A3 + 6% calcium dodecylbenzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite +1.5% fumed white carbon black + methyl oleate supplement
34、18％氰氟草酯·A1可分散油悬浮剂(10+8)34. 18% Cyhalofop-butyl·A1 dispersible oil suspension concentrate (10+8)
10％氰氟草酯+8％A1+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+15％150#溶剂油+油酸甲酯补足10% cyhalofop-butyl+8%A1+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+ 1.5% fumed white carbon black + 15% 150# solvent oil + methyl oleate supplement
35、20％氰氟草酯·A2水乳剂(10+10)35. 20% Cyhalofop-butyl·A2 water emulsion (10+10)
10％氰氟草酯+10％A2+20％150#溶剂油+3.5％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+5％蓖麻油聚氧乙烯醚+3％乙二醇+去离子水补足10% cyhalofop-butyl + 10% A2 + 20% 150# solvent oil + 3.5% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt + 5% castor oil polyoxyethylene ether + 3% ethylene glycol + to Ionized water replenishment
36、22％氰氟草酯·A4可分散油悬浮剂(10+12)36. 22% cyhalofop-butyl·A4 dispersible oil suspension concentrate (10+12)
10％氰氟草酯+12％A4+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+15％150#溶剂油+油酸甲酯补足10% cyhalofop-butyl+12%A4+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+ 1.5% fumed white carbon black + 15% 150# solvent oil + methyl oleate supplement
37、11％炔草酯·A1可分散油悬浮剂(3+8)37. 11% clodinafop-propargyl·A1 dispersible oil suspension concentrate (3+8)
3％炔草酯+8％A1+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+15％150#溶剂油+油酸甲酯补足3% clodinafop-propargyl+8%A1+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.5% organic bentonite+2.0 % Gas phase method white carbon black+15％150#solvent oil+methyl oleate supplement
38、13％炔草酯·A2水乳剂(3+10)38. 13% clodinafop-propargyl·A2 water emulsion (3+10)
3％炔草酯+10％A2+15％150#溶剂油+5％环己酮+3.5％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+5％蓖麻油聚氧乙烯醚+3％乙二醇+去离子水补足3% clodinafop + 10% A2 + 15% 150# solvent oil + 5% cyclohexanone + 3.5% phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt + 5% castor oil polyoxyethylene ether + 3% Ethylene glycol + deionized water supplement
39、15％炔草酯·A3可分散油悬浮剂(3+12)39. 15% clodinafop-propargyl·A3 dispersible oil suspension concentrate (3+12)
3％炔草酯+12％A3+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+15％150#溶剂油+油酸甲酯补足3% clodinafop + 12% A3 + 6% calcium dodecylbenzene sulfonate + 8% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5 % Gas phase method white carbon black+15％150#solvent oil+methyl oleate supplement
40、13％唑啉草酯·A1水悬浮剂(5+8)40. 13% pinoxaden·A1 water suspension concentrate (5+8)
5％唑啉草酯+8％A1+5％聚羧酸盐+2％丙二醇前段聚醚+2％脂肪醇聚氧乙烯醚+0.2％黄原胶+2.0％硅酸镁铝+3％乙二醇+0.1％有机硅消泡剂+去离子水补足5% pinoxaden+8%A1+5% polycarboxylate+2% propylene glycol front polyether+2% fatty alcohol polyoxyethylene ether+0.2% xanthan gum+2.0% magnesium aluminum silicate+3% ethyl Glycol + 0.1% organic silicon defoamer + deionized water to make up
41、15％唑啉草酯·A2乳油(5+10)41. 15% pinoxaden·A2 EC (5+10)
5％唑啉草酯+10％A2+15％四氢糠醇+1％磷酸三苯酯+5％十二烷基苯磺酸钙+3.5％苯乙基酚聚氧乙烯醚+5％蓖麻油聚氧乙烯醚+150#溶剂油补足5% pinoxaden + 10% A2 + 15% tetrahydrofurfuryl alcohol + 1% triphenyl phosphate + 5% calcium dodecylbenzene sulfonate + 3.5% phenethyl phenol polyoxyethylene ether + 5% castor oil Polyoxyethylene ether +150# solvent oil supplement
42、17％唑啉草酯·A3可分散油悬浮剂(5+12)42. 17% pinoxaden·A3 dispersible oil suspension concentrate (5+12)
5％唑啉草酯+12％A3+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+10％150#溶剂油+油酸甲酯补足5% pinoxaden+12%A3+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite+ 1.5% fumed white carbon black + 10% 150# solvent oil + methyl oleate supplement
43、14％烯草酮·A1可分散油悬浮剂(6+8)43. 14% clethodim·A1 dispersible oil suspension concentrate (6+8)
6％烯草酮+8％A1+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% clethodim+8%A1+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
44、16％烯草酮·A2乳油(6+10)44. 16% clethodim·A2 EC (6+10)
6％烯草酮+10％A2+4％十二烷基苯磺酸钙+4％苯乙基酚聚氧乙烯醚+4％脂肪醇聚氧乙烯醚+150#溶剂油补足6% clethodim + 10% A2 + 4% calcium dodecyl benzene sulfonate + 4% phenethyl phenol polyoxyethylene ether + 4% fatty alcohol polyoxyethylene ether + 150# solvent oil supplement
45、18％烯草酮·A4可分散油悬浮剂(6+12)45. 18% clethodim·A4 dispersible oil suspension concentrate (6+12)
6％烯草酮+12％A4+6％十二烷基苯磺酸钙+9％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% clethodim + 12% A4 + 6% calcium dodecyl benzene sulfonate + 9% sorbitan fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.5 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
46、23％烯禾啶·A1可分散油悬浮剂(15+8)46. 23% Enoxydim·A1 dispersible oil suspension concentrate (15+8)
15％烯禾啶+8％A1+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足15% Enoxypyr + 8% A1 + 6% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.2% organic bentonite + 1.5% fumed white carbon Black+5%150#solvent oil+methyl oleate supplement
47、25％烯禾啶·A2乳油(15+10)47. 25% Enoxydim·A2 EC (15+10)
15％烯禾啶+10％A2+4％十二烷基苯磺酸钙+6％苯乙基酚聚氧乙烯醚+3％脂肪醇聚氧乙烯醚+150#溶剂油补足15% Enoxypyr + 10% A2 + 4% calcium dodecyl benzene sulfonate + 6% phenethyl phenol polyoxyethylene ether + 3% fatty alcohol polyoxyethylene ether + 150# solvent oil supplement
48、27％烯禾啶·A4可分散油悬浮剂(15+12)48. 27% Enoxydim·A4 dispersible oil suspension concentrate (15+12)
15％烯禾啶+12％A4+6％十二烷基苯磺酸钙+9％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足15% Enoxypyr + 12% A4 + 6% calcium dodecyl benzene sulfonate + 9% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.5% fumed white carbon Black+5%150#solvent oil+methyl oleate supplement
49、12％精喹禾灵·A1可分散油悬浮剂(4+8)49. 12% quizalofop-p-ethyl·A1 dispersible oil suspension (4+8)
4％精喹禾灵+8％A1+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚 +2.4％有机膨润土+1.5％气相法白炭黑+20％150#溶剂油+油酸甲酯补足4% quizalofop-p-ethyl+8%A1+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.4% organic bentonite+1.5% fumed white Carbon black+20％150#solvent oil+methyl oleate supplement
50、14％精喹禾灵·A2水乳剂(4+10)50, 14% quizalofop-p-ethyl·A2 water emulsion (4+10)
4％精喹禾灵+10％A2+6％环己酮+20％150#溶剂油+3.5％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4.5％蓖麻油聚氧乙烯醚+3％乙二醇+去离子水补足4% quizalofop-p-ethyl+10%A2+6% cyclohexanone+20%150#solvent oil+3.5% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4.5% castor oil polyoxyethylene ether+3 % Ethylene glycol + deionized water supplement
51、16％精喹禾灵·A4可分散油悬浮剂(4+12)51. 16% quizalofop-p-ethyl·A4 dispersible oil suspension (4+12)
4％精喹禾灵+12％A4+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+20％150#溶剂油+油酸甲酯补足4% quizalofop-p-ethyl+12%A4+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5% fumed white Carbon black+20％150#solvent oil+methyl oleate supplement
52、12％精吡氟禾草灵·A1可分散油悬浮剂(4+8)52. 12% Refined fluoxyp-ethyl·A1 dispersible oil suspension (4+8)
4％精吡氟禾草灵+8％A1+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.4％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足4% diflufenicop-ethyl+8%A1+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.4% organic bentonite+1.5% gas phase French white carbon black + 5% 150# solvent oil + methyl oleate supplement
53、14％精吡氟禾草灵·A2水乳剂(4+10)53. 14% Refined fluoxyp-ethyl·A2 water emulsion (4+10)
4％精吡氟禾草灵+10％A2+20％150#溶剂油+3.5％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4.5％蓖麻油聚氧乙烯醚+3％乙二醇+去离子水补足4% diflufenicop-ethyl+10%A2+20%150#solvent oil+3.5% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4.5% castor oil polyoxyethylene ether+3% ethylene glycol + Deionized water supplement
54、16％精吡氟禾草灵·A4可分散油悬浮剂(4+12)54. 16% diflufenop-ethyl·A4 dispersible oil suspension concentrate (4+12)
4％精吡氟禾草灵+12％A4+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足4% diflufenicop-ethyl+12% A4+6% calcium dodecyl benzene sulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5% gas phase French white carbon black + 5% 150# solvent oil + methyl oleate supplement
55、12％高效氟吡甲禾灵·A1可分散油悬浮剂(4+8)55. 12% high-efficiency fluroxypyr·A1 dispersible oil suspension agent (4+8)
4％高效氟吡甲禾灵+8％A1+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.4％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足4% high-efficiency fluroxypyr+8%A1+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.4% organic bentonite+1.5% gas phase French white carbon black + 5% 150# solvent oil + methyl oleate supplement
56、14％高效氟吡甲禾灵·A2水乳剂(4+10)56. 14% high-efficiency fluroxypyr·A2 water emulsion (4+10)
4％高效氟吡甲禾灵+10％A2+20％150#溶剂油+3.5％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4.5％蓖麻油聚氧乙烯醚+3％乙二醇+去离子水补足4% high-efficiency fluroxypyr+10%A2+20%150#solvent oil+3.5% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4.5% castor oil polyoxyethylene ether+3% ethylene glycol + Deionized water supplement
57、16％高效氟吡甲禾灵·A4可分散油悬浮剂(4+12)57. 16% high-efficiency fluroxypyr·A4 dispersible oil suspension agent (4+12)
4％高效氟吡甲禾灵+12％A4+6％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足4% high-efficiency fluroxypyr+12%A4+6% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+1.5% gas phase French white carbon black + 5% 150# solvent oil + methyl oleate supplement
58、29％莠去津·A1可分散油悬浮剂(25+4)58, 29% atrazine·A1 dispersible oil suspension agent (25+4)
25％莠去津+4％A1+4％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+5％150#溶剂油+油酸甲酯补足25% atrazine+4%A1+4% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
59、30％莠去津·A2可分散油悬浮剂(25+5)59. 30% atrazine·A2 dispersible oil suspension agent (25+5)
25％莠去津+5％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+0.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足25% atrazine+5%A2+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+0.5 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
60、31％莠去津·A4可分散油悬浮剂(25+6)60, 31% atrazine·A4 dispersible oil suspension agent (25+6)
25％莠去津+6％A4+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+5％150#溶剂油+油酸甲酯补足25% atrazine+6%A4+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.8% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
61、29％异丙隆·A1可分散油悬浮剂(25+4)61. 29% Isoproturon·A1 dispersible oil suspension agent (25+4)
25％异丙隆+4％A1+4％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+5％150#溶剂油+油酸甲酯补足25% isoproturon+4%A1+4% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
62、30％异丙隆·A2可分散油悬浮剂(25+5)62. 30% Isoproturon·A2 dispersible oil suspension agent (25+5)
25％异丙隆+5％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+0.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足25% isoproturon+5%A2+6% calcium dodecylbenzene sulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+0.5 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
63、31％异丙隆·A3可分散油悬浮剂(25+6)63. 31% Isoproturon·A3 dispersible oil suspension agent (25+6)
25％异丙隆+6％A3+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+5％150#溶剂油+油酸甲酯补足25% isoproturon+6%A3+6% calcium dodecylbenzene sulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.8% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
64、29％绿麦隆·A1可分散油悬浮剂(25+4)64. 29% chlorotoluron·A1 dispersible oil suspension agent (25+4)
25％绿麦隆+4％A1+4％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+5％150#溶剂油+油酸甲酯补足25% chlorotoluene+4%A1+4% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
65、30％绿麦隆·A2可分散油悬浮剂(25+5)65. 30% chlorotoluron·A2 dispersible oil suspension agent (25+5)
25％绿麦隆+5％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+0.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足25% chlorotoluron+5%A2+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.0% organic bentonite+0.5 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
66、31％绿麦隆·A3可分散油悬浮剂(25+6)66. 31% chlorotoluron·A3 dispersible oil suspension agent (25+6)
25％绿麦隆+6％A3+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+5％150#溶剂油+油酸甲酯补足25% chlorotoluene+6%A3+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.8% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
67、34％敌草隆·A1可分散油悬浮剂(30+4)67. 34% Diuron·A1 dispersible oil suspension agent (30+4)
30％敌草隆+4％A1+4％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.6％有机膨润土+5％150#溶剂油+油酸甲酯补足30% diuron+4%A1+4% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.6% organic bentonite+5 ％150#Solvent oil+methyl oleate supplement
68、35％敌草隆·A2可分散油悬浮剂(30+5)68. 35% diuron·A2 dispersible oil suspension agent (30+5)
30％敌草隆+5％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+8％150#溶剂油+油酸甲酯补足30% diuron+5%A2+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.8% organic bentonite+8 ％150#Solvent oil+methyl oleate supplement
69、36％敌草隆·A4可分散油悬浮剂(30+6)69. 36% Diuron·A4 dispersible oil suspension agent (30+6)
30％敌草隆+6％A4+5％十二烷基苯磺酸钙+7％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.4％有机膨润土+8％150#溶剂油+油酸甲酯补足30% diuron+6%A4+5% calcium dodecylbenzenesulfonate+7% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.4% organic bentonite+8 ％150#Solvent oil+methyl oleate supplement
70、48％灭草松·A1水剂(40+8)70, 48% Benzosone·A1 water (40+8)
40％灭草松+8％A1+5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足40% Benazone+8%A1+5% Sodium Hydroxide+5% Fatty Alcohol Polyoxyethylene Ether+15% Octyl Decyl Glycoside+ Deionized Water
71、25％灭草松·A2可分散油悬浮剂(20+5)71. 25% Benzosone·A2 Dispersible Oil Suspension Concentrate (20+5)
20％灭草松+5％A2+6％十二烷基苯磺酸钙+8％失水山梨醇脂肪酸酯聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+0.8％气相法白炭黑+8％150#溶剂油+油酸甲酯补足20% trimethoprim+5%A2+6% calcium dodecylbenzenesulfonate+8% sorbitan fatty acid ester polyoxyethylene ether+4% castor oil polyoxyethylene ether+0.8% organic bentonite+0.8 % Fumed white carbon black + 8％ 150# solvent oil + methyl oleate supplement
72、52％灭草松·A3水剂(40+12)72. 52% Benzosone·A3 water (40+12)
40％灭草松+12％A3+5.5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足40% Benazone+12%A3+5.5% Sodium Hydroxide+5% Fatty Alcohol Polyoxyethylene Ether+15% Octyl Decyl Glycoside+Deionized Water
73、20％溴苯腈·A1水剂(12+8)73. 20% bromoxynil·A1 water agent (12+8)
12％溴苯腈+8％A1+4％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足12% bromoxynil + 8% A1 + 4% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octyl decyl glycoside + deionized water supplement
74、22％溴苯腈·A2乳油(12+10)74. 22% Bromoxynil·A2 EC (12+10)
12％溴苯腈+10％A2+10％N-辛基吡咯烷酮+3％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+150#溶剂油补足12% bromoxynil+10%A2+10%N-octylpyrrolidone+3% calcium dodecylbenzenesulfonate+5% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+150#solvent Oil replenishment
75、24％溴苯腈·A3水剂(12+12)75, 24% bromoxynil·A3 water (12+12)
12％溴苯腈+12％A3+5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足12% bromoxynil + 12% A3 + 5% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octyl decyl glycoside + deionized water supplement
76、27％敌稗·A1可分散油悬浮剂(25+2)76. 27% propanil·A1 dispersible oil suspension agent (25+2)
25％敌稗+2％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.6％有机膨润土+油酸甲酯补足25% propanyl + 2% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 0.6% organic bentonite + methyl oleate supplement
77、27.5％敌稗·A2乳油(25+2.5)77. 27.5% propanil·A2 EC (25+2.5)
25％敌稗+2.5％A2+10％N-辛基吡咯烷酮+10％N,N-二甲基癸酰胺+2％十二烷基苯磺酸钙+10％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+150#溶剂油补足25% propanil+2.5%A2+10%N-octylpyrrolidone+10%N,N-dimethyldecamide+2%calcium dodecylbenzenesulfonate+10% fatty alcohol polyoxyethylene ether+4 % Castor oil polyoxyethylene ether +150# solvent oil supplement
78、28％敌稗·A4可分散油悬浮剂(25+3)78. 28% propanil·A4 dispersible oil suspension agent (25+3)
25％敌稗+3％A4+5％十二烷基苯磺酸钙+7％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.4％有机膨润土+油酸甲酯补足25% propanyl + 3% A4 + 5% calcium dodecyl benzene sulfonate + 7% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 0.4% organic bentonite + methyl oleate supplement
79、17％环吡氟草酮·A1可分散油悬浮剂(9+8)79. 17% ciclofenac·A1 dispersible oil suspension concentrate (9+8)
9％环吡氟草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+10％150#溶剂油+油酸甲酯补足9% ciclofenone + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organic bentonite + 1.5% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
80、19％环吡氟草酮·A2可分散油悬浮剂(9+10)80, 19% ciclofenac·A2 dispersible oil suspension concentrate (9+10)
9％环吡氟草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+10％150#溶剂油+油酸甲酯补足9% ciclofenac + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 2.0% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
81、21％环吡氟草酮·A3可分散油悬浮剂(9+12)81. 21% cicloflurane·A3 dispersible oil suspension concentrate (9+12)
9％环吡氟草酮+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+10％150#溶剂油+油酸甲酯补足9% ciclofenac + 12% A3 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.2% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
82、10％双唑草酮·A1可分散油悬浮剂(2+8)82. 10% Bifentrazone·A1 dispersible oil suspension (2+8)
2％双唑草酮+8％A1+0.4％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+8％150#溶剂油+油酸甲酯补足2% carfentrazone+8%A1+0.4% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.5% organic bentonite+ 1.5% fumed white carbon black + 8% 150# solvent oil + methyl oleate supplement
83、12％双唑草酮·A2可分散油悬浮剂(2+10)83. 12% Bifentrazone·A2 Dispersible Oil Suspension Concentrate (2+10)
2％双唑草酮+10％A2+0.4％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+8％150#溶剂油+油酸甲酯补足2% carfentrazone+10%A2+0.4% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.5% organic bentonite+ 1.5% fumed white carbon black + 8% 150# solvent oil + methyl oleate supplement
84、14％双唑草酮·A3可分散油悬浮剂(2+12)84. 14% Bifentrazone·A3 Dispersible Oil Suspension Concentrate (2+12)
2％双唑草酮+12％A3+0.4％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+8％150#溶剂油+油酸甲酯补足2% carfentrazone+12%A3+0.4% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.2% organic bentonite+ 1.2% fumed white carbon black + 8% 150# solvent oil + methyl oleate supplement
85、17％苯唑氟草酮·A1可分散油悬浮剂(9+8)85. 17% oxaflutole·A1 dispersible oil suspension concentrate (9+8)
9％苯唑氟草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足9% oxaflufen+8%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.5% organic bentonite+1.5% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
86、19％苯唑氟草酮·A2可分散油悬浮剂(9+10)86. 19% oxaflutole·A2 dispersible oil suspension concentrate (9+10)
9％苯唑氟草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足9% oxaflufen + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 2.0% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
87、21％苯唑氟草酮·A3可分散油悬浮剂(9+12)87. 21% oxaflutole·A3 dispersible oil suspension concentrate (9+12)
9％苯唑氟草酮+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+5％150#溶剂油+油酸甲酯补足9% oxaflufen + 12% A3 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.2% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
88、20％三唑磺草酮·A1可分散油悬浮剂(12+8)88. 20% triazurone·A1 dispersible oil suspension (12+8)
12％三唑磺草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足12% Triazole Sulcotrione + 8% A1 + 4% Calcium Dodecylbenzene Sulfonate + 8% Cardanol Polyoxyethylene Ether + 4% Castor Oil Polyoxyethylene Ether + 1.5% Organic Bentonite + 1.5% Gas Phase Method White carbon black + 5% 150# solvent oil + methyl oleate supplement
89、22％三唑磺草酮·A2可分散油悬浮剂(12+10)89. 22% Triazurone·A2 dispersible oil suspension concentrate (12+10)
12％三唑磺草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足12% trifentrione + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 2.0% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
90、24％三唑磺草酮·A4可分散油悬浮剂(12+12)90, 24% triazurone·A4 dispersible oil suspension (12+12)
12％三唑磺草酮+12％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+5％150#溶剂油+油酸甲酯补足12% Trifentrione + 12% A4 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.2% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
91、14％呋喃磺草酮·A1可分散油悬浮剂(6+8)91. 14% fursotrione·A1 dispersible oil suspension concentrate (6+8)
6％呋喃磺草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯 醚+1.8％有机膨润土+1.8％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% fursotrione + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.8% gas phase method white Carbon black + 5% 150# solvent oil + methyl oleate supplement
92、16％呋喃磺草酮·A2可分散油悬浮剂(6+10)92. 16% fursotrione·A2 dispersible oil suspension concentrate (6+10)
6％呋喃磺草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% fursotrione + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 2.0% fumed white Carbon black + 5% 150# solvent oil + methyl oleate supplement
93、18％呋喃磺草酮·A4可分散油悬浮剂(6+12)93. 18% fursotrione·A4 dispersible oil suspension concentrate (6+12)
6％呋喃磺草酮+12％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% fursotrione + 12% A4 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.0% gas phase method white Carbon black + 5% 150# solvent oil + methyl oleate supplement
94、18％硝磺草酮·A1可分散油悬浮剂(10+8)94. 18% Mesotrione·A1 dispersible oil suspension concentrate (10+8)
10％硝磺草酮+8％A1+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+5％150#溶剂油+油酸甲酯补足10% Mesotrione+8%A1+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite+ 1.8% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
95、20％硝磺草酮·A2可分散油悬浮剂(10+10)95. 20% Mesotrione·A2 Dispersible Oil Suspension Concentrate (10+10)
10％硝磺草酮+10％A2+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足10% Mesotrione + 10% A2 + 0.5% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite+ 2.0% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
96、22％硝磺草酮·A3可分散油悬浮剂(10+12)96. 22% Mesotrione·A3 dispersible oil suspension concentrate (10+12)
10％硝磺草酮+12％A3+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足10% Mesotrione + 12% A3 + 0.5% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite+ 1.0% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
97、14％环磺酮·A1可分散油悬浮剂(6+8)97, 14% cyclosulfone·A1 dispersible oil suspension agent (6+8)
6％环磺酮+8％A1+1％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% cyclosulfone + 8% A1 + 1% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.8 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
98、16％环磺酮·A2可分散油悬浮剂(6+10)98. 16% cyclosulfone·A2 dispersible oil suspension agent (6+10)
6％环磺酮+10％A2+1％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% cyclosulfone+10%A2+1% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+2.0 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
99、18％环磺酮·A3可分散油悬浮剂(6+12)99. 18% cyclosulfone·A3 dispersible oil suspension agent (6+12)
6％环磺酮+12％A3+1％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% cyclosulfone + 12% A3 + 1% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.0 % Gas phase method white carbon black + 5% 150# solvent oil + methyl oleate supplement
100、11％苯唑草酮·A1可分散油悬浮剂(3+8)100, 11% mefentrazone·A1 dispersible oil suspension (3+8)
3％苯唑草酮+8％A1+0.2％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足3% carfentrazone + 8% A1 + 0.2% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite+ 2.0% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
101、13％苯唑草酮·A2可分散油悬浮剂(3+10)101. 13% Mefentrazone·A2 Dispersible Oil Suspension Concentrate (3+10)
3％苯唑草酮+10％A2+0.2％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足3% carfentrazone + 10% A2 + 0.2% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite+ 2.0% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
102、15％苯唑草酮·A3可分散油悬浮剂(3+12)102. 15% oxentrazone·A3 dispersible oil suspension (3+12)
3％苯唑草酮+12％A3+0.2％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足3% carfentrazone + 12% A3 + 0.2% citric acid + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organic bentonite+ 1.5% fumed white carbon black + 5% 150# solvent oil + methyl oleate supplement
103、14％异恶唑草酮·A1可分散油悬浮剂(6+8)103. 14% Isoxaflutole·A1 Dispersible Oil Suspension Concentrate (6+8)
6％异恶唑草酮+8％A1+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% isoxaflutole+8%A1+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite +1.8% fumed white carbon black +5% 150#solvent oil + methyl oleate supplement
104、16％异恶唑草酮·A2可分散油悬浮剂(6+10)104. 16% Isoxaflutole·A2 Dispersible Oil Suspension Concentrate (6+10)
6％异恶唑草酮+10％A2+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% isoxaflutole+10%A2+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite +2.0% fumed white carbon black+5%150#solvent oil+methyl oleate supplement
105、18％异恶唑草酮·A4可分散油悬浮剂(6+12)105. 18% Isoxaflutole·A4 Dispersible Oil Suspension Concentrate (6+12)
6％异恶唑草酮+12％A4+0.5％柠檬酸+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+5％150#溶剂油+油酸甲酯补足6% Isoxaflutole + 12% A4 + 0.5% Citric Acid + 4% Calcium Dodecylbenzene Sulfonate + 8% Cardanol Polyoxyethylene Ether + 4% Castor Oil Polyoxyethylene Ether + 1.2% Organic Bentonite +1.0% fumed white carbon black+5%150#solvent oil+methyl oleate supplement
106、28％双环磺草酮·A1可分散油悬浮剂(20+8)106. 28% Sulcotrione·A1 dispersible oil suspension concentrate (20+8)
20％双环磺草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+5％150#溶剂油+油酸甲酯补足20% Sulcotrione + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.0% organic bentonite + 5% 150# solvent Oil + methyl oleate supplement
107、30％双环磺草酮·A2可分散油悬浮剂(20+10)107. 30% Sulcotrione·A2 dispersible oil suspension agent (20+10)
20％双环磺草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+5％150#溶剂油+油酸甲酯补足20% Sulcotrione + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.2% fumed white Carbon black + 5% 150# solvent oil + methyl oleate supplement
108、32％双环磺草酮·A4可分散油悬浮剂(20+12)108. 32% Sulcotrione·A4 Dispersible Oil Suspension Concentrate (20+12)
20％双环磺草酮+12％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.5％有机膨润土+5％150#溶剂油+油酸甲酯补足20% Sulcotrione + 12% A4 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 0.5% organic bentonite + 5% 150# solvent Oil + methyl oleate supplement
109、18％吡氟酰草胺·A1可分散油悬浮剂(10+8)109, 18% diflufenican·A1 dispersible oil suspension agent (10+8)
10％吡氟酰草胺+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+5％150#溶剂油+油酸甲酯补足10% diflufenican + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 1.2% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
110、20％吡氟酰草胺·A2可分散油悬浮剂(10+10)110, 20% diflufenican·A2 dispersible oil suspension agent (10+10)
10％吡氟酰草胺+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足10% diflufenican + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organic bentonite + 1.5% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
111、22％吡氟酰草胺·A3可分散油悬浮剂(10+12)111. 22% diflufenican·A3 dispersible oil suspension concentrate (10+12)
10％吡氟酰草胺+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+0.8％有机膨润土+5％150#溶剂油+油酸甲酯补足10% diflufenican + 12% A3 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 0.8% organic bentonite + 5% 150# Solvent oil + methyl oleate supplement
112、29％氟咯草酮·A1可分散油悬浮剂(25+4)112, 29% flurochloridone·A1 dispersible oil suspension concentrate (25+4)
25％氟咯草酮+4％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+15％150#溶剂油+油酸甲酯补足25% flurochloridone+4%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.0% organic bentonite+2.0% fumed white Carbon black+15％150#solvent oil+methyl oleate supplement
113、60％氟咯草酮·A2可分散油悬浮剂(50+10)113. 60% flurochloridone·A2 dispersible oil suspension concentrate (50+10)
50％氟咯草酮+10％A2+6％十二烷基苯磺酸钙+8％蓖麻油聚氧乙烯醚+10％环戊酮+150#溶剂油补足50% flurochloridone + 10% A2 + 6% calcium dodecyl benzene sulfonate + 8% castor oil polyoxyethylene ether + 10% cyclopentanone + 150# solvent oil supplement
114、31％氟咯草酮·A3可分散油悬浮剂(25+6)114. 31% flurochloridone·A3 dispersible oil suspension (25+6)
25％氟咯草酮+6％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+15％150#溶剂油+油酸甲酯补足25% flurochloridone + 6% A3 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organic bentonite + 1.8% gas phase method white Carbon black+15％150#solvent oil+methyl oleate supplement
115、38％异噁草松·A1可分散油悬浮剂(30+8)115. 38% clomazone·A1 dispersible oil suspension (30+8)
30％异噁草松+8％A1+5％十二烷基苯磺酸钙+6％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+5％150#溶剂油+油酸甲酯补足30% clomazone+8%A1+5% calcium dodecylbenzenesulfonate+6% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.5% organic bentonite+2.5% fumed white Carbon black + 5% 150# solvent oil + methyl oleate supplement
116、40％异噁草松·A2乳油(30+10)116. 40% clomazone·A2 EC (30+10)
30％异噁草松+10％A2+6％十二烷基苯磺酸钙+10％蓖麻油聚氧乙烯醚+10％乙醇+150#溶剂油补足30% clomazone+10%A2+6% calcium dodecylbenzenesulfonate+10% castor oil polyoxyethylene ether+10% ethanol+150#solvent oil supplement
117、42％异噁草松·A4可分散油悬浮剂(30+12)117, 42% clomazone·A4 dispersible oil suspension concentrate (30+12)
30％异噁草松+12％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.2％有机膨润土+1.8％气相法白炭黑+15％150#溶剂油+油酸甲酯补足30% clomazone+12%A4+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+2.2% organic bentonite+1.8% fumed white Carbon black+15％150#solvent oil+methyl oleate supplement
118、10％唑草酮·A1悬乳剂(2+8)118. 10% carfentrazone·A1 suspoemulsion (2+8)
2％唑草酮+8％A1+3％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％异辛醇嵌段聚醚+3％蓖麻油聚氧乙烯醚+10％150#溶剂油+0.25％黄原胶+2.0％硅酸镁铝+2％乙二醇+去离子水补足2% carfentrazone+8%A1+3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4% isooctanol block polyether+3% castor oil polyoxyethylene ether+10％150#solvent Oil + 0.25% xanthan gum + 2.0% magnesium aluminum silicate + 2% ethylene glycol + deionized water to make up
119、12％唑草酮·A2水乳剂(2+10)119. 12% carfentrazone·A2 water emulsion (2+10)
2％唑草酮+10％A2+3％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+5％蓖麻油聚氧乙烯醚+10％150#溶剂油+3％乙二醇+去离子水补足2% carfentrazone+10%A2+3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+5% castor oil polyoxyethylene ether+10%150#solvent oil+3%ethylene glycol+deionized Water replenishment
120、14％唑草酮·A3水乳剂(2+12)120. 14% carfentrazone·A3 water emulsion (2+12)
2％唑草酮+12％A3+3％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+5％蓖麻油聚氧乙烯醚+10％150#溶剂油+0.25％黄原胶+2％乙二醇+去离子水补足2% carfentrazone+12%A3+3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+5% castor oil polyoxyethylene ether+10%150#solvent oil+0.25%xanthan gum+2% Ethylene glycol + deionized water supplement
121、33％氟磺胺草醚·A1水剂(25+8)121. 33% Fomesafen·A1 water (25+8)
25％氟磺胺草醚+8％A1+4％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足25% fomesafen + 8% A1 + 4% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octyl decyl glycoside + deionized water supplement
122、35％氟磺胺草醚·A2微乳剂(25+10)122. 35% fomesafen·A2 microemulsion (25+10)
25％氟磺胺草醚+10％A2+10％环己酮+10％乙醇+6％顺丁烯二仲辛酯磺酸钠+10％辛癸基 糖苷+去离子水补足25% fomesafen + 10% A2 + 10% cyclohexanone + 10% ethanol + 6% sodium di-sec-octyl maleate sulfonate + 10% octdecyl glycoside + deionized water supplement
123、37％氟磺胺草醚·A3水剂(25+12)123, 37% fomesafen·A3 water (25+12)
25％氟磺胺草醚+12％A3+4.5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足25% fomesafen + 12% A3 + 4.5% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octyl decyl glycoside + deionized water supplement
124、9％乙羧氟草醚·A1可分散油悬浮剂(1+8)124. 9% acifluorfen·A1 dispersible oil suspension (1+8)
1％乙羧氟草醚+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+10％150#溶剂油+油酸甲酯补足1% acifluorfen + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 2.0% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
125、11％乙羧氟草醚·A2水乳剂(1+10)125. 11% acifluorfen·A2 water emulsion (1+10)
1％乙羧氟草醚+10％A2+3％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％蓖麻油聚氧乙烯醚+10％150#溶剂油+0.1％黄原胶+2％乙二醇+去离子水补足1% acifluorfen+10%A2+3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4% castor oil polyoxyethylene ether+10%150#solvent oil+0.1%xanthan gum+ 2% ethylene glycol + deionized water supplement
126、13％乙羧氟草醚·A3可分散油悬浮剂(1+12)126, 13% acifluorfen·A3 dispersible oil suspension agent (1+12)
1％乙羧氟草醚+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+10％150#溶剂油+油酸甲酯补足1% acifluorfen + 12% A3 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organic bentonite + 1.5% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
127、20％乙氧氟草醚·A1可分散油悬浮剂(12+8)127. 20% oxyfluorfen·A1 dispersible oil suspension agent (12+8)
12％乙氧氟草醚+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％油溶性聚羧酸盐+1.4％有机膨润土+10％豆油+油酸甲酯补足12% oxyfluorfen+8%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+5% oil-soluble polycarboxylate+ 1.4% organic bentonite + 10% soybean oil + methyl oleate supplement
128、22％乙氧氟草醚·A2乳油(12+10)128, 22% oxyfluorfen·A2 EC (12+10)
12％乙氧氟草醚+10％A2+10％环戊酮+3％十二烷基苯磺酸钙+4％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+150#溶剂油补足12% oxyfluorfen + 10% A2 + 10% cyclopentanone + 3% calcium dodecyl benzene sulfonate + 4% fatty alcohol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 150# solvent Oil replenishment
129、24％乙氧氟草醚·A3可分散油悬浮剂(12+12)129. 24% oxyfluorfen·A3 dispersible oil suspension concentrate (12+12)
12％乙氧氟草醚+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+5％油溶性聚羧酸盐+1.4％有机膨润土+10％豆油+油酸甲酯补足12% oxyfluorfen+12%A3+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+5% oil-soluble polycarboxylate+ 1.4% organic bentonite + 10% soybean oil + methyl oleate supplement
130、16％乳氟禾草灵·A1可分散油悬浮剂(8+8)130. 16% Lactofop-ethyl·A1 dispersible oil suspension concentrate (8+8)
8％乳氟禾草灵+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+5％150#溶剂油+油酸甲酯补足8% Lactofop-ethyl+8% Al+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.8% organic bentonite+1.8% gas phase method White carbon black + 5% 150# solvent oil + methyl oleate supplement
131、18％乳氟禾草灵·A2乳油(8+10)131. 18% Lactofop-ethyl·A2 EC (8+10)
8％乳氟禾草灵+10％A2+3％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+150#溶剂油补足8% Lactofop-ethyl+10% A2+3% calcium dodecylbenzenesulfonate+6% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+150#solvent oil supplement
132、20％乳氟禾草灵·A3可分散油悬浮剂(8+12)132. 20% Lactofop-ethyl·A3 dispersible oil suspension agent (8+12)
8％乳氟禾草灵+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+10％150#溶剂油+油酸甲酯补足8% Lactofop-ethyl+12% A3+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.6% organic bentonite+1.6% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
133、38％三氟羧草醚·A1水剂(30+8)133, 38% acifluorfen·A1 water (30+8)
30％三氟羧草醚+8％A1+4.5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足30% acifluorfen + 8% A1 + 4.5% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octyl decyl glycoside + deionized water supplement
134、20％三氟羧草醚·A2可分散油悬浮剂(15+5)134. 20% acifluorfen·A2 dispersible oil suspension concentrate (15+5)
15％三氟羧草醚+5％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+10％150#溶剂油+油酸甲酯补足15% acifluorfen + 5% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.6% organic bentonite + 1.6% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
135、42％三氟羧草醚·A3水剂(30+12)135, 42% acifluorfen·A3 water (30+12)
30％三氟羧草醚+12％A3+5％氢氧化钠+5％脂肪醇聚氧乙烯醚+15％辛癸基糖苷+去离子水补足30% acifluorfen + 12% A3 + 5% sodium hydroxide + 5% fatty alcohol polyoxyethylene ether + 15% octdecyl glycoside + deionized water supplement
136、14％丙炔氟草胺·A1可分散油悬浮剂(6+8)136. 14% flumioxazin·A1 dispersible oil suspension concentrate (6+8)
6％丙炔氟草胺+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.6％有机膨润土+10％豆油+油酸甲酯补足6% flumioxazin+8%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.6% organic bentonite+10% soybean oil+ Methyl oleate supplement
137、16％丙炔氟草胺·A2乳油(6+10)137, 16% flumioxazin·A2 EC (6+10)
6％丙炔氟草胺+10％A2+15％环戊酮+3％十二烷基苯磺酸钙+4％脂肪醇聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+150#溶剂油补足6% fluroxypyr+10%A2+15% cyclopentanone+3% calcium dodecylbenzenesulfonate+4% fatty alcohol polyoxyethylene ether+4% castor oil polyoxyethylene ether+150#solvent Oil replenishment
138、18％丙炔氟草胺·A3可分散油悬浮剂(6+12)138. 18% flumioxazin·A3 dispersible oil suspension concentrate (6+12)
6％丙炔氟草胺+12％A3+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.4％有机膨润土+10％豆油+油酸甲酯补足6% fluroxypyr+12%A3+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.4% organic bentonite+10% soybean oil+ Methyl oleate supplement
139、32％甲磺草胺·A1可分散油悬浮剂(24+8)139, 32%Sulfentrazone·A1 dispersible oil suspension concentrate (24+8)
24％甲磺草胺+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.3％有机膨润土+10％150#溶剂油+油酸甲酯补足24%Sulfentrazone+8%A1+4%Calcium dodecylbenzenesulfonate+8%Cardanol polyoxyethylene ether+4% Castor oil polyoxyethylene ether+1.3%Organic bentonite+10％150#solvent Oil + methyl oleate supplement
140、34％甲磺草胺·A2悬乳剂(24+10)140. 34%Sulfentrazone·A2 suspoemulsion (24+10)
24％甲磺草胺+10％A2+8％150#溶剂油+4％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％丙二醇嵌段聚醚+4％蓖麻油聚氧乙烯醚+0.15％黄原胶+2％乙二醇+去离子水补足24％Sulfentrazone+10％A2+8％150#Solvent oil+4％Phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4％propylene glycol block polyether+4％castor oil polyoxyethylene ether +0.15% xanthan gum + 2% ethylene glycol + deionized water to make up
141、36％甲磺草胺·A4水悬浮剂(24+12)141. 36%Sulfentrazone·A4 water suspension agent (24+12)
24％甲磺草胺+12％A4+4％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％萘磺酸盐分散剂+2％脂肪醇聚氧乙烯醚+0.15％黄原胶+1％硅酸镁铝+3％乙二醇+去离子补足24%Sulfentrazone+12%A4+4%Phenethylphenol Polyoxyethylene Ether Phosphate Triethanolamine Salt+3%Naphthalene Sulfonate Dispersant+2%Fatty Alcohol Polyoxyethylene Ether+0.15%Xanthan Gum +1% magnesium aluminum silicate + 3% ethylene glycol + deionized supplement
142、32％苯嘧磺草胺·A1可分散油悬浮剂(24+8)142, 32% saflufenacil·A1 dispersible oil suspension concentrate (24+8)
24％苯嘧磺草胺+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+10％150#溶剂油+油酸甲酯补足24% saflufenacil+8%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.2% organic bentonite+1.0% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
143、34％苯嘧磺草胺·A2悬乳剂(24+10)143. 34% saflufenacil·A2 suspoemulsion (24+10)
24％苯嘧磺草胺+10％A2+8％150#溶剂油+4％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％丙二醇嵌段聚醚+4％蓖麻油聚氧乙烯醚+0.12％黄原胶+2％乙二醇+去离子水补足24% saflufenacil+10%A2+8%150#solvent oil+4% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+4% propylene glycol block polyether+4% castor oil polyoxyethylene Ether + 0.12% xanthan gum + 2% ethylene glycol + deionized water to make up
144、36％苯嘧磺草胺·A3水悬浮剂(24+12)144. 36% saflufenacil·A3 water suspension concentrate (24+12)
24％苯嘧磺草胺+12％A3+4％苯乙基酚聚氧乙烯醚磷酸酯三乙醇胺盐+3％萘磺酸盐分散剂+2％脂肪醇聚氧乙烯醚+0.15％黄原胶+1.2％硅酸镁铝+3％乙二醇+去离子补足24% saflufenacil+12%A3+4% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt+3% naphthalene sulfonate dispersant+2% fatty alcohol polyoxyethylene ether+0.15% xanthogen Glue + 1.2% magnesium aluminum silicate + 3% ethylene glycol + deionized supplement
145、24％噁草酮·A1可分散油悬浮剂(20+4)145. 24% oxadiazon·A1 dispersible oil suspension (20+4)
20％噁草酮+4％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+1.0％气相法白炭黑+10％150#溶剂油+油酸甲酯补足20% oxadiazon+4%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.2% organic bentonite+1.0% fumed white carbon Black+10％150#solvent oil+methyl oleate supplement
146、25％噁草酮·A2可分散油悬浮剂(20+5)146. 25% oxadiazon·A2 dispersible oil suspension concentrate (20+5)
20％噁草酮+5％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.0％有机膨润土+10％150#溶剂油+油酸甲酯补足20% oxadiazon + 5% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.0% organic bentonite + 10% 150# solvent oil +Methyl oleate supplement
147、26％噁草酮·A4可分散油悬浮剂(20+6)147. 26% oxadiazon·A4 dispersible oil suspension concentrate (20+6)
20％噁草酮+6％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.2％有机膨润土+10％150#溶剂油+油酸甲酯补足20% oxadiazon + 6% A4 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organic bentonite + 10% 150# solvent oil +Methyl oleate supplement
148、14％丙炔噁草酮·A1可分散油悬浮剂(6+8)148. 14% oxadiazon·A1 dispersible oil suspension concentrate (6+8)
6％丙炔噁草酮+8％A1+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+10％150#溶剂油+油酸甲酯补足6% oxadiazon+8%A1+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.6% organic bentonite+1.5% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
149、16％丙炔噁草酮·A2可分散油悬浮剂(6+10)149. 16% oxachlor·A2 dispersible oil suspension concentrate (6+10)
6％丙炔噁草酮+10％A2+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+10％150#溶剂油+油酸甲酯补足6% oxadiazon + 10% A2 + 4% calcium dodecyl benzene sulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organic bentonite + 1.5% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
150、18％丙炔噁草酮·A4可分散油悬浮剂(6+12)150. 18% Oxachlor·A4 Dispersible Oil Suspension Concentrate (6+12)
6％丙炔噁草酮+12％A4+4％十二烷基苯磺酸钙+8％腰果酚聚氧乙烯醚+4％蓖麻油聚氧乙烯醚+1.4％有机膨润土+1.2％气相法白炭黑+10％150#溶剂油+油酸甲酯补足6% oxadiazon+12%A4+4% calcium dodecylbenzenesulfonate+8% cardanol polyoxyethylene ether+4% castor oil polyoxyethylene ether+1.4% organic bentonite+1.2% gas phase method White carbon black+10％150#solvent oil+methyl oleate supplement
上述可分散油悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned dispersible oil suspension agent processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述可分散油悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。The above-mentioned dispersible oil suspension agent processing process: put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally shear evenly in the shearing machine. After the test is qualified, transfer To the storage tank for filling.
上述水悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned water suspension agent processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述水悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。The above-mentioned water suspension agent processing process: put all the materials into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and finally cut uniformly in the shearing machine, and transfer to the storage after the test is qualified. Can filling.
上述悬乳剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。The above-mentioned suspoemulsion processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, etc.
上述悬乳剂加工过程：将部分物料及助剂投入混料釜中，搅拌混合后过胶体磨，之后进 入砂磨机三级砂磨，砂磨完毕后转移至中间罐为水相；之后将剩余部分原药和助溶剂投入配料釜中，搅拌溶解至完全透明，搅拌均匀为油相；最后在剪切釜中开启剪切，将油相缓慢滴加至水相中，全部物料滴加完毕后，继续剪切1个小时，化验合格后，转移至储罐灌装。The above-mentioned suspoemulsion processing process: put part of the materials and additives into the mixing kettle, stir and mix, pass through the colloid mill, then enter the three-stage sand mill of the sand mill, and transfer to the intermediate tank as the water phase after the sand mill is completed; Put part of the original medicine and cosolvent into the batching kettle, stir and dissolve until it is completely transparent, and stir evenly into the oil phase; finally, open the shear in the shearing kettle, and slowly drip the oil phase into the water phase, after all the materials are dripped , Continue to cut for 1 hour, after passing the test, transfer to the storage tank for filling.
上述水乳剂加工设备：真空泵，配料釜，储罐，剪切釜。The above-mentioned water emulsion processing equipment: vacuum pump, batching kettle, storage tank, shearing kettle.
上述水乳剂加工过程：将原药和溶剂投入配料釜中，搅拌溶解至完全透明，之后加入乳化剂，搅拌均匀为油相，之后将乙二醇、消泡剂和去离子水抽入剪切釜内，最后在剪切状态下，将油相缓缓抽入剪切釜内，全部物料抽入后，继续剪切1个小时，化验合格后，转移至储罐灌装。The above-mentioned water emulsion processing process: Put the original medicine and solvent into the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir evenly into the oil phase, and then pump the glycol, defoamer and deionized water into the shear In the kettle, finally, under the shearing state, the oil phase is slowly drawn into the shearing kettle. After all the materials are drawn in, continue to shear for 1 hour. After passing the test, transfer to the storage tank for filling.
上述微乳剂加工设备：真空泵，配料釜，储罐。The above-mentioned microemulsion processing equipment: vacuum pump, batching kettle, storage tank.
上述微乳剂加工过程：将原药和溶剂投入配料釜中，搅拌溶解至完全透明，之后加入乳化剂，搅拌均匀，最后加去离子水，搅拌至溶液完全透明，化验合格后，转移至储罐灌装。The above microemulsion processing process: put the original drug and solvent into the batching kettle, stir and dissolve until completely transparent, then add the emulsifier, stir evenly, finally add deionized water, stir until the solution is completely transparent, and transfer to the storage tank after the test Filling.
上述乳油加工设备：真空泵，配料釜，储罐。The above-mentioned emulsifiable concentrate processing equipment: vacuum pump, batching kettle, storage tank.
上述乳油加工过程：将原药和溶剂投入配料釜中，搅拌溶解至完全透明，之后加入乳化剂，搅拌均匀至溶液完全透明，化验合格后，转移至储罐灌装。The above-mentioned emulsifiable concentrate processing process: put the original medicine and solvent into the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir evenly until the solution is completely transparent, and transfer to the storage tank for filling after passing the test.
上述水剂加工设备：真空泵，配料釜，储罐。The above-mentioned liquid processing equipment: vacuum pump, batching kettle, storage tank.
上述水剂加工过程：将原药和去离子投入配料釜中，搅拌溶解至完全透明，之后加入乳化剂，搅拌至溶液完全透明，化验合格后，转移至储罐灌装。The above-mentioned water preparation process: put the original medicine and deionized in the batching kettle, stir to dissolve until completely transparent, then add the emulsifier, stir until the solution is completely transparent, and transfer to the storage tank for filling after passing the test.
B)药效试验B)Efficacy test
苗后茎叶喷雾处理:Spray treatment of stems and leaves after seedling:
1)试验条件1) Test conditions
1.1)、供试靶标1.1), test target
西来稗、鳢肠、猪殃殃、看麦娘、日本看麦娘、陌上菜、波斯婆婆纳、牛繁缕、菵草、繁缕采自江苏淮安；鸭跖草、苣荬菜、金色狗尾草、虎尾草、大狗尾草、苦苣菜、水田稗、刺儿菜、苍耳采自黑龙江齐齐哈尔；野油菜、阿拉伯婆婆纳采自河南驻马店；丁香蓼、耳叶水苋采自浙江诸暨；反枝苋、播娘蒿、马唐、绿色狗尾草、小飞蓬、荠菜、牛筋草、圆叶牵牛、苘麻、藜、铁苋菜、龙葵采自山东青岛；长芒稗采自宁夏平罗。上述杂草采用盆栽法培养，用180х140mm塑料营养钵，摆放于搪瓷盘中，内装从农田采回经风干过筛的表层土壤(4/5处)，土壤湿度初期均控制在20％，挑选籽粒饱满均一的杂草种子，用25℃温水浸泡6小时，在28℃生化培养箱(黑暗)中催芽，将刚刚露白的杂草种子均匀摆放在土壤表面，根据种子粒径大小然后覆土0.5-1cm。Barnyard barnyard, snakehead intestines, pig scorpion, Kan Mai Niang, Japanese Kan Mai Niang, Moshang Cai, Persian Pona, Beef Chickweed, Potweed, and Chickweed were collected from Huai'an, Jiangsu; Commelina, Commelin, Chrysanthemum, Golden Setaria, Chrysanthemum, Setaria, Sonchus, Paddy Barnyard, Echinochloa, and Cocklebur were collected from Qiqihar, Heilongjiang; Wild rape and Arabian mother-in-law were collected from Zhumadian, Henan; Clove Polygonum, and Amaranthus edulis were collected from Zhuji, Zhejiang; Amaranthus retroflexus, Artemisia sowingii, Crabgrass, Green Setaria, Little Scoop, Shepherd's Purse, Gooseweed, Morning Glory, Abutilon, Chenopodium, Amaranth, Solanum were collected from Qingdao, Shandong; Barnyardgrass was collected from Ningxiaping Luo. The above-mentioned weeds are cultivated in pots. They are placed in an enamel tray in a 180х140mm plastic nutrient bowl, containing the top soil (4/5) collected from the farmland and air-dried and sieved. The soil moisture is initially controlled at 20%. Select Weed seeds with full and uniform grains, soaked in warm water at 25°C for 6 hours, incubate germination in a biochemical incubator (dark) at 28°C, evenly place the white weed seeds on the soil surface, and cover with 0.5 soil according to the size of the seed. -1cm.
1.2)、培养条件1.2), culture conditions
在可控日光温室内进行，温度20～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％，pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。It is carried out in a controllable solar greenhouse, with a temperature of 20 to 30°C, natural light, and a relative humidity of 57% to 72%. The soil type is loam, organic matter content is 1.63%, pH=7.1, alkali hydrolyzable nitrogen 84.3mg/kg, available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.
1.3)、仪器设备1.3), equipment
3WP-2000型行走式喷雾塔，农业部南京农业机械研究所。GA10型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)。3WP-2000 walking spray tower, Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
2)试验设计2) Experimental design
2.1)、试剂2.1), reagent
所需活性成分A来自专利CN201911321469.4，代表性化合物的制备实施例如下，其他化合物的合成方法类似，故不再赘述。The required active ingredient A comes from the patent CN201911321469.4. The preparation examples of representative compounds are as follows, and the synthesis methods of other compounds are similar, so they will not be repeated.
(1)化合物A1的合成(1) Synthesis of compound A1
将化合物a(0.5g，2.13mmol)，化合物b(313mg，2.55mmol)，催化量的TBAB(10mg)，DMF(10mL)置于圆底烧瓶中，室温15℃下搅拌24小时。液质检测少量原料剩余，即可处理。将反应液倒入到50mL水中，用甲基叔丁基醚萃取2次(50mL x 2)，有机相干燥，浓缩，经柱层析分离纯化，得到化合物A67(300mg，收率50％)。化合物A67为白色固体。Compound a (0.5 g, 2.13 mmol), compound b (313 mg, 2.55 mmol), a catalytic amount of TBAB (10 mg), and DMF (10 mL) were placed in a round bottom flask and stirred at room temperature 15°C for 24 hours. A small amount of remaining raw materials can be processed after liquid quality detection. The reaction solution was poured into 50 mL of water, extracted twice with methyl tert-butyl ether (50 mL x 2), the organic phase was dried, concentrated, and separated and purified by column chromatography to obtain compound A67 (300 mg, yield 50%). Compound A67 is a white solid.
Figure PCTCN2020081644-appb-000067
Figure PCTCN2020081644-appb-000067
将化合物A67(0.3g，1.06mmol)、甲醇(20mL)置于100mL单口瓶中，氢氧化锂(44.5mg，1.06mmol)溶解在2mL水中，室温下缓慢滴加到单口瓶中，室温搅拌12小时。液质检测原料反应完，用0.5M稀盐酸调pH至5-6，浓缩，用水和乙酸乙酯萃取。有机相干燥、浓缩得到化合物A1(200mg，收率70％)，化合物A1为白色固体。Put compound A67 (0.3g, 1.06mmol) and methanol (20mL) in a 100mL single-necked flask, dissolve lithium hydroxide (44.5mg, 1.06mmol) in 2mL of water, slowly add dropwise to the single-necked flask at room temperature, and stir at room temperature for 12 hour. After the liquid quality test, the raw material is reacted, the pH is adjusted to 5-6 with 0.5M dilute hydrochloric acid, concentrated, and extracted with water and ethyl acetate. The organic phase was dried and concentrated to obtain compound A1 (200 mg, yield 70%), and compound A1 was a white solid.
Figure PCTCN2020081644-appb-000068
Figure PCTCN2020081644-appb-000068
(2)化合物A2的合成(2) Synthesis of compound A2
将化合物A1(200mg，0.74mmol)，化合物c(75mg，0.74mmol)，DCC(152mg，0.74mmol)，无水DCM(20mL)置于100mL圆底烧瓶中，室温反应12小时。液质检测原料反应完，将反应液浓缩，经柱层析分离得到化合物A2(200mg，收率77％)，化合物A2为白色固体。Compound A1 (200 mg, 0.74 mmol), compound c (75 mg, 0.74 mmol), DCC (152 mg, 0.74 mmol), and anhydrous DCM (20 mL) were placed in a 100 mL round bottom flask and reacted at room temperature for 12 hours. Liquid quality detection The raw materials are reacted, the reaction solution is concentrated and separated by column chromatography to obtain compound A2 (200 mg, yield 77%), and compound A2 is a white solid.
Figure PCTCN2020081644-appb-000069
Figure PCTCN2020081644-appb-000069
所需活性成分B环吡氟草酮、双唑草酮、苯唑氟草酮、三唑磺草酮为本公司生产，其他由试剂公司购买。原药均采用丙酮作溶剂，用含量0.1％乳化剂吐温-80水溶液稀释，现用现稀释。The required active ingredients B, cicloflurzone, carfentrazone, flufentrazone, and trifentrazone are produced by the company, and the others are purchased by the reagent company. The original medicines all use acetone as the solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and are now diluted.
2.2)、试验处理2.2), test treatment
2.2.1)、剂量设置2.2.1), dose setting
在确定A与活性成分B配比或含量时，应从两种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上，设A、B活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。When determining the ratio or content of A and active ingredient B, the action characteristics and toxicities of the two agents should be measured, and the main purpose of the formulation should also be considered. In this study, based on the preliminary test, the single and mixed dosages of A and B active ingredients are shown in the table respectively. Use water without medicament and with the same solvent and emulsifier as a blank control.
2.2.2)、试验重复2.2.2), test repeat
每处理重复4次，每次每处理3盆，每盆播种杂草种子20粒，每处理共60株。Each treatment was repeated 4 times, 3 pots per treatment each time, 20 weed seeds were sown in each pot, and a total of 60 plants per treatment.
2.3)、处理方式2.3), processing method
2.3.1)、处理时间和次数2.3.1), processing time and frequency
试验共用药1次。待杂草3～4叶期，间苗，保持每盆内杂草15株，每处理保留45株，然后继续培养至禾本科杂草5～6叶、阔叶类杂草6～7叶进行处理。Test shared medicine once. At the 3~4 leaf stage of the weeds, thin the seedlings, keep 15 weeds in each pot, keep 45 weeds per treatment, and then continue to cultivate until 5-6 leaves for gramineous weeds and 6-7 leaves for broadleaf weeds for treatment .
2.3.2)、使用器械和用药方法2.3.2), the use of equipment and methods of medication
将培养好的试材均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔茎叶喷雾，喷液量按450公斤/公顷计。喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。 Place the cultivated test materials evenly on a platform with an area of 0.5 m 2 , and spray them with the stems and leaves of the 3WP-2000 walking spray tower. The spray volume is 450 kg/ha. The spray pressure is 0.3MPa. After all the liquid medicine is sprayed, close the air valve, 30 seconds later, open the spray tower door and take out the nutrient bowl. Then open the air valve, spray 50mL of water, and clean the spray tube.
3)试验方法3) Test method
采用盆栽法。杂草培养见1.1)，参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2)，采用茎叶处理法。处理后移入温室常规培养。Use potted plants. See 1.1) for weed cultivation, refer to the "Pesticide Indoor Bioassay Test Guidelines for Herbicides". See 2.3.2) for the medication method, and adopt the stem and leaf treatment method. After treatment, they were transferred to the greenhouse for routine cultivation.
4)数据调查与统计分析4) Data investigation and statistical analysis
4.1)、调查方法4.1), survey method
采用绝对数调查法，用刀片沿土壤表面切断存活杂草整株幼苗，用分析天平称量杂草鲜重。对于已经死亡的杂草，按鲜重为零计。Using the absolute number survey method, the whole seedling of the surviving weed was cut along the soil surface with a blade, and the fresh weight of the weed was weighed with an analytical balance. For weeds that have died, the fresh weight is zero.
4.2)、调查时间和次数4.2), survey time and frequency
处理后24天调查，共调查1次。24 days after the treatment, a total of 1 investigation was conducted.
4.3)、数据统计分析4.3), statistical analysis of data
用Gowing法计算各处理混合组合的理论鲜重抑制率(E0＝X+Y-X*Y/100)，然后与实测抑制率(E)相比较，评价二者混用对杂草的联合作用类型，当E-E0值大于10％为增效作用、小于-10％为拮抗作用、在-10％～10％之间为加成作用。并根据实际防效和除草剂特点、配方的平衡性等因素确定最佳配比。式中X为活性成分A用量为P时的鲜重抑制率；Y为活性成分B用量为Q时的鲜重抑制率。The Gowing method was used to calculate the theoretical fresh weight inhibition rate (E0=X+YX*Y/100) of each treatment mixture, and then compared with the measured inhibition rate (E) to evaluate the combined effect of the two mixed use on weeds. When E-E0 value greater than 10% is synergistic effect, less than -10% is antagonistic effect, and between -10% and 10% is additive effect. And according to the actual control effect, herbicide characteristics, formula balance and other factors to determine the best ratio. In the formula, X is the fresh weight inhibition rate when the amount of active ingredient A is P; Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
土壤封闭处理:Soil sealing treatment:
1)试验条件1) Test conditions
1.1)、供试靶标1.1), test target
西来稗采自江苏淮安；长芒稗采自宁夏平罗；水田稗采自黑龙江齐齐哈尔。Western barnyardgrass was collected from Huai'an, Jiangsu; long-mans barnyardgrass was collected from Pingluo, Ningxia; paddy barnyardgrass was collected from Qiqihar, Heilongjiang.
1.2)、培养条件1.2), culture conditions
在可控日光温室内进行，温度20～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％，pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。试验土壤定量装至盆钵的3/4处，然后从盆钵底部浇灌，使土壤完全湿润至饱和状态。将预处理的供试杂草种子，均匀定量撒播表面，根据种子大小覆土0.5-2cm，播种后24小时备用。It is carried out in a controllable solar greenhouse, with a temperature of 20 to 30°C, natural light, and a relative humidity of 57% to 72%. The soil type is loam, organic matter content is 1.63%, pH=7.1, alkali hydrolyzable nitrogen 84.3mg/kg, available phosphorus 38.5mg/kg, available potassium 82.1mg/kg. The test soil is quantitatively filled to 3/4 of the pot, and then watered from the bottom of the pot to make the soil completely wet to a saturated state. Spread the pretreated weed seeds evenly and quantitatively on the surface, cover 0.5-2cm of soil according to the seed size, and reserve 24 hours after sowing.
1.3)、仪器设备1.3), equipment
GA10型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)，移液器等。GA10 one-tenth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory), pipettes, etc.
2)试验设计2) Experimental design
2.1)、试剂2.1), reagent
原药均采用丙酮作溶剂，用含量0.1％乳化剂T-80水溶液稀释，现用现稀释。The original medicines all use acetone as the solvent, diluted with 0.1% emulsifier T-80 aqueous solution, and are now diluted.
2.2)、试验处理2.2), test treatment
2.2.1)、剂量设置2.2.1), dose setting
在确定A与活性成分B各组分配比或含量时，应从两种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上，设A、B活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。When determining the distribution ratio or content of each component of A and active ingredient B, the action characteristics and toxicity of the two drugs should be measured, and the main purpose of the formulation should also be considered. In this study, based on the preliminary test, the single and mixed dosages of A and B active ingredients are shown in the table respectively. Use water without medicament and with the same solvent and emulsifier as a blank control.
2.2.2)、试验重复2.2.2), test repeat
每处理重复4次，每次每处理3盆，每盆播种杂草种子30粒。Each treatment was repeated 4 times, 3 pots per treatment each time, and 30 weed seeds were sown in each pot.
3)试验方法3) Test method
将播种覆土的盆钵均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔土壤表面喷雾，喷液量按675公斤/公顷计。喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30 秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。 Place the pots and pots covered with soil evenly on a platform with an area of 0.5 m 2 , and spray the soil surface with a 3WP-2000 walking spray tower. The spray amount is 675 kg/ha. The spray pressure is 0.3MPa. After all the liquid medicine is sprayed, close the air valve, 30 seconds later, open the spray tower door and take out the nutrient bowl. Then open the air valve, spray 50mL of water, and clean the spray tube.
4)数据调查与统计分析4) Data investigation and statistical analysis
与苗后茎叶喷雾处理相同，故不再赘述。It is the same as the spray treatment of stems and leaves after seedling, so it will not be repeated.
统计结果见下表1-150，除已标记土壤封闭处理外，其他均为苗后茎叶喷雾处理。The statistical results are shown in the following table 1-150. Except for the marked soil sealing treatment, the others are all post-emergence stem and leaf spray treatment.
表1 A2混配五氟磺草胺对西来稗的实际防效与联合作用评价Table 1 Evaluation of actual control effect and joint effect of A2 blended penoxsulam on barnyardgrass
Figure PCTCN2020081644-appb-000070
Figure PCTCN2020081644-appb-000070
表2 A2混配双草醚对西来稗的实际防效与联合作用评价Table 2 Evaluation of the actual control effect and joint effect of A2 mixed bispyribac on barnyardgrass
Figure PCTCN2020081644-appb-000071
Figure PCTCN2020081644-appb-000071
表3 A2混配吡嘧磺隆对鳢肠的实际防效与联合作用评价Table 3 The actual control effect and joint effect evaluation of A2 mixed with pyrazosulfuron on the snakehead intestines
Figure PCTCN2020081644-appb-000072
Figure PCTCN2020081644-appb-000072
表4 A2混配烟嘧磺隆对西来稗的实际防效与联合作用评价Table 4 Evaluation of actual control effect and joint effect of A2 mixed nicosulfuron on barnyardgrass
Figure PCTCN2020081644-appb-000073
Figure PCTCN2020081644-appb-000073
表5 A2混配双氟磺草胺对猪殃殃的实际防效与联合作用评价Table 5 Evaluation of the actual control effect and joint effect of A2 mixed sulfentrazone on pig morbidity
Figure PCTCN2020081644-appb-000074
Figure PCTCN2020081644-appb-000074
表6 A2混配砜嘧磺隆对西来稗的实际防效与联合作用评价Table 6 The actual control effect and joint effect evaluation of A2 mixed sulfonesulfuron-methyl on barnyardgrass
Figure PCTCN2020081644-appb-000075
Figure PCTCN2020081644-appb-000075
表7 A2混配咪草烟对西来稗的实际防效与联合作用评价Table 7 Evaluation of actual control effect and joint effect of A2 mixed imazethapyr on barnyardgrass
Figure PCTCN2020081644-appb-000076
Figure PCTCN2020081644-appb-000076
表8 A2混配甲基咪草烟对西来稗的实际防效与联合作用评价Table 8 The actual control effect and joint effect evaluation of A2 mixed imazethapyr on barnyardgrass
Figure PCTCN2020081644-appb-000077
Figure PCTCN2020081644-appb-000077
表9 A2混配甲氧咪草烟对西来稗的实际防效与联合作用评价Table 9 Evaluation of the actual control effect and joint effect of A2 mixed imigra to barnyardgrass
Figure PCTCN2020081644-appb-000078
Figure PCTCN2020081644-appb-000078
表10 A2混配甲嘧磺隆对西来稗的实际防效与联合作用评价Table 10 Evaluation of actual control effect and joint effect of A2 mixed with metsulfuron on barnyardgrass
Figure PCTCN2020081644-appb-000079
Figure PCTCN2020081644-appb-000079
表11 A2混配氯酯磺草胺对鸭跖草的实际防效与联合作用评价Table 11 The actual control effect and joint effect evaluation of A2 mixed with chlorfentrazone on Commelina communis
Figure PCTCN2020081644-appb-000080
Figure PCTCN2020081644-appb-000080
表12 A2混配氰氟草酯对西来稗的实际防效与联合作用评价Table 12 The actual control effect and joint effect evaluation of A2 mixed with cyhalofop-butyl on barnyardgrass
Figure PCTCN2020081644-appb-000081
Figure PCTCN2020081644-appb-000081
表13 A2混配炔草酯对看麦娘的实际防效与联合作用评价Table 13 Evaluation of actual control effect and joint effect of A2 mixed clodinafop on Kanmai Niang
Figure PCTCN2020081644-appb-000082
Figure PCTCN2020081644-appb-000082
表14 A2混配唑啉草酯对看麦娘的实际防效与联合作用评价Table 14 Evaluation of actual control effect and joint effect of A2 mixed with pinoxaden on Kan Mai Niang
Figure PCTCN2020081644-appb-000083
Figure PCTCN2020081644-appb-000083
表15 A2混配烯草酮对西来稗的实际防效与联合作用评价Table 15 The actual control effect and joint effect evaluation of A2 mixed clethodim on barnyardgrass
Figure PCTCN2020081644-appb-000084
Figure PCTCN2020081644-appb-000084
表16 A2混配烯禾啶对西来稗的实际防效与联合作用评价Table 16 Evaluation of the actual control effect and joint effect of A2 mixed enoxypyr on barnyardgrass
Figure PCTCN2020081644-appb-000085
Figure PCTCN2020081644-appb-000085
表17 A2混配精喹禾灵对西来稗的实际防效与联合作用评价Table 17 The actual control effect and joint effect evaluation of A2 mixed quizalofop-p-ethyl on barnyardgrass
Figure PCTCN2020081644-appb-000086
Figure PCTCN2020081644-appb-000086
表18 A2混配精吡氟禾草灵对西来稗的实际防效与联合作用评价Table 18 The actual control effect and joint effect evaluation of A2 mixed fine fluoxyfop-ethyl on barnyardgrass
Figure PCTCN2020081644-appb-000087
Figure PCTCN2020081644-appb-000087
表19 A2混配高效氟吡甲禾灵对西来稗的实际防效与联合作用评价Table 19 Evaluation of the actual control effect and joint effect of A2 mixed with high-efficiency fluroxypyr on silylgrass
Figure PCTCN2020081644-appb-000088
Figure PCTCN2020081644-appb-000088
表20 A2混配莠去津对西来稗的实际防效与联合作用评价Table 20 Evaluation of actual control effect and joint effect of A2 mixed atrazine on barnyardgrass
Figure PCTCN2020081644-appb-000089
Figure PCTCN2020081644-appb-000089
表21 A2混配异丙隆对看麦娘的实际防效与联合作用评价Table 21 Evaluation of the actual control effect and joint effect of A2 mixed isoproturon on Kanmai Niang
Figure PCTCN2020081644-appb-000090
Figure PCTCN2020081644-appb-000090
表22 A2混配绿麦隆对看麦娘的实际防效与联合作用评价Table 22 Evaluation of actual control effect and joint effect of A2 mixed chlorotoluron on Kanmai Niang
Figure PCTCN2020081644-appb-000091
Figure PCTCN2020081644-appb-000091
表23 A2混配敌草隆对西来稗的实际防效与联合作用评价Table 23 Evaluation of actual control effect and joint effect of A2 mixed diuron on barnyardgrass
Figure PCTCN2020081644-appb-000092
Figure PCTCN2020081644-appb-000092
表24 A2混配灭草松对陌上菜的实际防效与联合作用评价Table 24 Evaluation of the actual control effect and joint effect of A2 mixed with Methasone on Moshangcai
Figure PCTCN2020081644-appb-000093
Figure PCTCN2020081644-appb-000093
表25 A2混配溴苯腈对反枝苋的实际防效与联合作用评价Table 25 Actual control effect and joint effect evaluation of A2 mixed bromoxynil on retro-branched amaranth
Figure PCTCN2020081644-appb-000094
Figure PCTCN2020081644-appb-000094
表26 A2混配敌稗对西来稗的实际防效与联合作用评价Table 26 Evaluation of the actual control effect and joint effect of A2 mixed propanil on western barnyardgrass
Figure PCTCN2020081644-appb-000095
Figure PCTCN2020081644-appb-000095
表27 A2混配环吡氟草酮对看麦娘的实际防效与联合作用评价Table 27 Evaluation of the actual control effect and combined effect of A2 mixed ciclofenac on Kanmai Niang
Figure PCTCN2020081644-appb-000096
Figure PCTCN2020081644-appb-000096
表28 A2混配双唑草酮对播娘蒿的实际防效与联合作用评价Table 28 Evaluation of actual control effect and combined effect of A2 mixed pyrenpyrid on Artemisia spp.
Figure PCTCN2020081644-appb-000097
Figure PCTCN2020081644-appb-000097
表29 A2混配苯唑氟草酮对马唐的实际防效与联合作用评价Table 29 Actual control effect and combined effect evaluation of A2 mixed oxaflutole on crabgrass
Figure PCTCN2020081644-appb-000098
Figure PCTCN2020081644-appb-000098
表30 A2混配三唑磺草酮对西来稗的实际防效与联合作用评价Table 30 Evaluation of the actual control effect and joint effect of A2 mixed triazuron on silican barnyardgrass
Figure PCTCN2020081644-appb-000099
Figure PCTCN2020081644-appb-000099
表31 A2混配呋喃磺草酮对西来稗的实际防效与联合作用评价Table 31 The actual control effect and joint effect evaluation of A2 mixed fursotrione on barnyardgrass
Figure PCTCN2020081644-appb-000100
Figure PCTCN2020081644-appb-000100
表32 A2混配硝磺草酮对马唐的实际防效与联合作用评价Table 32 The actual control effect and joint effect evaluation of A2 mixed mesotrione on crabgrass
Figure PCTCN2020081644-appb-000101
Figure PCTCN2020081644-appb-000101
表33 A2混配环磺酮对马唐的实际防效与联合作用评价Table 33 Actual control effect and combined effect evaluation of A2 mixed cyclosulfone on crabgrass
Figure PCTCN2020081644-appb-000102
Figure PCTCN2020081644-appb-000102
表34 A2混配苯唑草酮对绿色狗尾草的实际防效与联合作用评价Table 34 The actual control effect and joint effect evaluation of A2 mixed fentrazone on green setaria
Figure PCTCN2020081644-appb-000103
Figure PCTCN2020081644-appb-000103
表35 A2混配异噁唑草酮对西来稗的实际防效与联合作用评价Table 35 The actual control effect and joint effect evaluation of A2 mixed isoxaflutole on barnyardgrass
Figure PCTCN2020081644-appb-000104
Figure PCTCN2020081644-appb-000104
表36 A2混配双环磺草酮对西来稗的实际防效与联合作用评价Table 36 Evaluation of the actual control effect and joint effect of A2 mixed bicyclotrione on barnyardgrass
Figure PCTCN2020081644-appb-000105
Figure PCTCN2020081644-appb-000105
表37 A2混配吡氟酰草胺对波斯婆婆纳的实际防效与联合作用评价Table 37 The actual control effect and joint effect evaluation of A2 mixed diflufenican on Persian mother-in-law
Figure PCTCN2020081644-appb-000106
Figure PCTCN2020081644-appb-000106
表38 A2混配氟咯草酮对波斯婆婆纳的实际防效与联合作用评价Table 38 The actual control effect and combined effect evaluation of A2 mixed flurochloridone on Persian mother-in-law
Figure PCTCN2020081644-appb-000107
Figure PCTCN2020081644-appb-000107
表39 A2混配异噁草松对西来稗的实际防效与联合作用评价Table 39 Evaluation of actual control effect and joint effect of A2 mixed clomazone on barnyardgrass
Figure PCTCN2020081644-appb-000108
Figure PCTCN2020081644-appb-000108
表40 A2混配唑草酮对波斯婆婆纳的实际防效与联合作用评价Table 40 Evaluation of actual control effect and combined effect of A2 mixed carfentrazone on Persian mother-in-law
Figure PCTCN2020081644-appb-000109
Figure PCTCN2020081644-appb-000109
表41 A2混配氟磺胺草醚对反枝苋的实际防效与联合作用评价Table 41 The actual control effect and joint effect evaluation of A2 blended fomesafen on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000110
Figure PCTCN2020081644-appb-000110
表42 A2混配乙羧氟草醚对反枝苋的实际防效与联合作用评价Table 42 The actual control effect and joint effect evaluation of A2 mixed with acifluorfen on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000111
Figure PCTCN2020081644-appb-000111
表43 A2混配乙氧氟草醚对反枝苋的实际防效与联合作用评价Table 43 The actual control effect and joint effect evaluation of A2 mixed oxyfluorfen on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000112
Figure PCTCN2020081644-appb-000112
表44 A2混配乳氟禾草灵对反枝苋的实际防效与联合作用评价Table 44 The actual control effect and joint effect evaluation of A2 mixed Lactofop-ethyl on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000113
Figure PCTCN2020081644-appb-000113
表45 A2混配三氟羧草醚对反枝苋的实际防效与联合作用评价Table 45 The actual control effect and combined effect evaluation of A2 mixed acifluorfen on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000114
Figure PCTCN2020081644-appb-000114
表46 A2混配丙炔氟草胺对反枝苋的实际防效与联合作用评价Table 46 The actual control effect and joint effect evaluation of A2 mixed flumioxamide on Amaranthus retroflexus
Figure PCTCN2020081644-appb-000115
Figure PCTCN2020081644-appb-000115
表47 A2混配甲磺草胺对西来稗的实际防效与联合作用评价Table 47 Evaluation of the actual control effect and joint effect of A2 mixed sulfentrazone on barnyardgrass
Figure PCTCN2020081644-appb-000116
Figure PCTCN2020081644-appb-000116
表48 A2混配苯嘧磺草胺对小飞蓬的实际防效与联合作用评价Table 48 Evaluation of the actual control effect and joint effect of A2 mixed with saflufenacil on Scablon
Figure PCTCN2020081644-appb-000117
Figure PCTCN2020081644-appb-000117
表49 A2混配噁草酮对西来稗的实际防效与联合作用评价(土壤封闭处理)Table 49 Evaluation of the actual control effect and joint effect of A2 mixed oxadiazon on barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000118
Figure PCTCN2020081644-appb-000118
表50 A2混配丙炔噁草酮对西来稗的实际防效与联合作用评价(土壤封闭处理)Table 50 Evaluation of the actual control effect and combined effect of A2 mixed oxachlor on barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000119
Figure PCTCN2020081644-appb-000119
表51 A1混配五氟磺草胺对长芒稗的实际防效与联合作用评价Table 51 Evaluation of actual control effect and joint effect of A1 mixed penoxsulam on barnyardgrass
Figure PCTCN2020081644-appb-000120
Figure PCTCN2020081644-appb-000120
表52 A1混配双草醚对长芒稗的实际防效与联合作用评价Table 52 Evaluation of actual control effect and joint effect of A1 mixed bispyribac on barnyardgrass
Figure PCTCN2020081644-appb-000121
Figure PCTCN2020081644-appb-000121
表53 A1混配吡嘧磺隆对丁香蓼的实际防效与联合作用评价Table 53 The actual control effect and combined effect evaluation of A1 mixed pyrsulfuron-methyl on Polygonum syringae
Figure PCTCN2020081644-appb-000122
Figure PCTCN2020081644-appb-000122
表54 A1混配烟嘧磺隆对长芒稗的实际防效与联合作用评价Table 54 Evaluation of actual control effect and joint effect of A1 mixed nicosulfuron on barnyardgrass
Figure PCTCN2020081644-appb-000123
Figure PCTCN2020081644-appb-000123
表55 A1混配双氟磺草胺对牛繁缕的实际防效与联合作用评价Table 55 Evaluation of the actual control effect and joint effect of A1 mixed sulfentrazone on bovine chickweed
Figure PCTCN2020081644-appb-000124
Figure PCTCN2020081644-appb-000124
表56 A1混配砜嘧磺隆对长芒稗的实际防效与联合作用评价Table 56 Evaluation of actual control effect and joint effect of A1 mixed sulfonesulfuron on barnyardgrass
Figure PCTCN2020081644-appb-000125
Figure PCTCN2020081644-appb-000125
表57 A1混配咪草烟对长芒稗的实际防效与联合作用评价Table 57 Evaluation of actual control effect and joint effect of A1 mixed imazethapyr on barnyardgrass
Figure PCTCN2020081644-appb-000126
Figure PCTCN2020081644-appb-000126
表58 A1混配甲基咪草烟对长芒稗的实际防效与联合作用评价Table 58 Evaluation of the actual control effect and joint effect of A1 mixed imazethapyr on barnyardgrass
Figure PCTCN2020081644-appb-000127
Figure PCTCN2020081644-appb-000127
表59 A1混配甲氧咪草烟对长芒稗的实际防效与联合作用评价Table 59 Evaluation of the actual control effect and joint effect of A1 mixed imigra on barnyardgrass
Figure PCTCN2020081644-appb-000128
Figure PCTCN2020081644-appb-000128
表60 A1混配甲嘧磺隆对长芒稗的实际防效与联合作用评价Table 60 Evaluation of actual control effect and joint effect of A1 mixed with metsulfuron on barnyardgrass
Figure PCTCN2020081644-appb-000129
Figure PCTCN2020081644-appb-000129
表61 A1混配氯酯磺草胺对苣荬菜的实际防效与联合作用评价Table 61 Evaluation of the actual control effect and joint effect of A1 mixed chlorfentrazone on succhini
Figure PCTCN2020081644-appb-000130
Figure PCTCN2020081644-appb-000130
表62 A1混配氰氟草酯对长芒稗的实际防效与联合作用评价Table 62 Evaluation of actual control effect and joint effect of A1 mixed with cyhalofop-butyl on barnyardgrass
Figure PCTCN2020081644-appb-000131
Figure PCTCN2020081644-appb-000131
表63 A1混配炔草酯对日本看麦娘的实际防效与联合作用评价Table 63 Evaluation of the actual control and joint effects of A1 mixed clodinafop on the actual control effect and joint effect
Figure PCTCN2020081644-appb-000132
Figure PCTCN2020081644-appb-000132
表64 A1混配唑啉草酯对日本看麦娘的实际防效与联合作用评价Table 64 Evaluation of actual control effect and joint effect of A1 mixed pinoxaden on Japanese mites
Figure PCTCN2020081644-appb-000133
Figure PCTCN2020081644-appb-000133
表65 A1混配烯草酮对长芒稗的实际防效与联合作用评价Table 65 Evaluation of actual control effect and combined effect of A1 mixed clethodim on barnyardgrass
Figure PCTCN2020081644-appb-000134
Figure PCTCN2020081644-appb-000134
表66 A1混配烯禾啶对长芒稗的实际防效与联合作用评价Table 66 Evaluation of actual control effect and joint effect of A1 mixed enoxypyr on barnyardgrass
Figure PCTCN2020081644-appb-000135
Figure PCTCN2020081644-appb-000135
表67 A1混配精喹禾灵对长芒稗的实际防效与联合作用评价Table 67 Evaluation of actual control effect and joint effect of A1 mixed quizalofop on barnyardgrass
Figure PCTCN2020081644-appb-000136
Figure PCTCN2020081644-appb-000136
表68 A1混配精吡氟禾草灵对长芒稗的实际防效与联合作用评价Table 68 The actual control effect and joint effect evaluation of A1 mixed fine fluoxyp-ethyl on barnyardgrass
Figure PCTCN2020081644-appb-000137
Figure PCTCN2020081644-appb-000137
表69 A1混配高效氟吡甲禾灵对长芒稗的实际防效与联合作用评价Table 69 Evaluation of actual control effect and joint effect of A1 mixed high-efficiency fluroxypyr on barnyardgrass
Figure PCTCN2020081644-appb-000138
Figure PCTCN2020081644-appb-000138
表70 A1混配莠去津对长芒稗的实际防效与联合作用评价Table 70 Evaluation of actual control effect and joint effect of A1 mixed atrazine on barnyardgrass
Figure PCTCN2020081644-appb-000139
Figure PCTCN2020081644-appb-000139
表71 A1混配异丙隆对日本看麦娘的实际防效与联合作用评价Table 71 Evaluation of the actual control effect and joint effect of A1 mixed isoproturon on Japan Kanmai Niang
Figure PCTCN2020081644-appb-000140
Figure PCTCN2020081644-appb-000140
表72 A1混配绿麦隆对日本看麦娘的实际防效与联合作用评价Table 72 Evaluation of the actual control effect and joint effect of A1 blended chlorotoluron on Japan Kanmai Niang
Figure PCTCN2020081644-appb-000141
Figure PCTCN2020081644-appb-000141
表73 A1混配敌草隆对长芒稗的实际防效与联合作用评价Table 73 Evaluation of actual control effect and joint effect of A1 mixed diuron on barnyardgrass
Figure PCTCN2020081644-appb-000142
Figure PCTCN2020081644-appb-000142
表74 A1混配灭草松对苘麻的实际防效与联合作用评价Table 74 Evaluation of the actual control effect and joint effect of A1 mixed with Bencaxone on Abutilon
Figure PCTCN2020081644-appb-000143
Figure PCTCN2020081644-appb-000143
表75 A1混配溴苯腈对藜的实际防效与联合作用评价Table 75 Actual control effect and joint effect evaluation of A1 mixed bromoxynil on Chenopodium
Figure PCTCN2020081644-appb-000144
Figure PCTCN2020081644-appb-000144
表76 A1混配敌稗对长芒稗的实际防效与联合作用评价Table 76 Evaluation of the actual control effect and joint effect of A1 mixed with propanil on barnyardgrass
Figure PCTCN2020081644-appb-000145
Figure PCTCN2020081644-appb-000145
表77 A1混配环吡氟草酮对日本看麦娘的实际防效与联合作用评价Table 77 Evaluation of the actual control effect and combined effect of A1 mixed ciclofenac on the Japanese Kanmai Niang
Figure PCTCN2020081644-appb-000146
Figure PCTCN2020081644-appb-000146
表78 A1混配双唑草酮对荠菜的实际防效与联合作用评价Table 78 Evaluation of the actual control effect and combined effect of A1 blended fentrazone on shepherd's purse
Figure PCTCN2020081644-appb-000147
Figure PCTCN2020081644-appb-000147
表79 A1混配苯唑氟草酮对牛筋草的实际防效与联合作用评价Table 79 The actual control effect and joint effect evaluation of A1 mixed oxaflufen on goosegrass
Figure PCTCN2020081644-appb-000148
Figure PCTCN2020081644-appb-000148
表80 A1混配三唑磺草酮对长芒稗的实际防效与联合作用评价Table 80 Evaluation of the actual control effect and joint effect of A1 mixed triazole sulcotrione on barnyardgrass
Figure PCTCN2020081644-appb-000149
Figure PCTCN2020081644-appb-000149
表81 A1混配呋喃磺草酮对长芒稗的实际防效与联合作用评价Table 81 The actual control effect and combined effect evaluation of A1 mixed fursotrione on barnyardgrass
Figure PCTCN2020081644-appb-000150
Figure PCTCN2020081644-appb-000150
表82 A1混配硝磺草酮对牛筋草的实际防效与联合作用评价Table 82 Evaluation of actual control effect and joint effect of A1 mixed mesotrione on goosegrass
Figure PCTCN2020081644-appb-000151
Figure PCTCN2020081644-appb-000151
表83 A1混配环磺酮对牛筋草的实际防效与联合作用评价Table 83 Actual control effect and joint effect evaluation of A1 mixed cyclosulfone on goosegrass
Figure PCTCN2020081644-appb-000152
Figure PCTCN2020081644-appb-000152
表84 A1混配苯唑草酮对金色狗尾草的实际防效与联合作用评价Table 84 The actual control effect and combined effect evaluation of A1 mixed with oxaflutole on Setaria viridis
Figure PCTCN2020081644-appb-000153
Figure PCTCN2020081644-appb-000153
表85 A1混配异噁唑草酮对长芒稗的实际防效与联合作用评价Table 85 Evaluation of actual control effect and combined effect of A1 mixed isoxaflutole on barnyardgrass
Figure PCTCN2020081644-appb-000154
Figure PCTCN2020081644-appb-000154
表86 A1混配双环磺草酮对长芒稗的实际防效与联合作用评价Table 86 Evaluation of actual control effect and joint effect of A1 mixed bicyclotrione on barnyardgrass
Figure PCTCN2020081644-appb-000155
Figure PCTCN2020081644-appb-000155
表87 A1混配吡氟酰草胺对阿拉伯婆婆纳的实际防效与联合作用评价Table 87 The actual control effect and joint effect evaluation of A1 mixed diflufenican on Arabian mother-in-law
Figure PCTCN2020081644-appb-000156
Figure PCTCN2020081644-appb-000156
表88 A1混配氟咯草酮对阿拉伯婆婆纳的实际防效与联合作用评价Table 88 Evaluation of the actual control and joint effects of A1 mixed flurochloridone on Arabian mother-in-law
Figure PCTCN2020081644-appb-000157
Figure PCTCN2020081644-appb-000157
表89 A1混配异噁草松对长芒稗的实际防效与联合作用评价Table 89 Evaluation of actual control effect and joint effect of A1 mixed clomazone on barnyardgrass
Figure PCTCN2020081644-appb-000158
Figure PCTCN2020081644-appb-000158
表90 A1混配唑草酮对阿拉伯婆婆纳的实际防效与联合作用评价Table 90 Evaluation of the actual control and combined effects of A1 mixed carfentrazone on Arabian mother-in-law
Figure PCTCN2020081644-appb-000159
Figure PCTCN2020081644-appb-000159
表91 A1混配氟磺胺草醚对藜的实际防效与联合作用评价Table 91 Evaluation of the actual control effect and joint effect of A1 blended fomesafen on Chenopodium album
Figure PCTCN2020081644-appb-000160
Figure PCTCN2020081644-appb-000160
表92 A1混配乙羧氟草醚对藜的实际防效与联合作用评价Table 92 Evaluation of the actual control effect and joint effect of A1 mixed oxyfluorfen on Chenopodium
Figure PCTCN2020081644-appb-000161
Figure PCTCN2020081644-appb-000161
表93 A1混配乙氧氟草醚对藜的实际防效与联合作用评价Table 93 Evaluation of actual control effect and joint effect of A1 mixed oxyfluorfen on Chenopodium
Figure PCTCN2020081644-appb-000162
Figure PCTCN2020081644-appb-000162
表94 A1混配乳氟禾草灵对藜的实际防效与联合作用评价Table 94 Evaluation of actual control effect and joint effect of A1 mixed lactofen on Chenopodium album
Figure PCTCN2020081644-appb-000163
Figure PCTCN2020081644-appb-000163
表95 A1混配三氟羧草醚对藜的实际防效与联合作用评价Table 95 Evaluation of the actual control effect and joint effect of A1 mixed acifluorfen on Chenopodium album
Figure PCTCN2020081644-appb-000164
Figure PCTCN2020081644-appb-000164
表96 A1混配丙炔氟草胺对藜的实际防效与联合作用评价Table 96 Evaluation of the actual control effect and combined effect of A1 mixed flumioxazin on Chenopodium album
Figure PCTCN2020081644-appb-000165
Figure PCTCN2020081644-appb-000165
表97 A1混配甲磺草胺对长芒稗的实际防效与联合作用评价Table 97 Actual control effect and joint effect evaluation of A1 mixed sulfentrazone on barnyardgrass
Figure PCTCN2020081644-appb-000166
Figure PCTCN2020081644-appb-000166
表98 A1混配苯嘧磺草胺对圆叶牵牛的实际防效与联合作用评价Table 98 Evaluation of actual control effect and joint effect of A1 mixed with saflufenacil on morning glory rotundifolia
Figure PCTCN2020081644-appb-000167
Figure PCTCN2020081644-appb-000167
表99 A1混配噁草酮对长芒稗的实际防效与联合作用评价(土壤封闭处理)Table 99 Evaluation of actual control effect and joint effect of A1 mixed oxadiazon on barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000168
Figure PCTCN2020081644-appb-000168
表100 A1混配丙炔噁草酮对长芒稗的实际防效与联合作用评价(土壤封闭处理)Table 100 Evaluation of the actual control effect and joint effect of A1 mixed oxachlor on barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000169
Figure PCTCN2020081644-appb-000169
表101 A4混配五氟磺草胺对水田稗的实际防效与联合作用评价Table 101 Evaluation of actual control effect and joint effect of A4 mixed penoxsulam on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000170
Figure PCTCN2020081644-appb-000170
表102 A4混配双草醚对水田稗的实际防效与联合作用评价Table 102 The actual control effect and joint effect evaluation of A4 mixed bispyribac on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000171
Figure PCTCN2020081644-appb-000171
表103 A3混配吡嘧磺隆对耳叶水苋的实际防效与联合作用评价Table 103 Actual control effect and combined effect evaluation of A3 mixed pyrsulfuron-methyl on Amaranthus auricula
Figure PCTCN2020081644-appb-000172
Figure PCTCN2020081644-appb-000172
表104 A4混配烟嘧磺隆对水田稗的实际防效与联合作用评价Table 104 Evaluation of actual control effect and joint effect of A4 mixed nicosulfuron on paddy barnyardgrass
Figure PCTCN2020081644-appb-000173
Figure PCTCN2020081644-appb-000173
表105 A3混配双氟磺草胺对繁缕的实际防效与联合作用评价Table 105 Evaluation of the actual control effect and joint effect of A3 mixed sulfentrazone on chickweed
Figure PCTCN2020081644-appb-000174
Figure PCTCN2020081644-appb-000174
表106 A4混配砜嘧磺隆对水田稗的实际防效与联合作用评价Table 106 The actual control effect and joint effect evaluation of A4 mixed sulfone sulfuron-methyl on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000175
Figure PCTCN2020081644-appb-000175
表107 A4混配咪草烟对水田稗的实际防效与联合作用评价Table 107 Evaluation of actual control effect and joint effect of A4 mixed imazethapyr on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000176
Figure PCTCN2020081644-appb-000176
表108 A4混配甲基咪草烟对水田稗的实际防效与联合作用评价Table 108 Evaluation of the actual control effect and joint effect of A4 mixed imazethapyr on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000177
Figure PCTCN2020081644-appb-000177
表109 A4混配甲氧咪草烟对水田稗的实际防效与联合作用评价Table 109 The actual control effect and joint effect evaluation of A4 mixed imigra on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000178
Figure PCTCN2020081644-appb-000178
表110 A4混配甲嘧磺隆对水田稗的实际防效与联合作用评价Table 110 Evaluation of actual control effect and joint effect of A4 mixed with metsulfuron on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000179
Figure PCTCN2020081644-appb-000179
表111 A3混配氯酯磺草胺对刺儿菜的实际防效与联合作用评价Table 111 The actual control effect and joint effect evaluation of A3 mixed chlorfentrazone on Cieraria chinensis
Figure PCTCN2020081644-appb-000180
Figure PCTCN2020081644-appb-000180
表112 A4混配氰氟草酯对水田稗的实际防效与联合作用评价Table 112 Actual control effect and joint effect evaluation of A4 mixed with cyhalofop-butyl on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000181
Figure PCTCN2020081644-appb-000181
表113 A3混配炔草酯对菵草的实际防效与联合作用评价Table 113 Evaluation of actual control effect and joint effect of A3 mixed clodinafop on potflower
Figure PCTCN2020081644-appb-000182
Figure PCTCN2020081644-appb-000182
表114 A3混配唑啉草酯对菵草的实际防效与联合作用评价Table 114 Evaluation of actual control effect and joint effect of A3 mixed pinoxaden on calamus
Figure PCTCN2020081644-appb-000183
Figure PCTCN2020081644-appb-000183
表115 A4混配烯草酮对水田稗的实际防效与联合作用评价Table 115 Evaluation of actual control effect and joint effect of A4 mixed clethodim on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000184
Figure PCTCN2020081644-appb-000184
表116 A4混配烯禾啶对水田稗的实际防效与联合作用评价Table 116 Evaluation of actual control effect and joint effect of A4 mixed enoxypyr on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000185
Figure PCTCN2020081644-appb-000185
表117 A4混配精喹禾灵对水田稗的实际防效与联合作用评价Table 117 Evaluation of actual control effect and joint effect of A4 mixed quizalofop on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000186
Figure PCTCN2020081644-appb-000186
表118 A4混配精吡氟禾草灵对水田稗的实际防效与联合作用评价Table 118 Evaluation of the actual control effect and joint effect of A4 blended refined diflufen-op-ethyl on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000187
Figure PCTCN2020081644-appb-000187
表119 A4混配高效氟吡甲禾灵对水田稗的实际防效与联合作用评价Table 119 Evaluation of actual control effect and joint effect of A4 mixed high-efficiency fluroxypyr on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000188
Figure PCTCN2020081644-appb-000188
表120 A4混配莠去津对水田稗的实际防效与联合作用评价Table 120 Evaluation of actual control and joint effects of A4 mixed atrazine on paddy barnyardgrass
Figure PCTCN2020081644-appb-000189
Figure PCTCN2020081644-appb-000189
表121 A3混配异丙隆对菵草的实际防效与联合作用评价Table 121 Evaluation of actual control effect and joint effect of A3 mixed isoproturon on calamus
Figure PCTCN2020081644-appb-000190
Figure PCTCN2020081644-appb-000190
表122 A3混配绿麦隆对菵草的实际防效与联合作用评价Table 122 Evaluation of actual control effect and joint effect of A3 mixed chlorotoluron on calamus
Figure PCTCN2020081644-appb-000191
Figure PCTCN2020081644-appb-000191
表123 A4混配敌草隆对水田稗的实际防效与联合作用评价Table 123 The actual control effect and joint effect evaluation of A4 mixed diuron on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000192
Figure PCTCN2020081644-appb-000192
表124 A3混配灭草松对苍耳的实际防效与联合作用评价Table 124 Evaluation of the actual control effect and combined effect of A3 mixed with methasone on cocklebur
Figure PCTCN2020081644-appb-000193
Figure PCTCN2020081644-appb-000193
表125 A3混配溴苯腈对铁苋菜的实际防效与联合作用评价Table 125 The actual control effect and joint effect evaluation of A3 mixed bromoxynil on amaranth
Figure PCTCN2020081644-appb-000194
Figure PCTCN2020081644-appb-000194
表126 A4混配敌稗对水田稗的实际防效与联合作用评价Table 126 Evaluation of the actual control effect and joint effect of A4 mixed with barnyardgrass on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000195
Figure PCTCN2020081644-appb-000195
表127 A3混配环吡氟草酮对菵草的实际防效与联合作用评价Table 127 The actual control effect and joint effect evaluation of A3 mixed ciclofluzone on calamus
Figure PCTCN2020081644-appb-000196
Figure PCTCN2020081644-appb-000196
表128 A3混配双唑草酮对野油菜的实际防效与联合作用评价Table 128 The actual control effect and joint effect evaluation of A3 mixed pyrenpyrazone on wild rape
Figure PCTCN2020081644-appb-000197
Figure PCTCN2020081644-appb-000197
表129 A3混配苯唑氟草酮对虎尾草的实际防效与联合作用评价Table 129 The actual control effect and joint effect evaluation of A3 mixed oxaflutole on Chrysanthemum
Figure PCTCN2020081644-appb-000198
Figure PCTCN2020081644-appb-000198
表130 A4混配三唑磺草酮对水田稗的实际防效与联合作用评价Table 130 The actual control effect and joint effect evaluation of A4 mixed triazole sulcotrione on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000199
Figure PCTCN2020081644-appb-000199
表131 A4混配呋喃磺草酮对水田稗的实际防效与联合作用评价Table 131 The actual control effect and joint effect evaluation of A4 mixed fursotrione on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000200
Figure PCTCN2020081644-appb-000200
表132 A3混配硝磺草酮对虎尾草的实际防效与联合作用评价Table 132 Evaluation of actual control effect and joint effect of A3 mixed mesotrione on Chrysanthemum
Figure PCTCN2020081644-appb-000201
Figure PCTCN2020081644-appb-000201
Figure PCTCN2020081644-appb-000202
Figure PCTCN2020081644-appb-000202
表133 A3混配环磺酮对虎尾草的实际防效与联合作用评价Table 133 The actual control effect and joint effect evaluation of A3 mixed cyclosulfonone on Chrysanthemum sinensis
Figure PCTCN2020081644-appb-000203
Figure PCTCN2020081644-appb-000203
表134 A3混配苯唑草酮对大狗尾草的实际防效与联合作用评价Table 134 Evaluation of actual control effect and joint effect of A3 mixed with oxaflutole on Setaria serrata
Figure PCTCN2020081644-appb-000204
Figure PCTCN2020081644-appb-000204
表135 A4混配异噁唑草酮对水田稗的实际防效与联合作用评价Table 135 The actual control effect and joint effect evaluation of A4 mixed isoxaflutole on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000205
Figure PCTCN2020081644-appb-000205
表136 A4混配双环磺草酮对水田稗的实际防效与联合作用评价Table 136 Evaluation of actual control effect and joint effect of A4 mixed bicyclotrione on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000206
Figure PCTCN2020081644-appb-000206
表137 A3混配吡氟酰草胺对龙葵的实际防效与联合作用评价Table 137 The actual control effect and joint effect evaluation of A3 mixed diflufenican on Solanum
Figure PCTCN2020081644-appb-000207
Figure PCTCN2020081644-appb-000207
表138 A3混配氟咯草酮对龙葵的实际防效与联合作用评价Table 138 The actual control effect and combined effect evaluation of A3 mixed flurochloridone on Solanum
Figure PCTCN2020081644-appb-000208
Figure PCTCN2020081644-appb-000208
Figure PCTCN2020081644-appb-000209
Figure PCTCN2020081644-appb-000209
表139 A4混配异噁草松对水田稗的实际防效与联合作用评价Table 139 Evaluation of actual control effect and joint effect of A4 mixed clomazone on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000210
Figure PCTCN2020081644-appb-000210
表140 A3混配唑草酮对龙葵的实际防效与联合作用评价Table 140 The actual control effect and joint effect evaluation of A3 mixed carfentrazone on Solanum
Figure PCTCN2020081644-appb-000211
Figure PCTCN2020081644-appb-000211
表141 A3混配氟磺胺草醚对铁苋菜的实际防效与联合作用评价Table 141 The actual control effect and joint effect evaluation of A3 mixed with fomesafen on amaranth
Figure PCTCN2020081644-appb-000212
Figure PCTCN2020081644-appb-000212
表142 A3混配乙羧氟草醚对铁苋菜的实际防效与联合作用评价Table 142 Evaluation of actual control effect and joint effect of A3 mixed with acifluorfen on Amaranthus
Figure PCTCN2020081644-appb-000213
Figure PCTCN2020081644-appb-000213
表143 A3混配乙氧氟草醚对铁苋菜的实际防效与联合作用评价Table 143 The actual control effect and joint effect evaluation of A3 mixed oxyfluorfen on Amaranthus
Figure PCTCN2020081644-appb-000214
Figure PCTCN2020081644-appb-000214
表144 A3混配乳氟禾草灵对铁苋菜的实际防效与联合作用评价Table 144 Evaluation of actual control effect and combined effect of A3 mixed lactofen on Amaranthus
Figure PCTCN2020081644-appb-000215
Figure PCTCN2020081644-appb-000215
Figure PCTCN2020081644-appb-000216
Figure PCTCN2020081644-appb-000216
表145 A3混配三氟羧草醚对铁苋菜的实际防效与联合作用评价Table 145 Evaluation of actual control effect and joint effect of A3 mixed acifluorfen on Amaranthus
Figure PCTCN2020081644-appb-000217
Figure PCTCN2020081644-appb-000217
表146 A3混配丙炔氟草胺对铁苋菜的实际防效与联合作用评价Table 146 The actual control effect and joint effect evaluation of A3 mixed flumioxamide on Amaranthus
Figure PCTCN2020081644-appb-000218
Figure PCTCN2020081644-appb-000218
表147 A4混配甲磺草胺对水田稗的实际防效与联合作用评价Table 147 Evaluation of actual control effect and joint effect of A4 mixed sulfentrazone on paddy field barnyardgrass
Figure PCTCN2020081644-appb-000219
Figure PCTCN2020081644-appb-000219
表148 A3混配苯嘧磺草胺对苦苣菜的实际防效与联合作用评价Table 148 Evaluation of the actual control effect and joint effect of A3 mixed with saflufenacil on Sonchus officinalis
Figure PCTCN2020081644-appb-000220
Figure PCTCN2020081644-appb-000220
表149 A4混配噁草酮对水田稗的实际防效与联合作用评价(土壤封闭处理)Table 149 Evaluation of actual control effect and joint effect of A4 mixed oxadiazone on paddy field barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000221
Figure PCTCN2020081644-appb-000221
表150 A4混配丙炔噁草酮对水田稗的实际防效与联合作用评价(土壤封闭处理)Table 150 Evaluation of the actual control effect and joint effect of A4 mixed propinol on paddy barnyardgrass (soil sealing treatment)
Figure PCTCN2020081644-appb-000222
Figure PCTCN2020081644-appb-000222
C)大田示范C) Daejeon Demonstration
利用实施例1-150制得的除草剂组合物进行田间杂草效果试验。The herbicide composition prepared in Examples 1-150 was used to conduct field weed effect tests.
2018年在山东青岛试验点进行示范性推广试验。田间发生的杂草主要有：马唐、牛筋草、稗草、绿色狗尾草、野稷、反枝苋、铁苋菜、问荆、粟米草、水莎草等。In 2018, a demonstration promotion test was carried out at the Qingdao test site in Shandong. The main weeds that occur in the field are: crabgrass, goosegrass, barnyard grass, green setaria, wild grass, amaranthus retroflexus, amaranthus spp, amaranthus, millet grass, sedge, etc.
试验方法:experiment method:
茎叶处理:待杂草处于3-5叶期，手动喷雾器，兑水量30公斤/667m 2，采用茎叶喷雾处理。 Stem and leaf treatment: When the weeds are in the 3-5 leaf stage, use a manual sprayer, with a water volume of 30 kg/667m 2 , and use stem and leaf spray treatment.
具体试验药剂及剂量详见表151，小区面积50平方米，每处理重复4次。施药后45天调查防除效果见表151。The specific test agents and doses are shown in Table 151. The plot area is 50 square meters, and each treatment is repeated 4 times. See Table 151 for the investigation of the control effect 45 days after application.
Figure PCTCN2020081644-appb-000223
Figure PCTCN2020081644-appb-000223
表151所述复配组合物的大田示范效果情况Field demonstration effect of the compound composition described in Table 151
实施例序号Example number 用量(g a.i./ha)Dosage (g a.i./ha) 鲜重防效(％)Fresh weight control effect (%)
11 150150 97.897.8
22 180180 95.695.6
33 210210 93.893.8
44 150150 98.398.3
55 180180 95.295.2
66 210210 94.694.6
77 150150 97.597.5
88 180180 96.796.7
99 210210 94.994.9
1010 180180 96.696.6
1111 210210 96.796.7
1212 240240 94.194.1
1313 124.5124.5 97.197.1
1414 154.5154.5 96.396.3
1515 184.5184.5 94.994.9
1616 150150 96.396.3
1717 180180 97.897.8
1818 210210 95.295.2
1919 210210 95.495.4
2020 240240 97.897.8
21twenty one 270270 94.494.4
22twenty two 270270 95.995.9
23twenty three 300300 97.497.4
24twenty four 330330 95.295.2
2525 180180 95.195.1
2626 210210 98.998.9
2727 240240 95.595.5
2828 270270 94.294.2
2929 300300 98.998.9
3030 330330 94.794.7
3131 150150 94.794.7
3232 180180 98.598.5
3333 210210 95.595.5
3434 270270 93.993.9
3535 300300 98.398.3
3636 330330 95.895.8
3737 165165 97.597.5
3838 195195 95.195.1
3939 225225 93.693.6
4040 195195 97.697.6
4141 225225 94.994.9
4242 255255 94.194.1
4343 210210 97.397.3
4444 240240 95.895.8
4545 270270 94.694.6
4646 345345 96.196.1
4747 375375 96.596.5
4848 405405 93.493.4
4949 180180 96.896.8
5050 210210 95.895.8
5151 240240 94.794.7
5252 180180 95.695.6
5353 210210 97.597.5
5454 240240 94.794.7
5555 180180 95.195.1
5656 210210 97.397.3
5757 240240 94.294.2
5858 870870 95.295.2
5959 900900 97.197.1
6060 930930 94.794.7
6161 870870 94.994.9
6262 900900 97.897.8
6363 930930 95.295.2
6464 870870 93.793.7
6565 900900 98.798.7
6666 930930 93.593.5
6767 10201020 94.494.4
6868 10501050 97.797.7
6969 10801080 95.395.3
7070 720720 93.293.2
7171 750750 97.597.5
7272 780780 95.395.3
7373 300300 92.792.7
7474 330330 96.596.5
7575 360360 95.395.3
7676 16201620 94.594.5
7777 16501650 94.994.9
7878 16801680 97.297.2
7979 255255 94.194.1
8080 285285 94.894.8
8181 315315 96.396.3
8282 150150 93.593.5
8383 180180 94.594.5
8484 210210 96.896.8
8585 255255 94.294.2
8686 285285 94.794.7
8787 315315 96.296.2
8888 300300 94.994.9
8989 330330 93.293.2
9090 360360 98.598.5
9191 210210 92.392.3
9292 240240 94.194.1
9393 270270 96.996.9
9494 270270 95.195.1
9595 300300 92.592.5
9696 330330 96.796.7
9797 210210 94.894.8
9898 240240 92.292.2
9999 270270 96.396.3
100100 165165 94.294.2
101101 195195 93.893.8
102102 225225 94.494.4
103103 210210 97.997.9
104104 240240 95.795.7
105105 270270 94.594.5
106106 420420 97.197.1
107107 450450 93.393.3
108108 480480 93.893.8
109109 270270 97.297.2
110110 300300 93.793.7
111111 330330 94.294.2
112112 870870 96.596.5
113113 900900 93.893.8
114114 930930 92.992.9
115115 570570 99.899.8
116116 600600 92.692.6
117117 630630 92.992.9
118118 150150 96.696.6
119119 180180 94.394.3
120120 210210 92.392.3
121121 495495 97.997.9
122122 525525 94.694.6
123123 555555 96.896.8
124124 135135 95.495.4
125125 165165 95.895.8
126126 195195 97.497.4
127127 300300 92.192.1
128128 330330 93.593.5
129129 360360 96.496.4
130130 240240 93.593.5
131131 270270 95.495.4
132132 300300 96.396.3
133133 570570 93.193.1
134134 600600 93.293.2
135135 630630 99.399.3
136136 210210 92.192.1
137137 240240 92.792.7
138138 270270 95.595.5
139139 480480 95.195.1
140140 510510 93.693.6
141141 540540 98.298.2
142142 480480 93.493.4
143143 510510 97.997.9
144144 540540 94.694.6
145145 720720 91.591.5
146146 750750 96.796.7
147147 780780 94.994.9
148148 210210 93.793.7
149149 240240 95.895.8
150150 270270 96.396.3
经过大量试验和探索，本发明意外地发现，所述组合物用于防除耳叶水苋、反枝苋、铁苋菜、龙葵、鳢肠、猪殃殃、小飞蓬、荠菜、苘麻、波斯婆婆纳、阿拉伯婆婆纳、牛繁缕、繁缕、野油菜、丁香蓼、陌上菜、苣荬菜、苦苣菜、刺儿菜、苍耳、播娘蒿、藜、鸭跖草、圆叶牵牛等阔叶类杂草，看麦娘、日本看麦娘、虎尾草、西来稗、水田稗、长芒稗、大狗尾草、绿色狗尾草、金色狗尾草、马唐、牛筋草、菵草等禾本科杂草，具有令人惊讶的、意想不到的增效作用，这种增效作用在低剂量下表现更为显著，可降低用药量，降低对环境的污染，且合理复配降低了农用成本，对ALS、ACCase抑制剂抗性杂草高效，具有很好的应用 前景。同时经过测试在小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等大田中显示良好的选择性和优异的增效作用，可以开发成具有广泛市场价值的除草剂混剂。After a lot of experiments and explorations, the present invention unexpectedly discovered that the composition is used for the prevention and control of Amaranthus amaranthus, Amaranthus retroflexus, Amaranthus amaranthus, Solanum vulgaris, Channa intestines, Pork Salmon, Eleutherococcus sp Mother-in-law, Arabian mother-in-law, cow chickweed, chickweed, wild rape, Polygonum clove, Moshangcai, cocory, sorrel, chinensis, cocklebur, artemisia sowing, quinoa, dayflower, round Leaf morning glory and other broad-leaved weeds, Kan Mai Niang, Japanese Mai Niang, Chrysanthemum japonicum, Western barnyardgrass, Paddy barnyardgrass, Echinochloa crusgalli, Setaria viridis, Green Setaria, Golden Setaria, Crabgrass, Gooseweed, Sawgrass Grasses and other gramineous weeds have surprising and unexpected synergistic effects. This synergistic effect is more pronounced at low doses, which can reduce the amount of medicine used, reduce environmental pollution, and reduce reasonable compounding It is effective against ALS and ACCase inhibitor resistant weeds and has a good application prospect. At the same time, it has been tested in wheat fields, corn fields, rice fields, peanuts, sugarcane, sorghum, millet, potatoes, rapeseed, soybeans, cotton, vegetables, bluegrass, tall fescue, Zoysia grass and other fields. Excellent synergistic effect, can be developed into a herbicide mixture with broad market value.

Claims (10)

  1. 一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，包括除草有效量的活性成分A和活性成分B，其中，A herbicidal composition containing an R-type pyridyloxy carboxylic acid derivative, which is characterized in that it includes an effective amount of herbicidal active ingredient A and active ingredient B, wherein,
    活性成分A选自如式Ⅰ所示的R型吡啶氧基羧酸及其盐、酯衍生物中的一种或多种：The active ingredient A is selected from one or more of the R-type pyridyloxy carboxylic acid and its salts and ester derivatives as shown in formula I:
    Figure PCTCN2020081644-appb-100001
    Figure PCTCN2020081644-appb-100001
    其中，R 1、R 2分别独立地代表卤素、C1-C6烷基、卤代C1-C6烷基、C3-C6环烷基； Wherein, R 1 and R 2 each independently represent halogen, C1-C6 alkyl, halogenated C1-C6 alkyl, and C3-C6 cycloalkyl;
    R 3代表氢、卤素、C1-C6烷基、卤代C1-C6烷基； R 3 represents hydrogen, halogen, C1-C6 alkyl, halogenated C1-C6 alkyl;
    Q代表C1-C6烷基，卤代C1-C6烷基，C3-C6环烷基，C2-C6烯基，C2-C6炔基，卤素，氰基，氨基，硝基，甲酰基，C1-C6烷氧基，C1-C6烷硫基，C1-C6烷氧羰基，羟基C1-C6烷基，C1-C6烷氧基C1-C6烷基，氰基C1-C6烷基，C1-C6烷氨基C1-C6烷基，以及未取代或被选自C1-C6烷基、氰基、卤代C1-C6烷基、C1-C6烷基氨基、卤素和C1-C6烷氧基中的至少一个基团所取代的苯基、苄基、萘基、呋喃基、噻吩基、噻唑基、吡唑基、吡啶基或嘧啶基；Q represents C1-C6 alkyl, halogenated C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, halogen, cyano, amino, nitro, formyl, C1- C6 alkoxy, C1-C6 alkylthio, C1-C6 alkoxycarbonyl, hydroxy C1-C6 alkyl, C1-C6 alkoxy C1-C6 alkyl, cyano C1-C6 alkyl, C1-C6 alkane Amino C1-C6 alkyl group, and at least one unsubstituted or selected from C1-C6 alkyl group, cyano group, halogenated C1-C6 alkyl group, C1-C6 alkylamino group, halogen, and C1-C6 alkoxy group Phenyl, benzyl, naphthyl, furyl, thienyl, thiazolyl, pyrazolyl, pyridyl or pyrimidinyl substituted by the group;
    Y代表氨基，C1-C6烷基氨基，C1-C6烷基羰基氨基，以及未取代或被选自C1-C6烷基、卤素、氰基、C1-C6烷基氨基、C1-C6烷氧基和卤代C1-C6烷基中的至少一个基团所取代的苯基羰基氨基、苄基氨基或呋喃基亚甲基氨基；Y represents amino, C1-C6 alkylamino, C1-C6 alkylcarbonylamino, and unsubstituted or selected from C1-C6 alkyl, halogen, cyano, C1-C6 alkylamino, C1-C6 alkoxy And a phenylcarbonylamino, benzylamino or furylmethyleneamino group substituted by at least one of the halogenated C1-C6 alkyl groups;
    所述盐为金属盐、铵盐NH 4 +、伯胺盐R”NH 2、仲胺盐(R”) 2NH、叔胺盐(R”) 3N、季胺盐(R”) 4N +、多元胺盐、吗啉盐、N-甲基吗啉盐、哌啶盐、吡啶盐、氨基丙基吗啉盐、Jeff胺D-230盐、2,4,6-三(二甲基氨基甲基)苯酚和氢氧化钠的盐、C1-C16烷基锍盐、C1-C16烷基氧化锍盐、C1-C16烷基鏻盐或C1-C16烷醇鏻盐； The salt is metal salt, ammonium salt NH 4 + , primary amine salt R”NH 2 , secondary amine salt (R”) 2 NH, tertiary amine salt (R”) 3 N, quaternary amine salt (R”) 4 N + , polyamine salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropyl morpholine salt, Jeff amine D-230 salt, 2,4,6-tris(dimethyl (Aminomethyl) phenol and sodium hydroxide salt, C1-C16 alkyl sulfonium salt, C1-C16 alkyl sulfonium oxide salt, C1-C16 alkyl phosphonium salt or C1-C16 alkanol phosphonium salt;
    其中，R”分别独立地代表未取代或被选自卤素、羟基、C1-C6烷氧基、C1-C6烷硫基、羟基C1-C6烷氧基中的一个或多个基团所取代的C1-C16烷基，C2-C12烯基，C2-C12炔基，C3-C12环烷基，未取代或被C1-C6烷基取代的苯基或苄基；Wherein, R" each independently represents unsubstituted or substituted by one or more groups selected from halogen, hydroxyl, C1-C6 alkoxy, C1-C6 alkylthio, and hydroxy C1-C6 alkoxy. C1-C16 alkyl, C2-C12 alkenyl, C2-C12 alkynyl, C3-C12 cycloalkyl, unsubstituted or substituted phenyl or benzyl with C1-C6 alkyl;
    所述酯为
    Figure PCTCN2020081644-appb-100002
    其中，X代表O或S；     The ester is
    Figure PCTCN2020081644-appb-100002
    Among them, X represents O or S;
    M代表C1-C18烷基，卤代C1-C8烷基，未取代或被C1-C6烷基取代的C3-C6环烷基，C2-C6烯基，卤代C2-C6烯基，C2-C6炔基，C1-C6烷氧基，C1-C6烷氧羰基，C1-C6烷基磺酰基，氰基C1-C6烷基，硝基C1-C6烷基，C1-C6烷氧基C1-C6烷基，-(C1-C6烷基)-Z，
    Figure PCTCN2020081644-appb-100003
    以及未取代或被选自C1-C6烷基、卤代C1-C6烷基、氰基、C1-C6烷基氨基、卤素和C1-C6烷氧基中的至少一个基团所取代的苯基、
    Figure PCTCN2020081644-appb-100004
    四氢呋喃基、吡啶基、萘基、呋喃基、噻吩基、吡咯基、吡唑基或咪唑基；     M represents C1-C18 alkyl, halogenated C1-C8 alkyl, C3-C6 cycloalkyl that is unsubstituted or substituted by C1-C6 alkyl, C2-C6 alkenyl, halogenated C2-C6 alkenyl, C2- C6 alkynyl, C1-C6 alkoxy, C1-C6 alkoxycarbonyl, C1-C6 alkylsulfonyl, cyano C1-C6 alkyl, nitro C1-C6 alkyl, C1-C6 alkoxy C1- C6 alkyl, -(C1-C6 alkyl)-Z,
    Figure PCTCN2020081644-appb-100003
    And unsubstituted or substituted with at least one group selected from C1-C6 alkyl, halogenated C1-C6 alkyl, cyano, C1-C6 alkylamino, halogen, and C1-C6 alkoxy ,
    Figure PCTCN2020081644-appb-100004
    Tetrahydrofuryl, pyridyl, naphthyl, furyl, thienyl, pyrrolyl, pyrazolyl or imidazolyl;
    Z代表
    Figure PCTCN2020081644-appb-100005
    以及未取代或被选自C1-C6烷基、C1-C6烷氧基、C1-C6烷基氨基、卤代C1-C6烷基、氰基和卤素中的至少一个基团所取代的
    Figure PCTCN2020081644-appb-100006
    苯基、四氢呋喃基、吡啶基、吡唑基、噻吩基、呋喃基或萘基；     Z stands for
    Figure PCTCN2020081644-appb-100005
    And unsubstituted or substituted by at least one group selected from C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, halogenated C1-C6 alkyl, cyano and halogen
    Figure PCTCN2020081644-appb-100006
    Phenyl, tetrahydrofuranyl, pyridyl, pyrazolyl, thienyl, furanyl or naphthyl;
    R 4、R 5、R 6分别独立地代表氢，C1-C6烷基，C1-C6烷氧基羰基，以及未取代或被选自C1-C6烷基、C1-C6烷氧基、C1-C6烷基氨基、卤代C1-C6烷基、氰基和卤素中的至少一个基团所取代的苯基； R 4 , R 5 , and R 6 each independently represent hydrogen, C1-C6 alkyl, C1-C6 alkoxycarbonyl, and unsubstituted or selected from C1-C6 alkyl, C1-C6 alkoxy, C1- Phenyl substituted by at least one of C6 alkylamino, halogenated C1-C6 alkyl, cyano and halogen;
    R 7代表C1-C6烷基、C2-C6烯基、
    Figure PCTCN2020081644-appb-100007
    R 7 represents C1-C6 alkyl, C2-C6 alkenyl,
    Figure PCTCN2020081644-appb-100007
    活性成分B选自以下化合物或其酸/盐中的一种或多种：The active ingredient B is selected from one or more of the following compounds or their acids/salts:
    (1)ALS抑制剂：五氟磺草胺、双草醚、吡嘧磺隆、烟嘧磺隆、双氟磺草胺、砜嘧磺隆、咪草烟、甲基咪草烟、甲氧咪草烟、甲嘧磺隆、氯酯磺草胺；(1) ALS inhibitors: Penoxsulam, bispyrifen, pyrazosulfuron, nicosulfuron, sulfentrazone, sulfensulfuron, imazethapyr, imazethapyr, methoxy Imazethapyr, metsulfuron-methyl, chlorfentrazone;
    (2)ACCase抑制剂：氰氟草酯、炔草酯、唑啉草酯、烯草酮、烯禾啶、精喹禾灵、精吡氟禾草灵、高效氟吡甲禾灵；(2) ACCase inhibitors: cyhalofop-butyl, clodinafop-propargyl, pinoxaden, clethodim, enoxypyr, quizalofop-p-ethyl, diflufenop-ethyl, and high-efficiency haloxyfop;
    (3)PSII抑制剂：莠去津、异丙隆、绿麦隆、敌草隆、灭草松、溴苯腈、敌稗；(3) PSII inhibitors: Atrazine, Isoproturon, Chlortoluron, Diuron, Fenoxazone, Bromoxynil, Probarn;
    (4)HPPD抑制剂：环吡氟草酮、双唑草酮、苯唑氟草酮、三唑磺草酮、呋喃磺草酮、硝磺草酮、环磺酮、苯唑草酮、异噁唑草酮、双环磺草酮；(4) HPPD inhibitors: cicloflutod, carfentrazone, flufentrazone, trifentrazone, fursotrione, mesotrione, cyclosulfone, oxaflutodone, iso Oxfentrazone, Sulcotrione;
    (5)PDS抑制剂：吡氟酰草胺、氟咯草酮；(5) PDS inhibitors: diflufenican, flurochloridone;
    (6)DOXP抑制剂：异噁草松；(6) DOXP inhibitor: clomazone;
    (7)PPO抑制剂：唑草酮、氟磺胺草醚、乙羧氟草醚、乙氧氟草醚、乳氟禾草灵、三氟羧草醚、丙炔氟草胺、甲磺草胺、苯嘧磺草胺、噁草酮、丙炔噁草酮。(7) PPO inhibitors: carfentrazone, fomesafen, oxyfluorfen, oxyfluorfen, lactofen, acifluorfen, flufentrazone, sulfentrazone , Mefentrazone, oxadiazon, propinyl oxadiazone.
  2. 根据权利要求1所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，The herbicidal composition comprising an R-type pyridyloxy carboxylic acid derivative according to claim 1, wherein:
    R 1、R 2分别独立地代表氟、氯、溴、碘、甲基、乙基、丙基、异丙基、三氟甲基、环丙基； R 1 and R 2 each independently represent fluorine, chlorine, bromine, iodine, methyl, ethyl, propyl, isopropyl, trifluoromethyl, and cyclopropyl;
    R 3代表氢、氟、氯、溴、碘、甲基、三氟甲基； R 3 represents hydrogen, fluorine, chlorine, bromine, iodine, methyl, trifluoromethyl;
    Q代表甲基，乙基，丙基，异丙基，环丙基，乙烯基，乙炔基，氟，氯，溴，氰基，氨基，硝基，甲酰基，甲氧基，甲硫基，甲氧羰基，一氯甲基，一氟甲基，二氟甲基，三氟甲基，2-氯乙基，2,2,2-三氟乙基，羟基甲基，
    Figure PCTCN2020081644-appb-100008
    苄基，萘基，呋喃基，吡啶基，嘧啶基，以及未取代或被氯取代的噻唑基，未取代或被氟取代的噻吩基，未取代或被甲基或氟取代的
    Figure PCTCN2020081644-appb-100009
    未取代或被甲基、三氟甲基、氯和甲氧基中的至少一个基团所取代的苯基；     Q represents methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, Methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2,2,2-trifluoroethyl, hydroxymethyl,
    Figure PCTCN2020081644-appb-100008
    Benzyl, naphthyl, furanyl, pyridyl, pyrimidinyl, and unsubstituted or chloro-substituted thiazolyl, unsubstituted or fluorine-substituted thienyl, unsubstituted or methyl or fluorine-substituted
    Figure PCTCN2020081644-appb-100009
    Unsubstituted or substituted by at least one of methyl, trifluoromethyl, chlorine and methoxy;
    Y代表NH 2、
    Figure PCTCN2020081644-appb-100010
    Y stands for NH 2 ,
    Figure PCTCN2020081644-appb-100010
    所述盐为钠盐、锂盐、钾盐、铯盐、铷盐、钙盐、镁盐、钡盐、锶盐、锑盐、铋盐、镉盐、铈盐、铬盐、钴盐、钪盐、钛盐、锰盐、铜盐、铁盐、银盐、金盐、锌盐、铝盐、铵盐、四甲基铵盐、四乙基铵盐、四丙基铵盐、四丁基铵盐、N-十六烷基三甲基胺盐、N-苄基三甲基铵盐、苄基三乙基铵盐、胆碱盐、一甲胺盐、二甲胺盐、三甲胺盐、一乙胺盐、二乙胺盐、三乙胺盐、正丙胺盐、二丙胺盐、三丙胺盐、一异丙胺盐、二异丙胺盐、三异丙胺盐、正丁胺盐、二丁胺盐、三丁胺盐、异丁胺盐、叔丁胺盐、戊胺盐、己胺盐、庚胺盐、辛胺盐、十二烷基胺盐、十四烷基胺盐、二烯丙基胺盐、环己胺盐、环十二烷基胺盐、苯胺盐、邻甲苯胺盐、间甲苯胺盐、对甲苯胺盐、二苯胺盐、苄胺盐、单乙醇胺盐、N-甲基单乙醇胺盐、N,N-二甲基乙醇胺盐、N-乙基单乙醇胺盐、N,N-二乙基乙醇胺盐、N-丙基单乙醇胺盐、N,N-二正丙基乙醇胺盐、N-丁基单乙醇胺盐、二乙醇胺盐、N-甲基二乙醇胺盐、N-乙基二乙醇胺盐、N-丙基二乙醇胺盐、N-丁基二乙醇胺盐、N,N-二丁基乙醇胺盐、三乙醇胺盐、三丙醇胺盐、三异丙醇胺盐、三(2-羟基丙基)胺盐、二甘醇胺盐、六亚甲基四胺盐、乙二胺盐、二亚乙基三胺盐、二甲基氨基丙胺盐、1,2-丙二胺盐、三乙烯二胺盐、三乙烯四胺盐、联苯胺盐、N,N-双[氨基丙基]甲胺盐、2-甲基硫基丙胺盐、2-丁氧基乙胺盐、AEPD盐、三(羟甲基)氨基甲烷盐、吗啉盐、N-甲基吗啉盐、哌啶盐、吡啶盐、氨基丙基吗啉盐、Jeff胺D-230盐、2,4,6-三(二甲基氨基甲基)苯酚和氢氧化钠的盐、三甲基锍盐、三乙基锍盐；The salt is sodium salt, lithium salt, potassium salt, cesium salt, rubidium salt, calcium salt, magnesium salt, barium salt, strontium salt, antimony salt, bismuth salt, cadmium salt, cerium salt, chromium salt, cobalt salt, scandium Salt, titanium salt, manganese salt, copper salt, iron salt, silver salt, gold salt, zinc salt, aluminum salt, ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutyl Ammonium salt, N-hexadecyltrimethylamine salt, N-benzyltrimethylammonium salt, benzyltriethylammonium salt, choline salt, monomethylamine salt, dimethylamine salt, trimethylamine salt , Monoethylamine salt, diethylamine salt, triethylamine salt, n-propylamine salt, dipropylamine salt, tripropylamine salt, monoisopropylamine salt, diisopropylamine salt, triisopropylamine salt, n-butylamine salt, dibutyl Amine salt, tributylamine salt, isobutylamine salt, tert-butylamine salt, pentylamine salt, hexylamine salt, heptylamine salt, octylamine salt, dodecylamine salt, tetradecylamine salt, diallyl Amine salt, cyclohexylamine salt, cyclododecylamine salt, aniline salt, o-toluidine salt, m-toluidine salt, p-toluidine salt, diphenylamine salt, benzylamine salt, monoethanolamine salt, N-methyl Monoethanolamine salt, N,N-dimethylethanolamine salt, N-ethylmonoethanolamine salt, N,N-diethylethanolamine salt, N-propylmonoethanolamine salt, N,N-di-n-propylethanolamine salt , N-butyl monoethanolamine salt, diethanolamine salt, N-methyldiethanolamine salt, N-ethyldiethanolamine salt, N-propyldiethanolamine salt, N-butyldiethanolamine salt, N,N-diethanolamine Butylethanolamine salt, triethanolamine salt, tripropanolamine salt, triisopropanolamine salt, tris(2-hydroxypropyl)amine salt, diglycolamine salt, hexamethylenetetramine salt, ethylenediamine Salt, diethylenetriamine salt, dimethylaminopropylamine salt, 1,2-propanediamine salt, triethylenediamine salt, triethylenetetramine salt, benzidine salt, N,N-bis(aminopropyl) Base) methylamine salt, 2-methylthiopropylamine salt, 2-butoxyethylamine salt, AEPD salt, tris(hydroxymethyl)aminomethane salt, morpholine salt, N-methylmorpholine salt, piperazine Pyridine salt, pyridine salt, aminopropyl morpholine salt, Jeff amine D-230 salt, 2,4,6-tris (dimethylaminomethyl) phenol and sodium hydroxide salt, trimethylsulfonium salt, three Ethyl sulfonium salt;
    所述Ⅰ-1中X代表O或S；X in said I-1 represents O or S;
    M代表甲基，乙基，正丙基，异丙基，正丁基，仲丁基，异丁基，叔丁基，戊基，己基，庚基，辛基，壬基，癸基，十一烷基，十二烷基，十八烷基，三氟甲基，五氟乙基，3-氯丁基，2-氟乙基，2-氯乙基，2-溴乙基，2,2-二氟乙基，2,2,2-三氟乙基，4,4,4-三氟丁基，2,2,3,3,3-五氟丙基，环丙基，环丁基，环戊基，环己基，烯丙基，2-丙炔基，甲氧基，乙氧羰基，甲 基磺酰基，
    Figure PCTCN2020081644-appb-100011
    Figure PCTCN2020081644-appb-100012
    四氢呋喃基，四氢呋喃基亚甲基，吡啶基，吡啶基亚甲基，萘基，萘基亚甲基，呋喃基，呋喃基亚甲基，噻吩基，噻吩基亚甲基，
    Figure PCTCN2020081644-appb-100013
    以及未取代或甲基取代的
    Figure PCTCN2020081644-appb-100014
    未取代或被甲基、二甲基氨基、氯、甲氧基、三氟甲基或异丙基取代的苯基，未取代或被三氟甲基、溴、氯、氟、甲氧基、氰基或甲基取代的苄基；     M represents methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, ten Monoalkyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2, 2-Difluoroethyl, 2,2,2-trifluoroethyl, 4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl Group, cyclopentyl, cyclohexyl, allyl, 2-propynyl, methoxy, ethoxycarbonyl, methylsulfonyl,
    Figure PCTCN2020081644-appb-100011
    Figure PCTCN2020081644-appb-100012
    Tetrahydrofuryl, tetrahydrofurylmethylene, pyridyl, pyridylmethylene, naphthyl, naphthylmethylene, furyl, furylmethylene, thienyl, thienylmethylene,
    Figure PCTCN2020081644-appb-100013
    And unsubstituted or methyl substituted
    Figure PCTCN2020081644-appb-100014
    Unsubstituted or substituted by methyl, dimethylamino, chlorine, methoxy, trifluoromethyl or isopropyl phenyl, unsubstituted or substituted by trifluoromethyl, bromine, chlorine, fluorine, methoxy, Cyano or methyl substituted benzyl;
    R’代表氢、甲基、乙基、二氟甲基。R'represents hydrogen, methyl, ethyl, difluoromethyl.
  3. 根据权利要求1或2所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，活性成分A选自以下化合物中的一种或多种：The herbicidal composition comprising R-type pyridyloxy carboxylic acid derivatives according to claim 1 or 2, wherein the active ingredient A is selected from one or more of the following compounds:
    Figure PCTCN2020081644-appb-100015
    Figure PCTCN2020081644-appb-100015
    Figure PCTCN2020081644-appb-100016
    Figure PCTCN2020081644-appb-100016
    Figure PCTCN2020081644-appb-100017
    Figure PCTCN2020081644-appb-100017
    Figure PCTCN2020081644-appb-100018
    Figure PCTCN2020081644-appb-100018
    Figure PCTCN2020081644-appb-100019
    Figure PCTCN2020081644-appb-100019
    Figure PCTCN2020081644-appb-100020
    Figure PCTCN2020081644-appb-100020
    Figure PCTCN2020081644-appb-100021
    Figure PCTCN2020081644-appb-100021
    Figure PCTCN2020081644-appb-100022
    Figure PCTCN2020081644-appb-100022
    Figure PCTCN2020081644-appb-100023
    Figure PCTCN2020081644-appb-100023
    Figure PCTCN2020081644-appb-100024
    Figure PCTCN2020081644-appb-100024
    Figure PCTCN2020081644-appb-100025
    Figure PCTCN2020081644-appb-100025
    Figure PCTCN2020081644-appb-100026
    Figure PCTCN2020081644-appb-100026
    Figure PCTCN2020081644-appb-100027
    Figure PCTCN2020081644-appb-100027
    Figure PCTCN2020081644-appb-100028
    Figure PCTCN2020081644-appb-100028
    Figure PCTCN2020081644-appb-100029
    Figure PCTCN2020081644-appb-100029
    Figure PCTCN2020081644-appb-100030
    Figure PCTCN2020081644-appb-100030
  4. 根据权利要求1-3任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，A、B的重量比为1:100～100:1或1:50～50:1；优选为1:30～30:1或1:20～20:1；更优选为1:10～10:1或1:8～8:1；进一步优选为1:5～5:1或1:1～2:1。The herbicidal composition containing R-type pyridyloxy carboxylic acid derivative according to any one of claims 1 to 3, wherein the weight ratio of A to B is 1:100-100:1 or 1: 50 to 50:1; preferably 1:30 to 30:1 or 1:20 to 20:1; more preferably 1:10 to 10:1 or 1:8 to 8:1; further preferably 1:5 to 5:1 or 1:1～2:1.
  5. 根据权利要求1-4任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，所述除草组合物中A和B的质量百分含量占总量的1-95％，优选10-80％。The herbicidal composition containing R-type pyridyloxy carboxylic acid derivatives according to any one of claims 1 to 4, wherein the mass percentage of A and B in the herbicidal composition account for the total amount 1-95%, preferably 10-80%.
  6. 根据权利要求1-4任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，所述除草组合物中还包括常规助剂，优选地，所述常规助剂包括载体或表面活性剂。The herbicidal composition comprising R-type pyridyloxy carboxylic acid derivatives according to any one of claims 1 to 4, characterized in that the herbicidal composition also includes conventional adjuvants, preferably, the Conventional adjuvants include carriers or surfactants.
  7. 根据权利要求1-4任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，所述除草组合物进一步包括至少一种安全剂，优选地，所述安全剂选自双苯噁唑酸、cyprosulfamide、吡唑解草酯、解毒喹、赤霉酸、furilazole、metcamifen中的一种或多种。The herbicidal composition comprising R-type pyridyloxy carboxylic acid derivatives according to any one of claims 1 to 4, characterized in that the herbicidal composition further comprises at least one safener, preferably, The safener is selected from one or more of beoxadifen, cyprosulfamide, pyfentrazone, detox quine, gibberellic acid, furilazole, and metcamifen.
  8. 根据权利要求1-7任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物，其特征在于，所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。The herbicidal composition containing R-type pyridyloxy carboxylic acid derivative according to any one of claims 1-7, wherein the specific formulation of the herbicidal composition is a dispersible oil suspension, water suspension Formulations, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules, water emulsions or microemulsions.
  9. 如权利要求1-7任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物在防治杂草上的应用，优选地，将所述的除草组合物用于选择性防除有用作物中的杂草，更优选地，所述有用作物为转基因作物或者基因组编辑技术处理过的作物。The use of a herbicidal composition containing R-type pyridyloxy carboxylic acid derivatives according to any one of claims 1-7 for controlling weeds. Preferably, the herbicidal composition is used for selective Controlling weeds in useful crops, more preferably, said useful crops are transgenic crops or crops processed by genome editing technology.
  10. 一种防治不想要的植物生长的方法，其包括将权利要求1-7任意一项所述的一种包含R型吡啶氧基羧酸衍生物的除草组合物施用于植物、植物部位、植物种子或植物生长的区域，优选地，将所述的除草组合物用于选择性防除有用作物中的杂草，更优选地，所述有用作物 为转基因作物或者基因组编辑技术处理过的作物。A method for preventing and controlling the growth of unwanted plants, which comprises applying the herbicidal composition comprising an R-type pyridyloxy carboxylic acid derivative according to any one of claims 1-7 to plants, plant parts, and plant seeds Or areas where plants grow, preferably, the herbicidal composition is used to selectively control weeds in useful crops, more preferably, the useful crops are transgenic crops or crops processed by genome editing technology.
PCT/CN2020/081644 2019-08-27 2020-03-27 Herbicidal composition containing r-type pyridyloxy carboxylic acid derivatives and application thereof WO2021036251A1 (en)

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