WO2021053397A1 - Cosmetic or dermatological composition for cleansing and/or removing make-up, comprising succinic acid for preventing, reducing or eliminating skin imperfections, treating skin disorders and preventing, treating and combating hyper-seborrheic conditions of the scalp. - Google Patents

Cosmetic or dermatological composition for cleansing and/or removing make-up, comprising succinic acid for preventing, reducing or eliminating skin imperfections, treating skin disorders and preventing, treating and combating hyper-seborrheic conditions of the scalp. Download PDF

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Publication number
WO2021053397A1
WO2021053397A1 PCT/IB2020/000773 IB2020000773W WO2021053397A1 WO 2021053397 A1 WO2021053397 A1 WO 2021053397A1 IB 2020000773 W IB2020000773 W IB 2020000773W WO 2021053397 A1 WO2021053397 A1 WO 2021053397A1
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Prior art keywords
composition
agents
weight
composition according
chosen
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PCT/IB2020/000773
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French (fr)
Inventor
Géraldine LOUVET-POMMIER
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Roquette Freres
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Application filed by Roquette Freres filed Critical Roquette Freres
Priority to BR112022005201A priority Critical patent/BR112022005201A2/en
Priority to CN202080065519.1A priority patent/CN114449994A/en
Priority to KR1020227011116A priority patent/KR20220068226A/en
Priority to EP20792708.8A priority patent/EP4031100A1/en
Priority to JP2022517971A priority patent/JP2022548757A/en
Publication of WO2021053397A1 publication Critical patent/WO2021053397A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/185Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
    • A61K31/19Carboxylic acids, e.g. valproic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/185Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
    • A61K31/19Carboxylic acids, e.g. valproic acid
    • A61K31/191Carboxylic acids, e.g. valproic acid having two or more hydroxy groups, e.g. gluconic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/185Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
    • A61K31/19Carboxylic acids, e.g. valproic acid
    • A61K31/194Carboxylic acids, e.g. valproic acid having two or more carboxyl groups, e.g. succinic, maleic or phthalic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/068Microemulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362Polycarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/732Starch; Amylose; Amylopectin; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/738Cyclodextrins
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/04Antipruritics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/08Antiseborrheics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • A61P17/10Anti-acne agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/008Preparations for oily hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2300/00Mixtures or combinations of active ingredients, wherein at least one active ingredient is fully defined in groups A61K31/00 - A61K41/00
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/591Mixtures of compounds not provided for by any of the codes A61K2800/592 - A61K2800/596

Definitions

  • Cosmetic or dermatological composition for cleansing and / or make-up removal comprising succinic acid to prevent, reduce or eliminate skin imperfections, treat skin disorders and prevent, treat and fight against hyperseborrheic states of the scalp
  • the invention relates to a composition, useful in dermatology and / or cosmetics, preferably for cleaning, in other words hygiene, and / or removing make-up from keratin materials, preferably the skin, the scalp and the skin. hair, making it possible to prevent, reduce or eliminate skin imperfections and to treat skin disorders such as acne, and make it possible to prevent, treat and combat hyperseborrheic states of the scalp.
  • Seborrhea is a biological condition
  • hyperseborrhea and hyperkeratinization are biological disorders of the skin, all three of which lead to the development of skin imperfections.
  • Seborrhea and hyperseborrhea relate to the secretion of sebum.
  • Normal biological functioning of the skin requires the secretion of sebum by the sebaceous glands located in the dermis.
  • Sebum forms a lipid film on the surface of the epidermis and hair. This film protects the skin against drying out, lubricates the hair, and has a protective role by promoting anaerobic and lipophilic microorganisms: we speak of seborrhea.
  • the secretion of sebum can become excessive and cause the appearance of skin imperfections: we speak of hyper seborrhea.
  • the skin imperfections resulting from seborrhea are oily skin, even shiny and shiny, enlarged pores, a thick skin texture, redness.
  • Hyperkeratinization is a biological disorder which also induces skin imperfections. Usually induced by androgenic hormones, it consists of an increase in the synthesis of horny cells. Skin imperfections resulting from hyperkeratinization are loss of radiance in the complexion, and dull skin.
  • Hyperkeratinization and hyperseborrhea together or separately, cause obstruction of the hair follicles, i.e. the pores of the skin. This obstruction is visible by the appearance of skin disorders called “comedones”, either open, also called “blackheads”, when the sebum remains exposed to the air and darkens due to oxidation, or closed, also called “ white spots ”, when the sebum is no longer exposed to the air (ie when the obstruction is due to hyperkeratinization).
  • Propionobacterium acnes induces an inflammatory reaction causing redness and painful discomfort to the touch. Bacterial overgrowth can lead to superficial (papules and pustules) and deep (nodules) inflammatory lesions.
  • acne is a condition of the pilosebaceous follicle in which four factors intervene which are closely related: hyper seborrhea, hyperkeratinization, proliferation of Propionobacterium acnes and inflammation.
  • the scalp like the rest of the skin tissue, is a continuously renewing epidermis comprising hair follicles and sebaceous glands, which together form the pilosebaceous follicle.
  • sebum secrete sebum, which is poured into the pilosebaceous follicle.
  • the secretion of sebum is a normal phenomenon and useful to the skin as to the hair.
  • Sebum forms a lipid film on the surface of the epidermis and hair. This film protects the skin against drying out, lubricates the hair, and has a bactericidal role by promoting anaerobic and lipophilic microorganisms.
  • the sebum will protect the scalp and ensure the shine of the hair by lubricating them.
  • Oily hair is mainly due to an increase in the secretion of sebum by the sebaceous gland in the scalp. Called "hyper seborrhea", this phenomenon is associated with discomfort, feelings of discomfort, aesthetic disorders, even skin pathology.
  • Hyper seborrhea of the scalp leads to the appearance of oily hair and its aesthetic drawbacks. The hair is heavy, dull, lacks volume and has an overall shiny appearance, especially at the roots. The excess sebum accumulates on the roots which present an "oily" appearance. Heavy and flattened, hair is stranded and often looks dirty, or actually is, because the sebum traps the dust in the air that easily adhere to the hair.
  • Hyper seborrhea can cause the above-mentioned aesthetic disorders and feelings of discomfort, but also skin pathology which can result in seborrheic dermatitis or seborrheic alopecia.
  • Seborrheic dermatitis is an inflammatory skin disease (or dermatosis), characterized by the appearance of red plaques, covered with white or yellowish dandruff on the oily areas of the scalp, preferentially occurring on seborrheic skin. These lesions evolve in spurts.
  • the sebum present on these areas causes an abnormal proliferation of yeasts of the Malassezia type, naturally present on the skin. These microorganisms cause a specific inflammatory reaction, resulting in erythema (redness of the skin) and accelerated renewal of scalp and skin cells, causing unusual scaling.
  • Hyper seborrhea can lead to seborrheic alopecia or androgenetic alopecia, that is, hair loss.
  • the cause is an overactivity of the 5 ⁇ -reductase enzyme, which will lead in particular to an acceleration in the renewal of hair follicles.
  • the growth phase (anagenesis) is shortened while the telogen phase is lengthened.
  • the hair becomes finer and less colored, until a fluffy appearance is obtained.
  • the presence of excess sebum will surround the hair shaft up to the bulb, which will suffocate and devitalize it, quickly causing it to fall.
  • compositions generally comprise abrasive agents or astringent agents. Indeed, in order to remove make-up and cleanse, an action of regulating sebaceous secretion, a “purifying” action of absorption of sebum and an astringent action are sought.
  • Various solutions have also been proposed for reducing the excessive secretion of sebum in the scalp.
  • Compositions comprising abrasive agents or astringent agents have been used. Indeed, to try to solve the problem of seborrhea and hyper seborrhea, an action of regulating sebaceous secretion, a “purifying” action of absorption of sebum and an astringent action are sought.
  • a first technical problem solved by the present application is the provision of a cosmetic or dermatological cleaning and hygiene composition to purify the skin, rid it of its impurities and erase imperfections without attacking it or inducing hyper reaction seborrhea.
  • a second technical problem solved by the present application is the provision of a cosmetic or dermatological composition for cleaning the hair and the scalp which does not induce a rebound effect in the production of sebum by excitation of the sebaceous gland, and thus reducing the production of sebum after cleansing.
  • the present invention therefore relates to a cosmetic or dermatological composition for cleansing, in other words hygiene, and / or make-up removal from keratin materials, preferably the skin, comprising, in a physiologically acceptable medium, at least organic acid chosen from among linear or branched dicarboxylic acids, the carbon chain of which consists of 2 to 10 carbon atoms, preferably 3 to 5 carbon atoms, and most preferably 4 carbon atoms.
  • the invention also relates to a process for cleansing and / or removing make-up from keratin materials, in particular the skin, consisting in applying to said keratin materials, in particular the skin, a cosmetic composition according to the invention.
  • the invention also relates to the non-therapeutic cosmetic use of a cosmetic composition according to the invention for cleaning and / or removing make-up from skin having skin imperfections or skin disorders such as acne.
  • the present invention also relates to a cosmetic composition according to the invention for preventing, reducing or eliminating skin imperfections such as oily skin, shiny skin, shiny skin, dilated pores, a thick skin texture, loss. radiance, dull skin.
  • the present invention also relates to a dermatological composition according to the invention for treating skin disorders such as acne.
  • a subject of the invention is also the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing or eliminating cosmetic hyper seborrheic conditions of the scalp, such as oily hair, heavy hair, dull hair. , shiny, dirty, sticky, difficult to comb.
  • the invention also relates to a dermatological composition according to the invention for its use in the treatment of pathological hyperseborrheic conditions of the scalp such as seborrheic dermatitis or seborrheic alopecia.
  • the subject of the invention is a cosmetic or dermatological composition for cleansing and / or removing make-up from keratin materials, comprising, in a physiologically acceptable medium, at least one organic acid chosen from linear or branched dicarboxylic acids, including the carbon chain consists of 2 to 10 carbon atoms, preferably 3 to 5 carbon atoms, and most preferably 4 carbon atoms.
  • the organic acid is succinic acid.
  • the succinic acid is in the form of a salt, in particular a sodium salt, such as monosodium or disodium.
  • Succinic acid is an organic acid with two carboxyl groups, of semi-structural formula COOH-CH2-CH2-COOH.
  • This acid can now be produced by biotechnological processes known to those skilled in the art. Mention will be made, for example, of “Biosuccinium®” marketed by the company Reverdia, or “Beauté by Roquette® SA 130” marketed by Roquette.
  • the succinic acid is present in the composition according to the invention in a content ranging from 0.1 to 15% by weight, preferably from 1 to 10% by weight, preferably from 1.5% to 8% by weight, preferably from 2 to 5% by weight, relative to the total weight of the composition.
  • the succinic acid is present in a content ranging from 0.1 to 3% by weight, preferably from 0.5 to 2% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition.
  • the succinic acid has a bactericidal function, in particular on Gram-positive bacteria such as those of the species Propionobacterium spp., In particular Propionobacterium acnes.
  • succinic acid can also be a mechanical exfoliating agent for the skin, called “scrubbing” or exfoliation, when it is in crystallized solid form; or a chemical exfoliating agent of the skin, when it is in dissolved form.
  • the composition according to the invention comprises at least one sebum absorber.
  • a sebum absorber is a solid, hydrophobic or amphiphilic, solid or porous particle having the capacity to absorb sebum by hydrophobic affinity and / or by trapping in the porosity of said particle.
  • the sebum retained on, or trapped in, the particle can then be removed by any operation allowing the particle to be removed.
  • the products of sebum oxidation or degradation are also absorbed by the sebum absorber.
  • the sebum absorber helps to purify and mattify the skin.
  • the sebum-absorbing agent gives the skin a pleasant and "velvety" feel.
  • the sebum absorbing agent is chosen from sebum absorbers of plant origin chosen from native or modified cellulose, microcrystalline cellulose, native or modified granular starches, native or modified cyclodextrins, dextrins and maltodextrins, and / or at least one sebum absorber of mineral origin, such as clays and silicas and their salts, and mixtures thereof.
  • corn starch such as the product Beauté by Roquette® ST 005 (INCI: Zea (mays) starch), sold by the company ROQUETTE.
  • the modified granular starches may also be modified starches such as octenylsuccinilated starches.
  • modified starches such as octenylsuccinilated starches.
  • Beauté by Roquette® ST 012 product (INCI: Aluminum starch octenylsuccinate) sold by the company ROQUETTE.
  • the Beauté by Roquette® ST 012 product makes it possible on the one hand to absorb sebum but also to give the composition according to the invention a "velvet touch".
  • the modified starches there may also be mentioned the product Beauté by Roquette® ST 118 (INCI: sodium carboxymethyl starch), sold by the company ROQUETTE.
  • microcrystalline cellulose as sebum absorbing agent and by way of illustration, the product Microcel TM 100 (INCI: Microcrystalline cellulose), sold by the company ROQUETTE.
  • clays which may be chosen from kaolin (INCI kaolin), ghassoul (INCI:ixie Lava Clay), green clay (INCI: illite) , montmorillonite, silica (INCI: Silica), and also mica.
  • the sebum absorber is present in the composition according to the invention in a content ranging from 1 to 80% by weight, preferably 2 to 60% by weight, preferably from 3% to 40%, and preferably, the content of sebum absorber is approximately 3% to 20% by weight, and ideally 4 to 10% by weight, relative to the total weight of the composition.
  • the cosmetic or dermatological composition for caring for keratin materials comprises at least one monocarboxylic acid, or its salt, chosen from linear or branched, the carbon chain of which consists of 2 to 12 carbon atoms, preferably of 3 to 8 carbon atoms, and most preferably 6 carbon atoms.
  • citric acid and its salts gluconic acid, its lactone and its salts, lactic acid and its salts, glycolic acid and its salts, glucuronic acid and its salts, maltobionic acid and its salts, lactobionic acid and its salts, malic acid and its salts, tartaric acid and its salts, mandelic acid and its salts, sorbic acid and its salts, benzoic acid and its salts , fatty acids (or carboxylic acids with an aliphatic chain) having a carbon chain of 4 to 12 atoms and their salts, preferably natural fatty acids such as in particular butyric, caproic, caprylic, capric and lauric acids.
  • the salts of these monocarboxylic acids are preferably sodium salts.
  • the cosmetic or dermatological composition comprises, in a physiologically acceptable medium, succinic acid and at least one monocarboxylic acid, or its salt, chosen from linear or branched monocarboxylic acids, of which the chain carbonaceous consists of 2 to 12 carbon atoms, preferably 3 to 8 carbon atoms, and most preferably 6 carbon atoms.
  • the monocarboxylic acid is gluconic acid.
  • the monocarboxylic acid is a fatty acid having a carbon chain of 4 to 12 atoms, or is a salt of these fatty acids.
  • Gluconic acid is preferably present in a content ranging from 0.1 to 2% by weight, preferably from 0.5 to 1% by weight, relative to the total weight of the composition.
  • the monocarboxylic acid is the cyclic form of gluconic acid, called gluconolactone.
  • composition according to the invention comprises a combination of succinic acid and gluconic acid exhibits increased bactericidal activity against Propionobacterium acnes.
  • the physiologically acceptable medium is preferably cosmetically or dermatologically acceptable.
  • physiologically acceptable medium or “cosmetically acceptable” or “dermatologically acceptable” means any medium which does not exhibit deleterious side effects and in particular which does not produce redness, inflammation, heating or tightness. or tingling that is unacceptable to a user of cosmetic or dermatological products.
  • the medium is thus compatible with the keratin materials of human beings.
  • the keratin materials will be the skin, the mucous membranes, the scalp, the hair, the hair system, the eyelashes, the eyebrows, the nails, and preferably the skin.
  • the cosmetic composition according to the invention can be in all the galenic forms used in this cosmetic field, normally used for topical application such as aqueous, hydroalcoholic or oily solutions, solutions or dispersions of the lotion or serum type, d '' liquid consistency emulsions or semi-liquid of the milk type, obtained by dispersing a fatty phase in an aqueous phase (O / W) or vice versa (W / O), or suspensions or emulsions, of soft, semi-solid or solid consistency, of the type cream, aqueous or anhydrous gel, anhydrous compositions, solid compositions of microemulsions, microcapsules, microparticles, or vesicular dispersions of ionic and / or nonionic type.
  • aqueous, hydroalcoholic or oily solutions, solutions or dispersions of the lotion or serum type d '' liquid consistency emulsions or semi-liquid of the milk type, obtained by dispersing a fatty phase in an aqueous phase
  • compositions are prepared by the usual methods known to those skilled in the art.
  • the composition according to the invention can be in the form of emulsions, ie, compositions comprising an aqueous phase and an oily phase dispersed in one another, for example water emulsions.
  • emulsions ie, compositions comprising an aqueous phase and an oily phase dispersed in one another, for example water emulsions.
  • W / O oil-in-water
  • O / W oil-in-water
  • multiple W / O / E or O / W / H
  • the composition is in the form of a water-in-oil emulsion.
  • Water-in-oil (W / O) emulsions comprise an aqueous phase dispersed in an oily phase. These emulsions have a continuous oily phase.
  • the composition is in the form of an oil-in-water emulsion.
  • These emulsions comprise an oily phase dispersed in an aqueous phase.
  • These emulsions have an aqueous continuous phase.
  • dosage forms in the form of oil-in-water or water-in-oil emulsions or in the form of a microemulsion suitable for cleansing and / or removing make-up from keratin materials, preferably the skin, washing creams will be mentioned.
  • foams, milks, facial cleansers in the form of milks, scrubs preferably the skin, washing creams.
  • the dosage forms suitable for cleaning the scalp and / or the hair, in the form of an oil-in-water or water-in-oil emulsion, or of a microemulsion
  • the dosage forms for rinsed application will be mentioned, say "rinse-off" in English: shampoos, hair conditioners, hair masks, serums, foams, balms, creams, sprays, conditioners, conditioners, hair creams.
  • compositions according to the invention are in the form of an aqueous single-phase solution or of a hydroalcoholic single-phase solution, or in the form of a solid composition.
  • aqueous single-phase solution means a composition comprising an aqueous continuous phase comprising water and optionally, one or more organic solvents miscible with water.
  • hydroalcoholic monophasic solution is understood to mean a composition comprising a continuous hydroalcoholic phase comprising at least one alcohol, and according to one aspect, several alcohols miscible with one another or miscible with water.
  • solid single-phase composition means a composition consisting of one or more solid phases mixed together, heterogeneously or homogeneously, preferably homogeneously.
  • aqueous, hydroalcoholic or solid monophasic compositions suitable for cleansing and / or removing make-up from keratin materials, preferably the skin, shower gels, face cleansers in the form of a lotion, lotions, micellar waters, scrubs, dry soaps, cleansing bars, liquid cleansers, powders such as additive bath powders or foaming bath powders or effervescent bath powders, shower creams , sprays.
  • the aqueous monophasic composition makes it possible to form a cleanser for the face, firstly to clean the skin but also to prevent, reduce or eliminate skin imperfections such as oily skin, shiny skin, shiny skin, large pores, thick skin texture, loss of radiance, dull skin.
  • aqueous, hydroalcoholic or solid monophasic compositions suitable for cleaning keratin materials, preferably the scalp and the hair, liquid shampoos, lotions, gels, skin care products. rinse, dry shampoos.
  • the cosmetic composition according to the invention comprises an aqueous phase comprising water and optionally, one or more organic solvents miscible with water.
  • the water-in-oil emulsion according to the invention comprises from 0.5 to 75% by weight of water, preferably from 10 to 50%, preferably from 20 to 40 %, preferably 30 to 35%, by weight of water relative to the total weight of the composition.
  • the oil-in-water emulsion according to the invention comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition.
  • the microemulsion according to the invention comprises from 40 to 60% by weight of water, relative to the total weight of the composition.
  • the aqueous single-phase composition comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition.
  • the hydroalcoholic single-phase composition comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition.
  • composition may comprise, in the aqueous phase, at least one solvent soluble in water.
  • water-soluble solvent denotes a compound which is liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure).
  • the water-soluble solvents which can be used in the compositions according to the invention can be volatile.
  • the composition according to the invention comprising at least one monoalcohol having from 1 to 5 carbon atoms, preferably ethanol or propanediol (or 1, 2 - mono propylene glycol).
  • the latter is preferably of natural origin or obtained by a fermentation or biotechnological process, such as the product Zemea® sold by the company DUPONT and the product TILAMAR® PDO with N00VISTA sold by DSM.
  • the monoalcohol having 1 to 5 atoms is present in a content ranging from 0.5 to 25% by weight, preferably from 1 to 15% by weight, preferably from 2 to 10% by weight , relative to the total weight of the composition.
  • the emulsion according to the invention can also comprise at least one humectant.
  • the humectant may be chosen from polyols and / or esters of fatty acids and of polyethylene glycol.
  • polyols is understood to mean any molecule having in its structure at least two free hydroxy (—OH) groups. These polyols are preferably liquid at room temperature (25 ° C).
  • the polyol will be chosen from maltitol, mannitol, xylitol, erythritol, sorbitol, isosorbide, glycerol or glycerin, glucose, sucrose, polydextrose, hydrogenated glucose syrups , dextrins, maltodextrins, glucose syrups, and mixtures thereof.
  • the composition comprises from 0.5 to 25% by weight of polyols, preferably from 1 to 15% by weight, and even more preferably from 2 to 10% by weight, and more preferably from 2 to 6 % by weight, of polyols, relative to the total weight of the composition.
  • composition according to the invention comprises at least one oil.
  • oil means a compound which is liquid at room temperature (25 ° C), and which, when it is introduced in an amount of at least 1% by weight in water at 25 ° C, is not at all soluble in water, or soluble in an amount of less than 10% by weight, relative to the weight of oil introduced into the water.
  • the oil will be chosen from volatile oils, non-volatile oils and mixtures thereof.
  • the liquid fatty phase advantageously comprises one or more non-volatile oils which provide an emollient effect on the skin.
  • non-volatile oil means an oil which remains on keratin materials at room temperature and atmospheric pressure for at least several hours and in particular having a vapor pressure of less than 10 3 mm Hg (0.13Pa).
  • fatty esters such as cetearyl isononoate, isotridecyl isononoate, isostearyl isostearate, isopropyl isostearate, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, isononyl isononate, 2-ethyl-hexyl palmitate, 2-hexyldecyl laurate, 2-octyl decyl palmitate, myristate or 2-octyldodecyl lactate, 2-diethyl hexyl succinate, diisostearyl malate, triacetin, tricprin
  • non-volatile oils can also be oils of the hydrocarbon or silicone type such as paraffin oil, squalane oil, petrolatum, dimethylsiloxanes and their mixtures.
  • the non-volatile oil is chosen from stearic acid, jojoba oil (INCI: simmondsia Chinensis Seed Oil), grape seed oil (INCI: vitis vinifera seed oil), macadamia oil (INCI: Macadamia ternifolia seed oil), refined oleic sunflower oil (Helianthus annuus seed oil), mixture of coconut caprate and caprylate such as the product Miglyol Coco 810 (INCI: Coco -Caprylate / Caprate), sweet almond oil (INCI: Prunus Amygdalus Dulcis Oil), sesame oil (INCI: Sesamum indicum seed oil).
  • jojoba oil INCI: simmondsia Chinensis Seed Oil
  • grape seed oil INCI: vitis vinifera seed oil
  • macadamia oil ICI: Macadamia ternifolia seed oil
  • refined oleic sunflower oil Helianthus annuus seed oil
  • the non-volatile oil is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 2 to 20% by weight, preferably from 5 to 15% by weight, relative to the total weight of the composition.
  • the liquid fatty phase can also comprise volatile oils.
  • volatile oil is meant an oil capable of evaporating from the skin in less than one hour at room temperature and atmospheric pressure.
  • the volatile oils can for example be chosen from silicone oils or triglycerides of short fatty acids to reduce the greasy feel.
  • the volatile oil is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 2 to 20% by weight, of preferably from 5 to 15% by weight, relative to the total weight of the composition.
  • the fatty or oily phase of the composition according to the invention can also comprise at least one fatty phase structuring agent such as a wax and / or a pasty compound.
  • wax means a fatty substance with a reversible liquid / solid state change, having a melting point greater than 30 ° C and generally less than 90 ° C, which is liquid under the conditions of preparation of composition and exhibits in the solid state an anisotropic crystalline organization.
  • the waxes used according to the invention may consist of polar or non-polar waxes or of a mixture of the two.
  • non-polar is understood to mean a wax containing only carbon, hydrogen and / or phosphorus atoms and in particular a hydrocarbon.
  • Polar waxes can in particular be chosen from animal waxes, vegetable waxes and synthetic or silicone waxes containing polar groups such as esters.
  • waxes of Carnauba, Candelilla, bee (Cera alba), Chinese insect (Ericerus pela); from Japan, from Sumac, from Montan, triesters of C8-C20 acids and of glycerin such as glycerin tribhenate, acetylated glycol stearate sold in particular by the company VEVY under the trade name CETACENE, and mixtures thereof.
  • These waxes can in particular be used in the form predispersed in an oil, as is the case with the mixture of candelilla wax and jojoba seed oil.
  • the wax is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 5 to 10% by weight, relative to the total weight of the composition.
  • pasty compound is understood to mean lipophilic fatty substances which, like waxes, are capable of undergoing a reversible change of liquid / solid state and have an anisotropic crystalline organization in the solid state, but which are different from waxes in that they contain, at a temperature of 23 ° C, a liquid fraction and a solid fraction.
  • the pasty compound is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 5 to 10% by weight, relative to to the total weight of the composition.
  • the composition according to the invention comprises at least one gelling agent.
  • gelling agent means a compound which, in the presence of a solvent, creates more or less strong intermacromolecular bonds thus inducing a three-dimensional network which freezes said solvent.
  • the gelling agent is chosen from hydrophilic organic gelling agents, and / or lipophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents.
  • the composition when the composition is an aqueous monophasic or hydroalcoholic monophasic composition, the composition comprises at least one gelling agent chosen from organic hydrophilic gelling agents, amphiphilic organic gelling agents, and / or inorganic gelling agents.
  • the gelling agent makes it possible to viscosify the continuous phase, that is to say to adjust the viscosity of the continuous phase to a value ranging from 100 mPa.s to 20,000 mPa.s.
  • the organic gelling agent can be chosen from polymers of synthetic origin or of plant origin, preferably of plant origin, chemically modified or not. It can thus be chosen from gums obtained from plants such as gum arabic, gum ghatti, tragacanth, konjac gum, tara gum, locust bean gum, guar gum or their derivatives; gums extracted from seaweed such as alginates and carrageenans; gums resulting from a microbial fermentation such as xanthans, for example, the product Keltrol CG (INCI: xanthan gum), sold by the company CP KELCO or the product Xanthan Gum FNCS-PC (INCI: xanthan gum) sold by the company JUNGBUNZLAUER INTERNATIONAL AG, mannans, scleroglucans or their derivatives; cellulose and its derivatives such as carboxymethylcellulose or hydroxyethylcellulose; starch and its derivatives such as in particular modified starches, in particular acetylated, carb
  • carbomers mention will be made, for example, of the product Carbopol Ultrez 30 (INCI: carbomer) from the company LUBRIZOL ADVANCED MATERIALS, Inc. or the CARBOPOL ETD 2050 POLYMER (INCI: carbomer).
  • gum arabic and of xanthan gum such as the product Solagum AX (INCI: Acacia Senegal Gum (and) Xanthan Gum), sold by the company SEPPIC, mixtures of starch and cellulose derivatives. or gums such the Beauté by Roquette® DS 112 product (INCI: Starch acetate (and) Hydroxyethylcellulose (and) Xanthan gum), sold by the company ROQUETTE.
  • the inorganic gelling agent can be chosen from magnesium and / or aluminum silicates.
  • An example of such a mineral gelling agent is Veegum® Pure from Vanderbilt Minerais LLC, which is a silicate of aluminum and magnesium.
  • the composition further comprises a binder.
  • the solid compositions according to the invention comprise at least one binder.
  • binding agent is understood to mean compounds which confer increased cohesion on the cosmetic composition. This cohesion can be adjusted depending on the amount and chemical affinity of the binding agent relative to the ingredients of the cosmetic composition.
  • the binder will be chosen from caprylic / capric acid triglycerides such as the product Labrafac CC (INCI: capric / caprylic triglicerides) or Cetyl Dimethicone (INCI).
  • caprylic / capric acid triglycerides such as the product Labrafac CC (INCI: capric / caprylic triglicerides) or Cetyl Dimethicone (INCI).
  • the binder will be present in the composition according to the invention at a content ranging from 0.5% to 20%, preferably from 1 to 15%, preferably from 5 to 12%, by weight relative to the total weight of the composition.
  • the binders will also have emollient properties.
  • the cosmetic composition according to the invention can also comprise one or more oil-in-water (O / W) or water-in-oil (W / O) emulsifiers.
  • the oil-in-water (O / W) emulsifier is an emulsifier with an HLB greater than or equal to 8 and chosen from optionally polyethoxylated sorbitan esters, esters of fatty acids and of glycerol, esters or polyesters of fatty acids and sucrose, esters of fatty acids and of polyethylene glycol, modified polysiloxanes polyethers, ethers of fatty alcohols and of polyethylene glycol, alkylpolyglycosides and hydrogenated lecithin, fatty alcohols, sorbitan esters without that this list is not exhaustive, and their mixtures.
  • Montanov 68 (INCI: Cetearyl alcohol (and) cetearyl glucoside), marketed by the company SEPPIC
  • Montanov L (INCI: C14-C22 Alcohols & C12-20 Alkyl Glucoside)
  • Montanov 202 (INCI: Arachidyl Alcohol (and) Behenyl Alcohol (and) Arachidyl Glucoside)
  • Citrol GMS 40 I NCI: Glyceryl stearate
  • CRODA or the product Imwitor 960K (INCI: Glyceryl stearate)
  • BIESTERFELD the product Imwitor 372P (INCI: Glyceryl stearate citrate)
  • the company BIESTERFELD the product Glucate SS (INCI: Methyl Glucose Sesquistearate), sold by the company LUBRIZOL ADVANCE
  • fatty alcohols mention will be made, for example, of the product sold under the name Promulgen D (INCI: Cetearyl alcohol (and) Ceteareth-20).
  • the O / W emulsifier can be advantageously chosen from emulsifier systems composed of a cyclodextrin and of a water-in-oil emulsifier of natural origin, such as the emulsifier system marketed by Roquette Fromme under the name Beauté. by Roquette® DS 146.
  • the water-in-oil (W / O) emulsifier is an emulsifier of HLB less than 8 and chosen from nonethoxylated fatty esters of polyols, and in particular from nonethoxylated fatty esters of glycerol, of polyglycerols, sorbitol, sorbitan, anydrodrohexitols such as in particular isosorbide, mannitol, xylitol, erythritol, maltitol, sucrose, glucose, polydextrose, hydrogenated glucose syrups, dextrins and starches hydrolyzed.
  • Oily phase viscosity agent [0146] Oily phase viscosity agent
  • composition according to the invention may also comprise at least one viscosifying agent, in other words viscosifying agent, of the fatty phase, that is to say a lipophilic or amphiphilic viscosifying agent, chosen from among fatty alcohols.
  • viscosifying agent in other words viscosifying agent, of the fatty phase, that is to say a lipophilic or amphiphilic viscosifying agent, chosen from among fatty alcohols.
  • lipophilic or amphiphilic viscosing agent means a molecule or macromolecule capable of increasing the viscosity of an oil without substantially changing its physical or chemical properties.
  • Lanette 16 (INCI: cetyl alcohol)
  • Lanette O (INCI: cetearyl Alcohol).
  • the composition according to the invention comprises at least one surfactant chosen from ionic, nonionic, anionic or surfactants. amphoteric or zwitterionic. These surfactants are chosen for their detergent and foaming function.
  • composition according to the invention comprises at least one surfactant chosen from anionic surfactants, amphoteric or zwitterionic surfactants.
  • the anionic surfactants are chosen from anionic carboxylic surfactants, anionic sulphated surfactants, sulphonate surfactants, anionic phosphate surfactants, and mixtures thereof, preferably from anionic sulphonate surfactants, anionic carboxylic surfactants, and mixtures thereof.
  • anionic surfactant means a surfactant comprising only anionic groups as ionic or ionizable groups.
  • an entity is qualified as being “anionic” when it has at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the composition of the invention. (medium, pH for example) and not comprising a cationic charge.
  • sulphated anionic surfactant is meant an anionic surfactant comprising at least one sulphate function (-OSO 3 H or -OSO 3 ), and possibly additionally comprising one or more other functions derived from acids, such as acid functions.
  • the alkylsulphates, the alkylethersulphates, the alkylamidoethersulphates, the alkylarylpolyethersulphates, the monoglyceride-sulphates, as well as the salts of these compounds are sulphated anionic surfactants.
  • the alkyl groups of these compounds cited by way of example contain from 6 to 30 carbon atoms, and the aryl group denote a phenyl or benzyl group.
  • non-sulfated anionic surfactant is understood to mean a surfactant which does not fall within the definition of “sulfated anionic surfactant” as defined above.
  • the anionic carboxylic surfactants comprise at least one carboxylic or carboxylate function (-COOH or -COO), but do not include a sulphonic or sulphonate function (-SO 3 H or -SO 3 ), nor a sulphate function (-OSO 3 H) or -OSO 3 );
  • the anionic sulphonate surfactants comprise at least one sulphonic or sulphonate function (-SO3H or -SO3), and can optionally also comprise one or more carboxylic or carboxylate functions (-COOH or -COO) and / or phosphates, but do not include a sulfate function (-OSO 3 H or -OSO 3 ).
  • - phosphate anionic surfactants comprise at least one phosphoric or phosphate function (-OPO 3 H 2 or -OPO 3 2 ), but do not include a carboxylic or carboxylate function (-COOH or -COO), nor a sulphonic or sulphonate function ( - SO3H or -SO3-), nor of sulfate function (-OSO3H or -OSO3).
  • an anionic surfactant comprising at least one sulfate function (-OSO3H or - OSO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and unless otherwise indicated. , such as a sulfated anionic surfactant;
  • An anionic surfactant comprising at least one sulfate function (-OSO 3 H or -OSO 3 ), and at least one sulfonic or sulfonate function (-SO 3 H or -SO 3 ), is considered, within the meaning of l invention and unless otherwise specified, as a sulfated anionic surfactant;
  • an anionic surfactant comprising at least one sulphonic or sulphonate function (-SO3H or -SO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and except otherwise specified, as an unsulfated anionic sulfonate surfactant;
  • An anionic surfactant comprising at least one sulphate function (-OSO3H or -OSO3), and at least one sulphonic or sulphonate function (-SO3H or -SO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and unless otherwise indicated, as a sulphated anionic surfactant.
  • the anionic carboxylic surfactants can be chosen from the following compounds: acylglycinates, acyllactylates, acylsarcosinates, acylglutamates; alkyl-D-galactoside-uronic acids, alkyl ethercarboxylic acids, alkyl (aryl) ethercarboxylic acids, alkylamidoethercarboxylic acids; as well as the salts of these compounds.
  • the alkyl and / or acyl groups of these compounds contain from 6 to 30 carbon atoms, more preferably from 8 to 28, more preferably still from 10 to 24, still better from 12 to 22, carbon atoms.
  • the aryl group preferably denotes a phenyl or benzyl group.
  • These compounds can be polyoxyalkylenated, in particular polyoxyethylene, and then preferably contain from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. It is also possible to use monoesters of C6-C24 alkyl and of polyglycoside-polycarboxylic acids such as C6-C24 alkyl polyglycosidecitrates, C6-C24 alkyl polyglycoside-tartrates, and their salts. According to one embodiment, the anionic carboxylic surfactants are chosen from
  • acylglutamates in particular C6 C24, or even C12-C20, such as stearoylglutamates, and in particular sodium or disodium stearoylglutamate or cocoylglutamates, in particular sodium or disodium cocoyl glutamate;
  • acylsarcosinates in particular in C6 C24, or even in C12-C20, such as cocoyl sarcosinates and in particular sodium cocoyl sarcosinate, lauroyl sarcosinates and in particular sodium lauroyl sarcosinate, palmitoylsarcosinates, and in particular sodium palmitoylsarcosinate ;
  • acyllactylates in particular C12-C28, or even C14-C24, such as behenoyllactylates, and in particular sodium behenoyllactylate, (iso) stearoyl lactylates, and in particular sodium (iso) stearoyl lactylate;
  • acylglycinates in particular C12-C20 acylglycinates such as cocoyl glycinates and in particular sodium cocoyl glycinate;
  • the anionic sulphonate surfactants can be chosen from the following compounds: alkylsulphonates, alkylamidesulphonates, alkylarylsulphonates, C6-C24 alkyl polyglycoside-sulphosuccinates, alpha-olefinesulphonates, paraffin-sulphonates, alkylsulphinetuccinates, sulphosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, N-acyltaurates, acylisethionates; alkylsulfolaurates; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 12 to 28, even better still from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; it being possible for these compounds to be polyoxyalkylenated, in particular
  • the anionic sulfonate surfactants are chosen from: C6-C24 alkylsulfosuccinates, in particular C12-C20, in particular laurylsulfosuccinates; C6-C24, especially C12-C20, alkylethersulfosuccinates; (C6-C24) acylisethionates, preferably (C12-C18) acylisethionates; the alpha- olefin sulfonates; and their mixtures; and in particular in the form of alkali metal or alkaline earth metal, ammonium or aminoalcohol salts.
  • the anionic surfactants can be chosen from C6-C24 alkyl monoesters and polyglycoside-dicarboxylic acids such as alkyl glucoside-citrates, alkyl polyglycoside-tartrates and alkyl polyglycosidesulfosuccinates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, the alkyl or acyl group of all these compounds preferably comprising from 12 to 20 carbon atoms.
  • polyglycoside-dicarboxylic acids such as alkyl glucoside-citrates, alkyl polyglycoside-tartrates and alkyl polyglycosidesulfosuccinates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, the alkyl or acyl group of all these compounds preferably comprising from 12 to 20 carbon atom
  • anionic surfactants which can be used in the compositions of the present invention is that of acyllactylates in which the acyl group contains from 8 to 20 carbon atoms.
  • alkyl-D-galactosideuronic acids and their salts as well as polyoxyalkylenated (C6-C24 alkyl) ethercarboxylic acids, (C624 alkyl) (C6-C24 aryl) polyoxyalkylenated ether-carboxylic acids.
  • polyoxyalkylenated (C6-24 alkyl) amidoethercarboxylic acids and their salts in particular those comprising from 2 to 50 ethylene oxide units, and mixtures thereof.
  • the anionic phosphate surfactants are chosen from: C6-C24, especially C12-C20, alkyl phosphates; C6-C24 alkyl ether phosphates, in particular C12-C20; and their mixtures.
  • amphoteric or zwitterionic surfactants can be chosen from derivatives of secondary or tertiary or quaternary aliphatic amines, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms and containing at least one anionic group. such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.
  • (C8-C20) alkyl betaines for example cocobetaine; sulfobetaines; (C8-C20) alkyl sulfobetaines; alkyl (C8-C20) amidoalkyl (C3-C8) betaines, for example cocamidopropylbetaine; or alkyl (C8-C20) amidoalkyl (C6-C8) sulfobetaines.
  • the composition according to the invention further comprises at least one film-forming agent.
  • the film-forming agent may be chosen from polymers of natural origin or derived from natural products such as hydroxypropyl methyl-cellulose (HPMC), hydroxypropyl-cellulose (HPC), or synthetic polymers such as l. polyvinyl alcohol (PVA), and / or plasticizers other than polyols, such as polyethylene glycol, triethyl citrate, polysorbate, or even waxes such as Carnauba wax, or hydrogenated castor oil. Mention will also be made of the Beauté by Roquette® ST 720 hydroxypropylated pea starch as a film-forming agent.
  • the cosmetic composition according to the invention can also comprise at least one coloring material chosen from water-soluble or liposoluble dyes, the fillers having the effect of coloring and / or opacifying the composition and / or of coloring keratin materials, preferably skin, such as pigments, nacres, lakes (water-soluble dyes adsorbed on an inert mineral support), and mixtures thereof.
  • These coloring materials can optionally be surface treated with a hydrophobic agent such as silanes, silicones, fatty acid soaps, C9-15 fluoroalcohol phosphates, acrylate / dimethicone copolymers, mixed C9-15 fluoroalcohol phosphates / silicones copolymers, lecithins, wax. of carnauba, polyethylene, chitosan and optionally acylated amino acids such as lauroyl lysine, disodium stearoyl glutamate and aluminum acyl glutamate, phytic acid.
  • pigment is understood to mean white or colored particles, inorganic or organic, intended to color and / or opacify the cosmetic composition.
  • pigments mention will be made of inorganic or organic, natural or synthetic pigments.
  • pigments are in particular iron, titanium or zinc oxides, as well as composite pigments and goniochromatic, pearlescent, interference, photochromic or thermochromic pigments, without this list being limiting.
  • nacres is understood to mean any colored particles which may or may not be iridescent and which exhibit a color effect by optical interference.
  • the makeup and / or care composition according to the invention comprises at least colored particles, preferably pigments such as iron oxide pigments and / or nacres.
  • the cosmetic composition according to the invention can also contain at least one filler.
  • fillers are talc, boron nitride, starch, polyamides, silicone resins, powders of silicone elastomers and powders of acrylic polymers, in particular of poly (methyl methacrylate) or styrene acrylate copolymer powders (Sunsphere Powders from Dow).
  • Sensory agents make it possible to modify the sensory profile of the cosmetic or dermatological composition, to make it more pleasant for the user.
  • the sensory agents can be chosen from modified starches such as carboxymethylated starches, for example Beauté by Roquette® ST 118 from Roquette, silicas or talcs, or mixtures thereof. These sensory agents provide softness to the touch for solid compositions, or a cushion effect for compositions in liquid or gel form.
  • the conditioning agents can be chosen from cationic polymers, such as polyquaternium.
  • composition according to the invention can also comprise at least one cosmetic active.
  • an anti-acne agent As a cosmetic active ingredient or cosmetically active ingredient or cosmetically active substance, there will be mentioned an anti-acne agent, a sebum-regulating agent, an antibacterial agent, an antifungal agent, a keratolytic agent, a kerato-regulating agent, an astringent agent, an anti-inflammatory agent, an anti-irritant, an antioxidant, an anti-radical agent, a wound-healing agent, an anti-aging agent, a moisturizing agent, an emollient agent, a tightening agent, a depigmenting agent , a mattifying agent, an antipollution agent, an agent stimulating the microcirculation, an agent desquamating agent, a tightening agent, vitamins, minerals, an ingredient or substance intended to cleanse or purify the skin, such surfactants which will be chosen from those having no stimulating activity on sebogenesis.
  • the composition according to the invention comprises at least one cosmetic active agent having emollient activity such as an emollient agent.
  • glyceryl stearate (INCI name), MOD (INCI: Octyldodecyl Myristate), the product Lipocire A (INCI: C10-18 Triglycerides), the product Lexfeel NS (INCI: Diheptyl Succinate (and) Capryloyl Glycerin / Sebacic Acid Copolymer), sold by the company INOLEX, the product Labrafac CC (INCI: capric / caprylic triglicerides), sold by the company GATTEFOSSE, a coconut oil ester such as that the product Tegosoft AC (INCI: isoamyl cocoate), sold by the company EVONIK, the product DUB VCI 10 (INCI: Isodecyl Neopentanoate) from the company STEARINERIE DUBOIS, Cetiol OE (INCI: dicaprylyl Ether), the product Mango butter ( INC
  • tocopherol for example, the product Covi-ox® T-70 C (INCI: tocopherol), sold by the company BASF, which can be used as an antioxidant.
  • the moisturizing agent will be chosen from humectants, film-forming agents, occlusive agents and lyotropic agents.
  • film-forming agents there will be mentioned, in addition to the film-forming agents described above, collagen, elastin, pectin, gelatin, chitosan, glycosaminoglycans such as hyaluronic acid.
  • lyotropic agents mention will in particular be made of lanolin and its derivatives, ceramides and essential fatty acids.
  • the moisturizing agent is a humectant chosen from ethoxylated compounds or humectants as described above, preferably sorbitol.
  • a humectant chosen from ethoxylated compounds or humectants as described above, preferably sorbitol.
  • the cosmetic or dermatological composition according to the invention further comprises at least one emollient agent, and / or at least one sebum-regulating agent and / or at least one other antibacterial agent.
  • the cosmetic active ingredient is present in a content ranging from 0.1% to 15% by weight, relative to the total weight of the composition, preferably from 0.5 to 10% by weight, and so even more preferably, from 1 to 5% by weight relative to the total weight of the composition.
  • composition according to the invention can comprise other ingredients as long as they do not interfere with the desired properties of the composition.
  • these other ingredients can for example be exfoliation or exfoliation agents, preservatives such as sodium benzoate (INCI: Sodium benzoate) such as the product Microcare NB, sold by the company Thor, or benzoic acid, or potassium sorbate (INCI: Potassium sorbate), such as the product Microcare KS, also sold by the company Thor, or sorbic acid, pH adjusters such as citric acid, soda or arginine, agents antimicrobials, perfumes, sun filters, chelating agents and mixtures thereof.
  • preservatives such as sodium benzoate (INCI: Sodium benzoate) such as the product Microcare NB, sold by the company Thor, or benzoic acid, or potassium sorbate (INCI: Potassium sorbate), such as the product Microcare KS, also sold by the company Thor, or sorbic acid
  • pH adjusters such as citric acid, soda or argin
  • sunscreens by way of illustration, mention will be made of Solvaeil XT 300 (INCI: Titanium Dioxide (and) Caprylic / Capric Triglycéride (and) Polyhydroxystearic Acid (and) Stearic Acid (and) Alumina), from the company CRODA , EUSOLEX 2292 (INCI: ETHYLHEXYL METHOXYCINNAMATE) or EUSOLEX T-2000 (INCI: Cl 77891 & ALUMINA & SIMETHICONE) from the company Merck KGaA.
  • Solvaeil XT 300 ICI: Titanium Dioxide (and) Caprylic / Capric Triglycéride (and) Polyhydroxystearic Acid (and) Stearic Acid (and) Alumina
  • EUSOLEX 2292 INCI: ETHYLHEXYL METHOXYCINNAMATE
  • EUSOLEX T-2000 INCI: Cl 77891 & ALUMINA & SIMETHICONE
  • the emulsions, aqueous monophasic compositions, hydroalcoholic and the solid compositions according to the invention will be prepared with "bio-sourced” ingredients.
  • bio-sourced is meant an ingredient whose dry mass in carbon atoms of renewable origin is at least 50%, preferably at least 80%, and better still at least 90%, by weight based on the total dry mass of carbon atoms of the ingredient.
  • emulsions, aqueous, hydroalcoholic single-phase compositions and the solid compositions according to the invention will be prepared by any technique known to those skilled in the art.
  • the cosmetic or dermatological composition is an aqueous monophasic composition composed of, preferably consisting of, water, a mixture of gluconic acid and succinic acid, and at least one other ingredient chosen from sebum absorbers; preservatives such as benzoic acid, sorbic acid and their salts or a mixture; gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents; surfactants such as anionic or amphoteric surfactants, sensory agents; humectants; emollients; moisturizers; coloring matters; film-forming agents; occlusive agents; conditioning agents; the perfumes.
  • preservatives such as benzoic acid, sorbic acid and their salts or a mixture
  • gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents
  • surfactants such as anionic or amphoteric sur
  • the cosmetic or dermatological composition is composed of:
  • sebum absorbers preservatives such as benzoic acid, sorbic acid and their salts or a mixture
  • gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents, sensory agents, humectants, emollients, moisturizers, coloring matters, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being
  • the cosmetic or dermatological composition consists of:
  • the cosmetic or dermatological composition is in the form of a microemulsion, and is composed, preferably consisting of:
  • surfactants chosen from anionic surfactants or amphoteric or zwitterionic surfactants
  • ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizing agents, coloring materials, film-forming agents, occlusive agents, conditioning agents , the perfumes.
  • the cosmetic or dermatological composition is in the form of a microemulsion is composed, preferably constituted:
  • composition from 5 to 50% by weight, relative to the total weight of the composition, from one to four surfactants chosen from anionic surfactants or amphoteric or zwitterionic surfactants,
  • compositions from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients , moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
  • ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients , moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
  • the cosmetic or dermatological composition is in a solid monophasic form, and is composed:
  • At least one surfactant chosen from anionic or amphoteric surfactants
  • At least one other ingredient chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes.
  • the cosmetic or dermatological composition is composed, preferably constituted:
  • surfactants chosen from anionic surfactants, or amphoteric or zwitterionic surfactants,
  • compositions from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
  • ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
  • the cosmetic or dermatological composition is in a solid monophasic form, and is composed:
  • At least one surfactant chosen from anionic or amphoteric surfactants
  • composition further comprising lauric acid, or stearic acid, or a mixture thereof.
  • the cosmetic or dermatological composition is composed:
  • surfactants chosen from anionic surfactants, or amphoteric surfactants or zwitterionics,
  • compositions from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes
  • a subject of the invention is also a process for cleansing and / or removing make-up from keratin materials, in particular the skin, the scalp or the hair, consisting in applying to said keratin materials, in particular the skin, a composition cosmetic according to the invention.
  • said process comprises an additional and final step of rinsing, preferably with water.
  • said process is a so-called "rinsed application” process, which comprises the steps:
  • compositions of the present invention are used in a context in which the composition is finally rinsed or washed from the hair. or the skin after or during the application of the product
  • a “leave-in” product refers to a composition which is applied to the hair or the skin and not subjected to a rinsing step.
  • Cosmetic use for preventing, reducing or eliminating skin imperfections is also the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing or eliminating skin imperfections.
  • Skin imperfections are understood as aesthetic drawbacks and are to be distinguished from pathological skin disorders. Skin imperfections include oily skin, shiny skin, shiny skin, large pores, thick skin texture, redness, itching, loss of radiance, dull skin.
  • a subject of the present invention is also the non-therapeutic cosmetic use of a cosmetic or dermatological composition according to the invention, for cleaning and / or removing make-up from skin having skin imperfections or skin disorders such as acne.
  • the present invention also relates to a composition according to the invention for its use in the treatment of skin disorders such as acne.
  • the present invention also relates to the use of a composition according to the invention for the treatment of skin disorders such as acne.
  • the present invention also relates to the use of a composition according to the invention for obtaining a medicament intended for the treatment of skin disorders such as acne.
  • the present invention also relates to a method of therapeutic treatment of skin disorders such as acne, comprising the administration of a composition according to the invention to a patient in need thereof.
  • Skin disorders such as acne should be distinguished from skin imperfections which only cause aesthetic inconvenience.
  • Acne is a chronic inflammatory disease of the pilosebaceous follicle in which four closely related factors occur: hyperseborrhea, hyperkeratinization, proliferation of Propionobacterium acnes and inflammation.
  • composition according to the invention makes it possible to treat skin disorders resulting from hyperseborrhea and / or hyperkeratinization and / or proliferation of bacteria of the genus Propionobacterium spp and / or inflammation
  • the shine is mainly localized on the middle part of the face: forehead, nose, chin, commonly called the T zone; ii) pathological skin disorders which result from the presence and / or proliferation of bacteria of the genus Propionobacterium spp., preferably of Propionobacterium Acnes and / or inflammation, and / or hyperkeratinization and / or hyper seborrhea.
  • Acne-prone skin also suffers from skin shine and enlarged pores, but pimples and blackheads persist and breakouts are frequent.
  • treatment or “method of treatment” are not absolute terms and; when applied to acne, they denote a procedure or a plan of action designed, even with a low probability of success but having to induce an overall beneficial effect such as the delay in the onset of the pathology, or the decrease in the severity of one or more symptoms or stabilization of the pathology.
  • the treatment means the delay in the onset or the reduction in severity or even the disappearance of skin disorders such as comedones, and / or superficial inflammatory lesions papules and pustules) and deep (nodules), and / or the proliferation of Propionobacterium acnes.
  • Normal hair corresponds to hair that is soft to the touch, supple, which disentangles and combs easily, has a shiny appearance and does not break. Also, the scalp is healthy, without dandruff, irritation or redness. In this case, the sebaceous glands are functioning normally, secreting a small amount of sebum in order to protect the scalp and lubricate the hair. However, it happens that they undergo an internal imbalance or caused by external aggressions, then causing disturbances in the production of sebum. Hyper seborrhea is a physiological phenomenon resulting in excessive production of sebum. The excess secreted sebum spreads over the scalp, but it also spreads down the hair shaft, making it greasy and heavy.
  • the amount of sebum present on the scalp can be measured by various devices known to those skilled in the art. Most are based on applying a translucent plate against the scalp to collect the sebum present and then measuring the amount of light transmitted through the plate. [0237] Cosmetic use for preventing, reducing or eliminating cosmetic hyperseborrheic states of the scalp
  • the invention relates to the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing, or eliminating cosmetic hyperseborrheic states of the scalp.
  • Cosmetic hyperseborrheic conditions of the scalp refer to oily hair and their aesthetic drawbacks. We will mention heavy hair, dull, shiny, dirty, sticky, difficult to comb. They are to be distinguished from pathological hyperseborrheic states of the scalp.
  • the invention also relates to a composition according to the invention for its use in the treatment of pathological hyperseborrheic states of the scalp.
  • the present invention also relates to the use of a composition according to the invention for the treatment of pathological hyperseborrheic states of the scalp.
  • the present invention also relates to the use of a composition according to the invention for obtaining a medicament intended for the treatment of pathological hyperseborrheic states of the scalp.
  • the present invention also relates to a method of therapeutic treatment of pathological hyperseborrheic states of the scalp, comprising the administration of a composition according to the invention to a patient in need thereof.
  • treatment or “method of treatment” are not absolute terms and; when applied to seborrheic dermatitis or seborrheic alopecia, they denote a procedure or course of action designed, even with a low probability of success but expected to induce an overall beneficial effect such as delaying the onset of the pathology, or the reduction in the severity of one or more symptoms or the stabilization of the pathology.
  • the treatment means the delay in the onset or the reduction in severity or even the disappearance of red patches, covered with white or yellowish films on the fatty areas of the leather. scalp occurring on seborrheic skin.
  • the treatment is understood to mean the delay or reduction of hair loss, or even the disappearance of hair loss.
  • Example 1 shower gel
  • composition in the form of an oil-in-water emulsion the composition of which is reproduced in Table 1 below, in the form of a shower gel for cleaning is prepared.
  • Phase A1 is prepared by mixing the ingredients of phase A1 with stirring, heating at 80 ° C. for 40 minutes. Still with stirring, phase A2 is added to phase A1 while maintaining 80 ° C.
  • phase B is prepared by mixing the ingredients of phase B with stirring at 80 ° C. Phase B is then added to phase A1 + A2, with stirring, at 80 ° C. for 10 minutes. The mixture is cooled to 25 ° C., then phases C and D are added. Finally, the pH is adjusted to a value greater than or equal to 4.6 using the ingredients of phase E.
  • Example 2 facial cleanser
  • a cosmetic composition for cleansing and removing makeup in the form of an aqueous single-phase solution is prepared. Its composition is described in Table 2 below. [0256] [Table 2]
  • Phase A is prepared by mixing the ingredients at 80 ° C for 40 minutes, then cooled to 25 ° and phase B is added.
  • the pH is adjusted to a value greater than or equal to 4.6 using the gluconolactone and sodium hydroxide.
  • Example 3 Clarifying Cleanser
  • a cleansing and clarifying fluid gel for the skin is prepared.
  • the entire preparation is carried out at room temperature.
  • the hydroxypropylmethylcellulose and sorbitol are mixed in water, with gentle stirring.
  • the carboxymethylated starch is added with gentle stirring until this starch is hydrated.
  • Ingredients B and C are then added successively, and then one waits for their complete dissolution.
  • Ingredient D is then added successively, and then waited for its complete dissolution.
  • ingredient E is added, and then waits for complete dissolution.
  • Example 4 shampoo [0263] In this example, a shampoo is prepared.
  • Example 5 cleansing bars for the body
  • body cleansing bars three solid compositions are prepared for cleansing the body, called "body cleansing bars”.
  • Phase A is heated to 85-90 ° C, then homogenized for a short time. Cool to 75-80 ° C with stirring, then add ingredients B to E successively with stirring. It is transferred to a mold and then allowed to cool to room temperature.
  • Phase A is heated to 85-90 ° C, then homogenized for a short time. Cooled to 75-80 ° C with stirring, then ingredients B to E are added successively with stirring. It is transferred to a mold and then allowed to cool to room temperature. [0272] [Table 7]
  • Phase B is prepared separately in a bowl with gentle stirring. Then phase B is added to phase A, and mixed until a homogeneous mixture is obtained. Ingredients C to H are then added successively, allowing time to have a homogeneous dispersion. The mixture obtained is then placed in a mold, and it is left to stand at room temperature for 24 hours. A bar of "soap" is obtained with visible sodium coco-sulfate needles.
  • Example 6 shower cleanser for the face and the body
  • a thick gel cleanser is prepared using the ingredients of Table 10. [0282] [Table 11]: fluid gel cleaner 2
  • a fluid gel cleanser is prepared using the ingredients of Table 11.
  • Example 7 effervescent powder for the bath
  • effervescent powders for the bath are prepared. [0286] [Table 12]: effervescent powder 1
  • An effervescent powder for the bath is prepared according to Table 13.
  • Example 8 powders for the bath
  • a foaming powder for the bath is prepared according to Table 16.
  • Example 9 exfoliating cleanser for the face and the body
  • a fluid cleansing and exfoliating gel is prepared according to Table 17.
  • a fluid cleansing and exfoliating gel is prepared according to Table 18. [0304] [Table 19]: cleansing and exfoliating gel 3
  • a fluid cleansing and exfoliating gel is prepared according to Table 19. [0306]
  • Example 10 “in the shower” cream or lotion for the body
  • three lotions are prepared for use in the shower, and one cream for use in the shower with rinsing after use.
  • a "shower lotion” according to Table 21 is prepared in the form of a white cream.
  • a "shower lotion” according to Table 22 is prepared in the form of a white cream. [0314] [Table 23]: cream in the shower
  • a "shower cream” according to Table 22 is prepared in the form of a white cream.
  • Example 11 cleansers in solid form
  • cleansers are prepared in solid form: a cleansing bar for the hair and the body, a cleansing bar with activated carbon, and a solid soap.
  • [0318] cleansing bar for the hair and the body
  • phase A In a stirred bowl, the ingredients of phase A are combined. The mixture is heated to 80-85 ° C. with stirring. This temperature is maintained. Phase B is then added. The ingredients of phase C are mixed separately, then this premix is added to the contents of the bowl. Ingredients D to G are then added successively. When the mixture is quite homogeneous, the preparation is poured into a mold and then allowed to cool to room temperature. We get a solid bar. [0322] [Table 26]: solid soap
  • a solid soap is prepared according to Table 26.
  • Example 12 body wash spray
  • hydroalcoholic solutions are prepared which can be used as a spray on the body with rinsing after application.
  • spray 1 [Table 27]: spray 1
  • a two-phase spray is prepared according to Table 27. [0327] [Table 28]: spray 2
  • a liquid single-phase spray is prepared according to Table 28.
  • Example 13 solution for cleaning cloth
  • a solution suitable for impregnating a cleaning wipe is prepared according to Table 29. [0333]
  • a washing solution without sulphated surfactants is prepared according to Table 30.
  • Example 15 hair and body cleanser [0337] [Table 31]
  • a hair and body cleanser is prepared according to Table 31.

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Abstract

The invention relates to a composition for use in the field of dermatology and/or cosmetics, preferably for cleansing and/or removing make-up from keratin materials, preferably for use on the skin, scalp and hair, for preventing, reducing or eliminating skin imperfections and treating skin disorders such as acne, and preventing, treating and combating hyper-seborrheic conditions of the scalp.

Description

Description Description
Titre : Composition cosmétique ou dermatologique pour le nettoyage et/ou le démaquillage comprenant de l’acide succinique pour prévenir, réduire ou éliminer les imperfections cutanées, traiter des troubles cutanés et prévenir, traiter et lutter contre les états hyper séborrhéiques du cuir cheveluTitle: Cosmetic or dermatological composition for cleansing and / or make-up removal comprising succinic acid to prevent, reduce or eliminate skin imperfections, treat skin disorders and prevent, treat and fight against hyperseborrheic states of the scalp
Domaine technique Technical area
[0001] L’invention se rapporte à une composition, utile en dermatologie et/ou en cosmétique, préférentiellement pour le nettoyage, autrement dit l’hygiène, et/ou le démaquillage des matières kératiniques, préférentiellement la peau, le cuir chevelu et les cheveux, permettant de prévenir, réduire ou éliminer les imperfections cutanées et de traiter des troubles cutanés tels que l’acné, et permettant de prévenir, traiter et lutter contre les états hyper séborrhéiques du cuir chevelu. The invention relates to a composition, useful in dermatology and / or cosmetics, preferably for cleaning, in other words hygiene, and / or removing make-up from keratin materials, preferably the skin, the scalp and the skin. hair, making it possible to prevent, reduce or eliminate skin imperfections and to treat skin disorders such as acne, and make it possible to prevent, treat and combat hyperseborrheic states of the scalp.
Technique antérieure Prior art
[0002] Les troubles de la peau [0002] Skin disorders
[0003] La séborrhée est une condition biologique, et l’hyper séborrhée et l’hyperkératinisation sont des troubles biologiques de la peau, qui mènent tous les trois à l’apparition d’imperfections cutanées. [0003] Seborrhea is a biological condition, and hyperseborrhea and hyperkeratinization are biological disorders of the skin, all three of which lead to the development of skin imperfections.
[0004] La séborrhée et l’hyper séborrhée concernent la sécrétion de sébum. Un fonctionnement biologique normal de la peau nécessite la sécrétion de sébum par les glandes sébacées situées dans le derme. Le sébum forme un film lipidique à la surface de l’épiderme et des poils. Ce film protège la peau contre le dessèchement, lubrifie le poil, et a un rôle protecteur en favorisant les microorganismes anaérobies et lipophiles : on parle de séborrhée. La sécrétion de sébum peut devenir excessive et entraîner l’apparition d’imperfections cutanées : on parle d’hyper séborrhée. Les imperfections cutanées résultant de la séborrhée sont une peau grasse, voire luisante et brillante, des pores dilatés, un grain de peau épais, des rougeurs. [0004] Seborrhea and hyperseborrhea relate to the secretion of sebum. Normal biological functioning of the skin requires the secretion of sebum by the sebaceous glands located in the dermis. Sebum forms a lipid film on the surface of the epidermis and hair. This film protects the skin against drying out, lubricates the hair, and has a protective role by promoting anaerobic and lipophilic microorganisms: we speak of seborrhea. The secretion of sebum can become excessive and cause the appearance of skin imperfections: we speak of hyper seborrhea. The skin imperfections resulting from seborrhea are oily skin, even shiny and shiny, enlarged pores, a thick skin texture, redness.
[0005] L’hyperkératinisation est un trouble biologique qui induit aussi des imperfections cutanées. Généralement induite par les hormones androgènes, elle consiste en une augmentation de la synthèse des cellules cornées. Les imperfections cutanées résultant de l’hyperkératinisation sont une perte d’éclat du teint, et une peau terne. [0005] Hyperkeratinization is a biological disorder which also induces skin imperfections. Usually induced by androgenic hormones, it consists of an increase in the synthesis of horny cells. Skin imperfections resulting from hyperkeratinization are loss of radiance in the complexion, and dull skin.
[0006] En plus des imperfections cutanées évoquées précédemment, l’hyper séborrhée et l’hyperkératinisation peuvent provoquer, indépendamment ou ensemble simultanément des pathologies comme l’acné. L’acné est une maladie inflammatoire chronique du follicule pilo-sébacé qui atteint la plupart des adolescents et des adultes. La pathologie est variée dans sa présentation et sa sévérité. L’élément commun réside dans la rétention sébacée qui se traduit cliniquement par des lésions élémentaires spécifiques. [0006] In addition to the skin imperfections mentioned above, hyper seborrhea and hyperkeratinization can cause, independently or together simultaneously, pathologies such as acne. Acne is a chronic inflammatory disease of the pilosebaceous follicle that affects most adolescents and adults. The pathology is varied in its presentation and severity. The common element is the sebaceous retention which clinically results in specific elementary lesions.
[0007] L’hyperkératinisation et l’hyper séborrhée provoquent, ensemble ou séparément, l’obstruction des follicules piligères, c’est-à-dire des pores de la peau. Cette obstruction est visible par l’apparition de troubles cutanés appelés « comédons », soit ouverts, aussi appelés « points noirs », quand le sébum reste exposé à l’air et noircit du fait de l’oxydation, soit fermés, aussi appelés « points blancs », quand le sébum n’est plus exposé à l’air (i.e. quand l’obstruction est due l’hyperkératinisation). [0007] Hyperkeratinization and hyperseborrhea, together or separately, cause obstruction of the hair follicles, i.e. the pores of the skin. This obstruction is visible by the appearance of skin disorders called "comedones", either open, also called "blackheads", when the sebum remains exposed to the air and darkens due to oxidation, or closed, also called " white spots ”, when the sebum is no longer exposed to the air (ie when the obstruction is due to hyperkeratinization).
[0008] Dans ces comédons, la prolifération de bactéries du genre Propionobacterium spp., notamment Propionobacterium acnés, induit une réaction inflammatoire causant une rougeur et une gêne douloureuse au touché. La prolifération bactérienne peut entraîner des lésions inflammatoires superficielles (papules et pustules) et profondes (nodules). In these comedones, the proliferation of bacteria of the genus Propionobacterium spp., In particular Propionobacterium acnes, induces an inflammatory reaction causing redness and painful discomfort to the touch. Bacterial overgrowth can lead to superficial (papules and pustules) and deep (nodules) inflammatory lesions.
[0009] Ainsi, l’acné est une affection du follicule pilo-sébacé dans laquelle intervient quatre facteurs qui sont étroitement liés : une hyper séborrhée, une hyperkératinisation, la prolifération de Propionobacterium acnés et une inflammation. [0009] Thus, acne is a condition of the pilosebaceous follicle in which four factors intervene which are closely related: hyper seborrhea, hyperkeratinization, proliferation of Propionobacterium acnes and inflammation.
[0010] L’hygiène et le démaquillage quotidiens contribuent à lutter contre l’apparition des imperfections et troubles cutanés. Une hygiène méticuleuse peut suffire à atténuer voire à éradiquer le phénomène. [0010] Daily hygiene and make-up removal help to fight against the appearance of imperfections and skin disorders. Meticulous hygiene may be enough to reduce or even eradicate the phenomenon.
[0011] Les imperfections cutanées peuvent résulter d’un mauvais démaquillage : nettoyage non adapté au type de peau. [0011] Skin imperfections can result from poor make-up removal: cleaning not suitable for the skin type.
[0012] Les troubles du cuir chevelu et des cheveux [0012] Disorders of the scalp and hair
[0013] Le cuir chevelu, comme le reste du tissu cutané, est un épiderme à renouvellement continuel comprenant des follicules pileux et des glandes sébacées, qui forment ensemble le follicule pilo-sébacé. The scalp, like the rest of the skin tissue, is a continuously renewing epidermis comprising hair follicles and sebaceous glands, which together form the pilosebaceous follicle.
[0014] Les glandes sébacées sécrètent le sébum, qui est déversé dans le follicule pilo- sébacé. La sécrétion de sébum est un phénomène normal et utile à la peau comme à la chevelure. Le sébum forme un film lipidique à la surface de l’épiderme et des poils. Ce film protège la peau contre le dessèchement, lubrifie le poil, et a un rôle bactéricide en favorisant les microorganismes anaérobies et lipophiles. Ainsi, le sébum va protéger le cuir chevelu et assure la brillance des cheveux en les lubrifiant. [0014] The sebaceous glands secrete sebum, which is poured into the pilosebaceous follicle. The secretion of sebum is a normal phenomenon and useful to the skin as to the hair. Sebum forms a lipid film on the surface of the epidermis and hair. This film protects the skin against drying out, lubricates the hair, and has a bactericidal role by promoting anaerobic and lipophilic microorganisms. Thus, the sebum will protect the scalp and ensure the shine of the hair by lubricating them.
[0015] Les cheveux gras sont principalement dus à une augmentation de la sécrétion de sébum par la glande sébacée au niveau du cuir chevelu. Appelé "hyper séborrhée", ce phénomène est associé à des désagréments, des sensations d’inconforts, des désordres esthétiques, voire une pathologie cutanée. [0016] Une hyper séborrhée du cuir chevelu, entraine une apparition de cheveux gras et ses inconvénients esthétiques. Les cheveux sont lourds, ternes, manquent de volume et présentent un aspect général luisant, surtout au niveau des racines. L’excès de sébum s’accumule sur les racines qui présentent un aspect « huileux ». Lourds et aplatis, les cheveux se plaquent en mèches et semblent souvent sales, ou le sont réellement, car le sébum piège les poussières présentes dans l’air qui adhèrent facilement sur les cheveux. Oily hair is mainly due to an increase in the secretion of sebum by the sebaceous gland in the scalp. Called "hyper seborrhea", this phenomenon is associated with discomfort, feelings of discomfort, aesthetic disorders, even skin pathology. [0016] Hyper seborrhea of the scalp leads to the appearance of oily hair and its aesthetic drawbacks. The hair is heavy, dull, lacks volume and has an overall shiny appearance, especially at the roots. The excess sebum accumulates on the roots which present an "oily" appearance. Heavy and flattened, hair is stranded and often looks dirty, or actually is, because the sebum traps the dust in the air that easily adhere to the hair.
[0017] Une hyper séborrhée peut entraîner les désordres esthétiques précédemment cités et des sensations d’inconfort, mais également une pathologie cutanée qui peut se traduire par la dermatite séborrhéique ou l’alopécie séborrhéique. [0017] Hyper seborrhea can cause the above-mentioned aesthetic disorders and feelings of discomfort, but also skin pathology which can result in seborrheic dermatitis or seborrheic alopecia.
[0018] La dermatite séborrhéique est une malade de la peau (ou dermatose) inflammatoire, caractérisée par l’apparition de plaques rouges, recouvertes de pellicules blanches ou jaunâtres sur les zones grasses du cuir chevelu survenant préférentiellement sur une peau séborrhéique. Ces lésions évoluent par poussées. [0018] Seborrheic dermatitis is an inflammatory skin disease (or dermatosis), characterized by the appearance of red plaques, covered with white or yellowish dandruff on the oily areas of the scalp, preferentially occurring on seborrheic skin. These lesions evolve in spurts.
[0019] Le sébum présent sur ces zones entraîne une prolifération anormale de levures de type Malassezia, naturellement présentes sur la peau. Ces micro-organismes provoquent une réaction inflammatoire spécifique, se traduisant par un érythème (rougeur de la peau) et un renouvellement accéléré des cellules du cuir chevelu et de la peau, provoquant une desquamation inhabituelle. The sebum present on these areas causes an abnormal proliferation of yeasts of the Malassezia type, naturally present on the skin. These microorganisms cause a specific inflammatory reaction, resulting in erythema (redness of the skin) and accelerated renewal of scalp and skin cells, causing unusual scaling.
[0020] Il s’agit d’une maladie bénigne et non contagieuse, mais chronique : elle évolue par poussées récidivantes. À cause du caractère apparent des lésions, la dermatite séborrhéique a un retentissement sur la qualité de vie. [0020] This is a benign disease and not contagious, but chronic: it progresses by relapsing attacks. Because of the apparent nature of the lesions, seborrheic dermatitis has an impact on the quality of life.
[0021] L’hyper séborrhée peut amener à une alopécie séborrhéique ou alopécie androgénétique, c’est-à-dire une chute de cheveux. En cause, une hyperactivité de l’enzyme 5a-réductase qui va entraîner notamment une accélération du renouvellement des follicules pileux. La phase de croissance (anagenèse) est raccourcie tandis que la phase télogène est allongée. Les cheveux deviennent plus fins et moins colorés, jusqu’à l’obtention d’un duvet. De plus, la présence d’un excès de sébum va entourer la tige du cheveu jusqu’au bulbe ce qui va l’asphyxier et le dévitaliser, entraînant rapidement sa chute. [0021] Hyper seborrhea can lead to seborrheic alopecia or androgenetic alopecia, that is, hair loss. The cause is an overactivity of the 5α-reductase enzyme, which will lead in particular to an acceleration in the renewal of hair follicles. The growth phase (anagenesis) is shortened while the telogen phase is lengthened. The hair becomes finer and less colored, until a fluffy appearance is obtained. In addition, the presence of excess sebum will surround the hair shaft up to the bulb, which will suffocate and devitalize it, quickly causing it to fall.
[0022] Dans l’état de la technique, diverses solutions ont été proposées pour nettoyer et démaquiller les peaux atteintes d’imperfections et de troubles cutanés, Ces compositions comprennent généralement des agents abrasifs ou des agents astringents. En effet, pour démaquiller et nettoyer, une action de régulation de la sécrétion sébacée, une action « purifiante » d’absorption du sébum et une action astringente sont recherchées. [0023] Diverses solutions ont également été proposées pour réduire la sécrétion excessive de sébum au niveau du cuir chevelu. Des compositions comprenant des agents abrasifs ou des agents astringents ont été utilisées. En effet, pour essayer de résoudre le problème de séborrhée et d’hyper séborrhée, une action de régulation de la sécrétion sébacée, une action « purifiante » d’absorption du sébum et une action astringente sont recherchées. In the state of the art, various solutions have been proposed for cleaning and removing make-up from skin affected by imperfections and skin disorders. These compositions generally comprise abrasive agents or astringent agents. Indeed, in order to remove make-up and cleanse, an action of regulating sebaceous secretion, a “purifying” action of absorption of sebum and an astringent action are sought. Various solutions have also been proposed for reducing the excessive secretion of sebum in the scalp. Compositions comprising abrasive agents or astringent agents have been used. Indeed, to try to solve the problem of seborrhea and hyper seborrhea, an action of regulating sebaceous secretion, a “purifying” action of absorption of sebum and an astringent action are sought.
[0024] Cependant, ces produits, du fait de l’accumulation, de la fréquence d’utilisation et de leurs compositions sont en réalité souvent bien trop agressifs et enlèvent la protection naturelle qui n’est autre que le sébum. Ces produits induisent un effet rebond par excitation de la glande sébacée et augmentant ainsi la production de sébum. [0024] However, these products, due to the accumulation, the frequency of use and their compositions are in reality often far too aggressive and remove the natural protection which is none other than the sebum. These products induce a rebound effect by stimulating the sebaceous gland and thus increasing the production of sebum.
[0025] Le document WO 2015 /106175, décrit l’acide succinique comme ayant un effet bactéricide sur Propionobacterium spp. L’effet kératolytique de l’acide succinique est aussi connu, si bien qu’on lui attribue une propriété de « peeling » de la peau. [0025] Document WO 2015/106175 describes succinic acid as having a bactericidal effect on Propionobacterium spp. The keratolytic effect of succinic acid is also known, so that it is attributed a property of "peeling" the skin.
Problèmes techniques Technical problems
[0026] Un premier problème technique résolu par la présente demande est la fourniture d’une composition cosmétique ou dermatologique de nettoyage et d’hygiène pour purifier la peau, la débarrasser de ses impuretés et gommer les imperfections sans l’agresser ni induire une hyper séborrhée réactionnelle. A first technical problem solved by the present application is the provision of a cosmetic or dermatological cleaning and hygiene composition to purify the skin, rid it of its impurities and erase imperfections without attacking it or inducing hyper reaction seborrhea.
[0027] Un second problème technique résolu par la présente demande est la fourniture d’une composition cosmétique ou dermatologique de nettoyage des cheveux et du cuir chevelu n’induisant pas d’effet rebond de production de sébum par excitation de la glande sébacée, et réduisant ainsi la production de sébum après nettoyage. [0027] A second technical problem solved by the present application is the provision of a cosmetic or dermatological composition for cleaning the hair and the scalp which does not induce a rebound effect in the production of sebum by excitation of the sebaceous gland, and thus reducing the production of sebum after cleansing.
Exposé de l’invention Disclosure of the invention
[0028] La présente invention concerne donc une composition cosmétique ou dermatologique pour le nettoyage, autrement dit l’hygiène, et/ou démaquillage des matières kératiniques, préférentiellement la peau, comprenant, dans un milieu physiologiquement acceptable, au moins acide organique choisi parmi les acides dicarboxyliques linéaires ou branchés, dont la chaîne carbonée est constituée de 2 à 10 atomes de carbones, préférentiellement de 3 à 5 atomes de carbones, et tout préférentiellement de 4 atomes de carbones. The present invention therefore relates to a cosmetic or dermatological composition for cleansing, in other words hygiene, and / or make-up removal from keratin materials, preferably the skin, comprising, in a physiologically acceptable medium, at least organic acid chosen from among linear or branched dicarboxylic acids, the carbon chain of which consists of 2 to 10 carbon atoms, preferably 3 to 5 carbon atoms, and most preferably 4 carbon atoms.
[0029] L’invention concerne également un procédé de nettoyage et/ou de démaquillage des matières kératiniques, en particulier la peau, consistant à appliquer sur lesdites matières kératiniques, en particulier la peau, une composition cosmétique selon l’invention. [0030] L’invention concerne également l’utilisation cosmétique non thérapeutique d’une composition cosmétique selon l’invention pour nettoyer et/ou démaquiller les peaux ayant des imperfections cutanées ou des troubles cutanés tels que l’acné. The invention also relates to a process for cleansing and / or removing make-up from keratin materials, in particular the skin, consisting in applying to said keratin materials, in particular the skin, a cosmetic composition according to the invention. The invention also relates to the non-therapeutic cosmetic use of a cosmetic composition according to the invention for cleaning and / or removing make-up from skin having skin imperfections or skin disorders such as acne.
[0031] La présente invention concerne également une composition cosmétique selon l’invention pour prévenir, réduire ou éliminer les imperfections cutanées telles que la peau grasse, la peau luisante, la peau brillante, les pores dilatés, un grain de peau épais, la perte d’éclat, la peau terne. The present invention also relates to a cosmetic composition according to the invention for preventing, reducing or eliminating skin imperfections such as oily skin, shiny skin, shiny skin, dilated pores, a thick skin texture, loss. radiance, dull skin.
[0032] La présente invention concerne également une composition dermatologique selon l’invention pour traiter les troubles cutanés tels que l’acné. [0032] The present invention also relates to a dermatological composition according to the invention for treating skin disorders such as acne.
[0033] L’invention a également pour objet l’utilisation cosmétique non thérapeutique d’une composition selon l’invention pour prévenir, réduire ou éliminer les états hyper séborrhéiques cosmétiques du cuir chevelu, tels que des cheveux gras, des cheveux lourds, ternes, luisant, sales, collants, difficiles à coiffer. A subject of the invention is also the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing or eliminating cosmetic hyper seborrheic conditions of the scalp, such as oily hair, heavy hair, dull hair. , shiny, dirty, sticky, difficult to comb.
[0034] L’invention concerne également une composition dermatologique selon l’invention pour son utilisation dans le traitement des états hyper séborrhéiques pathologiques du cuir chevelu tels que la dermatite séborrhéique ou l’alopécie séborrhéique. The invention also relates to a dermatological composition according to the invention for its use in the treatment of pathological hyperseborrheic conditions of the scalp such as seborrheic dermatitis or seborrheic alopecia.
Description détaillée detailed description
[0035] Ainsi, l’invention a pour objet une composition cosmétique ou dermatologique pour le nettoyage et/ou démaquillage des matières kératiniques, comprenant, dans un milieu physiologiquement acceptable, au moins un acide organique choisi parmi les acides dicarboxyliques linéaires ou branchés, dont la chaîne carbonée est constituée de 2 à 10 atomes de carbones, préférentiellement de 3 à 5 atomes de carbones, et tout préférentiellement de 4 atomes de carbones. Thus, the subject of the invention is a cosmetic or dermatological composition for cleansing and / or removing make-up from keratin materials, comprising, in a physiologically acceptable medium, at least one organic acid chosen from linear or branched dicarboxylic acids, including the carbon chain consists of 2 to 10 carbon atoms, preferably 3 to 5 carbon atoms, and most preferably 4 carbon atoms.
[0036] Acide succinique [0036] Succinic acid
[0037] Selon un mode de réalisation, l’acide organique est l’acide succinique. Selon un autre mode de réalisation, l’acide succinique est sous forme d’un sel, notamment d’un sel de sodium, tel que le monosodium ou le disodium. [0037] According to one embodiment, the organic acid is succinic acid. According to another embodiment, the succinic acid is in the form of a salt, in particular a sodium salt, such as monosodium or disodium.
[0038] L'acide succinique (ou acide butanedioïque) est un acide organique avec deux groupes carboxyles, de formule semi-développée COOH-CH2-CH2-COOH. Cet acide peut aujourd’hui être produit par des procédés biotechnologiques connus de l’homme du métier. On citera par exemple le « Biosuccinium® » commercialisé par la société Reverdia, ou le « Beauté by Roquette® SA 130 » commercialisé par Roquette. Succinic acid (or butanedioic acid) is an organic acid with two carboxyl groups, of semi-structural formula COOH-CH2-CH2-COOH. This acid can now be produced by biotechnological processes known to those skilled in the art. Mention will be made, for example, of “Biosuccinium®” marketed by the company Reverdia, or “Beauté by Roquette® SA 130” marketed by Roquette.
[0039] Selon un mode de réalisation, l’acide succinique est présent dans la composition selon l’invention en une teneur allant de de 0.1 à 15% en poids, de préférence de 1 à 10% en poids, de préférence de 1 ,5% à 8% en poids, préférentiellement de 2 à 5% en poids, par rapport au poids total de la composition. According to one embodiment, the succinic acid is present in the composition according to the invention in a content ranging from 0.1 to 15% by weight, preferably from 1 to 10% by weight, preferably from 1.5% to 8% by weight, preferably from 2 to 5% by weight, relative to the total weight of the composition.
[0040] Selon un autre mode de réalisation, l’acide succinique est présent en une teneur allant de 0,1 à 3% en poids, de préférence de 0,5 à 2% en poids, et mieux encore de 1 à 2% en poids, par rapport au poids total de la composition. According to another embodiment, the succinic acid is present in a content ranging from 0.1 to 3% by weight, preferably from 0.5 to 2% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition.
[0041] Avantageusement, l’acide succinique a une fonction bactéricide, notamment sur les bactéries Gram-positives tels que celles de l’espèce Propionobacterium spp., notamment Propionobacterium acnés. Advantageously, the succinic acid has a bactericidal function, in particular on Gram-positive bacteria such as those of the species Propionobacterium spp., In particular Propionobacterium acnes.
[0042] De manière complémentaire, l’acide succinique peut aussi être un agent exfolient mécanique de la peau, dit « scrubbing » ou gommage, quand il est sous forme solide cristallisée ; ou un agent exfolient chimique de la peau, quand il est sous forme dissoute. [0042] In a complementary manner, succinic acid can also be a mechanical exfoliating agent for the skin, called “scrubbing” or exfoliation, when it is in crystallized solid form; or a chemical exfoliating agent of the skin, when it is in dissolved form.
[0043] Absorbeur de sébum [0043] Sebum absorber
[0044] Selon un mode de réalisation, la composition selon l’invention comprend au moins un agent absorbeur de sébum. [0044] According to one embodiment, the composition according to the invention comprises at least one sebum absorber.
[0045] Un agent absorbeur de sébum est une particule solide hydrophobe ou amphiphile, pleine ou poreuse, ayant la capacité d’absorber le sébum par affinité hydrophobe et/ou par piégeage dans la porosité de ladite particule. Le sébum retenu sur, ou piégé dans, la particule, peut alors être éliminé par toute opération permettant le retrait de la particule. De même, les produits d’oxydation ou de dégradation du sébum sont aussi absorbés par l’absorbeur de sébum. L’absorbeur de sébum permet de purifier et de matifier la peau. [0045] A sebum absorber is a solid, hydrophobic or amphiphilic, solid or porous particle having the capacity to absorb sebum by hydrophobic affinity and / or by trapping in the porosity of said particle. The sebum retained on, or trapped in, the particle can then be removed by any operation allowing the particle to be removed. Likewise, the products of sebum oxidation or degradation are also absorbed by the sebum absorber. The sebum absorber helps to purify and mattify the skin.
[0046] Avantageusement également, l’agent absorbeur de sébum donne un toucher agréable et « de velours » à la peau. [0046] Also advantageously, the sebum-absorbing agent gives the skin a pleasant and "velvety" feel.
[0047] Typiquement, l’agent absorbeur de sébum est choisi parmi les absorbeurs de sébum d’origine végétale choisi parmi la cellulose native ou modifiée, la cellulose microcristalline, les amidons granulaires natifs ou modifiés, les cyclodextrines natives ou modifiés, les dextrines et les maltodextrines, et/ou au moins un absorbeur de sébum d’origine minérale tels que les argiles et les silices et leurs sels, et leurs mélanges. Typically, the sebum absorbing agent is chosen from sebum absorbers of plant origin chosen from native or modified cellulose, microcrystalline cellulose, native or modified granular starches, native or modified cyclodextrins, dextrins and maltodextrins, and / or at least one sebum absorber of mineral origin, such as clays and silicas and their salts, and mixtures thereof.
[0048] Parmi les amidons, on citera l’amidon de maïs, tel que le produit Beauté by Roquette® ST 005 (INCI : Zea (mays) starch), vendu par la société ROQUETTE. Among the starches, mention will be made of corn starch, such as the product Beauté by Roquette® ST 005 (INCI: Zea (mays) starch), sold by the company ROQUETTE.
[0049] Typiquement, les amidons granulaires modifiés pourront être aussi des amidons modifiés comme les amidons octénylsuccinilés. On citera par exemple, le produit Beauté by Roquette® ST 012 (INCI : Aluminium starch octénylsuccinate) vendu par la société ROQUETTE. Avantageusement, le produit Beauté by Roquette® ST 012 permet d’une part d’absorber le sébum mais également de conférer à la composition selon l’invention un « toucher velours ». Parmi les amidons modifiés, on peut citer aussi le produit Beauté by Roquette® ST 118 (INCI : sodium carboxymethyl starch), vendu par la société ROQUETTE Typically, the modified granular starches may also be modified starches such as octenylsuccinilated starches. Mention will be made, for example, of the Beauté by Roquette® ST 012 product (INCI: Aluminum starch octenylsuccinate) sold by the company ROQUETTE. Advantageously, the Beauté by Roquette® ST 012 product makes it possible on the one hand to absorb sebum but also to give the composition according to the invention a "velvet touch". Among the modified starches, there may also be mentioned the product Beauté by Roquette® ST 118 (INCI: sodium carboxymethyl starch), sold by the company ROQUETTE.
[0050] On citera, pour la cellulose microcristalline en tant qu’agent absorbeur de sébum et à titre illustratif, le produit Microcel™ 100 (INCI : Microcristalline cellulose), vendu par la société ROQUETTE . Mention will be made, for microcrystalline cellulose as sebum absorbing agent and by way of illustration, the product Microcel ™ 100 (INCI: Microcrystalline cellulose), sold by the company ROQUETTE.
[0051] On pourra également citer les mélanges de cellulose gum et de cellulose microcristalline (INCI : Microcrystalline Cellulose & Cellulose Gum) comme les produits Tabulose® SC 591 et Tabulose® SC 611 vendus tous deux également par la société ROQUETTE. Mention may also be made of mixtures of cellulose gum and microcrystalline cellulose (INCI: Microcrystalline Cellulose & Cellulose Gum) such as the products Tabulose® SC 591 and Tabulose® SC 611 both also sold by the company ROQUETTE.
[0052] Typiquement, parmi les absorbeurs de sébum d’origine minérale, on citera les argiles qui pourront être choisies parmi le kaolin (INCI kaolin), le ghassoul (INCI : Moroccan Lava Clay), l’argile verte (INCI : illite), la montmorillonite, la silice (INCI : Silica), et également le mica. Typically, among the sebum absorbers of mineral origin, mention will be made of clays which may be chosen from kaolin (INCI kaolin), ghassoul (INCI: Moroccan Lava Clay), green clay (INCI: illite) , montmorillonite, silica (INCI: Silica), and also mica.
[0053] Parmi les absorbeurs de sébum d’origine végétale, on citera par exemple le charbon actif. Among the sebum absorbers of plant origin, mention will be made, for example, of activated charcoal.
[0054] Pour les cyclodextrines, on citera le produit Beauté by Roquette® CD 102 (INCI : Cyclodextrin) vendu par la société ROQUETTE ou le produit Kleptose® 10 (INCI : Beta- cyclodextrin) également vendu par la société ROQUETTE. For cyclodextrins, mention will be made of the Beauté by Roquette® CD 102 product (INCI: Cyclodextrin) sold by the company ROQUETTE or the product Kleptose® 10 (INCI: Beta-cyclodextrin) also sold by the company ROQUETTE.
[0055] Selon un mode de réalisation, l’absorbeur de sébum est présent dans la composition selon l’invention en une teneur allant de 1 à 80% en poids, de préférence 2 à 60% en poids, de préférence de 3% à 40%, et de façon préférée, la teneur en absorbeur de sébum est d’environ 3% à 20% en poids, et idéalement de 4 à 10% en poids, par rapport au poids total de la composition. According to one embodiment, the sebum absorber is present in the composition according to the invention in a content ranging from 1 to 80% by weight, preferably 2 to 60% by weight, preferably from 3% to 40%, and preferably, the content of sebum absorber is approximately 3% to 20% by weight, and ideally 4 to 10% by weight, relative to the total weight of the composition.
[0056] Acide monocarboxylique Monocarboxylic acid
[0057] Selon une variante, la composition cosmétique ou dermatologique de soin des matières kératiniques comprend au moins un acide monocarboxylique, ou son sel, choisi parmi linéaires ou branchés, dont la chaîne carbonée est constituée de 2 à 12 atomes de carbones, préférentiellement de 3 à 8 atomes de carbones, et tout préférentiellement de 6 atomes de carbones. On citera l’acide citrique et ses sels, l’acide gluconique, sa lactone et ses sels, l’acide lactique et ses sels, l’acide glycolique et ses sels, l’acide glucuronique et ses sels, l’acide maltobionique et ses sels, l’acide lactobionique et ses sels, l’acide malique et ses sels, l’acide tartarique et ses sels, l’acide mandélique et ses sels, l’acide sorbique et ses sels, l’acide benzoique et ses sels, les acides gras (ou acides carboxyliques à chaîne aliphatique) possédant une chaîne carbonée de 4 à 12 atomes et leurs sels, de préférence les acides gras naturels comme en particulier les acides butyrique, caproïque, caprylique, caprique et laurique. Les sels de ces acides monocarboxyliques sont de préférence des sels de sodium. According to one variant, the cosmetic or dermatological composition for caring for keratin materials comprises at least one monocarboxylic acid, or its salt, chosen from linear or branched, the carbon chain of which consists of 2 to 12 carbon atoms, preferably of 3 to 8 carbon atoms, and most preferably 6 carbon atoms. Mention will be made of citric acid and its salts, gluconic acid, its lactone and its salts, lactic acid and its salts, glycolic acid and its salts, glucuronic acid and its salts, maltobionic acid and its salts, lactobionic acid and its salts, malic acid and its salts, tartaric acid and its salts, mandelic acid and its salts, sorbic acid and its salts, benzoic acid and its salts , fatty acids (or carboxylic acids with an aliphatic chain) having a carbon chain of 4 to 12 atoms and their salts, preferably natural fatty acids such as in particular butyric, caproic, caprylic, capric and lauric acids. The salts of these monocarboxylic acids are preferably sodium salts.
[0058] Selon un mode de réalisation, la composition cosmétique ou dermatologique comprend, dans un milieu physiologiquement acceptable, de l’acide succinique et au moins un acide monocarboxylique, ou son sel, choisi parmi les acides monocarboxyliques linéaires ou branchés, dont la chaîne carbonée est constituée de 2 à 12 atomes de carbones, préférentiellement de 3 à 8 atomes de carbones, et tout préférentiellement de 6 atomes de carbones. According to one embodiment, the cosmetic or dermatological composition comprises, in a physiologically acceptable medium, succinic acid and at least one monocarboxylic acid, or its salt, chosen from linear or branched monocarboxylic acids, of which the chain carbonaceous consists of 2 to 12 carbon atoms, preferably 3 to 8 carbon atoms, and most preferably 6 carbon atoms.
[0059] Préférentiellement, l’acide monocarboxylique est l’acide gluconique. Selon une alternative, l’acide monocarboxylique est un acide gras possédant une chaîne carbonée de 4 à 12 atomes, ou est un sel de ces acides gras. Preferably, the monocarboxylic acid is gluconic acid. Alternatively, the monocarboxylic acid is a fatty acid having a carbon chain of 4 to 12 atoms, or is a salt of these fatty acids.
[0060] L’acide gluconique est préférentiellement présent en une teneur allant de 0,1 à 2% en poids, de préférence de 0,5 à 1% en poids, par rapport au poids total de la composition. Gluconic acid is preferably present in a content ranging from 0.1 to 2% by weight, preferably from 0.5 to 1% by weight, relative to the total weight of the composition.
[0061] Selon une autre variante, l’acide monocarboxylique est la forme cyclique de l’acide gluconique, appelée gluconolactone. [0061] According to another variant, the monocarboxylic acid is the cyclic form of gluconic acid, called gluconolactone.
[0062] Avantageusement, la composition selon l’invention comprend une combinaison d’acide succinique et d’acide gluconique présente une activité bactéricide accrue vis-à-vis de Propionobacterium acnés. Advantageously, the composition according to the invention comprises a combination of succinic acid and gluconic acid exhibits increased bactericidal activity against Propionobacterium acnes.
[0063] Galénique Galenic
[0064] Le milieu physiologiquement acceptable est de préférence cosmétiquement ou dermatologiquement acceptable. On entend par « milieu physiologiquement acceptable » ou « cosmétiquement acceptable » ou « dermatologiquement acceptable », tout milieu qui ne présente pas d’effets secondaires délétères et en particulier qui ne produit pas de rougeurs, d’inflammation, d’échauffement, de tiraillements ou de picotements inacceptables pour un utilisateur de produits cosmétiques ou dermatologiques. Le milieu est ainsi compatible avec les matières kératiniques d’êtres humains. The physiologically acceptable medium is preferably cosmetically or dermatologically acceptable. The term “physiologically acceptable medium” or “cosmetically acceptable” or “dermatologically acceptable” means any medium which does not exhibit deleterious side effects and in particular which does not produce redness, inflammation, heating or tightness. or tingling that is unacceptable to a user of cosmetic or dermatological products. The medium is thus compatible with the keratin materials of human beings.
[0065] Typiquement, les matières kératiniques seront la peau, les muqueuses, le cuir chevelu, les cheveux, le système pileux, les cils, les sourcils, les ongles, et préférentiellement, la peau. Typically, the keratin materials will be the skin, the mucous membranes, the scalp, the hair, the hair system, the eyelashes, the eyebrows, the nails, and preferably the skin.
[0066] La composition cosmétique selon l’invention peut se présenter sous toutes les formes galéniques utilisées dans ce domaine cosmétique, normalement utilisées pour une application topique telles que solutions aqueuses, hydroalcooliques ou huileuses, de solutions ou dispersions du type lotion ou sérum, d'émulsions de consistance liquide ou semi-liquide du type lait, obtenues par dispersion d'une phase grasse dans une phase aqueuse (H/E) ou inversement (E/H), ou de suspensions ou émulsions, de consistance molle, semi-solide ou solide, du type crème, de gel aqueux ou anhydre, des compositions anhydres, de compositions solides de microémulsions, de microcapsules, de microparticules, ou de dispersions vésiculaires de type ionique et/ou non ionique. The cosmetic composition according to the invention can be in all the galenic forms used in this cosmetic field, normally used for topical application such as aqueous, hydroalcoholic or oily solutions, solutions or dispersions of the lotion or serum type, d '' liquid consistency emulsions or semi-liquid of the milk type, obtained by dispersing a fatty phase in an aqueous phase (O / W) or vice versa (W / O), or suspensions or emulsions, of soft, semi-solid or solid consistency, of the type cream, aqueous or anhydrous gel, anhydrous compositions, solid compositions of microemulsions, microcapsules, microparticles, or vesicular dispersions of ionic and / or nonionic type.
[0067] Ces compositions sont préparées par les méthodes usuelles connues de l’homme du métier. These compositions are prepared by the usual methods known to those skilled in the art.
[0068] Selon un mode de réalisation, la composition selon l’invention peut se présenter sous forme d’émulsions, i.e., de compositions comportant une phase aqueuse et une phase huileuse dispersées l’une dans l’autre, par exemple des émulsions eau-dans-huile (E/H) ou huile-dans-eau (H/E) ou multiple (E/H/E ou H/E/H) According to one embodiment, the composition according to the invention can be in the form of emulsions, ie, compositions comprising an aqueous phase and an oily phase dispersed in one another, for example water emulsions. -in-oil (W / O) or oil-in-water (O / W) or multiple (W / O / E or O / W / H)
[0069] Selon un mode de réalisation, la composition se présente sous forme d’émulsion eau-dans-huile. [0069] According to one embodiment, the composition is in the form of a water-in-oil emulsion.
[0070] Les émulsions eau-dans-huile (E/H) comportent une phase aqueuse dispersée dans une phase huileuse. Ces émulsions comportent une phase continue huileuse. Water-in-oil (W / O) emulsions comprise an aqueous phase dispersed in an oily phase. These emulsions have a continuous oily phase.
[0071] Selon un mode de réalisation, la composition se présente sous forme d’émulsion huile-dans-eau. Ces émulsions comportent une phase huileuse dispersée dans une phase aqueuse. Ces émulsions comportent une phase continue aqueuse. According to one embodiment, the composition is in the form of an oil-in-water emulsion. These emulsions comprise an oily phase dispersed in an aqueous phase. These emulsions have an aqueous continuous phase.
[0072] On citera, parmi les formes galéniques sous forme d’émulsions huile-dans-eau ou eau-dans-huile ou sous forme de microémulsion, convenant au nettoyage et/ou démaquillage des matières kératiniques, préférentiellement la peau, les crèmes lavantes, les mousses, les laits, les nettoyants visage sous forme de laits, les gommages. Among the dosage forms in the form of oil-in-water or water-in-oil emulsions or in the form of a microemulsion, suitable for cleansing and / or removing make-up from keratin materials, preferably the skin, washing creams will be mentioned. , foams, milks, facial cleansers in the form of milks, scrubs.
[0073] On citera, parmi les formes galéniques, convenant au nettoyage du cuir chevelu et/ou des cheveux, sous forme d’émulsion huile-dans-eau ou eau-dans-huile, ou de microémulsion les formes galéniques pour application rincée, dites « rinse-off » en anglais : les shampoings, les conditionneurs de cheveux, les masques capillaires, les sérums, les mousses, les baumes, les crèmes, les sprays, les après-shampoings, les démêlants, les crèmes capillaires. Among the dosage forms, suitable for cleaning the scalp and / or the hair, in the form of an oil-in-water or water-in-oil emulsion, or of a microemulsion, the dosage forms for rinsed application will be mentioned, say "rinse-off" in English: shampoos, hair conditioners, hair masks, serums, foams, balms, creams, sprays, conditioners, conditioners, hair creams.
[0074] Selon un mode de réalisation, les compositions selon l’invention se présentent sous forme de solution monophasique aqueuse ou de solution monophasique hydroalcoolique, ou sous forme d’une composition solide. [0074] According to one embodiment, the compositions according to the invention are in the form of an aqueous single-phase solution or of a hydroalcoholic single-phase solution, or in the form of a solid composition.
[0075] On entend par solution monophasique aqueuse, une composition comprenant une phase continue aqueuse comprenant de l’eau et optionnellement, un ou plusieurs solvants organiques miscible à l’eau. [0076] On entend par solution monophasique hydroalcoolique, une composition comprenant une phase hydroalcoolique continue comprenant au moins un alcool, et selon un aspect, plusieurs alcools miscibles entre eux ou miscibles à l’eau. The term “aqueous single-phase solution” means a composition comprising an aqueous continuous phase comprising water and optionally, one or more organic solvents miscible with water. The term “hydroalcoholic monophasic solution” is understood to mean a composition comprising a continuous hydroalcoholic phase comprising at least one alcohol, and according to one aspect, several alcohols miscible with one another or miscible with water.
[0077] On entend par composition monophasique solide, une composition constituée d’une ou plusieurs phases solides mélangées entre elles, de façon hétérogène ou homogène, préférentiellement de façon homogène. The term "solid single-phase composition" means a composition consisting of one or more solid phases mixed together, heterogeneously or homogeneously, preferably homogeneously.
[0078] On citera, parmi les formes galéniques, sous forme de compositions monophasique aqueuse, hydroalcoolique ou solide, convenant au nettoyage et/ou démaquillage des matières kératiniques, préférentiellement la peau, les gels douche, les nettoyants visage sous forme de lotion, les lotions, les eaux micellaires, les gommages, les savons secs, les barres nettoyantes, les nettoyants liquides, les poudres telles que des poudres additifs pour le bain ou des poudres moussantes pour le bain ou des poudres effervescentes pour le bain, les crèmes de douche, des sprays. Mention will be made, among the dosage forms, in the form of aqueous, hydroalcoholic or solid monophasic compositions, suitable for cleansing and / or removing make-up from keratin materials, preferably the skin, shower gels, face cleansers in the form of a lotion, lotions, micellar waters, scrubs, dry soaps, cleansing bars, liquid cleansers, powders such as additive bath powders or foaming bath powders or effervescent bath powders, shower creams , sprays.
[0079] Selon un mode de réalisation, la composition monophasique aqueuse permet de former un nettoyant pour le visage, pour d’une part nettoyer la peau mais également prévenir, réduire ou éliminer les imperfections cutanées telles que la peau grasse, la peau luisante, la peau brillante, les pores dilatés, un grain de peau épais, la perte d’éclat, la peau terne. According to one embodiment, the aqueous monophasic composition makes it possible to form a cleanser for the face, firstly to clean the skin but also to prevent, reduce or eliminate skin imperfections such as oily skin, shiny skin, shiny skin, large pores, thick skin texture, loss of radiance, dull skin.
[0080] On citera, parmi les formes galéniques, sous forme de compositions monophasique aqueuse, hydroalcoolique ou solide, convenant au nettoyage des matières kératiniques, préférentiellement le cuir chevelu et les cheveux, les shampoings liquides, les lotions, les gels, les produits de rinçage, les shampoings secs. Mention will be made, among the galenic forms, in the form of aqueous, hydroalcoholic or solid monophasic compositions, suitable for cleaning keratin materials, preferably the scalp and the hair, liquid shampoos, lotions, gels, skin care products. rinse, dry shampoos.
[0081] Phase aqueuse [0081] Aqueous phase
[0082] La composition cosmétique selon l’invention comprend une phase aqueuse comprenant de l’eau et optionnellement, un ou plusieurs solvants organiques miscible à l’eau. The cosmetic composition according to the invention comprises an aqueous phase comprising water and optionally, one or more organic solvents miscible with water.
[0083] Selon un mode de réalisation, l’émulsion eau-dans-huile selon l’invention comprend de 0,5 à 75% en poids d’eau, de préférence, de 10 à 50%, de préférence de 20 à 40%, de préférence de 30 à 35%, en poids d’eau par rapport au poids total de la composition. According to one embodiment, the water-in-oil emulsion according to the invention comprises from 0.5 to 75% by weight of water, preferably from 10 to 50%, preferably from 20 to 40 %, preferably 30 to 35%, by weight of water relative to the total weight of the composition.
[0084] Selon un mode de réalisation, l’émulsion huile-dans-eau selon l’invention comprend de 50 à 99% en poids d’eau, de préférence, de 60 à 95%, de préférence de 70 à 90%, de préférence de 80 à 85%, en poids d’eau par rapport au poids total de la composition. [0085] Selon un mode de réalisation, la microémulsion selon l’invention comprend de 40 à 60% en poids d’eau, par rapport au poids total de la composition. According to one embodiment, the oil-in-water emulsion according to the invention comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition. According to one embodiment, the microemulsion according to the invention comprises from 40 to 60% by weight of water, relative to the total weight of the composition.
[0086] Selon un mode de réalisation, la composition monophasique aqueuse comprend de 50 à 99% en poids d’eau, de préférence, de 60 à 95%, de préférence de 70 à 90%, de préférence de 80 à 85%, en poids d’eau par rapport au poids total de la composition. According to one embodiment, the aqueous single-phase composition comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition.
[0087] Selon un mode de réalisation, la composition monophasique hydroalcoolique comprend de 50 à 99% en poids d’eau, de préférence, de 60 à 95%, de préférence de 70 à 90%, de préférence de 80 à 85%, en poids d’eau par rapport au poids total de la composition. According to one embodiment, the hydroalcoholic single-phase composition comprises from 50 to 99% by weight of water, preferably from 60 to 95%, preferably from 70 to 90%, preferably from 80 to 85%, by weight of water relative to the total weight of the composition.
[0088] La composition peut comprendre, dans la phase aqueuse, au moins un solvant soluble dans l’eau. The composition may comprise, in the aqueous phase, at least one solvent soluble in water.
[0089] Par « solvant soluble dans l’eau », on désigne un composé liquide à température ambiante et miscible à l’eau (miscibilité dans l’eau supérieure à 50% en poids à 25°C et pression atmosphérique). The term "water-soluble solvent" denotes a compound which is liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure).
[0090] Les solvants hydrosolubles utilisables dans les compositions selon l'invention peuvent être volatils. The water-soluble solvents which can be used in the compositions according to the invention can be volatile.
[0091] Parmi les solvants hydrosolubles pouvant être utilisés dans les compositions conformes à l'invention, on peut citer les mono-alcools ayant de 1 à 5 atomes de carbone tels que l'éthanol et l'isopropanol, les cétones en C3-C4 et les aldéhydes en C2-C4. Among the water-soluble solvents which can be used in the compositions in accordance with the invention, mention may be made of mono-alcohols having from 1 to 5 carbon atoms such as ethanol and isopropanol, C3-C4 ketones and C2-C4 aldehydes.
[0092] Ainsi, selon un mode préféré de réalisation, la composition selon l’invention comprenant au moins un mono-alcool ayant de 1 à 5 atomes de carbone, de préférence l’éthanol ou le propanediol (ou 1 ,2 - mono propylène glycol). Ce dernier est de préférence d’origine naturel ou obtenu par un procédé fermentaire ou biotechnologique, comme le produit Zemea® vendu par la société DUPONT et le produit TILAMAR® PDO with N00VISTA vendu pas DSM. Thus, according to a preferred embodiment, the composition according to the invention comprising at least one monoalcohol having from 1 to 5 carbon atoms, preferably ethanol or propanediol (or 1, 2 - mono propylene glycol). The latter is preferably of natural origin or obtained by a fermentation or biotechnological process, such as the product Zemea® sold by the company DUPONT and the product TILAMAR® PDO with N00VISTA sold by DSM.
[0093] Typiquement, le mono-alcool ayant de 1 à 5 atomes est présent en une teneur allant de 0,5 à 25% en poids, de préférence de 1 à 15% en poids, de préférence de 2 à 10% en poids, par rapport au poids total de la composition. Typically, the monoalcohol having 1 to 5 atoms is present in a content ranging from 0.5 to 25% by weight, preferably from 1 to 15% by weight, preferably from 2 to 10% by weight , relative to the total weight of the composition.
[0094] Humectants [0094] Humectants
[0095] L’émulsion selon l’invention peut comprendre également au moins un humectant. L’humectant pourra être choisi parmi les polyols et/ou les esters d'acides gras et de polyéthylèneglycol. [0096] Par « polyols », on entend toute molécule présentant dans sa structure au moins deux groupements hydroxy (-OH) libres. Ces polyols sont de préférence liquides à température ambiante (25°C). The emulsion according to the invention can also comprise at least one humectant. The humectant may be chosen from polyols and / or esters of fatty acids and of polyethylene glycol. The term “polyols” is understood to mean any molecule having in its structure at least two free hydroxy (—OH) groups. These polyols are preferably liquid at room temperature (25 ° C).
[0097] Typiquement, le polyol sera choisi parmi le maltitol, le mannitol, le xylitol, l’érythritol, le sorbitol, l’isosorbide, le glycérol ou la glycérine, le glucose, le saccharose, le polydextrose, les sirops de glucose hydrogénés, les dextrines, les maltodextrines, les sirops de glucose, et leurs mélanges. Typically, the polyol will be chosen from maltitol, mannitol, xylitol, erythritol, sorbitol, isosorbide, glycerol or glycerin, glucose, sucrose, polydextrose, hydrogenated glucose syrups , dextrins, maltodextrins, glucose syrups, and mixtures thereof.
[0098] A titre illustratif, on citera en particulier les produits Beauté by Roquette® PO 070 (INCI : Sorbitol), Beauté by Roquette® PO 160 (INCI : Sorbitol), Beauté by Roquette® PO 260 (INCI : Mannitol), Beauté by Roquette® PO 370 (INCI : Xylitol), Beauté by Roquette® PO 500 (INCI : Isosorbide) commercialisés par la société ROQUETTE, la glycérine (INCI : glycerin) vendue par la société COOPER, le propylene glycol (INCI : propylene Glycol) de la société COOPER, le Butylène Glycol (INCI : 1,3-BUTANEDIOL). By way of illustration, mention will in particular be made of the products Beauté by Roquette® PO 070 (INCI: Sorbitol), Beauté by Roquette® PO 160 (INCI: Sorbitol), Beauté by Roquette® PO 260 (INCI: Mannitol), Beauté by Roquette® PO 370 (INCI: Xylitol), Beauté by Roquette® PO 500 (INCI: Isosorbide) marketed by the company ROQUETTE, glycerin (INCI: glycerin) sold by the company COOPER, propylene glycol (INCI: propylene Glycol) from COOPER, Butylene Glycol (INCI: 1,3-BUTANEDIOL).
[0099] On citera parmi les esters d'acides gras et de polyéthylèneglycol, le produit vendu sous la dénomination Glucamate SSE-20 (INCI : PEG-20 METHYL GLUCOSE SESQUISTEARATE) par la société LUBRIZOL ADVANCED MATERIALS, Inc. Mention will be made, among the esters of fatty acids and of polyethylene glycol, of the product sold under the name Glucamate SSE-20 (INCI: PEG-20 METHYL GLUCOSE SESQUISTEARATE) by the company LUBRIZOL ADVANCED MATERIALS, Inc.
[0100] La composition comprend de 0,5 à 25% en poids de polyols, de préférence, de 1 à 15% en poids, et de manière encore plus préférée de 2 à 10% en poids, et plus préférentiellement de 2 à 6% en poids, de polyols, par rapport au poids total de la composition. [0100] The composition comprises from 0.5 to 25% by weight of polyols, preferably from 1 to 15% by weight, and even more preferably from 2 to 10% by weight, and more preferably from 2 to 6 % by weight, of polyols, relative to the total weight of the composition.
[0101] Phase huileuse [0101] Oily phase
[0102] La composition selon l’invention comprend au moins une huile. [0102] The composition according to the invention comprises at least one oil.
[0103] Au sens de la présente invention, on entend par « huile » un composé liquide à température ambiante (25°C), et qui, lorsqu'il est introduit à raison d'au moins 1% en poids dans l'eau à 25°C, n'est pas du tout soluble dans l'eau, ou soluble à hauteur de moins de 10% en poids, par rapport au poids d'huile introduit dans l'eau. For the purposes of the present invention, the term “oil” means a compound which is liquid at room temperature (25 ° C), and which, when it is introduced in an amount of at least 1% by weight in water at 25 ° C, is not at all soluble in water, or soluble in an amount of less than 10% by weight, relative to the weight of oil introduced into the water.
[0104] Selon un mode de réalisation, l’huile sera choisie parmi les huiles volatiles, les huiles non volatiles et leurs mélanges. [0104] According to one embodiment, the oil will be chosen from volatile oils, non-volatile oils and mixtures thereof.
[0105] La phase grasse liquide comprend avantageusement une ou plusieurs huiles non volatiles qui procurent un effet émollient sur la peau. The liquid fatty phase advantageously comprises one or more non-volatile oils which provide an emollient effect on the skin.
[0106] On entend par « huile non volatile », une huile restant sur les matières kératiniques à une température ambiante et pression atmosphérique au moins plusieurs heures et ayant notamment une pression de vapeur inférieure à 103 mm de Hg (0,13Pa). [0107] Parmi les huiles non volatiles, on peut citer les esters gras tels que l'isononoate de cetearyl, l'isononoate d'isotridecyl, l'isostearate d'isostearyl, l'isostearate d'isopropyl, le myristate d'isopropyl, le palmitate d'isopropyl, stéarate de butyle, le laurate d'hexyle, l'isononate d'isononyle, le palmitate de 2-éthyl-hexyle, le laurate de 2-hexyldécyle, le palmitate de 2-octyl décyle, le myristate ou la lactate de 2-octyldodécyle, le succinate de 2-diéthyl hexyle, le malate de diisostéaryle, la triacétine, la tricprine, les triglycérides d’acide caprylique/caprique, le mélange de caprate et caprylate de coco, les benzoates d'alcools en C12 à C15, les esters de glycol tels que le butylène glycol cocoate, le triisostéarate de glycérine, l'acetate de tocopherol, les acides gras supérieurs tels que l'acide myristique, l'acide palmitique, l'acide stéarique, l'acide béhénique, l'acide oléique, l'acide linoléique, l'acide linolénique ou l'acide isostéarique, les alcools gras supérieurs tel que l'alcool oléique, les huiles végétales comme l'huile d'avocat, l'huile de camélias, l’huile de noisette, l’huile de tsubaki, l'huile de noix de cajou, l'huile d’argan, l'huile de soja, l'huile de pépins de raisin, l'huile de sésame, l'huile de maïs, l’huile de germes de blé, l'huile de colza, l'huile de tournesol, l'huile de coton, l'huile de jojoba, l'huile d'arachide, l’huile de macadamia, l’huile d’amande douce, l'huile d'olive et leurs mélanges, les beurres végétaux comme le beurre de karité, le beurre de camellia. The term “non-volatile oil” means an oil which remains on keratin materials at room temperature and atmospheric pressure for at least several hours and in particular having a vapor pressure of less than 10 3 mm Hg (0.13Pa). Among the non-volatile oils, mention may be made of fatty esters such as cetearyl isononoate, isotridecyl isononoate, isostearyl isostearate, isopropyl isostearate, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, isononyl isononate, 2-ethyl-hexyl palmitate, 2-hexyldecyl laurate, 2-octyl decyl palmitate, myristate or 2-octyldodecyl lactate, 2-diethyl hexyl succinate, diisostearyl malate, triacetin, tricprine, caprylic / capric acid triglycerides, mixture of caprate and coconut caprylate, alcohol benzoates in C12 to C15, glycol esters such as butylene glycol cocoate, glycerin triisostearate, tocopherol acetate, higher fatty acids such as myristic acid, palmitic acid, stearic acid, behenic, oleic acid, linoleic acid, linolenic acid or isostearic acid, higher fatty alcohols urs such as oleic alcohol, vegetable oils such as avocado oil, camellia oil, hazelnut oil, tsubaki oil, cashew oil, olive oil, argan, soybean oil, grape seed oil, sesame oil, corn oil, wheat germ oil, rapeseed oil, sunflower oil, cottonseed oil, jojoba oil, peanut oil, macadamia oil, sweet almond oil, olive oil and their mixtures, vegetable butters such as shea butter, camellia butter.
[0108] Ces huiles non volatiles peuvent également être des huiles de type hydrocarbures ou siliconées telles que l'huile de paraffine, de squalane, la vaseline, les diméthyls siloxanes et leurs mélanges. These non-volatile oils can also be oils of the hydrocarbon or silicone type such as paraffin oil, squalane oil, petrolatum, dimethylsiloxanes and their mixtures.
[0109] Selon un mode de réalisation, l’huile non volatile est choisi parmi l’acide stéarique, l’huile de de jojoba (INCI : simmondsia Chinensis Seed Oil), l’huile de pépin de raisin (INCI : vitis vinifera seed oil), l’huile de macadamia (INCI : Macadamia ternifolia seed oil), l’huile de tournesol oléique raffinée (Helianthus annuus seed oil), le mélange de caprate et caprylate de coco tel que le produit Miglyol Coco 810 (INCI : Coco-Caprylate/Caprate), l’huile d’amande douce (INCI : Prunus Amygdalus Dulcis Oil), l’huile de sésame (INCI : Sesamum indicum seed oil). According to one embodiment, the non-volatile oil is chosen from stearic acid, jojoba oil (INCI: simmondsia Chinensis Seed Oil), grape seed oil (INCI: vitis vinifera seed oil), macadamia oil (INCI: Macadamia ternifolia seed oil), refined oleic sunflower oil (Helianthus annuus seed oil), mixture of coconut caprate and caprylate such as the product Miglyol Coco 810 (INCI: Coco -Caprylate / Caprate), sweet almond oil (INCI: Prunus Amygdalus Dulcis Oil), sesame oil (INCI: Sesamum indicum seed oil).
[0110] Selon un mode de réalisation, l’huile non volatile est présente en une teneur allant de 0,5 à 50% en poids, de préférence de 1 à 25% en poids, de préférence de 2 à 20% en poids, de préférence de 5 à 15% en poids, par rapport au poids total de la composition. [0110] According to one embodiment, the non-volatile oil is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 2 to 20% by weight, preferably from 5 to 15% by weight, relative to the total weight of the composition.
[0111] La phase grasse liquide peut également comprendre des huiles volatiles. Par huile volatile, on entend une huile susceptible de s'évaporer de la peau, en moins d'une heure à température ambiante et pression atmosphérique. Les huiles volatiles peuvent être par exemple choisies parmi les huiles de silicones ou triglycérides d’acides gras courts pour réduire le toucher gras. [0112] Selon un mode de réalisation, l’huile volatile est présente en une teneur allant de 0,5 à 50% en poids, de préférence de 1 à 25% en poids, de préférence de 2 à 20% en poids, de préférence de 5 à 15% en poids, par rapport au poids total de la composition. [0111] The liquid fatty phase can also comprise volatile oils. By volatile oil is meant an oil capable of evaporating from the skin in less than one hour at room temperature and atmospheric pressure. The volatile oils can for example be chosen from silicone oils or triglycerides of short fatty acids to reduce the greasy feel. [0112] According to one embodiment, the volatile oil is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 2 to 20% by weight, of preferably from 5 to 15% by weight, relative to the total weight of the composition.
[0113] La phase grasse ou huileuse de la composition selon l’invention peut en outre comprendre au moins un agent structurant de phase grasse tel qu’une cire et/ou un composé pâteux. The fatty or oily phase of the composition according to the invention can also comprise at least one fatty phase structuring agent such as a wax and / or a pasty compound.
[0114] Cire [0114] Wax
[0115] Par « cire », on entend un corps gras à changement d'état liquide / solide réversible, ayant une température de fusion supérieure à 30°C et généralement inférieure à 90°C, qui est liquide dans les conditions de préparation de la composition et présente à l’état solide une organisation cristalline anisotrope. Les cires utilisées selon l'invention peuvent être constituées de cires polaires ou apolaires ou d'un mélange des deux. Par « apolaire », on entend une cire ne renfermant que des atomes de carbone, d'hydrogène et/ou de phosphore et en particulier un hydrocarbure. The term "wax" means a fatty substance with a reversible liquid / solid state change, having a melting point greater than 30 ° C and generally less than 90 ° C, which is liquid under the conditions of preparation of composition and exhibits in the solid state an anisotropic crystalline organization. The waxes used according to the invention may consist of polar or non-polar waxes or of a mixture of the two. The term “non-polar” is understood to mean a wax containing only carbon, hydrogen and / or phosphorus atoms and in particular a hydrocarbon.
[0116] Les cires polaires peuvent notamment être choisies parmi les cires animales, les cires végétales et les cires synthétiques ou de silicone renfermant des groupements polaires tels que les esters. On peut ainsi mentionner les cires de Carnauba, de Candelilla, d’abeille (Cera alba), d'insecte de Chine (Ericerus pela); du Japon, de Sumac, de Montan, les triesters d'acides en C8-C20 et de glycérine tels que le tribéhénate de glycérine, le stéarate de glycol acétylé commercialisé notamment par la société VEVY sous la dénomination commerciale CETACENE, et leurs mélanges. Ces cires peuvent notamment être utilisées sous forme prédispersée dans une huile, comme c'est le cas du mélange de cire de candelilla et d'huile de graine de jojoba. Polar waxes can in particular be chosen from animal waxes, vegetable waxes and synthetic or silicone waxes containing polar groups such as esters. We can thus mention the waxes of Carnauba, Candelilla, bee (Cera alba), Chinese insect (Ericerus pela); from Japan, from Sumac, from Montan, triesters of C8-C20 acids and of glycerin such as glycerin tribhenate, acetylated glycol stearate sold in particular by the company VEVY under the trade name CETACENE, and mixtures thereof. These waxes can in particular be used in the form predispersed in an oil, as is the case with the mixture of candelilla wax and jojoba seed oil.
[0117] Selon un mode de réalisation, la cire est présente en une teneur allant de 0,5 à 50% en poids, de préférence de 1 à 25% en poids, de préférence de 5 à 10% en poids, par rapport au poids total de la composition. [0117] According to one embodiment, the wax is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 5 to 10% by weight, relative to the total weight of the composition.
[0118] Composé pâteux [0118] Pasty compound
[0119] On entend par “composé pâteux” des corps gras lipophiles qui, comme les cires, sont capables de subir un changement d’état liquide/solide réversible et ont à l’état solide une organisation cristalline anisotrope, mais qui se différencient des cires par le fait qu’ils renferment, à une température de 23°C, une fraction liquide et une fraction solide. The term “pasty compound” is understood to mean lipophilic fatty substances which, like waxes, are capable of undergoing a reversible change of liquid / solid state and have an anisotropic crystalline organization in the solid state, but which are different from waxes in that they contain, at a temperature of 23 ° C, a liquid fraction and a solid fraction.
[0120] Selon un mode de réalisation, le composé pâteux est présent en une teneur allant de 0,5 à 50% en poids, de préférence de 1 à 25% en poids, de préférence de 5 à 10% en poids, par rapport au poids total de la composition. [0120] According to one embodiment, the pasty compound is present in a content ranging from 0.5 to 50% by weight, preferably from 1 to 25% by weight, preferably from 5 to 10% by weight, relative to to the total weight of the composition.
[0121] Agent gélifiant [0122] Selon un mode de réalisation, la composition selon l’invention comprend au moins un agent gélifiant. [0121] Gelling agent [0122] According to one embodiment, the composition according to the invention comprises at least one gelling agent.
[0123] Par agent gélifiant, on entend un composé qui, en présence d’un solvant, crée des liaisons intermacromoléculaire plus ou moins fortes induisant ainsi un réseau tridimensionnel qui fige ledit solvant. [0123] The term "gelling agent" means a compound which, in the presence of a solvent, creates more or less strong intermacromolecular bonds thus inducing a three-dimensional network which freezes said solvent.
[0124] L’agent gélifiant est choisi parmi les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques liphophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux. [0124] The gelling agent is chosen from hydrophilic organic gelling agents, and / or lipophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents.
[0125] Selon un mode de réalisation, lorsque la composition est une composition monophasique aqueuse ou monophasique hydroalcoolique, la composition comprend au moins un agent gélifiant choisi parmi les gélifiants hydrophiles organiques, les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux. According to one embodiment, when the composition is an aqueous monophasic or hydroalcoholic monophasic composition, the composition comprises at least one gelling agent chosen from organic hydrophilic gelling agents, amphiphilic organic gelling agents, and / or inorganic gelling agents.
[0126] L’agent gélifiant permet de viscosifier la phase continue, c’est-à-dire d’ajuster la viscosité de la phase continue à une valeur allant de 100 mPa.s à 20 000 mPa.s. [0126] The gelling agent makes it possible to viscosify the continuous phase, that is to say to adjust the viscosity of the continuous phase to a value ranging from 100 mPa.s to 20,000 mPa.s.
[0127] L’agent gélifiant organique peut être choisi parmi les polymères d’origine synthétique ou d’origine végétale, préférentiellement d’origine végétale, modifiés chimiquement ou non. Il peut être ainsi choisi parmi les gommes issues de plantes comme la gomme arabique, la gomme ghatti, la gomme adragante, la gomme de konjac , la gomme de tara, la gomme de caroube, la gomme de guar ou leurs dérivés ; les gommes extraits d’algues comme les alginates et les carraghénanes; les gommes issues d’une fermentation microbienne comme les xanthanes, par exemple, le produit Keltrol CG (INCI : xanthan gum), vendu par la société CP KELCO ou le produit Xanthan Gum FNCS- PC (INCI : xanthan gum) vendu par la société JUNGBUNZLAUER INTERNATIONAL AG, les mannanes, les scléroglucanes ou leurs dérivés; la cellulose et ses dérivés comme la carboxyméthylcellulose ou l’hydroxyéthylcellulose ; l'amidon et ses dérivés comme en particulier les amidons modifiés, notamment acétylés, carboxyméthylés, octénylsuccinates ou hydroxypropylés ; les polymères synthétiques comme les polyacide- acryliques ou les carbomères, et leurs mélanges. [0127] The organic gelling agent can be chosen from polymers of synthetic origin or of plant origin, preferably of plant origin, chemically modified or not. It can thus be chosen from gums obtained from plants such as gum arabic, gum ghatti, tragacanth, konjac gum, tara gum, locust bean gum, guar gum or their derivatives; gums extracted from seaweed such as alginates and carrageenans; gums resulting from a microbial fermentation such as xanthans, for example, the product Keltrol CG (INCI: xanthan gum), sold by the company CP KELCO or the product Xanthan Gum FNCS-PC (INCI: xanthan gum) sold by the company JUNGBUNZLAUER INTERNATIONAL AG, mannans, scleroglucans or their derivatives; cellulose and its derivatives such as carboxymethylcellulose or hydroxyethylcellulose; starch and its derivatives such as in particular modified starches, in particular acetylated, carboxymethylated, octenylsuccinate or hydroxypropylated; synthetic polymers such as polyacrylic acids or carbomers, and mixtures thereof.
[0128] Parmi les carbomères, on citera par exemple le produit Carbopol Ultrez 30 (INCI : carbomer) de la société LUBRIZOL ADVANCED MATERIALS, Inc. ou le CARBOPOL ETD 2050 POLYMER (INCI : carbomer). Among the carbomers, mention will be made, for example, of the product Carbopol Ultrez 30 (INCI: carbomer) from the company LUBRIZOL ADVANCED MATERIALS, Inc. or the CARBOPOL ETD 2050 POLYMER (INCI: carbomer).
[0129] On citera également les mélanges de gomme arabique et de gomme xanthane tel que le produit Solagum AX (INCI : Acacia Sénégal Gum (and) Xanthan Gum), vendu par la Société SEPPIC, les mélanges d’amidon et de dérivés de cellulose ou de gommes tels que le produit Beauté by Roquette® DS 112 (INCI : Starch acetate (and) Hydroxyethylcellulose (and) Xanthan gum), vendu par la société ROQUETTE. Mention will also be made of mixtures of gum arabic and of xanthan gum such as the product Solagum AX (INCI: Acacia Senegal Gum (and) Xanthan Gum), sold by the company SEPPIC, mixtures of starch and cellulose derivatives. or gums such the Beauté by Roquette® DS 112 product (INCI: Starch acetate (and) Hydroxyethylcellulose (and) Xanthan gum), sold by the company ROQUETTE.
[0130] L’agent gélifiant minéral peut être choisi parmi les silicates de magnésium et/ou d’aluminium. Un exemple d’un tel agent gélifiant minéral est le Veegum® Pure de Vanderbilt Minerais LLC, qui est un silicate d’aluminium et de magnésium. [0130] The inorganic gelling agent can be chosen from magnesium and / or aluminum silicates. An example of such a mineral gelling agent is Veegum® Pure from Vanderbilt Minerais LLC, which is a silicate of aluminum and magnesium.
[0131] Liant [0131] Binder
[0132] Selon un mode de réalisation, la composition comprend en outre un liant. [0132] According to one embodiment, the composition further comprises a binder.
[0133] Préférentiellement, les compositions solides selon l’invention comprennent au moins un liant. [0133] Preferably, the solid compositions according to the invention comprise at least one binder.
[0134] On entend par « liant » des composés conférant une cohésion accrue de la composition cosmétique. Cette cohésion peut être ajustée en fonction de la quantité et de l’affinité chimique de l’agent liant par rapport aux ingrédients de la composition cosmétique. The term “binder” is understood to mean compounds which confer increased cohesion on the cosmetic composition. This cohesion can be adjusted depending on the amount and chemical affinity of the binding agent relative to the ingredients of the cosmetic composition.
[0135] Typiquement, le liant sera choisi parmi les triglycérides d’acide caprylique/caprique tels le produit Labrafac CC (INCI : capric/caprylic triglicerides) ou le Cetyl Dimethicone (INCI). [0135] Typically, the binder will be chosen from caprylic / capric acid triglycerides such as the product Labrafac CC (INCI: capric / caprylic triglicerides) or Cetyl Dimethicone (INCI).
[0136] Le liant sera présent dans la composition selon l’invention à une teneur allant de 0,5% à 20%, de préférence de 1 à 15%, de préférence de 5 à 12%, en poids par rapport au poids total de la composition. The binder will be present in the composition according to the invention at a content ranging from 0.5% to 20%, preferably from 1 to 15%, preferably from 5 to 12%, by weight relative to the total weight of the composition.
[0137] Avantageusement, les liants auront également des propriétés émollientes. Advantageously, the binders will also have emollient properties.
[0138] Agent émulsionnant [0138] Emulsifying agent
[0139] La composition cosmétique selon l’invention peut également comprendre un ou plusieurs les émulsionnants huile-dans-eau (H/E) ou eau-dans-huile (E/H). [0139] The cosmetic composition according to the invention can also comprise one or more oil-in-water (O / W) or water-in-oil (W / O) emulsifiers.
[0140] L’émulsionnant huile-dans-eau (H/E) est un agent émulsionnant de HLB supérieure ou égale à 8 et choisi parmi les esters de sorbitane éventuellement polyéthoxylés, les esters d'acides gras et de glycérol, les esters ou polyesters d'acides gras et de sucrose, les esters d'acides gras et de polyéthylèneglycol, les polysiloxanes modifiés polyéthers, les éthers d'alcools gras et de polyéthylèneglycol, les alkylpolyglycosides et la lécithine hydrogénée, les alcools gras, les esters de sorbitane sans que cette liste ne soit limitative, et leurs mélanges. The oil-in-water (O / W) emulsifier is an emulsifier with an HLB greater than or equal to 8 and chosen from optionally polyethoxylated sorbitan esters, esters of fatty acids and of glycerol, esters or polyesters of fatty acids and sucrose, esters of fatty acids and of polyethylene glycol, modified polysiloxanes polyethers, ethers of fatty alcohols and of polyethylene glycol, alkylpolyglycosides and hydrogenated lecithin, fatty alcohols, sorbitan esters without that this list is not exhaustive, and their mixtures.
[0141] On citera, à titre illustratif, le produit Montanov 68 (INCI : Cetearyl alcohol (and) cetearyl glucoside), commercialisé par la société SEPPIC, le produit Montanov L (INCI : C14-C22 Alcohols & C12-20 Alkyl Glucoside), commercialisé par la société SEPPIC, le Montanov 202 (INCI : Arachidyl Alcohol (and) Behenyl Alcohol (and) Arachidyl Glucoside), le Citrol GMS 40 (I NCI : Glyceryl stéarate), vendu par la société CRODA, ou le produit Imwitor 960K (INCI : Glyceryl stéarate), vendu par la société BIESTERFELD, le produit Imwitor 372P (INCI : Glyceryl stéarate citrate), vendu par la société BIESTERFELD, le produit Glucate SS (INCI : Methyl Glucose Sesquistearate), vendu par la société LUBRIZOL ADVANCED MATERIALS, Inc, le plurol stearique (Polyglyceryl-6 Distearate), le Natragem E145 (INCI : Polyglyceryl-4 Laurate/Succinate (and) Aqua), vendu par la société CRODA, le produit Span 60 (INCI : sorbitan stéarate), vendu par la société SIGMA ALDRICH. By way of illustration, mention will be made of the product Montanov 68 (INCI: Cetearyl alcohol (and) cetearyl glucoside), marketed by the company SEPPIC, the product Montanov L (INCI: C14-C22 Alcohols & C12-20 Alkyl Glucoside) , marketed by the company SEPPIC, Montanov 202 (INCI: Arachidyl Alcohol (and) Behenyl Alcohol (and) Arachidyl Glucoside), Citrol GMS 40 (I NCI: Glyceryl stearate), sold by the company CRODA, or the product Imwitor 960K (INCI: Glyceryl stearate), sold by the company BIESTERFELD, the product Imwitor 372P (INCI: Glyceryl stearate citrate), sold by the company BIESTERFELD, the product Glucate SS (INCI: Methyl Glucose Sesquistearate), sold by the company LUBRIZOL ADVANCED MATERIALS, Inc, the stearic plurol (Polyglyceryl-6 Distearate), the Natragem E145 (INCI: Polyglyceryl-4 Laurate / Succinate (and ) Aqua), sold by the company CRODA, the product Span 60 (INCI: sorbitan stearate), sold by the company SIGMA ALDRICH.
[0142] Parmi les esters de sorbitane, on citera par exemple le produit Span 20. Among the sorbitan esters, mention will be made, for example, of the product Span 20.
[0143] Parmi les alcools gras, on citera par exemple le produit vendu sous la dénomination Promulgen D (INCI : Cetearyl alcohol (and) Ceteareth-20). Among the fatty alcohols, mention will be made, for example, of the product sold under the name Promulgen D (INCI: Cetearyl alcohol (and) Ceteareth-20).
[0144] L’émulsionnant H/E peut être avantageusement choisi parmi les systèmes émulsionnants composés d’une cyclodextrine et d’un émulsionnant eau-dans-huile d’origine naturelle, tels que le système émulsionnant commercialisé par Roquette Frères sous le nom Beauté by Roquette® DS 146. The O / W emulsifier can be advantageously chosen from emulsifier systems composed of a cyclodextrin and of a water-in-oil emulsifier of natural origin, such as the emulsifier system marketed by Roquette Frères under the name Beauté. by Roquette® DS 146.
[0145] L’émulsionnant eau-dans-huile (E/H) est un agent émulsionnant de HLB inférieure à 8 et choisi parmi les esters gras non éthoxylés de polyols, et notamment parmi les esters gras non éthoxylés de glycérol, de polyglycérols, de sorbitol, de sorbitan, d’anydrodrohexitols comme en particulier l’isosorbide, de mannitol, de xylitol, d’érythritol, de maltitol, de saccharose, de glucose, de polydextrose, de sirops de glucose hydrogéné, de dextrines et d’amidons hydrolysés. The water-in-oil (W / O) emulsifier is an emulsifier of HLB less than 8 and chosen from nonethoxylated fatty esters of polyols, and in particular from nonethoxylated fatty esters of glycerol, of polyglycerols, sorbitol, sorbitan, anydrodrohexitols such as in particular isosorbide, mannitol, xylitol, erythritol, maltitol, sucrose, glucose, polydextrose, hydrogenated glucose syrups, dextrins and starches hydrolyzed.
[0146] Agent viscosant de phase grasse [0146] Oily phase viscosity agent
[0147] Selon un mode de réalisation, la composition selon l’invention pourra comprendre en outre au moins un agent viscosant, autrement dit viscosifiant, de phase grasse, c’est- à-dire un agent viscosant lipophile ou amphiphile, choisi parmi les alcools gras. According to one embodiment, the composition according to the invention may also comprise at least one viscosifying agent, in other words viscosifying agent, of the fatty phase, that is to say a lipophilic or amphiphilic viscosifying agent, chosen from among fatty alcohols.
[0148] On entend par agent viscosant lipophile ou amphiphile, une molécule ou macromolécule capable d’augmenter la viscosité d’une huile sans en changer substantiellement les propriétés physiques ou chimiques. [0148] The term “lipophilic or amphiphilic viscosing agent” means a molecule or macromolecule capable of increasing the viscosity of an oil without substantially changing its physical or chemical properties.
[0149] On citera parmi les alcools gras, le Lanette 16 (INCI : cetyl alcohol), le Lanette O (INCI : cetearyl Alcohol). Among the fatty alcohols, mention will be made of Lanette 16 (INCI: cetyl alcohol), Lanette O (INCI: cetearyl Alcohol).
[0150] Tensioactifs [0150] Surfactants
[0151] Selon un mode de réalisation, la composition selon l’invention comprend au moins un tensioactif choisi parmi les tensioactifs ioniques, non ioniques, anioniques ou amphotères ou zwitterioniques. Ces tensioactifs sont choisis pour leur fonction détergente et moussante. According to one embodiment, the composition according to the invention comprises at least one surfactant chosen from ionic, nonionic, anionic or surfactants. amphoteric or zwitterionic. These surfactants are chosen for their detergent and foaming function.
[0152] Selon un autre mode de réalisation, la composition selon l’invention comprend au moins un tensioactif choisi parmi les tensioactifs anioniques, les tensioactifs amphotères ou zwitterioniques. [0152] According to another embodiment, the composition according to the invention comprises at least one surfactant chosen from anionic surfactants, amphoteric or zwitterionic surfactants.
[0153] Les tensioactifs anioniques sont choisis parmi les tensioactifs anioniques carboxyliques, les tensioactifs anioniques sulfatés, les tensioactifs sulfonates, les tensioactifs anioniques phosphates, et leurs mélanges, de préférence parmi les tensioactifs anioniques sulfonates, les tensioactifs anioniques carboxyliques, et leurs mélanges. The anionic surfactants are chosen from anionic carboxylic surfactants, anionic sulphated surfactants, sulphonate surfactants, anionic phosphate surfactants, and mixtures thereof, preferably from anionic sulphonate surfactants, anionic carboxylic surfactants, and mixtures thereof.
[0154] Par « tensioactif anionique », on entend un tensioactif ne comportant à titre de groupements ioniques ou ionisables que des groupements anioniques. Dans la présente description, on qualifie une entité comme étant "anionique" lorsqu'elle possède au moins une charge négative permanente ou lorsqu'elle peut être ionisée en une entité chargée négativement, dans les conditions d'utilisation de la composition de l'invention (milieu, pH par exemple) et ne comprenant pas de charge cationique. Par « tensioactif anionique sulfaté », on entend un tensioactif anionique comprenant au moins une fonction sulfate (-OSO3H ou -OSO3 ), et pouvant éventuellement comprendre en outre une ou plusieurs autres fonctions dérivées d'acides, telles que les fonctions acides carboxyliques ou carboxylates (-COOH ou -COO ), les fonctions sulfonates (-SO3H ou -SO3 ) et/ou les fonctions phosphates. A titre d'exemple, les alkylsulfates, les alkyléthersulfates, les alkylamidoéthersulfates, les alkylarylpolyéthersulfates, les monoglycéride-sulfates, ainsi que les sels de ces composés, sont des tensioactifs anioniques sulfatés. Les groupes alkyles de ces composés cités à titre d'exemple, comportent de 6 à 30 atomes de carbone, et le groupe aryle désignent un groupe phényle ou benzyle. Ces composés cités à titre d'exemple peuvent être polyoxyalkylénés, notamment polyoxyéthylénés et comporter de 1 à 50 motifs oxyde d'éthylène. On entend par « tensioactif anionique non sulfaté », un tensioactif qui n'entre pas dans la définition de « tensioactif anionique sulfaté » telle que définie ci-avant. The term “anionic surfactant” means a surfactant comprising only anionic groups as ionic or ionizable groups. In the present description, an entity is qualified as being “anionic” when it has at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the composition of the invention. (medium, pH for example) and not comprising a cationic charge. By “sulphated anionic surfactant” is meant an anionic surfactant comprising at least one sulphate function (-OSO 3 H or -OSO 3 ), and possibly additionally comprising one or more other functions derived from acids, such as acid functions. carboxylic or carboxylate (-COOH or -COO), sulfonate functions (-SO 3 H or -SO 3 ) and / or phosphate functions. By way of example, the alkylsulphates, the alkylethersulphates, the alkylamidoethersulphates, the alkylarylpolyethersulphates, the monoglyceride-sulphates, as well as the salts of these compounds, are sulphated anionic surfactants. The alkyl groups of these compounds cited by way of example contain from 6 to 30 carbon atoms, and the aryl group denote a phenyl or benzyl group. These compounds cited by way of example can be polyoxyalkylenated, in particular polyoxyethylenated, and contain from 1 to 50 ethylene oxide units. The term “non-sulfated anionic surfactant” is understood to mean a surfactant which does not fall within the definition of “sulfated anionic surfactant” as defined above.
[0155] Il est également entendu selon l'invention queIt is also understood according to the invention that
- les tensioactifs anioniques carboxyliques comprennent au moins une fonction carboxylique ou carboxylate (-COOH ou -COO ), mais ne comprennent pas de fonction sulfonique ou sulfonate (-SO3H ou -SO3 ), ni de fonction sulfate (-OSO3H ou -OSO3 ) ;- the anionic carboxylic surfactants comprise at least one carboxylic or carboxylate function (-COOH or -COO), but do not include a sulphonic or sulphonate function (-SO 3 H or -SO 3 ), nor a sulphate function (-OSO 3 H) or -OSO 3 );
- les tensioactifs anioniques sulfonates comprennent au moins une fonction sulfonique ou sulfonate (-SO3H ou -SO3 ), et peuvent éventuellement comprendre en outre une ou plusieurs fonctions carboxyliques ou carboxylates (-COOH ou -COO ) et/ou phosphates, mais ne comprennent pas de fonction sulfate (-OSO3H ou -OSO3 ). - les tensioactifs anioniques phosphates comprennent au moins une fonction phosphorique ou phosphate (-OPO3H2 ou -OPO3 2 ), mais ne comprennent pas de fonction carboxylique ou carboxylate (-COOH ou -COO ), ni de fonction sulfonique ou sulfonate (- SO3H ou -SO3-), ni de fonction sulfate (-OSO3H ou -OSO3 ). - the anionic sulphonate surfactants comprise at least one sulphonic or sulphonate function (-SO3H or -SO3), and can optionally also comprise one or more carboxylic or carboxylate functions (-COOH or -COO) and / or phosphates, but do not include a sulfate function (-OSO 3 H or -OSO 3 ). - phosphate anionic surfactants comprise at least one phosphoric or phosphate function (-OPO 3 H 2 or -OPO 3 2 ), but do not include a carboxylic or carboxylate function (-COOH or -COO), nor a sulphonic or sulphonate function ( - SO3H or -SO3-), nor of sulfate function (-OSO3H or -OSO3).
[0156] Autrement dit : [0156] In other words:
[0157] - un tensioactif anionique comprenant au moins une fonction sulfate (-OSO3H ou - OSO3 ), et au moins une fonction carboxylique ou carboxylate (-COOH ou -COO ), est considéré, au sens de l'invention et sauf indication contraire, comme un tensioactif anionique sulfaté ; - an anionic surfactant comprising at least one sulfate function (-OSO3H or - OSO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and unless otherwise indicated. , such as a sulfated anionic surfactant;
[0158] - un tensioactif anionique comprenant au moins une fonction sulfate (-OSO3H ou -OSO3 ), et au moins une fonction sulfonique ou sulfonate (-SO3H ou -SO3 ), est considéré, au sens de l'invention et sauf indication contraire, comme un tensioactif anionique sulfaté ; - An anionic surfactant comprising at least one sulfate function (-OSO 3 H or -OSO 3 ), and at least one sulfonic or sulfonate function (-SO 3 H or -SO 3 ), is considered, within the meaning of l invention and unless otherwise specified, as a sulfated anionic surfactant;
[0159] - un tensioactif anionique comprenant au moins une fonction sulfonique ou sulfonate (-SO3H ou -SO3 ), et au moins une fonction carboxylique ou carboxylate (-COOH ou -COO ), est considéré, au sens de l'invention et sauf indication contraire, comme un tensioactif anionique sulfonate non sulfaté ; · un tensioactif anionique comprenant au moins une fonction sulfate (-OSO3H ou -OSO3 ), et au moins une fonction sulfonique ou sulfonate (-SO3H ou -SO3 ), et au moins une fonction carboxylique ou carboxylate (-COOH ou -COO ), est considéré, au sens de l'invention et sauf indication contraire, comme un tensioactif anionique sulfaté. [0159] an anionic surfactant comprising at least one sulphonic or sulphonate function (-SO3H or -SO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and except otherwise specified, as an unsulfated anionic sulfonate surfactant; An anionic surfactant comprising at least one sulphate function (-OSO3H or -OSO3), and at least one sulphonic or sulphonate function (-SO3H or -SO3), and at least one carboxylic or carboxylate function (-COOH or -COO), is considered, within the meaning of the invention and unless otherwise indicated, as a sulphated anionic surfactant.
[0160] Les tensioactifs anioniques carboxyliques peuvent être choisis parmi les composés suivants : les acylglycinates, les acyllactylates, les acylsarcosinates, les acylglutamates ; les acides alkyl-D-galactoside-uroniques, les acides alkyléthercarboxyliques, les acides alkyl(aryl)éthercarboxyliques, les acides alkylamidoéthercarboxyliques ; ainsi que les sels de ces composés. Les groupes alkyle et/ou acyle de ces composés comportent de 6 à 30 atomes de carbone, plus préférentiellement de 8 à 28, plus préférentiellement encore de 10 à 24, encore mieux de 12 à 22, atomes de carbone. Le groupe aryle désigne de préférence un groupe phényle ou benzyle. Ces composés peuvent être polyoxyalkylénés, notamment polyoxyéthylénés et comportent alors de préférence de 1 à 50 motifs oxyde d'éthylène, mieux de 2 à 10 motifs oxyde d'éthylène. On peut également utiliser les monoesters d'alkyle en C6-C24 et d'acides polyglycoside-polycarboxyliques tels que les polyglycosidecitrates d'alkyle en C6 C24, les polyglycoside-tartrates d'alkyle en C6 C24, et leurs sels. [0161] Selon un mode de réalisation, les tensioactifs anioniques carboxyliques sont choisis parmi The anionic carboxylic surfactants can be chosen from the following compounds: acylglycinates, acyllactylates, acylsarcosinates, acylglutamates; alkyl-D-galactoside-uronic acids, alkyl ethercarboxylic acids, alkyl (aryl) ethercarboxylic acids, alkylamidoethercarboxylic acids; as well as the salts of these compounds. The alkyl and / or acyl groups of these compounds contain from 6 to 30 carbon atoms, more preferably from 8 to 28, more preferably still from 10 to 24, still better from 12 to 22, carbon atoms. The aryl group preferably denotes a phenyl or benzyl group. These compounds can be polyoxyalkylenated, in particular polyoxyethylene, and then preferably contain from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. It is also possible to use monoesters of C6-C24 alkyl and of polyglycoside-polycarboxylic acids such as C6-C24 alkyl polyglycosidecitrates, C6-C24 alkyl polyglycoside-tartrates, and their salts. According to one embodiment, the anionic carboxylic surfactants are chosen from
- les acylglutamates notamment en C6 C24, voire en C12-C20, tels que les stéaroylglutamates, et en particulier le stéaroylglutamate de sodium ou de disodium ou les cocoylglutamates, en particulier le cocoyl glutamate de sodium ou de disodium;- acylglutamates in particular C6 C24, or even C12-C20, such as stearoylglutamates, and in particular sodium or disodium stearoylglutamate or cocoylglutamates, in particular sodium or disodium cocoyl glutamate;
- les acylsarcosinates notamment en C6 C24, voire en C12-C20, tels que les cocoyl sarcosinates et en particulier le cocoyl sarcosinate de sodium, les lauroyl sarcosinates et en particulier les lauroyl sarcosinate de sodium, les palmitoylsarcosinates, et en particulier le palmitoylsarcosinate de sodium ;- acylsarcosinates in particular in C6 C24, or even in C12-C20, such as cocoyl sarcosinates and in particular sodium cocoyl sarcosinate, lauroyl sarcosinates and in particular sodium lauroyl sarcosinate, palmitoylsarcosinates, and in particular sodium palmitoylsarcosinate ;
- les acyllactylates notamment en C12-C28, voire en C14-C24, tels que les béhénoyllactylates, et en particulier le behenoyllactylate de sodium, les (iso)stearoyl lactylates, et en particulier l'(iso)stearoyl lactylatede sodium ;- acyllactylates, in particular C12-C28, or even C14-C24, such as behenoyllactylates, and in particular sodium behenoyllactylate, (iso) stearoyl lactylates, and in particular sodium (iso) stearoyl lactylate;
- les acylglycinates en C6 C24, notamment en C12-C20 tels que les cocoyl glycinates et en particulier le cocoyl glycinate de sodium;- C6 C24 acylglycinates, in particular C12-C20 acylglycinates such as cocoyl glycinates and in particular sodium cocoyl glycinate;
- les acides alkyl(C6-C30)éthercarboxyliques, notamment les acides alkyl(C6- C24)éthercarboxyliques; - alkyl (C6-C30) ethercarboxylic acids, in particular alkyl (C6-C24) ethercarboxylic acids;
- les acides alkyl(C6-C30) aryléthercarboxyliques, notamment les acides alkyl(C6-C24) aryléthercarboxyliques ;- alkyl (C6-C30) arylethercarboxylic acids, in particular alkyl (C6-C24) arylethercarboxylic acids;
- les acides alkyl(C6-C30)amidoéthercarboxyliques, notamment les acides alkyl(C6-- alkyl (C6-C30) amidoethercarboxylic acids, in particular alkyl (C6-
C24)amidoéthercarboxyliques ;C24) amidoethercarboxylic;
- et leurs mélanges ; et en particulier sous forme de sels de métaux alcalins ou alcalino- terreux, d'ammonium, ou d'aminoalcool. - and their mixtures; and in particular in the form of alkali metal or alkaline earth metal, ammonium or aminoalcohol salts.
[0162] Les tensioactifs anioniques sulfonates peuvent être choisis parmi les composés suivants : les alkylsulfonates, les alkylamidesulfonates, les alkylarylsulfonates, les polyglycoside-sulfosuccinates d'alkyle en C6-C24, les alphaoléfinesulfonates, les paraffine-sulfonates, les alkylsulfosuccinates, les alkyléthersulfosuccinates, les alkylamidesulfosuccinates, les alkylsulfoacétates, les N-acyltaurates, les acyliséthionates ; les alkylsulfolaurates ; ainsi que les sels de ces composés ; les groupes alkyle de ces composés comportant de 6 à 30 atomes de carbone, notamment de 12 à 28, encore mieux de 14 à 24, voire de 16 à 22, atomes de carbone ; le groupe aryle désignant de préférence un groupe phényle ou benzyle ; ces composés pouvant être polyoxyalkylénés, notamment polyoxyéthylénés et comportant alors de préférence de 1 à 50 motifs oxyde d'éthylène, mieux de 2 à 10 motifs oxyde d'éthylène. The anionic sulphonate surfactants can be chosen from the following compounds: alkylsulphonates, alkylamidesulphonates, alkylarylsulphonates, C6-C24 alkyl polyglycoside-sulphosuccinates, alpha-olefinesulphonates, paraffin-sulphonates, alkylsulphinetuccinates, sulphosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, N-acyltaurates, acylisethionates; alkylsulfolaurates; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 12 to 28, even better still from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; it being possible for these compounds to be polyoxyalkylenated, in particular polyoxyethylene, and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units.
[0163] Selon un mode de réalisation, les tensioactifs anioniques sulfonates sont choisis parmi : les alkylsulfosuccinates en C6-C24, notamment en C12-C20, notamment les laurylsulfosuccinates ; les alkyléthersulfosuccinates en C6-C24, notamment en C12-C20; les (C6-C24)acyliséthionates, de préférence les (C12-C18) acyliséthionates ; les alpha- oléfine-sulfonates ; et leurs mélanges ; et en particulier sous forme de sels de métaux alcalins ou alcalino-terreux, d'ammonium, ou d'aminoalcool. According to one embodiment, the anionic sulfonate surfactants are chosen from: C6-C24 alkylsulfosuccinates, in particular C12-C20, in particular laurylsulfosuccinates; C6-C24, especially C12-C20, alkylethersulfosuccinates; (C6-C24) acylisethionates, preferably (C12-C18) acylisethionates; the alpha- olefin sulfonates; and their mixtures; and in particular in the form of alkali metal or alkaline earth metal, ammonium or aminoalcohol salts.
[0164] Selon un mode de réalisation, les tensioactifs anioniques peuvent être choisis parmi les monoesters d'alkyle en C6-C24 et d'acides polyglycoside-dicarboxyliques tels que les glucoside-citrates d'alkyle, les polyglycoside-tartrates d'alkyle et les polyglycosidesulfosuccinates d'alkyle, les alkylsulfosuccinamates, les acyliséthionates et les N-acyltaurates, le groupe alkyle ou acyle de tous ces composés comportant de préférence de 12 à 20 atomes de carbone. Un autre groupe d'agents tensioactifs anioniques utilisables dans les compositions de la présente invention est celui des acyllactylates dont le groupe acyle comporte de 8 à 20 atomes de carbone. En outre, on peut encore citer les acides alkyl-D-galactosideuroniques et leurs sels ainsi que les acides (alkyl en C6-C24)éthercarboxyliques polyoxyalkylénés, les acides (alkyl en C6 24)(aryl en C6-C24)éther-carboxyliques polyoxyalkylénés, les acides (alkyl en C6-24)amidoéther- carboxyliques polyoxyalkylénés et leurs sels, en particulier ceux comportant de 2 à 50 motifs oxyde d'éthylène, et leurs mélanges. [0164] According to one embodiment, the anionic surfactants can be chosen from C6-C24 alkyl monoesters and polyglycoside-dicarboxylic acids such as alkyl glucoside-citrates, alkyl polyglycoside-tartrates and alkyl polyglycosidesulfosuccinates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, the alkyl or acyl group of all these compounds preferably comprising from 12 to 20 carbon atoms. Another group of anionic surfactants which can be used in the compositions of the present invention is that of acyllactylates in which the acyl group contains from 8 to 20 carbon atoms. In addition, there may also be mentioned alkyl-D-galactosideuronic acids and their salts as well as polyoxyalkylenated (C6-C24 alkyl) ethercarboxylic acids, (C624 alkyl) (C6-C24 aryl) polyoxyalkylenated ether-carboxylic acids. , polyoxyalkylenated (C6-24 alkyl) amidoethercarboxylic acids and their salts, in particular those comprising from 2 to 50 ethylene oxide units, and mixtures thereof.
[0165] Les tensioactifs anioniques phosphates sont choisis parmi : les alkyl phosphates en C6-C24, notamment en C12-C20 ; les alkyléther phosphates en C6-C24 notamment en C12-C20 ; et leurs mélanges. The anionic phosphate surfactants are chosen from: C6-C24, especially C12-C20, alkyl phosphates; C6-C24 alkyl ether phosphates, in particular C12-C20; and their mixtures.
[0166] Les tensioactifs amphotères ou zwitterioniques peuvent être choisis parmi les dérivés d'amines aliphatiques secondaires ou tertiaires ou quaternaires, dans lesquels le groupe aliphatique est une chaîne linéaire ou ramifiée comportant de 8 à 22 atomes de carbone et contenant au moins un groupe anionique tel que, par exemple, un groupe carboxylate, sulfonate, sulfate, phosphate ou phosphonate. On peut citer également : les alkyl(C8-C20)bétaïnes, par exemple la cocobetaïne ; les sulfobétaïnes ; les alkyl(C8- C20)sulfobetaïnes ; les alkyl(C8-C20)amidoalkyl(C3-C8)bétaïnes, par exemple la cocamidopropylbetaïne ; ou les alkyl(C8-C20)amidoalkyl(C6-C8)sulfobétaïnes. The amphoteric or zwitterionic surfactants can be chosen from derivatives of secondary or tertiary or quaternary aliphatic amines, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms and containing at least one anionic group. such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may also be made of: (C8-C20) alkyl betaines, for example cocobetaine; sulfobetaines; (C8-C20) alkyl sulfobetaines; alkyl (C8-C20) amidoalkyl (C3-C8) betaines, for example cocamidopropylbetaine; or alkyl (C8-C20) amidoalkyl (C6-C8) sulfobetaines.
[0167] Agents filmoqènes [0167] Film-forming agents
[0168] Selon un mode de réalisation, la composition selon l’invention comprend en outre au moins un agent filmogène. [0168] According to one embodiment, the composition according to the invention further comprises at least one film-forming agent.
[0169] L’agent filmogène pourra être choisi parmi des polymères d’origine naturelle ou dérivés de produits naturels tels que l'hydroxypropyl méthyl-cellulose (HPMC), l'hydroxypropyl-cellulose (HPC), ou des polymères synthétiques tels que l'alcool polyvinylique (PVA), et/ou des plastifiants autres que les polyols, comme du polyéthylène glycol, du triéthylcitrate, du polysorbate, ou encore des cires comme la cire de Carnauba, ou de l'huile de ricin hydrogénée. [0170] On citera aussi l’amidon de pois hydroxypropylé Beauté by Roquette® ST 720 comme agent filmogène. The film-forming agent may be chosen from polymers of natural origin or derived from natural products such as hydroxypropyl methyl-cellulose (HPMC), hydroxypropyl-cellulose (HPC), or synthetic polymers such as l. polyvinyl alcohol (PVA), and / or plasticizers other than polyols, such as polyethylene glycol, triethyl citrate, polysorbate, or even waxes such as Carnauba wax, or hydrogenated castor oil. Mention will also be made of the Beauté by Roquette® ST 720 hydroxypropylated pea starch as a film-forming agent.
[0171] Matière colorante [0171] Coloring matter
[0172] La composition cosmétique selon l’invention peut encore comprendre au moins une matière colorante choisie parmi les colorants hydrosolubles ou liposolubles, les charges ayant pour effet de colorer et/ou opacifier la composition et/ou de colorer les matières kératiniques, préférentiellement la peau, telles que les pigments, les nacres, les laques (colorants hydrosolubles adsorbés sur un support minéral inerte), et leurs mélanges. Ces matières colorantes peuvent être éventuellement traitées en surface par un agent hydrophobe tel que les silanes, silicones, savons d’acides gras, C9-15 fluoroalcool phosphates, copolymères acrylate/dimethicone, copolymères mixtes C9-15 fluoroalcool phosphates / silicones, lécithines, cire de carnauba, polyéthylène, chitosan et acides aminés éventuellement acylés tels que la lauroyl lysine, le disodium stearoyl glutamate et l’aluminium acyl glutamate, l’acide phytique. The cosmetic composition according to the invention can also comprise at least one coloring material chosen from water-soluble or liposoluble dyes, the fillers having the effect of coloring and / or opacifying the composition and / or of coloring keratin materials, preferably skin, such as pigments, nacres, lakes (water-soluble dyes adsorbed on an inert mineral support), and mixtures thereof. These coloring materials can optionally be surface treated with a hydrophobic agent such as silanes, silicones, fatty acid soaps, C9-15 fluoroalcohol phosphates, acrylate / dimethicone copolymers, mixed C9-15 fluoroalcohol phosphates / silicones copolymers, lecithins, wax. of carnauba, polyethylene, chitosan and optionally acylated amino acids such as lauroyl lysine, disodium stearoyl glutamate and aluminum acyl glutamate, phytic acid.
[0173] On entend par « pigments », des particules blanches ou colorées, minérales ou organiques, destinées à colorer et/ou opacifier la composition cosmétique. The term “pigments” is understood to mean white or colored particles, inorganic or organic, intended to color and / or opacify the cosmetic composition.
[0174] Parmi les pigments, on citera les pigments minéraux ou organiques, naturels ou de synthèse. Des exemples de pigments sont notamment les oxydes de fer, de titane ou de zinc, ainsi que les pigments composites et les pigments goniochromatiques, perlescents, interférentiels, photochromes ou thermochromes, sans que cette liste ne soit limitative. Among the pigments, mention will be made of inorganic or organic, natural or synthetic pigments. Examples of pigments are in particular iron, titanium or zinc oxides, as well as composite pigments and goniochromatic, pearlescent, interference, photochromic or thermochromic pigments, without this list being limiting.
[0175] Parmi les pigments traités en surface par des lécithines, on citera les produits UNIPURE WHITE LC981 HLC (INCI: Cl 77891 (and) Hydrogenated Lecithin, UNIPURE YELLOW LC 182 HLC (INCI: Cl 77492 (and) Hydrogenated Lecithin), UNIPURE BLACK LC989 HLC (INCI: Cl 77499 (and) Hydrogenated Lecithin, UNIPURE RED LC381HLC (INCI: Cl 77491 (and) Hydrogenated Lecithin) de la société Sensient Cosmetic Technologies. Among the pigments treated at the surface with lecithins, mention will be made of the products UNIPURE WHITE LC981 HLC (INCI: Cl 77891 (and) Hydrogenated Lecithin, UNIPURE YELLOW LC 182 HLC (INCI: Cl 77492 (and) Hydrogenated Lecithin), UNIPURE BLACK LC989 HLC (INCI: Cl 77499 (and) Hydrogenated Lecithin, UNIPURE RED LC381HLC (INCI: Cl 77491 (and) Hydrogenated Lecithin) from the company Sensient Cosmetic Technologies.
[0176] Parmi les pigments traités en surface par l’acide phytique, on citera les produits Unipure White LC 985 PHY (INCI : Cl 77891 (and) Phytic Acid (and) Sodium Hydroxide), Unipure Yellow LC 188 PHY (INCI : Cl 77492 (and) Phytic Acid (and) Sodium Hydroxide ), Unipure Red LC 388 PHY (INCI : Cl 77491 (and) Phytic Acid (and) Sodium Hydroxide ), Unipure Black LC 998 PHY(INCI : Cl 77499 (and) Phytic Acid (and) Sodium Hydroxide), de la société Sensient Cosmetic Technologies. Among the pigments treated at the surface with phytic acid, mention will be made of the products Unipure White LC 985 PHY (INCI: Cl 77891 (and) Phytic Acid (and) Sodium Hydroxide), Unipure Yellow LC 188 PHY (INCI: Cl 77492 (and) Phytic Acid (and) Sodium Hydroxide), Unipure Red LC 388 PHY (INCI: Cl 77491 (and) Phytic Acid (and) Sodium Hydroxide), Unipure Black LC 998 PHY (INCI: Cl 77499 (and) Phytic Acid (and) Sodium Hydroxide), from Sensient Cosmetic Technologies.
[0177] On entend par « nacres », toutes particules colorées irisées ou non et qui présentent un effet de couleur par interférence optique. [0178] On citera parmi les nacres, le mica titane recouvert d’oxyde métallique tel que l’oxyde de fer ou l’oxyde de titane. The term “nacres” is understood to mean any colored particles which may or may not be iridescent and which exhibit a color effect by optical interference. Among the nacres, mention will be made of titanium mica coated with metal oxide such as iron oxide or titanium oxide.
[0179] Selon un mode de réalisation, la composition de maquillage et/ou de soin selon l’invention comprend au moins des particules colorées, préférentiellement des pigments tels que des pigments d’oxyde de fer et/ou des nacres. [0179] According to one embodiment, the makeup and / or care composition according to the invention comprises at least colored particles, preferably pigments such as iron oxide pigments and / or nacres.
[0180] Charges [0180] Charges
[0181] La composition cosmétique selon l'invention peut en outre renfermer au moins une charge. Par ce terme, on entend toute particule de forme quelconque (notamment sphérique ou lamellaire), minérale ou organique, insoluble dans la composition. Des exemples de charges sont le talc, le nitrure de bore, l’amidon, les polyamides, les résines de silicone, les poudres d’élastomères de silicone et les poudres de polymères acryliques, en particulier de poly(méthacrylate de méthyle) ou les poudres de copolymère styrène acrylate (Sunsphere Powders de Dow). The cosmetic composition according to the invention can also contain at least one filler. By this term is meant any particle of any shape (in particular spherical or lamellar), mineral or organic, insoluble in the composition. Examples of fillers are talc, boron nitride, starch, polyamides, silicone resins, powders of silicone elastomers and powders of acrylic polymers, in particular of poly (methyl methacrylate) or styrene acrylate copolymer powders (Sunsphere Powders from Dow).
[0182] Agents sensoriels [0182] Sensory agents
[0183] Les agents sensoriels permettent de modifier le profil sensoriel de la composition cosmétique ou dermatologique, pour la rendre plus agréable à l’utilisateur. Les agents sensoriels peuvent être choisis parmi les amidons modifiés tels que les amidons carboxyméthylés, par exemple le Beauté by Roquette® ST 118 de Roquette, les silices, ou les talcs, ou leurs mélanges. Ces agents sensoriels apportent de la douceur au touché pour les compositions solides, ou un effet coussin pour les compositions sous forme liquide ou gel. [0183] Sensory agents make it possible to modify the sensory profile of the cosmetic or dermatological composition, to make it more pleasant for the user. The sensory agents can be chosen from modified starches such as carboxymethylated starches, for example Beauté by Roquette® ST 118 from Roquette, silicas or talcs, or mixtures thereof. These sensory agents provide softness to the touch for solid compositions, or a cushion effect for compositions in liquid or gel form.
[0184] Agents conditionneurs [0184] Conditioning agents
[0185] Les agents conditionneurs peuvent être choisis parmi les polymères cationiques, tels que les polyquaternium. The conditioning agents can be chosen from cationic polymers, such as polyquaternium.
[0186] Principes actifs [0186] Active ingredients
[0187] La composition selon l’invention peut également comprendre au moins un actif cosmétique. [0187] The composition according to the invention can also comprise at least one cosmetic active.
[0188] On citera en tant qu’actif cosmétique ou ingrédient cosmétiquement actif ou substance cosmétiquement active, un agent anti-acnéique, un agent sébo-régulateur, un agent antibactérien, un agent antifongique, un agent kératolytique, un agent kérato- régulateur, un agent astringent, un agent anti-inflammatoire, un agent anti-irritant, un agent antioxydant, un agent anti radicalaire, un agent cicatrisant, un agent anti-âge, un agent hydratant, un agent émollient, un agent tenseur, un agent dépigmentant, un agent matifiant, un agent antipollution, un agent stimulant la microcirculation, un agent desquamant, un agent tenseur, des vitamines, des minéraux, un ingrédient ou substance destiné à nettoyer ou purifier la peau, tels des agents tensio-actifs qui seront choisis parmi ceux n’ayant pas d’activité stimulatrice sur la sébogénese. As a cosmetic active ingredient or cosmetically active ingredient or cosmetically active substance, there will be mentioned an anti-acne agent, a sebum-regulating agent, an antibacterial agent, an antifungal agent, a keratolytic agent, a kerato-regulating agent, an astringent agent, an anti-inflammatory agent, an anti-irritant, an antioxidant, an anti-radical agent, a wound-healing agent, an anti-aging agent, a moisturizing agent, an emollient agent, a tightening agent, a depigmenting agent , a mattifying agent, an antipollution agent, an agent stimulating the microcirculation, an agent desquamating agent, a tightening agent, vitamins, minerals, an ingredient or substance intended to cleanse or purify the skin, such surfactants which will be chosen from those having no stimulating activity on sebogenesis.
[0189] Selon un mode de réalisation, la composition selon l’invention comprend au moins un actif cosmétique ayant une activité émolliente tel qu’un agent émollient. [0189] According to one embodiment, the composition according to the invention comprises at least one cosmetic active agent having emollient activity such as an emollient agent.
[0190] On citera, en tant qu’agent émollient et à titre illustratif, le glyceryl stéarate (nom INCI), le MOD (INCI : Octyldodecyl Myristate), le produit Lipocire A (INCI : C10-18 Triglycérides), le produit Lexfeel NS (INCI : Diheptyl Succinate (and) Capryloyl Glycerin/Sebacic Acid Copolymer), vendu par la société INOLEX, le produit Labrafac CC (INCI : capric/caprylic triglicerides), vendu par la société GATTEFOSSE, un ester d’huile de coco tel que le produit Tegosoft AC (INCI : isoamyl cocoate), vendu par la société EVONIK, le produit DUB VCI 10 (INCI : Isodecyl Neopentanoate) de la société STEARINERIE DUBOIS, le Cetiol OE (INCI : dicaprylyl Ether), le produit Mango butter (INCI : Mangifera Indica (Mango) Seed Butter). Mention will be made, as emollient agent and by way of illustration, of glyceryl stearate (INCI name), MOD (INCI: Octyldodecyl Myristate), the product Lipocire A (INCI: C10-18 Triglycerides), the product Lexfeel NS (INCI: Diheptyl Succinate (and) Capryloyl Glycerin / Sebacic Acid Copolymer), sold by the company INOLEX, the product Labrafac CC (INCI: capric / caprylic triglicerides), sold by the company GATTEFOSSE, a coconut oil ester such as that the product Tegosoft AC (INCI: isoamyl cocoate), sold by the company EVONIK, the product DUB VCI 10 (INCI: Isodecyl Neopentanoate) from the company STEARINERIE DUBOIS, Cetiol OE (INCI: dicaprylyl Ether), the product Mango butter ( INCI: Mangifera Indica (Mango) Seed Butter).
[0191] Parmi les vitamines, on citera le tocophérol, par exemple, le produit Covi-ox® T-70 C (INCI : tocophérol), vendu par la société BASF, qui pourra être utilisé en tant qu’antioxydant. Among the vitamins, mention will be made of tocopherol, for example, the product Covi-ox® T-70 C (INCI: tocopherol), sold by the company BASF, which can be used as an antioxidant.
[0192] L’agent hydratant sera choisi parmi les agents humectants, les agents filmogènes, les agents occlusifs et les agents lyotropes. [0192] The moisturizing agent will be chosen from humectants, film-forming agents, occlusive agents and lyotropic agents.
[0193] Parmi les agents filmogènes, on citera, outre les agents filmogènes décrits précédemment, le collagène, l’élastine, la pectine, la gélatine, le chitosan, les glycosaminoglycanes tels l’acide hyaluronique. [0193] Among the film-forming agents, there will be mentioned, in addition to the film-forming agents described above, collagen, elastin, pectin, gelatin, chitosan, glycosaminoglycans such as hyaluronic acid.
[0194] Parmi les agents occlusifs, on citera la vaseline, la paraffine, l’huile de vaseline, l’huile de germe de blé, le beurre de karité, la cire d’abeille. [0194] Among the occlusive agents, mention will be made of petroleum jelly, paraffin, petrolatum oil, wheat germ oil, shea butter, beeswax.
[0195] Parmi les agents lyotropes, on citera notamment la lanoline et ses dérivés, les céramides, les acides gras essentiels. Among the lyotropic agents, mention will in particular be made of lanolin and its derivatives, ceramides and essential fatty acids.
[0196] Selon un mode de réalisation préféré, l’agent hydratant est un humectant choisi parmi les composés éthoxylés ou les humectants tels que précédemment décrits, préférentiellement le sorbitol. On citera le produit Beauté by Roquette® PO 070 (INCI : Sorbitol) et Beauté by Roquette® PO 160 (INCI : Sorbitol), commercialisés par la société ROQUETTE. [0196] According to a preferred embodiment, the moisturizing agent is a humectant chosen from ethoxylated compounds or humectants as described above, preferably sorbitol. Mention will be made of the product Beauté by Roquette® PO 070 (INCI: Sorbitol) and Beauté by Roquette® PO 160 (INCI: Sorbitol), marketed by the company ROQUETTE.
[0197] Parmi les composés éthoxylés, on citera les produits à base de glucose, d'alcool méthylique et de dérivés de sucre, tels que le produit Glucam™ E-20 Humectant, vendu par la société LUBRIZOL ADVANCED MATERIALS Inc.) [0198] Selon un mode de réalisation, la composition cosmétique ou dermatologique selon l’invention comprend en outre au moins un agent émollient, et/ou au moins un agent sébo-régulateur et/ou au moins un autre agent antibactérien. Among the ethoxylated compounds, mention will be made of products based on glucose, methyl alcohol and sugar derivatives, such as the product Glucam ™ E-20 Humectant, sold by the company LUBRIZOL ADVANCED MATERIALS Inc.) [0198] According to one embodiment, the cosmetic or dermatological composition according to the invention further comprises at least one emollient agent, and / or at least one sebum-regulating agent and / or at least one other antibacterial agent.
[0199] Typiquement, l’actif cosmétique est présent en une teneur allant de 0,1% à 15% en poids, par rapport au poids total de la composition, de préférence de 0,5 à 10% en poids, et de manière encore plus préférée, de 1 à 5% en poids par rapport au poids total de la composition. Typically, the cosmetic active ingredient is present in a content ranging from 0.1% to 15% by weight, relative to the total weight of the composition, preferably from 0.5 to 10% by weight, and so even more preferably, from 1 to 5% by weight relative to the total weight of the composition.
[0200] Additifs [0200] Additives
[0201] La composition selon l'invention peut comprendre d’autres ingrédients pour autant qu'ils n'interfèrent pas avec les propriétés souhaitées de la composition. Ces autres ingrédients peuvent par exemple être des agents de gommage ou d’exfoliation, des agents conservateurs tels que le benzoate de sodium (INCI : Sodium benzoate) comme le produit Microcare NB, vendu par la société Thor, ou l’acide benzoique, ou le sorbate de potassium (INCI : Potassium sorbate), tel que le produit Microcare KS, également vendu par la société Thor, ou l’acide sorbique, des ajusteurs de pH tels l’acide citrique, la soude ou l’arginine, des agents antimicrobiens, des parfums, des filtres solaires, des agents chélatants et leurs mélanges. [0201] The composition according to the invention can comprise other ingredients as long as they do not interfere with the desired properties of the composition. These other ingredients can for example be exfoliation or exfoliation agents, preservatives such as sodium benzoate (INCI: Sodium benzoate) such as the product Microcare NB, sold by the company Thor, or benzoic acid, or potassium sorbate (INCI: Potassium sorbate), such as the product Microcare KS, also sold by the company Thor, or sorbic acid, pH adjusters such as citric acid, soda or arginine, agents antimicrobials, perfumes, sun filters, chelating agents and mixtures thereof.
[0202] Parmi les filtres solaires, on citera à titre illustratif, le Solvaeil XT 300 (INCI : Titanium Dioxide (and) Caprylic/Capric Triglycéride (and) Polyhydroxystearic Acid (and) Stearic Acid (and) Alumina), de la société CRODA, l’EUSOLEX 2292 (INCI: ETHYLHEXYL METHOXYCINNAMATE) ou EUSOLEX T-2000 (INCI : Cl 77891 & ALUMINA & SIMETHICONE) de la société Merck KGaA. [0202] Among the sunscreens, by way of illustration, mention will be made of Solvaeil XT 300 (INCI: Titanium Dioxide (and) Caprylic / Capric Triglycéride (and) Polyhydroxystearic Acid (and) Stearic Acid (and) Alumina), from the company CRODA , EUSOLEX 2292 (INCI: ETHYLHEXYL METHOXYCINNAMATE) or EUSOLEX T-2000 (INCI: Cl 77891 & ALUMINA & SIMETHICONE) from the company Merck KGaA.
[0203] Selon un mode de réalisation, les émulsions, compositions monophasique aqueuse, hydroalcoolique et les compositions solides selon l’invention seront préparées avec des ingrédients « bio-sourcés ». Par « bio-sourcé », on entend un ingrédient dont la masse sèche en atomes de carbone d’origine renouvelable est d’au moins 50%, de préférence d’au moins 80%, et mieux encore d’au moins 90%, en poids par rapport à la masse sèche totale d’atomes de carbone de l’ingrédient. [0203] According to one embodiment, the emulsions, aqueous monophasic compositions, hydroalcoholic and the solid compositions according to the invention will be prepared with "bio-sourced" ingredients. By “bio-sourced” is meant an ingredient whose dry mass in carbon atoms of renewable origin is at least 50%, preferably at least 80%, and better still at least 90%, by weight based on the total dry mass of carbon atoms of the ingredient.
[0204] Les émulsions, compositions monophasique aqueuse, hydroalcoolique et les compositions solides selon l’invention seront préparées par toute technique connue de l’homme du métier. [0204] The emulsions, aqueous, hydroalcoholic single-phase compositions and the solid compositions according to the invention will be prepared by any technique known to those skilled in the art.
[0205] Mode de réalisations particuliers [0205] Specific embodiment
[0206] Selon un mode de réalisation, la composition cosmétique ou dermatologique est une composition monophasique aqueuse composée de, préférentiellement constituée, d’eau, d’un mélange d’acide gluconique et d’acide succinique, et d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum ; les agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange; les agents gélifiants tels que les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux; les tensioactifs tels que les tensioactifs anioniques ou amphotères, les agents sensoriels; les humectants; les émollients; les agents hydratants; les matières colorantes; les agents filmogènes; les agents occlusifs; les agents conditionneurs; les parfums. According to one embodiment, the cosmetic or dermatological composition is an aqueous monophasic composition composed of, preferably consisting of, water, a mixture of gluconic acid and succinic acid, and at least one other ingredient chosen from sebum absorbers; preservatives such as benzoic acid, sorbic acid and their salts or a mixture; gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents; surfactants such as anionic or amphoteric surfactants, sensory agents; humectants; emollients; moisturizers; coloring matters; film-forming agents; occlusive agents; conditioning agents; the perfumes.
[0207] Selon une première variante du mode de réalisation précédent, la composition cosmétique ou dermatologique est composée de : [0207] According to a first variant of the previous embodiment, the cosmetic or dermatological composition is composed of:
- de 40 à 60% en poids d’eau, par rapport au poids total de la composition, - 40 to 60% by weight of water, relative to the total weight of the composition,
- de 0,5 à 5% en poids, par rapport au poids total de la composition d’un mélange d’acide succinique et d’acide gluconique, - from 0.5 to 5% by weight, relative to the total weight of the composition of a mixture of succinic acid and gluconic acid,
- de 5 à 50% en poids, par rapport au poids total de la composition, d’au moins un tensioactif tel que les tensioactifs anioniques ou amphotères, - from 5 to 50% by weight, relative to the total weight of the composition, of at least one surfactant such as anionic or amphoteric surfactants,
- de 0,1 à 10% en poids d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange, les agents gélifiants tels que les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 0.1 to 10% by weight of at least one other ingredient chosen from sebum absorbers, preservatives such as benzoic acid, sorbic acid and their salts or a mixture, gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents, sensory agents, humectants, emollients, moisturizers, coloring matters, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[0208] Selon une deuxième variante du mode de réalisation précédent, la composition cosmétique ou dermatologique est constituée de : According to a second variant of the previous embodiment, the cosmetic or dermatological composition consists of:
- de 40 à 60% en poids d’eau, par rapport au poids total de la composition, - 40 to 60% by weight of water, relative to the total weight of the composition,
- de 0,5 à 5% en poids, par rapport au poids total de la composition d’un mélange d’acide succinique et d’acide gluconique, - from 0.5 to 5% by weight, relative to the total weight of the composition of a mixture of succinic acid and gluconic acid,
- de 5 à 50% en poids, par rapport au poids total de la composition, de un à quatre tensioactifs choisis parmi les tensioactifs anioniques ou amphotères, - from 5 to 50% by weight, relative to the total weight of the composition, from one to four surfactants chosen from anionic or amphoteric surfactants,
- de 0,1 à 10% en poids de un à dix ingrédients choisis parmi les absorbeurs de sébum, les agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange, les agents gélifiants tels que les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. [0209] Selon un autre mode de réalisation, la composition cosmétique ou dermatologique est sous forme de microémulsion, et est composée, préférentiellement constituée : - from 0.1 to 10% by weight of one to ten ingredients chosen from sebum absorbers, preservatives such as benzoic acid, sorbic acid and their salts or a mixture, gelling agents such as agents hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents, sensory agents, humectants, emollients, hydrating agents, coloring matters, film-forming agents, occlusive agents, conditioning agents , perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%. According to another embodiment, the cosmetic or dermatological composition is in the form of a microemulsion, and is composed, preferably consisting of:
- d’eau, - water,
- de une à trois huiles, - from one to three oils,
- d’un mélange d’acide succinique et d’acide gluconique, - a mixture of succinic acid and gluconic acid,
- de un à quatre tensioactifs choisis parmi les tensioactifs anioniques ou les tensioactifs amphotères ou zwitterioniques, - from one to four surfactants chosen from anionic surfactants or amphoteric or zwitterionic surfactants,
- de un à dix ingrédients choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums. - from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizing agents, coloring materials, film-forming agents, occlusive agents, conditioning agents , the perfumes.
[0210] Selon une variante du mode de réalisation précédent, la composition cosmétique ou dermatologique est sous forme d’une microémulsion est composée, préférentiellement constituée : [0210] According to a variant of the previous embodiment, the cosmetic or dermatological composition is in the form of a microemulsion is composed, preferably constituted:
- de 40 à 60% en poids d’eau, par rapport au poids total de la composition - 40 to 60% by weight of water, relative to the total weight of the composition
- de 0,5 à 5% en poids, par rapport au poids total de la composition, d’une à trois huiles,- from 0.5 to 5% by weight, relative to the total weight of the composition, of one to three oils,
- de 0,5 à 5% en poids, par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique, - from 0.5 to 5% by weight, relative to the total weight of the composition, of a mixture of succinic acid and gluconic acid,
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à quatre tensioactifs choisi parmi les tensioactifs anioniques ou les tensioactifs amphotères ou zwitterioniques, - from 5 to 50% by weight, relative to the total weight of the composition, from one to four surfactants chosen from anionic surfactants or amphoteric or zwitterionic surfactants,
- de 0,1 à 10% en poids, par rapport au poids total de la composition, d’un à dix ingrédients choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients , moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[0211] Selon un autre mode de réalisation, la composition cosmétique ou dermatologique est sous une forme monophasique solide, et est composée : [0211] According to another embodiment, the cosmetic or dermatological composition is in a solid monophasic form, and is composed:
- d’eau, - water,
- d’au moins une huile, - at least one oil,
- d’au moins une cire, ou d’un beurre végétal, ou leur mélange, - at least one wax, or vegetable butter, or a mixture thereof,
- d’un mélange d’acide succinique et d’acide gluconique, , - a mixture of succinic acid and gluconic acid,,
- d’au moins un tensioactif choisi parmi les tensioactifs anioniques ou amphotères,- at least one surfactant chosen from anionic or amphoteric surfactants,
- d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums. - at least one other ingredient chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes.
[0212] Selon une variante du mode de réalisation précédent, la composition cosmétique ou dermatologique est composée, préférentiellement constituée : [0212] According to a variant of the previous embodiment, the cosmetic or dermatological composition is composed, preferably constituted:
- de moins de 20% en poids, par rapport au poids total de la composition, d’eau, - less than 20% by weight, relative to the total weight of the composition, of water,
- de 10 à 60% en poids, par rapport au poids total de la composition, d’une à trois huiles,- from 10 to 60% by weight, relative to the total weight of the composition, of one to three oils,
- de 1 à 30% en poids, par rapport au poids total de la composition, d’une ou deux cires, ou d’un ou deux beurres végétaux, ou leurs mélanges, - from 1 to 30% by weight, relative to the total weight of the composition, of one or two waxes, or of one or two vegetable butters, or mixtures thereof,
- de 0,5 à 5% en poids par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique - from 0.5 to 5% by weight relative to the total weight of the composition, of a mixture of succinic acid and gluconic acid
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à six tensioactifs choisis parmi les tensioactifs anioniques, ou les tensioactifs amphotères ou zwitterioniques, - from 5 to 50% by weight, relative to the total weight of the composition, from one to six surfactants chosen from anionic surfactants, or amphoteric or zwitterionic surfactants,
- de 0,1 à 10% en poids, par rapport au poids total de la composition, d’un à dix ingrédients choisis parmi les absorbeurs de sébum, agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[0213] Selon un autre mode de réalisation, la composition cosmétique ou dermatologique est sous une forme monophasique solide, et est composée : [0213] According to another embodiment, the cosmetic or dermatological composition is in a solid monophasic form, and is composed:
- d’eau, - water,
- d’un mélange d’acide succinique et d’acide gluconique, - a mixture of succinic acid and gluconic acid,
- d’au moins un tensioactif choisi parmi les tensioactifs anioniques ou amphotères,- at least one surfactant chosen from anionic or amphoteric surfactants,
- d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, ladite composition comprenant en outre l’acide laurique, ou l’acide stéarique, ou leur mélange. - at least one other ingredient chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizing agents, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, said composition further comprising lauric acid, or stearic acid, or a mixture thereof.
[0214] Selon une variante du mode de réalisation précédent, la composition cosmétique ou dermatologique est composée : [0214] According to a variant of the previous embodiment, the cosmetic or dermatological composition is composed:
- de moins de 20% en poids, par rapport au poids total de la composition, d’eau, - less than 20% by weight, relative to the total weight of the composition, of water,
- de 0,5 à 5% en poids par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique - from 0.5 to 5% by weight relative to the total weight of the composition, of a mixture of succinic acid and gluconic acid
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à six tensioactifs choisis parmi les tensioactifs anioniques, ou les tensioactifs amphotères ou zwitterioniques, - from 5 to 50% by weight, relative to the total weight of the composition, from one to six surfactants chosen from anionic surfactants, or amphoteric surfactants or zwitterionics,
- de 0,1 à 10% en poids , par rapport au poids total de la composition, d’un à dix ingrédients choisis parmi les absorbeurs de sébum, agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums - from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes
- de 1 à 20% en poids par rapport au poids total de la composition d’acide laurique et de 1 à 20% en poids par rapport au poids total de la composition d’acide stéarique, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 1 to 20% by weight relative to the total weight of the lauric acid composition and from 1 to 20% by weight relative to the total weight of the stearic acid composition, the sum of the percentages by weight of all the ingredients being equal to 100%.
[0215] Procédé de nettoyage et/ou de démaquillage des matières kératiniques[0215] Process for cleaning and / or removing make-up from keratin materials
[0216] L’invention a également pour objet un procédé de nettoyage et/ou de démaquillage des matières kératiniques, en particulier la peau, le cuir chevelu ou les cheveux, consistant à appliquer sur lesdites matières kératiniques, en particulier la peau, une composition cosmétique selon l’invention. [0216] A subject of the invention is also a process for cleansing and / or removing make-up from keratin materials, in particular the skin, the scalp or the hair, consisting in applying to said keratin materials, in particular the skin, a composition cosmetic according to the invention.
[0217] Selon un mode de réalisation du procédé de nettoyage et/ou démaquillage des matières kératiniques, ledit procédé comprend une étape supplémentaire et finale de rinçage, préférentiellement à l’eau. [0217] According to one embodiment of the process for cleaning and / or removing make-up from keratin materials, said process comprises an additional and final step of rinsing, preferably with water.
[0218] Selon un mode de réalisation du procédé de nettoyage et/ou démaquillage des matières kératiniques, ledit procédé est un procédé dit « d’application rincée », qui comprend les étapes : [0218] According to one embodiment of the process for cleansing and / or removing make-up from keratin materials, said process is a so-called "rinsed application" process, which comprises the steps:
- d’application de la composition cosmétique ou dermatologique, - application of the cosmetic or dermatological composition,
- puis de pose de la composition cosmétique ou dermatologique sur les matières kératiniques où elle a été appliquée pendant un temps allant de 5 secondes ou 10 secondes à 2 minutes, ou 5 minutes, ou 10 minutes, ou pendant le temps nécessaire à l’utilisateur pour terminer l’application, - then applying the cosmetic or dermatological composition to the keratin materials where it has been applied for a time ranging from 5 seconds or 10 seconds to 2 minutes, or 5 minutes, or 10 minutes, or for the time required by the user to end the application,
- puis de rinçage des matières kératiniques, préférentiellement à l’eau, pour éliminer la composition cosmétique ou dermatologique. - then rinsing the keratin materials, preferably with water, to remove the cosmetic or dermatological composition.
[0219] Le terme « application rincée », par opposition au terme « sans rinçage », est utilisé dans le présent document pour signifier que les compositions de la présente invention sont utilisées dans un contexte dans lequel la composition est finalement rincée ou lavée des cheveux ou la peau après ou pendant l'application du produit Un produit « sans rinçage » fait référence à une composition qui est appliquée sur les cheveux ou la peau et non soumise à une étape de rinçage. The term "rinsed application", as opposed to the term "without rinsing", is used in the present document to mean that the compositions of the present invention are used in a context in which the composition is finally rinsed or washed from the hair. or the skin after or during the application of the product A “leave-in” product refers to a composition which is applied to the hair or the skin and not subjected to a rinsing step.
[0220] Utilisation cosmétique pour prévenir, réduire ou éliminer les imperfections cutanées [0221] La présente invention a également pour objet l’utilisation cosmétique non thérapeutique d’une composition selon l’invention pour prévenir, réduire ou éliminer les imperfections cutanées. [0220] Cosmetic use for preventing, reducing or eliminating skin imperfections [0221] A subject of the present invention is also the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing or eliminating skin imperfections.
[0222] Les imperfections cutanées s’entendent d’inconvénients esthétiques et sont à distinguer des troubles cutanés pathologiques. Parmi les imperfections cutanées, on citera la peau grasse, la peau luisante, la peau brillante, les pores dilatés, un grain de peau épais, des rougeurs, des démangeaisons, la perte d’éclat, la peau terne. [0222] Skin imperfections are understood as aesthetic drawbacks and are to be distinguished from pathological skin disorders. Skin imperfections include oily skin, shiny skin, shiny skin, large pores, thick skin texture, redness, itching, loss of radiance, dull skin.
[0223] Utilisation cosmétique pour nettoyer et/ou démaquiller [0223] Cosmetic use for cleaning and / or removing make-up
[0224] La présente invention a également pour objet l’utilisation cosmétique non thérapeutique d’une composition cosmétique ou dermatologique selon l’invention, pour nettoyer et/ou démaquiller les peaux ayant des imperfections cutanées ou des troubles cutanés tels que l’acné. [0224] A subject of the present invention is also the non-therapeutic cosmetic use of a cosmetic or dermatological composition according to the invention, for cleaning and / or removing make-up from skin having skin imperfections or skin disorders such as acne.
[0225] Traitement de l’acné [0225] Acne treatment
[0226] La présente invention concerne également une composition selon l’invention pour son utilisation dans le traitement des troubles cutanés tels que l’acné. [0226] The present invention also relates to a composition according to the invention for its use in the treatment of skin disorders such as acne.
[0227] La présente invention concerne également l’utilisation d’une composition selon l’invention pour le traitement des troubles cutanés tels que l’acné. [0227] The present invention also relates to the use of a composition according to the invention for the treatment of skin disorders such as acne.
[0228] La présente invention concerne également l’utilisation d’une composition selon l’invention pour l’obtention d’un médicament destiné au traitement des troubles cutanés tels que l’acné. [0228] The present invention also relates to the use of a composition according to the invention for obtaining a medicament intended for the treatment of skin disorders such as acne.
[0229] La présente invention concerne également une méthode de traitement thérapeutique des troubles cutanés tels que l’acné, comprenant l’administration d’une composition selon l’invention à un patient en ayant besoin. [0229] The present invention also relates to a method of therapeutic treatment of skin disorders such as acne, comprising the administration of a composition according to the invention to a patient in need thereof.
[0230] Les troubles cutanés tels que l’acné sont à distinguer des imperfections cutanées qui provoquent uniquement des désagréments esthétiques. L’acné est une maladie inflammatoire chronique du follicule pilo sébacé dans laquelle intervient quatre facteurs qui sont étroitement liés : une hyper séborrhée, une hyperkératinisation, la prolifération de Propionobacterium acnés et une inflammation. [0230] Skin disorders such as acne should be distinguished from skin imperfections which only cause aesthetic inconvenience. Acne is a chronic inflammatory disease of the pilosebaceous follicle in which four closely related factors occur: hyperseborrhea, hyperkeratinization, proliferation of Propionobacterium acnes and inflammation.
[0231] Avantageusement, la composition selon l’invention permet de traiter les troubles cutanés résultant d’une hyperséborrhée et/ou d’une hyperkératinisation et/ou de la prolifération des bactéries du genre Propionobacterium spp et/ou d’une inflammation[0231] Advantageously, the composition according to the invention makes it possible to treat skin disorders resulting from hyperseborrhea and / or hyperkeratinization and / or proliferation of bacteria of the genus Propionobacterium spp and / or inflammation
[0232] On distingue donc i) les imperfections cutanées cosmétiques correspondant à une peau grasse caractérisée par une production ou surproduction de sébum (séborrhée et hyper séborrhée) donnant à la peau un aspect gras et luisant. Le grain de peau est plus épais et les pores dilatés ce qui donne l’aspect d’un teint terne puisque la peau réfléchit moins bien la lumière. Des imperfections de types boutons rouges et des points noirs peuvent apparaître occasionnellement. Dans le cas d’une peau mixte, la brillance est surtout localisée sur la partie médiane du visage : front, nez, menton, communément appelée la zone T ; ii) les troubles cutanés pathologiques qui résultent de la présence et/ou de la prolifération des bactéries du genre Propionobacterium spp., préférentiellement de Propionobacterium Acnés et/ou d’une inflammation, et/ou d’une hyperkératinisation et/ou d’une hyper séborrhée. Une peau à tendance acnéique souffre également de brillances cutanées, de pores dilatés mais les boutons et les points noirs persistent et les poussées sont fréquentes. [0232] A distinction is therefore made between i) cosmetic skin imperfections corresponding to oily skin characterized by production or overproduction of sebum (seborrhea and hyperseborrhea) giving the skin looks greasy and shiny. The skin texture is thicker and the pores dilated which gives the appearance of a dull complexion since the skin reflects less light. Occasionally, blemishes such as red pimples and blackheads may appear. In the case of combination skin, the shine is mainly localized on the middle part of the face: forehead, nose, chin, commonly called the T zone; ii) pathological skin disorders which result from the presence and / or proliferation of bacteria of the genus Propionobacterium spp., preferably of Propionobacterium Acnes and / or inflammation, and / or hyperkeratinization and / or hyper seborrhea. Acne-prone skin also suffers from skin shine and enlarged pores, but pimples and blackheads persist and breakouts are frequent.
[0233] Les termes « traitement » ou « méthode de traitement » ne sont pas des termes absolus et ; lorsqu’ils sont appliqués à l’acné, ils désignent une procédure ou un plan d’action conçu, même avec une probabilité faible de succès mais devant induire un effet bénéfique global tel que le retard de l’apparition de la pathologie, ou la diminution de la gravité d’un ou plusieurs symptômes ou la stabilisation de la pathologie. The terms "treatment" or "method of treatment" are not absolute terms and; when applied to acne, they denote a procedure or a plan of action designed, even with a low probability of success but having to induce an overall beneficial effect such as the delay in the onset of the pathology, or the decrease in the severity of one or more symptoms or stabilization of the pathology.
[0234] Typiquement, dans le cas de l’acné, le traitement d’entend du retard de l’apparition ou la diminution de la gravité voir de la disparition des troubles cutanés tels que les comédons, et/ou des lésions inflammatoires superficielles papules et pustules) et profondes (nodules), et/ou de la prolifération de Propionobacterium acnés. [0234] Typically, in the case of acne, the treatment means the delay in the onset or the reduction in severity or even the disappearance of skin disorders such as comedones, and / or superficial inflammatory lesions papules and pustules) and deep (nodules), and / or the proliferation of Propionobacterium acnes.
[0235] Hyper séborrhée du cuir chevelu [0235] Hyper seborrhea of the scalp
[0236] Les cheveux normaux correspondent à des cheveux doux au toucher, souples, qui se démêlent et se coiffent facilement, d’aspect brillant et qui ne se cassent pas. Egalement, le cuir chevelu est sain, sans pellicules, irritations ou rougeurs. Dans ce cas, les glandes sébacées fonctionnent normalement, sécrétant une petite quantité de sébum afin de protéger le cuir chevelu et de lubrifier les cheveux. Cependant, il arrive qu’elles subissent un déséquilibre interne ou provoqué par des agressions extérieures, entraînant alors des troubles de la production de sébum. L’hyper séborrhée est un phénomène physiologique se traduisant par une production excessive de sébum. Le sébum sécrété en excès s’étale sur le cuir chevelu, mais il se répand aussi le long de la tige des cheveux, les rendant gras et lourds. La quantité de sébum présente sur le cuir chevelu peut être mesurée par divers appareils connus de l’Homme du métier. La plupart sont basés sur le fait d’appliquer une plaque translucide contre le cuir chevelu pour récolter le sébum présent puis de mesurer la quantité de lumière transmise à travers la plaque. [0237] Utilisation cosmétique pour prévenir, réduire ou éliminer les états hyper séborrhéiques cosmétiques du cuir chevelu [0236] Normal hair corresponds to hair that is soft to the touch, supple, which disentangles and combs easily, has a shiny appearance and does not break. Also, the scalp is healthy, without dandruff, irritation or redness. In this case, the sebaceous glands are functioning normally, secreting a small amount of sebum in order to protect the scalp and lubricate the hair. However, it happens that they undergo an internal imbalance or caused by external aggressions, then causing disturbances in the production of sebum. Hyper seborrhea is a physiological phenomenon resulting in excessive production of sebum. The excess secreted sebum spreads over the scalp, but it also spreads down the hair shaft, making it greasy and heavy. The amount of sebum present on the scalp can be measured by various devices known to those skilled in the art. Most are based on applying a translucent plate against the scalp to collect the sebum present and then measuring the amount of light transmitted through the plate. [0237] Cosmetic use for preventing, reducing or eliminating cosmetic hyperseborrheic states of the scalp
[0238] L’invention concerne l’utilisation cosmétique non thérapeutique d’une composition selon l’invention pour prévenir, réduire, ou éliminer les états hyper séborrhéiques cosmétiques du cuir chevelu. [0238] The invention relates to the non-therapeutic cosmetic use of a composition according to the invention for preventing, reducing, or eliminating cosmetic hyperseborrheic states of the scalp.
[0239] Les états hyper séborrhéiques cosmétiques du cuir chevelu s’entendent des cheveux gras leurs inconvénients esthétiques. On citera des cheveux lourds, ternes, luisant, sales, collants, difficiles à coiffer. Ils sont à distinguer des états hyperséborrhéiques pathologiques du cuir chevelu. [0239] Cosmetic hyperseborrheic conditions of the scalp refer to oily hair and their aesthetic drawbacks. We will mention heavy hair, dull, shiny, dirty, sticky, difficult to comb. They are to be distinguished from pathological hyperseborrheic states of the scalp.
[0240] Traitement des états hyper séborrhéiques pathologiques du cuir chevelu[0240] Treatment of pathological hyper seborrheic states of the scalp
[0241] L’invention concerne également une composition selon l’invention pour son utilisation dans le traitement des états hyper séborrhéiques pathologiques du cuir chevelu. [0241] The invention also relates to a composition according to the invention for its use in the treatment of pathological hyperseborrheic states of the scalp.
[0242] La présente invention concerne également l’utilisation d’une composition selon l’invention pour le traitement des états hyper séborrhéiques pathologiques du cuir chevelu. [0242] The present invention also relates to the use of a composition according to the invention for the treatment of pathological hyperseborrheic states of the scalp.
[0243] La présente invention concerne également l’utilisation d’une composition selon l’invention pour l’obtention d’un médicament destiné au traitement des états hyper séborrhéiques pathologiques du cuir chevelu. [0243] The present invention also relates to the use of a composition according to the invention for obtaining a medicament intended for the treatment of pathological hyperseborrheic states of the scalp.
[0244] La présente invention concerne également une méthode de traitement thérapeutique des états hyper séborrhéiques pathologiques du cuir chevelu, comprenant l’administration d’une composition selon l’invention chez un patient en ayant besoin. [0244] The present invention also relates to a method of therapeutic treatment of pathological hyperseborrheic states of the scalp, comprising the administration of a composition according to the invention to a patient in need thereof.
[0245] On citera parmi les états hyper séborrhéiques pathologiques du cuir chevelu la dermatite séborrhéique ou l’alopécie séborrhéique. [0245] Among the pathological hyperseborrheic conditions of the scalp, we will mention seborrheic dermatitis or seborrheic alopecia.
[0246] Les termes « traitement » ou « méthode de traitement » ne sont pas des termes absolus et ; lorsqu’ils sont appliqués à la dermatite séborrhéique ou l’alopécie séborrhéique, ils désignent une procédure ou un plan d’action conçu, même avec une probabilité faible de succès mais devant induire un effet bénéfique global tel que le retard de l’apparition de la pathologie, ou la diminution de la gravité d’un ou plusieurs symptômes ou la stabilisation de la pathologie. The terms "treatment" or "method of treatment" are not absolute terms and; when applied to seborrheic dermatitis or seborrheic alopecia, they denote a procedure or course of action designed, even with a low probability of success but expected to induce an overall beneficial effect such as delaying the onset of the pathology, or the reduction in the severity of one or more symptoms or the stabilization of the pathology.
[0247] Typiquement, dans le cas de la dermatite séborrhéique, le traitement d’entend du retard de l’apparition ou la diminution de la gravité voir de la disparition des plaques rouges, recouvertes de pellicules blanches ou jaunâtres sur les zones grasses du cuir chevelu survenant sur une peau séborrhéique. [0248] Typiquement, dans le cas de l’alopécie séborrhéique, le traitement s’entend du retard ou de la diminution de la chute de cheveu voir de la disparition de la chute des cheveux. [0247] Typically, in the case of seborrheic dermatitis, the treatment means the delay in the onset or the reduction in severity or even the disappearance of red patches, covered with white or yellowish films on the fatty areas of the leather. scalp occurring on seborrheic skin. Typically, in the case of seborrheic alopecia, the treatment is understood to mean the delay or reduction of hair loss, or even the disappearance of hair loss.
[0249] Ainsi, on distingue donc : i) les états hyper séborrhéiques cosmétiques du cuir chevelu qui sont des désordres uniquement esthétiques et qui se caractérisent par des cheveux gras, des cheveux lourds, ternes, luisants, sales, collants, difficiles à coiffer, et ii) les états hyper séborrhéiques pathologiques du cuir chevelu que peuvent être la dermatite séborrhéique ou l’alopécie séborrhéique. Exemples [0249] Thus, we therefore distinguish: i) cosmetic hyper seborrheic states of the scalp which are purely aesthetic disorders and which are characterized by greasy hair, heavy hair, dull, shiny, dirty, sticky, difficult to comb, and ii) pathological hyperseborrheic conditions of the scalp which may be seborrheic dermatitis or seborrheic alopecia. Examples
[0250] Exemple 1 : gel douche [0250] Example 1: shower gel
[0251] Dans cet exemple, une composition sous forme d’émulsion huile-dans-eau dont la composition est reproduite dans le tableau 1 ci-après, sous forme de gel douche pour le nettoyage est préparée. In this example, a composition in the form of an oil-in-water emulsion, the composition of which is reproduced in Table 1 below, in the form of a shower gel for cleaning is prepared.
[0252] Tableau 11
Figure imgf000035_0001
[0252] Table 11
Figure imgf000035_0001
[0253] On prépare la phase A1 en mélangeant les ingrédients de la phase A1 sous agitation en chauffant à 80°C pendant 40 minutes. Toujours sous agitation, on ajoute la phase A2 dans la phase A1 en maintenant 80°C. A part, on prépare la phase B en mélangeant les ingrédients de la phase B sous agitation à 80°C. On ajoute ensuite la phase B dans la phase A1+A2, sous agitation, à 80°C, pendant 10 minutes. On refroidit à 25°C, puis on ajoute les phases C et D. Enfin, on ajuste le pH à une valeur supérieure ou égale à 4,6 en utilisant les ingrédients de la phase E. [0254] Exemple 2 : nettoyant pour le visage Phase A1 is prepared by mixing the ingredients of phase A1 with stirring, heating at 80 ° C. for 40 minutes. Still with stirring, phase A2 is added to phase A1 while maintaining 80 ° C. Separately, phase B is prepared by mixing the ingredients of phase B with stirring at 80 ° C. Phase B is then added to phase A1 + A2, with stirring, at 80 ° C. for 10 minutes. The mixture is cooled to 25 ° C., then phases C and D are added. Finally, the pH is adjusted to a value greater than or equal to 4.6 using the ingredients of phase E. [0254] Example 2: facial cleanser
[0255] Dans cet exemple, une composition cosmétique pour le nettoyage et le démaquillage sous forme de solution monophasique aqueuse est préparée. Sa composition est décrite dans le tableau 2 ci-après. [0256] [Tableau 2]
Figure imgf000036_0001
In this example, a cosmetic composition for cleansing and removing makeup in the form of an aqueous single-phase solution is prepared. Its composition is described in Table 2 below. [0256] [Table 2]
Figure imgf000036_0001
[0257] On prépare la phase A en mélangeant les ingrédients à 80°C pendant 40 minutes, puis on refroidit à 25° et on ajoute la phase B. on ajuste le pH à une valeur supérieure ou égale à 4,6 en utilisant la gluconolactone et l’hydroxyde de sodium. Phase A is prepared by mixing the ingredients at 80 ° C for 40 minutes, then cooled to 25 ° and phase B is added. The pH is adjusted to a value greater than or equal to 4.6 using the gluconolactone and sodium hydroxide.
[0258] Exemple 3 : nettoyant clarifiant [0259] Dans cet exemple, on prépare un gel fluide nettoyant et clarifiant pour la peau. [0258] Example 3: Clarifying Cleanser [0260] In this example, a cleansing and clarifying fluid gel for the skin is prepared.
[0260] [Tableau 3]
Figure imgf000037_0001
[0260] [Table 3]
Figure imgf000037_0001
[0261] Toute la préparation est réalisée à température ambiante. On mélange rhydroxypropylmethylcellulose et le sorbitol dans de l’eau, sous agitation douce. On ajoute l’amidon carboxyméthylé sous agitation douce jusqu’à ce que cet amidon soit hydraté. On ajoute ensuite successivement les ingrédients B et C, puis on attend leur dissolution complète. On ajoute ensuite successivement l’ingrédient D, puis on attend sa dissolution complète. On ajoute ensuite l’ingrédient E, puis on attend sa dissolution complète. Finalement, on ajoute les ingrédients F, G et H. The entire preparation is carried out at room temperature. The hydroxypropylmethylcellulose and sorbitol are mixed in water, with gentle stirring. The carboxymethylated starch is added with gentle stirring until this starch is hydrated. Ingredients B and C are then added successively, and then one waits for their complete dissolution. Ingredient D is then added successively, and then waited for its complete dissolution. Next, ingredient E is added, and then waits for complete dissolution. Finally, we add the ingredients F, G and H.
[0262] Exemple 4 : shampoing [0263] Dans cet exemple, on prépare un shampoing. [0262] Example 4: shampoo [0263] In this example, a shampoo is prepared.
[0264] [Tableau 4]
Figure imgf000038_0001
l’ingrédient C, et on attend jusqu’à dispersion homogène. On ajoute ensuite les ingrédients D à I successivement sous agitation douce jusqu’à obtenir un mélange homogène. On ajuste le pH à 4, 6-4, 8 avec une solution concentrée de soude.
[0264] [Table 4]
Figure imgf000038_0001
ingredient C, and wait until homogeneous dispersion. Ingredients D to I are then added successively with gentle stirring until a homogeneous mixture is obtained. The pH is adjusted to 4.6-4.8 with a concentrated sodium hydroxide solution.
[0266] Exemple 5 : barres nettoyantes pour le corps [0266] Example 5: cleansing bars for the body
[0267] Dans cet exemple, on prépare trois compositions solides pour nettoyer le corps, appelées « barres nettoyantes pour le corps ». In this example, three solid compositions are prepared for cleansing the body, called "body cleansing bars".
[0268] [Tableau 5]
Figure imgf000039_0001
[0268] [Table 5]
Figure imgf000039_0001
[0269] On chauffe la phase A jusqu’à 85-90°C, puis on homogénéise pendant un court instant. On refroidit jusqu’à 75-80°C sous agitation, puis on ajoute les ingrédients B à E successivement sous agitation. On transfert dans un moule, puis on laisse refroidir à température ambiante. [0269] Phase A is heated to 85-90 ° C, then homogenized for a short time. Cool to 75-80 ° C with stirring, then add ingredients B to E successively with stirring. It is transferred to a mold and then allowed to cool to room temperature.
[0270] [Tableau 6]
Figure imgf000039_0002
[0271] On chauffe la phase A jusqu’à 85-90°C, puis on homogénéise pendant un court instant. On refroidit jusqu’à 75-80°C sous agitation, puis on ajoute les ingrédients B à E successivement sous agitation. On transfert dans un moule, puis on laisse refroidir à température ambiante. [0272] [Tableau 7]
Figure imgf000040_0001
[0270] [Table 6]
Figure imgf000039_0002
Phase A is heated to 85-90 ° C, then homogenized for a short time. Cooled to 75-80 ° C with stirring, then ingredients B to E are added successively with stirring. It is transferred to a mold and then allowed to cool to room temperature. [0272] [Table 7]
Figure imgf000040_0001
[0273] On prépare la phase B à part dans un bol sous agitation douce. Puis on ajoute a phase B dans la phase A, et on mélange jusqu’à obtention d’un mélange homogène. On ajoute ensuite les ingrédients C à H successivement, en laissant le temps pour avoir une dispersion homogène. On place ensuite le mélange obtenu dans un moule, et on laisse reposer à température ambiante pendant 24 heures. On obtient une barre de « savon » avec des aiguilles de sodium coco-sulfate visibles. Phase B is prepared separately in a bowl with gentle stirring. Then phase B is added to phase A, and mixed until a homogeneous mixture is obtained. Ingredients C to H are then added successively, allowing time to have a homogeneous dispersion. The mixture obtained is then placed in a mold, and it is left to stand at room temperature for 24 hours. A bar of "soap" is obtained with visible sodium coco-sulfate needles.
[0274] Exemple 6 : nettoyant douche pour le visage et le corps [0274] Example 6: shower cleanser for the face and the body
[0275] Dans cet exemple, on prépare quatre nettoyants douche sous des formes de fluidité différente : liquide, gel fluide et gel épais. [0276] [Tableau 8] : nettoyant gel fluide 1
Figure imgf000041_0001
In this example, four shower cleansers are prepared in different fluidity forms: liquid, fluid gel and thick gel. [0276] [Table 8]: fluid gel cleaner 1
Figure imgf000041_0001
[0277] Dans l’eau chauffée à 65°C, on ajoute lentement le magnésium aluminium silicate and la gomme de xanthane l’un après l’autre sous agitation cisaillante pour bien disperser. On maintient sous agitation jusqu’à hydratation complète. On maintient à 65°C, et on ajoute les ingrédients B. Puis on refroidit à température ambiante. On ajoute alors les ingrédients C à F en suivant l’ordre du tableau 8, en attendant la dispersion complète entre chaque ajout, en évitant l’incorporation d’air. On ajuste finalement à pH 4, 6-4, 8 avec une solution de soude concentrée. [0277] In water heated to 65 ° C., the magnesium aluminum silicate and the xanthan gum are slowly added one after the other with shearing stirring in order to disperse well. Stirring is maintained until complete hydration. Maintain at 65 ° C, and add the ingredients B. Then cool to room temperature. Ingredients C to F are then added following the order of Table 8, while awaiting complete dispersion between each addition, avoiding the incorporation of air. It is finally adjusted to pH 4, 6-4, 8 with a concentrated sodium hydroxide solution.
[0278] [Tableau 9] : nettoyant liquide
Figure imgf000042_0001
[0278] [Table 9]: liquid cleaner
Figure imgf000042_0001
[0279] On ajoute l’ingrédient B à la phase A, puis l’ingrédient C, sous agitation, et on chauffe à 60°C. On refroidit ensuite à température ambiante, puis on ajoute les phases D à I successivement sous agitation. [0280] [Tableau 10] : gel épais
Figure imgf000042_0002
Ingredient B is added to phase A, then ingredient C, with stirring, and the mixture is heated to 60 ° C. It is then cooled to room temperature, then phases D to I are added successively with stirring. [0280] [Table 10]: thick gel
Figure imgf000042_0002
[0281] On prépare un nettoyant gel épais en utilisant les ingrédients du tableau 10. [0282] [Tableau 11] : nettoyant gel fluide 2
Figure imgf000043_0001
[0281] A thick gel cleanser is prepared using the ingredients of Table 10. [0282] [Table 11]: fluid gel cleaner 2
Figure imgf000043_0001
[0283] On prépare un nettoyant gel fluide en utilisant les ingrédients du tableau 11. [0284] Exemple 7 : poudre effervescente pour le bain [0283] A fluid gel cleanser is prepared using the ingredients of Table 11. [0284] Example 7: effervescent powder for the bath
[0285] Dans cet exemple, on prépare des poudres effervescentes pour le bain. [0286] [Tableau 12] : poudre effervescente 1
Figure imgf000043_0002
In this example, effervescent powders for the bath are prepared. [0286] [Table 12]: effervescent powder 1
Figure imgf000043_0002
[0287] On prépare une poudre effervescente pour le bain selon le tableau 12. [0288] Tableau 13] : poudre effervescente 2
Figure imgf000044_0001
An effervescent powder for the bath is prepared according to Table 12. [0288] Table 13]: effervescent powder 2
Figure imgf000044_0001
[0289] On prépare une poudre effervescente pour le bain selon le tableau 13. An effervescent powder for the bath is prepared according to Table 13.
[0290] Exemple 8 : poudres pour le bain [0290] Example 8: powders for the bath
[0291] Dans cet exemple, on prépare deux « poudres additifs » pour le bain ; et une « poudre moussante » pour le bain. In this example, two “additive powders” are prepared for the bath; and a "foaming powder" for the bath.
[0292] [Tableau 14] : poudre additif pour le bain 1
Figure imgf000044_0002
[0292] [Table 14]: additive powder for bath 1
Figure imgf000044_0002
[0293] On prépare une poudre effervescente pour le bain selon le tableau 14. [0294] Tableau 15] : poudre additif pour le bain 2
Figure imgf000045_0001
Figure imgf000045_0002
An effervescent powder for the bath is prepared according to Table 14. [0294] Table 15]: additive powder for bath 2
Figure imgf000045_0001
Figure imgf000045_0002
[0297] On prépare une poudre moussante pour le bain selon le tableau 16. [0298] Exemple 9 : nettoyant gommant pour le visage et le corps [0297] A foaming powder for the bath is prepared according to Table 16. [0298] Example 9: exfoliating cleanser for the face and the body
[0299] Dans cet exemple, on prépare trois gels nettoyant et gommant pour le visage et le corps. [0300] [Tableau 17] : gel nettoyant et gommant 1
Figure imgf000046_0001
In this example, three cleansing and exfoliating gels are prepared for the face and the body. [0300] [Table 17]: cleansing and exfoliating gel 1
Figure imgf000046_0001
[0301] On prépare un gel nettoyant et gommant fluide selon le tableau 17. A fluid cleansing and exfoliating gel is prepared according to Table 17.
[0302] [Tableau 18] : gel nettoyant et gommant 2
Figure imgf000047_0001
[0302] [Table 18]: cleansing and exfoliating gel 2
Figure imgf000047_0001
[0303] On prépare un gel nettoyant et gommant fluide selon le tableau 18. [0304] [Tableau 19] : gel nettoyant et gommant 3
Figure imgf000047_0002
A fluid cleansing and exfoliating gel is prepared according to Table 18. [0304] [Table 19]: cleansing and exfoliating gel 3
Figure imgf000047_0002
[0305] On prépare un gel nettoyant et gommant fluide selon le tableau 19. [0306] Exemple 10 : crème ou lotion « sous la douche » pour le corps A fluid cleansing and exfoliating gel is prepared according to Table 19. [0306] Example 10: “in the shower” cream or lotion for the body
[0307] Dans cet exemple, on prépare trois lotions à utiliser sous la douche, et une crème à utiliser sous la douche avec rinçage après utilisation. In this example, three lotions are prepared for use in the shower, and one cream for use in the shower with rinsing after use.
[0308] [Tableau 20] : lotion sous la douche 1
Figure imgf000048_0001
[0309] On prépare une « lotion sous la douche » selon le tableau 20, sous la forme d’une crème blanche.
[0308] [Table 20]: lotion in the shower 1
Figure imgf000048_0001
A "shower lotion" according to Table 20 is prepared in the form of a white cream.
[0310] [Tableau 21] : lotion sous la douche 2
Figure imgf000049_0001
[0310] [Table 21]: lotion in the shower 2
Figure imgf000049_0001
[0311] On prépare une « lotion sous la douche » selon le tableau 21, sous la forme d’une crème blanche. A "shower lotion" according to Table 21 is prepared in the form of a white cream.
[0312] [Tableau 22] : lotion sous la douche 3
Figure imgf000050_0001
[0312] [Table 22]: lotion in the shower 3
Figure imgf000050_0001
[0313] On prépare une « lotion sous la douche » selon le tableau 22, sous la forme d’une crème blanche. [0314] [Tableau 23] : crème sous la douche
Figure imgf000051_0001
[0313] A "shower lotion" according to Table 22 is prepared in the form of a white cream. [0314] [Table 23]: cream in the shower
Figure imgf000051_0001
[0315] On prépare une « crème sous la douche » selon le tableau 22, sous la forme d’une crème blanche. [0315] A "shower cream" according to Table 22 is prepared in the form of a white cream.
[0316] Exemple 11 : nettoyants sous forme solide [0317] Dans cet exemple, on prépare des nettoyants sous forme solide : une barre nettoyante pour les cheveux et le corps, une barre nettoyante au charbon actif, et un savon solide. [0318] [Tableau 24] : barre nettoyante pour les cheveux et le corps
Figure imgf000052_0001
[0316] Example 11: cleansers in solid form [0317] In this example, cleansers are prepared in solid form: a cleansing bar for the hair and the body, a cleansing bar with activated carbon, and a solid soap. [0318] [Table 24]: cleansing bar for the hair and the body
Figure imgf000052_0001
[0320] [Tableau 25] : barre nettoyante au charbon actif
Figure imgf000053_0001
[0320] [Table 25]: cleaning bar with activated carbon
Figure imgf000053_0001
[0321] Dans un bol agité, on combine les ingrédients de la phase A. On chauffe à 80- 85°C sous agitation. On maintient cette température. On ajoute ensuite la phase B. On mélange à part les ingrédients de la phase C, puis on ajoute ce pré-mélange au contenu du bol. On ajoute ensuite successivement les ingrédients D à G. Lorsque le mélange est bien homogène, on fait couler la préparation dans un moule, puis on laisse refroidir à température ambiante. On obtient une barre solide. [0322] [Tableau 26] : savon solide
Figure imgf000054_0001
In a stirred bowl, the ingredients of phase A are combined. The mixture is heated to 80-85 ° C. with stirring. This temperature is maintained. Phase B is then added. The ingredients of phase C are mixed separately, then this premix is added to the contents of the bowl. Ingredients D to G are then added successively. When the mixture is quite homogeneous, the preparation is poured into a mold and then allowed to cool to room temperature. We get a solid bar. [0322] [Table 26]: solid soap
Figure imgf000054_0001
[0323] On prépare un savon solide selon le tableau 26. A solid soap is prepared according to Table 26.
Exemple 12 : spray nettoyant pour le corps Example 12: body wash spray
[0324] Dans cet exemple, on prépare des solutions hydroalcooliques utilisables en spray sur le corps avec rinçage après application. [0325] [Tableau 27] : spray 1
Figure imgf000054_0002
In this example, hydroalcoholic solutions are prepared which can be used as a spray on the body with rinsing after application. [0325] [Table 27]: spray 1
Figure imgf000054_0002
[0326] On prépare un spray biphasique selon le tableau 27. [0327] [Tableau 28] : spray 2
Figure imgf000055_0001
A two-phase spray is prepared according to Table 27. [0327] [Table 28]: spray 2
Figure imgf000055_0001
[0328] On prépare un spray monophasique liquide selon le tableau 28. A liquid single-phase spray is prepared according to Table 28.
[0329] Exemple 13 : solution pour linqette nettoyante [0329] Example 13: solution for cleaning cloth
[0330] Dans cet exemple, on prépare une solution pour imprégner des lingettes nettoyantes. In this example, a solution is prepared for impregnating cleaning wipes.
[0331] [Tableau 29]
Figure imgf000055_0002
[0331] [Table 29]
Figure imgf000055_0002
[0332] On prépare une solution apte à imprégner une lingette nettoyante selon le tableau 29. [0333] Exemple 14 : solution lavante « sans-sulfate » pour visage et corps [0334] [Tableau 30]
Figure imgf000056_0001
A solution suitable for impregnating a cleaning wipe is prepared according to Table 29. [0333] Example 14: “sulfate-free” washing solution for face and body [0334] [Table 30]
Figure imgf000056_0001
[0335] On prépare une solution lavante sans tensioactifs sulfatés selon le tableau 30. A washing solution without sulphated surfactants is prepared according to Table 30.
[0336] Exemple 15 : nettoyant cheveux et corps [0337] [Tableau 31]
Figure imgf000057_0001
[0336] Example 15: hair and body cleanser [0337] [Table 31]
Figure imgf000057_0001
[0338] On prépare un nettoyant cheveux et corps selon le tableau 31. A hair and body cleanser is prepared according to Table 31.

Claims

Revendications Claims
[Revendication 1] Composition cosmétique ou dermatologique pour le nettoyage et/ou le démaquillage des matières kératiniques comprenant, dans un milieu physiologiquement acceptable : - de l’acide succinique, [Claim 1] Cosmetic or dermatological composition for cleansing and / or removing make-up from keratin materials comprising, in a physiologically acceptable medium: - succinic acid,
- et au moins un acide monocarboxylique, ou son sel, choisi parmi les acides monocarboxyliques linéaires ou branchés, dont la chaîne carbonée est constituée de 2 à 12 atomes de carbones, préférentiellement de 3 à 8 atomes de carbones, et tout préférentiellement de 6 atomes de carbones. - and at least one monocarboxylic acid, or its salt, chosen from linear or branched monocarboxylic acids, the carbon chain of which consists of 2 to 12 carbon atoms, preferably 3 to 8 carbon atoms, and most preferably 6 atoms of carbons.
[Revendication 2] Composition selon la revendication 1 , caractérisée en ce que l’au moins un acide monocarboxylique est l’acide gluconique. [Claim 2] A composition according to claim 1, characterized in that the at least one monocarboxylic acid is gluconic acid.
[Revendication 3] Composition selon la revendication 1 ou 2, caractérisée en ce qu’elle comprend au moins un tensioactif choisi parmi les tensioactifs anioniques, les tensioactifs amphotères ou zwitterioniques. [Claim 3] Composition according to claim 1 or 2, characterized in that it comprises at least one surfactant chosen from anionic surfactants, amphoteric or zwitterionic surfactants.
[Revendication 4] Composition selon la revendication 3 caractérisée en ce que les tensioactifs anioniques sont choisis parmi les tensioactifs anioniques carboxyliques, les tensioactifs anioniques sulfatés, les tensioactifs anioniques sulfonates et les tensioactifs anioniques phosphates. [Claim 4] Composition according to Claim 3, characterized in that the anionic surfactants are chosen from anionic carboxylic surfactants, anionic sulphated surfactants, anionic sulphonate surfactants and anionic phosphate surfactants.
[Revendication 5] Composition selon l’une quelconque des revendications précédentes, caractérisée en ce que l’acide succinique est présent en une teneur allant de 0,1 à 15% en poids, par rapport au poids total de la composition. [Claim 5] Composition according to any one of the preceding claims, characterized in that the succinic acid is present in a content ranging from 0.1 to 15% by weight, relative to the total weight of the composition.
[Revendication 6] Composition selon la revendication 5, caractérisée en ce que l’acide succinique est présent en une teneur allant de 0,1 à 3% en poids, de préférence de 0,5 à 3% en poids, et de préférence encore de 1 à 2% en poids, par rapport au poids total de la composition. [Claim 6] Composition according to Claim 5, characterized in that the succinic acid is present in a content ranging from 0.1 to 3% by weight, preferably from 0.5 to 3% by weight, and more preferably still from 1 to 2% by weight, relative to the total weight of the composition.
[Revendication 7] Composition selon l’une quelconque des revendications précédentes, caractérisée en ce que l’acide gluconique est présent en une teneur allant de 0,1 à 2% en poids, de préférence de 0,5 à 1% en poids, par rapport au poids total de la composition. [Claim 7] Composition according to any one of the preceding claims, characterized in that the gluconic acid is present in a content ranging from 0.1 to 2% by weight, preferably from 0.5 to 1% by weight, relative to the total weight of the composition.
[Revendication 8] Composition selon l’une quelconque des revendications précédentes, comprenant au moins un agent absorbeur de sébum d’origine végétale choisi parmi la cellulose native ou modifiée, la cellulose microcristalline, les amidons granulaires natifs ou modifiés, les cyclodextrines natives ou modifiés, les dextrines et les maltodextrines, et/ou au moins un absorbeur de sébum d’origine minérale tels que les argiles et les silices et leurs sels, et leurs mélanges. [Claim 8] Composition according to any one of the preceding claims, comprising at least one sebum absorber of plant origin chosen from native or modified cellulose, microcrystalline cellulose, native or modified granular starches, native or modified cyclodextrins. , dextrins and maltodextrins, and / or at least one sebum absorber of mineral origin such as clays and silicas and their salts, and mixtures thereof.
[Revendication 9] Composition selon les revendications 1 à 8, comprenant au moins un agent gélifiant choisi parmi les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques lipophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux. [Claim 9] Composition according to claims 1 to 8, comprising at least one gelling agent chosen from hydrophilic organic gelling agents, and / or lipophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or gelling agents minerals.
[Revendication 10] Composition selon l’une quelconque des revendications 1 à 9 caractérisée en ce que la composition est sous forme d’une émulsion eau-dans-huile ou huile-dans eau ou sous forme de microémulsion. [Claim 10] Composition according to any one of claims 1 to 9 characterized in that the composition is in the form of a water-in-oil or oil-in-water emulsion or in the form of a microemulsion.
[Revendication 11] Composition selon la revendication 10, caractérisée en ce qu’elle comprend au moins un agent émulsionnant, choisi parmi les émulsionnants huile-dans- eau ou eau-dans-huile. [Claim 11] Composition according to claim 10, characterized in that it comprises at least one emulsifying agent, chosen from oil-in-water or water-in-oil emulsifiers.
[Revendication 12] Composition selon l’une quelconque des revendications 1 à 11 caractérisée en ce que ladite composition se présente sous la forme d’une crème lavante, d’une mousse, d’un lait, d’un nettoyant visage, d’un gommage. [Claim 12] Composition according to any one of claims 1 to 11, characterized in that the said composition is in the form of a cleansing cream, of a foam, of a milk, of a facial cleanser, of a scrub.
[Revendication 13] Composition selon l’une quelconque des revendications 1 à 11, caractérisée en ce que la composition se présente sous une forme galénique pour application rincée choisie parmi : les shampoings, les conditionneurs de cheveux, les masques capillaires, les sérums, les mousses, les baumes, les crèmes, les sprays, les après-shampoings, les démêlants, les crèmes capillaires. [Claim 13] Composition according to any one of Claims 1 to 11, characterized in that the composition is in a pharmaceutical form for rinsed application chosen from: shampoos, hair conditioners, hair masks, serums, foams, balms, creams, sprays, conditioners, conditioners, hair creams.
[Revendication 14] Composition selon l’une quelconque des revendications 1 à 9 caractérisée en ce que la composition est sous forme d’une composition monophasique aqueuse ou hydroalcoolique ou solide. [Claim 14] Composition according to any one of claims 1 to 9 characterized in that the composition is in the form of an aqueous or hydroalcoholic or solid single-phase composition.
[Revendication 15] Composition selon la revendication 14, caractérisée en ce que ladite composition est une composition monophasique aqueuse ou hydroalcoolique et qu’elle comprend au moins un agent gélifiant choisi parmi les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux. [Claim 15] Composition according to Claim 14, characterized in that the said composition is an aqueous or hydroalcoholic single-phase composition and that it comprises at least one gelling agent chosen from hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or mineral gelling agents.
[Revendication 16] Composition selon la revendication 15 caractérisée en ce que la composition se présente sous la forme d’un gel lavant tel qu’un gel douche, d’un nettoyant visage, d’une lotion, d’un gommage. [Claim 16] Composition according to Claim 15, characterized in that the composition is in the form of a washing gel such as a shower gel, a face cleanser, a lotion or a scrub.
[Revendication 17] Composition selon la revendication 15 caractérisée en ce que la composition se présente sous la forme d’un shampoing liquide, d’une lotion, d’un gel, d’un produit de rinçage. [Claim 17] A composition according to claim 15 characterized in that the composition is in the form of a liquid shampoo, a lotion, a gel, a rinse aid.
[Revendication 18] Composition selon la revendication 14 caractérisée en ce que ladite composition est une composition solide, et en ce qu’elle comprend au moins un liant. [Claim 18] A composition according to claim 14 characterized in that said composition is a solid composition, and in that it comprises at least one binder.
[Revendication 19] Composition selon la revendication 18 caractérisée en ce que ladite composition est sous forme de savon sec. [Claim 19] A composition according to claim 18 characterized in that said composition is in the form of a dry soap.
[Revendication 20] Composition selon la revendication 19, caractérisée en ce que ladite composition solide est sous forme de shampoing sec. [Claim 20] A composition according to claim 19, characterized in that said solid composition is in the form of a dry shampoo.
[Revendication 21] Composition selon l’une quelconque des revendications précédentes, comprenant au moins un émollient, et/ou un agent sébo-régulateur et/ou au moins un autre agent antibactérien. [Claim 21] A composition according to any one of the preceding claims, comprising at least one emollient, and / or a sebum-regulating agent and / or at least one other antibacterial agent.
[Revendication 22] Composition selon l’une quelconque des revendications précédentes, comprenant en outre au moins un autre ingrédient choisi parmi des agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange ; les agents sensoriels ; les humectants ; les agents hydratants ; les matières colorantes ; les agents filmogènes ; les agents occlusifs ; les agents conditionneurs ; les parfums. [Claim 22] A composition according to any one of the preceding claims, further comprising at least one other ingredient selected from preservatives such as benzoic acid, sorbic acid and their salts or a mixture; sensory agents; humectants; moisturizers; coloring matters; film-forming agents; occlusive agents; conditioning agents; the perfumes.
[Revendication 23] Composition cosmétique selon la revendication 1 caractérisée en ce que ladite composition est une composition monophasique aqueuse composée d’eau, d’un mélange d’acide gluconique, et d’acide succinique et d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum ; les agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange; les agents gélifiants tels que les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux; les tensioactifs tels que les tensioactifs anioniques ou amphotères, les agents sensoriels; les humectants; les émollients; les agents hydratants; les matières colorantes; les agents filmogènes; les agents occlusifs; les agents conditionneurs; les parfums. [Claim 23] Cosmetic composition according to claim 1 characterized in that said composition is an aqueous single-phase composition composed of water, a mixture of gluconic acid, and succinic acid and at least one other ingredient chosen from among sebum absorbers; preservatives such as benzoic acid, sorbic acid and their salts or a mixture; gelling agents such as hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents; surfactants such as anionic or amphoteric surfactants, sensory agents; humectants; emollients; moisturizers; coloring matters; film-forming agents; occlusive agents; conditioning agents; the perfumes.
[Revendication 24] Composition selon la revendication 1 caractérisée en ce qu’elle est composée de : - de 40 à 60% en poids d’eau, par rapport au poids total de la composition ; [Claim 24] Composition according to Claim 1, characterized in that it is composed of: - from 40 to 60% by weight of water, relative to the total weight of the composition;
- de 0,5 à 5% en poids, par rapport au poids total de la composition d’un mélange d’acide succinique et d’acide gluconique, - de 5 à 50% en poids, par rapport au poids total de la composition, d’au moins un tensioactif tel que les tensioactifs anioniques ou amphotères, , - from 0.5 to 5% by weight, relative to the total weight of the composition of a mixture of succinic acid and gluconic acid, - from 5 to 50% by weight, relative to the total weight of the composition, of at least one surfactant such as anionic or amphoteric surfactants,,
- de 0,1 à 10% en poids d d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs tels que l’acide benzoique, l’acide sorbique et leurs sels ou un mélange, les agents gélifiants les agents gélifiants organiques hydrophiles, et/ou les agents gélifiants organiques amphiphiles, et/ou les agents gélifiants minéraux, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 0.1 to 10% by weight of at least one other ingredient chosen from sebum absorbers, preservatives such as benzoic acid, sorbic acid and their salts or a mixture, gelling agents hydrophilic organic gelling agents, and / or amphiphilic organic gelling agents, and / or inorganic gelling agents, sensory agents, humectants, emollients, hydrating agents, coloring matters, film-forming agents, occlusive agents, agents conditioners, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[Revendication 25] Composition selon la revendication 1 caractérisée en ce qu’elle est sous forme de microémulsion et en ce qu’elle est composée : [Claim 25] A composition according to claim 1 characterized in that it is in the form of a microemulsion and in that it is composed:
- d’eau, - water,
- de une à trois huiles, - d’un mélange d’acide succinique et d’acide gluconique, - from one to three oils, - a mixture of succinic acid and gluconic acid,
- de un à quatre tensioactif choisi parmi les tensioactifs anioniques, ou les tensioactifs amphotères ou zwitterioniques, - from one to four surfactants chosen from anionic surfactants, or amphoteric or zwitterionic surfactants,
- de un à dix ingrédients choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums. - from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizing agents, coloring materials, film-forming agents, occlusive agents, conditioning agents , the perfumes.
[Revendication 26] Composition selon la revendication 1, caractérisée en ce que la composition est sous forme de microémulsion et en ce qu’elle est composée: [Claim 26] A composition according to claim 1, characterized in that the composition is in the form of a microemulsion and in that it is composed:
- de 40 à 60% en poids d’eau, par rapport au poids total de la composition - de 0,5 à 5% en poids, par rapport au poids total de la composition, d’une à trois huiles,- from 40 to 60% by weight of water, relative to the total weight of the composition - from 0.5 to 5% by weight, relative to the total weight of the composition, of one to three oils,
- de 0,5 à 5% en poids, par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique, - from 0.5 to 5% by weight, relative to the total weight of the composition, of a mixture of succinic acid and gluconic acid,
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à quatre tensioactifs choisi parmi les tensioactifs anioniques ou les tensioactifs amphotères ou zwitterioniques, - from 5 to 50% by weight, relative to the total weight of the composition, from one to four surfactants chosen from anionic surfactants or amphoteric or zwitterionic surfactants,
- de 0,1 à 10% en poids, par rapport au poids total de la composition, d’un à dix ingrédients choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients , moisturizing agents, coloring materials, film-forming agents, occlusive agents, agents conditioners, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[Revendication 27] Composition selon la revendication 1 caractérisée en ce qu’elle est sous une forme monophasique solide, et en ce qu’elle est composée : - d’eau, [Claim 27] A composition according to claim 1 characterized in that it is in a solid monophasic form, and in that it is composed of: - water,
- d’au moins une huile, - at least one oil,
- d’au moins une cire, ou d’un beurre végétal, ou leur mélange, - at least one wax, or vegetable butter, or a mixture thereof,
- d’un mélange d’acide succinique et d’acide gluconique, , - a mixture of succinic acid and gluconic acid,,
- d’au moins un tensioactif choisi parmi les tensioactifs anioniques ou amphotères, - d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums. - at least one surfactant chosen from anionic or amphoteric surfactants, - at least one other ingredient chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, agents moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes.
[Revendication 28] Composition selon la revendication 1 ou 27, caractérisée qu’elle est composée : [Claim 28] Composition according to claim 1 or 27, characterized that it is composed:
- de moins de 20% en poids, par rapport au poids total de la composition, d’eau, - less than 20% by weight, relative to the total weight of the composition, of water,
- de 10 à 60% en poids, par rapport au poids total de la composition, d’une à trois huiles,- from 10 to 60% by weight, relative to the total weight of the composition, of one to three oils,
- de 1 à 30% en poids, par rapport au poids total de la composition, d’une ou deux cires, ou d’un ou deux beurres végétaux, ou leurs mélanges, - de 0,5 à 5% en poids par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique - from 1 to 30% by weight, relative to the total weight of the composition, of one or two waxes, or one or two vegetable butters, or mixtures thereof, - from 0.5 to 5% by weight relative to to the total weight of the composition, of a mixture of succinic acid and gluconic acid
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à six tensioactifs choisis parmi les tensioactifs anioniques, ou les tensioactifs amphotères ou zwitterioniques, - de 0,1 à 10% en poids, par rapport au poids total de la composition, d’un à dix ingrédients choisis parmi les absorbeurs de sébum, agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 5 to 50% by weight, relative to the total weight of the composition, from one to six surfactants chosen from anionic surfactants, or amphoteric or zwitterionic surfactants, - from 0.1 to 10% by weight, relative to for the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, the sum of the percentages by weight of all the ingredients being equal to 100%.
[Revendication 29] Composition selon la revendication 1 caractérisée en ce qu’elle est sous une forme monophasique solide, et en ce qu’elle est composée : [Claim 29] A composition according to claim 1 characterized in that it is in a solid monophasic form, and in that it is composed:
- d’eau, - water,
- d’un mélange d’acide succinique et d’acide gluconique, - d’au moins un tensioactif choisi parmi les tensioactifs anioniques ou amphotères,- a mixture of succinic acid and gluconic acid, - at least one surfactant chosen from anionic or amphoteric surfactants,
- d’au moins un autre ingrédient choisi parmi les absorbeurs de sébum, les agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums, ladite composition comprenant en outre l’acide laurique, ou l’acide stéarique, ou leur mélange. - at least one other ingredient chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizing agents, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes, said composition further comprising lauric acid, or stearic acid, or a mixture thereof.
[Revendication 30] Composition selon la revendication 1 ou 30, caractérisée qu’elle est composée : - de moins de 20% en poids, par rapport au poids total de la composition, d’eau, [Claim 30] Composition according to claim 1 or 30, characterized that it is composed of: - less than 20% by weight, relative to the total weight of the composition, of water,
- de 0,5 à 5% en poids par rapport au poids total de la composition, d’un mélange d’acide succinique et d’acide gluconique - from 0.5 to 5% by weight relative to the total weight of the composition, of a mixture of succinic acid and gluconic acid
- de 5 à 50% en poids, par rapport au poids total de la composition, d’un à six tensioactifs choisis parmi les tensioactifs anioniques, ou les tensioactifs amphotères ou zwitterioniques, - from 5 to 50% by weight, relative to the total weight of the composition, from one to six surfactants chosen from anionic surfactants, or amphoteric or zwitterionic surfactants,
- de 0,1 à 10% en poids , par rapport au poids total de la composition, d’un à dix ingrédients choisis parmi les absorbeurs de sébum, agents conservateurs, les agents gélifiants, les agents sensoriels, les humectants, les émollients, les agents hydratants, les matières colorantes, les agents filmogènes, les agents occlusifs, les agents conditionneurs, les parfums - from 0.1 to 10% by weight, relative to the total weight of the composition, from one to ten ingredients chosen from sebum absorbers, preservatives, gelling agents, sensory agents, humectants, emollients, moisturizers, coloring materials, film-forming agents, occlusive agents, conditioning agents, perfumes
- de 1 à 20% en poids par rapport au poids total de la composition d’acide laurique et de 1 à 20% en poids par rapport au poids total de la composition d’acide stéarique, la somme des pourcentages en poids de tous les ingrédients étant égale à 100%. - from 1 to 20% by weight relative to the total weight of the lauric acid composition and from 1 to 20% by weight relative to the total weight of the stearic acid composition, the sum of the percentages by weight of all the ingredients being equal to 100%.
[Revendication 31] Procédé de nettoyage et/ou de démaquillage des matières kératiniques, en particulier la peau, le cuir chevelu ou les cheveux consistant à appliquer sur lesdites matières kératiniques, en particulier la peau, le cuir chevelu ou les cheveux, une composition cosmétique selon l’une quelconque des revendications précédentes. [Claim 31] A method of cleansing and / or removing make-up from keratin materials, in particular the skin, the scalp or the hair, consisting in applying to said keratin materials, in particular the skin, the scalp or the hair, a cosmetic composition according to any one of the preceding claims.
[Revendication 32] Procédé selon la revendication 31 , caractérisé en ce qu’il comprenant une étape supplémentaire de rinçage, préférentiellement à l’eau. [Claim 32] A method according to claim 31, characterized in that it comprises an additional step of rinsing, preferably with water.
[Revendication 33] Utilisation cosmétique non thérapeutique d’une composition cosmétique selon l’une quelconque des revendications 10, 11, 12, 14, 15, 16, 18, 19 ou 23 à 30, pour nettoyer et/ou démaquiller les peaux ayant des imperfections cutanées. [Claim 33] Non-therapeutic cosmetic use of a cosmetic composition according to any one of claims 10, 11, 12, 14, 15, 16, 18, 19 or 23 to 30, for cleaning and / or removing make-up from skin having skin imperfections.
[Revendication 34] Utilisation cosmétique non thérapeutique d’une composition cosmétique selon l’une quelconque des revendications 10, 11, 12, 14, 15, 16, 18, 19 ou 23 à 30, pour prévenir, réduire ou éliminer les imperfections cutanées telles que la peau grasse, la peau luisante, la peau brillante, les pores dilatés, un grain de peau épais, la perte d’éclat, la peau terne. [Claim 34] Non-therapeutic cosmetic use of a cosmetic composition according to any one of claims 10, 11, 12, 14, 15, 16, 18, 19 or 23 to 30, for preventing, reducing or eliminating skin imperfections such as as oily skin, shiny skin, shiny skin, large pores, thick skin texture, loss of radiance, dull skin.
[Revendication 35] Composition dermatologique selon l’une quelconque des revendications 10, 11, 12, 14, 15, 16, 18, 19 ou 23 à 30, pour traiter les troubles cutanés tels que l’acné. [Claim 35] A dermatological composition according to any one of claims 10, 11, 12, 14, 15, 16, 18, 19 or 23-30, for treating skin disorders such as acne.
[Revendication 36] Utilisation cosmétique non thérapeutique d’une composition cosmétique selon l’une quelconque des revendications 10, 11, 13, 14, 15, 17, 18, 20 ou 23 à 30. pour prévenir, réduire ou éliminer les états hyper séborrhéiques cosmétiques du cuir chevelu. [Claim 36] Non-therapeutic cosmetic use of a cosmetic composition according to any one of claims 10, 11, 13, 14, 15, 17, 18, 20 or 23 to 30. for preventing, reducing or eliminating hypereborrheic states scalp cosmetics.
[Revendication 37] Utilisation cosmétique non thérapeutique selon la revendication 33, caractérisée en ce que les états hyper séborrhéiques cosmétiques sont des cheveux gras, des cheveux lourds, ternes, luisant, sales, collants, difficiles à coiffer. [Claim 37] Non-therapeutic cosmetic use according to Claim 33, characterized in that the cosmetic hypereborrheic states are greasy hair, heavy hair, dull, shiny, dirty, sticky, difficult to comb.
[Revendication 38] Composition dermatologique selon l’une quelconque des revendications 10, 11, 13, 14, 15, 17, 18, 20 ou 23 à 30 pour son utilisation dans le traitement des états hyper séborrhéiques pathologiques du cuir chevelu, tels que la dermatite séborrhéique ou l’alopécie séborrhéique. [Claim 38] A dermatological composition according to any one of claims 10, 11, 13, 14, 15, 17, 18, 20 or 23 to 30 for its use in the treatment of pathological hyperseborrheic conditions of the scalp, such as seborrheic dermatitis or seborrheic alopecia.
PCT/IB2020/000773 2019-09-20 2020-09-18 Cosmetic or dermatological composition for cleansing and/or removing make-up, comprising succinic acid for preventing, reducing or eliminating skin imperfections, treating skin disorders and preventing, treating and combating hyper-seborrheic conditions of the scalp. WO2021053397A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR112022005201A BR112022005201A2 (en) 2019-09-20 2020-09-18 Cosmetic or dermatological composition for cleaning and/or removing make-up, comprising succinic acid to prevent, reduce or eliminate skin imperfections, treat skin disorders and prevent, treat and combat hyperseborrheic conditions of the scalp
CN202080065519.1A CN114449994A (en) 2019-09-20 2020-09-18 Cosmetic or dermatological composition for cleansing and/or removing cosmetics, comprising succinic acid, for preventing, reducing or eliminating skin defects, treating skin diseases and preventing, treating and combating excessive seborrhoeic disorders of the scalp
KR1020227011116A KR20220068226A (en) 2019-09-20 2020-09-18 Cosmetic or dermatological composition for removing and/or cleansing makeup comprising succinic acid for preventing, reducing or eliminating skin imperfections, treating skin disorders and preventing, treating and combating hyperseborrheic conditions of the scalp
EP20792708.8A EP4031100A1 (en) 2019-09-20 2020-09-18 Cosmetic or dermatological composition for cleansing and/or removing make-up, comprising succinic acid for preventing, reducing or eliminating skin imperfections, treating skin disorders and preventing, treating and combating hyper-seborrheic conditions of the scalp
JP2022517971A JP2022548757A (en) 2019-09-20 2020-09-18 Cleansing and/or makeup containing succinic acid to prevent, reduce or eliminate skin imperfections, treat skin disorders, and prevent, treat and control excessively seborrheic conditions of the scalp or cosmetic or dermatological compositions for removing

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FR1910413 2019-09-20
FR1910412 2019-09-20
FR1910413 2019-09-20
FR1910414 2019-09-20
FR1910414 2019-09-20
FR1910412 2019-09-20

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CN115944574A (en) * 2023-02-27 2023-04-11 广州旭妆生物科技有限公司 Composition for removing blackheads, cosmetic and preparation method
CN116407478A (en) * 2023-05-11 2023-07-11 杭州以息互联网科技有限公司 Mild acne-removing composition and application thereof

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