WO2021040309A1 - Photomask, method for manufacturing same, and method for manufacturing display device using same - Google Patents

Photomask, method for manufacturing same, and method for manufacturing display device using same Download PDF

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Publication number
WO2021040309A1
WO2021040309A1 PCT/KR2020/011003 KR2020011003W WO2021040309A1 WO 2021040309 A1 WO2021040309 A1 WO 2021040309A1 KR 2020011003 W KR2020011003 W KR 2020011003W WO 2021040309 A1 WO2021040309 A1 WO 2021040309A1
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WIPO (PCT)
Prior art keywords
layer
photomask
pattern
substrate
pattern layer
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Application number
PCT/KR2020/011003
Other languages
French (fr)
Korean (ko)
Inventor
심우영
백상윤
장기석
정순신
문정민
Original Assignee
엘지디스플레이 주식회사
연세대학교 산학협력단
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Publication of WO2021040309A1 publication Critical patent/WO2021040309A1/en

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2051Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source
    • G03F7/2059Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source using a scanning corpuscular radiation beam, e.g. an electron beam
    • G03F7/2063Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source using a scanning corpuscular radiation beam, e.g. an electron beam for the production of exposure masks or reticles
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/50Mask blanks not covered by G03F1/20 - G03F1/34; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/60Substrates
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/7095Materials, e.g. materials for housing, stage or other support having particular properties, e.g. weight, strength, conductivity, thermal expansion coefficient
    • G03F7/70958Optical materials or coatings, e.g. with particular transmittance, reflectance or anti-reflection properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0337Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/304Mechanical treatment, e.g. grinding, polishing, cutting

Definitions

  • the present specification relates to a photomask, and more particularly, to provide a photomask capable of forming a pattern layer having a narrow line width even with light having a long wavelength, a method of manufacturing the same, and a method of manufacturing a display device using the same.
  • Such a display device includes at least one substrate, and a plurality of fine patterns are disposed on the substrate. In order to form such a fine pattern, a patterning process using photolithography may be performed.
  • One or more photomasks may be used in the photolithography process.
  • problems such as suppression of resolution due to diffraction are known.
  • a light source with a short wavelength capable of suppressing diffraction may be used, but in order to use a light source with a short wavelength, it is necessary to replace the existing production facility with a production facility capable of using a light source with a short wavelength.
  • replacement of production equipment can incur enormous costs. Accordingly, the inventors of the present specification invented a photomask capable of forming a fine pattern without changing production equipment, a method for manufacturing the same, and a method for manufacturing a display device using the same.
  • a photomask according to an exemplary embodiment of the present specification includes a flexible substrate layer and a pattern layer.
  • the above-described base layer may be a flexible base layer in which a concave portion is located on one surface.
  • the above-described pattern layer may fill the above-described concave portion, and one surface may be exposed.
  • the maximum depth of the above-described concave portion and the maximum thickness of the above-described pattern layer may correspond to each other.
  • the above-described photomask may include a contact surface divided into a pattern region in which one surface of the above-described pattern layer is exposed and a substrate region in which the above-described flexible substrate layer is exposed.
  • the above-described pattern layer may fill the above-described concave portion to planarize the above-described contact surface.
  • Each of the above-described pattern region and the above-described substrate region may have a planar shape.
  • the above-described contact surface may have a planar shape.
  • the above-described pattern region and the above-described substrate region may be located on the same plane.
  • the above-described flexible substrate layer may have a transmittance of 80% to 99% for light having a wavelength of 10 nm to 600 nm.
  • the above-described pattern layer may have a transmittance of 0% to 10% for light having a wavelength of 10 nm to 600 nm.
  • the above-described flexible substrate layer may include polydimethylsiloxane.
  • the pattern layer described above may include chromium.
  • a photomask manufacturing method includes forming a pattern layer protruding on a substrate, forming a flexible substrate layer positioned on the above-described substrate and covering the above-described pattern layer, and the above It may include the step of peeling one flexible substrate layer from the above-described substrate.
  • Forming the protruding pattern layer on the above-described substrate includes forming a photoresist layer on the above-described substrate, patterning the above-described photoresist layer, and patterning the above-described patterned photoresist layer. It may include depositing a layer and stripping the photoresist layer described above.
  • the step of peeling the above-described flexible substrate layer may be a step of peeling the protruding pattern layer and the above-described flexible substrate layer formed on the above-described substrate.
  • a method of manufacturing a display device may include exposing the above-described photoresist layer in a state in which the pattern layer of the above-described photomask is in contact with a photoresist layer positioned on a substrate. .
  • the photomask since the photomask includes a flexible substrate layer having a concave portion on one surface and a pattern layer filling the above-described concave portion, it is possible to contact along the surface of the photoresist layer, so that a short wavelength light source is not used. There is an effect of realizing a fine pattern by contact printing.
  • the method of manufacturing a photomask has an effect of manufacturing a photomask capable of implementing a fine pattern by contact printing since it can contact along the surface of the photoresist layer.
  • the method of manufacturing a display device has an effect of manufacturing a display device having a fine pattern by exposing the photoresist layer in a state in which the above-described photomask is in contact with the photoresist layer. have.
  • FIG. 1 is a schematic cross-sectional view of a photomask according to an embodiment.
  • FIG. 2 is a schematic plan view of a photomask according to an exemplary embodiment.
  • 3 to 8 are schematic diagrams for explaining a method of manufacturing a photomask according to an exemplary embodiment.
  • FIG. 9 is a schematic diagram illustrating a method of manufacturing a display device according to an exemplary embodiment.
  • FIG. 10 is a schematic diagram illustrating a method of manufacturing a display device according to a comparative example.
  • FIG. 11 is data for explaining a method of manufacturing a display device according to a comparative example.
  • 15 is data showing formation of a fine pattern using a photomask according to an embodiment on a rough surface of a substrate and a surface having defects.
  • 16 and 17 are data for a reflective display manufactured using a photomask according to an embodiment.
  • FIG. 1 is a schematic cross-sectional view of a photomask according to an embodiment of the present specification.
  • a photomask 100 fills a flexible substrate layer 110 and a concave portion 111 in which a concave portion 111 is positioned on one surface, and a pattern layer having one surface exposed ( 120).
  • the flexible substrate layer 110 may include a flexible material. Since the photomask 100 includes the flexible substrate layer 110, the photomask 100 can contact the photoresist layer without a gap, thereby preventing a reduction in resolution due to diffraction in the exposure process of the photoresist layer. .
  • the flexible substrate layer 110 may have excellent light transmittance.
  • the flexible substrate layer 110 may have a transmittance of 80% to 99% for light having a wavelength of 10 nm to 600 nm, for example.
  • a light source having a small output may be used.
  • the flexible substrate layer 110 is a flexible material, and may include, for example, polydimethylsiloxane (PDMS).
  • PDMS polydimethylsiloxane
  • the flexible substrate layer 110 has a concave portion 111 positioned on one surface thereof. Since the concave portion 111 is positioned on one surface of the flexible substrate layer 110, the pattern layer 120 may be embedded in the flexible substrate layer 110.
  • the pattern layer 120 fills the concave portion 111, and one surface is exposed. Referring to FIG. 1, while the pattern layer 120 is inserted into the flexible substrate layer 110, one surface of the pattern layer 120 may be exposed on the one surface of the photomask.
  • the pattern layer 120 has light blocking properties and may block a part of the light irradiated to the photomask 100.
  • the pattern layer 120 may have a transmittance of 0% to 10% for light having a wavelength of 10 nm to 600 nm.
  • the pattern layer 120 may include metal.
  • the pattern layer 120 may include chromium.
  • chromium is used as the material for the pattern layer 120, the processability is excellent, and the light-shielding pattern layer can be easily formed.
  • the photomask 100 may include a contact surface 130 in contact with the photoresist.
  • the maximum depth d of the concave portion 111 and the maximum thickness t of the pattern layer 120 correspond to each other. That the maximum depth d of the concave portion 111 and the maximum thickness t of the pattern layer 120 correspond to each other means that the maximum depth d of the concave portion 111 and the maximum thickness of the pattern layer 120 ( It can mean that t) is substantially the same.
  • the maximum depth d of the concave portion 111 may mean a degree in which the concave portion 111 is maximally depressed in the thickness direction of the photomask 100.
  • the maximum depth d of the concave portion 111 may be, for example, a difference between a minimum value and a maximum value of a thickness between one surface of the flexible substrate layer 110 on which the concave portion 111 is formed and the opposite surface. .
  • the maximum depth d of the concave portion 111 is, for example, the maximum depth of the concave portion 111 measured in a direction perpendicular to the contact surface 130 from the contact surface 130 when the contact surface 130 has a planar shape It can mean (d).
  • the maximum thickness t of the pattern layer 120 may mean a maximum value of the thickness measured in the thickness direction of the photomask 100 of the pattern layer 120 filling the concave portion 111.
  • the maximum thickness t of the pattern layer 120 is, for example, the maximum thickness of the pattern layer 120 measured in a direction perpendicular to the contact surface 130 from the contact surface 130 when the contact surface 130 has a flat shape. It can mean (t).
  • the maximum depth (d) of the concave portion 111 and the maximum thickness (t) of the pattern layer 120 are measured at each concave portion. It may mean the depth of the concave portion 111 and the thickness of the pattern layer 120.
  • the maximum depth (d) of the concave portion 111 and the maximum thickness (t) of the pattern layer 120 correspond to each other, so that the pattern layer 120 can fill the concave portion 111 to the contact surface 130 of the photomask. I can. Accordingly, when the contact surface 130 of the photomask 100 contacts the photoresist, the gap between the edge portion of the pattern layer 120 and the photoresist can be minimized. When the gap between the edge portion of the pattern layer 120 and the photoresist is minimized, light diffracts while passing through the edge portion of the pattern layer 120 to reduce resolution.
  • the pattern layer 120 may fill the concave portion 111 to planarize the contact surface 130. That is, the pattern layer 120 may fill the concave portion 111 so that there is no step difference between the pattern layer 120 and the flexible substrate layer 110 on the contact surface 130.
  • the contact surface 130 may be divided into a pattern region 131 in which one surface of the pattern layer 120 is exposed and a substrate region 132 in which the flexible substrate layer 110 is exposed. Accordingly, when the contact surface 130 contacts the photoresist, the pattern region 131 and the substrate region 132 constituting the contact surface 130 contact the photoresist, and one surface of the pattern layer 120 is in contact with the photoresist. I can contact you.
  • the photomask 100 has the above-described structure, since the gap between the pattern layer 120 and the photoresist can be minimized, a reduction in resolution due to diffraction can be effectively suppressed.
  • the pattern region 131 and the substrate region 132 may each have a planar shape. That is, one exposed surface of the pattern layer 120 may have a planar shape, and the flexible substrate exposed because the pattern layer 120 is not located on one surface where the concave portion 111 of the flexible substrate layer 110 is located. A portion of the layer 110 may also have a planar shape.
  • the contact surface 130 may also have a planar shape. Since the contact surface 130 of the photomask 100 is in a planar shape, the gap between the pattern layer 120 and the photoresist is minimized when the contact surface 130 contacts the photoresist, thereby suppressing deterioration of resolution due to diffraction. have.
  • the pattern region 131 and the substrate region 132 may be located on the same plane. That is, there may be no step difference between the pattern layer 120 and the flexible substrate layer 110 on the contact surface 130.
  • the load of the photomask is minimized while minimizing the gap between the photoresist and the pattern layer 120 when the photomask 100 contacts the photoresist. Since it may be dispersed in the flexible substrate layer 110, damage to the pattern layer 120 due to contact between the photoresist and the pattern layer 120 may be prevented.
  • 3 to 8 are diagrams illustrating a method of manufacturing a photomask according to an exemplary embodiment.
  • a photomask manufacturing method includes the steps of forming the pattern layer 120 protruding on the substrate 140, and the protruding pattern layer 120 positioned on the substrate 140 and described above. ) Forming the flexible substrate layer 110 covering the ), and peeling the above-described flexible substrate layer 110 from the above-described substrate 140.
  • the type of the substrate 140 is not particularly limited, for example, a silicon layer (Si), a silicon oxide layer (SiO 2 ), and a nickel (Ni) layer sequentially stacked as a sacrificial layer may be used.
  • Forming the pattern layer 120 protruding on the substrate 140 includes, for example, forming a photoresist layer 150 on the substrate 140 and patterning the photoresist layer 150.
  • the steps may include depositing the pattern layer 120 on the patterned photoresist layer 150 and stripping the photoresist layer 150.
  • FIG. 4 is a view showing that a photoresist layer 150 is formed on the substrate 140.
  • the type of the photoresist layer 150 is not particularly limited, but, for example, polymethylmethacrylate (PMMA) may be used.
  • a method of forming the photoresist layer 150 on the substrate 140 may be, for example, a method of coating a photoresist composition on the substrate 140.
  • FIG. 5 is a diagram illustrating a patterned photoresist layer 150 formed on the substrate 140.
  • a method of patterning the photoresist layer 150 may be, for example, e-beam lithography.
  • the deposition method of the pattern layer 120 may be, for example, a chemical vapor deposition method such as a thermal evaporation method, a plasma vapor deposition method, an atmospheric vapor deposition method, a low pressure vapor deposition method, or a physical vapor deposition method such as a thermal evaporation method, an electron beam evaporation method, or sputtering.
  • a chemical vapor deposition method such as a thermal evaporation method, a plasma vapor deposition method, an atmospheric vapor deposition method, a low pressure vapor deposition method, or a physical vapor deposition method such as a thermal evaporation method, an electron beam evaporation method, or sputtering.
  • the step of stripping the photoresist layer 150 may be performed in a step in which the pattern layer 120 is deposited on the patterned photoresist layer 150 shown in FIG. 6.
  • the pattern layer 120 disposed on the photoresist layer 150 is also removed, and The protruding pattern layer 120 may be formed.
  • the flexible substrate layer 110 may be formed, for example, by a method of photocuring or thermosetting after coating the composition.
  • the aforementioned concave portion may be formed on one surface of the substrate layer 110.
  • FIG. 8 is a diagram illustrating peeling of the flexible substrate layer 110 from the substrate 140.
  • the step of peeling the flexible substrate layer 110 may be a step of peeling the protruding pattern layer 120 formed on the substrate 140 together with the flexible substrate layer 110.
  • the substrate layer 110 is peeled after applying and curing a polydimethylsiloxane (PDMS) composition on the substrate 140 and the pattern layer 120, the pattern layer 120 is peeled off from the substrate 140 Can be.
  • PDMS polydimethylsiloxane
  • FIG. 9 is a diagram for describing a method of manufacturing a display device according to an exemplary embodiment of the present specification.
  • a photoresist layer 151 disposed on a substrate 141 is in contact with the pattern layer 120 of the photomask described above. And exposing the photoresist layer 151 to light.
  • the substrate 141 is a substrate on which a pattern is to be formed by a photolithography process, and its type is not particularly limited as long as it is used in the field of a display device.
  • the photoresist layer 151 is a photosensitive layer used to form a pattern by a photolithography process, and its type is not particularly limited as long as it is used in the field of a display device.
  • the pattern layer 120 directly contacts the photoresist layer 151.
  • the flexible substrate layer 110 may also directly contact the photoresist layer 151.
  • FIG. 10 is a diagram illustrating a method of manufacturing a display device according to a comparative example.
  • the photoresist layer 151 is spaced apart from the photoresist layer 151 on the substrate 141 with a specific gap S. ) Can be performed.
  • the photomask 200 when the photomask 200 is a flat and stiff material, for example, a fine metal mask, the photomask 200 is brought into contact with the photomask 200 and the photoresist layer 151. In order to prevent damage to ), the photomask 200 may be disposed with a specific gap S.
  • damage to the pattern layer may be applied when the protruding pattern layer contacts the photoresist layer, thus preventing damage to the photomask by contact.
  • a photomask may be disposed with a specific gap.
  • FIG. 11 is a data for explaining that the resolution of the photolithography process decreases due to the diffraction of light when the photoresist layer is exposed with a photomask disposed with a specific gap (S) as shown in FIG. 10 to be.
  • the photolithography process shown in FIG. 10 is intended to be irradiated with light as indicated by a dotted line, but the photomask 200 is spaced apart from the photoresist layer 151 by a specific gap S. It can be seen that the light was irradiated as indicated by a solid line as a result of proceeding the process in the state of being turned on.
  • FIG. 12 is data for explaining fine patterns that can be formed when using a photomask according to an exemplary embodiment of the present specification.
  • FIG. 12 is a view of forming a resolution test pattern (USAF Resolving Power Test Target 1951) using a light source having a wavelength of 400 nm to 500 nm and a photomask according to an embodiment of the present specification.
  • a protruding pattern layer 120 was formed on the substrate 140, and plan photographs thereof are shown in b and e.
  • a photomask including the flexible substrate layer 110 and the pattern layer 120 was manufactured, and plan photographs are shown in c and f. I got it.
  • a patterned photoresist layer 151 was formed on the substrate 141 by using the above-described photomask, and plan photographs thereof are shown in d and g. Referring to FIG.
  • the line width of the patterned layer 120 of the photomask is effectively reflected in the line width of the patterned photoresist layer 151 formed using the photomask, as can be seen through i.
  • 13 is data for explaining fine patterns that can be formed when using a photomask according to embodiments of the present specification.
  • FIG. 13 illustrates a line pattern and a dot pattern formed by using a photomask and a light source having a wavelength of 400 nm to 500 nm according to exemplary embodiments of the present specification.
  • a line having a line width of 60 nm and 160 nm is a light source of 400 nm to 500 nm, not a short wavelength such as Deep UV (DUV) or Extreme UV (EUV). Patterns and dot patterns can be formed.
  • DUV Deep UV
  • EUV Extreme UV
  • FIG. 14 is data showing that a pattern is formed on a curved surface rather than a flat surface using a photomask according to an exemplary embodiment of the present specification.
  • a PET substrate was placed on a structure having a radius of curvature of 250 nm, and a photomask according to an embodiment of the present specification was exposed using a light source having a wavelength of 400 nm to 500 nm. Referring to FIG. 13, it can be seen that even when exposure is performed on a substrate having a curvature, a pattern having a line width of 38 nm is formed.
  • the photomask according to an embodiment of the present specification includes a flexible substrate layer in which a concave portion is located and a pattern layer that fills the concave portion, and the maximum depth of the concave portion and the maximum thickness of the pattern layer correspond to each other.
  • the contact surface of the photomask may be in close contact with a substrate having a curvature, and thus, a reduction in resolution due to diffraction may be prevented, and thus a fine pattern may be formed even on a substrate having a curvature.
  • 15 is a data showing that a pattern is formed on a rough surface of a substrate and a surface having defects by using a photomask according to an exemplary embodiment of the present specification.
  • a rough surface was formed using leaves (a).
  • the surface of the leaf is rougher than the plastic substrate and has defects, so it is difficult to implement a pattern when using a conventional photolithography process.
  • a pattern was formed on a rough surface formed using leaves using a photomask according to an embodiment of the present specification (b, c, d, e, f, g).
  • a photomask according to an embodiment of the present specification (b, c, d, e, f, g).
  • patterns were formed in areas with defects such as curl, step, and kink (k, l, m).
  • the photomask according to the embodiments of the present specification since the photomask can adhere closely along the surface shape of the photoresist layer, a fine pattern can be formed even on a rough surface or a defective area.
  • 16 is data for a reflective display manufactured using a photomask according to an exemplary embodiment of the present specification.
  • An image was implemented on the substrate using a plasmonic nano pattern with a size of 0.96 mm in width and 1.2 mm in height (b). Patterning was performed on a silver (Ag) substrate using a photomask according to an embodiment of the present specification, and plasmonic nanopatterns having different sizes were formed in portions requiring different colors (c to k).
  • plasmonic nano-patterns of various sizes can be formed, and thus a reflective display can be implemented by using a resonance phenomenon of light reflected from a nano-sized pattern.
  • 17 is data for a reflective display manufactured using a photomask according to an exemplary embodiment of the present specification.
  • a reflective display having various colors can be manufactured by forming a plasmonic nano pattern. Since the implemented color can be changed according to the type of metal substrate and the thickness of the photoresist, even if the same photomask is used, the type of the metal substrate and the thickness of the photoresist can be changed to manufacture a reflective display in which various colors are implemented. I can.

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  • Optics & Photonics (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)

Abstract

Embodiments of the present specification relate to a photomask, a method for manufacturing same, and a method for manufacturing a display device using same and, more specifically, to a photomask comprising: a base layer having a recessed portion located on one side thereof; and a pattern layer filling the recessed portion and having one surface exposed, wherein the maximum depth of the recessed portion and the maximum thickness of the pattern layer correspond to each other, and thus, the photomask can expose a photoresist while in close contact with the photoresist and form a pattern having a fine line width even when a light source having a relatively long wavelength is used.

Description

포토마스크, 이의 제조방법 및 이를 이용한 표시장치의 제조방법 Photomask, manufacturing method thereof, and manufacturing method of display device using same
본 명세서는 포토마스크에 관한 것으로서, 보다 상세하게는 긴 파장을 가지는 광으로도 좁은 선폭을 가지는 패턴층을 형성할 수 있는 포토마스크, 이의 제조방법 및 이를 이용한 표시장치의 제조방법을 제공하는 것이다.The present specification relates to a photomask, and more particularly, to provide a photomask capable of forming a pattern layer having a narrow line width even with light having a long wavelength, a method of manufacturing the same, and a method of manufacturing a display device using the same.
정보화 사회의 발전에 따라 고화질 및 고해상 표시 장치의 개발이 요구되고 있다. 이러한 표시장치는 적어도 1개의 기판을 구비하며, 기판 상에는 복수의 미세 패턴들이 배치된다. 이러한 미세 패턴을 형성하기 위해서 포토리소그래피를 이용한 패터닝 공정이 수행될 수 있다. With the development of the information society, the development of high-definition and high-resolution display devices is required. Such a display device includes at least one substrate, and a plurality of fine patterns are disposed on the substrate. In order to form such a fine pattern, a patterning process using photolithography may be performed.
포토리소그래피 공정에는 1장 이상의 포토마스크가 사용될 수 있다. 포토마스크를 이용한 포토리소그래피 분야에서는, 회절현상에 의한 해상력 억제 등의 문제점이 알려져 있다.One or more photomasks may be used in the photolithography process. In the field of photolithography using a photomask, problems such as suppression of resolution due to diffraction are known.
미세한 패턴을 형성하기 위하여 회절현상을 억제할 수 있는 단파장의 광원이 사용될 수 있으나, 단파장의 광원을 사용하기 위해서는 기존의 생산설비를 단파장의 광원을 사용할 수 있는 생산설비로의 교체가 요구된다. 그러나, 생산설비의 교체는 막대한 비용을 발생시킬 수 있다. 이에, 본 명세서의 발명자들은 생산설비를 교체하지 않고도 미세한 패턴을 형성할 수 있는 포토마스크, 이의 제조방법 및 이를 이용한 표시장치의 제조방법을 발명하였다.In order to form a fine pattern, a light source with a short wavelength capable of suppressing diffraction may be used, but in order to use a light source with a short wavelength, it is necessary to replace the existing production facility with a production facility capable of using a light source with a short wavelength. However, replacement of production equipment can incur enormous costs. Accordingly, the inventors of the present specification invented a photomask capable of forming a fine pattern without changing production equipment, a method for manufacturing the same, and a method for manufacturing a display device using the same.
이하에서 설명하게 될 본 명세서의 실시예들에 따른 해결 과제들은 이상에서 언급한 과제들로 제한되지 않으며, 언급되지 않은 또 다른 과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다. The problems to be solved according to the embodiments of the present specification to be described below are not limited to the problems mentioned above, and other problems that are not mentioned will be clearly understood by those skilled in the art from the following description.
본 명세서의 일 실시예에 따른 포토마스크는 가요성 기재층 및 패턴층을 포함한다.A photomask according to an exemplary embodiment of the present specification includes a flexible substrate layer and a pattern layer.
전술한 기재층은 일면에 오목부가 위치하는 가요성 기재층일 수 있다. 전술한 패턴층은 전술한 오목부를 충진하고, 일면이 노출될 수 있다.The above-described base layer may be a flexible base layer in which a concave portion is located on one surface. The above-described pattern layer may fill the above-described concave portion, and one surface may be exposed.
전술한 오목부의 최대 깊이와 전술한 패턴층의 최대 두께는 서로 대응될 수 있다.The maximum depth of the above-described concave portion and the maximum thickness of the above-described pattern layer may correspond to each other.
전술한 포토마스크는 전술한 패턴층의 일면이 노출된 패턴영역 및 전술한 가요성 기재층이 노출된 기재영역으로 구분되는 접촉면을 포함할 수 있다.The above-described photomask may include a contact surface divided into a pattern region in which one surface of the above-described pattern layer is exposed and a substrate region in which the above-described flexible substrate layer is exposed.
전술한 패턴층은 전술한 오목부를 충진하여 전술한 접촉면을 평탄화할 수 있다.The above-described pattern layer may fill the above-described concave portion to planarize the above-described contact surface.
전술한 패턴영역 및 전술한 기재영역은 각각 평면 형상일 수 있다.Each of the above-described pattern region and the above-described substrate region may have a planar shape.
전술한 접촉면은 평면 형상일 수 있다.The above-described contact surface may have a planar shape.
전술한 패턴영역 및 전술한 기재영역은 동일 평면 상에 위치할 수 있다.The above-described pattern region and the above-described substrate region may be located on the same plane.
전술한 가요성 기재층은 파장이 10nm 내지 600nm인 광에 대한 투과율이 80% 내지 99%일 수 있다.The above-described flexible substrate layer may have a transmittance of 80% to 99% for light having a wavelength of 10 nm to 600 nm.
전술한 패턴층은 파장이 10nm 내지 600nm인 광에 대한 투과율이 0% 내지 10%일 수 있다.The above-described pattern layer may have a transmittance of 0% to 10% for light having a wavelength of 10 nm to 600 nm.
전술한 가요성 기재층은 폴리디메틸실록산을 포함할 수 있다.The above-described flexible substrate layer may include polydimethylsiloxane.
전술한 패턴층은 크롬을 포함할 수 있다.The pattern layer described above may include chromium.
본 명세서의 일 실시예에 따른 포토마스크 제조방법은, 기판 상에 돌출된 패턴층을 형성하는 단계와, 전술한 기판 상에 위치하고 전술한 패턴층을 덮는 가요성 기재층을 형성하는 단계와, 전술한 가요성 기재층을 전술한 기판으로부터 박리하는 단계를 포함할 수 있다.A photomask manufacturing method according to an embodiment of the present specification includes forming a pattern layer protruding on a substrate, forming a flexible substrate layer positioned on the above-described substrate and covering the above-described pattern layer, and the above It may include the step of peeling one flexible substrate layer from the above-described substrate.
전술한 기판 상에 돌출된 패턴층을 형성하는 단계는, 전술한 기판 상에 포토레지스트층을 형성하는 단계와, 전술한 포토레지스트층을 패터닝하는 단계와, 전술한 패터닝된 포토레지스트층 상에 패턴층을 증착하는 단계와, 전술한 포토레지스트층을 스트립하는 단계를 포함할 수 있다.Forming the protruding pattern layer on the above-described substrate includes forming a photoresist layer on the above-described substrate, patterning the above-described photoresist layer, and patterning the above-described patterned photoresist layer. It may include depositing a layer and stripping the photoresist layer described above.
전술한 가요성 기재층을 박리하는 단계는, 전술한 기판 상에 형성된 돌출된 패턴층 및 전술한 가요성 기재층을 박리하는 단계일 수 있다.The step of peeling the above-described flexible substrate layer may be a step of peeling the protruding pattern layer and the above-described flexible substrate layer formed on the above-described substrate.
본 명세서의 일 실시예에 따른 표시장치의 제조방법은, 기판 상에 위치하는 포토레지스트층에 전술한 포토마스크의 패턴층을 접촉시킨 상태에서 전술한 포토레지스트층을 노광하는 단계를 포함할 수 있다.A method of manufacturing a display device according to an exemplary embodiment of the present specification may include exposing the above-described photoresist layer in a state in which the pattern layer of the above-described photomask is in contact with a photoresist layer positioned on a substrate. .
본 명세서의 실시예들에 따르면, 포토마스크가 일면에 오목부가 위치하는 가요성 기재층 및 전술한 오목부를 충진하는 패턴층을 포함함으로써 포토레지스트층 표면을 따라 접촉할 수 있어 단파장 광원을 사용하지 않아도 컨택트 프린팅(contact printing)에 의해 미세 패턴을 구현할 수 있는 효과가 있다.According to the embodiments of the present specification, since the photomask includes a flexible substrate layer having a concave portion on one surface and a pattern layer filling the above-described concave portion, it is possible to contact along the surface of the photoresist layer, so that a short wavelength light source is not used. There is an effect of realizing a fine pattern by contact printing.
또한, 본 명세서의 실시예들에 따르면, 포토마스크 제조방법은, 포토레지스트층 표면을 따라 접촉할 수 있어 컨택트 프린팅에 의해 미세 패턴을 구현할 수 있는 포토마스크를 제조할 수 있는 효과가 있다.In addition, according to the embodiments of the present specification, the method of manufacturing a photomask has an effect of manufacturing a photomask capable of implementing a fine pattern by contact printing since it can contact along the surface of the photoresist layer.
또한, 본 명세서의 실시예들에 따르면, 표시장치 제조방법은, 전술한 포토마스크를 포토레지스트층에 접촉시킨 상태에서 포토레지스트층을 노광하여 미세 패턴이 구현된 표시장치를 제조할 수 있는 효과가 있다.In addition, according to the exemplary embodiments of the present specification, the method of manufacturing a display device has an effect of manufacturing a display device having a fine pattern by exposing the photoresist layer in a state in which the above-described photomask is in contact with the photoresist layer. have.
도 1은 일 실시에 따른 포토마스크의 개략적인 단면도이다.1 is a schematic cross-sectional view of a photomask according to an embodiment.
도 2는 일 실시예에 따른 포토마스크의 개략적인 평면도이다.2 is a schematic plan view of a photomask according to an exemplary embodiment.
도 3 내지 도 8은 일 실시예에 따른 포토마스크의 제조방법을 설명하기 위한 개략도이다.3 to 8 are schematic diagrams for explaining a method of manufacturing a photomask according to an exemplary embodiment.
도 9는 일 실시예에 따른 표시장치의 제조방법을 설명하기 위한 개략도이다.9 is a schematic diagram illustrating a method of manufacturing a display device according to an exemplary embodiment.
도 10은 비교예에 따른 표시장치의 제조방법을 설명하기 위한 개략도이다.10 is a schematic diagram illustrating a method of manufacturing a display device according to a comparative example.
도 11은 비교예에 따른 표시장치의 제조방법을 설명하기 위한 자료이다.11 is data for explaining a method of manufacturing a display device according to a comparative example.
도 12 내지 도 14는 실시예에 따른 포토마스크로 구현한 미세 패턴에 대한 자료이다.12 to 14 are data on fine patterns implemented with a photomask according to an embodiment.
도 15는 기재의 거친 표면 및 결점을 가지는 표면 위에 실시예에 따른 포토마스크를 이용하여 미세 패턴을 형성하는 것을 보여주는 자료이다.15 is data showing formation of a fine pattern using a photomask according to an embodiment on a rough surface of a substrate and a surface having defects.
도 16 및 도 17은 실시예에 따른 포토마스크를 이용하여 제작한 반사형 디스플레이에 대한 자료이다.16 and 17 are data for a reflective display manufactured using a photomask according to an embodiment.
본 명세서의 이점 및 특징, 그리고 그것들을 달성하는 방법은 첨부되는 도면과 함께 상세하게 후술되어 있는 실시예들을 참조하면 명확해질 것이다. 그러나 본 명세서는 이하에서 개시되는 실시예들에 한정되는 것이 아니라 서로 다른 다양한 형태로 구현될 것이며, 단지 본 실시예들은 본 명세서의 개시가 완전하도록 하며, 본 명세서가 속하는 기술분야에서 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이며, 본 명세서는 청구항의 범주에 의해 정의될 뿐이다. Advantages and features of the present specification, and a method of achieving them will become apparent with reference to the embodiments described below in detail together with the accompanying drawings. However, the present specification is not limited to the embodiments disclosed below, but will be implemented in various different forms. It is provided to fully inform the scope of the invention to those who have it, and this specification is only defined by the scope of the claims.
본 명세서의 실시예를 설명하기 위한 도면에 개시된 형상, 크기, 비율, 각도, 개수 등은 예시적인 것이므로 본 명세서가 도시된 사항에 한정되는 것은 아니다. 명세서 전체에 걸쳐 동일 참조 부호는 동일 구성 요소를 지칭한다. 또한, 본 명세서를 설명함에 있어서, 관련된 공지 기술에 대한 구체적인 설명이 본 명세서의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우 그 상세한 설명은 생략한다. 본 명세서 상에서 언급된 "포함한다", "갖는다", "이루어진다" 등이 사용되는 경우 "~만"이 사용되지 않는 이상 다른 부분이 추가될 수 있다. 구성 요소를 단수로 표현한 경우에 특별히 명시적인 기재 사항이 없는 한 복수를 포함하는 경우를 포함한다. The shape, size, ratio, angle, number, etc. disclosed in the drawings for explaining the embodiments of the present specification are exemplary, and the present specification is not limited to the illustrated matters. The same reference numerals refer to the same elements throughout the specification. In addition, in describing the present specification, when it is determined that a detailed description of a related known technology may unnecessarily obscure the subject matter of the present specification, the detailed description thereof will be omitted. When "include", "have", "consists of" and the like mentioned in the present specification are used, other parts may be added unless "only" is used. In the case of expressing the constituent elements in the singular, it includes the case of including the plural unless specifically stated otherwise.
구성 요소를 해석함에 있어서, 별도의 명시적 기재가 없더라도 오차 범위를 포함하는 것으로 해석한다.In interpreting the constituent elements, it is interpreted as including an error range even if there is no explicit description.
위치 관계에 대한 설명일 경우, 예를 들어, "~상에", "~상부에", "~하부에", "~옆에" 등으로 두 부분의 위치 관계가 설명되는 경우, "바로" 또는 "직접"이 사용되지 않는 이상 두 부분 사이에 하나 이상의 다른 부분이 위치할 수도 있다.In the case of a description of the positional relationship, for example, when the positional relationship of two parts is described as "on the top", "upper of the", "lower of the", and "the side of the", "right" Alternatively, one or more other parts may be located between the two parts unless "direct" is used.
시간 관계에 대한 설명일 경우, 예를 들어, "~후에", "~에 이어서", "~다음에", "~전에" 등으로 시간 적 선후 관계가 설명되는 경우, "바로" 또는 "직접"이 사용되지 않는 이상 연속적이지 않은 경우도 포함할 수 있다.In the case of a description of a temporal relationship, for example, "after", "following", "after", "before", etc., when a temporal predecessor relationship is described, "right" or "directly" It may also include non-contiguous cases unless "is used.
본 명세서의 여러 실시예들의 각각 특징들이 부분적으로 또는 전체적으로 서로 결합 또는 조합 가능하고, 기술적으로 다양한 연동 및 구동이 가능하며, 각 실시예들이 서로에 대하여 독립적으로 실시 가능할 수도 있고 연관 관계로 함께 실시할 수도 있다.Each of the features of the various embodiments of the present specification can be partially or entirely combined or combined with each other, technically various interlocking and driving are possible, and each of the embodiments may be independently implemented with respect to each other or can be implemented together in an association relationship. May be.
이하, 첨부된 도면을 참조하여 본 명세서의 다양한 실시예들을 상세히 설명한다.Hereinafter, various embodiments of the present specification will be described in detail with reference to the accompanying drawings.
도 1은 본 명세서의 일 실시예에 따른 포토마스크의 개략적인 단면도이다.1 is a schematic cross-sectional view of a photomask according to an embodiment of the present specification.
도 1을 참조하면, 일 실시예에 따른 포토마스크(100)는 일면에 오목부(111)가 위치하는 가요성 기재층(110) 및 오목부(111)를 충진하고 일면이 노출된 패턴층(120)을 포함한다.Referring to FIG. 1, a photomask 100 according to an exemplary embodiment fills a flexible substrate layer 110 and a concave portion 111 in which a concave portion 111 is positioned on one surface, and a pattern layer having one surface exposed ( 120).
가요성 기재층(110)은 가요성 물질을 포함할 수 있다. 포토마스크(100)가 가요성 기재층(110)을 포함함으로써, 포토마스크(100)가 포토레지스트층과 간극 없이 접촉할 수 있어 포토레지스트층의 노광 공정에서 회절 현상에 의한 해상력 저하를 예방할 수 있다.The flexible substrate layer 110 may include a flexible material. Since the photomask 100 includes the flexible substrate layer 110, the photomask 100 can contact the photoresist layer without a gap, thereby preventing a reduction in resolution due to diffraction in the exposure process of the photoresist layer. .
가요성 기재층(110)은 빛에 대한 투광성이 우수할 수 있다. 가요성 기재층(110)은, 예를 들면, 파장이 10nm 내지 600nm인 광에 대한 투과율이 80% 내지 99%일 수 있다. 가요성 기재층(110)의 투광성이 우수할 경우, 출력이 작은 광원을 이용할 수 있다. The flexible substrate layer 110 may have excellent light transmittance. The flexible substrate layer 110 may have a transmittance of 80% to 99% for light having a wavelength of 10 nm to 600 nm, for example. When the flexible substrate layer 110 has excellent light transmittance, a light source having a small output may be used.
가요성 기재층(110)은 가요성 물질로서, 예를 들면, 폴리디메틸실록산(PDMS, polydimethyl)을 포함할 수 있다. 폴리디메틸실록산(PDMS)을 가요성 기재층(110) 물질로서 사용할 경우, 투명성이 우수하면서도 가요성이 우수하여 컨택트 프린팅에 적합한 포토마스크를 제공할 수 있다.The flexible substrate layer 110 is a flexible material, and may include, for example, polydimethylsiloxane (PDMS). When polydimethylsiloxane (PDMS) is used as the material of the flexible substrate layer 110, it is possible to provide a photomask suitable for contact printing due to excellent transparency and excellent flexibility.
가요성 기재층(110)은 일면에 오목부(111)가 위치한다. 가요성 기재층(110)의 일면에 오목부(111)가 위치함으로써, 패턴층(120)이 가요성 기재층(110)에 삽입될(embedded) 수 있다.The flexible substrate layer 110 has a concave portion 111 positioned on one surface thereof. Since the concave portion 111 is positioned on one surface of the flexible substrate layer 110, the pattern layer 120 may be embedded in the flexible substrate layer 110.
패턴층(120)은 오목부(111)를 충진하고, 일면이 노출된다. 도 1을 참조하면, 패턴층(120)이 가요성 기재층(110)에 삽입되면서도 패턴층(120)의 일면이 포토마스크의 일면상에 노출될 수 있다.The pattern layer 120 fills the concave portion 111, and one surface is exposed. Referring to FIG. 1, while the pattern layer 120 is inserted into the flexible substrate layer 110, one surface of the pattern layer 120 may be exposed on the one surface of the photomask.
패턴층(120)은 차광성을 가져 포토마스크(100)에 조사된 광의 일부를 차단할 수 있다. 예를 들면, 패턴층(120)은 파장이 10nm 내지 600nm인 광에 대한 투과율이 0% 내지 10%일 수 있다.The pattern layer 120 has light blocking properties and may block a part of the light irradiated to the photomask 100. For example, the pattern layer 120 may have a transmittance of 0% to 10% for light having a wavelength of 10 nm to 600 nm.
패턴층(120)은 금속을 포함할 수 있다. 예를 들면, 패턴층(120)은 크롬을 포함할 수 있다. 크롬을 패턴층(120) 물질로서 사용할 경우, 공정성이 우수하여 차광성 패턴층을 용이하게 형성할 수 있다.The pattern layer 120 may include metal. For example, the pattern layer 120 may include chromium. When chromium is used as the material for the pattern layer 120, the processability is excellent, and the light-shielding pattern layer can be easily formed.
포토마스크(100)는 포토레지스트와 접촉하는 접촉면(130)을 포함할 수 있다.The photomask 100 may include a contact surface 130 in contact with the photoresist.
오목부(111)의 최대 깊이(d)와 패턴층(120)의 최대 두께(t)는 서로 대응된다. 오목부(111)의 최대 깊이(d)와 패턴층(120)의 최대 두께(t)가 서로 대응된다는 것은, 오목부(111)의 최대 깊이(d)와 패턴층(120)의 최대 두께(t)가 실질적으로 동일하다는 것을 의미할 수 있다.The maximum depth d of the concave portion 111 and the maximum thickness t of the pattern layer 120 correspond to each other. That the maximum depth d of the concave portion 111 and the maximum thickness t of the pattern layer 120 correspond to each other means that the maximum depth d of the concave portion 111 and the maximum thickness of the pattern layer 120 ( It can mean that t) is substantially the same.
오목부(111)의 최대 깊이(d)는 오목부(111)가 포토마스크(100)의 두께 방향으로 오목부(110)가 최대로 함몰된 정도를 의미할 수 있다. 오목부(111)의 최대 깊이(d)는, 예를 들면, 가요성 기재층(110)의 오목부(111)가 형성된 일면과 그 반대면 사이의 두께의 최소값과 최대값의 차이일 수 있다.The maximum depth d of the concave portion 111 may mean a degree in which the concave portion 111 is maximally depressed in the thickness direction of the photomask 100. The maximum depth d of the concave portion 111 may be, for example, a difference between a minimum value and a maximum value of a thickness between one surface of the flexible substrate layer 110 on which the concave portion 111 is formed and the opposite surface. .
오목부(111)의 최대 깊이(d)는, 예를 들어, 접촉면(130)이 평면 형상일 때에는 접촉면(130)으로부터 접촉면(130)에 수직인 방향으로 측정된 오복부(111)의 최대 깊이(d)를 의미할 수 있다. The maximum depth d of the concave portion 111 is, for example, the maximum depth of the concave portion 111 measured in a direction perpendicular to the contact surface 130 from the contact surface 130 when the contact surface 130 has a planar shape It can mean (d).
패턴층(120)의 최대 두께(t)는 오목부(111)를 충진하고 있는 패턴층(120)이 가지는, 포토마스크(100)의 두께 방향으로 측정된 두께의 최대값을 의미할 수 있다.The maximum thickness t of the pattern layer 120 may mean a maximum value of the thickness measured in the thickness direction of the photomask 100 of the pattern layer 120 filling the concave portion 111.
패턴층(120)의 최대 두께(t)는, 예를 들어, 접촉면(130)이 평면 형상일 때에는 접촉면(130)으로부터 접촉면(130)에 수직인 방향으로 측정된 패턴층(120)의 최대 두께(t)를 의미할 수 있다.The maximum thickness t of the pattern layer 120 is, for example, the maximum thickness of the pattern layer 120 measured in a direction perpendicular to the contact surface 130 from the contact surface 130 when the contact surface 130 has a flat shape. It can mean (t).
패턴층(120)의 일면에 복수의 오목부(111)가 위치할 경우, 오목부(111)의 최대 깊이(d) 및 패턴층(120)의 최대 두께(t)는 각각의 오목부에서 측정된 오목부(111)의 깊이 및 패턴층(120)의 두께를 의미할 수 있다.When a plurality of concave portions 111 are located on one side of the pattern layer 120, the maximum depth (d) of the concave portion 111 and the maximum thickness (t) of the pattern layer 120 are measured at each concave portion. It may mean the depth of the concave portion 111 and the thickness of the pattern layer 120.
오목부(111)의 최대 깊이(d)와 패턴층(120)의 최대 두께(t)가 서로 대응됨으로써, 패턴층(120)이 포토마스크의 접촉면(130)까지 오목부(111)를 충진할 수 있다. 따라서, 포토마스크(100)의 접촉면(130)이 포토레지스트와 접촉할 때 패턴층(120)의 엣지 부분과 포토레지스트의 간극이 최소화될 수 있다. 패턴층(120)의 엣지 부분과 포토레지스트의 간극이 최소화되면 빛이 패턴층(120)의 엣지 부분을 통과하면서 회절되어 해상력이 저하하는 문제를 해결할 수 있다.The maximum depth (d) of the concave portion 111 and the maximum thickness (t) of the pattern layer 120 correspond to each other, so that the pattern layer 120 can fill the concave portion 111 to the contact surface 130 of the photomask. I can. Accordingly, when the contact surface 130 of the photomask 100 contacts the photoresist, the gap between the edge portion of the pattern layer 120 and the photoresist can be minimized. When the gap between the edge portion of the pattern layer 120 and the photoresist is minimized, light diffracts while passing through the edge portion of the pattern layer 120 to reduce resolution.
패턴층(120)은 오목부(111)를 충진하여 접촉면(130)을 평탄화할 수 있다. 즉, 패턴층(120)은 접촉면(130)에서 패턴층(120)과 가요성 기재층(110)의 단차가 존재하지 않도록 오목부(111)를 충진할 수 있다.The pattern layer 120 may fill the concave portion 111 to planarize the contact surface 130. That is, the pattern layer 120 may fill the concave portion 111 so that there is no step difference between the pattern layer 120 and the flexible substrate layer 110 on the contact surface 130.
도 2를 참조하면, 접촉면(130)은 패턴층(120)의 일면이 노출된 패턴영역(131) 및 가요성 기재층(110)이 노출된 기재영역(132)으로 구분될 수 있다. 따라서, 접촉면(130)이 포토레지스트와 접촉할 때, 접촉면(130)을 구성하는 패턴영역(131) 및 기재영역(132)이 포토레지스트와 접촉하며, 패턴층(120)의 일면이 포토레지스트와 접촉할 수 있다. 포토마스크(100)가 전술한 구조를 가질 경우, 패턴층(120)과 포토레지스트의 간극이 최소화될 수 있으므로, 회절 현상에 의한 해상력 저하를 효과적으로 억제할 수 있다.Referring to FIG. 2, the contact surface 130 may be divided into a pattern region 131 in which one surface of the pattern layer 120 is exposed and a substrate region 132 in which the flexible substrate layer 110 is exposed. Accordingly, when the contact surface 130 contacts the photoresist, the pattern region 131 and the substrate region 132 constituting the contact surface 130 contact the photoresist, and one surface of the pattern layer 120 is in contact with the photoresist. I can contact you. When the photomask 100 has the above-described structure, since the gap between the pattern layer 120 and the photoresist can be minimized, a reduction in resolution due to diffraction can be effectively suppressed.
패턴영역(131) 및 기재영역(132)은 각각 평면 형상일 수 있다. 즉, 패턴층(120)의 노출된 일면은 평면 형상일 수 있으며, 가요성 기재층(110)의 오목부(111)가 위치하는 일면에서 패턴층(120)이 위치하지 않아 노출된 가요성 기재층(110) 부분도 평면 형상일 수 있다. 또한, 접촉면(130)도 평면 형상일 수 있다. 포토마스크(100)의 접촉면(130)이 평면 형상이므로, 접촉면(130)이 포토레지스트와 접촉할 때 패턴층(120)과 포토레지스트 사이의 간극이 최소화되어 회절현상에 의한 해상력 저하를 억제할 수 있다.The pattern region 131 and the substrate region 132 may each have a planar shape. That is, one exposed surface of the pattern layer 120 may have a planar shape, and the flexible substrate exposed because the pattern layer 120 is not located on one surface where the concave portion 111 of the flexible substrate layer 110 is located. A portion of the layer 110 may also have a planar shape. In addition, the contact surface 130 may also have a planar shape. Since the contact surface 130 of the photomask 100 is in a planar shape, the gap between the pattern layer 120 and the photoresist is minimized when the contact surface 130 contacts the photoresist, thereby suppressing deterioration of resolution due to diffraction. have.
패턴영역(131) 및 기재영역(132)은 동일 평면 상에 위치할 수 있다. 즉, 접촉면(130)에서 패턴층(120)과 가요성 기재층(110) 사이의 단차가 없을 수 있다. 패턴영역(131) 및 기재영역(132)이 동일한 평면 상에 위치할 경우, 포토마스크(100)가 포토레지스트에 접촉할 때 포토레지스트와 패턴층(120)의 간극을 최소화하면서도, 포토마스크의 하중이 가요성 기재층(110)에도 분산될 수 있어 포토레지스트와 패턴층(120)의 접촉에 의한 패턴층(120)의 손상을 예방할 수 있다.The pattern region 131 and the substrate region 132 may be located on the same plane. That is, there may be no step difference between the pattern layer 120 and the flexible substrate layer 110 on the contact surface 130. When the pattern region 131 and the substrate region 132 are located on the same plane, the load of the photomask is minimized while minimizing the gap between the photoresist and the pattern layer 120 when the photomask 100 contacts the photoresist. Since it may be dispersed in the flexible substrate layer 110, damage to the pattern layer 120 due to contact between the photoresist and the pattern layer 120 may be prevented.
도 3 내지 도 8은 일 실시예에 따른 포토마스크 제조방법을 도시한 도면이다.3 to 8 are diagrams illustrating a method of manufacturing a photomask according to an exemplary embodiment.
본 실시예를 설명함에 있어 이전 실시예와 동일 또는 대응되는 구성요소에 대한 설명은 생략하기로 한다. 이하, 이를 참조하여 본 발명의 실시예에 따른 포토마스크 제조방법에 대해 설명하기로 한다.In describing the present embodiment, descriptions of components that are the same as or corresponding to the previous embodiment will be omitted. Hereinafter, a method of manufacturing a photomask according to an embodiment of the present invention will be described with reference to this.
본 명세서의 일 실시예에 따른 포토마스크 제조방법은, 기판(140) 상에 돌출된 패턴층(120)을 형성하는 단계와, 전술한 기판(140) 상에 위치하고 전술한 돌출된 패턴층(120)을 덮는 가요성 기재층(110)을 형성하는 단계와, 전술한 가요성 기재층(110)을 전술한 기판(140)으로부터 박리하는 단계를 포함한다.A photomask manufacturing method according to an exemplary embodiment of the present specification includes the steps of forming the pattern layer 120 protruding on the substrate 140, and the protruding pattern layer 120 positioned on the substrate 140 and described above. ) Forming the flexible substrate layer 110 covering the ), and peeling the above-described flexible substrate layer 110 from the above-described substrate 140.
도 3은 기판(140) 상에 돌출된 패턴층(120)이 형성된 것을 나타낸 도면이다. 기판(140)의 종류는 특별히 제한되는 것은 아니나, 예를 들면, 실리콘층(Si), 실리콘 산화물층(SiO2) 및 희생층으로서 니켈(Ni) 층이 순차적으로 적층된 것을 사용할 수 있다.3 is a view showing that the pattern layer 120 protruding on the substrate 140 is formed. The type of the substrate 140 is not particularly limited, for example, a silicon layer (Si), a silicon oxide layer (SiO 2 ), and a nickel (Ni) layer sequentially stacked as a sacrificial layer may be used.
기판(140) 상에 돌출된 패턴층(120)을 형성하는 단계는, 예를 들면, 기판(140) 상에 포토레지스트층(150)을 형성하는 단계와, 포토레지스트층(150)을 패터닝하는 단계와, 패터닝된 포토레지스트층(150) 상에 패턴층(120))을 증착하는 단계와, 포토레지스트층(150)을 스트립하는 단계를 포함할 수 있다.Forming the pattern layer 120 protruding on the substrate 140 includes, for example, forming a photoresist layer 150 on the substrate 140 and patterning the photoresist layer 150. The steps may include depositing the pattern layer 120 on the patterned photoresist layer 150 and stripping the photoresist layer 150.
도 4는 기판(140) 상에 포토레지스트층(150)이 형성된 것을 나타낸 도면이다. 포토레지스트층(150)의 종류는 특별히 제한되는 것은 아니나, 예를 들면, 폴리메틸메타크릴레이트(PMMA, polymethylmethacrylate)를 사용할 수 있다. 포토레지스트층(150)을 기판(140) 상에 형성하는 방법은, 예를 들면, 포토레지스트 조성물을 기판(140) 상에 코팅하는 방법일 수 있다.4 is a view showing that a photoresist layer 150 is formed on the substrate 140. The type of the photoresist layer 150 is not particularly limited, but, for example, polymethylmethacrylate (PMMA) may be used. A method of forming the photoresist layer 150 on the substrate 140 may be, for example, a method of coating a photoresist composition on the substrate 140.
도 5는 기판(140) 상에 형성된 포토레지스트층(150)이 패터닝된 것을 나타낸 도면이다. 포토레지스트층(150)의 패터닝 방법은, 예를 들면, 전자빔 리소그래피(e-beam lithography)일 수 있다.5 is a diagram illustrating a patterned photoresist layer 150 formed on the substrate 140. A method of patterning the photoresist layer 150 may be, for example, e-beam lithography.
도 6은 패터닝된 포토레지스트층(150) 상에 패턴층(120)이 증착된 것을 나타낸 도면이다. 패턴층(120)의 증착 방법은, 예를 들면, 열 증착법, 플라즈마 증착법, 상압 증착법, 저압 증착법 등의 화학적 기상 증착법 또는 열 증착법, 전자빔증발법, 스퍼터링 등의 물리적 기상 증착법을 사용할 수 있다.6 is a diagram illustrating that the pattern layer 120 is deposited on the patterned photoresist layer 150. The deposition method of the pattern layer 120 may be, for example, a chemical vapor deposition method such as a thermal evaporation method, a plasma vapor deposition method, an atmospheric vapor deposition method, a low pressure vapor deposition method, or a physical vapor deposition method such as a thermal evaporation method, an electron beam evaporation method, or sputtering.
포토레지스트층(150)을 스트립하는 단계는, 도 6에 도시한 패터닝된 포토레지스트층(150) 상에 패턴층(120)이 증착된 단계에서 수행될 수 있다. 도 6에 도시한 단계에서 포토레지스트층(150)을 스트립하면, 포토레지스트층(150) 상에 위치하는 패턴층(120)도 함께 제거되면서, 도 3에 도시한 것과 같이 기판(140) 상에 돌출된 패턴층(120)이 형성될 수 있다.The step of stripping the photoresist layer 150 may be performed in a step in which the pattern layer 120 is deposited on the patterned photoresist layer 150 shown in FIG. 6. When the photoresist layer 150 is stripped in the step shown in FIG. 6, the pattern layer 120 disposed on the photoresist layer 150 is also removed, and The protruding pattern layer 120 may be formed.
도 7은 기판(140) 상에 위치하고, 돌출된 패턴층(120)을 덮는 가요성 기재층(110)을 형성된 것을 나타낸 도면이다. 가요성 기재층(110) 은, 예를 들면, 조성물을 코팅한 후 광경화 또는 열경화하는 방법에 의해 형성될 수 있다. 기판(140) 상에 돌출된 패턴층(120)이 형성된 상태에서 가요성 기재층(110)을 형성할 경우, 기재층(110)의 일면에 전술한 오목부가 형성될 수 있다.7 is a view showing that a flexible base layer 110 is formed on the substrate 140 and covers the protruding pattern layer 120. The flexible substrate layer 110 may be formed, for example, by a method of photocuring or thermosetting after coating the composition. When the flexible substrate layer 110 is formed while the pattern layer 120 protruding on the substrate 140 is formed, the aforementioned concave portion may be formed on one surface of the substrate layer 110.
도 8은 가요성 기재층(110)을 기판(140)으로부터 박리하는 것을 나타낸 도면이다. 가요성 기재층(110)을 박리하는 단계는, 가요성 기재층(110)과 함께 기판(140) 상에 형성된 돌출된 패턴층(120)을 박리하는 단계일 수 있다.FIG. 8 is a diagram illustrating peeling of the flexible substrate layer 110 from the substrate 140. The step of peeling the flexible substrate layer 110 may be a step of peeling the protruding pattern layer 120 formed on the substrate 140 together with the flexible substrate layer 110.
예를 들어, 폴리디메틸실록산(PDMS) 조성물을 기판(140) 및 패턴층(120) 상에 도포하고 경화한 후에 기재층(110)을 박리하면, 패턴층(120)까지 기판(140)으로부터 박리될 수 있다. 기재층(110)을 박리하는 단계에 의하여, 전술한 실시예에 따른 포토마스크가 제조될 수 있다.For example, if the substrate layer 110 is peeled after applying and curing a polydimethylsiloxane (PDMS) composition on the substrate 140 and the pattern layer 120, the pattern layer 120 is peeled off from the substrate 140 Can be. By peeling off the base layer 110, the photomask according to the above-described embodiment may be manufactured.
도 9는 본 명세서의 일 실시예에 따른 표시장치의 제조방법을 설명하기 위한 도면이다. 9 is a diagram for describing a method of manufacturing a display device according to an exemplary embodiment of the present specification.
본 실시예를 설명함에 있어 이전 실시예와 동일 또는 대응되는 구성요소에 대한 설명은 생략하기로 한다. 이하, 이를 참조하여 본 발명의 실시예에 따른 표시장치 제조방법에 대해 설명하기로 한다.In describing the present embodiment, descriptions of components that are the same as or corresponding to the previous embodiment will be omitted. Hereinafter, a method of manufacturing a display device according to an exemplary embodiment of the present invention will be described with reference to this.
도 9를 참조하면, 본 명세서의 일 실시예에 따른 표시장치의 제조방법은, 기판(141) 상에 위치하는 포토레지스트층(151)에 전술한 포토마스크의 패턴층(120)을 접촉시킨 상태에서 포토레지스트층(151)을 노광하는 단계를 포함한다.Referring to FIG. 9, in a method of manufacturing a display device according to an exemplary embodiment of the present specification, a photoresist layer 151 disposed on a substrate 141 is in contact with the pattern layer 120 of the photomask described above. And exposing the photoresist layer 151 to light.
기판(141)은 포토 리소그래피 공정에 의하여 패턴을 형성하고자 하는 기판으로서, 표시장치 분야에서 사용되는 것이라면 그 종류는 특별히 제한되지 않는다.The substrate 141 is a substrate on which a pattern is to be formed by a photolithography process, and its type is not particularly limited as long as it is used in the field of a display device.
포토레지스트층(151)은 포토 리소그래피 공정에 의하여 패턴을 형성하기 위하여 사용되는 감광성 층으로서, 표시장치 분야에서 사용되는 것이라면 그 종류는 특별히 제한되지 않는다.The photoresist layer 151 is a photosensitive layer used to form a pattern by a photolithography process, and its type is not particularly limited as long as it is used in the field of a display device.
도 9를 참조하면, 패턴층(120)이 포토레지스트층(151)에 직접 접촉한다. 또한, 가요성 기재층(110) 또한 포토레지스트층(151)에 직접 접촉할 수 있다.Referring to FIG. 9, the pattern layer 120 directly contacts the photoresist layer 151. In addition, the flexible substrate layer 110 may also directly contact the photoresist layer 151.
전술한 포토마스크를 사용할 경우, 패턴층(120)과 포토레지스트층(151) 사이에 간극이 존재하지 않으므로, 패턴층(120)과 포토레지스트층(151) 사이의 간극으로 인한 해상력 저하를 예방할 수 있다. When the above-described photomask is used, since there is no gap between the pattern layer 120 and the photoresist layer 151, it is possible to prevent a decrease in resolution due to the gap between the pattern layer 120 and the photoresist layer 151. have.
도 10은 비교예에 따른 표시장치의 제조방법을 설명하는 도면이다. 비교예에 따른 표시장치의 제조방법은, 포토마스크(200)가 기판(141) 상에 위치하는 포토레지스트층(151)과 특정한 간극(S)을 두고 이격되도록 위치하는 상태에서 포토레지스트층(151)에 대한 노광이 수행될 수 있다.10 is a diagram illustrating a method of manufacturing a display device according to a comparative example. In a method of manufacturing a display device according to the comparative example, the photoresist layer 151 is spaced apart from the photoresist layer 151 on the substrate 141 with a specific gap S. ) Can be performed.
예를 들어, 포토마스크(200)가 평평하면서 뻣뻣한 재질, 예를 들면, 파인 메탈 마스크(Fine metal mask)인 경우에는 포토마스크(200)와 포토레지스트층(151)의 접촉에 의하여 포토마스크(200)에 손상이 가해지는 것을 예방하기 위하여 특정한 간극(S)을 두고 포토마스크(200)가 배치될 수 있다.For example, when the photomask 200 is a flat and stiff material, for example, a fine metal mask, the photomask 200 is brought into contact with the photomask 200 and the photoresist layer 151. In order to prevent damage to ), the photomask 200 may be disposed with a specific gap S.
또 다른 예시에서, 기재 상에 돌출된 패턴층이 형성된 마스크를 사용할 경우에는, 돌출된 패턴층이 포토레지스트층과 접촉할 경우 패턴층에 손상이 가해질 수 있으므로, 접촉에 의한 포토마스크의 손상을 예방하기 위하여 특정한 간극을 두고 포토마스크가 배치될 수 있다.In another example, when a mask having a protruding pattern layer formed on a substrate is used, damage to the pattern layer may be applied when the protruding pattern layer contacts the photoresist layer, thus preventing damage to the photomask by contact. In order to do so, a photomask may be disposed with a specific gap.
포토마스크(200)와 포토레지스트층(151) 사이에 간극(S)이 존재할 경우에는 포토마스크(200)를 통과하는 빛이 회절에 의하여 포토마스크(200)에 의하여 차광되지 않는 문제가 발생할 수 있다. 예를 들어, 패턴층이 특정한 선폭(R)을 가지도록 형성되었음에도 포토리소그래피 공정에 의하여 상기 선폭(R)을 가지는 미세 패턴이 형성되지 않을 수 있다.If there is a gap S between the photomask 200 and the photoresist layer 151, there may be a problem that light passing through the photomask 200 is not blocked by the photomask 200 due to diffraction. . For example, even though the pattern layer is formed to have a specific line width R, a fine pattern having the line width R may not be formed by a photolithography process.
도 11은 도 10에 도시한 것과 같이 특정한 간극(S)을 두고 포토마스크가 배치된 상태에서 포토레지스트층을 노광할 경우 빛의 회절 현상에 의하여 포토리소그래피 공정의 해상력이 저하하는 것을 설명하기 위한 자료이다.11 is a data for explaining that the resolution of the photolithography process decreases due to the diffraction of light when the photoresist layer is exposed with a photomask disposed with a specific gap (S) as shown in FIG. 10 to be.
도 11을 참조하면, 도 10에 도시한 포토리소그래피 공정은 점선으로 표시한 것과 같이 광이 조사될 것을 의도한 것이나, 포토마스크(200)가 특정한 간극(S)만큼 포토레지스트층(151)과 이격된 상태에서 공정을 진행한 결과 실선으로 표시한 것과 같이 광이 조사된 것을 알 수 있다.Referring to FIG. 11, the photolithography process shown in FIG. 10 is intended to be irradiated with light as indicated by a dotted line, but the photomask 200 is spaced apart from the photoresist layer 151 by a specific gap S. It can be seen that the light was irradiated as indicated by a solid line as a result of proceeding the process in the state of being turned on.
본 명세서의 실시예에 따른 표시장치의 제조방법에 의할 경우, 포토마스크의 패턴층을 포토레지스트에 접촉시킨 상태로 포토레지스트층을 노광할 수 있으므로, 해상력 저하를 효과적으로 예방할 수 있다.In the case of the method of manufacturing a display device according to an exemplary embodiment of the present specification, since the photoresist layer can be exposed while the pattern layer of the photomask is in contact with the photoresist, deterioration of resolution can be effectively prevented.
도 12는 본 명세서의 일 실시예에 따른 포토마스크에 의할 경우 형성할 수 있는 미세 패턴을 설명하기 위한 자료이다.12 is data for explaining fine patterns that can be formed when using a photomask according to an exemplary embodiment of the present specification.
도 12는 400nm 내지 500nm의 파장을 가지는 광원과 본 명세서의 실시예에 따른 포토마스크를 이용하여 해상력 테스트 패턴 (USAF Resolving Power Test Target 1951)을 형성한 것이다. 기판(140) 상에 돌출된 패턴층(120)을 형성하였으며, 그 평면 사진은 b 및 e에 나타내었다. 전술한 기판(140) 상에 돌출된 패턴층(120)을 이용하여, 가요성 기재층(110) 및 패턴층(120)을 포함하는 포토마스크를 제조하였으며, 그 평면 사진은 c 및 f에 나타내었다. 전술한 포토마스크를 이용하여 기판(141) 상에 패터닝된 포토레지스트층(151)을 형성하였으며, 그 평면 사진은 d 및 g에 나타내었다. 도 12를 참고하면, DUV(Deep UV)나 EUV(Extreme UV) 같은 단파장이 아닌 400nm 내지 500nm의 광원을 사용하여, 파장의 약 1/10의 선폭인 51nm의 선폭을 가지는 포토레지스트층(151)이 형성된 것을 알 수 있다.12 is a view of forming a resolution test pattern (USAF Resolving Power Test Target 1951) using a light source having a wavelength of 400 nm to 500 nm and a photomask according to an embodiment of the present specification. A protruding pattern layer 120 was formed on the substrate 140, and plan photographs thereof are shown in b and e. Using the pattern layer 120 protruding on the above-described substrate 140, a photomask including the flexible substrate layer 110 and the pattern layer 120 was manufactured, and plan photographs are shown in c and f. I got it. A patterned photoresist layer 151 was formed on the substrate 141 by using the above-described photomask, and plan photographs thereof are shown in d and g. Referring to FIG. 12, a photoresist layer 151 having a line width of 51 nm, which is about 1/10 of a wavelength, using a light source of 400 nm to 500 nm rather than a short wavelength such as DUV (Deep UV) or EUV (Extreme UV). It can be seen that this was formed.
도 12를 참조하면, i를 통해 알 수 있듯이 포토마스크의 패턴층(120)의 선폭이 포토마스크를 이용하여 형성된 패터닝된 포토레지스트층(151)의 선폭에 효과적으로 반영되는 것을 알 수 있다.Referring to FIG. 12, it can be seen that the line width of the patterned layer 120 of the photomask is effectively reflected in the line width of the patterned photoresist layer 151 formed using the photomask, as can be seen through i.
도 13은 본 명세서의 실시예들에 따른 포토마스크에 의할 경우 형성할 수 있는 미세 패턴을 설명하기 위한 자료이다.13 is data for explaining fine patterns that can be formed when using a photomask according to embodiments of the present specification.
도 13은 본 명세서의 실시예들에 따른 포토마스크와 파장이 400nm 내지 500nm인 광원을 이용하여 라인 패턴(line patter) 및 닷 패턴(dot patter)을 형성한 것이다. 도 13을 통해 알 수 있듯이, 본 명세서의 실시예들에 따른 포토마스크를 사용할 경우 DUV(Deep UV)나 EUV(Extreme UV) 같은 단파장이 아닌 400nm 내지 500nm의 광원으로 60nm 및 160nm의 선폭을 가지는 라인 패턴 및 닷 패턴을 형성할 수 있다.13 illustrates a line pattern and a dot pattern formed by using a photomask and a light source having a wavelength of 400 nm to 500 nm according to exemplary embodiments of the present specification. As can be seen from FIG. 13, when the photomask according to the embodiments of the present specification is used, a line having a line width of 60 nm and 160 nm is a light source of 400 nm to 500 nm, not a short wavelength such as Deep UV (DUV) or Extreme UV (EUV). Patterns and dot patterns can be formed.
도 14는 본 명세서의 일 실시예에 따른 포토마스크를 이용하여 평면이 아닌 곡면상에 패턴을 형성한 것을 나타낸 자료이다.14 is data showing that a pattern is formed on a curved surface rather than a flat surface using a photomask according to an exemplary embodiment of the present specification.
250nm의 곡률반경을 가지는 구조물 위에 PET 기재를 위치시키고, 본 명세서의 실시예에 따른 포토마스크를 400nm 내지 500nm의 파장을 가지는 광원을 이용하여 노광을 실시하였다. 도 13을 참조하면, 곡률을 가지는 기재 위에서 노광을 실시하였음에도, 선폭이 38nm인 패턴이 형성되는 것을 알 수 있다. 본 명세서의 일 실시예에 따른 포토마스크는 일면에 오목부가 위치하는 가요성 기재층 및 오목부를 충진하는 패턴층을 포함하고, 오목부의 최대 깊이와 패턴층의 최대 두께가 서로 대응되는 특징을 가지기 때문에 포토마스크의 접촉면이 곡률을 가지는 기재에도 밀착될 수 있으며, 이로 인해 회절에 의한 해상력 저하를 예방할 수 있으므로 곡률을 가지는 기재 상에도 미세한 패턴을 형성할 수 있는 것으로 보인다.A PET substrate was placed on a structure having a radius of curvature of 250 nm, and a photomask according to an embodiment of the present specification was exposed using a light source having a wavelength of 400 nm to 500 nm. Referring to FIG. 13, it can be seen that even when exposure is performed on a substrate having a curvature, a pattern having a line width of 38 nm is formed. The photomask according to an embodiment of the present specification includes a flexible substrate layer in which a concave portion is located and a pattern layer that fills the concave portion, and the maximum depth of the concave portion and the maximum thickness of the pattern layer correspond to each other. The contact surface of the photomask may be in close contact with a substrate having a curvature, and thus, a reduction in resolution due to diffraction may be prevented, and thus a fine pattern may be formed even on a substrate having a curvature.
도 15는 본 명세서의 일 실시예에 따른 포토마스크를 이용하여 기재의 거친 표면 및 결점을 가지는 표면 위에 패턴을 형성한 것을 나타낸 자료이다.15 is a data showing that a pattern is formed on a rough surface of a substrate and a surface having defects by using a photomask according to an exemplary embodiment of the present specification.
나뭇잎을 이용하여 거친 표면을 형성하였다(a). 나뭇잎 표면은 플라스틱 기재보다 표면이 더 거칠며, 결점을 가지기 때문에 종래의 포토리소그래피 공정을 이용할 경우 패턴을 구현하기 어렵다. A rough surface was formed using leaves (a). The surface of the leaf is rougher than the plastic substrate and has defects, so it is difficult to implement a pattern when using a conventional photolithography process.
나뭇잎을 이용하여 형성된 거친 표면에 본 명세서의 일 실시예에 따른 포토마스크를 이용하여 패턴을 형성하였다(b, c, d, e, f, g). 본 명세서의 일 실시예에 따른 포토마스크를 이용한 결과, 나뭇잎의 표면이 거침에도 불구하고 패턴이 성공적으로 형성되는 것을 알 수 있다.A pattern was formed on a rough surface formed using leaves using a photomask according to an embodiment of the present specification (b, c, d, e, f, g). As a result of using the photomask according to the exemplary embodiment of the present specification, it can be seen that the pattern is successfully formed even though the surface of the leaf is rough.
또한, 컬(Curl), 스텝(Step) 및 킹크(Kink)와 같은 결점을 갖는 영역에도 패턴이 형성되었다(k, l, m). In addition, patterns were formed in areas with defects such as curl, step, and kink (k, l, m).
따라서, 본 명세서의 실시예들에 따른 포토마스크를 사용할 경우 포토마스크가 포토레지스트층의 표면 형상을 따라 밀착할 수 있으므로, 거친 표면이나 결점이 있는 영역에도 미세한 패턴을 형성할 수 있다.Therefore, when the photomask according to the embodiments of the present specification is used, since the photomask can adhere closely along the surface shape of the photoresist layer, a fine pattern can be formed even on a rough surface or a defective area.
도 16은 본 명세서의 실시예에 따른 포토마스크를 이용하여 제작한 반사형 디스플레이에 대한 자료이다.16 is data for a reflective display manufactured using a photomask according to an exemplary embodiment of the present specification.
가로 0.96mm, 세로 1.2mm 크기로 플라스모닉 나노 패턴을 이용하여 기재 상에 이미지를 구현하였다(b). 은(Ag) 기재에 본 명세서의 실시예에 따른 포토마스크를 이용하여 패터닝을 수행하여, 각기 다른 색상이 요구되는 부분에는 다른 크기를 가지는 플라즈모닉 나노 패턴을 형성하였다(c 내지 k).An image was implemented on the substrate using a plasmonic nano pattern with a size of 0.96 mm in width and 1.2 mm in height (b). Patterning was performed on a silver (Ag) substrate using a photomask according to an embodiment of the present specification, and plasmonic nanopatterns having different sizes were formed in portions requiring different colors (c to k).
본 명세서의 실시예에 따른 포토마스크를 이용하면 크기가 다양한 플라즈모닉 나노 패턴을 형성할 수 있으므로, 나노 크기의 패턴에서 반사되는 빛의 공명현상을 이용하여 반사형 디스플레이를 구현할 수 있다.When the photomask according to the embodiment of the present specification is used, plasmonic nano-patterns of various sizes can be formed, and thus a reflective display can be implemented by using a resonance phenomenon of light reflected from a nano-sized pattern.
도 17은 본 명세서의 실시예에 따른 포토마스크를 이용하여 제작한 반사형 디스플레이에 대한 자료이다.17 is data for a reflective display manufactured using a photomask according to an exemplary embodiment of the present specification.
본 명세서의 실시예에 따른 포토마스크를 이용하면 플라즈모닉 나노 패턴을 형성하여 다양한 색상을 구현한 반사형 디스플레이를 제조할 수 있다. 금속 기재의 종류 및 포토 레지스트의 두께에 따라 구현되는 컬러를 변화시킬 수 있으므로, 동일한 포토마스크를 이용하여도 금속 기재의 종류 및 포토 레지스트의 두께를 다르게 하여 다양한 컬러가 구현된 반사형 디스플레이를 제조할 수 있다.When the photomask according to the embodiment of the present specification is used, a reflective display having various colors can be manufactured by forming a plasmonic nano pattern. Since the implemented color can be changed according to the type of metal substrate and the thickness of the photoresist, even if the same photomask is used, the type of the metal substrate and the thickness of the photoresist can be changed to manufacture a reflective display in which various colors are implemented. I can.
이상 첨부된 도면을 참조하여 본 명세서의 실시예들을 더욱 상세하게 설명하였으나, 본 명세서는 반드시 이러한 실시예로 국한되는 것은 아니고, 본 명세서의 기술사상을 벗어나지 않는 범위 내에서 다양하게 변형 실시될 수 있다. 따라서, 본 명세서에 개시된 실시예들은 본 명세서의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 실시예에 의하여 본 명세서의 기술 사상의 범위가 한정되는 것은 아니다. 그러므로, 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다. 본 명세서의 보호 범위는 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 명세서의 권리범위에 포함되는 것으로 해석되어야 할 것이다.Although the embodiments of the present specification have been described in more detail with reference to the accompanying drawings, the present specification is not necessarily limited to these embodiments, and various modifications may be made without departing from the spirit of the present specification. . Accordingly, the embodiments disclosed in the present specification are not intended to limit the technical idea of the present specification, but to describe, and the scope of the technical idea of the present specification is not limited by these exemplary embodiments. Therefore, it should be understood that the embodiments described above are illustrative and non-limiting in all respects. The scope of protection of the present specification should be construed by the claims, and all technical ideas within the scope equivalent thereto should be construed as being included in the scope of the present specification.
[부호의 설명][Explanation of code]
100: 포토마스크100: photomask
110: 기재층110: base layer
111: 오목부111: recess
120: 패턴층120: pattern layer
130: 접촉면130: contact surface
131: 패턴영역131: pattern area
132: 기재영역132: substrate area
140: 기판140: substrate
150: 포토레지스트층150: photoresist layer
CROSS-REFERENCE TO RELATED APPLICATIONCROSS-REFERENCE TO RELATED APPLICATION
본 특허출원은 2019년 08월 23일 한국에 출원한 특허출원번호 제 10-2019-0103926 호에 대해 미국 특허법 119(a)조 (35 U.S.C § 119(a))에 따라 우선권을 주장하며, 그 모든 내용은 참고문헌으로 본 특허출원에 병합된다. 아울러, 본 특허출원은 미국 이외에 국가에 대해서도 위와 동일한 이유로 우선권을 주장하면 그 모든 내용은 참고문헌으로 본 특허출원에 병합된다.This patent application claims priority in accordance with Article 119(a) of the U.S. Patent Law (35 USC § 119(a)) with respect to Patent Application No. 10-2019-0103926 filed in Korea on August 23, 2019. All contents are incorporated into this patent application by reference. In addition, if this patent application claims priority for countries other than the United States for the same reason as above, all the contents are incorporated into this patent application as references.

Claims (14)

  1. 일면에 오목부가 위치하는 가요성 기재층; 및A flexible substrate layer in which a concave portion is located on one side; And
    상기 오목부를 충진하고, 일면이 노출된 패턴층을 포함하며,Filling the concave portion, including a pattern layer exposed on one side,
    상기 오목부의 최대 깊이와 상기 패턴층의 최대 두께가 서로 대응되는 포토마스크.A photomask in which a maximum depth of the concave portion and a maximum thickness of the pattern layer correspond to each other.
  2. 제 1항에 있어서,The method of claim 1,
    상기 패턴층의 일면이 노출된 패턴영역 및 상기 가요성 기재층이 노출된 기재영역으로 구분되는 접촉면을 포함하는 포토마스크.A photomask comprising a contact surface divided into a pattern region in which one surface of the pattern layer is exposed and a substrate region in which the flexible substrate layer is exposed.
  3. 제 2항에 있어서,The method of claim 2,
    상기 패턴층은 상기 오목부를 충진하여 상기 접촉면을 평탄화하는 포토마스크.The pattern layer is a photomask for flattening the contact surface by filling the concave portion.
  4. 제 2항에 있어서,The method of claim 2,
    상기 패턴영역 및 상기 기재영역은 각각 평면 형상인 포토마스크.The pattern area and the substrate area are each planar photomask.
  5. 제 2항에 있어서,The method of claim 2,
    상기 접촉면은 평면 형상인 포토마스크.The contact surface is a planar photomask.
  6. 제 2항에 있어서,The method of claim 2,
    상기 패턴영역 및 상기 기재영역은 동일 평면 상에 위치하는 포토마스크.The pattern region and the substrate region are a photomask positioned on the same plane.
  7. 제 1항에 있어서,The method of claim 1,
    상기 가요성 기재층은 파장이 10nm 내지 600nm인 광에 대한 투과율이 80% 내지 99% 인 포토마스크.The flexible substrate layer is a photomask having a transmittance of 80% to 99% for light having a wavelength of 10 nm to 600 nm.
  8. 제 1항에 있어서,The method of claim 1,
    상기 패턴층은 파장이 10nm 내지 600nm인 광에 대한 투과율이 0% 내지 10% 인 포토마스크.The pattern layer is a photomask having a transmittance of 0% to 10% for light having a wavelength of 10 nm to 600 nm.
  9. 제 1항에 있어서,The method of claim 1,
    상기 가요성 기재층은 폴리디메틸실록산을 포함하는 포토마스크.The flexible substrate layer is a photomask comprising polydimethylsiloxane.
  10. 제 1항에 있어서,The method of claim 1,
    상기 패턴층은 크롬을 포함하는 포토마스크.The pattern layer is a photomask containing chromium.
  11. 기판 상에 돌출된 패턴층을 형성하는 단계;Forming a pattern layer protruding on the substrate;
    상기 기판 상에 위치하고, 상기 돌출된 패턴층을 덮는 가요성 기재층을 형성하는 단계; 및Forming a flexible substrate layer on the substrate and covering the protruding pattern layer; And
    상기 가요성 기재층을 상기 기판으로부터 박리하는 단계를 포함하는 포토마스크 제조방법.A photomask manufacturing method comprising the step of peeling the flexible substrate layer from the substrate.
  12. 제 11항에 있어서,The method of claim 11,
    상기 기판 상에 돌출된 패턴층을 형성하는 단계는,Forming the pattern layer protruding on the substrate,
    상기 기판 상에 포토레지스트층을 형성하는 단계;Forming a photoresist layer on the substrate;
    상기 포토레지스트층을 패터닝하는 단계;Patterning the photoresist layer;
    상기 패터닝된 포토레지스트층 상에 패턴층을 증착하는 단계; 및Depositing a pattern layer on the patterned photoresist layer; And
    상기 포토레지스트층을 스트립하는 단계를 포함하는 포토마스크 제조방법. A photomask manufacturing method comprising the step of stripping the photoresist layer.
  13. 제 11항에 있어서,The method of claim 11,
    상기 가요성 기재층을 박리하는 단계는 상기 기판 상에 형성된 돌출된 패턴층 및 상기 가요성 기재층을 박리하는 단계인 포토마스크 제조방법.The step of peeling the flexible substrate layer is a step of peeling the protruding pattern layer and the flexible substrate layer formed on the substrate.
  14. 기판 상에 위치하는 포토레지스트층에 제 1항의 포토마스크의 패턴층을 접촉시킨 상태에서 상기 포토레지스트층을 노광하는 단계를 포함하는 표시장치의 제조방법.A method of manufacturing a display device comprising the step of exposing the photoresist layer in a state in which the pattern layer of the photomask of claim 1 is in contact with the photoresist layer positioned on a substrate.
PCT/KR2020/011003 2019-08-23 2020-08-19 Photomask, method for manufacturing same, and method for manufacturing display device using same WO2021040309A1 (en)

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US20090130573A1 (en) * 2005-05-19 2009-05-21 Searete Llc, A Limited Liability Corporation Of The State Of Delaware Multilayer active mask lithography
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