WO2021003765A1 - Flexible and easy-to-clean power generation and development composite center control cover plate for vehicles and manufacturing method therefor - Google Patents

Flexible and easy-to-clean power generation and development composite center control cover plate for vehicles and manufacturing method therefor Download PDF

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Publication number
WO2021003765A1
WO2021003765A1 PCT/CN2019/096371 CN2019096371W WO2021003765A1 WO 2021003765 A1 WO2021003765 A1 WO 2021003765A1 CN 2019096371 W CN2019096371 W CN 2019096371W WO 2021003765 A1 WO2021003765 A1 WO 2021003765A1
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Prior art keywords
ito glass
parts
spin
prepared
coated
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PCT/CN2019/096371
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French (fr)
Chinese (zh)
Inventor
张敬敏
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山东光韵智能科技有限公司
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Publication of WO2021003765A1 publication Critical patent/WO2021003765A1/en
Priority to ZA2021/06141A priority Critical patent/ZA202106141B/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B05D3/0272—After-treatment with ovens
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0493—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases using vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B05D7/574—Three layers or more the last layer being a clear coat at least some layers being let to dry at least partially before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K37/00—Dashboards
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00—Other substrates
    • B05D2203/30—Other inorganic substrates, e.g. ceramics, silicon
    • B05D2203/35—Glass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Definitions

  • the present invention relates to the technical field of vehicle accessories, in particular to a flexible and easy-to-clean power generation and development composite central control cover for vehicles and a manufacturing method thereof.
  • the central control of an automobile is a place to control comfortable entertainment devices such as automobile air conditioning and audio.
  • the material of the cover plate of the automobile central control is generally PP.
  • the high-quality cover plate in the prior art is still based on the PP after foaming modification treatment to obtain a light weight and soft touch plastic. Essentially the same.
  • the unavoidable problem is that the copolymer type PP material has only a low heat distortion temperature (100°C), low transparency, low gloss, low rigidity, and is easy to absorb dust and oil in the car, making it difficult to clean.
  • the typical failure mode is that the cover plate will inevitably be deformed and scrapped after the airbag in the car is ejected, or blistering after exposure to material defects (such as Nissan Sylphy has exposed the cover plate blistering problem Prosecute).
  • material defects such as Nissan Sylphy has exposed the cover plate blistering problem Prosecute.
  • PP polypropylene
  • the material has other inherent defects: 1. The product has poor cold resistance and low low-temperature impact strength. 2. Products are susceptible to aging due to light, heat and oxygen during use. 3. The colorability is not good. 4. Easy to burn. 5. High static electricity, poor dyeability, printability and adhesion.
  • the central control cover in the prior art is only used for structural integrity support and shape modification. It occupies a large visible area in the car but has a single function and has little effect. Because of its pure black color, it is easy to absorb light and heat, which is the interior of the car.
  • the main heat absorption source of summer high temperature (of course, in order to drive safety and the front glass does not reflect the cover plate to affect the driving vision, the central control cover plate must be guaranteed to be black), these light and heat are wasted in vain, and for the convenience of people, It is often necessary to renovate the central control to add display equipment (such as car navigation, reversing impact and multimedia playback devices, etc.). On the one hand, it causes additional secondary costs and on the other hand, it brings hidden dangers to the safety of line transformation. Therefore, there is an urgent need in the market for a central control cover that adds an auxiliary control system, lowers the temperature in the car, integrates power generation and collection, and has its own development function and a soft and easy-to-clean surface.
  • the purpose of the present invention is to provide a central control cover that adds an auxiliary control system, lowers the temperature in the vehicle, integrates power generation and collection, and has a developing function and a soft and easy-to-clean surface.
  • the present invention adopts the following technical solution: a flexible and easy-to-clean power-generating and developing composite central control cover for vehicles, characterized in that the central control cover is divided into two parts: a light-receiving area and a functional area.
  • the area is provided with seven layers of upper lining layer, upper ITO glass, upper absorption layer, hole conduction layer, lower absorption layer, lower ITO glass, and bottom lining layer from top to bottom; the functional area includes auxiliary integrated circuits arranged under the cover plate.
  • the control center, the display screen fixed on the front middle of the central control cover and controlled by the auxiliary integrated electric control center.
  • the auxiliary integrated electric control center includes an electrochemical capacitive energy storage device connected to the upper and lower ITO glass through wires, and The electrochemical capacitor energy storage device is connected in parallel with the main battery of the car.
  • the integrated voltage multiplier is a DC stabilized power supply with an output voltage of 12V, a processing chip that supplies energy through a 12V DC stabilized power supply, and a 12V DC stabilized power supply supplies energy.
  • Memory and I/O channels, the display screen includes a touch structure under the screen and a display panel powered by a 12V DC power supply;
  • the manufacturing method of the light receiving area includes the following steps:
  • Step 1 Prepare two curved ITO glass plates prepared in step 1), and apply the zinc powder prepared in step 1) step 2 to the upper surfaces of the two ITO glass plates evenly.
  • Stage 1) The hydrochloric acid aqueous solution prepared in step 2 is slowly dripped on the zinc powder until the zinc powder is completely wetted, and kept for 2min-3min.
  • the hydrochloric acid aqueous solution and the zinc powder are washed with ethanol and deionized water respectively until they are completely cleaned, and two pieces are obtained.
  • step 2 Invert the single-sided etched ITO glass obtained in step 1, and then repeat step 1 to obtain two double-sided etched ITO glasses, namely the upper ITO glass to be used and the lower ITO glass to be used;
  • step 1 3Mix the tetrabutyl titanate and diethanolamine prepared in step 1) step 1 with 150 to 160 parts by weight of ethanol, and stir for 1.5h-2h at a rate of 600rpm/min-800rpm/min to obtain a mixed solution A; Mix 15-17 parts by weight of deionized water and 75-80 parts of ethanol to form an alcohol-water mixed solution, which is mixed liquid B; mix and stir evenly with mixed liquid A and mixed liquid B to obtain mixed liquid C, the mixed liquid C is allowed to stand for 28h-30h in a closed environment, and the mixed liquid C is solized to obtain the sol liquid C;
  • step 2 the upper and lower surfaces of the upper and lower ITO glass to be used and the upper surface of the lower ITO glass to be used are spin-coated to obtain spin-coated ITO glass and spin-coated ITO glass;
  • step 5 Put the spin-coated ITO glass and spin-coated ITO glass obtained in step 4 in a resistance furnace, and bake at a temperature of 460°C-480°C for 80min-100min to obtain prefabricated top ITO glass and prefabricated bottom ITO glass;
  • step 6 Mix 2 to 2.5 parts by weight of lead iodide prepared in step 1) in step 1 with 5 parts to 6 parts of N,N dimethyl diamide, and heat to 75°C-80°C to iodide The lead is completely dissolved and mixed liquid D is obtained;
  • step 8 Mix the product a obtained in step 7 with the isopropanol prepared in step 2 of step 1) into a mixture E with a solid content concentration of 9mg/ml-12mg/ml;
  • the lower surface of the prefabricated upper ITO glass 2 and the upper surface of the prefabricated lower ITO glass 6 obtained in step 5 are uniformly spin-coated at a spin-coating rate of 1500rpm/min-1600rpm/min and a spin-coating time of 65s-70s.
  • step 8 put the spin-coated prefabricated upper ITO glass and prefabricated lower ITO glass in a vacuum environment and completely dry at 65°C-70°C, and then completely immerse the dried upper ITO glass and lower ITO glass in the step 8 In the obtained mixture E, keep it for 25min-30min, and then under the protection of sufficient nitrogen prepared in step 1) step 2, completely dry it at 65°C-70°C and then cool it to room temperature to obtain the final ITO glass 2 and ITO glass 6 under final production;
  • Step 1 Prepare the carbon nanotube film, and the obtained composite structure is the required light receiving area.
  • the present invention Compared with the prior art, the present invention has the following advantages: (1) An auxiliary control system is added.
  • the present invention essentially adds a set of auxiliary electronic control system controlled by a 12V power supply similar to a mobile phone outside the main electronic control system of the car.
  • the existence of this system firstly solves the corresponding power supply problems including the cigarette lighter and the central control display screen (under sufficient sunlight, with the photoelectric conversion rate of the present invention of about 17%, the power supply can be fully charged in one round of sunlight.
  • the battery capacity of the invented DC power supply can be set according to the actual situation. It is recommended to use a capacity of about 20 amp-hours. There is no problem with continuous supply of cigarette lighter, display and sound power for two hours).
  • the temperature inside the car is lowered. No matter what season (even in winter), under sunny conditions, the temperature inside the car will be 10°C-20°C higher than the outside when parking outdoors. The sultry inside the car will not only affect people's physical comfort In addition, the excessively high temperature in the car can easily lead to accelerated aging and even partial denaturation and decomposition of related materials such as plastic and artificial leather in the car to release toxic and harmful substances.
  • the present invention can significantly reduce the temperature difference between the inside and outside of the car by converting part of the light energy (the actual measurement is about 2°C-4 °C temperature difference), play a positive role.
  • the power generation, collection and use of electricity are integrated, with its own development function, and has a good market prospect.
  • ITO glass itself is a smooth and hard material, which is easy to clean actively.
  • the titanium dioxide gel film is cured after the surface is etched. It feels soft and the photocatalyst effect of titanium dioxide will consume part of the ultraviolet energy and reduce the temperature rise in the car. This part can reduce about 1°C). On the other hand, it can disinfect and sterilize and improve the air quality in the car.
  • the present invention has the characteristics of adding an auxiliary control system, lowering the temperature in the vehicle, integrating power generation and collection, and has the characteristics of a developing function and a soft and easy-to-clean surface.
  • Fig. 1 is a front view of the forest belt of the present invention
  • Fig. 2 is a sectional view of A-A in Fig. 1;
  • upper lining layer 1 upper ITO glass 2, upper absorption layer 3, hole conduction layer 4, lower absorption layer 5, lower ITO glass 6, underlaying layer 7, auxiliary integrated electric control center 8, display screen 9.
  • a flexible, easy-to-clean power-generating and developing composite central control cover plate for vehicles is divided into two parts: a light-receiving area and a functional area.
  • the light-receiving area is provided with an upper lining layer 1 and an upper ITO glass 2 from top to bottom. 7.
  • the upper absorption layer 3, the hole conduction layer 4, the lower absorption layer 5, the lower ITO glass 6, and the backing layer 7 have seven layers;
  • the functional area includes an auxiliary integrated electric control center 8 arranged under the cover plate, which is fixed in the central control
  • the manufacturing method of the light receiving area includes the following steps:
  • Step 1 Prepare two curved ITO glass plates prepared in step 1), and apply the zinc powder prepared in step 1) step 2 to the upper surfaces of the two ITO glass plates evenly.
  • Stage 1) The hydrochloric acid aqueous solution prepared in step 2 is slowly dripped on the zinc powder until the zinc powder is completely wetted, and kept for 2min-3min.
  • the hydrochloric acid aqueous solution and the zinc powder are washed with ethanol and deionized water respectively until they are completely cleaned, and two pieces are obtained.
  • step 2 Invert the single-sided etched ITO glass obtained in step 1, and then repeat step 1 to obtain two double-sided etched ITO glass, namely the upper ITO glass 2 to be used and the lower ITO glass 6 to be used;
  • step 2 the upper and lower surfaces of the upper ITO glass 2 to be used and the upper surface of the lower ITO glass 6 to be used are spin-coated to obtain the spin-coated ITO glass 2 and the spin-coated ITO glass 6;
  • step 5 Put the spin-coated ITO glass 2 and spin-coated ITO glass 6 obtained in step 4 in a resistance furnace, and bake at a temperature of 460°C-480°C for 80min-100min to obtain prefabricated ITO glass 2 and prefabricated ITO glass 6;
  • step 8 Mix the product a obtained in step 7 with the isopropanol prepared in step 2 of step 1) into a mixture E with a solid content concentration of 9mg/ml-12mg/ml;
  • the lower surface of the prefabricated upper ITO glass 2 and the upper surface of the prefabricated lower ITO glass 6 obtained in step 5 are uniformly spin-coated at a spin-coating rate of 1500rpm/min-1600rpm/min and a spin-coating time of 65s-70s. Then put the spin-coated prefabricated upper ITO glass 2 and prefabricated lower ITO glass 6 in a vacuum environment and completely dry at 65°C-70°C, and then dry the upper ITO glass 2 and lower ITO glass 6 Completely immerse in the mixture E obtained in step 8, keep it for 25min-30min, and then under the protection of sufficient nitrogen gas prepared in step 1) step 2, use 65°C-70°C to completely dry and cool to room temperature to obtain the final product. ITO glass 2 and final ITO glass 6;
  • the coating rate and the spin coating time of 32s-35s are respectively spin-coated on the lower surface of the final upper ITO glass 2 and the upper surface of the final lower ITO glass 6 obtained in step 9, and then the spin-coated final ITO glass 2
  • the bottom surface of the ITO glass 6 is closely attached to the top surface of the final ITO glass 6 in a vacuum environment, and dried under the protection of a sufficient amount of nitrogen for 35min-40min, and the furnace is cooled to room temperature and then taken out.
  • the lower surface of the glass 6 is closely attached to the fixing stage 1) Step 1 Prepare the carbon nanotube film, and the obtained composite structure is the required light receiving area.
  • the backing layer of the present invention is made of black light-absorbing material, which will not cause the negative effects of reflection and glare and affect driving.
  • the overall photoelectric conversion rate of the light-receiving area is 16.8%-17.5%, which can achieve low energy consumption and turn harm into profit.
  • the internal temperature is 3°C-5°C, and it also has the function of multimedia terminal, the same below.
  • Example 2 The whole is the same as Example 1. The difference is that the manufacturing method of the light-receiving area includes the following steps: 1) Preparation of raw materials 1 Preparation of raw materials: prepare iodine with a molar concentration of 52mol/L-58mol/L in parts by weight Hydrogen ethanol solution 9Kg, aminomethane 16Kg, sufficient lead iodide, tetrabutyl titanate 55Kg, diethanolamine 15Kg, poly-3hexylthiophene 1Kg, sufficient 70nm thick carbon nanotube film;
  • Example 3 The whole is the same as Example 1. The difference is that the manufacturing method of the light-receiving area includes the following steps: 1) Preparation of raw materials 1 Preparation of raw materials: prepare iodine with a molar concentration of 52mol/L-58mol/L in parts by weight Hydrogen ethanol solution 12Kg, aminomethane 18Kg, sufficient lead iodide, tetrabutyl titanate 50Kg, diethanolamine 12Kg, poly-3hexylthiophene 1.2Kg, sufficient 120nm thick carbon nanotube film;
  • the invention has the characteristics of adding an auxiliary control system, lowering the temperature in the vehicle, integrating power generation and collection, and has the characteristics of a developing function and a soft and easy-to-clean surface.

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Abstract

Disclosed in the present invention are a flexible and easy-to-clean power generation and development composite center control cover plate for vehicles and a manufacturing method therefor. The center control cover plate is divided into two parts, i.e., a light receiving area and a function area; the light receiving area is provided, from top to bottom, with seven layers, i.e., an upper lining layer, upper ITO glass, an upper absorbing layer, a hole conducting layer, a lower absorbing layer, lower ITO glass and a bottom lining layer; the function area comprises an auxiliary integrated electric control center and a display screen, wherein the auxiliary integrated electric control center comprises an electrochemical capacitance energy storage device, a 12 V direct-current voltage-stabilized power supply, a processing chip to which energy is supplied by means of the 12 V direct-current voltage-stabilized power supply, a memory, and an I/O passage, and the display screen comprises an in-screen touch control structure and a development panel. According to the present invention, the auxiliary control system is added, the temperature in a vehicle is reduced, electricity generation, electricity collection and electricity utilization are integrated, the developing function is achieved, and the surface is soft and easy to clean.

Description

一种车用柔质易洁发电显影复合中控盖板及其制造方法Flexible and easy-cleaning power-generating and developing composite central control cover plate for vehicle and manufacturing method thereof 技术领域Technical field
技术领域本发明涉及车用配件技术领域，尤其涉及一种车用柔质易洁发电显影复合中控盖板及其制造方法。TECHNICAL FIELD The present invention relates to the technical field of vehicle accessories, in particular to a flexible and easy-to-clean power generation and development composite central control cover for vehicles and a manufacturing method thereof.
背景技术Background technique
背景技术汽车中控是控制汽车空调、音响等舒适娱乐装置的地方。现有技术中，汽车中控的盖板的材料一般为PP材质，现有技术中优质的盖板也仍是在PP的基础上采用发泡改性处理后获得质轻、触感柔软的塑料，本质上是一样的。但无可避免的问题在于：共聚物型的PP材料仅有较低的热变形温度（100℃）、低透明度、低光泽度、低刚性，且易吸附车内灰尘和油污，形成较难洁净和较易失效的车内饰部件之一，典型的失效模式就是车内气囊弹出后盖板必然变形报废，或因材料缺陷暴晒后起泡（如日产轩逸就有曝出过盖板起泡问题起诉）。而在2017年10月27日，世界卫生组织国际癌症研究机构公布的致癌物清单初步整理参考，聚丙烯（即PP）在3类致癌物清单中。同时，该材料还有其它固有缺陷：1、制品耐寒性差，低温冲击强度低。2、制品在使用中易受光、热和氧的作用而老化。3、着色性不好。4、易燃烧。5、静电度高，染色性、印刷性和黏合性差。BACKGROUND OF THE INVENTION The central control of an automobile is a place to control comfortable entertainment devices such as automobile air conditioning and audio. In the prior art, the material of the cover plate of the automobile central control is generally PP. The high-quality cover plate in the prior art is still based on the PP after foaming modification treatment to obtain a light weight and soft touch plastic. Essentially the same. But the unavoidable problem is that the copolymer type PP material has only a low heat distortion temperature (100°C), low transparency, low gloss, low rigidity, and is easy to absorb dust and oil in the car, making it difficult to clean. And one of the car interior parts that are more prone to failure, the typical failure mode is that the cover plate will inevitably be deformed and scrapped after the airbag in the car is ejected, or blistering after exposure to material defects (such as Nissan Sylphy has exposed the cover plate blistering problem Prosecute). On October 27, 2017, the list of carcinogens published by the International Agency for Research on Cancer of the World Health Organization was initially compiled for reference, and polypropylene (ie PP) was included in the list of three types of carcinogens. At the same time, the material has other inherent defects: 1. The product has poor cold resistance and low low-temperature impact strength. 2. Products are susceptible to aging due to light, heat and oxygen during use. 3. The colorability is not good. 4. Easy to burn. 5. High static electricity, poor dyeability, printability and adhesion.
技术问题technical problem
现有技术中的中控盖板其作用仅仅用作结构完整性支撑和外形修饰，占车内可视面积大但功能单一且作用不大，由于其颜色纯黑易吸光吸热，是车内夏季高温的主要吸热源（当然，为了行车安全和前挡玻璃不倒映盖板影响驾驶视线，中控盖板必须保证为黑色），这些光和热白白浪费掉了，而人们为了方便使用，往往还必须自已改造中控增加显示设备（如车载导航、倒车影响和多媒体播放装置等），一方面造成额外的二次成本，另一方面带来线路改造安全隐患。因此，市面上急需一种增加辅控系统、降低车内温度、发电集电用电一体化、自身具备显影功能、表面柔软易洁的中控盖板。The central control cover in the prior art is only used for structural integrity support and shape modification. It occupies a large visible area in the car but has a single function and has little effect. Because of its pure black color, it is easy to absorb light and heat, which is the interior of the car. The main heat absorption source of summer high temperature (of course, in order to drive safety and the front glass does not reflect the cover plate to affect the driving vision, the central control cover plate must be guaranteed to be black), these light and heat are wasted in vain, and for the convenience of people, It is often necessary to renovate the central control to add display equipment (such as car navigation, reversing impact and multimedia playback devices, etc.). On the one hand, it causes additional secondary costs and on the other hand, it brings hidden dangers to the safety of line transformation. Therefore, there is an urgent need in the market for a central control cover that adds an auxiliary control system, lowers the temperature in the car, integrates power generation and collection, and has its own development function and a soft and easy-to-clean surface.
技术解决方案Technical solutions
发明内容本发明旨在提供一种增加辅控系统、降低车内温度、发电集电用电一体化、自身具备显影功能、表面柔软易洁的中控盖板。SUMMARY OF THE INVENTION The purpose of the present invention is to provide a central control cover that adds an auxiliary control system, lowers the temperature in the vehicle, integrates power generation and collection, and has a developing function and a soft and easy-to-clean surface.
为了实现上述目的，本发明采用以下技术方案：一种车用柔质易洁发电显影复合中控盖板，其特征在于：该中控盖板分为受光区和功能区两个部分，其中受光区由上至下设置有上衬层、上ITO玻璃、上吸收层、空穴传导层、下吸收层、下ITO玻璃、底衬层七层；功能区包括设置在盖板下方的辅助集成电控中心、固定在中控盖板正面中部受辅助集成电控中心控制的显示屏，其中辅助集成电控中心包括通过导线与上ITO玻璃和下ITO玻璃相连接的电化学电容能量存储装置、将电化学电容能量存储装置与汽车主电瓶并连的集成有电压倍增器的输出电压为12V的直流稳压电源、通过12V直流稳压电源供给能量的处理芯片、通过12V直流稳压电源供给能量的存储器及I/O通道，显示屏包括屏下触控结构和通过12V直流稳压电源供给能量的显像面板；In order to achieve the above objective, the present invention adopts the following technical solution: a flexible and easy-to-clean power-generating and developing composite central control cover for vehicles, characterized in that the central control cover is divided into two parts: a light-receiving area and a functional area. The area is provided with seven layers of upper lining layer, upper ITO glass, upper absorption layer, hole conduction layer, lower absorption layer, lower ITO glass, and bottom lining layer from top to bottom; the functional area includes auxiliary integrated circuits arranged under the cover plate. The control center, the display screen fixed on the front middle of the central control cover and controlled by the auxiliary integrated electric control center. The auxiliary integrated electric control center includes an electrochemical capacitive energy storage device connected to the upper and lower ITO glass through wires, and The electrochemical capacitor energy storage device is connected in parallel with the main battery of the car. The integrated voltage multiplier is a DC stabilized power supply with an output voltage of 12V, a processing chip that supplies energy through a 12V DC stabilized power supply, and a 12V DC stabilized power supply supplies energy. Memory and I/O channels, the display screen includes a touch structure under the screen and a display panel powered by a 12V DC power supply;
其中，受光区的制造方法包括以下步骤：Among them, the manufacturing method of the light receiving area includes the following steps:
1）原材料准备1) Preparation of raw materials
①原材料准备：按重量份准备摩尔浓度52mol/L-58mol/L的碘化氢乙醇溶液9份-12份、氨基甲烷16份-18份、足量碘化铅、钛酸四丁酯50份-55份、二乙醇胺12份-15份、聚-3己基噻吩1份-1.2份、足量70nm-120nm厚的碳纳米管薄膜、足量弧形ITO玻璃板；①Preparation of raw materials: prepare 9-12 parts of hydrogen iodide ethanol solution with molar concentration of 52mol/L-58mol/L, 16-18 parts of aminomethane, sufficient lead iodide, 50 parts of tetrabutyl titanate according to weight parts -55 parts, 12-15 parts of diethanolamine, 1 part-1.2 parts of poly-3hexylthiophene, sufficient carbon nanotube film of 70nm-120nm thickness, and sufficient curved ITO glass plate;
②辅材准备：准备足量无水乙醇、足量乙醚、足量N,N二甲基二酰胺、足量氮气、足量二氯苯、足量异丙醇、足量锌粉、足量溶质质量分数20%的盐酸水溶液、足量去离子水；② Preparation of auxiliary materials: prepare enough absolute ethanol, enough ether, enough N,N dimethyl diamide, enough nitrogen, enough dichlorobenzene, enough isopropanol, enough zinc powder, enough Hydrochloric acid aqueous solution with 20% solute mass fraction, sufficient deionized water;
2）受光区制造方法2) Manufacturing method of light receiving area
①准备两块阶段1）步骤①准备的弧形ITO玻璃板，将阶段1）步骤②准备的锌粉分别均匀涂抹在两块ITO玻璃板的上表面上，涂抹至目视完全覆盖，然后将阶段1）步骤②准备的盐酸水溶液缓慢滴加在锌粉上直至锌粉完全润湿，保持2min-3min，将盐酸水溶液和锌粉采用乙醇和去离子水分别清洗至完全清洗干净，获得两块单面润蚀ITO玻璃；①Prepare two curved ITO glass plates prepared in step 1), and apply the zinc powder prepared in step 1) step ② to the upper surfaces of the two ITO glass plates evenly. Stage 1) The hydrochloric acid aqueous solution prepared in step ② is slowly dripped on the zinc powder until the zinc powder is completely wetted, and kept for 2min-3min. The hydrochloric acid aqueous solution and the zinc powder are washed with ethanol and deionized water respectively until they are completely cleaned, and two pieces are obtained. Etching ITO glass on one side;
②将步骤①获得的单面润蚀ITO玻璃翻转，然后重复一次步骤①，获得两块双面润蚀ITO玻璃，即为待用上ITO玻璃和待用下ITO玻璃；②Invert the single-sided etched ITO glass obtained in step ①, and then repeat step ① to obtain two double-sided etched ITO glasses, namely the upper ITO glass to be used and the lower ITO glass to be used;
③将阶段1）步骤①准备的钛酸四丁酯、二乙醇胺与按重量份计的150份-160份乙醇混合均匀，以600rpm/min-800rpm/min的速率搅拌1.5h-2h，获得混液A；将按重量份计的15份-17份去离子水与75份-80份乙醇混配成醇水混溶液，即为混液B；将混液A和混液B混合并搅拌均匀后，获得混液C，将混液C在密闭环境内静置28h-30h，混液C溶胶化，获得溶胶液C；③Mix the tetrabutyl titanate and diethanolamine prepared in step 1) step ① with 150 to 160 parts by weight of ethanol, and stir for 1.5h-2h at a rate of 600rpm/min-800rpm/min to obtain a mixed solution A; Mix 15-17 parts by weight of deionized water and 75-80 parts of ethanol to form an alcohol-water mixed solution, which is mixed liquid B; mix and stir evenly with mixed liquid A and mixed liquid B to obtain mixed liquid C, the mixed liquid C is allowed to stand for 28h-30h in a closed environment, and the mixed liquid C is solized to obtain the sol liquid C;
④将步骤③获得的溶胶液C以1200rpm/min-1300rpm/min的旋涂速率，每次45s-50s的旋涂时间，旋涂两次，涂层干结后厚度150nm-180nm的工艺，分别在步骤②获得的待用上ITO玻璃的上下两个表面及待用下ITO玻璃的上表面进行旋涂处理，获得旋涂上ITO玻璃和旋涂下ITO玻璃；④Spin the sol solution C obtained in step ③ at a spin-coating speed of 1200rpm/min-1300rpm/min, each spin-coating time of 45s-50s, spin coating twice, the thickness of the coating after drying is 150nm-180nm, respectively In step ②, the upper and lower surfaces of the upper and lower ITO glass to be used and the upper surface of the lower ITO glass to be used are spin-coated to obtain spin-coated ITO glass and spin-coated ITO glass;
⑤将步骤④获得的旋涂上ITO玻璃和旋涂下ITO玻璃置于电阻炉中，采用460℃-480℃的温度烘烤80min-100min，获得预制上ITO玻璃和预制下ITO玻璃；⑤ Put the spin-coated ITO glass and spin-coated ITO glass obtained in step ④ in a resistance furnace, and bake at a temperature of 460℃-480℃ for 80min-100min to obtain prefabricated top ITO glass and prefabricated bottom ITO glass;
  ⑥将阶段1）步骤①准备的按重量份计的碘化铅2份-2.5份与5份-6份的N,N二甲基二酰胺混合均匀，加热至75℃-80℃至碘化铅完全溶解，获得混液D；⑥ Mix 2 to 2.5 parts by weight of lead iodide prepared in step 1) in step ① with 5 parts to 6 parts of N,N dimethyl diamide, and heat to 75℃-80℃ to iodide The lead is completely dissolved and mixed liquid D is obtained;
⑦将阶段1）步骤①准备的碘化氢乙醇溶液和氨基甲烷混合均匀，然后在冰水浴0℃环境内持续搅拌45min-50min，然后边搅拌边加热至55℃-60℃直至完全烘干，将烘干产物与按重量份计250份-280份的乙醚混合均匀，重结晶后抽滤，将抽滤获得的固体在真空下采用55℃-60℃完全烘干，获得待用产物a；⑦Mix the ethanol solution of hydrogen iodide and aminomethane prepared in step 1) in step ①, and then keep stirring for 45min-50min in an ice-water bath at 0℃, and then heat to 55℃-60℃ while stirring until it is completely dried. Mix the dried product with 250-280 parts by weight of ethyl ether uniformly, recrystallize and filter with suction, and dry the solid obtained by suction at 55°C-60°C under vacuum to obtain product a for use;
⑧将步骤⑦获得的待用产物a与阶段1）步骤②准备的异丙醇混配成固含物浓度9mg/ml-12mg/ml的混液E；⑧ Mix the product a obtained in step ⑦ with the isopropanol prepared in step ② of step 1) into a mixture E with a solid content concentration of 9mg/ml-12mg/ml;
⑨在步骤⑤获得的预制上ITO玻璃2的下表面和预制下ITO玻璃6的上表面，以1500rpm/min-1600rpm/min的旋涂速率，65s-70s的旋涂时间均匀旋涂步骤⑥获得的全部混液D，然后将旋涂后的预制上ITO玻璃和预制下ITO玻璃置于真空环境内采用65℃-70℃完全烘干，然后将烘干的上ITO玻璃和下ITO玻璃完全浸入步骤⑧获得的混液E中，保持25min-30min，然后在阶段1）步骤②准备的足量氮气保护下，采用65℃-70℃完全烘干然后炉冷至室温，获得终制上ITO玻璃2和终制下ITO玻璃6；⑨The lower surface of the prefabricated upper ITO glass 2 and the upper surface of the prefabricated lower ITO glass 6 obtained in step ⑤ are uniformly spin-coated at a spin-coating rate of 1500rpm/min-1600rpm/min and a spin-coating time of 65s-70s. Then put the spin-coated prefabricated upper ITO glass and prefabricated lower ITO glass in a vacuum environment and completely dry at 65℃-70℃, and then completely immerse the dried upper ITO glass and lower ITO glass in the step ⑧ In the obtained mixture E, keep it for 25min-30min, and then under the protection of sufficient nitrogen prepared in step 1) step ②, completely dry it at 65℃-70℃ and then cool it to room temperature to obtain the final ITO glass 2 and ITO glass 6 under final production;
⑩将阶段1）步骤①准备的聚-3己基噻吩与阶段1）步骤②准备的二氯苯混配成质量浓度10mg/ml的混液F，将混液F以750rpm/min-800rpm/min的旋涂速率、32s-35s的旋涂时间分别旋涂在步骤⑨获得的终制上ITO玻璃的下表面和终制下ITO玻璃的上表面，然后将旋涂好的终制上ITO玻璃的下表面和终制下ITO玻璃的上表面在真空环境内紧密贴合，并在足量氮气保护下烘干35min-40min，随炉冷至室温后取出，在取出物原终制下ITO玻璃的下表面紧密贴合固定阶段1）步骤①准备的碳纳米管薄膜，获得的复合结构即为所需受光区。⑩The poly-3hexylthiophene prepared in step 1) in step ① and the dichlorobenzene prepared in step ② in step 1) are mixed into mixed solution F with a mass concentration of 10mg/ml, and the mixed solution F is rotated at 750rpm/min-800rpm/min. The coating rate and the spin coating time of 32s-35s are respectively spin-coated on the lower surface of the final ITO glass and the upper surface of the final ITO glass obtained in step ⑨, and then the spin-coated final ITO glass is applied to the lower surface Closely adhere to the upper surface of the final ITO glass in a vacuum environment, and dry under the protection of sufficient nitrogen for 35min-40min, then take it out after cooling to room temperature in the furnace, and the lower surface of the ITO glass after the original final product is taken out Closely fitting and fixing stage 1) Step ① Prepare the carbon nanotube film, and the obtained composite structure is the required light receiving area.
有益效果Beneficial effect
与现有技术相比较，本发明具有以下优点：（1）增加辅控系统，本发明实质上在车的主电控系外增设了一套类似于手机的12V电源支配的辅助电控系统，这套系统的存在一是解决了包括点烟器、中控显示屏相应的供电问题（日光充足的情况下，以本发明17%左右的光电转换率，一轮日晒即可充满电源，本发明的直流电源电池容量可根据实情设置，推荐使用20安时左右的容量，持续供给点烟、显示及声音用电两小时没有任何问题），二是变相增大了整车电能总容量，且为主电瓶亏电或老化后临时启动点火提供了备用电源，三是节约了后期改造费用，降低了电路系统改造带来的风险、隐患。（2）降低了车内温度，无论哪个季节（哪怕是冬季），阳光充足的条件下，户外停车时车内温度都会高于外界10℃-20℃，车内闷热不仅会影响人的体感舒适，而且过高的车内温度易导致车内塑料、人造革等相关材料加速老化甚至部分变性分解释放有毒有害物质，本发明通过转换部分光能能明显降低车内外温差（实测约降低2℃-4℃的温差），起到正面作用。（3）本发电集电用电一体化、自身具备显影功能，具有很好的市场前景。（4）ITO玻璃本身就是光滑硬质材料，易主动清洁，表面润蚀后固化了二氧化钛凝胶膜，手感柔软，且二氧化钛的光触媒作用一方面会消耗部分紫外线的能量，降低车内温升（这部分能降低1℃左右），另一方面能消毒除菌，改善车内空气质量，最主要的是，用于本发明时，表层的二氧化钛层带来的超亲水表面实际上是具有莲花效应的自洁面，有良好的自洁效果。因而本发明具有增加辅控系统、降低车内温度、发电集电用电一体化、自身具备显影功能、表面柔软易洁的特性。Compared with the prior art, the present invention has the following advantages: (1) An auxiliary control system is added. The present invention essentially adds a set of auxiliary electronic control system controlled by a 12V power supply similar to a mobile phone outside the main electronic control system of the car. The existence of this system firstly solves the corresponding power supply problems including the cigarette lighter and the central control display screen (under sufficient sunlight, with the photoelectric conversion rate of the present invention of about 17%, the power supply can be fully charged in one round of sunlight. The battery capacity of the invented DC power supply can be set according to the actual situation. It is recommended to use a capacity of about 20 amp-hours. There is no problem with continuous supply of cigarette lighter, display and sound power for two hours). It provides backup power for the temporary ignition of the main battery after it loses electricity or is aging. The third is to save the cost of later transformation and reduce the risks and hidden dangers caused by the circuit system transformation. (2) The temperature inside the car is lowered. No matter what season (even in winter), under sunny conditions, the temperature inside the car will be 10℃-20℃ higher than the outside when parking outdoors. The sultry inside the car will not only affect people's physical comfort In addition, the excessively high temperature in the car can easily lead to accelerated aging and even partial denaturation and decomposition of related materials such as plastic and artificial leather in the car to release toxic and harmful substances. The present invention can significantly reduce the temperature difference between the inside and outside of the car by converting part of the light energy (the actual measurement is about 2℃-4 ℃ temperature difference), play a positive role. (3) The power generation, collection and use of electricity are integrated, with its own development function, and has a good market prospect. (4) ITO glass itself is a smooth and hard material, which is easy to clean actively. The titanium dioxide gel film is cured after the surface is etched. It feels soft and the photocatalyst effect of titanium dioxide will consume part of the ultraviolet energy and reduce the temperature rise in the car. This part can reduce about 1℃). On the other hand, it can disinfect and sterilize and improve the air quality in the car. The most important thing is that when used in the present invention, the super-hydrophilic surface brought by the titanium dioxide layer on the surface actually has a lotus Effective self-cleaning face with good self-cleaning effect. Therefore, the present invention has the characteristics of adding an auxiliary control system, lowering the temperature in the vehicle, integrating power generation and collection, and has the characteristics of a developing function and a soft and easy-to-clean surface.
附图说明Description of the drawings
图1是本发明林带的正视图；图2是图1的A-A剖示图；Fig. 1 is a front view of the forest belt of the present invention; Fig. 2 is a sectional view of A-A in Fig. 1;
     图中：上衬层1、上ITO玻璃2、上吸收层3、空穴传导层4、下吸收层5、下ITO玻璃6、底衬层7、辅助集成电控中心8、显示屏9。... In the figure: upper lining layer 1, upper ITO glass 2, upper absorption layer 3, hole conduction layer 4, lower absorption layer 5, lower ITO glass 6, underlaying layer 7, auxiliary integrated electric control center 8, display screen 9.
本发明的最佳实施方式The best mode of the invention
实施例1：Example 1:
一种车用柔质易洁发电显影复合中控盖板，该中控盖板分为受光区和功能区两个部分，其中受光区由上至下设置有上衬层1、上ITO玻璃2、上吸收层3、空穴传导层4、下吸收层5、下ITO玻璃6、底衬层7共七层；功能区包括设置在盖板下方的辅助集成电控中心8、固定在中控盖板正面中部受辅助集成电控中心8控制的显示屏9，其中辅助集成电控中心8包括通过导线与上ITO玻璃2和下ITO玻璃6相连接的电化学电容能量存储装置、将电化学电容能量存储装置与汽车主电瓶并连的集成有电压倍增器的输出电压为12V的直流稳压电源、通过12V直流稳压电源供给能量的处理芯片、通过12V直流稳压电源供给能量的存储器及I/O通道，显示屏9包括屏下触控结构和通过12V直流稳压电源供给能量的显像面板；A flexible, easy-to-clean power-generating and developing composite central control cover plate for vehicles. The central control cover plate is divided into two parts: a light-receiving area and a functional area. The light-receiving area is provided with an upper lining layer 1 and an upper ITO glass 2 from top to bottom. 7. The upper absorption layer 3, the hole conduction layer 4, the lower absorption layer 5, the lower ITO glass 6, and the backing layer 7 have seven layers; the functional area includes an auxiliary integrated electric control center 8 arranged under the cover plate, which is fixed in the central control The display screen 9 controlled by the auxiliary integrated electric control center 8 in the middle of the front of the cover plate, wherein the auxiliary integrated electric control center 8 includes an electrochemical capacitive energy storage device connected to the upper ITO glass 2 and the lower ITO glass 6 through wires, and the electrochemical The capacitive energy storage device is connected in parallel with the main battery of the car, and is integrated with a voltage multiplier and an output voltage of 12V DC stabilized power supply, a processing chip that supplies energy through a 12V DC stabilized power supply, a memory that supplies energy through a 12V DC stabilized power supply, and I/O channel, the display screen 9 includes a touch structure under the screen and a display panel supplied with energy through a 12V DC power supply;
其中，受光区的制造方法包括以下步骤：Among them, the manufacturing method of the light receiving area includes the following steps:
1）原材料准备1) Preparation of raw materials
①原材料准备：准备摩尔浓度52mol/L-58mol/L的碘化氢乙醇溶液10.4Kg、氨基甲烷17.2Kg、足量碘化铅、钛酸四丁酯51.6Kg、二乙醇胺14.2Kg、聚-3己基噻吩1.14Kg、足量100nm厚的碳纳米管薄膜、两块与设计尺寸相适应的弧形ITO玻璃板；① Preparation of raw materials: prepare a molar concentration of 52mol/L-58mol/L hydrogen iodide ethanol solution 10.4Kg, aminomethane 17.2Kg, sufficient lead iodide, tetrabutyl titanate 51.6Kg, diethanolamine 14.2Kg, poly-3 1.14Kg of hexylthiophene, a carbon nanotube film with a thickness of 100nm, and two curved ITO glass plates adapted to the design size;
②辅材准备：准备足量无水乙醇、足量乙醚、足量N,N二甲基二酰胺、足量氮气、足量二氯苯、足量异丙醇、足量锌粉、足量溶质质量分数20%的盐酸水溶液、足量去离子水；② Preparation of auxiliary materials: prepare enough absolute ethanol, enough ether, enough N,N dimethyl diamide, enough nitrogen, enough dichlorobenzene, enough isopropanol, enough zinc powder, enough Hydrochloric acid aqueous solution with 20% solute mass fraction, sufficient deionized water;
2）受光区制造方法2) Manufacturing method of light receiving area
①准备两块阶段1）步骤①准备的弧形ITO玻璃板，将阶段1）步骤②准备的锌粉分别均匀涂抹在两块ITO玻璃板的上表面上，涂抹至目视完全覆盖，然后将阶段1）步骤②准备的盐酸水溶液缓慢滴加在锌粉上直至锌粉完全润湿，保持2min-3min，将盐酸水溶液和锌粉采用乙醇和去离子水分别清洗至完全清洗干净，获得两块单面润蚀ITO玻璃；①Prepare two curved ITO glass plates prepared in step 1), and apply the zinc powder prepared in step 1) step ② to the upper surfaces of the two ITO glass plates evenly. Stage 1) The hydrochloric acid aqueous solution prepared in step ② is slowly dripped on the zinc powder until the zinc powder is completely wetted, and kept for 2min-3min. The hydrochloric acid aqueous solution and the zinc powder are washed with ethanol and deionized water respectively until they are completely cleaned, and two pieces are obtained. Etching ITO glass on one side;
②将步骤①获得的单面润蚀ITO玻璃翻转，然后重复一次步骤①，获得两块双面润蚀ITO玻璃，即为待用上ITO玻璃2和待用下ITO玻璃6；②Invert the single-sided etched ITO glass obtained in step ①, and then repeat step ① to obtain two double-sided etched ITO glass, namely the upper ITO glass 2 to be used and the lower ITO glass 6 to be used;
③将阶段1）步骤①准备的钛酸四丁酯、二乙醇胺与按重量份计的150Kg-160Kg乙醇混合均匀，以600rpm/min-800rpm/min的速率搅拌1.5h-2h，获得混液A；将按重量份计的15Kg-17Kg去离子水与75Kg-80Kg乙醇混配成醇水混溶液，即为混液B；将混液A和混液B混合并搅拌均匀后，获得混液C，将混液C在密闭环境内静置28h-30h，混液C溶胶化，获得溶胶液C；③Mix the tetrabutyl titanate and diethanolamine prepared in step 1) and 150Kg-160Kg ethanol in parts by weight uniformly, and stir for 1.5h-2h at a rate of 600rpm/min-800rpm/min to obtain mixed solution A; Mix 15Kg-17Kg deionized water and 75Kg-80Kg ethanol in parts by weight to form an alcohol-water mixed solution, which is mixed solution B; mix and stir evenly with mixed solution A and mixed solution B to obtain mixed solution C. Let stand for 28h-30h in a closed environment, and the mixed liquid C is solized to obtain sol liquid C;
④将步骤③获得的溶胶液C以1200rpm/min-1300rpm/min的旋涂速率，每次45s-50s的旋涂时间，旋涂两次，涂层干结后厚度150nm-180nm的工艺，分别在步骤②获得的待用上ITO玻璃2的上下两个表面及待用下ITO玻璃6的上表面进行旋涂处理，获得旋涂上ITO玻璃2和旋涂下ITO玻璃6；④Spin the sol solution C obtained in step ③ at a spin-coating speed of 1200rpm/min-1300rpm/min, each spin-coating time of 45s-50s, spin coating twice, the thickness of the coating after drying is 150nm-180nm, respectively In step ②, the upper and lower surfaces of the upper ITO glass 2 to be used and the upper surface of the lower ITO glass 6 to be used are spin-coated to obtain the spin-coated ITO glass 2 and the spin-coated ITO glass 6;
⑤将步骤④获得的旋涂上ITO玻璃2和旋涂下ITO玻璃6置于电阻炉中，采用460℃-480℃的温度烘烤80min-100min，获得预制上ITO玻璃2和预制下ITO玻璃6；⑤ Put the spin-coated ITO glass 2 and spin-coated ITO glass 6 obtained in step ④ in a resistance furnace, and bake at a temperature of 460℃-480℃ for 80min-100min to obtain prefabricated ITO glass 2 and prefabricated ITO glass 6;
⑥将阶段1）步骤①准备的按重量份计的碘化铅2Kg-2.5Kg与5Kg-6Kg的N,N二甲基二酰胺混合均匀，加热至75℃-80℃至碘化铅完全溶解，获得混液D；⑥ Mix the lead iodide 2Kg-2.5Kg and 5Kg-6Kg N,N dimethyl diamide prepared in step 1) by weight, and heat to 75℃-80℃ until lead iodide is completely dissolved , Obtain mixed liquid D;
⑦将阶段1）步骤①准备的碘化氢乙醇溶液和氨基甲烷混合均匀，然后在冰水浴0℃环境内持续搅拌45min-50min，然后边搅拌边加热至55℃-60℃直至完全烘干，将烘干产物与按重量份计250Kg-280Kg的乙醚混合均匀，重结晶后抽滤，将抽滤获得的固体在真空下采用55℃-60℃完全烘干，获得待用产物a；⑦Mix the ethanol solution of hydrogen iodide and aminomethane prepared in step 1) in step ①, and then keep stirring for 45min-50min in an ice-water bath at 0℃, and then heat to 55℃-60℃ while stirring until it is completely dried. Mix the dried product with 250Kg-280Kg of ether in parts by weight uniformly, recrystallize and filter with suction, and dry the solid obtained by the suction filter at 55°C-60°C under vacuum to obtain the ready-to-use product a;
⑧将步骤⑦获得的待用产物a与阶段1）步骤②准备的异丙醇混配成固含物浓度9mg/ml-12mg/ml的混液E；⑧ Mix the product a obtained in step ⑦ with the isopropanol prepared in step ② of step 1) into a mixture E with a solid content concentration of 9mg/ml-12mg/ml;
⑨在步骤⑤获得的预制上ITO玻璃2的下表面和预制下ITO玻璃6的上表面，以1500rpm/min-1600rpm/min的旋涂速率，65s-70s的旋涂时间均匀旋涂步骤⑥获得的全部混液D，然后将旋涂后的预制上ITO玻璃2和预制下ITO玻璃6置于真空环境内采用65℃-70℃完全烘干，然后将烘干的上ITO玻璃2和下ITO玻璃6完全浸入步骤⑧获得的混液E中，保持25min-30min，然后在阶段1）步骤②准备的足量氮气保护下，采用65℃-70℃完全烘干然后炉冷至室温，获得终制上ITO玻璃2和终制下ITO玻璃6；⑨The lower surface of the prefabricated upper ITO glass 2 and the upper surface of the prefabricated lower ITO glass 6 obtained in step ⑤ are uniformly spin-coated at a spin-coating rate of 1500rpm/min-1600rpm/min and a spin-coating time of 65s-70s. Then put the spin-coated prefabricated upper ITO glass 2 and prefabricated lower ITO glass 6 in a vacuum environment and completely dry at 65℃-70℃, and then dry the upper ITO glass 2 and lower ITO glass 6 Completely immerse in the mixture E obtained in step ⑧, keep it for 25min-30min, and then under the protection of sufficient nitrogen gas prepared in step 1) step ②, use 65℃-70℃ to completely dry and cool to room temperature to obtain the final product. ITO glass 2 and final ITO glass 6;
⑩将阶段1）步骤①准备的聚-3己基噻吩与阶段1）步骤②准备的二氯苯混配成质量浓度10mg/ml的混液F，将混液F以750rpm/min-800rpm/min的旋涂速率、32s-35s的旋涂时间分别旋涂在步骤⑨获得的终制上ITO玻璃2的下表面和终制下ITO玻璃6的上表面，然后将旋涂好的终制上ITO玻璃2的下表面和终制下ITO玻璃6的上表面在真空环境内紧密贴合，并在足量氮气保护下烘干35min-40min，随炉冷至室温后取出，在取出物原终制下ITO玻璃6的下表面紧密贴合固定阶段1）步骤①准备的碳纳米管薄膜，获得的复合结构即为所需受光区。⑩The poly-3hexylthiophene prepared in step 1) in step ① and the dichlorobenzene prepared in step ② in step 1) are mixed into mixed solution F with a mass concentration of 10mg/ml, and the mixed solution F is rotated at 750rpm/min-800rpm/min. The coating rate and the spin coating time of 32s-35s are respectively spin-coated on the lower surface of the final upper ITO glass 2 and the upper surface of the final lower ITO glass 6 obtained in step ⑨, and then the spin-coated final ITO glass 2 The bottom surface of the ITO glass 6 is closely attached to the top surface of the final ITO glass 6 in a vacuum environment, and dried under the protection of a sufficient amount of nitrogen for 35min-40min, and the furnace is cooled to room temperature and then taken out. The lower surface of the glass 6 is closely attached to the fixing stage 1) Step ① Prepare the carbon nanotube film, and the obtained composite structure is the required light receiving area.
本发明的底衬层为黑色吸光材料，不会造成反光刺眼、影响驾驶的负面效果，受光区的整体光电转换率为16.8%-17.5%，能低能耗实现变害为利，平均可降低车内温度3℃-5℃，还具有多媒体终端的功能，下同。The backing layer of the present invention is made of black light-absorbing material, which will not cause the negative effects of reflection and glare and affect driving. The overall photoelectric conversion rate of the light-receiving area is 16.8%-17.5%, which can achieve low energy consumption and turn harm into profit. The internal temperature is 3℃-5℃, and it also has the function of multimedia terminal, the same below.
本发明的实施方式Embodiments of the invention
实施例2：整体与实施例1一致，差异之处在于：其中，受光区的制造方法包括以下步骤：1）原材料准备①原材料准备：按重量份准备摩尔浓度52mol/L-58mol/L的碘化氢乙醇溶液9Kg、氨基甲烷16Kg、足量碘化铅、钛酸四丁酯55Kg、二乙醇胺15Kg、聚-3己基噻吩1Kg、足量70nm厚的碳纳米管薄膜；Example 2: The whole is the same as Example 1. The difference is that the manufacturing method of the light-receiving area includes the following steps: 1) Preparation of raw materials ① Preparation of raw materials: prepare iodine with a molar concentration of 52mol/L-58mol/L in parts by weight Hydrogen ethanol solution 9Kg, aminomethane 16Kg, sufficient lead iodide, tetrabutyl titanate 55Kg, diethanolamine 15Kg, poly-3hexylthiophene 1Kg, sufficient 70nm thick carbon nanotube film;
　实施例3：整体与实施例1一致，差异之处在于：其中，受光区的制造方法包括以下步骤：1）原材料准备①原材料准备：按重量份准备摩尔浓度52mol/L-58mol/L的碘化氢乙醇溶液12Kg、氨基甲烷18Kg、足量碘化铅、钛酸四丁酯50Kg、二乙醇胺12Kg、聚-3己基噻吩1.2Kg、足量120nm厚的碳纳米管薄膜；Example 3: The whole is the same as Example 1. The difference is that the manufacturing method of the light-receiving area includes the following steps: 1) Preparation of raw materials ① Preparation of raw materials: prepare iodine with a molar concentration of 52mol/L-58mol/L in parts by weight Hydrogen ethanol solution 12Kg, aminomethane 18Kg, sufficient lead iodide, tetrabutyl titanate 50Kg, diethanolamine 12Kg, poly-3hexylthiophene 1.2Kg, sufficient 120nm thick carbon nanotube film;
工业实用性Industrial applicability
本发明具有增加辅控系统、降低车内温度、发电集电用电一体化、自身具备显影功能、表面柔软易洁的特性。The invention has the characteristics of adding an auxiliary control system, lowering the temperature in the vehicle, integrating power generation and collection, and has the characteristics of a developing function and a soft and easy-to-clean surface.
序列表自由内容Sequence Listing Free Content
对所公开的实施例的上述说明，仅为了使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的，本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下，在其它实施例中实现。因此，本发明将不会被限制于本文所示的这些实施例，而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments is only to enable those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be obvious to those skilled in the art, and the general principles defined herein can be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention will not be limited to the embodiments shown in this document, but should conform to the widest scope consistent with the principles and novel features disclosed in this document.

Claims (1)

  1. 一种车用柔质易洁发电显影复合中控盖板，其特征在于：该中控盖板分为受光区和功能区两个部分，其中受光区由上至下设置有上衬层(1)、上ITO玻璃(2)、上吸收层(3)、空穴传导层(4)、下吸收层(5)、下ITO玻璃(6)、底衬层(7)共七层；功能区包括设置在盖板下方的辅助集成电控中心(8)、固定在中控盖板正面中部受辅助集成电控中心(8)控制的显示屏(9)，其中辅助集成电控中心(8)包括通过导线与上ITO玻璃(2)和下ITO玻璃(6)相连接的电化学电容能量存储装置、将电化学电容能量存储装置与汽车主电瓶并连的集成有电压倍增器的输出电压为12V的直流稳压电源、通过12V直流稳压电源供给能量的处理芯片、通过12V直流稳压电源供给能量的存储器及I/O通道，显示屏(9)包括屏下触控结构和通过12V直流稳压电源供给能量的显像面板；A flexible, easy-to-clean, power-generating and developing composite central control cover plate for vehicles is characterized in that: the central control cover plate is divided into two parts: a light-receiving area and a functional area, wherein the light-receiving area is provided with an upper lining (1) from top to bottom. ), the upper ITO glass (2), the upper absorption layer (3), the hole conduction layer (4), the lower absorption layer (5), the lower ITO glass (6), the bottom layer (7), a total of seven layers; functional area It includes an auxiliary integrated electric control center (8) arranged under the cover, and a display screen (9) fixed on the front middle of the central control cover and controlled by the auxiliary integrated electric control center (8), of which the auxiliary integrated electric control center (8) It includes an electrochemical capacitive energy storage device connected to the upper ITO glass (2) and the lower ITO glass (6) through a wire, and the output voltage of an integrated voltage multiplier that connects the electrochemical capacitive energy storage device and the main car battery in parallel is The 12V DC stabilized power supply, the processing chip that supplies energy through the 12V DC stabilized power supply, the memory and I/O channels that supply energy through the 12V DC stabilized power supply, the display screen (9) includes the under-screen touch structure and the 12V DC Display panel with energy supplied by stabilized power supply;
    　　其中，受光区的制造方法包括以下步骤：　　 Among them, the manufacturing method of the light receiving area includes the following steps:
    　　1）原材料准备　　1) Raw material preparation
    　　①原材料准备：按重量份准备摩尔浓度52mol/L-58mol/L的碘化氢乙醇溶液9份-12份、氨基甲烷16份-18份、足量碘化铅、钛酸四丁酯50份-55份、二乙醇胺12份-15份、聚-3己基噻吩1份-1.2份、足量70nm-120nm厚的碳纳米管薄膜、足量弧形ITO玻璃板；①Preparation of raw materials: prepare 9-12 parts of hydrogen iodide ethanol solution with molar concentration of 52mol/L-58mol/L, 16-18 parts of aminomethane, sufficient lead iodide, 50 parts of tetrabutyl titanate according to weight parts -55 parts, 12-15 parts of diethanolamine, 1 part-1.2 parts of poly-3hexylthiophene, sufficient carbon nanotube film of 70nm-120nm thickness, and sufficient curved ITO glass plate;
    　　②辅材准备：准备足量无水乙醇、足量乙醚、足量N,N二甲基二酰胺、足量氮气、足量二氯苯、足量异丙醇、足量锌粉、足量溶质质量分数20%的盐酸水溶液、足量去离子水；② Preparation of auxiliary materials: prepare enough absolute ethanol, enough ether, enough N,N dimethyl diamide, enough nitrogen, enough dichlorobenzene, enough isopropanol, enough zinc powder, enough Hydrochloric acid aqueous solution with 20% solute mass fraction, sufficient deionized water;
    　　2）受光区制造方法　　2) Manufacturing method of light receiving area
    　　①准备两块阶段1）步骤①准备的弧形ITO玻璃板，将阶段1）步骤②准备的锌粉分别均匀涂抹在两块ITO玻璃板的上表面上，涂抹至目视完全覆盖，然后将阶段1）步骤②准备的盐酸水溶液缓慢滴加在锌粉上直至锌粉完全润湿，保持2min-3min，将盐酸水溶液和锌粉采用乙醇和去离子水分别清洗至完全清洗干净，获得两块单面润蚀ITO玻璃；①Prepare two curved ITO glass plates prepared in step 1), and apply the zinc powder prepared in step 1) step ② to the upper surfaces of the two ITO glass plates evenly. Stage 1) The hydrochloric acid aqueous solution prepared in step ② is slowly dripped on the zinc powder until the zinc powder is completely wetted, and kept for 2min-3min. The hydrochloric acid aqueous solution and the zinc powder are washed with ethanol and deionized water respectively until they are completely cleaned to obtain two pieces Etching ITO glass on one side;
    　　②将步骤①获得的单面润蚀ITO玻璃翻转，然后重复一次步骤①，获得两块双面润蚀ITO玻璃，即为待用上ITO玻璃(2)和待用下ITO玻璃(6)；　　②Turn over the single-sided etched ITO glass obtained in step ①, and then repeat step ① to obtain two double-sided etched ITO glasses, namely the upper ITO glass to be used (2) and the lower ITO glass to be used (6);
    　　③将阶段1）步骤①准备的钛酸四丁酯、二乙醇胺与按重量份计的150份-160份乙醇混合均匀，以600rpm/min-800rpm/min的速率搅拌1.5h-2h，获得混液A；将按重量份计的15份-17份去离子水与75份-80份乙醇混配成醇水混溶液，即为混液B；将混液A和混液B混合并搅拌均匀后，获得混液C，将混液C在密闭环境内静置28h-30h，混液C溶胶化，获得溶胶液C；③Mix the tetrabutyl titanate and diethanolamine prepared in step 1) step ① with 150 to 160 parts by weight of ethanol, and stir for 1.5h-2h at a rate of 600rpm/min-800rpm/min to obtain a mixed solution A; Mix 15-17 parts by weight of deionized water and 75-80 parts of ethanol to form an alcohol-water mixed solution, which is mixed liquid B; mix and stir evenly with mixed liquid A and mixed liquid B to obtain mixed liquid C, the mixed liquid C is allowed to stand for 28h-30h in a closed environment, and the mixed liquid C is solized to obtain the sol liquid C;
    　　④将步骤③获得的溶胶液C以1200rpm/min-1300rpm/min的旋涂速率，每次45s-50s的旋涂时间，旋涂两次，涂层干结后厚度150nm-180nm的工艺，分别在步骤②获得的待用上ITO玻璃(2)的上下两个表面及待用下ITO玻璃(6)的上表面进行旋涂处理，获得旋涂上ITO玻璃(2)和旋涂下ITO玻璃(6)；④Spin the sol solution C obtained in step ③ at a spin-coating speed of 1200rpm/min-1300rpm/min, each spin-coating time of 45s-50s, spin coating twice, the thickness of the coating after drying is 150nm-180nm, respectively In step ②, the upper and lower surfaces of the upper ITO glass (2) to be used and the upper surface of the lower ITO glass (6) to be used are spin-coated to obtain spin-coated ITO glass (2) and spin-coated ITO glass ( 6);
    　　⑤将步骤④获得的旋涂上ITO玻璃(2)和旋涂下ITO玻璃(6)置于电阻炉中，采用460℃-480℃的温度烘烤80min-100min，获得预制上ITO玻璃(2)和预制下ITO玻璃(6)；⑤ Put the spin-coated ITO glass (2) and spin-coated ITO glass (6) obtained in step ④ in a resistance furnace, and bake at a temperature of 460℃-480℃ for 80min-100min to obtain prefabricated ITO glass (2) ) And prefabricated ITO glass (6);
    　　⑥将阶段1）步骤①准备的按重量份计的碘化铅2份-2.5份与5份-6份的N,N二甲基二酰胺混合均匀，加热至75℃-80℃至碘化铅完全溶解，获得混液D；⑥ Mix 2 to 2.5 parts by weight of lead iodide prepared in step 1) in step ① with 5 parts to 6 parts of N,N dimethyl diamide, and heat to 75℃-80℃ to iodide The lead is completely dissolved and mixed liquid D is obtained;
    　　⑦将阶段1）步骤①准备的碘化氢乙醇溶液和氨基甲烷混合均匀，然后在冰水浴0℃环境内持续搅拌45min-50min，然后边搅拌边加热至55℃-60℃直至完全烘干，将烘干产物与按重量份计250份-280份的乙醚混合均匀，重结晶后抽滤，将抽滤获得的固体在真空下采用55℃-60℃完全烘干，获得待用产物a；⑦Mix the ethanol solution of hydrogen iodide and aminomethane prepared in step 1) in step ①, and then keep stirring for 45min-50min in an ice-water bath at 0℃, and then heat to 55℃-60℃ while stirring until it is completely dried. Mix the dried product with 250-280 parts by weight of ethyl ether uniformly, recrystallize and filter with suction, and dry the solid obtained by suction at 55°C-60°C under vacuum to obtain product a for use;
    　　⑧将步骤⑦获得的待用产物a与阶段1）步骤②准备的异丙醇混配成固含物浓度9mg/ml-12mg/ml的混液E；　　⑧ Mix the product a obtained in step ⑦ with the isopropanol prepared in step ② of step 1) into a mixture E with a solid content of 9mg/ml-12mg/ml;
    　　⑨在步骤⑤获得的预制上ITO玻璃(2)的下表面和预制下ITO玻璃(6)的上表面，以1500rpm/min-1600rpm/min的旋涂速率，65s-70s的旋涂时间均匀旋涂步骤⑥获得的全部混液D，然后将旋涂后的预制上ITO玻璃(2)和预制下ITO玻璃(6)置于真空环境内采用65℃-70℃完全烘干，然后将烘干的上ITO玻璃(2)和下ITO玻璃(6)完全浸入步骤⑧获得的混液E中，保持25min-30min，然后在阶段1）步骤②准备的足量氮气保护下，采用65℃-70℃完全烘干然后炉冷至室温，获得终制上ITO玻璃(2)和终制下ITO玻璃(6)；⑨The lower surface of the prefabricated upper ITO glass (2) and the upper surface of the prefabricated lower ITO glass (6) obtained in step ⑤ are uniformly spun at a spin coating speed of 1500rpm/min-1600rpm/min and a spin coating time of 65s-70s Coat all the mixed solution D obtained in step ⑥, and then place the spin-coated prefabricated upper ITO glass (2) and prefabricated lower ITO glass (6) in a vacuum environment at 65℃-70℃ to completely dry, and then dry the dried The upper ITO glass (2) and the lower ITO glass (6) are completely immersed in the mixture E obtained in step ⑧ for 25 min-30 min, and then under the protection of sufficient nitrogen gas prepared in step 1) step ②, use 65°C-70°C completely After drying, the furnace is cooled to room temperature to obtain the final ITO glass (2) and the final ITO glass (6);
    　　⑩将阶段1）步骤①准备的聚-3己基噻吩与阶段1）步骤②准备的二氯苯混配成质量浓度10mg/ml的混液F，将混液F以750rpm/min-800rpm/min的旋涂速率、32s-35s的旋涂时间分别旋涂在步骤⑨获得的终制上ITO玻璃(2)的下表面和终制下ITO玻璃(6)的上表面，然后将旋涂好的终制上ITO玻璃(2)的下表面和终制下ITO玻璃(6)的上表面在真空环境内紧密贴合，并在足量氮气保护下烘干35min-40min，随炉冷至室温后取出，在取出物原终制下ITO玻璃(6)的下表面紧密贴合固定阶段1）步骤①准备的碳纳米管薄膜，获得的复合结构即为所需受光区。⑩The poly-3hexylthiophene prepared in step 1) in step ① and the dichlorobenzene prepared in step ② in step 1) are mixed into mixed solution F with a mass concentration of 10mg/ml, and the mixed solution F is rotated at 750rpm/min-800rpm/min. The coating rate and the spin coating time of 32s-35s are respectively spin-coated on the lower surface of the final upper ITO glass (2) and the upper surface of the final lower ITO glass (6) obtained in step ⑨, and then the spin-coated final product The lower surface of the upper ITO glass (2) and the upper surface of the finished lower ITO glass (6) are closely attached in a vacuum environment, and dried under the protection of a sufficient amount of nitrogen for 35min-40min, and taken out after being cooled to room temperature in the furnace. The lower surface of the ITO glass (6) is closely attached and fixed after the original final product is taken out. 1) The carbon nanotube film prepared in step ①, the obtained composite structure is the required light receiving area.
     To
PCT/CN2019/096371 2019-07-05 2019-07-17 Flexible and easy-to-clean power generation and development composite center control cover plate for vehicles and manufacturing method therefor WO2021003765A1 (en)

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