WO2020262798A1 - Apparatus and method for producing aqueous chlorine dioxide eliminating risk of explosion by supplying and reacting raw material using power source-free decompression method - Google Patents

Apparatus and method for producing aqueous chlorine dioxide eliminating risk of explosion by supplying and reacting raw material using power source-free decompression method Download PDF

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Publication number
WO2020262798A1
WO2020262798A1 PCT/KR2020/003536 KR2020003536W WO2020262798A1 WO 2020262798 A1 WO2020262798 A1 WO 2020262798A1 KR 2020003536 W KR2020003536 W KR 2020003536W WO 2020262798 A1 WO2020262798 A1 WO 2020262798A1
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Prior art keywords
chlorine dioxide
raw material
water
gas
tank
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PCT/KR2020/003536
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French (fr)
Korean (ko)
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김인오
이재웅
지희권
이한기
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주식회사 이노푸스
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Publication of WO2020262798A1 publication Critical patent/WO2020262798A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/80After-treatment of the mixture
    • B01F23/808Filtering the mixture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/42Auxiliary equipment or operation thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/48Mixing liquids with liquids; Emulsifying characterised by the nature of the liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/80After-treatment of the mixture
    • B01F23/803Venting, degassing or ventilating of gases, fumes or toxic vapours from the mixture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/21Measuring
    • B01F35/211Measuring of the operational parameters
    • B01F35/2111Flow rate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30Driving arrangements; Transmissions; Couplings; Brakes
    • B01F35/32Driving arrangements
    • B01F35/32005Type of drive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/712Feed mechanisms for feeding fluids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/717Feed mechanisms characterised by the means for feeding the components to the mixer
    • B01F35/71805Feed mechanisms characterised by the means for feeding the components to the mixer using valves, gates, orifices or openings

Definitions

  • the present invention is to produce pure chlorine dioxide water with high yield using sodium chlorite and acid.
  • the container for storing sodium chlorite and acid is used as a ringer bag to facilitate user handling, and tap water is used. By doing so, it does not require a power source such as a pressure pump, etc., and by ensuring that raw materials are supplied only when the reaction tank is depressurized, the risk of explosion by supplying and reacting raw materials in a decompression method without a power source. It relates to an apparatus and a method for producing a chlorine dioxide water removal.
  • Chlorine dioxide (ClO 2 ) is a powerful oxidizing agent that oxidizes toxic chemicals such as almost all bacteria, viruses, molds (anthrax), etc., but it is a material that is safe for the human body when used in an appropriate concentration (WHO safety highest standard A-1 grade).
  • chlorine dioxide is not only 5 times higher in oxidizing power and 10 times higher in water solubility than chlorine oxidizing agents, which are widely used in the past, and does not produce chloramine, which is known as a toxic ingredient, so it is the latest beverage manufacturing process and food product in developed countries. It is widely attracting attention as an alternative oxidizing agent for chlorine in various industrial fields ranging from sterilization and disinfection in processing and storage processes, water purification plants, and organic matter and odor removal processes in wastewater treatment plants.
  • chlorine dioxide does not generate carcinogenic disinfection by-products such as THMs, HAAs, HANs, etc., which are emerging as the biggest problem of chlorine-based oxidizing agents, as well as a wide and high level against various kinds of microorganisms, bacteria, and viruses in a wide pH range. It has the advantage of having sterilization and is the only material that can remove the resistant bacteria of chlorine-based disinfectants and the biofilm, a hotbed of bacteria.
  • chlorine dioxide which is both an oxidizing agent and a sterilant, has a strong sterilization power that completely removes various viruses and protozoa, compared to conventional oxidizing sterilants such as chlorine, ozone, bromine chloride, and chloramine, and oxidizes heavy metals such as iron and manganese. It also has a function to precipitate into oxides and hydroxides.
  • the chlorine dioxide injection device capable of selectively injecting gases, solutions, and bubbles described in Patent Publication No. 1977036 (announced on May 10, 2019) filed by the applicant of the present invention uses a pump in manufacturing chlorine dioxide.
  • a configuration is shown in which sodium chlorite and an acid solution must be supplied and air is supplied to the chlorine dioxide reactor using an air pump.
  • the apparatus for producing chlorine dioxide described in Japanese Unexamined Patent Publication No. 2011-508718 uses a tank-type first to third raw material supply unit and an inert gas supply unit to produce chlorine dioxide.
  • the configuration to be manufactured is shown.
  • the above inventions still have a tank-type raw material storage unit to install the main body of the chlorine dioxide production device, use a pressurizing device such as a pump, or require a separate air injection device, and the device is too large and complicated. There was a problem that it was done.
  • Patent Document 1 Patent Publication No. 1977036 (announced on May 10, 2019)
  • Patent Document 2 Patent Publication No. 1736825 (announced on May 17, 2017)
  • Patent Document 3 Japanese Patent Publication No. 2011-508718 (published on March 17, 2011)
  • Patent Document 4 Patent Publication No. 1901260 (announced on September 28, 2018)
  • the present invention is to solve the problems of the prior art as described above, by storing a sodium chlorite solution and an acid solution, which are raw materials for producing chlorine dioxide, in a Ringer bag and supplying it to a reaction tank, relatively simple and safe manufacturing
  • the purpose is to produce chlorine dioxide water with equipment.
  • the present invention accommodates and manages a Ringer bag storing sodium chlorite solution and acid solution in one storage unit, and by having only a reaction tank and a gas filtration tank, the installation location is not specified, but in various places as necessary. It is intended to produce aqueous chlorine dioxide.
  • the present invention does not use a pressurizing device such as a pump, and it is an object of the present invention to conveniently produce pure chlorine dioxide water by simply connecting a water pipe or the like without a separate power source.
  • the present invention provides a decompression unit to prevent oversupply of raw materials by supplying raw materials only during decompression, and therefore, by limiting the concentration of chlorine dioxide gas, it is an object of the present invention to eliminate the risk of explosion of the reaction tank. It is done with.
  • the present invention supplies the raw material liquid using a ringer bag and a decompression unit. After exhaustion, anyone can safely use the ringer bag containing the raw material liquid. It is intended to be able to be replaced and handled efficiently without spillage of the raw material liquid.
  • an object of the present invention is to produce a desired concentration of chlorine dioxide water by adjusting the operation cycle and opening time of a solenoid valve for supplying a raw material liquid according to the water supply amount.
  • the present invention has the following configuration to have the object as described above.
  • the present invention includes [1] a first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing residual moisture, sodium chlorite, and acid contained in the chlorine dioxide gas generated in the reaction tank 200; The pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  • the first raw material storage unit 110 and the second raw material storage unit 120 store first and second raw material solutions for chlorine dioxide production, respectively, and are accommodated in the raw material storage and storage unit 100 to
  • the first and second raw material solutions are supplied to 200
  • the reaction tank 200 is installed below the raw material storage and receiving unit 100, and an air inlet pipe 210 for introducing external air, and the reaction tank 200 )
  • the filter unit 320 is installed in the gas filtration tank 300, and the filter unit 320 is a Teflon mesh, a glass ball, a polymer, silicon, or equivalent Filling with at least one selected from materials that are easy to stagnate moisture without reacting with chlorine dioxide as water, by reacting a trace amount of sodium chlorite and acid contained in the chlorine dioxide gas discharged through the gas discharge pipe 220
  • a device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that it generates chlorine dioxide gas by car and removes sodium chlorite and acid contained in moisture to generate pure chlorine dioxide gas. It is about.
  • the water supply pipe 410 of the decompression unit 400 is provided with a bypass pipe 430 in parallel with the aspirator 420 ,
  • a first water shutoff solenoid valve 411 is installed, and a second water shutoff solenoid valve 431 is installed in the bypass pipe 430. It relates to an apparatus for producing chlorine dioxide water that eliminates the risk of explosion through supply and reaction.
  • the present invention [4] in the above [1] or [2], the first raw material storage unit 110 and the second raw material storage unit 120, a ringer bag, and supplied to each ringer bag / Shut-off valves 112 and 122 and first and second solenoid valves 113 and 123 are installed to control the supply of the first raw material and the second raw material to the reaction tank 200, and the gas discharge pipe 220
  • a third solenoid valve 222 is installed in the decompression release inlet pipe 223 in order to discharge it to the gas filtration tank 300 by depressurization and to facilitate the discharge of the solution after the reaction accumulated in the reaction tank 200. It relates to an apparatus for producing chlorine dioxide water, which removes the risk of explosion by supplying and reacting raw materials in a decompression method without a power source, characterized in that it controls so as to inhale the air of.
  • the present invention [5] in the above [1] or [2], by installing a water flow detection sensor 412 on the upstream side of the water supply pipe 410, the water flow in the water supply pipe 410 It relates to an apparatus for producing chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that the apparatus is turned off when not detected.
  • the present invention [6] a first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas;
  • a reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively;
  • a gas filtration tank 300 for removing sodium chlorite and acid remaining in moisture contained in the chlorine dioxide gas generated in the reaction tank 200;
  • the pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  • the solenoid valve 411 of the water supply pipe 410 By opening the solenoid valve 411 of the water supply pipe 410, the gas filtration tank 300 is decompressed by the aspirator 420 at the same time as water is supplied, and the reaction tank 200 is depressurized by the decompression of the gas filtration tank 300.
  • reaction tank 200 decompression step step 2
  • Chlorine dioxide gas generation step step 4 in which air is introduced into the air inlet pipe 210 by the decompression of the reaction tank 200 to generate chlorine dioxide gas;
  • Gas generation step (5 steps);
  • the pure chlorine dioxide gas is supplied to the aspirator 420 through the gas supply pipe 310, and water is supplied to the aspirator 420 through the water supply pipe 410, so that the pure chlorine dioxide gas and water
  • It relates to a method for producing chlorine dioxide water, which removes the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that consisting of: mixing to prepare chlorine dioxide water,
  • the present invention [7] in the above [6], the supply of the first and second raw material liquids to the reaction tank 200 in the third step, the supply/cutting valves 112 and 122 and the first and second solenoid valves (113, 123), characterized in that when the water flow is not detected from the water flow detection sensor 412 installed in the water supply pipe 410 in the 2nd to 6th steps, the device is turned off. It relates to a method for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  • the present invention is made by the above-described configuration, by storing a sodium chlorite solution and an acid solution, which are raw materials for producing chlorine dioxide, in a Ringer bag and supplying it to a reaction tank, thereby being a relatively simple and safe port manufacturing facility. Chlorine water can be prepared.
  • the present invention accommodates and manages a Ringer bag storing sodium chlorite solution and acid solution in one storage unit, and has only a reaction tank, a gas filtration tank, and a decompression unit, so that the installation location is not specified, as required.
  • Chlorine dioxide water can be produced in various places.
  • the present invention does not use a pressurizing device such as a pump, and it is possible to easily produce chlorine dioxide water by simply connecting a water pipe or the like without a separate power source.
  • the present invention prevents oversupply of raw materials by allowing raw materials to be supplied only at the time of reduced pressure, and thus, by limiting the concentration of chlorine dioxide gas, it is possible to eliminate the risk of explosion of the reaction tank.
  • the present invention is to supply the raw material liquid using a ringer bag and a decompression unit, unlike the prior art in which the raw material liquid stored in the raw material tank is supplied using a pressure pump, and the ringer bag containing the raw material liquid after the raw material liquid is exhausted.
  • the ringer bag containing the raw material liquid after the raw material liquid is exhausted can safely replace it and use it efficiently without leaking raw material.
  • the present invention by controlling the opening time and the operation cycle of the solenoid valve for supplying the raw material liquid according to the amount of water supplied, it is possible to prepare a desired concentration of chlorine dioxide water.
  • 1 is a schematic diagram of an apparatus for producing chlorine dioxide according to the prior art.
  • Fig. 2 is a schematic diagram showing an external configuration of the present invention.
  • Figure 3 is a schematic diagram of the storage unit of the raw material storage tank of the present invention.
  • FIG. 4 is a schematic diagram showing a chlorine dioxide water production apparatus of the present invention.
  • FIG. 5 is a schematic diagram of a chlorine dioxide water production process of the present invention
  • the present invention relates to an apparatus for producing pure chlorine dioxide water for producing chlorine dioxide water without using a separate power source using only a water supply pipe for tap water supplied from such a tap water supply source when there is an ordinary tap water supply source.
  • the present invention includes a raw material storage tank storage unit 100 for storing the first raw material storage tank 110 and the second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas;
  • a reaction tank 200 for generating chlorine dioxide gas by receiving and reacting the sodium chlorite solution and the acid solution stored in the first and second raw material storage tanks 110 and 120, respectively;
  • a gas filtration tank 300 for removing remaining sodium chlorite and acid by a secondary reaction of a trace amount of unreacted sodium chlorite and acid to residual moisture contained in the chlorine dioxide gas generated in the reaction tank 200, and ; It is composed of a decompression unit 400 that receives pure chlorine dioxide gas that has passed through the gas filtration tank 300 and mixes it with water to produce chlorine dioxide water.
  • the raw material storage tank storage unit 100 of the present invention accommodates the first raw material storage tank 110 and the second raw material storage tank 120, and the first raw material storage tank 110 And the 2nd raw material storage tank 120 uses a so-called Ringer bag, which is both used as an infusion container.
  • first and second raw material storage tanks 110 and 120 as ringer bags, it is possible to facilitate storage, transport and use of raw materials, and also when supplying the raw material solution to the reaction tank 200 Unlike the prior art, it does not require a pressurizing device to pressurize the first and second raw material storage tanks 110 and 120.
  • the present invention has the convenience of being able to easily supply and replace the first and second raw materials by using the first and second raw material storage tanks 110 and 120 as a ringer bag.
  • the safety of users and managers is ensured by replacing them with new first and second raw material storage tanks 110 and 120 without risk of leakage of raw materials after use.
  • the first and second raw material storage tanks 110 and 120 made of the Ringer bag are reaction tanks 200 installed below the first and second raw material storage tanks 110 and 120, respectively, and contain sodium chlorite solution, hydrochloric acid, phosphoric acid and sulfuric acid. It has a first raw material supply pipe 111 and a second raw material supply pipe 121 for supplying an inorganic acid or organic acid solution, and supply/blocking valves 112 and 122 are respectively provided in the first and second raw material supply pipes 111 and 121. In addition, a first solenoid valve 113 and a second solenoid valve 123 are installed behind the supply/blocking valves 112 and 122.
  • the supply/blocking valves 112 and 122 and the first and second solenoid valves 113 and 123 are used. It is also characterized in that it supplies raw materials to the reaction tank 200 installed in the.
  • an appropriate amount of the solution stored in the first and second raw material storage tanks 110 and 120 is supplied by using the supply/blocking valves 112 and 122, and the raw material solution thus supplied is the first solenoid valve 113 and the first solenoid valve. 2 It is supplied to the reaction tank 200 through the solenoid valve 123.
  • the operation of the first and second solenoid valves 113 and 123 is controlled by installing a control operation unit 500 on the outer surface covering the reaction tank 200 and the gas filtration tank 300, which are components for producing chlorine dioxide water. It is desirable to be able to do it.
  • the raw materials stored in the first and second raw material storage tanks 110 and 120 are sodium chlorite solution and inorganic or organic acid solutions such as sulfuric acid, hydrochloric acid, and phosphoric acid, respectively.
  • the inorganic acid or organic acid solution such as sulfuric acid, hydrochloric acid and phosphoric acid is collectively referred to as "acid".
  • sulfuric acid is used in the examples, in the present invention, only sulfuric acid is not required, and inorganic or organic acids such as hydrochloric acid and phosphoric acid may be used.
  • the reaction tank 200 of the present invention includes a sodium chlorite solution supplied from the first raw material storage tank 110 and the second raw material storage tank 120, hydrochloric acid, phosphoric acid, sulfuric acid, etc. It is a configuration that forms a space in which chlorine dioxide gas is generated by reacting an inorganic acid or organic acid solution.
  • reaction tank 200 when a sulfuric acid solution is used as the acid solution, chlorine dioxide gas is generated by the following reaction.
  • the reaction tank 200 includes an air inlet pipe 210 through which air is introduced from the outside, a gas discharge pipe 220 for discharging chlorine dioxide gas generated in the reaction tank to the gas filtration tank 300, and chlorine dioxide in the apparatus of the present invention.
  • the mixed solution discharge pipe 230 was opened after the reaction to discharge the mixed solution after the reaction remaining in the reaction tank 200 in order to maintain an appropriate concentration of chlorine dioxide water and increase the yield.
  • the air inlet pipe 210 is external air introduced, and the gas filtration tank 300 is decompressed by a decompression action generated by the decompression unit 400 described below, and the inside of the gas filtration tank 300 is As the inside of the reaction tank 200 is decompressed as the pressure is reduced, external air naturally flows into the reaction tank 200 through the air inlet pipe 210.
  • the air inlet pipe 210 is for introducing air from the outside of the apparatus of the present invention, and it is preferable that a filter is installed at the inlet of the inlet pipe 210 to provide only clean air.
  • a flow meter may be further installed at the inlet side of the air inlet pipe 210 so as to measure the flow rate of the incoming air as necessary to check the incoming flow rate.
  • the flow rate measured by the flow meter may be displayed through the control operation unit 500 on the outer surface covering the components for producing the chlorine dioxide solution described above.
  • an aeration filter 211 is installed on the opposite side of the inlet port of the air inlet pipe 210, that is, on the inner bottom of the reaction tank 200, and an aeration filter house 212 is installed around the aeration filter 211.
  • Such a configuration is substantially the same as described in Patent Document 4, which was previously applied and registered by the applicant of the present invention.
  • the aeration filter house 212 has a communication hole 213 communicating with the outside in a lower portion. By forming the communication hole 213 in this way, air is supplied to the mixed solution of sodium chlorite and sulfuric acid to form a vortex, thereby promoting the generation of chlorine dioxide gas, thereby facilitating the chlorine dioxide generation reaction.
  • the aeration filter 211 uses a ceramic filter or a glass filter to generate fine air bubbles, thereby promoting generation of chlorine dioxide gas.
  • the present invention further installs a moisture removal filter 221 on the side of the reaction tank 200 of the gas discharge pipe 220 for discharging the chlorine dioxide gas generated in the reaction tank 200 to the gas filtration tank 300, and the gas filtration tank 300 Most of the solution of sodium chlorite, hydrochloric acid, phosphoric acid and sulfuric acid, including moisture, can be removed first from the chlorine dioxide gas discharged to the gas.
  • the present invention may further install the mixed solution discharge pipe 230 after the reaction for discharging the mixed solution after the reaction inside the reaction tank 200.
  • the mixed solution discharge pipe 230 takes a method of discharging the mixed solution after the reaction after operating the apparatus of the present invention for a certain period of time, or discharges when the mixed solution reaches an appropriate level after reaction in the reaction tank 200.
  • Various manipulations can be made as needed, such as taking a method.
  • the mixed solution discharge pipe 230 is discharged from the after reaction mixed solution discharge guide pipe 231, which is extended to a certain position inside the reaction tank 200, and the mixed solution discharge guide pipe 231 after the reaction.
  • a third solenoid valve 222 may be installed at the side of the reaction tank 200 and the decompression release inlet pipe 223.
  • the third solenoid valve 222 discharges the mixed solution after the reaction inside the reaction tank 200, the reaction remaining inside the reaction tank 200 is mixed by communicating the inside and the outside of the reaction tank 200. It can make it easier to discharge the solution.
  • the operation of the third solenoid valve 222 may be performed through the control operation unit 500 on the outer surface covering the components for producing the chlorine dioxide solution described above.
  • the gas filtration tank 300 completely removes moisture, sodium chlorite, and acid contained in the chlorine dioxide gas produced in the reaction tank 200, and supplies pure chlorine dioxide gas to the decompression unit 400.
  • moisture removal filter 221 installed in the gas discharge pipe 220 of the reaction tank 200.
  • the chlorine dioxide gas produced in the reaction tank 200 is discharged from the reaction tank 200 to the gas filtration tank 300 through the gas discharge pipe 220.
  • the gas filtration tank 300 communicated by the decompression unit 400 and the gas supply pipe 310 by the decompression unit 400 is decompressed, and thus, the gas filtration tank 300 and the gas discharge pipe 220 communicate with each other.
  • the chlorine dioxide gas generated inside the reaction tank 200 is naturally discharged to the gas filtration tank 300 through the gas discharge pipe 220.
  • the pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied to the depressurization unit 400 described below through the gas supply pipe 310.
  • a filter unit 320 is formed inside the gas filtration tank 300 to react the residual sodium chlorite and acid discharged together with the chlorine dioxide gas through the gas discharge pipe 220 to perform a secondary reaction of generating chlorine dioxide gas. , The remaining moisture, sodium chlorite, and pure chlorine dioxide gas from which the acid has been removed are supplied to the decompression unit 400.
  • the filter unit 320 is filled with at least one selected from materials that do not react with chlorine dioxide, such as Teflon mesh, glass ball, polymer, silicon, etc., and which can facilitate moisture retention, thereby secondarily supplying chlorine dioxide gas. It produces a reaction and also functions to remove remaining sodium chlorite and acid.
  • materials that do not react with chlorine dioxide such as Teflon mesh, glass ball, polymer, silicon, etc.
  • the depressurization unit 400 is a configuration that enables the apparatus of the present invention to easily manufacture aqueous chlorine dioxide without requiring a separate power source.
  • the depressurization unit 400 is formed by a combination of the gas supply pipe 310 and a water supply pipe 410 connected from the water pipe, and chlorine dioxide gas supplied from the gas supply pipe 310 and the water supply pipe 410 respectively It also acts to mix and water in the aspirator (420).
  • a chlorine dioxide water supply pipe 432 connected to the aspirator 420 is installed at the rear of the depressurization unit 400 to supply chlorine dioxide water to a user's need.
  • the depressurization unit 400 generates decompression as the water supplied from the water supply pipe 410 passes through the aspirator 420, and the pure dioxide passed through the gas filtration tank 300 by this decompression
  • the apparatus for producing pure chlorine dioxide water according to the present invention does not require a separate power source.
  • the depressurization unit 400 of the present invention installs a first water shutoff solenoid valve 411 on the aspirator 420 connected to the water supply pipe 410 in order to induce the initial depressurization, and A second water shutoff solenoid valve 431 may be installed in the bypass pipe 430 in parallel with the speaker 420.
  • a water flow detection sensor 412 is installed on the upper side of the water supply pipe 410. At this time, when the water flow is not detected by the water flow detection sensor 412, the apparatus of the present invention is controlled to not operate.
  • the operation and status display of the first and second water shutoff solenoid valves 411 and 431 and the water flow detection sensor 412 are provided on the outer surface covering the components for producing the chlorine dioxide solution described above. ) Through.
  • the present invention is made by the above-described configurations, and the method for producing pure chlorine dioxide water according to the present invention will be described in detail below.
  • Step 1 is a preparatory step for operating the apparatus of the present invention, in which the first and second raw material storage tanks 110 and 120, respectively, in which the first raw material and the second raw material are accommodated, are provided at the top of the device of the present invention. 100).
  • the user can safely handle the raw material solution by shutting off the valve of the supply/cutting valve 112. You will be able to.
  • the present invention is differentiated from the prior art in that the user can easily and safely handle the first and second raw materials by using the ringer bag as described above for storage of the first and second raw materials.
  • Step 2 is a step for depressurizing the inside of the reaction tank 200.
  • the first and second raw materials are stored in the raw material storage container 100 to assemble and combine all the devices of the present invention, and then the device of the present invention This is the first practical step to drive.
  • Step 2 is made by opening the on-off valve 413 and the first water shut-off solenoid valve 411 of the water supply pipe 410, and the opening of the on-off valve 413 and the first water shut-off solenoid valve 411 Accordingly, a decompression action is performed in the decompression unit 400.
  • the second water shut-off solenoid valve 431 is shut off, so that water along the water supply pipe 410 It is supplied to the aspirator 420, and since the gas supply pipe 310 is connected to one side of the aspirator 420, the gas filtration tank 300 communicating with the gas supply pipe 310 is depressurized, and the gas filtration tank ( 300) and the reaction tank 200 communicated by the gas discharge pipe 220 is depressurized.
  • the second water shutoff solenoid valve 431 initially shut off is opened or shut off after a certain period of time. You can adjust the water supply by doing.
  • reaction tank depressurization step When the reaction tank depressurization step is maintained as described above, the reaction tank maintains a constant decompression state, and air is continuously sucked from the outside.
  • Step 3 is a step of supplying the first and second raw materials of the present invention to the reaction tank 200, and after the second step, the first and second raw material supply pipes connected to the first and second raw material storage tanks 110 and 120 (
  • the first and second solenoid valves 113 and 123 are opened as well as opening the valves of the supply/cutting valve 112 of the 111 and 121, and thus stored in the first and second raw material storage tanks 110 and 120.
  • the first and second raw materials are supplied to the reaction tank 200.
  • the first and second raw material storage tanks 110 and 120 are installed on the upper side of the reaction tank 200 and the reaction tank 200 is depressurized by the depressurization of the decompression unit 400, so that the first and second raw materials are Even without a separate power source such as a pressure pump, it is naturally supplied to the reaction tank 200.
  • the amount of water calculated relative to the internal structure and area of the reaction tank 200 is put before supplying the raw materials stored in the first and second raw material storage tanks 110 and 120. In this way, the risk of explosion can be prevented by reacting the first and second raw materials in water.
  • Step 4 is a step of generating chlorine dioxide gas in earnest in the reaction tank 200, and is a step in which the first and second raw materials and air are mixed to generate chlorine dioxide gas.
  • the generated chlorine dioxide gas is discharged to the gas filtration tank 300 through the gas discharge pipe 220.
  • a moisture removal filter 221 is installed at the inlet side of the gas discharge pipe 220 to discharge chlorine dioxide gas to the gas filtration tank 300 while firstly removing moisture, sodium chlorite and acid.
  • the apparatus of the present invention does not operate. Therefore, when the water supply is stopped, the apparatus of the present invention is turned off. The solenoid valves 113 and 123 are also closed. Therefore, when the supply of water is stopped, the supply of raw materials is always stopped, and the risk of explosion due to oversupply of raw materials is also removed.
  • Step 5 is to remove the remaining trace amounts of sodium chlorite and acid even after first removing the moisture, sodium chlorite, and acid by the moisture removal filter 221 installed at the inlet of the gas discharge pipe 220 of the reaction tank 200. It reacts secondarily to generate chlorine dioxide gas, removes remaining sodium chlorite and acid, and generates and discharges only pure chlorine dioxide gas.
  • the chlorine dioxide gas flowing into the gas filtration tank 300 through the gas discharge pipe 220 of the reaction tank 200 is filtered. Passing through the unit 320, a trace amount of sodium chlorite and acid discharged together with the chlorine dioxide gas generated in the reaction tank are also reacted secondarily to generate chlorine dioxide gas, and sodium chlorite and acid remaining in the moisture are removed. Is done.
  • Step 6 is a step of preparing aqueous chlorine dioxide, in which pure chlorine dioxide gas is mixed with water.
  • the chlorine dioxide gas generated inside the reaction tank 200 by the above 4 steps is transferred to the gas filtering tank 300 through the gas discharge pipe 220.
  • the pure chlorine dioxide gas from which sodium chlorite and acid have been removed is passed through the gas supply pipe 310 through the aspirator of the decompression unit 400 ( 420, the supplied pure chlorine dioxide gas is mixed with water supplied from the water supply pipe 410 from the aspirator 420, and is supplied to the chlorine dioxide water supply pipe 432 to produce chlorine dioxide water.
  • the present invention continuously manufactures and supplies aqueous chlorine dioxide by going through the steps 1 to 6 as described above.
  • the device is stopped by stopping the supply of water to the water supply pipe 410, specifically by closing the on-off valve 413 or the first water shut-off solenoid valve 411, water flow Is stopped, and the water flow detection sensor 412 detects that the water flow is stopped and turns off the device.

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Abstract

The objective of the present invention is to produce pure aqueous chlorine dioxide at a high yield using sodium chlorite and acid. The present invention relates to an apparatus for producing aqueous chlorine dioxide, the apparatus comprising: a first raw material storage tank (110) and a second raw material storage tank (120) which store raw materials for producing chlorine dioxide gas; a reaction tank (200) which is supplied with a sodium chlorite solution and an acid solution stored in the first and second raw material storage tanks (110, 120), respectively, and in which the sodium chlorite solution and acid solution are reacted; a gas filtration tank (300) for filtering chlorine dioxide gas generated in the reaction tank (200); and a decompression unit (400), wherein the gas stored in the gas filtration tank (300) is supplied to the decompression unit (400) and mixed with water therein to produce aqueous chlorine dioxide.

Description

동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치 및 제조 방법An apparatus and manufacturing method for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source
본 발명은 아염소산나트륨과 산을 이용하여 높은 수율로 순수 이산화염소수를 제조하고자 하는 것이며, 특히 아염소산나트륨과 산을 저장하는 용기를 링거백으로 하여 사용자의 취급을 용이하게 하며, 수도물을 사용하는 것에 의하여 가압 펌프 등과 같은 동력원을 필요로 하지 않으면서, 반응조의 감압시에만 원료 공급이 이루어지도록 하는 것에 의해 폭발 위험성 없이 안전하게 이산화염소수를 제조하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치 및 제조 방법에 관한 것이다.The present invention is to produce pure chlorine dioxide water with high yield using sodium chlorite and acid. In particular, the container for storing sodium chlorite and acid is used as a ringer bag to facilitate user handling, and tap water is used. By doing so, it does not require a power source such as a pressure pump, etc., and by ensuring that raw materials are supplied only when the reaction tank is depressurized, the risk of explosion by supplying and reacting raw materials in a decompression method without a power source. It relates to an apparatus and a method for producing a chlorine dioxide water removal.
이산화염소(ClO2)는 거의 모든 세균과 바이러스, 곰팡이(탄저균) 등과 유독성 화학물질을 산화시키는 강력한 산화제이나, 적정 농도로 사용하면 인체에 안전한 물질이다(WHO 안전최고기준 A-1 등급).Chlorine dioxide (ClO 2 ) is a powerful oxidizing agent that oxidizes toxic chemicals such as almost all bacteria, viruses, molds (anthrax), etc., but it is a material that is safe for the human body when used in an appropriate concentration (WHO safety highest standard A-1 grade).
또한, 이산화염소는 기존에 널리 사용되고 있는 염소 산화제보다 산화력은 5배 이상, 물에 대한 용해도는 10배 이상 높을 뿐 아니라, 유독 성분으로 알려진 클로라민을 생성하지 않아 선진국을 중심으로 최근 음료 제조 공정, 식품 가공 및 저장 공정의 살균 소독, 정수장, 하·폐수처리장의 유기물 및 악취 제거 공정 등에 이르기까지 다양한 산업 분야에서 염소의 대체 산화제로 널리 주목받고 있다.In addition, chlorine dioxide is not only 5 times higher in oxidizing power and 10 times higher in water solubility than chlorine oxidizing agents, which are widely used in the past, and does not produce chloramine, which is known as a toxic ingredient, so it is the latest beverage manufacturing process and food product in developed countries. It is widely attracting attention as an alternative oxidizing agent for chlorine in various industrial fields ranging from sterilization and disinfection in processing and storage processes, water purification plants, and organic matter and odor removal processes in wastewater treatment plants.
특히 이산화염소는 염소계 산화제의 가장 큰 문제점으로 대두되고 있는 THMs, HAAs, HANs 등과 같은 발암성 소독 부산물을 발생시키지 않을 뿐만 아니라, 넓은 pH 범위에서 다양한 종류의 미생물 및 박테리아, 바이러스 등에 대해 광범위하고도 높은 멸균력을 가지고 있는 장점을 가지고 있으며, 염소계 소독제의 내성균과 세균의 온상인 세균막(Biofilm)을 제거할 수 있는 거의 유일한 물질이다.In particular, chlorine dioxide does not generate carcinogenic disinfection by-products such as THMs, HAAs, HANs, etc., which are emerging as the biggest problem of chlorine-based oxidizing agents, as well as a wide and high level against various kinds of microorganisms, bacteria, and viruses in a wide pH range. It has the advantage of having sterilization and is the only material that can remove the resistant bacteria of chlorine-based disinfectants and the biofilm, a hotbed of bacteria.
또한, 산화제인 동시에 멸균제인 이산화염소는 염소, 오존, 염화브롬, 클로라민 등 기존의 산화 살균제에 비해 각종 바이러스, 원생 동물 등을 완전 제거하는 강한 멸균력을 가지고 있으며, 철, 망간 등 중금속을 산화시켜 산화물 및 수산화물로 침전시키는 기능도 가지고 있다.In addition, chlorine dioxide, which is both an oxidizing agent and a sterilant, has a strong sterilization power that completely removes various viruses and protozoa, compared to conventional oxidizing sterilants such as chlorine, ozone, bromine chloride, and chloramine, and oxidizes heavy metals such as iron and manganese. It also has a function to precipitate into oxides and hydroxides.
본 발명의 출원인이 출원한 특허공보 제1977036호(2019. 5. 10. 공고)에 기재된 가스, 용액 및 거품을 선택적으로 분사할 수 있는 이산화염소 분사 장치는 이산화염소를 제조함에 있어서, 펌프를 사용하여 아염소산나트륨과 산 용액을 공급하고 에어 펌프를 사용하여 이산화염소 반응조에 공기를 공급하여야 하는 구성이 나타나 있다.The chlorine dioxide injection device capable of selectively injecting gases, solutions, and bubbles described in Patent Publication No. 1977036 (announced on May 10, 2019) filed by the applicant of the present invention uses a pump in manufacturing chlorine dioxide. Thus, a configuration is shown in which sodium chlorite and an acid solution must be supplied and air is supplied to the chlorine dioxide reactor using an air pump.
또한, 특허공보 1736825호(2017. 5. 17. 공고)에 기재된 휴대용 일정한 농도의 순수 이산화염소 가스 발생장치는 점적수단과 아염소산나트륨 저장조와 산 저장조에 공기 조절 밸브를 부착하여 이산화염소를 제조하는 구성이 나타나 있다.In addition, the portable constant concentration pure chlorine dioxide gas generator described in Patent Publication No. 1736825 (announcement on May 17, 2017) is used to manufacture chlorine dioxide by attaching an air control valve to a dropping means, sodium chlorite storage tank and acid storage tank. The composition is shown.
또한, 일본 공표특허공보 특표2011-508718호(2011. 3.17. 공표, 특허문헌 3)에 기재된 이산화염소 제조장치는, 탱크 형태의 제1 내지 제3 원료공급부와 비활성기체 공급부를 사용하여 이산화염소를 제조하는 구성이 나타나 있다.In addition, the apparatus for producing chlorine dioxide described in Japanese Unexamined Patent Publication No. 2011-508718 (published on March 17, 2011, Patent Document 3) uses a tank-type first to third raw material supply unit and an inert gas supply unit to produce chlorine dioxide. The configuration to be manufactured is shown.
또한, 본 발명의 출원인이 출원한 특허공보 제1901260호(2018. 09. 28. 공고)에 기재된 고수율 순수 이산화염소 제조 장치는, 저농도의 아염소산나트륨 용액과 황산 용액을 사용하여 이산화염소를 제조하는 기술이 나타나 있으나, 여전히 제1 에어 펌프 및 제2 에어펌프를 사용하여 이산화염소를 제조하는 구성이 나타나 있다.In addition, the high-yield pure chlorine dioxide production apparatus described in Patent Publication No. 1901260 (announced on September 28, 2018) filed by the applicant of the present invention produces chlorine dioxide using a low concentration sodium chlorite solution and a sulfuric acid solution. However, a configuration for producing chlorine dioxide using a first air pump and a second air pump is still shown.
그렇지만, 상기 발명들은 여전히 이산화염소 제조 장치 본체를 설치하기 위하여 탱크 형태의 원료 저장부를 갖거나, 펌프 등의 가압장치를 사용하거나, 별도의 공기 주입장치를 필요로 하는 것으로, 장치가 지나치게 크고, 복잡하게 이루어진다는 문제점을 가지고 있었다.However, the above inventions still have a tank-type raw material storage unit to install the main body of the chlorine dioxide production device, use a pressurizing device such as a pump, or require a separate air injection device, and the device is too large and complicated. There was a problem that it was done.
<특허문헌><Patent Literature>
(특허문헌 1) : 특허공보 제1977036호(2019. 5. 10. 공고)(Patent Document 1): Patent Publication No. 1977036 (announced on May 10, 2019)
(특허문헌 2) : 특허공보 1736825호(2017. 5. 17. 공고)(Patent Document 2): Patent Publication No. 1736825 (announced on May 17, 2017)
(특허문헌 3) : 일본 공표특허공보 2011-508718호(2011. 3. 17. 공표)(Patent Document 3): Japanese Patent Publication No. 2011-508718 (published on March 17, 2011)
(특허문헌 4) : 특허공보 제1901260호(2018. 09. 28. 공고)(Patent Document 4): Patent Publication No. 1901260 (announced on September 28, 2018)
본 발명은 상기와 같은 선행기술들의 문제점을 해결하고자 하는 것으로, 이산화염소를 제조하기 위한 원료 물질인 아염소산나트륨 용액과 산 용액을 링거백에 보관하여 반응조로 공급하는 것에 의하여, 비교적 간단하고 안전한 제조 설비로 이산화염소수를 제조하고자 하는 것을 목적으로 하는 것이다.The present invention is to solve the problems of the prior art as described above, by storing a sodium chlorite solution and an acid solution, which are raw materials for producing chlorine dioxide, in a Ringer bag and supplying it to a reaction tank, relatively simple and safe manufacturing The purpose is to produce chlorine dioxide water with equipment.
또한, 본 발명은 아염소산나트륨 용액과 산 용액을 보관하는 링거백을 하나의 수납부에 수납하고 관리하며, 반응조와 가스 여과조만을 갖는 것에 의하여, 설치 장소를 특정하지 않고, 필요에 따라 다양한 장소에서 이산화염소수를 제조하고자 하는 것을 목적으로 하는 것이다.In addition, the present invention accommodates and manages a Ringer bag storing sodium chlorite solution and acid solution in one storage unit, and by having only a reaction tank and a gas filtration tank, the installation location is not specified, but in various places as necessary. It is intended to produce aqueous chlorine dioxide.
또한, 본 발명은 펌프 등의 가압 장치를 사용하지 않는 것으로, 별도의 동력원 없이 단순히 수도관 등에 연결하는 것에 의하여 간편하게 순수 이산화염소수를 제조하는 것을 목적으로 하는 것이다.In addition, the present invention does not use a pressurizing device such as a pump, and it is an object of the present invention to conveniently produce pure chlorine dioxide water by simply connecting a water pipe or the like without a separate power source.
또한, 본 발명은 감압부를 제공하여 감압시에만 원료 공급을 하는 것에 의하여 원료의 과공급을 방지하며, 따라서 이산화염소 가스의 농도를 제한하는 것에 의하여, 반응조가 폭발하는 등의 위험을 제거하는 것을 목적으로 하는 것이다.In addition, the present invention provides a decompression unit to prevent oversupply of raw materials by supplying raw materials only during decompression, and therefore, by limiting the concentration of chlorine dioxide gas, it is an object of the present invention to eliminate the risk of explosion of the reaction tank. It is done with.
또한, 본 발명은 가압펌프를 이용하여 원료 탱크에 저장된 원료액을 공급하는 선행기술과 달리, 링거백과 감압부를 이용하여 원료액을 공급하는 것으로, 소진시킨 후에 원료액이 들어 있는 링거백을 누구나 안전하게 교체할 수 있게 하여, 원료액의 유출 없이 효율적으로 취급하고자 하는 것을 목적으로 하는 것이다.In addition, unlike the prior art of supplying the raw material liquid stored in the raw material tank using a pressure pump, the present invention supplies the raw material liquid using a ringer bag and a decompression unit. After exhaustion, anyone can safely use the ringer bag containing the raw material liquid. It is intended to be able to be replaced and handled efficiently without spillage of the raw material liquid.
또한, 본 발명은 물 공급량에 따라 원료액을 공급하는 솔레노이드 밸브의 작동 주기와 개방 시간을 조절하는 것에 의하여, 원하는 농도의 이산화염소수를 제조하고자 하는 것을 목적으로 하는 것이다.In addition, an object of the present invention is to produce a desired concentration of chlorine dioxide water by adjusting the operation cycle and opening time of a solenoid valve for supplying a raw material liquid according to the water supply amount.
본 발명은 상기와 같은 목적을 갖는 것으로 아래와 같은 구성을 가진다.The present invention has the following configuration to have the object as described above.
본 발명은 [1] 이산화염소 가스를 제조하기 위한 원료를 저장하는 제1 원료 저장조(110) 및 제2 원료 저장조(120)와; 상기 제1, 2 원료 저장조(110, 120)에 각각 저장된 아염소산나트륨 용액과 산 용액을 공급받아 반응시키는 반응조(200)와; 상기 반응조(200)에서 발생된 이산화염소 가스에 포함된 잔류 습기, 아염소산나트륨 및 산을 제거하기 위한 가스 여과조(300)와; 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받아 감압부(400)에서 물과 혼합하여 이산화염소수를 제조하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 있어서, 상기 제1 원료저장부(110) 및 제2 원료저장부(120)는 이산화염소 제조를 위한 제1, 2 원료 용액을 각각 저장하면서, 원료 저장수납부(100)에 수납되어 반응조(200)로 제1, 2 원료 용액을 공급하며, 상기 반응조(200)는 상기 원료 저장 수납부(100)의 아래쪽에 설치되며, 외부 공기를 유입하는 공기 유입관(210)과, 반응조(200)에서 생성되는 이산화염소 가스를 가스 여과조(300)로 배출하는 가스 배출관(220)을 가지며, 상기 가스 여과조(300)는, 상기 반응조(200)에서 생성된 이산화염소 가스를 순수 이산화염소 가스로 만들어 감압부(400)로 공급하는 가스 공급관(310)을 가지며, 상기 감압부(400)는, 물 공급관(410)으로부터 물을 공급 받으면서, 가스 여과조(300)로부터 순수 이산화염소 가스를 공급받는, 아스피레이터(420)로 이루어지는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 관한 것이다.The present invention includes [1] a first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing residual moisture, sodium chlorite, and acid contained in the chlorine dioxide gas generated in the reaction tank 200; The pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source. In the apparatus, the first raw material storage unit 110 and the second raw material storage unit 120 store first and second raw material solutions for chlorine dioxide production, respectively, and are accommodated in the raw material storage and storage unit 100 to The first and second raw material solutions are supplied to 200, and the reaction tank 200 is installed below the raw material storage and receiving unit 100, and an air inlet pipe 210 for introducing external air, and the reaction tank 200 ) Has a gas discharge pipe 220 for discharging the chlorine dioxide gas generated in the gas filtration tank 300, and the gas filtration tank 300 makes the chlorine dioxide gas generated in the reaction tank 200 into pure chlorine dioxide gas. Has a gas supply pipe 310 supplied to the decompression unit 400, the decompression unit 400, while receiving water from the water supply pipe 410, receiving pure chlorine dioxide gas from the gas filtration tank 300. It relates to an apparatus for producing chlorine dioxide water, characterized in that consisting of a sputter 420, removing the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
또한, 본 발명은 [2] 상기 [1]에 있어서, 상기 가스 여과조(300)에는 필터부(320)를 설치하고, 상기 필터부(320)는 테프론메쉬, 글래스볼, 폴리머, 규소 또는 이와 균등물로서 이산화염소와 반응하지 않으면서 습기 정체에 용이한 재료 중에서 선택되는 적어도 하나로 채우는 것으로, 가스 배출관(220)을 통해서 배출되는 이산화염소 가스에 포함되어 있는 미량의 아염소산나트륨과 산까지 반응시켜 2차로 이산화염소 가스를 생성시키며, 습기에 포함된 아염소산나트륨 및 산을 제거하여 순수 이산화염소 가스를 생성하는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 관한 것이다.In addition, the present invention [2] in the above [1], the filter unit 320 is installed in the gas filtration tank 300, and the filter unit 320 is a Teflon mesh, a glass ball, a polymer, silicon, or equivalent Filling with at least one selected from materials that are easy to stagnate moisture without reacting with chlorine dioxide as water, by reacting a trace amount of sodium chlorite and acid contained in the chlorine dioxide gas discharged through the gas discharge pipe 220 A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that it generates chlorine dioxide gas by car and removes sodium chlorite and acid contained in moisture to generate pure chlorine dioxide gas. It is about.
또한, 본 발명은 [3] 상기 [1] 또는 [2]에 있어서, 상기 감압부(400)의 물 공급관(410)은, 아스피레이터(420)와 병렬로 우회관(430)을 설치하고, 상기 물공급관(410)에는 제1 물 차단 솔레노이드 밸브(411)를 설치하고, 상기 우회관(430)에는 제2 물 차단 솔레노이드 밸브(431)을 설치하는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 관한 것이다.In addition, the present invention [3] in [1] or [2], the water supply pipe 410 of the decompression unit 400 is provided with a bypass pipe 430 in parallel with the aspirator 420 , In the water supply pipe 410, a first water shutoff solenoid valve 411 is installed, and a second water shutoff solenoid valve 431 is installed in the bypass pipe 430. It relates to an apparatus for producing chlorine dioxide water that eliminates the risk of explosion through supply and reaction.
또한, 본 발명은 [4] 상기 [1] 또는 [2]에 있어서, 상기 제1 원료저장부(110) 및 제2 원료저장부(120)는, 링거백으로 하며, 각각의 링거백에는 공급/차단 밸브(112, 122)와 제1, 제2 솔레노이드 밸브(113, 123)를 설치하여 반응조(200)로의 제1 원료 및 제2 원료 공급을 제어하며, 상기 가스 배출관(220)은 가스를 가스 여과조(300)로 감압에 의해 배출시키고, 반응조(200)에 누적된 반응 후 용액의 배출을 원활하게 하기 위하여, 감압해제 유입관(223)에 제3 솔레노이드 밸브(222)를 설치하여, 외부의 공기를 흡입할 수 있도록 제어하는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 관한 것이다.In addition, the present invention [4] in the above [1] or [2], the first raw material storage unit 110 and the second raw material storage unit 120, a ringer bag, and supplied to each ringer bag / Shut-off valves 112 and 122 and first and second solenoid valves 113 and 123 are installed to control the supply of the first raw material and the second raw material to the reaction tank 200, and the gas discharge pipe 220 A third solenoid valve 222 is installed in the decompression release inlet pipe 223 in order to discharge it to the gas filtration tank 300 by depressurization and to facilitate the discharge of the solution after the reaction accumulated in the reaction tank 200. It relates to an apparatus for producing chlorine dioxide water, which removes the risk of explosion by supplying and reacting raw materials in a decompression method without a power source, characterized in that it controls so as to inhale the air of.
또한, 본 발명은 [5] 상기 [1] 또는 [2]에 있어서, 상기 물 공급관(410)의 상류측에 물 흐름 감지 센서(412)를 설치하여, 물 공급관(410)에서의 물 흐름이 감지되지 않는 경우에, 장치를 off시키는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 관한 것이다.In addition, the present invention [5] in the above [1] or [2], by installing a water flow detection sensor 412 on the upstream side of the water supply pipe 410, the water flow in the water supply pipe 410 It relates to an apparatus for producing chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that the apparatus is turned off when not detected.
또한, 본 발명은 [6] 이산화염소 가스를 제조하기 위한 원료를 저장하는 제1 원료 저장조(110) 및 제2 원료 저장조(120)와; 상기 제1, 2 원료 저장조(110, 120)에 각각 저장된 아염소산나트륨 용액과 산 용액을 공급받아 반응시키는 반응조(200)와; 상기 반응조(200)에서 발생된 이산화염소 가스에 포함된 습기에 잔류하는 아염소산나트륨 및 산을 제거하기 위한 가스 여과조(300)와; 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받아 감압부(400)에서 물과 혼합하여 이산화염소수를 제조하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법에 있어서, 링거백으로 이루어진 제1 원료 저장조(110)와 제2 원료 저장조(120)를 원료 저장조 수납부(100)에 수납하는, 제1, 2 원료 저장조(110, 120) 수납 단계(1 단계); 물 공급관(410)의 솔레노이드 밸브(411)를 개방하여 물 공급과 동시에 아스피레이터(420)에 의하여 가스 여과조(300)를 감압시키며, 상기 가스 여과조(300)의 감압에 의해 반응조(200)를 감압시키는, 반응조(200) 감압 단계(2 단계); 제1 원료 저장조(110)와 제2 원료 저장조(120)에 저장된 제1, 2 원료를 반응조(200)에 공급하는, 제1, 2 원료액 공급 단계(3 단계); 반응조(200)의 감압에 의해 공기 유입관(210)으로 공기가 유입되어 이산화염소 가스를 생성하는, 이산화염소 가스 생성 단계(4 단계); 반응조(200)로부터 생성된 이산화염소 가스를 가스 배출관(220)을 통해서 가스 여과조(300)로 공급하고, 이산화염소 가스가 가스 여과조(300)를 통과하면서 순수 이산화염소 가스가 생성되는, 순수 이산화염소 가스 생성 단계(5 단계); 상기 순수 이산화연염소 가스가 가스 공급관(310)을 통해서 아스피레이터(420)로 공급되며, 물이 물 공급관(410)을 통해서 아스피레이터(420)로 공급되어, 순수 이산화염소 가스와 물이 혼합되어 이산화염소수를 제조하는, 이산화염소수 제조 단계(5단계);로 이루어지는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법에 관한 것이다.In addition, the present invention [6] a first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing sodium chlorite and acid remaining in moisture contained in the chlorine dioxide gas generated in the reaction tank 200; The pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source. In the method, the first and second raw material storage tanks 110 and 120 receiving step (1) of storing the first raw material storage tank 110 and the second raw material storage tank 120 made of a ringer bag in the raw material storage tank storage unit 100 step); By opening the solenoid valve 411 of the water supply pipe 410, the gas filtration tank 300 is decompressed by the aspirator 420 at the same time as water is supplied, and the reaction tank 200 is depressurized by the decompression of the gas filtration tank 300. Decompressing, the reaction tank 200 decompression step (step 2); Supplying the first and second raw materials stored in the first raw material storage tank 110 and the second raw material storage tank 120 to the reaction tank 200 (step 3); Chlorine dioxide gas generation step (step 4) in which air is introduced into the air inlet pipe 210 by the decompression of the reaction tank 200 to generate chlorine dioxide gas; Pure chlorine dioxide in which chlorine dioxide gas generated from the reaction tank 200 is supplied to the gas filtration tank 300 through the gas discharge pipe 220, and pure chlorine dioxide gas is generated as the chlorine dioxide gas passes through the gas filtration tank 300 Gas generation step (5 steps); The pure chlorine dioxide gas is supplied to the aspirator 420 through the gas supply pipe 310, and water is supplied to the aspirator 420 through the water supply pipe 410, so that the pure chlorine dioxide gas and water It relates to a method for producing chlorine dioxide water, which removes the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source, characterized in that consisting of: mixing to prepare chlorine dioxide water, preparing chlorine dioxide water (step 5).
또한, 본 발명은 [7] 상기 [6]에 있어서, 상기 3 단계에서 제1, 2 원료액의 반응조(200)에의 공급은, 공급/차단 밸브(112, 122) 및 제1, 2 솔레노이드 밸브(113, 123)에 의하여 이루어지며, 상기 2 단계 내지 6단계에 있어서 물 공급관(410)에 설치된 물 흐름 감지 센서(412)로부터 물 흐름이 감지되지 않는 경우에는, 장치가 off되는 것을 특징으로 하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법에 관한 것이다.In addition, the present invention [7] in the above [6], the supply of the first and second raw material liquids to the reaction tank 200 in the third step, the supply/ cutting valves 112 and 122 and the first and second solenoid valves (113, 123), characterized in that when the water flow is not detected from the water flow detection sensor 412 installed in the water supply pipe 410 in the 2nd to 6th steps, the device is turned off. It relates to a method for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
본 발명은 상기와 같은 구성에 의하여 이루어지는 것으로, 이산화염소를 제조하기 위한 원료 물질인 아염소산나트륨 용액과 산 용액을 링거백에 보관하고 반응조로 공급하는 것에 의하여, 비교적 간단하고 안전항 제조 설비로 이산화염소수를 제조할 수 있다.The present invention is made by the above-described configuration, by storing a sodium chlorite solution and an acid solution, which are raw materials for producing chlorine dioxide, in a Ringer bag and supplying it to a reaction tank, thereby being a relatively simple and safe port manufacturing facility. Chlorine water can be prepared.
또한, 본 발명은 아염소산나트륨 용액과 산 용액을 보관하는 링거백을 하나의 수납부에 수납하고 관리하며, 반응조와 가스 여과조와 감압부만을 갖는 것에 의하여, 설치 장소를 특정하지 않고, 필요에 따라 다양한 장소에서 이산화염소수를 제조할 수 있다.In addition, the present invention accommodates and manages a Ringer bag storing sodium chlorite solution and acid solution in one storage unit, and has only a reaction tank, a gas filtration tank, and a decompression unit, so that the installation location is not specified, as required. Chlorine dioxide water can be produced in various places.
또한, 본 발명은 펌프 등의 가압 장치를 사용하지 않는 것으로, 별도의 동력원 없이 단순히 수도관 등에 연결하는 것에 의하여 간편하게 이산화염소수를 제조할 수 있다.In addition, the present invention does not use a pressurizing device such as a pump, and it is possible to easily produce chlorine dioxide water by simply connecting a water pipe or the like without a separate power source.
또한, 본 발명은 감압시에만 원료 공급이 이루어지도록 하는 것에 의하여 원료 과공급을 방지하며, 따라서 이산화염소 가스의 농도를 제한하는 것에 의하여 반응조가 폭발하는 등의 위험을 제거할 수 있다.In addition, the present invention prevents oversupply of raw materials by allowing raw materials to be supplied only at the time of reduced pressure, and thus, by limiting the concentration of chlorine dioxide gas, it is possible to eliminate the risk of explosion of the reaction tank.
또한, 본 발명은 가압펌프를 이용하여 원료 탱크에 저장된 원료액을 공급하는 선행기술과 달리, 링거백과 감압부를 이용하여 원료액을 공급하는 것으로, 원료액을 소진시킨 후에 원료액이 들어 있는 링거백을 누구나 안전하게 교체하여, 원료액의 누출없이 효율적으로 사용할 수 있게 된다.In addition, the present invention is to supply the raw material liquid using a ringer bag and a decompression unit, unlike the prior art in which the raw material liquid stored in the raw material tank is supplied using a pressure pump, and the ringer bag containing the raw material liquid after the raw material liquid is exhausted. Anyone can safely replace it and use it efficiently without leaking raw material.
또한, 본 발명은 물 공급량에 따라 원료액을 공급하는 솔레노이드 밸브의 개방 시간과 작동 주기를 조절하는 것에 의하여, 원하는 농도의 이산화염소수를 제조할 수 있다.In addition, according to the present invention, by controlling the opening time and the operation cycle of the solenoid valve for supplying the raw material liquid according to the amount of water supplied, it is possible to prepare a desired concentration of chlorine dioxide water.
도 1은 선행기술에 따른 이산화염소 제조 장치의 개략도.1 is a schematic diagram of an apparatus for producing chlorine dioxide according to the prior art.
도 2는 본 발명의 외형 구성을 나타내는 개략도.Fig. 2 is a schematic diagram showing an external configuration of the present invention.
도 3은 본 발명의 원료 저장조 수납부의 개략도.Figure 3 is a schematic diagram of the storage unit of the raw material storage tank of the present invention.
도 4는 본 발명의 이산화염소수 제조 장치를 나타내는 모식도.Figure 4 is a schematic diagram showing a chlorine dioxide water production apparatus of the present invention.
도 5는 본 발명의 이산화염소수 제조 공정의 개략도Figure 5 is a schematic diagram of a chlorine dioxide water production process of the present invention
아래에서는 첨부된 도면을 참조하여 본 발명의 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치 및 제조 방법에 대해서 설명한다.Hereinafter, with reference to the accompanying drawings, a description will be given of an apparatus and a method for producing chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source of the present invention.
본 발명은, 통상의 수도물 공급원이 있는 경우에 그러한 수도물 공급원에서 공급되는 수도물의 물 공급관 만을 이용하여 별도의 동력원을 이용하지 않으면서 이산화염소수를 제조하는 순수 이산화염소수 제조 장치에 관한 것이다. The present invention relates to an apparatus for producing pure chlorine dioxide water for producing chlorine dioxide water without using a separate power source using only a water supply pipe for tap water supplied from such a tap water supply source when there is an ordinary tap water supply source.
다만, 수도물 공급원이 없는 지역의 경우에는 별도로 일정한 압력으로 물을 공급할 수 있는 물 공급관을 설치하여 운용할 필요가 있다.However, in the case of an area where there is no water supply source, it is necessary to separately install and operate a water supply pipe capable of supplying water at a constant pressure.
본 발명은 이산화염소 가스를 제조하기 위한 원료를 저장하는 제1 원료 저장조(110) 및 제2 원료 저장조(120)를 수납하는 원료 저장조 수납부(100)와; 상기 제1, 2 원료 저장조(110, 120)에 각각 저장된 아염소산나트륨 용액과 산 용액을 공급받아 반응시켜 이산화염소 가스를 생성시키는 반응조(200)와; 상기 반응조(200)에서 발생된 이산화염소 가스에 포함된 잔류 습기에 미량의 반응되지 않은 아염소산나트륨과 산의 2차로 반응으로, 남아 있는 아염소산나트륨 및 산을 제거하기 위한 가스 여과조(300)와; 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받아 물과 혼합시켜 이산화염소수를 제조하는 감압부(400)로 구성되는 것으로, 아래에서는 각각의 구성들에 대해서 구체적으로 살펴본다.The present invention includes a raw material storage tank storage unit 100 for storing the first raw material storage tank 110 and the second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for generating chlorine dioxide gas by receiving and reacting the sodium chlorite solution and the acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing remaining sodium chlorite and acid by a secondary reaction of a trace amount of unreacted sodium chlorite and acid to residual moisture contained in the chlorine dioxide gas generated in the reaction tank 200, and ; It is composed of a decompression unit 400 that receives pure chlorine dioxide gas that has passed through the gas filtration tank 300 and mixes it with water to produce chlorine dioxide water. Each of the components will be described below in detail.
[원료 저장조 수납부(100)][Raw material storage tank storage unit 100]
도 2 내지 도 4에 나타나 있는 것과 같이, 본 발명의 원료 저장조 수납부(100)는 제1 원료 저장조(110) 및 제2 원료 저장조(120)를 수납하는 것으로, 상기 제1 원료 저장조(110) 및 제2 원료 저장조(120)는, 모두 수액 용기로 사용되고 있는 소위 링거백을 사용한다.2 to 4, the raw material storage tank storage unit 100 of the present invention accommodates the first raw material storage tank 110 and the second raw material storage tank 120, and the first raw material storage tank 110 And the 2nd raw material storage tank 120 uses a so-called Ringer bag, which is both used as an infusion container.
상기와 같이, 제1, 2 원료 저장조(110, 120)를 링거백으로 하는 것에 의하여, 원료의 보관, 이송 및 사용을 용이하게 할 수 있으며, 또한 원료 용액을 반응조(200)로 공급하는 경우에도 선행기술들과 달리 제1, 2 원료 저장조(110, 120)를 가압하기 위한 가압장치를 필요로 하지 않는다.As described above, by using the first and second raw material storage tanks 110 and 120 as ringer bags, it is possible to facilitate storage, transport and use of raw materials, and also when supplying the raw material solution to the reaction tank 200 Unlike the prior art, it does not require a pressurizing device to pressurize the first and second raw material storage tanks 110 and 120.
또한, 본 발명은 상기 제1, 2 원료 저장조(110, 120)를 링거백으로 하는 것에 의하여, 제1, 2 원료의 공급 및 교체가 용이하게 이루어질 수 있다는 편리함을 가지며, 제1, 2 원료를 사용한 후에 원료 유출의 위험 없이 새로운 제1, 2 원료 저장조(110, 120)로 교체하는 것에 의하여, 사용자 및 관리자의 안전성이 확보된다.In addition, the present invention has the convenience of being able to easily supply and replace the first and second raw materials by using the first and second raw material storage tanks 110 and 120 as a ringer bag. The safety of users and managers is ensured by replacing them with new first and second raw material storage tanks 110 and 120 without risk of leakage of raw materials after use.
상기 링거백으로 이루어진 제1, 2 원료 저장조(110, 120)는 제1, 2 원료 저장조(110, 120)의 아래쪽에 설치되는 반응조(200)로 각각 아염소산나트륨 용액과 염산, 인산 황산 등의 무기산 또는 유기산 용액을 공급하기 위한 제1 원료 공급관(111) 및 제2 원료 공급관(121)을 가지며, 상기 제1, 2 원료 공급관(111, 121)에는 각각 공급/차단 밸브(112, 122)을 설치하고, 상기 공급/차단 밸브(112, 122)의 후방에 제1 솔레노이드 밸브(113) 및 제2 솔레노이드 밸브(123)를 설치한다.The first and second raw material storage tanks 110 and 120 made of the Ringer bag are reaction tanks 200 installed below the first and second raw material storage tanks 110 and 120, respectively, and contain sodium chlorite solution, hydrochloric acid, phosphoric acid and sulfuric acid. It has a first raw material supply pipe 111 and a second raw material supply pipe 121 for supplying an inorganic acid or organic acid solution, and supply/blocking valves 112 and 122 are respectively provided in the first and second raw material supply pipes 111 and 121. In addition, a first solenoid valve 113 and a second solenoid valve 123 are installed behind the supply/blocking valves 112 and 122.
본 발명은, 제1, 2 원료 저장조(110, 120)에 펌프 등의 가압장치를 연결하지 않고, 단순히 공급/차단 밸브(112, 122)과 제1, 2 솔레노이드밸브(113, 123)만으로 아래에 설치되는 반응조(200)로 원료를 공급한다는 점에서도 특징이 있다.In the present invention, without connecting a pressurizing device such as a pump to the first and second raw material storage tanks 110 and 120, only the supply/blocking valves 112 and 122 and the first and second solenoid valves 113 and 123 are used. It is also characterized in that it supplies raw materials to the reaction tank 200 installed in the.
다시 말하면, 제1, 2 원료 저장조(110, 120)에 저장된 용액을 공급/차단 밸브(112, 122)를 이용하여 적정량을 공급하며, 이렇게 공급되는 원료 용액은 제1 솔레노이드밸브(113) 및 제2 솔레노이드밸브(123)를 통해서 반응조(200)로 공급한다.In other words, an appropriate amount of the solution stored in the first and second raw material storage tanks 110 and 120 is supplied by using the supply/blocking valves 112 and 122, and the raw material solution thus supplied is the first solenoid valve 113 and the first solenoid valve. 2 It is supplied to the reaction tank 200 through the solenoid valve 123.
이때 제1, 2 솔레노이드 밸브(113, 123)의 조작은, 이산화염소수를 제조하는 구성들인 반응조(200) 및 가스 여과조(300)를 커버하는 외부 표면에 제어 조작부(500)를 설치하여 제어 조작할 수 있도록 하는 것이 바람직하다. At this time, the operation of the first and second solenoid valves 113 and 123 is controlled by installing a control operation unit 500 on the outer surface covering the reaction tank 200 and the gas filtration tank 300, which are components for producing chlorine dioxide water. It is desirable to be able to do it.
또한, 상기 제1, 2 원료 저장조(110, 120)에 저장되는 원료는 각각 아염소산나트륨 용액과 황산, 염산, 인산 등의 무기산 또는 유기산 용액이다.In addition, the raw materials stored in the first and second raw material storage tanks 110 and 120 are sodium chlorite solution and inorganic or organic acid solutions such as sulfuric acid, hydrochloric acid, and phosphoric acid, respectively.
본 발명에서는 상기 황산, 염산, 인산 등의 무기산 또는 유기산 용액을 총칭하여 "산"이라고 기재한다. 또한, 실시예에서는 황산을 사용하는 것으로 기재하였지만, 본 발명은 반드시 황산만을 사용하여야 하는 것은 아니며, 염산, 인산 등의 무기산 또는 유기산을 사용할 수도 있다.In the present invention, the inorganic acid or organic acid solution such as sulfuric acid, hydrochloric acid and phosphoric acid is collectively referred to as "acid". In addition, although it has been described that sulfuric acid is used in the examples, in the present invention, only sulfuric acid is not required, and inorganic or organic acids such as hydrochloric acid and phosphoric acid may be used.
[반응조(200)][Reaction tank 200]
도 2 및 도 4에 나타나 있는 것과 같이, 본 발명의 반응조(200)는, 상기 제1 원료 저장조(110) 및 제2 원료 저장조(120)로부터 공급되는 아염소산나트륨 용액과 염산, 인산, 황산 등의 무기산 또는 유기산 용액을 반응시켜 이산화염소 가스를 발생시키는 공간을 이루는 구성이다.2 and 4, the reaction tank 200 of the present invention includes a sodium chlorite solution supplied from the first raw material storage tank 110 and the second raw material storage tank 120, hydrochloric acid, phosphoric acid, sulfuric acid, etc. It is a configuration that forms a space in which chlorine dioxide gas is generated by reacting an inorganic acid or organic acid solution.
상기 반응조(200)에서는 산 용액으로 황산 용액을 사용하는 경우에 아래와 같은 반응에 의해 이산화염소 가스를 생성하게 된다.In the reaction tank 200, when a sulfuric acid solution is used as the acid solution, chlorine dioxide gas is generated by the following reaction.
5NaClO2 + 2H2SO4 → 4ClO2 + 2Na2SO4 + NaCl + 2H2O5NaClO 2 + 2H 2 SO 4 → 4ClO 2 + 2Na 2 SO 4 + NaCl + 2H 2 O
상기 반응조(200)는 외부로부터 공기가 유입되는 공기 유입관(210)과, 반응조에서 생성되는 이산화염소 가스를 가스 여과조(300)로 배출하는 가스 배출관(220)과, 본 발명의 장치에서 이산화염소 반응조(200)의 반응 후 혼합 용액을 배출하여 이산화염소수의 적정 농도를 유지시키고, 수율을 높이기 위하여 반응조(200)에 남아 있는 반응 후 혼합 용액을 배출하기 위한 반응 후 혼합 용액 배출관(230)을 가진다.The reaction tank 200 includes an air inlet pipe 210 through which air is introduced from the outside, a gas discharge pipe 220 for discharging chlorine dioxide gas generated in the reaction tank to the gas filtration tank 300, and chlorine dioxide in the apparatus of the present invention. After the reaction in the reaction tank 200, the mixed solution discharge pipe 230 was opened after the reaction to discharge the mixed solution after the reaction remaining in the reaction tank 200 in order to maintain an appropriate concentration of chlorine dioxide water and increase the yield. Have.
상기 공기 유입관(210)은 외부 공기가 유입되는 것으로, 아래에서 설명하는 감압부(400)에 의하여 발생되는 감압 작용에 의하여, 가스 여과조(300)가 감압되며, 상기 가스 여과조(300) 내부가 감압됨에 따라 반응조(200) 내부가 감압됨에 따라, 자연스럽게 공기 유입관(210)을 통해서 외부 공기가 반응조(200)로 유입된다.The air inlet pipe 210 is external air introduced, and the gas filtration tank 300 is decompressed by a decompression action generated by the decompression unit 400 described below, and the inside of the gas filtration tank 300 is As the inside of the reaction tank 200 is decompressed as the pressure is reduced, external air naturally flows into the reaction tank 200 through the air inlet pipe 210.
상기 공기 유입관(210)은 본 발명의 장치 외부로부터 공기를 유입하기 위한 것이며, 유입관(210) 입구에는 필터를 설치하여 깨끗한 공기만을 제공할 수 있도록 하는 것이 바람직하다. 또한, 필요에 따라 유입되는 공기의 유량을 측정할 수 있도록 공기 유입관(210)의 입구측에 유량계를 더 설치하여 유입되는 유량을 확인할 수 있다.The air inlet pipe 210 is for introducing air from the outside of the apparatus of the present invention, and it is preferable that a filter is installed at the inlet of the inlet pipe 210 to provide only clean air. In addition, a flow meter may be further installed at the inlet side of the air inlet pipe 210 so as to measure the flow rate of the incoming air as necessary to check the incoming flow rate.
이 때 상기 유량계에 의해서 측정되는 유량은, 앞에서 설명한 이산화염소수를 제조하는 구성들을 커버하는 외부 표면에 제어 조작부(500)를 통해서 표시될 수 있도록 할 수 있다.At this time, the flow rate measured by the flow meter may be displayed through the control operation unit 500 on the outer surface covering the components for producing the chlorine dioxide solution described above.
또한, 상기 공기 유입관(210)의 유입구 반대측, 다시 말하면 반응조(200) 내부 저면에는 폭기필터(211)를 설치하고, 폭기필터(211) 주위에는 폭기필터 하우스(212)를 설치한다. 이와 같은 구성은 본 발명의 출원인이 선출원하여 등록받은 특허문헌 4의 기재에 따른 것과 실질적으로 동일한 것이다. In addition, an aeration filter 211 is installed on the opposite side of the inlet port of the air inlet pipe 210, that is, on the inner bottom of the reaction tank 200, and an aeration filter house 212 is installed around the aeration filter 211. Such a configuration is substantially the same as described in Patent Document 4, which was previously applied and registered by the applicant of the present invention.
상기 폭기필터 하우스(212)는, 하부에 외부와 연통하는 연통구멍(213)을 형성한다. 이렇게 연통구멍(213)을 형성하는 것에 의하여, 아염소산나트륨과 황산의 혼합 용액에 공기를 공급하여 와류를 형성하는 것에 의하여 이산화염소 가스의 생성을 촉진시켜, 이산화염소 생성 반응이 활발하게 한다.The aeration filter house 212 has a communication hole 213 communicating with the outside in a lower portion. By forming the communication hole 213 in this way, air is supplied to the mixed solution of sodium chlorite and sulfuric acid to form a vortex, thereby promoting the generation of chlorine dioxide gas, thereby facilitating the chlorine dioxide generation reaction.
또한, 폭기필터(211)는, 세라믹 필터 또는 글래스 필터를 사용하여, 미세한 공기 방울을 발생시켜서, 이산화염소 가스의 생성을 촉진시킨다.In addition, the aeration filter 211 uses a ceramic filter or a glass filter to generate fine air bubbles, thereby promoting generation of chlorine dioxide gas.
본 발명은 상기 반응조(200)에서 생성되는 이산화염소 가스를 가스 여과조(300)로 배출하는 가스 배출관(220)의 반응조(200) 측에 습기 제거 필터(221)를 더 설치하여 가스 여과조(300)로 배출되는 이산화염소 가스에서 1차로 습기를 비롯한 아염소산나트륨과 염산, 인산 황산 등의 무기산 또는 유기산 용액을 대부분 제거할 수 있다.The present invention further installs a moisture removal filter 221 on the side of the reaction tank 200 of the gas discharge pipe 220 for discharging the chlorine dioxide gas generated in the reaction tank 200 to the gas filtration tank 300, and the gas filtration tank 300 Most of the solution of sodium chlorite, hydrochloric acid, phosphoric acid and sulfuric acid, including moisture, can be removed first from the chlorine dioxide gas discharged to the gas.
또한, 본 발명은 상기 반응조(200) 내부의 반응 후 혼합용액의 배출 등을 위하여, 반응 후 혼합용액 배출관(230)을 더 설치할 수 있다. 상기 반응 후 혼합용액 배출관(230)은 본 발명의 장치를 일정 시간 작동시킨 후에 반응 후 혼합용액을 배출하는 방식을 취하거나, 반응조(200)에 반응 후 혼합용액이 적정 수준에 이른 경우에 배출하는 방식을 취하는 등, 필요에 따라 다양한 조작이 이루어지질 수 있다.In addition, the present invention may further install the mixed solution discharge pipe 230 after the reaction for discharging the mixed solution after the reaction inside the reaction tank 200. After the reaction, the mixed solution discharge pipe 230 takes a method of discharging the mixed solution after the reaction after operating the apparatus of the present invention for a certain period of time, or discharges when the mixed solution reaches an appropriate level after reaction in the reaction tank 200. Various manipulations can be made as needed, such as taking a method.
상기 반응 후 혼합용액 배출관(230)은, 상기 반응조(200) 내부의 일정 위치까지 뻗어져 설치되는 반응 후 혼합용액 배출유도관(231), 상기 반응 후 혼합용액 배출유도관(231)으로부터 배출되는 혼합용액을 외부로 배출하는 반응 후 혼합용액 배출관(232), 반응 후 혼합용액 배출관(232)의 일측에 설치하는 드레인 밸브(233)를 가진다.After the reaction, the mixed solution discharge pipe 230 is discharged from the after reaction mixed solution discharge guide pipe 231, which is extended to a certain position inside the reaction tank 200, and the mixed solution discharge guide pipe 231 after the reaction. A mixed solution discharge pipe 232 after reaction for discharging the mixed solution to the outside, and a drain valve 233 installed at one side of the mixed solution discharge pipe 232 after reaction.
또한 상기 반응 후 혼합용액 배출관(230)으로의 용액 배출을 원활하게 하기 위하여, 상기 반응조(200)와 감압해제 유입관(223) 측에 제3 솔레노이드 밸브(222)를 설치할 수 있다. 상기 제3 솔레노이드 밸브(222)는 반응조(200) 내부의 반응 후 혼합용액의 배출 등을 하는 경우에, 반응조(200) 내부와 외부를 연통시키는 것에 의하여 반응조(200) 내부에 남아 있는 반응 후 혼합용액의 배출을 더 용이하게 할 수 있다.In addition, in order to smoothly discharge the solution to the mixed solution discharge pipe 230 after the reaction, a third solenoid valve 222 may be installed at the side of the reaction tank 200 and the decompression release inlet pipe 223. When the third solenoid valve 222 discharges the mixed solution after the reaction inside the reaction tank 200, the reaction remaining inside the reaction tank 200 is mixed by communicating the inside and the outside of the reaction tank 200. It can make it easier to discharge the solution.
마찬가지로, 상기 제3 솔레노이드 밸브(222)의 조작은, 앞에서 설명한 이산화염소수를 제조하는 구성들을 커버하는 외부 표면에 제어 조작부(500)를 통해서 할 수 있다.Similarly, the operation of the third solenoid valve 222 may be performed through the control operation unit 500 on the outer surface covering the components for producing the chlorine dioxide solution described above.
[가스 여과조(300)][Gas filtration tank 300]
상기 가스 여과조(300)는 상기 반응조(200)에서 제조된 이산화염소 가스에 포함되어 있는 습기, 아염소산나트륨 및 산을 완전히 제거하고, 순수 이산화염소 가스를 감압부(400)로 공급하고자 하는 것이다.The gas filtration tank 300 completely removes moisture, sodium chlorite, and acid contained in the chlorine dioxide gas produced in the reaction tank 200, and supplies pure chlorine dioxide gas to the decompression unit 400.
본 발명에서는 상기 반응조(200)의 가스 배출관(220)에 설치된 습기제거 필터(221)에 의해 1차로 대부분의 습기, 아염소산나트륨 및 산을 제거할 수 있다.In the present invention, most of moisture, sodium chlorite, and acid can be firstly removed by the moisture removal filter 221 installed in the gas discharge pipe 220 of the reaction tank 200.
그렇지만, 상기 반응조(200)로부터 가스 여과조(300)로 이산화염소 가스가 배출되는 과정에서 일부 습기, 아염소산나트륨 및 산이 함께 배출되게 되는데, 이때 가스 여과조(300)에서는 함께 배출되는 아염소산나트륨과 산을 반응시켜서 2차로 이산화염소 가스 생성 반응을 시키고, 잔류하는 습기, 아염소산나트륨 및 산을 제거하여 순수 이산화염소 가스를 감압부(400)로 공급하게 된다.However, in the process of discharging chlorine dioxide gas from the reaction tank 200 to the gas filtration tank 300, some moisture, sodium chlorite, and acid are discharged together.At this time, sodium chlorite and acid discharged together in the gas filtration tank 300 By reacting, the chlorine dioxide gas is generated secondly, and residual moisture, sodium chlorite, and acid are removed to supply pure chlorine dioxide gas to the decompression unit 400.
상기 반응조(200)에서 제조된 이산화염소 가스는 상기 가스 배출관(220)을 통해서, 반응조(200)로부터 가스 여과조(300)로 배출된다.The chlorine dioxide gas produced in the reaction tank 200 is discharged from the reaction tank 200 to the gas filtration tank 300 through the gas discharge pipe 220.
이것은, 감압부(400)에 의하여 감압부(400)와 가스 공급관(310)에 의해 연통되는 가스 여과조(300)가 감압되고, 따라서, 가스 여과조(300)와 가스 배출관(220)에 의해 연통되는 반응조(200)의 내부가 감압됨에 따라, 자연스럽게 반응조(200) 내부에 생성된 이산화염소 가스가 가스 배출관(220)을 통해서 가스 여과조(300)로 배출되는 것이다.This is, the gas filtration tank 300 communicated by the decompression unit 400 and the gas supply pipe 310 by the decompression unit 400 is decompressed, and thus, the gas filtration tank 300 and the gas discharge pipe 220 communicate with each other. As the inside of the reaction tank 200 is depressurized, the chlorine dioxide gas generated inside the reaction tank 200 is naturally discharged to the gas filtration tank 300 through the gas discharge pipe 220.
또한, 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스는, 가스 공급관(310)을 통해서 아래에서 설명하는 감압부(400)로 공급된다.In addition, the pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied to the depressurization unit 400 described below through the gas supply pipe 310.
상기 가스 여과조(300)의 내부에는 필터부(320)를 형성하여, 가스 배출관(220)을 통해서 이산화염소 가스와 함께 배출되는 잔류 아염소산나트륨과 산을 반응시켜서 2차로 이산화염소 가스 생성 반응을 시키고, 남아 있는 습기, 아염소산나트륨 및 산을 제거한 순수 이산화염소 가스를 감압부(400)로 공급하게 된다.A filter unit 320 is formed inside the gas filtration tank 300 to react the residual sodium chlorite and acid discharged together with the chlorine dioxide gas through the gas discharge pipe 220 to perform a secondary reaction of generating chlorine dioxide gas. , The remaining moisture, sodium chlorite, and pure chlorine dioxide gas from which the acid has been removed are supplied to the decompression unit 400.
이때 상기 필터부(320)는 테프론메쉬, 글래스볼, 폴리머, 규소 등과 같이 이산화염소와 반응하지 않으며 습기의 정체를 용이하게 할 수 있는 재료 중에서 선택되는 적어도 하나로 채우는 것에 의하여, 2차로 이산화염소 가스를 반응 생성시키며, 또한 남아 있는 아염소산나트륨 및 산을 제거하는 기능을 한다.At this time, the filter unit 320 is filled with at least one selected from materials that do not react with chlorine dioxide, such as Teflon mesh, glass ball, polymer, silicon, etc., and which can facilitate moisture retention, thereby secondarily supplying chlorine dioxide gas. It produces a reaction and also functions to remove remaining sodium chlorite and acid.
[감압부(400)][Depressurization unit 400]
상기 감압부(400)는, 본 발명의 장치가 별도의 동력원을 필요로 하지 않으면서도 이산화염소수를 용이하게 제조할 수 있게 하는 구성이다.The depressurization unit 400 is a configuration that enables the apparatus of the present invention to easily manufacture aqueous chlorine dioxide without requiring a separate power source.
상기 감압부(400)는, 상기 가스 공급관(310)과, 수도관에서 이어지는 물 공급관(410)의 결합에 의하여 이루어지며, 상기 가스 공급관(310)과 물 공급관(410)에서 각각 공급되는 이산화염소 가스와 물을 아스피레이터(420)에서 혼합하는 작용도 한다.The depressurization unit 400 is formed by a combination of the gas supply pipe 310 and a water supply pipe 410 connected from the water pipe, and chlorine dioxide gas supplied from the gas supply pipe 310 and the water supply pipe 410 respectively It also acts to mix and water in the aspirator (420).
또한, 상기 감압부(400)의 후방에는 상기 아스피레이터(420)에 연결되어 이산화염소수를 사용자가 필요로 하는 곳에 공급하는 이산화염소수 공급관(432)을 설치한다.In addition, a chlorine dioxide water supply pipe 432 connected to the aspirator 420 is installed at the rear of the depressurization unit 400 to supply chlorine dioxide water to a user's need.
또한, 상기 감압부(400)는, 상기 물 공급관(410)에서 공급되는 물이 아스피레이터(420)를 통과함에 따라 감압을 발생시키고, 이러한 감압에 의해 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받는 것으로, 본 발명의 순수 이산화염소수 제조 장치는 별도의 동력원을 필요로 하지 않게 되는 것이다.In addition, the depressurization unit 400 generates decompression as the water supplied from the water supply pipe 410 passes through the aspirator 420, and the pure dioxide passed through the gas filtration tank 300 by this decompression By receiving chlorine gas, the apparatus for producing pure chlorine dioxide water according to the present invention does not require a separate power source.
또한, 본 발명의 감압부(400)는, 초기 감압을 유도하기 위하여 물 공급관(410)에 연결되는 아스피레이터(420)의 상부에 제1 물 차단 솔레노이드밸브(411)를 설치하고, 상기 아스피레이터(420)와 병렬로 우회관(430)에 제2 물 차단 솔레노이드밸브(431)를 설치할 수 있다.In addition, the depressurization unit 400 of the present invention installs a first water shutoff solenoid valve 411 on the aspirator 420 connected to the water supply pipe 410 in order to induce the initial depressurization, and A second water shutoff solenoid valve 431 may be installed in the bypass pipe 430 in parallel with the speaker 420.
또한, 본 발명은 상기 물 공급에 의해 감압부가 작동하는 것이므로, 물 공급관(410)의 상부측에 물 흐름 감지 센서(412)를 설치한다. 이때 상기 물 흐름 감지 센서(412)에 의하여 물 흐름이 감지되지 않게 되면, 본 발명의 장치가 작동되지 않도록 제어한다.In addition, in the present invention, since the decompression unit is operated by the water supply, a water flow detection sensor 412 is installed on the upper side of the water supply pipe 410. At this time, when the water flow is not detected by the water flow detection sensor 412, the apparatus of the present invention is controlled to not operate.
또한, 상기 제1, 2 물 차단 솔레노이드밸브(411, 431) 및 물 흐름 감지 센서(412)의 조작 및 상태 표시는, 앞에서 설명한 이산화염소수를 제조하는 구성들을 커버하는 외부 표면에 제어 조작부(500)를 통해서 할 수 있다.In addition, the operation and status display of the first and second water shutoff solenoid valves 411 and 431 and the water flow detection sensor 412 are provided on the outer surface covering the components for producing the chlorine dioxide solution described above. ) Through.
다만, 본 발명의 경우에 수도관이 제공되지 않는 지역에서는 지하수 또는 공업용수 등을 이용하기 위하여 별도의 수조와 가압 펌프를 이용하여 일정한 물 공급이 이루어지는 물 공급관을 준비할 필요가 있다.However, in the case of the present invention, in an area where a water pipe is not provided, it is necessary to prepare a water supply pipe through which a constant water supply is provided using a separate water tank and a pressure pump in order to use groundwater or industrial water.
본 발명은 상기와 같은 구성들에 의하여 이루어지는 것으로, 아래에서는 본 발명의 순수 이산화염소수 제조 방법에 대해서 구체적으로 설명한다.The present invention is made by the above-described configurations, and the method for producing pure chlorine dioxide water according to the present invention will be described in detail below.
[원료 저장조 수납 단계 : 1 단계][Raw material storage tank storage step: Step 1]
1 단계는 본 발명의 장치를 가동시키기 위한 준비 단계로서, 제1 원료와 제2 원료가 각각 수용된 제1, 제2 원료 저장조(110, 120)를 본 발명의 장치 상단에 마련된 원료 저장조 수납부(100)에 수납시킨다.Step 1 is a preparatory step for operating the apparatus of the present invention, in which the first and second raw material storage tanks 110 and 120, respectively, in which the first raw material and the second raw material are accommodated, are provided at the top of the device of the present invention. 100).
상기 제1, 제2 원료 저장조(110, 120)를 원료 저장조 수납부(100)에 수납시키거나 제거할 때에는 공급/차단 밸브(112)의 밸브를 차단하는 것에 의하여 사용자가 안전하게 원료 용액을 취급할 수 있게 된다.When storing or removing the first and second raw material storage tanks 110 and 120 in the raw material storage storage unit 100, the user can safely handle the raw material solution by shutting off the valve of the supply/cutting valve 112. You will be able to.
본 발명은 제1, 2 원료의 저장을 상기와 같은 링거백을 이용하는 것에 의하여 사용자가 제1, 제2 원료를 용이하고 안전하게 취급할 수 있다는 점에서도 선행기술들과 차별화된 것이다.The present invention is differentiated from the prior art in that the user can easily and safely handle the first and second raw materials by using the ringer bag as described above for storage of the first and second raw materials.
[반응조 감압 단계 : 2 단계][Reaction tank decompression step: step 2]
2 단계는 반응조(200) 내부를 감압시키기 위한 단계로서, 상기 1 단계에서 제1, 2 원료를 원료 저장조 수납부(100)에 수납하여 본 발명의 장치 모두를 조립 결합시킨 후에, 본 발명의 장치를 구동시키기 위한 실질적인 첫번째 단계라고 할 수 있다.Step 2 is a step for depressurizing the inside of the reaction tank 200. In the first step, the first and second raw materials are stored in the raw material storage container 100 to assemble and combine all the devices of the present invention, and then the device of the present invention This is the first practical step to drive.
2 단계는 물 공급관(410)의 개폐 밸브(413) 및 제1 물 차단 솔레노이드 밸브(411)를 개방함에 따라 이루어지는 것으로, 상기 개폐 밸브(413) 및 제1 물 차단 솔레노이드 밸브(411)의 개방에 따라, 감압부(400)에서 감압 작용이 이루어진다. 이 때, 초기에 개폐 밸브(413)를 개방하고, 제1 물 차단 솔레노이드밸브(411)를 개방하면서, 제2 물 차단 솔레노이드밸브(431)를 차단하는 것에 의해, 물 공급관(410)을 따라 물이 아스피레이터(420)로 공급되며, 아스피레이터(420)의 일측에 가스 공급관(310)이 연결되어 있으므로, 가스 공급관(310)과 연통되는 가스 여과조(300)가 감압되며, 가스 여과조(300)와 가스 배출관(220)에 의하여 연통되는 반응조(200)가 감압되게 된다.Step 2 is made by opening the on-off valve 413 and the first water shut-off solenoid valve 411 of the water supply pipe 410, and the opening of the on-off valve 413 and the first water shut-off solenoid valve 411 Accordingly, a decompression action is performed in the decompression unit 400. At this time, by initially opening the on-off valve 413 and opening the first water shut-off solenoid valve 411, the second water shut-off solenoid valve 431 is shut off, so that water along the water supply pipe 410 It is supplied to the aspirator 420, and since the gas supply pipe 310 is connected to one side of the aspirator 420, the gas filtration tank 300 communicating with the gas supply pipe 310 is depressurized, and the gas filtration tank ( 300) and the reaction tank 200 communicated by the gas discharge pipe 220 is depressurized.
또한, 본 발명에서는 반응조(200)의 감압 상태를 원활하게 유지시키거나, 이산화염소수의 농도를 조절하기 위하여, 초기에 차단하였던 제2 물 차단 솔레노이드밸브(431)를 일정 시간 경과 후에 개방하거나 차단하는 것에 의하여 물 공급을 조절할 수 있다.In addition, in the present invention, in order to smoothly maintain the decompression state of the reaction tank 200 or to control the concentration of the chlorine dioxide solution, the second water shutoff solenoid valve 431 initially shut off is opened or shut off after a certain period of time. You can adjust the water supply by doing.
상기와 같이 반응조 감압 단계가 유지되면, 반응조는 일정한 감압상태를 유지하게 되어 외부로부터 계속적으로 공기의 흡입이 이루어진다.When the reaction tank depressurization step is maintained as described above, the reaction tank maintains a constant decompression state, and air is continuously sucked from the outside.
[제1, 2 원료액 공급 단계 : 3 단계][1st and 2nd raw material supply step: 3rd step]
3 단계는 본 발명의 제1, 2 원료를 반응조(200)로 공급하는 단계로서, 상기 2 단계 후에, 상기 제1, 2 원료 저장조(110, 120)에 연결되어 있는 제1, 2 원료 공급관(111, 121)의 공급/차단 밸브(112)의 밸브를 개방함과 아울러, 제1, 2 솔레노이드 밸브(113, 123)를 개방하여, 제1, 2 원료 저장조(110, 120)에 저장되어 있는 제1, 2 원료를 반응조(200)로 공급하는 것이다.Step 3 is a step of supplying the first and second raw materials of the present invention to the reaction tank 200, and after the second step, the first and second raw material supply pipes connected to the first and second raw material storage tanks 110 and 120 ( The first and second solenoid valves 113 and 123 are opened as well as opening the valves of the supply/cutting valve 112 of the 111 and 121, and thus stored in the first and second raw material storage tanks 110 and 120. The first and second raw materials are supplied to the reaction tank 200.
이때 상기 제1, 2 원료 저장조(110, 120)는 상기 반응조(200)의 상측에 설치되어 있으면서, 상기 감압부(400)의 감압에 의해 반응조(200)가 감압되므로, 제1, 2 원료가 가압 펌프 등과 같은 별도의 동력원이 없어도 자연스럽게 반응조(200)로 공급된다.At this time, the first and second raw material storage tanks 110 and 120 are installed on the upper side of the reaction tank 200 and the reaction tank 200 is depressurized by the depressurization of the decompression unit 400, so that the first and second raw materials are Even without a separate power source such as a pressure pump, it is naturally supplied to the reaction tank 200.
다만, 본 발명의 장치를 처음 구동시키는 경우에는 제1, 2 원료 저장조(110, 120)에 저장된 원료를 공급하기 전에 반응조(200) 내부 구조와 면적 대비 계산된 물의 량을 넣는다. 이렇게 하는 것에 의하여 제1, 2 원료가 물속에서 반응하는 것에 의하여 폭발 위험성을 방지할 수 있다.However, when the apparatus of the present invention is driven for the first time, the amount of water calculated relative to the internal structure and area of the reaction tank 200 is put before supplying the raw materials stored in the first and second raw material storage tanks 110 and 120. In this way, the risk of explosion can be prevented by reacting the first and second raw materials in water.
[이산화염소 가스 생성 단계 : 4 단계][Chlorine dioxide gas generation step: 4 steps]
4 단계는 반응조(200) 내부에서 이산화염소 가스를 본격적으로 생성시키는 단계로서, 제1, 2 원료 및 공기가 혼합되어 이산화염소 가스가 생성되는 단계이다.Step 4 is a step of generating chlorine dioxide gas in earnest in the reaction tank 200, and is a step in which the first and second raw materials and air are mixed to generate chlorine dioxide gas.
상기 2 단계에서 상기 반응조(200)의 내부가 감압되면, 반응조(200)의 내부에서 외부와 연통된 공기 유입관(210)에 의하여 공기가 유입되므로, 반응조(200)에서는 자연스럽게 제1, 2 원료와 공기가 혼합되면서, 이산화염소 가스의 생성이 원활하게 이루어진다.When the inside of the reaction tank 200 is depressurized in the second step, air is introduced from the inside of the reaction tank 200 through the air inlet pipe 210 communicating with the outside, so that the first and second raw materials are naturally in the reaction tank 200. As the and air are mixed, chlorine dioxide gas is generated smoothly.
상기와 같이 하여, 생성되는 이산화염소 가스는 가스 배출관(220)을 통해서 가스 여과조(300)로 배출된다. 이때, 상기 가스 배출관(220)의 입구 측에는 습기제거 필터(221)를 설치하여, 1차로 습기, 아염소산나트륨 및 산을 제거시키면서 이산화염소 가스를 가스 여과조(300)로 배출시킨다.As described above, the generated chlorine dioxide gas is discharged to the gas filtration tank 300 through the gas discharge pipe 220. At this time, a moisture removal filter 221 is installed at the inlet side of the gas discharge pipe 220 to discharge chlorine dioxide gas to the gas filtration tank 300 while firstly removing moisture, sodium chlorite and acid.
또한, 앞에서 설명한 것과 같이, 감압을 위한 물 공급관(410)의 물 흐름이 감지되지 않으면 본 발명의 장치가 작동하지 않게 되므로, 물 공급이 중단되면 본 발명의 장치가 off되므로, 상기 제1, 2 솔레노이드 밸브(113, 123)도 폐쇄된다. 따라서 물 공급이 중단되는 경우에는 항상 원료의 공급이 중단되므로, 원료의 과공급에 따른 폭발 위험성도 제거된다.In addition, as described above, if the water flow of the water supply pipe 410 for depressurization is not detected, the apparatus of the present invention does not operate. Therefore, when the water supply is stopped, the apparatus of the present invention is turned off. The solenoid valves 113 and 123 are also closed. Therefore, when the supply of water is stopped, the supply of raw materials is always stopped, and the risk of explosion due to oversupply of raw materials is also removed.
[순수 이산화염소 가스 생성 단계 : 5 단계][Pure chlorine dioxide gas generation step: 5 steps]
5 단계는 상기 반응조(200)의 가스 배출관(220)의 입구에 설치된 습기제거 필터(221)에 의하여 1차로 상기 습기, 아염소산나트륨 및 산을 제거시키고도 남아 있는 미량의 아염소산나트륨과 산을 2차로 반응시켜 이산화염소 가스를 생성시키며, 남아 있는 아염소산나트륨 및 산을 제거하여, 순수 이산화염소 가스만을 생성시켜 배출하는 것이다.Step 5 is to remove the remaining trace amounts of sodium chlorite and acid even after first removing the moisture, sodium chlorite, and acid by the moisture removal filter 221 installed at the inlet of the gas discharge pipe 220 of the reaction tank 200. It reacts secondarily to generate chlorine dioxide gas, removes remaining sodium chlorite and acid, and generates and discharges only pure chlorine dioxide gas.
4 단계에 의해서 반응조(200) 내부에서 생성된 이산화염소 가스를 순수 이산화염소 가스로 만들기 위해서는, 상기 반응조(200)의 가스 배출관(220)을 통해서 가스 여과조(300)로 유입되는 이산화염소 가스가 필터부(320)를 지나면서, 상기 반응조에서 생성된 이산화염소 가스에 함께 배출되는 미량의 아염소산나트륨과 산까지도 2차로 반응시켜 이산화염소 가스를 생성시키며, 습기에 잔류하는 아염소산나트륨 및 산을 제거하게 된다.In order to convert the chlorine dioxide gas generated inside the reaction tank 200 into pure chlorine dioxide gas by step 4, the chlorine dioxide gas flowing into the gas filtration tank 300 through the gas discharge pipe 220 of the reaction tank 200 is filtered. Passing through the unit 320, a trace amount of sodium chlorite and acid discharged together with the chlorine dioxide gas generated in the reaction tank are also reacted secondarily to generate chlorine dioxide gas, and sodium chlorite and acid remaining in the moisture are removed. Is done.
이를 위하여, 상기 반응조(200)와 연통되는 가스 배출관(220)의 끝단을 상기 가스 여과조(300)의 필터부(320) 하측까지 연장할 필요가 있으며, 상기 감압부(400)와 연통되는 가스 공급관(310)의 끝단은 필터부(320) 상측에 설치한다.To this end, it is necessary to extend the end of the gas discharge pipe 220 in communication with the reaction tank 200 to the lower side of the filter unit 320 of the gas filtration tank 300, and a gas supply pipe in communication with the depressurization unit 400 The end of 310 is installed above the filter unit 320.
[이산화염소수 제조 단계 : 6 단계][Steps for preparing chlorine dioxide solution: Step 6]
6 단계는 이산화염소수를 제조하는 단계로서, 순수 이산화염소 가스가 물과 혼합되는 단계이다.Step 6 is a step of preparing aqueous chlorine dioxide, in which pure chlorine dioxide gas is mixed with water.
상기 4 단계에 의해서 반응조(200) 내부에서 생성된 이산화염소 가스는, 상기 가스 배출관(220)을 통해서 가스 여과조(300)로 이동하게 된다. 또한, 상기 5 단계에서 가스 여과조(300)의 필터부(320)를 지나면서, 아염소산나트륨 및 산이 제거된 순수 이산화염소 가스는 가스 공급관(310)을 통해서 감압부(400)의 아스피레이터(420)로 공급되며, 공급된 순수 이산화염소 가스는 아스피레이터(420)에서 물 공급관(410)에서 공급되는 물과 혼합되어, 이산화염소수를 만들어 이산화염소수 공급관(432)으로 공급된다.The chlorine dioxide gas generated inside the reaction tank 200 by the above 4 steps is transferred to the gas filtering tank 300 through the gas discharge pipe 220. In addition, while passing through the filter unit 320 of the gas filtration tank 300 in step 5, the pure chlorine dioxide gas from which sodium chlorite and acid have been removed is passed through the gas supply pipe 310 through the aspirator of the decompression unit 400 ( 420, the supplied pure chlorine dioxide gas is mixed with water supplied from the water supply pipe 410 from the aspirator 420, and is supplied to the chlorine dioxide water supply pipe 432 to produce chlorine dioxide water.
본 발명은 상기와 같은 1 단계 내지 6 단계를 거치는 것에 의하여 계속적으로 이산화염소수를 제조 공급하게 된다. The present invention continuously manufactures and supplies aqueous chlorine dioxide by going through the steps 1 to 6 as described above.
또한, 본 발명에서 장치를 중지는, 물 공급관(410)으로의 물 공급을 중지시키는 것에 의해서, 구체적으로는 개폐 밸브(413) 또는 제1 물 차단 솔레노이드 밸브(411)를 잠그는 것에 의하여, 물 흐름을 중지시키고, 물 흐름 감지 센서(412)가 물 흐름이 중지된 것을 감지하여 장치를 off시키게 된다.In addition, in the present invention, the device is stopped by stopping the supply of water to the water supply pipe 410, specifically by closing the on-off valve 413 or the first water shut-off solenoid valve 411, water flow Is stopped, and the water flow detection sensor 412 detects that the water flow is stopped and turns off the device.
<부호의 설명><Explanation of code>
100 : 원료 저장조 수납부100: raw material storage tank storage unit
110 : 제1 원료 저장조 110: first raw material storage tank
111 : 제1 원료 공급관 111: first raw material supply pipe
112: 공급/차단 밸브 112: supply/shutoff valve
113 : 제1 솔레노이드 밸브 113: first solenoid valve
120 : 제2원료 저장조 120: second raw material storage tank
121 : 제1 원료 공급관 121: first raw material supply pipe
122: 공급/차단 밸브 122: supply/shutoff valve
123 : 제2 솔레노이드 밸브 123: second solenoid valve
200 : 반응조200: reaction tank
210 : 공기 유입관 210: air inlet pipe
211 : 폭기필터 211: aeration filter
212 : 폭기필터 하우스 212: Aeration filter house
213 : 연통 구멍 213: communication hole
220 : 가스 배출관 220: gas discharge pipe
221 : 습기제거 필터 221: moisture removal filter
222 : 제3 솔레노이드 밸브 222: third solenoid valve
223 : 감압해제 유입관 223: decompression release inlet pipe
230 : 반응 후 혼합용액 배출관 230: mixed solution discharge pipe after reaction
231 : 반응 후 혼합 용액 배출 유도관 231: After the reaction, the mixed solution discharge guide tube
232 : 반응 후 혼합 용액 배출관 232: mixed solution discharge pipe after reaction
233 : 드레인 밸브 233: drain valve
300 : 가스 여과조300: gas filtration tank
310 : 가스 공급관 310: gas supply pipe
320 : 필터부 320: filter unit
400 : 감압부400: decompression unit
410 : 물 공급관 410: water supply pipe
411 : 제1 물 차단 솔레노이드 밸브 411: first water shut off solenoid valve
412 : 물 흐름 감지 센서 412: water flow detection sensor
413 : 개폐 밸브 413: on-off valve
420 : 아스피레이터 420: aspirator
430 : 우회관 430: bypass pipe
431 : 제2 물 차단 솔레노이드 밸브 431: second water shut-off solenoid valve
432 : 이산화염소수 공급관 432: chlorine dioxide water supply pipe
440 : 사용 후 배출관 440: discharge pipe after use
500 : 제어 조작부500: control operation part

Claims (7)

  1. 이산화염소 가스를 제조하기 위한 원료를 저장하는 제1 원료 저장조(110) 및 제2 원료 저장조(120)와; 상기 제1, 2 원료 저장조(110, 120)에 각각 저장된 아염소산나트륨 용액과 산 용액을 공급받아 반응시키는 반응조(200)와; 상기 반응조(200)에서 발생된 이산화염소 가스에 포함된 잔류 습기, 아염소산나트륨 및 산을 제거하기 위한 가스 여과조(300)와; 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받아 감압부(400)에서 물과 혼합하여 이산화염소수를 제조하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치에 있어서,A first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing residual moisture, sodium chlorite, and acid contained in the chlorine dioxide gas generated in the reaction tank 200; The pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source. In the device,
    상기 제1 원료저장부(110) 및 제2 원료저장부(120)는 이산화염소 제조를 위한 제1, 2 원료 용액을 각각 저장하면서, 원료 저장수납부(100)에 수납되어 반응조(200)로 제1, 2 원료 용액을 공급하며,The first raw material storage unit 110 and the second raw material storage unit 120 store the first and second raw material solutions for chlorine dioxide production, respectively, and are accommodated in the raw material storage and storage unit 100 to the reaction tank 200. Supplying the first and second raw material solutions,
    상기 반응조(200)는 상기 원료 저장 수납부(100)의 아래쪽에 설치되며, 외부 공기를 유입하는 공기 유입관(210)과, 반응조(200)에서 생성되는 이산화염소 가스를 가스 여과조(300)로 배출하는 가스 배출관(220)을 가지며,The reaction tank 200 is installed below the raw material storage unit 100, an air inlet pipe 210 for introducing external air, and chlorine dioxide gas generated in the reaction tank 200 to the gas filtration tank 300. It has a gas discharge pipe 220 to discharge,
    상기 가스 여과조(300)는, 상기 반응조(200)에서 생성된 이산화염소 가스를 순수 이산화염소 가스로 만들어 감압부(400)로 공급하는 가스 공급관(310)을 가지며,The gas filtration tank 300 has a gas supply pipe 310 for supplying the chlorine dioxide gas generated in the reaction tank 200 to pure chlorine dioxide gas to the decompression unit 400,
    상기 감압부(400)는, 물 공급관(410)으로부터 물을 공급 받으면서, 가스 여과조(300)로부터 순수 이산화염소 가스를 공급받는, 아스피레이터(420)로 이루어지는 것을 특징으로 하는,The depressurization unit 400 is characterized in that it comprises an aspirator 420, which receives water from the water supply pipe 410 and receives pure chlorine dioxide gas from the gas filtration tank 300,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치.A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  2. 제1항에 있어서,The method of claim 1,
    상기 가스 여과조(300)에는 필터부(320)를 설치하고, 상기 필터부(320)는 테프론메쉬, 글래스볼, 폴리머, 규소와 같이 이산화염소와 반응하지 않으면서 습기 정체에 용이한 재료 중에서 선택되는 적어도 하나로 채우는 것으로, 가스 배출관(220)을 통해서 배출되는 이산화염소 가스에 포함되어 있는 미량의 아염소산나트륨과 산까지 반응시켜 2차로 이산화염소 가스를 생성시키며, 습기에 포함된 아염소산나트륨 및 산을 제거하여 순수 이산화염소 가스를 생성하는 것을 특징으로 하는,A filter unit 320 is installed in the gas filtration tank 300, and the filter unit 320 is selected from materials that do not react with chlorine dioxide, such as Teflon mesh, glass ball, polymer, and silicon, and are easy to stagnate moisture. By filling at least one, a trace amount of sodium chlorite and acid contained in the chlorine dioxide gas discharged through the gas discharge pipe 220 are reacted to generate chlorine dioxide gas secondarily, and sodium chlorite and acid contained in moisture are Characterized in that to generate pure chlorine dioxide gas by removing,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치.A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  3. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2,
    상기 감압부(400)의 물 공급관(410)은, 아스피레이터(420)와 병렬로 우회관(430)을 설치하고, 상기 물공급관(410)에는 제1 물 차단 솔레노이드 밸브(411)를 설치하고, 상기 우회관(430)에는 제2 물 차단 솔레노이드 밸브(431)을 설치하는 것을 특징으로 하는,The water supply pipe 410 of the decompression unit 400 is provided with a bypass pipe 430 in parallel with the aspirator 420, and a first water shut-off solenoid valve 411 is installed in the water supply pipe 410 And, characterized in that the second water blocking solenoid valve 431 is installed in the bypass pipe 430,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치.A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  4. 제1항 또는 제2항에 있어서, The method according to claim 1 or 2,
    상기 제1 원료저장부(110) 및 제2 원료저장부(120)는, 링거백으로 하며, 각각의 링거백에는 공급/차단 밸브(112, 122)와 제1, 제2 솔레노이드 밸브(113, 123)를 설치하여 반응조(200)로의 제1 원료 및 제2 원료 공급을 제어하며,The first raw material storage unit 110 and the second raw material storage unit 120 are ringer bags, and supply/shut-off valves 112 and 122 and first and second solenoid valves 113 and 113 are provided in each ringer bag. 123) to control the supply of the first raw material and the second raw material to the reaction tank 200,
    상기 가스 배출관(220)은 가스를 가스 여과조(300)로 감압에 의해 배출시키고, 반응조(200)에 누적된 반응 후 용액의 배출을 원활하게 하기 위하여, 감압해제 유입관(223)에 제3 솔레노이드 밸브(222)를 설치하여, 외부의 공기를 흡입할 수 있도록 제어하는 것을 특징으로 하는,The gas discharge pipe 220 discharges the gas to the gas filtration tank 300 by decompression, and in order to facilitate the discharge of the solution after the reaction accumulated in the reaction tank 200, a third solenoid in the decompression release inlet pipe 223 By installing a valve 222, characterized in that the control so as to intake outside air,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치.A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  5. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2,
    상기 물 공급관(410)의 상류측에 물 흐름 감지 센서(412)를 설치하여, 물 공급관(410)에서의 물 흐름이 감지되지 않는 경우에, 장치를 off시키는 것을 특징으로 하는,By installing a water flow detection sensor 412 on the upstream side of the water supply pipe 410, characterized in that when the water flow in the water supply pipe 410 is not detected, the device is turned off,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 장치.A device for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  6. 이산화염소 가스를 제조하기 위한 원료를 저장하는 제1 원료 저장조(110) 및 제2 원료 저장조(120)와; 상기 제1, 2 원료 저장조(110, 120)에 각각 저장된 아염소산나트륨 용액과 산 용액을 공급받아 반응시키는 반응조(200)와; 상기 반응조(200)에서 발생된 이산화염소 가스에 포함된 습기에 잔류하는 아염소산나트륨 및 산을 제거하기 위한 가스 여과조(300)와; 상기 가스 여과조(300)를 통과한 순수 이산화염소 가스를 공급받아 감압부(400)에서 물과 혼합하여 이산화염소수를 제조하는, 동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법에 있어서,A first raw material storage tank 110 and a second raw material storage tank 120 for storing raw materials for producing chlorine dioxide gas; A reaction tank 200 for receiving and reacting sodium chlorite solution and acid solution stored in the first and second raw material storage tanks 110 and 120, respectively; A gas filtration tank 300 for removing sodium chlorite and acid remaining in moisture contained in the chlorine dioxide gas generated in the reaction tank 200; The pure chlorine dioxide gas that has passed through the gas filtration tank 300 is supplied and mixed with water in the decompression unit 400 to produce chlorine dioxide water, which eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source. In the way,
    링거백으로 이루어진 제1 원료 저장조(110)와 제2 원료 저장조(120)를 원료 저장조 수납부(100)에 수납하는, 제1, 2 원료 저장조(110, 120) 수납 단계(1 단계);First and second raw material storage tanks 110 and 120 receiving step (step 1) of storing the first raw material storage tank 110 and the second raw material storage tank 120 made of a ringer bag in the raw material storage tank storage unit 100;
    물 공급관(410)의 솔레노이드 밸브(411)를 개방하여 물 공급과 동시에 아스피레이터(420)에 의하여 가스 여과조(300)를 감압시키며, 상기 가스 여과조(300)의 감압에 의해 반응조(200)를 감압시키는, 반응조(200) 감압 단계(2 단계);By opening the solenoid valve 411 of the water supply pipe 410, the gas filtration tank 300 is decompressed by the aspirator 420 at the same time as water is supplied, and the reaction tank 200 is depressurized by the decompression of the gas filtration tank 300. Decompressing, the reaction tank 200 decompression step (step 2);
    제1 원료 저장조(110)와 제2 원료 저장조(120)에 저장된 제1, 2 원료를 반응조(200)에 공급하는, 제1, 2 원료액 공급 단계(3 단계);Supplying the first and second raw materials stored in the first raw material storage tank 110 and the second raw material storage tank 120 to the reaction tank 200 (step 3);
    반응조(200)의 감압에 의해 공기 유입관(210)으로 공기가 유입되어 이산화염소 가스를 생성하는, 이산화염소 가스 생성 단계(4 단계);Chlorine dioxide gas generation step (step 4) in which air is introduced into the air inlet pipe 210 by the decompression of the reaction tank 200 to generate chlorine dioxide gas;
    반응조(200)로부터 생성된 이산화염소 가스를 가스 배출관(220)을 통해서 가스 여과조(300)로 공급하고, 이산화염소 가스가 가스 여과조(300)를 통과하면서 순수 이산화염소 가스가 생성되는, 순수 이산화염소 가스 생성 단계(5 단계);Pure chlorine dioxide in which chlorine dioxide gas generated from the reaction tank 200 is supplied to the gas filtration tank 300 through the gas discharge pipe 220, and pure chlorine dioxide gas is generated as the chlorine dioxide gas passes through the gas filtration tank 300 Gas generation step (5 steps);
    상기 순수 이산화연염소 가스가 가스 공급관(310)을 통해서 아스피레이터(420)로 공급되며, 물이 물 공급관(410)을 통해서 아스피레이터(420)로 공급되어, 순수 이산화염소 가스와 물이 혼합되어 이산화염소수를 제조하는, 이산화염소수 제조 단계(5단계);로 이루어지는 것을 특징으로 하는,The pure chlorine dioxide gas is supplied to the aspirator 420 through the gas supply pipe 310, and water is supplied to the aspirator 420 through the water supply pipe 410, so that the pure chlorine dioxide gas and water Characterized in that consisting of; mixing to prepare chlorine dioxide water, chlorine dioxide water production step (step 5);
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법.A method for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
  7. 제6항에 있어서,The method of claim 6,
    상기 3 단계에서 제1, 2 원료액의 반응조(200)에의 공급은, 공급/차단 밸브(112, 122) 및 제1, 2 솔레노이드 밸브(113, 123)에 의하여 이루어지며,In the third step, the supply of the first and second raw material liquids to the reaction tank 200 is performed by the supply/blocking valves 112 and 122 and the first and second solenoid valves 113 and 123,
    상기 2 단계 내지 6단계에 있어서 물 공급관(410)에 설치된 물 흐름 감지 센서(412)로부터 물 흐름이 감지되지 않는 경우에는, 장치가 off되는 것을 특징으로 하는,When the water flow is not detected from the water flow detection sensor 412 installed in the water supply pipe 410 in steps 2 to 6, the device is turned off,
    동력원 없는 감압 방식 원료 공급 및 반응으로 폭발 위험성을 제거한 이산화염소수 제조 방법.A method for producing chlorine dioxide water that eliminates the risk of explosion by supplying and reacting raw materials in a reduced pressure method without a power source.
PCT/KR2020/003536 2019-06-24 2020-03-13 Apparatus and method for producing aqueous chlorine dioxide eliminating risk of explosion by supplying and reacting raw material using power source-free decompression method WO2020262798A1 (en)

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KR102482888B1 (en) * 2020-05-19 2022-12-28 유숙정 Aqueous chlorine dioxide having high purity and the manufacturing method thereof
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