WO2020218851A1 - Environment-friendly nonflammable furniture material including expanded vermiculite and method for manufacturing same - Google Patents

Environment-friendly nonflammable furniture material including expanded vermiculite and method for manufacturing same Download PDF

Info

Publication number
WO2020218851A1
WO2020218851A1 PCT/KR2020/005384 KR2020005384W WO2020218851A1 WO 2020218851 A1 WO2020218851 A1 WO 2020218851A1 KR 2020005384 W KR2020005384 W KR 2020005384W WO 2020218851 A1 WO2020218851 A1 WO 2020218851A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
mixture
charcoal
expanded vermiculite
parts
Prior art date
Application number
PCT/KR2020/005384
Other languages
French (fr)
Korean (ko)
Inventor
임흥묵
Original Assignee
임흥묵
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 임흥묵 filed Critical 임흥묵
Publication of WO2020218851A1 publication Critical patent/WO2020218851A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • C04B14/202Vermiculite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • C04B14/204Mica; Vermiculite expanded
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/10Burned or pyrolised refuse
    • C04B18/101Burned rice husks or other burned vegetable material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/34Natural resins, e.g. rosin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to an eco-friendly non-combustible furniture material including expanded vermiculite and a method of manufacturing the same, and more particularly, it is eco-friendly, harmless to the human body, can provide humidity control function, antibacterial property and deodorization, and is easy to handle with light weight compared to volume.
  • the present invention relates to an eco-friendly non-combustible furniture material including expanded vermiculite having superior compressive strength compared to conventional non-combustible furniture materials and a manufacturing method thereof.
  • Furniture stores various objects or provides a space for objects to be used in a more comfortable position, and is generally made of solid wood, plywood, MDF, HDF, P/B, and H/B.
  • furniture mainly using wood is relatively affected by moisture due to its material characteristics, and this moisture induces the growth of mold and moth in the furniture, as well as an environment suitable for insects such as cockroaches to inhabit.
  • the user side is making various efforts to prevent the items such as blankets, clothes, or books stored therein from being deteriorated, but the effect is still insufficient.
  • the conventional furniture made of artificial or synthetic wood is non-flammable and is manufactured to be lightweight for ease of transportation and operation.
  • conventional furniture materials are manufactured by including various types of non-combustible compositions.
  • non-combustible compositions use non-flammable agents or flame retardants made of various kinds of chemical substances to lower the price, and these chemical substances include various allergic diseases or respiratory diseases including formalin, toluene, volatile organic substances, etc. Not only does it cause various problems that are harmful to the human body such as, but also causes environmental pollution when discarded.
  • a furniture material using expanded vermiculite is disclosed.
  • the expanded vermiculite has a porous characteristic, when a furniture material is manufactured with expanded vermiculite as a main component, the strength is basically weak, so it is difficult to satisfy the strength level of the product when applied to a sink top, a bookcase, a dining table, etc.
  • recently released furniture materials further contain various types of additives to add various functional properties such as antibacterial and deodorizing properties to increase marketability.
  • additives When these additives are added to the furniture material containing expanded vermiculite as a main component, the bonding strength of each component is further lowered, and as a result, the compressive strength of the furniture material may be further weakened.
  • the present invention was conceived to solve the problems of conventional furniture materials, and provides excellent compressive strength over a certain level while having non-combustible and lightweight characteristics, and is easy to manufacture in various shapes desired by users, and is harmless to the human body and humidity. It is an object of the present invention to provide an eco-friendly non-combustible furniture material including expanded vermiculite and a method of manufacturing the same so as to have various functional characteristics such as control function, antibacterial property and deodorant property.
  • One aspect of the present invention is a second mixture formed by mixing the expanded vermiculite pulverized into 20 to 25 mesh and 5 to 30 parts by weight of the first mixture based on 100 parts by weight of the expanded vermiculite; And a third mixture formed by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh. Consisting of, wherein the first mixture comprises 50 to 70% by weight of rosin powder pulverized with 300 to 325 mesh based on the total weight, and 30 to 50% by weight of alcohol, based on the total weight of the second mixture 80 to It provides an eco-friendly non-combustible furniture material comprising expanded vermiculite, characterized in that it comprises 95% by weight and 5 to 20% by weight of the third mixture.
  • the third mixture may contain 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is a first charcoal made of oak as a raw material and having a bar-shaped structure It may include 20 to 50% by weight of the powder, and 50 to 80% by weight of the second charcoal powder, which is made of pine and has a spherical structure.
  • the third mixture contains 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda
  • the charcoal is a first charcoal powder 10 made of oak as a raw material and having a bar-shaped structure.
  • the second charcoal powder having a spherical structure with pine as a raw material, and 20 to 45% by weight of the third charcoal powder formed by burning rice husk in a high temperature vacuum state. I can.
  • Another aspect of the present invention is a first step of preparing a first mixture by mixing 50 to 70% by weight of rosin powder pulverized into 300 to 325 mesh and 30 to 50% by weight of alcohol at room temperature; A second step of heating vermiculite at 1,000 to 1,100°C to prepare expanded vermiculite, and pulverizing the expanded vermiculite into 20 to 25 mesh; A third step of mixing 5 to 30 parts by weight of the first mixture with respect to 100 parts by weight of pulverized expanded vermiculite and stirring at 100° C.
  • a fourth step of preparing a liquefied third mixture by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh based on 100 parts by weight of the liquid silicate soda and stirring for 2 to 3 hours; And a fifth step of preparing a fourth mixture by stirring 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture for 2 to 3 hours based on the total weight of the fourth mixture.
  • the third mixture may be prepared by mixing 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is obtained by burning oak wood in a vacuum at 800°C. It may include 20 to 50% by weight of the first charcoal powder having a rod-shaped structure provided, and 50 to 80% by weight of the second charcoal powder having a spherical structure prepared by burning pine trees at 800°C in a vacuum.
  • the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is obtained by burning oak wood in a vacuum at 800°C. 10 to 35% by weight of the first charcoal powder having a rod-shaped structure provided, 25 to 45% by weight of the second charcoal powder having a spherical structure prepared by burning pine trees in a vacuum at 800°C, and a vacuum of rice hull at 1,500°C
  • eco-friendly compositions such as expanded vermiculite, charcoal, and liquid silicate soda are used, and various functional characteristics such as humidity control function, antibacterial and deodorizing properties can be provided by the expanded vermiculite and charcoal. It can prevent various allergic diseases or respiratory diseases arising from furniture that directly or indirectly touches.
  • the furniture material is molded while the resin powder fills the gap between the expanded vermiculite and the charcoal in a state where the porous expanded vermiculite is combined with charcoal, the manufactured furniture material is lightweight and non-combustible by volume, but has excellent compressive strength compared to existing non-combustible furniture materials. It has the effect of increasing the added value of furniture materials.
  • the eco-friendly non-combustible furniture material manufactured according to the present embodiment is pulverized and liquefied at the time of disposal, it can be used again as a material for other furniture materials, so it is advantageous in recycling of resources and environmental protection.
  • FIG. 1 is a flowchart illustrating a method of manufacturing an eco-friendly non-combustible furniture material including expanded vermiculite according to an embodiment of the present invention.
  • Figure 2 is a photograph showing the expanded vermiculite used in an embodiment of the present invention.
  • FIG. 3 is a photograph showing a rosin powder used in an embodiment of the present invention.
  • FIG. 4 is a photograph showing a state before the third charcoal powder used in an embodiment of the present invention is pulverized.
  • FIG. 5 is a flowchart illustrating a method of manufacturing an eco-friendly furniture material including expanded vermiculite according to another embodiment of the present invention.
  • FIG. 6 is a perspective view schematically showing a furniture material according to an embodiment of the present invention by partially cutting it.
  • FIG. 6 is a perspective view schematically showing a furniture material according to an embodiment of the present invention by partially cutting it.
  • the eco-friendly non-combustible furniture material 10 including expanded vermiculite includes an inner body 1 and a coating layer 2 covering the surface of the inner body 1 I can.
  • the coating layer 2 may be formed by coating an inorganic binder on the surface of the inner body 1.
  • the inner body 1 may be formed including 90% by weight of the second mixture and 10% by weight of the third mixture based on the total weight.
  • the second mixture may be formed by mixing expanded vermiculite and 5 to 30 parts by weight of the first mixture based on 100 parts by weight of expanded vermiculite.
  • the content of the first mixture is less than 5 parts by weight, the bonding strength of the rosin powder may not be sufficient, so that the strength of the furniture material may decrease.
  • a relatively high content of the expanded vermiculite may cause problems in that the homogeneity of the second mixture is deteriorated, such as not being properly liquefied when the second mixture is prepared, or a part of the expanded vermiculite is locally agglomerated. This homogeneity problem can consequently act as a cause of lowering the compressive strength of furniture materials.
  • the content of the first mixture exceeds 30 parts by weight, the content of expanded vermiculite is relatively small, and various effects of the expanded vermiculite may not be properly implemented.
  • the expanded vermiculite may be pulverized into particles having a size of 20 to 25 mesh. If the size of the pulverized expanded vermiculite is less than 20 mesh, there may be a problem that the vermiculite particles are exposed to the surface of the molded furniture material, making it difficult to see visually. If the size of the pulverized expanded vermiculite exceeds 25 mesh, when mixing raw materials Since mixing is difficult, the liquefaction of the second mixture is not performed properly, which may cause manufacturing problems.
  • the expanded vermiculite is a lightweight, natural material that is harmless to the human body and is an eco-friendly material.
  • the expanded vermiculite has excellent non-combustibility of the first grade, and has good absorption capacity as a porous structure, so it is very effective when used as a furniture material mainly installed indoors.
  • the first mixture may include 50 to 70% by weight of rosin powder pulverized with 300 to 325 mesh and 30 to 50% by weight of alcohol based on the total weight.
  • liquid sodium silicate as a binder to reinforce strength.
  • liquid silicate soda due to its characteristics, liquid silicate soda has poor flow characteristics, so it is difficult to uniformly mix when mixing raw materials, and if a certain amount or more is excessively added, problems such as agglomeration or lump formation may occur.
  • liquid sodium silicate may be replaced with a first mixture consisting of rosin powder and alcohol, and used as a binder between expanded vermiculite, which will be described later.
  • the size of the pulverized rosin powder is less than 300 mesh, some of the particles of the rosin powder may be exposed to the surface of the furniture material, causing visually unfavorable problems. If the size of the pulverized rosin powder exceeds 325 mesh, the dispersibility As this decreases, the homogeneity of the first mixture is lowered, and thus the second mixture is not properly liquefied, so that the bonding strength of the rosin powder may decrease, and as a result, the compressive strength of the furniture material may decrease.
  • such rosin powder When liquefied, such rosin powder is a natural material with excellent adhesion and bonding power, and is harmless to the human body, and is located in the gap between adjacent expanded vermiculite to increase the bonding strength between expanded vermiculite, thereby improving the compressive strength of furniture material that is compressed and molded with high heat.
  • the resin powder since the resin powder is a material having excellent waterproof properties, it can impart excellent waterproof properties to the finished furniture material.
  • the content of the rosin powder in the first mixture is less than 50% by weight, the bonding force between the expanded vermiculite is lowered, and thus the compressive strength of the furniture material may be lowered.
  • rosin is a vaporizable material, it is preferable that the content of rosin powder does not exceed 70% by weight in order to maintain the incombustibility of the present invention at a certain level.
  • the content of alcohol in the first mixture is less than 30% by weight, mixing may not be performed properly when the first mixture is blended, so that some of the rosin powder may remain undissolved, thereby reducing homogeneity.
  • the alcohol content exceeds 50% by weight, the content of the rosin powder is relatively small, so as described above, the compressive strength of the building material is deteriorated.
  • the third mixture may be formed by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh.
  • the size of the pulverized charcoal is less than 200 mesh, there may be a problem that the charcoal particles are exposed to the surface of the molded furniture material, making it difficult to see visually. If the size of the pulverized charcoal exceeds 325 mesh, liquid sodium silicate It is not mixed properly and some clumps or lumps may occur. Accordingly, the third mixture may not properly fill the space between the hole of the expanded vermiculite and the expanded vermiculite, and as a result, the quality and strength of the furniture material may be deteriorated.
  • the charcoal is a natural material that is harmless to the human body and is environmentally friendly, has excellent humidity control functions, has excellent antibacterial properties, sterilization properties, and deodorization properties, and can be expected to radiate far-infrared rays.
  • charcoal may be made of a variety of wood as a raw material, preferably may be prepared from a raw material consisting of oak and pine.
  • the charcoal is 20 to 50% by weight of the first charcoal powder having an oak as a raw material and a bar-shaped structure, and 50 to 80% by weight of the second charcoal powder having a pine tree as a raw material and having a spherical structure May contain %.
  • the second charcoal powder may serve to improve homogeneity when blended with the second mixture by maintaining the viscosity of the second mixture in a thick state.
  • the second charcoal powder is filled in the gaps provided between the first charcoal powders that are in close contact with each other to increase the density of the third mixture and at the same time serve as a binder to allow the charcoal to be well combined with the liquid sodium silicate. Accordingly, when a third mixture is prepared by composing charcoal with the first charcoal powder and the second charcoal powder as in the present embodiment, as a result, the first charcoal powder and the second charcoal powder having different shapes are combined in an entangled state to compress furniture materials. Strength and workability can be further improved.
  • the content of charcoal in the third mixture may be limited to 15 to 25 parts by weight based on 100 parts by weight of liquid silicate soda.
  • the content of the first charcoal powder is less than 20% by weight, the overall strength provided by the charcoal may decrease, and the content of the second charcoal powder is relatively increased. Since it is a weak material, it is preferable to maintain the content of the first charcoal powder at 20% by weight or more in order to maintain the non-flammability of the present embodiment at a certain level.
  • the third mixture may further include a third charcoal powder in addition to the first and second charcoal powders, if necessary.
  • the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda. If the content of charcoal is less than 40 parts by weight, the bonding strength is weakened and the strength of the composition decreases, and the functional characteristics of charcoal such as excellent humidity control function, antibacterial property, sterilization property and deodorization property may not be properly implemented.
  • this third mixture is stirred for 2 to 3 hours with 10 to 35% by weight of the first charcoal powder, 25 to 45% by weight of the second charcoal powder, and 20 to 45% by weight of the third charcoal powder based on 100 parts by weight of liquid silicate soda. It can be prepared.
  • the third charcoal powder may be formed by burning rice husk in a high temperature vacuum.
  • the rice husk is an eco-friendly material that is inexpensive and has far-infrared radiation, and is harmless to the human body.
  • the third charcoal powder prepared from rice husk has the advantage of being well mixed with liquid silicate soda serving as an inorganic binder.
  • the third charcoal powder acts as a curing agent when reacted with liquid sodium silicate, and thus, it may play a role of further improving the non-combustibility of furniture and increasing the strength. If the content of the third charcoal powder is less than 20% by weight, the effect of the third charcoal powder may not be properly realized, and if the content of the third charcoal powder is more than 45% by weight, the bonding strength may be weakened.
  • the inner body 1 may include 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture based on the total weight. .
  • the expanded vermiculite contained in the second mixture has a porous structure, and the resin powder of the first mixture has filled some of the spaces between the pores of the expanded vermiculite and the expanded vermiculite.
  • the second mixture and the third mixture are stirred , while the third mixture fills the remaining spaces in the expanded vermiculite of the second mixture, it is possible to form the inner body 1 of the furniture material having significantly improved compressive strength.
  • the content of the third mixture is less than 5% by weight, some of the empty spaces of the second mixture are not filled, so that the compressive strength of the furniture material to be molded may be lowered.
  • the content of the third mixture is more than 20% by weight, a part of the third mixture remains even after all the empty spaces of the second mixture are filled, resulting in a problem that the homogeneity of the inner body 1 is lowered.
  • the content of the liquid sodium silicate increases, making it difficult to uniformly mix the raw material when mixing the raw material, and a problem such as lumping or lumping of some components in the molded interior body 1 may occur. (1) A problem of deteriorating the quality may occur.
  • FIG. 1 is a flow chart illustrating a method of manufacturing an eco-friendly non-combustible furniture material including expanded vermiculite according to an embodiment of the present invention
  • FIG. 2 is a photograph showing the expanded vermiculite used in an embodiment of the present invention
  • FIG. 3 is Fig. 4 is a picture showing a state before the third charcoal powder used in an embodiment of the present invention is pulverized.
  • a first step of pulverizing the rosin powder into 300 to 325 mesh, and mixing 50 to 70% by weight of the pulverized rosin powder and 30 to 50% by weight of alcohol may be performed ( S1).
  • the first step is preferably performed at room temperature.
  • a second step (S2) of preparing and crushing expanded vermiculite may be performed.
  • vermiculite is rapidly heated at 1,000 to 1,100°C so that it expands up to about 20 times.
  • the expanded vermiculite as a main component can be prepared by transforming the vermiculite into a porous material having numerous holes.
  • the vermiculite when the vermiculite is calcined at a temperature lower than 1,000°C, some of the vermiculite is calcined less, and thus the properties of the expanded vermiculite prepared may be deteriorated.
  • the vermiculite particles when the vermiculite is calcined at a temperature higher than 1,100°C, the vermiculite particles may crumble or crumble, and the vermiculite powder may be blown out or part of the vermiculite may be aggregated into a lump when mixing the raw materials.
  • the expanded vermiculite after the second step is pulverized into particles having a size of 20 to 25 mesh. If the size of the pulverized expanded vermiculite exceeds 25 mesh, mixing may be difficult when mixing the raw materials, which may cause a problem in that the liquefaction of the second mixture is not properly performed in the third step below.
  • the second mixture is not properly liquefied, the workability is significantly lowered when preparing the compressed body for manufacturing furniture, so even if the compressed body is processed by pressing the fourth mixture of the present embodiment at high temperature and high pressure, the shape will be as desired by the manufacturer. There may be a problem that it is not formed properly or its quality is significantly deteriorated.
  • the second step of expanding vermiculite is a process of heating the vermiculite at a very high temperature for a certain period of time, a purification action in which all foreign substances such as radon and various bacteria in the vermiculite are removed can be performed together. Therefore, the stability of furniture materials can be further increased.
  • a third step of preparing a liquefied second mixture using the expanded vermiculite pulverized in the second step as a main component proceeds (S2).
  • this third step 5 to 30 parts by weight of the first mixture is mixed with respect to 100 parts by weight of expanded vermiculite and stirred at 100° C. for 1 to 2 hours to prepare a second mixture.
  • the second mixture may be formed by simultaneously adding the first mixture and expanded vermiculite to a mixer to mix, and then stirring the mixture at 100° C. for 1 to 2 hours and cooling naturally.
  • the stirring and natural cooling process of the expanded vermiculite and the first mixture may preferably be repeated five times, which is to increase the viscosity of the second mixture in order to improve workability when manufacturing furniture with a fourth mixture to be described later. This is in order to increase the level to an appropriate maintenance level and also to improve the reactivity with the third mixture described later.
  • the process of stirring and natural cooling of the expanded vermiculite and the first mixture is repeated 4 or less times, the viscosity of the second mixture does not rise to a sufficient level of fluidity, and as a result, the reactivity with the third mixture decreases and the strength of the furniture material decreases. Problems may occur.
  • the stirring and natural cooling process of the expanded vermiculite and the first mixture is preferably repeated only five times, since there is no significant difference in effect even if repeated six or more times.
  • the charcoal is pulverized into 200 to 325 mesh, and liquid sodium silicate (sodium silicate) serving as an inorganic binder and the pulverized charcoal are stirred to prepare a third liquefied mixture. (S4). Since the third mixture fills the space between the expanded vermiculite and the expanded vermiculite in the second mixture, it can increase the strength of the molded furniture material.
  • liquid sodium silicate sodium silicate
  • such charcoal may be made of a variety of wood as a raw material, preferably may be prepared from a raw material consisting of oak and pine.
  • the charcoal may include two types of charcoal powder having different textures, and more specifically, the first charcoal powder having a large and elongated bar-shaped structure and a relatively small and rounded sphere-shaped It may include a second charcoal powder having a texture.
  • the first charcoal powder may be prepared by burning oak wood at 800°C in a vacuum and has a relatively harder strength
  • the second charcoal powder may be prepared by burning pine wood at 800°C in a vacuum.
  • the charcoal may preferably include 20 to 50% by weight of the first charcoal powder and 50 to 80% by weight of the second charcoal powder.
  • the third mixture may be prepared by further mixing and stirring the third charcoal powder.
  • the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda. If the content of charcoal is less than 40 parts by weight, the bonding strength is weakened and the strength of the composition decreases, and the functional characteristics of charcoal such as excellent humidity control function, antibacterial property, sterilization property and deodorization property may not be properly implemented.
  • the third charcoal powder may be prepared by burning rice husk at 1,500° C. vacuum.
  • rice husk is preferably used in preparing the third charcoal powder in this embodiment is because the carbon content of rice husk is very high.
  • the first to third charcoal powder obtained through the above process is preferably mixed with liquid sodium silicate after passing through five crushing operations. At this time, if the crushing operation is repeated less than five times, the homogeneity of the third mixture may be reduced, and the adhesive strength of the liquid sodium silicate may be decreased.
  • the third mixture prepared as described above may be rolled to a thickness of 2 to 3 mm using a roller in a rolling mill and pressurized in a subsequent process (S10) may be additionally repeated three times.
  • the first to third charcoal powders included in the third mixture are spread evenly throughout the third mixture, thereby improving adhesion, and as a result, the strength of the composition may be improved.
  • a fifth step of preparing a fourth mixture by mixing the second mixture and the third mixture is performed (S5).
  • the fourth mixture may be prepared by stirring 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture for 2 to 3 hours based on the total weight of the fourth mixture.
  • the expanded vermiculite contained in the second mixture has a porous structure, and the resin powder of the first mixture has filled some of the spaces between the pores of the expanded vermiculite and the expanded vermiculite.
  • the second mixture and the third mixture are stirred , As the third mixture fills the voids between the expanded vermiculite of the second mixture, a fourth mixture having significantly improved compressive strength is formed.
  • the content of the third mixture is less than 5% by weight, a part of the space of the second mixture is not filled, so that the compressive strength of the compressed body and the finished furniture material may decrease.
  • the content of the third mixture is more than 20% by weight, a portion of the third mixture remains even after all the empty spaces of the second mixture are filled, resulting in a problem that the homogeneity of the fourth mixture decreases.
  • the content of the liquid soda silicate increases, making it difficult to uniformly mix the raw materials, and problems such as lumping or lumping of some components in the fourth mixture may occur. Problems can arise.
  • a mold having a shape corresponding to the shape of the furniture material to be produced is prepared, and the fourth mixture is put into a mold heated at 180 to 230°C, and pressed for 5 minutes with a high pressure press of 2,000 to 2,300 tons to obtain a desired shape. Proceeds to the sixth step of providing the compressed body (S6).
  • the mold may have various shapes and thicknesses according to the furniture material.
  • the first mixture is prepared by mixing the rosin powder and alcohol to make the rosin powder homogeneous.
  • the expanded vermiculite is mixed to prepare a liquefied second mixture to homogenize the expanded vermiculite, and a third liquefied mixture in which the charcoal becomes homogeneous is prepared by mixing liquid sodium silicate and finely ground charcoal. 2
  • charcoal is filled between the expanded vermiculite, and the fourth mixture is homogeneous and has excellent bonding strength between the components, so that a fourth mixture capable of providing high strength can be prepared. Therefore, while taking all the beneficial effects of each component, it is possible to minimize problems that may occur while each component is mixed.
  • charcoal fills the space formed in the expanded vermiculite, and soda silicate and rosin powder are combined to fill the gap, so that it is possible to manufacture eco-friendly non-combustible furniture material that is lightweight and has superior strength and non-flammability than existing furniture materials.
  • a seventh step of natural cooling for 72 hours or more by demolding the compressed body from the mold is performed (S7). If the natural cooling time of the seventh step is less than 72 hours, the strength of the compressed body may decrease. In addition, when the temperature for cooling the compressed body is significantly different from room temperature, defects such as cracks may occur during the drying process of the compressed body.
  • the eighth step of removing the surface foreign matter of the compressed body using sandpaper or chamfering is performed (S80).
  • a foreign material removal process is not limited to sandpaper or chamfering, and may be performed through various other methods.
  • a ninth step of coating the surface of the compressed body with an inorganic binder is performed (S9).
  • an inorganic binder is first coated on the upper and side surfaces of the compact, dried, and then turned over and secondarily coated with an inorganic binder on the lower and side surfaces of the compact and dried. Furniture materials can be completed.
  • the eco-friendly non-combustible furniture material configured as described above can be applied to furniture for various purposes, such as desk tops and wardrobes having a thickness of 15, 18, 23 and 28 mm.
  • the furniture material of the present invention can be modified in various forms other than those described above, and all modified embodiments should also be construed as belonging to the scope of the present invention, unless departing from the technical spirit of the present invention.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Building Environments (AREA)

Abstract

The present invention provides an environment-friendly nonflammable furniture material comprising expanded vermiculite and a method for manufacturing same, wherein the material, by using an environment-friendly composition, is harmless to the human body, can provide a humidity control function and antibacterial and deodorant properties, is easy to handle due to being lightweight relative to its volume, and is non-flammable while having superior compressive strength.

Description

팽창 질석을 포함하는 친환경 불연성 가구재 및 그 제조 방법Eco-friendly non-combustible furniture material containing expanded vermiculite and its manufacturing method
본 발명은 팽창 질석을 포함하는 친환경 불연성 가구재 및 그 제조 방법에 관한 것으로, 더욱 상세하게는 인체에 무해한 친환경적이며, 습도 조절 기능, 항균성 및 탈취성을 제공할 수 있고, 부피 대비 경량으로 취급이 용이하고 불연성을 가지면서도 기존의 불연성 가구재 대비 우수한 압축 강도를 가지는 팽창 질석을 포함하는 친환경 불연성 가구재 및 그 제조 방법에 관한 것이다.The present invention relates to an eco-friendly non-combustible furniture material including expanded vermiculite and a method of manufacturing the same, and more particularly, it is eco-friendly, harmless to the human body, can provide humidity control function, antibacterial property and deodorization, and is easy to handle with light weight compared to volume. The present invention relates to an eco-friendly non-combustible furniture material including expanded vermiculite having superior compressive strength compared to conventional non-combustible furniture materials and a manufacturing method thereof.
가구는 각종 사물을 보관하거나 사용 중인 물건을 더욱 편안한 자세로 사용할 수 있도록 물건이 놓을 수 있는 공간을 제공하며, 일반적으로 원목, 합판, MDF, HDF, P/B, H/B 등으로 이루어진다.Furniture stores various objects or provides a space for objects to be used in a more comfortable position, and is generally made of solid wood, plywood, MDF, HDF, P/B, and H/B.
이와 같이 목재를 주로 사용하는 가구는 재질적 특성상 습기의 영향을 비교적 많이 받게 되며, 이러한 습기는 가구 내에 곰팡이나 좀의 번식을 유발하는 것을 물론이고 심지어는 바퀴 벌레 등의 해충이 서식하기에 적합한 환경을 제공함으로써 가구를 사용하는 사용자측에서는 그 내부에 보관된 이불, 옷 또는 책 등의 물품이 변질되는 것을 방지하기 위하여 다양한 노력을 취하고 있지만, 아직까지는 그 효과가 미흡한 실정이다. As such, furniture mainly using wood is relatively affected by moisture due to its material characteristics, and this moisture induces the growth of mold and moth in the furniture, as well as an environment suitable for insects such as cockroaches to inhabit. By providing the furniture, the user side is making various efforts to prevent the items such as blankets, clothes, or books stored therein from being deteriorated, but the effect is still insufficient.
또한, 원목을 이용하는 경우 강도나 기타 여러 가지 면에서 바람직하다 하겠으나 원목 자체를 수입에 의존하여야 함에 따라 국익에 반할 뿐만 아니라 고가(高價)이고, 가공성에 한계가 있어 상당한 부담을 주게 되며, 이러한 점을 고려하여 합판, MDF 등과 같은 목재 재질 또는 파티클 보드로 구성되어 비교적 염가로 공급되고 있는 인조목이나 합성목 등이 널리 사용되고 있다In addition, in the case of using solid wood, it may be said that it is desirable in terms of strength and other various aspects, but as the wood itself must be dependent on imports, it is not only contrary to national interests, it is expensive, and there is a limit in processability, which puts a considerable burden on it. Considering that, artificial wood or synthetic wood, which is made of wood materials such as plywood, MDF, or particle board, which are supplied at a relatively low price, is widely used.
종래의 인조목이나 합성목으로 된 가구재는 불연성을 가지며 운반 및 작업 상의 용이함을 위해 경량이 되도록 제작하는 것이 바람직하다. 또한, 싱크대 상판, 책장, 식탁 등에 사용되는 가구재의 특성상 고강도를 요구하는 제품이 많다.It is preferable that the conventional furniture made of artificial or synthetic wood is non-flammable and is manufactured to be lightweight for ease of transportation and operation. In addition, there are many products that require high strength due to the characteristics of furniture materials used for sink tops, bookcases, and dining tables.
이 중에서 불연성과 관련된 문제를 해소하기 위해, 종래의 가구재는 여러 가지 종류의 불연성 조성물을 포함시켜 제조하고 있다.Among them, in order to solve the problem related to non-combustibility, conventional furniture materials are manufactured by including various types of non-combustible compositions.
그러나, 종래의 불연성 조성물은 가격을 낮추기 위해 다양한 종류의 화학 물질로 이루어진 불연제 또는 난연제 등을 사용하게 되는데, 이러한 화학 물질은 포르말린, 톨루엔, 휘발성 유기 물질 등을 포함하여 각종 알레르기성 질환이나 호흡기 질환과 같은 인체에 해로운 여러 가지 문제를 일으킬 뿐만 아니라 폐기시 환경 오염을 발생시키게 된다.However, conventional non-combustible compositions use non-flammable agents or flame retardants made of various kinds of chemical substances to lower the price, and these chemical substances include various allergic diseases or respiratory diseases including formalin, toluene, volatile organic substances, etc. Not only does it cause various problems that are harmful to the human body such as, but also causes environmental pollution when discarded.
또한, 가구재의 무게를 줄이기 위한 하나의 방법으로, 팽창 질석을 이용하는 가구재가 개시되어 있다. 그러나, 상기 팽창 질석은 다공질의 특성을 가지고 있어서, 팽창 질석을 주성분으로 가구재를 제조하면, 기본적으로 강도가 약하기 때문에 싱크대 상판, 책장, 식탁 등에 적용하는 경우 제품의 강도 수준을 만족시키기 어렵다.In addition, as one method for reducing the weight of the furniture material, a furniture material using expanded vermiculite is disclosed. However, since the expanded vermiculite has a porous characteristic, when a furniture material is manufactured with expanded vermiculite as a main component, the strength is basically weak, so it is difficult to satisfy the strength level of the product when applied to a sink top, a bookcase, a dining table, etc.
또한, 최근 출시되는 가구재는 상품성을 높이기 위해 항균성 및 탈취성 등의 여러 기능적 특성을 추가하기 위해 다양한 종류의 첨가제를 더 포함하고 있다. 팽창 질석을 주성분으로 하는 가구재에 이러한 첨가제들을 추가하면 각 성분의 결합력은 더 저하되므로, 결과적으로 가구재의 압축 강도가 더 약화되는 결과를 초래할 수 있다.In addition, recently released furniture materials further contain various types of additives to add various functional properties such as antibacterial and deodorizing properties to increase marketability. When these additives are added to the furniture material containing expanded vermiculite as a main component, the bonding strength of each component is further lowered, and as a result, the compressive strength of the furniture material may be further weakened.
선행기술문헌Prior art literature
특허문헌Patent Literature
국내등록특허공보 10-0695910호Korean Patent Publication No. 10-0695910
국내등록특허공보 10-1213988호Korean Patent Publication No. 10-1213988
본 발명은 종래의 가구재가 가지는 문제를 해소하기 위해 안출된 것으로서, 불연성 및 경량의 특징을 가지면서도 일정 수준 이상의 우수한 압축 강도를 제공하고 사용자가 원하는 다양한 형태로 제작이 용이하며, 인체에 무해하고 습도 조절 기능, 항균성 및 탈취성 등의 다양한 기능적 특성을 가질 수 있도록 한 팽창 질석을 포함하는 친환경 불연성 가구재 및 그 제조 방법을 제공하는데 그 목적이 있다.The present invention was conceived to solve the problems of conventional furniture materials, and provides excellent compressive strength over a certain level while having non-combustible and lightweight characteristics, and is easy to manufacture in various shapes desired by users, and is harmless to the human body and humidity. It is an object of the present invention to provide an eco-friendly non-combustible furniture material including expanded vermiculite and a method of manufacturing the same so as to have various functional characteristics such as control function, antibacterial property and deodorant property.
본 발명의 일 측면은, 20 내지 25메쉬로 분쇄한 팽창 질석과, 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하여 형성되는 제2 혼합물; 및 액상 규산 소다와 200 내지 325메쉬로 분쇄한 숯을 혼합하여 형성되는 제3 혼합물; 로 이루어지되, 상기 제1 혼합물은, 총 중량에 대하여 300 내지 325메쉬로 분쇄한 송진 분말 50 내지 70중량%와, 알코올 30 내지 50중량%를 포함하고, 총 중량에 대하여 상기 제2 혼합물 80 내지 95중량%와 상기 제3 혼합물 5 내지 20중량%를 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재를 제공한다.One aspect of the present invention is a second mixture formed by mixing the expanded vermiculite pulverized into 20 to 25 mesh and 5 to 30 parts by weight of the first mixture based on 100 parts by weight of the expanded vermiculite; And a third mixture formed by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh. Consisting of, wherein the first mixture comprises 50 to 70% by weight of rosin powder pulverized with 300 to 325 mesh based on the total weight, and 30 to 50% by weight of alcohol, based on the total weight of the second mixture 80 to It provides an eco-friendly non-combustible furniture material comprising expanded vermiculite, characterized in that it comprises 95% by weight and 5 to 20% by weight of the third mixture.
본 발명의 일 실시 예에서, 상기 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 15 내지 25중량부를 포함할 수 있고, 상기 숯은, 참나무를 원료로 하고 막대 형태의 조직을 갖는 제1 숯 분말 20 내지 50중량%, 및 소나무를 원료로 하고 구 형태의 조직을 갖는 제2 숯 분말 50 내지 80중량%를 포함할 수 있다.In one embodiment of the present invention, the third mixture may contain 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is a first charcoal made of oak as a raw material and having a bar-shaped structure It may include 20 to 50% by weight of the powder, and 50 to 80% by weight of the second charcoal powder, which is made of pine and has a spherical structure.
본 발명의 일 실시 예에서, 상기 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 포함하고, 상기 숯은, 참나무를 원료로 하고 막대 형태의 조직을 갖는 제1 숯 분말 10 내지 35중량%와, 소나무를 원료로 하고 구 형태의 조직을 갖는 제2 숯 분말 25 내지 45중량%와, 왕겨를 고온 진공 상태에서 연소하여 형성되는 제3 숯 분말 20 내지 45중량%를 포함할 수 있다.In an embodiment of the present invention, the third mixture contains 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is a first charcoal powder 10 made of oak as a raw material and having a bar-shaped structure. To 35% by weight, and 25 to 45% by weight of the second charcoal powder having a spherical structure with pine as a raw material, and 20 to 45% by weight of the third charcoal powder formed by burning rice husk in a high temperature vacuum state. I can.
본 발명의 다른 측면은, 300 내지 325메쉬로 분쇄한 송진 분말 50 내지 70중량%와 알코올 30 내지 50중량%를 상온에서 혼합하여 제1 혼합물을 마련하는 제1 단계; 질석을 1,000 내지 1,100℃에서 가열하여 팽창 질석을 마련하고, 이 팽창 질석을 20 내지 25메쉬로 분쇄하는 제2 단계; 분쇄한 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하고 100℃에서 교반하여 액상화된 제2 혼합물을 마련하는 제3 단계; 액상 규산 소다와, 상기 액상 규산 소다 100중량부에 대하여 200 내지 325메쉬로 분쇄한 숯을 혼합하고 2 내지 3시간 동안 교반하여 액상화된 제3 혼합물을 마련하는 제4 단계; 및 제4 혼합물의 총 중량에 대하여 제2 혼합물 80 내지 95중량%와 제3 혼합물 5 내지 20중량%를 2 내지 3시간 동안 교반하여 제4 혼합물을 마련하는 제5 단계; 제4 혼합물을 2,000 내지 2,300톤 압력의 유압 프레스로 180 내지 230℃에서 5분간 프레싱하여 원하는 형상의 압축체를 마련하는 제6 단계; 상기 압축체를 탈형하여 72시간 이상 자연 냉각하는 제7 단계; 상기 압축체의 표면 이물질을 제거하는 제8 단계; 및 상기 압축체의 표면에 무기 바인더를 코팅하는 제9 단계; 를 포함하는 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법을 제공한다.Another aspect of the present invention is a first step of preparing a first mixture by mixing 50 to 70% by weight of rosin powder pulverized into 300 to 325 mesh and 30 to 50% by weight of alcohol at room temperature; A second step of heating vermiculite at 1,000 to 1,100°C to prepare expanded vermiculite, and pulverizing the expanded vermiculite into 20 to 25 mesh; A third step of mixing 5 to 30 parts by weight of the first mixture with respect to 100 parts by weight of pulverized expanded vermiculite and stirring at 100° C. to prepare a liquefied second mixture; A fourth step of preparing a liquefied third mixture by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh based on 100 parts by weight of the liquid silicate soda and stirring for 2 to 3 hours; And a fifth step of preparing a fourth mixture by stirring 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture for 2 to 3 hours based on the total weight of the fourth mixture. A sixth step of preparing a compressed body having a desired shape by pressing the fourth mixture at 180 to 230°C for 5 minutes with a hydraulic press having a pressure of 2,000 to 2,300 tons; A seventh step of naturally cooling the compressed body by demolding for 72 hours or more; An eighth step of removing foreign substances on the surface of the compressed body; And a ninth step of coating an inorganic binder on the surface of the compressed body. It provides a method of manufacturing an eco-friendly non-combustible furniture material containing expanded vermiculite comprising a.
본 발명의 일 실시 예에서, 제4 단계에서, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 15 내지 25중량부를 혼합하여 마련할 수 있고, 상기 숯은, 참나무를 800℃ 진공에서 연소하여 마련되는 막대 형태의 조직을 갖는 제1 숯 분말 20 내지 50중량%, 및 소나무를 800℃ 진공에서 연소하여 마련되는 구 형태의 조직을 갖는 제2 숯 분말 50 내지 80중량%를 포함할 수 있다.In an embodiment of the present invention, in the fourth step, the third mixture may be prepared by mixing 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is obtained by burning oak wood in a vacuum at 800°C. It may include 20 to 50% by weight of the first charcoal powder having a rod-shaped structure provided, and 50 to 80% by weight of the second charcoal powder having a spherical structure prepared by burning pine trees at 800°C in a vacuum.
본 발명의 일 실시 예에서, 제4 단계에서, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 혼합하여 마련할 수 있고, 상기 숯은, 참나무를 800℃ 진공에서 연소하여 마련되는 막대 형태의 조직을 갖는 제1 숯 분말 10 내지 35중량%, 소나무를 800℃ 진공에서 연소하여 마련되는 구 형태의 조직을 갖는 제2 숯 분말 25 내지 45중량%, 및 왕겨를 1,500℃ 진공에서 연소하여 마련되는 제3 숯 분말 20 내지 45중량%; 을 포함할 수 있다.In an embodiment of the present invention, in the fourth step, the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda, and the charcoal is obtained by burning oak wood in a vacuum at 800°C. 10 to 35% by weight of the first charcoal powder having a rod-shaped structure provided, 25 to 45% by weight of the second charcoal powder having a spherical structure prepared by burning pine trees in a vacuum at 800°C, and a vacuum of rice hull at 1,500°C Third charcoal powder prepared by burning in 20 to 45% by weight; It may include.
본 발명에 따르면, 인체에 무해한 팽창 질석, 숯 및 액상 규산 소다와 같은 친환경적 조성물을 사용하며, 팽창 질석과 숯에 의해 습도 조절 기능과, 항균성 및 탈취성 등의 다양한 기능적 특성을 제공할 수 있으며 인체와 직간접적으로 닿는 가구로부터 발생하는 각종 알레르기성 질환이나 호흡기 질환을 방지할 수 있다.According to the present invention, eco-friendly compositions such as expanded vermiculite, charcoal, and liquid silicate soda are used, and various functional characteristics such as humidity control function, antibacterial and deodorizing properties can be provided by the expanded vermiculite and charcoal. It can prevent various allergic diseases or respiratory diseases arising from furniture that directly or indirectly touches.
또한, 다공질로 된 팽창 질석에 숯이 결합된 상태로 송진 분말이 팽창 질석과 숯의 틈새를 채우면서 가구재가 성형되므로 제조된 가구재가 부피 대비 경량이고 불연성을 가지면서도 기존의 불연성 가구재 대비 우수한 압축 강도를 가지게 되어 가구재의 부가가치를 높일 수 있는 효과가 있다.In addition, since the furniture material is molded while the resin powder fills the gap between the expanded vermiculite and the charcoal in a state where the porous expanded vermiculite is combined with charcoal, the manufactured furniture material is lightweight and non-combustible by volume, but has excellent compressive strength compared to existing non-combustible furniture materials. It has the effect of increasing the added value of furniture materials.
또한, 본 실시 예에 의해 제조된 친환경 불연성 가구재는 폐기시 분쇄하여 액상화시키면 다시 다른 가구재의 재료로 활용할 수 있어 자원의 재활용에도 유리하고 환경 보호에도 유리하다는 이점이 있다.In addition, if the eco-friendly non-combustible furniture material manufactured according to the present embodiment is pulverized and liquefied at the time of disposal, it can be used again as a material for other furniture materials, so it is advantageous in recycling of resources and environmental protection.
도 1은 본 발명의 일 실시 예에 따른 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법을 도시한 흐름도이다.1 is a flowchart illustrating a method of manufacturing an eco-friendly non-combustible furniture material including expanded vermiculite according to an embodiment of the present invention.
도 2는 본 발명의 일 실시 예에 사용되는 팽창 질석을 나타낸 사진이다.Figure 2 is a photograph showing the expanded vermiculite used in an embodiment of the present invention.
도 3은 본 발명의 일 실시 예에 사용되는 송진 분말을 나타낸 사진이다.3 is a photograph showing a rosin powder used in an embodiment of the present invention.
도 4는 본 발명의 일 실시 예에 사용되는 제3 숯 분말이 분쇄되기 전의 상태를 나타낸 사진이다.4 is a photograph showing a state before the third charcoal powder used in an embodiment of the present invention is pulverized.
도 5는 본 발명의 다른 실시 예에 따른 팽창 질석을 포함하는 친환경 가구재의 제조 방법을 도시한 흐름도이다.5 is a flowchart illustrating a method of manufacturing an eco-friendly furniture material including expanded vermiculite according to another embodiment of the present invention.
도 6은 본 발명의 일 실시 예에 의한 가구재를 부분적으로 절개하여 개략적으로 나타낸 사시도이다.6 is a perspective view schematically showing a furniture material according to an embodiment of the present invention by partially cutting it.
이하, 본 발명의 바람직한 실시 예를 설명한다. 그러나, 본 발명의 범위가 이하 설명하는 실시 예로 한정되지 않고 청구 범위에 기재된 바에 의해 정의되며, 본 발명의 분야에서 통상의 지식을 가진 자가 청구 범위에 기재된 권리 범위 내에서 다양한 변형과 개작을 할 수 있다.Hereinafter, a preferred embodiment of the present invention will be described. However, the scope of the present invention is not limited to the embodiments described below and is defined by what is described in the claims, and those of ordinary skill in the field of the present invention can make various modifications and adaptations within the scope of the rights described in the claims. have.
도 6은 본 발명의 일 실시 예에 의한 가구재를 부분적으로 절개하여 개략적으로 나타낸 사시도이다.6 is a perspective view schematically showing a furniture material according to an embodiment of the present invention by partially cutting it.
도 6을 참조하면, 본 발명의 일 실시 예에 의한 팽창 질석을 포함하는 친환경 불연성 가구재(10)는, 내부 몸체(1)와 내부 몸체(1)의 표면을 커버하는 코팅층(2)을 포함할 수 있다. 코팅층(2)은 내부 몸체(1)의 표면에 무기 바인더를 코팅하여 형성될 수 있다.6, the eco-friendly non-combustible furniture material 10 including expanded vermiculite according to an embodiment of the present invention includes an inner body 1 and a coating layer 2 covering the surface of the inner body 1 I can. The coating layer 2 may be formed by coating an inorganic binder on the surface of the inner body 1.
또한, 내부 몸체(1)는, 총 중량에 대하여 제2 혼합물 90중량%와 제3 혼합물 10중량%를 포함하여 형성될 수 있다.In addition, the inner body 1 may be formed including 90% by weight of the second mixture and 10% by weight of the third mixture based on the total weight.
상기 제2 혼합물은, 팽창 질석과, 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하여 형성될 수 있다.The second mixture may be formed by mixing expanded vermiculite and 5 to 30 parts by weight of the first mixture based on 100 parts by weight of expanded vermiculite.
이때, 제1 혼합물의 함량이 5중량부 보다 적으면 송진 분말의 결합력이 충분하지 않아 가구재의 강도가 저하될 수 있다. 또한, 상대적으로 팽창 질석의 함량이 많아져 제2 혼합물 마련시 액상화가 제대로 되지 않거나 팽창 질석 중의 일부가 국부적으로 뭉쳐지게 되는 등 제2 혼합물의 균질성이 저하되는 문제가 발생할 수 있다. 이러한 균질성의 문제는 결과적으로 가구재의 압축 강도를 저하시키는 원인으로 작용할 수 있다.At this time, if the content of the first mixture is less than 5 parts by weight, the bonding strength of the rosin powder may not be sufficient, so that the strength of the furniture material may decrease. In addition, a relatively high content of the expanded vermiculite may cause problems in that the homogeneity of the second mixture is deteriorated, such as not being properly liquefied when the second mixture is prepared, or a part of the expanded vermiculite is locally agglomerated. This homogeneity problem can consequently act as a cause of lowering the compressive strength of furniture materials.
또한, 제1 혼합물의 함량이 30중량부를 초과하면 상대적으로 팽창 질석의 함량이 적어지면서 팽창 질석의 다양한 효과가 제대로 구현되지 못할 수 있다.In addition, when the content of the first mixture exceeds 30 parts by weight, the content of expanded vermiculite is relatively small, and various effects of the expanded vermiculite may not be properly implemented.
이때, 팽창 질석은 20 내지 25 메쉬 크기의 입자로 분쇄될 수 있다. 분쇄한 팽창 질석의 크기가 20메쉬 미만인 경우 질석 입자가 성형된 가구재의 표면에 노출되어 시각적으로 보기에 좋지 않게 되는 문제가 발생할 수 있고, 분쇄한 팽창 질석의 크기가 25메쉬를 초과하면 원료 배합시 혼합이 어려워 제2 혼합물의 액상화가 제대로 이루어지지 않게 되어 제조 상의 문제가 발생할 수 있다.At this time, the expanded vermiculite may be pulverized into particles having a size of 20 to 25 mesh. If the size of the pulverized expanded vermiculite is less than 20 mesh, there may be a problem that the vermiculite particles are exposed to the surface of the molded furniture material, making it difficult to see visually.If the size of the pulverized expanded vermiculite exceeds 25 mesh, when mixing raw materials Since mixing is difficult, the liquefaction of the second mixture is not performed properly, which may cause manufacturing problems.
또한, 상기 팽창 질석은 부피 대비 경량이고, 천연 재료로서 인체에 무해하고 친환경적인 소재이다. 또한, 상기 팽창 질석은 1급의 우수한 불연성을 가지고 있으며, 다공질의 구조로서 흡수 능력이 좋기 때문에 주로 실내에 설치되는 가구재로 활용시 매우 효과적이다.In addition, the expanded vermiculite is a lightweight, natural material that is harmless to the human body and is an eco-friendly material. In addition, the expanded vermiculite has excellent non-combustibility of the first grade, and has good absorption capacity as a porous structure, so it is very effective when used as a furniture material mainly installed indoors.
상기 제1 혼합물은, 총 중량에 대하여 300 내지 325메쉬로 분쇄한 송진 분말 50 내지 70중량%와, 알코올 30 내지 50중량%를 포함할 수 있다.The first mixture may include 50 to 70% by weight of rosin powder pulverized with 300 to 325 mesh and 30 to 50% by weight of alcohol based on the total weight.
종래의 가구재 중 일부는 강도를 보강하기 위해 결합제로 액상 규산 소다를 사용한다. 그러나, 액상 규산 소다는 그 특성 상 흐름성이 좋지 않아 원료 배합시 균일한 배합이 어려워 일정 량 이상을 과다하게 투입하면 한쪽에 뭉쳐지거나 덩어리가 지는 등의 문제가 발생할 수 있다.Some of the conventional furniture materials use liquid sodium silicate as a binder to reinforce strength. However, due to its characteristics, liquid silicate soda has poor flow characteristics, so it is difficult to uniformly mix when mixing raw materials, and if a certain amount or more is excessively added, problems such as agglomeration or lump formation may occur.
이러한 문제를 해소하기 위해, 본 실시 예에서는 액상 규산 소다 중 일부를 송진 분말과 알코올로 이루어진 제1 혼합물로 대체하여 후술하는 팽창 질석 간의 결합제로 사용할 수 있다.In order to solve this problem, in this embodiment, some of the liquid sodium silicate may be replaced with a first mixture consisting of rosin powder and alcohol, and used as a binder between expanded vermiculite, which will be described later.
또한, 분쇄한 송진 분말의 크기가 300메쉬 미만인 경우 송진 분말의 입자 중 일부가 가구재의 표면에 노출되어 시각적으로 좋지 않은 문제가 발생할 수 있고, 분쇄한 송진 분말의 크기가 325메쉬를 초과하면 분산성이 저하되어 제1 혼합물의 균질성이 저하되고 이에 제2 혼합물의 액상화가 제대로 이루어지지 않게 되어 송진 분말의 결합력이 저하될 수 있고 결과적으로 가구재의 압축 강도가 낮아질 수 있다.In addition, if the size of the pulverized rosin powder is less than 300 mesh, some of the particles of the rosin powder may be exposed to the surface of the furniture material, causing visually unfavorable problems.If the size of the pulverized rosin powder exceeds 325 mesh, the dispersibility As this decreases, the homogeneity of the first mixture is lowered, and thus the second mixture is not properly liquefied, so that the bonding strength of the rosin powder may decrease, and as a result, the compressive strength of the furniture material may decrease.
이러한 송진 분말은 액상화되면 접착력 및 결합력이 우수한 천연 소재로서, 인체에 무해하고, 인접한 팽창 질석의 틈새에 위치하여 팽창 질석 간의 결합력을 높임으로써 고열로 압착하여 성형되는 가구재의 압축 강도를 향상시킬 수 있다. 또한, 송진 분말은 방수성이 우수한 물질이므로 완성된 가구재에 우수한 방수성을 부여할 수 있다.When liquefied, such rosin powder is a natural material with excellent adhesion and bonding power, and is harmless to the human body, and is located in the gap between adjacent expanded vermiculite to increase the bonding strength between expanded vermiculite, thereby improving the compressive strength of furniture material that is compressed and molded with high heat. . In addition, since the resin powder is a material having excellent waterproof properties, it can impart excellent waterproof properties to the finished furniture material.
제1 혼합물에서 송진 분말의 함량이 50중량% 보다 적으면 팽창 질석 간의 결합력이 낮아져 가구재의 압축 강도가 저하되는 문제가 발생할 수 있다. 다만, 송진은 기화성 물질이므로, 본 발명의 불연성을 일정 수준으로 유지하기 위해서는 송진 분말의 함량이 70중량%를 초과하지 않도록 하는 것이 바람직하다.If the content of the rosin powder in the first mixture is less than 50% by weight, the bonding force between the expanded vermiculite is lowered, and thus the compressive strength of the furniture material may be lowered. However, since rosin is a vaporizable material, it is preferable that the content of rosin powder does not exceed 70% by weight in order to maintain the incombustibility of the present invention at a certain level.
또한, 제1 혼합물에서 알코올의 함량이 30중량% 보다 적으면 제1 혼합물 배합시 혼합이 제대로 되지 않아 송진 분말 중 일부가 녹지 않은 채로 있을 수 있어 균질성이 저하될 수 있다. 또한, 알코올의 함량이 50중량%를 초과하면 상대적으로 송진 분말의 함량이 적어지므로 앞서 설명한 대로 건축재의 압축 강도가 저하되는 문제가 발생하게 된다.In addition, if the content of alcohol in the first mixture is less than 30% by weight, mixing may not be performed properly when the first mixture is blended, so that some of the rosin powder may remain undissolved, thereby reducing homogeneity. In addition, when the alcohol content exceeds 50% by weight, the content of the rosin powder is relatively small, so as described above, the compressive strength of the building material is deteriorated.
상기 제3 혼합물은, 액상 규산 소다와 200 내지 325메쉬로 분쇄한 숯을 혼합하여 형성될 수 있다.The third mixture may be formed by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh.
이때, 분쇄한 숯의 크기가 200메쉬 미만인 경우 숯 입자가 성형된 가구재의 표면에 노출되어 시각적으로 보기에 좋지 않게 되는 문제가 발생할 수 있고, 분쇄한 숯의 크기가 325메쉬를 초과하면 액상 규산 소다와 제대로 혼합되지 않고 일부가 뭉치거나 덩어리가 지는 문제가 발생할 수 있다. 이에 제3 혼합물이 팽창 질석의 구멍과 팽창 질석 사이사이의 공간을 제대로 채우지 못하여 결과적으로 가구재의 품질 및 강도가 저하되는 문제가 발생할 수 있다.At this time, if the size of the pulverized charcoal is less than 200 mesh, there may be a problem that the charcoal particles are exposed to the surface of the molded furniture material, making it difficult to see visually.If the size of the pulverized charcoal exceeds 325 mesh, liquid sodium silicate It is not mixed properly and some clumps or lumps may occur. Accordingly, the third mixture may not properly fill the space between the hole of the expanded vermiculite and the expanded vermiculite, and as a result, the quality and strength of the furniture material may be deteriorated.
상기 숯은 천연 소재로서 인체에 무해하고 친환경적이며, 습도 조절 기능이 뛰어나고, 우수한 항균성, 살균성 및 탈취성을 가지며, 원적외선을 방사하는 효과 등을 기대할 수 있다.The charcoal is a natural material that is harmless to the human body and is environmentally friendly, has excellent humidity control functions, has excellent antibacterial properties, sterilization properties, and deodorization properties, and can be expected to radiate far-infrared rays.
또한, 이러한 숯은 다양한 나무를 원료로 할 수 있으며, 바람직하게는 참나무와 소나무로 이루어진 원료로부터 마련할 수 있다.In addition, such charcoal may be made of a variety of wood as a raw material, preferably may be prepared from a raw material consisting of oak and pine.
본 실시 예에서, 상기 숯은, 참나무를 원료로 하고 막대 형태의 조직을 갖는 제1 숯 분말 20 내지 50중량%와, 소나무를 원료로 하고 구 형태의 조직을 갖는 제2 숯 분말 50 내지 80중량%를 포함할 수 있다.In this embodiment, the charcoal is 20 to 50% by weight of the first charcoal powder having an oak as a raw material and a bar-shaped structure, and 50 to 80% by weight of the second charcoal powder having a pine tree as a raw material and having a spherical structure May contain %.
이때, 제2 숯 분말은 제2 혼합물의 점도를 걸쭉한 상태로 유지하여 제2 혼합물과의 배합시 균질성을 향상시키는 역할을 할 수 있다. 그리고, 제2 숯 분말은 서로 밀접하여 있는 제1 숯 분말의 사이마다 마련되는 틈새에 채워져 제3 혼합물의 밀도를 높임과 동시에 숯이 액상 규산 소다와 잘 결합되도록 하는 결합제의 역할을 한다. 이에 본 실시 예와 같이 제1 숯 분말과 제2 숯 분말로 숯을 구성하여 제3 혼합물을 마련하면 결과적으로 형태가 상이한 제1 숯 분말과 제2 숯 분말이 서로 얽힌 상태로 결합하여 가구재의 압축 강도 및 가공성을 더욱 향상시킬 수 있다.At this time, the second charcoal powder may serve to improve homogeneity when blended with the second mixture by maintaining the viscosity of the second mixture in a thick state. In addition, the second charcoal powder is filled in the gaps provided between the first charcoal powders that are in close contact with each other to increase the density of the third mixture and at the same time serve as a binder to allow the charcoal to be well combined with the liquid sodium silicate. Accordingly, when a third mixture is prepared by composing charcoal with the first charcoal powder and the second charcoal powder as in the present embodiment, as a result, the first charcoal powder and the second charcoal powder having different shapes are combined in an entangled state to compress furniture materials. Strength and workability can be further improved.
그리고, 본 실시 예에서와 같이, 숯이 제1 숯 분말과 제2 숯 분말로 이루어지는 경우, 제3 혼합물에서 숯의 함량은 액상 규산 소다 100중량부에 대하여 15 내지 25중량부로 한정될 수 있다.And, as in the present embodiment, when the charcoal is composed of the first charcoal powder and the second charcoal powder, the content of charcoal in the third mixture may be limited to 15 to 25 parts by weight based on 100 parts by weight of liquid silicate soda.
이때, 제1 숯 분말의 함량이 20중량% 미만이면 전반적으로 숯이 제공하는 강도가 저하될 수 있고 상대적으로 제2 숯 분말의 함량이 늘어나는데 제2 숯 분말의 재료가 되는 소나무는 불에 상대적으로 약한 물질이므로 본 실시 예의 불연성을 일정 수준으로 유지하기 위해서는 제1 숯 분말의 함량을 20 중량% 이상으로 유지하는 것이 바람직하다.At this time, if the content of the first charcoal powder is less than 20% by weight, the overall strength provided by the charcoal may decrease, and the content of the second charcoal powder is relatively increased. Since it is a weak material, it is preferable to maintain the content of the first charcoal powder at 20% by weight or more in order to maintain the non-flammability of the present embodiment at a certain level.
또한, 제1 숯 분말의 함량이 50중량%를 초과하면 제3 혼합물의 균질성이 저하되며 이에 가구재 성형시 압축이 제대로 되지 않는 문제가 발생할 수 있다.In addition, when the content of the first charcoal powder exceeds 50% by weight, the homogeneity of the third mixture decreases, and there may be a problem in that compression is not properly performed when molding furniture.
한편, 다른 실시 예로서, 상기 제3 혼합물은 필요시 숯이 제1 및 제2 숯 분말 이외에 제3 숯 분말을 더 포함할 수 있다.Meanwhile, as another embodiment, the third mixture may further include a third charcoal powder in addition to the first and second charcoal powders, if necessary.
이때, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 혼합하여 마련할 수 있다. 숯의 함량이 40중량부 보다 적으면 결합력이 약해져 조성물의 강도가 저하되고, 숯의 기능적 특성인 우수한 습도 조절 기능, 항균성, 살균성 및 탈취성이 제대로 구현되지 못할 수 있다.At this time, the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda. If the content of charcoal is less than 40 parts by weight, the bonding strength is weakened and the strength of the composition decreases, and the functional characteristics of charcoal such as excellent humidity control function, antibacterial property, sterilization property and deodorization property may not be properly implemented.
또한, 이러한 제3 혼합물은 액상 규산 소다 100중량부에 대하여 제1 숯 분말 10 내지 35중량, 제2 숯 분말 25 내지 45중량% 및 제3 숯 분말 20 내지 45중량%를 2 내지 3시간 동안 교반하여 마련할 수 있다.In addition, this third mixture is stirred for 2 to 3 hours with 10 to 35% by weight of the first charcoal powder, 25 to 45% by weight of the second charcoal powder, and 20 to 45% by weight of the third charcoal powder based on 100 parts by weight of liquid silicate soda. It can be prepared.
또한, 상기 제3 숯 분말은 왕겨를 고온 진공에서 연소하여 형성할 수 있다. 상기 왕겨는 가격이 저렴하고 원적외선 방출능이 있는 친환경적 재료로서 인체에 무해한 특징을 가진다. 또한, 왕겨로부터 마련된 제3 숯 분말은 무기질 바인더의 역할을 하는 액상 규산 소다와 혼합이 잘 되는 이점이 있다.In addition, the third charcoal powder may be formed by burning rice husk in a high temperature vacuum. The rice husk is an eco-friendly material that is inexpensive and has far-infrared radiation, and is harmless to the human body. In addition, the third charcoal powder prepared from rice husk has the advantage of being well mixed with liquid silicate soda serving as an inorganic binder.
이에 제3 숯 분말은 액상 규산 소다와 반응시 경화제로 작용하게 되므로, 이에 가구의 불연성을 더 향상시키고 강도를 더 높이는 역할을 할 수 있다. 제3 숯 분말의 함량이 20중량% 보다 적으면 이러한 제3 숯 분말의 효과가 제대로 구현되지 않을 수 있고, 제3 숯 분말의 함량이 45중량% 보다 많으면 결합력이 약해질 수 있다.Accordingly, the third charcoal powder acts as a curing agent when reacted with liquid sodium silicate, and thus, it may play a role of further improving the non-combustibility of furniture and increasing the strength. If the content of the third charcoal powder is less than 20% by weight, the effect of the third charcoal powder may not be properly realized, and if the content of the third charcoal powder is more than 45% by weight, the bonding strength may be weakened.
이와 같이, 본 실시 예에 의한 팽창 질석을 포함하는 친환경 불연성 가구재에서 내부 몸체(1)는, 총 중량에 대하여 제2 혼합물 80 내지 95중량%와 제3 혼합물 5 내지 20중량%를 포함할 수 있다.In this way, in the eco-friendly non-combustible furniture material including expanded vermiculite according to the present embodiment, the inner body 1 may include 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture based on the total weight. .
제2 혼합물에 포함된 팽창 질석은 다공질의 구조로서, 제1 혼합물의 송진 분말이 팽창 질석의 구멍과 팽창 질석 사이사이의 공간들 중 일부를 채운 상태인데, 제2 혼합물과 제3 혼합물을 교반하면, 제3 혼합물이 제2 혼합물의 팽창 질석에 있는 나머지 공간들을 채우면서 압축 강도가 크게 향상된 가구재의 내부 몸체(1)를 형성할 수 있다.The expanded vermiculite contained in the second mixture has a porous structure, and the resin powder of the first mixture has filled some of the spaces between the pores of the expanded vermiculite and the expanded vermiculite. When the second mixture and the third mixture are stirred , While the third mixture fills the remaining spaces in the expanded vermiculite of the second mixture, it is possible to form the inner body 1 of the furniture material having significantly improved compressive strength.
이때, 제3 혼합물의 함량이 5중량% 보다 적으면 제2 혼합물의 빈 공간 중 일부가 채워지지 않아 성형되는 가구재의 압축 강도가 저하될 수 있다.In this case, if the content of the third mixture is less than 5% by weight, some of the empty spaces of the second mixture are not filled, so that the compressive strength of the furniture material to be molded may be lowered.
또한, 제3 혼합물의 함량이 20중량% 보다 많으면 제2 혼합물의 빈 공간을 모두 채우고도 제3 혼합물 중 일부가 남게 되어 내부 몸체(1)의 균질성이 저하되는 문제가 발생할 수 있다. 더불어, 이 경우, 액상 규산 소다의 함량이 증가하여 원료 배합시 균일한 배합이 어려워지면서 성형된 내무 몸체(1) 내에서 일부 성분이 한쪽에 뭉쳐지거나 덩어리가 지는 등의 문제가 발생할 수 있어서 내부 몸체(1)의 품질이 저하되는 문제가 발생할 수 있다.In addition, if the content of the third mixture is more than 20% by weight, a part of the third mixture remains even after all the empty spaces of the second mixture are filled, resulting in a problem that the homogeneity of the inner body 1 is lowered. In addition, in this case, the content of the liquid sodium silicate increases, making it difficult to uniformly mix the raw material when mixing the raw material, and a problem such as lumping or lumping of some components in the molded interior body 1 may occur. (1) A problem of deteriorating the quality may occur.
이하, 첨부된 도면을 참조하여 본 발명의 팽창 질석을 포함하는 친환경 불연성 가구재를 제조하는 방법의 바람직한 실시 예를 설명한다. Hereinafter, a preferred embodiment of a method for manufacturing an eco-friendly non-combustible furniture material including expanded vermiculite of the present invention will be described with reference to the accompanying drawings.
도 1은 본 발명의 일 실시 예에 따른 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법을 도시한 흐름도이고, 도 2는 본 발명의 일 실시 예에 사용되는 팽창 질석을 나타낸 사진이고, 도 3은 본 발명의 일 실시 예에 사용되는 송진 분말을 나타낸 사진이고, 도 4는 본 발명의 일 실시 예에 사용되는 제3 숯 분말이 분쇄되기 전의 상태를 나타낸 사진이다.1 is a flow chart illustrating a method of manufacturing an eco-friendly non-combustible furniture material including expanded vermiculite according to an embodiment of the present invention, FIG. 2 is a photograph showing the expanded vermiculite used in an embodiment of the present invention, and FIG. 3 is Fig. 4 is a picture showing a state before the third charcoal powder used in an embodiment of the present invention is pulverized.
도 1 내지 도 4를 참조하면, 먼저 송진 분말을 300 내지 325메쉬로 분쇄하고, 분쇄한 송진 분말 50 내지 70중량%와 알코올 30 내지 50중량%를 혼합하여 마련하는 제1 단계를 진행할 수 있다(S1). 이때, 송진 분말과 알코올의 혼합 온도가 높으면 알코올이 기화될 수 있으므로, 제1 단계는 상온에서 실시하는 것이 바람직하다.Referring to FIGS. 1 to 4, first, a first step of pulverizing the rosin powder into 300 to 325 mesh, and mixing 50 to 70% by weight of the pulverized rosin powder and 30 to 50% by weight of alcohol may be performed ( S1). At this time, since the alcohol may be vaporized when the mixing temperature of the rosin powder and the alcohol is high, the first step is preferably performed at room temperature.
이때, 기존의 액상 규산 소다 중 일부를 송진 분말로 대체하여 사용하면, 액상 규산 소다가 갖는 흐름성 저하의 문제가 최소화되어 원료 배합시 배합이 원활해질 수 있고, 조해성(deliquescence)이 해소되어 백화 현상이 크게 줄어 들게 된다.At this time, if some of the existing liquid sodium silicate is replaced with rosin powder, the problem of lowering the flowability of the liquid sodium silicate is minimized, so that when mixing raw materials, the blending can be smooth, and deliquescence is eliminated and whitening occurs. This will be greatly reduced.
이에 후술하는 제4 혼합물로 성형체를 성형시 정량 투입을 원활하게 할 수 있어서 성형체가 성형되는 시간을 상대적으로 단축시키고 결과적으로 가구재의 제작 비용 및 제작 효율을 향상시킬 수 있는 효과를 기대할 수 있다.Accordingly, it is possible to smoothly quantitatively input the molded body when molding the molded body with the fourth mixture to be described later, so that the time during which the molded body is molded can be relatively shortened, and as a result, an effect of improving the manufacturing cost and manufacturing efficiency of the furniture material can be expected.
다음으로 팽창 질석을 마련하고 분쇄하는 제2 단계(S2)를 진행할 수 있다. 제2 단계를 진행하기 위해서는, 먼저 질석(Vermiculite)을 1,000 내지 1,100℃에서 급격히 가열하여 약 20배까지 팽창되도록 한다. 이에 질석을 수 많은 구멍을 갖는 다공질의 소재로 변형되도록 하여 주성분이 되는 팽창 질석을 마련할 수 있다.Next, a second step (S2) of preparing and crushing expanded vermiculite may be performed. In order to proceed with the second step, first, vermiculite is rapidly heated at 1,000 to 1,100°C so that it expands up to about 20 times. Accordingly, the expanded vermiculite as a main component can be prepared by transforming the vermiculite into a porous material having numerous holes.
이때, 질석을 1,000℃ 보다 더 낮은 온도에서 소성하면 질석 중 일부가 소성이 덜 되어 마련된 팽창 질석의 특성이 저하되는 문제가 발생할 수 있다. 또한, 질석을 1,100℃ 보다 더 높은 온도에서 소성하면 질석 입자가 푸석거리거나 바스러질 수 있으며, 원료 배합시 질석 가루가 날리거나 일부가 덩어리로 뭉쳐지는 문제 등이 발생할 수 있다.In this case, when the vermiculite is calcined at a temperature lower than 1,000°C, some of the vermiculite is calcined less, and thus the properties of the expanded vermiculite prepared may be deteriorated. In addition, when the vermiculite is calcined at a temperature higher than 1,100°C, the vermiculite particles may crumble or crumble, and the vermiculite powder may be blown out or part of the vermiculite may be aggregated into a lump when mixing the raw materials.
그리고, 제2 단계를 마친 팽창 질석을 20 내지 25메쉬 크기의 입자로 분쇄한다. 분쇄한 팽창 질석의 크기가 25메쉬를 초과하면 원료 배합시 혼합이 어려워 이하 제3 단계에서 제2 혼합물의 액상화가 제대로 이루어지지 않게 되는 문제가 발생할 수 있다.Then, the expanded vermiculite after the second step is pulverized into particles having a size of 20 to 25 mesh. If the size of the pulverized expanded vermiculite exceeds 25 mesh, mixing may be difficult when mixing the raw materials, which may cause a problem in that the liquefaction of the second mixture is not properly performed in the third step below.
만약 제2 혼합물 마련시 액상화가 제대로 되지 않으면 가구재를 제조하기 위한 압축체 마련시 가공성이 현저히 낮아지기 때문에, 본 실시 예의 제4 혼합물을 고온 고압으로 프레싱하여 압축체를 가공하더라도 그 형상이 제작자가 원하는 대로 제대로 형성되지 못하거나 그 품질이 현저히 저하되는 문제가 발생할 수 있다.If the second mixture is not properly liquefied, the workability is significantly lowered when preparing the compressed body for manufacturing furniture, so even if the compressed body is processed by pressing the fourth mixture of the present embodiment at high temperature and high pressure, the shape will be as desired by the manufacturer. There may be a problem that it is not formed properly or its quality is significantly deteriorated.
한편, 이렇게 질석을 팽창시키는 제2 단계는 질석을 매우 높은 온도에서 일정 시간 동안 가열하는 공정이기 때문에, 이 과정에서 질석 내에 있던 라돈 등의 이물질 및 각종 세균 등이 모두 제거되는 정제 작용이 함께 이루어질 수 있어서 가구재의 안정성을 더 높일 수 있다.On the other hand, since the second step of expanding vermiculite is a process of heating the vermiculite at a very high temperature for a certain period of time, a purification action in which all foreign substances such as radon and various bacteria in the vermiculite are removed can be performed together. Therefore, the stability of furniture materials can be further increased.
다음으로, 제2 단계에서 분쇄한 팽창 질석을 주성분으로 하여 액상화된 제2 혼합물을 마련하는 제3 단계를 진행한다(S2). 이러한 제3 단계는 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하고 100℃에서 1 내지 2 시간 동안 교반하여 제2 혼합물을 마련하게 된다.Next, a third step of preparing a liquefied second mixture using the expanded vermiculite pulverized in the second step as a main component proceeds (S2). In this third step, 5 to 30 parts by weight of the first mixture is mixed with respect to 100 parts by weight of expanded vermiculite and stirred at 100° C. for 1 to 2 hours to prepare a second mixture.
이때, 상기 제2 혼합물은, 제1 혼합물과 팽창 질석을 혼합기에 동시에 투입하여 혼합한 후, 이 혼합물을 100℃에서 1 내지 2시간 동안 교반하고 자연 냉각하는 과정을 거쳐 형성할 수 있다.At this time, the second mixture may be formed by simultaneously adding the first mixture and expanded vermiculite to a mixer to mix, and then stirring the mixture at 100° C. for 1 to 2 hours and cooling naturally.
이때 팽창 질석과 제1 혼합물의 교반 및 자연 냉각 과정은 바람직하게 5회를 반복할 수 있는데, 이는 후술하는 제4 혼합물로 가구재를 제작할 때의 작업성을 향상시키기 위해 제2 혼합물의 점도를 유동성이 적절히 유지되는 수준까지 높이고 후술하는 제3 혼합물과의 반응성 또한 향상시키기 위해서이다.At this time, the stirring and natural cooling process of the expanded vermiculite and the first mixture may preferably be repeated five times, which is to increase the viscosity of the second mixture in order to improve workability when manufacturing furniture with a fourth mixture to be described later. This is in order to increase the level to an appropriate maintenance level and also to improve the reactivity with the third mixture described later.
만약 팽창 질석과 제1 혼합물의 교반 및 자연 냉각 과정을 4회 이하로 반복하면 제2 혼합물의 점도가 유동성이 충분한 수준까지 상승하지 못하여 결과적으로 제3 혼합물과의 반응성이 저하되고 가구재의 강도가 저하되는 문제가 발생할 수 있다.If the process of stirring and natural cooling of the expanded vermiculite and the first mixture is repeated 4 or less times, the viscosity of the second mixture does not rise to a sufficient level of fluidity, and as a result, the reactivity with the third mixture decreases and the strength of the furniture material decreases. Problems may occur.
또한, 이러한 팽창 질석과 제1 혼합물의 교반 및 자연 냉각 과정은 6회 이상 반복하더라도 효과 상의 차이가 크지 없기 때문에 바람직하게는 5회만 반복하게 된다.In addition, the stirring and natural cooling process of the expanded vermiculite and the first mixture is preferably repeated only five times, since there is no significant difference in effect even if repeated six or more times.
다음으로, 숯을 200 내지 325메쉬로 분쇄하고, 무기질 바인더의 역할을 하는 액상 규산 소다(규산 나트륨, Sodium Silicate)와 분쇄한 숯을 교반하여 액상화된 제3 혼합물을 마련하는 제4 단계를 진행한다(S4). 제3 혼합물은 제2 혼합물에서 팽창 질석의 구멍과 팽창 질석 사이사이의 공간을 채우는 작용을 하게 되므로 성형된 가구재의 강도를 높이는 작용을 할 수 있다.Next, the charcoal is pulverized into 200 to 325 mesh, and liquid sodium silicate (sodium silicate) serving as an inorganic binder and the pulverized charcoal are stirred to prepare a third liquefied mixture. (S4). Since the third mixture fills the space between the expanded vermiculite and the expanded vermiculite in the second mixture, it can increase the strength of the molded furniture material.
또한, 본 실시 예에서, 이러한 숯은 다양한 나무를 원료로 할 수 있으며, 바람직하게는 참나무와 소나무로 이루어진 원료로부터 마련할 수 있다.In addition, in the present embodiment, such charcoal may be made of a variety of wood as a raw material, preferably may be prepared from a raw material consisting of oak and pine.
본 실시 예에서, 이러한 숯은 서로 다른 조직을 갖는 2가지 종류의 숯 분말을 포함할 수 있으며 더 구체적으로는 크고 길쭉한 막대 형태의 조직을 갖는 제1 숯 분말과 상대적으로 작고 둥글둥글한 구 형태의 조직을 갖는 제2 숯 분말을 포함할 수 있다.In this embodiment, the charcoal may include two types of charcoal powder having different textures, and more specifically, the first charcoal powder having a large and elongated bar-shaped structure and a relatively small and rounded sphere-shaped It may include a second charcoal powder having a texture.
제1 숯 분말은 참나무를 800℃ 진공에서 연소하여 마련할 수 있고 상대적으로 더 단단하 강도를 가지며, 제2 숯 분말은 소나무를 800℃ 진공에서 연소하여 마련할 수 있다.The first charcoal powder may be prepared by burning oak wood at 800°C in a vacuum and has a relatively harder strength, and the second charcoal powder may be prepared by burning pine wood at 800°C in a vacuum.
본 실시 예에서, 숯은 바람직하게 제1 숯 분말 20 내지 50중량%와 제2 숯 분말 50 내지 80중량%를 포함할 수 있다.In this embodiment, the charcoal may preferably include 20 to 50% by weight of the first charcoal powder and 50 to 80% by weight of the second charcoal powder.
한편, 다른 예로서, 제3 혼합물은 제3 숯 분말을 더 혼합하고 교반하여 마련할 수 있다. 이때, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 혼합하여 마련할 수 있다. 숯의 함량이 40중량부 보다 적으면 결합력이 약해져 조성물의 강도가 저하되고, 숯의 기능적 특성인 우수한 습도 조절 기능, 항균성, 살균성 및 탈취성이 제대로 구현되지 못할 수 있다.On the other hand, as another example, the third mixture may be prepared by further mixing and stirring the third charcoal powder. At this time, the third mixture may be prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda. If the content of charcoal is less than 40 parts by weight, the bonding strength is weakened and the strength of the composition decreases, and the functional characteristics of charcoal such as excellent humidity control function, antibacterial property, sterilization property and deodorization property may not be properly implemented.
상기 제3 숯 분말은 왕겨를 1,500℃ 진공에서 연소하여 마련할 수 있다. 본 실시 예에서 바람직하게 제3 숯 분말 마련시 왕겨를 사용하는 이유는 왕겨의 탄소 함유량이 매우 높기 때문이다.The third charcoal powder may be prepared by burning rice husk at 1,500° C. vacuum. The reason why rice husk is preferably used in preparing the third charcoal powder in this embodiment is because the carbon content of rice husk is very high.
또한, 위의 과정을 거쳐 얻어진 제1 내지 제3 숯 분말은 5차례의 파쇄 작업을 거친 후 액상 규산 소다와 혼합하는 것이 바람직하다. 이때, 파쇄 작업을 5차례 보다 적게 반복하면 제3 혼합물의 균질성이 저하되고 액상 규산 소다의 접착력도 저하되는 문제가 발생할 수 있다.In addition, the first to third charcoal powder obtained through the above process is preferably mixed with liquid sodium silicate after passing through five crushing operations. At this time, if the crushing operation is repeated less than five times, the homogeneity of the third mixture may be reduced, and the adhesive strength of the liquid sodium silicate may be decreased.
또한, 도 5에서와 같이, 필요시 이와 같이 마련된 제3 혼합물은 후 공정으로 압연기에서 롤러를 이용하여 2 내지 3mm 두께로 로울링하며 가압하는 작업(S10)을 추가적으로 3회 정도 반복할 수 있다.In addition, as shown in FIG. 5, if necessary, the third mixture prepared as described above may be rolled to a thickness of 2 to 3 mm using a roller in a rolling mill and pressurized in a subsequent process (S10) may be additionally repeated three times.
이러한 작업을 통해, 제3 혼합물에 포함된 제1 내지 제3 숯 분말이 제3 혼합물 전체에 골고루 퍼지게 되면서 접착력이 좋아지게 되고, 결과적으로 조성물의 강도가 향상될 수 있다.Through this operation, the first to third charcoal powders included in the third mixture are spread evenly throughout the third mixture, thereby improving adhesion, and as a result, the strength of the composition may be improved.
다음으로, 제2 혼합물과 제3 혼합물을 혼합하여 제4 혼합물을 마련하는 제5 단계를 진행한다(S5). 이때, 제4 혼합물은 제4 혼합물의 총 중량에 대하여 제2 혼합물 80 내지 95중량%와 제3 혼합물 5 내지 20중량%를 2 내지 3시간 교반하여 마련할 수 있다.Next, a fifth step of preparing a fourth mixture by mixing the second mixture and the third mixture is performed (S5). At this time, the fourth mixture may be prepared by stirring 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture for 2 to 3 hours based on the total weight of the fourth mixture.
제2 혼합물에 포함된 팽창 질석은 다공질의 구조로서, 제1 혼합물의 송진 분말이 팽창 질석의 구멍과 팽창 질석 사이사이의 공간들 중 일부를 채운 상태인데, 제2 혼합물과 제3 혼합물을 교반하면, 제3 혼합물이 제2 혼합물의 팽창 질석 사이사이의 빈 공간들을 채우면서 압축 강도가 크게 향상된 제4 혼합물을 형성하게 된다.The expanded vermiculite contained in the second mixture has a porous structure, and the resin powder of the first mixture has filled some of the spaces between the pores of the expanded vermiculite and the expanded vermiculite. When the second mixture and the third mixture are stirred , As the third mixture fills the voids between the expanded vermiculite of the second mixture, a fourth mixture having significantly improved compressive strength is formed.
이때, 제3 혼합물의 함량이 5중량% 보다 적으면 제2 혼합물의 공간 중 일부가 채워지지 않아 압축체 및 완성된 가구재의 압축 강도가 저하될 수 있다.At this time, if the content of the third mixture is less than 5% by weight, a part of the space of the second mixture is not filled, so that the compressive strength of the compressed body and the finished furniture material may decrease.
또한, 제3 혼합물의 함량이 20중량% 보다 많으면 제2 혼합물의 빈 공간을 모두 채우고도 제3 혼합물 중 일부가 남게 되어 제4 혼합물의 균질성이 저하되는 문제가 발생할 수 있다. 더불어, 이 경우, 액상 규산 소다의 함량이 증가하여 원료 배합시 균일한 배합이 어려워지면서 제4 혼합물에서 일부 성분이 한쪽에 뭉쳐지거나 덩어리가 지는 등의 문제가 발생할 수 있어서 압축체의 품질이 저하되는 문제가 발생할 수 있다.In addition, if the content of the third mixture is more than 20% by weight, a portion of the third mixture remains even after all the empty spaces of the second mixture are filled, resulting in a problem that the homogeneity of the fourth mixture decreases. In addition, in this case, the content of the liquid soda silicate increases, making it difficult to uniformly mix the raw materials, and problems such as lumping or lumping of some components in the fourth mixture may occur. Problems can arise.
다음으로, 제작하고자 하는 가구재의 형상과 대응하는 형상을 갖는 금형을 마련하고, 제4 혼합물을 180 내지 230℃로 가열된 금형에 투입하고 2,000 내지 2,300톤의 고압압 프레스로 5분간 프레싱하여 원하는 형상의 압축체를 마련하는 제6 단계를 진행한다(S6). 이때, 상기 금형은 가구재에 따라 다양한 형상과 두께로 이루어질 수 있다.Next, a mold having a shape corresponding to the shape of the furniture material to be produced is prepared, and the fourth mixture is put into a mold heated at 180 to 230°C, and pressed for 5 minutes with a high pressure press of 2,000 to 2,300 tons to obtain a desired shape. Proceeds to the sixth step of providing the compressed body (S6). In this case, the mold may have various shapes and thicknesses according to the furniture material.
또한, 본 실시 예에서는 모든 성분을 동시에 혼합하여 최종 제품인 제4 혼합물을 한 번에 마련하는 것이 아니라, 송진 분말과 알코올을 혼합하여 송진 분말이 균질하게 제1 혼합물을 마련하고, 이 제1 혼합물에 팽창 질석을 혼합하여 팽창 질석이 균질화게 액상화된 제2 혼합물을 마련하고, 액상 규산 소다와 잘게 분쇄한 숯을 혼합하여 숯이 균질하게 된 액상화된 제3 혼합물을 마련하여, 이 제3 혼합물에 제2 혼합물을 혼합하여 팽창 질석의 사이사이마다 숯이 채워지면서 균질하고 각 성분 간의 결합력이 우수하여 높은 강도를 제공할 수 있는 제4 혼합물을 마련할 수 있게 된다. 따라서, 각 성분이 갖는 유익한 효과들은 모두 취하면서 각 성분이 혼합하면서 발생 가능한 문제점은 최소화할 수 있는 것이다.In addition, in this embodiment, instead of preparing the fourth mixture, which is the final product, by mixing all the components at the same time, the first mixture is prepared by mixing the rosin powder and alcohol to make the rosin powder homogeneous. The expanded vermiculite is mixed to prepare a liquefied second mixture to homogenize the expanded vermiculite, and a third liquefied mixture in which the charcoal becomes homogeneous is prepared by mixing liquid sodium silicate and finely ground charcoal. 2 By mixing the mixture, charcoal is filled between the expanded vermiculite, and the fourth mixture is homogeneous and has excellent bonding strength between the components, so that a fourth mixture capable of providing high strength can be prepared. Therefore, while taking all the beneficial effects of each component, it is possible to minimize problems that may occur while each component is mixed.
이와 같이 압축체를 고열 및 고압으로 5분간 프레싱하면 금형 내부에서 제4 혼합물 전체에 골고루 열이 전달되면서 제4 혼합물에 포함된 여러 성분들의 입자가 강한 압력과 고열에 의해 전체적으로 고르게 결합되면서 강도가 우수하고 불연성 등 여러 기능적 특성이 전체적으로 고르게 구현되는 가구재를 제조할 수 있게 된다.In this way, when the compressed body is pressed at high heat and high pressure for 5 minutes, heat is evenly transferred to the entire fourth mixture inside the mold, and the particles of various components contained in the fourth mixture are evenly bonded together by strong pressure and high heat, resulting in excellent strength. And, it is possible to manufacture furniture materials that have various functional characteristics such as non-combustibility and are evenly realized as a whole.
특히, 팽창 질석에 형성되어 있는 공간을 숯이 채우고 규산 소다와 송진 분말이 그 틈새를 메꾸며 결합되어, 경량이면서 기존의 가구재 보다 우수한 강도와 불연성을 가지는 친환경 불연성 가구재를 제조할 수 있다.In particular, charcoal fills the space formed in the expanded vermiculite, and soda silicate and rosin powder are combined to fill the gap, so that it is possible to manufacture eco-friendly non-combustible furniture material that is lightweight and has superior strength and non-flammability than existing furniture materials.
이때, 고열로 프레싱하는 시간이 5분 미만이면 금형 내부에서 골고루 열이 전달되지 못하여 제4 혼합물에 포함된 여러 성분들의 입자가 제대로 반응하지 못하여 가구재의 형상이 제대로 나타나지 않거나 가구재의 특성이 부분적으로 저하되는 불량 제품이 발생할 수 있다.At this time, if the pressing time with high heat is less than 5 minutes, heat cannot be transferred evenly inside the mold, and the particles of various components included in the fourth mixture do not react properly, so that the shape of the furniture material does not appear properly or the characteristics of the furniture material partially deteriorate. A defective product may occur.
다음으로, 상기 압축체를 금형으로부터 탈형하여 72시간 이상 자연 냉각하는 제7 단계를 진행한다(S7). 만약 제7 단계의 자연 냉각 시간이 72시간 미만이면 압축체의 강도가 저하될 수 있다. 또한, 압축체를 냉각하는 온도가 실온과 크게 차이가 나는 경우 압축체가 건조되는 과정에서 크랙 등의 불량이 발생할 수 있다.Next, a seventh step of natural cooling for 72 hours or more by demolding the compressed body from the mold is performed (S7). If the natural cooling time of the seventh step is less than 72 hours, the strength of the compressed body may decrease. In addition, when the temperature for cooling the compressed body is significantly different from room temperature, defects such as cracks may occur during the drying process of the compressed body.
다음으로, 상기 압축체의 표면 이물질을 사포나 면치기 등을 이용하여 제거하는 제8 단계를 진행한다(S80). 본 발명에서 이러한 이물질 제거 과정은 사포나 면치기에 한정되는 것이 아니며 그 외에 다른 다양한 방법을 통해서도 이루어질 수 있다.Next, the eighth step of removing the surface foreign matter of the compressed body using sandpaper or chamfering is performed (S80). In the present invention, such a foreign material removal process is not limited to sandpaper or chamfering, and may be performed through various other methods.
다음으로, 상기 압축체의 표면을 무기 바인더로 코팅하는 제9 단계를 진행한다(S9). 이를 위해 압축체의 상면과 측면에 1차적으로 무기 바인더를 코팅하고 건조한 다음, 뒤집어서 압축체의 저면과 측면에 2차적으로 무기 바인더를 코팅하고 건조하여 최종적으로 경량이면서 우수한 불연성과 강도를 가지는 친환경 불연성 가구재를 완성할 수 있다.Next, a ninth step of coating the surface of the compressed body with an inorganic binder is performed (S9). To this end, an inorganic binder is first coated on the upper and side surfaces of the compact, dried, and then turned over and secondarily coated with an inorganic binder on the lower and side surfaces of the compact and dried. Furniture materials can be completed.
이와 같이 구성된 친환경 불연성 가구재는 15, 18, 23, 28mm 두께의 책상 상판, 옷장 등 다양한 용도의 가구에 적용될 수 있다.The eco-friendly non-combustible furniture material configured as described above can be applied to furniture for various purposes, such as desk tops and wardrobes having a thickness of 15, 18, 23 and 28 mm.
한편, 본 발명의 가구재는 위에서 설명한 것 이외에 다양한 형태로 변형 실시가 가능한 것으로 본 발명의 기술적 사상을 벗어나지 않는 한, 변형되는 실시 예들 또한 모두 본 발명의 권리 범위에 속하는 것으로 해석되어야 한다.On the other hand, the furniture material of the present invention can be modified in various forms other than those described above, and all modified embodiments should also be construed as belonging to the scope of the present invention, unless departing from the technical spirit of the present invention.
부호의 설명Explanation of sign
S1: 제1 혼합물 마련S1: Prepare the first mixture
S2: 팽창 질석 마련 및 분쇄S2: Prepare and crush expanded vermiculite
S3: 제2 혼합물 마련S3: second mixture preparation
S4: 제3 혼합물 마련S4: prepare third mixture
S5: 제4 혼합물 마련S5: Prepare the fourth mixture
S6: 압축제를 마련하는 단계S6: Step of preparing a compressing agent
S7: 압축체를 냉각하는 단계S7: cooling the compressed body
S8: 압축체의 이물질을 제거하는 단계S8: Step of removing foreign substances from the compressed body
S9: 압축체의 표면을 코팅하는 단계S9: coating the surface of the compressed body
S10: 제3 혼합물을 로울링하며 가압하는 단계S10: Rolling and pressurizing the third mixture
1: 내부 몸체1: inner body
2: 코팅층2: coating layer
10: 가구재10: Furniture materials

Claims (6)

  1. 20 내지 25메쉬로 분쇄한 팽창 질석과, 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하여 형성되는 제2 혼합물; 및 액상 규산 소다와 200 내지 325메쉬로 분쇄한 숯을 혼합하여 형성되는 제3 혼합물; 로 이루어지되,A second mixture formed by mixing the expanded vermiculite pulverized into 20 to 25 mesh and 5 to 30 parts by weight of the first mixture based on 100 parts by weight of the expanded vermiculite; And a third mixture formed by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh. Is made of,
    상기 제1 혼합물은, 총 중량에 대하여 300 내지 325메쉬로 분쇄한 송진 분말 50 내지 70중량%와, 알코올 30 내지 50중량%를 포함하고,The first mixture includes 50 to 70% by weight of rosin powder pulverized with 300 to 325 mesh based on the total weight, and 30 to 50% by weight of alcohol,
    총 중량에 대하여 상기 제2 혼합물 80 내지 95중량%와 상기 제3 혼합물 5 내지 20중량%를 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재.Eco-friendly non-combustible furniture material comprising expanded vermiculite, comprising 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture based on the total weight.
  2. 제1항에 있어서, 상기 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 15 내지 25중량부를 포함하고,The method of claim 1, wherein the third mixture comprises 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda,
    상기 숯은, 참나무를 원료로 하고 막대 형태의 조직을 갖는 제1 숯 분말 20 내지 50중량%, 및 소나무를 원료로 하고 구 형태의 조직을 갖는 제2 숯 분말 50 내지 80중량%를 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재.The charcoal contains 20 to 50% by weight of the first charcoal powder having an oak as a raw material and a bar-shaped structure, and 50 to 80% by weight of the second charcoal powder having a pine tree as a raw material and a spherical structure Eco-friendly non-combustible furniture material containing expanded vermiculite characterized by.
  3. 제1항에 있어서, 상기 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 포함하고,The method of claim 1, wherein the third mixture comprises 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda,
    상기 숯은, 참나무를 원료로 하고 막대 형태의 조직을 갖는 제1 숯 분말 10 내지 35중량%와, 소나무를 원료로 하고 구 형태의 조직을 갖는 제2 숯 분말 25 내지 45중량%와, 왕겨를 고온 진공 상태에서 연소하여 형성되는 제3 숯 분말 20 내지 45중량%를 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재.The charcoal includes 10 to 35% by weight of the first charcoal powder having a structure in the form of a rod and using oak as a raw material, 25 to 45% by weight of the second charcoal powder having a structure in the form of a sphere and using pine Eco-friendly non-combustible furniture material comprising expanded vermiculite, characterized in that it contains 20 to 45% by weight of the third charcoal powder formed by burning in a high temperature vacuum state.
  4. 300 내지 325메쉬로 분쇄한 송진 분말 50 내지 70중량%와 알코올 30 내지 50중량%를 상온에서 혼합하여 제1 혼합물을 마련하는 제1 단계;A first step of preparing a first mixture by mixing 50 to 70% by weight of rosin powder pulverized into 300 to 325 mesh and 30 to 50% by weight of alcohol at room temperature;
    질석을 1,000 내지 1,100℃에서 가열하여 팽창 질석을 마련하고, 이 팽창 질석을 20 내지 25메쉬로 분쇄하는 제2 단계;A second step of heating vermiculite at 1,000 to 1,100°C to prepare expanded vermiculite, and pulverizing the expanded vermiculite into 20 to 25 mesh;
    분쇄한 팽창 질석 100중량부에 대하여 제1 혼합물 5 내지 30중량부를 혼합하고 100℃에서 교반하여 액상화된 제2 혼합물을 마련하는 제3 단계;A third step of mixing 5 to 30 parts by weight of the first mixture with respect to 100 parts by weight of pulverized expanded vermiculite and stirring at 100° C. to prepare a liquefied second mixture;
    액상 규산 소다와, 상기 액상 규산 소다 100중량부에 대하여 200 내지 325메쉬로 분쇄한 숯을 혼합하고 2 내지 3시간 동안 교반하여 액상화된 제3 혼합물을 마련하는 제4 단계;A fourth step of preparing a liquefied third mixture by mixing liquid silicate soda and charcoal pulverized with 200 to 325 mesh based on 100 parts by weight of the liquid silicate soda and stirring for 2 to 3 hours;
    제4 혼합물의 총 중량에 대하여 제2 혼합물 80 내지 95중량%와 제3 혼합물 5 내지 20중량%를 2 내지 3시간 동안 교반하여 제4 혼합물을 마련하는 제5 단계; A fifth step of preparing a fourth mixture by stirring 80 to 95% by weight of the second mixture and 5 to 20% by weight of the third mixture for 2 to 3 hours based on the total weight of the fourth mixture;
    제4 혼합물을 2,000 내지 2,300톤 압력의 유압 프레스로 180 내지 230℃에서 5분간 프레싱하여 원하는 형상의 압축체를 마련하는 제6 단계;A sixth step of preparing a compressed body having a desired shape by pressing the fourth mixture at 180 to 230°C for 5 minutes with a hydraulic press having a pressure of 2,000 to 2,300 tons;
    상기 압축체를 탈형하여 72시간 이상 자연 냉각하는 제7 단계;A seventh step of naturally cooling the compressed body by demolding for 72 hours or more;
    상기 압축체의 표면 이물질을 제거하는 제8 단계; 및An eighth step of removing foreign substances on the surface of the compressed body; And
    상기 압축체의 표면에 무기 바인더를 코팅하는 제9 단계; 를 포함하는 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법.A ninth step of coating an inorganic binder on the surface of the compressed body; A method of manufacturing an eco-friendly non-combustible furniture material comprising expanded vermiculite comprising a.
  5. 제4항에 있어서,The method of claim 4,
    제4 단계에서, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 15 내지 25중량부를 혼합하여 마련하고,In the fourth step, the third mixture is prepared by mixing 15 to 25 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda,
    상기 숯은, 참나무를 800℃ 진공에서 연소하여 마련되는 막대 형태의 조직을 갖는 제1 숯 분말 20 내지 50중량%, 및 소나무를 800℃ 진공에서 연소하여 마련되는 구 형태의 조직을 갖는 제2 숯 분말 50 내지 80중량%를 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법.The charcoal is 20 to 50% by weight of the first charcoal powder having a bar-shaped structure prepared by burning oak at 800°C in a vacuum, and a second charcoal having a spherical structure prepared by burning pine trees at 800°C in a vacuum. A method for producing an eco-friendly non-combustible furniture material comprising expanded vermiculite, characterized in that it contains 50 to 80% by weight of powder.
  6. 제4항에 있어서,The method of claim 4,
    제4 단계에서, 제3 혼합물은 액상 규산 소다 100중량부에 대하여 숯 40 내지 80중량부를 혼합하여 마련하고,In the fourth step, the third mixture is prepared by mixing 40 to 80 parts by weight of charcoal based on 100 parts by weight of liquid silicate soda,
    상기 숯은, 참나무를 800℃ 진공에서 연소하여 마련되는 막대 형태의 조직을 갖는 제1 숯 분말 10 내지 35중량%, 소나무를 800℃ 진공에서 연소하여 마련되는 구 형태의 조직을 갖는 제2 숯 분말 25 내지 45중량%, 및 왕겨를 1,500℃ 진공에서 연소하여 마련되는 제3 숯 분말 20 내지 45중량%; 을 포함하는 것을 특징으로 하는 팽창 질석을 포함하는 친환경 불연성 가구재의 제조 방법.The charcoal is 10 to 35% by weight of a first charcoal powder having a rod-shaped structure prepared by burning oak at 800°C in a vacuum, and a second charcoal powder having a sphere-shaped structure prepared by burning pine trees at 800°C in a vacuum 25 to 45% by weight, and 20 to 45% by weight of third charcoal powder prepared by burning rice husks at 1,500°C in vacuum; A method of manufacturing an eco-friendly non-combustible furniture material comprising expanded vermiculite, comprising: a.
PCT/KR2020/005384 2019-04-25 2020-04-23 Environment-friendly nonflammable furniture material including expanded vermiculite and method for manufacturing same WO2020218851A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2019-0048364 2019-04-25
KR1020190048364A KR102044658B1 (en) 2019-04-25 2019-04-25 Manufacturing method for environment-friendly nonflammable furniture material including expanded vermiculite

Publications (1)

Publication Number Publication Date
WO2020218851A1 true WO2020218851A1 (en) 2020-10-29

Family

ID=68535081

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2020/005384 WO2020218851A1 (en) 2019-04-25 2020-04-23 Environment-friendly nonflammable furniture material including expanded vermiculite and method for manufacturing same

Country Status (2)

Country Link
KR (1) KR102044658B1 (en)
WO (1) WO2020218851A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102044658B1 (en) * 2019-04-25 2019-11-13 임흥묵 Manufacturing method for environment-friendly nonflammable furniture material including expanded vermiculite
KR102223950B1 (en) 2020-05-12 2021-03-04 심재우 Eco-friendly flame-retardant furniture and manufacturing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100659537B1 (en) * 2006-04-05 2006-12-19 김성구 An incombustible panel for construction and method of manufacturing thereof
KR100822073B1 (en) * 2005-07-12 2008-04-15 대한민국(관리부서 : 산림청 국립산림과학원장) Forming material including charcoal and manufacturing method thereof
KR20100124396A (en) * 2009-05-19 2010-11-29 주식회사 코켐스 Functional charcoal coatings composition
KR20150030401A (en) * 2013-09-12 2015-03-20 임기태 Multi-functional artificial marble composition, its production method and multi-functional artificial marble using it
KR20190035979A (en) * 2017-09-25 2019-04-04 재단법인 한국탄소융합기술원 Manufacturing method of inorganic heat insulating board using magnesium sulfate inorganic binder and Inorganic heat insulating board manufactured by this
KR102044658B1 (en) * 2019-04-25 2019-11-13 임흥묵 Manufacturing method for environment-friendly nonflammable furniture material including expanded vermiculite

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100695910B1 (en) 2006-12-11 2007-03-20 (주)정진브이앤피 High Strong Vermiculite Board Fabricated Using Expanded Vermiculite
KR101213988B1 (en) 2012-04-13 2012-12-20 주식회사 우드메탈 Functional panel and its manufacturing method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100822073B1 (en) * 2005-07-12 2008-04-15 대한민국(관리부서 : 산림청 국립산림과학원장) Forming material including charcoal and manufacturing method thereof
KR100659537B1 (en) * 2006-04-05 2006-12-19 김성구 An incombustible panel for construction and method of manufacturing thereof
KR20100124396A (en) * 2009-05-19 2010-11-29 주식회사 코켐스 Functional charcoal coatings composition
KR20150030401A (en) * 2013-09-12 2015-03-20 임기태 Multi-functional artificial marble composition, its production method and multi-functional artificial marble using it
KR20190035979A (en) * 2017-09-25 2019-04-04 재단법인 한국탄소융합기술원 Manufacturing method of inorganic heat insulating board using magnesium sulfate inorganic binder and Inorganic heat insulating board manufactured by this
KR102044658B1 (en) * 2019-04-25 2019-11-13 임흥묵 Manufacturing method for environment-friendly nonflammable furniture material including expanded vermiculite

Also Published As

Publication number Publication date
KR102044658B1 (en) 2019-11-13

Similar Documents

Publication Publication Date Title
WO2020218851A1 (en) Environment-friendly nonflammable furniture material including expanded vermiculite and method for manufacturing same
US5611882A (en) Board stock and method of manufacture from recycled paper
WO2020218853A1 (en) Eco-friendly incombustible construction material having improved humidity regulation function, and manufacturing method therefor
EP0613420B1 (en) Board stock and method of manufacture from recycled paper
KR100816979B1 (en) Construction close uses the clam shell and the charcoal re-and the manufacturing method
CN1218818C (en) Multi-kinds of boards and board compositions using broken grass and wood and clay and its manufacturing method
WO2021020894A1 (en) Well-being heating chair and method for manufacturing same
KR102103120B1 (en) Environment-friendly nonflammable chair including expanded vermiculite and method of manufacturing the same
CN108484214A (en) A kind of preparation method of energy-saving wall material
KR102103121B1 (en) well-being heat chair and method of manufacturing the same
KR102122155B1 (en) Environment-friendly nonflammable furniture material including expanded vermiculite
KR100219442B1 (en) Material for interior finishof building and method for fabricating the same
KR102416255B1 (en) Method for manufacturing pulp molded products with high cohesive strength and pulp molded products manufactured thereby
DE3105534A1 (en) "MOLDED PARTS WITH HIGH MECHANICAL STABILITY AT HIGH TEMPERATURES, METHOD FOR THEIR PRODUCTION AND THEIR USE"
KR20150063653A (en) Method of Light Charcoal-embedded Loess Board Production
KR102103099B1 (en) Environment-friendly nonflammable composition with easy humidity control and method of manufacturing the same
KR100344930B1 (en) Method for manufacturing ochreous panel for construction interior
KR102484574B1 (en) Incombustible board using styrofoam and manufacturing mehtod thereof
KR102203946B1 (en) Heat insulation material composition, Heat insulation panel prepared using this
JP2003080509A (en) Wood fiber board
KR101447989B1 (en) Loess composition, method for manufacturing loess construction materials and loess construction materials manufactured by thereof
KR20200001276A (en) Exterior block for construction with functional and environmental property, and method for manufacturing the same
KR101964956B1 (en) Forming material including charcoal with thermal conductors and manufacturing method thereof
KR200338628Y1 (en) For building panel of yellow soil main material
KR100650229B1 (en) Styropor Hwangto Board

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20796053

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20796053

Country of ref document: EP

Kind code of ref document: A1