WO2020191565A1 - Tour de récupération de chaleur perdue multifonctionnelle intégrée de gaz de combustion - Google Patents

Tour de récupération de chaleur perdue multifonctionnelle intégrée de gaz de combustion Download PDF

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Publication number
WO2020191565A1
WO2020191565A1 PCT/CN2019/079419 CN2019079419W WO2020191565A1 WO 2020191565 A1 WO2020191565 A1 WO 2020191565A1 CN 2019079419 W CN2019079419 W CN 2019079419W WO 2020191565 A1 WO2020191565 A1 WO 2020191565A1
Authority
WO
WIPO (PCT)
Prior art keywords
flue gas
recovery tower
desulfurization
spray layer
waste heat
Prior art date
Application number
PCT/CN2019/079419
Other languages
English (en)
Chinese (zh)
Inventor
王海超
吴小舟
刘哲毅
端木琳
李祥立
Original Assignee
大连理工大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大连理工大学 filed Critical 大连理工大学
Priority to PCT/CN2019/079419 priority Critical patent/WO2020191565A1/fr
Publication of WO2020191565A1 publication Critical patent/WO2020191565A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

Definitions

  • the invention belongs to the technical field of recovery and utilization of flue gas waste heat of thermal power plant boilers, and particularly relates to a high-efficiency multifunctional flue gas waste heat recovery tower integrating desulfurization and denitrification, dust removal and condensed water recovery.
  • the country has attached great importance to energy conservation and emission reduction. How to improve the thermal efficiency of the boiler and make full use of the waste heat of the boiler flue gas has become one of the research hotspots.
  • the exhaust gas temperature of industrial coal-fired boilers is generally not lower than 180°C, even as high as 250°C.
  • the high-temperature flue gas discharged wastes a lot of heat energy and also pollutes the surrounding atmospheric environment. If the flue gas waste heat recovery tower is used to spray and condense the low-temperature flue gas, the flue gas and the spray water can be directly contacted for heat exchange, and the boiler exhaust gas temperature can be reduced to the dew point temperature and below, and the water vapor in the flue gas can be condensed and released.
  • the purpose of the present invention is to provide a high-efficiency multifunctional flue gas waste heat recovery tower integrating desulfurization, denitrification, dust removal and condensate water recovery, which can effectively remove SO 2 , NO X and smoke dust in the flue gas, greatly reducing It reduces the pollution of the flue gas to the atmosphere, and at the same time recovers the waste heat of the flue gas, reducing investment costs.
  • An efficient and multifunctional flue gas waste heat recovery tower integrating desulfurization, denitrification, dust removal and condensate water recovery, including a dust collector 2, a recovery tower body 3, a denitrification agent delivery pump 28, a denitrification agent solution tank 11, and a desulfurization agent delivery pump 26 , Desulfurizer solution tank 12 and plate heat exchanger 30, in which:
  • the main body 3 of the recovery tower is provided with a slurry circulation pool, a flue gas inlet, a packing layer 4, a desulfurization spray layer 5, an inclined baffle 10, a flue gas inlet separator 6, a flue gas distributor 7, and a denitration from bottom to top.
  • the flue gas inlet is arranged near the bottom of the recovery tower body 3, and the dust collector 2 is connected to the flue gas inlet. After dust is removed by the dust collector 2, the flue gas enters the flue gas inlet Inside the main body 3 of the recovery tower,
  • the packing layer 4 is horizontally arranged in the recovery tower body 3, the packing layer 4 is located above the flue gas inlet, and a desulfurization spray layer 5 is horizontally arranged above the packing layer 4, and the packing layer 4 has In the gap, the dust-removed flue gas entering from the flue gas inlet contacts the surface of the filler in the filler layer 4 with the desulfurizing agent sprayed by the desulfurization spray layer 5 to desulfurize the dust-removed flue gas,
  • the inclined baffle 10 is arranged above the desulfurization spray layer 5, the flue gas inlet separator 6 is fixed on the upper surface of the inclined baffle 10, and the desulfurized flue gas passes through the flue gas inlet separator 6 It flows up to above the inclined baffle 10.
  • the flue gas inlet separator 6 is a gas-water separator, which is composed of many baffles. The fluid changes its flow direction many times in the flue gas inlet separator 6 due to the suspended droplets With greater mass and inertia, when the flow direction of the baffle changes, the flue gas bypasses the baffle and continues forward, and the water droplets will accumulate on the baffle, and finally fall to the bottom of the inclined baffle 10, passing through the trap discharge;
  • a flue gas distributor 7 is horizontally arranged above the flue gas inlet gas distributor 6 to evenly distribute the desulfurized flue gas to flow upwards,
  • the denitrification spray layer 8 is horizontally arranged in the recovery tower body 3, above the flue gas distributor 7, and the denitrification agent sprayed by the denitrification spray layer 8 passes through the flue gas distributor 7 The flue gas flowing upward is denitrified, and the denitrification agent sprayed by the denitrification spray layer 8 is discharged to the outside of the recovery tower body 3 through the inclined baffle 10;
  • the demister 9 is horizontally arranged in the recovery tower main body 3, above the denitration spray layer 8.
  • the denitrated flue gas passes through the demister 9 to remove water mist, and is removed from the The flue gas outlet above the mist eliminator 9 is discharged,
  • the denitration agent solution tank 11 is connected to the denitration spray layer 8 through a denitration agent delivery pump 28 to provide the denitration spray layer 8 with a denitration agent,
  • the desulfurization agent solution tank 12 is connected to the slurry circulation pool at the bottom of the recovery tower body 3 through the desulfurization agent delivery pump 26, and the desulfurization agent solution tank 12 is used to provide the desulfurization agent in the slurry circulation pool; a circulating spray is provided at the bottom of the waste heat recovery tower 3.
  • a circulating spray is provided at the bottom of the waste heat recovery tower 3.
  • part of the condensed water from the flue gas and desulfurization slurry is composed of circulating spray water, which is discharged from the circulating spray water outlet, and is driven by the waste heat recovery tower circulating water pump 13 to return to the desulfurization spray layer 5 in the tower for circulating spraying.
  • the circulating spray water After the circulating spray water is cooled by the heat exchange of the plate heat exchanger 30, it flows out from the spray water side outlet of the plate heat exchanger 30 and returns to the desulfurization spray layer 5 in the tower for circulating spraying.
  • the plate heat exchanger 30 needs regular maintenance. There are multiple valves on the spray water side to realize that the circulating spray water directly enters the desulfurization spray layer 5 for circulating spraying.
  • the plate heat exchanger 30 simultaneously transfers the heat in the circulating spray water to the heating network return water, and the heating network return water enters the heating network heater for further heating, and sends it to the heating network after reaching the operating requirements;
  • a bypass pipeline is provided between the outlet pipe of the dust collector 2 and the inlet pipe of the chimney 25, on which a flue gas bypass pipe valve K1, and the flue gas bypass pipe valve K1 fails in the waste heat recovery tower 3 or It is turned on during maintenance, and the high-temperature flue gas is directly discharged through the chimney 25 after being dedusted by the dust collector 2.
  • a denitration agent delivery valve 29 is provided between the denitrification agent delivery pump 28 and the denitrification agent solution tank 11 to control the pumping of the denitration agent; between the desulfurization agent delivery pump 26 and the desulfurization agent solution tank 12 A desulfurizing agent delivery valve 27 is provided on the pipeline to control the pumping of the desulfurizing agent.
  • the desulfurizing agent is a NaOH solution with a concentration of 50% by mass; the denitration agent is H 2 O 2 with a concentration of 27.5% by mass.
  • the main body 3 of the recovery tower is integrally cast, and the demister 9, the denitration spray layer 8, the desulfurization spray layer 5, and the flue gas distributor 7 are all provided with a support frame on the lower side, It is used to fix the demister 9, the denitration spray layer 8, the desulfurization spray layer 5, and the flue gas distributor 7 in the recovery tower body 3, respectively.
  • the high-efficiency and multifunctional flue gas waste heat recovery tower utilizes the heat energy in the flue gas to a great extent, realizes the organic combination of energy saving and environmental protection, and has a high degree of integration and saves equipment space.
  • the area is greatly reduced, and it can be widely used in industrial boiler houses, thermal power plants, and other desulfurization, denitrification and flue gas waste heat utilization projects.
  • Figure 1 is a system diagram of an efficient and multifunctional flue gas waste heat recovery tower in an embodiment of the present invention.
  • connection not only refers to a direct connection between components, but also refers to a connection between components through other elements such as pipelines.
  • FIG. 1 is a system diagram of an efficient and multifunctional flue gas waste heat recovery tower in an embodiment of the present invention.
  • a high-efficiency and multifunctional flue gas waste heat recovery tower is provided, which includes a dust collector 2, a recovery tower body 3, a denitrification agent delivery pump 28, a denitrification agent solution tank 11, and a desulfurization agent delivery pump 26.
  • the main body 3 of the recovery tower is provided with a slurry circulation pool, a flue gas inlet, a packing layer 4, a desulfurization spray layer 5, an oblique baffle 10, a flue gas inlet separator 6, a flue gas distributor 7, and a denitration spray from bottom to top.
  • the flue gas produced by the boiler 1 passes through the dust collector 2 under the action of the induced draft fan, and the dust-removed flue gas is connected to the flue gas inlet of the recovery tower body 3 through the waste heat recovery tower inlet valve K1 through the flue gas pipeline.
  • the flue gas pipe from the dust collector 2 is connected to the pipe entering the chimney 25 through the bypass pipe valve K2 through the flue gas bypass pipe.
  • the flue gas inlet is arranged near the bottom of the recovery tower main body 3, and the dust collector 2 is connected with the flue gas inlet. After dust is removed by the dust collector 2, the flue gas enters the recovery tower main body 3 from the flue gas inlet.
  • the packing layer 4 is horizontally arranged in the main body 3 of the recovery tower, the packing layer 4 is located above the flue gas inlet, and the desulfurization spray layer 5 is horizontally arranged above the packing layer 4.
  • the packing layer 4 has gaps, and the dedusted smoke entering from the flue gas inlet
  • the desulfurization agent sprayed by the gas and the desulfurization spray layer 5 contacts the surface of the filler in the filler layer 4 to desulfurize the dust-removed flue gas.
  • the inclined baffle 10 is arranged above the desulfurization spray layer 5, and the flue gas inlet distributor 6 is fixed on the upper surface of the inclined baffle 10, and the desulfurized flue gas flows upward through the flue gas inlet distributor 6 to above the inclined baffle 10.
  • the setting of the inclined baffle 10 is convenient for draining the denitration spray liquid outside and reusing it after treatment.
  • the angle between the inclined baffle 10 and the horizontal plane is 6°.
  • the oblique baffle 10 is arranged above the desulfurization spray layer 5, the flue gas inlet separator 6 is fixed on the upper surface of the oblique baffle 10, and the desulfurized flue gas flows up to the oblique baffle 10 through the flue gas inlet separator 6
  • the flue gas inlet separator 6 is a gas-water separator, which is composed of many baffles. The fluid changes its flow direction many times in the flue gas inlet separator 6.
  • a flue gas distributor 7 is horizontally arranged above the flue gas inlet separator 6 to evenly distribute the desulfurized flue gas to flow upward.
  • the denitrification spray layer 8 is horizontally arranged in the main body 3 of the recovery tower, above the flue gas distributor 7, and the denitrification agent sprayed by the denitrification spray layer 8 is used to denitrate the flue gas flowing upward through the flue gas distributor 7.
  • the denitration agent sprayed by the spray layer 8 is discharged to the outside of the recovery tower body 3 through the inclined baffle 10.
  • the demister 9 is horizontally arranged in the recovery tower body 3, above the denitration spray layer 8.
  • the denitrated flue gas passes through the demister 9 to remove water mist, and is discharged from the flue gas outlet arranged above the demister 9 .
  • the flue gas outlet is connected to the chimney 25, and the flue gas is discharged through the chimney 25.
  • the sulfur and nitrogen content in the flue gas meets national emission standards and then is discharged into the atmosphere.
  • the denitration agent solution tank 11 is connected to the denitration spray layer 8 through a denitration agent delivery pump 28 to provide a denitration agent to the denitration spray layer 8.
  • a denitration agent delivery valve 29 is provided between the denitration agent delivery pump 28 and the denitration agent solution tank 11 to control the pumping of the denitration agent.
  • the desulfurization agent solution tank 12 is connected to the slurry circulation pool at the bottom of the recovery tower body 3 through the desulfurization agent delivery pump 26.
  • the desulfurization agent solution tank 12 is used to provide the desulfurization agent in the slurry circulation pool; the bottom of the waste heat recovery tower 3 is provided with circulating spray water At the outlet, part of the condensed water precipitated by the flue gas and the desulfurization slurry constituted circulating spray water is discharged from the circulating spray water outlet, and is driven by the waste heat recovery tower circulating water pump 13 to return to the desulfurization spray layer 5 in the tower for cyclic spraying.
  • the pipeline between the desulfurizer delivery pump 26 and the desulfurizer solution tank 12 is provided with a desulfurizer delivery valve 27 to control the pumping of the desulfurizer.
  • the desulfurizing agent is a NaOH solution with a mass percentage of 50%.
  • the denitration agent is H 2 O 2 with a mass percentage of 27.5%, which has high denitration efficiency, relatively low price, and no secondary pollution.
  • the recovery tower body 3 is integrally cast and molded, and the demister 9, the denitration spray layer 8, the desulfurization spray layer 5, and the flue gas distributor 7 are all provided with supports on the lower side
  • the rack is used to fix the demister 9, the denitration spray layer 8, the desulfurization spray layer 5, and the flue gas distributor 7 in the recovery tower body 3, respectively.
  • the circulating spray water is driven by a water pump and circulates between the plate heat exchanger 30 and the waste heat recovery tower 3.
  • the upper part of the waste heat recovery tower 3 is provided with a spray circulating water inlet, and the lower part is provided with a spray circulating water outlet.
  • the outlet is connected with the heat medium inlet of the plate heat exchanger 30.
  • the heat medium outlet of the plate heat exchanger 30 passes through the spray pipe, The valve is connected to the inlet of the spray circulating water, thus forming a closed loop.
  • the circulating spray water After the circulating spray water is cooled by the heat exchange of the plate heat exchanger 30, it passes through the valve, the desulfurizer circulating pump 13, and multiple valves to enter the spray water side of the plate heat exchanger 30. After the heat exchange, it flows from the plate heat exchanger 30.
  • the spray water side outlet flows out, and is controlled by multiple valves to return to the desulfurization spray layer 5 in the tower for cyclic spraying.
  • the valves on the inlet pipe and outlet pipe of the spray water side are closed, and the valve between the inlet pipe and the outlet pipe is opened, so that the circulating spray water directly enters the desulfurization spray layer 5 for processing. Spray cyclically.
  • the plate heat exchanger 30 simultaneously transfers the heat in the circulating spray water to the heating network return water, and the heating network return water enters the heating network heater for further heating, and sends it to the heating network after meeting the operating requirements.
  • the plate heat exchanger 30 is used for cooling by spraying water, and at the same time, the return water of the heating heating network, the return water of the heating network is heated by the plate exchange, and then enters the heating network heater for further heating, and then is sent to the heating network after reaching the operating requirements.
  • the operating temperature of the high-efficiency multifunctional flue gas waste heat recovery tower integrating desulfurization, denitrification, dust removal and condensed water recovery provided by the present invention is 38 ⁇ 100°C, the operating temperature range is wider, and the desulfurization and denitrification efficiency is stable, reaching The emission requirements of related pollutants in the Pollutant Emission Standard and the Comprehensive Air Pollutant Emission Standard.
  • the flue gas waste heat recovery tower provided by the present invention can simultaneously realize multiple functions such as desulfurization, de-sales, further dust reduction, waste heat recovery, and condensed water recovery, etc., can reduce pollutant discharge, has a small floor area, has good desulfurization and de-sales effects, and initial investment And the operation cost is low, the operation is easy, and the fully automated operation can be realized.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

Une tour de récupération de chaleur perdue de gaz de combustion multifonctionnelle intégrée, qui est utilisée pour la récupération et l'utilisation de chaleur perdue de gaz de combustion provenant de fours dans des centrales électriques de cogénération. Le gaz de combustion pénètre dans un corps de tour de récupération (3) à partir d'une entrée de gaz de combustion, passe à travers une couche de pulvérisation de désulfuration (5), puis s'écoule de façon régulière à travers un distributeur de gaz de combustion (7) vers une couche de pulvérisation de désulfuration (8). Un désembueur (9) est disposé au-dessus de la couche de pulvérisation de désulfuration (8), et un orifice d'échappement relié à un tuyau de gaz de combustion s'étendant dans une cheminée (25) est disposé au-dessus du désembueur (9). La tour de récupération de chaleur perdue est également reliée à un échangeur de chaleur à plaques (30), ce qui réduit la température de l'eau de pulvérisation en circulation entrant dans la tour de récupération de chaleur perdue. L'eau de retour provenant d'un réseau de chauffage est chauffée par l'échangeur de chaleur à plaques (30) puis entre dans un dispositif de chauffage de réseau de chauffage pour un chauffage supplémentaire, et est envoyée au réseau de chauffage lors de l'atteinte des exigences de fonctionnement. La tour de récupération de chaleur perdue de gaz de combustion multifonctionnelle intégrée peut simultanément effectuer une dénitrification, une désulfuration, une élimination de poussière et une récupération de condensat sur un gaz de combustion, ce qui permet d'économiser de l'espace de sol et de réduire les coûts d'investissement et d'exploitation.
PCT/CN2019/079419 2019-03-25 2019-03-25 Tour de récupération de chaleur perdue multifonctionnelle intégrée de gaz de combustion WO2020191565A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2019/079419 WO2020191565A1 (fr) 2019-03-25 2019-03-25 Tour de récupération de chaleur perdue multifonctionnelle intégrée de gaz de combustion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2019/079419 WO2020191565A1 (fr) 2019-03-25 2019-03-25 Tour de récupération de chaleur perdue multifonctionnelle intégrée de gaz de combustion

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WO2020191565A1 true WO2020191565A1 (fr) 2020-10-01

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CN104383798A (zh) * 2014-09-25 2015-03-04 华北电力大学(保定) 一种烟气脱硫脱硝的净化回收系统
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CN206853296U (zh) * 2017-05-11 2018-01-09 深圳市卓益节能环保设备有限公司 一种汽水分离装置
CN107983133A (zh) * 2017-12-26 2018-05-04 上海亨远船舶设备有限公司 一种烟气湿式联合脱硫脱硝的系统及方法
CN108295634A (zh) * 2018-04-11 2018-07-20 江苏垦乐节能环保科技有限公司 一种烧结烟气高效脱硫脱硝系统及其实现方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102512927A (zh) * 2011-12-31 2012-06-27 艾淑艳 脱硫脱硝一体化烟气净化系统及其净化工艺
CN104028051A (zh) * 2014-05-15 2014-09-10 西安长庆科技工程有限责任公司 一种伴生气凝液回收装置
CN104056535A (zh) * 2014-06-03 2014-09-24 陈浩 一种有机吸收剂法烟气脱硫脱硝脱汞系统
CN104014236A (zh) * 2014-06-19 2014-09-03 南京凯盛开能环保能源有限公司 一种烟气净化与余热深度回收一体化装置
CN104383798A (zh) * 2014-09-25 2015-03-04 华北电力大学(保定) 一种烟气脱硫脱硝的净化回收系统
CN106925097A (zh) * 2017-04-28 2017-07-07 陶汉中 一种基于液相氧化对烟气脱硫脱硝的组合塔及其工艺
CN206853296U (zh) * 2017-05-11 2018-01-09 深圳市卓益节能环保设备有限公司 一种汽水分离装置
CN107983133A (zh) * 2017-12-26 2018-05-04 上海亨远船舶设备有限公司 一种烟气湿式联合脱硫脱硝的系统及方法
CN108295634A (zh) * 2018-04-11 2018-07-20 江苏垦乐节能环保科技有限公司 一种烧结烟气高效脱硫脱硝系统及其实现方法

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