WO2020188953A1 - 分散系、処理方法、及び化学反応装置 - Google Patents

分散系、処理方法、及び化学反応装置 Download PDF

Info

Publication number
WO2020188953A1
WO2020188953A1 PCT/JP2020/000039 JP2020000039W WO2020188953A1 WO 2020188953 A1 WO2020188953 A1 WO 2020188953A1 JP 2020000039 W JP2020000039 W JP 2020000039W WO 2020188953 A1 WO2020188953 A1 WO 2020188953A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
mode
resonator
super
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2020/000039
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
日浦　英文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP2021506182A priority Critical patent/JPWO2020188953A1/ja
Priority to US17/436,317 priority patent/US20220176329A1/en
Publication of WO2020188953A1 publication Critical patent/WO2020188953A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/50—Mixing liquids with solids
    • B01F23/51—Methods thereof
    • B01F23/511—Methods thereof characterised by the composition of the liquids or solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
    • B01F31/80—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
    • B01F31/81—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations by vibrations generated inside a mixing device not coming from an external drive, e.g. by the flow of material causing a knife to vibrate or by vibrating nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40—Mixing liquids with liquids; Emulsifying
    • B01F23/48—Mixing liquids with liquids; Emulsifying characterised by the nature of the liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/50—Mixing liquids with solids
    • B01F23/58—Mixing liquids with solids characterised by the nature of the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40—Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40—Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B01F33/401—Methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/128—Infrared light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00—Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/001—Optical devices or arrangements for the control of light using movable or deformable optical elements based on interference in an adjustable optical cavity

Definitions

  • the present invention relates to a dispersion system based on vibration coupling, a treatment method, and a chemical reaction.
  • Water is the most important substance on the planet. Water is an essential substance from the perspectives of the global environment, life activities, and human economic activities. Compared to materials of the same series, water has a very high melting point and boiling point, and is a liquid in a fairly wide temperature range of 0 to 100 ° C. In this way, the physical properties of water are specific. In addition, water has the chemical property of having an outstandingly high ability to dissolve various substances, and water is indispensable as a medium and reaction raw material for a wide variety of chemical reactions from photosynthesis to industrial synthesis. Furthermore, energy is produced by utilizing the fact that water moves back and forth between the three states of gas (water vapor), liquid (water), and solid (ice).
  • water is useful in a wide range of fields from daily life to various industrial activities as a solvent for various substances, a dispersoid of aerosols, or a dispersion medium for colloids and emulsions.
  • water itself has the most versatile function among substances.
  • Patent Document 1 a method of converting the chemical and physical properties of water by using a vibration super strong coupling (vibrational ultra strong coupling) between the optical mode of a resonator and the vibration mode of water, particularly , A method of promoting a chemical reaction has been devised.
  • Water in a vibrating super-strongly bound state is called super-strongly bound water and has extremely high reactivity.
  • it is difficult to produce ultra-strongly bound water in large quantities its use in industry has not progressed.
  • Patent Document 2 discloses a method of utilizing vibration coupling between the optical mode of an optical system and the vibration mode of a chemical substance vibration system. The principle of this method is to reduce the vibration energy of a chemical substance based on the vibration coupling, reduce the activation energy of the chemical reaction related to the vibration mode, and increase the reaction rate as a result.
  • Patent Document 3 discloses a method using a bond between an electromagnetic wave and a substance. This method results in a reflective or photonic structure with an electromagnetic mode that resonates with the transition in the molecule, biomolecule, or substance and the above-mentioned molecule, biomolecule, or substance within or in a structure of the above type. Includes the process of placing on top.
  • the effective range of the external resonator is at most several micrometers, it is difficult to construct the above-mentioned dispersion in the first place, and even if the above-mentioned dispersion can be constructed, a significant amount cannot be obtained.
  • An example of an object of the present invention is to provide a dispersion system containing a liquid in a vibrationally coupled state.
  • a spherical body composed of a liquid in a vibrationally coupled state is provided.
  • a dispersion system in which the whispering gallery mode in which the spherical state of the liquid is spontaneously formed and the vibration mode of the liquid are resonantly coupled.
  • a sphere that is a dispersoid and consists of a dielectric The liquid, which is the dispersion medium in the spherical state, With A dispersion system is provided in which the whispering gallery mode in which the spherical state of the dielectric is spontaneously formed and the vibration mode of the liquid are resonantly coupled.
  • the reaction vessel that carries out the chemical reaction and An introduction port for introducing the dispersion system into the reaction vessel, An outlet that discharges the reaction product produced by the chemical reaction, A chemical reactor having the above is provided.
  • Schematic diagram showing the principle of vibration coupling Infrared transmission spectrum representing the formation of super strong bound water The figure which shows the comparison of the chemical reactivity of normal water and super strong binding water
  • Schematic diagram showing a comparison between TE mode and TM mode Schematic diagram showing the argument mode dependence of the light intensity distribution in WG mode
  • Schematic diagram illustrating the first embodiment of the present invention Schematic diagram illustrating the first and second embodiments of the present invention
  • Schematic diagram of the chemical reaction system according to the first embodiment of the present invention Schematic diagram of the chemical reaction system according to the second embodiment of the present invention
  • the figure which shows the electric field strength distribution of WG mode leaking from a microdielectric sphere resonator The figure which shows the relationship between the resonance diameter and the specific refractive index of a microdielectric sphere resonator
  • a microsphere resonator that spontaneously forms a WG (whispering gallery) mode is used. Specifically, by vibrating and coupling the WG mode, which is a kind of optical mode, and the vibration mode of a liquid (for example, water), a liquid in a vibrationally coupled state such as super-strongly bonded water is generated.
  • This generating means is classified into the following two types according to the usage of the microsphere resonator. The first means is that the liquid itself becomes a sphere to form a micro water polo resonator or a micro liquid ball resonator.
  • an aerosol having a dispersoid in a vibration super strong coupling state or a vibration coupling state can be obtained.
  • the microdielectric sphere resonator is a dispersoid
  • the liquid located around the dispersoid is a dispersion medium that is in a vibration super strong coupling state or a vibration coupling state.
  • a colloid or emulsion is obtained.
  • the micro water polo or macrodielectric sphere does not necessarily have to be a perfect sphere (true sphere) in order for the microsphere resonator to operate. Even if these spheres are flat spheroids that expand and contract in the uniaxial direction, as long as the equatorial (great circle) plane is a perfect circle or a shape close to a perfect circle to the extent that WG mode is formed, the microsphere resonator Works as a resonator and does not interfere with the formation of the WG mode. Therefore, it is possible to obtain the aerosol, colloid or emulsion of the present invention even if the microsphere is a flat spheroid.
  • the shape of the microsphere may dynamically change within a certain range.
  • a variation in resonance diameter of about 6% is allowed when obtaining an aerosol, colloid or emulsion of super-strongly bound water.
  • the value becomes about 0.11. That is, even if the shape of the microsphere changes dynamically within the range of 0 to 0.11 in flatness, an aerosol, colloid or emulsion of super-strongly bound water can be obtained.
  • the first means described above is characterized in that the resonator is composed only of a liquid. That is, the liquid is integrated with the resonator.
  • a spherical liquid in an oscillating super strong coupling state or an oscillating coupling state becomes an aerosol that is self-contained.
  • the liquid spheres are on the order of micrometers in diameter and are self-contained without the need for the installation of macroscopic external structures or the input of external energy. Since the external resonator is not required, the manufacturing cost can be reduced. Further, since the liquid is not bound by the external resonator, the liquid in the vibration super strong coupling state or the vibration coupling state can be produced in a desired place in a desired amount.
  • the second means described above is characterized in that the WG mode leaking from the microdielectric ball resonator is used for vibration coupling.
  • the microdielectric sphere resonator is a colloid or emulsion in which the dispersoid and the liquid are the dispersion medium.
  • the diameter of the dispersoid dielectric is on the order of micrometers and is dispersed in the dispersant liquid.
  • an external resonator becomes unnecessary when generating a liquid in a super strong coupling state or a vibration coupling state.
  • super-strongly bound water or a liquid in an oscillating bonded state can be generated in a three-dimensional free space at an arbitrary place and in a desired amount. The reason for this is that it is not bound by an external resonator.
  • a microdielectric spherical body dispersed in a liquid is used as a resonator, a required large amount of liquid in a super strong coupling state or a vibration coupling state can be obtained.
  • the reason is that by vibrating the WG mode that seeps out from the microdielectric sphere resonator and the vibration mode of the liquid, the entire liquid that is the dispersion medium can be converted into a liquid that is in a super strong coupling state or a vibration coupling state. Is.
  • the microdielectric sphere resonator 53 of the second embodiment has a feature that a dielectric material composed of a wide variety of liquids and solids can be used. Microdielectric spheres can be mass-produced by existing fine particle production methods and emulsion production methods. Further, the dispersible water may be ordinary water. Therefore, the colloid or emulsion 56 of the present invention is characterized in that it can be mass-produced by a scale-up method.
  • the reaction solution is sent from the reaction vessel 85 to the microdielectric sphere separator 88 via the discharge port 92, and the microdielectric sphere resonance is performed from the reaction solution using the microdielectric sphere separator 88.
  • Remove the vessel If the removed micro-dielectric sphere resonator is solid, it is sent from the micro-dielectric sphere separator 88 to the micro-dielectric sphere supply device 80 via the micro-dielectric sphere recovery pipe 87, and the reaction is repeated for the next reaction. Use. Since the solid microdielectric sphere resonator is not consumed by the reaction, it can be regenerated many times.
  • the remaining reaction solution is transferred to the product separation device 89 via the pipe 83, and the target product is separated from the remaining reaction solution by using the product separation device 89.
  • the target product is moved to the product recovery container 90 via the pipe 83, and the target product is recovered to complete the series of steps.
  • the batch-type chemical reaction system 93 using the microdielectric ball resonator described above has the following nine features: (1) It can be applied to a wide range of chemical reactions involving water, and the reaction can be remarkably promoted. (2) Although the super-strongly bound water produced by the microdielectric sphere is highly reactive, it is originally water, so it can be safely handled before and after the reaction. (3) Unlike other resources, water, which is the source of super-strongly bound water, is ubiquitous all over the earth, so it can be obtained at a very low price anytime, anywhere. (4) The water itself is harmless and there is no possibility of environmental pollution, so it is extremely environmentally friendly.
  • the microdielectric sphere resonator 98 packed in the column may be one in which a colloid made of a microdielectric sphere resonator is supported on a fiber or the like, or one in which a colloid made of a microdielectric sphere resonator is precipitated. It may be.
  • the former carrier type has an advantage that the outflow of the mixed solution becomes smooth because the distance between the microdielectric sphere resonators can be adjusted by the carrier. Therefore, it is suitable when the mixed solution is easily clogged, for example, when the resonance diameter of the microdielectric sphere resonator is as small as several ⁇ m or less.
  • the steps of mixing and separating water and the microdielectric sphere resonator are not required before and after the reaction. Therefore, this system can be extended to a multi-step reaction system.
  • the version can be upgraded to a multi-step reaction system simply by serially connecting 95 groups of reaction columns corresponding to each step of the multi-step reaction.
  • the inlet 92 and outlet 98 of the reaction column 95 are packaged in conformity with JIS standards, etc., it can be used in various chemical plants, water and sewage treatment systems, artificial liver systems, and other existing continuous systems. It is also possible to incorporate the system as a reaction column unit.
  • a liquid in a vibrationally coupled state can be freely generated at a desired time and in a desired place. (7) Since it is composed of a liquid in a vibrationally coupled state, it is useful for promoting the reaction. (8) As shown by V in Table 6, detoxification, virus removal, promotion of cell culture, and other methods that could not be achieved by reference technology can contribute to the biotechnology and medical fields.
  • Table 3 shows the resonance diameter of the micro water polo resonator used to generate ultra-strongly coupled water.
  • the resonance diameter at which the micro water polo resonator becomes super strong coupling water is uniquely determined. Specific numerical values for this resonance diameter are shown in the "Exact match" line in Table 3.
  • the resonance diameter at which the micro water polo resonator becomes super strong coupling water is not determined by one point, but has a range of half width. This range is shown by the intersection of solid lines 1 and 2 and diagonal lines 3 and 4 in FIG. 10 (line segments between black circles in light water and white circles in heavy water).
  • the specific numerical values of this resonance diameter range are shown in the row of "match within half width" in Table 3.
  • the allowable range of the resonance diameter is as wide as ⁇ 5.9% in the case of the light water polo resonator and ⁇ 6.4% in the case of the heavy water micro water polo resonator.
  • the geometric standard deviation of the particle size distribution is 1.10 or less, so that the above allowable range can be sufficiently achieved by the existing technology. Therefore, water is special in that strict diameter control is not required, and a micro water polo resonator can be easily manufactured. In the case of a microdielectric sphere resonator, the same argument holds if water is the dispersion medium.
  • the resonance diameter is larger when heavy water is used than when light water is used.
  • the binding ratio of super strong bound water ⁇ R / 2 ⁇ 0 is almost the same when light water and heavy water are used, so light water, heavy water, or a mixture thereof is used to generate super strong bound water. You may.
  • Example 1 it was shown that the micro water polo of light water and heavy water acts as a resonator, and the resonance diameter required for the generation of super strong bound water is concretely shown.
  • the resonance diameter of the micro-water polo resonator required to generate ultra-strongly coupled water is in the range of about 6% before and after the perfect match value due to the very broad absorption band of the stretching vibration of water. It was revealed that it was in.
  • the radial mode number and the declination mode number dependence of the resonance diameter at which the micro water polo resonator floating in the air is converted into super-strongly coupled water is shown.
  • the vertical axis is the resonance diameter: D
  • the horizontal axis is the declination mode number: m.
  • (A) is the case of TE mode
  • (B) is the case of TM mode.
  • Table 4 shows the dependence of the resonance diameter of the micro water polo resonator required for the generation of super-strongly coupled water on the radial mode number and the declination mode number.
  • this embodiment also has an allowable range of resonance diameter, which is the same as that of the first embodiment. That is, the allowable range of the resonance diameter is ⁇ 5.9% in the case of light water and ⁇ 6.4% in the case of heavy water.
  • the reason why the resonance diameter required for generating super strong bound water is smaller in light water than in heavy water is as described in Example 1.
  • the simple reason is that the wavelength of the WG mode is longer in the stretch vibration mode of heavy water than in the stretch vibration mode of light water.
  • the binding ratio of super strong bound water: ⁇ R / 2 ⁇ 0 is almost the same when light water and heavy water are used, so light water, heavy water, or a mixture thereof is used to generate super strong bound water. You may.
  • the electric field in WG mode has a diameter outside the resonator depending on the declination mode number: m or the specific refractive index: nr. Explain how it is distributed in the direction.
  • the WG mode of the microdielectric sphere resonator is outside the sphere resonator regardless of the declination mode number. It has a finite electric field strength. Therefore, if this leaking WG mode is used for vibration coupling with the expansion / contraction vibration mode of water, the water existing around the microdielectric sphere resonator can be removed in the range of at least one argument mode number of 1 ⁇ m ⁇ 64. It can always be converted to super-strongly bound water.
  • the leaked electric field maintains more than a quarter of the strength of the interfacial electric field.
  • the declination mode number: m be as large as possible in the generation of super-strongly coupled water by the micro water polo resonator. That is, it is the exact opposite of the generation of super-strongly coupled water by the microdielectric sphere resonator.
  • the electric field in the WG mode leaks considerably in any of the cases 1 to 4.
  • ⁇ 0.4 ⁇ 0.05 that is, the leaked electric field maintains about 40 ⁇ 5% of the interfacial electric field. Therefore, as long as the specific refractive index is at least within the range of 1.083 ⁇ n r ⁇ 4.566, the water existing around the microdielectric sphere resonator can always be converted into super-strongly coupled water.
  • the leakage electric field in the WG mode decreases as the specific refractive index increases.
  • the specific refractive index the easier it is for total reflection and the less leakage in the WG mode.
  • the dependence of the leaked electric field on the specific refractive index is relatively small.
  • Example 3 it has been shown by numerical calculation that the leaked electric field of the microdielectric ball resonator existing in water can be used for the generation of super-strongly coupled water.
  • Declination mode number of the leaked electric field range From the m dependence, in the case of a microdielectric sphere resonator existing in water, super-strongly coupled water can be generated in a range of at least 1 ⁇ m ⁇ 64, and the declination mode. It was clarified that the smaller the number, the larger the amount of super-strongly bound water can be produced.
  • Example 4 when water is used as the dispersion medium, the relationship between the resonance diameter and the specific refractive index of the microdielectric sphere resonator required for the generation of super-strongly coupled water is the type of deflection (TE mode, TM mode).
  • TE mode the specific refractive index of the microdielectric sphere resonator required for the generation of super-strongly coupled water
  • TM mode the specific refractive index of the microdielectric sphere resonator required for the generation of super-strongly coupled water.
  • env refractive index outside the resonator.
  • (A) is the case of TE mode
  • (B) is the case of TM mode.
  • solid dielectrics examples include magnesium fluoride (MgF 2 ), polydimethyldioxane (PDMS), calcium fluoride (CaF 2 ), silicon oxide (SiO 2 ), barium fluoride (BaF 2 ).
  • MgF 2 magnesium fluoride
  • PDMS polydimethyldioxane
  • CaF 2 calcium fluoride
  • SiO 2 silicon oxide
  • BaF 2 barium fluoride
  • the dielectric When the dielectric is a liquid, it is used in the emulsion of the present invention.
  • liquid dielectrics are: octane, carbon tetrachloride (CCl 4 ), diethyl phthalate, benzene, dichlorobenzene, nitrobenzene, bromoform (CHBr 3 ), and carbon disulfide (CS 2 ). At least one.
  • the resonance diameter required for the generation of super-strongly bound water suddenly increases as the specific refractive index increases, regardless of the type of water, the type of deflection, and the radial mode number. After increasing, it passes through a maximum value and then gradually decreases.
  • the resonance diameter of the microsphere resonator required to convert a liquid other than water into a vibrationally coupled state is the same as the molecular frequency and the specific refractive index.
  • the allowable range of the resonance diameter required to generate the liquid in the vibrationally coupled state will be described.
  • FIGS. 14, 9 and 10 only “perfect match” is shown with respect to the resonance diameter, and “match within half width” as shown in Example 1 is not shown. This is to avoid the complexity of charts.
  • the half width of the vibration mode is approximately 1/50 of the molecular frequency, so the allowable range of the resonance diameter is ⁇ 1%.
  • the permissible range of the resonance diameter for the mixed solution containing the aqueous solution and water is ⁇ 5.9% when the OH expansion / contraction vibration is vibrationally coupled, and ⁇ 6.4% when the OD expansion / contraction vibration is vibrationally coupled.
  • an aerosol having a liquid in a vibrationally coupled state as a dispersoid and a liquid in a vibrationally coupled state as a dispersion medium are used. It is shown that colloids can be realized in a wide variety of liquids. This is because the only requirements are the resonance diameter and the specific refractive index. For example, not only liquids of glycerin, methanol, 2-propanol, 2-methyl-2-propanol, phenyl isocyanate, and acetone, but also aqueous solutions such as hydrogen peroxide solution and formalin, and various solutes such as blood. It is a mixed solution containing a dispersoid. In this way, aerosols, colloids, and emulsions in a vibration-bonded state can be produced for a wide variety of liquids, from pure liquids to solutions and mixed liquids.
  • the present invention does not choose the vibration mode and the molecular frequency.
  • aerosols, colloids, and emulsions in a vibrationally coupled state can be produced for liquids having a wide variety of vibration modes and molecular frequencies.
  • a gas such as air is a dispersion medium
  • a liquid other than pure water constitutes a micro liquid sphere resonator
  • the dispersoid aerosol and a liquid other than pure water are dispersed.
  • the resonance diameter required for a liquid other than pure water to be in a vibrationally coupled state is the molecular frequency, specific refractive index, and deflection.
  • Examples of utilization of the present invention include general industrial fields that utilize the physical and chemical properties of liquids such as water.
  • it can be expected to be used in a wide range of industrial fields, from industrial fields that use chemical reactions involving liquids such as water to healthcare, medical, and pharmaceutical fields.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
PCT/JP2020/000039 2019-03-20 2020-01-06 分散系、処理方法、及び化学反応装置 Ceased WO2020188953A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2021506182A JPWO2020188953A1 (https=) 2019-03-20 2020-01-06
US17/436,317 US20220176329A1 (en) 2019-03-20 2020-01-06 Dispersion system, treatment method and chemical reaction apparatus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019053611 2019-03-20
JP2019-053611 2019-03-20

Publications (1)

Publication Number Publication Date
WO2020188953A1 true WO2020188953A1 (ja) 2020-09-24

Family

ID=72519782

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2020/000039 Ceased WO2020188953A1 (ja) 2019-03-20 2020-01-06 分散系、処理方法、及び化学反応装置

Country Status (3)

Country Link
US (1) US20220176329A1 (https=)
JP (1) JPWO2020188953A1 (https=)
WO (1) WO2020188953A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113282995A (zh) * 2021-06-11 2021-08-20 重庆大学 一种自修正的结构分散振动控制系统设计方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6082132A (ja) * 1983-10-11 1985-05-10 Ishikawajima Harima Heavy Ind Co Ltd レ−ザ光による反応器
US20040238744A1 (en) * 2003-01-15 2004-12-02 Stephen Arnold Perturbation approach to resonance shift of whispering gallery modes in a dielectric microsphere as a probe of a surrounding medium
JP2010530142A (ja) * 2007-06-13 2010-09-02 オーイーウェイブス，インコーポレーテッド ウィスパリングギャラリーモード共振器に同期されるチューニング可能レーザ
JP2011518650A (ja) * 2008-03-11 2011-06-30 イミュノライト・エルエルシー 外部放射源からの内部エネルギー活性のためのプラズモニクス支援システムおよび方法
JP2014513304A (ja) * 2011-05-06 2014-05-29 ユニベルシテ ドゥ ストラスブール 分子または物質の特性を改変する方法およびデバイス
WO2018038130A1 (ja) * 2016-08-26 2018-03-01 日本電気株式会社 化学反応装置、及びその製造方法
WO2018211820A1 (ja) * 2017-05-18 2018-11-22 日本電気株式会社 物、装置、及び処理方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6082132A (ja) * 1983-10-11 1985-05-10 Ishikawajima Harima Heavy Ind Co Ltd レ−ザ光による反応器
US20040238744A1 (en) * 2003-01-15 2004-12-02 Stephen Arnold Perturbation approach to resonance shift of whispering gallery modes in a dielectric microsphere as a probe of a surrounding medium
JP2010530142A (ja) * 2007-06-13 2010-09-02 オーイーウェイブス，インコーポレーテッド ウィスパリングギャラリーモード共振器に同期されるチューニング可能レーザ
JP2011518650A (ja) * 2008-03-11 2011-06-30 イミュノライト・エルエルシー 外部放射源からの内部エネルギー活性のためのプラズモニクス支援システムおよび方法
JP2014513304A (ja) * 2011-05-06 2014-05-29 ユニベルシテ ドゥ ストラスブール 分子または物質の特性を改変する方法およびデバイス
WO2018038130A1 (ja) * 2016-08-26 2018-03-01 日本電気株式会社 化学反応装置、及びその製造方法
WO2018211820A1 (ja) * 2017-05-18 2018-11-22 日本電気株式会社 物、装置、及び処理方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113282995A (zh) * 2021-06-11 2021-08-20 重庆大学 一种自修正的结构分散振动控制系统设计方法

Also Published As

Publication number Publication date
US20220176329A1 (en) 2022-06-09
JPWO2020188953A1 (https=) 2020-09-24

Similar Documents

Publication Publication Date Title
Righini et al. Biosensing by WGM microspherical resonators
Zhu et al. Ultra-wideband high-efficiency solar absorber and thermal emitter based on semiconductor InAs microstructures
Schejn et al. Size-controlled synthesis of ZnO quantum dots in microreactors
Venditti Gold nanoparticles in photonic crystals applications: A review
Bian et al. Quantum dots from microfluidics for nanomedical application
JP7110982B2 (ja) 化学反応装置の製造方法
Qian et al. Surface nanodroplets: formation, dissolution, and applications
Vasquez et al. Three-phase co-assembly: in situ incorporation of nanoparticles into tunable, highly ordered, porous silica films
Gardosi et al. Photonic microresonators created by slow optical cooking
Sparks et al. Templated chemically deposited semiconductor optical fiber materials
Cao et al. Colored daytime radiative cooling textiles supported by semiconductor quantum dots
Liu et al. Preparation of stable phase change material emulsions for thermal energy storage and thermal management applications: a review
Jiao et al. Controllable synthesis of upconversion nanophosphors toward scale‐up productions
Righini Glassy microspheres for energy applications
Wang et al. 2D-material-integrated whispering-gallery-mode microcavity
Liu et al. Recent advances in liquid metal photonics: technologies and applications
Yi et al. Cooperative optical trapping of polystyrene microparticle and protein forming a submillimeter linear assembly of microparticle
Creff et al. Self-assembly of bridged silsesquioxanes: modulating structural evolution via cooperative covalent and noncovalent interactions
WO2020188953A1 (ja) 分散系、処理方法、及び化学反応装置
Valuckas et al. Fabrication of monodisperse colloids of resonant spherical silicon nanoparticles: applications in optical trapping and printing
US9771490B2 (en) Inks for 3D printing gradient refractive index (GRIN) optical components
Curtin et al. Synthesis of tunable gold nanostars via 3D-printed microfluidic device with vibrating sharp-tip acoustic mixing
Yuan et al. A systematic study of the factors affecting the surface quality of chemically vapor-deposited diamond during chemical and mechanical polishing
Sugimoto et al. Core/shell architecture made from Mie-resonant silicon nanoparticle: Design, fabrication, and photonic applications
Zhang et al. Physical and Chemical Preparation Techniques and Applications of Photonic Crystals: A Review

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20774586

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2021506182

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20774586

Country of ref document: EP

Kind code of ref document: A1