WO2020116247A1 - プラズマ処理装置及び下部ステージ - Google Patents
プラズマ処理装置及び下部ステージ Download PDFInfo
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- WO2020116247A1 WO2020116247A1 PCT/JP2019/046216 JP2019046216W WO2020116247A1 WO 2020116247 A1 WO2020116247 A1 WO 2020116247A1 JP 2019046216 W JP2019046216 W JP 2019046216W WO 2020116247 A1 WO2020116247 A1 WO 2020116247A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32715—Workpiece holder
- H01J37/32724—Temperature
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32137—Radio frequency generated discharge controlling of the discharge by modulation of energy
- H01J37/32155—Frequency modulation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32174—Circuits specially adapted for controlling the RF discharge
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32532—Electrodes
- H01J37/32541—Shape
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32532—Electrodes
- H01J37/32568—Relative arrangement or disposition of electrodes; moving means
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/46—Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/70—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32091—Radio frequency generated discharge the radio frequency energy being capacitively coupled to the plasma
Definitions
- Example embodiments of the present disclosure relate to a plasma processing apparatus and a lower stage.
- the conventional plasma processing apparatus is described in Patent Documents 1 and 2.
- the distance between the upper electrode and the lower electrode is set so that the intensity distribution of the electric field formed between the electrodes is more uniform in the plane parallel to the processing surface of the member to be processed. It is partially different in.
- a capacitively coupled plasma (CCP) processing apparatus using a very high frequency (VHF) band frequency for plasma generation is drawing attention.
- the VHF band is a frequency in the range of about 30 MHz to 300 MHz.
- a structure is known in which electromagnetic waves are radiated perpendicularly to the surface of the wafer.
- a plasma processing device that can improve the in-plane uniformity of plasma and a lower stage used for this are expected.
- the lower stage is directed to the lower stage for generating a plasma with the upper electrode.
- the lower stage includes a lower dielectric body made of ceramics, a lower electrode embedded in the lower dielectric body, and a heating element embedded in the lower dielectric body.
- the distance d edge between the upper surface and the lower electrode at the outer edge of the lower dielectric is smaller than the distance d center between the upper surface of the central region of the lower dielectric and the lower electrode.
- the lower electrode has an inclined region inclined with respect to the upper surface between the outer edge position and the central region.
- the plasma processing apparatus and the lower stage used therefor it is possible to improve the in-plane uniformity of plasma.
- FIG. 1 is an explanatory diagram showing a device configuration of a plasma processing apparatus.
- FIG. 2 is a plan view of a mesh-shaped lower electrode.
- FIG. 3 is a graph showing the relationship between the radial distance r (mm) from the center and the position z (mm).
- the lower stage is directed to the lower stage for generating a plasma with the upper electrode.
- the lower stage includes a lower dielectric body made of ceramics, a lower electrode embedded in the lower dielectric body, and a heating element embedded in the lower dielectric body.
- the distance d edge between the upper surface and the lower electrode at the outer edge of the lower dielectric is smaller than the distance d center between the upper surface of the central region of the lower dielectric and the lower electrode.
- the lower electrode has an inclined region inclined with respect to the upper surface between the outer edge position and the central region.
- the lower electrode is formed in a mesh shape, a thin film shape, or by a printing method, and is embedded in the ceramics.
- the lower dielectric, together with the lower electrode tends to bend the in-plane electric field vector group so as to be perpendicular to the lower stage surface. Therefore, when VHF waves are introduced onto the lower stage to generate plasma, the in-plane uniformity of plasma is improved.
- the plasma processing apparatus including the lower stage can be supplied with VHF power between the upper electrode and the lower electrode. Due to the VHF wave, plasma is generated between the upper electrode and the lower electrode.
- the plasma processing apparatus is configured so that a downward direction of a normal to the thickness direction at the center of the lower electrode is a Z axis, an X axis perpendicular to the Z axis, and a direction perpendicular to both the Z axis and the X axis.
- a downward direction of a normal to the thickness direction at the center of the lower electrode is a Z axis, an X axis perpendicular to the Z axis, and a direction perpendicular to both the Z axis and the X axis.
- the relative dielectric constant of the lower dielectric is ⁇ r
- the speed of light is c
- the frequency of VHF power is f
- the circular constant is ⁇
- the ceramic material can be AlN. Since AlN has high heat resistance, it has an advantage of high resistance to plasma.
- VHF power can be introduced as VHF waves from the side of the process vessel into the space between the upper electrode and the lower stage.
- the VHF wave can be introduced into the processing container via the waveguide, and the VHF wave generates plasma between the upper electrode and the lower electrode.
- the VHF wave is introduced from the VHF wave introducing unit between the upper electrode and the lower electrode, the gas inside becomes plasma and plasma is generated.
- the introduction part of the VHF wave is located at the lateral end (horizontal end), and since the VHF wave is introduced from various lateral directions into this space, a standing wave is formed. It is hard to be done.
- the lower stage can be driven so that it can move vertically.
- FIG. 1 is an explanatory diagram showing a device configuration of a plasma processing apparatus 100 according to an exemplary embodiment.
- a three-dimensional orthogonal coordinate system is set.
- the vertical direction of the plasma processing apparatus is the Z-axis direction, and the two directions perpendicular to this are the X-axis and the Y-axis, respectively.
- the plasma processing apparatus 100 includes a lower stage LS.
- the lower stage LS is a lower stage for generating plasma with the upper electrode 5.
- the lower stage LS includes a lower dielectric 8 made of ceramics, a lower electrode 6 embedded in the lower dielectric 8, and a temperature control device TEMP (including a heating element) embedded in the lower dielectric 8. ing.
- the plasma processing apparatus 100 is provided with the upper electrode 5 and the lower electrode 6 that are arranged to face each other in the processing container 1, and generates plasma in the space SP between these electrodes.
- the upper electrode 5 may be provided with a recess on the lower surface, and the upper dielectric may be disposed in the recess.
- the VHF wave introducing unit 9 can be provided at the lateral end of the space SP.
- a VHF wave waveguide 2 made of a dielectric plate is provided on the upper open end of the processing container 1, and a lid member 3 is provided on the VHF wave waveguide 2 if necessary.
- the center of the lid member 3 is open, the side wall around the opening constitutes the outer conductor 3a of the coaxial tube, and the inner conductor 3b is arranged at the axial center.
- the inner conductor 3b is integrally formed with the upper electrode 5 and is electrically connected thereto.
- the upper surface of the lower dielectric 8 is flat and parallel to the XY plane. Further, the planar shapes (shapes viewed from the Z-axis direction) of the lower dielectric 8 and the lower electrode 6 are circular.
- the mesh-shaped lower electrode 6 is used to deform the effective shape of the lower dielectric 8 that affects the VHF wave. That is, the distance d edge between the upper surface at the outer edge of the lower dielectric 8 and the lower electrode is smaller than the distance d center between the upper surface of the central region of the lower dielectric 8 and the lower electrode 6. small.
- the lower electrode 6 has an inclined region that is inclined with respect to the upper surface (XY plane) between the outer edge position and the central region. In this example, it has a shape that is recessed downward, and the entire region except the center is the inclined region.
- the lower dielectric 8 effectively acts on the VHF wave in the same manner as the lower dielectric 8 having a thick central portion and a thin outer peripheral portion.
- FIG. 2 is a plan view of a mesh-shaped lower electrode.
- the lower electrode 6 has a mesh shape and includes an outer frame portion 6A made of a conductor and a mesh body 6B made of a conductor indicated in the outer frame portion 6A.
- the size of one opening in the mesh is about 1 mm, and preferably 0.5 mm to 3 mm from the viewpoint of electromagnetic wave shielding.
- the area of one opening about 0.785 mm 2: is preferably (Example 20% ⁇ ), preferably 0.196mm 2 ⁇ 28.3mm 2 from the viewpoint of electromagnetic shielding.
- the area of one opening is preferably about 1 mm 2 (eg ⁇ 20%), and from the viewpoint of electromagnetic wave shielding, it is preferably 0.25 mm 2 to 9 mm 2 .
- the lower electrode 6 is embedded in the ceramic.
- the material of the lower electrode 6 is preferably a material that can withstand even when the lower dielectric 8 is sintered and formed, and Ta or Mo can be used.
- the lower dielectric 8 tends to bend the in-plane electric field vector group together with the mesh-shaped lower electrode 6 so as to be perpendicular to the lower stage surface. Therefore, when the VHF wave is introduced onto the lower stage to generate the plasma, the uniformity of the plasma in the plane is improved.
- the VHF wave introduced in the central part of the VHF wave waveguide 2 in the horizontal direction travels radially to the peripheral part along the horizontal direction. After that, the VHF wave travels downward in a waveguide 1w formed of a concave portion (planar shape is circular ring-shaped, depth is in the Z-axis direction) provided in the side wall of the processing container 1, and reaches the VHF wave introducing portion 9. It is introduced and proceeds from the outer peripheral portion toward the central portion.
- the planar shape of the VHF wave introducing unit 9 is a circular ring shape, and the VHF wave travels from all horizontal azimuths toward the axial center of the processing container.
- the VHF wave introducing unit 9 is located in the lateral direction of the plasma generation space SP.
- VHF power is introduced as a VHF wave into the space between the upper electrode and the lower stage from the side of the processing container.
- the VHF wave generated from the VHF wave generator 13 is introduced into the horizontal VHF wave waveguide 2 through the waveguide.
- the VHF wave introducing unit 9 is located at the lateral end (horizontal end), and since VHF waves are introduced from various lateral directions into this space, a standing wave is formed. There is an advantage that it is hard to be done.
- the electric field vector generated between the upper electrode 5 and the lower electrode 6 tends to incline downward from the vertical direction in the outer peripheral region of the electrode. Since the lower electrode 6 is provided with the lower dielectric 8 that bends the electric field vector, the dielectric can make the electric field vector uniform in the plane. Therefore, the plasma distribution generated between the upper electrode 5 and the lower electrode 6 can be made uniform in the plane by introducing the VHF wave in the lateral direction and making the direction of the electric field vector uniform. That is, the lower dielectric 8 has a lens function of bending the electric field vector.
- the lower electrode 6 can be moved vertically by the drive stage DRV. As a result, plasma can be generated under optimum conditions. Further, the lower electrode 6 is provided with a temperature adjusting device TEMP.
- the temperature control device TEMP includes a medium passage for flowing a cooling medium, a heating element (heater), and a temperature sensor, and the control device 12 controls the lower electrode 6 to a target temperature. .. For example, if the target temperature is T1° C., if the output of the temperature sensor is smaller than T1° C., the heater is heated, and if it is higher than T1° C., the heater is not heated and the cooling medium is flown into the medium passage. , It should be controlled.
- the heating element as the temperature control device TEMP is preferably embedded in the lower dielectric 8 and can be made of the above-mentioned refractory metal or carbon. A wire for power supply is connected to the heating element.
- the control device 12 also controls the exhaust device 14.
- the exhaust device 14 exhausts the gas in the annular exhaust passage 4 provided in the outer wall of the processing container 1.
- the exhaust passage 4 is provided in the lateral direction of the plasma generation space SP, and communicates with a plurality of exhaust holes provided along the circumferential direction on the inner surface of the processing container. Thereby, the gas in the plasma generation space SP can be exhausted, and the pressure in this space can be set to an appropriate value. This pressure may be changed depending on the processing content, but can be set to 0.1 Pa to 100 Pa, for example.
- a pump normally used in a vacuum system device such as a rotary pump, an ion pump, a cryostat, or a turbo molecular pump can be adopted.
- the control device 12 controls the flow rate controller 11 that controls the flow rate of the gas generated from the gas source 10.
- the flow rate controller 11 may be a simple valve. As a result, the target gas can be introduced into the processing container 1.
- the controller 12 also controls the VHF wave generator 13.
- the frequency of the VHF wave is about 30 MHz to 300 MHz.
- gases that can be used for the gas source 10 include noble gases such as Ar, gases containing carbon and fluorine such as CF 4 and C 4 F 8 and gases such as N 2 and O 2 .
- Aluminum can be used as the material of the upper electrode 5 and the lower electrode 6.
- Aluminum nitride (AlN) can be used as the material of the lower dielectric 8. That is, the material of the ceramics that constitutes the lower dielectric 8 is AlN. Since AlN has high heat resistance, it has an advantage of high resistance to plasma.
- quartz can be used as the material of the VHF wave waveguide 2 in the horizontal direction, air may be used as long as the waveguide can be formed.
- silicon or the like can be used, and processing such as film formation or etching can be performed on this substrate.
- an electrostatic chuck may be provided, a DC bias potential may be added to the lower dielectric 8, or a high frequency voltage may be applied between the upper and lower electrodes.
- a configuration in which a magnet is arranged in the is also conceivable.
- VHF electric power can be supplied between the upper electrode 5 and the lower electrode 6 when the VHF wave is introduced. Due to this VHF wave, plasma is generated between the upper electrode and the lower electrode.
- the plasma processing apparatus has a tertiary structure having a Z-axis in a downward direction of a normal to the thickness direction at the center of the lower electrode, an X-axis perpendicular to the Z-axis, and a Y-axis perpendicular to both the Z-axis and the X-axis.
- the origin of the coordinate system is the center of gravity of the upper surface of the lower dielectric
- the lower electrode is set as follows.
- the relative permittivity ⁇ r of the lower dielectric, the speed of light is c, the frequency of VHF power is f, the circular constant is ⁇ , and the wave number in the dielectric of VHF power is k( ( ⁇ r ) 0.5 ⁇ 2 ⁇ f/c ).
- the position (x, z) of the upper surface of the lower electrode in the XZ plane is set so as to satisfy the following equation: (Equation 1).
- Equation 1 is set so that an electric field vector in the plasma generation space is obtained and an electric field that cancels the radial component of the electric field vector is generated on the surface of the lower electrode. That is, the electric field E in the plasma generation space has a radial component (the following (formula 2)) and a Z-axis direction component (the following (formula 3)).
- the shape of the lower electrode is the shape of (Equation 4) or (Equation 5) below.
- a and a 0 are appropriate constants, and E 0 is a reference electric field generated in the plasma generation space.
- FIG. 3 is a graph showing the relationship between the radial distance r (mm) from the center and the position z (mm) on the Z axis. Note that z is the distance from the lower dielectric surface to the lower electrode. Since the Z-axis is directed downward, as shown in the graph, the shape of the lower electrode is downwardly convex in any vertical cross section.
- the same figure shows the case where alumina (Al 2 O 3 ) is used as the lower dielectric, the case where quartz (Quartz) is used, and the case where air (Air) is used.
- the lower electrode is greatly inclined.
- the lower electrode and the lower dielectric having a diameter of 200 mm are used, even if the thickness of the lower dielectric in the Z-axis direction is 70 mm or less, the above effect is exerted to cancel the lateral component of the electric field vector.
- the in-plane uniformity of plasma can be improved.
- the lower stage LS is driven by the drive stage DRV so as to be movable in the vertical direction. That is, since the plasma distribution state can be changed by moving the position of the lower stage LS, by moving the lower stage so that the plasma is most uniformly and stably generated, the in-plane uniformity of the plasma can be obtained. You can improve your sex.
- various gas introduction methods are possible.
- the inner conductor 3b located at the center of the upper electrode 5 it is possible to form a through hole along the Z-axis direction to form a gas introduction path.
- an upper dielectric may be provided on the lower surface of the upper electrode, and the upper dielectric may have a shower structure having a plurality of through holes. Thereby, the in-plane uniformity of gas concentration can be improved.
- a waveguide extending in the horizontal direction that communicates with the waveguide 1w formed of a recess provided in the sidewall of the processing container 1 may be formed in place of the solid dielectric waveguide. it can.
- an insulator block made of a ring-shaped insulator can be arranged between the outer conductor 3a and the inner conductor 3b.
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Abstract
Description
以下、実施の形態に係るプラズマ処理装置について説明する。同一要素には、同一符号を用い、重複する説明は省略する。
・電界のZ軸方向成分:Ez(r,z)=E0・cos(kz)・・・(式3)
なお、(式1)の微分方程式を満たす場合、下部電極の形状は、以下の(式4)又は(式5)の形状となる。a、a0は適当な定数、E0はプラズマ発生空間内で発生する基準の電界である。
・sin(kz)=a・exp(-k2r2/4)・・・(式4)
・z=a0・exp(-k2r2/4)、(k・r<<1の場合)・・・(式5)、なお、rはxに読み替えることができる。
Claims (6)
- 上部電極との間にプラズマを発生させるための下部ステージにおいて、
セラミックスからなる下部誘電体と、
前記下部誘電体内に埋設された下部電極と、
前記下部誘電体内に埋設された発熱体と、
を備え、
前記下部誘電体の中央領域の上部表面と前記下部電極との間の離隔距離dcenterよりも、
前記下部誘電体の外縁位置の上部表面と前記下部電極との間の離隔距離dedgeは小さく、
前記下部電極は、前記外縁位置と前記中央領域との間に、前記上部表面に対して傾斜した傾斜領域を有している、
下部ステージ。 - 請求項1に記載の下部ステージを備えたプラズマ処理装置において、
前記上部電極と前記下部電極との間には、VHF電力が供給される、
ことを特徴とするプラズマ処理装置。 - 前記下部電極の中心における厚み方向の法線の下向き方向をZ軸、このZ軸に垂直なX軸、このZ軸とX軸の双方に垂直なY軸を有する三次元直交座標系を設定し、座標系の原点を前記下部誘電体の上部表面の重心位置とした場合、
前記下部誘電体の比誘電率をεr、
光速をc、
前記VHF電力の周波数をf、
円周率をπ、
前記VHF電力の誘電体中の波数をk(=(εr)0.5・2πf/c)、
とすると、
XZ平面内における前記下部電極の上部表面の位置(x、z)は、以下の方程式:
dx/dz=-2/xk・cot(kz)
を満たすように設定される、
請求項2に記載のプラズマ処理装置。 - 前記セラミックスの材料は、AlNである、
請求項2又は3に記載のプラズマ処理装置。 - VHF電力は、VHF波として処理容器の側方から上部電極と下部ステージとの間の空間内に導入される請求項2~4のいずれか一項に記載のプラズマ処理装置。
- 前記下部ステージは、上下方向に移動できるように駆動される、請求項2~5のいずれか一項に記載のプラズマ処理装置。
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| US17/299,483 US11929234B2 (en) | 2018-12-06 | 2019-11-26 | Plasma processing apparatus and lower stage |
| KR1020217021024A KR102604045B1 (ko) | 2018-12-06 | 2019-11-26 | 플라스마 처리 장치 및 하부 스테이지 |
| JP2020559087A JP7079947B2 (ja) | 2018-12-06 | 2019-11-26 | プラズマ処理装置 |
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| JPH08186094A (ja) * | 1994-12-28 | 1996-07-16 | Sumitomo Metal Ind Ltd | プラズマ処理装置 |
| JPH09503350A (ja) * | 1994-05-13 | 1997-03-31 | アプライド マテリアルズ インコーポレイテッド | 有磁気場励起マルチ容量プラズマ発生装置および関連方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3224011B2 (ja) | 1996-05-23 | 2001-10-29 | シャープ株式会社 | プラズマ励起化学蒸着装置及びプラズマエッチング装置 |
| JP5056029B2 (ja) | 2007-01-26 | 2012-10-24 | 住友電気工業株式会社 | 半導体製造装置用ウェハ保持体、その製造方法およびそれを搭載した半導体製造装置 |
| KR101842675B1 (ko) * | 2009-07-08 | 2018-03-27 | 플라즈마시, 인크. | 플라즈마 처리를 위한 장치 및 방법 |
| JP7208873B2 (ja) * | 2019-08-08 | 2023-01-19 | 東京エレクトロン株式会社 | シャワープレート、下部誘電体、及びプラズマ処理装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09503350A (ja) * | 1994-05-13 | 1997-03-31 | アプライド マテリアルズ インコーポレイテッド | 有磁気場励起マルチ容量プラズマ発生装置および関連方法 |
| JPH08186094A (ja) * | 1994-12-28 | 1996-07-16 | Sumitomo Metal Ind Ltd | プラズマ処理装置 |
| JP2003506889A (ja) * | 1999-08-10 | 2003-02-18 | ユナキス・トレーディング・アクチェンゲゼルシャフト | 面積の大きな基板の処理のためのプラズマ反応装置 |
| JP2001250815A (ja) * | 2000-03-06 | 2001-09-14 | Hitachi Ltd | プラズマ処理装置及びプラズマ処理方法 |
| JP2011519117A (ja) * | 2008-03-20 | 2011-06-30 | アプライド マテリアルズ インコーポレイテッド | プラズマチャンバ内の調整可能接地面 |
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| Publication number | Publication date |
|---|---|
| JPWO2020116247A1 (ja) | 2021-10-28 |
| KR102604045B1 (ko) | 2023-11-21 |
| KR20210091336A (ko) | 2021-07-21 |
| JP7079947B2 (ja) | 2022-06-03 |
| US20220068603A1 (en) | 2022-03-03 |
| US11929234B2 (en) | 2024-03-12 |
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