WO2020093643A1 - System and method for treating black and odorous river channel sewage - Google Patents

System and method for treating black and odorous river channel sewage Download PDF

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WO2020093643A1
WO2020093643A1 PCT/CN2019/078642 CN2019078642W WO2020093643A1 WO 2020093643 A1 WO2020093643 A1 WO 2020093643A1 CN 2019078642 W CN2019078642 W CN 2019078642W WO 2020093643 A1 WO2020093643 A1 WO 2020093643A1
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tank
fermentation
carbon
sludge
black
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PCT/CN2019/078642
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French (fr)
Chinese (zh)
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武涛
王聪
王丽
史鑫
吴迪
许盛凯
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江苏澳洋生态园林股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

Definitions

  • the invention relates to the technical field of sewage treatment, in particular to a black smelly river sewage treatment system and a black smelly sewage treatment method.
  • the "Water Pollution Prevention Action Plan” issued by the State Council sets out clear requirements for the treatment of black and odorous water bodies: By 2020, the black and odorous water bodies in prefecture-level and above urban built-up areas will be controlled within 10%; by 2030, the urban built-up areas The black and odorous water body was eliminated.
  • the main cause of black odor in the water body is that exogenous organic matter and ammonia nitrogen consume oxygen in the water.
  • a large amount of organic matter is further decomposed under the action of anaerobic bacteria, producing hydrogen sulfide, amine, ammonia and other Odor and volatile small molecule compounds, which emit odor; at the same time, under anaerobic conditions, methane, nitrogen and hydrogen sulfide generated in the sediment are insoluble in water and carry sludge into the water during the ascent Phase, making the water body black.
  • CN105923926A uses carbon separation device, biological pool of MBR process and membrane pool of MBR process to treat black and odorous sewage to obtain better treatment effect, but it is difficult to use on a large scale due to its high treatment cost, low efficiency, high equipment cost and other issues, and The use of this method is difficult to effectively and effectively treat sewage in black and smelly rivers.
  • CN107673561B is to set up a diversion wall body in situ in the river channel, and set up a variety of treatment tanks for comprehensive treatment. Although this method can integrate the advantages of multiple treatment processes, setting up the diversion wall in the river channel will affect the river's flood discharge capacity and at the same time. The cost of the project is high and it is difficult to handle it flexibly.
  • the invention overcomes the defects of the black and smelly river sewage treatment in the prior art, and provides a black and smelly river sewage treatment system and method.
  • the sewage in the black and smelly river is extracted into the system through the pipeline, and the black
  • the large volume of impurities in the smelly river sewage is removed, and then passed into the carbon fluidized bed, and the fluid in the carbon fluidized bed is sent to the solid-liquid separation device for solid-liquid separation.
  • the solid after solid-liquid separation is subjected to carbon regeneration, and the liquid is sent.
  • a black and odorous river sewage treatment system including a pretreatment device, a carbon fluidized bed, a solid-liquid separation device, a biological adsorption tank, an aerobic tank, a catalytic oxidation tank, and an outlet pool, which are connected to carbon
  • the regeneration equipment and the carbon regeneration equipment are connected to a carbon fluidized bed.
  • the biological adsorption tank is also connected to a fermentation tank. After adsorption in the biological adsorption tank, the sludge is transported to the fermentation tank for fermentation. After the fermentation is completed, part of the sludge is returned to the biological adsorption tank to continue adsorption Treatment, the supernatant in the biological adsorption tank is sent to the aerobic tank for processing.
  • system is also provided with a carbonization device, and the sludge after fermentation in the fermentation tank is partially transferred to the carbonization device for carbonization;
  • the carbonization equipment is connected to a carbon fluidized bed
  • the sludge in the biological adsorption tank is produced by selecting and enriching indigenous microorganisms in black and smelly river sewage as strains for enrichment cultivation;
  • the aerobic tank is connected to the outflow tank, and part of the sludge in the aerobic tank is transported to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
  • the fermentation tank is connected to the outflow tank, and part of the sludge in the fermentation tank is transferred to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
  • a surfactant is added to the biological adsorption tank, and the surfactant is a biological surfactant, such as rhamnolipid;
  • cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added.
  • the cast iron particles include iron, carbon, copper, and cerium, and the weight ratio is 65-80: 5-25: 5: 0.5;
  • a ferrous source is added to the catalytic oxidation pool
  • the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment to be carbonized with the sludge generated in the fermentation tank;
  • system can be set on a mobile device for maneuvering the black and smelly river course.
  • a black and smelly river sewage treatment method includes the following steps:
  • the carbon separated by the solid-liquid separation equipment is sent to the carbon regeneration equipment, and the supernatant is sent to the biosorption tank, which is filled with sludge produced by the enrichment and cultivation of indigenous microorganisms in the black and smelly river sewage as strains ,
  • the residence time is 20-80min;
  • the fermentation tank is connected to the outflow tank, and part of the sludge in the fermentation tank is transferred to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
  • a surfactant is added to the biological adsorption tank, and the surfactant is a biological surfactant, such as rhamnolipid;
  • cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added.
  • the cast iron particles include iron, carbon, copper, and cerium, and the weight ratio is 65-80: 5-25: 5: 0.5;
  • a ferrous source is added to the catalytic oxidation pool
  • the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment to be carbonized with the sludge generated in the fermentation tank;
  • the present invention is a black and smelly river sewage treatment system and method, which has a simple structure and convenient operation, can quickly and easily reduce the concentration of pollutants in the black and smelly water body, and has a long-lasting and lasting effect on the black and smelly river sewage treatment Compared with the traditional treatment process, the treatment efficiency has the following advantages:
  • the sewage after the adsorption treatment is aerobic and catalytic, so that the water quality can be discharged after reaching the discharge standard;
  • a small amount of sludge is added to the drainage to improve the self-purification ability of the water body, which is an effective method for purifying the black and smelly river sewage.
  • FIG. 1 is a schematic diagram of a black and smelly river sewage treatment system of the present invention
  • a black and smelly river sewage treatment method includes the following steps:
  • a surfactant is added to the biological adsorption tank, the surfactant is a biological surfactant, such as rhamnolipid, cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added, and the cast iron particles include iron and carbon , Copper and cerium, the weight ratio of 70: 15: 5: 0.5, the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment, and the sludge generated in the fermentation tank is carbonized.
  • the surfactant is a biological surfactant, such as rhamnolipid
  • cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added
  • the cast iron particles include iron and carbon , Copper and cerium, the weight ratio of 70: 15: 5: 0.5
  • the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment, and the sludge generated in the fermentation tank is carbonized.
  • COD Water quality of black and smelly sewage in a river: COD is 258mg / L; total phosphorus is 4.18mg / L; ammonia nitrogen is 11.35mg / L; dissolved oxygen is 0.27mg / L; transparency is 10cm; SS (suspended matter) is 214.4mg / L.
  • Fluidized bed treatment COD after adsorption is 158mg / L; total phosphorus 3.58mg / L; ammonia nitrogen 6.35mg / L; transparency 2cm; SS (suspended matter) 65mg / L;
  • COD is 98mg / L after adsorption; total phosphorus 2.18mg / L; ammonia nitrogen 4.13mg / L; transparency is 2cm; SS (suspended matter) is 76mg / L;
  • Aerobic tank COD after aerobic treatment is 78mg / L; total phosphorus 1.38mg / L; ammonia nitrogen 1.65mg / L;
  • Catalytic oxidation tank COD after catalytic oxidation is 34mg / L; total phosphorus 0.67mg / L; ammonia nitrogen 0.73mg / L.

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

Disclosed is a system for treating black and odorous river channel sewage, comprising a pretreatment device, a carbon fluidized bed, a solid-liquid separation apparatus, a biological adsorption tank, an aerobic tank, a catalytic oxidation tank, and an effluent tank, which are arranged successively, wherein the solid-liquid separation apparatus is connected with a carbon regeneration apparatus, the carbon regeneration apparatus is connected with the carbon fluidized bed, and the biological adsorption tank is further connected with a fermentation tank. After being adsorbed in the biological adsorption tank, sludge is transported to the fermentation tank for fermentation, and after fermentation is finished, a portion of the sludge is refluxed to the biological adsorption tank for a further adsorption treatment, and the supernatant in the biological adsorption tank is transported to the aerobic tank for treatment.

Description

一种黑臭河道污水处理系统及方法Black and smelly river sewage treatment system and method 技术领域Technical field
本发明涉及一种污水处理技术领域,尤其涉及黑臭河道污水处理系统与黑臭污水处理方法。The invention relates to the technical field of sewage treatment, in particular to a black smelly river sewage treatment system and a black smelly sewage treatment method.
背景技术Background technique
国务院发布的《水污染防治行动计划》中对黑臭水体治理提出了明确要求:到2020年,我国地级及以上城市建成区黑臭水体均控制在10%以内;到2030年,城市建成区黑臭水体总体得到消除。The "Water Pollution Prevention Action Plan" issued by the State Council sets out clear requirements for the treatment of black and odorous water bodies: By 2020, the black and odorous water bodies in prefecture-level and above urban built-up areas will be controlled within 10%; by 2030, the urban built-up areas The black and odorous water body was eliminated.
水体发生黑臭的主要原因是外源有机物和氨氮消耗水中氧气,当溶解氧下降到一个过低水平时,大量有机物在厌氧菌的作用下进一步分解,产生硫化氢、胺、氨和其他带异味易挥发的小分子化合物,从而散发出臭味;同时,在厌氧条件下,沉积物中产生的甲烷、氮气与硫化氢等难溶于水的气体,在上升过程中携带污泥进入水相,使水体发黑。The main cause of black odor in the water body is that exogenous organic matter and ammonia nitrogen consume oxygen in the water. When the dissolved oxygen drops to a too low level, a large amount of organic matter is further decomposed under the action of anaerobic bacteria, producing hydrogen sulfide, amine, ammonia and other Odor and volatile small molecule compounds, which emit odor; at the same time, under anaerobic conditions, methane, nitrogen and hydrogen sulfide generated in the sediment are insoluble in water and carry sludge into the water during the ascent Phase, making the water body black.
目前常用的治理方法就是人工曝气、底泥疏浚和调水等,但是这些方法存在净化周期长,治理效果差,基本上治标不治本,治理费用比较高,难以长期持续应用。At present, the commonly used treatment methods are artificial aeration, sediment dredging and water transfer. However, these methods have long purification cycles, poor treatment effects, basically no cure for the symptoms, and relatively high treatment costs, which are difficult to apply for a long time.
CN105923926A利用碳分离装置、MBR工艺的生物池与MBR工艺的膜池结合处理黑臭污水得到了较好的处理效果,但由于其处理成本高、效率低、设备造价高等问题难以大规模使用,且该方法的使用难以持久有效的处理黑臭河道中的污水。CN105923926A uses carbon separation device, biological pool of MBR process and membrane pool of MBR process to treat black and odorous sewage to obtain better treatment effect, but it is difficult to use on a large scale due to its high treatment cost, low efficiency, high equipment cost and other issues, and The use of this method is difficult to effectively and effectively treat sewage in black and smelly rivers.
CN107673561B则是在河道原位设置导流墙体,并设置多种处理池进行综合处理,该方法虽然可以综合多种处理工艺的优点,但在河道中设置导流墙会影响河道泄洪能力、同时工程造价高,难以灵活机动处理。CN107673561B is to set up a diversion wall body in situ in the river channel, and set up a variety of treatment tanks for comprehensive treatment. Although this method can integrate the advantages of multiple treatment processes, setting up the diversion wall in the river channel will affect the river's flood discharge capacity and at the same time. The cost of the project is high and it is difficult to handle it flexibly.
发明内容Summary of the invention
本发明克服了现有技术中对黑臭河道污水处理的缺陷,提供一种黑臭河道污水处理系统和方法,将黑臭河道中的污水通过管道抽取至系统中,首先经过预处理装置将黑臭河道污水中的较大体积杂质去除,然后通入碳流化床,将碳流化床内流体送入固液分离设备内进行固液分离,固液分离后的固体进行碳再生,液体送入生物吸附池进行吸附,将生物吸附池中混合液进行固液分离,然后污泥进行厌氧发酵,发酵结束后返回生物吸附池继续吸附,而上清液则通入生化反应池和/或催化氧化池,处理结束后排入所述黑臭河道中。The invention overcomes the defects of the black and smelly river sewage treatment in the prior art, and provides a black and smelly river sewage treatment system and method. The sewage in the black and smelly river is extracted into the system through the pipeline, and the black The large volume of impurities in the smelly river sewage is removed, and then passed into the carbon fluidized bed, and the fluid in the carbon fluidized bed is sent to the solid-liquid separation device for solid-liquid separation. The solid after solid-liquid separation is subjected to carbon regeneration, and the liquid is sent. Into the biological adsorption tank for adsorption, solid-liquid separation of the mixed liquid in the biological adsorption tank, and then anaerobic fermentation of sludge, after the fermentation is completed, return to the biological adsorption tank to continue adsorption, and the supernatant is passed into the biochemical reaction tank and / or The catalytic oxidation pool is discharged into the black and smelly river channel after the treatment.
一种黑臭河道污水处理系统,包括依次设置的预处理装置、碳流化床、固液分离设备、生物吸附池、好氧池、催化氧化池及出水池,所述固液分离设备连接碳再生设备,碳再生设备连接碳流化床,所述生物吸附池还连接有发酵池,生物吸附池内吸附后污泥输送至发酵池发酵,发酵结束后,部分污泥回流至生物吸附池继续吸附处理,生物吸附池内的上清液输送至好氧池处理。A black and odorous river sewage treatment system, including a pretreatment device, a carbon fluidized bed, a solid-liquid separation device, a biological adsorption tank, an aerobic tank, a catalytic oxidation tank, and an outlet pool, which are connected to carbon The regeneration equipment and the carbon regeneration equipment are connected to a carbon fluidized bed. The biological adsorption tank is also connected to a fermentation tank. After adsorption in the biological adsorption tank, the sludge is transported to the fermentation tank for fermentation. After the fermentation is completed, part of the sludge is returned to the biological adsorption tank to continue adsorption Treatment, the supernatant in the biological adsorption tank is sent to the aerobic tank for processing.
进一步地,所述系统中还设置有碳化设备,所述发酵池发酵后的污泥,部分输送至碳化设备中进行碳化;Further, the system is also provided with a carbonization device, and the sludge after fermentation in the fermentation tank is partially transferred to the carbonization device for carbonization;
进一步地,所述碳化设备连接碳流化床;Further, the carbonization equipment is connected to a carbon fluidized bed;
进一步地,所述生物吸附池内污泥是选取黑臭河道污水中土著微生物作为菌种,进行富集培养产生的;Further, the sludge in the biological adsorption tank is produced by selecting and enriching indigenous microorganisms in black and smelly river sewage as strains for enrichment cultivation;
进一步地,所述好氧池连接出水池,好氧池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中;Further, the aerobic tank is connected to the outflow tank, and part of the sludge in the aerobic tank is transported to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
进一步地,所述发酵池连接出水池,发酵池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中;Further, the fermentation tank is connected to the outflow tank, and part of the sludge in the fermentation tank is transferred to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
进一步地,所述生物吸附池内添加表面活性剂,所述表面活性剂为生物表面活性剂,例如鼠李糖脂;Further, a surfactant is added to the biological adsorption tank, and the surfactant is a biological surfactant, such as rhamnolipid;
进一步地,所述催化氧化池中投加铸铁颗粒,并加入双氧水,所述铸铁颗粒包括铁、碳、铜及铈,其重量比65-80:5-25:5:0.5;Further, cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added. The cast iron particles include iron, carbon, copper, and cerium, and the weight ratio is 65-80: 5-25: 5: 0.5;
进一步地,催化氧化池中还添加亚铁源;Further, a ferrous source is added to the catalytic oxidation pool;
进一步地,将催化氧化池内产生的污泥送入碳化设备中,与发酵池内产生的污泥进行碳化处理;Further, the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment to be carbonized with the sludge generated in the fermentation tank;
进一步地,基于废水水质情况,可以省略好氧池、碳化设备、碳再生设备;Further, based on the quality of wastewater, aerobic tanks, carbonization equipment, and carbon regeneration equipment can be omitted;
进一步地,所述系统可设置在移动设备上进行对黑臭河道进行机动处理。Further, the system can be set on a mobile device for maneuvering the black and smelly river course.
一种黑臭河道污水处理方法,包括如下步骤:A black and smelly river sewage treatment method includes the following steps:
1)抽取黑臭河道污水进入预处理装置中,粗格栅过滤掉水体中的大粒径渣体,细格栅进一步除去较小杂质;1) Extract the black and smelly river sewage into the pretreatment device, the coarse grid filters out the large-size slag in the water body, and the fine grid further removes smaller impurities;
2)经过预处理装置过滤后进入碳流化床,污水与其中的碳颗粒充分混均,产生吸附作用,15-60min后,碳流化床内的混合物送入固液分离设备后,碳再生设备和/或碳化设备中的碳送入碳流化床中继续吸附;2) After filtering through the pretreatment device, it enters the carbon fluidized bed. The sewage and the carbon particles in it are fully mixed and homogenized to produce adsorption. After 15-60 minutes, the mixture in the carbon fluidized bed is sent to the solid-liquid separation device, and the carbon is regenerated. The carbon in the equipment and / or carbonization equipment is sent to the carbon fluidized bed to continue adsorption;
3)固液分离设备分离出的碳送入碳再生设备,而上清液则送入生物吸附池中,生物吸附池内填充有黑臭河道污水中土著微生物作为菌种富集培养产生的污泥,停留时间20-80min;3) The carbon separated by the solid-liquid separation equipment is sent to the carbon regeneration equipment, and the supernatant is sent to the biosorption tank, which is filled with sludge produced by the enrichment and cultivation of indigenous microorganisms in the black and smelly river sewage as strains , The residence time is 20-80min;
4)生物吸附池内上清液送入好氧池,剩余污泥则送入发酵池发酵处理,发酵结束后,部分污泥回流至生物吸附池继续吸附处理;4) The supernatant in the biological adsorption tank is sent to the aerobic tank, and the remaining sludge is sent to the fermentation tank for fermentation treatment. After the fermentation, part of the sludge is returned to the biological adsorption tank to continue the adsorption treatment;
5)好氧池内部分污泥回流至生物吸附池,好氧池出水送入催化氧化池中,催化氧化池出水则进入出水池后排放。5) Part of the sludge in the aerobic tank returns to the biological adsorption tank, and the effluent from the aerobic tank is sent to the catalytic oxidation tank, and the effluent from the catalytic oxidation tank enters the outlet tank and is discharged.
进一步地,所述发酵池连接出水池,发酵池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中;Further, the fermentation tank is connected to the outflow tank, and part of the sludge in the fermentation tank is transferred to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank;
进一步地,所述生物吸附池内添加表面活性剂,所述表面活性剂为生物表面活性剂,例如鼠李糖脂;Further, a surfactant is added to the biological adsorption tank, and the surfactant is a biological surfactant, such as rhamnolipid;
进一步地,所述催化氧化池中投加铸铁颗粒,并加入双氧水,所述铸铁颗粒包括铁、碳、铜及铈,其重量比65-80:5-25:5:0.5;Further, cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added. The cast iron particles include iron, carbon, copper, and cerium, and the weight ratio is 65-80: 5-25: 5: 0.5;
进一步地,催化氧化池中还添加亚铁源;Further, a ferrous source is added to the catalytic oxidation pool;
进一步地,将催化氧化池内产生的污泥送入碳化设备中,与发酵池内产生的污泥进行碳化处理;Further, the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment to be carbonized with the sludge generated in the fermentation tank;
由以上方案可见,本发明是一种黑臭河道污水处理系统及方法,其结构简单,运作方便,可以快速、简便降低黑臭水体中污染物浓度,并对黑臭河道污水处理具有长效持久处理效力,与传统处理工艺相比,具有如下优势:It can be seen from the above solutions that the present invention is a black and smelly river sewage treatment system and method, which has a simple structure and convenient operation, can quickly and easily reduce the concentration of pollutants in the black and smelly water body, and has a long-lasting and lasting effect on the black and smelly river sewage treatment Compared with the traditional treatment process, the treatment efficiency has the following advantages:
1、以碳流化床和生物吸附池对黑臭水体进行两级吸附,大部分污染物被吸附处理;1. Carry out two-stage adsorption of black and odorous water by carbon fluidized bed and biological adsorption pool, most of the pollutants are adsorbed;
2、吸附处理后的污水进行好氧、催化处理,使水质达到排放标准后排放;2. The sewage after the adsorption treatment is aerobic and catalytic, so that the water quality can be discharged after reaching the discharge standard;
3、采用黑臭河道污水中土著微生物作为菌源,不会对处理区域带来微生物生态风险;3. The use of indigenous microorganisms in black and smelly river sewage as the source of bacteria will not bring microbial ecological risks to the treatment area;
4、排水中加入少量污泥,提高水体自净能力,是一种黑臭河道污水净化的有效手段。4. A small amount of sludge is added to the drainage to improve the self-purification ability of the water body, which is an effective method for purifying the black and smelly river sewage.
附图说明BRIEF DESCRIPTION
图1为本发明黑臭河道污水处理系统示意图;FIG. 1 is a schematic diagram of a black and smelly river sewage treatment system of the present invention;
具体实施方式detailed description
下面通过实施例对本发明作进一步的详细说明,以令本领域技术人员参照 说明书文字能够据以实施。The present invention will be further described in detail through the following examples, so that those skilled in the art can implement it by referring to the text of the description.
应当理解,本文所使用的诸如“具有”,“包含”以及“包括”术语并不排除一个或多个其它元件或其组合的存在或添加。It should be understood that the terms such as “having”, “including” and “including” used herein do not exclude the presence or addition of one or more other elements or combinations thereof.
实施例1Example 1
一种黑臭河道污水处理方法,包括如下步骤:A black and smelly river sewage treatment method includes the following steps:
1)抽取黑臭河道污水进入预处理装置中,粗格栅过滤掉水体中的大粒径渣体,细格栅进一步除去较小杂质;1) Extract the black and smelly river sewage into the pretreatment device, the coarse grid filters out the large-size slag in the water body, and the fine grid further removes smaller impurities;
2)经过预处理装置过滤后进入碳流化床,污水与其中的碳颗粒充分混均,产生吸附作用,45min后,碳流化床内的混合物送入固液分离设备后,碳再生设备和/或碳化设备中的碳送入碳流化床中继续吸附;2) After filtering through the pretreatment device, it enters the carbon fluidized bed. The sewage and the carbon particles in it are fully mixed and homogenized to produce adsorption. After 45 minutes, the mixture in the carbon fluidized bed is sent to the solid-liquid separation equipment, the carbon regeneration equipment and / Or the carbon in the carbonization equipment is sent to the carbon fluidized bed to continue adsorption;
3)固液分离设备分离出的碳送入碳再生设备,而上清液则送入生物吸附池中,生物吸附池内填充有黑臭河道污水中土著微生物作为菌种富集培养产生的污泥,停留时间60min;3) The carbon separated by the solid-liquid separation equipment is sent to the carbon regeneration equipment, and the supernatant is sent to the biosorption tank, which is filled with sludge produced by the enrichment and cultivation of indigenous microorganisms in the black and smelly river sewage as strains , Residence time 60min;
4)生物吸附池内上清液送入好氧池,剩余污泥则送入发酵池发酵处理,发酵结束后,部分污泥回流至生物吸附池继续吸附处理;4) The supernatant in the biological adsorption tank is sent to the aerobic tank, and the remaining sludge is sent to the fermentation tank for fermentation treatment. After the fermentation, part of the sludge is returned to the biological adsorption tank to continue the adsorption treatment;
5)好氧池内部分污泥回流至生物吸附池,好氧池出水送入催化氧化池中,催化氧化池出水则进入出水池后排放;5) Part of the sludge in the aerobic tank returns to the biological adsorption tank, the aerobic tank effluent is sent to the catalytic oxidation tank, and the catalytic oxidation tank effluent is discharged into the pond;
所述生物吸附池内添加表面活性剂,所述表面活性剂为生物表面活性剂,例如鼠李糖脂,所述催化氧化池中投加铸铁颗粒,并加入双氧水,所述铸铁颗粒包括铁、碳、铜及铈,其重量比70:15:5:0.5,将催化氧化池内产生的污泥送入碳化设备中,与发酵池内产生的污泥进行碳化处理。A surfactant is added to the biological adsorption tank, the surfactant is a biological surfactant, such as rhamnolipid, cast iron particles are added to the catalytic oxidation tank, and hydrogen peroxide is added, and the cast iron particles include iron and carbon , Copper and cerium, the weight ratio of 70: 15: 5: 0.5, the sludge generated in the catalytic oxidation tank is sent to the carbonization equipment, and the sludge generated in the fermentation tank is carbonized.
实施例2Example 2
某河道黑臭污水水质情况:COD为258mg/L;总磷4.18mg/L;氨氮11.35mg/L;溶解氧为0.27mg/L;透明度为10cm;SS(悬浮物)为214.4mg/L。Water quality of black and smelly sewage in a river: COD is 258mg / L; total phosphorus is 4.18mg / L; ammonia nitrogen is 11.35mg / L; dissolved oxygen is 0.27mg / L; transparency is 10cm; SS (suspended matter) is 214.4mg / L.
流化床处理:吸附结束后COD为158mg/L;总磷3.58mg/L;氨氮6.35mg/L;透明度为2cm;SS(悬浮物)为65mg/L;Fluidized bed treatment: COD after adsorption is 158mg / L; total phosphorus 3.58mg / L; ammonia nitrogen 6.35mg / L; transparency 2cm; SS (suspended matter) 65mg / L;
生物吸附池:吸附结束后COD为98mg/L;总磷2.18mg/L;氨氮4.13mg/L;透明度为2cm;SS(悬浮物)为76mg/L;Biological adsorption tank: COD is 98mg / L after adsorption; total phosphorus 2.18mg / L; ammonia nitrogen 4.13mg / L; transparency is 2cm; SS (suspended matter) is 76mg / L;
好氧池:好氧处理后COD为78mg/L;总磷1.38mg/L;氨氮1.65mg/L;Aerobic tank: COD after aerobic treatment is 78mg / L; total phosphorus 1.38mg / L; ammonia nitrogen 1.65mg / L;
催化氧化池:催化氧化后COD为34mg/L;总磷0.67mg/L;氨氮0.73mg/L。Catalytic oxidation tank: COD after catalytic oxidation is 34mg / L; total phosphorus 0.67mg / L; ammonia nitrogen 0.73mg / L.
对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be apparent to those skilled in the art, and the general principles defined herein can be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention will not be limited to the embodiments shown in this document, but should conform to the widest scope consistent with the principles and novel features disclosed in this document.

Claims (10)

  1. 一种黑臭河道污水处理系统,其特征在于:包括依次设置的预处理装置、碳流化床、固液分离设备、生物吸附池、好氧池、催化氧化池及出水池,所述固液分离设备连接碳再生设备,碳再生设备连接碳流化床,所述生物吸附池还连接有发酵池,生物吸附池内吸附后污泥输送至发酵池发酵,发酵结束后,部分污泥回流至生物吸附池继续吸附处理,生物吸附池内的上清液输送至好氧池处理。A black and smelly river sewage treatment system, characterized in that it includes a pretreatment device, a carbon fluidized bed, a solid-liquid separation device, a biological adsorption tank, an aerobic tank, a catalytic oxidation tank and an outlet tank arranged in this order. The separation device is connected to a carbon regeneration device, the carbon regeneration device is connected to a carbon fluidized bed, and the biological adsorption tank is also connected to a fermentation tank. After the adsorption in the biological adsorption tank, the sludge is transported to the fermentation tank for fermentation. After the fermentation is completed, part of the sludge is returned to the biological The adsorption tank continues the adsorption treatment, and the supernatant in the biological adsorption tank is sent to the aerobic tank for treatment.
  2. 如权利要求1所述的系统,其特征在于,所述系统中还设置有碳化设备,所述发酵池发酵后的污泥,部分输送至碳化设备中进行碳化。The system according to claim 1, wherein a carbonization device is further provided in the system, and the sludge after fermentation in the fermentation tank is partially transferred to the carbonization device for carbonization.
  3. 如权利要求2所述的系统,其特征在于,所述碳化设备连接碳流化床。The system of claim 2, wherein the carbonization device is connected to a carbon fluidized bed.
  4. 如权利要求1所述的系统,其特征在于,所述生物吸附池内污泥是选取黑臭河道污水中土著微生物作为菌种,进行富集培养产生的。The system according to claim 1, wherein the sludge in the biological adsorption tank is produced by selecting and enriching indigenous microorganisms in the sewage of the black and odorous river as a bacterial strain.
  5. 如权利要求1所述的系统,其特征在于,所述好氧池连接出水池,好氧池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中;The system according to claim 1, wherein the aerobic tank is connected to the outlet tank, and part of the sludge in the aerobic tank is transported to the outlet tank, and discharged into the black and smelly river channel with the outlet water of the outlet tank;
    优选的,所述系统可设置在移动设备上进行对黑臭河道进行机动处理。Preferably, the system may be set on a mobile device for maneuvering the black and smelly river channel.
  6. 如权利要求1所述的系统,其特征在于,所述发酵池连接出水池,发酵池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中。The system according to claim 1, wherein the fermentation tank is connected to the outlet tank, and part of the sludge in the fermentation tank is transported to the outlet tank, and discharged into the black and odorous river channel with the outlet tank outlet water.
  7. 如权利要求1所述的系统,其特征在于,所述生物吸附池内添加表面活性剂,所述表面活性剂为生物表面活性剂,例如鼠李糖脂。The system according to claim 1, wherein a surfactant is added to the biological adsorption tank, and the surfactant is a biological surfactant, such as rhamnolipid.
  8. 如权利要求1所述的系统,其特征在于,所述催化氧化池中投加铸铁颗粒,并加入双氧水,所述铸铁颗粒包括铁、碳、铜及铈,其重量比65-80:5-25:5:0.5。The system of claim 1, wherein cast iron particles are added to the catalytic oxidation tank and hydrogen peroxide is added, the cast iron particles include iron, carbon, copper and cerium, and the weight ratio is 65-80: 5- 25: 5: 0.5.
  9. 利用权利要求1所述的一种黑臭河道污水处理系统的污水处理方法,Using the sewage treatment method of the black and smelly river sewage treatment system of claim 1,
    包括如下步骤:It includes the following steps:
    1)抽取黑臭河道污水进入预处理装置中,粗格栅过滤掉水体中的大粒径渣体,细格栅进一步除去较小杂质;1) Extract the black and smelly river sewage into the pretreatment device, the coarse grid filters out the large-size slag in the water body, and the fine grid further removes smaller impurities;
    2)经过预处理装置过滤后进入碳流化床,污水与其中的碳颗粒充分混均,产生吸附作用,15-60min后,碳流化床内的混合物送入固液分离设备后,碳再生设备和/或碳化设备中的碳送入碳流化床中继续吸附;2) After filtering through the pretreatment device, it enters the carbon fluidized bed. The sewage and the carbon particles in it are fully mixed and homogenized to produce adsorption. After 15-60 minutes, the mixture in the carbon fluidized bed is sent to the solid-liquid separation device, and the carbon is regenerated. The carbon in the equipment and / or carbonization equipment is sent to the carbon fluidized bed to continue adsorption;
    3)固液分离设备分离出的碳送入碳再生设备,而上清液则送入生物吸附池中,生物吸附池内填充有黑臭河道污水中土著微生物作为菌种富集培养产生的污泥,停留时间20-80min;3) The carbon separated by the solid-liquid separation equipment is sent to the carbon regeneration equipment, and the supernatant is sent to the biosorption tank, which is filled with sludge produced by the enrichment and cultivation of indigenous microorganisms in the black and smelly river sewage as strains , The residence time is 20-80min;
    4)生物吸附池内上清液送入好氧池,剩余污泥则送入发酵池发酵处理,发酵结束后,部分污泥回流至生物吸附池继续吸附处理;4) The supernatant in the biological adsorption tank is sent to the aerobic tank, and the remaining sludge is sent to the fermentation tank for fermentation treatment. After the fermentation, part of the sludge is returned to the biological adsorption tank to continue the adsorption treatment;
    5)好氧池内部分污泥回流至生物吸附池,好氧池出水送入催化氧化池中,催化氧化池出水则进入出水池后排放。5) Part of the sludge in the aerobic tank returns to the biological adsorption tank, and the effluent from the aerobic tank is sent to the catalytic oxidation tank, and the effluent from the catalytic oxidation tank enters the outlet tank and is discharged.
  10. 如权利要求9所述的方法,其特征在于,所述发酵池连接出水池,发酵池内部分污泥输送至出水池,随着出水池出水排放至黑臭河道中。The method according to claim 9, wherein the fermentation tank is connected to the outflow tank, and part of the sludge in the fermentation tank is transported to the outflow tank, and discharged into the black and smelly river channel with the outflow of the outflow tank.
PCT/CN2019/078642 2018-11-06 2019-03-19 System and method for treating black and odorous river channel sewage WO2020093643A1 (en)

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