WO2020067506A1 - 鉄道車輪 - Google Patents
鉄道車輪 Download PDFInfo
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- WO2020067506A1 WO2020067506A1 PCT/JP2019/038360 JP2019038360W WO2020067506A1 WO 2020067506 A1 WO2020067506 A1 WO 2020067506A1 JP 2019038360 W JP2019038360 W JP 2019038360W WO 2020067506 A1 WO2020067506 A1 WO 2020067506A1
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- proeutectoid cementite
- cementite
- railway wheel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60B—VEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
- B60B17/00—Wheels characterised by rail-engaging elements
- B60B17/0006—Construction of wheel bodies, e.g. disc wheels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60B—VEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
- B60B17/00—Wheels characterised by rail-engaging elements
- B60B17/0003—Wheel bodies characterised by use of non-metallic material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/34—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tyres; for rims
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60B—VEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
- B60B2360/00—Materials; Physical forms thereof
- B60B2360/10—Metallic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60B—VEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
- B60B2360/00—Materials; Physical forms thereof
- B60B2360/10—Metallic materials
- B60B2360/102—Steel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/003—Cementite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
Definitions
- the present disclosure relates to railway wheels.
- Rail cars run on the rails that make up the tracks.
- a railway vehicle has a plurality of railway wheels.
- the railway wheel supports the vehicle, contacts the rail, and moves while rotating on the rail.
- Railway wheels are worn by contact with rails.
- an increase in the weight loaded on rail vehicles and an increase in speed of rail vehicles have been promoted.
- improvement in wear resistance of railway wheels is required.
- Patent Document 1 JP-A-9-202937
- Patent Document 2 JP-A-2012-107295
- Patent Document 3 JP-A-2013-231212
- Patent Document 4 Japanese Patent Application Laid-Open No. 2004-315928
- the railway wheel disclosed in Patent Document 1 has, in mass%, C: 0.4 to 0.75%, Si: 0.4 to 0.95%, Mn: 0.6 to 1.2%, and Cr: It contains 0 to less than 0.2%, P: less than 0.03%, and S: 0.03% or less, with the balance being Fe and other unavoidable impurities.
- a region from the surface of the wheel tread portion to at least a depth of 50 mm has a pearlite structure.
- the method for manufacturing a railway wheel disclosed in Patent Document 1 discloses a method in which a cooling curve of a wheel tread portion passes through a pearlite generation region in a continuous cooling transformation curve diagram and is on a longer time side than a martensitic transformation curve. Including a quenching step of cooling.
- the steel for wheels disclosed in Patent Document 2 is, by mass%, C: 0.65 to 0.84%, Si: 0.02 to 1.00%, Mn: 0.50 to 1.90%, Cr : 0.02 to 0.50%, V: 0.02 to 0.20%, S ⁇ 0.04%, P ⁇ 0.05%, Cu ⁇ 0.20%, Ni ⁇ 0.20%
- the balance has a chemical composition of Fe and impurities.
- This chemical composition further satisfies the following relationship: [34 ⁇ 2.7 + 29.5 ⁇ C + 2.9 ⁇ Si + 6.9 ⁇ Mn + 10.8 ⁇ Cr + 30.3 ⁇ Mo + 44.3 ⁇ V ⁇ 43] and [0.76 ⁇ exp (0.05 ⁇ C) ⁇ exp ( 1.35 ⁇ Si) ⁇ exp (0.38 ⁇ Mn) ⁇ exp (0.77 ⁇ Cr) ⁇ exp (3.0 ⁇ Mo) ⁇ exp (4.6 ⁇ V) ⁇ 25].
- Patent Document 2 describes that this vehicle steel is excellent in wear resistance, rolling contact fatigue resistance, and spoke ring resistance by satisfying the above chemical composition and the above formula.
- the steel for wheels disclosed in Patent Document 3 is, by mass%, C: 0.65 to 0.84%, Si: 0.4 to 1.0%, Mn: 0.50 to 1.40%, Cr : 0.02 to 0.13%, S: 0.04% or less, V: 0.02 to 0.12%, and Fn1 defined by the formula (1) is 32 to 43; Fn2 represented by (2) is 25 or less, and the balance consists of Fe and impurities.
- Patent Document 3 describes that this wheel steel has the above chemical composition, and that Fn1 and Fn2 satisfy the above ranges, thereby exhibiting excellent wear resistance, rolling contact fatigue resistance, and spoke ring resistance. I have.
- the railway vehicle wheel disclosed in Patent Document 4 has, in mass%, C: 0.85 to 1.20%, Si: 0.10 to 2.00%, Mn: 0.05 to 2.00%, If necessary, one or more of Cr, Mo, V, Nb, B, Co, Cu, Ni, Ti, Mg, Ca, Al, Zr, and N are contained in a predetermined amount, and the balance is Fe and An integrated railway vehicle wheel made of steel containing a chemical component consisting of other unavoidable impurities, wherein at least a part of a tread surface and / or a flange surface of the wheel has a pearlite structure.
- the life of the railcar wheel depends on the amount of wear on the tread surface and the flange surface (paragraph [0002] of Patent Literature 4). It is described that it depends on thermal cracks on the tread and flange surfaces that occur as soon as possible. And it is described that the wear resistance and the thermal crack of a tread surface and a flange surface can be suppressed because the railcar wheel has the above configuration.
- the railway wheel proposed in Patent Document 1 has an appropriate hardenability and a property of obtaining a pearlite structure, so that the Cr content is kept low and an appropriate amount of Si is contained.
- the C content of the railway wheel described in Patent Document 1 is 0.4 to 0.75%, and this wheel is made of so-called hypoeutectoid steel. Therefore, there is a limit in improving the wear resistance.
- an example of a method of manufacturing a railway wheel is as follows.
- the steel slab is hot worked to form a railway wheel shaped intermediate product.
- Heat treatment (tread quenching) is performed on the formed intermediate product.
- the tread surface and the flange portion of the intermediate product are rapidly cooled.
- fine pearlite having high wear resistance is generated in the matrix structure of the surface layer portion of the tread.
- a hardened layer made of martensite or made of martensite and bainite
- the quenched layer is subject to wear. Therefore, after the tread quenching, the quenched layer formed on the outermost layer of the tread is removed by cutting to expose the fine pearlite to the tread.
- railway vehicle wheels made of hypereutectoid steel have excellent wear resistance.
- the proeutectoid cementite is formed in the railway wheel, for example, in a plate portion and / or a boss portion of the railway wheel. Is easily generated.
- Proeutectoid cementite reduces the toughness of the steel.
- the thickness of the plate portion is smaller than that of the boss portion and the rim portion. Therefore, a decrease in toughness due to pro-eutectoid cementite may lead to breakage of the wheel, particularly in the plate portion.
- An object of the present disclosure is to provide a railway wheel having excellent toughness even when the C content is as high as 0.80% or more.
- the railway wheel according to the present disclosure Rim part, Boss part, A plate portion disposed between the rim portion and the boss portion and connected to the rim portion and the boss portion;
- the chemical composition of the railway wheel is, in mass%, C: 0.80 to 1.60%, Si: 1.00% or less, Mn: 0.10-1.25%, P: 0.050% or less, S: 0.030% or less, Al: 0.010 to 0.650%, N: 0.0030 to 0.0200%, Cr: 0 to 0.60%, V: 0 to 0.12%, and
- the balance consists of Fe and impurities
- the area ratio of pearlite is 85.0% or more
- the area ratio of proeutectoid cementite is 0.90 to 15.00%
- the defined average value of the width W of the proeutectoid cementite is 0.95 ⁇ m or less.
- a in the formula (1) is an area ( ⁇ m 2 ) of the pro-eutectoid cementite, and P is an outer peripheral length ( ⁇ m) of the pro-eutectoid cementite.
- the railway wheel according to the present disclosure Rim part, Boss part, A plate portion disposed between the rim portion and the boss portion and connected to the rim portion and the boss portion;
- the chemical composition of the railway wheel is, in mass%, C: 0.80 to 1.60%, Si: 1.00% or less, Mn: 0.10-1.25%, P: 0.050% or less, S: 0.030% or less, Al: 0.010 to 0.650%, N: 0.0030 to 0.0200%, Cr: 0 to 0.60%, V: 0 to 0.12%, and
- the balance consists of Fe and impurities
- the area ratio of pearlite is 85.0% or more
- the area ratio of proeutectoid cementite is 0.90 to 15.00%
- the maximum width of the proeutectoid cementite is Is 1.80 ⁇ m or less.
- the railway wheel according to the present disclosure has excellent toughness even when the C content is as high as 0.80% or more.
- FIG. 1 is a sectional view parallel to the central axis of the railway wheel.
- FIG. 2 is a diagram showing a heat pattern in a heat treatment simulating tread quenching.
- FIG. 3 is a diagram showing a heat pattern in a heat treatment simulating tread quenching, which is different from FIG.
- FIG. 4 is an image diagram showing the relationship between the isothermal transformation diagram of the steel having the chemical composition shown in Table 1 and the heat patterns of FIGS. 2 and 3.
- FIG. 5 is a schematic diagram for explaining measurement positions in the Vickers hardness test.
- FIG. 6 is a microstructure photograph image of Test No. 5 (0.90% C material) obtained by microstructure observation.
- FIG. 7 is a microstructure photograph image of Test No. 8 (1.00% C material) obtained by microstructure observation.
- FIG. 6 is a microstructure photograph image of Test No. 5 (0.90% C material) obtained by microstructure observation.
- FIG. 7 is a microstructure photograph image of Test No. 8 (1.00% C material)
- FIG. 8 shows the Vickers hardness (HV), the Charpy impact value (J / cm 2 ), and the presence or absence of proeutectoid cementite in hypereutectoid steel materials (0.90% C material and 1.00% C material).
- FIG. 9 is a microstructure photograph image of Test No. 5 (0.90% C material) in Table 2 obtained by SEM.
- FIG. 10 is a microstructure photograph image of Test No. 8 (1.00% C material) in Table 2 obtained by SEM.
- FIG. 11 is a diagram showing the relationship between the proeutectoid cementite width and the Charpy impact value of Test Nos. 1, 2, 4, 5, 7, and 8 in Table 2.
- FIG. 12 is a diagram in which binarization processing is performed on the microstructure photograph image shown in FIG. 9 to identify proeutectoid cementite.
- FIG. 13 is a diagram in which a skeleton line obtained by performing a thinning process on the proeutectoid cementite of FIG. 12 is superimposed and displayed on the proeutectoid cementite.
- FIG. 14 is a schematic diagram in which a part of the binarized pro-eutectoid cementite and the skeleton line 60 of the pro-eutectoid cementite are enlarged.
- FIG. 15 is a diagram showing an optical microscope photograph image and an image after binarization processing.
- FIG. 16 is a diagram illustrating an example of a cooling device for cooling an intermediate product.
- FIG. 17 is a diagram showing a heat pattern in a heat treatment simulating tread quenching adopted in the example.
- FIG. 1 is a cross-sectional view including the central axis of the railway wheel according to the present embodiment.
- a railway wheel 1 has a disk shape and includes a boss 2, a plate 3, and a rim 4.
- the boss 2 has a cylindrical shape and is arranged at the center of the railway wheel 1 in the radial direction of the railway wheel 1 (the direction perpendicular to the center axis).
- the boss 2 has a through hole 21.
- the central axis of the through-hole 21 coincides with the central axis of the railway wheel 1.
- a rail axle (not shown) is inserted into the through hole 21.
- the thickness T2 of the boss 2 is greater than the thickness T3 of the plate 3.
- the rim portion 4 is formed at an outer peripheral edge of the railway wheel 1.
- the rim 4 includes a tread 41 and a flange 42.
- the tread 41 is connected to the flange 42.
- the thickness T4 of the rim portion 4 is larger than the thickness T3 of the plate portion 3.
- the plate 3 is disposed between the boss 2 and the rim 4 and is connected to the boss 2 and the rim 4. More specifically, the inner peripheral edge of the plate 3 is connected to the boss 2, and the outer peripheral edge of the plate 3 is connected to the rim 4.
- the thickness T3 of the plate portion 3 is smaller than the thickness T2 of the boss portion 2 and the thickness T4 of the rim portion 4.
- the diameter of the railway wheel 1 is not particularly limited, but is, for example, 700 mm to 1000 mm.
- the present inventors first studied a chemical composition suitable for enhancing wear resistance of a railway wheel. As a result, in a railway wheel, even if the same hardness is obtained, it is better to increase the C content to 0.80% or more and to increase the hardness than to increase the hardness by increasing the V content. It was found that the wear resistance when used as a railway wheel was increased. Although this mechanism is not clear, the following items can be considered.
- the tread of the railway wheel in use receives an external force (load) from the rail.
- the cementite in the pearlite of the surface layer immediately below the tread is crushed by this external force, and the hardness is increased by dispersion strengthening. Further, the carbon in the crushed fine cementite is supersaturated with ferrite in pearlite to form a solid solution, and the hardness of the surface layer immediately below the tread is increased by solid solution strengthening.
- the above-described mechanism increases the wear resistance of the railway wheel.
- V is contained in steel
- the hardness of the steel is increased by precipitation strengthening of V carbonitride.
- V carbonitride is generated in the ferrite, it mainly increases the hardness of the ferrite. That is, although the content of V increases the hardness of ferrite, it does not significantly affect the refinement of pearlite. Therefore, although the wear resistance can be increased to some extent by containing V, the wear resistance cannot be increased as much as the dispersion strengthening by crushed cementite and the solid solution strengthening of C.
- the present inventors considered that it is preferable to use hypereutectoid steel having a C content of 0.80 to 1.60% in the chemical composition of the railway wheel in order to enhance the wear resistance.
- pro-eutectoid cementite is easily generated in railway wheels made of hypereutectoid steel having a C content of 0.80% or more. Proeutectoid cementite reduces the toughness of railway wheels.
- the present inventors have studied a method of increasing toughness in a railway wheel made of hypereutectoid steel having a high C content.
- the present inventors studied to increase the toughness of a railway wheel made of hypereutectoid steel by suppressing the formation of proeutectoid cementite.
- it has been found that it is very difficult to completely suppress the generation of proeutectoid cementite in the case of a railway wheel made of hypereutectoid steel having a high C content.
- the present inventors do not increase the toughness of railway wheels made of hypereutectoid steel by suppressing the formation of proeutectoid cementite, but on the assumption that proeutectoid cementite is formed, the form of proeutectoid cementite It was thought that the toughness of railway wheels made of hypereutectoid steel could be improved by controlling the temperature. Therefore, the present inventors further studied the relationship between the form of proeutectoid cementite generated in a railway wheel made of hypereutectoid steel and the toughness of the railway wheel.
- the shape of the steel material was a round bar having a diameter of 20 mm and a length of 125 mm. Heat treatment of the heat pattern shown in FIGS. 2 and 3 was performed among the steel materials to change the form of proeutectoid cementite generated in the steel materials TP1 and TP2.
- the heat patterns shown in FIGS. 2 and 3 indicate the temperature of the atmosphere of the heat treatment. That is, it indicates the temperature of the atmosphere in which the steel material is placed during the heat treatment.
- the heat pattern HP1 in FIG. 2 is a heat pattern in which the residence time of the steel materials TP1 and TP2 in the production temperature range of proeutectoid cementite (720 ° C.) is increased in the steel materials TP1 and TP2.
- the heat pattern HP2 in FIG. 3 the residence time of the steel material TP2 (1.00% C material) in the temperature range for the formation of proeutectoid cementite by quenching is shortened, or the steel material TP1 (0. In the case of (90% C material), the heat pattern does not pass through the temperature range for the formation of proeutectoid cementite.
- FIG. 4 is an image diagram showing the relationship between the isothermal transformation diagrams of the steel materials TP1 and TP2 and the heat patterns HP1 and HP2 in FIGS. 2 and 3.
- FIG. 4 shows proeutectoid cementite nose and pearlite nose in the chemical composition of steel materials TP1 and TP2.
- the position of the pearlite nose is substantially the same between the steel TP1 (0.90% C material) and the steel TP2 (1.00% C material).
- the proeutectoid cementite nose the steel material TP2 (1.00% C material, broken line in FIG. 4) is shifted to the left from the steel material TP1 (0.90% C material: solid line in FIG. 4). .
- the cooling liquid is sprayed on the treads 41 shown in FIG. 1 to cool the railway wheels 1 while performing the quenching.
- the thickness T2 of the boss 2 is greater than the thickness T3 of the plate 3, and the boss 2 is far from the rim 4 with which the coolant contacts. Therefore, in the tread quenching, the cooling speed of the boss portion 2 is lower than the cooling speed of the plate portion 3. Therefore, as shown in FIG. 2, in the heat pattern HP1, heat patterns HP11 and HP12 assuming the cooling speed in the boss portion 2 and heat patterns HP13 and HP14 assuming the cooling speed in the plate portion 3 are prepared. Similarly, as shown in FIG. 3, in the heat pattern HP2, a heat pattern HP21 assuming a cooling speed in the boss portion 2 and a heat pattern HP22 assuming a cooling speed in the plate portion 3 were prepared.
- the heat patterns HP11 and HP12 assuming the cooling rate at the boss portion have different holding times at 720 ° C. Specifically, in the heat pattern HP11, the holding time at 720 ° C. was 47 minutes, and in the heat pattern HP12, the holding time at 720 ° C. was 17 minutes. In other words, it was assumed that the amount of pro-eutectoid cementite generated in the steel material heat-treated in the heat pattern HP11 was larger than the amount of pro-eutectoid cementite generated in the steel material heat-treated in the heat pattern HP12. Similarly, in FIG. 2, in the heat patterns HP13 and HP14 assuming the cooling rate in the plate portion 3, the holding time at 720 ° C. is different.
- the holding time at 720 ° C. was 47 minutes
- the holding time at 720 ° C. was 17 minutes. That is, it was assumed that the amount of pro-eutectoid cementite generated in the steel material heat-treated in the heat pattern HP13 was larger than the amount of pro-eutectoid cementite generated in the steel material heat-treated in the heat pattern HP14.
- a plurality of steel materials TP1 were prepared, and a plurality of steel materials TP2 were prepared. Each steel material was subjected to a heat treatment using heat patterns HP11 to HP14, HP21 and HP22 simulating tread quenching. Specifically, test materials of Test Nos. 1 to 8 shown in Table 2 were produced by combining steel materials TP1 and TP2 and heat patterns HP11 to HP14, HP21 and HP22.
- the Vickers hardness of the steel materials of Test Nos. 1 to 8 after the heat treatment was determined. Specifically, as shown in FIG. 5, in a cross section perpendicular to the longitudinal direction (Longitudinal-direction) of the steel material 100 of each test number, a center point P1 of the steel material 100 and a circle having a radius of 1 mm centered on the point P1 are shown.
- the Vickers hardness (HV) was measured in accordance with JIS Z 2244 (2009) at five points P2 to P5 at a 90 ° pitch position. The test force at this time was 9.8 N (1.0 kgf). The average value of the obtained Vickers hardness was defined as the Vickers hardness (HV) of the test number.
- U-notch test pieces in accordance with JIS Z 2242 (2005) were collected from the center position in the cross section perpendicular to the longitudinal direction of the steel material of each test number.
- the cross section perpendicular to the longitudinal direction of the U notch test piece was a square of 10 mm ⁇ 10 mm, and the length of the U notch test piece in the longitudinal direction was 55 mm.
- the longitudinal direction of the U-notch test piece was parallel to the longitudinal direction of the steel material.
- a U-notch was formed at the center of the length of the U-notch test piece (that is, at the center of a length of 55 mm).
- the notch depth was 2 mm, and the notch bottom radius was 1 mm.
- a Charpy impact test in a room temperature atmosphere was performed.
- the Charpy impact value (J / cm 2 ) was determined for each of the four U-notch test pieces for each test number, and the average value was defined as the Charpy impact value (J / cm 2 ) for that test number.
- the microstructure of the steel material of each test number after the heat treatment was observed, and the presence or absence of proeutectoid cementite was investigated.
- a sample for microstructure observation was collected from the center position of the cross section perpendicular to the longitudinal direction of the steel material of each test number after the heat treatment.
- a cross section perpendicular to the longitudinal direction of the steel material was defined as an observation surface.
- the observation surface of each sample was mirror-finished by mechanical polishing. Thereafter, the observation surface was etched using a sodium picrate solution (100 ml of water + 2 g of picric acid + 25 g of sodium hydroxide), which is a corrosive solution suitable for the appearance of proeutectoid cementite.
- the sample was immersed in a boiled sodium picrate solution.
- a photographic image was generated using a 500-fold optical microscope for an arbitrary field of view (200 ⁇ m ⁇ 200 ⁇ m) in the observation surface of the sample after etching.
- the proeutectoid cementite formed at the former austenite grain boundary exhibits a black color. Therefore, the presence or absence of proeutectoid cementite could be confirmed.
- FIG. 6 is a microstructure photograph image of Test No. 5 (0.90% C material) obtained by the above microstructure observation.
- FIG. 7 is a microstructure photograph image of Test No. 8 (1.00% C material) obtained by the above microstructure observation. Referring to FIGS. 6 and 7, black regions (regions indicated by black arrows) in these photographic images are proeutectoid cementite.
- the area ratio of proeutectoid cementite confirmed in the above visual field was determined. Specifically, the area of proeutectoid cementite in the visual field (200 ⁇ m ⁇ 200 ⁇ m) was determined. The ratio of the area of the obtained proeutectoid cementite to the total area of the visual field was defined as the proeutectoid cementite area ratio (%).
- FIG. 8 shows the Vickers hardness (HV), the Charpy impact value (J / cm 2 ), and the presence or absence of proeutectoid cementite in hypereutectoid steel materials (0.90% C material and 1.00% C material).
- FIG. 8 in Test Nos. 1, 2, 4, and 5 in which heat pattern HP1 was applied using steel material TP1 (0.90% C material), proeutectoid cementite was present in the microstructure. Therefore, the Charpy impact value was 8.5 J / cm 2 or less.
- Test No. 1 Heat Pattern HP11
- Test No. 2 Heat Pattern HP12
- Test No. 1 was higher than that of Test No. 1. .
- the Charpy impact values for Test Nos. 1 and 2 were comparable.
- Test No. 4 Heating Pattern HP13
- Test No. 5 Heat Pattern HP14
- Test No. 5 having a shorter holding time at 720 ° C. has a higher Vickers hardness than Test No. 4.
- the Charpy impact values of Test Nos. 4 and 5 were equivalent.
- Test Nos. 3 and 6 using the steel material TP1 and applying the heat pattern HP2 (HP21 and HP22) no proeutectoid cementite was present in the microstructure. Therefore, the Charpy impact value was as high as 14 J / cm 2 or more.
- Test Nos. 7 and 8 to which the heat pattern HP2 (HP21 and HP22) was applied using the steel material TP2 (1.00% C material), as in Test Nos. 1, 2, 4 and 5, the microstructure was the first. Precipitated cementite was present. However, despite the presence of pro-eutectoid cementite, the Charpy impact values of Test Nos. 7 and 8 were significantly higher than those of Test Nos. 1, 2, 4, and 5, which also had pro-eutectoid cementite, and were 14 J / It exceeded cm 2. In particular, when Test No. 2 and Test No. 7 were compared, the Charpy impact values were greatly different although the Vickers hardnesses of both were almost the same. Similarly, when Test No. 5 and Test No. 8 were compared, the Charpy impact values were greatly different although the Vickers hardnesses of both were almost the same.
- FIG. 9 is a microstructure photograph image of Test No. 5 obtained by SEM.
- FIG. 10 is a microstructure photograph image of Test No. 8 obtained by SEM.
- a region surrounded by a white line is proeutectoid cementite (reference numeral 50).
- the morphology of pro-eutectoid cementite generated in Test No. 8 having a high Charpy impact value is remarkably different from the morphology of pro-eutectoid cementite generated in Test No. 5 having a low Charpy impact value.
- the proeutectoid cementite of Test No. 8 was formed such that the width of the proeutectoid cementite was narrower overall than the proeutectoid cementite of Test No. 5.
- the present inventors thought that even if proeutectoid cementite was formed on the plate portion 3 of the railway wheel 1, if the width of the generated proeutectoid cementite was narrow, it was possible to suppress a decrease in toughness.
- the present inventors paid attention to the width of pro-eutectoid cementite in the microstructure photograph image.
- the present inventors have defined the following two indices for the width of proeutectoid cementite.
- (B) Regulation using the maximum width of proeutectoid cementite as an index The average value of the width of proeutectoid cementite in the above (A) is described in Non-Patent Document 1. It can be obtained based on the described rectangle-like method (ribbon-like method).
- the maximum width of the proeutectoid cementite in the above (B) can be determined by performing a thinning process which is one of the image processing methods.
- the average value of the width W of the proeutectoid cementite is determined by the rectangular approximation method described in Non-Patent Document 1. Specifically, it is determined by the following method.
- the above microstructure photographic image (200 ⁇ m ⁇ 200 ⁇ m) obtained by the above 500 ⁇ optical microscope is binarized by image processing to specify proeutectoid cementite.
- the area A of the specified pro-eutectoid cementite is determined.
- the outer peripheral length P (outer peripheral length) of the specified proeutectoid cementite is determined.
- the proeutectoid cementite is a rectangle having an area A and an outer peripheral length P. Then, assuming that the cementite is rectangular, the long side of the rectangle is regarded as the length L of the proeutectoid cementite, and the short side of the rectangle is regarded as the width W of the proeutectoid cementite. That is, the proeutectoid cementite is regarded as a rectangle satisfying the following equations (a) and (b).
- A L ⁇ W (a)
- P 2 ⁇ (L + W) (b)
- the width W of the proeutectoid cementite can be defined by the following expression (1) based on the expressions (a) and (b).
- W 1/2 ⁇ (P / 2 ⁇ ((P / 2) 2 ⁇ 4A) 1/2 ) (1)
- the width W of each proeutectoid cementite can be determined from the area A and the peripheral length P of each proeutectoid cementite specified in the observation visual field. Then, using the width W of each proeutectoid cementite, the average value of the width W of the proeutectoid cementite can be obtained.
- each pro-eutectoid cementite specified in the observation visual field was subjected to the method described above.
- the area A and the peripheral length P were determined.
- the average value of the area A of the specified proeutectoid cementite was determined, and the average value of the outer peripheral length P was determined.
- a pro-eutectoid cementite width W defined by the equation (1) was obtained.
- the obtained proeutectoid cementite width W was defined as the average value ( ⁇ m) of the proeutectoid cementite width W for the test number. Then, a relationship between the obtained average value of the proeutectoid cementite width W and the Charpy impact value was obtained.
- FIG. 11 is a diagram showing the relationship between the average value of the proeutectoid cementite width W of Test Nos. 1, 2, 4, 5, 7, and 8, and the Charpy impact value.
- the Charpy impact value is 8.5 J / cm. 2 or less.
- the Charpy impact value exceeds 8.5 J / cm 2 , and the pro-eutectoid cementite width W is further reduced.
- the present inventors have found that in a railway wheel made of hypereutectoid steel, by controlling the form of proeutectoid cementite, specifically, the proeutectoid cementite width defined by the formula (1) is obtained.
- the average value of W 0.95 ⁇ m or less, it was found that the Charpy impact value was more than 8.5 J / cm 2 and excellent toughness was obtained despite the presence of proeutectoid cementite.
- FIG. 12 is a diagram in which binarization processing is performed on the microstructure photograph image shown in FIG. 9 to specify proeutectoid cementite.
- the proeutectoid cementite 50 can be easily specified.
- the proeutectoid cementite 50 in the microstructure is black, and the region other than the proeutectoid cementite (pearlite region) is white.
- the specified pro-eutectoid cementite 50 is subjected to a thinning process.
- the thinning process is a process of converting a binarized image (proeutectoid cementite 50) into a line image having a width of one pixel (one pixel), and is a well-known image processing method.
- a line image obtained by the thinning processing is referred to as a “skeleton line”.
- FIG. 13 is a diagram in which a skeleton line 60 obtained by performing a thinning process on the proeutectoid cementite 50 of FIG.
- FIG. 14 is a schematic diagram in which a part of the binarized pro-eutectoid cementite 50 and the skeleton line 60 of the pro-eutectoid cementite 50 are enlarged.
- a straight line is drawn perpendicular to skeleton line 60 at an arbitrary measurement point P of skeleton line 60.
- a line segment L between two intersections with the contour of the proeutectoid cementite 50 is defined as the width of the proeutectoid cementite at the measurement point P.
- a straight line perpendicular to the skeleton line 60 is drawn at the measurement point P ⁇ b> 1 of the skeleton line 60, and the straight line between the intersections of the two points with the contour of the proeutectoid cementite 50 is drawn.
- the length of the line segment L1 is defined as the width of the proeutectoid cementite 50 at the measurement point P1.
- the length of a line segment L2 perpendicular to the skeleton line 60 at the measurement point P2 is defined as the width of the proeutectoid cementite 50 at the measurement point P2.
- a branch point BP where the skeleton line 60 branches may occur.
- the skeleton line 60 in the reference circle Cref having a diameter of 1.5 ⁇ m and centered on the branch point BP is excluded from the measurement of the width of the proeutectoid cementite.
- the length of the line segment L is also excluded from the measurement of the width of the proeutectoid cementite 50.
- the line segment L3 of the measurement point P3 outside the reference circle Cref intersects with the point P4 on the skeleton line 60 in addition to the measurement point P3. That is, the line segment L3 intersects the skeleton line 60 at least twice. In this case, the line segment L3 is excluded from the measurement of the width of the proeutectoid cementite 50.
- the maximum width of the proeutectoid cementite measured in each visual field is defined as the maximum width ( ⁇ m) of the proeutectoid cementite.
- the present inventors measured the maximum width of proeutectoid cementite by the above method. As a result, it has been found that if the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less, the Charpy impact value exceeds 8.5 J / cm 2 and excellent toughness can be obtained.
- the railway wheel of the present embodiment completed based on the above knowledge has the following configuration.
- the chemical composition of the railway wheel is, in mass%, C: 0.80 to 1.60%, Si: 1.00% or less, Mn: 0.10-1.25%, P: 0.050% or less, S: 0.030% or less, Al: 0.010 to 0.650%, N: 0.0030 to 0.0200%, Cr: 0 to 0.60%, V: 0 to 0.12%, and
- the balance consists of Fe and impurities
- the area ratio of pearlite is 85.0% or more
- the area ratio of proeutectoid cementite is 0.90 to 15.00%
- the defined average value of the width W of the proeutectoid cementite is 0.95 ⁇ m or less.
- a in the formula (1) is an area ( ⁇ m 2 ) of the pro-eutectoid cementite, and P is an outer peripheral length ( ⁇ m) of the pro-eutectoid cementite.
- the chemical composition of the railway wheel is, in mass%, C: 0.80 to 1.60%, Si: 1.00% or less, Mn: 0.10-1.25%, P: 0.050% or less, S: 0.030% or less, Al: 0.010 to 0.650%, N: 0.0030 to 0.0200%, Cr: 0 to 0.60%, V: 0 to 0.12%, and
- the balance consists of Fe and impurities
- the area ratio of pearlite is 85.0% or more
- the area ratio of proeutectoid cementite is 0.90 to 15.00%
- the maximum width of the proeutectoid cementite is Is 1.80 ⁇ m or less.
- the railway wheel of [4] is the railway wheel of [3], In the microstructure of the boss portion of the railway wheel, the area ratio of pearlite is 85.0% or more, and the area ratio of the proeutectoid cementite is 0.90 to 15.00%. The large value is 1.80 ⁇ m or less.
- the railway wheel 1 of the present embodiment includes a boss 2, a plate 3, and a rim 4.
- the chemical composition of the railway wheel 1 of the present embodiment contains the following elements.
- C 0.80 to 1.60% Carbon (C) increases the hardness of the steel and increases the wear resistance of the railway wheel 1. If the C content is less than 0.80%, this effect cannot be obtained even if other element contents are within the range of the present embodiment. On the other hand, if the C content exceeds 1.60%, even if other element contents are within the range of the present embodiment, an excessively large amount of pro-eutectoid cementite precipitates at the prior austenite grain boundary, and The area ratio exceeds 15.00%. In this case, the toughness of the railway wheel 1 decreases. Therefore, the C content is 0.80 to 1.60%. A preferred lower limit of the C content is 0.85%, more preferably 0.87%, further preferably 0.90%, and still more preferably 0.95%. A preferred upper limit of the C content is 1.55%, more preferably 1.45%, further preferably 1.30%, more preferably 1.15%, and still more preferably 1.05%. %.
- Si 1.00% or less Silicon (Si) is inevitably contained. That is, the Si content is more than 0%. Si enhances the hardness of steel by solid solution strengthening ferrite. However, if the Si content exceeds 1.00%, proeutectoid cementite is likely to be generated even if the content of other elements is within the range of the present embodiment. If the Si content exceeds 1.00%, the hardenability of the steel becomes too high, and martensite is easily formed. In this case, the thickness of the quenched layer formed on the tread during quenching of the tread increases. As a result, the cutting amount increases and the yield decreases.
- the Si content is 1.00% or less.
- the preferable upper limit of the Si content is 0.90%, more preferably 0.80%, further preferably 0.70%, and further preferably 0.50%.
- the lower limit of the Si content is not particularly limited. However, excessive reduction of the Si content increases manufacturing costs. Therefore, a preferable lower limit of the Si content is 0.01%, and more preferably 0.05%. From the viewpoint of increasing the hardness of the steel, the lower limit of the Si content is more preferably 0.10%, and still more preferably 0.15%.
- Mn 0.10-1.25%
- Mn increases the hardness of steel by solid solution strengthening ferrite. Mn further forms MnS and improves the machinability of the steel. If the Mn content is less than 0.10%, these effects cannot be obtained even if other element contents are within the range of the present embodiment. On the other hand, if the Mn content exceeds 1.25%, the hardenability of the steel becomes too high even if the content of other elements is within the range of the present embodiment. In this case, the thickness of the quenched layer increases, and the yield in the manufacturing process decreases. Further, when the railway wheel 1 is used, the rim portion 4 is burned by frictional heat generated between the rim portion 4 and the brake. In this case, the crack resistance of the steel may decrease.
- the Mn content is 0.10 to 1.25%.
- a preferred lower limit of the Mn content is 0.50%, more preferably 0.60%, and further preferably 0.70%.
- a preferred upper limit of the Mn content is 1.10%, more preferably 1.00%, further preferably 0.95%, and still more preferably 0.90%.
- P 0.050% or less Phosphorus (P) is an unavoidable impurity. That is, the P content is more than 0%. P segregates at the grain boundaries and lowers the toughness of the steel. Therefore, the P content is 0.050% or less.
- the preferable upper limit of the P content is 0.030%, and more preferably 0.020%.
- the P content is preferably as low as possible. However, excessive reduction of the P content increases manufacturing costs. Therefore, in consideration of ordinary industrial production, a preferable lower limit of the P content is 0.001%, more preferably 0.002%.
- S 0.030% or less Sulfur (S) is inevitably contained. That is, the S content is more than 0%. S forms MnS and enhances machinability of steel. On the other hand, if the S content is too high, the toughness of the steel decreases. Therefore, the S content is 0.030% or less. A preferred upper limit of the S content is 0.020%. Excessive reduction of the S content increases manufacturing costs. Therefore, a preferable lower limit of the S content is 0.001%, more preferably 0.002%, and a further preferable lower limit is 0.005%.
- Al 0.010 to 0.650%
- Aluminum (Al) deoxidizes steel. Al further suppresses the formation of proeutectoid cementite and increases the toughness of the steel. Al further combines with N to form AlN and refines crystal grains. Refining the crystal grains increases the toughness of the steel. If the Al content is less than 0.010%, these effects cannot be sufficiently obtained even if other element contents are within the range of the present embodiment. On the other hand, if the Al content exceeds 0.650%, the nonmetallic inclusions increase and the toughness of the steel decreases even if the content of other elements is within the range of the present embodiment. Therefore, the Al content is 0.010 to 0.650%.
- a preferable lower limit of the Al content is 0.012%, more preferably 0.020%, further preferably 0.025%, and further preferably 0.030%.
- the preferred upper limit of the Al content is 0.600%, more preferably 0.500%, further preferably 0.300%, more preferably less than 0.250%, and still more preferably 0.1%. 240%.
- the Al content referred to in this specification means the content of acid-soluble Al (sol. Al).
- N 0.0030 to 0.0200%
- Nitrogen (N) combines with Al to form AlN and refines prior austenite grains. The refinement of the prior austenite grains increases the toughness of the steel. If the N content is less than 0.0030%, this effect cannot be sufficiently obtained even if other element contents are within the range of the present embodiment. On the other hand, if the N content exceeds 0.0200%, the effect is saturated even if the content of other elements is within the range of the present embodiment. Therefore, the N content is 0.0030 to 0.0200%.
- a preferred lower limit of the N content is 0.0035%, more preferably 0.0040%.
- a preferred upper limit of the N content is 0.0100%, and more preferably 0.0080%.
- the balance of the chemical composition of the railway wheel 1 according to the present embodiment consists of Fe and impurities.
- the impurities are mixed in from the ore, scrap, or the production environment as raw materials when the railway wheel 1 is manufactured industrially, and have an adverse effect on the railway wheel 1 of the present embodiment. Means acceptable within the range not given.
- the impurities other than the above-mentioned impurities include, for example, O, Cu, Ni, and Mo.
- the contents of these impurity elements are, for example, as follows. O: 0.0070% or less, Cu: 0.20% or less, more preferably 0.10% or less, further preferably 0.08% or less, Ni: 0.20% or less, more preferably 0.10% or less. , More preferably, 0.08% or less, Mo: 0.07% or less.
- the chemical composition of the railway wheel 1 of the present embodiment may further contain Cr instead of part of Fe.
- Chromium (Cr) is an optional element and need not be contained. That is, the Cr content may be 0%. When contained, Cr narrows the lamella spacing of pearlite. This significantly increases the hardness of the pearlite. However, if the Cr content exceeds 0.60%, the quenchability becomes excessively high and the thickness of the quenched layer after quenching the treads becomes excessive even if the content of other elements is within the range of the present embodiment. To increase. Therefore, the Cr content is 0 to 0.60%.
- a preferable lower limit of the Cr content is more than 0%, more preferably 0.01%, further preferably 0.02%, and further preferably 0.03%.
- a preferable upper limit of the Cr content is 0.55%, more preferably 0.40%, further preferably 0.30%, further preferably 0.25%, and further preferably 0.20%. %.
- the chemical composition of the railway wheel 1 of the present embodiment may further contain V instead of part of Fe.
- V 0 to 0.12% Vanadium (V) is an optional element and may not be contained. That is, the V content may be 0%. When included, V forms any of carbides, nitrides, and carbonitrides to precipitate and strengthen steel (specifically, ferrite in steel). As a result, the hardness of the railway wheel 1 increases, and the wear resistance further increases. However, if the V content exceeds 0.12%, the quenchability increases, and the thickness of the quenched layer after tread quenching excessively increases. Therefore, the V content is 0 to 0.12%.
- a preferred lower limit of the V content is more than 0%, more preferably 0.01%, further preferably 0.02%, and further preferably 0.03%.
- a preferred upper limit of the V content is 0.11%, and more preferably 0.10%.
- the area ratio of pearlite is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%.
- phases other than pearlite and proeutectoid cementite are, for example, martensite and / or bainite.
- the area ratio of pearlite is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%.
- phases other than pearlite and proeutectoid cementite are, for example, martensite and / or bainite.
- the pearlite area ratio is preferably 95.0% or more, and more preferably 97.0% or more.
- phases other than pearlite and pro-eutectoid cementite are, for example, martensite and / or bainite.
- the pearlite area ratio and the proeutectoid cementite area ratio in the microstructure of the plate portion 3, the boss portion 2, and the rim portion 4 are determined by the following methods.
- the central position in the thickness direction of the plate portion 3 (the central position in the thickness T3 in FIG. 1), the central position in the thickness direction of the boss portion 2 (the central position in the thickness T2 in FIG. 1), the thickness of the rim portion 4.
- a sample is taken from the center position in the direction (the center position of the thickness T4 in FIG. 1).
- the observation surface of each sample is mirror-finished by mechanical polishing. Thereafter, etching is performed on the observation surface using a sodium picrate solution (100 ml of water + 2 g of picric acid + 25 g of sodium hydroxide).
- the sample is immersed in a boiled sodium picrate solution.
- a photographic image is generated using an optical microscope with a magnification of 500 for an arbitrary visual field (200 ⁇ m ⁇ 200 ⁇ m) in the observation surface of the sample after etching.
- pearlite and proeutectoid cementite have different contrasts.
- the black region indicated by the arrow is proeutectoid cementite
- the remaining light gray region is pearlite.
- each phase of the microstructure can be distinguished based on the contrast. Therefore, pearlite and proeutectoid cementite are specified based on the contrast.
- the area ratio (%) of pearlite is determined based on the specified total area of pearlite and the area of the observation visual field (40000 ⁇ m 2 ).
- the area ratio (%) of the proeutectoid cementite is determined based on the specified total area of the proeutectoid cementite and the area of the observation visual field (40000 ⁇ m 2 ).
- the average value of the width W of the proeutectoid cementite defined by the expression (1) is 0.95 ⁇ m or less.
- W 1/2 ⁇ (P / 2 ⁇ ((P / 2) 2 ⁇ 4A) 1/2 ) (1)
- a in the formula (1) is the area of pro-eutectoid cementite ( ⁇ m 2 )
- P is the outer peripheral length of pro-eutectoid cementite ( ⁇ m).
- the plate portion 3 As described above, with reference to FIG. 1, among the rim portion 4, the plate portion 3, and the boss portion 2 of the railway wheel 1, the plate portion 3 has the smallest thickness T3. Therefore, in the railway wheel 1, the plate portion 3 is required to have high toughness. In the microstructure of the plate portion 3, if the average value of the width W of the proeutectoid cementite defined by the formula (1) is 0.95 ⁇ m or less, the toughness is significantly increased as shown in FIG. Therefore, in the microstructure of at least the plate portion 3 of the railway wheel of the present embodiment, the average value of the width W of the proeutectoid cementite defined by the expression (1) is 0.95 ⁇ m or less.
- the preferable upper limit of the average value of the width W of the proeutectoid cementite is 0.90 ⁇ m, more preferably 0.85 ⁇ m, further preferably 0.80 ⁇ m, further preferably 0.75 ⁇ m, and still more preferably 0. It is less than 0.70 ⁇ m, more preferably 0.68 ⁇ m, and still more preferably 0.65 ⁇ m.
- FIG. 15 is a diagram showing a microstructure photograph image obtained using an optical microscope and an image after binarization processing. Referring to FIG. 15, in the microstructure photograph images of mark A and mark B, the black region is proeutectoid cementite, and the other light gray regions are pearlite.
- the image obtained by binarizing these microstructure photograph images by image processing is the image in the “binarization” column of FIG.
- proeutectoid cementite is shown in white, and pearlite is shown in black.
- proeutectoid cementite may be shown in black and pearlite may be shown in white.
- the binarization process can be performed by a known image processing application such as ImageJ (trademark).
- ImageJ trademark
- the number of pixels of the image is not particularly limited, a preferable range of the number of pixels of the image is 300,000 pixels or more, more preferably 400,000 pixels or more, and further preferably 500,000 pixels or more.
- the upper limit of the number of pixels is not particularly limited, but is, for example, 2 million pixels, may be 1.2 million pixels, or may be 1 million pixels.
- each specified proeutectoid cementite is specified.
- the continuously connected area is specified as one cementite.
- the area A ( ⁇ m 2 ) of each specified proeutectoid cementite is determined.
- the outer peripheral length P ( ⁇ m) of each of the specified proeutectoid cementite is determined.
- the area A and the outer peripheral length P can be obtained by a known image processing application such as ImageJ (trademark).
- ImageJ trademark
- the area A and the peripheral length P of each target proeutectoid cementite are determined.
- the average value of the area A of all the targeted proeutectoid cementite is determined, and the average value of the outer peripheral length P is determined.
- a proeutectoid cementite width W defined by the equation (1) is obtained.
- the obtained proeutectoid cementite width W is regarded as the average value of the proeutectoid cementite width W.
- the average value of the proeutectoid cementite width W of the mark A in FIG. 15 is 0.52 ⁇ m
- the average value of the proeutectoid cementite width W of the mark B is 0.95 ⁇ m.
- the pearlite area ratio is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%. Further, the average value of the proeutectoid cementite width W is 0.95 ⁇ m or less.
- proeutectoid cementite exists in the plate portion 3. However, since the average value of the proeutectoid cementite width W of the plate portion 3 is 0.95 ⁇ m or less, the railway wheel 1 of the present embodiment exhibits excellent toughness.
- the pearlite area ratio is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, In addition, the average value of the proeutectoid cementite width W is 0.95 ⁇ m or less. In this case, the railway wheel 1 shows more excellent toughness.
- a preferred upper limit of the average value of the width W of the proeutectoid cementite in the boss portion 2 is 0.90 ⁇ m, more preferably 0.85 ⁇ m, further preferably 0.80 ⁇ m, and further preferably 0.75 ⁇ m, More preferably, it is less than 0.70 ⁇ m, more preferably 0.68 ⁇ m, and still more preferably 0.65 ⁇ m.
- the average value of the width W of the pro-eutectoid cementite in the boss portion 2 was calculated using the microstructure photograph image (observation field: 200 ⁇ m ⁇ 200 ⁇ m) of the boss portion obtained by the optical microscope described above.
- the average value of the precipitated cementite width W can be determined by the same method as the method for determining the average value.
- the pro-eutectoid cementite in the plate portion 3 is determined not by the average value of the width W but by the maximum width of pro-eutectoid cementite. Can also be defined.
- the area ratio of pearlite is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, The maximum width of proeutectoid cementite is 1.80 ⁇ m or less.
- the plate portion 3 As described above, with reference to FIG. 1, among the rim portion 4, the plate portion 3, and the boss portion 2 of the railway wheel 1, the plate portion 3 has the smallest thickness T3. Therefore, in the railway wheel 1, the plate portion 3 is required to have high toughness. In the microstructure of the plate portion 3, if the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less, the toughness is significantly increased. Therefore, in the microstructure of at least the plate portion 3 of the railway wheel of the present embodiment, the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less.
- a preferred upper limit of the maximum width of the proeutectoid cementite is 1.75 ⁇ m, more preferably 1.70 ⁇ m, further preferably 1.60 ⁇ m, further preferably 1.50 ⁇ m, and still more preferably 1.40 ⁇ m. Yes, more preferably 1.30 ⁇ m, further preferably 1.20 ⁇ m, and still more preferably 1.10 ⁇ m.
- the maximum width of proeutectoid cementite is determined by the following method.
- a sample is taken from an arbitrary thickness center position of the plate portion 3 (the center position of the thickness T3 of the plate portion 3 in FIG. 1).
- An arbitrary surface among the surfaces of the sample is defined as an observation surface.
- the observation surface is mirror-finished by mechanical polishing. Thereafter, the observation surface is etched using a nital liquid.
- Eight arbitrary visual fields of the observation surface of the sample after etching are observed at a magnification of 2000 using a scanning electron microscope (SEM), and a microstructure photograph image of a secondary electron image of each visual field (60 ⁇ m ⁇ 45 ⁇ m) is generated. .
- SEM scanning electron microscope
- the number of pixels of the image is not particularly limited, a preferable range of the number of pixels of the image is 300,000 pixels or more, more preferably 400,000 pixels or more, and further preferably 500,000 pixels or more.
- the upper limit of the number of pixels is not particularly limited, but is, for example, 3 million pixels, may be 2 million pixels, or may be 1.5 million pixels.
- the width of the proeutectoid cementite at a measurement point within a range of a reference circle Cref having a diameter of 1.5 ⁇ m from the branch point of the skeleton line and the line segment at the measurement point include the measurement point.
- the width of proeutectoid cementite when it intersects the skeleton line at two or more points is out of scope.
- the width of the proeutectoid cementite is specified in each field of view, excluding the width of the proeutectoid cementite.
- the largest width is defined as the maximum width of proeutectoid cementite.
- the pearlite area ratio is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, In addition, the maximum width of proeutectoid cementite is 1.80 ⁇ m or less. In this case, the railway wheel 1 shows more excellent toughness.
- a preferred upper limit of the maximum width of the proeutectoid cementite in the boss portion 2 is 1.75 ⁇ m, more preferably 1.70 ⁇ m, further preferably 1.60 ⁇ m, further preferably 1.50 ⁇ m, and further preferably It is 1.40 ⁇ m, more preferably 1.30 ⁇ m, further preferably 1.20 ⁇ m, and further preferably 1.10 ⁇ m.
- the manufacturing method includes a step of manufacturing steel for railway wheels (material manufacturing step), a step of forming a wheel-shaped intermediate product from steel for railway wheels by hot working (forming step), and a formed intermediate product.
- a heat treatment quenching of the tread
- cutting step cutting to form a railway wheel
- molten steel having the above-described chemical composition is melted using an electric furnace or a converter, and then cast into a steel ingot.
- the steel ingot may be either a slab by continuous casting or an ingot cast by a mold.
- Hot-work slabs or ingots to produce steel materials for railway wheels of desired size The hot working is, for example, hot forging, hot rolling or the like.
- steel materials for railway wheels are manufactured by the following method.
- hot rolling for example, a slab rolling mill is used. The slab rolling is performed on the material by a slab rolling mill to produce a steel material for railway wheels. If a continuous rolling mill is installed downstream of the bulk rolling mill, the steel material after the bulk rolling is further subjected to hot rolling using a continuous rolling mill to produce a steel material for railway wheels. Is also good.
- horizontal stands having a pair of horizontal rolls and vertical stands having a pair of vertical rolls are alternately arranged in a line.
- the heating temperature of the heating furnace in hot rolling is not particularly limited, but is, for example, 1100 to 1350 ° C.
- the steel material for railway wheels may be a cast material (slab or ingot). That is, the above-described hot working step may be omitted. Through the above steps, a steel material for railway wheels, which is a material for railway wheels, is manufactured.
- a wheel-shaped intermediate product is formed by hot working using the prepared steel material for railway wheels. Since the intermediate product has a wheel shape, the intermediate product includes a boss portion, a plate portion, and a rim portion including a tread surface and a flange portion.
- the hot working is, for example, hot forging, hot rolling or the like.
- rough land forging for forming a wheel-shaped coarse intermediate product by hot forging is performed.
- Hot rolling using a wheel rolling machine is performed on the crude intermediate product after the rough land forging.
- Rotary forging is performed on the rough intermediate product after the hot rolling to form a through hole in a central portion corresponding to the boss portion.
- the preferred heating temperature of the steel material for railway wheels during hot working in the forming step is 1220 ° C or higher.
- a preferred lower limit of the heating temperature during hot working is 1230 ° C., more preferably 1250 ° C., and further preferably 1300 ° C.
- the preferred upper limit of the heating temperature during hot working is 1350 ° C.
- the method of cooling the intermediate product after hot working is not particularly limited. Cooling may be performed by cooling, or cooling by water.
- tread quenching is performed on the formed wheel-shaped intermediate product. Specifically, reheating the hot working (hot forging or hot rolling) after the intermediate product over Ac m transformation point (reheating). After heating, quenching (tread quenching) is performed on the tread and the flange of the intermediate product. At this time, it is not necessary to rapidly cool the plate portion 3, and the average cooling rate CR 800-500 from 800 ° C. to 500 ° C. in the plate portion 3 may be less than 0.500 ° C./sec. However, the average cooling rate CR 750-700 from 750 ° C. to 700 ° C. in the plate portion 3 is set to 0.022 ° C./sec or more.
- the temperature range of 750 to 700 ° C. is a temperature range in which proeutectoid cementite precipitates.
- the average cooling rate CR 750-700 is 0.022 ° C./sec or more
- the average value of the width W of the proeutectoid cementite in the plate portion 3 is 0.95 ⁇ m or less
- the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less.
- the toughness of the railway wheel is good.
- the average cooling rate CR 750-700 in the plate portion 3 from 750 ° C. to 700 ° C. is 0.022 ° C./sec or more
- the average value of the width W of the proeutectoid cementite in the plate portion 3 becomes 0.95 ⁇ m or less.
- the maximum width of the proeutectoid cementite in the plate portion 3 is 1.80 ⁇ m or less.
- a preferable lower limit of the average cooling rate CR 750-700 in the plate portion 3 is 0.025 ° C./sec, more preferably 0.030 ° C./sec, further preferably 0.040 ° C./sec. Is 0.045 ° C./sec, more preferably 0.050 ° C./sec, further preferably 0.052 ° C./sec, more preferably 0.055 ° C./sec, and still more preferably 0 100 ° C./sec, more preferably 0.500 ° C./sec.
- the average cooling rate CR 750-700 exceeds 33.000 ° C./sec , the average cooling rate CR 800-500 also becomes 0.500 ° C./sec or more. In this case, the generation of pro-eutectoid cementite is suppressed, and the area ratio of pro-eutectoid cementite can be made less than 0.90% in the steel having the above chemical composition. However, it is necessary to improve the cooling capacity of the cooling device at the time of tread quenching, which increases the equipment cost. If the cooling rate increases, a quenched layer may be formed not only on the tread but also on the surfaces of the plate portion 3 and the boss portion 2.
- the railway wheel 1 in the present embodiment is based on the premise that at least the plate portion 3 contains proeutectoid cementite. Therefore, it is not necessary to control the cooling rate strictly in the plate portion 3 such that the generation of proeutectoid cementite is suppressed and the generation of the quenched layer is suppressed. As a result, complication of the manufacturing process can be suppressed.
- FIG. 16 is a diagram illustrating an example of a cooling device for cooling an intermediate product.
- the cooling device 10 includes a rotating device 11 having a rotating shaft, one or a plurality of boss cooling nozzles 12, one or a plurality of plate cooling nozzles 13, and one or a plurality of tread cooling nozzles 14.
- the tread cooling nozzle 14 is arranged around the rotation axis of the cooling device 10.
- the nozzle opening of the tread cooling nozzle 14 is arranged to face the tread 41 of the intermediate product.
- the nozzle opening of the tread cooling nozzle 14 may be arranged to face the surface of the flange 42 of the intermediate product.
- the plate portion cooling nozzle 13 is arranged such that the nozzle port faces the surface of the plate portion 3.
- the boss cooling nozzle 12 is arranged so that the nozzle port faces the surface of the boss 2.
- the tread cooling nozzle 14 injects a cooling liquid from the nozzle opening to mainly cool the tread 41 of the rim 4 and the surface of the flange 42.
- the cooling liquid is, for example, water, mist, spray or the like.
- the plate portion cooling nozzle 13 mainly cools the plate portion 3 by injecting a cooling gas from the nozzle port.
- the cooling gas is, for example, compressed air.
- the boss cooling nozzle 12 also injects a cooling gas from the nozzle opening to mainly cool the boss 2.
- the cooling device 10 further includes a plurality of thermometers 20.
- the thermometer 20 is arranged around the intermediate product, and measures the temperature of the rim portion 4, the tread surface 41, the flange portion 42, the plate portion 3, and the boss portion 2.
- the plurality of thermometers 20 include the tread 41, the surface of the flange 42, the surface of the rim 4 other than the surface of the tread 41 and the flange 42 (for example, the side surface of the rim 4), and the plate.
- the temperature distribution on the surface of the part 3 and the temperature distribution on the surface of the boss part 2 can be measured.
- the intermediate product heated above the A cm transformation point is placed in the cooling device 10. While rotating the intermediate product by the rotating device 11, the cooling liquid is injected from the tread cooling nozzle 14 to perform the tread quenching. Further, during the tread quenching, cooling gas is injected from the plate cooling nozzle 13 and / or the boss cooling nozzle 12 to cool the plate 3 and / or the boss 2. While measuring the temperature distribution of the intermediate product with the thermometer 20, the cooling rate of the plate portion 3 at 750 to 700 ° C. is adjusted to be 0.022 to 33.000 ° C./sec.
- Fine pearlite is generated on the surface layer of the tread 41 by the tread quenching.
- the C content of the railway wheel 1 of the present embodiment is as high as 0.80 to 1.60%. Therefore, the wear resistance of the fine pearlite increases.
- the average cooling rate CR 750-700 at 750 to 700 ° C. in the plate portion 3 is adjusted to 0.022 to 33.000 ° C./sec.
- the pearlite area ratio is 85.0% or more and the area ratio of proeutectoid cementite is 0.90 to 15.00%, but the width W of proeutectoid cementite is Can be 0.95 ⁇ m or less.
- the maximum width of the proeutectoid cementite can be 1.80 ⁇ m or less. For this reason, although proeutectoid cementite is present in the microstructure, sufficient toughness can be obtained.
- the pearlite area ratio is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, and
- the average value of the width W of the proeutectoid cementite is 0.95 ⁇ m or less, or the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less, the average cooling rate CR 800 at 800 to 500 ° C. in the plate portion 3 and the boss portion 2. Even if ⁇ 500 is less than 0.500 ° C./sec, the average cooling rate CR 750-700 at 750 to 700 ° C.
- the area ratio of pearlite is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, and the average value of the width W of proeutectoid cementite is 0.95 ⁇ m or less, and also in the microstructure of the boss portion 2, the area ratio of pearlite is 85.0% or more and the area ratio of proeutectoid cementite is 0.90 to 15.00%.
- the average value of the width W becomes 0.95 ⁇ m or less.
- the area ratio of pearlite is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, and the maximum width of proeutectoid cementite is 1.80 ⁇ m or less.
- the area ratio of pearlite is 85.0% or more, the area ratio of proeutectoid cementite is 0.90 to 15.00%, and the maximum width of proeutectoid cementite is 1%. .80 ⁇ m or less.
- the cooling device 10 may not include the boss portion cooling nozzle 12. Further, the cooling device 10 may include the tread cooling nozzle 14 and may not include the plate cooling nozzle 13 and the boss cooling nozzle 12.
- the average cooling rate CR 750-700 at 750 to 700 ° C. in the plate portion 3 or the plate portion 3 and the boss portion 2 is adjusted by adjusting the injection amount of the cooling liquid of the tread cooling nozzle 14 during the tread quenching. Can be adjusted to 0.022 to 33.000 ° C./sec.
- the intermediate product is reheated.
- the intermediate product after hot working may be directly (without reheating) subjected to tread quenching.
- Temper up the intermediate product after hardening the tread as necessary Tempering at a known temperature and time is sufficient.
- the tempering temperature is, for example, 400 to 600 ° C.
- the railway wheel of the present embodiment is manufactured.
- the pearlite area ratio is at least 85.0% and the area ratio of proeutectoid cementite is 0.90 to 15.00 in at least the microstructure of the plate portion 3. %,
- the average value of the width W of the proeutectoid cementite defined by the formula (1) is 0.95 ⁇ m or less.
- the maximum width of the proeutectoid cementite is 1.80 ⁇ m or less.
- the pearlite area ratio is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%.
- the average value of the width W of the pro-eutectoid cementite defined in (1) is 0.95 ⁇ m or less, and in the microstructure of the boss portion 2, the pearlite area ratio is 85.0% or more.
- the area ratio is 0.90 to 15.00%, and the average value of the width W of the proeutectoid cementite defined by the formula (1) is 0.95 ⁇ m or less. Therefore, in the railway wheel of the present embodiment, sufficient toughness can be obtained although proeutectoid cementite is present.
- the pearlite area ratio is at least 85.0% and the area ratio of proeutectoid cementite is 0.90 to 15 at least in the microstructure of the plate portion 3. 0.000%, and the maximum width of proeutectoid cementite is 1.80 ⁇ m or less.
- the pearlite area ratio is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%.
- the maximum width of precipitated cementite is 1.80 ⁇ m or less, and in the microstructure of the boss portion 2, the pearlite area ratio is 85.0% or more, and the area ratio of proeutectoid cementite is 0.90 to 15.00%. And the maximum width of proeutectoid cementite is 1.80 ⁇ m or less. Therefore, in the railway wheel of the present embodiment, sufficient toughness can be obtained although proeutectoid cementite is present.
- An ingot (a truncated cone with a top diameter of 107 mm, a bottom diameter of 97 mm, and a height of 230 mm) was manufactured from the molten steel by an ingot making method.
- the ingot was heated to 1250 ° C. to simulate the hot working process of the railway wheel manufacturing process, and then hot forged to produce a round bar having a diameter of 40 mm. Further, a round bar (steel material) having a diameter of 20 mm and a length of 125 mm was collected from the center of the round bar by machining.
- a simulated tread quenching test simulating tread quenching during the manufacturing process of the railway wheel was performed on the steel material of each test number. Specifically, the heat treatment of the heat pattern shown in Table 4 and FIG. 17 was performed on the steel material of each test number. In each heat pattern, the average cooling rate of the steel material temperature of 800 ⁇ 500 °C CR 800-500 (°C / sec), and the average cooling rate in the steel material temperature of 750 ⁇ 700 °C CR 750-700 (°C / second) , And Table 4. Through the above manufacturing process, a steel material simulating a railway wheel (simulated railway wheel steel material) was manufactured.
- the average cooling rate CR 800-500 is reduced to 0.420 ° C./sec by starting cooling from 950 ° C., maintaining the temperature at 690 ° C. for a predetermined time, and then restarting cooling.
- the average cooling rate CR 750-700 was adjusted to 0.530 ° C./sec.
- the cooling is started from 950 ° C., kept at 720 ° C. for a predetermined time, restarted cooling, then kept at 650 ° C. for a predetermined time, and then restarted cooling, so that the average cooling rate CR 800-500 was adjusted to 0.175 ° C./sec, and the average cooling rate CR 750-700 was adjusted to 0.0480 ° C./sec.
- Test pieces for microstructure observation were collected from the center position of the cross section perpendicular to the longitudinal direction of the simulated railway wheel steel of each test number after the heat treatment.
- a cross section perpendicular to the longitudinal direction of the test material was used as an observation surface on the surface of the test piece.
- the observation surface of each test piece was mirror-finished by mechanical polishing. Thereafter, the observation surface was subjected to etching using a sodium picrate solution (100 ml of water + 2 g of picric acid + 25 g of sodium hydroxide). In the etching, the test piece was immersed in a boiled sodium picrate solution.
- a photographic image for microstructure observation was generated using an optical microscope at a magnification of 500 with respect to an arbitrary visual field (200 ⁇ m ⁇ 200 ⁇ m) in the observation surface of the test piece after etching.
- the pearlite, proeutectoid cementite, and other phases differ in contrast, as described above. Therefore, pearlite and proeutectoid cementite were specified based on the contrast of the photographic image.
- the area ratio (%) of pearlite was determined based on the specified total area of pearlite and the area of the observation visual field.
- the area ratio (%) of the pro-eutectoid cementite was determined based on the specified total area of pro-eutectoid cementite and the area of the observation visual field.
- Table 4 shows the obtained pearlite area ratio and proeutectoid cementite area ratio.
- pro-eutectoid cementite width W defined by the equation (1) was obtained.
- the obtained proeutectoid cementite width W was regarded as the average value of the proeutectoid cementite width W.
- Table 4 shows the obtained average value ( ⁇ m) of the pro-eutectoid cementite width W.
- Test Nos. 12 to 16 calculation of the average value of the proeutectoid cementite width W was omitted because the area ratio of proeutectoid cementite was extremely small (described as “ ⁇ ” in Table 4).
- the specified pro-eutectoid cementite was subjected to a thinning process to obtain a skeleton line of the pro-eutectoid cementite.
- the straight line perpendicular to the skeleton line from any measurement point of the skeletal line is defined as the line segment length between the intersection of two points with the contour of the proeutectoid cementite as the width of the proeutectoid cementite at the measurement point. did.
- the width of the proeutectoid cementite when it intersected was excluded from the target.
- the maximum value of the width of the proeutectoid cementite was specified in each field of view, excluding the width of the proeutectoid cementite in the case.
- the largest width was defined as the maximum width of proeutectoid cementite.
- Table 4 shows the obtained maximum width ( ⁇ m) of proeutectoid cementite. In Test Nos. 12 to 16, calculation of the maximum width of pro-eutectoid cementite was omitted because the area ratio of pro-eutectoid cementite was extremely small (denoted by "-" in Table 4).
- U-notch test specimens based on JIS Z 2242 (2005) were collected from the center position of the cross section perpendicular to the longitudinal direction of the simulated railway wheel steel material of each test number.
- the cross section perpendicular to the longitudinal direction (Longitudinal-direction) of the U notch test piece was a square of 10 mm ⁇ 10 mm, and the length of the U notch test piece in the longitudinal direction was 55 mm.
- the longitudinal direction of the U-notch test piece was parallel to the longitudinal direction of the steel material.
- a U-notch was formed at the center of the length of the U-notch test piece (that is, at the center of a length of 55 mm).
- the notch depth was 2 mm, and the notch bottom radius was 1.0 mm.
- a Charpy impact test in a room temperature atmosphere was performed.
- the Charpy impact value (J / cm 2 ) was determined for four U-notch test pieces, and the average value of the four U-notch test pieces was defined as the Charpy impact value (J / cm 2 ) of the test number.
- Table 4 shows the obtained Charpy impact values.
- Table 4 shows the test results. Referring to Table 4, the chemical compositions of the simulated railway wheel steel materials of Test Nos. 1 to 7 were appropriate. Further, in the heat treatment simulating the tread quenching, the average cooling rate CR 800-500 (° C./second ) and the average cooling rate CR 750-700 (° C./second ) were appropriate. Therefore, the pearlite area ratio was 85.0% or more, and the area ratio of proeutectoid cementite was 0.90 to 15.00%. Further, the average value of the width W of the proeutectoid cementite was 0.95 ⁇ m or less. The maximum width of the proeutectoid cementite was 1.80 ⁇ m or less. Therefore, the Charpy impact value exceeded 8.5 J / cm 2 , and excellent toughness was obtained.
- the average cooling rate CR 750-700 was as low as 0.010 to 0.019 ° C./sec. Therefore, in the microstructures of the simulated railway wheel steel materials of these test numbers, the average value of the width W of the proeutectoid cementite exceeded 0.95 ⁇ m. Further, the maximum width of the proeutectoid cementite exceeded 1.80 ⁇ m. Therefore, the Charpy impact value was 8.5 J / cm 2 or less. In Test Nos. 11 to 15, the average cooling rate CR 800-500 exceeded 0.500 ° C./sec. In Test Nos. 14 and 15, the average cooling rate CR 750-700 exceeded 33.000 ° C./sec. Was. Therefore, the area ratio of proeutectoid cementite was less than 0.90%, which was out of the scope of the present invention.
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Abstract
Description
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、かつ、式(1)で定義される前記初析セメンタイトの幅Wの平均値は0.95μm以下である。
W=1/2×(P/2-((P/2)2-4A)1/2) (1)
ここで、式(1)中のAは前記初析セメンタイトの面積(μm2)であり、Pは前記初析セメンタイトの外周長(μm)である。
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、前記初析セメンタイトの最大幅は1.80μm以下である。
図1は本実施形態による鉄道車輪の中心軸を含む断面図である。図1を参照して、鉄道車輪1は円盤状であり、ボス部2と、板部3と、リム部4とを備える。ボス部2は円筒状であり、鉄道車輪1の径方向(中心軸に対して垂直な方向)において、鉄道車輪1の中央部に配置される。ボス部2は貫通孔21を有する。貫通孔21の中心軸は、鉄道車輪1の中心軸と一致する。貫通孔21には、図示しない鉄道用車軸が挿入される。ボス部2の厚さT2は、板部3の厚さT3よりも厚い。リム部4は、鉄道車輪1の外周の縁部に形成されている。リム部4は、踏面41と、フランジ部42とを含む。踏面41は、フランジ部42と繋がっている。鉄道車輪1の使用時において、踏面41及びフランジ部42はレール表面と接触する。リム部4の厚さT4は、板部3の厚さT3よりも厚い。板部3は、ボス部2とリム部4との間に配置され、ボス部2及びリム部4とつながっている。具体的には、板部3の内周縁部はボス部2とつながっており、板部3の外周縁部はリム部4とつながっている。板部3の厚さT3は、ボス部2の厚さT2及びリム部4の厚さT4よりも薄い。鉄道車輪1の直径は特に限定されるものではないが、たとえば、700mm~1000mmである。
本発明者らは初めに、鉄道車輪において、耐摩耗性を高めるのに適切な化学組成について検討を行った。その結果、鉄道車輪においては、同じ硬さを得るにしても、V含有量を高めて硬さを高めるよりも、C含有量を0.80%以上に高めて硬さを高めた方が、鉄道車輪として使用したときの耐摩耗性が高まることが分かった。このメカニズムは定かではないが、次の事項が考えられる。使用中の鉄道車輪の踏面は、レールから外力(荷重)を受ける。この外力により踏面直下の表層のパーライト中のセメンタイトが破砕され、分散強化により硬さが高まる。さらに、破砕された微細なセメンタイト中の炭素がパーライト中のフェライトに過飽和に固溶し、固溶強化により踏面直下の表層の硬さを高める。
過共析鋼の鉄道車輪を模擬した、表1に示す化学組成の鋼材TP1、TP2を作製した。
(A)初析セメンタイトの幅の平均値を指標とした規定
(B)初析セメンタイトの最大幅を指標とした規定
上記(A)の初析セメンタイトの幅の平均値は、非特許文献1に記載の長方形近似法(ribbon-like method)に基づいて求めることができる。上記(B)の初析セメンタイトの最大幅は、画像処理方法の1つである細線化処理を実施することにより求めることができる。以下、上記(A)及び(B)について詳述する。
初析セメンタイトの幅Wの平均値を、非特許文献1に記載の長方形近似法により求める。具体的には、次の方法により求める。上述の500倍の光学顕微鏡により得られた上述のミクロ組織写真画像(200μm×200μm)を画像処理により2値化して、初析セメンタイトを特定する。特定された初析セメンタイトの面積Aを求める。さらに、特定された初析セメンタイトの外周の長さP(外周長)を求める。得られた各初析セメンタイトの面積A及び外周長Pとを用いて、初析セメンタイトを面積A及び外周長Pを有する長方形であると仮定する。そして、セメンタイトを長方形と仮定したときの長方形の長辺を初析セメンタイトの長さLとみなし、長方形の短辺を初析セメンタイトの幅Wとみなす。つまり、初析セメンタイトを次の式(a)及び式(b)を満たす長方形とみなす。
A=L×W (a)
P=2×(L+W) (b)
W=1/2×(P/2-((P/2)2-4A)1/2) (1)
L=1/2×(P/2+((P/2)2-4A)1/2)
初析セメンタイトの最大幅を、次の方法で求めた。上述の観察面に対して、機械研磨による鏡面仕上げの後、ナイタール液を用いたエッチングを実施した。エッチング後の観察面内の任意の8視野において、走査型電子顕微鏡(SEM)を用いて2000倍で観察し、二次電子像のミクロ組織写真画像(60μm×45μm)を生成する。ミクロ組織写真画像を画像処理により2値化して、初析セメンタイトを特定する。特定された初析セメンタイトに対して、細線化処理を実施する。
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、かつ、式(1)で定義される前記初析セメンタイトの幅Wの平均値は0.95μm以下である。
W=1/2×(P/2-((P/2)2-4A)1/2) (1)
ここで、式(1)中のAは前記初析セメンタイトの面積(μm2)であり、Pは前記初析セメンタイトの外周長(μm)である。
前記鉄道車輪の前記ボス部のミクロ組織において、パーライトの面積率は85.0%以上であり、前記初析セメンタイトの面積率は0.90~15.00%であり、かつ、式(1)で定義される前記初析セメンタイトの幅Wの平均値は0.95μm以下である。
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、前記初析セメンタイトの最大幅は1.80μm以下である。
前記鉄道車輪の前記ボス部のミクロ組織において、パーライトの面積率は85.0%以上であり、前記初析セメンタイトの面積率は0.90~15.00%であり、前記初析セメンタイトの最大幅は1.80μm以下である。
前記化学組成は、
Cr:0.02~0.60%、及び、
V:0.02~0.12%、
からなる群から選択される1元素以上を含有する。
本実施形態の鉄道車輪1は、図1に示すとおり、ボス部2と、板部3とリム部4とを備える。本実施形態の鉄道車輪1の化学組成は、次の元素を含有する。
炭素(C)は、鋼の硬度を高め、鉄道車輪1の耐摩耗性を高める。C含有量が0.80%未満であれば、他の元素含有量が本実施形態の範囲内であっても、この効果が得られない。一方、C含有量が1.60%を超えれば、他の元素含有量が本実施形態の範囲内であっても、旧オーステナイト粒界に初析セメンタイトが過剰に多く析出し、初析セメンタイトの面積率が15.00%を超える。この場合、鉄道車輪1の靱性が低下する。したがって、C含有量は0.80~1.60%である。C含有量の好ましい下限は0.85%であり、さらに好ましくは0.87%であり、さらに好ましくは0.90%であり、さらに好ましくは0.95%である。C含有量の好ましい上限は1.55%であり、さらに好ましくは1.45%であり、さらに好ましくは1.30%であり、さらに好ましくは1.15%であり、さらに好ましくは1.05%である。
シリコン(Si)は不可避に含有される。つまり、Si含有量は0%超である。Siは、フェライトを固溶強化して鋼の硬さを高める。しかしながら、Si含有量が1.00%を超えれば、他の元素含有量が本実施形態の範囲内であっても、初析セメンタイトが生成しやすくなる。Si含有量が1.00%を超えればさらに、鋼の焼入れ性が高くなりすぎ、マルテンサイトが生成しやすくなる。この場合、踏面焼入れ時に踏面上に形成される焼入れ層の厚みが増大する。その結果、切削量が増大して歩留りが低下する。Si含有量が1.00%を超えればさらに、鉄道車輪1の使用中に、ブレーキとの間に発生する摩擦熱によりリム部4に焼きが入る。この場合、鋼の耐き裂性が低下する場合がある。したがって、Si含有量は1.00%以下である。Si含有量の好ましい上限は0.90%であり、さらに好ましくは0.80%であり、さらに好ましくは0.70%であり、さらに好ましくは0.50%である。Si含有量の下限は特に制限されない。しかしながら、Si含有量の過剰な低減は製造コストを高める。したがって、Si含有量の好ましい下限は0.01%であり、さらに好ましくは0.05%である。鋼の硬さを高める観点では、Si含有量のさらに好ましい下限は0.10%であり、さらに好ましくは0.15%である。
マンガン(Mn)はフェライトを固溶強化して鋼の硬さを高める。Mnはさらに、MnSを形成し、鋼の被削性を向上する。Mn含有量が0.10%未満であれば、他の元素含有量が本実施形態の範囲内であっても、これらの効果は得られない。一方、Mn含有量が1.25%を超えれば、他の元素含有量が本実施形態の範囲内であっても、鋼の焼入れ性が高くなりすぎる。この場合、焼入れ層の厚みが増大し、製造工程時における歩留まりが低下する。さらに、鉄道車輪1の使用時に、ブレーキとの間に発生する摩擦熱によりリム部4に焼きが入る。この場合、鋼の耐き裂性が低下する場合がある。したがって、Mn含有量は0.10~1.25%である。Mn含有量の好ましい下限は0.50%であり、さらに好ましくは0.60%であり、さらに好ましくは0.70%である。Mn含有量の好ましい上限は1.10%であり、さらに好ましくは1.00%であり、さらに好ましくは0.95%であり、さらに好ましくは0.90%である。
りん(P)は、不可避に含有される不純物である。つまり、P含有量は0%超である。Pは粒界に偏析して鋼の靭性を低下する。したがって、P含有量は0.050%以下である。P含有量の好ましい上限は0.030%であり、さらに好ましくは0.020%である。P含有量はなるべく低い方が好ましい。しかしながら、P含有量の過剰な低減は製造コストを高める。したがって、通常の工業生産を考慮した場合、P含有量の好ましい下限は0.001%であり、さらに好ましくは0.002%である。
硫黄(S)は、不可避に含有される。つまり、S含有量は0%超である。SはMnSを形成し、鋼の被削性を高める。一方、S含有量が高すぎれば、鋼の靭性が低下する。したがって、S含有量は0.030%以下である。S含有量の好ましい上限は0.020%である。S含有量の過剰な低減は製造コストを高める。したがって、S含有量の好ましい下限は0.001%であり、さらに好ましくは0.002%であり、さらに好ましい下限は0.005%である。
アルミニウム(Al)は、鋼を脱酸する。Alはさらに、初析セメンタイトの生成を抑制し、鋼の靱性を高める。Alはさらに、Nと結合してAlNを形成し、結晶粒を微細化する。結晶粒を微細化することにより、鋼の靱性が高まる。Al含有量が0.010%未満であれば、他の元素含有量が本実施形態の範囲内であっても、これらの効果が十分に得られない。一方、Al含有量が0.650%を超えれば、他の元素含有量が本実施形態の範囲内であっても、非金属介在物が増加して鋼の靱性が低下する。したがって、Al含有量は0.010~0.650%である。Al含有量の好ましい下限は0.012%であり、さらに好ましくは0.020%であり、さらに好ましくは0.025%であり、さらに好ましくは0.030%である。Al含有量の好ましい上限は0.600%であり、さらに好ましくは0.500%であり、さらに好ましくは0.300%であり、さらに好ましくは0.250%未満であり、さらに好ましくは0.240%である。本明細書でいうAl含有量は、酸可溶Al(sol.Al)の含有量を意味する。
窒素(N)は、Alと結合してAlNを形成し、旧オーステナイト粒を微細化する。旧オーステナイト粒が微細化することにより、鋼の靭性が高まる。N含有量が0.0030%未満であれば、他の元素含有量が本実施形態の範囲内であっても、この効果が十分に得られない。一方、N含有量が0.0200%を超えれば、他の元素含有量が本実施形態の範囲内であっても、その効果が飽和する。したがって、N含有量は0.0030~0.0200%である。N含有量の好ましい下限は、0.0035%であり、さらに好ましくは0.0040%である。N含有量の好ましい上限は、0.0100%であり、さらに好ましくは0.0080%である。
本実施形態の鉄道車輪1の化学組成はさらに、Feの一部に代えて、Crを含有してもよい。
クロム(Cr)は、任意元素であり、含有されなくてもよい。つまり、Cr含有量は0%であってもよい。含有される場合、Crは、パーライトのラメラ間隔を狭める。これにより、パーライトの硬度が顕著に増大する。しかしながら、Cr含有量が0.60%を超えれば、他の元素含有量が本実施形態の範囲内であっても、焼入れ性が過剰に高くなり、踏面焼入れ後の焼入れ層の厚さが過剰に増大する。したがって、Cr含有量は0~0.60%である。Cr含有量の好ましい下限は0%超であり、さらに好ましくは0.01%であり、さらに好ましくは0.02%であり、さらに好ましくは0.03%である。Cr含有量の好ましい上限は0.55%であり、さらに好ましくは0.40%であり、さらに好ましくは0.30%であり、さらに好ましくは0.25%であり、さらに好ましくは0.20%である。
バナジウム(V)は任意元素であり、含有されなくてもよい。つまり、V含有量は0%であってもよい。含有される場合、Vは、炭化物、窒化物、及び炭窒化物のいずれかを形成して、鋼(具体的には鋼中のフェライト)を析出強化する。その結果、鉄道車輪1の硬さが増大して、耐摩耗性をさらに高める。しかしながら、V含有量が0.12%を超えれば、焼入れ性が高くなり、踏面焼入れ後の焼入れ層の厚さが過剰に増大する。したがって、V含有量は0~0.12%である。V含有量の好ましい下限は0%超であり、さらに好ましくは0.01%であり、さらに好ましくは0.02%であり、さらに好ましくは0.03%である。V含有量の好ましい上限は0.11%であり、さらに好ましくは0.10%である。
本実施形態の鉄道車輪1の板部3のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%である。板部3のミクロ組織のうち、パーライト及び初析セメンタイト以外の相はたとえば、マルテンサイト及び/又はベイナイトである。
(A)初析セメンタイトの幅Wの平均値を指標とする規定
本実施形態の鉄道車輪1では、板部3のミクロ組織において、パーライト面積率が85.0%以上であり、かつ、初析セメンタイトの面積率が0.90~15.00%である。つまり、板部3において、初析セメンタイトが存在している。しかしながら、後述のとおり、初析セメンタイト幅Wの平均値が0.95μm以下であるため、本実施形態の鉄道車輪1は、優れた靭性を示す。
本実施形態の鉄道車輪ではさらに、少なくとも板部のミクロ組織において、式(1)で定義される初析セメンタイトの幅Wの平均値が0.95μm以下である。
W=1/2×(P/2-((P/2)2-4A)1/2) (1)
ここで、式(1)中のAは初析セメンタイトの面積(μm2)であり、Pは初析セメンタイトの外周長(μm)である。
好ましくは、本実施形態の鉄道車輪1のボス部2のミクロ組織においても、パーライト面積率が85.0%以上であり、初析セメンタイトの面積率が0.90~15.00%であり、かつ、初析セメンタイト幅Wの平均値が0.95μm以下である。この場合、鉄道車輪1はさらに優れた靭性を示す。ボス部2における初析セメンタイトの幅Wの平均値の好ましい上限は0.90μmであり、さらに好ましくは0.85μmであり、さらに好ましくは0.80μmであり、さらに好ましくは0.75μmであり、さらに好ましくは0.70μm未満であり、さらに好ましくは0.68μmであり、さらに好ましくは0.65μmである。
本実施形態による鉄道車輪1において、板部3内の初析セメンタイトを、上述の幅Wの平均値ではなく、初析セメンタイトの最大幅で定義することもできる。この場合、本実施形態の鉄道車輪1の板部3のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、初析セメンタイトの最大幅は1.80μm以下である。
上述の鉄道車輪を製造する方法の一例を説明する。本製造方法は、鉄道車輪用鋼を製造する工程(素材製造工程)と、熱間加工により、鉄道車輪用鋼から車輪形状の中間品を成形する工程(成形工程)と、成形された中間品に対して熱処理(踏面焼入れ)を実施する工程(熱処理工程)と、熱処理後の中間品の踏面等から焼入れ層を切削加工により除去して鉄道車輪とする工程(切削加工工程)とを含む。以下、各工程について説明する。
素材製造工程では、電気炉又は転炉等を用いて上述の化学組成を有する溶鋼を溶製した後、鋳造して鋼塊にする。なお、鋼塊は連続鋳造による鋳片、鋳型によって鋳込まれたインゴットのいずれであってもよい。
成形工程では、準備された鉄道車輪用鋼材を用いて、熱間加工により車輪形状の中間品を成形する。中間品は車輪形状を有するため、ボス部と、板部と、踏面及びフランジ部を含むリム部とを備える。熱間加工はたとえば、熱間鍛造、熱間圧延等である。たとえば、熱間鍛造により車輪形状の粗中間品を成形する荒地鍛造を実施する。荒地鍛造後の粗中間品に対して、車輪圧延機を用いた熱間圧延を実施する。熱間圧延後の粗中間品に対して回転鍛造を実施して、ボス部に相当する中央部に貫通孔を形成する。以上の構成により、熱間加工により車輪形状の中間品を成形する。
熱処理工程では、成形された車輪形状の中間品に対して踏面焼入れを実施する。具体的には、熱間加工(熱間鍛造又は熱間圧延)後の中間品をAcm変態点以上に再加熱する(再加熱処理)。加熱後、中間品の踏面及びフランジ部に対して急冷(踏面焼入れ)を実施する。このとき、板部3に対して急冷する必要はなく、板部3における800℃から500℃に至るまでの平均冷却速度CR800-500は0.500℃/秒未満であってよい。しかしながら、板部3における750℃から700℃に至るまでの平均冷却速度CR750-700を0.022℃/秒以上とする。
上述のとおり、熱処理後の中間品の踏面の表層には微細パーライトが形成されるが、その上層には焼入れ層が形成されている。鉄道車輪の使用において、焼入れ層の耐摩耗性は低いため、切削加工により焼入れ層を除去する。切削加工は周知の方法で行えば足りる。
各試験番号の鋼材に対して、鉄道車輪の製造工程中の踏面焼入れを模擬した模擬踏面焼入れ試験を実施した。具体的には、各試験番号の鋼材に対して、表4及び図17に示すヒートパターンの熱処理を実施した。各ヒートパターンにおいて、鋼材温度が800~500℃の平均冷却速度CR800-500(℃/秒)、及び、鋼材温度が750~700℃での平均冷却速度CR750-700(℃/秒)は、表4に示すとおりであった。以上の製造工程により、鉄道車輪を模擬した鋼材(模擬鉄道車輪鋼材)を製造した。
熱処理後の各試験番号の模擬鉄道車輪鋼材の長手方向に垂直な断面の中心位置から、ミクロ組織観察用の試験片を採取した。試験片の表面のうち、供試材の長手方向に垂直な断面を観察面とした。各試験片の観察面を機械研磨により鏡面仕上げした。その後、観察面に対して、ピクリン酸ソーダ液(水100ml+ピクリン酸2g+水酸化ナトリウム25g)を用いたエッチングを実施した。エッチングでは、煮沸したピクリン酸ソーダ液に試験片を浸漬した。エッチング後の試験片の観察面内の任意の1視野(200μm×200μm)に対して、500倍の光学顕微鏡を用いてミクロ組織観察用の写真画像を生成した。視野において、パーライト、初析セメンタイト、及び他の相(マルテンサイト、ベイナイト)は、上述のとおり、コントラストが異なる。したがって、写真画像のコントラストに基づいて、パーライト及び初析セメンタイトを特定した。特定されたパーライトの総面積と観察視野の面積とに基づいて、パーライトの面積率(%)を求めた。また、特定された初析セメンタイトの総面積と観察視野の面積とに基づいて、初析セメンタイトの面積率(%)を求めた。得られたパーライト面積率及び初析セメンタイト面積率を表4に示す。
上述のエッチング後の試験片の観察面内の任意の1視野(200μm×200μm)のミクロ組織観察用の写真画像に対して、画像処理アプリケーションImageJ(商品名)を用いて、2値化処理を実施し、視野(写真画像)中の個々の初析セメンタイトを特定した。特定された各初析セメンタイトの面積A(μm2)を求めた。さらに、特定された各初析セメンタイトの外周長P(μm)を求めた。各初析セメンタイトの面積A及び外周長Pは上述の画像処理アプリケーションを用いて求めた。特定された各初析セメンタイトにおいて、面積Aが0.80μm2未満のものは、ノイズである可能性があるため、除外した。対象となる各初析セメンタイトの面積A及び外周長さPを求めた。対象となった全ての初析セメンタイトの面積Aの平均値を求め、かつ、外周長Pの平均値を求めた。求めた面積Aの平均値と、求めた外周長Pの平均値とを用いて、式(1)で定義された初析セメンタイト幅Wを求めた。求めた初析セメンタイト幅Wを初析セメンタイト幅Wの平均値とみなした。求めた初析セメンタイト幅Wの平均値(μm)を表4に示す。なお、試験番号12~16は、初析セメンタイトの面積率が極めて小さかったため、初析セメンタイト幅Wの平均値の算出を省略した(表4中で「-」と記載)。
上述の観察面に対して、機械研磨による鏡面仕上げの後、ナイタール液を用いたエッチングを実施した。エッチング後の試験片の観察面内の任意の8視野を、走査型電子顕微鏡(SEM)を用いて2000倍で観察し、各視野(60μm×45μm)の二次電子像のミクロ組織写真画像を生成した。ミクロ組織観察用の写真画像に対して、画像処理アプリケーションImageJ(商品名)を用いて、2値化処理を実施し、視野(写真画像)中の個々の初析セメンタイトを特定した。そして、2値化処理によりミクロ組織写真画像中の初析セメンタイトを特定した後、特定された初析セメンタイトに対して、細線化処理を実施して、初析セメンタイトの骨格線を得た。
各試験番号の模擬鉄道車輪鋼材の長手方向に垂直な断面の中心位置から、JIS Z 2242(2005)に準拠したUノッチ試験片を採取した。Uノッチ試験片の長手方向(Longitudinal-direction)に垂直な断面は10mm×10mmの正方形とし、Uノッチ試験片の長手方向の長さは55mmとした。Uノッチ試験片の長手方向は、鋼材の長手方向と平行とした。Uノッチ試験片の長さ中央位置(つまり、長さ55mmの中央位置)に、Uノッチを形成した。ノッチ深さを2mmとし、ノッチ底半径を1.0mmとした。JIS Z 2242(2005)に準拠して、室温大気中でのシャルピー衝撃試験を実施した。4個のUノッチ試験片に対してシャルピー衝撃値(J/cm2)を求め、4個の平均値を、その試験番号のシャルピー衝撃値(J/cm2)と定義した。得られたシャルピー衝撃値を表4に示す。
試験結果を表4に示す。表4を参照して、試験番号1~7の模擬鉄道車輪鋼材の化学組成は適切であった。さらに、踏面焼入れを模擬した熱処理において、平均冷却速度CR800-500(℃/秒)、及び、平均冷却速度CR750-700(℃/秒)が適切であった。そのため、パーライト面積率は85.0%以上であり、かつ、初析セメンタイトの面積率が0.90~15.00%であった。さらに、初析セメンタイトの幅Wの平均値が0.95μm以下であった。また、初析セメンタイトの最大幅が1.80μm以下であった。そのため、シャルピー衝撃値が8.5J/cm2を超え、優れた靭性が得られた。
2 ボス部
3 板部
4 リム部
41 踏面
42 フランジ部
Claims (5)
- 鉄道車輪であって、
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、かつ、式(1)で定義される前記初析セメンタイトの幅Wの平均値は0.95μm以下である、
鉄道車輪。
W=1/2×(P/2-((P/2)2-4A)1/2) (1)
ここで、式(1)中のAは前記初析セメンタイトの面積(μm2)であり、Pは前記初析セメンタイトの外周長(μm)である。 - 請求項1に記載の鉄道車輪であってさらに、
前記鉄道車輪の前記ボス部のミクロ組織において、パーライトの面積率は85.0%以上であり、前記初析セメンタイトの面積率は0.90~15.00%であり、かつ、式(1)で定義される前記初析セメンタイトの幅Wの平均値は0.95μm以下である、
鉄道車輪。 - 鉄道車輪であって、
リム部と、
ボス部と、
前記リム部と前記ボス部との間に配置され、前記リム部と前記ボス部とにつながる板部とを備え、
前記鉄道車輪の化学組成は、質量%で、
C:0.80~1.60%、
Si:1.00%以下、
Mn:0.10~1.25%、
P:0.050%以下、
S:0.030%以下、
Al:0.010~0.650%、
N:0.0030~0.0200%、
Cr:0~0.60%、
V:0~0.12%、及び、
残部がFe及び不純物からなり、
前記鉄道車輪の前記板部のミクロ組織において、パーライトの面積率は85.0%以上であり、初析セメンタイトの面積率は0.90~15.00%であり、前記初析セメンタイトの最大幅は1.80μm以下である、
鉄道車輪。 - 請求項3に記載の鉄道車輪であって、
前記鉄道車輪の前記ボス部のミクロ組織において、パーライトの面積率は85.0%以上であり、前記初析セメンタイトの面積率は0.90~15.00%であり、前記初析セメンタイトの最大幅は1.80μm以下である、
鉄道車輪。 - 請求項1~請求項4のいずれか1項に記載の鉄道車輪であって、
前記化学組成は、
Cr:0.02~0.60%、及び、
V:0.02~0.12%、
からなる群から選択される1元素以上を含有する、
鉄道車輪。
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