WO2020013373A1 - Fire extinguishing sheet and tape having excellent flexibility and self-extinguishing function, and manufacturing method therefor - Google Patents

Fire extinguishing sheet and tape having excellent flexibility and self-extinguishing function, and manufacturing method therefor Download PDF

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Publication number
WO2020013373A1
WO2020013373A1 PCT/KR2018/008578 KR2018008578W WO2020013373A1 WO 2020013373 A1 WO2020013373 A1 WO 2020013373A1 KR 2018008578 W KR2018008578 W KR 2018008578W WO 2020013373 A1 WO2020013373 A1 WO 2020013373A1
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Prior art keywords
fire
sheet
extinguishing
self
fighting
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PCT/KR2018/008578
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French (fr)
Korean (ko)
Inventor
이상열
김성엽
강성천
최석민
한석만
Original Assignee
주식회사 파이어캅
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Publication of WO2020013373A1 publication Critical patent/WO2020013373A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/30Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0007Solid extinguishing substances
    • A62D1/0021Microcapsules
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0064Gels; Film-forming compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/54Filled microcapsules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • B32B2307/4026Coloured within the layer by addition of a colorant, e.g. pigments, dyes

Definitions

  • the present invention relates to a fire-fighting sheet and tape having excellent ductility and having a self-extinguishing function and a method of manufacturing the same.
  • Gas fire extinguishing systems, powder fire extinguishing systems, aqueous fire extinguishing systems and the like are widely used as fire extinguishing systems in the event of fire.
  • the fire extinguishing mechanism of the gas fire extinguishing system is mainly extinguished by reducing the oxygen concentration of the fire source by physical fire extinguishing.
  • the powder fire extinguishing system the powder sprayed by the action of pressurized gas is brought into contact with a flame to extinguish through physicochemical suppression.
  • fire extinguishing is realized by three actions such as cooling of water fog, choking and blocking of heat radiation.
  • Korean Patent Registration No. 10-1756229 discloses a fire extinguishing sticker that automatically reacts to a fire occurring in front and rear of an outlet.
  • the conventional temperature-responsive fire extinguishing sticker was difficult to attach to the first bent or angled because of the lack of ductility, and second, it was difficult to produce a large size, that is, 250x250mm or more.
  • the present invention has been made in order to solve the above problems, it is configured to form an air layer in the fire protection disaster prevention layer to be excellent in ductility, can be attached to bent or angled, it is excellent in ductility that can be produced in a large size It is to provide a fire fighting sheet having a self-extinguishing function and a method of manufacturing the same.
  • Fire fighting sheet which is an embodiment of the present invention devised to solve the above problems, the sheet; And a fire prevention layer having a self-extinguishing function attached to one surface of the sheet, wherein the fire prevention layer includes: a fire prevention bead consisting of a polymer microcapsule with a fire fighting component embedded therein; And a binder including a ceramic powder and a copolymer to form an air layer in order to prevent the occurrence of cracks in sheet bending while allowing the fire prevention beads to adhere to the sheet, and has excellent ductility and self extinguishing function.
  • the fire fighting sheet may further include an adhesive layer formed on one surface of the fire fighting disaster prevention side.
  • the fire protection layer may further include a natural dye to give the color of the fire protection layer.
  • the fire protection layer may further include an oil for preventing the surface surface active effect and bubbles during curing.
  • the fire protection layer may further include a softener and a thickener for preventing static electricity and enhancing the flexibility of the fire protection beads.
  • the thickener may include at least one of hydrocyclophoryl mesyl-cellulose / mesyl cellulose and sodium alginate and zeolite.
  • the softener may include at least one of carbanite, mineral oil, vegetable oil.
  • the fire protection disaster beads may be included 40 to 60% by weight
  • the binder may be contained 30 to 50% by weight.
  • the ceramic powder may be 3 to 7% by weight
  • the copolymer may include 23 to 47% by weight.
  • the thickener may be 0.5 to 3% by weight
  • the softener may be included 0.5 to 3% by weight.
  • the dye may be contained 0.5 to 2.0% by weight.
  • the fire prevention disaster prevention layer the first disaster prevention layer in contact with the sheet; And a second disaster prevention layer having a plurality of protrusions protruding in a matrix form on the first disaster prevention layer.
  • the protrusion may be any one of a disc shape, a cylindrical shape, and a square plate shape.
  • the fire-fighting component is perfluoro propane, perfluorobutane, chlorotetrafluoroethane, pentafluoroethane, heptafluoropropane, trifluoromethane, hexafluoropropane, trifluoroiodide, hydrochloro It may include one or more materials selected from the group consisting of a fluorocarbon admixture and an incombustible inert gas mixed gas.
  • the method for manufacturing a fire fighting sheet includes the steps of preparing a sheet; fire fighting prevention beads, a binder including a ceramic powder and a copolymer, a softening agent, and a thickening agent: preparing the fire fighting disaster beads, the binder, Producing fire-fighting materials by supplying the softener and the thickener to an automatic stirrer and stirring; Coating the fire prevention material on the sheet by spraying the fire prevention material through a spraying device while transferring the sheet through a roller; Ventilating and drying the sheet coated with the fire prevention raw material to prepare an aid fire fighting sheet; And cutting the aid fire fighting sheet through an automatic cutting cutter to complete the fire fighting sheet.
  • the fire-fighting disaster prevention raw material the fire-fighting disaster prevention beads 40 to 60% by weight
  • the binder may include 30 to 50% by weight, vegetable oil 3 to 7% by weight.
  • a method for manufacturing a fire fighting sheet includes a method for manufacturing a fire fighting sheet having a protrusion having a matrix form, comprising: preparing a form having a groove having a matrix form corresponding to the protrusion; Curing and drying the fire prevention raw material into the formwork; Preparing a fire protection layer by separating the dried fire prevention material from the formwork; Attaching a double-sided adhesive tape to one surface of the fire protection layer may comprise the step of completing a fire fighting sheet having a sheet.
  • the fire protection beads consisting of polymer microcapsules are fixed using a copolymer, the ductility is strengthened by forming an air layer that generates itself upon stirring In addition, it is possible to provide a fire fighting seat that can be attached to a bent position.
  • the fire prevention disaster bead consisting of microcapsules and the copolymer is formed by stirring together the air layer is formed when stirring, it is possible to manufacture a firefighting sheet of a large size of 250 * 250mm or more do.
  • FIG. 1 is a cross-sectional view of a first embodiment of a sheet for fire fighting which is an embodiment of the present invention.
  • Figure 2 is a cross-sectional view of a second embodiment of a firefighting sheet which is one embodiment of the present invention.
  • FIG. 3 is a cross-sectional view of a third embodiment of a fire fighting seat according to one embodiment of the present invention.
  • FIG. 4 is a view for explaining the operation of the fire protection disaster beads used in the fire protection sheet which is an embodiment of the present invention.
  • Figure 5 is an image for explaining an example of producing a fire extinguishing sheet is an embodiment of the present invention in a variety of colors.
  • Figure 6 is an image showing that the fire fighting sheet which is an embodiment of the present invention has sufficient ductility.
  • FIG. 7 is a view showing an example in which the fire fighting sheet is an embodiment of the present invention attached to the angled position and the column position.
  • FIG. 8 is a view showing a practical example in which the fire fighting sheet is an embodiment of the invention in large size.
  • FIG. 9 is a flowchart for explaining a first embodiment of a fire fighting seat and a method of manufacturing the same according to another embodiment of the present invention.
  • FIG. 10 is a flow chart for explaining a second embodiment of a fire fighting seat and a method of manufacturing the same according to another embodiment of the present invention.
  • FIG. 1 is a cross-sectional view of a first embodiment of a firefighting sheet which is an embodiment of the present invention
  • Figure 2 is a cross-sectional view of a second embodiment of a firefighting sheet which is an embodiment of the present invention
  • Figure 3 is a firefighting sheet of an embodiment of the present invention It is sectional drawing of 3rd Example
  • FIG. 4 is a figure for demonstrating the operation
  • the fire fighting sheet as shown in FIG. 1 may be configured to include the sheet 10 and the fire prevention layer 20 largely.
  • Sheet 10 is made of a general synthetic resin material, or a paper material and the other surface is formed with an adhesive layer (not shown) so that the fire-fighting sheet according to the present invention can be attached to the object.
  • the fire protection layer 20 attached to one surface of the sheet 10 may be configured to include a fire protection bead consisting of a polymer microcapsule having a fire protection component embedded therein and a binder for fixing the fire protection bead so as to have a self-extinguishing function. Can be.
  • the fire fighting component may be a clean fire extinguishing agent notified by the Fire and Disaster Prevention Agency, and more specifically, perfluoropropane, perfluorobutane, chlorotetrafluoroethane, pentafluoroethane, heptafluoropropane, and trifluoro. It may include one or more substances selected from the group consisting of methane, hexafluoropropane, trifluoro iodide, hydrochlorofluorocarbon admixture and incombustible inert gas mixed gas.
  • Perblue orpropane is fluorine carbide in which all hydrogen atoms are replaced with fluorine atoms in the skeleton of n-propane, and its boiling point is -36.7 ° C and the digestion concentration is 7.3 vol%. It is environmentally friendly, non-toxic, inert, non-conductive and has an ODP (Ozone Layer Destruction Index) of zero.
  • the fluorobutane is a fluorine carbide in which all hydrogen atoms are replaced with fluorine atoms in the skeleton of n-propane, and has a boiling point of -2.2 ° C and a digestion concentration of 5.0 to 5.9 vol%. Colorless, non-flammable gas with low toxicity.
  • Chlorotetrafluoroethane is a substance in which four of the hydrogen atoms of ethane are replaced by fluorine atoms and one by chlorine atoms. Digestion concentrations range from 6.4 to 8.2 vol% and are commonly used under the name FE-241.
  • Pentafluoroloethane is a substance in which five of the hydrogen atoms of ethane are replaced with fluorine.
  • the boiling point is -11 ° C and the digestion concentration is 8.1 to 9.4 vol%. Due to its excellent stability, it is mostly compatible with metals and rubbers, and has a merit of requiring a small amount of chemicals per unit volume. Commonly referred to as HFC-125, FE-25.
  • Heptafluoropropane acts as a fire extinguishing agent and inhibits the activation of corals by the ability of radicals to absorb electrons.
  • Global ODP is 0, boiling point is -16.4 °C, and digestion concentration is 5.8 ⁇ 6.6 vol%.
  • HFC-227ea or FM-200 Commonly referred to as HFC-227ea or FM-200.
  • Trifluoromethane is the most economical, it does not contain bromine and chlorine, so ODP is zero and its toxicity is harmless. Digestion concentration is 14 ⁇ 15vol%, colorless and odorless and is commonly used under the names HFC-23 and FE-13.
  • Hexaflouropropane contains no bromine and chlorine, resulting in zero ODP and low toxicity. Commonly known as FE-36.
  • Trifluorodide has chemical extinguishing as well as physical extinguishing performance and the concentration of extinguishing agent is 3.1 vol%.
  • Hydrochlorofluorocarbon admixture is a fire extinguishing agent mixed with HCFC-123: HCFC-22: HCFC-124: C 10 H 16 in a ratio of 4.75%: 82%: 9.5%: 3.75%. vol%.
  • Incombustible inert gas mixtures include IG-1, IG-55, IG-100 and IG-541.
  • IG-1 has more than 99.9 vol% argon
  • IG-55 has 50 vol% nitrogen
  • Silver is more than 99.9% vol%
  • IG-541 is a mixed digestive agent consisting of 52vol% argon 40vol% and 8vol% carbon dioxide. They have zero ODP and do not possess chemical extinguishing properties and are mainly digested by lowering the concentration of oxygen in confined spaces. Even at concentrations of drugs that can exert digestive abilities, there is no problem with human breathing, so it can be used where people are.
  • Microcapsules are nano-sized, hollow ball capsules.
  • the microcapsules contain a number of firefighting components. Such microcapsules burst when a fire occurs and the temperature rises above the reference value (see FIG. 4) and the extinguishing component is directed to the ignition point.
  • the microcapsules use a thermoplastic resin so that the seal can be released by temperature.
  • the binder may be configured to include a copolymer and a ceramic powder in order to prevent cracking even during the bending of the sheet 10, while functioning to fix the fire protection beads.
  • the ceramic powder helps to spread the fire protection beads evenly, and the copolymer allows itself to form an air layer when stirred through a stirrer.
  • the embossing effect and the connection coupling force between the fire prevention beads by the air layer are improved, so that the break for the microcapsules does not occur even if the fire fighting sheet is bent or angled.
  • the ductility is imparted to the manufacturing process and the finished product, according to the example according to the present invention, it is possible to manufacture a fire extinguishing sheet having a large size of 250 mm * 250 mm or more, and to attach the sheet 10 to an angled or rounded place. Done.
  • the fire prevention layer 20 includes a first disaster prevention layer 21 in contact with the sheet 10 and a second disaster prevention layer 22 protruding from the first disaster prevention layer 21. Can be.
  • the second disaster prevention layer 22 is a form having a plurality of protrusions protruding in a matrix form on the first disaster prevention layer 21, the protrusion may be any one of a disk, cylindrical, square plate shape. . It is to be understood that the shape of the protrusions is only one example and can be manufactured in various forms.
  • the fire-fighting sheet having the fire prevention layer 20 embossed (protrusion or block type) as in the second embodiment since the outside air contact area is wider than in the first embodiment, the fire fighting efficiency can be improved. do.
  • the protruding second disaster prevention layer has an effect of suppressing the transfer of flame.
  • the fire that is normally generated is diffused while moving on the wall or the ceiling.
  • the second disaster prevention layer of the second embodiment according to the present invention has a plurality of matrix-shaped protrusions, and the second disaster prevention layer serves not only as a structure for preventing the flame from moving laterally.
  • the self-extinguishing function is also exhibited against the flame in the transverse direction. Accordingly, it has the function of extending the golden time of the fire by preventing the spread of the flame as much as possible to block the movement of the flame to the surroundings.
  • the first disaster prevention layer 21 and the second disaster prevention layer 22 are made of the same material, and a manufacturing method thereof will be described with reference to FIGS. 9 and 10.
  • an adhesive layer 10 ′ may be further formed on the other surface of the fire prevention disaster prevention layer 20 for the directing direction of the fire protection component, which corresponds to the third embodiment shown in FIG. 3.
  • the sheet 10 is formed on one surface and the adhesive layer 10 ′ is formed on the other surface of the fire prevention layer 20.
  • the fire protection sheet can be attached to the structure in the direction in which the fire prevention layer 20 is directed, thereby increasing the utilization.
  • the portability can be improved by configuring in the form of a tape.
  • the adhesive layer (10 ') is configured in the form of a cylindrical tape can be configured to detach the adhesive layer (10 ') as needed, and then cut to a suitable size by the user to attach the adhesive layer (10') to the object.
  • the other surface of the sheet 10, that is, the surface on which the fire prevention layer 20 is not attached may be configured so that a separate adhesive is not attached.
  • Fire protection layer 20 fire protection beads, binders, thickeners, softeners, may be configured to include a natural dye.
  • Fire disaster prevention beads may be included 40 to 60% by weight relative to the fire prevention layer 20. When included in less than 40% by weight, the fire efficiency is reduced, when included in more than 60% by weight, the adhesive force to the sheet 10 paper falls and there is a problem that the crack or chipping is issued.
  • the binder is 30 to 50% by weight, more specifically, the ceramic powder is 3 to 7% by weight, the copolymer is to be included 23 to 47% by weight.
  • the ceramic powder plays a role of uniform distribution per area of the capsule raw material when coating the area, while the copolymer functions as a binding function, thereby increasing the connection bonding force between the coating raw materials through blending with each other to smooth the warpage. To improve the deflection by forming an air layer. It is a function to reduce cracking.
  • the thickener is 0.5 to 3% by weight
  • the softener is 0.5 to 3% by weight
  • the thickener may include at least one of hydrocyclophoryl mesyl- cellulose / mesyl cellulose and solidium alginate, geolite
  • the softener may include at least one of carbanite, mineral oil, vegetable oil, and the softener functions to increase processability.
  • the softening agent functions to alleviate the surface surfactant effect and surface roughness and to prevent bubble phenomenon during curing.
  • Vegetable oils can be used in place of these thickeners and emollients. Jojoba oil, olive oil, soybean oil and the like can be used as a vegetable oil, and serves to prevent the surface surfactant effect and bubbles during curing.
  • a small amount of natural dye may also be added to give the color of the fire fighting sheet.
  • FIG. 5 is an image for explaining an example in which the fire fighting sheet is an embodiment of the present invention in a variety of colors. As illustrated in FIG. 5, the fire fighting sheet according to the present invention may be manufactured in various colors.
  • Figure 6 is an image showing that the fire fighting sheet which is an embodiment of the present invention has sufficient ductility.
  • the fire extinguishing sheet according to the embodiment of the present invention is very excellent in ductility, and can be adhered to the cylindrical structure as it is, as well as being adhered as it is, without breaking or breaking the fire protection layer 20 even at an angle such as an edge. It can be attached as it is.
  • FIG. 7 is a view showing an example in which the fire fighting sheet is an embodiment of the present invention attached to the angled position and the column position.
  • the fire fighting sheet according to an embodiment of the present invention is excellent in ductility and can be attached to the inner surface or the outer surface of the corner of the square pillar (O) that is the attachment object, respectively (Fig. 7 (a)),
  • the attachment object is a column structure (O)
  • the inside or outside of the column structure (O) is attached round to the inside of the fire protection layer 20
  • the fire prevention layer 20 is facing outward it is possible to extinguish the fire generated from the outside of the pillar structure (O).
  • FIG. 8 is a view showing a practical example in which the fire fighting seat is an embodiment of the invention in large size.
  • the fire protection material according to the present invention is excellent in ductility during the manufacturing process it is possible to manufacture a fire sheet for a large size of 250mm * 250mm or more.
  • the sheet 10 is prepared (S11).
  • a material which becomes a raw material of the fire prevention layer 20, such as fire prevention beads, a binder including a ceramic powder and a copolymer, a softener and a thickener, an oil and a natural dye is prepared (S12).
  • these fire fighting disaster prevention raw materials are mixed in a stirrer to produce the fire prevention disaster prevention raw material (S13).
  • Such a first embodiment is a method of manufacturing the first embodiment and the third embodiment of the fire-fighting sheet which is one embodiment of the present invention described in FIGS. 1 and 3.
  • FIG. 10 is a flow chart for explaining a second embodiment of a fire fighting sheet and a method of manufacturing the same according to another embodiment of the present invention.
  • a mold having a groove having a matrix form corresponding to the protrusion is prepared (S21).
  • the fire-prevention raw material is added to the die and cured and dried (S22, S23).
  • a fire fighting disaster prevention layer 20 is manufactured by separating the dried fire prevention disaster prevention raw material from the mold, and attaching a double-sided adhesive tape to one surface of the fire protection disaster prevention layer 20 to complete a fire protection sheet having a sheet 10 ( S24).
  • the method according to the first embodiment it is possible to produce a fire-fighting sheet having a projection in the form of a matrix. That is, in the first embodiment, after attaching a plurality of shape films on the sheet paper, and then coating the fire-fighting disaster prevention raw material, the production of the fire-fighting sheet having a plurality of protrusions on the sheet by the plurality of shape films may be completed. It should be understood.
  • the fire protection beads consisting of polymer microcapsules are fixed using a copolymer, the ductility is strengthened by forming an air layer that generates itself upon stirring In addition, it is possible to provide a fire fighting seat that can be attached to a bent position.
  • the fire prevention disaster bead consisting of microcapsules and the copolymer is formed by stirring together the air layer is formed when stirring, it is possible to manufacture a firefighting sheet of a large size of 250 * 250mm or more do.
  • the fire extinguishing sheet having excellent ductility as described above and having a self-extinguishing function and a method of manufacturing the same are not limited to the configuration and operation of the embodiments described above.
  • the above embodiments may be configured such that various modifications may be made by selectively combining all or part of the embodiments.

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Abstract

The present invention relates to a fire extinguishing sheet having excellent flexibility and a self-extinguishing function, and a manufacturing method therefor, the fire extinguishing sheet comprising a sheet and a fire prevention layer, which is attached to one surface of the sheet and has a self-extinguishing function, wherein the fire prevention layer comprises: a fire prevention bead having polymer microcapsules containing fire-extinguishing substances; and a binder, which comprises a ceramic powder and a copolymer, for adhering the fire prevention bead to the sheet and forming an air layer in order to prevent the generation of cracks even if sheet bending occurs.

Description

연성이 우수하며 자기 소화기능을 갖는 소방용 시트와 테이프 및 그 제조 방법 Fire-fighting sheet and tape with excellent ductility and self-extinguishing function and method of manufacturing the same
본 발명은 연성이 우수하며 자기 소화기능을 갖는 소방용 시트와 테이프 및 그 제조 방법에 관한 것이다.The present invention relates to a fire-fighting sheet and tape having excellent ductility and having a self-extinguishing function and a method of manufacturing the same.
화재발생시의 소화시스템으로서 기체 소화 시스템, 분말 소화 시스템, 수계 소화 시스템 등이 널리 이용되고 있다. 기체 소화 시스템의 소화 메커니즘은 주로 물리적 소화로 화재 발생지의 산소 농도를 절감시킴으로써 소화시키고, 분말 소화 시스템에 의하면 가압 기체의 작용으로 분사되는 분말을 불꽃에 접촉시켜 물리 화학 억제 작용을 통하여 소화하고, 수계 소화 시스템에 의하면 물안개의 냉각, 질식, 열 복사의 차단 등 3가지 작용으로 화재를 억제하여 소화 목적을 실현한다.Gas fire extinguishing systems, powder fire extinguishing systems, aqueous fire extinguishing systems and the like are widely used as fire extinguishing systems in the event of fire. The fire extinguishing mechanism of the gas fire extinguishing system is mainly extinguished by reducing the oxygen concentration of the fire source by physical fire extinguishing. According to the powder fire extinguishing system, the powder sprayed by the action of pressurized gas is brought into contact with a flame to extinguish through physicochemical suppression. According to the fire extinguishing system, fire extinguishing is realized by three actions such as cooling of water fog, choking and blocking of heat radiation.
아파트와 같은 집단시설 화재, 지하도 및 지하철 화재 등의 경우, 유독 물질 및 가스 발생으로 인하여 직접 위 소화 시스템으로 소화하기가 용이하지 않다. 화재가 확산되는 것을 저지하기 위하여 위 시설에 난연성 재료나 도료가 사용되어 수동적으로 화재 확산을 저지하고 있기는 하지만, 기존 소화 시스템과 같이 적극적으로 화재를 진압할 수 있는 방안이 필요하다. 마찬가지로, 스마트폰 배터리, 컴퓨터, 전기 모터, 배전판 등 고온의 열이 발생하는 장치에는 난연성 필름이나 난연성 시트가 함께 채택되는 경우가 많지만, 이들 기구나 장치에도 보다 적극적인 소화 시스템이 필요하다.In the case of group facility fires such as apartments, underpasses and subway fires, it is not easy to extinguish the gastrointestinal system directly due to the generation of toxic substances and gases. Although flame retardant materials or paints are used in the above facilities to prevent the spread of fire, the fire spread is passively prevented. However, there is a need to actively extinguish the fire like the existing fire extinguishing system. Similarly, flame retardant films or flame retardant sheets are often employed in devices that generate high temperature heat, such as smartphone batteries, computers, electric motors, and distribution boards, but more aggressive fire extinguishing systems are required for these devices and devices.
이에 따라 온도 반응형 소화용 스티커가 개발되었다. 한국 등록 특허 10-1756229호에는, 콘센트 전후면에 발생하는 화재에 대하여 자동으로 반응하는 소화용 스티커가 개시되어 있다. Accordingly, a temperature responsive fire extinguishing sticker has been developed. Korean Patent Registration No. 10-1756229 discloses a fire extinguishing sticker that automatically reacts to a fire occurring in front and rear of an outlet.
하지만, 종래의 온도 반응형 소화용 스티커는 연성이 부족하여서 첫째 구부러지거나 각진 곳에 부착시키는 것이 어려웠고, 둘째, 대형 사이즈 즉, 250x250mm 이상의 사이즈로 제작하는 것이 어려웠다.However, the conventional temperature-responsive fire extinguishing sticker was difficult to attach to the first bent or angled because of the lack of ductility, and second, it was difficult to produce a large size, that is, 250x250mm or more.
더욱이, 또한 2차 코팅으로 인한 돌출형(블록), 엠보싱, 레일형태, 매트릭스 타입 등의 다양한 형태에 대한 고객이 요구하는 제품을 제작하는 것도 어려웠다.Moreover, it was also difficult to produce products that the customer required for various shapes such as protrusions (blocks), embossing, rail types, matrix types, etc. due to the secondary coating.
본 발명은 상술한 문제점을 해결하기 위하여 안출된 것으로서, 소방 방재층 내에 공기층을 형성하여 연성이 우수하도록 구성하여, 휘어지거나 각진 곳에도 부착이 가능하고, 대형 사이즈로도 제작이 가능한 연성이 우수하며 자기 소화기능을 갖는 소방용 시트 및 그 제조 방법을 제공하기 위한 것이다.The present invention has been made in order to solve the above problems, it is configured to form an air layer in the fire protection disaster prevention layer to be excellent in ductility, can be attached to bent or angled, it is excellent in ductility that can be produced in a large size It is to provide a fire fighting sheet having a self-extinguishing function and a method of manufacturing the same.
상술한 과제를 해결하기 위하여 안출된 본 발명의 일실시예인 소방용 시트는, 시트; 및 상기 시트의 일면에 부착되는 자기소화기능을 구비한 소방 방재층을 포함하고, 상기 소방방재층은, 소방 성분이 내장된 폴리머 마이크로 캡슐로 구성되는 소방방재 비드; 및 상기 소방 방재 비드가 상기 시트에 부착되게 하면서 시트 굽힘에도 크랙 발생을 예방하기 위하여 공기층을 형성되도록 하는 세라믹파우더 및 공중합체를 포함하는 바인더를 포함하여 연성이 우수하고 자기 소화 기능을 갖는다.Fire fighting sheet which is an embodiment of the present invention devised to solve the above problems, the sheet; And a fire prevention layer having a self-extinguishing function attached to one surface of the sheet, wherein the fire prevention layer includes: a fire prevention bead consisting of a polymer microcapsule with a fire fighting component embedded therein; And a binder including a ceramic powder and a copolymer to form an air layer in order to prevent the occurrence of cracks in sheet bending while allowing the fire prevention beads to adhere to the sheet, and has excellent ductility and self extinguishing function.
여기서, 상기 소방용 시트는,상기 소방 방재측의 일면에 형성되는 접착제층을 더 포함할 수 있다.Here, the fire fighting sheet may further include an adhesive layer formed on one surface of the fire fighting disaster prevention side.
여기서, 상기 소방 방재층은, 상기 소방방재층의 색상을 부여하는 천연 염료를 더 포함할 수 있다.Here, the fire protection layer may further include a natural dye to give the color of the fire protection layer.
여기서, 상기 소방 방재층은, 표면 계면 활성 효과 및 경화시 기포현상을 방지하기 위한 오일을 더 포함할 수 있다.Here, the fire protection layer may further include an oil for preventing the surface surface active effect and bubbles during curing.
여기서, 상기 소방 방재층은, 정전기 방지 및 상기 소방 방재 비드의 유연성 강화를 위한 연화제 및 점증제를 더 포함할 수 있다.Here, the fire protection layer may further include a softener and a thickener for preventing static electricity and enhancing the flexibility of the fire protection beads.
여기서, 상기 점증제는, 하이드로시포로필메실-셀루로스/메실 셀루로스 그리고 솔리디움 알지네이트, 지오라이트 중 적어도 하나를 포함할 수 있다.Here, the thickener may include at least one of hydrocyclophoryl mesyl-cellulose / mesyl cellulose and sodium alginate and zeolite.
여기서, 상기 연화제는, 카바나이트, 광유, 식물유, 중 적어도 하나를 포함할 수 있다.Here, the softener may include at least one of carbanite, mineral oil, vegetable oil.
여기서, 상기 소방 방재 비드는 40~60 중량% 포함되고, 상기 바인더는 30~50 중량% 포함될 수 있다.Here, the fire protection disaster beads may be included 40 to 60% by weight, the binder may be contained 30 to 50% by weight.
여기서, 상기 세라믹 파우더는 3~7 중량%, 상기 공중합체는 23~47 중량% 포함될 수 있다.Here, the ceramic powder may be 3 to 7% by weight, the copolymer may include 23 to 47% by weight.
여기서, 상기 점증제는 0.5~3중량%, 상기 연화제는 0.5~3중량% 포함될 수 있다.Here, the thickener may be 0.5 to 3% by weight, the softener may be included 0.5 to 3% by weight.
여기서, 상기 염료는 0.5~2.0 중량 % 포함될 수 있다.Here, the dye may be contained 0.5 to 2.0% by weight.
여기서, 상기 소방 방재층은, 상기 시트에 접하는 제 1 방재층; 및 상기 제 1 방재층 위에 매트릭스 형태로 돌출 형성되는 다수의 돌출부를 구비한 제 2 방재층을 포함할 수 있다.Here, the fire prevention disaster prevention layer, the first disaster prevention layer in contact with the sheet; And a second disaster prevention layer having a plurality of protrusions protruding in a matrix form on the first disaster prevention layer.
여기서, 상기 돌출부는 원판형, 원통형, 사각판형 중 어느 하나일 수 있다.Here, the protrusion may be any one of a disc shape, a cylindrical shape, and a square plate shape.
여기서, 상기 소방 성분은, 퍼플루오로프로판, 퍼플루오로부탄, 클로로테트라플루오르에탄, 펜타플루오로에탄, 헵타플루오로프로판, 트리플루오로메탄, 헥사플루오로프로판, 트리플루오로이오다이드, 하이드로클로로플루오로카본 혼화제 및 불연성불활성기체 혼합가스로 이루어지는 군 중 선택되는 물질을 하나 이상 포함할 수 있다.Here, the fire-fighting component is perfluoro propane, perfluorobutane, chlorotetrafluoroethane, pentafluoroethane, heptafluoropropane, trifluoromethane, hexafluoropropane, trifluoroiodide, hydrochloro It may include one or more materials selected from the group consisting of a fluorocarbon admixture and an incombustible inert gas mixed gas.
본 발명의 다른 실시예인 소방용 시트 제조 방법은, 시트를 준비하는 단계;소방 방재 비드, 세라믹 파우더와 공중합체를 포함하는 바인더, 연화제, 및 점증제를 준비하는 단계: 상기 소방 방재 비드, 상기 바인더, 상기 연화제 및 상기 점증제를 자동교반기에 공급하여 교반시킴으로써 소방 방재 원료를 생산하는 단계; 상기 시트를 롤러를 통해 이송시키면서, 분사 장치를 통해 상기 소방 방재 원료를 분사하여 상기 시트상에 소방 방재 원료를 코팅하는 단계; 상기 소방 방재 원료가 코팅된 시트를 송풍 건조하여 원조 소방용 시트를 제작하는 단계; 및 상기 원조 소방용 시트를 자동 커팅 절단기를 통해 커팅하여 소방용 시트를 완성하는 단계를 포함할 수 있다.In another embodiment of the present invention, the method for manufacturing a fire fighting sheet includes the steps of preparing a sheet; fire fighting prevention beads, a binder including a ceramic powder and a copolymer, a softening agent, and a thickening agent: preparing the fire fighting disaster beads, the binder, Producing fire-fighting materials by supplying the softener and the thickener to an automatic stirrer and stirring; Coating the fire prevention material on the sheet by spraying the fire prevention material through a spraying device while transferring the sheet through a roller; Ventilating and drying the sheet coated with the fire prevention raw material to prepare an aid fire fighting sheet; And cutting the aid fire fighting sheet through an automatic cutting cutter to complete the fire fighting sheet.
여기서, 상기 소방 방재 원료는, 상기 소방 방재 비드 40~60 중량%, 상기 바인더는 30~50 중량%, 식물성 오일 3~7%중량 를 포함할 수 있다.Here, the fire-fighting disaster prevention raw material, the fire-fighting disaster prevention beads 40 to 60% by weight, the binder may include 30 to 50% by weight, vegetable oil 3 to 7% by weight.
본 발명의 또 다른 실시예인 소방용 시트 제조 방법은, 매트릭스 형태의 돌출부를 구비한 소방용 시트 제조 방법으로서, 상기 돌출부에 대응하는 매트릭스 형태의 홈을 구비한 거푸집을 준비하는 단계; 상기 거푸집에 소방 방재 원료를 투입한 후 경화 건조하는 단계; 건조된 소방 방재 원료를 상기 거푸집에서 분리하여 소방 방재층을 제조하는 단계; 상기 소방 방재층의 일면에 양면 접착 테이프를 부착하여 시트를 구비하는 소방용 시트를 완성하는 단계를 포함할 수 있다.In another embodiment of the present invention, a method for manufacturing a fire fighting sheet includes a method for manufacturing a fire fighting sheet having a protrusion having a matrix form, comprising: preparing a form having a groove having a matrix form corresponding to the protrusion; Curing and drying the fire prevention raw material into the formwork; Preparing a fire protection layer by separating the dried fire prevention material from the formwork; Attaching a double-sided adhesive tape to one surface of the fire protection layer may comprise the step of completing a fire fighting sheet having a sheet.
상술한 구성을 가진 본 발명의 일실시예에 따르면, 공중합체를 이용하여 폴리머 마이크로 캡슐로 구성되는 소방방재 비드를 고정하게 되므로, 교반시 자체적으로 발생하는 공기층을 형성하여 연성이 강화되게 되어서 각진 곳이나 구부러진 곳에도 부착이 가능한 소방용 시트를 제공할 수 있게 된다. According to one embodiment of the present invention having the above-described configuration, since the fire protection beads consisting of polymer microcapsules are fixed using a copolymer, the ductility is strengthened by forming an air layer that generates itself upon stirring In addition, it is possible to provide a fire fighting seat that can be attached to a bent position.
또한, 본 발명의 일실시예에 따르면, 마이크로 캡슐로 구성되는 소방 방재 비드와 교반시 공기층이 형성되는 공중합체를 함께 교반하여 제작하게 되므로, 250*250mm 이상의 대형사이즈의 소방용 시트의 제작이 가능하게 된다. In addition, according to an embodiment of the present invention, since the fire prevention disaster bead consisting of microcapsules and the copolymer is formed by stirring together the air layer is formed when stirring, it is possible to manufacture a firefighting sheet of a large size of 250 * 250mm or more do.
도 1은 본 발명의 일실시예인 소방용 시트의 제 1 실시예의 단면도.1 is a cross-sectional view of a first embodiment of a sheet for fire fighting which is an embodiment of the present invention.
도 2는 본 발명의 일실시예인 소방용 시트의 제 2 실시예의 단면도.Figure 2 is a cross-sectional view of a second embodiment of a firefighting sheet which is one embodiment of the present invention.
도 3은 본 발명의 일실시예인 소방용 시트의 제 3 실시예의 단면도3 is a cross-sectional view of a third embodiment of a fire fighting seat according to one embodiment of the present invention;
도 4는, 본 발명의 일실시예인 소방용 시트에 사용되는 소방 방재 비드의 동작을 설명하기 위한 도면.4 is a view for explaining the operation of the fire protection disaster beads used in the fire protection sheet which is an embodiment of the present invention.
도 5는 본 발명의 일실시예인 소방용 시트가 다양한 색상으로 제작되는 예를 설명하기 위한 이미지도.Figure 5 is an image for explaining an example of producing a fire extinguishing sheet is an embodiment of the present invention in a variety of colors.
도 6은 본 발명의 일실시예인 소방용 시트가 충분한 연성을 가짐을 나타내는 이미지도.Figure 6 is an image showing that the fire fighting sheet which is an embodiment of the present invention has sufficient ductility.
도 7은 본 발명의 일실시예인 소방용 시트가 각이진 위치 및 기둥 위치에 부착되는 예를 나타내는 도면. 7 is a view showing an example in which the fire fighting sheet is an embodiment of the present invention attached to the angled position and the column position.
도 8은 발명의 일실시예인 소방용 시트가 대형으로 제작된 실제 예를 나타내는 도면. 8 is a view showing a practical example in which the fire fighting sheet is an embodiment of the invention in large size.
도 9는 본 발명의 다른 실시예인 소방용 시트 및 그 제조 방법의 제 1 실시예를 설명하기 위한 흐름도. 9 is a flowchart for explaining a first embodiment of a fire fighting seat and a method of manufacturing the same according to another embodiment of the present invention.
도 10은 본 발명의 다른 실시예인 소방용 시트 및 그 제조 방법의 제 2 실시예를 설명하기 위한 흐름도.10 is a flow chart for explaining a second embodiment of a fire fighting seat and a method of manufacturing the same according to another embodiment of the present invention.
이하, 본 발명의 바람직한 실시예에 따른 연성이 우수하며 자기 소화기능을 갖는 소방용 시트 와 테이프 및 그 제조 방법에 대하여 첨부한 도면을 참조하여 상세히 설명한다. 본 명세서에서는 서로 다른 실시예라도 동일*유사한 구성에 대해서는 동일*유사한 참조번호를 부여하고, 그 설명은 처음 설명으로 갈음한다.Hereinafter, a fire extinguishing sheet having excellent softness and having a self-extinguishing function according to a preferred embodiment of the present invention and a tape and a method of manufacturing the same will be described in detail with reference to the accompanying drawings. In the present specification, even if different embodiments are given the same * similar reference numerals for the same * similar configuration, the description is replaced with the first description.
도 1은 본 발명의 일실시예인 소방용 시트의 제 1 실시예의 단면도이고, 도 2는 본 발명의 일실시예인 소방용 시트의 제 2 실시예의 단면도이며, 도 3은 본 발명의 일실시예인 소방용 시트의 제 3 실시예의 단면도이고, 도 4는, 본 발명의 일실시예인 소방용 시트에 사용되는 소방 방재 비드의 동작을 설명하기 위한 도면이다. 1 is a cross-sectional view of a first embodiment of a firefighting sheet which is an embodiment of the present invention, Figure 2 is a cross-sectional view of a second embodiment of a firefighting sheet which is an embodiment of the present invention, Figure 3 is a firefighting sheet of an embodiment of the present invention It is sectional drawing of 3rd Example, FIG. 4 is a figure for demonstrating the operation | movement of the fire prevention disaster prevention beads used for the fire protection sheet which is one Embodiment of this invention.
도 1에 도시된 바와 같은 소방용 시트는 크게 시트(10)와 소방 방재층(20)을 포함하여 구성될 수 있다. The fire fighting sheet as shown in FIG. 1 may be configured to include the sheet 10 and the fire prevention layer 20 largely.
시트(10)는 일반적인 합성 수지재, 또는 종이재로 이루어지며 타면에는 접착제층(미도시)이 형성되어서 본 발명에 따른 소방용 시트가 목적물에 부착될 수 있게 구성된다. Sheet 10 is made of a general synthetic resin material, or a paper material and the other surface is formed with an adhesive layer (not shown) so that the fire-fighting sheet according to the present invention can be attached to the object.
시트(10)의 일면에 부착되는 소방 방재층(20)은 자기 소화기능을 구비하도록 소방 성분이 내장된 폴리머 마이크로 캡슐로 구성되는 소방 방재 비드와 소방 방재 비드를 고정하기 위한 바인더를 포함하여 구성될 수 있다.The fire protection layer 20 attached to one surface of the sheet 10 may be configured to include a fire protection bead consisting of a polymer microcapsule having a fire protection component embedded therein and a binder for fixing the fire protection bead so as to have a self-extinguishing function. Can be.
소방성분으로는, 소방 방재청에서 고시하는 청정 소화 약제일 수 있으며, 보다 구체적으로는, 퍼플루오로프로판, 퍼플루오로부탄, 클로로테트라플루오르에탄, 펜타플루오로에탄, 헵타플루오로프로판, 트리플루오로메탄, 헥사플루오로프로판, 트리플루오로이오다이드, 하이드로클로로플루오로카본 혼화제 및 불연성불활성기체 혼합가스로 이루어지는 군 중 선택되는 물질을 하나 이상를 포함할 수 있다.The fire fighting component may be a clean fire extinguishing agent notified by the Fire and Disaster Prevention Agency, and more specifically, perfluoropropane, perfluorobutane, chlorotetrafluoroethane, pentafluoroethane, heptafluoropropane, and trifluoro. It may include one or more substances selected from the group consisting of methane, hexafluoropropane, trifluoro iodide, hydrochlorofluorocarbon admixture and incombustible inert gas mixed gas.
퍼블루오르프로판은 n-프로판의 골격에서 모든 수소 원자가 불소 원자로 치환되는 탄화 불소로서, 끓는점이 -36.7℃이고, 소화 농도가 7.3vol%이다. 친환경적이며 무독성이고, 불활성, 비전도성이며 ODP(오존층 파괴지수)가 0이다.Perblue orpropane is fluorine carbide in which all hydrogen atoms are replaced with fluorine atoms in the skeleton of n-propane, and its boiling point is -36.7 ° C and the digestion concentration is 7.3 vol%. It is environmentally friendly, non-toxic, inert, non-conductive and has an ODP (Ozone Layer Destruction Index) of zero.
퍼블로오로부탄은, n-프로판의 골격에서 모든 수소 원자가 불소 원자로 치환되는 탄화 불소로서, 끓는점이 -2.2℃이고, 소화 농도가 5.0~5.9vol%이다. 무색의 비가연성 가스로서 독성이 낮다.The fluorobutane is a fluorine carbide in which all hydrogen atoms are replaced with fluorine atoms in the skeleton of n-propane, and has a boiling point of -2.2 ° C and a digestion concentration of 5.0 to 5.9 vol%. Colorless, non-flammable gas with low toxicity.
클로로테트라플루오르에탄은 에탄의 수소 원자 중 4개는 불소 원자로 1개는 염소 원자로 치환한 물질이다. 소화 농도는 6.4~8.2vol%이며, FE-241라는 이름으로 통용된다. Chlorotetrafluoroethane is a substance in which four of the hydrogen atoms of ethane are replaced by fluorine atoms and one by chlorine atoms. Digestion concentrations range from 6.4 to 8.2 vol% and are commonly used under the name FE-241.
펜타플로우로에탄은 에탄의 수소 원자 중 5개를 불소로 치환한 물질로서, 끓는 점이 -11℃이며, 소화 농도는 8.1~9.4vol%이다. 안정성이 뛰어나기 때문에 대부분 금속과 고무 등에 상용성이 있고, 단위 체적당 소요 약제량이 적다는 장점이 있다. HFC-125, FE-25라는 이름으로 통용된다. Pentafluoroloethane is a substance in which five of the hydrogen atoms of ethane are replaced with fluorine. The boiling point is -11 ° C and the digestion concentration is 8.1 to 9.4 vol%. Due to its excellent stability, it is mostly compatible with metals and rubbers, and has a merit of requiring a small amount of chemicals per unit volume. Commonly referred to as HFC-125, FE-25.
헵타플루오로프로판은 냉각 소화작용을 하며 래디칼의 전자 흡수 능력으로 산호의 활성화를 억제한다. ODP가 0, 끓는점이 -16.4℃, 소화 농도가 5.8~6.6 vol%로 전역 방출 방식이 적합하다. HFC-227ea 또는 FM-200이라는 이름으로 통용된다.Heptafluoropropane acts as a fire extinguishing agent and inhibits the activation of corals by the ability of radicals to absorb electrons. Global ODP is 0, boiling point is -16.4 ℃, and digestion concentration is 5.8 ~ 6.6 vol%. Commonly referred to as HFC-227ea or FM-200.
트리플로오로 메탄은 가장 경제적이고, 브롬과 염소를 함유하고 있지 않아 ODP가 0이며 독성이 낮아 인체에 무해하다. 소화 농도는 14~15vol%, 무색 무취이며, HFC-23, FE-13이라는 이름으로 통용된다. Trifluoromethane is the most economical, it does not contain bromine and chlorine, so ODP is zero and its toxicity is harmless. Digestion concentration is 14 ~ 15vol%, colorless and odorless and is commonly used under the names HFC-23 and FE-13.
헥사플르오로프로판은 브롬과 염소를 함유하고 있지 않아 ODP 가 0이며 독성이 낮다. FE-36이라는 이름으로 통용된다. Hexaflouropropane contains no bromine and chlorine, resulting in zero ODP and low toxicity. Commonly known as FE-36.
트리플루오로다이드는 물리적 소화 성능 뿐만 아니라 화학적 소화 성능을 지니고 있으며 소화 약제의 농도는 3.1vol%이다.Trifluorodide has chemical extinguishing as well as physical extinguishing performance and the concentration of extinguishing agent is 3.1 vol%.
하이드로클로로플루오로카본 혼화제는 HCFC-123:HCFC-22:HCFC-124:C10H16가 4.75%:82%:9.5%:3.75%비율로 혼합된 소화약제로서 ODP가 0.044이고 소화 농도가 7.2vol%이다.Hydrochlorofluorocarbon admixture is a fire extinguishing agent mixed with HCFC-123: HCFC-22: HCFC-124: C 10 H 16 in a ratio of 4.75%: 82%: 9.5%: 3.75%. vol%.
불연성불활성 기체 혼합가스는 IG-1, IG-55, IG-100 및 IG-541이 있는데 IG-1은 아르곤이 99.9vol%이상, IG-55는 질소가 50vol%, 아르곤 50vol%, IG-100은 질소가 99.9%vol%이상, IG-541은 질소 52vol% 아르곤 40vol% 그리고 이산화탄소 8vol%로 이루어진 환(혼)합 소화 약제이다. 이들은 ODP가 0이며, 화학적 소화 특성을 지니고 있는 것이 아니고 주로 밀폐된 공간에서 산소의 농도를 낮추는 것에 의해 소화시킨다. 소화 성능을 발휘할 수 있는 약제의 농도에서도 사람의 호흡에 문제가 없으므로 사람이 있는 곳에도 사용할 수 있다.Incombustible inert gas mixtures include IG-1, IG-55, IG-100 and IG-541. IG-1 has more than 99.9 vol% argon, IG-55 has 50 vol% nitrogen, 50 vol% argon and IG-100. Silver is more than 99.9% vol%, IG-541 is a mixed digestive agent consisting of 52vol% argon 40vol% and 8vol% carbon dioxide. They have zero ODP and do not possess chemical extinguishing properties and are mainly digested by lowering the concentration of oxygen in confined spaces. Even at concentrations of drugs that can exert digestive abilities, there is no problem with human breathing, so it can be used where people are.
마이크로 캡슐은 그 크기가 나노 사이즈로서 속이 비어있는 공모양의 캡슐이다. 이 마이크로 캡슐 내에는 다수의 소방 성분이 내장되게 된다. 이와 같은 마이크로 캡슐은 화재가 발생되어서 온도가 기준값 이상으로 상승되게 되면, 터지게 되며 (도 4참조) 소화 성분이 발화점으로 향하게 된다. 이와 같이 밀봉이 온도에 의해 해제될 수 있도록 마이크로 캡슐은 열가소성 수지를 사용하게 된다. Microcapsules are nano-sized, hollow ball capsules. The microcapsules contain a number of firefighting components. Such microcapsules burst when a fire occurs and the temperature rises above the reference value (see FIG. 4) and the extinguishing component is directed to the ignition point. As such, the microcapsules use a thermoplastic resin so that the seal can be released by temperature.
본 발명에서 바인더는 소방 방재 비드를 고정하는 기능을 하면서도, 시트(10)의 굽힘등에도 크랙이 발생하지 않도록 하기 위하여 공중합체 및 세라믹 파우더를 포함하여 구성될 수 있다. 세라믹 파우더는 상기 소방 방재 비드가 고르게 퍼지도록 하는 것을 도와주며, 공중합체는, 교반기를 통해 교반하는 경우, 자체적으로 공기층을 형성하도록 한다. 이러한 공기층에 의한 엠보싱 효과 및 소방 방재 비드간의 연결 결합력이 향상되어서, 소방용 시트가 휘거나 각을 주더라도 마이크로 캡슐에 대한 깨어짐이 발생하게 되지 아니한다. 이와 같이 제조 공정 및 완성품에 대하여 연성을 부여하므로, 본 발명에 따른 예에 의하면 250mm*250mm 이상의 대형 사이즈의 소방용 시트의 제조가 가능하게 되며, 각진 곳이나 둥근 곳에 대해서도 시트(10)의 부착이 가능하게 된다. In the present invention, the binder may be configured to include a copolymer and a ceramic powder in order to prevent cracking even during the bending of the sheet 10, while functioning to fix the fire protection beads. The ceramic powder helps to spread the fire protection beads evenly, and the copolymer allows itself to form an air layer when stirred through a stirrer. The embossing effect and the connection coupling force between the fire prevention beads by the air layer are improved, so that the break for the microcapsules does not occur even if the fire fighting sheet is bent or angled. Thus, since the ductility is imparted to the manufacturing process and the finished product, according to the example according to the present invention, it is possible to manufacture a fire extinguishing sheet having a large size of 250 mm * 250 mm or more, and to attach the sheet 10 to an angled or rounded place. Done.
한편, 도 2에는 제 2 실시예가 도시되어 있다. 제 2 실시예의 경우 소방 방재층(20)은 시트(10)에 접하는 제 1 방재층(21)과, 제 1 방재층(21) 위에 돌출 형성되는 제 2 방재층(22)을 포함하여 구성될 수 있다. 2 shows a second embodiment. In the second embodiment, the fire prevention layer 20 includes a first disaster prevention layer 21 in contact with the sheet 10 and a second disaster prevention layer 22 protruding from the first disaster prevention layer 21. Can be.
제 2 방재층(22)은 상기 제 1 방재층(21) 위에 매트릭스 형태로 돌출 형성되는 다수의 돌출부를 구비한 형태가 되며, 돌출부의 형태는 원판형, 원통형, 사각판형 중 어느 하나일 수 있다. 돌출부의 형태는 하나의 예시에 불과하며 다양한 형태로 제작될 수 있음이 이해되어야 할 것이다. The second disaster prevention layer 22 is a form having a plurality of protrusions protruding in a matrix form on the first disaster prevention layer 21, the protrusion may be any one of a disk, cylindrical, square plate shape. . It is to be understood that the shape of the protrusions is only one example and can be manufactured in various forms.
제 2 실시예와 같이 엠보싱(돌출형 또는 블록형)된 소방 방재층(20)을 구비한 소방용 시트의 경우, 외기 접촉면적이 제 1 실시예보다 넓게 되므로, 소방효율을 높일 수 있다는 장점을 가지게 된다. 또한 돌출된 제 2 방재층은 화염의 전달을 억제하는 효과를 가진다. 상세하게 설명하면, 통상 발생된 화재가 확산되는 것은 벽 또는 천정등의 벽지등을 타고 이동하면서 확산되게 된다. 본 발명에 따른 제 2 실시예의 제 2 방재층은 다수의 매트릭스형태의 돌출부를 구비하며, 상기 제 2 방재층은, 화염이 횡방향으로 이동하는 것을 방지하는 구조물로서의 역할을 할 뿐 아니라. 횡방향의 화염에 대해서도 자기 소화기능을 발휘하게 된다. 이에 따라 화염의 확산이동을 최대한 방지하여 주변으로 화염이 이동하는 것을 차단하여 화재의 골든타임을 연장하는 기능을 가지게 된다. In the case of the fire-fighting sheet having the fire prevention layer 20 embossed (protrusion or block type) as in the second embodiment, since the outside air contact area is wider than in the first embodiment, the fire fighting efficiency can be improved. do. In addition, the protruding second disaster prevention layer has an effect of suppressing the transfer of flame. In detail, the fire that is normally generated is diffused while moving on the wall or the ceiling. The second disaster prevention layer of the second embodiment according to the present invention has a plurality of matrix-shaped protrusions, and the second disaster prevention layer serves not only as a structure for preventing the flame from moving laterally. The self-extinguishing function is also exhibited against the flame in the transverse direction. Accordingly, it has the function of extending the golden time of the fire by preventing the spread of the flame as much as possible to block the movement of the flame to the surroundings.
여기서 제 1 방재층(21)과 제 2 방재층(22)은 동일한 물질로 이루어지며, 이의 제조 방법에 대해서는 도 9와 도 10에서 설명하도록 한다.Here, the first disaster prevention layer 21 and the second disaster prevention layer 22 are made of the same material, and a manufacturing method thereof will be described with reference to FIGS. 9 and 10.
한편, 소방 성분의 표출 방향성을 위하여 소방 방재층(20)의 타면에는 접착제층(10')이 더 형성될 수 있으며, 이는 도 3에 도시된 제 3 실시예에 해당한다. 제 3 실시예에 따르면, 도 3에 도시된 바와 같이, 소방 방재층(20)을 중심으로 일면에는 시트(10)가, 타면에는 접착제층(10')이 형성된다. 이상과 같이 구성하게 되면, 소방 방재층(20)이 향하는 방향으로 있는 구조물에 소방용 시트를 부착시킬 수 있게 되어서 활용도가 높아지게 된다. 또한 제 3 실시예와 같이 구성하는 경우, 테이프 형태로 구성하여서 휴대성을 높일 수 있다. 즉, 원통형의 테이프 형태로 구성하여 필요에 따라 접착제층(10')을 일단 분리한 후, 사용자에 의해 적당한 사이즈로 커팅한 후 목적물에 접착제층(10')을 부착시킬 수 있게 구성될 수 있다. 이 때에는 시트(10)의 타면, 즉 소방방재층(20)이 부착되지 아니한 면에는 별도의 접착제가 부착되지 않게 구성될 수 있다. Meanwhile, an adhesive layer 10 ′ may be further formed on the other surface of the fire prevention disaster prevention layer 20 for the directing direction of the fire protection component, which corresponds to the third embodiment shown in FIG. 3. According to the third embodiment, as shown in FIG. 3, the sheet 10 is formed on one surface and the adhesive layer 10 ′ is formed on the other surface of the fire prevention layer 20. When configured as described above, the fire protection sheet can be attached to the structure in the direction in which the fire prevention layer 20 is directed, thereby increasing the utilization. In the case of the configuration as in the third embodiment, the portability can be improved by configuring in the form of a tape. That is, it is configured in the form of a cylindrical tape can be configured to detach the adhesive layer (10 ') as needed, and then cut to a suitable size by the user to attach the adhesive layer (10') to the object. . In this case, the other surface of the sheet 10, that is, the surface on which the fire prevention layer 20 is not attached may be configured so that a separate adhesive is not attached.
한편, 이와 같은 소방 방재층(20)의 구성 성분에 대하여 설명하도록 한다.On the other hand, the component of such a fire prevention layer 20 is demonstrated.
소방 방재층(20)은, 소방 방재 비드, 바인더, 점증제, 연화제, 천연 염료를 포함하여 구성될 수 있다. Fire protection layer 20, fire protection beads, binders, thickeners, softeners, may be configured to include a natural dye.
소방 방재 비드의 구성요소는 상술하였으므로 이에 대한 설명을 생략한다. 소방 방재 비드는 소방 방재층(20)에 대하여 40~60 중량% 포함될 수 있다. 40 중량% 이하로 포함되는 경우, 소방효율이 떨어지게 되며, 60중량% 이상 포함되게 되면, 시트(10)지에 대한 접착력이 떨어지며 깨짐이나 부스러짐 현상이 발행되는 문제점이 생긴다.Since the components of the fire protection beads have been described above, description thereof will be omitted. Fire disaster prevention beads may be included 40 to 60% by weight relative to the fire prevention layer 20. When included in less than 40% by weight, the fire efficiency is reduced, when included in more than 60% by weight, the adhesive force to the sheet 10 paper falls and there is a problem that the crack or chipping is issued.
바인더는 30~50 중량% 포함되며, 보다 구체적으로는 세라믹 파우더는 3~7 중량%, 공중합체는 23~47 중량% 포함되게 된다. 세라믹 파우더는, 상술한 바와 같이, 면적 코팅시 캡슐 원자재의 면적당 균일한 분포를 해주는 역할을 하며 공중합체는 바인딩 기능을 하면서도, 서로간의 배합을 통해 코팅 원자재 간의 연결 결합력을 높혀 주어 휘어짐을 원활하게 하며, 공기층 형성을 통해 휘어짐을 향상시켜 주고. 깨어짐 현상을 줄여주는 기능을 한다. The binder is 30 to 50% by weight, more specifically, the ceramic powder is 3 to 7% by weight, the copolymer is to be included 23 to 47% by weight. As described above, the ceramic powder plays a role of uniform distribution per area of the capsule raw material when coating the area, while the copolymer functions as a binding function, thereby increasing the connection bonding force between the coating raw materials through blending with each other to smooth the warpage. To improve the deflection by forming an air layer. It is a function to reduce cracking.
상기 점증제는 0.5~3중량%, 상기 연화제는 0.5~3중량% 포함되는데, 점증제는, 하이드로시포로필메실-셀루로스/메실 셀루로스 그리고 솔리디움 알지네이트, 지오라이트 중 적어도 하나를 포함할 수 있고, 연화제는, 카바나이트, 광유, 식물유, 중 적어도 하나를 포함하며 이 연화제는 가공성을 높이는 기능을 한다. 또한 연화제는 표면 계면 활성효과 및 표면 거칠기를 완화하고 경화시 기포 현상을 방지하는 기능을 한다. 이러한 점증제 및 연화제 대신에 식물성 오일을 사용할 수 있다. 식물성 오일로 호호바 오일, 올리브 오일, 콩유 등이 이용될 수 있으며, 표면 계면 활성 효과 및 경화시 기포현상을 방지하기 위한 기능을 한다.The thickener is 0.5 to 3% by weight, the softener is 0.5 to 3% by weight, the thickener may include at least one of hydrocyclophoryl mesyl- cellulose / mesyl cellulose and solidium alginate, geolite The softener may include at least one of carbanite, mineral oil, vegetable oil, and the softener functions to increase processability. In addition, the softening agent functions to alleviate the surface surfactant effect and surface roughness and to prevent bubble phenomenon during curing. Vegetable oils can be used in place of these thickeners and emollients. Jojoba oil, olive oil, soybean oil and the like can be used as a vegetable oil, and serves to prevent the surface surfactant effect and bubbles during curing.
또한 소방용 시트의 색상을 부여하기 위하여 천연 염료가 소량 첨가될 수 있다. A small amount of natural dye may also be added to give the color of the fire fighting sheet.
도 5는 본 발명의 일실시예인 소방용 시트가 다양한 색상으로 제작되는 예를 설명하기 위한 이미지도이다. 도 5에 도시된 바와 같이 본 발명에 따른 소방용 시트는 다양한 색상으로 제작될 수 있다.5 is an image for explaining an example in which the fire fighting sheet is an embodiment of the present invention in a variety of colors. As illustrated in FIG. 5, the fire fighting sheet according to the present invention may be manufactured in various colors.
도 6은 본 발명의 일실시예인 소방용 시트가 충분한 연성을 가짐을 나타내는 이미지도이다. 상술한 바와 같이, 본 발명의 일실시예인 소방용 시트는 연성이 매우 우수하므로, 원통형 구조물에 대하여 그대로 밀착하여 부착시킬 수 있을 뿐만 아니라 모서리와 같은 각진 곳에도 소방 방재층(20)의 부서짐이나 깨짐 없이 그대로 부착이 가능하게 된다. Figure 6 is an image showing that the fire fighting sheet which is an embodiment of the present invention has sufficient ductility. As described above, the fire extinguishing sheet according to the embodiment of the present invention is very excellent in ductility, and can be adhered to the cylindrical structure as it is, as well as being adhered as it is, without breaking or breaking the fire protection layer 20 even at an angle such as an edge. It can be attached as it is.
도 7은 본 발명의 일실시예인 소방용 시트가 각이진 위치 및 기둥 위치에 부착되는 예를 나타내는 도면이다. 도시된 바와 같이, 본 발명의 일실시예에 따른 소방용 시트는 연성이 우수하여 부착 객체인 사각 기둥(O)의 모서리의 내측면 또는 외측면에 각각 부착가능하며(도 7의(a)), 부착 객체가 기둥 구조물(O)인 경우, 기둥 구조물(O)의 내측 또는 외측으로도 라운드지게 부착이 되어서 소방 방재층(20)의 내측으로 향하는 경우, 기둥 구조물의 안쪽에서 화재가 발생하는 경우 진화가 가능하게 되고, 소방 방재층(20)이 외측을 향하게 되는 경우 기둥 구조물(O)의 외부에서 발생되는 화재를 진화시킬 수 있게 된다. 7 is a view showing an example in which the fire fighting sheet is an embodiment of the present invention attached to the angled position and the column position. As shown, the fire fighting sheet according to an embodiment of the present invention is excellent in ductility and can be attached to the inner surface or the outer surface of the corner of the square pillar (O) that is the attachment object, respectively (Fig. 7 (a)), When the attachment object is a column structure (O), when the inside or outside of the column structure (O) is attached round to the inside of the fire protection layer 20, if the fire occurs inside the column structure extinguish It becomes possible, if the fire prevention layer 20 is facing outward it is possible to extinguish the fire generated from the outside of the pillar structure (O).
도 8은 발명의 일실시예인 소방용 시트가 대형으로 제작된 실제 예를 나타내는 도면이다. 본 발명에 따른 소방 방재재료에 의하면 제조 공정시 연성이 우수하게 되어서 250mm*250mm 이상의 대형사이즈의 소방용 시트도 제작이 가능하게 된다. 8 is a view showing a practical example in which the fire fighting seat is an embodiment of the invention in large size. According to the fire protection material according to the present invention is excellent in ductility during the manufacturing process it is possible to manufacture a fire sheet for a large size of 250mm * 250mm or more.
이하 상술한 구성 및 효과를 가지는 본 발명의 일실시예인 소방용 시트를 제작하는 방법에 대하여 도 9 및 도 10을 참조하여 설명하도록 한다. Hereinafter, a method of manufacturing a fire fighting sheet which is an embodiment of the present invention having the above-described configuration and effects will be described with reference to FIGS. 9 and 10.
도 9는 본 발명의 다른 실시예인 소방용 시트 및 그 제조 방법의 제 1 실시예를 설명하기 위한 흐름도이다. 우선, 시트(10)를 준비한다(S11). 그 다음, 소방 방재 비드, 세라믹 파우더와 공중합체를 포함하는 바인더, 연화제 및 점증제, 오일, 천연 염료 등 소방 방재층(20)의 원료가 되는 재료를 준비한다(S12). 그리고 이들 소방 방재 원재료를 교반기에서 혼합하여 소방 방재 원료를 생산한다(S13).  9 is a flow chart for explaining a first embodiment of a fire fighting sheet and a method of manufacturing the same according to another embodiment of the present invention. First, the sheet 10 is prepared (S11). Next, a material which becomes a raw material of the fire prevention layer 20, such as fire prevention beads, a binder including a ceramic powder and a copolymer, a softener and a thickener, an oil and a natural dye, is prepared (S12). And these fire fighting disaster prevention raw materials are mixed in a stirrer to produce the fire prevention disaster prevention raw material (S13).
한편, S11 단계에서 준비된 시트(10)를 롤러를 통해 이송시키면서, 분사 장치를 통해 상기 소방 방재 원료를 분사하여 상기 시트(10)상에 소방 방재 원료를 코팅하여 소방 방재층(20)을 형성한다(S14). 이와 같이 상기 소방 방재 원료가 코팅됨으로써 소방 방재층(20)의 형성된 시트(10)를 송풍 건조하여 원조 소방용 시트를 한다(S15). 그 다음, 상기 원조 소방용 시트를 자동 커팅 절단기를 통해 커팅하여 소방용 시트를 완성한다(S16). 이 전에 제 3 실시예를 제작하기 위하여 접착제층(10')을 더 코팅하는 단계가 추가될 수 있음이 이해되어야 할 것이다. 이와 같은 제 1 실시예는 도 1 및 도 3에서 설명하는 본 발명의 일실시예인 소방용 시트의 제 1 실시예 및 제 3 실시예를 제작하는 방법이다.On the other hand, while transporting the sheet 10 prepared in step S11 through the roller, by spraying the fire-fighting disaster prevention raw material through the injection device to form a fire-fighting disaster prevention layer 20 by coating the fire-fighting disaster prevention raw material on the sheet (10). (S14). In this way, by coating the fire-fighting disaster prevention raw material, the sheet 10 formed of the fire-fighting disaster prevention layer 20 is blown and dried to form an original fire-fighting sheet (S15). Next, the fire fighting sheet is cut through an automatic cutting cutter to complete the fire fighting sheet (S16). It will be appreciated that further coating of the adhesive layer 10 'may be added prior to fabricating the third embodiment. Such a first embodiment is a method of manufacturing the first embodiment and the third embodiment of the fire-fighting sheet which is one embodiment of the present invention described in FIGS. 1 and 3.
한편, 도 2의 제 2 실시예를 제작하는 방법은 도 10에 따른 순서를 따른다. Meanwhile, the method of manufacturing the second embodiment of FIG. 2 follows the procedure according to FIG. 10.
도 10은 본 발명의 다른 실시예인 소방용 시트 및 그 제조 방법의 제 2 실시예를 설명하기 위한 흐름도이다. 우선, 상기 돌출부에 대응하는 매트릭스 형태의 홈을 구비한 거푸집을 준비한다(S21). 그 다음, 상기 거푸집에 소방 방재 원료를 투입한 후 경화 건조한다(S22, S23). 건조된 소방 방재 원료를 상기 거푸집에서 분리하여 소방 방재층(20)을 제조하고, 상기 소방 방재층(20)의 일면에 양면 접착 테이프를 부착하여 시트(10)를 구비하는 소방용 시트를 완성한다(S24). 10 is a flow chart for explaining a second embodiment of a fire fighting sheet and a method of manufacturing the same according to another embodiment of the present invention. First, a mold having a groove having a matrix form corresponding to the protrusion is prepared (S21). Then, the fire-prevention raw material is added to the die and cured and dried (S22, S23). A fire fighting disaster prevention layer 20 is manufactured by separating the dried fire prevention disaster prevention raw material from the mold, and attaching a double-sided adhesive tape to one surface of the fire protection disaster prevention layer 20 to complete a fire protection sheet having a sheet 10 ( S24).
한편, 제 1 실시예에 따른 방법으로도, 매트릭스형태의 돌출부를 가진 소방용 시트의 제작이 가능하다. 즉, 제 1 실시예에서, 시트지 상에 복수의 형상필름을 부착시킨 후, 소방 방재 원료를 코팅하게 되면, 복수의 형상 필름에 의해 시트 위에 복수의 돌출부를 구비한 소방용 시트의 제작이 완성될 수도 있음이 이해되어야 할 것이다.On the other hand, also in the method according to the first embodiment, it is possible to produce a fire-fighting sheet having a projection in the form of a matrix. That is, in the first embodiment, after attaching a plurality of shape films on the sheet paper, and then coating the fire-fighting disaster prevention raw material, the production of the fire-fighting sheet having a plurality of protrusions on the sheet by the plurality of shape films may be completed. It should be understood.
상술한 구성을 가진 본 발명의 일실시예에 따르면, 공중합체를 이용하여 폴리머 마이크로 캡슐로 구성되는 소방방재 비드를 고정하게 되므로, 교반시 자체적으로 발생하는 공기층을 형성하여 연성이 강화되게 되어서 각진 곳이나 구부러진 곳에도 부착이 가능한 소방용 시트를 제공할 수 있게 된다. According to one embodiment of the present invention having the above-described configuration, since the fire protection beads consisting of polymer microcapsules are fixed using a copolymer, the ductility is strengthened by forming an air layer that generates itself upon stirring In addition, it is possible to provide a fire fighting seat that can be attached to a bent position.
또한, 본 발명의 일실시예에 따르면, 마이크로 캡슐로 구성되는 소방 방재 비드와 교반시 공기층이 형성되는 공중합체를 함께 교반하여 제작하게 되므로, 250*250mm 이상의 대형사이즈의 소방용 시트의 제작이 가능하게 된다.In addition, according to an embodiment of the present invention, since the fire prevention disaster bead consisting of microcapsules and the copolymer is formed by stirring together the air layer is formed when stirring, it is possible to manufacture a firefighting sheet of a large size of 250 * 250mm or more do.
상기와 같은 연성이 우수하며 자기 소화기능을 갖는 소방용 시트 및 그 제조 방법은 위에서 설명된 실시예들의 구성과 작동 방식에 한정되는 것이 아니다. 상기 실시예들은 각 실시예들의 전부 또는 일부가 선택적으로 조합되어 다양한 변형이 이루어질 수 있도록 구성될 수도 있다.The fire extinguishing sheet having excellent ductility as described above and having a self-extinguishing function and a method of manufacturing the same are not limited to the configuration and operation of the embodiments described above. The above embodiments may be configured such that various modifications may be made by selectively combining all or part of the embodiments.

Claims (17)

  1. 시트; 및 Sheet; And
    상기 시트의 일면에 부착되는 자기소화기능을 구비한 소방 방재층을 포함하고,It includes a fire prevention layer having a self-extinguishing function attached to one surface of the sheet,
    상기 소방방재층은, The fire prevention layer,
    소방 성분이 내장된 폴리머 마이크로 캡슐로 구성되는 소방방재 비드; 및Fire protection beads consisting of a polymer microcapsule containing a fire protection component; And
    상기 소방 방재 비드가 상기 시트에 부착되게 하면서 시트 굽힘에도 크랙 발생을 예방하기 위하여 공기층을 형성되도록 하는 세라믹파우더 및 공중합체를 포함하는 바인더를 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트형 테이프.Fire-fighting sheet type tape having excellent ductility and self-extinguishing function, including a binder including a ceramic powder and a copolymer to form an air layer to prevent cracking even when the sheet is bent while the fire prevention beads are attached to the sheet. .
  2. 제 1 항에 있어서,The method of claim 1,
    상기 소방 방재측의 일면에 형성되는 접착제층을 더 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.A fire fighting sheet further comprising an adhesive layer formed on one surface of the fire fighting disaster prevention side, having excellent ductility and self-extinguishing function.
  3. 제 1 항에 있어서,The method of claim 1,
    상기 소방 방재층은,The fire prevention layer,
    상기 소방방재층의 색상을 부여하는 천연 염료를 더 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.Further comprising a natural dye to give the color of the fire prevention layer, excellent ductility and fire extinguishing sheet having a self-extinguishing function.
  4. 제 1 항에 있어서,The method of claim 1,
    상기 소방 방재층은, The fire prevention layer,
    표면 계면 활성 효과 및 경화시 기포현상을 방지하기 위한 오일을 더 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.A fire extinguishing sheet having excellent ductility and self-extinguishing function, further comprising an oil for preventing surface surfactant effects and bubbles during curing.
  5. 제 1 항에 있어서,The method of claim 1,
    정전기 방지 및 소방 방재 비드의 유연성 강화를 위한 연화제 및 점증제를 더 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트. A fire extinguishing sheet having excellent softness and self-extinguishing function, further comprising a softener and a thickener for enhancing antistatic and flexibility of fire protection beads.
  6. 제 5 항에 있어서,The method of claim 5,
    상기 점증제는, 하이드로시포로필메실-셀루로스/메실 셀루로스 그리고 솔리디움 알지네이트, 지오라이트 중 적어도 하나를 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The thickening agent, hydrocyclophoric mesyl- cellulose / mesyl cellulose and solidum alginate, at least one of the zeolite, excellent ductility and fire extinguishing sheet having a self-extinguishing function.
  7. 제 5 항에 있어서,The method of claim 5, wherein
    상기 연화제는, 카바나이트, 광유, 식물유, 중 적어도 하나를 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The softening agent, carbanite, mineral oil, vegetable oil, containing at least one, excellent in ductility and fire extinguishing sheet having a self-extinguishing function.
  8. 제 1 항에 있어서,The method of claim 1,
    상기 소방 방재 비드는 40~60 중량% 포함되고, 상기 바인더는 30~50 중량% 포함되는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The fire protection disaster bead is included 40 to 60% by weight, the binder is contained 30 to 50% by weight, excellent ductility and fire extinguishing sheet having a self-extinguishing function.
  9. 제 8 항에 있어서The method of claim 8
    상기 세라믹 파우더는 3~7 중량%, 상기 공중합체는 23~47 중량% 포함되는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The ceramic powder is 3 to 7% by weight, the copolymer is included 23 to 47% by weight, excellent ductility and fire fighting sheet having a self-extinguishing function.
  10. 제 5 항에 있어서,The method of claim 5, wherein
    상기 점증제는 0.5~3중량%, 상기 연화제는 0.5~3중량% 포함되는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The thickener is 0.5 to 3% by weight, the softener is contained 0.5 to 3% by weight, excellent ductility and fire fighting sheet having a self-extinguishing function.
  11. 제 2 항에 있어서,The method of claim 2,
    상기 염료는 0.5~2.0 중량 % 포함되는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The dye is contained 0.5 to 2.0% by weight, excellent ductility and fire fighting sheet having a self-extinguishing function.
  12. 제 1 항에 있어서,The method of claim 1,
    상기 소방 방재층은,The fire prevention layer,
    상기 시트에 접하는 제 1 방재층; 및 A first disaster prevention layer in contact with the sheet; And
    상기 제 1 방재층 위에 매트릭스 형태로 돌출 형성되는 다수의 돌출부를 구비한 제 2 방재층을 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.A fire protection sheet having excellent ductility and having a self-extinguishing function, including a second disaster prevention layer having a plurality of protrusions protruding in a matrix form on the first disaster prevention layer.
  13. 제 11항에 있어서,The method of claim 11,
    상기 돌출부는 원판형, 원통형, 사각판형 중 어느 하나인, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.The protruding portion is any one of a disc, a cylinder, and a square plate, excellent ductility and fire extinguishing sheet having a self-extinguishing function.
  14. 제 1 항에 있어서, The method of claim 1,
    상기 소방 성분은,The firefighting component,
    퍼플루오로프로판, 퍼플루오로부탄, 클로로테트라플루오르에탄, 펜타플루오로에탄, 헵타플루오로프로판, 트리플루오로메탄, 헥사플루오로프로판, 트리플루오로이오다이드, 하이드로클로로플루오로카본 혼화제 및 불연성불활성기체 혼합가스로 이루어지는 군 중 선택되는 물질을 하나 이상 포함하는, 연성이 우수하며 자기 소화기능을 갖는 소방용 시트.Perfluoropropane, perfluorobutane, chlorotetrafluoroethane, pentafluoroethane, heptafluoropropane, trifluoromethane, hexafluoropropane, trifluoroiodide, hydrochlorofluorocarbon admixtures and incombustibles Fire extinguishing sheet having one or more substances selected from the group consisting of gas mixture gas, having excellent ductility and self-extinguishing function.
  15. 시트를 준비하는 단계;Preparing a sheet;
    소방 방재 비드, 세라믹 파우더와 공중합체를 포함하는 바인더, 연화제, 및 점증제를 준비하는 단계: Preparing fire protection beads, a binder comprising a ceramic powder and a copolymer, a softener, and a thickener:
    상기 소방 방재 비드, 상기 바인더, 상기 연화제 및 상기 점증제를 자동교반기에 공급하여 교반함으로써 소방 방재 원료를 생산하는 단계; Producing fire-fighting disaster prevention raw materials by supplying and stirring the fire-fighting disaster prevention beads, the binder, the softener and the thickener into an automatic stirrer;
    상기 시트를 롤러를 통해 이송시키면서, 분사 장치를 통해 상기 소방 방재 원료를 분사하여 상기 시트상에 소방 방재 원료를 코팅하는 단계; Coating the fire prevention material on the sheet by spraying the fire prevention material through a spraying device while transferring the sheet through a roller;
    상기 소방 방재 원료가 코팅된 시트를 송풍 건조하여 원조 소방용 시트를 제작하는 단계; 및 Ventilating and drying the sheet coated with the fire prevention raw material to prepare an aid fire fighting sheet; And
    상기 원조 소방용 시트를 자동 커팅 절단기를 통해 커팅하여 소방용 시트를 완성하는 단계를 포함하는, 소방용 시트 제조 방법. And cutting the aid fire fighting sheet through an automatic cutting cutter to complete the fire fighting sheet.
  16. 제 15 항에 있어서,The method of claim 15,
    상기 소방 방재 원료는, The firefighting disaster prevention raw material,
    상기 소방 방재 비드 40~60 중량%, 상기 바인더는 30~50 중량%, 식물성 오일 3~7%중량 를 포함하는, 소방용 시트 제조 방법. 40 to 60% by weight of the fire protection beads, the binder is 30 to 50% by weight, vegetable oil containing 3 to 7% by weight, fire fighting sheet manufacturing method.
  17. 매트릭스 형태의 돌출부를 구비한 소방용 시트 제조 방법으로서, A fire fighting sheet manufacturing method having a projection in the form of a matrix,
    상기 돌출부에 대응하는 매트릭스 형태의 홈을 구비한 거푸집을 준비하는 단계;Preparing a formwork having a groove having a matrix shape corresponding to the protrusion;
    상기 거푸집에 소방 방재 원료를 투입한 후 경화 건조하는 단계;Curing and drying the fire prevention raw material into the formwork;
    건조된 소방 방재 원료를 상기 거푸집에서 분리하여 소방 방재층을 제조하는 단계; 및 Preparing a fire protection layer by separating the dried fire prevention material from the formwork; And
    상기 소방 방재층의 일면에 양면 접착 테이프를 부착하여 시트를 구비하는 소방용 시트를 완성하는 단계를 포함하는, 소방용 시트 제조 방법.Comprising the step of attaching a double-sided adhesive tape on one surface of the fire protection disaster prevention layer comprising the step of completing a fire fighting sheet having a sheet, fire fighting sheet manufacturing method.
PCT/KR2018/008578 2018-07-10 2018-07-27 Fire extinguishing sheet and tape having excellent flexibility and self-extinguishing function, and manufacturing method therefor WO2020013373A1 (en)

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