WO2020013182A1 - Cosmetic preparation - Google Patents
Cosmetic preparation Download PDFInfo
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- WO2020013182A1 WO2020013182A1 PCT/JP2019/027154 JP2019027154W WO2020013182A1 WO 2020013182 A1 WO2020013182 A1 WO 2020013182A1 JP 2019027154 W JP2019027154 W JP 2019027154W WO 2020013182 A1 WO2020013182 A1 WO 2020013182A1
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- Prior art keywords
- oil
- cosmetic
- powder
- mass
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Definitions
- the present invention relates to cosmetics, and more particularly to a cosmetic that has a matte finish but is smooth.
- the present invention has been made in view of the above conventional technology, and a problem to be solved is to provide a smooth cosmetic product having a matte finish.
- the cosmetic according to the present invention contains the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
- P Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics (P1) Dextrin palmitate 3.5 to 10% by mass
- V Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic (V2)
- the powder is preferably a plate-like powder.
- the blending amount of tri (caprylic / capric acid) glyceryl is 10 to 30% by mass based on the total amount of the cosmetic.
- the oil component preferably contains (v3) a semi-solid oil component.
- the cosmetic is filled in a tubular container.
- a smooth cosmetic can be obtained while having a matte finish.
- the cosmetic according to the present invention comprises the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
- P Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics (P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
- V Oil containing (v1) and (v2)
- V1 Volatile oil 5 to 50% by mass of the total amount of the cosmetic (V2)
- the powder is not particularly limited as long as it is generally used in cosmetics, and can be used. However, in the present invention, the coloring material is not included in the powder.
- the amount of the powder must be increased in order to secure the stability, so that a feeling of dryness may be felt.
- the powder of the present invention needs to contain dextrin palmitate. It is necessary that the blending amount of dextrin palmitate is 3.5 to 10% by mass based on the total amount of the cosmetic. Moreover, it is preferable that it is 4 mass% or more. If the amount of dextrin palmitate is too small, the stability is poor. Moreover, it is preferable that it is 9 mass% or less. If the amount of dextrin palmitate is too large, the smoothness of the growth is impaired.
- a plate-like powder as the powder.
- the feeling of use may be poor.
- the plate-like powder is not particularly limited by a particle structure such as porous or non-porous as long as it is a powder usually used in cosmetics, and inorganic powders, glittering powders, organic powders, Dye powders, composite powders and the like can be mentioned.
- the ratio of the minor axis to the major axis of the plate-like powder is preferably at least 10 with respect to the major axis.
- the plate-like powder examples include sericite, mica, synthetic mica, talc, zinc oxide, aluminum oxide, silicic anhydride, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, calcium sulfate, chromium oxide, chromium hydroxide, Carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, kaolin, silicon carbide, barium sulfate, bentonite, smectite, inorganic powders such as boron nitride, bismuth oxychloride, mica coated with titanium oxide, mica coated with iron oxide Mica titanium coated with iron oxide, mica titanium coated with organic pigment, glass flakes coated with titanium oxide, aluminum powder, glittering powders such as laminated powder of polyethylene terephthalate, organic powders such as N-acyl lysine, and mica titanium coated with fine particles of titanium oxide Emissions, particulate zinc oxide coated mica titanium, and a composite powder, and the like, such as barium-coated mica titanium s
- the compounding amount of the powder is 15 to 40% by mass based on the total amount of the cosmetic. Further, it is preferably at least 20% by mass. If the amount of the powder is too small, the matte feeling is insufficient. Moreover, it is preferable that it is 35 mass% or less. If the amount of the powder is too large, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
- the oil (V) includes a volatile oil, a non-volatile liquid oil, a semi-solid oil, and a solid oil.
- the volatile oil can be used without any particular limitation as long as it is generally used in cosmetics.
- the volatile oil component preferably includes an oil component having a boiling point of less than 250 ° C.
- volatile oil component examples include decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, ethyltrisiloxane, and light liquid isoparaffin. .
- the compounding amount of the volatile oil component needs to be 5 to 50% by mass based on the total amount of the cosmetic. Further, the content is preferably 10% by mass or more. If the amount of the volatile oil is too small, the matte feeling is insufficient. Moreover, it is preferable that it is 30 mass% or less. If the amount of the volatile oil is too large, the fit at the time of application is reduced.
- the non-volatile liquid oil component is not particularly limited as long as it is commonly used in cosmetics.
- the non-volatile liquid oil preferably includes an oil having a boiling point of 250 ° C. or higher.
- Non-volatile liquid oils include, for example, polar oils, hydrocarbon oils, natural animal and vegetable oils and semi-synthetic oils, silicone oils, and the like.
- the cosmetic of the present invention preferably contains a polar oil component among the non-volatile liquid oil components. By blending a polar oil, it is possible to obtain a cosmetic having a more moist feeling.
- the cosmetic according to the present invention needs to contain glyceryl tri (caprylate / caprinate), which is a polar oil component. It is preferable that the compounding amount is 10 to 30% by mass based on the total amount of the cosmetic. Further, the content is more preferably 20% by mass or more. If the amount of glyceryl tri (capryl / caprin) is too small, the matt feeling and moist feeling may be poor. Further, the content is more preferably 25% by mass or less. If the blending amount of glyceryl tri (caprylate / caprin) is too large, the mat feeling and the fit may be poor.
- polar oils include, for example, diisostearyl malate, neopentyl glycol dicaprate, glyceryl tri-2-ethylhexanoate, pentaerythrityl tetra-2-ethylhexanoate, diethylhexyl sebacate, octyldodecanol, diisostearic acid Glyceryl, diglyceryl triisostearate, trimethylolpropane tri-2-ethylhexanoate, oxystearyl oxystearate, pentaerythrityl tetra (ethylhexanoate / benzoate), trioctanoin, pentaerythrityl tetraoctanoate, hexahydroxy Dipentaerythrityl stearate, castor oil, diisopropyl sebacate, pentaerythrit tetraoctanoate,
- hydrocarbon oil examples include hydrogenated polyisobutene, liquid paraffin, squalane, squalene, heavy liquid isoparaffin, polyisobutylene, ⁇ -olefin oligomer and the like.
- Natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, kaya oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sasanqua oil, safflower oil, sinagiri oil Oil, cinnamon oil, turtle oil, soybean oil, teaseed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, germ oil, persic oil, palm oil, red palm oil, palm kernel oil, castor oil , Sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, coconut oil, tricoconut oil fatty acid glyceride,
- the amount of the non-volatile liquid oil should be 30 to 65% by mass based on the total amount of the cosmetic. Further, the content is preferably 35% by mass or more. If the amount of the non-volatile liquid oil is too small, the moist feeling is insufficient. Moreover, it is preferable that it is 60 mass% or less. If the amount of the non-volatile liquid oil is too large, the matte feeling is insufficient.
- the semi-solid oil component is not particularly limited as long as it is generally used for cosmetics.
- the semi-solid oil preferably includes an oil having a melting point of 30 to 50 ° C.
- semi-solid oil component examples include petrolatum, tetra (behenic acid / benzoic acid / ethylhexanoic acid) pentaerythrit, dipentaerythrityl hexahydroxystearate, dimer dilinoleate, macadamia nut oil polyglyceryl-6 ester sbehenate, tetra (Hydroxystearic acid / isostearic acid) dipentaerythrityl, bisdiglyceryl polyacyl adipate-2 and the like.
- petrolatum tetra (behenic acid / benzoic acid / ethylhexanoic acid) pentaerythrit, dipentaerythrityl hexahydroxystearate, dimer dilinoleate, macadamia nut oil polyglyceryl-6 ester sbehenate
- tetra Hydroxystearic acid / iso
- the solid oil can be used without any particular limitation as long as it is generally used in cosmetics.
- solid oils and fats examples include solid oils and fats, waxes, solid hydrocarbons, and higher alcohols.
- solid oils such as cacao butter and hydrogenated castor oil
- waxes such as mocro, carnauba wax, beeswax, salami beeswax, candelilla wax and jojoba wax: hydrocarbon waxes such as polyethylene wax, paraffin wax, ceresin, and microcrystalline wax
- cetyl Higher alcohols such as alcohol, stearyl alcohol, behenyl alcohol, and butyl alcohol
- silicone wax examples include silicone wax;
- the cosmetic of the present invention needs to have a P / V ratio of 0.30 to 0.75.
- the P / V ratio can be calculated by dividing the blended amount of the powder by the blended amount of the liquid oil. Note that the P / V ratio is a value calculated excluding the coloring material.
- the P / V ratio is preferably 0.35 or more. Further, the P / V ratio is more preferably 0.38 or more. If the P / V ratio is too low, the matte feeling will be insufficient. Further, the P / V ratio is preferably 0.60 or less. If the P / V ratio is too high, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
- the P / V ratio 30 minutes after application is preferably 0.5 to 0.8.
- the cosmetic of the present invention preferably has a hardness of 15 to 80 gf.
- the hardness is preferably 20 gf or more. If the hardness is too low, the fit may be poor. Further, the hardness is preferably 70 gf or less. If the hardness is too high, smoothness may be poor.
- the hardness was measured using a rheometer manufactured by Sun Kagaku Co., Ltd. under the following conditions (load weight: 2 kg, needle diameter: 5.6 ⁇ , needle penetration depth: 3 mm, rising speed: 20 mm / min, measurement) Temperature: 25 ° C).
- the cosmetic of the present invention can be filled in various containers such as a tube-shaped container and a jar container, but is preferably filled in a tube-shaped container.
- a cosmetic having a matte finish is difficult to take out of a container when it is made into a tube-shaped cosmetic because the hardness and viscosity of the cosmetic are hard, so that it is difficult to make a tube-shaped cosmetic.
- components usually used in cosmetics for example, coloring materials, surfactants, water-soluble polymers, thickeners, coating agents, humectants, and ultraviolet absorbers Agents, cosmetic ingredients, fibers, fragrances, water and the like can be added as necessary.
- a coloring material may be blended in the cosmetic according to the present invention.
- the coloring material is compounded for the purpose of coloring the preparation.
- pigments, pearl pigments, and lacquered ones of these can be used which are usually blended in cosmetics.
- inorganic white pigments titanium dioxide, zinc oxide
- inorganic red pigments iron oxide (iron oxide), iron titanate
- inorganic brown pigments ⁇ -iron oxide
- inorganic yellow pigments Yellow iron oxide, loess
- inorganic black pigments black iron oxide, carbon, lower titanium oxide
- inorganic purple pigments mango violet, cobalt violet
- inorganic green pigments chromium oxide, chromium hydroxide, titanic acid
- Cobalt inorganic blue pigments (ultramarine, navy blue)
- pearl pigments titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, colored titanium oxide-coated mica, bismuth oxychloride, fish scale foil
- metal powder pigments Alluminal, copper powder
- organic pigments red 202, red 205, red 220, red 228, red 405, orange 203
- nonionic surfactants for example, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene-based surfactants such as polyoxyethylene hydrogenated castor oil derivatives, Examples thereof include alkyl polyglycosides such as octyl polyglycoside, polyglycerin-based surfactants such as polyglycerin fatty acid ester and polyglycerin alkyl ether, sugar alcohol hydroxyalkyl ethers such as maltitol hydroxyalkyl ether, and fatty acid diethanolamide.
- alkyl polyglycosides such as octyl polyglycoside
- polyglycerin-based surfactants such as polyglycerin fatty acid ester and polyglycerin alkyl ether
- sugar alcohol hydroxyalkyl ethers such as maltitol hydroxyalkyl ether
- fatty acid diethanolamide for example, polyoxy
- anionic surfactants such as higher fatty acid salts, alkylbenzene sulfonates, phosphates, alkyl sulfates, alkyl sulfates, polyoxyethylene alkyl sulfates, amino acids, alkyltrimethylammonium salts, dialkyldimethyl Cationic surfactants such as ammonium salts and alkyldimethylamine oxides, and other surfactants can also be blended.
- natural water-soluble polymers include, for example, plant polymers (e.g., gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (cassow extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (eg, xanthan gum, dextran, succinoglucan, burlan, etc.); animal macromolecules (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
- plant polymers e.g., gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (cassow extract), starch (Rice, corn, potato, wheat), glycyr
- Semi-synthetic water-soluble polymers include, for example, starch-based polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, cellulose sodium sulfate) , Hydroxypropylcellulose, carboxymethylcellulose, carboxymethylcellulose sodium, crystalline cellulose, cellulose powder, etc.); and alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.).
- starch-based polymers eg, carboxymethyl starch, methylhydroxypropyl starch, etc.
- cellulose-based polymers methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, cellulose sodium sulfate
- Hydroxypropylcellulose carboxymethylcellulose, carboxymethylcellulose sodium, crystalline cellulose, cellulose powder, etc.
- Examples of the synthetic water-soluble polymer include a vinyl polymer (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.); and a polyoxyethylene polymer (eg, polyethylene glycol 20,000, 40).
- Acrylic polymers eg, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.
- polyethylene imines cationic polymers, and the like.
- thickener examples include gum arabic, carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate, xanthan gum, aluminum magnesium silicate, bentonite, hectorite, AlMg silicate (Vegum), Laponite, silicic anhydride and the like.
- gum arabic ethylcellulose
- CMC hydroxyethylcellulose
- PVP sodium polyacrylate
- carboxyvinyl polymer locust bean gum
- guar gum tamarint gum
- the film-forming agent examples include siliconized pullulan, trimethylsiloxysilicic acid, dimethylaminomethacrylate quaternary salt, vinylpyrrolidone / methacrylic acid-N, N-dimethyl-ethylantinioethyl salt copolymer, and silicone / polyether-based Polyurethane resin, (methacryloyloxyethylcarboxybetaine / methacrylalkyl) copolymer, dextrin, (vinylpyrrolidone / VA) copolymer, alkyl acrylate ammonium, polyvinyl alcohol, polyethyl acrylate, (alkyl acrylate / octyl acrylamide) copolymer, (Acrylates / propyl methacrylate trimethicone) copolymer, polyvinyl acetate, (alkyl acrylate / dimethicone) copolymer, polyether grafted acrylic Recone,
- humectant examples include dipropylene glycol, polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12. -Hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayobara extract, Achillea millefolium extract, melilot extract, etc.
- EO diglycerin
- the ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers (eg, para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester , N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid ultraviolet absorbers (eg, homomenthyl-N-acetylanthranilate, etc.); Salicylic acid-based ultraviolet absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.);
- incorporable components include, for example, preservatives (eg, ethyl paraben, butyl paraben); whitening agents (eg, placental extract, saxifrage extract, arbutin); blood circulation promoters (nicotinic acid, benzyl nicotinate, nicotine) Acid tocopherol, nicotinic acid ⁇ -butoxyester, minoxidil or an analog thereof, vitamin Es, ⁇ -oryzanol, alkoxycarbonylpyridine N-oxide, carpronium chloride, and acetylcholine or a derivative thereof; various extracts (eg, ginger, Ubak, spinach, radish, birch, loquat, carrot, aloe, mallow, iris, grape, loofah, lily, saffron, senkyu, gingerbread, hypericum, ononis, garlic, capsicum, chimpanzee, cypress, button, seaweed, etc.), activation Agent
- Lip cosmetics such as lip gloss, base lip base, lipstick overcoat, lip balm, etc.
- makeup cosmetics such as eye shadow, blusher, foundation, makeup base, skin care cosmetics, hair makeup It can be applied to materials.
- the present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. Unless otherwise specified, the compounding amount is shown in mass% based on the system in which the component is compounded. Prior to the description of the examples, the evaluation test method used in the present invention will be described.
- Evaluation (2) Usability (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling) Ten professional panels applied the sample to the lips, and evaluated the feeling of use (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling) at the time of application. A: Nine or more persons answered that the feeling of use was good (smooth, matte, inconspicuous vertical wrinkles, and moist). B: Eight people answered that the usability was good. C: Seven persons answered that the usability was good. D: Five or more and less than seven answered that the feeling of use was good. E: Four persons answered that the usability was good. F: Less than 4 persons answered that the feeling of use was good. When the above evaluation was E or more, the usability was good, and F was inferior in usability.
- Evaluation (3) Stability The sample was stored at a low temperature (5 ° C.) and a high temperature (40 ° C.) for 30 days, and compared with a standard product stored at a normal temperature (25 ° C.) to confirm the presence or absence of separation or the like.
- the present inventors manufactured cosmetics (lip cosmetics) shown in Tables 1 and 2 below by a conventional method, filled them into a tubular container, and measured them by the above-described evaluation methods. The results are shown in Tables 1 and 2.
- Test Example 1-1 revealed that when the amount of the volatile oil component was 3% by mass, the matte feeling was not satisfactory.
- Test Examples 1-4 and 1-5 show that by increasing the amount of tri (caprylic acid / capric acid) glyceryl which is a polar oil component (non-volatile liquid oil component), the matt feeling and the moist feeling are improved.
- Test Example 1-6 shows that when the amount of dextrin palmitate is small, the stability tends to deteriorate.
- the present inventors studied the P / V ratio.
- the present inventors produced cosmetics (lip cosmetics) shown in Table 3 below by a conventional method, filled them into a tubular container, and measured them by the above-mentioned evaluation method. Table 3 shows the results.
- the cosmetic according to the present invention is characterized by containing the following powder (P) and oil (V), and having a P / V ratio of 0.30 to 0.75.
- P Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics (P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
- V Oil containing (v1) and (v2)
- V1 Volatile oil 5 to 50% by mass of the total amount of the cosmetic (V2)
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Abstract
Provided is a cosmetic preparation which gives a matte but smooth finish. The cosmetic preparation is characterized by comprising the following powder (P) and oily ingredient (V), the P/V ratio being 0.30-0.75.
(P) A powder including (p1); 15-40 mass% of the whole cosmetic preparation. (p1) Dextrin palmitate; 3.5-10 mass% of the whole cosmetic preparation.
(V) An oily ingredient comprising (v1) and (v2). (v1) A volatile oil; 5-50 mass% of the whole cosmetic preparation. (v2) A nonvolatile liquid oil comprising a caprylic/capric triglyceride; 30-65 mass% of the whole cosmetic preparation.
Description
本出願は、２０１８年７月１０日付け出願の日本国特許出願２０１８－１３１０７１号の優先権を主張しており、ここに折り込まれるものである。
This application claims the priority of Japanese Patent Application No. 2018-131071 filed on Jul. 10, 2018, which is incorporated herein by reference.
本発明は、化粧料に関し、特にマットな仕上がりでありながらも、なめらかな化粧料に関する。
(4) The present invention relates to cosmetics, and more particularly to a cosmetic that has a matte finish but is smooth.
化粧料を塗布した肌や唇の質感は、つや感とマット感を付与するものに大きく二分される。中でも液状の化粧料でマットな質感を有する化粧料は、なめらかさに劣り、経時でしわが目立ってしまうものが多かった。また、マット感を有する化粧料は、硬すぎてチューブ化できず、容器から直接塗布するのではなく、容器にあらかじめ入れられた塗布具を使って塗布するもの、または中皿またはジャータイプ用の容器に充填されているもの（例えば、特許文献１参照）であった。
質 The texture of the skin and lips to which the cosmetic is applied is roughly divided into two which give a glossy and matte feeling. Above all, liquid cosmetics having a matte texture are often inferior in smoothness and often show wrinkles over time. In addition, cosmetics having a matte feeling are too hard to be formed into a tube, and are not applied directly from a container, but are applied using an applicator previously placed in a container, or for an inner plate or a jar type. The container was filled (for example, see Patent Document 1).
本発明は前記従来技術に鑑み行われたものであり、その解決すべき課題は、マットな仕上がりでありながらも、なめらかな化粧料を提供することにある。
The present invention has been made in view of the above conventional technology, and a problem to be solved is to provide a smooth cosmetic product having a matte finish.
本発明者らが前述の課題を解決すべく鋭意研究を行った結果、特定量のパルミチン酸デキストリンを含む粉末、揮発性油分、トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分を含み、Ｐ／Ｖ比を調整することにより、マットな仕上がりでありながらも、なめらかな化粧料を得られることを見出し、本発明を完成するに至った。
As a result of intensive studies conducted by the present inventors to solve the above-mentioned problems, it has been found that a powder containing a specific amount of dextrin palmitate, a volatile oil, and a non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl are contained. It has been found that by adjusting the P / V ratio, a smooth cosmetic can be obtained while having a matte finish, and the present invention has been completed.
すなわち、本発明にかかる化粧料は、以下の粉末（Ｐ）と、油分（Ｖ）を含み、Ｐ／Ｖ比が０．３０～０．７５であることを特徴とする。
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン ３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％
前記化粧料において、粉末が板状粉末であることが好適である。
前記化粧料において、トリ（カプリル酸／カプリン酸）グリセリルの配合量が化粧料全量中１０～３０質量％であることが好適である。
前記化粧料において、（Ｖ）油分に（ｖ３）半固形油分を含むことが好適である。
前記化粧料において、チューブ状容器に充填されていることが好適である。 That is, the cosmetic according to the present invention contains the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
In the cosmetic, the powder is preferably a plate-like powder.
In the above-mentioned cosmetics, it is preferable that the blending amount of tri (caprylic / capric acid) glyceryl is 10 to 30% by mass based on the total amount of the cosmetic.
In the cosmetic, (V) the oil component preferably contains (v3) a semi-solid oil component.
In the cosmetic, it is preferable that the cosmetic is filled in a tubular container.
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン ３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％
前記化粧料において、粉末が板状粉末であることが好適である。
前記化粧料において、トリ（カプリル酸／カプリン酸）グリセリルの配合量が化粧料全量中１０～３０質量％であることが好適である。
前記化粧料において、（Ｖ）油分に（ｖ３）半固形油分を含むことが好適である。
前記化粧料において、チューブ状容器に充填されていることが好適である。 That is, the cosmetic according to the present invention contains the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
In the cosmetic, the powder is preferably a plate-like powder.
In the above-mentioned cosmetics, it is preferable that the blending amount of tri (caprylic / capric acid) glyceryl is 10 to 30% by mass based on the total amount of the cosmetic.
In the cosmetic, (V) the oil component preferably contains (v3) a semi-solid oil component.
In the cosmetic, it is preferable that the cosmetic is filled in a tubular container.
本発明によれば、マットな仕上がりでありながらも、なめらかな化粧料を得ることができる。
According to the present invention, a smooth cosmetic can be obtained while having a matte finish.
以下、本発明の実施の形態について詳細に説明する。
本発明にかかる化粧料は、以下の粉末（Ｐ）と、油分（Ｖ）を含み、Ｐ／Ｖ比が０．３０～０．７５であることを特徴とする。
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン 化粧料全量中３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％ Hereinafter, embodiments of the present invention will be described in detail.
The cosmetic according to the present invention comprises the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
本発明にかかる化粧料は、以下の粉末（Ｐ）と、油分（Ｖ）を含み、Ｐ／Ｖ比が０．３０～０．７５であることを特徴とする。
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン 化粧料全量中３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％ Hereinafter, embodiments of the present invention will be described in detail.
The cosmetic according to the present invention comprises the following powder (P) and oil (V), and has a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
（（Ｐ）粉末）
粉末は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。しかし、本発明において、色材は粉末に含まれないものとしている。 ((P) powder)
The powder is not particularly limited as long as it is generally used in cosmetics, and can be used. However, in the present invention, the coloring material is not included in the powder.
粉末は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。しかし、本発明において、色材は粉末に含まれないものとしている。 ((P) powder)
The powder is not particularly limited as long as it is generally used in cosmetics, and can be used. However, in the present invention, the coloring material is not included in the powder.
粉末として、疎水化処理していない粉末を用いることが好ましい。疎水化処理粉末を用いると、安定性を確保するために粉末量を増量しなくてはいけなくなってしまうため、パサつきを感じる場合がある。
It is preferable to use a powder that has not been subjected to a hydrophobic treatment. When the hydrophobized powder is used, the amount of the powder must be increased in order to secure the stability, so that a feeling of dryness may be felt.
（（ｐ１）パルミチン酸デキストリン）
本発明の粉末には、パルミチン酸デキストリンを含むことが必要である。
パルミチン酸デキストリンの配合量は、化粧料全量中３．５～１０質量％であることが必要である。また、４質量％以上であることが好ましい。パルミチン酸デキストリンの配合量が少なすぎると、安定性に劣る。
また、９質量％以下であることが好ましい。パルミチン酸デキストリンの配合量が多すぎると、のびのなめらかさが損なわれる。 ((P1) dextrin palmitate)
The powder of the present invention needs to contain dextrin palmitate.
It is necessary that the blending amount of dextrin palmitate is 3.5 to 10% by mass based on the total amount of the cosmetic. Moreover, it is preferable that it is 4 mass% or more. If the amount of dextrin palmitate is too small, the stability is poor.
Moreover, it is preferable that it is 9 mass% or less. If the amount of dextrin palmitate is too large, the smoothness of the growth is impaired.
本発明の粉末には、パルミチン酸デキストリンを含むことが必要である。
パルミチン酸デキストリンの配合量は、化粧料全量中３．５～１０質量％であることが必要である。また、４質量％以上であることが好ましい。パルミチン酸デキストリンの配合量が少なすぎると、安定性に劣る。
また、９質量％以下であることが好ましい。パルミチン酸デキストリンの配合量が多すぎると、のびのなめらかさが損なわれる。 ((P1) dextrin palmitate)
The powder of the present invention needs to contain dextrin palmitate.
It is necessary that the blending amount of dextrin palmitate is 3.5 to 10% by mass based on the total amount of the cosmetic. Moreover, it is preferable that it is 4 mass% or more. If the amount of dextrin palmitate is too small, the stability is poor.
Moreover, it is preferable that it is 9 mass% or less. If the amount of dextrin palmitate is too large, the smoothness of the growth is impaired.
また、粉末として、板状粉末を用いることが好ましい。球状粉末を用いると、使用感に劣ってしまう場合がある。
板 Further, it is preferable to use a plate-like powder as the powder. When a spherical powder is used, the feeling of use may be poor.
板状粉末は、通常化粧料に使用される粉体であれば多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、複合粉体類等が挙げられる。
板状粉末の短径と長径の比率は、短径１に対して長径１０以上が好ましい。 The plate-like powder is not particularly limited by a particle structure such as porous or non-porous as long as it is a powder usually used in cosmetics, and inorganic powders, glittering powders, organic powders, Dye powders, composite powders and the like can be mentioned.
The ratio of the minor axis to the major axis of the plate-like powder is preferably at least 10 with respect to the major axis.
板状粉末の短径と長径の比率は、短径１に対して長径１０以上が好ましい。 The plate-like powder is not particularly limited by a particle structure such as porous or non-porous as long as it is a powder usually used in cosmetics, and inorganic powders, glittering powders, organic powders, Dye powders, composite powders and the like can be mentioned.
The ratio of the minor axis to the major axis of the plate-like powder is preferably at least 10 with respect to the major axis.
板状粉末としては、例えば、セリサイト、マイカ、合成マイカ、タルク、酸化亜鉛、酸化アルミニウム、無水ケイ酸、酸化マグネシウム、酸化ジルコニウム、炭酸マグネシウム、炭酸カルシウム、硫酸カルシウム、酸化クロム、水酸化クロム、カーボンブラック、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、カオリン、炭化珪素、硫酸バリウム、ベントナイト、スメクタイト、窒化硼素等の無機粉体類、オキシ塩化ビスマス、酸化チタン被覆マイカ、酸化鉄被覆マイカ、酸化鉄被覆マイカチタン、有機顔料被覆マイカチタン、酸化チタン被覆ガラスフレーク、アルミニウムパウダー、ポリエチレンテレフタレート積層末等の光輝性粉体類、Ｎ－アシルリジン等の有機粉体類、微粒子酸化チタン被覆マイカチタン、微粒子酸化亜鉛被覆マイカチタン、硫酸バリウム被覆マイカチタン等の複合粉体類等が挙げられる。
これらのうち、セリサイト、マイカ、合成マイカ、タルクを用いることが好ましい。 Examples of the plate-like powder include sericite, mica, synthetic mica, talc, zinc oxide, aluminum oxide, silicic anhydride, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, calcium sulfate, chromium oxide, chromium hydroxide, Carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, kaolin, silicon carbide, barium sulfate, bentonite, smectite, inorganic powders such as boron nitride, bismuth oxychloride, mica coated with titanium oxide, mica coated with iron oxide Mica titanium coated with iron oxide, mica titanium coated with organic pigment, glass flakes coated with titanium oxide, aluminum powder, glittering powders such as laminated powder of polyethylene terephthalate, organic powders such as N-acyl lysine, and mica titanium coated with fine particles of titanium oxide Emissions, particulate zinc oxide coated mica titanium, and a composite powder, and the like, such as barium-coated mica titanium sulfate.
Of these, sericite, mica, synthetic mica, and talc are preferably used.
これらのうち、セリサイト、マイカ、合成マイカ、タルクを用いることが好ましい。 Examples of the plate-like powder include sericite, mica, synthetic mica, talc, zinc oxide, aluminum oxide, silicic anhydride, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, calcium sulfate, chromium oxide, chromium hydroxide, Carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, kaolin, silicon carbide, barium sulfate, bentonite, smectite, inorganic powders such as boron nitride, bismuth oxychloride, mica coated with titanium oxide, mica coated with iron oxide Mica titanium coated with iron oxide, mica titanium coated with organic pigment, glass flakes coated with titanium oxide, aluminum powder, glittering powders such as laminated powder of polyethylene terephthalate, organic powders such as N-acyl lysine, and mica titanium coated with fine particles of titanium oxide Emissions, particulate zinc oxide coated mica titanium, and a composite powder, and the like, such as barium-coated mica titanium sulfate.
Of these, sericite, mica, synthetic mica, and talc are preferably used.
粉末の配合量は、化粧料全量中１５～４０質量％であることが必要である。また、２０質量％以上であることが好ましい。粉末の配合量が少なすぎると、マット感が不足する。
また、３５質量％以下であることが好ましい。粉末の配合量が多すぎると、なめらかさが低減したり、経時でのパサつきや乾燥感が高まったりする。 It is necessary that the compounding amount of the powder is 15 to 40% by mass based on the total amount of the cosmetic. Further, it is preferably at least 20% by mass. If the amount of the powder is too small, the matte feeling is insufficient.
Moreover, it is preferable that it is 35 mass% or less. If the amount of the powder is too large, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
また、３５質量％以下であることが好ましい。粉末の配合量が多すぎると、なめらかさが低減したり、経時でのパサつきや乾燥感が高まったりする。 It is necessary that the compounding amount of the powder is 15 to 40% by mass based on the total amount of the cosmetic. Further, it is preferably at least 20% by mass. If the amount of the powder is too small, the matte feeling is insufficient.
Moreover, it is preferable that it is 35 mass% or less. If the amount of the powder is too large, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
（（Ｖ）油分）
油分（Ｖ）は、揮発性油分、不揮発性液状油分、半固形油分、固形油分が挙げられる。 ((V) oil content)
The oil (V) includes a volatile oil, a non-volatile liquid oil, a semi-solid oil, and a solid oil.
油分（Ｖ）は、揮発性油分、不揮発性液状油分、半固形油分、固形油分が挙げられる。 ((V) oil content)
The oil (V) includes a volatile oil, a non-volatile liquid oil, a semi-solid oil, and a solid oil.
（（ｖ１）揮発性油分）
揮発性油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。揮発性油分は、好ましくは沸点２５０℃未満の油分が挙げられる。 ((V1) volatile oil)
The volatile oil can be used without any particular limitation as long as it is generally used in cosmetics. The volatile oil component preferably includes an oil component having a boiling point of less than 250 ° C.
揮発性油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。揮発性油分は、好ましくは沸点２５０℃未満の油分が挙げられる。 ((V1) volatile oil)
The volatile oil can be used without any particular limitation as long as it is generally used in cosmetics. The volatile oil component preferably includes an oil component having a boiling point of less than 250 ° C.
揮発性油分としては、例えば、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、ドデカメチルシクロヘキサシロキサン、メチルトリメチコン、ジメチルポリシロキサン、デカメチルテトラシロキサン、エチルトリシロキサン、軽質流動イソパラフィン等が挙げられる。
Examples of the volatile oil component include decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, ethyltrisiloxane, and light liquid isoparaffin. .
揮発性油分の配合量は、化粧料全量中５～５０質量％であることが必要である。また、１０質量％以上であることが好ましい。揮発性油分の配合量が少なすぎると、マット感が不足する。
また、３０質量％以下であることが好ましい。揮発性油分の配合量が多すぎると、塗布時のフィット感が低減する。 The compounding amount of the volatile oil component needs to be 5 to 50% by mass based on the total amount of the cosmetic. Further, the content is preferably 10% by mass or more. If the amount of the volatile oil is too small, the matte feeling is insufficient.
Moreover, it is preferable that it is 30 mass% or less. If the amount of the volatile oil is too large, the fit at the time of application is reduced.
また、３０質量％以下であることが好ましい。揮発性油分の配合量が多すぎると、塗布時のフィット感が低減する。 The compounding amount of the volatile oil component needs to be 5 to 50% by mass based on the total amount of the cosmetic. Further, the content is preferably 10% by mass or more. If the amount of the volatile oil is too small, the matte feeling is insufficient.
Moreover, it is preferable that it is 30 mass% or less. If the amount of the volatile oil is too large, the fit at the time of application is reduced.
（（ｖ２）不揮発性液状油分）
不揮発性液状油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。不揮発性液状油分は、好ましくは沸点２５０℃以上の油分が挙げられる。
不揮発性液状油分としては、例えば、極性油分、炭化水素油、天然動植物油及び半合成油、シリコーン油等が挙げられる。 ((V2) nonvolatile liquid oil)
The non-volatile liquid oil component is not particularly limited as long as it is commonly used in cosmetics. The non-volatile liquid oil preferably includes an oil having a boiling point of 250 ° C. or higher.
Non-volatile liquid oils include, for example, polar oils, hydrocarbon oils, natural animal and vegetable oils and semi-synthetic oils, silicone oils, and the like.
不揮発性液状油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。不揮発性液状油分は、好ましくは沸点２５０℃以上の油分が挙げられる。
不揮発性液状油分としては、例えば、極性油分、炭化水素油、天然動植物油及び半合成油、シリコーン油等が挙げられる。 ((V2) nonvolatile liquid oil)
The non-volatile liquid oil component is not particularly limited as long as it is commonly used in cosmetics. The non-volatile liquid oil preferably includes an oil having a boiling point of 250 ° C. or higher.
Non-volatile liquid oils include, for example, polar oils, hydrocarbon oils, natural animal and vegetable oils and semi-synthetic oils, silicone oils, and the like.
本発明の化粧料には、不揮発性液状油分のうち、極性油分を含むことが好ましい。極性油分を配合することで、さらにしっとり感に優れた化粧料を得ることができる。
化粧 The cosmetic of the present invention preferably contains a polar oil component among the non-volatile liquid oil components. By blending a polar oil, it is possible to obtain a cosmetic having a more moist feeling.
本発明にかかる化粧料には、極性油分であるトリ（カプリル／カプリン）酸グリセリルを配合することが必要である。また、その配合量は、化粧料全量中１０～３０質量％であることが好ましい。また、２０質量％以上であることがより好ましい。トリ（カプリル／カプリン）酸グリセリルの配合量が少なすぎると、マット感やしっとり感に劣る場合がある。
また、２５質量％以下であることがより好ましい。トリ（カプリル／カプリン）酸グリセリルの配合量が多すぎると、マット感やフィット感に劣る場合がある。 The cosmetic according to the present invention needs to contain glyceryl tri (caprylate / caprinate), which is a polar oil component. It is preferable that the compounding amount is 10 to 30% by mass based on the total amount of the cosmetic. Further, the content is more preferably 20% by mass or more. If the amount of glyceryl tri (capryl / caprin) is too small, the matt feeling and moist feeling may be poor.
Further, the content is more preferably 25% by mass or less. If the blending amount of glyceryl tri (caprylate / caprin) is too large, the mat feeling and the fit may be poor.
また、２５質量％以下であることがより好ましい。トリ（カプリル／カプリン）酸グリセリルの配合量が多すぎると、マット感やフィット感に劣る場合がある。 The cosmetic according to the present invention needs to contain glyceryl tri (caprylate / caprinate), which is a polar oil component. It is preferable that the compounding amount is 10 to 30% by mass based on the total amount of the cosmetic. Further, the content is more preferably 20% by mass or more. If the amount of glyceryl tri (capryl / caprin) is too small, the matt feeling and moist feeling may be poor.
Further, the content is more preferably 25% by mass or less. If the blending amount of glyceryl tri (caprylate / caprin) is too large, the mat feeling and the fit may be poor.
その他の極性油分としては、例えば、リンゴ酸ジイソステアリル、ジカプリン酸ネオペンチルグリコール、トリ２－エチルヘキサン酸グリセリル、テトラ２－エチルヘキサン酸ペンタエリスリチル、セバシン酸ジエチルヘキシル、オクチルドデカノール、ジイソステアリン酸グリセリル、トリイソステアリン酸ジグリセリル、トリ２－エチルヘキサン酸トリメチロールプロパン、オキシステアリン酸オキシステアリル、テトラ（エチルヘキサン酸／安息香酸）ペンタエリスリチル、トリオクタノイン、テトラオクタン酸ペンタエリスリチル、ヘキサヒドロキシステアリン酸ジペンタエリスリチル、ヒマシ油、セバシン酸ジイソプロピル、テトラオクタン酸ペンタエリスリット、トリイソステアリン酸トリメチロールプロパン等が挙げられる。
Other polar oils include, for example, diisostearyl malate, neopentyl glycol dicaprate, glyceryl tri-2-ethylhexanoate, pentaerythrityl tetra-2-ethylhexanoate, diethylhexyl sebacate, octyldodecanol, diisostearic acid Glyceryl, diglyceryl triisostearate, trimethylolpropane tri-2-ethylhexanoate, oxystearyl oxystearate, pentaerythrityl tetra (ethylhexanoate / benzoate), trioctanoin, pentaerythrityl tetraoctanoate, hexahydroxy Dipentaerythrityl stearate, castor oil, diisopropyl sebacate, pentaerythrit tetraoctanoate, trimethylolpropane triisostearate and the like.
炭化水素油としては、水添ポリイソブテン、流動パラフィン、スクワラン、スクワレン、重質流動イソパラフィン、ポリイソブチレン、α－オレフィンオリゴマー等が挙げられる。
天然動植物油及び半合成油としては、アボガド油、アマニ油、アーモンド油、オリーブ油、カヤ油、肝油、キョウニン油、小麦胚芽油、ゴマ油、コメ胚芽油、コメヌカ油、サザンカ油、サフラワー油、シナギリ油、シナモン油、タートル油、大豆油、茶実油、ツバキ油、月見草油、トウモロコシ油、ナタネ油、日本キリ油、胚芽油、パーシック油、パーム油、レッドパーム油、パーム核油、ヒマシ油、ヒマワリ油、ブドウ油、ホホバ油、マカデミアナッツ油、綿実油、ヤシ油、トリヤシ油脂肪酸グリセライド、落花生油、液状ラノリン、還元ラノリン、ラノリンアルコール、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ＰＯＥラノリンアルコールエーテル、ＰＯＥラノリンアルコールアセテート、ラノリン脂肪酸ポリエチレングリコール、ＰＯＥ水素添加ラノリンアルコールエーテル、卵黄油等が挙げられる。
シリコーン油としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、フェニルトリメチコン等が挙げられる。 Examples of the hydrocarbon oil include hydrogenated polyisobutene, liquid paraffin, squalane, squalene, heavy liquid isoparaffin, polyisobutylene, α-olefin oligomer and the like.
Natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, kaya oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sasanqua oil, safflower oil, sinagiri oil Oil, cinnamon oil, turtle oil, soybean oil, teaseed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, germ oil, persic oil, palm oil, red palm oil, palm kernel oil, castor oil , Sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, coconut oil, tricoconut oil fatty acid glyceride, peanut oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin alcohol Acetate, lanolin fatty acid polyethylene glycol, OE hydrogenated lanolin alcohol ether, yolk oil, and the like.
Examples of the silicone oil include dimethylpolysiloxane, methylphenylpolysiloxane, and phenyltrimethicone.
天然動植物油及び半合成油としては、アボガド油、アマニ油、アーモンド油、オリーブ油、カヤ油、肝油、キョウニン油、小麦胚芽油、ゴマ油、コメ胚芽油、コメヌカ油、サザンカ油、サフラワー油、シナギリ油、シナモン油、タートル油、大豆油、茶実油、ツバキ油、月見草油、トウモロコシ油、ナタネ油、日本キリ油、胚芽油、パーシック油、パーム油、レッドパーム油、パーム核油、ヒマシ油、ヒマワリ油、ブドウ油、ホホバ油、マカデミアナッツ油、綿実油、ヤシ油、トリヤシ油脂肪酸グリセライド、落花生油、液状ラノリン、還元ラノリン、ラノリンアルコール、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ＰＯＥラノリンアルコールエーテル、ＰＯＥラノリンアルコールアセテート、ラノリン脂肪酸ポリエチレングリコール、ＰＯＥ水素添加ラノリンアルコールエーテル、卵黄油等が挙げられる。
シリコーン油としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、フェニルトリメチコン等が挙げられる。 Examples of the hydrocarbon oil include hydrogenated polyisobutene, liquid paraffin, squalane, squalene, heavy liquid isoparaffin, polyisobutylene, α-olefin oligomer and the like.
Natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, kaya oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sasanqua oil, safflower oil, sinagiri oil Oil, cinnamon oil, turtle oil, soybean oil, teaseed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, germ oil, persic oil, palm oil, red palm oil, palm kernel oil, castor oil , Sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, coconut oil, tricoconut oil fatty acid glyceride, peanut oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin alcohol Acetate, lanolin fatty acid polyethylene glycol, OE hydrogenated lanolin alcohol ether, yolk oil, and the like.
Examples of the silicone oil include dimethylpolysiloxane, methylphenylpolysiloxane, and phenyltrimethicone.
不揮発性液状油分の配合量は、化粧料全量中３０～６５質量％であることが必要である。また、３５質量％以上であることが好ましい。不揮発性液状油分の配合量が少なすぎると、しっとり感が不足する。
また、６０質量％以下であることが好ましい。不揮発性液状油分の配合量が多すぎると、マット感が不足する。 The amount of the non-volatile liquid oil should be 30 to 65% by mass based on the total amount of the cosmetic. Further, the content is preferably 35% by mass or more. If the amount of the non-volatile liquid oil is too small, the moist feeling is insufficient.
Moreover, it is preferable that it is 60 mass% or less. If the amount of the non-volatile liquid oil is too large, the matte feeling is insufficient.
また、６０質量％以下であることが好ましい。不揮発性液状油分の配合量が多すぎると、マット感が不足する。 The amount of the non-volatile liquid oil should be 30 to 65% by mass based on the total amount of the cosmetic. Further, the content is preferably 35% by mass or more. If the amount of the non-volatile liquid oil is too small, the moist feeling is insufficient.
Moreover, it is preferable that it is 60 mass% or less. If the amount of the non-volatile liquid oil is too large, the matte feeling is insufficient.
（（ｖ３）半固形油分）
半固形油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。半固形油分は、好ましくは融点３０～５０℃の油分が挙げられる。 ((V3) semi-solid oil content)
The semi-solid oil component is not particularly limited as long as it is generally used for cosmetics. The semi-solid oil preferably includes an oil having a melting point of 30 to 50 ° C.
半固形油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。半固形油分は、好ましくは融点３０～５０℃の油分が挙げられる。 ((V3) semi-solid oil content)
The semi-solid oil component is not particularly limited as long as it is generally used for cosmetics. The semi-solid oil preferably includes an oil having a melting point of 30 to 50 ° C.
半固形油分としては、例えば、ワセリン、テトラ（ベヘン酸／安息香酸／エチルヘキサン酸）ペンタエリスリット、ヘキサヒドロキシステアリン酸ジペンタエリスリチル、ダイマージリノール酸エステル、マカダミアナッツ油ポリグリセリル－６エステルズベヘネート、テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチル、ビスジグリセリルポリアシルアジペート－２等が挙げられる。
Examples of the semi-solid oil component include petrolatum, tetra (behenic acid / benzoic acid / ethylhexanoic acid) pentaerythrit, dipentaerythrityl hexahydroxystearate, dimer dilinoleate, macadamia nut oil polyglyceryl-6 ester sbehenate, tetra (Hydroxystearic acid / isostearic acid) dipentaerythrityl, bisdiglyceryl polyacyl adipate-2 and the like.
（（ｖ４）固形油分）
固形油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。 ((V4) solid oil content)
The solid oil can be used without any particular limitation as long as it is generally used in cosmetics.
固形油分は、化粧料に一般的に使用されているものであれば特に制限されず使用することができる。 ((V4) solid oil content)
The solid oil can be used without any particular limitation as long as it is generally used in cosmetics.
固形油分としては、例えば、固体油脂、ロウ類、固形炭化水素、高級アルコールが挙げられる。例えば、カカオ脂、硬化ヒマシ油等の固体油脂；モクロウ、カルナウバロウ、ミツロウ、サラシミツロウ、キャンデリラロウ、ホホバロウ等のロウ類：ポリエチレンワックス、パラフィンワックス、セレシン、マイクロクリスタリンワックス等の炭化水素ワックス；セチルアルコール、ステアリルアルコール、ベヘニルアルコール、バチルアルコール等の高級アルコール；シリコーンワックス等が例示される。
Examples of the solid oil component include solid oils and fats, waxes, solid hydrocarbons, and higher alcohols. For example, solid oils such as cacao butter and hydrogenated castor oil; waxes such as mocro, carnauba wax, beeswax, salami beeswax, candelilla wax and jojoba wax: hydrocarbon waxes such as polyethylene wax, paraffin wax, ceresin, and microcrystalline wax; cetyl Higher alcohols such as alcohol, stearyl alcohol, behenyl alcohol, and butyl alcohol; silicone wax;
本発明の化粧料は、Ｐ／Ｖ比が０．３０～０．７５であることが必要である。Ｐ／Ｖ比は、粉末の配合量を、液状油分の配合量で除することにより計算することができる。なお、Ｐ／Ｖ比は、色材を除いて算出した値である。Ｐ／Ｖ比が０．３０～０．７５であることにより、マット感を有しつつ、なめらかな使用感が得られる。
Ｐ／Ｖ比は、０．３５以上であることが好ましい。また、Ｐ／Ｖ比は、０．３８以上であることがより好ましい。Ｐ／Ｖ比が低すぎると、マット感が不足する。
また、Ｐ／Ｖ比は、０．６０以下であることが好ましい。Ｐ／Ｖ比が高すぎると、なめらかさが低減したり、経時でのパサつきや乾燥感が高まったりする。 The cosmetic of the present invention needs to have a P / V ratio of 0.30 to 0.75. The P / V ratio can be calculated by dividing the blended amount of the powder by the blended amount of the liquid oil. Note that the P / V ratio is a value calculated excluding the coloring material. When the P / V ratio is 0.30 to 0.75, a smooth feeling of use can be obtained while having a matte feeling.
The P / V ratio is preferably 0.35 or more. Further, the P / V ratio is more preferably 0.38 or more. If the P / V ratio is too low, the matte feeling will be insufficient.
Further, the P / V ratio is preferably 0.60 or less. If the P / V ratio is too high, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
Ｐ／Ｖ比は、０．３５以上であることが好ましい。また、Ｐ／Ｖ比は、０．３８以上であることがより好ましい。Ｐ／Ｖ比が低すぎると、マット感が不足する。
また、Ｐ／Ｖ比は、０．６０以下であることが好ましい。Ｐ／Ｖ比が高すぎると、なめらかさが低減したり、経時でのパサつきや乾燥感が高まったりする。 The cosmetic of the present invention needs to have a P / V ratio of 0.30 to 0.75. The P / V ratio can be calculated by dividing the blended amount of the powder by the blended amount of the liquid oil. Note that the P / V ratio is a value calculated excluding the coloring material. When the P / V ratio is 0.30 to 0.75, a smooth feeling of use can be obtained while having a matte feeling.
The P / V ratio is preferably 0.35 or more. Further, the P / V ratio is more preferably 0.38 or more. If the P / V ratio is too low, the matte feeling will be insufficient.
Further, the P / V ratio is preferably 0.60 or less. If the P / V ratio is too high, the smoothness is reduced, and the feeling of dryness and dryness over time are increased.
本発明の化粧料において、塗布３０分後のＰ／Ｖ比が０．５～０．８であることが好ましい。
に お い て In the cosmetic of the present invention, the P / V ratio 30 minutes after application is preferably 0.5 to 0.8.
本発明の化粧料は、硬度が１５～８０ｇｆであることが好ましい。本発明の化粧料は、硬度が１５～８０ｇｆであることにより、化粧料の安定性がさらに良好になり、さらに種々の容器を用いることができる。
硬度は２０ｇｆ以上であることが好ましい。硬度が低すぎると、フィット感に劣る場合がある。また、硬度は７０ｇｆ以下であることが好ましい。硬度が高すぎると、なめらかさに劣る場合がある。
なお、硬度の測定方法は、サン科学社製レオメータを用いて次の条件で測定した（負荷重：２ｋｇ、針の径：５．６φ、針入深度：３ｍｍ、上昇速度：２０ｍｍ／ｍｉｎ、測定温度：２５℃）。 The cosmetic of the present invention preferably has a hardness of 15 to 80 gf. When the cosmetic of the present invention has a hardness of 15 to 80 gf, the stability of the cosmetic is further improved, and various containers can be used.
The hardness is preferably 20 gf or more. If the hardness is too low, the fit may be poor. Further, the hardness is preferably 70 gf or less. If the hardness is too high, smoothness may be poor.
The hardness was measured using a rheometer manufactured by Sun Kagaku Co., Ltd. under the following conditions (load weight: 2 kg, needle diameter: 5.6φ, needle penetration depth: 3 mm, rising speed: 20 mm / min, measurement) Temperature: 25 ° C).
硬度は２０ｇｆ以上であることが好ましい。硬度が低すぎると、フィット感に劣る場合がある。また、硬度は７０ｇｆ以下であることが好ましい。硬度が高すぎると、なめらかさに劣る場合がある。
なお、硬度の測定方法は、サン科学社製レオメータを用いて次の条件で測定した（負荷重：２ｋｇ、針の径：５．６φ、針入深度：３ｍｍ、上昇速度：２０ｍｍ／ｍｉｎ、測定温度：２５℃）。 The cosmetic of the present invention preferably has a hardness of 15 to 80 gf. When the cosmetic of the present invention has a hardness of 15 to 80 gf, the stability of the cosmetic is further improved, and various containers can be used.
The hardness is preferably 20 gf or more. If the hardness is too low, the fit may be poor. Further, the hardness is preferably 70 gf or less. If the hardness is too high, smoothness may be poor.
The hardness was measured using a rheometer manufactured by Sun Kagaku Co., Ltd. under the following conditions (load weight: 2 kg, needle diameter: 5.6φ, needle penetration depth: 3 mm, rising speed: 20 mm / min, measurement) Temperature: 25 ° C).
本発明の化粧料は、チューブ状容器やジャー容器など種々の容器に充填することができるが、チューブ状容器に充填することが好適である。マットな仕上がりの化粧料は、化粧料の硬度や粘度が硬いため、チューブ状化粧料にすると容器から出すことが困難であったため、チューブ状化粧料にすることが困難であった。しかし、本願発明では、マットな仕上がりでありながらも、なめらかで塗布しやすいチューブ状化粧料を得ることも可能である。
化粧 The cosmetic of the present invention can be filled in various containers such as a tube-shaped container and a jar container, but is preferably filled in a tube-shaped container. A cosmetic having a matte finish is difficult to take out of a container when it is made into a tube-shaped cosmetic because the hardness and viscosity of the cosmetic are hard, so that it is difficult to make a tube-shaped cosmetic. However, in the present invention, it is also possible to obtain a tube-shaped cosmetic which is smooth and easy to apply while having a matte finish.
本発明にかかる化粧料には、上記必須成分以外に、通常化粧料に使用される成分、例えば、色材、界面活性剤、水溶性高分子、増粘剤、皮膜剤、保湿剤、紫外線吸収剤、美容成分、繊維、香料、水等を必要に応じて配合することができる。
In the cosmetic according to the present invention, in addition to the above essential components, components usually used in cosmetics, for example, coloring materials, surfactants, water-soluble polymers, thickeners, coating agents, humectants, and ultraviolet absorbers Agents, cosmetic ingredients, fibers, fragrances, water and the like can be added as necessary.
また、本発明にかかる化粧料には、色材を配合しても良い。色材は、製剤を着色することを目的に配合されるものである。色材としては、顔料、パール顔料、これらをレーキ化したものなど、化粧料に通常配合されるものを使用することができる。
色 Further, a coloring material may be blended in the cosmetic according to the present invention. The coloring material is compounded for the purpose of coloring the preparation. As the coloring material, pigments, pearl pigments, and lacquered ones of these can be used which are usually blended in cosmetics.
具体的には、無機白色系顔料（二酸化チタン、酸化亜鉛）、無機赤色系顔料（酸化鉄(べンガラ)、チタン酸鉄）、無機褐色系顔料（γ－酸化鉄）、無機黄色系顔料（黄酸化鉄、黄土）、無機黒色系顔料（黒酸化鉄、カーボン、低次酸化チタン）、無機紫色系顔料（マンゴバイオレット、コバルトバイオレット）、無機緑色系顔料（酸化クロム、水酸化クロム、チタン酸コバルト）、無機青色系顔料（群青、紺青）、パール顔料（酸化チタン被覆マイカ、酸化チタン被覆オキシ塩化ビスマス、酸化チタン被覆タルク、着色酸化チタン被覆マイカ、オキシ塩化ビスマス、魚鱗箔）、金属粉末顔料（アルミニウムパウダー、カッパーパウダー）、有機顔料（赤色２０２号、赤色２０５号、赤色２２０号、赤色２２８号、赤色４０５号、橙色２０３号、橙色２０４号、黄色２０５号、黄色４０１号、青色４０４号）、ジルコニウム、バリウム、アルミニウムレーキの有機顔料（赤色３号、赤色１０４号、赤色２２７号、赤色４０１号、橙色２０５号、黄色４号、黄色２０２号、緑色３号、青色１号）、天然色素（クロロフィル、カルチノイド系（β－カロチン）、カルサミン、コチニール、カルコン、クルクミン、ベタニン、フラボノール、フラボン、アントシアニジン、アントラキノン、ナフトキノン）、機能性顔料（窒化ホウ素、フォトクロミック顔料、合成フッ素金雲母、鉄含有合成フッ素金雲母、微粒子複合粉体（ハイブリッドファインパウダー））等が挙げられる。
Specifically, inorganic white pigments (titanium dioxide, zinc oxide), inorganic red pigments (iron oxide (iron oxide), iron titanate), inorganic brown pigments (γ-iron oxide), inorganic yellow pigments ( Yellow iron oxide, loess, inorganic black pigments (black iron oxide, carbon, lower titanium oxide), inorganic purple pigments (mango violet, cobalt violet), inorganic green pigments (chromium oxide, chromium hydroxide, titanic acid) Cobalt), inorganic blue pigments (ultramarine, navy blue), pearl pigments (titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, colored titanium oxide-coated mica, bismuth oxychloride, fish scale foil), metal powder pigments (Aluminum powder, copper powder), organic pigments (red 202, red 205, red 220, red 228, red 405, orange 203) No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404), organic pigments of zirconium, barium, aluminum lake (Red No. 3, Red No. 104, Red No. 227, Red No. 401, Orange No. 205, Yellow No. 4) No., Yellow No. 202, Green No. 3, Blue No. 1), natural pigments (chlorophyll, carcinoid (β-carotene), calsamine, cochineal, chalcone, curcumin, betanin, flavonol, flavone, anthocyanidin, anthraquinone, naphthoquinone), function Pigments (boron nitride, photochromic pigments, synthetic fluorophlogopite, iron-containing synthetic fluorophlogopite, fine particle composite powder (hybrid fine powder)), and the like.
非イオン性界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレン多価アルコール脂肪酸部分エステル、ポリオキシエチレン硬化ヒマシ油誘導体等のポリオキシエチレン系界面活性剤、オクチルポリグリコシド等のアルキルポリグリコシド類、ポリグリセリン脂肪酸エステル、ポリグリセリンアルキルエーテル等のポリグリセリン系界面活性剤、マルチトールヒドロキシアルキルエーテル等の糖アルコールヒドロキシアルキルエーテル類、脂肪酸ジエタノールアミド等が挙げられる。
また、高級脂肪酸塩類、アルキルベンゼンスルホン酸塩類、リン酸エステル類、アルキル硫酸塩類、アルキル硫酸エステル塩類、ポリオキシエチレンアルキル硫酸エステル塩類等のアニオン性界面活性剤、アミノ酸類、アルキルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、アルキルジメチルアミンオキサイド等のカチオン性界面活性剤、その他の界面活性剤を配合することもできる。 As nonionic surfactants, for example, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene-based surfactants such as polyoxyethylene hydrogenated castor oil derivatives, Examples thereof include alkyl polyglycosides such as octyl polyglycoside, polyglycerin-based surfactants such as polyglycerin fatty acid ester and polyglycerin alkyl ether, sugar alcohol hydroxyalkyl ethers such as maltitol hydroxyalkyl ether, and fatty acid diethanolamide.
Further, anionic surfactants such as higher fatty acid salts, alkylbenzene sulfonates, phosphates, alkyl sulfates, alkyl sulfates, polyoxyethylene alkyl sulfates, amino acids, alkyltrimethylammonium salts, dialkyldimethyl Cationic surfactants such as ammonium salts and alkyldimethylamine oxides, and other surfactants can also be blended.
また、高級脂肪酸塩類、アルキルベンゼンスルホン酸塩類、リン酸エステル類、アルキル硫酸塩類、アルキル硫酸エステル塩類、ポリオキシエチレンアルキル硫酸エステル塩類等のアニオン性界面活性剤、アミノ酸類、アルキルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、アルキルジメチルアミンオキサイド等のカチオン性界面活性剤、その他の界面活性剤を配合することもできる。 As nonionic surfactants, for example, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene-based surfactants such as polyoxyethylene hydrogenated castor oil derivatives, Examples thereof include alkyl polyglycosides such as octyl polyglycoside, polyglycerin-based surfactants such as polyglycerin fatty acid ester and polyglycerin alkyl ether, sugar alcohol hydroxyalkyl ethers such as maltitol hydroxyalkyl ether, and fatty acid diethanolamide.
Further, anionic surfactants such as higher fatty acid salts, alkylbenzene sulfonates, phosphates, alkyl sulfates, alkyl sulfates, polyoxyethylene alkyl sulfates, amino acids, alkyltrimethylammonium salts, dialkyldimethyl Cationic surfactants such as ammonium salts and alkyldimethylamine oxides, and other surfactants can also be blended.
天然の水溶性高分子としては、例えば、植物系高分子（例えば、アラビアガム、トラガカントガム、ガラクタン、グアガム、キャロブガム、カラヤガム、カラギーナン、ペクチン、カンテン、クインスシード(マルメロ)、アルゲコロイド(カッソウエキス)、デンプン(コメ、トウモロコシ、バレイショ、コムギ)、グリチルリチン酸）；微生物系高分子（例えば、キサンタンガム、デキストラン、サクシノグルカン、ブルラン等）；動物系高分子（例えば、コラーゲン、カゼイン、アルブミン、ゼラチン等）等が挙げられる。
Examples of natural water-soluble polymers include, for example, plant polymers (e.g., gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (cassow extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (eg, xanthan gum, dextran, succinoglucan, burlan, etc.); animal macromolecules (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
半合成の水溶性高分子としては、例えば、デンプン系高分子（例えば、カルボキシメチルデンプン、メチルヒドロキシプロピルデンプン等）；セルロース系高分子（メチルセルロース、エチルセルロース、メチルヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、セルロース硫酸ナトリウム、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム、結晶セルロース、セルロース末等）；アルギン酸系高分子（例えば、アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル等）等が挙げられる。
Semi-synthetic water-soluble polymers include, for example, starch-based polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, cellulose sodium sulfate) , Hydroxypropylcellulose, carboxymethylcellulose, carboxymethylcellulose sodium, crystalline cellulose, cellulose powder, etc.); and alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.).
合成の水溶性高分子としては、例えば、ビニル系高分子（例えば、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルピロリドン、カルボキシビニルポリマー等）；ポリオキシエチレン系高分子（例えば、ポリエチレングリコール２０，０００、４０，０００、６０，０００等）；アクリル系高分子（例えば、ポリアクリル酸ナトリウム、ポリエチルアクリレート、ポリアクリルアミド等）；ポリエチレンイミン；カチオンポリマー等が挙げられる。
Examples of the synthetic water-soluble polymer include a vinyl polymer (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.); and a polyoxyethylene polymer (eg, polyethylene glycol 20,000, 40). Acrylic polymers (eg, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethylene imines; cationic polymers, and the like.
増粘剤としては、例えば、アラビアガム、カラギーナン、カラヤガム、トラガカントガム、キャロブガム、クインスシード（マルメロ）、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アラギン酸ナトリウム、メチルセルロース、エチルセルロース、ＣＭＣ、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ＰＶＡ、ＰＶＭ、ＰＶＰ、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、ローカストビーンガム、グアガム、タマリントガム、ジアルキルジメチルアンモニウム硫酸セルロース、キサンタンガム、ケイ酸アルミニウムマグネシウム、ベントナイト、ヘクトライト、ケイ酸ＡｌＭｇ(ビーガム)、ラポナイト、無水ケイ酸等が挙げられる。
Examples of the thickener include gum arabic, carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate, xanthan gum, aluminum magnesium silicate, bentonite, hectorite, AlMg silicate (Vegum), Laponite, silicic anhydride and the like.
皮膜剤としては、例えば、シリコーン化プルラン、トリメチルシロキシケイ酸、ジメチルアミノメタクリレート４級化塩、ビニルピロリドン・メタクリル酸－N，N－ジメチル－エチルアンチニオエチル塩共重合体、シリコーン／ポリエーテル系ポリウレタン樹脂、（メタクリロイルオキシエチルカルボキシベタイン／メタクリルアルキル）コポリマー、デキストリン、（ビニルピロリドン／ＶＡ）コポリマー、アクリル酸アルキルコポリマーアンモニウム、ポリビニルアルコール、ポリアクリル酸エチル、（アクリル酸アルキル／オクチルアクリルアミド）コポリマー、（アクリレーツ／メタクリル酸プロピルトリメチコン）コポリマー、ポリ酢酸ビニル、（アクリル酸アルキル／ジメチコン）コポリマー、ポリエーテルグラフトアクリルシリコーン、トリメチルシロキシケイ酸、フロロ変成シリコーンレジン等が挙げられる。
Examples of the film-forming agent include siliconized pullulan, trimethylsiloxysilicic acid, dimethylaminomethacrylate quaternary salt, vinylpyrrolidone / methacrylic acid-N, N-dimethyl-ethylantinioethyl salt copolymer, and silicone / polyether-based Polyurethane resin, (methacryloyloxyethylcarboxybetaine / methacrylalkyl) copolymer, dextrin, (vinylpyrrolidone / VA) copolymer, alkyl acrylate ammonium, polyvinyl alcohol, polyethyl acrylate, (alkyl acrylate / octyl acrylamide) copolymer, (Acrylates / propyl methacrylate trimethicone) copolymer, polyvinyl acetate, (alkyl acrylate / dimethicone) copolymer, polyether grafted acrylic Recone, trimethylsiloxy silicic acid, fluorosilicone-modified silicone resin and the like.
保湿剤としては、例えば、ジプロピレングリコール、ポリエチレングリコール、プロピレングリコール、グリセリン、１，３－ブチレングリコール、キシリトール、ソルビトール、マルチトール、コンドロイチン硫酸、ヒアルロン酸、ムコイチン硫酸、カロニン酸、アテロコラーゲン、コレステリル－１２－ヒドロキシステアレート、乳酸ナトリウム、胆汁酸塩、ｄｌ－ピロリドンカルボン酸塩、短鎖可溶性コラーゲン、ジグリセリン（ＥＯ）ＰＯ付加物、イザヨイバラ抽出物、セイヨウノコギリソウ抽出物、メリロート抽出物等が挙げられる。
Examples of the humectant include dipropylene glycol, polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12. -Hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayobara extract, Achillea millefolium extract, melilot extract, etc.
紫外線吸収剤としては、例えば、安息香酸系紫外線吸収剤（例えば、パラアミノ安息香酸(以下、ＰＡＢＡと略す)、ＰＡＢＡモノグリセリンエステル、Ｎ，Ｎ－ジプロポキシＰＡＢＡエチルエステル、Ｎ，Ｎ－ジエトキシＰＡＢＡエチルエステル、Ｎ，Ｎ－ジメチルＰＡＢＡエチルエステル、Ｎ，Ｎ－ジメチルＰＡＢＡブチルエステル、Ｎ，Ｎ－ジメチルＰＡＢＡエチルエステル等）；アントラニル酸系紫外線吸収剤（例えば、ホモメンチル－Ｎ－アセチルアントラニレート等）；サリチル酸系紫外線吸収剤（例えば、アミルサリシレート、メンチルサリシレート、ホモメンチルサリシレート、オクチルサリシレート、フェニルサリシレート、ベンジルサリシレート、ｐ－イソプロパノールフェニルサリシレート等）；桂皮酸系紫外線吸収剤（例えば、オクチルシンナメート、エチル－４－イソプロピルシンナメート、メチル－２，５－ジイソプロピルシンナメート、エチル－２，４－ジイソプロピルシンナメート、メチル－２，４－ジイソプロピルシンナメート、プロピル－ｐ－メトキシシンナメート、イソプロピル－ｐ－メトキシシンナメート、イソアミル－ｐ－メトキシシンナメート、オクチル－ｐ－メトキシシンナメート(２－エチルヘキシル－ｐ－メトキシシンナメート)、２－エトキシエチル－ｐ－メトキシシンナメート、シクロヘキシル－ｐ－メトキシシンナメート、エチル－α－シアノ－β－フェニルシンナメート、２－エチルヘキシル－α－シアノ－β－フェニルシンナメート、グリセリルモノ－２－エチルヘキサノイル-ジパラメトキシシンナメート等）；ベンゾフェノン系紫外線吸収剤（例えば、２，４－ジヒドロキシベンゾフェノン、２，２’－ジヒドロキシ－４－メトキシベンゾフェノン、２，２’－ジヒドロキシ－４，４’－ジメトキシベンゾフェノン、２，２’，４，４’－テトラヒドロキシベンゾフェノン、２－ヒドロキシ－４－メトキシベンゾフェノン、２－ヒドロキシ－４－メトキシ－４’－メチルベンゾフェノン、２－ヒドロキシ－４－ メトキシベンゾフェノン－５－スルホン酸塩、４－フェニルベンゾフェノン、２－エチルヘキシル－４’－フェニル-ベンゾフェノン－２－カルボキシレート、２－ヒドロキシ－４－ｎ－オクトキシベンゾフェノン、４－ヒドロキシ－３－カルボキシベンゾフェノン等）；３－（４’－メチルベンジリデン）－ｄ，ｌ－カンファー、３－ベンジリデン－ｄ，ｌ－カンファー；２－フェニル－５－メチルベンゾキサゾール；２，２’－ヒドロキシ－５－メチルフェニルベンゾトリアゾール；２－（２’－ヒドロキシ－５’－ｔ－オクチルフェニル） ベンゾトリアゾール；２－（２’－ヒドロキシ－５’－メチルフェニルベンゾトリアゾール；ジベンザラジン；ジアニソイルメタン；４－メトキシ－４’－ｔ－ブチルジベンゾイルメタン；５－（３，３－ジメチル－２－ノルボルニリデン）－３－ペンタン－２－オン等が挙げられる。
Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers (eg, para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester , N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid ultraviolet absorbers (eg, homomenthyl-N-acetylanthranilate, etc.); Salicylic acid-based ultraviolet absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid-based ultraviolet absorber (Eg octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxy Cinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl -P-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); Benzov Non-UV absorbers (eg, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4 '-Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4- {methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, -Ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); 3- (4'-methylbenzylidene) -d, l-Camphor, 3-benzylidene d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 4-methoxy-4'-t-butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene)- 3-pentan-2-one and the like.
その他の配合可能成分としては、例えば、防腐剤（エチルパラベン、ブチルパラベン等）；美白剤（例えば、胎盤抽出物、ユキノシタ抽出物、アルブチン等）；血行促進剤（ニコチン酸、ニコチン酸ベンジル、ニコチン酸トコフェロール、ニコチン酸β－ブトキシエステル、ミノキシジル又はその類縁体、ビタミンＥ類、γ－オリザノール、アルコキシカルボニルピリジンＮ－オキシド、塩化カルプロニウム、及びアセチルコリン又はその誘導体等）；各種抽出物（例えば、ショウガ、ウバク、オウレン、シコン、バーチ、ビワ、ニンジン、アロエ、ゼニアオイ、アイリス、ブドウ、ヘチマ、ユリ、サフラン、センキュウ、ショウキュウ、オトギリソウ、オノニス、ニンニク、トウガラシ、チンピ、トウキ、ボタン、海藻等）、賦活剤（例えば、パンテニールエチルエーテル、ニコチン酸アミド、ビオチン、パントテン酸、ローヤルゼリー、コレステロール誘導体等）；抗脂漏剤（例えば、ピリドキシン類、チアントール等）等が挙げられる。
Other incorporable components include, for example, preservatives (eg, ethyl paraben, butyl paraben); whitening agents (eg, placental extract, saxifrage extract, arbutin); blood circulation promoters (nicotinic acid, benzyl nicotinate, nicotine) Acid tocopherol, nicotinic acid β-butoxyester, minoxidil or an analog thereof, vitamin Es, γ-oryzanol, alkoxycarbonylpyridine N-oxide, carpronium chloride, and acetylcholine or a derivative thereof; various extracts (eg, ginger, Ubak, spinach, radish, birch, loquat, carrot, aloe, mallow, iris, grape, loofah, lily, saffron, senkyu, gingerbread, hypericum, ononis, garlic, capsicum, chimpanzee, cypress, button, seaweed, etc.), activation Agent (for example Examples thereof include panthenyl ethyl ether, nicotinamide, biotin, pantothenic acid, royal jelly, cholesterol derivatives, etc.); antiseborrheic agents (eg, pyridoxines, thianthol, etc.).
本発明の化粧料は、リップグロス、下地用のリップベース、口紅オーバーコート、リップクリームなどの唇用化粧料、アイシャドー、頬紅、ファンデーション、化粧下地等のメーキャップ化粧料、スキンケア化粧料、毛髪化粧料などに応用することができる。
Lip cosmetics such as lip gloss, base lip base, lipstick overcoat, lip balm, etc., makeup cosmetics such as eye shadow, blusher, foundation, makeup base, skin care cosmetics, hair makeup It can be applied to materials.
本発明について、以下に実施例を挙げてさらに詳述するが、本発明はこれにより何ら限定されるものではない。配合量は特記しない限り、その成分が配合される系に対する質量％で示す。
実施例の説明に先立ち本発明で用いた評価試験方法について説明する。 The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. Unless otherwise specified, the compounding amount is shown in mass% based on the system in which the component is compounded.
Prior to the description of the examples, the evaluation test method used in the present invention will be described.
実施例の説明に先立ち本発明で用いた評価試験方法について説明する。 The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. Unless otherwise specified, the compounding amount is shown in mass% based on the system in which the component is compounded.
Prior to the description of the examples, the evaluation test method used in the present invention will be described.
評価（１）：硬度測定試験
容器充填前の試料の硬度を、サン科学社製レオメータを用いて以下の条件で測定した（負荷重：２ｋｇ、針の径：５．６φ、針入深度：３ｍｍ、上昇速度：２０ｍｍ／ｍｉｎ、測定温度：２５℃）。 Evaluation (1): Hardness Measurement Test The hardness of the sample before filling the container was measured using a rheometer manufactured by Sun Kagaku Co., Ltd. under the following conditions (loading weight: 2 kg, needle diameter: 5.6φ, penetration depth: 3 mm). , Rising speed: 20 mm / min, measuring temperature: 25 ° C).
容器充填前の試料の硬度を、サン科学社製レオメータを用いて以下の条件で測定した（負荷重：２ｋｇ、針の径：５．６φ、針入深度：３ｍｍ、上昇速度：２０ｍｍ／ｍｉｎ、測定温度：２５℃）。 Evaluation (1): Hardness Measurement Test The hardness of the sample before filling the container was measured using a rheometer manufactured by Sun Kagaku Co., Ltd. under the following conditions (loading weight: 2 kg, needle diameter: 5.6φ, penetration depth: 3 mm). , Rising speed: 20 mm / min, measuring temperature: 25 ° C).
評価（２）：使用感（なめらかさ、マット感、縦じわの目立たなさ、しっとり感）
専門パネル１０名が唇に試料を塗布し、塗布時の使用感（なめらかさ、マット感、縦じわの目立たなさ、しっとり感）を評価した。
Ａ：９名以上が使用感が良好である（なめらかさがある、マット感がある、縦皺が目立たない、しっとり感がある）と回答した。
Ｂ：８名が使用感が良好であると回答した。
Ｃ：７名が使用感が良好であると回答した。
Ｄ：５名以上７名未満が使用感が良好であると回答した。
Ｅ：４名が使用感が良好であると回答した。
Ｆ：４名未満が使用感が良好であると回答した。
上記評価がE以上は、使用感がよく、Fは使用感が劣るものとした。 Evaluation (2): Usability (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling)
Ten professional panels applied the sample to the lips, and evaluated the feeling of use (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling) at the time of application.
A: Nine or more persons answered that the feeling of use was good (smooth, matte, inconspicuous vertical wrinkles, and moist).
B: Eight people answered that the usability was good.
C: Seven persons answered that the usability was good.
D: Five or more and less than seven answered that the feeling of use was good.
E: Four persons answered that the usability was good.
F: Less than 4 persons answered that the feeling of use was good.
When the above evaluation was E or more, the usability was good, and F was inferior in usability.
専門パネル１０名が唇に試料を塗布し、塗布時の使用感（なめらかさ、マット感、縦じわの目立たなさ、しっとり感）を評価した。
Ａ：９名以上が使用感が良好である（なめらかさがある、マット感がある、縦皺が目立たない、しっとり感がある）と回答した。
Ｂ：８名が使用感が良好であると回答した。
Ｃ：７名が使用感が良好であると回答した。
Ｄ：５名以上７名未満が使用感が良好であると回答した。
Ｅ：４名が使用感が良好であると回答した。
Ｆ：４名未満が使用感が良好であると回答した。
上記評価がE以上は、使用感がよく、Fは使用感が劣るものとした。 Evaluation (2): Usability (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling)
Ten professional panels applied the sample to the lips, and evaluated the feeling of use (smoothness, matte feeling, inconspicuous vertical wrinkles, moist feeling) at the time of application.
A: Nine or more persons answered that the feeling of use was good (smooth, matte, inconspicuous vertical wrinkles, and moist).
B: Eight people answered that the usability was good.
C: Seven persons answered that the usability was good.
D: Five or more and less than seven answered that the feeling of use was good.
E: Four persons answered that the usability was good.
F: Less than 4 persons answered that the feeling of use was good.
When the above evaluation was E or more, the usability was good, and F was inferior in usability.
評価（３）：安定性
試料を低温（５℃）および高温（４０℃）で３０日間保管し、常温（２５℃）で保管した標準品と比較し、分離等の有無を確認した。
Ｇ：分離なし
Ｂ：分離あり Evaluation (3): Stability The sample was stored at a low temperature (5 ° C.) and a high temperature (40 ° C.) for 30 days, and compared with a standard product stored at a normal temperature (25 ° C.) to confirm the presence or absence of separation or the like.
G: No separation B: Separation
試料を低温（５℃）および高温（４０℃）で３０日間保管し、常温（２５℃）で保管した標準品と比較し、分離等の有無を確認した。
Ｇ：分離なし
Ｂ：分離あり Evaluation (3): Stability The sample was stored at a low temperature (5 ° C.) and a high temperature (40 ° C.) for 30 days, and compared with a standard product stored at a normal temperature (25 ° C.) to confirm the presence or absence of separation or the like.
G: No separation B: Separation
本発明者らは、下記表１および表２に示す化粧料（唇用化粧料）を常法により製造し、チューブ状容器に充填し、上記評価方法にて測定した。結果を表１および表２に示す。
(4) The present inventors manufactured cosmetics (lip cosmetics) shown in Tables 1 and 2 below by a conventional method, filled them into a tubular container, and measured them by the above-described evaluation methods. The results are shown in Tables 1 and 2.
試験例１－１より、揮発性油分の配合量が３質量％の場合、マット感に満足できないことが明らかになった。
試験例１－４、１－５より、極性油分（不揮発性液状油分）であるトリ（カプリル酸／カプリン酸）グリセリルの配合量を増やすことで、マット感やしっとり感が向上することがわかる。
試験例１－６より、パルミチン酸デキストリンが少ない場合、安定性が悪くなってしまう傾向にあることがわかる。 Test Example 1-1 revealed that when the amount of the volatile oil component was 3% by mass, the matte feeling was not satisfactory.
Test Examples 1-4 and 1-5 show that by increasing the amount of tri (caprylic acid / capric acid) glyceryl which is a polar oil component (non-volatile liquid oil component), the matt feeling and the moist feeling are improved.
Test Example 1-6 shows that when the amount of dextrin palmitate is small, the stability tends to deteriorate.
試験例１－４、１－５より、極性油分（不揮発性液状油分）であるトリ（カプリル酸／カプリン酸）グリセリルの配合量を増やすことで、マット感やしっとり感が向上することがわかる。
試験例１－６より、パルミチン酸デキストリンが少ない場合、安定性が悪くなってしまう傾向にあることがわかる。 Test Example 1-1 revealed that when the amount of the volatile oil component was 3% by mass, the matte feeling was not satisfactory.
Test Examples 1-4 and 1-5 show that by increasing the amount of tri (caprylic acid / capric acid) glyceryl which is a polar oil component (non-volatile liquid oil component), the matt feeling and the moist feeling are improved.
Test Example 1-6 shows that when the amount of dextrin palmitate is small, the stability tends to deteriorate.
次に、本発明者らは、Ｐ／Ｖ比について検討を行った。本発明者らは、下記表３に示す化粧料（唇用化粧料）を常法により製造し、チューブ状容器に充填し、上記評価方法にて測定した。結果を表３に示す。
Next, the present inventors studied the P / V ratio. The present inventors produced cosmetics (lip cosmetics) shown in Table 3 below by a conventional method, filled them into a tubular container, and measured them by the above-mentioned evaluation method. Table 3 shows the results.
表３より、Ｐ／Ｖ比が低すぎるとなめらかではあるものの、マット感が不足し、Ｐ／Ｖ比が高すぎるとマット感は高いものの、なめらかさおよびしっとり感が不足する傾向にあることが明らかになった。
From Table 3, it can be seen that if the P / V ratio is too low, the smoothness is insufficient, but the matte feeling is insufficient, and if the P / V ratio is too high, the matte feeling is high, but the smoothness and moistness tend to be insufficient. It was revealed.
これらのことから、本発明にかかる化粧料は、以下の粉末（Ｐ）と、油分（Ｖ）を含み、Ｐ／Ｖ比が０．３０～０．７５であることを特徴とする。
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン 化粧料全量中３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％ From these, the cosmetic according to the present invention is characterized by containing the following powder (P) and oil (V), and having a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン 化粧料全量中３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％ From these, the cosmetic according to the present invention is characterized by containing the following powder (P) and oil (V), and having a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic
Claims (5)
- 以下の粉末（Ｐ）と、油分（Ｖ）を含み、Ｐ／Ｖ比が０．３０～０．７５であることを特徴とする化粧料。
（Ｐ）（ｐ１）を含む粉末 化粧料全量中１５～４０質量％
（ｐ１）パルミチン酸デキストリン 化粧料全量中３．５～１０質量％
（Ｖ）（ｖ１）および（ｖ２）を含む油分
（ｖ１）揮発性油分 化粧料全量中５～５０質量％
（ｖ２）トリ（カプリル酸／カプリン酸）グリセリルを含む不揮発性液状油分 化粧料全量中３０～６５質量％ A cosmetic comprising the following powder (P) and oil (V) and having a P / V ratio of 0.30 to 0.75.
(P) Powder containing (p1) 15 to 40% by mass in the total amount of cosmetics
(P1) Dextrin palmitate 3.5 to 10% by mass based on the total amount of the cosmetic
(V) Oil containing (v1) and (v2) (v1) Volatile oil 5 to 50% by mass of the total amount of the cosmetic
(V2) Non-volatile liquid oil containing tri (caprylic / capric acid) glyceryl 30 to 65% by mass based on the total amount of the cosmetic - 請求項１に記載の化粧料において、粉末が板状粉末であることを特徴とする化粧料。 に お い て The cosmetic according to claim 1, wherein the powder is a plate-like powder.
- 請求項１または２に記載の化粧料において、トリ（カプリル酸／カプリン酸）グリセリルの配合量が化粧料全量中１０～３０質量％であることを特徴とする化粧料。 に お い て The cosmetic according to claim 1 or 2, wherein the blending amount of tri (caprylic / capric acid) glyceryl is 10 to 30% by mass based on the total amount of the cosmetic.
- 請求項１～３のいずれかに記載の化粧料において、（Ｖ）油分に（ｖ３）半固形油分を含むことを特徴とする化粧料。 (4) The cosmetic according to any one of (1) to (3), wherein (V) an oil component contains (v3) a semi-solid oil component.
- 請求項１～４のいずれかに記載の化粧料において、チューブ状容器に充填されていることを特徴とする化粧料。 (5) The cosmetic according to any one of (1) to (4), which is filled in a tubular container.
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| CN201980046148.XA CN112399845B (en) | 2018-07-10 | 2019-07-09 | Cosmetic product |
| JP2020530198A JP7254803B2 (en) | 2018-07-10 | 2019-07-09 | cosmetics |
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| PCT/JP2019/027154 WO2020013182A1 (en) | 2018-07-10 | 2019-07-09 | Cosmetic preparation |
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| JP (1) | JP7254803B2 (en) |
| CN (1) | CN112399845B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115551597A (en) * | 2020-06-29 | 2022-12-30 | 莱雅公司 | Compositions comprising pigments coated with isopropyl triisostearate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001302484A (en) * | 2000-04-17 | 2001-10-31 | Nippon Shikizai Inc | Unemulsion-based cosmetic |
| JP2005306856A (en) * | 2004-03-26 | 2005-11-04 | Kose Corp | Oil-based cosmetic |
| WO2011049246A1 (en) * | 2009-10-23 | 2011-04-28 | 東レ・ダウコーニング株式会社 | Novel organopolysiloxane copolymer |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2665951B2 (en) * | 1988-09-27 | 1997-10-22 | 株式会社資生堂 | Solid water-in-oil emulsified cosmetic |
| JP3781707B2 (en) * | 2002-09-25 | 2006-05-31 | ポーラ化成工業株式会社 | Cosmetics with a lame appearance |
| JP3942540B2 (en) * | 2002-12-27 | 2007-07-11 | 株式会社コーセー | Oily gel cosmetic |
| WO2006003733A1 (en) * | 2004-07-02 | 2006-01-12 | Shiseido Company, Ltd. | Oily-particle-containing composition for external use |
| KR100884480B1 (en) * | 2007-02-27 | 2009-02-17 | 주식회사 엘지생활건강 | Solid-type wax-free cosmetic composition for blocking ultraviolet ray |
| JP2008266211A (en) * | 2007-04-20 | 2008-11-06 | Mandom Corp | Cosmetic containing powder coated with silicone |
| WO2011010652A1 (en) * | 2009-07-23 | 2011-01-27 | 株式会社資生堂 | Water-in-oil emulsion cosmetic composition |
| FR3022776B1 (en) * | 2014-06-30 | 2018-03-02 | L'oreal | ANHYDROUS COMPOSITION COMPRISING A LIPOPHILIC GELIFIER, AT LEAST ONE PARTICULAR CHARGE AND A FATTY PHASE |
| FR3022775B1 (en) * | 2014-06-30 | 2018-03-02 | L'oreal | ANHYDROUS COMPOSITION COMPRISING A LIPOPHILIC GELIFIER, AT LEAST TWO SEPARATE LOADS OF ANOTHER AND A FATTY PHASE |
| JP6181697B2 (en) * | 2015-04-13 | 2017-08-16 | 千葉製粉株式会社 | Dextrin fatty acid esters and cosmetics |
| JP6604829B2 (en) * | 2015-11-19 | 2019-11-13 | 花王株式会社 | Solid oily cleansing cosmetic |
| KR101841554B1 (en) * | 2016-09-12 | 2018-03-26 | 한국콜마주식회사 | Solid cosmetic composition with high melting point and high glossy |
| CN107041851B (en) * | 2016-12-23 | 2020-11-03 | 广州智媛生物科技有限公司 | Foundation make-up composition for dark skin color and preparation method thereof |
-
2019
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- 2019-07-09 WO PCT/JP2019/027154 patent/WO2020013182A1/en active Application Filing
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001302484A (en) * | 2000-04-17 | 2001-10-31 | Nippon Shikizai Inc | Unemulsion-based cosmetic |
| JP2005306856A (en) * | 2004-03-26 | 2005-11-04 | Kose Corp | Oil-based cosmetic |
| WO2011049246A1 (en) * | 2009-10-23 | 2011-04-28 | 東レ・ダウコーニング株式会社 | Novel organopolysiloxane copolymer |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE GNPD February 2013 (2013-02-01), "Volume & Curl Mascara S", XP055675712, Database accession no. 2155316 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115551597A (en) * | 2020-06-29 | 2022-12-30 | 莱雅公司 | Compositions comprising pigments coated with isopropyl triisostearate |
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| JPWO2020013182A1 (en) | 2021-07-15 |
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| TW202019380A (en) | 2020-06-01 |
| CN112399845A (en) | 2021-02-23 |
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