TW202019380A - Cosmetic - Google Patents

Cosmetic Download PDF

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Publication number
TW202019380A
TW202019380A TW108124298A TW108124298A TW202019380A TW 202019380 A TW202019380 A TW 202019380A TW 108124298 A TW108124298 A TW 108124298A TW 108124298 A TW108124298 A TW 108124298A TW 202019380 A TW202019380 A TW 202019380A
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Taiwan
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oil
cosmetics
mass
acid
powder
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TW108124298A
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Chinese (zh)
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中田子
大賀光
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日商資生堂股份有限公司
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/08Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

The present invention provides a smooth cosmetic while having a matte finish. The cosmetic of the present invention comprising the following powder (P) and oil (V) and having a P/V ratio of 0.30 to 0.75. (P) is a powder containing (p1), is 15 to 40% by mass in the total amount of the cosmetic. (p1) is a dextrin palmitate, is 3.5 to 10% by mass in the total amount of the cosmetic. (V) is an oil containing (v1) and (v2). (v1) is a volatile oil component, is 5 to 50% by mass in the total amount of the cosmetic. (v2) is a non-volatile liquid oil containing tri (caprylic acid/capric acid) glyceryl, is 30 to 65% by mass in the total amount of the cosmetic.

Description

化妝料 Makeup

本申請案主張2018年7月10日申請的日本專利申請案2018-131071號的優先權,並將其併入本文。 This application claims the priority of Japanese Patent Application No. 2018-131071 filed on July 10, 2018, and incorporates it into this document.

本發明係關於化妝料,特別關於雖具有霧面消光成果卻也光滑的化妝料。 The present invention relates to cosmetics, and in particular to cosmetics which are smooth even though they have matte matting results.

塗佈有化妝料的肌膚及嘴唇的質感,大致上二分為會賦予光澤感與霧面消光感者。其中,屬於液狀的化妝料且具有霧面消光質感的化妝料,大多為光滑度不佳,且皺紋經時變明顯者。此外,具有霧面消光感的化妝料由於太硬而無法製成管,且並非從容器直接塗佈,而係使用預先置入容器中的塗佈器進行塗佈者,或者為充填於內托盤或罐式用的容器中者(參照例如專利文獻1)。 The texture of skin and lips coated with cosmetics is roughly divided into two that give gloss and matte matte feeling. Among them, the cosmetics that are liquid cosmetics and have a matte matte texture are mostly those with poor smoothness and wrinkles that become noticeable over time. In addition, the cosmetics with matte matte feeling are too hard to be made into tubes, and are not directly applied from the container, but are applied by using an applicator pre-installed in the container, or filled in the inner tray Or a container for a can (see, for example, Patent Document 1).

[先前技術文獻] [Prior Technical Literature]

[專利文獻] [Patent Literature]

[專利文獻1]日本特開平11-269039號公報 [Patent Document 1] Japanese Patent Laid-Open No. 11-269039

本發明係有鑑於前述以往的技術而進行者,本發明欲解決之課題係提供一種雖具有霧面消光成果卻也光滑的化妝料。 The present invention has been carried out in view of the aforementioned prior art, and the problem to be solved by the present invention is to provide a smooth cosmetic material that has a matte matte effect.

本發明者等為了解決前述課題而進行深入研究的結果,發現藉由含有特定量之含棕櫚酸糊精酯的粉末、揮發性油份、含三(辛酸/癸酸)甘油酯的不揮發性液狀油份並且調整P/V比,則可獲得雖具有霧面消光成果卻也光滑的化妝料,從而完成本發明。 The inventors have conducted intensive studies to solve the aforementioned problems, and found that by containing a specific amount of a palmitate-containing dextrin ester-containing powder, a volatile oil, and non-volatile matter containing tri(octanoic acid/decanoic acid) glyceride The liquid oil content and the P/V ratio are adjusted to obtain a smooth cosmetic material that has a matte matte effect, thereby completing the present invention.

亦即,本發明之化妝料係含有下述之粉末(P)與油份(V),且P/V比為0.30至0.7。 That is, the cosmetic of the present invention contains the following powder (P) and oil (V), and the P/V ratio is 0.30 to 0.7.

(P)為含(p1)的粉末,且係化妝料總量中的15至40質量%, (P) is a powder containing (p1), and is 15 to 40% by mass in the total amount of cosmetics,

(p1)為棕櫚酸糊精酯,且係3.5至10質量%; (p1) is dextrin palmitate and is 3.5 to 10% by mass;

(V)為含(v1)及(v2)的油份, (V) is the oil containing (v1) and (v2),

(v1)為揮發性油份,且係化妝料總量中的5至50質量%, (v1) is a volatile oil and is 5 to 50% by mass in the total amount of cosmetics,

(v2)為含三(辛酸/癸酸)甘油酯的不揮發性液狀油份,且係化妝料總量中的30至65質量%; (v2) is a non-volatile liquid oil containing tri(caprylic acid/capric acid) glyceride, and is 30 to 65% by mass in the total amount of cosmetics;

前述化妝料中,粉末適合為板狀粉末。 In the aforementioned cosmetics, the powder is suitably a plate-like powder.

前述化妝料中,三(辛酸/癸酸)甘油酯之調配量適合為化妝料總量中的10至30質量%。 In the aforementioned cosmetics, the blending amount of tri(octanoic acid/capric acid) glyceride is suitably 10 to 30% by mass of the total cosmetics.

前述化妝料中,(V)油份中適合含有(v3)半固形油份。 In the aforementioned cosmetics, the (V) oil component preferably contains (v3) a semi-solid oil component.

前述化妝料,適合充填於管狀容器中。 The aforementioned cosmetics are suitable for filling in tubular containers.

依據本發明可獲得雖具有霧面消光成果卻也光滑的化妝料。 According to the present invention, it is possible to obtain a cosmetic that is smooth even though it has a matte finish.

以下係針對本發明之實施形態進行詳細的說明。 The following is a detailed description of the embodiments of the present invention.

本發明之化妝料係含有下述之粉末(P)與油份(V),且P/V比為0.30至0.75。 The cosmetic of the present invention contains the following powder (P) and oil (V), and the P/V ratio is 0.30 to 0.75.

(P)為含(p1)的粉末,且係化妝料總量中的15至40質量%, (P) is a powder containing (p1), and is 15 to 40% by mass in the total amount of cosmetics,

(p1)為棕櫚酸糊精酯,且係化妝料總量中的3.5至10質量%; (p1) is dextrin palmitate and is 3.5 to 10% by mass in the total amount of cosmetics;

(V)為含(v1)及(v2)的油份, (V) is the oil containing (v1) and (v2),

(v1)為揮發性油份,且係化妝料總量中的5至50質量%, (v1) is a volatile oil and is 5 to 50% by mass in the total amount of cosmetics,

(v2)為含三(辛酸/癸酸)甘油酯的不揮發性液狀油份,且係化妝料總量中的30至65質量%。 (v2) is a non-volatile liquid oil containing tri(caprylic acid/capric acid) glyceride, and is 30 to 65% by mass in the total amount of cosmetics.

((P)粉末) ((P) powder)

粉末並無特別限制,若為通常使用於化妝料者則可使用。然而,在本發明中,粉末中不包含有色材料。 The powder is not particularly limited, and can be used if it is generally used in cosmetics. However, in the present invention, no colored material is contained in the powder.

粉末較佳係使用未經疏水化處理的粉末。若使用疏水化處理的粉末,則必須增加粉末量以確保穩定性,故有感覺到乾澀的情況。 The powder is preferably one that has not been hydrophobized. If the hydrophobized powder is used, the amount of powder must be increased to ensure stability, so dryness may be felt.

((p1)棕櫚酸糊精酯) ((p1) dextrin palmitate)

本發明之粉末中必須含有棕櫚酸糊精酯。 The powder of the present invention must contain dextrin palmitate.

棕櫚酸糊精酯之調配量必須係化妝料總量中的3.5至10質量%。此外,較佳係4質量%以上。棕櫚酸糊精酯之調配量過少,則穩定性不佳。 The formulation amount of dextrin palmitate must be 3.5 to 10% by mass in the total amount of cosmetics. In addition, it is preferably 4% by mass or more. If the amount of dextrin palmitate is too small, the stability is not good.

此外,較佳係9質量%以下。棕櫚酸糊精酯之調配量過多,則會損害塗抹推展的光滑度。 In addition, it is preferably 9% by mass or less. Too much dextrin palmitate will damage the smoothness of the spread.

此外,較佳係使用板狀粉末作為粉末。若使用球狀粉末,則有使用感劣化的情況。 In addition, it is preferable to use a plate-like powder as the powder. If spherical powder is used, the feeling of use may deteriorate.

板狀粉末若為通常使用於化妝料的粉體,則不受多孔質、無孔質等之粒子構造等特別限定,可列舉無機粉體類、光輝性粉體類、有機粉體類、色素粉體類、複合粉體類等。 If the plate-shaped powder is a powder generally used in cosmetics, it is not particularly limited by the particle structure of porous, non-porous, etc., and examples include inorganic powders, bright powders, organic powders, and pigments. Powders, composite powders, etc.

板狀粉末之短徑與長徑的比率較佳係相對於短徑1而言長徑10以上。 The ratio of the short diameter to the long diameter of the plate-shaped powder is preferably a long diameter of 10 or more with respect to the short diameter 1.

板狀粉末可列舉例如:絹雲母、雲母、合成雲母、滑石、氧化鋅、氧化鋁、矽酐、氧化鎂、氧化鋯、碳酸鎂、碳酸鈣、硫酸鈣、氧化鉻、氫氧化鉻、碳黑、矽酸鋁、矽酸鎂、矽酸鋁鎂、高嶺土、碳化矽、硫酸鋇、膨土、綠土(smectite)、氮化硼等無機粉體類;氧氯化鉍、氧化鈦被覆雲母、氧化鐵被覆雲母、氧化鐵被覆雲母鈦、有機顏料被覆雲母鈦、氧化鈦被覆玻璃薄片、鋁粉末、聚對酞酸乙二酯積層末等光輝性粉體類;N-醯基離胺酸等有機粉體類;微粒子氧化鈦被覆雲母鈦、微粒子氧化鋅被覆雲母鈦、硫酸鋇被覆雲母鈦等複合粉體類等。 Examples of the plate-like powder include sericite, mica, synthetic mica, talc, zinc oxide, aluminum oxide, silicon anhydride, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, calcium sulfate, chromium oxide, chromium hydroxide, and carbon black , Aluminum silicate, magnesium silicate, magnesium aluminum silicate, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride and other inorganic powders; bismuth oxychloride, titanium oxide coated mica, Bright powders such as iron oxide-coated mica, iron oxide-coated mica titanium, organic pigment-coated mica titanium, titanium oxide-coated glass flakes, aluminum powder, polyethylene terephthalate lamination, etc.; N-acrylic acid, etc. Organic powders; composite powders such as mica titanium coated with fine particles of titanium, mica titanium coated with fine particles of zinc oxide, and mica titanium coated with barium sulfate, etc.

其中,較佳係使用絹雲母、雲母、合成雲母、滑石。 Among them, sericite, mica, synthetic mica, and talc are preferably used.

粉末之調配量必須係化妝料總量中的15至40質量%。此 外,較佳係20質量%以上。粉末之調配量過少,則霧面消光感不足。 The blending amount of the powder must be 15 to 40% by mass in the total amount of cosmetics. this In addition, it is preferably 20% by mass or more. If the amount of powder is too small, the matte feeling of the matte surface will be insufficient.

此外,較佳係35質量%以下。粉末之調配量過多,則光滑度降低,或乾澀、乾燥感經時提高。 In addition, it is preferably 35% by mass or less. If the amount of powder is too much, the smoothness will decrease, or the dryness and dryness will increase with time.

((V)油份) ((V)oil content)

油份(V)可列舉揮發性油份、不揮發性液狀油份、半固形油份、固形油份。 The oil (V) includes volatile oil, non-volatile liquid oil, semi-solid oil, and solid oil.

((v1)揮發性油份) ((v1) volatile oil)

揮發性油份並無特別限制,若為通常使用於化妝料者則可使用。揮發性油份較佳可列舉沸點未達250℃的油份。 The volatile oil content is not particularly limited, and can be used if it is generally used in cosmetics. Preferred volatile oils include oils having a boiling point of less than 250°C.

揮發性油份可列舉例如:十甲基環五矽氧烷、八甲基環四矽氧烷、十二甲基環六矽氧烷、甲基聚三甲基矽氧烷(methyl trimethicone)、聚二甲基矽氧烷、十甲基四矽氧烷、乙基三矽氧烷、輕質液體異烷烴等。 Examples of the volatile oil include: decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecylcyclohexasiloxane, methyl trimethicone, Polydimethylsiloxane, decamethyltetrasiloxane, ethyltrisiloxane, light liquid isoalkane, etc.

揮發性油份的調配量必須係化妝料總量中的5至50質量%。此外,較佳係10質量%以上。揮發性油份之調配量過少,則霧面消光感不足。 The blending amount of volatile oil must be 5 to 50% by mass in the total amount of cosmetics. In addition, it is preferably 10% by mass or more. If the blending amount of volatile oil is too small, the matt feeling of matte surface will be insufficient.

此外,較佳係30質量%以下。揮發性油份之調配量過多,則塗佈時的服貼感降低。 In addition, it is preferably 30% by mass or less. If the amount of volatile oil is too much, the sticking feeling during coating will decrease.

((v2)不揮發性液狀油份) ((v2) Non-volatile liquid oil)

不揮發性液狀油份並無特限制,若為通常使用於化妝料者則可使用。不揮發性液狀油份較佳可列舉沸點250℃以上的油份。 The non-volatile liquid oil content is not particularly limited, and can be used if it is generally used in cosmetics. The nonvolatile liquid oil preferably includes an oil having a boiling point of 250°C or higher.

不揮發性液狀油份可列舉例如極性油份、烴油、天然動植物油及半合成油、矽油等。 Examples of nonvolatile liquid oils include polar oils, hydrocarbon oils, natural animal and vegetable oils, semi-synthetic oils, and silicone oils.

在本發明之化妝料中,不揮發性液狀油份之中較佳係含有極 性油份。藉由調配極性油份,可更獲得濕潤感優異的化妝料。 In the cosmetic of the present invention, it is preferable that the nonvolatile liquid oil contains Sexual oil. By blending polar oils, cosmetics with excellent moisturization can be obtained.

本發明之化妝料中,必須調配屬於極性油份的三(辛/癸)酸甘油酯。此外,其調配量較佳係化妝料總量中的10至30質量%。此外,更佳係20質量%以上。三(辛/癸)酸甘油酯之調配量過少,則有霧面消光感及濕潤感不佳的情況。 In the cosmetic of the present invention, triglyceride (caprylic/decanoic acid) which is a polar oil must be blended. In addition, the formulation amount thereof is preferably 10 to 30% by mass in the total amount of cosmetics. In addition, it is more preferably 20% by mass or more. If the amount of tris(caprylic/capric) glyceride is too small, the matt matte feeling and moist feeling may be poor.

此外,更佳係25質量%以下。三(辛/癸)酸甘油酯之調配量過多,則有霧面消光感及服貼感不佳的情況。 In addition, it is more preferably 25% by mass or less. If the amount of tris(caprylic/decanoic acid) glyceride is too much, there may be a matt matte feeling and poor fit.

其他的極性油份可列舉例如:蘋果酸二異硬脂酯、二癸酸新戊二醇酯、三2-乙基己酸甘油酯、四2-乙基己酸新戊四醇酯、癸二酸二乙基己酯、辛基十二醇、二異硬脂酸甘油酯、三異硬脂酸二甘油酯、三2-乙基己酸三羥甲基丙烷酯、羥基硬脂酸羥基硬脂酯、四(乙基己酸/苯甲酸)新戊四醇酯、三異辛酸甘油酯、四辛酸新戊四醇酯、六羥基硬脂酸二新戊四醇酯、蓖麻油、癸二酸二異丙酯、四辛酸新戊四醇酯、三異硬脂酸三羥甲基丙烷酯等。 Other polar oils include, for example, diisostearyl malate, neopentyl glycol dicaprate, glycerol tri-2-ethylhexanoate, neopentyltetraol tetrakis 2-ethylhexanoate, and decane Diethylhexyl diacid, octyldodecanol, glyceryl diisostearate, diglyceryl triisostearate, trimethylolpropane tri-2-ethylhexanoate, hydroxyl hydroxystearate Stearate, Tetrakis(ethylhexanoic acid/benzoic acid) neopentaerythritol ester, Triisooctanoic acid glyceride, Tetraoctanoic acid pentaerythritol ester, Hexahydroxystearic acid dipentaerythritol ester, Castor oil, Decane Diisopropyl diacid, neopentyl tetraoctanoate, trimethylolpropane triisostearate, etc.

烴油可列舉:氫化聚異丁烯、液體石蠟、鯊烷、鯊烯、重質液體異烷烴、聚異丁烯、α-烯烴寡聚物等。 Examples of the hydrocarbon oil include hydrogenated polyisobutylene, liquid paraffin, squalane, squalene, heavy liquid isoparaffin, polyisobutylene, and α-olefin oligomers.

天然動植物油及半合成油可列舉:鰐梨油、亞麻仁油、扁桃油(almond oil)、橄欖油、榧籽油、肝油、杏仁油(apricot kernel oil)、小麥胚芽油、芝麻油、米胚芽油、米糠油、茶梅(Camellia sasanqua)油、紅花籽油、川泡桐油、桂皮油、海龜油、大豆油、茶籽油、山茶花油、月見草油、玉米油、菜籽油、日本桐油、胚芽油、杏/桃仁油、棕櫚油、紅棕櫚油、棕櫚仁油、蓖麻油、葵花籽油、葡萄籽油、荷荷芭油、澳洲胡桃油、棉籽油、椰子油、三 椰子油脂肪酸甘油酯、花生油、液狀羊毛脂、還原羊毛脂、羊毛脂醇、乙酸羊毛脂、羊毛脂脂肪酸異丙酯、POE羊毛脂醇醚、POE羊毛脂醇乙酸酯、羊毛脂脂肪酸聚乙二醇、POE氫化羊毛脂醇醚、蛋黃油等。 Examples of natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, japonica seed oil, liver oil, apricot kernel oil, wheat germ oil, sesame oil, rice germ Oil, rice bran oil, Camellia sasanqua oil, safflower seed oil, paulownia oil, cassia oil, sea turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, rape seed oil, Japanese tung oil, Germ oil, apricot/peach kernel oil, palm oil, red palm oil, palm kernel oil, castor oil, sunflower oil, grape seed oil, jojoba oil, Australian walnut oil, cottonseed oil, coconut oil, three Coconut oil fatty acid glyceride, peanut oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, isopropyl lanolin fatty acid, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid poly Ethylene glycol, POE hydrogenated lanolin alcohol ether, egg butter, etc.

矽油可列舉聚二甲基矽氧烷、聚甲基苯基矽氧烷、苯基聚三甲基矽氧烷等。 Examples of the silicone oil include polydimethylsiloxane, polymethylphenylsiloxane, and phenylpolytrimethylsiloxane.

不揮發性液狀油份之調配量必須係化妝料總量中的30至65質量%。此外,較佳係35質量%以上。不揮發性液狀油份之調配量過少則濕潤感不足。 The blending amount of the non-volatile liquid oil must be 30 to 65% by mass in the total amount of cosmetics. In addition, it is preferably 35% by mass or more. If the amount of non-volatile liquid oil is too small, the moist feeling will be insufficient.

此外,較佳係60質量%以下。不揮發性液狀油份之調配量過多則霧面消光感不足。 In addition, it is preferably 60% by mass or less. If the amount of non-volatile liquid oil is too large, the matt matte feeling will be insufficient.

((v3)半固形油份) ((v3) semi-solid oil)

半固形油份並無特別限制,若為通常使用於化妝料者則可使用。半固形油份較佳可列舉溶點30至50℃的油份。 The semi-solid oil content is not particularly limited, and can be used if it is generally used in cosmetics. The semi-solid oil preferably includes an oil having a melting point of 30 to 50°C.

半固形油份可列舉例如:凡士林、四(二十二酸/苯甲酸/乙基己酸)新戊四醇酯、六羥基硬脂酸二新戊四醇酯、二聚體二亞麻油酸酯、澳洲胡桃油聚甘油-6酯二十二酸酯、四(羥基硬脂酸/異硬脂酸)二新戊四醇酯、雙二甘油多醯基己二酸酯-2等。 Examples of semi-solid oils include petroleum jelly, tetrakis(docosanoic acid/benzoic acid/ethylhexanoic acid) neopentaerythritol, hexahydroxystearic acid dipentaerythritol, dimer dilinolenic acid Ester, Australian walnut oil polyglycerol-6 ester behenate, tetra(hydroxystearic acid/isostearic acid) dipentaerythritol ester, bisdiglycerol polyadipate-2, etc.

((v4)固形油份) ((v4) solid oil)

固形油份並無特別限制,若為通常使用於化妝料者則可使用。 The solid oil content is not particularly limited, and can be used if it is generally used in cosmetics.

固形油份可列舉例如固體油脂、蠟類、固形烴、高級醇。可例示例如:可可脂、氫化蓖麻油等固體油脂;日本蠟、巴西棕櫚蠟、蜂蠟、白蜂蠟、堪地里拉蠟、荷荷巴蠟等蠟類:聚乙烯蠟、石蠟、地蠟、微晶蠟 等烴蠟;鯨蠟醇、硬脂醇、二十二醇、鯊肝醇等高級醇;聚矽氧蠟等。 Examples of solid oils include solid fats and oils, waxes, solid hydrocarbons, and higher alcohols. Examples include: cocoa butter, hydrogenated castor oil and other solid oils and fats; Japanese wax, carnauba wax, beeswax, white beeswax, candelilla wax, jojoba wax and other waxes: polyethylene wax, paraffin wax, ozokerite, microcrystalline wax Other hydrocarbon waxes; higher alcohols such as cetyl alcohol, stearyl alcohol, eicosanediol, squalanol; polysiloxane wax, etc.

本發明之化妝料的P/V比必須係0.30至0.75。P/V比可藉由將粉末之調配量除以液狀油份之調配量而計算。又,P/V比係排除有色材料而算出的值。藉由使P/V比為0.30至0.75,則在具有霧面消光感的同時獲得光滑的使用感。 The P/V ratio of the cosmetic of the present invention must be 0.30 to 0.75. The P/V ratio can be calculated by dividing the formulated amount of powder by the formulated amount of liquid oil. In addition, the P/V ratio is a value calculated by excluding colored materials. By setting the P/V ratio from 0.30 to 0.75, a smooth feeling of use can be obtained while having a matte matte feeling.

P/V比較佳係0.35以上。此外,P/V比更佳係0.38以上。P/V比過低則霧面消光感不足。 P/V is better than 0.35. In addition, the P/V ratio is more preferably 0.38 or more. If the P/V ratio is too low, the matt matte feeling is insufficient.

此外,P/V比較佳係0.60以下。P/V比過高,則光滑度降低,或乾澀、乾燥感經時提高。 In addition, P/V is better than 0.60. If the P/V ratio is too high, the smoothness decreases, or the dryness and dryness improve with time.

在本發明之化妝料中,塗佈30分鐘後的P/V比較佳係0.5至0.8。 In the cosmetic of the present invention, the P/V after 30 minutes of application is preferably 0.5 to 0.8.

本發明之化妝料的硬度較佳係15至80gf。藉由使本發明之化妝料的硬度為15至80gf,則化妝料的穩定性變得更良好,並且可使用各種容器。 The hardness of the cosmetic of the present invention is preferably 15 to 80 gf. By setting the hardness of the cosmetic of the present invention to 15 to 80 gf, the stability of the cosmetic becomes better, and various containers can be used.

硬度較佳係20gf以上。硬度過低則有服貼感不佳的情況。此外,硬度較佳係70gf以下。硬度過高則有光滑度不佳的情況。 The hardness is preferably 20 gf or more. If the hardness is too low, there may be a poor feeling of service. In addition, the hardness is preferably 70 gf or less. If the hardness is too high, the smoothness may be poor.

又,硬度的測定方法係使用Sun科學(Sun Scientific)公司製的流變計且依下述的條件而測定(負荷重:2kg、針徑:5.6

Figure 108124298-A0202-12-0008-6
、針入深度:3mm、上升速度:20mm/分鐘、測定溫度:25℃)。 In addition, the measurement method of the hardness is measured using the rheometer manufactured by Sun Scientific (Sun Scientific) under the following conditions (load weight: 2 kg, needle diameter: 5.6
Figure 108124298-A0202-12-0008-6
, Penetration depth: 3mm, Ascent speed: 20mm/min, Measuring temperature: 25°C).

本發明的化妝料可充填於管狀容器及罐式容器等各種的容器中,惟適合充填於管狀容器。有霧面消光成果的化妝料由於化妝料之硬度及黏度硬,因此當製成管狀化妝料時則難以從容器取出,故難以製成管 狀化妝料。然而,在本案發明中,可獲得雖具有霧面消光成果卻也光滑且易於塗佈的管狀化妝料。 The cosmetic material of the present invention can be filled in various containers such as a tube container and a can container, but it is suitable for filling the tube container. Cosmetics with matte matting results are hard to remove from the container when they are made into tubular cosmetics due to their hardness and viscosity, so it is difficult to make tubes Shaped cosmetics. However, in the present invention, it is possible to obtain a tubular cosmetic that is smooth and easy to apply despite having a matte matte effect.

本發明之化妝料中,除了上述必要成分以外,還可因應需求調配通常使用於化妝料的成分,例如有色材料、界面活性劑、水溶性高分子、增黏劑、膜形成劑、保濕劑、紫外線吸收劑、美容成分、纖維、香料、水等。 In the cosmetics of the present invention, in addition to the above-mentioned essential ingredients, ingredients commonly used in cosmetics, such as colored materials, surfactants, water-soluble polymers, tackifiers, film formers, humectants, UV absorbers, beauty ingredients, fibers, fragrances, water, etc.

此外,本發明之化妝料中可調配有色材料。有色材料係以使製劑著色為目的而調配者。有色材料可使用顏料、珠光顏料、此等經色澱化者等通常調配於化妝料者。 In addition, the cosmetic materials of the present invention can be provided with colored materials. Colored materials are formulated for the purpose of coloring the preparation. As the colored material, pigments, pearlescent pigments, or those that have undergone lake treatment, etc., which are usually formulated in cosmetics, can be used.

具體而言,可列舉:無機白色系顏料(二氧化鈦、氧化鋅)、無機紅色系顏料(氧化鐵(鐵丹)、鈦酸鐵)、無機褐色系顏料(γ-氧化鐵)、無機黃色系顏料(黃氧化鐵、黃土)、無機黑色系顏料(黑氧化鐵、碳、低次氧化鈦)、無機紫色系顏料(錳紫、鈷紫)、無機綠色系顏料(氧化鉻、氫氧化鉻、鈦酸鈷)、無機藍色系顏料(群青、普魯士藍)、珠光顏料(氧化鈦被覆雲母、氧化鈦被覆氧氯化鉍、氧化鈦被覆滑石、著色氧化鈦被覆雲母、氧氯化鉍、魚鱗箔)、金屬粉末顏料(鋁粉末、銅粉末)、有機顏料(紅色202號、紅色205號、紅色220號、紅色228號、紅色405號、橙色203號、橙色204號、黃色205號、黃色401號、藍色404號)、鋯、鋇、鋁色澱的有機顏料(紅色3號、紅色104號、紅色227號、紅色401號、橙色205號、黃色4號、黃色202號、綠色3號、藍色1號)、天然色素(葉綠素、類胡蘿蔔素系(β-胡蘿蔔素)、紅花素、胭脂蟲紅、查耳酮、薑黃素、甜菜苷、黃酮醇、黃酮、花青素、蒽醌、萘醌)、機能性顏料 (氮化硼、光致變色顏料、合成氟金雲母、含鐵合成氟金雲母、微粒子複合粉體(混合細粉末))等。 Specific examples include inorganic white pigments (titanium dioxide, zinc oxide), inorganic red pigments (iron oxide (iron oxide), iron titanate), inorganic brown pigments (γ-iron oxide), inorganic yellow pigments (Yellow iron oxide, loess), inorganic black pigments (black iron oxide, carbon, lower titanium oxide), inorganic purple pigments (manganese violet, cobalt purple), inorganic green pigments (chromium oxide, chromium hydroxide, titanium) Cobalt acid), inorganic blue pigments (ultramarine blue, Prussian blue), pearlescent pigments (titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil ), metal powder pigments (aluminum powder, copper powder), organic pigments (red 202, red 205, red 220, red 228, red 405, orange 203, orange 204, yellow 205, yellow 401 No., blue No. 404), zirconium, barium, aluminum lake organic pigments (Red No. 3, Red No. 104, Red No. 227, Red No. 401, Orange No. 205, Yellow No. 4, Yellow No. 202, Green No. 3 , Blue No. 1), natural pigments (chlorophyll, carotenoids (β-carotene), safflower, cochineal, chalcone, curcumin, betanin, flavonol, flavonoids, anthocyanins, anthracene Quinone, naphthoquinone), functional pigments (Boron nitride, photochromic pigments, synthetic fluorophlogopite, iron-containing synthetic fluorophlogopite, fine particle composite powder (mixed fine powder)), etc.

非離子性界面活性劑可列舉例如:聚氧乙烯烷基醚、聚氧乙烯脂肪酸酯、聚氧乙烯多元醇脂肪酸部分酯、聚氧乙烯氫化蓖麻油衍生物等聚氧乙烯系界面活性劑、辛基多醣苷等烷基多醣苷類、聚甘油脂肪酸酯、聚甘油烷基醚等聚甘油系界面活性劑、麥芽糖醇羥烷基醚等糖醇羥烷基醚類、脂肪酸二乙醇醯胺等。 Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyol fatty acid partial esters, polyoxyethylene hydrogenated castor oil derivatives, and other polyoxyethylene-based surfactants. Alkyl polyglycosides such as octyl polyglycosides, polyglycerin fatty acid esters such as polyglycerin fatty acid esters, polyglycerin alkyl ethers, sugar alcohol hydroxyalkyl ethers such as maltitol hydroxyalkyl ethers, fatty acid diethanolamide Wait.

此外,也可調配高級脂肪酸鹽類、烷基苯磺酸鹽類、磷酸酯類、烷基硫酸鹽類、烷基硫酸酯鹽類、聚氧乙烯烷基硫酸酯鹽類等陰離子性界面活性劑、胺基酸類、烷基三甲基銨鹽、二烷基二甲基銨鹽、烷基二甲基氧化胺等陽離子性界面活性劑、其他的界面活性劑。 In addition, anionic surfactants such as higher fatty acid salts, alkylbenzene sulfonates, phosphates, alkyl sulfates, alkyl sulfates, polyoxyethylene alkyl sulfates, etc. can also be formulated , Amino acids, alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salt, alkyl dimethyl amine oxide and other cationic surfactants, and other surfactants.

天然的水溶性高分子可列舉例如:植物系高分子(例如阿拉伯膠、黃蓍膠、半乳聚醣、瓜爾膠、長角豆膠、刺梧桐樹膠、角叉菜膠、果膠、洋菜膠、榅桲籽(木梨)、藻膠體(褐藻萃取物)、澱粉(米、玉米、馬鈴薯、小麥)、甘草酸);微生物系高分子(例如黃原膠、右旋糖酐(dextran)、琥珀醯葡聚醣、聚三葡萄糖等);動物系高分子(例如膠原蛋白、酪蛋白、白蛋白、明膠等)等。 Examples of natural water-soluble polymers include plant-based polymers (such as gum arabic, tragacanth, galactosan, guar gum, carob gum, karaya gum, carrageenan, pectin, and Vegetable gum, quince seed (wood pear), algal colloid (brown algae extract), starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (such as xanthan gum, dextran, succinate) (Dextran, polytriglucose, etc.); animal-based polymers (such as collagen, casein, albumin, gelatin, etc.), etc.

半合成的水溶性高分子可列舉例如:澱粉系高分子(例如羧甲基澱粉、甲基羥基丙基澱粉等);纖維素系高分子(甲基纖維素、乙基纖維素、甲基羥基丙基纖維素、羥基乙基纖維素、纖維素硫酸鈉、羥基丙基纖維素、羧基甲基纖維素、羧基甲基纖維素鈉、結晶纖維素、纖維素粉末等);藻酸系高分子(例如藻酸鈉、藻酸丙二醇酯等)等。 Examples of semi-synthetic water-soluble polymers include starch-based polymers (for example, carboxymethyl starch, methylhydroxypropyl starch, etc.); and cellulose-based polymers (methyl cellulose, ethyl cellulose, methyl hydroxyl) Propyl cellulose, hydroxyethyl cellulose, sodium sulfate cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, etc.); alginic acid-based polymer (Eg sodium alginate, propylene glycol alginate, etc.), etc.

合成的水溶性高分子可列舉例如:乙烯系高分子(例如聚乙烯醇、聚乙烯基甲基醚、聚乙烯基吡咯啶酮、羧基乙烯聚合物等);聚氧乙烯系高分子(例如聚乙二醇20,000、40,000、60,000等);丙烯酸系高分子(例如聚丙烯酸鈉、聚丙烯酸乙酯、聚丙烯醯胺等);聚乙烯亞胺;陽離子聚合物等。 Synthetic water-soluble polymers include, for example, vinyl-based polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymers, etc.); polyoxyethylene-based polymers (eg, Ethylene glycol 20,000, 40,000, 60,000, etc.); acrylic polymer (such as sodium polyacrylate, polyethyl acrylate, polypropylene amide, etc.); polyethyleneimine; cationic polymer, etc.

增黏劑可列舉例如:阿拉伯膠、角叉菜膠、刺梧桐樹膠、黃蓍膠、長角豆膠、榅桲籽(木梨)、酪蛋白、糊精、明膠、果膠酸鈉、藻酸鈉、甲基纖維素、乙基纖維素、CMC、羥基乙基纖維素、羥基丙基纖維素、PVA、PVM、PVP、聚丙烯酸鈉、羧基乙烯聚合物、刺槐豆膠、瓜爾膠、大瑪琳膠、二烷基二甲基銨硫酸纖維素、黃原膠、矽酸鋁鎂、膨土、鋰膨潤石(hectorite)、矽酸AlMg(VEEGUM;矽酸鎂鋁)、合成鋰皂石(laponite)、矽酐等。 Examples of the tackifier include gum arabic, carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (wood pear), casein, dextrin, gelatin, sodium pectin, alginic acid Sodium, methyl cellulose, ethyl cellulose, CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, large Marin gum, dialkyl dimethyl ammonium cellulose sulfate, xanthan gum, aluminum magnesium silicate, bentonite, lithium bentonite (hectorite), AlMg silicate (VEEGUM; magnesium aluminum silicate), laponite (laponite), silicon anhydride, etc.

膜形成劑可列舉例如:聚矽氧化聚三葡萄糖、三甲基矽氧基矽酸、二甲基胺基甲基丙烯酸四級鹽、乙烯基吡咯啶酮/甲基丙烯酸-N,N-二甲基-乙基銨基乙基鹽共聚物、聚矽氧/聚醚系聚胺酯樹脂、(甲基丙烯醯基氧基乙基羧基甜菜鹼/甲基丙烯酸烷基酯)共聚物、糊精、(乙烯基吡咯啶酮/VA)共聚物、丙烯酸烷基酯共聚物銨、聚乙烯醇、聚丙烯酸乙酯、(丙烯酸烷基酯/辛基丙烯醯胺)共聚物、(丙烯酸酯/甲基丙烯酸丙基聚三甲基矽氧烷酯)共聚物、聚乙酸乙烯酯、(丙烯酸烷基酯/聚二甲基矽氧烷)共聚物、聚醚接枝丙烯酸聚矽氧、三甲基矽氧基矽酸、氟改質聚矽氧樹脂等。 Examples of the film-forming agent include: polysilicon oxide polytriglucose, trimethylsiloxysilicic acid, dimethylaminomethacrylic acid quaternary salt, vinylpyrrolidone/methacrylic acid-N,N-di Methyl-ethylammonium ethyl salt copolymer, polysiloxane/polyether polyurethane resin, (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymer, dextrin, (Vinylpyrrolidone/VA) copolymer, alkyl acrylate copolymer ammonium, polyvinyl alcohol, polyethyl acrylate, (alkyl acrylate/octyl acrylamide) copolymer, (acrylate/methyl (Propyl acrylate polytrimethylsiloxane) copolymer, polyvinyl acetate, (alkyl acrylate/polydimethylsiloxane) copolymer, polyether grafted acrylic polysiloxane, trimethylsilicone Oxysilicic acid, fluorine modified silicone resin, etc.

保濕劑可列舉例如:二丙二醇、聚乙二醇、丙二醇、甘油、1,3-丁二醇、木糖醇、山梨醇、麥芽糖醇、軟骨素硫酸、玻尿酸、黏液素硫 酸、栝樓仁酸、缺端膠原蛋白(atelocollagen)、12-羥基硬脂酸膽甾酯、乳酸鈉、膽汁酸鹽、d1-吡咯啶酮羧酸鹽、短鏈可溶性膠原蛋白、二甘油(EO)PO加成物、繅絲花萃取物、蓍萃取物、黃香草木樨萃取物等。 Examples of the humectant include dipropylene glycol, polyethylene glycol, propylene glycol, glycerin, 1,3-butanediol, xylitol, sorbitol, maltitol, chondroitin sulfuric acid, hyaluronic acid, and mucin sulfur Acid, Konjac acid, atelocollagen, cholesteryl 12-hydroxystearate, sodium lactate, bile acid salt, d1-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO ) PO adducts, silk reel extracts, yarrow extracts, yellow vanilla extracts, etc.

紫外線吸收劑可列舉例如:苯甲酸系紫外線吸收劑(例如對胺苯甲酸(以下縮寫為PABA)、PABA單甘油酯、N,N-二丙氧基PABA乙酯、N,N-二乙氧基PABA乙酯、N,N-二甲基PABA乙酯、N,N-二甲基PABA丁酯、N,N-二甲基PABA乙酯等);鄰胺苯甲酸系紫外線吸收劑(例如N-乙醯基鄰胺苯甲酸3,3,5-三甲基環己酯等);柳酸系紫外線吸收劑(例如柳酸戊酯、柳酸薄荷酯、柳酸3,3,5-三甲基環己酯、柳酸辛酯、柳酸苯酯、柳酸苄酯、柳酸對異丙醇苯酯等);桂皮酸系紫外線吸收劑(例如桂皮酸辛酯、4-異丙基桂皮酸乙酯、2,5-二異丙基桂皮酸甲酯、2,4-二異丙基桂皮酸乙酯、2,4-二異丙基桂皮酸甲酯、對甲氧基桂皮酸丙酯、對甲氧基桂皮酸異丙酯、對甲氧基桂皮酸異戊酯、對甲氧基桂皮酸辛酯(對甲氧基桂皮酸2-乙基己酯)、對甲氧基桂皮酸2-乙氧基乙酯、對甲氧基桂皮酸環己酯、α-氰基-β-苯基桂皮酸乙酯、α-氰基-β-苯基桂皮酸2-乙基己酯、單-2-乙基己醯基二對甲氧基桂皮酸甘油酯等);二苯基酮系紫外線吸收劑(例如2,4-二羥基二苯基酮、2,2’-二羥基-4-甲氧基二苯基酮、2,2’-二羥基-4,4’-二甲氧基二苯基酮、2,2’,4,4’-四羥基二苯基酮、2-羥基-4-甲氧基二苯基酮、2-羥基-4-甲氧基-4’-甲基二苯基酮、2-羥基-4-甲氧基二苯基酮-5-磺酸鹽、4-苯基二苯基酮、2-乙基己基-4’-苯基-二苯基酮-2-羧酸酯、2-羥基-4-正辛氧基二苯基酮、4-羥基-3-羧基二苯基酮等);3-(4’-甲基亞苄基)-d,1-樟腦、3-亞苄基-d,1-樟腦;2-苯基-5-甲基苯并

Figure 108124298-A0202-12-0012-5
唑;2,2’-羥基-5-甲基苯基苯 并三唑;2-(2’-羥基-5’-三級辛基苯基)苯并三唑;2-(2’-羥基-5’-甲基苯基苯并三唑;雙亞苄肼;二大茴香醯基甲烷;4-甲氧基-4’-三級丁基二苯甲醯基甲烷;5-(3,3-二甲基-2-亞降莰基)-3-戊-2-酮等。 Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers (for example, p-aminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglyceride, N,N-dipropoxy PABA ethyl ester, and N,N-diethoxy PABA ethyl ester, N,N-dimethyl PABA ethyl ester, N,N-dimethyl PABA butyl ester, N,N-dimethyl PABA ethyl ester, etc.); o-aminobenzoic acid ultraviolet absorber (for example N-Acetylanthranilic acid 3,3,5-trimethylcyclohexyl ester, etc.); Salicylic acid-based ultraviolet absorbers (eg amyl salicylate, menthyl salicylate, salicylic acid 3,3,5- Trimethylcyclohexyl ester, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid-based ultraviolet absorbers (such as octyl cinnamate, 4-isopropylcinnamate Ethyl acetate, methyl 2,5-diisopropyl cinnamate, ethyl 2,4-diisopropyl cinnamate, methyl 2,4-diisopropyl cinnamate, propyl p-methoxycinnamate Ester, isopropyl p-methoxycinnamate, isoamyl p-methoxycinnamate, octyl p-methoxycinnamate (2-ethylhexyl p-methoxycinnamate), p-methoxycinnamic acid 2-ethoxyethyl, cyclohexyl p-methoxycinnamate, ethyl α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate, Mono-2-ethylhexyl di-p-methoxycinnamic acid glyceride, etc.); diphenyl ketone ultraviolet absorber (for example, 2,4-dihydroxydiphenyl ketone, 2,2'-dihydroxy- 4-methoxydiphenyl ketone, 2,2'-dihydroxy-4,4'-dimethoxydiphenyl ketone, 2,2',4,4'-tetrahydroxydiphenyl ketone, 2 -Hydroxy-4-methoxydiphenyl ketone, 2-hydroxy-4-methoxy-4'-methyldiphenyl ketone, 2-hydroxy-4-methoxydiphenyl ketone-5-sulfon Acid salt, 4-phenyl diphenyl ketone, 2-ethylhexyl-4'-phenyl-diphenyl ketone-2-carboxylic acid ester, 2-hydroxy-4-n-octyloxy diphenyl ketone, 4-hydroxy-3-carboxydiphenyl ketone, etc.); 3-(4'-methylbenzylidene)-d,1-camphor, 3-benzylidene-d,1-camphor; 2-phenyl- 5-methylbenzo
Figure 108124298-A0202-12-0012-5
Azole; 2,2'-hydroxy-5-methylphenylbenzotriazole;2-(2'-hydroxy-5'-tertiaryoctylphenyl)benzotriazole;2-(2'-hydroxyl-5'-methylphenylbenzotriazole; bisbenzylidene hydrazine; dianise acetyl methane; 4-methoxy-4'-tertiary butyl dibenzoyl methane; 5-(3, 3-dimethyl-2-norbenzylidene)-3-pentan-2-one, etc.

其他可調配的成分可列舉例如:防腐劑(對羥苯甲酸乙酯、對羥苯甲酸丁酯等);美白劑(例如胎盤萃取物、虎耳草萃取物、熊果苷等);血液循環促進劑(菸鹼酸、菸鹼酸苄酯、菸鹼酸生育酚酯、菸鹼酸β-丁氧基酯、米諾地爾(minoxidil)或其類似物、維生素E類、γ-穀醇、烷氧基羰基吡啶N-氧化物、卡普氯銨(carpronium chloride)、及乙醯膽鹼或其衍生物等);各種萃取物(例如生薑、黃柏、黃蓮、紫根、樺樹、枇杷、胡蘿蔔、蘆薈、錦葵、鳶尾、葡萄、絲瓜、百合、番紅花、川芎、乾燥薑、小連翹、芒柄花、大蒜、辣椒、陳皮、日本當歸、牡丹、海藻等)、活化劑(例如泛醇基乙基醚、菸鹼醯胺、生物素、泛酸、蜂王漿、膽固醇衍生物等);抗脂溢劑(例如吡哆醇類、二甲噻蒽(thianthol)等)等。 Other ingredients that can be formulated include, for example: preservatives (ethyl paraben, butyl paraben, etc.); whitening agents (such as placenta extract, saxifrage extract, arbutin, etc.); blood circulation Accelerator (nicotinic acid, benzyl nicotinate, tocopheryl nicotinate, β-butoxy nicotinic acid, minoxidil or its analogues, vitamin E, γ-glutamine , Alkoxycarbonylpyridine N-oxide, carpronium chloride, and acetylcholine or its derivatives, etc.); various extracts (such as ginger, yellow cedar, yellow lotus, purple root, birch, Loquat, carrot, aloe, mallow, iris, grape, loofah, lily, saffron, Chuanxiong, dried ginger, small forsythia, mangosteen flower, garlic, pepper, orange peel, Japanese angelica, peony, seaweed, etc.), activator ( For example, panthenyl ethyl ether, nicotinamide, biotin, pantothenic acid, royal jelly, cholesterol derivatives, etc.); anti-seborrheic agents (such as pyridoxine, thianthol, etc.), etc.

本發明之化妝料可應用於唇彩、打底用的唇底、口紅保護層、潤唇膏等唇用化妝料、眼影、腮紅、粉底、底妝等上妝化妝料、皮膚保養化妝料、毛髮化妝料等。 The cosmetics of the present invention can be applied to lip cosmetics such as lip gloss, lip base for primer, lipstick protective layer, lip balm, eye makeup, blusher, foundation, base makeup and other makeup cosmetics, skin care cosmetics, hair Cosmetics, etc.

[實施例] [Example]

以下列舉實施例以更詳細地說明本發明,惟本發明不限於此等。除非另有說明,否則調配量係以相對於調配該成分之系統而言之質量%表示。 The following examples are given to illustrate the present invention in more detail, but the present invention is not limited thereto. Unless otherwise stated, the blending amount is expressed in% by mass relative to the system in which the ingredient is blended.

在說明實施例之前,針對本發明所使用的評估試驗方法進行說明。 Before describing the examples, the evaluation test method used in the present invention will be described.

評估(1):硬度測定試驗 Evaluation (1): Hardness determination test

使用Sun科學公司製流變計並以下述的條件來測定容器充填前之試樣的硬度(負荷重:2kg、針徑:5.6

Figure 108124298-A0202-12-0014-4
、針入深度:3mm、上升速度:20mm/分鐘、測定溫度:25℃)。 The hardness of the sample before filling the container (load weight: 2 kg, needle diameter: 5.6) was measured using the rheometer manufactured by Sun Scientific under the following conditions
Figure 108124298-A0202-12-0014-4
, Penetration depth: 3mm, Ascent speed: 20mm/min, Measuring temperature: 25°C).

評估(2):使用感(光滑度、霧面消光感、縱向皺紋的明顯度、濕潤感) Evaluation (2): Use feeling (smoothness, matte matte feeling, noticeability of longitudinal wrinkles, moist feeling)

10名專業評審將試樣塗佈於唇,並評估塗佈時的使用感(光滑度、霧面消光感、縱向皺紋的明顯度、濕潤感)。 Ten professional reviewers applied the sample to the lips, and evaluated the feeling of use (smoothness, matte matte feeling, longitudinal wrinkle visibility, moisturizing feeling) during application.

A:9名以上回答了使用感良好(有光滑度、有霧面消光感、縱向皺紋不明顯、有濕潤感)。 A: 9 or more people answered that the feeling of use was good (smoothness, matte matte feeling, longitudinal wrinkles are not obvious, and moist feeling).

B:8名回答了使用感良好。 B: Eight people answered that the feeling of use was good.

C:7名回答了使用感良好。 C: Seven people answered that the feeling of use was good.

D:5名以上未達7名回答了使用感良好。 D: Five or more and less than seven answered that the feeling of use was good.

E:4名回答了使用感良好。 E: 4 people answered that the feeling of use was good.

F:未達4名回答了使用感良好。 上述評估為E以上則設定為使用感佳者,F則設定為使用感欠佳者。 F: Less than 4 people answered that the feeling of use was good. When the above evaluation is E or more, it is set as a person with a good sense of use, and F is set as a person with a poor sense of use.

評估(3):穩定性 Evaluation (3): Stability

將試樣在低溫(5℃)及高溫(40℃)保管30天,並與在常溫(25℃)保管的標準品做比較,以確認分離等的有無。 The samples were stored at a low temperature (5°C) and a high temperature (40°C) for 30 days, and compared with the standard products stored at normal temperature (25°C) to confirm the presence or absence of separation.

G:無分離 G: No separation

B:有分離 B: There is separation

本發明者等使用習知的方法來製造下述表1及表2所示的化妝料(唇用化妝料),充填於管狀容器中,並使用上述評估方法測定。 將結果表示於表1及表2。 The present inventors prepared the cosmetics (lip cosmetics) shown in Tables 1 and 2 below using a known method, filled them in a tubular container, and measured them using the evaluation method described above. The results are shown in Table 1 and Table 2.

【表1】

Figure 108124298-A0202-12-0015-1
【Table 1】
Figure 108124298-A0202-12-0015-1

【表2】

Figure 108124298-A0202-12-0016-7
【Table 2】
Figure 108124298-A0202-12-0016-7

從試驗例1-1可明顯得知,揮發性油份的調配量為3質量%時,無法滿足霧面消光感。 It is obvious from Test Example 1-1 that when the blending amount of the volatile oil is 3% by mass, the matte matte feeling cannot be satisfied.

從試驗例1-4、1-5可知,藉由增加屬於極性油份(不揮發性液狀油份)的三(辛酸/癸酸)甘油酯的調配量,提高了霧面消光感及濕潤感。 It can be seen from Test Examples 1-4 and 1-5 that by increasing the blending amount of tri(octanoic acid/decanoic acid) glyceride which is a polar oil (non-volatile liquid oil), the matte matte feeling and moistness are improved sense.

從試驗例1-6可知,棕櫚酸糊精酯少時,有穩定性變差的傾向。 It can be seen from Test Examples 1-6 that when there is little dextrin palmitate, the stability tends to deteriorate.

其次,本發明者等針對P/V比進行檢討。本發明者等使用習知的方法來製造下述表3所示的化妝料(唇用化妝料),充填於管狀容器中,並使用上述評估方法測定。將結果表示於表3。 Next, the present inventors reviewed the P/V ratio. The present inventors prepared the cosmetics (lip cosmetics) shown in Table 3 below using a known method, filled them in a tubular container, and measured them using the evaluation method described above. The results are shown in Table 3.

【表3】

Figure 108124298-A0202-12-0017-8
【table 3】
Figure 108124298-A0202-12-0017-8

從表3可明顯得知,P/V比過低則雖然光滑但有霧面消光感不足的傾向,P/V比過高則雖然霧面消光感高但有光滑度及濕潤感不足的傾向。 From Table 3, it is obvious that if the P/V ratio is too low, the matte matte feeling tends to be insufficient, but if the P/V ratio is too high, the matt matte feeling is high, but the smoothness and moistness tend to be insufficient. .

據此,本發明之化妝料係含有下述的粉末(P)與油份(V),且P/V比為0.30至0.75。 According to this, the cosmetic of the present invention contains the following powder (P) and oil (V), and the P/V ratio is 0.30 to 0.75.

(P)為含(p1)的粉末,且係化妝料總量中的15至40質量%, (P) is a powder containing (p1), and is 15 to 40% by mass in the total amount of cosmetics,

(p1)為棕櫚酸糊精酯,且係化妝料總量中的3.5至10質量%;(V)為含(v1)及(v2)的油份, (p1) is dextrin palmitate and is 3.5 to 10% by mass in the total amount of cosmetics; (V) is the oil containing (v1) and (v2),

(v1)為揮發性油份,且係化妝料總量中的5至50質量%, (v1) is a volatile oil and is 5 to 50% by mass in the total amount of cosmetics,

(v2)為含三(辛酸/癸酸)甘油酯的不揮發性液狀油份,且係化妝料總量中的30至65質量%。 (v2) is a non-volatile liquid oil containing tri(caprylic acid/capric acid) glyceride, and is 30 to 65% by mass in the total amount of cosmetics.

Claims (5)

一種化妝料,係含有下述之粉末(P)與油份(V),且P/V比為0.30至0.75;其中, A cosmetic material containing the following powder (P) and oil (V), and the P/V ratio is 0.30 to 0.75; wherein, (P)為含(p1)之粉末,且係化妝料總量中的15至40質量%, (P) is powder containing (p1), and is 15 to 40% by mass in the total amount of cosmetics, (p1)為棕櫚酸糊精酯,且係化妝料總量中的3.5至10質量%; (p1) is dextrin palmitate and is 3.5 to 10% by mass in the total amount of cosmetics; (V)為含(v1)及(v2)的油份, (V) is the oil containing (v1) and (v2), (v1)為揮發性油份,且係化妝料總量中的5至50質量%, (v1) is a volatile oil and is 5 to 50% by mass in the total amount of cosmetics, (v2)為含三(辛酸/癸酸)甘油酯之不揮發性液狀油份,且係化妝料總量中的30至65質量%。 (v2) is a non-volatile liquid oil containing tri(octanoic acid/capric acid) glyceride, and is 30 to 65% by mass in the total amount of cosmetics. 如申請專利範圍第1項所述之化妝料,其中,粉末為板狀粉末。 The cosmetic as described in item 1 of the patent application, wherein the powder is a plate-like powder. 如申請專利範圍第1或2項所述之化妝料,其中,三(辛酸/癸酸)甘油酯之調配量為化妝料總量中的10至30質量%。 The cosmetics as described in item 1 or 2 of the patent application, wherein the blending amount of tri(caprylic/capric) glyceride is 10 to 30% by mass of the total cosmetics. 如申請專利範圍第1至3項中任一項所述之化妝料,其中,(V)油份中含(v3)半固形油份。 The cosmetic material according to any one of the items 1 to 3 of the patent application range, wherein (V) oil contains (v3) semi-solid oil. 如申請專利範圍第1至4項中任一項所述之化妝料,其係充填於管狀容器中。 The cosmetic material according to any one of items 1 to 4 of the patent application scope is filled in a tubular container.
TW108124298A 2018-07-10 2019-07-10 Cosmetic TW202019380A (en)

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