TWI806859B - Liquid eye-makeup composition of water dispersion form - Google Patents
Liquid eye-makeup composition of water dispersion form Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
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Abstract
Description
本發明是有關於一種水分散型的液態眼部化妝品組成物,更詳細而言,有關於一種包括多孔性粉末、多元醇及油溶性膜形成劑的水分散型的液態眼部化妝品組成物。 The present invention relates to a water-dispersed liquid eye cosmetic composition, more specifically, to a water-dispersible liquid eye cosmetic composition comprising porous powder, polyhydric alcohol and an oil-soluble film forming agent.
彩妝發揮改善皮膚瑕疵、強調眼部與唇部而呈現精緻的容貌的重要作用。於混合於彩妝化妝品的成分中,著色物質(Coloring material)遮蓋斑點或印痕而呈現健康且具有迷人色調的皮膚。 Makeup plays an important role in improving skin imperfections and emphasizing the eyes and lips for a refined look. Among the ingredients mixed in make-up cosmetics, the coloring material (Coloring material) covers spots or scars to present a healthy and attractive skin tone.
上述彩妝分為用於使整個面部的膚色均勻且遮蓋瑕疵的底妝、及用於唇部、眼部、指甲等而局部地提高立體感的局部彩妝。底妝包括妝前底霜、粉底、化妝用粉等,局部彩妝包括唇部化妝品、眼部彩妝化妝品等。 The above-mentioned makeup is classified into a base makeup that is used to even out the skin tone of the entire face and cover blemishes, and a spot makeup that is used on the lips, eyes, nails, etc. to locally enhance the three-dimensional effect. Base makeup includes pre-makeup base cream, foundation, makeup powder, etc. Partial makeup includes lip cosmetics, eye makeup cosmetics, etc.
其中,眼部彩妝化妝品有睫毛膏、眼線筆、眼影、眉筆等,眼部彩妝化妝品用於塗抹至眼部周邊而強調眼部輪廓且對眼形賦予美感的目的。Among them, the eye makeup cosmetics include mascara, eyeliner, eye shadow, eyebrow pencil, etc., and the eye makeup cosmetics are applied to the periphery of the eyes to emphasize the outline of the eyes and to give beauty to the shape of the eyes.
眼部周圍的皮膚幾乎不分泌汗液、皮脂,且皮膚容易乾燥,膠原蛋白與彈性蛋白的組織(作為皮膚決定組織)少於其他部分的皮膚因而彈力較少,血管神經集中而較為敏感且皮膚容易受到刺激。特別是,塗抹眼影的上眼瞼為活動較多的部分,故而最初塗抹時的附著性、與塗抹眼影化妝品後即便眼皮活動亦保持最初塗抹狀態的持久性非常重要。The skin around the eyes hardly secretes sweat and sebum, and the skin is prone to dryness. The tissue of collagen and elastin (as the skin determining tissue) is less than that of other parts of the skin, so it is less elastic. The blood vessels and nerves are concentrated and sensitive, and the skin is easily irritated. In particular, the upper eyelid where the eyeshadow is applied is a part that moves a lot, so the adhesion at the time of initial application and the durability of the initial application state even if the eyelid moves after application of eyeshadow cosmetics are very important.
通常,化妝品組成物根據連續相及分散相的種類而分為油中水(water in oil,W/O)型、水中油(oil in water,O/W)型、油分散及水分散等,連續相為水的水中油型或水分散型雖表現出清爽且輕薄的使用感,但存在防水效果(即耐水性)下降的缺點,且存在光澤感較低的問題。Generally, cosmetic compositions are divided into water in oil (W/O) type, oil in water (O/W) type, oil dispersion, and water dispersion type according to the type of continuous phase and dispersed phase. Although the oil-in-water type or water dispersion type with water as the continuous phase has a refreshing and light feeling of use, it has the disadvantages of reduced waterproof effect (that is, water resistance) and low gloss.
作為用以解決上述問題的先前技術,韓國註冊專利第1060805號有關於一種持久性優異的防水眼部化妝品組成物,其揭示一種含有5重量%以下的高熔點蠟,使用表面塗覆有氟的聚乙烯粉末作為填充劑,含有氟類黏度調節劑及膜形成劑,藉此提供耐油性優異的油中水型或油分散眼部化妝品組成物。As a prior art for solving the above-mentioned problems, Korean Registered Patent No. 1060805 relates to a waterproof eye cosmetic composition with excellent durability, which discloses a water-in-oil type or oil-dispersed eye cosmetic composition with excellent oil resistance by using polyethylene powder coated with fluorine on the surface as a filler, containing a fluorine-based viscosity modifier and a film forming agent, containing a high-melting point wax at less than 5% by weight in Korean Registered Patent No. 1060805.
然而,油中水型或油分散型存在使用感較水中油型或水分散型略微厚重的缺點,且存在難以使用不易溶於油相的原料製備的問題。並且,於利用乳化劑進行乳化的情形時,在實現色調的方面存在極限。However, the water-in-oil type or the oil-dispersed type has the disadvantage that the feeling of use is slightly thicker than the oil-in-water type or the water-dispersed type, and there is a problem that it is difficult to use raw materials that are not easily soluble in the oil phase. In addition, when emulsifying with an emulsifier, there is a limit in realizing color tone.
因此,實情為需開發一種具有劑型穩定性、輕薄且皮膚負擔感較少、提高耐水性及妝容持久性且光澤度優異的眼部化妝品組成物。Therefore, there is a real need to develop an eye cosmetic composition that has stable dosage forms, is thin and light, has less burden on the skin, has improved water resistance and makeup durability, and has excellent gloss.
[先前技術文獻] [專利文獻] 韓國註冊專利第1060805號,持久性優異的防水眼部化妝品組成物[Prior Art Documents] [Patent Documents] Korean Patent No. 1060805, Waterproof Eye Cosmetic Composition with Excellent Durability
[發明欲解決的課題][Problem to be solved by the invention]
本發明者等人為了解決如上所述的問題,製備包括多孔性粉末、多元醇及油溶性膜形成劑的水分散型的液態眼部化妝品組成物,確認到如下情形而完成本發明:與現有的水分散型的眼部化妝品組成物相比,此種眼部化妝品組成物具有劑型穩定性、輕薄且皮膚負擔感較少、耐水性及妝容持久性提高且具有光澤感。In order to solve the above-mentioned problems, the present inventors prepared a water-dispersed liquid eye cosmetic composition including a porous powder, a polyhydric alcohol, and an oil-soluble film-forming agent, and completed the present invention after confirming that the eye cosmetic composition has dosage form stability, is light and thin, has less burden on the skin, and has improved water resistance and makeup durability and glossiness compared with conventional water-dispersed eye cosmetic compositions.
因此,本發明的目的在於提供一種表現出輕薄的使用感,並且耐水性及妝容持久性提高且光澤感優異的眼部化妝品組成物。 [解決課題的手段]Therefore, an object of the present invention is to provide an eye cosmetic composition that exhibits a thin feeling of use, has improved water resistance and makeup durability, and is excellent in luster. [means to solve the problem]
為了達成上述目的,本發明提供一種包括多孔性粉末、多元醇及油溶性膜形成劑的水分散型的液態眼部化妝品組成物。In order to achieve the above objects, the present invention provides a water-dispersed liquid eye cosmetic composition comprising a porous powder, a polyhydric alcohol, and an oil-soluble film forming agent.
於本發明的一實施例中,上述多元醇可為選自由甘油、赤藻糖醇、1,2-丙二醇、1,3-丁二醇、山梨糖醇、聚甘油、丙二醇、麥芽酚甘油、二丙二醇、1,2-戊二醇、異戊二醇、木糖醇、聚乙二醇、異戊二醇、木糖醇及其等的組合所組成的族群中的一種以上。In one embodiment of the present invention, the above-mentioned polyhydric alcohol can be one or more selected from the group consisting of glycerin, erythritol, 1,2-propylene glycol, 1,3-butanediol, sorbitol, polyglycerol, propylene glycol, maltol glycerol, dipropylene glycol, 1,2-pentanediol, isopentyl glycol, xylitol, polyethylene glycol, isopentyl glycol, xylitol, and combinations thereof.
於本發明的一實施例中,上述多元醇可為1,3-丁二醇。In an embodiment of the present invention, the polyol mentioned above may be 1,3-butanediol.
於本發明的一實施例中,上述多孔性粉末可具有1.0 μm至30.0 μm的粒徑。In an embodiment of the present invention, the above-mentioned porous powder may have a particle size of 1.0 μm to 30.0 μm.
於本發明的一實施例中,上述多孔性粉末可為選自由矽(Silicon)、聚胺基甲酸酯(PU)、聚甲基丙烯酸甲酯(PMMA:poly-(methyl methacrylate))、聚乙烯吡咯啶酮(PVP:poly-(vinyl pyrrolidone))、聚己內酯(PCL:poly-(caprolactone))、聚L-乳酸(PLLA:Poly-(L-Lactic Acid))、聚胺基甲酸酯(PU:polyurethane)、尼龍(Nylon)、澱粉(Starch)及其等的組合所組成的族群中的一種以上的粉末。In one embodiment of the present invention, the above-mentioned porous powder can be selected from silicon (Silicon), polyurethane (PU), polymethyl methacrylate (PMMA: poly-(methyl methacrylate)), polyvinylpyrrolidone (PVP: poly-(vinyl pyrrolidone)), polycaprolactone (PCL: poly-(caprolactone)), poly L-lactic acid (PLLA: Poly-(L-Lactic Acrylate) id)), polyurethane (PU:polyurethane), nylon (Nylon), starch (Starch) and the combination of the group consisting of more than one powder.
於本發明的一實施例中,上述油溶性膜形成劑可為選自由合成聚合物、自由基介質型聚合物或縮聚型聚合物、天然聚合物及其混合物所組成的族群中的一種以上。In an embodiment of the present invention, the oil-soluble film-forming agent may be at least one selected from the group consisting of synthetic polymers, free-radical polymers or polycondensation polymers, natural polymers and mixtures thereof.
於本發明的一實施例中,相對於整體眼部化妝品組成物的總重量,可包括5.0重量%至15.0重量%的上述多元醇。In an embodiment of the present invention, relative to the total weight of the overall eye cosmetic composition, the above-mentioned polyhydric alcohol may be included in an amount of 5.0 wt % to 15.0 wt %.
於本發明的一實施例中,相對於整體眼部化妝品組成物的總重量,可包括8.0重量%至14.0重量%的上述多孔性粉末。In an embodiment of the present invention, relative to the total weight of the overall eye cosmetic composition, the above-mentioned porous powder may be included in an amount of 8.0 wt % to 14.0 wt %.
於本發明的一實施例中,相對於整體眼部化妝品組成物的總重量,可包括1.0重量%至3.0重量%的上述油溶性膜形成劑。In an embodiment of the present invention, relative to the total weight of the overall eye cosmetic composition, the above-mentioned oil-soluble film-forming agent may be included in an amount of 1.0 wt % to 3.0 wt %.
於本發明的一實施例中,上述組成物可應用至眼線筆、睫毛膏、眼影或眉粉的化妝品。 [發明之效果]In one embodiment of the present invention, the above-mentioned composition can be applied to cosmetics such as eyeliner, mascara, eye shadow or eyebrow powder. [Effect of Invention]
本發明的水分散型的液態眼部化妝品組成物包括多孔性粉末、多元醇及油溶性膜形成劑,藉此可提高耐水性及妝容持久性。The water-dispersed liquid eye cosmetic composition of the present invention includes porous powder, polyhydric alcohol and oil-soluble film forming agent, thereby improving water resistance and makeup durability.
並且,於本發明中,液態眼部化妝品組成物製備成水分散型,因此可表現出水潤且清爽的使用感,色調表現力優異,可表現出卓越的光澤感。In addition, in the present invention, the liquid eye cosmetic composition is prepared in a water-dispersed type, so it can exhibit a moist and refreshing feeling of use, excellent color tone expressiveness, and excellent luster.
本發明提供一種包括多孔性粉末、多元醇及油溶性膜形成劑的水分散型的液態眼部化妝品組成物。以下,詳細地對本發明進行說明。The present invention provides a water-dispersed liquid eye cosmetic composition comprising porous powder, polyhydric alcohol and an oil-soluble film forming agent. Hereinafter, the present invention will be described in detail.
本發明中所提及的水分散型的液態眼部化妝品組成物是指連續相為水相、分散相包括油相的液態眼部化妝品組成物。The water-dispersed liquid eye cosmetic composition mentioned in the present invention refers to a liquid eye cosmetic composition in which the continuous phase is an aqueous phase and the dispersed phase includes an oil phase.
於將先前的液態眼部化妝品組成物製備成水分散型的情形時,若使用連續相為水的水分散型,則因水而使用感輕薄且清爽,但存在耐水性及妝容持久性下降的問題。另一方面,與水分散型相比,油分散型的化妝品組成物的清爽使用感下降,若使用於油相中的溶解度欠佳的原料,則存在難以將原料分散至組成物中而原料析出的問題。When the conventional liquid eye cosmetic composition is prepared as a water-dispersed type, if a water-dispersed type with water as the continuous phase is used, the feeling of use is light and refreshing due to water, but there are problems in that water resistance and makeup durability are reduced. On the other hand, compared with the water-dispersed type, the oil-dispersed cosmetic composition has a lower refreshing feeling, and if a raw material with poor solubility in the oil phase is used, it is difficult to disperse the raw material in the composition and cause the raw material to precipitate.
於本發明中,藉由改善耐水性及妝容持久性以及同時藉由將多孔性粉末及多元醇應用至用於分散難溶於水相的原料的水分散型來解決如上所述的問題。In the present invention, the above-mentioned problems are solved by improving water resistance and makeup durability and simultaneously by applying porous powder and polyol to a water dispersion type for dispersing raw materials hardly soluble in an aqueous phase.
本發明中所提及的“油溶性”是指不溶於水而溶於油、溶劑之類的物質的性質。The "oil solubility" mentioned in the present invention refers to the property of being insoluble in water but soluble in oil, solvent and the like.
於本發明的一實施例中,上述多元醇可為選自由甘油、赤藻糖醇、1,2-丙二醇、1,3-丁二醇、山梨糖醇、聚甘油、丙二醇、麥芽酚甘油、二丙二醇、1,2-戊二醇、異戊二醇、木糖醇、聚乙二醇、異戊二醇、木糖醇及其等的組合所組成的族群中的一種以上。較佳為1,3-丁二醇,但並不限制於此。In one embodiment of the present invention, the above-mentioned polyhydric alcohol can be one or more selected from the group consisting of glycerin, erythritol, 1,2-propylene glycol, 1,3-butanediol, sorbitol, polyglycerol, propylene glycol, maltol glycerol, dipropylene glycol, 1,2-pentanediol, isopentyl glycol, xylitol, polyethylene glycol, isopentyl glycol, xylitol, and combinations thereof. 1,3-butanediol is preferred, but not limited thereto.
於本發明的一實施例中,上述多元醇對皮膚無副作用,使上述油溶性膜形成劑容易分散至水中,從而可提高水分散型的穩定性。In an embodiment of the present invention, the above polyol has no side effects on the skin, and the above oil-soluble film forming agent is easily dispersed in water, thereby improving the stability of the water-dispersed type.
相對於整體眼部化妝品組成物的總重量,可包括5.0重量%至15.0重量%的上述多元醇,若上述多元醇相對於整體眼部化妝品組成物的總重量未滿5.0重量%,則不易將上述油溶性膜形成劑分散至水中而不具備劑型穩定性的效果,若超過15.0重量%,則妝容持久性會下降。The above-mentioned polyol may be included in an amount of 5.0% to 15.0% by weight relative to the total weight of the entire eye cosmetic composition. If the above-mentioned polyol is less than 5.0% by weight relative to the total weight of the entire eye cosmetic composition, it will be difficult to disperse the above-mentioned oil-soluble film-forming agent in water and will not have the effect of dosage form stability. If it exceeds 15.0% by weight, the makeup durability will be reduced.
於本發明的一實施例中,上述多孔性粉末可具有1.0 μm至30.0 μm的粒徑。若上述多孔性粉末小於1.0 μm,則於塗抹時產生滑移現象,若超過30.0 μm,則於塗抹至皮膚時會表現出粗糙的使用感。In an embodiment of the present invention, the above-mentioned porous powder may have a particle size of 1.0 μm to 30.0 μm. If the above-mentioned porous powder is less than 1.0 μm, it will cause slippage when applied, and if it exceeds 30.0 μm, it will show a rough feeling when applied to the skin.
於本發明的一實施例中,上述多孔性粉末的吸油量可為0.3 g/g至3.0 g/g。較佳為0.4 g/g至2.0 g/g,但並不限制於此。In an embodiment of the present invention, the oil absorption of the porous powder may be 0.3 g/g to 3.0 g/g. It is preferably 0.4 g/g to 2.0 g/g, but not limited thereto.
於上述多孔性粉末的吸油量未滿0.3 g/g的情形時,不易將油溶性膜形成劑分散至水中,從而會產生凝聚現象,於超過3.0 g/g的情形時,在塗抹時會賦予厚重的使用感且會產生乾燥感。When the oil absorption of the porous powder is less than 0.3 g/g, it is difficult to disperse the oil-soluble film-forming agent in water, and aggregation phenomenon occurs, and when it exceeds 3.0 g/g, it gives a thick feeling of use and a dry feeling when applied.
於本發明的一實施例中,上述多孔性粉末可為選自由矽(Silicon)、聚胺基甲酸酯(PU)、聚甲基丙烯酸甲酯(PMMA:poly-(methyl methacrylate))、聚乙烯吡咯啶酮(PVP:poly-(vinyl pyrrolidone))、聚己內酯(PCL:poly-(caprolactone))、聚L-乳酸(PLLA:Poly-(L-Lactic Acid))、聚胺基甲酸酯(PU:polyurethane)、尼龍(Nylon)、澱粉(Starch)及其等的組合所組成的族群中的一種以上的粉末,較佳為可為多孔性矽粉末。In one embodiment of the present invention, the above-mentioned porous powder can be selected from silicon (Silicon), polyurethane (PU), polymethyl methacrylate (PMMA: poly-(methyl methacrylate)), polyvinylpyrrolidone (PVP: poly-(vinyl pyrrolidone)), polycaprolactone (PCL: poly-(caprolactone)), poly L-lactic acid (PLLA: Poly-(L-Lactic Acrylate) id)), polyurethane (PU:polyurethane), nylon (Nylon), starch (Starch) and other combinations of the group consisting of more than one powder, preferably porous silicon powder.
較佳為相對於整體眼部化妝品組成物的總重量,包括8.0重量%至14.0重量%的上述多孔性粉末,若上述多孔性粉末相對於整體眼部化妝品組成物的總重量未滿8.0重量%,則油溶性膜形成劑不具備穩定化效果,若超過14.0重量%,則劑型穩定性會下降。Preferably, 8.0% to 14.0% by weight of the above-mentioned porous powder is included relative to the total weight of the entire eye cosmetic composition. If the above-mentioned porous powder is less than 8.0% by weight relative to the total weight of the entire eye cosmetic composition, the oil-soluble film forming agent does not have a stabilizing effect, and if it exceeds 14.0% by weight, the stability of the dosage form will decrease.
於本發明的一實施例中,上述多孔性粉末使油溶性膜形成劑容易分散至水中,從而可提高水分散型的穩定性,因此包括上述多孔性粉末的眼部化妝品組成物的色調表現力優異,可滿足輕薄且柔滑的使用感。In an embodiment of the present invention, the above-mentioned porous powder makes the oil-soluble film-forming agent easily dispersed in water, thereby improving the stability of the water-dispersed type. Therefore, the eye cosmetic composition including the above-mentioned porous powder has excellent color tone expressiveness, and can satisfy a light and smooth feeling of use.
於本發明的一實施例中,上述油溶性膜形成劑包括於眼部化妝品組成物,藉此可溶解揮發度較高的油,因此於塗抹眼部化妝品組成物時,可形成柔軟、光澤感良好且妝容持久性優異的膜。In one embodiment of the present invention, the above-mentioned oil-soluble film-forming agent is included in the eye cosmetic composition, so as to dissolve oil with high volatility, so when the eye cosmetic composition is applied, a soft, glossy and long-lasting film can be formed.
上述油溶性膜形成劑可為選自由合成聚合物、自由基介質型聚合物或縮聚型聚合物、天然聚合物及其混合物所組成的族群中的一種以上,較佳為可為丙烯酸酯類聚合物,更佳為丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer)。The above-mentioned oil-soluble film-forming agent can be at least one selected from the group consisting of synthetic polymers, free-radical media polymers or polycondensation polymers, natural polymers and mixtures thereof, preferably acrylate polymers, more preferably butyl acrylate/hydroxypropyl dimethicone acrylate copolymer (Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer).
作為示例,上述丙烯酸酯類聚合物的油溶性膜形成劑可為選自由丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、丙烯酸酯/聚二甲基矽氧烷共聚物、丙烯酸酯/丙烯酸山萮酯/聚二甲基矽氧烷甲基丙烯酸酯共聚物、丙烯酸酯/聚三甲基矽氧烷甲基丙烯酸酯共聚物、及丙烯酸酯/丙烯酸硬脂酯/聚二甲基矽氧烷甲基丙烯酸酯共聚物所組成的族群中的一種以上。As an example, the oil-soluble film-forming agent for the above-mentioned acrylate polymer may be one or more selected from the group consisting of butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, acrylate/polydimethylsiloxane copolymer, acrylate/behenyl acrylate/polydimethylsiloxane methacrylate copolymer, acrylate/polytrimethicone methacrylate copolymer, and acrylate/stearyl acrylate/polydimethylsiloxane methacrylate copolymer.
於本發明的一實施例中,藉由包括上述丙烯酸酯類聚合物的油溶性膜形成劑而形成的膜的厚度較薄且具有柔軟的特性,因此可賦予舒適的使用感且耐水性提高。In an embodiment of the present invention, the film formed by the oil-soluble film-forming agent including the above-mentioned acrylate polymer is thinner and soft, so it can provide a comfortable feeling of use and improve water resistance.
於本說明書中,“自由基介質型聚合物”的表述是指藉由聚合包括不飽和、特別是乙烯性不飽和的單體而獲得的聚合物,各單體(不同於縮聚)可進行均聚合。In this specification, the expression "radical-mediated polymer" refers to a polymer obtained by polymerizing monomers including unsaturated, especially ethylenically unsaturated, and each monomer (different from polycondensation) can be homopolymerized.
相對於整體眼部化妝品組成物的總重量,可包括1.0重量%至3.0重量%的上述油溶性膜形成劑,若上述油溶性膜形成劑相對於整體眼部化妝品組成物的總重量未滿1.0重量%,則妝容持久性下降且光澤感下降,若超過3.0重量%,則於將眼部化妝品組成物塗抹至皮膚時,皮膚乾燥而會產生皮膚緊繃現象。較佳為1.6重量%至3.0重量%,但並不限制於此。The above-mentioned oil-soluble film-forming agent may be included in an amount of 1.0% to 3.0% by weight relative to the total weight of the entire eye cosmetic composition. If the above-mentioned oil-soluble film-forming agent is less than 1.0% by weight relative to the total weight of the entire eye cosmetic composition, the durability of the makeup will be reduced and the gloss will be reduced. If it exceeds 3.0% by weight, the skin will be dry and tight when the eye cosmetic composition is applied to the skin. It is preferably 1.6% by weight to 3.0% by weight, but not limited thereto.
為了增加乾燥速度,本發明的組成物可更含有乙醇。較佳為相對於組成物的總重量,含有3.0重量%至8.0重量%的乙醇。於乙醇的含量相對於組成物的總重量超過8.0重量%的情形時,對皮膚及眼球等造成刺激且產生難聞的氣味,於未滿3.0重量%的情形時,會不具備吸收及乾燥速度的增進效果。In order to increase the drying speed, the composition of the present invention may further contain ethanol. Preferably, ethanol is contained in an amount of 3.0% by weight to 8.0% by weight based on the total weight of the composition. When the content of ethanol exceeds 8.0% by weight relative to the total weight of the composition, it irritates the skin and eyeballs and produces an unpleasant smell, and when it is less than 3.0% by weight, it does not have the effect of improving absorption and drying speed.
本發明的組成物可應用至眼線筆、睫毛膏、眼影或眉粉的化妝品。The composition of the present invention can be applied to cosmetics such as eyeliner, mascara, eye shadow or eyebrow powder.
本發明的組成物可更包括本技術領域中公知的添加劑。此種添加劑可根據本發明的組成物的應用領域而不同。The composition of the present invention may further include additives known in the art. Such additives may vary depending on the field of application of the composition of the present invention.
作為可使用的添加劑的非限制性的例,可列舉保濕劑、脂肪酸、防腐劑、pH值調節劑、抗氧化劑、顏料、染料、穩定劑、增黏劑、脂質等,可由業者適當地選擇。Non-limiting examples of additives that can be used include humectants, fatty acids, preservatives, pH adjusters, antioxidants, pigments, dyes, stabilizers, thickeners, lipids, etc., and can be appropriately selected by the practitioner.
作為保濕劑,可使用選自由赤藻糖醇、木糖醇、麥芽糖醇、丙二醇、山梨糖醇、聚甘油、聚乙二醇、1,2-戊二醇、異丙二醇、胺基酸、乳酸鈉、吡咯啶酮羧酸鈉、木葡聚糖、木瓜籽、角叉菜膠、果膠、甘露聚糖、卡德蘭多糖、聚半乳糖、皮膚素硫酸鹽、肝糖、角質素硫酸鹽、軟骨素、硫酸黏液素、角質硫酸鹽、刺槐豆膠、琥珀醯聚糖、栝蔞仁酸(Calonym acid)、玻尿酸、肝素硫酸鹽、玻尿酸鈉、膠原蛋白、黏多糖類、軟骨素硫酸鹽、二甲基聚矽氧烷、甲基苯基矽氧烷、乳酸菌或雙叉乳酸桿菌的培養上清液及其等的組合所組成的族群中的一種。As a humectant, one selected from the group consisting of erythritol, xylitol, maltitol, propylene glycol, sorbitol, polyglycerin, polyethylene glycol, 1,2-pentanediol, isopropylene glycol, amino acid, sodium lactate, sodium pyrrolidone carboxylate, xyloglucan, papaya seed, carrageenan, pectin, mannan, cardranan, galactose, dermatan sulfate, glycogen, keratin sulfate, chondroitin, mucilage sulfate One of the group consisting of keratin, cutin sulfate, locust bean gum, succinylated sugar, calonym acid, hyaluronic acid, heparin sulfate, sodium hyaluronate, collagen, mucopolysaccharides, chondroitin sulfate, dimethylpolysiloxane, methylphenylsiloxane, culture supernatant of lactic acid bacteria or bifidus lactobacillus, and combinations thereof.
作為脂肪酸,可列舉選自由月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、亞麻油酸及其等的混合物所組成的族群中的一種脂肪酸。Examples of the fatty acid include one fatty acid selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof.
增黏劑為於用作化妝品組成物時提供適當的黏度而提高使用感者,可使用選自由海藻酸鈉、三仙膠、矽酸鋁、木瓜籽萃取物、阿拉伯膠、羥乙基瓜爾膠、羧甲基瓜爾膠、瓜爾膠、葡聚糖、黃蓍膠、纖維素、羥丙基纖維素、甲基羥丙基纖維素、甲基纖維素、羧甲基纖維素、羥乙基纖維素、羧基乙烯基聚合物、聚乙烯醇、聚乙烯吡咯啶酮及其等的組合所組成的族群中的一種。The thickener is used to provide an appropriate viscosity and improve the feeling of use when used as a cosmetic composition. It can be selected from the group consisting of sodium alginate, sanxian gum, aluminum silicate, papaya seed extract, gum arabic, hydroxyethyl guar gum, carboxymethyl guar gum, guar gum, dextran, tragacanth gum, cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, and the like. kind of.
脂質可使用選自由芒果脂、牛油樹(Shea)脂、可可籽脂、澳洲胡桃油、鯊肝醇、山萮醇、鯨蠟硬脂醇、鯨蠟醇、硬脂醇及其等的組合所組成的族群中的至少一種。As the lipid, at least one selected from the group consisting of mango butter, shea butter, cocoa seed butter, macadamia oil, batyl alcohol, behenyl alcohol, cetearyl alcohol, cetyl alcohol, stearyl alcohol, and combinations thereof can be used.
作為防腐劑,可使用苯甲酸鹽、水楊酸鹽、山梨酸鹽、二羥基乙酸鹽、對羥基苯甲酸酯、2,4,4-三氯-2-羥基二苯基醚、3,3,4-三氯對稱二苯脲、氯化苄烷銨、檜木醇、間苯二酚、對羥基苯甲酸甲酯、對羥基苯甲酸丙酯等對羥基苯甲酸酯類、苯氧基乙醇、辛二醇、己二醇等。As preservatives, parabens such as benzoate, salicylate, sorbate, diglycolic acid salt, paraben, 2,4,4-trichloro-2-hydroxydiphenyl ether, 3,3,4-trichlorodiphenylurea, benzalkonium chloride, hinokitiol, resorcinol, methylparaben, propylparaben, and other parabens, phenoxyethanol, caprylyl glycol, hexanediol, etc. can be used.
作為pH值調節劑,可使用氫氧化鈉、三乙醇胺、檸檬酸、檸檬酸鈉、硼酸、硼砂(borax)、磷酸氫鉀等。As the pH adjuster, sodium hydroxide, triethanolamine, citric acid, sodium citrate, boric acid, borax, potassium hydrogenphosphate, and the like can be used.
作為抗氧化劑,可使用二丁基羥基甲苯、丁基羥基茴香醚、沒食子酸丙酯、抗壞血酸等。As the antioxidant, dibutylhydroxytoluene, butylhydroxyanisole, propyl gallate, ascorbic acid, and the like can be used.
作為顏料,可使用氧化矽、雲母、滑石、絹雲母、硫酸鋇、二氧化鈦、氧化鉻、氧化鐵、氧化鋅、二氧化鈰、二氧化鋯、碳黑、鋇、鍶、尼龍粉、聚甲基丙烯酸甲酯(PMMA)等。As pigments, silicon oxide, mica, talc, sericite, barium sulfate, titanium dioxide, chromium oxide, iron oxide, zinc oxide, cerium dioxide, zirconium dioxide, carbon black, barium, strontium, nylon powder, polymethyl methacrylate (PMMA) and the like can be used.
本發明的一實施例的水分散型的液態眼部化妝品組成物的製備方法並無特別限定,可使用於業界中使用的任意的乳化方法。The method for preparing the water-dispersed liquid eye cosmetic composition according to an embodiment of the present invention is not particularly limited, and any emulsification method used in the industry can be used.
更具體而言,本發明的水分散型的液態眼部化妝品組成物可藉由如下方法製備。More specifically, the water-dispersed liquid eye cosmetic composition of the present invention can be prepared by the following method.
S1)於混合多孔性粉末與油溶性膜形成劑後,均勻地分散; S2)將多元醇放入至上述S1)中並均勻地分散; S3)於上述S2)中混合水與添加劑並均勻地分散,藉此製備水分散型液態眼部化妝品組成物。S1) After mixing the porous powder and the oil-soluble film forming agent, uniformly disperse; S2) Put polyhydric alcohol into the above S1) and uniformly disperse; S3) Mix water and additives in the above S2) and uniformly disperse, thereby preparing a water-dispersed liquid eye cosmetic composition.
此時,於上述S1)、S2)及S3)中執行的混合在本發明中並無特別限定,使用於化妝品製備領域中使用的通常的混合機、均化機、均質機或高壓均質機等。At this time, the mixing performed in the above-mentioned S1), S2) and S3) is not particularly limited in the present invention, and it is used in a common mixer, homogenizer, homogenizer or high-pressure homogenizer used in the field of cosmetic preparation.
並且,於進行混合時,攪拌速度可根據使用的裝置及組成含量而進行各種變更。In addition, when mixing, the stirring speed can be changed variously according to the apparatus used and the composition content.
以下,為了有助於理解本發明而提出較佳的實施例。然而,下述實施例僅用以例示本發明,於本技術領域內具有常識者應明白可於本發明的範疇及技術思想範圍內實現各種變更及修正,當然此種變更及修正亦屬於隨附的發明申請專利範圍。Hereinafter, preferred examples are presented to facilitate the understanding of the present invention. However, the following embodiments are only used to illustrate the present invention, and those with common sense in the technical field should understand that various changes and modifications can be realized within the scope of the present invention and the scope of technical ideas. Of course, such changes and modifications also belong to the scope of the accompanying invention application patent.
實施例 1 :水分散型的液態眼部化妝品組成物 按照下述表1的組成製備作為水分散型的液態眼部化妝品組成物的實施例1。 Example 1 : Water-dispersed liquid eye cosmetic composition Example 1 was prepared as a water-dispersed liquid eye cosmetic composition according to the composition in Table 1 below.
[表1]
<實施例1的製備方法> 1)於混合多孔性粉末(成分1)與油溶性膜形成劑(成分3)後,利用均質機均勻地分散。 2)將多元醇(成分2)放入至上述1)而均勻地分散。 3)將成分4至成分8放入至上述2)而均勻地分散。 4)將成分9慢慢地添加至上述3)而利用均質機進行混合。<Preparation method of Example 1> 1) After mixing the porous powder (component 1) and the oil-soluble film forming agent (component 3), they were uniformly dispersed with a homogenizer. 2) Put the polyol (component 2) in the above 1) and disperse it uniformly. 3) Components 4 to 8 are put into the above 2) and uniformly dispersed. 4) Component 9 was gradually added to the above 3) and mixed with a homogenizer.
實施例 2 :包括多孔性粉末及油溶性膜形成劑的化妝品組成物 按照1:1混合作為多孔性粉末的氧化矽*HDI/三羥甲基己內酯交聯聚合物與作為油溶性膜形成劑的丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物來製備化妝品組成物。 Example 2 : Cosmetic Composition Comprising Porous Powder and Oil-Soluble Film-Forming Agent A cosmetic composition was prepared by mixing silicon oxide*HDI/trimethylolcaprolactone crosslinked polymer as porous powder and butyl acrylate/hydroxypropyl dimethicone acrylate copolymer as oil-soluble film-forming agent at 1:1.
比較例 1 :水中油( O/W )劑型的液態眼部化妝品組成物 按照下述表2的組成製備作為水中油劑型的液態眼部化妝品組成物的比較例1。 Comparative Example 1 : Oil-in-water ( O/W ) liquid eye cosmetic composition Comparative Example 1 was prepared as an oil-in-water liquid eye cosmetic composition according to the composition in Table 2 below.
[表2]
<比較例1的製備方法> 1)於混合純化水(成分1)與添加劑(成分2)後,利用均質機均勻地分散。 2)將珍珠與色素(成分3)放入至上述1)而均勻地分散。 3)將成分4至成分7放入至上述2)而均勻地分散。 4)將成分8慢慢地添加至上述3)而利用均質機進行混合。<The preparation method of comparative example 1> 1) After mixing purified water (component 1) and an additive (component 2), it dispersed uniformly with the homogenizer. 2) Put pearls and pigment (ingredient 3) in the above 1) and disperse evenly. 3) Components 4 to 7 are put into the above 2) and uniformly dispersed. 4) Component 8 was gradually added to the above 3) and mixed with a homogenizer.
比較例 2 :包括無氣孔的粉末的化妝品組成物 與上述實施例2的化妝品組成物相同地製備,使用無氣孔的矽粉末(JGC CATALYSTS AND CHEMICALS LTD公司,SPHERICA BA-1)來代替氧化矽*HDI/三羥甲基己內酯交聯聚合物而製備比較例2。 Comparative Example 2 : Cosmetic composition comprising non-porous powder was prepared in the same manner as the cosmetic composition of Example 2 above, using non-porous silicon powder (JGC CATALYSTS AND CHEMICALS LTD, SPHERICA BA-1) instead of silicon oxide*HDI/trimethylolcaprolactone crosspolymer to prepare Comparative Example 2.
比較例 3 :不包括油溶性膜形成劑的水分散型的液態眼部化妝品組成物 除上述實施例1的組成中的成分3即膜形成劑以外,藉由與實施例1相同的方法製備比較例3。 Comparative Example 3 : Water-dispersed liquid eye cosmetic composition not including an oil-soluble film-forming agent Comparative Example 3 was prepared in the same manner as in Example 1 except for the film-forming agent, which is the component 3 in the composition of Example 1 above.
比較例 4 :包括丙烯酸類膜形成劑的水分散型的液態眼部化妝品組成物 使用丙烯酸類膜形成劑來代替上述實施例1的組成中的成分3,具體的製備方法為與上述實施例1的製備方法相同地製備比較例4。 Comparative Example 4 : Water-dispersed liquid eye cosmetic composition including an acrylic film-forming agent An acrylic film-forming agent was used instead of component 3 in the composition of Example 1 above, and the specific preparation method was to prepare Comparative Example 4 in the same manner as in Example 1 above.
實驗例 1 :劑型的透明性(白濁)的比較 於製備上述實施例1及比較例1後,放入至小玻璃瓶而利用肉眼對透明性進行比較。圖1為其比較照片。 Experimental Example 1 : Comparison of transparency (cloudiness) of dosage forms After preparing the above-mentioned Example 1 and Comparative Example 1, they were placed in small glass bottles and compared with the naked eye for transparency. Figure 1 is a comparison photo.
參照圖1,確認到與幾乎不表現出白濁的實施例1相比,比較例1的白濁嚴重。因此,確認到上述實施例1的透明度高於比較例1,因此可具有容易混合色素來實現色調的效果。Referring to FIG. 1 , it was confirmed that the white turbidity of Comparative Example 1 was severe compared with Example 1, which showed little turbidity. Therefore, it was confirmed that the transparency of the above-mentioned Example 1 is higher than that of Comparative Example 1, and therefore it is possible to easily mix the coloring matter to achieve the effect of color tone.
實驗例 2 :與粉末有無氣孔對應的透明性(白濁)的比較 為了根據粉末有無氣孔而確認油溶性膜形成劑的分散效果,如下述表3般製備實施例2及比較例2而將一部分塗抹至皮氏培養皿來利用肉眼對透明性進行比較。圖2為其比較照片。 Experimental Example 2 : Comparison of transparency (cloudiness) according to the presence or absence of powder pores In order to confirm the dispersion effect of the oil-soluble film-forming agent according to the presence or absence of powder pores, Example 2 and Comparative Example 2 were prepared as shown in Table 3 below, and a part was applied to a Petri dish to compare the transparency with the naked eye. Figure 2 is a comparison photo.
[表3]
參照圖2,確認到與透明而幾乎不表現出白濁的實施例2相比,比較例2不透明且白濁嚴重。藉此,包括多孔性粉末的實施例2的透明度高於包括無氣孔的粉末的比較例2而容易混合色素來實現色調,油溶性膜形成劑不與多孔性粉末分離而均勻地分散,藉此可表現出妝容持久性及耐水性效果。Referring to FIG. 2 , it was confirmed that Comparative Example 2 was opaque and had severe cloudiness compared to Example 2 which was transparent and showed little cloudiness. Thus, Example 2 including porous powder has higher transparency than Comparative Example 2 including non-porous powder, and it is easy to mix pigments to achieve color tone, and the oil-soluble film-forming agent is uniformly dispersed without being separated from the porous powder, thereby exhibiting long-lasting makeup and water resistance effects.
實驗例 3 :耐水性測定 為了測定上述實施例1、比較例3及比較例4的耐水性,於將各50 μl的樣品分別塗抹至人造皮革後,在室溫下放置30分鐘。此後,擔載至水中而確認殘留的程度,將其結果示於表4及圖3。 Experimental Example 3 : Measurement of Water Resistance In order to measure the water resistance of the above-mentioned Example 1, Comparative Example 3 and Comparative Example 4, 50 μl of each sample was applied to the artificial leather and left at room temperature for 30 minutes. After that, it was loaded in water to confirm the degree of residue, and the results are shown in Table 4 and FIG. 3 .
[表4]
根據上述表4及圖3,確認到實施例1具有明顯高於比較例3至比較例4的耐水性。確認到不包括油溶性膜形成劑的比較例3的耐水性最差,包括丙烯酸類膜形成劑的比較例4的耐水性較實施例1下降2倍以上。藉此,確認到本發明的水分散型的液態眼部化妝品組成物藉由包括丙烯酸酯類膜形成劑而具有優異的耐水性。From the above-mentioned Table 4 and FIG. 3 , it was confirmed that Example 1 has significantly higher water resistance than Comparative Examples 3 to 4. It was confirmed that the water resistance of Comparative Example 3 not including an oil-soluble film-forming agent was the worst, and that of Comparative Example 4 including an acrylic film-forming agent was lower than that of Example 1 by more than two times. Accordingly, it was confirmed that the water-dispersed liquid eye cosmetic composition of the present invention has excellent water resistance by including an acrylic film-forming agent.
實驗例 4 :光澤感測定 為了根據是否具有膜形成劑及種類而確認光澤效果,將相同量(50 μl)的上述實施例1及比較例3至比較例4塗抹至試紙,利用光澤計以60°的反射角度對塗抹有實驗溶液的試紙照射光,之後測定反射量而測定光澤度。將其結果示於下述表5,數值越大則意味著光澤度越優異。 Experimental example 4 : Glossiness measurement In order to confirm the gloss effect according to the presence and type of the film forming agent, the same amount (50 μl) of the above-mentioned Example 1 and Comparative Example 3 to Comparative Example 4 was applied to the test paper, and the test paper coated with the test solution was irradiated with light at a reflection angle of 60° by a gloss meter, and then the amount of reflection was measured to measure the glossiness. The results are shown in Table 5 below, and the larger the numerical value, the better the glossiness.
[表5]
根據上述表5可知,包括油溶性膜形成劑的實施例1的光澤度遠遠高於不包括膜形成劑的比較例3,且亦表現出高於包括丙烯酸類膜形成劑的比較例4的光澤度。According to the above Table 5, it can be seen that the glossiness of Example 1 including an oil-soluble film forming agent is much higher than that of Comparative Example 3 not including a film forming agent, and also exhibits higher gloss than that of Comparative Example 4 including an acrylic film forming agent.
並且,確認到上述實施例1於3小時後亦具有較比較例3至比較例4卓越的光澤度。因此,確認到本發明的水分散型的液態眼部化妝品組成物藉由包括油溶性膜形成劑而光澤度變高且其持久性亦優異。And, it was confirmed that the above-mentioned Example 1 also had excellent glossiness compared with Comparative Examples 3 to 4 after 3 hours. Therefore, it was confirmed that the water-dispersed liquid eye cosmetic composition of the present invention has high gloss and excellent durability by including the oil-soluble film forming agent.
無none
圖1是對與實施例1及比較例1的眼部化妝品組成物的劑型對應的透明性(白濁)進行比較的照片。 圖2是對與實施例2及比較例2的組成物中所包括的粉末有無氣孔對應的透明性(白濁)進行比較的照片。 圖3是對實施例1與比較例3至比較例4的眼部化妝品組成物的耐水性進行比較的照片。FIG. 1 is a photograph comparing the transparency (white turbidity) corresponding to the dosage forms of eye cosmetic compositions of Example 1 and Comparative Example 1. FIG. FIG. 2 is a photograph comparing transparency (cloudiness) according to the presence or absence of pores in the powders included in the compositions of Example 2 and Comparative Example 2. FIG. 3 is a photograph comparing the water resistance of the eye cosmetic compositions of Example 1 and Comparative Examples 3 to 4. FIG.
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CN1572287A (en) * | 2003-05-28 | 2005-02-02 | 欧莱雅 | Cosmetic compositions for making up and/or caring for skin |
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