WO2019241945A1 - Method for simultaneously forming patterns on both sides of transparent substrate - Google Patents

Method for simultaneously forming patterns on both sides of transparent substrate Download PDF

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Publication number
WO2019241945A1
WO2019241945A1 PCT/CN2018/092093 CN2018092093W WO2019241945A1 WO 2019241945 A1 WO2019241945 A1 WO 2019241945A1 CN 2018092093 W CN2018092093 W CN 2018092093W WO 2019241945 A1 WO2019241945 A1 WO 2019241945A1
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Prior art keywords
photoresist layer
pattern
transparent substrate
thin film
photoresist
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PCT/CN2018/092093
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French (fr)
Chinese (zh)
Inventor
许铭案
林文福
陈香婷
井川昭彦
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日本光电子化学株式会社
许铭案
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Application filed by 日本光电子化学株式会社, 许铭案 filed Critical 日本光电子化学株式会社
Priority to PCT/CN2018/092093 priority Critical patent/WO2019241945A1/en
Publication of WO2019241945A1 publication Critical patent/WO2019241945A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/48Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326

Definitions

  • the invention relates to a method for forming a pattern, in particular to a method for forming a pattern on both sides of a transparent substrate at the same time.
  • Transparent electronics is an emerging technology focused on manufacturing thin and transparent electronic components such as displays, chips and circuits.
  • smart devices such as smart phones, smart watches, smart display components, etc., are likely to trend toward transparent electronic devices. These transparent electronic devices are gradually moving towards personalized, beautiful design, etc. These must be achieved through semiconductor manufacturing.
  • An object of the present invention is to solve the above problems and provide a method for simultaneously forming a pattern on both sides of a transparent substrate.
  • the invention provides a method for simultaneously forming a pattern on both sides of a transparent substrate, comprising: forming a first thin film layer on an upper surface of the transparent substrate; and simultaneously forming a second thin film layer on a lower surface of the transparent substrate; and A first photoresist layer is formed on the first thin film layer and a second photoresist layer is simultaneously formed on the second thin film layer; a first photomask is placed on the first photoresist layer and simultaneously on the second light A second photomask is placed on the resist layer for exposure; at the same time, a part of the photoresist layer on the upper and lower surfaces of the transparent substrate is removed, so that the uncovered portion of the first thin film layer forms a first pattern space and the first pattern space.
  • the uncovered portion of the two thin film layers forms a second pattern space. If the first photoresist layer and the second photoresist layer use a positive photoresist material, removing a part of the photoresist layer is to remove the exposed photoresist. The first photoresist layer and the second photoresist layer portion. If a negative photoresist material is used in the first photoresist layer and the second photoresist layer, removing a portion of the photoresist layer is to remove the first photoresist layer that has not been exposed.
  • a material of the first photoresist layer and the second photoresist layer is selected from polymers or copolymers containing a carboxylic acid group (COOH).
  • the material of the first photoresist layer and the second photoresist layer is selected from the group consisting of: acrylic resin, acrylic-epoxy resin, and acrylic-melamine Melamine resin, acrylic-styrene resin or a combination of the above resins.
  • An object of the present invention is to provide a method for simultaneously forming a pattern on both sides of a transparent substrate, comprising: forming a first photoresist layer on an upper surface of a transparent substrate; and simultaneously forming a second photoresist layer on a lower surface of the transparent substrate.
  • a photoresist layer placing a first photomask on the first photoresist layer and a second photomask on the second photoresist layer for exposure; and simultaneously removing a part (part of the upper and lower surfaces of the transparent substrate) )
  • a photoresist layer such that a portion of the substrate not covered by the first photoresist layer forms a first pattern space and a portion of the substrate not covered by the second photoresist layer forms a second pattern space; wherein, if the first photoresist Layer and the second photoresist layer use a positive photoresist material, then removing a part of the photoresist layer is to remove the exposed first photoresist layer and the second photoresist layer, and if the first photoresist layer and the The second photoresist layer uses a negative photoresist material, so removing a part of the photoresist layer is to remove the unexposed first photoresist layer and the second photoresist layer portion; at the same time, a first photo
  • the exposed first photoresist layer is formed to form a first thin film pattern and the exposed second photoresist layer is formed to form a second thin film pattern; wherein during the exposure, the first photoresist layer and the second photoresist layer are formed.
  • the photoresist layer absorbs light in different wavelength ranges.
  • the first photoresist layer mainly absorbs light bands below 400 nanometers (nm), and the second photoresist layer mainly absorbs light bands above 400 nanometers (nm).
  • a light source is used when performing exposure, the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first characteristic wavelength is mainly light below 400 nanometers, and the second characteristic The wavelength is mainly light above 400 nanometers.
  • a first light source and a second light source are used in the exposure.
  • the first light source has a first characteristic wavelength, mainly light below 400 nanometers
  • the second light source has a second
  • the characteristic wavelength is mainly light above 400 nanometers.
  • a photoresist pattern is produced by using a yellow light lithography process, and then a functional pattern is formed by a technical method of a thin film etching or lift-off process.
  • the upper and lower layers of light are used. Blocking the absorption of light in different light wavelength ranges to produce different patterns, and do not affect each other during the exposure process, to achieve the process of simultaneously forming a pattern on both sides of a transparent substrate at the same time, to reduce the steps and processes of a double-sided pattern process on a transparent substrate Cost and improve the technical efficiency of the process yield.
  • FIG. 1 is a schematic view of forming a pattern on both sides of a transparent substrate simultaneously.
  • FIG. 2 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate by a thin film etching process according to a first embodiment of the present invention.
  • FIG. 3A to FIG. 3F are schematic diagrams of structural changes of simultaneously forming a pattern on both sides of a transparent substrate using a thin film etching process according to the first embodiment of the present invention.
  • FIG. 4 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate by using a photoresist lift-off process according to a second embodiment of the present invention.
  • FIG. 5A to FIG. 5E are schematic diagrams of structural changes of simultaneously forming a pattern on both sides of a transparent substrate by using a photoresist lift-off process according to a second embodiment of the present invention.
  • 70 a second thin film pattern; 72 a second thin film layer; 74 a second photoresist layer; 75 a second photomask.
  • the present invention uses a photoresist lift-off process or a thin film etching technique to realize a process of simultaneously forming a pattern on both sides of a transparent substrate at the same time, thereby reducing the The steps and costs of the double-sided pattern process, and improve the technical efficacy of the process yield.
  • FIG. 1 is a schematic view of forming a pattern on both sides of a transparent substrate at the same time according to the present invention.
  • a first thin film pattern 60 is provided on an upper surface 12 of a transparent substrate 10
  • a second thin film pattern 70 is provided on a lower surface 14 of the transparent substrate 10.
  • the transparent substrate 10 can be a glass, quartz, or plastic substrate, such as polyethylene terephthalate (PET), polyvinyl butyral resin (PVB), or the like.
  • PET polyethylene terephthalate
  • PVB polyvinyl butyral resin
  • the transparent substrate 10 has a light transmittance of more than 80% in a visible light band.
  • the materials of the first thin film pattern 60 and the first thin film pattern 70 can be selected from any combination of the following: a metal film, a non-metal film, an inorganic metal oxide film, or a non-metal oxide film.
  • the thickness and pattern form of the first thin film pattern 60 and the second thin film pattern 70 may be the same or different.
  • the first thin film pattern 60 and the first thin film pattern 70 may be formed by a thin film etching process or a photoresist lift-off process.
  • FIG. 2 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate using a thin film etching process according to a first embodiment of the present invention
  • FIGS. 3A to 3F are first embodiment of the present invention using thin film etching. Schematic diagram of structural changes in the process of simultaneously forming a pattern on both sides of a transparent substrate.
  • Step 101 forming a thin film layer on the upper and lower surfaces of the transparent substrate (see FIG. 3A); that is, forming a first thin film layer 62 on the upper surface of the transparent substrate, and simultaneously forming a second thin film on the lower surface of the transparent substrate Layer 72.
  • the first thin film layer 62 and the second thin film layer 72 may be formed by physical vapor deposition: sputtering, evaporation, or ion plating; chemical vapor deposition may also be used: plasma enhanced chemical vapor deposition, metal-based chemistry Vapor deposition; or liquid chemical deposition: sol-gel, organic metal cracking, etc.
  • the thickness and pattern form of the first thin film pattern 60 and the second thin film pattern 70 may be the same or different. Preferably, the thickness of the first thin film pattern 60 and the second thin film pattern 70 are different, and the pattern form of the first thin film pattern 60 and the second thin film pattern 70 are different.
  • Step 102 forming a photoresist layer on the upper and lower thin film layers simultaneously (see FIG. 3B); forming a first photoresist layer 64 on the first thin film layer 62, and simultaneously on the second thin film layer 72 A second photoresist layer 74 is formed by coating.
  • Step 103 performing exposure (as shown in FIG. 3C); after placing a first photomask 65 on the first photoresist layer 64 and a second photomask 75 on the second photoresist layer 74, exposure is performed simultaneously.
  • Step 104 Remove the unexposed photoresist layer on both sides at the same time (see FIG. 3D); remove the unexposed first photoresist layer and the second photoresist layer at the same time, so that the first thin film layer is not covered A portion of the first pattern space 66 forms a second pattern space 76 and a portion of the second thin film layer that is not covered forms a second pattern space 76.
  • the pattern space of the photoresist layer can be etched. The pattern space of the photoresist layer will expose the uncovered film layer.
  • the photoresist layer is described using a negative photoresist material, it should be noted that the photoresist layer may also use a positive photoresist.
  • positive and negative photoresist materials The difference between using positive and negative photoresist materials is that after the positive photoresist material is exposed, the positive photoresist that shines on the light part will be removed in a subsequent removal action, while the negative photoresist material is exposed to the negative light of the light part after exposure. The resistance remains in the subsequent removal action, but the negative photoresist that does not shine on the light part is removed in the subsequent removal action.
  • Step 105 At the same time, remove the upper and lower uncovered thin film layers (see FIG. 3E); remove the first thin film layer below the first pattern space 66 and the second thin film layer below the second pattern space 76, respectively. .
  • the uncovered thin film layer can be etched using different etching solutions required for the thin film layer.
  • Step 106 simultaneously remove the remaining photoresist layer on the top and bottom (see FIG. 3F); remove the first photoresist layer to form a first thin film pattern 60 and the second photoresist layer to form a second thin film pattern 70 ;
  • the first photoresist layer 64 and the second photoresist layer 74 absorb different light wavelengths. That is, the first photoresist layer 64 and the second photoresist layer 74 absorb light in different light wavelength ranges, so that different patterns are generated on the upper and lower surfaces of the substrate, and they do not affect each other during the exposure process.
  • step 106 the remaining photoresist layers on the upper and lower surfaces may not be removed, but hard baking may be adopted to retain the remaining photoresist layers on the upper and lower surfaces (as shown in FIG. 3E) and hard bake Both are formed as permanent materials, and the first thin film pattern 60 and the second thin film pattern 70 may be protected.
  • FIG. 4 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate using a photoresist lift-off process according to a second embodiment of the present invention.
  • FIGS. 5A to 5E are applications of the second embodiment of the present invention The schematic diagram of the photoresist lift-off process for simultaneously forming a pattern on both sides of a transparent substrate.
  • Step 111 forming photoresist layers on the upper and lower surfaces of the transparent substrate (as shown in FIG. 5A); coating a top surface of a transparent substrate 10 to form a first photoresist layer 64, and simultaneously coating and forming on the lower surface of the transparent substrate ⁇ second photoresist layer 74.
  • Step 112 performing exposure (FIG. 5B); placing a first photomask 65 on the first photoresist layer 64 and a second photomask 75 on the second photoresist layer 74, and then performing exposure.
  • Step 113 Remove the exposed photoresist layer on both sides at the same time (see FIG. 5C); remove the exposed first photoresist layer and the second photoresist layer at the same time, so that the substrate not covered by the first photoresist layer A first pattern space 66 is partially formed, and a second pattern space 76 is formed with a portion of the substrate not covered by the second photoresist layer.
  • the pattern space of the photoresist layer can be etched. The pattern space of the photoresist layer will expose the uncovered substrate.
  • the photoresist layer is described using a negative photoresist material, it should be noted that the photoresist layer may also be used a positive photoresist.
  • the difference between using positive and negative photoresist materials is that after the positive photoresist material is exposed, the positive photoresist that shines on the light part will be removed in a subsequent removal action, while the negative photoresist material is exposed to the negative light of the light part after exposure. The resistance remains in the subsequent removal action, but the negative photoresist that does not shine on the light part is removed in the subsequent removal action. That is, in this step, a part of the first photoresist layer and the second photoresist layer on the upper and lower surfaces of the transparent substrate are simultaneously removed. The resulting pattern using positive and negative photoresist is complementary to the opposite.
  • Step 114 forming a thin film layer at the same time in the pattern space on the upper and lower surfaces (as shown in FIG. 5D); forming a first thin film layer 62 in the first pattern space 66 and forming a second thin film layer 72 in the second pattern space 76.
  • Step 115 Remove the remaining photoresist layers on the upper and lower surfaces at the same time (see FIG. 5E); simultaneously remove the exposed first photoresist layer to form a first thin film pattern 60 and the exposed second photoresist layer to form a Second thin film pattern 70. Using different etching solutions required for the photoresist layer, the pattern space of the photoresist layer can be etched.
  • the first photoresist layer and the second photoresist layer absorb different light wavelengths. That is, the first photoresist layer 64 and the second photoresist layer 74 absorb light in different light wavelength ranges, so that the exposure of the upper and lower surfaces of the substrate can be performed simultaneously without affecting each other to generate different patterns.
  • step 115 the remaining photoresist layers on the upper and lower surfaces may not be removed, but a hard baking method may be adopted to retain the remaining photoresist layers on the upper and lower surfaces (as shown in FIG. 5D) and hard bake. Both are formed as permanent materials, and the first thin film pattern 60 and the second thin film pattern 70 may be protected.
  • the first photoresist layer mainly absorbs light bands below 400 nanometers (nm)
  • the second photoresist layer mainly absorbs light bands above 400 nanometers (nm).
  • the first photoresist layer mainly absorbs light bands below 400 nanometers (nm)
  • the second photoresist layer mainly absorbs light bands above 400 nanometers (nm).
  • a light source when performing exposure, a light source is used, and the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first characteristic wavelength is mainly light below 400 nanometers (nm), and the second The characteristic wavelength is mainly light above 400 nanometers (nm).
  • the first characteristic wavelength is between 300 nm and 400 nm
  • the second characteristic wavelength is between 400 nm and 500 nm.
  • the light with a characteristic wavelength of the light source means that the light with the characteristic wavelength has a stronger light intensity in a wavelength range than light with other wavelengths.
  • the first characteristic wavelength is mainly light below 400 nanometers (nm).
  • the first characteristic wavelength is at 365 nm, that is, the first characteristic wavelength has a wavelength around 365 nm which is higher than other wavelengths.
  • Light has a stronger light intensity.
  • the light source may be incident from the upper surface of the transparent substrate 10 or may be incident from the lower surface of the transparent substrate 10.
  • first light sources from different exposure systems can also be used, that is, a first light source and a second light source.
  • the first light source has a first characteristic wavelength, which is mainly light below 400 nanometers (nm).
  • the second light source has a light having a second characteristic wavelength mainly above 400 nanometers (nm).
  • the first characteristic wavelength is between 300 nanometers (nm) and 400 nanometers (nm)
  • the second characteristic wavelength is between 400 nanometers (nm) and 500 nanometers (nm).
  • the first light source and the second light source may be incident from the same surface of the transparent substrate 10 or may be incident from the upper and lower surfaces of the transparent substrate 10 respectively.
  • the material composition of the first photoresist layer 64 and the second photoresist layer 74 is different. Therefore, it is performed in step 102 of the first embodiment of the present invention.
  • the first photoresist layer 64 mainly absorbs light bands below 400 nanometers (nm), and the light bands greater than 400 nanometers (nm) There is no reaction; and the second photoresist layer 74 mainly absorbs light bands above 400 nanometers (nm), but has no response to light bands below 400 nanometers (nm).
  • the first photoresist layer 64 mainly absorbs light bands above 400 nanometers (nm), but has no response to light bands less than 400 nanometers (nm), and the second photoresist layer 74 mainly absorbs 400 nanometers ( nm), but no response to light bands larger than 400 nanometers (nm).
  • the present invention makes the first photoresist layer 64 and the second photoresist layer 74 have different material compositions to absorb light in different light wavelength ranges, so that the exposure of the upper and lower surfaces of the substrate can be performed simultaneously and Do not affect each other to produce different patterns.
  • the photoresist in the present invention may use a positive photoresist or a negative photoresist
  • the first photoresist layer and the second photoresist layer of the present invention use a high-resolution negative photoresist.
  • the materials of the first photoresist layer and the second photoresist layer are mainly composed of a polymer resin (Resin), a photoinitiator, a monomer, a solvent (Solvent), and additives (Additives).
  • Resin polymer resin
  • Solvent solvent
  • additives additives
  • the function of the polymer resin (Resin) is adhesion, developability, pigment dispersibility, flowability, heat resistance, chemical resistance, analysis Capability; the function of the photoinitiator lies in the photosensitivity and resolution; the function of the monomer is adhesion, development, and resolution; the function of the solvent (solvent) lies in viscosity and coating properties; additives
  • the functions of (Additives) are coating, leveling and foaming.
  • the polymer resin (Resin) may be a polymer or copolymer containing a carboxylic acid group (COOH), such as an acrylic resin, an acrylic-epoxy resin, and an acrylic-melamine ( Melamine) resin, acrylic-styrene (Styrene) resin, phenol-phenolic (Phenolic Aldehyde) resin and other resins, or any combination of the above resins, but not limited to this.
  • the weight percentage of the resin in the photoresist may range from 0.1% to 99%.
  • the monomers can be divided into water-insoluble and water-soluble monomers.
  • the water-insoluble monomers can be erythritol triacrylate, trimethyl ether propane triacrylate, and trimethyl ether propane. Trimethacrylate, tris, di-ethanol isocyanate triacrylate, di, trimethylolpropane tetraacrylate, diisopentaerythritol pentaacrylate, pentaacrylate, tetraacetic acid isopentaerythritol; dihexanone hexaacetate Alcohol, diisopentaerythritol hexaacetate, or a polyfunctional monomer, dendritic / multiplex acrylate oligomer, multiplex fluorene polyether acrylate, urethane.
  • Water-soluble monomers can be monomers of Ethoxylated (polyoxyethylene) (EO) base and Propoxylated (polyoxypropylene) (PO); for example: di- (di- (Oxyethylene oxyethylene) vinyl acrylic acid, pentapolyoxyethylene trimethanol propane triacrylate, trioxoethylene di, di-bis-p-phenol methane diacrylate, thirty oxyethylene di, di-double pairs Purpose of phenol methane dimethacrylate, ethoxyethylene trimethanol propane triacrylate, pentaoxyethylene trimethanol propane triacrylate, methyl oxygen 550 oxyethylene monomethacrylate, dioxane Ethylene Diacrylate, Tetraoxyethylene Diacrylate, Tetraoxyethylene Dimethacrylate, Six Peroxyethylene Diacrylate, Six Peroxyethylene Dimethacrylate, Polyoxypropylene Monomethacrylate .
  • two or more monomers can also be added and mixed to form a co-monomer.
  • the photoinitiator can be selected from acetophenone, Benzophenone or bis-imidazole, Benzoin, Mix Benzyl, ⁇ -aminoketone, Acylphosphine oxide, or benzoylformate with any photoinitiator , But not limited to this.
  • the weight percentage of the photoinitiator in the photoresist may range from 0.1 to 10%.
  • Solvent can be ethylene glycol monopropyl ether, di-ethylene glycol dimethyl ether, tetrahydrofuran, ethylene glycol monomethyl ether, glycol ether (ethyleneglycol monoethyl ether), di-ethylene glycol monomethyl ether, di-ethylene glycol monoethyl ether, di-ethylene glycol monomonomethyl ether -butyl ether, propylene glycol mono-methyl ether acetate, propylene glycol mono-ethyl ether acetate, propylene glycol mono-propyl ether acetate, 3 -Ethyl3-ethoxypropionate, etc., or any mixture of the above solvents, but it is not limited to this.
  • the weight percentage of the solvent in the photoresist may range from 0.1% to 99%.
  • the additive is generally a pigment dispersant. This is a component that must be added to the photoresist containing the pigment. Generally, it is a non-ionic interface active agent. 0.1 to 5%.
  • step 102 of the first embodiment of the present invention When exposure is performed at step 102 of the first embodiment of the present invention and when exposure is performed at step 112 of the embodiment of the second embodiment of the present invention, it further includes: (1) substrate cleaning (2) Coating, (3) pre-baking, (4) exposure, (5) developing, (6) post-baking and other processing steps.
  • the film pattern of the present invention can be a single-layer film or a multi-layer film.
  • the invention provides a method for simultaneously forming a pattern on both sides of a transparent substrate, and uses a thin film etching or lift-off process to realize the simultaneous formation of a pattern on both sides of a transparent substrate.
  • the process can reduce the steps and costs of the double-sided pattern process of the transparent substrate, and improve the technical efficiency of the process yield.

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Abstract

The present invention provides a method for simultaneously forming patterns on both sides of a transparent substrate, the method mainly involving: simultaneously forming a first photoresist layer and a second photoresist on upper and lower sides of a transparent substrate, and simultaneously forming a first thin film pattern and a second thin film pattern on the upper and lower sides of the transparent substrate via a photolithography program and by means of thin film deposition and etching, wherein the first photoresist layer and the second photoresist layer carry out a reaction by means of absorbing light in different light wavelength ranges during exposure, thereby forming different patterns, and do not affect each other in the process of exposure. By means of the method in the present invention, the steps and costs of a double-sided pattern process of a transparent substrate can be reduced, and the yield of the process can be improved.

Description

一种在透明基材双面同时形成图案的方法Method for simultaneously forming patterns on both sides of transparent substrate 技术领域Technical field
本发明是关于一种形成图案的方法,特别关于一种在透明基材双面同时形成图案的方法。The invention relates to a method for forming a pattern, in particular to a method for forming a pattern on both sides of a transparent substrate at the same time.
背景技术Background technique
随全球软性电子(flexible electronic)商机的快速崛起,国际上已大力投资并组成跨公司的软性透明研发,积极投入大批人力与研发经费,布局相关未来的软性透明电子产品,包括软性显示器(Flexible Display)、软性太阳能(Flexible Solar Cell)、或软性照明(Flexible Lighting)等等,期许在下一波软性电子的热潮中能抢得市场的先机。透明电子是一种新兴的技术,专注于制造薄而透明的电子组件,如显示器,芯片和电路。目前,智能型装置如智能型手机、智能型手表、智能型显示组件等,都有可能朝向透明电子装置的趋势。这些具有透明的电子装置,逐渐都走向个性化、美观的造型设计等,这些都必须通过半导体制造来实现。With the rapid rise of global flexible electronics business opportunities, the international community has invested heavily and formed cross-company soft and transparent R & D, actively invested a large amount of manpower and R & D funds, and laid out relevant future soft and transparent electronic products, including soft Displays (Flexible Display), Flexible Solar (Cell), or Flexible Lighting (Flexible Lighting), etc., are expected to seize the market opportunity in the next wave of flexible electronics boom. Transparent electronics is an emerging technology focused on manufacturing thin and transparent electronic components such as displays, chips and circuits. At present, smart devices such as smart phones, smart watches, smart display components, etc., are likely to trend toward transparent electronic devices. These transparent electronic devices are gradually moving towards personalized, beautiful design, etc. These must be achieved through semiconductor manufacturing.
目前许多的透明电子产品,均在透明基板的双面上制作图案、线路、保护薄膜等。传统上,要在基板上的双面制作图案技术,必须通过多次的微影工艺,其程序包括涂布、光罩贴合、曝光、显影、蚀刻、去光阻等工艺,不仅技术过程繁琐,且过程中有多次进行定位的要求,通常多次的定位程序往往导致良品率不高的结果。At present, many transparent electronic products make patterns, circuits, and protective films on both sides of a transparent substrate. Traditionally, to make a pattern on both sides of a substrate, the lithography process must be repeated multiple times. The process includes coating, mask lamination, exposure, development, etching, and photoresist removal. Not only is the technical process complicated. , And there are multiple positioning requirements in the process, usually multiple positioning procedures often lead to low yield.
因此,如何解决在透明基材双面同时形成图案的问题,成为目前相关软性工艺厂商所希望要求的发展方向。Therefore, how to solve the problem of simultaneously forming a pattern on both sides of a transparent substrate has become the development direction that the related soft process manufacturers hope to demand.
发明内容Summary of the Invention
本发明的目的在于解决上述问题,提供一种在透明基材双面同时形成图案的方法。An object of the present invention is to solve the above problems and provide a method for simultaneously forming a pattern on both sides of a transparent substrate.
本发明提供一种在透明基材双面同时形成图案的方法,包含:于该透明基板的上表面形成一第一薄膜层,且同时于该透明基板的下表面形成一第二薄膜层;于该第一薄膜层上形成一第一光阻层与于该第二薄膜层上同时形成一第二光阻层;于该第一光阻层放置一第一光罩与同时于该第二光阻层上放置一第二光罩后进行曝光;同时移除该透明基板的上下表面其中一部分的光阻层,使得该第一薄膜层未被覆盖的部分形成一第一图案空间,与该第二薄膜层未被覆盖的部分形成一第二图案空间,其中,若该第一光阻层与该第二光阻层使用正光阻材料,则移除部分光阻层为移除被曝光的该第一光阻层与该第二光阻层部分,若该第一光阻层与该第二光阻层使用负光阻材料,则移除部分光阻层为移除未被曝光的该第一光阻层与该第二光阻层部分;同时移除该第一图案空间下方的该第一薄膜层与该第二图案空间下方的该第二薄膜层;及同时移除该第一光阻层以形成一第一薄膜图案与该第二光阻层以形成一第二薄膜图案;其中,在进行曝光时,该第一光阻层与该第二光阻层是 吸收不同光波长范围的光。The invention provides a method for simultaneously forming a pattern on both sides of a transparent substrate, comprising: forming a first thin film layer on an upper surface of the transparent substrate; and simultaneously forming a second thin film layer on a lower surface of the transparent substrate; and A first photoresist layer is formed on the first thin film layer and a second photoresist layer is simultaneously formed on the second thin film layer; a first photomask is placed on the first photoresist layer and simultaneously on the second light A second photomask is placed on the resist layer for exposure; at the same time, a part of the photoresist layer on the upper and lower surfaces of the transparent substrate is removed, so that the uncovered portion of the first thin film layer forms a first pattern space and the first pattern space. The uncovered portion of the two thin film layers forms a second pattern space. If the first photoresist layer and the second photoresist layer use a positive photoresist material, removing a part of the photoresist layer is to remove the exposed photoresist. The first photoresist layer and the second photoresist layer portion. If a negative photoresist material is used in the first photoresist layer and the second photoresist layer, removing a portion of the photoresist layer is to remove the first photoresist layer that has not been exposed. A photoresist layer and the second photoresist layer portion; the first figure is removed at the same time The first thin film layer below the space and the second thin film layer below the second pattern space; and simultaneously removing the first photoresist layer to form a first thin film pattern and the second photoresist layer to form a first Two thin-film patterns; wherein, during exposure, the first photoresist layer and the second photoresist layer absorb light of different light wavelength ranges.
根据本发明的特征,该第一光阻层与该第二光阻层的材料是选自含羧酸基(COOH)的聚合物或共聚物。According to a feature of the present invention, a material of the first photoresist layer and the second photoresist layer is selected from polymers or copolymers containing a carboxylic acid group (COOH).
根据本发明的特征,该第一光阻层与该第二光阻层的材料是选自:压克力(Acrylic)树脂、压克力-环氧(Epoxy)树脂、压克力-美耐皿(Melamine)树脂、压克力-苯乙烯(Styrene)树脂或以上树脂的组合。According to the features of the present invention, the material of the first photoresist layer and the second photoresist layer is selected from the group consisting of: acrylic resin, acrylic-epoxy resin, and acrylic-melamine Melamine resin, acrylic-styrene resin or a combination of the above resins.
本发明的目的在提供一种在透明基材双面同时形成图案的方法,包含:于一透明基板的上表面形成一第一光阻层,且同时于该透明基板的下表面形成一第二光阻层;于该第一光阻层放置一第一光罩与于该第二光阻层上放置一第二光罩后进行曝光;同时移除该透明基板的上下表面其中一部分的(part)光阻层,使得该第一光阻层未覆盖的基板部分形成一第一图案空间与该第二光阻层未覆盖的基板部分形成一第二图案空间;其中,若该第一光阻层与该第二光阻层使用正光阻材料,则移除部分光阻层为移除被曝光的该第一光阻层与该第二光阻层部分,若该第一光阻层与该第二光阻层使用负光阻材料,则移除部分光阻层为移除未被曝光的该第一光阻层与该第二光阻层部分;同时于该第一图案空间形成一第一薄膜层与于该第二图案空间形成一第二薄膜层;及同时移除曝光的该第一光阻层以形成一第一薄膜图案与曝光的该第二光阻层以形成一第二薄膜图案;其中,在进行曝光时,该第一光阻层与该第二光阻层是吸收不同光波长范围的光。An object of the present invention is to provide a method for simultaneously forming a pattern on both sides of a transparent substrate, comprising: forming a first photoresist layer on an upper surface of a transparent substrate; and simultaneously forming a second photoresist layer on a lower surface of the transparent substrate. A photoresist layer; placing a first photomask on the first photoresist layer and a second photomask on the second photoresist layer for exposure; and simultaneously removing a part (part of the upper and lower surfaces of the transparent substrate) ) A photoresist layer such that a portion of the substrate not covered by the first photoresist layer forms a first pattern space and a portion of the substrate not covered by the second photoresist layer forms a second pattern space; wherein, if the first photoresist Layer and the second photoresist layer use a positive photoresist material, then removing a part of the photoresist layer is to remove the exposed first photoresist layer and the second photoresist layer, and if the first photoresist layer and the The second photoresist layer uses a negative photoresist material, so removing a part of the photoresist layer is to remove the unexposed first photoresist layer and the second photoresist layer portion; at the same time, a first photoresist layer is formed in the first pattern space. A thin film layer and forming a second thin film layer in the second pattern space; and The exposed first photoresist layer is formed to form a first thin film pattern and the exposed second photoresist layer is formed to form a second thin film pattern; wherein during the exposure, the first photoresist layer and the second photoresist layer are formed. The photoresist layer absorbs light in different wavelength ranges.
根据本发明的特征,该第一光阻层主要吸收400纳米(nm)以下的光波段,且该第二光阻层主要吸收400纳米(nm)以上的光波段。根据本发明的特征,在进行曝光时是使用一光源,该光源具有一第一特征波长与一第二特征波长,其中该第一特征波长主要是在400纳米以下的光,且该第二特征波长主要是在400纳米以上的光。According to a feature of the present invention, the first photoresist layer mainly absorbs light bands below 400 nanometers (nm), and the second photoresist layer mainly absorbs light bands above 400 nanometers (nm). According to a feature of the present invention, a light source is used when performing exposure, the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first characteristic wavelength is mainly light below 400 nanometers, and the second characteristic The wavelength is mainly light above 400 nanometers.
根据本发明的特征,在进行曝光时是使用一第一光源与一第二光源,该第一光源具有第一特征波长,主要是在400纳米以下的光,且该第二光源具有一第二特征波长主要是在400纳米以上的光。According to the features of the present invention, a first light source and a second light source are used in the exposure. The first light source has a first characteristic wavelength, mainly light below 400 nanometers, and the second light source has a second The characteristic wavelength is mainly light above 400 nanometers.
本发明运用黄光微影工艺进行光阻图案制作,后再以薄膜蚀刻(etching)或光阻掀离(Lift-off)工艺的技术手段形成功能性的图案,微影工艺程序中,通过上下层光阻吸收不同光波长范围的光,而产生不同的图案,且曝光过程中不互相影响,来实现同时在透明基材双面同时形成图案的工艺,达到降低透明基板的双面图案工艺的步骤与成本,并提高工艺良品率的技术功效。为让本发明的上述和其他目的、特征、和优点能更明显易懂,下文特举数个较佳实施例,并配合所附图式,作详细说明如下。In the present invention, a photoresist pattern is produced by using a yellow light lithography process, and then a functional pattern is formed by a technical method of a thin film etching or lift-off process. In the lithography process, the upper and lower layers of light are used. Blocking the absorption of light in different light wavelength ranges to produce different patterns, and do not affect each other during the exposure process, to achieve the process of simultaneously forming a pattern on both sides of a transparent substrate at the same time, to reduce the steps and processes of a double-sided pattern process on a transparent substrate Cost and improve the technical efficiency of the process yield. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, several preferred embodiments are exemplified below, and described in detail with the accompanying drawings.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明在透明基材双面同时形成图案的示意意图。FIG. 1 is a schematic view of forming a pattern on both sides of a transparent substrate simultaneously.
图2是本发明第一实施例运用薄膜蚀刻工艺在透明基材双面同时形成图案的方法流程图。FIG. 2 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate by a thin film etching process according to a first embodiment of the present invention.
图3A至图3F为本发明第一实施例运用薄膜蚀刻工艺在透明基材双面同时形成图案的结构变化示意图。FIG. 3A to FIG. 3F are schematic diagrams of structural changes of simultaneously forming a pattern on both sides of a transparent substrate using a thin film etching process according to the first embodiment of the present invention.
图4是本发明第二实施例运用光阻掀离工艺在透明基材双面同时形成图案的方法流程图。4 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate by using a photoresist lift-off process according to a second embodiment of the present invention.
图5A至图5E为本发明第二实施例运用光阻掀离工艺在透明基材双面同时形成图案的结构变化示意图。5A to FIG. 5E are schematic diagrams of structural changes of simultaneously forming a pattern on both sides of a transparent substrate by using a photoresist lift-off process according to a second embodiment of the present invention.
图中:In the picture:
10透明基板;12上表面;14下表面;60第一薄膜图案;10 transparent substrates; 12 upper surface; 14 lower surface; 60 first thin film pattern;
62第一薄膜层;64第一光阻层;65第一光罩;62 the first thin film layer; 64 the first photoresist layer; 65 the first photomask;
70第二薄膜图案;72第二薄膜层;74第二光阻层;75第二光罩。70 a second thin film pattern; 72 a second thin film layer; 74 a second photoresist layer; 75 a second photomask.
具体实施方式detailed description
根据本发明的实施例,本发明运用光阻掀离(Lift-off)工艺或薄膜蚀刻(etching)的技术手段,来实现同时在透明基材双面同时形成图案的工艺,达到降低透明基板的双面图案工艺的步骤与成本,并提高工艺良品率的技术功效。According to an embodiment of the present invention, the present invention uses a photoresist lift-off process or a thin film etching technique to realize a process of simultaneously forming a pattern on both sides of a transparent substrate at the same time, thereby reducing the The steps and costs of the double-sided pattern process, and improve the technical efficacy of the process yield.
请先参考图1,其为本发明在透明基材双面同时形成图案的示意意图。在一透明基板10的上表面12具有一第一薄膜图案60,且在该透明基板10的下表面14具有一第二薄膜图案70。该透明基板10可以玻璃、石英、塑料基板,例如聚对苯二甲酸乙二酯(Polyethylene terephthalate,简称PET)、聚乙烯醇缩丁醛树脂(Polyvinyl Butyral Resin简称PVB)等。该透明基板10在可见光波段的光透度大于80%以上。Please refer to FIG. 1 first, which is a schematic view of forming a pattern on both sides of a transparent substrate at the same time according to the present invention. A first thin film pattern 60 is provided on an upper surface 12 of a transparent substrate 10, and a second thin film pattern 70 is provided on a lower surface 14 of the transparent substrate 10. The transparent substrate 10 can be a glass, quartz, or plastic substrate, such as polyethylene terephthalate (PET), polyvinyl butyral resin (PVB), or the like. The transparent substrate 10 has a light transmittance of more than 80% in a visible light band.
该第一薄膜图案60与该第一薄膜图案70的材料可选自以下的任意组合:金属薄膜、非金属薄膜、无机金属氧化薄膜、或非金属氧化薄膜。该第一薄膜图案60与该第二薄膜图案70的厚度与图案形式可以是一样或不一样。且该第一薄膜图案60与该第一薄膜图案70可通过薄膜蚀刻工艺或光阻掀离工艺所形成。The materials of the first thin film pattern 60 and the first thin film pattern 70 can be selected from any combination of the following: a metal film, a non-metal film, an inorganic metal oxide film, or a non-metal oxide film. The thickness and pattern form of the first thin film pattern 60 and the second thin film pattern 70 may be the same or different. The first thin film pattern 60 and the first thin film pattern 70 may be formed by a thin film etching process or a photoresist lift-off process.
请参考图2与图3,图2是本发明第一实施例运用薄膜蚀刻工艺在透明基材双面同时形成图案的方法流程图;图3A至图3F是本发明第一实施例运用薄膜蚀刻工艺在透明基材双面同时形成图案的结构变化示意图。Please refer to FIG. 2 and FIG. 3. FIG. 2 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate using a thin film etching process according to a first embodiment of the present invention; and FIGS. 3A to 3F are first embodiment of the present invention using thin film etching. Schematic diagram of structural changes in the process of simultaneously forming a pattern on both sides of a transparent substrate.
步骤101:于透明基板的上下表面形成薄膜层(如图3A);亦即是于该透明基板的上表面形成一第一薄膜层62,且同时于该透明基板的下表面形成一第二薄膜层72。其中,形成该第一薄膜层62与该第二薄膜层72可以使用物理气相沉积:溅镀、蒸镀或离子镀;也可以使用化学气相沉积: 电浆增强式化学气相沉积、有基金属化学气相沉积;或液相化学沉积:溶胶凝胶、有机金属裂解等。该第一薄膜图案60与该第二薄膜图案70的厚度与图案形式可以是一样或不一样。较佳地,该第一薄膜图案60与该第二薄膜图案70的厚度不一样,且该第一薄膜图案60与该第二薄膜图案70的图案形式不一样。Step 101: forming a thin film layer on the upper and lower surfaces of the transparent substrate (see FIG. 3A); that is, forming a first thin film layer 62 on the upper surface of the transparent substrate, and simultaneously forming a second thin film on the lower surface of the transparent substrate Layer 72. Wherein, the first thin film layer 62 and the second thin film layer 72 may be formed by physical vapor deposition: sputtering, evaporation, or ion plating; chemical vapor deposition may also be used: plasma enhanced chemical vapor deposition, metal-based chemistry Vapor deposition; or liquid chemical deposition: sol-gel, organic metal cracking, etc. The thickness and pattern form of the first thin film pattern 60 and the second thin film pattern 70 may be the same or different. Preferably, the thickness of the first thin film pattern 60 and the second thin film pattern 70 are different, and the pattern form of the first thin film pattern 60 and the second thin film pattern 70 are different.
步骤102:于上下两面薄膜层上同时分别形成光阻层(如图3B);于该第一薄膜层62上涂布形成一第一光阻层64,且同时于该第二薄膜层72上涂布形成一第二光阻层74。Step 102: forming a photoresist layer on the upper and lower thin film layers simultaneously (see FIG. 3B); forming a first photoresist layer 64 on the first thin film layer 62, and simultaneously on the second thin film layer 72 A second photoresist layer 74 is formed by coating.
步骤103:进行曝光(如图3C);于该第一光阻层64放置一第一光罩65与于该第二光阻层74上放置一第二光罩75后,同时进行曝光。Step 103: performing exposure (as shown in FIG. 3C); after placing a first photomask 65 on the first photoresist layer 64 and a second photomask 75 on the second photoresist layer 74, exposure is performed simultaneously.
步骤104:同时移除两面未被曝光的光阻层(如图3D);同时移除未被曝光的该第一光阻层与该第二光阻层,使得该第一薄膜层未被覆盖的部分形成一第一图案空间66与该第二薄膜层未被覆盖的部分形成一第二图案空间76。运用光阻层所需的不同蚀刻液,即可蚀刻出光阻层的图案空间。而光阻层的图案空间会让未被覆盖的薄膜层暴露出来。需注意,在该第一实施例中,虽然光阻层是使用负光阻材料做说明,需注意的是,光阻层亦可以使用正光阻。使用正负光阻材料的差异在于:正光阻材料于曝光后,照到光部分的正光阻会被接续的移除动作中去除,而负光阻材料于曝光后,照到光部分的负光阻在接续的移除动作保留,而是未照到光部分的负光阻在接续的移除动作中去除。亦即是,在该步骤中,同时移除该透明基板的上、下表面上其中一部分的(part)第一光阻层及第二光阻层,使用正负光阻最后所形成的图案是为相反互补。Step 104: Remove the unexposed photoresist layer on both sides at the same time (see FIG. 3D); remove the unexposed first photoresist layer and the second photoresist layer at the same time, so that the first thin film layer is not covered A portion of the first pattern space 66 forms a second pattern space 76 and a portion of the second thin film layer that is not covered forms a second pattern space 76. Using different etching solutions required for the photoresist layer, the pattern space of the photoresist layer can be etched. The pattern space of the photoresist layer will expose the uncovered film layer. It should be noted that, in this first embodiment, although the photoresist layer is described using a negative photoresist material, it should be noted that the photoresist layer may also use a positive photoresist. The difference between using positive and negative photoresist materials is that after the positive photoresist material is exposed, the positive photoresist that shines on the light part will be removed in a subsequent removal action, while the negative photoresist material is exposed to the negative light of the light part after exposure. The resistance remains in the subsequent removal action, but the negative photoresist that does not shine on the light part is removed in the subsequent removal action. That is, in this step, a part of the first photoresist layer and the second photoresist layer on the upper and lower surfaces of the transparent substrate are removed at the same time, and the pattern finally formed using the positive and negative photoresists is For the opposite complement.
步骤105:同时移除上下面未被覆盖的薄膜层(如图3E);分别移除该第一图案空间66下方的该第一薄膜层与该第二图案空间76下方的该第二薄膜层。运用薄膜层所需的不同蚀刻液,即可蚀刻未被覆盖的薄膜层。Step 105: At the same time, remove the upper and lower uncovered thin film layers (see FIG. 3E); remove the first thin film layer below the first pattern space 66 and the second thin film layer below the second pattern space 76, respectively. . The uncovered thin film layer can be etched using different etching solutions required for the thin film layer.
步骤106:同时移除上下面其余的光阻层(如图3F);移除该第一光阻层以形成一第一薄膜图案60与该第二光阻层以形成一第二薄膜图案70;Step 106: simultaneously remove the remaining photoresist layer on the top and bottom (see FIG. 3F); remove the first photoresist layer to form a first thin film pattern 60 and the second photoresist layer to form a second thin film pattern 70 ;
其中,本实施例的步骤103进行曝光时,该第一光阻层64与该第二光阻层74是吸收不同的光波长。亦即是,该第一光阻层64与该第二光阻层74通过吸收不同光波长范围的光,而使得基板上下表面产生不同的图案,且曝光过程中不互相影响。When exposure is performed in step 103 in this embodiment, the first photoresist layer 64 and the second photoresist layer 74 absorb different light wavelengths. That is, the first photoresist layer 64 and the second photoresist layer 74 absorb light in different light wavelength ranges, so that different patterns are generated on the upper and lower surfaces of the substrate, and they do not affect each other during the exposure process.
此外,在该第一实施例中,在步骤106:亦可以不移除上下表面剩余的光阻层,而采用硬烤方式,将上下表面剩余的光阻层保留(如图3E)并硬烤以均形成为永久材,亦可对该第一薄膜图案60与该第二薄膜图案70形成保护。In addition, in the first embodiment, in step 106: the remaining photoresist layers on the upper and lower surfaces may not be removed, but hard baking may be adopted to retain the remaining photoresist layers on the upper and lower surfaces (as shown in FIG. 3E) and hard bake Both are formed as permanent materials, and the first thin film pattern 60 and the second thin film pattern 70 may be protected.
请参考图4与图5,图4是本发明第二实施例运用光阻掀离工艺在透明基材双面同时形成图案的方法流程图;图5A至图5E是本发明第二实施例运用光阻掀离工艺在透明基材双面同时形成 图案的方法流程示意图。Please refer to FIG. 4 and FIG. 5. FIG. 4 is a flowchart of a method for simultaneously forming a pattern on both sides of a transparent substrate using a photoresist lift-off process according to a second embodiment of the present invention. FIGS. 5A to 5E are applications of the second embodiment of the present invention The schematic diagram of the photoresist lift-off process for simultaneously forming a pattern on both sides of a transparent substrate.
步骤111:于透明基板的上下表面形成光阻层(如图5A);于一透明基板10的上表面涂布形成一第一光阻层64,且同时于该透明基板的下表面涂布形成一第二光阻层74。Step 111: forming photoresist layers on the upper and lower surfaces of the transparent substrate (as shown in FIG. 5A); coating a top surface of a transparent substrate 10 to form a first photoresist layer 64, and simultaneously coating and forming on the lower surface of the transparent substrate一 second photoresist layer 74.
步骤112:进行曝光(图5B);于该第一光阻层64放置一第一光罩65与于该第二光阻层74上放置一第二光罩75后进行曝光。Step 112: performing exposure (FIG. 5B); placing a first photomask 65 on the first photoresist layer 64 and a second photomask 75 on the second photoresist layer 74, and then performing exposure.
步骤113:同时移除两面被曝光的光阻层(如图5C);同时移除被曝光的该第一光阻层与该第二光阻层,使得该第一光阻层未覆盖的基板部分形成一第一图案空间66,与该第二光阻层未覆盖的基板部分形成一第二图案空间76。运用光阻层所需的不同蚀刻液,即可蚀刻出光阻层的图案空间。而光阻层的图案空间会让未被覆盖的基板暴露出来。需注意,在该第二实施例中,虽然光阻层是使用负光阻材料做说明,需注意的是,光阻层亦可以使用正光阻。使用正负光阻材料的差异在于:正光阻材料于曝光后,照到光部分的正光阻会被接续的移除动作中去除,而负光阻材料于曝光后,照到光部分的负光阻在接续的移除动作保留,而是未照到光部分的负光阻在接续的移除动作中去除。亦即是,在该步骤中,同时移除该透明基板的上、下表面上其中一部分的第一光阻层及第二光阻层。使用正负光阻最后所形成的图案是为相反互补。Step 113: Remove the exposed photoresist layer on both sides at the same time (see FIG. 5C); remove the exposed first photoresist layer and the second photoresist layer at the same time, so that the substrate not covered by the first photoresist layer A first pattern space 66 is partially formed, and a second pattern space 76 is formed with a portion of the substrate not covered by the second photoresist layer. Using different etching solutions required for the photoresist layer, the pattern space of the photoresist layer can be etched. The pattern space of the photoresist layer will expose the uncovered substrate. It should be noted that in this second embodiment, although the photoresist layer is described using a negative photoresist material, it should be noted that the photoresist layer may also be used a positive photoresist. The difference between using positive and negative photoresist materials is that after the positive photoresist material is exposed, the positive photoresist that shines on the light part will be removed in a subsequent removal action, while the negative photoresist material is exposed to the negative light of the light part after exposure. The resistance remains in the subsequent removal action, but the negative photoresist that does not shine on the light part is removed in the subsequent removal action. That is, in this step, a part of the first photoresist layer and the second photoresist layer on the upper and lower surfaces of the transparent substrate are simultaneously removed. The resulting pattern using positive and negative photoresist is complementary to the opposite.
步骤114:于上下表面的图案空间同时形成薄膜层(如图5D);于该第一图案空间66形成一第一薄膜层62与于该第二图案空间76形成一第二薄膜层72。Step 114: forming a thin film layer at the same time in the pattern space on the upper and lower surfaces (as shown in FIG. 5D); forming a first thin film layer 62 in the first pattern space 66 and forming a second thin film layer 72 in the second pattern space 76.
步骤115:同时移除上下表面剩余的光阻层(如图5E);同时移除曝光的该第一光阻层以形成一第一薄膜图案60与曝光的该第二光阻层以形成一第二薄膜图案70。运用光阻层所需的不同蚀刻液,即可蚀刻出光阻层的图案空间。Step 115: Remove the remaining photoresist layers on the upper and lower surfaces at the same time (see FIG. 5E); simultaneously remove the exposed first photoresist layer to form a first thin film pattern 60 and the exposed second photoresist layer to form a Second thin film pattern 70. Using different etching solutions required for the photoresist layer, the pattern space of the photoresist layer can be etched.
其中,在本实施例的步骤112时进行曝光时,该第一光阻层与该第二光阻层是吸收不同的光波长。亦即是,该第一光阻层64与该第二光阻层74通过吸收不同光波长范围的光,而使得基板上下表面的曝光可以同时进行且不互相影响,以产生不同的图案。When exposure is performed at step 112 in this embodiment, the first photoresist layer and the second photoresist layer absorb different light wavelengths. That is, the first photoresist layer 64 and the second photoresist layer 74 absorb light in different light wavelength ranges, so that the exposure of the upper and lower surfaces of the substrate can be performed simultaneously without affecting each other to generate different patterns.
此外,在该第二实施例中,在步骤115:亦可以不移除上下表面剩余的光阻层,而采用硬烤方式,将上下表面剩余的光阻层保留(如图5D)并硬烤以均形成为永久材,亦可对该第一薄膜图案60与该第二薄膜图案70形成保护。In addition, in this second embodiment, in step 115: the remaining photoresist layers on the upper and lower surfaces may not be removed, but a hard baking method may be adopted to retain the remaining photoresist layers on the upper and lower surfaces (as shown in FIG. 5D) and hard bake. Both are formed as permanent materials, and the first thin film pattern 60 and the second thin film pattern 70 may be protected.
在本发明第一实施例的步骤102时进行曝光时与在本发明第二实施例的实施例的步骤112时进行曝光时,该第一光阻层主要吸收400纳米(nm)以下的光波段,且该第二光阻层主要吸收400纳米(nm)以上的光波段。较佳地,该第一光阻层主要吸收400纳米(nm)以下的光波段,且该第二光阻层主要吸收400纳米(nm)以上的光波段。When exposure is performed at step 102 of the first embodiment of the present invention and when exposure is performed at step 112 of the second embodiment of the present invention, the first photoresist layer mainly absorbs light bands below 400 nanometers (nm) Moreover, the second photoresist layer mainly absorbs light bands above 400 nanometers (nm). Preferably, the first photoresist layer mainly absorbs light bands below 400 nanometers (nm), and the second photoresist layer mainly absorbs light bands above 400 nanometers (nm).
且,在进行曝光时,是使用一光源,且该光源具有一第一特征波长与一第二特征波长,其 中该第一特征波长主要是在400纳米(nm)以下的光,且该第二特征波长主要是在400纳米(nm)以上的光。较佳地,该第一特征波长是介于300nm至400nm之间,且该第二特征波长是介于400nm至500nm之间。在此,该光源具有的特征波长的光是指:该特征波长的光在一波长范围内具有比起其他波长的光有着更强的光强度。例如,该第一特征波长主要是在400纳米(nm)以下的光,较佳地,该第一特征波长是在于365nm,亦即,具有该第一特征波长在365nm前后具有比起其他波长的光有着更强的光强度。曝光时,该光源可由该透明基板10的上表面入射,亦可以由该透明基板10的下表面入射。Moreover, when performing exposure, a light source is used, and the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first characteristic wavelength is mainly light below 400 nanometers (nm), and the second The characteristic wavelength is mainly light above 400 nanometers (nm). Preferably, the first characteristic wavelength is between 300 nm and 400 nm, and the second characteristic wavelength is between 400 nm and 500 nm. Here, the light with a characteristic wavelength of the light source means that the light with the characteristic wavelength has a stronger light intensity in a wavelength range than light with other wavelengths. For example, the first characteristic wavelength is mainly light below 400 nanometers (nm). Preferably, the first characteristic wavelength is at 365 nm, that is, the first characteristic wavelength has a wavelength around 365 nm which is higher than other wavelengths. Light has a stronger light intensity. During exposure, the light source may be incident from the upper surface of the transparent substrate 10 or may be incident from the lower surface of the transparent substrate 10.
在进行曝光时,亦可以使用来自不同曝光系统的光源,亦即是一第一光源与一第二光源,该第一光源具有第一特征波长,主要是在400纳米(nm)以下的光,且该第二光源具有一第二特征波长主要是在400纳米(nm)以上的光。较佳地,该第一特征波长是介于300纳米(nm)至400纳米(nm)之间,且该第二特征波长是介于400纳米(nm)至500纳米(nm)之间。曝光时,该第一光源与该第二光源可由该透明基板10的同一面入射,或由该透明基板10的上下表面分别入射。When performing exposure, light sources from different exposure systems can also be used, that is, a first light source and a second light source. The first light source has a first characteristic wavelength, which is mainly light below 400 nanometers (nm). And the second light source has a light having a second characteristic wavelength mainly above 400 nanometers (nm). Preferably, the first characteristic wavelength is between 300 nanometers (nm) and 400 nanometers (nm), and the second characteristic wavelength is between 400 nanometers (nm) and 500 nanometers (nm). During exposure, the first light source and the second light source may be incident from the same surface of the transparent substrate 10 or may be incident from the upper and lower surfaces of the transparent substrate 10 respectively.
由于透明基板会穿透光线,为了能达成同时曝光的要求,该第一光阻层64与该第二光阻层74的材料成分不相同,因此,在本发明第一实施例的步骤102进行曝光时与在本发明第二实施例的实施例的步骤112进行曝光时,该第一光阻层64主要吸收400纳米(nm)以下的光波段,而对大于400纳米(nm)的光波段没有反应;且该第二光阻层74主要吸收400纳米(nm)以上的光波段,而对小于400纳米(nm)的光波段没有反应。亦可以是,该第一光阻层64主要吸收400纳米(nm)以上的光波段,而对小于400纳米(nm)的光波段没有反应,且该第二光阻层74主要吸收400纳米(nm)以下的光波段,而对大于400纳米(nm)的光波段没有反应。在曝光过程中,本发明通过使得该第一光阻层64与该第二光阻层74的材料成分不相同,以吸收不同光波长范围的光,而使得基板上下表面的曝光可以同时进行且不互相影响,以产生不同的图案。Since the transparent substrate can penetrate light, in order to achieve the requirement of simultaneous exposure, the material composition of the first photoresist layer 64 and the second photoresist layer 74 is different. Therefore, it is performed in step 102 of the first embodiment of the present invention. During exposure and when exposure is performed in step 112 of the embodiment of the second embodiment of the present invention, the first photoresist layer 64 mainly absorbs light bands below 400 nanometers (nm), and the light bands greater than 400 nanometers (nm) There is no reaction; and the second photoresist layer 74 mainly absorbs light bands above 400 nanometers (nm), but has no response to light bands below 400 nanometers (nm). It is also possible that the first photoresist layer 64 mainly absorbs light bands above 400 nanometers (nm), but has no response to light bands less than 400 nanometers (nm), and the second photoresist layer 74 mainly absorbs 400 nanometers ( nm), but no response to light bands larger than 400 nanometers (nm). During the exposure process, the present invention makes the first photoresist layer 64 and the second photoresist layer 74 have different material compositions to absorb light in different light wavelength ranges, so that the exposure of the upper and lower surfaces of the substrate can be performed simultaneously and Do not affect each other to produce different patterns.
虽然本发明中的光阻可以使用正光阻或负光阻,但较佳地,本发明的第一光阻层与第二光阻层是使用高分辨率负型光阻剂。第一光阻层与第二光阻层的材料主要由高分子树脂(Resin)、感光起始剂(Photo initiator)、单体(Monomer)、溶剂(Solvent),以及添加剂(Additives)所组成。通过调整上述组成物,该第一光阻层64与该第二光阻层74的材料成分达到不相同以主要吸收不同光波长范围的光。Although the photoresist in the present invention may use a positive photoresist or a negative photoresist, preferably, the first photoresist layer and the second photoresist layer of the present invention use a high-resolution negative photoresist. The materials of the first photoresist layer and the second photoresist layer are mainly composed of a polymer resin (Resin), a photoinitiator, a monomer, a solvent (Solvent), and additives (Additives). By adjusting the above composition, the material composition of the first photoresist layer 64 and the second photoresist layer 74 is different to mainly absorb light in different light wavelength ranges.
在第一光阻层64与该第二光阻层74的材料中,高分子树脂(Resin)的功能在于附着性、显影性、颜料分散性、流动性、耐热性、耐化性、解析能力;感光起始剂(Photo initiator)的功能在于感光特性、解析能力;单体(Monomer)的功能在于附着性、显影性、解析能力;溶剂(Solvent)的功能在于粘度与涂布性质;添加剂(Additives)的功能则在于涂布性、流平性及起泡性。Among the materials of the first photoresist layer 64 and the second photoresist layer 74, the function of the polymer resin (Resin) is adhesion, developability, pigment dispersibility, flowability, heat resistance, chemical resistance, analysis Capability; the function of the photoinitiator lies in the photosensitivity and resolution; the function of the monomer is adhesion, development, and resolution; the function of the solvent (solvent) lies in viscosity and coating properties; additives The functions of (Additives) are coating, leveling and foaming.
高分子树脂(Resin)可以为含羧酸基(COOH)的聚合物或共聚物,如压克力(Acrylic)树脂、压克力-环氧(Epoxy)树脂、压克力-美耐皿(Melamine)树脂、压克力-苯乙烯(Styrene)树脂、苯酚-酚醛(PhenolicAldehyde)树脂等树脂,或以上树脂的任意混合,但不以此为限。树脂在光阻中的重量百分比范围可以是0.1%至99%。The polymer resin (Resin) may be a polymer or copolymer containing a carboxylic acid group (COOH), such as an acrylic resin, an acrylic-epoxy resin, and an acrylic-melamine ( Melamine) resin, acrylic-styrene (Styrene) resin, phenol-phenolic (Phenolic Aldehyde) resin and other resins, or any combination of the above resins, but not limited to this. The weight percentage of the resin in the photoresist may range from 0.1% to 99%.
单体可分非水溶性及水溶性单体,其中,非水溶性单体(water-insolubleMonomer)可以为戊赤藻糖醇三丙烯酸酯、三甲基醚丙烷三丙烯酸酯、三甲基醚丙烷三甲基丙烯酸酯、三,二-乙醇异氰酸酯三丙烯酸酯,二,三甲醇丙烷四丙烯酸酯、二异戊四醇五丙烯酸酯、五丙烯酸酯、四乙酸异戊四醇;六乙酸二己四醇、六乙酸二异戊四醇,或为多官能基单体、树状/多丛族丙烯酸酯寡体、多丛蔟聚醚丙烯酸酯、氨甲酸乙酯。水溶性单体(water-soluble monomer)则可为Ethoxylated(聚氧乙烯)(简称EO)base和Propoxylated(聚氧丙烯)(简称PO)的单体(monomer);例如为:二-(二-氧乙烯氧乙烯)乙烯基丙烯酸酉旨、十五聚氧乙烯三甲醇丙烷三丙烯酸酯、三十氧乙烯二,二-双对酚甲烷二丙烯酸酯、三十个氧乙烯二,二-双对酚甲烷二甲基丙烯酸酉旨、二十氧乙烯三甲醇丙烷三丙烯酸酯、十五氧乙烯三甲醇丙烷三丙烯酸酯、甲基氧五百五十个氧乙烯单甲基丙烯酸酯、二百氧乙烯二丙烯酸酯、四百氧乙烯二丙烯酸酉旨、四百氧乙烯二甲基丙烯酸酯、六百氧乙烯二丙烯酸酯、六百氧乙烯二甲基丙烯酸酯、聚氧丙烯单甲基丙烯酸酯。当然亦可添加两种以上单体(monomer)混合成共单体(co-monomer)。单体或共单体在光阻中的重量百分比范围可以是0.1%至99%。The monomers can be divided into water-insoluble and water-soluble monomers. Among them, the water-insoluble monomers can be erythritol triacrylate, trimethyl ether propane triacrylate, and trimethyl ether propane. Trimethacrylate, tris, di-ethanol isocyanate triacrylate, di, trimethylolpropane tetraacrylate, diisopentaerythritol pentaacrylate, pentaacrylate, tetraacetic acid isopentaerythritol; dihexanone hexaacetate Alcohol, diisopentaerythritol hexaacetate, or a polyfunctional monomer, dendritic / multiplex acrylate oligomer, multiplex fluorene polyether acrylate, urethane. Water-soluble monomers can be monomers of Ethoxylated (polyoxyethylene) (EO) base and Propoxylated (polyoxypropylene) (PO); for example: di- (di- (Oxyethylene oxyethylene) vinyl acrylic acid, pentapolyoxyethylene trimethanol propane triacrylate, trioxoethylene di, di-bis-p-phenol methane diacrylate, thirty oxyethylene di, di-double pairs Purpose of phenol methane dimethacrylate, ethoxyethylene trimethanol propane triacrylate, pentaoxyethylene trimethanol propane triacrylate, methyl oxygen 550 oxyethylene monomethacrylate, dioxane Ethylene Diacrylate, Tetraoxyethylene Diacrylate, Tetraoxyethylene Dimethacrylate, Six Peroxyethylene Diacrylate, Six Peroxyethylene Dimethacrylate, Polyoxypropylene Monomethacrylate . Of course, two or more monomers can also be added and mixed to form a co-monomer. The weight percentage of the monomer or comonomer in the photoresist may range from 0.1% to 99%.
光起始剂(Photo initiator),可以选自苯乙酮系化合物(acetophenone)、二苯甲酮(Benzophenone)系化合物或二咪唑系化合物(bis-imidazole)、苯偶姻系化合物(Benzoin),苯偶酰系化合物(Benzil)、α-氨基酮系化合物(α-amino ketone)、酰基膦氧化物系化合物(Acyl phosphine oxide)或苯甲酰甲酸酯系化合物以上光起始剂任意的混合,但不以此为限。光起始剂在光阻中的重量百分比范围可以是至0.1至10%。The photoinitiator can be selected from acetophenone, Benzophenone or bis-imidazole, Benzoin, Mix Benzyl, α-aminoketone, Acylphosphine oxide, or benzoylformate with any photoinitiator , But not limited to this. The weight percentage of the photoinitiator in the photoresist may range from 0.1 to 10%.
溶剂(Solvent)可以为乙二醇丙醚(ethylene glycol monopropylether)、二甘醇二甲醚(di-ethylene glycol dimethyl ether)、四氢呋喃、乙二醇甲醚(ethylene glycol monomethyl ether)、乙二醇乙醚(ethyleneglycol monoethyl ether)、二甘醇一甲醚(di-ethylene glycol mono—methylether)、二甘醇一乙醚(di-ethylene glycol mono-ethyl ether)、二甘醇一丁醚(di-ethylene glycol mono-butyl ether)、丙二醇甲醚醋酸酯(propylene glycol mono-methyl ether acetate)、丙二醇乙醚醋酸酯(propylene glycol mono—ethyl ether acetate)、丙二醇丙醚醋酸酯(propylene glycol mono-propyl ether acetate)、3-乙氧基丙酸乙酯(ethyl3-ethoxy propionate)等,或以上溶剂任意的混合,但不限于此。溶剂在光阻中的重量百分比范围可以是0.1%至99%。Solvent can be ethylene glycol monopropyl ether, di-ethylene glycol dimethyl ether, tetrahydrofuran, ethylene glycol monomethyl ether, glycol ether (ethyleneglycol monoethyl ether), di-ethylene glycol monomethyl ether, di-ethylene glycol monoethyl ether, di-ethylene glycol monomonomethyl ether -butyl ether, propylene glycol mono-methyl ether acetate, propylene glycol mono-ethyl ether acetate, propylene glycol mono-propyl ether acetate, 3 -Ethyl3-ethoxypropionate, etc., or any mixture of the above solvents, but it is not limited to this. The weight percentage of the solvent in the photoresist may range from 0.1% to 99%.
添加剂一般为颜料分散剂,此为含有颜料的光阻所必需加入的成份,一般为非离子型接口活性剂,举例如:Solsperse39000,Solsperse21000,此分散剂在光阻中的重量百分比范围可以是至0.1至5%。The additive is generally a pigment dispersant. This is a component that must be added to the photoresist containing the pigment. Generally, it is a non-ionic interface active agent. 0.1 to 5%.
在本发明第一实施例的步骤102时进行曝光时与在本发明第二实施例的实施例的步骤112时进行曝光时,更包含:(1)基板洗净(Substrate Clean);(2)涂布(Coating);(3)软烤(pre-baking);(4)曝光(exposure);(5)显影(Developing);(6)硬烤(Post-baking)等加工步骤。When exposure is performed at step 102 of the first embodiment of the present invention and when exposure is performed at step 112 of the embodiment of the second embodiment of the present invention, it further includes: (1) substrate cleaning (2) Coating, (3) pre-baking, (4) exposure, (5) developing, (6) post-baking and other processing steps.
特别的是,由于本发明薄膜图案可以采用单层薄膜或多层薄膜。本发明提供一种在透明基材双面同时形成图案的方法,运用薄膜蚀刻(etching)或光阻掀离(Lift-off)工艺的技术手段,来实现同时在透明基材双面同时形成图案的工艺,达到降低透明基板的双面图案工艺的步骤与成本,并提高工艺良品率的技术功效。In particular, since the film pattern of the present invention can be a single-layer film or a multi-layer film. The invention provides a method for simultaneously forming a pattern on both sides of a transparent substrate, and uses a thin film etching or lift-off process to realize the simultaneous formation of a pattern on both sides of a transparent substrate. The process can reduce the steps and costs of the double-sided pattern process of the transparent substrate, and improve the technical efficiency of the process yield.
以上所述实施例仅是为充分说明本发明而所举的较佳的实施例,本发明的保护范围不限于此。本技术领域的技术人员在本发明基础上所作的等同替代或变换,均在本发明的保护范围之内。本发明的保护范围以权利要求书为准。The above-mentioned embodiments are merely preferred embodiments for fully explaining the present invention, and the protection scope of the present invention is not limited thereto. Equivalent substitutions or changes made by those skilled in the art on the basis of the present invention are all within the protection scope of the present invention. The protection scope of the present invention is subject to the claims.

Claims (12)

  1. 一种在透明基材双面同时形成图案的方法,其特征在于,包含:A method for simultaneously forming a pattern on both sides of a transparent substrate, comprising:
    透明基板,并于该透明基板的上表面形成一第一薄膜层,且同时于该透明基板的下表面形成一第二薄膜层;A transparent substrate, and forming a first thin film layer on an upper surface of the transparent substrate, and simultaneously forming a second thin film layer on a lower surface of the transparent substrate;
    于该第一薄膜层上形成一第一光阻层,并于该第二薄膜层上同时形成一第二光阻层;Forming a first photoresist layer on the first thin film layer, and simultaneously forming a second photoresist layer on the second thin film layer;
    于该第一光阻层放置一第一光罩,并同时于该第二光阻层上放置一第二光罩后进行曝光;Placing a first photomask on the first photoresist layer, and simultaneously exposing after placing a second photomask on the second photoresist layer;
    同时移除该透明基板的上、下表面上其中一部分的第一光阻层及第二光阻层,使得该第一薄膜层未被覆盖的部分形成一第一图案空间,并于该第二薄膜层未被覆盖的部分形成一第二图案空间,其中,若该第一光阻层与该第二光阻层使用正光阻材料,则移除部分光阻层为移除被曝光的该第一光阻层与该第二光阻层部分,若该第一光阻层与该第二光阻层使用负光阻材料,则移除部分光阻层为移除未被曝光的该第一光阻层与该第二光阻层部分;At the same time, a part of the first photoresist layer and the second photoresist layer on the upper and lower surfaces of the transparent substrate are removed, so that the uncovered portion of the first thin film layer forms a first pattern space and is formed on the second The uncovered portion of the thin film layer forms a second pattern space, wherein if the first photoresist layer and the second photoresist layer use a positive photoresist material, removing a part of the photoresist layer is to remove the first exposed photoresist layer. A photoresist layer and the second photoresist layer, if the first photoresist layer and the second photoresist layer use a negative photoresist material, removing a part of the photoresist layer is to remove the first unexposed photoresist layer A photoresist layer and the second photoresist layer portion;
    同时移除该第一图案空间下方的该第一薄膜层与该第二图案空间下方的该第二薄膜层;及Simultaneously removing the first thin film layer under the first pattern space and the second thin film layer under the second pattern space; and
    同时移除剩余的该第一光阻层以形成一第一薄膜图案与剩余的该第二光阻层以形成一第二薄膜图案;Simultaneously removing the remaining first photoresist layer to form a first thin film pattern and the remaining second photoresist layer to form a second thin film pattern;
    其中,在进行曝光时,该第一光阻层与该第二光阻层是吸收不同光波长范围的光。During the exposure, the first photoresist layer and the second photoresist layer absorb light in different light wavelength ranges.
  2. 如权利要求1所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层与该第二光阻层的材料是选自含羧酸基的聚合物或共聚物,且该第一光阻层的材料成分是不相同于该第二光阻层的材料成分。The method of claim 1, wherein a material of the first photoresist layer and the second photoresist layer is selected from polymers or copolymers containing carboxylic acid groups. And the material composition of the first photoresist layer is different from that of the second photoresist layer.
  3. 如权利要求1所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层与该第二光阻层的材料是选自:压克力树脂、压克力-环氧树脂、压克力-美耐皿树脂、压克力-苯乙烯树脂或以上树脂的组合。The method of claim 1, wherein a material of the first photoresist layer and the second photoresist layer is selected from the group consisting of acrylic resin and acrylic -Epoxy resin, acrylic-melamine resin, acrylic-styrene resin or a combination of the above resins.
  4. 如权利要求1所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层主要吸收波长为400纳米以下的光波段,且该第二光阻层主要吸收波长为400纳米以上的光波段。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 1, wherein the first photoresist layer mainly absorbs light wavelengths below 400 nanometers, and the second photoresist layer mainly absorbs wavelengths It is an optical band above 400 nm.
  5. 如权利要求1所述的在透明基材双面同时形成图案的方法,其特征在于,在进行曝光时是使用一光源,该光源具有一第一特征波长与一第二特征波长,其中该第一特征波长主要是在400纳米以下的光,且该第二特征波长主要是在400纳米以上的光。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 1, wherein a light source is used when performing exposure, and the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first A characteristic wavelength is mainly light below 400 nanometers, and the second characteristic wavelength is mainly light above 400 nanometers.
  6. 如权利要求1所述的在透明基材双面同时形成图案的方法,其特征在于,在进行曝光时是使用一第一光源与一第二光源,该第一光源具有第一特征波长,主要是在400纳米以下的光,且该第二光源具有一第二特征波长主要是在400纳米以上的光。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 1, wherein a first light source and a second light source are used when exposing, and the first light source has a first characteristic wavelength, mainly It is light below 400 nanometers, and the second light source has a light having a second characteristic wavelength mainly above 400 nanometers.
  7. 一种在透明基材双面同时形成图案的方法,其特征在于,包含:A method for simultaneously forming a pattern on both sides of a transparent substrate, comprising:
    于一透明基板的上表面形成一第一光阻层,且同时于该透明基板的下表面形成一第二光阻层;Forming a first photoresist layer on the upper surface of a transparent substrate, and simultaneously forming a second photoresist layer on the lower surface of the transparent substrate;
    于该第一光阻层放置一第一光罩,并于该第二光阻层上放置一第二光罩后进行曝光;Placing a first photomask on the first photoresist layer, and exposing after placing a second photomask on the second photoresist layer;
    同时移除该透明基板的上、下表面部分的第一光阻层和第二光阻层,使得该第一光阻层未覆盖的基板部分形成一第一图案空间,并于该第二光阻层未覆盖的基板部分形成一第二图案空间;其中,若该第一光阻层与该第二光阻层使用正光阻材料,则移除部分光阻层为移除被曝光的该第一光阻层与该第二光阻层部分,若该第一光阻层与该第二光阻层使用负光阻材料,则移除部分光阻层为移除未被曝光的该第一光阻层与该第二光阻层部分;At the same time, the first photoresist layer and the second photoresist layer on the upper and lower surface portions of the transparent substrate are removed, so that a portion of the substrate not covered by the first photoresist layer forms a first pattern space, and The part of the substrate not covered by the resist layer forms a second pattern space; wherein if the first photoresist layer and the second photoresist layer use a positive photoresist material, removing a part of the photoresist layer is to remove the first exposed photoresist layer. A photoresist layer and the second photoresist layer, if the first photoresist layer and the second photoresist layer use a negative photoresist material, removing a part of the photoresist layer is to remove the first unexposed photoresist layer A photoresist layer and the second photoresist layer portion;
    同时于该第一图案空间形成一第一薄膜层与于该第二图案空间形成一第二薄膜层;及Forming a first thin film layer in the first pattern space and a second thin film layer in the second pattern space; and
    同时移除剩余的该第一光阻层以形成一第一薄膜图案与剩余的该第二光阻层以形成一第二薄膜图案;Simultaneously removing the remaining first photoresist layer to form a first thin film pattern and the remaining second photoresist layer to form a second thin film pattern;
    其中,在进行曝光时,该第一光阻层与该第二光阻层是吸收不同光波长范围的光。During the exposure, the first photoresist layer and the second photoresist layer absorb light in different light wavelength ranges.
  8. 如权利要求7所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层与该第二光阻层的材料是选自含羧酸基的聚合物或共聚物,且该第一光阻层的材料成分是不相同于该第二光阻层的材料成分。The method of claim 7, wherein a material of the first photoresist layer and the second photoresist layer is selected from polymers or copolymers containing carboxylic acid groups. And the material composition of the first photoresist layer is different from that of the second photoresist layer.
  9. 如权利要求7所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层与该第二光阻层的材料是选自:压克力树脂、压克力-环氧树脂、压克力-美耐皿树脂、压克力-苯乙烯树脂或以上树脂的组合。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 7, wherein the material of the first photoresist layer and the second photoresist layer is selected from the group consisting of acrylic resin and acrylic -Epoxy resin, acrylic-melamine resin, acrylic-styrene resin or a combination of the above resins.
  10. 如权利要求7所述的在透明基材双面同时形成图案的方法,其特征在于,该第一光阻层主要吸收波长为400纳米以下的光波段,且该第二光阻层主要吸收波长为400纳米以上的光波段。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 7, wherein the first photoresist layer mainly absorbs light wavelengths below 400 nm, and the second photoresist layer mainly absorbs wavelengths It is an optical band above 400 nm.
  11. 如权利要求7所述的在透明基材双面同时形成图案的方法,其特征在于,在进行曝光时是使用一光源,该光源具有一第一特征波长与一第二特征波长,其中该第一特征波长主要是在400纳米以下的光,且该第二特征波长主要是在400纳米以上的光。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 7, wherein a light source is used when exposing, and the light source has a first characteristic wavelength and a second characteristic wavelength, wherein the first A characteristic wavelength is mainly light below 400 nanometers, and the second characteristic wavelength is mainly light above 400 nanometers.
  12. 如权利要求7所述的在透明基材双面同时形成图案的方法,其特征在于,在进行曝光时是使用一第一光源与一第二光源,该第一光源具有第一特征波长,主要是在400纳米以下的光,且该第二光源具有一第二特征波长主要是在400纳米以上的光。The method for simultaneously forming a pattern on both sides of a transparent substrate according to claim 7, wherein a first light source and a second light source are used when exposing, and the first light source has a first characteristic wavelength, mainly It is light below 400 nanometers, and the second light source has a light having a second characteristic wavelength mainly above 400 nanometers.
PCT/CN2018/092093 2018-06-21 2018-06-21 Method for simultaneously forming patterns on both sides of transparent substrate WO2019241945A1 (en)

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CN103985663A (en) * 2014-05-15 2014-08-13 中国电子科技集团公司第四十一研究所 Method for etching two-sided thin film circuit patterns into ultrathin quartz substrate in photoetching mode
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CN103489789A (en) * 2012-06-13 2014-01-01 刘毅楠 Ceramic substrate dual surface photolithography technique and structure
CN103985663A (en) * 2014-05-15 2014-08-13 中国电子科技集团公司第四十一研究所 Method for etching two-sided thin film circuit patterns into ultrathin quartz substrate in photoetching mode
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